origin of overpressure and pore pressure prediction in the baram province brunei accurate pore pressure prediction is critical in hydrocarbon exploration and is especially important in the rapidly deposited tertiary baram delta province where all economic fields exhibit overpressures commonly of high magnitude and with narrow transition zones a pore pressure database was compiled using wireline formation interval tests drillstem tests and mud weights from 157 wells in 61 fields throughout brunei overpressures are observed in 54 fields both in the inner shelf deltaic sequences and in the underlying prodelta shales porosity vs vertical effective stress plots from 31 fields reveal that overpressures are primarily generated by disequilibrium compaction in the prodelta shales but have been generated by fluid expansion in the inner shelf deltaic sequences however the geology of brunei precludes overpressures in the inner shelf deltaics being generated by any conventional fluid expansion mechanism e g kerogen to gas maturation and we propose that these overpressures have been vertically transferred into reservoir units via faults from the prodelta shales sediments overpressured by disequilibrium compaction exhibit different physical properties to those overpressured by vertical transfer and hence different pore pressure prediction strategies need to be applied in the prodelta shales and inner shelf deltaic sequences sonic and density log data detect overpressures generated by disequilibrium compaction and pore pressures are accurately predicted using an eaton exponent of 3 0 sonic log data detect vertically transferred overpressures even in the absence of a porosity anomaly and pore pressures are reasonably predicted using an eaton exponent of 6 5

controls on phosphorus regeneration and burial during formation of eastern mediterranean sapropels the carbon c and phosphorus p geochemistry of sapropels from four sites in the eastern mediterranean sea was determined to obtain more insight into the role of differences in sediment accumulation rates and bottom water anoxia on p regeneration and burial in sediments sediment corg porg with org organic ratios above redfield indicate enhanced regeneration of p relative to c from organic matter during formation of the most recent sapropel s1 and a pliocene sapropel odp site 969e i 282c release of p from fe oxides was relatively unimportant increased burial of ca p authigenic carbonate fluorapatite and or biogenic hydroxyapatite occurred but was of minor importance compared to the enhanced p release from organic matter for sapropel s1 corg porg and corg preac with reac reactive defined as the sum of organic fe bound authigenic and biogenic ca p ratios decreased with increasing sedimentation rate and oxygen exposure and decreasing water depth whether the water column in the deep basin was dysoxic semi euxinic s1 or euxinic pliocene does not appear to affect the estimated burial efficiencies of porg and preac enhanced corg burial under the euxinic water column explains the much higher corg porg and corg preac ratios in the pliocene sapropel on average 2860 and 760 respectively compared to sapropel s1 on average 530 and 160 respectively

duration of s1 the most recent sapropel in the eastern mediterranean sea as indicated by accelerator mass spectrometry radiocarbon and geochemical evidence slowly accumulated 5 cm kyr 1 and rapidly accumulated 5 20 cm kyr 1 sediments have been compared to define the initiation and termnation times of the most recent sapropel s1 in the eastern mediterranean sea the ba a1 ratio has been employed as a more persistent index of productivity than cg accelerator mass spectrometry radiocarbon dating of pelagic foraminifera indicates a maximum duration for increased ba a1 levels in s 1 from 9500 6000 uncorrected radiocarbon convention years b p in the rapidly accumulated sediments and 9500 5300 years b p in the slowly accumulated sediments this difference is ascribed to bioturbation affecting the slower accumulated s1 sediments in the two most rapidly accumulated s1 units from the adriatic and aegean seas there is a saddle of lower values centered on 7500 years b p in the corg and ba ai profiles so that the visual s 1 unit appears as a doublet geochemical evidence indicates that this intervening period is best interpreted as an episode of increased ventilation and bottom water oxygenation during the period of sapropel accumulation

the inorganic geochemistry of cretaceous black shales dsdp leg 41 in comparison to modern upwelling sediments from the gulf of california

fluid flow in sedimentary basins abstract the pore waters in sedimentary basins are ultimately derived from sea water meteoric water mineral bound water or from the underlying basement geochemically these waters initially have different signatures however the pore water compositions are easily altered by reactions with minerals or by mixing with other fluids meteoric water is driven downwards into sedimentary basins by the gravitational potential which approximately corresponds to the elevation of the ground water table above the sea or lake level it is difficult to model such flow however because the permeability on a large scale is almost impossible to represent realistically the continuity of confined sandstone and limestone aquifers plays an important role in determining the flux of meteoric water received by rocks in different parts of the basin but this is again difficult to predict pore water flow driven by compaction typically has velocities several orders of magnitude lower than what is commonly found in meteoric water flow regimes the average rate of upwards flow is lower than the rate of subsidence and the difference is the rate of incorporation of sea water in the topmost layer at the sea floor the salinity of formation water provides important constraints on fluid flow in sedimentary basins in the north sea basin and the gulf coast basin these types of data indicate that vertical mixing by compaction driven flow and convection is limited compaction driven flow obeys darcy s law but there are complex interdependencies between pressure permeability and compaction given the low compressibility of water the flow which can result from pressure release alone is very limited except on a local scale along permeable faults and fractures the main flow of pore water during burial is driven by compaction which is a slow process even when overpressure is released abruptly with a resulting increase in the net effective stress in the case of high permeability faults the flow into the fault from low permeability sedimentary rocks at depth may be rate limiting the displacement of pore water in adjacent sediments near the top of the faults may also slow down fluid flow on fractures that do not reach the sea floor modelling of fluid flow in sedimentary basins should be based on permeability distributions which are mostly determined by primary facies diagenesis and the tectonic history of the basin extensional tectonics produce a predominantly vertical fracture network which may serve as conduits for pore water flowing deep into the crust upward flow of hot fluids in basement fractures must have a high velocity in order to produce large thermal anomalies concentrations of dissolved components precipitate at the surface and form deposits of quartz and ore minerals if basement fractures are overlain by a thick sequence of soft sediments the rate of flow on the fractures will be reduced because of the low permeability in the sedimentary cover and conductive heat transport will dominate flow of water at high enough velocities to bring hot water to the surface and produce hot springs is most likely to occur in fractured basements rocks or well cemented sedimentary rocks concentrated precipitation of dissolved components will occur near the surface where the rate of cooling is highest also sediment hosted ores precipitated from flow of hot water on fractures are therefore likely to form before accumulation of thick overlying sedimentary sequences

redox zonation of elements at an oxic post oxic boundary in deep sea sediments abstract deep sea sediments generally provide limited evidence of redox control on the post depositional redistributions of elements this is because only a fraction of any element is reactive and observed elemental distributions are the result of a number of competing processes which are simultaneously active so that redox effects are not dominant a detailed investigation is reported of a core which is unusual in showing unequivocal evidence of direct redox control operating in a homogeneous environment that is relatively free from competing processes a progressive oxidation front has migrated slowly downwards into a uniform turbidite over a long period ca 250 ky the reactive fractions of several redox sensitive elements now show a remarkable degree of organisation around the redox boundary of this front with the different elements exhibiting individual responses solid phase enrichments are not coincident but are arranged in a clear succession of concentration peaks along the redox gradient from oxic to postoxic conditions the succession is mn i fe se and pt cu and pb v zn and sb and u the movement directions of most elements can be inferred from the peak shapes against the homogeneous turbidite background composition the system seems to have been essentially isolated within the sediment for most elements so that no loss or gain can be ascribed to redox processes exceptions are u and v which have been augmented by uptake from ocean bottom waters into the sediments by an efficient redox trap mechanism

present day stress of the central persian gulf implications for drilling and well performance abstract the present day state of stress in the persian gulf is poorly understood but has significant impacts on well drilling and performance the upper permian to lower triassic formation of kangan dalan persian gulf exhibits a complex structural context in the neighborhood of the oman mountains and the zagros orogenies this formation is divided into four reservoir layers k1 to k4 where three main lithologies limestone dolomite and anhydrite are alternating we conduct an analysis of the present day stress and natural fractures at the wellbore using full bore fmi logs leak off test and density logs for this purpose borehole breakout and tensile fracture data are used to determine orientation of s h furthermore density log leak off test and kirsch equation for tensile fracture formation in the wellbores are used to calculate the magnitude of s v s h and s h respectively vertical stress s v gradient at 3100 m depth approximates 20 mpa km 2 9 psi m indicating a bulk density of 2 04 g cm 3 a total of 131 drilling induced tensile fractures and 21 breakouts with an overall length of 262 m are observed in two wells indicating a mean maximum horizontal stress s h orientation of n53 18 45 for drilling induced tensile fracture ditf data and n50 10 79 for breakout data the mean orientation of s h rotates counterclockwise with depth from k2 n70 4 2 to k4 n40 5 1 reservoirs noticed correlation between these data and stress orientations from earthquake focal mechanism solution first of all indicates that the stresses are linked to the resistance forces generated by the arabia eurasia collision at the zagros orogeny and secondly confirms the reliability of focal mechanism solution data near continental collision zones in the kangan dalan formation the nw se main open fracture direction is found as a common regional direction which is sub perpendicular to the present day maximum horizontal stress minimum horizontal stress s h gradient in reservoir sections is estimated to be equal to 17 mpa km 2 5 psi m the concluded strike slip stress regime s h s v s h in the study area is consistent with the compressive regime in the zagros thrust fold belt the present day stress in the kangan dalan formation has implications for wellbore stability lost circulation and well inflow performance relationship ipr wells are more unstable if deviated toward the s v direction whereas well productivity and mud loss increase in wells deviated toward s h which conveys the idea of a strike slip faulting effect tends to keep the natural fractures open in that direction

a high resolution historical record of holocene anoxygenic primary production in the black sea i reconstruct the historical record of anoxygenic primary production in the black sea over the last 8200 years by an analysis of chlorobium carotenoids in sediments anoxygenic photosynthesis in the black sea occurs only when hydrogen sulfide containing deep water penetrates the euphotic zone the data show that the black sea has experienced large fluctuations in the extent of anoxygenic primary production and therefore the depth of the h2s chemocline throughout much of the holocene changes in the depth of the h2s chemocline also shift the dominant phytoplankton populations in the water column to noncarbonate bearing species and result in the formation of intense dark bands in sediments

sulfur isotopic trends and pathways of iron sulfide formation in upper holocene sediments of the anoxic black sea down core trends for extents of iron sulfidation in upper holocene microlaminated deposits of the black sea abyssal plain imply that most of the pyrite in these sediments is formed in the sulfidic water column and or very close to the sediment water interface sulfur isotopic data for pyrite within microlaminated muds from two localities in the deep basin show striking uniformity between sites and down core with a mean 34scdt value of 37 2 0 9 1 n 18 these isotopic trends support the hypothesis of early pyrite formation isotopic compositions of pyrite sulfur in the microlaminated bottom sediments are similar to those reported for particulate reduced sulfur collected in middepth sediment traps and to 34s values for water column dissolved sulfide within a narrow zone immediately below the o2 h2s interface these three sulfur reservoirs are distinctly different from the isotopic composition of ambient dissolved sulfide of the deep water column 175 m with 34s values for the deep dissolved sulfide reservoir being consistently lower by 2 to 4 these isotopic relationships suggest that iron sulfidation is occurring dominantly within a narrow shallow region at the top of the sulfidic water mass isotopic data from a fine grained turbidite collected in the deep basin and from rapidly accumulating iron monosulfide rich muds on the anoxic upper slope are enriched in34s relative to the microlaminated deposits the enrichments on the basin margin reflect a large component of iron sulfide formed during rapid burial a broad suite of geochemical data including sulfur isotopic results are consistent with an upper slope sediment source for the ubiquitous muddy turbidites of the deep basin the collective effects of reworking transport and redeposition result in a complete conversion of avs to pyrite with little additional iron sulfidation this conclusion is supported by a detailed isotopic mass balance the present isotopic study also highlights fundamental differences in the reactivities of the iron reservoirs distributed throughout the anoxic basin sediments of the upper slope and the genetically linked turbidites of the deep basin show similar extents of iron sulfidation that are significantly lower than those of the microlaminated deposits of the deep basin floor suggesting dramatically shorter timescales of iron reactivity for the microlaminated sediments of the deep basin importantly isotopic patterns from the modern black sea should assist greatly in the recognition and interpretation of ancient anoxia in the stratigraphic record

impact of fabric microcracks and stress field on shale anisotropy summary few data are available on shales in terms of seismic to ultrasonic properties and anisotropy although all are important with regards to imaging problems often encountered in such lithologies additionally mechanisms causing changes in these properties are not well documented due to the fine grain size of such materials and time required for testing under controlled pore pressure conditions the results presented here are derived from a set of experiments run on muderong shale with pore pressure control in order to evaluate the effect of stress magnitude and stress anisotropy on ultrasonic response this shale was noted to have a linear velocitymean effective stress response and extremely high anisotropy both likely the result of the presence of fluid filled cracks in a low permeability porous medium changes in velocity and vp vs ratios are dependent on both stress and smectite content s wave velocity is significantly affected by the presence of smectite in this and other shales and at low stress 20 mpa is less sensitive to stress change than p wave velocity vp vs ratios are noted to increase in this shale up to 20 mpa effective stress then decrease slightly due to stress induced loss of interlayer water in smectite intrinsic anisotropy comes from composition a strong compaction fabric and the presence of microfractures changes to ultrasonic anisotropy are the result of the magnitude of the stresses their orientation with respect to the fractures and the degree of stress anisotropy

evidence for the evolution of an oxygen minimum layer at the beginning of s 1 sapropel deposition in the eastern mediterranean the sediments of the eastern mediterranean basin contain a series of organic rich sapropels intercalated with organic poor nannofossil oozes until recently the timing of the onset of sapropel formation was not known accurately because of the low resolution achievable by conventional radiocarbon dating compilation of all available 14c ams dates show that the base of s 1 the most recent sapropel was initiated 8800 years b p 14c age corrected by 400 years for reservoir effect under a 500 m water column and moved progressively into deeper water reaching depths of 3500 m at 8200 years b p the linear correlation between the age of s 1 onset and water depth r 0 71 suggests that formation of sapropels moved into deeper water at a rate of 1000 m 200 year a model is suggested in which export production which sank below the well mixed surface layers 500 m was respired consuming dissolved oxygen in the levantine deep water until a threshold value was reached when sapropels began to be preserved in the sediment this resulted in a progressively deepening oxygen minimum zone with time until eventually the entire deep water in the basin was oxygen depleted assuming that the threshold value for sapropel formation was complete anoxia it was calculated that primary productivity in the basin during the deposition of s 1 was a factor of 5 greater than that found at present

on the late pleistocene holocene sapropel record of climatic and oceanographic variability in the eastern mediterranean sapropels and intercalated marls in a piston core from the eastern mediterranean are chemically and mineralogical distinct kaolinite smectite and total s contents fe a1 ba a1 co a1 mo a1 and v a1 are higher whereas quartz mg calcite illite contents si a1 ti a1 k a1 rb a1 and zr a1 are lower in the sapropels missing and ghost sapropels are identified by mineralogical and chemical properties that are not prone to diagenesis primary production was higher ba a1 and bottom water and or interstitial oxygenation was lower co a1 mo a1 ni a1 and v a1 during sapropel formation wind speeds quartz clay si a1 and zr a1 and bottom water salinities mg calcite calcite were higher during periods of marl formation sapropels represent a fundamentally different sedimentary facies whose formation is linked to changes in the hydrological balance in the basin driven by precessionally modulated changes in monsoon strength and subtropical precipitation changes which altered circulation production and sediment source areas

pore pressure estimation in reservoir rocks from seismic reflection data a method is used to obtain pore pressure in shaly sandstones based upon an acoustic model for seismic velocity versus clay content and effective pressure calibration of the model requires log data porosity clay content and sonic velocities to obtain the dry rock moduli and the effective stress coefficients as a function of depth and pore pressure the seismic p wave velocity derived from reflection tomography is fitted to the theoretical velocity by using pore pressure as the fitting parameter this approach based on a rock physics model is an improvement over existing pore pressure prediction methods which mainly rely on empirical relations between velocity and pressure the method is applied to the tune field in the viking graben sedimentary basin of the north sea we have obtained a high resolution velocity map that reveals the sensitivity to pore pressure and fluid saturation in the tarbert reservoir the velocity map of the tarbert reservoir and the inverted pressure distribution agree with the structural features of the tarbert formation and its known pressure compartments

organic matter production and preservation and evolution of anoxia in the holocene black sea dating of sediments collected in gravity cores during leg 1 of the 1988 r v knorr expedition to the black sea suggests that the onset of water column anoxia at 7 5 ka was virtually synchronous across the basin over a depth range of 200 2250 m a finely laminated organic carbon oc rich sapropel unit ii was produced as a result of this anoxia the trigger for increased oc production and development of anoxia was the spillover of saline waters through the bosporus that probably began at 9 0 ka and peaked between 7 0 and 5 5 ka this spillover enhanced vertical mixing and nutrient cycling and caused a short term 2 3 kyr burst in surface water productivity during the early part of unit ii deposition continued incursion of saline waters enhanced vertical stability and inhibited mixing of nutrients into surface waters thus limiting primary production and decreasing the oc flux to sediments beginning 5 5 ka concentration accumulation rate and degree of preservation of organic matter all decreased in the upper part of unit ii as a result of decreasing productivity but anoxia persisted throughout most of the water column the end of unit ii sapropel deposition was synchronous across the black sea as the result of the first blooms of the coccolith emiliania huxleyi which presumably marked an increase in surface water salinity above 11 and the beginning of unit i deposition the high coccolith carbonate fluxes that occurred during deposition of unit i diluted the oc concentration in the sediments but oc accumulation rates are about the same as those in upper part of unit ii

development of photic zone euxinia in the eastern mediterranean basin during deposition of pliocene sapropels abstract carotenoids were analysed in ca 1 cm thick subsamples of three laterally time equivalent sapropels from a west east transect of the eastern mediterranean basin to study euxinic periods during pliocene sapropel formation the amount of intact isorenieratene summed all trans and cis isomers ranged from non detectable at the base and top of a sapropel up to 140 g g sediment in the central parts isorenieratene accumulation rates at the central and western site are remarkably similar and increase sharply to levels of up to 3 0 mg m 2 yr 1 in the central part of the sapropel and then drop to low levels this pattern indicates an expansion of euxinic conditions reaching into the photic zone followed by deepening of the chemocline during deposition of this pliocene sapropel the sapropel from the easternmost site of the basin which contains less organic carbon shows much lower isorenieratene accumulation rates and even absence of isorenieratene in the central part of the sapropel ba al ratios indicate enhanced palaeoproductivity during sapropel formation supporting previously proposed models according to which increased productivity is the driving force for the generation of euxinic conditions

varve calibrated records of carbonate and organic carbon accumulation over the last 2000 years in the black sea sedimentologic and geochemical studies of box and gravity cores recovered from the black sea during the first leg of a multileg international black sea expedition in 1988 allow reconstruction of the basinwide holocene environmental history of the black sea in the deeper parts of the basin box cores typically recovered a flocculent surface layer fluff laminated coccolith marls of unit i 25 45 cm thick and the upper 5 10 cm of finely laminated dark colored sapropels of unit ii fine grained homogeneous mud turbidites are interbedded with units i and ii over much of the basin but the stratigraphie position of these turbidites differs from site to site the deposition of individual turbidites up to 15 cm thick does not appear to have significantly disturbed underlying laminae sediment trap deployments in the black sea suggest that light and dark laminae couplets represent annual increments of sedimentation i e varves we have therefore constructed a varve chronology for the sequence in order to correlate and date distinctive sedimentation and paleoenvironmental events distinctive groups of laminae in unit i can be correlated across the entire deeper basin a distance of more than 1000 km this implies a remarkable homogeneity in production accumulation and preservation of biogenic material over much of the black sea during deposition of unit i the change from deposition of finely laminated organic carbon rich sapropels unit ii to laminated more calcareous coccolith rich marls unit i is thought to represent the crossing of a salinity threshold for emiliania huxleyi the varve chronology sets this change at about 1 63 ka 1633 100 yr b p but the record of magnetic secular variation measured in several cores produces an age estimate of about 2 0 ka for the base of unit i or about 1 2 times the varve age the average of six calibrated accelerator mass spectrometry radiocarbon ages for the base of unit i is 2 7 ka or about 1 7 times the varve age following the initial change to coccolith dominated sedimentation deposition of sapropel resumed for at least one significant period 1 56 1 25 ka since 1 25 ka cycles of carbonate deposition with quasi decadal periodicities have produced characteristic darker and lighter assemblages of laminae these cycles may have been climatically driven geochemical analyses coupled with the varve ages adopted herein indicate that accumulation rates of carbonate are nearly an order of magnitude higher in unit i averaging 35 45 g m 2 yr 1 than in sapropelic unit ii which contains primarily detrital carbonate the accumulation of lithogenic components in parts of unit i is only 1 5 times the rate in unit ii deepwater organic carbon accumulation rates are somewhat higher in unit i 3 5 4 5 g m 2 yr 1 than in the upper part of unit ii organic carbon accumulation rates in unit i are somewhat antithetic to those of carbonate and on the basis of this and additional constraints placed by pyrolysis and carbon isotopic analyses of organic material it appears that terrestrial organic matter is an important component perhaps 25 of total organic carbon burial in the basin unit i in the western part of the black sea has a higher terrestrial organic component and higher accumulation rates of terrigenous clastic material than unit i in the eastern part this difference between eastern and western black sea is to be expected because of the major rivers that empty into the western black sea from eastern europe ukraine and russia shallow slope sites but still within euxinic bottom waters have lower organic carbon accumulation rates and lower pyrolysis hydrogen indices than deepwater basinal sites suggesting selective resuspension and oxidation of organic matter at basin margins and focusing of organic matter deposition toward the basin center a comparison of the black sea data with those from several open ocean sites with similar water depths showed no significant difference between organic carbon accumulation rates under oxic and anoxic conditions for a given bulk accumulation rate the organic carbon accumulation rates normalized to primary productivity are about the same in both settings

review of recent advances in the interpretation of eastern mediterranean sapropel s1 from geochemical evidence abstract the sediments of the eastern mediterranean basin contain c org enriched layers sapropels interbedded with the c org poor sediments which form by far the greater part of the record while it is generally appreciated that different surface ocean productivity and bottom water conditions are necessary for the formation and preservation of these two sediment types less attention has been paid to diagenetic effects which are an expected consequence of transitions between dramatically different bottom water oxygenation levels a geochemical interpretation has emerged of post depositional oxidation of the most recent sapropel s1 initially based on the relationship of the mn fe c org and s concentration depth profiles observed around s1 and the characteristic shapes of these elemental profiles known from other situations this indicates that post depositional oxidation has removed approximately half of the visual evidence of the sapropel 6 cm from a total of 12 cm in the deep basin the oxidation interpretation from redox sensitive element redistribution profiles has subsequently been consolidated with evidence from pore water o 2 no 3 mn 2 and fe 2 studies from characteristic solid phase ba profiles which yield palaeoproductivity records and from oxidation sensitive indicator trace elements i and se so far these geochemical observations have been concentrated in the deeper central parts of the basin where sediment accumulation rates are lower than on the basin margins and radiocarbon dating indicates that s1 formation occurred between 5 3 and 9 0 ky uncorrected conventional radiocarbon time it remains to be demonstrated whether or not these times are applicable to the entire e mediterranean basin the implications of these findings to guide sampling in future work on the s1 productivity episode and on older sapropels for palaeoenvironmental investigations are discussed

origin and transformation of organic matter in pliocene pleistocene mediterranean sapropels organic geochemical evidence reviewed abstract drilling of deep water post messinian sedimentary sequences by odp legs 160 and 161 in the mediterranean sea has shown that occurrence of organic carbon rich sapropels and sapropel like sediments extends from the levantine basin westward into the alboran basin in the eastern mediterranean sapropel deposition started in the early pliocene whereas in the western basin the onset of sapropel formation occurred later in the early pleistocene precessional cycles are apparently the primary external forcing for sapropel formation nevertheless the pattern of sapropel occurrence suggests that the precessional influence is modulated by the glaciation cycles large differences were observed in the organic carbon contents of sapropels recovered in the eastern and western mediterranean correspondence between organic carbon contents rock eval hydrogen index values and elemental c n ratios indicate that both variations in the production and preservation of marine organic matter have led to the accumulation of high amounts of organic matter in sapropels molecular organic geochemical compositions of sapropels from the eastern mediterranean further confirm that the major fraction of organic matter in sapropels is derived from marine algal sources and has undergone variable oxidation enhanced marine productivity and improved preservation of organic matter is central to sapropel formation accumulation of increased amounts of land derived material at times of sapropel formation is also evidenced supporting the hypothesis of significant periodic freshwater discharges

active post depositional oxidation of the most recent sapropel s1 in sediments of the eastern mediterranean sea abstract over a wide area of the eastern mediterranean basin two mn rich layers have been observed above the most recent sapropel s1 one immediately above the sapropel top and one a few centimetres closer to the sediment surface different mechanisms have been proposed to explain the occurrence of these two mn peaks either both peaks have a diagenetic origin in which case the upper mn peak is actively forming or the lower peak is actively forming and the upper peak has a different formation mechanism high resolution porewater including a gel sampler used for the first time in marine sediments and solid phase data are now used to demonstrate that the oxidation front is located at the level of the lower mn peak which therefore is presently being formed a barium organic carbon relationship is used to calculate the initial organic carbon profile of the s1 sapropel the palaeoproductivity profiles generated by this method demonstrate that the original sapropel unit was bounded by the upper mn peak this implies that the interval between the two mn peaks where a low organic carbon content is now observed was originally part of the sapropel the initially deposited organic carbon has been oxidised by a progressive downwards moving oxidation front the penetration depth of this oxidation front i e the distance between the two mn peaks is mainly determined by the organic carbon content the sediment accumulation rate and the bioturbation depth the upper mn peak appears to have formed as a result of either mn precipitation upon oxygenation of previously anoxic eastern mediterranean deep water or preservation of a surficial mn peak at the end of the high productivity episode in either case the upper mn peak marks the end of sapropel formation as indicated by the ba profiles this means that formation of the s1 sapropel ceased more recently than is indicated by radiocarbon dating of the visible top of s1

geochemical constraints on pliocene sapropel formation in the eastern mediterranean abstract seventeen eastern mediterranean pliocene sapropels from odp sites 964 966 967 and 969 some of which are coeval have been analysed for their geochemistry the sapropels are characterized by very high organic carbon contents up to 30 which are reported to be the result of both increased productivity and improved preservation although the organic matter in the sapropels is mainly of marine origin the 13 c org values and c n ratios appear terrestrial this is the result of anaerobic organic matter degradation which preferentially removed nitrogen and 13 c rich organic components a comparison with ti al profiles which mimic the precession index and a calculation of organic carbon accumulation rates indicate that sedimentation rates were at most 30 lower or at most 50 higher during sapropel formation thus sapropel formation lasted from between 2000 and 10 000 years at site 964 to between 4500 and 12 000 years at site 967 a synthesis of new data and a comparison with existing models indicates that productivity which increased due to extra nutrients supplied as a result of winter mixing and as a result of enhanced input by the nile was the driving mechanism behind sapropel formation the resulting sapropel formation was simultaneous at different depths but lasted longer in the part of the basin closest to the nile

enhanced regeneration of phosphorus during formation of the most recent eastern mediterranean sapropel s1 phosphorus regeneration and burial fluxes during and after formation of the most recent sapropel s1 were determined for two deep basin low sedimentation sites in the eastern mediterranean sea organic c p ratios and burial fluxes indicate enhanced regeneration of p relative to c during deposition of sapropel s1 this is largely due to the enhanced release of p from organic matter during sulfate reduction release of p from fe bound p also increased but this was only a relatively minor source of dissolved p pore water hpo4 concentrations remained too low for carbonate fluorapatite formation an increased burial of biogenic ca p i e fish debris was observed for one site estimated benthic fluxes of p during sapropel formation were elevated relative to the present day 900 to 2800 vs 70 to 120 mol m 2 yr 1 the present day sedimentary p cycle in the deep basin sediments is characterized by two major zones of reaction 1 the zone near the sediment water interface where substantial release of hpo4 from organic matter takes place and 2 the oxidation front at the top of the s1 where upward diffusing hpo4 from below the sapropel is sorbed to fe oxides the efficiency of aerobic organisms in retaining p is reflected in the low organic c p ratios in the oxidized part of the sapropel burial efficiencies for reactive p were significantly lower during s1 times compared with the present day 7 to 15 vs 64 to 77 budget calculations for the eastern mediterranean sea demonstrate that the weakening of the antiestuarine circulation and the enhanced regeneration of p both contributed to a significant increase in deep water hpo 4 concentrations during sapropel s1 times provided that sufficient vertical mixing occurred enhanced regeneration of p at the seafloor may have played a key role in maintaining increased productivity during sapropel s1 formation copyright 2002 elsevier science ltd

review of pore pressure prediction challenges in high temperature areas pore pressure prediction relies heavily on interpretation of seismic and well attributes such as velocity resistivity and density which capture porosity changes during shale compaction under vertical loading relationships such as eaton 1975 were developed in the gulf of mexico using a relatively simple lithological mix of geologically young sandstones and shale mudrocks at relatively low temperatures an alternative approach using data from the same region was more deterministic also with vertical stress e g hottman and johnson 1965 bowers 1995 another approach using mean stress developed by harrold et al 2000 used similar sand and shale sequences at relatively low temperatures from data in southeast asia basins all the above approaches can be shown to provide acceptable prediction of pore pressure in shale mudrocks in young rapidly deposited siliciclastic sequences such as the baram delta brunei tingay et al 2009 and along the west african margin swarbrick et al 2011 the re

a stable isotope study of pyrite formation in the late pleistocene and holocene sediments of the black sea the abundance and isotopic composition of total and pyrite sulphur have been determined in a core in the central black sea pyrite varies in concentration from roughly 2 wt in the sapropel unit 2 to 0 8 wt in the modern horizon unit 1 and ca 0 1 wt in the lowermost horizons of unit 3 lake beds an intermediate mud flow horizon and the upper part of the lake beds have similar values to those in the modern sediments the degree of pyritization dop is lowest 0 05 in the lower lake beds and highest 0 55 in unit 1 the sapropel has values of ca 0 48 34spyrite varies from a minimum of 37 in the sapropel to 33 in unit 1 up to 15 in the upper lake beds and 0 in the lower lake beds the unit 1 and sapropel values are similar to the 34s values reported by fry et al 1991 of dissolved sulphide immediately below the water column oxic anoxic interface 36 to 38 but significantly heavier than those in the deep waters of the basin ca 41 these results are interpreted as a reflection of the presence of four different types of pyrite in the sediments of the black sea 1 pyrite in units 1 and 2 that is formed within the upper part of the water column immediately below the oxic anoxic interface where 34s of dissolved sulphide is 36 2 pyrite in the mud flow layer lying between unit 1 and the sapropel unit 2 with a significantly heavier isotopic composition that was formed around the margins of the basin under conditions that were probably more closed with respect to dissolved sulphate than those in which the pyrite in units 1 and 2 were formed 3 pyrite in the upper part of the lake beds unit 3 that was formed under closed system conditions by reaction between excess reducible fe remaining in these freshwater sediments and downward diffusing sulphate and or sulphide from the overlying organic rich sapropel and 4 pyrite in the lower part of the unit 3 representing a phase formed from the ambient sulphate in the freshwaters of the late pleistocene lake the isotopic information supports earlier suggestions that pyrite in the modern sediments of the black sea forms mainly in the water column with only minor amounts forming in the sediment because of the severe fe limitation of the bottom sediments that accumulate 2 000 m below the main fe and hs reaction zone at the oxic anoxic interface at shallow depths in the water column

pore pressure estimation from mudrock porosities in tertiary basins southeast asia porosity reduction during mechanical compaction of a sediment generally has been assumed to be controlled by the increase in vertical effective stress which is convenient because vertical stress profiles may be readily calculated from density logs poroelasticity theory shows however that mean effective stress controls porosity reduction according to published data horizontal stresses increase with overpressure as well as with depth so mean stress and vertical stress profiles are poorly correlated in overpressured sections we have used wireline logs to compare the pore pressures estimated in mudrocks by relating porosity to mean effective stress and to vertical effective stress for overpressured tertiary sections in southeast asia wells from three different basins were studied mudrock porosities were estimated from the sonic log response and sorted by lithology according to the natural gamma log response two sets of normal compaction curves relating porosity to mean effective stress and to vertical effective stress were determined empirically by fitting data points where the pore pressure was thought to be hydrostatic these curves were then used to estimate the minimum pore pressure corresponding to mudrock porosity values in the overpressured sections the pore pressures inferred using the mean effective stress are consistent with direct measurements of pore pressure in the adjacent sands in contrast pore pressures inferred in mudrocks using the vertical effective stress are significantly lower for the overpressured sections implying discontinuities in the pore pressure profiles at lithological boundaries which cannot readily be explained we conclude that the pore pressures estimated using the vertical effective stress are wrong and that empirical relationships between porosity and vertical effective stress should not be used for estimating pore pressures porosity should be empirically related to mean effective stress instead

after the deluge mediterranean stagnation and sapropel formation in an east mediterranean marine core the upper sapropel begins soon after the start of a global event a very heavy precipitation which occurred in the equatorial latitudes during the late glacial early holocene this heavy precipitation in africa channelled by the nile river across 35 of latitude produced a low salinity surface layer in the east mediterranean in this confined basin with high bottom salinity the steep salinity gradient stratified the water column the stagnant bottom waters triggered the sapropel formation cretaceous sapropels in the tropical oceans may result from the same chain of events in warm humid climates with contrasting wet and dry seasonal rhythm

organic content and preservational controls in surficial shelf and slope sediments from the arabian sea pakistan margin abstract in the arabian sea organic rich deposits occur on the continental slope at depths roughly coincident with the impingement of an intense water column oxygen minimum zone omz this relationship has often been taken as causal and such deposits are often proposed as modern analogues of organic rich facies from the palaeorecord however there are numerous other potential preservational controls on continental margins and their relative importance remains unclear and much debated we report the results of organic inorganic and stable c isotope analyses on surficial sediments from three transects of the pakistan margin ranging in depth from well above to well below the omz organic carbon c org and total nitrogen n total contents show expected mid slope maxima although these do not mirror bottom water dissolved o 2 profiles maximal values are observed near the lower boundary of the omz or even in homogenous sediments below it together lignin yields and 13 c org values indicate a general paucity of terrigenous organic matter om this information combined with c org n total relationships suggests that the om contents of all sediments are dictated by differing accumulation of a predominant marine fraction while there are no obvious redox related differences in c org n total or om hydrogen richness across the margin there are clear minima in 13 c org within the omz in apparent contradiction with maximal accumulation of marine om the latter phenomenon is ascribed either to local source effects such as variable algal isotopic signatures or to differences in om preservation state possibly linked to bottom water redox conditions this remains to be clarified but along with the rough correspondence between mid slope sedimentary c org maxima and bottom water o 2 minima may indicate that o 2 availability is an important factor in determining sedimentary om content on this margin however evidence from redox sensitive indicators i c org mn al for persistent accumulation of om rich deposits under oxidizing conditions in homogeneous sediments below the omz clearly indicates that o 2 availability is not the sole or over riding control on om distributions

factors controlling the thermo mechanical deformation of oil shales implications for compaction of mudstones and exploitation abstract six permian to miocene organic matter rich mudstones were subjected to unconfined compression tests under three thermo mechanical regimes the aims of this study were to assess the role of factors that control deformation and highlight implications for mudstone compaction and oil shale exploitation axial strain ranged from 1 9 to 23 at 25 c 5 3 70 mpa 12 79 at 25 310 c 31 42 mpa and 1 38 40 at 25 350 c 0 8 mpa the axial strain data showed that the principal factor controlling mudstone compaction is temperature with a secondary role for effective stress during high temperature tests dehydration of smectite in the 94 150 c interval resulted in a distinct axial strain effect decomposition of organic matter and other minerals caused visible strain only above 280 c tests up to 350 c resulted in mass loss of 4 54 43 8 wt with 1 1 8 wt due to organic matter a strong positive correlation was found between the petroleum generation indices 4 6 55 8 and expulsion efficiencies 38 6 96 2 while compaction 0 68 51 4 correlated with axial strain 1 38 40 solid volume loss 2 55 12 15 due to petroleum generation from kerogen resulted in an increase in porosity 1 56 6 36 low rate heating and low retorting temperature are necessary to optimise yield from oil shale exploitation

african monsoons an immediate climate response to orbital insolation the croll milankovitch astronomical theory of climate1 3 has received strong support from the evidence of a linear climatic forcing by obliquity and precession although nonlinearity had to be assumed for eccentricity4 5 moreover interglacials have appeared to be controlled by the orbital insolation6 although a phase shift of 6 000 5 000 yr is seen between an astronomical climate index and terrestrial climate indicators dominated by the northern ice sheet dynamics climate proxy data of low latitudes are less directly dependent on the ice sheets here it is shown that during the past 464 000 yr african monsoons signalled by the east mediterranean sapropels were heaviest always and only when a northern summer monsoon index computed from the orbital variation of insolation reached maximum values this occurred during all the interglacials but also twice during glacial periods thus tropical aridity is not the single climatic pattern of glacial periods an immediate terrestrial climate response to orbital variations of insolation is established

the ordovician sierras pampeanas puna basin connection basement thinning and basin formation in the proto andean back arc article i nfo the ordovician sierras pampeanas located in a continental back arc position at the proto andean margin of southwest gondwana experienced substantial mantle heat transfer during the ordovician famatina orogeny converting neoproterozoic and early cambrian metasediments to migmatites and granites the high grade metamorphic basement underwent intense extensional shearing during the early and middle ordovician contemporaneously up to 7000 m marine sediments were deposited in extensional back arc basins covering the pre ordovician basement extensional ordovician tectonics were more effective in mid and lower crustal migmatites than in higher levels of the crust at a depth of about 13 km the separating boundary between low strain solid upper and high strain lower migmatitic crust evolved to an intra crustal detachment the detachment zone varies in thickness but does not exceed about 500 m the formation of anatectic melt at the metamorphic peak and the resulting drop in shear strength initiated extensional tectonics which continued along localized ductile shear zones until the migmatitic crust cooled to amphibolite facies p t conditions p t d t data in combination with field evidence suggest significant ca 52 crustal thinning below the detachment corresponding to a thinning factor of 2 1 ductile thinning of the upper crust is estimated to be less than that of the lower crust and might range between 25 and 44 constituting total crustal thinning factors of 1 7 2 0 while the migmatites experienced retrograde decompression during the ordovician rocks along and above the detachment show isobaric cooling this suggests that the magnitude of upper crustal extension controls the amount of space created for sediments deposited at the surface upper crustal extension and thinning is compensated by newly deposited sediments maintaining constant pressure at detachment level thinning of the migmatitic lower crust is compensated by elevation of the crust mantle boundary the degree of mechanical coupling between migmatitic lower and solid upper crust across the detachment zone is the main factor controlling upper crustal extension basin formation and sediment thickness in the back arc basin the initiation of crustal extension in the back arc however crucially depends on the presence of anatectic melt in the middle and lower crust consumption of melt and cooling of the lower crust correlate with decreasing deposition rates in the sedimentary basins and decreasing rates of crustal extension

anoxia vs productivity what controls the formation of organic carbon rich sediments and sedimentary rocks discussion the prevailing explanation for the origin of organic rich sediments and rocks invokes deposition under conditions of anoxia however recent research suggests that high primary production and not water column anoxia provides the first order control on the accumulation of organic rich facies in the modern oceans oxygen minima do not appear to have any direct effect on carbon accumulation in continental margin or marginal sea environments sediments accumulating in the modern black sea the type euxinic basin are not particularly enriched in organic matter despite the presence of an anoxic water column although a sapropel containing extremely high carbon concentrations was deposited during the holocene at a time when the basin was oxic results of a recently published co pled ocean atmosphere model indicate that during the cretaceous thermohaline and surface circulation in the oceans was similar to or more intense than modern conditions despite the overall equable climate such conditions confound the idea that circulation in the cretaceous atlantic for example was punctuated by oceanic anoxic events brought about by more sluggish circulation sporadic temporal and spatial increases in primary production reflecting changes in the behavior and or state of the ocean atmosphere system constitute a more tenable explanation for the occurrence of modern and quaternary carbon rich sediments and cretaceous black shales consequently the fundamental control on the accumulation of carbon rich facies in the oceans and marginal seas is not the presence or absence of anoxia

assessment of β the compression coefficient of mudstones and its relationship with detailed lithology abstract the mechanical compaction of soils and fine grained sediments is commonly described in soil mechanics by a relationship between void ratio and effective stress the relationship is defined by two parameters derived from the slope of the line relating void ratio and log effective stress and e the void ratio at a chosen effective stress e g 100 kpa and e are strongly correlated and are related to the atterburg liquid limit which is itself related in a general way to the grain size and mineralogy of the sediment in general finer grained sediments have higher initial void ratios and compact faster than coarser sediments porosity depth trends for mudstones in sedimentary basins are therefore strongly influenced by lithology steps or changes in the slope of porosity depth trends can be caused by lithological change rather than changes in the pressure regime a method is presented to evaluate for mechanically compacted mudstones using porosities determined from the density log fdc and based on the relationship between effective stress and void ratio developed in soil mechanics the method allows one to obtain rapidly approximate values for materials for which it is essentially impossible to obtain compaction parameters experimentally calculated values for mudstones in wells 8 3 2 and 30 2 1 on the norwegian margin vary between 0 2 and 0 65 the values correlate positively with the clay particle content of the mudstones which we have determined for 50 mudstone samples from the same wells the strong link between mudstone lithology and suggests that a downhole log may be a useful way to visualize downhole variations in mudstone lithology the log also shows how lithology affects the rate of porosity loss with depth or effective stress for example porosity in mudstones within both wells 8 3 2 and 30 2 1 is essentially constant over 700 m sections of normally pressured mudstones the log and grain size data indicate that this reflects changes in the lithological character and of the muds and not as commonly inferred a change in the pressure regime

an analysis of horizontal microcracking during catagenesis example from the catskill delta complex horizontal bitumen filled microcracks are common within clay laminae of the finely laminated organic carbon rich shale in the lower half of the heavily jointed upper devonian dunkirk shale western new york state such cracks are not found higher in the dunkirk shale where moderate bioturbation resulted in a relatively porous and permeable microfabric horizontal microcracks in a hydrocarbon source rock that carries regional vertical joints indicating a horizontal least principal stress owe their presence to material properties of the fractured shale and the magnitude and orientation of the crack driving stress during kerogen maturation three material properties favored the horizontal initiation of microcracks in the dunkirk shale 1 the abundance of flat kerogen grains oriented parallel to layering 2 a marked strength anisotropy in large part caused by the laminated nature of the rock and 3 the tight strongly oriented planar clay grain fabric produced by gravitational compaction of flocculated clay at shallow burial depth the latter was especially important to sustaining elevated pore pressure the crack driving stress which was generated by the conversion of kerogen to bitumen poroelastic deformation of the low permeability laminated shale pressurized by catagenesis perhaps enhanced by compaction disequilibrium prior to kerogen conversion elevated the in situ horizontal stress in excess of the vertical stress which remained constant during pore pressure buildup thereby favoring the propagation of microcracks in the horizontal plane

overpressures in the taranaki basin distribution causes and implications for exploration analysis of subsurface pressure data from taranaki basin using direct e g repeat formation tester and indirect measurements drilling parameters and wireline log data such as sonic and resistivity indicates the presence of three pressure zones a near hydrostatic regime zone a that extends across the entire basin and to varying depths an underlying overpressured regime zone b with pressures approximately 1100 psi 7 584 mpa above hydrostatic that extends throughout the manaia graben and north along the eastern basin margin at depths of 1900 to 4100 m 6234 13 451 ft and a third regime zone c with approximately 2100 psi 14 479 mpa overpressure that directly underlies zone a and zone b in different parts of the basin although well penetrations are limited the primary cause of overpressure is interpreted to be disequilibrium compaction preserved in upper eocene and oligocene marine shales in parts of the basin hydrocarbon generation and in particular cracking to gas at high maturities is interpreted to contribute to overpressures the overpressures drain laterally and vertically into permeable units intervening transition zones seals comprise lithologic boundaries diagenetic zones and fault planes oligocene carbonates although commonly thin provide an effective barrier to vertical hydraulic communication over much of the basin the manaia graben is a partially closed system with overpressures retained by a complex combination of a top shale seal overlying a regional sequence boundary lithologic barriers within fault compartments fault planes and subcropping sequences episodic fault breach enables vertical transfer of fluids from zone b to zone a in a dynamic fault valve process to date all oil reserves have been found in zone a a large proportion of gas condensate reserves are within zone b and no commercial reserves have been established within zone c the spatial definition of these zones and the appropriate pressure regime is important for well design drilling safety determining hydrocarbon column heights and gas expansion factors and for exploration migration analysis regional analysis of pressure regimes can identify subsurface barriers and seals faults in particular are key elements in fluid migration and the focusing of liquids at abrupt pressure transitions the strength of fault planes and diagenetic zones is the likely control on dynamic fluid release zone c has been very lightly explored and may represent a potential for large dry gas accumulations the zone may be sealed by a diagenetic zone crosscutting lithologic boundaries conventional mapping horizons

overpressure retardation of organic matter maturation a kinetic model and its application abstract a kinetic model t p ro has been developed to address the issue that overpressure increases the activation energies during organic matter maturation and that the retardation of organic matter maturation by overpressure is due to the fact that organic matter is hindered from progressive molecular ordering under overpressured conditions the mean effective stress i e mean stress minus pore pressure is much lower and the pore pressure is usually higher than under hydrostatic pressure conditions as a result the progressive molecular ordering of the vitrinite such as the aromatization is retarded and the vitrinite reflectance can hardly be increased the reflectance values predicted by t p ro model as it has been applied to the well ld3011 at yinggehai basin in south china sea are similar to the measured ones the kinetic model predicts that overpressure can cause the oil window floor and the peak oil generation to shift to greater burial depth in the case of yinggehai basin the local geological conditions are prone to generate light hydrocarbons and natural gas instead of oil hence they constitute the predominant products in this high temperature heating rate basin

the ability of rock physics models to infer marine in situ pore pressure pore fluid pressure is an important parameter defining the mechanical strength of marine sediments obtaining high spatial resolution in situ pore pressure measurements in marine sediments however is a challenge and as a result only a handful of in situ pore pressure measurements exist at scientific drill sites integrating rock physics models with standard iodp odp measurements provides a potentially widely applicable approach for calculating in situ pore pressure here we use a rock physics approach to estimate in situ pore pressure at two scientific ocean drill sites where in situ pressure is well constrained odp site 1173 used as reference for normal hydrostatic fluid pressures and odp site 948 where previous studies infer high fluid pressures 0 45 0 95 where the pore pressure ratio is defined as the pore pressure above hydrostatic divided by the difference between the largest principal stress and hydrostatic stress our analysis indicates that the rock physics method provides an accurate low precision method for estimating in situ pore pressure at these drill sites and sensitivity analysis indicates this method can detect modestly high 0 6 pore pressure at the 95 confidence level this approach has broad applicability because it provides an inexpensive high resolution meter scale method for retrospectively detecting and quantifying high pore pressure at any drill site where quality wireline logs and ocean drilling data exist

organic matter and trace element rich sapropels and black shales a geochemical comparison a distinct pliocene eastern mediterranean sapropel i 282 recovered from three ocean drilling program odp leg 160 sites has been investigated for its organic and inorganic composition this sapropel is characterized by high organic carbon corg and trace element contents and the presence of isorenieratene derivatives the latter suggests that the base of the photic zone was sulphidic during formation of the sapropel combined with evidence of bottom water anoxia preservation of laminae high redox sensitive trace element contents and the abundance and isotopic composition of pyrite this leads to the tentative conclusion that almost the entire water column may have been anoxic this anoxia resulted from high productivity and not from stagnation because an approximation of the trace element budget during sapropel formation shows that water exchange with the western mediterranean is needed entire water column anoxia has been suggested earlier for several black shales with regard to the depositional environment and the corg content however only the cenomanian turonian boundary event ctbe black shales appear to be comparable to this sapropel the proposed trace element removal mechanism of scavenging and co precipitation in an anoxic water column is thought to be similar for both types of deposits the ultimate trace element source for the sapropel however is seawater whereas it is hydrothermal and fluvial input for ctbe black shales because they have a larger temporal and spatial distribution nonetheless the corg rich eastern mediterranean pliocene sapropel discussed here may be considered to be a younger analogue of ctbe black shales

cyclic variations in the chemical composition of eastern mediterranean pliocene sediments a key for understanding sapropel formation abstract two pliocene mediterranean sediment cores from ocean drilling program odp leg 160 sites 964 pisano plateau ionian basin and 967 lower northern slope of eratosthenes seamount south of cyprus have been analyzed for major and minor elements si ti al fe mg ca k ba cr ni v zn zr by x ray fluorescence analysis at a depth resolution of 3 to 4 cm a total of 430 samples core 964c 9h comprises five sapropels with up to 9 7 total organic carbon toc one 2 5 m thick turbidite and a 50 cm segment of a second turbidite whereas core 967b 9h contains eight sapropels with toc contents of up to 6 7 cyclic variations in carbonate content and detrital matter composition are evident at both sites at site 964 pisano plateau terrigenous detrital matter chemistry reflects periods of stronger saharan dust input higher si al and zr al ratios alternating with fluvial input from the northern borderlands higher mg al ratios cyclicity is not well expressed at this location because turbidites and winnowing occur site 967 eratosthenes seamount sediments are strongly influenced by discharge from the nile river during humid periods low k al and mg al ratios at site 967 sapropels occur only during periods of enhanced nile discharge with correspondingly lower si al ti al mg al k al and zr al ratios accumulation rates of carbonate and terrigenous detrital matter were 30 lower during such episodes because of the reduction in eolian input and carbonate production and or carbonate dissolution periodical ba enrichments which are not only seen in the sapropels but in every k al minimum document the association of enhanced bioproductivity and sapropel formation as calculated from excess ba concentrations productivity increased by up to a factor of five during intervals of intensified nile runoff fluviatile discharge seems to be responsible for an enhanced input of nutrients and suspended matter containing low mg al and k al ratios based on organic carbon concentrations episodes of sapropel formation lasted at least from 1000 to 4000 years at site 964 and from 2000 to 6000 years at site 967 periods of enhanced bio productivity as defined by ba enrichments lasted from 8000 to 12 000 years at site 967 episodes of high river discharge and corresponding nutrient input as well as conditions of sapropel formation seem to have lasted longer in the eastern part of the basin site 967 than at the pisano plateau site 964

compaction and overpressuring in pleistocene sediments on the louisiana shelf gulf of mexico abstract pleistocene shales on the louisiana shelf have accumulated at relatively high sedimentation rates 1400 m ma resulting in compaction disequilibrium and excess pore pressures mathematical models of gravitational compaction are useful tools for quantifying the rates at which various diagenetic processes affect porosity effective stress and pore pressure one of the major constraints in compaction modelling is characterising the mechanical compressibility of the sediments under one dimensional loading soil mechanics theory provides a useful framework by quantifying sediment effective stress in terms of two mechanical parameters both of which can be determined from uniaxial compression tests using a tri axial apparatus these mechanical parameters have been measured for natural and remoulded sediments and many values are published in the geotechnical literature if mechanical compaction is quantified accurately then it is possible to distinguish and quantify other porosity reducing mechanisms in sedimentary basins this paper re examined published data from two wells in the eugene island area of the louisiana shelf in order to characterize the effective stress behaviour of shale sediments mechanical parameters were estimated and found to agree with values from consolidation tests on core samples recovered from nearby sites during leg 96 of the deep sea drilling program using a continuum mechanics model for gravitational compaction the estimated mechanical parameters were used to forward model the sudden increase in pore pressure at 2 km burial depth the modelling results gave a lower bound on the effective permeability of the shallow nearly normally pressured section and an upper bound for the deeper overpressured section the effective permeability in the overpressured section has to be only about 5 times lower than that of the normally pressured section in order to account for the pressure contrast theoretical models for the effective permeability of sand shale mixtures suggest that the permeability difference between the two sections may be due to variations in the shale fraction

benthic phosphorus regeneration net primary production and ocean anoxia a model of the coupled marine biogeochemical cycles of carbon and phosphorus we examine the relationships between ocean ventilation primary production water column anoxia and benthic regeneration of phosphorus using a mass balance model of the coupled marine biogeochemical cycles of carbon c and phosphorus p the elemental cycles are coupled via the redfield c p ratio of marine phytoplankton and the c p ratio of organic matter preserved in marine sediments the model assumes that on geologic timescales net primary production in the oceans is limited by the upwelling of dissolved phosphorus to the photic zone the model incorporates the dependence on bottom water oxygenation of the regeneration of nutrient phosphorus from particulate matter deposited at the water sediment interface evidence from marine and lacustrine settings modern and ancient demonstrates that sedimentary burial of phosphorus associated with organic matter and ferric oxyhydroxides decreases when bottom water anoxia dysoxia expands steady state simulations show that a reduction in the rate of thermohaline circulation or a decrease of the oxygen content of downwelling water masses intensifies water column anoxia dysoxia and at the same time increases surface water productivity the first effect reflects the declining supply of oxygen to the deeper parts of the ocean the second effect is caused by the enhanced benthic regeneration of phosphorus from organic matter and ferric oxyhydroxides sedimentary burial of organic carbon and authigenic calcium phosphate mineral francolite on the other hand is promoted by reduced ocean ventilation according to the model global scale anoxia dysoxia leads to a more efficient recycling of reactive phosphorus within the ocean system consequently higher rates of primary production and organic carbon burial can be achieved even when the continental supply of reactive phosphorus to the oceans remains unchanged

investigation of present day in situ stresses and pore pressure in the south cambay basin western india implications for drilling reservoir development and fault reactivation abstract this work presents the assessment of present day stresses and pore pressures in a prolific onshore hydrocarbon bearing field located in the southern cambay basin western india through the development of a comprehensive geomechanical model a c quality wellbore breakouts inferred from the available four arm caliper logs and anisotropy analyses of dipole shear sonic logs indicate a ne n40 e to n50 e azimuth for maximum horizontal stress shmax pore pressure characterisation reveals mild overpressure in the lower eocene shale caused by disequilibrium compaction resulting from high sedimentation rates vertical stress sv was derived from density logs and a poroelastic strain model was employed to quantify the minimum shmin and maximum horizontal stress components shmax being later validated with leak off tests based on the relative magnitudes of three principal in situ stress components post rift strata upper eocene and younger reveal a normal faulting regime sv shmax shmin whereas a normal fault to strike slip faulting shmax sv shmin transition is observed in the syn rift unit lower eocene and older the mohr coulomb rock failure criterion was utilised to depict the shear failure gradient to prevent wellbore instability and results were validated with caliper logs we have also analysed the fault reactivation potential at reservoir level using frictional fault theory and stress polygons the results indicate that a minimum of 31 increase in pore pressure by fluid injection and hydraulic fracturing treatment can cause shear slippage of critically oriented faults resulting in induced seismicity our study has helped to understand the interplay between stress states and pore fluid pressure and their impact on reservoir development drilling and completion design and fault stability analysis in any given oil and gas field

mediterranean quaternary sapropels an immediate response of the african monsoon to variation of insolation abstract in the subsurface of the east mediterranean sea eleven discrete basin wide organic rich black sapropels were deposited during the last 465 000 years they are dated by oxygen isotopic chronostratigraphy the most recent sapropel has been shown to be the consequence of heavy nile river summer floods due to increased monsoonal summer precipitation over ethiopia and not of scandinavian ice sheet meltwater influx into the east mediterranean sea as was previously believed while most sapropels were deposited during interglacials two thick sapropels formed during glacial periods as shown by their position in the oxygen isotopic stratigraphy and by their pollen record in core rc9 181 the new evidence presented here is that the sapropel sequence in this core including the two glacial sapropels correlates on a one to one basis with the highest values of an index of insolation on top of the atmosphere the concept of this index derives from an analysis of the african monsoon process the index variation is computed for the last 465 000 years from the caloric northern summer insolation in the tropical latitudes controlled by variations of the earth s orbital parameters it is conjectured that this index might be linked through the climate system to the monsoonal precipitation which in africa produces the nile river summer flood

sulphidic mediterranean surface waters during pliocene sapropel formation sapropels organic matter rich layers are common in neogene sediments of the eastern mediterranean sea the formation of these layers has been attributed to climate related increases in organic matter production1 2 3 and increased organic matter preservation due to oxygen depletion in more stagnant bottom waters2 3 here we report that eastern mediterranean pliocene sapropels4 contain molecular fossils of a compound isorenieratene known to be synthesized by photosynthetic green sulphur bacteria suggesting that sulphidic euxinic and therefore anoxic conditions prevailed in the photic zone of the water column these sapropels also have a high trace metal content which is probably due to the efficient scavenging of these metals by precipitating sulphides in a euxinic water column the abundance and sulphur isotope composition of pyrite are consistent with iron sulphide formation in the water column we conclude that basin wide water column euxinia occurred over substantial periods during pliocene sapropel formation in the eastern mediterranean sea and that the ultimate degradation of the increased organic matter production was strongly influential in generating and sustaining the euxinic conditions