atlantic paleogene biserial heterohelicid foraminifera and oxygen minima through most of the paleogene the planktonic foraminifera called biserial heterohelicids record the most depleted carbon isotope ratios among planktonic foraminiferal species they are interpreted to occupy an oxygen minimum habitat stronger interplanktonic carbon isotope contrasts and more enriched near surface carbon isotope values correspond to higher abundances of biserial heterohelicids this group appears to have preferred latitudes and times when the oxygen minimum was well developed biserial heterohelicid generic and specific diversity are directly related to the interplanktonic carbon isotope contrast minimal specific diversity characterizes the oligocene when interplanktonic and surface to bottom carbon isotope contrasts were consistently low diversity and abundance decreases were coeval with increased oceanic ventilation

a tsunami deposit at the cretaceous tertiary boundary in texas at sites near the brazos river texas an iridium anomaly and the paleontologic cretaceous tertiary boundary directly overlie a sandstone bed in which coarse grained sandstone with large clasts of mudstone and reworked carbonate nodules grades upward to wave ripple laminated very fine grained sandstone this bed is the only sandstone bed in a sequence of uppermost cretaceous to lowermost paleocene mudstone that records about 1 million years of quiet water deposition in midshelf to outer shelf depths conditions for depositing such a sandstone layer at these depths are most consistent with the occurrence of a tsunami about 50 to 100 meters high the most likely source for such a tsunami at the cretaceous tertiary boundary is a bolidewater impact

de glauconiarum origine the glauconitic facies is widespread on present day continental shelves from 50 s to 65 n and at water depths between 50 and 500 m and is in particularly great abundance on the upper slope and outer shelf between 200 and 300 m it is also common in many ancient rocks of post late precambrian age it occurs as sand to pebble sized essentially green particles granular facies but also as a surface coating on particles and hardgrounds and as a diffuse impregnation film and diffuse facies we suggest the replacement of the term glauconite which has been interchangeably used to designate a morphological form and a specific mineral by glaucony facies and glauconitic smectite and glauconitic mica as end members of the glauconitic mineral family the widely accepted model of burst and hower for glauconitization requires a degraded micaceous 2 1 layer lattice structure parent clay mineral however detailed analysis of numerous samples of recent glaucony reveals that such a parent substrate is exceptional the model therefore requires modification generally the parent material is carbonate particles argillaceous kaolinitic faecal pellets infillings of foraminiferal tests various mineral grains and rock fragments that pass gradually into the commonly occurring green grains we show that the process of glauconitization is achieved by de novo authigenic growth of automorphous crystallites in the pores of the substrate accompanied by progressive alteration and replacement of the substrate it is this two fold evolution that causes the verdissement of granular substrates macrofossils and hardgrounds the authigenic mineral is an iron rich and potassium poor glauconitic smectite while new smectites are growing into the remaining pore space the earlier smectites are modified by incorporation of potassium producing decreasingly expandable minerals with a non expandable glauconitic mica as the end member this mineralogical diversity of the glauconitic mineral family explains the highly variable physical and chemical properties of glaucony four categories nascent little evolved evolved and highly evolved glaucony are distinguished glauconitization appears to be controlled by a delicate balance between degree of physical confinement of a particle and the amount of ionic exchange between the micro environment and ambient open marine sea water the optimum conditions for glauconitization are those of semi confinement as a result the interior of a grain is more glauconitized than its less confined periphery similarly for identical substrate types large grains 500 m provide more favourable substrates for glauconitization than lesser confined small grains on a larger scale the formation of glaucony is governed by the availability of iron and potassium and the balance between detrital influx and winnowing low accumulation rates expose grains to the open marine environment for sufficiently long times 105 106 years for highly evolved glaucony

dinoflagellate cysts sea level changes and planktonic foraminifers across the cretaceous tertiary boundary at el haria northwest tunisia abstract dinoflagellate cysts and planktonic foraminifers have been studied from the cretaceous tertiary k t boundary interval at el haria northwest tunisia a high resolution integrated biostratigraphy is presented the k t boundary is drawn at the level of extinction of cretaceous planktonic foraminifers and is coincident with the first occurrence of the dinoflagellate cyst species danea californica the final extinction of planktonic foraminifers is foreshadowed by a reduction in their total abundance some 5 kyr earlier at the base of the boundary clay this reduction is coeval with reported anomalies in siderophyle elements and 13 c values in the same area dinoflagellate cysts do not show accelerated rates of extinction at k t time associations of dinoflagellate cysts however change drastically and parallel changes in relative numbers of sporomorphs spores and pollen and in the quantity of land derived organic matter jointly these changes reflect a rapidly falling sea level during the final 17 kyr of the mesozoic which culminates at the level of the k t boundary this steep sea level fall at k t time represents a peak regressive pulse at the end of the well documented latest cretaceous regressive trend this short term sea level fall might show to be a wide spread phenomenon which could have caused an excess shrinking of the already reduced areal extent of marginal seas since deep waters in cretaceous oceans were primarily produced in shallow marginal seas the rate of formation of deep water might have been minimized at k t time minimum rates of formation of deep water might have curtailed the slow upward mixing of relatively cool and nutrient rich deeper water through which the thermocline weakened and surficial waters became depleted in nutrients consequently phytoplankton productivity rapidly diminished which in combination with a weakened thermal gradient pushed the highly depth stratified cretaceous planktonic foraminiferal fauna to extinction over a period of time of some 5 kyr guembelitria cretacea was the sole planktonic foraminifer which could accommodate to the low productivity conditions the oscillating rise in sea level at the beginning of the cenozoic reinforced the upward mixing of relatively cool and nutrient rich deeper water steepened the thermocline and replenished the photic layer with nutrients concomitant niche differentiation in the photic layer progressively stimulated morphological innovation amongst early cenozoic planktonic foraminifers the final return of normally sized planktonic foraminifers and of stable and well balanced dinoflagellate cyst associations at about 125 kyr after the k t boundary seems to indicate that primary productivity and niche differentiation in the photic layer begin to revert to optimum levels the earliest cenozoic planktonic foraminiferal species globoconusa minutula and parvularugoglobigerina fringa are thought to have developed from a benthic foraminiferal species rather than having a planktonic ancestry

proximal cretaceous tertiary boundary impact deposits in the caribbean trace element isotopic and mineralogic studies indicate that the proposed impact at the cretaceous tertiary k t boundary occurred in an ocean basin although a minor component of continental material is required the size and abundance of shocked minerals and the restricted geographic occurrence of the ejecta layer and impact wave deposits suggest an impact between the americas coarse boundary sediments at sites 151 and 153 in the colombian basin and 5 to 450 meter thick boundary sediments in cuba may be deposits of a giant wave produced by a nearby oceanic impact on the southern peninsula of haiti a approximately 50 centimeter thick ejecta layer occurs at the k t boundary this ejecta layer is approximately 25 times as thick as that at any known k t site and suggests an impact site within approximately 1000 kilometers seismic reflection profiles suggest that a buried approximately 300 km diameter candidate structure occurs in the colombian basin

antarctic marine temperatures late campanian through early paleocene an oxygen isotope paleotemperature study of benthic foraminifera from the upper campanian through lower paleocene section at seymour island near the coast of antarctica was done in conjunction with careful scanning electron microscope observations to monitor the state of foraminiferal preservation the isotopic compositions of those samples which were deemed to be well preserved were the basis of the conclusion that campanian through paleocene high latitude shelf waters near antarctica had temperatures between approximately 4 5 and 10 5 c temperatures during early and middle maastrichtian time were slightly higher than those of either the late campanian or late maastrichtian the inference of temperate climatic conditions in antarctica is in agreement with paleoclimatic conclusions drawn on the species composition of the planktonic foraminiferal assemblages and the character of the planktonic foraminifera as well as with published conclusions based upon paleobotanical evidence the maastrichtian and campanian water temperatures at seymour island are similar to those inferred from published isotope ratios of pacific late cretaceous benthic foraminifera from low latitudes indicating that campanian through early paleocene deep ocean waters at least in the pacific and perhaps elsewhere as well could have formed by sinking of surface waters in polar regions

a sequence of events across the cretaceous tertiary boundary the lithological and biological sequence of events across the cretaceous tertiary k t as developed in thick and complete landbased sections and termed the standard k t event sequence is also found in many i sdp cores from all over the globe microtektite like spherules have been found in almost every core or outcrop with an iridium anomaly forming a worldwide strewnfield these microtektites are an excellent indicator of the k t boundary level the basal paleocene globigerina eugubma zone is nov established in all major ocean basins the difference in faunas between the pacific and tethys atlantic oceans may point to different recovery of the oldest paleocene planktonic foraminiferal assemblages in different ocean basins planktonic foraminifera and nannoplankton apparently show a different extinction recovery pattern at the k t boundary which suggests that the nannoplankton underwent final extinction later and recover later than planktonic foraminifera these patterns may be important for the evaluation of the type and range of environmental stress resulting from the hypothesized impact s at the k t boundary blocking of sunlight by the dust cloud still can account for the clear mass mortality at the k t boundary but seems less likely as explanation for the final nannoplankton extinction as photosynthetic nannoplankton appear to survive 1000 10 000 years into the tertiary

extended cretaceous tertiary boundary extinctions and delayed population change in planktonic foraminifera from brazos river texas high resolution planktonic foraminiferal analysis of three brazos river sections indicates a nearly continuous cretaceous tertiary k t boundary sedimentary record second only to the world s most complete record at el kef tunisia species extinctions occur over an extended period of time and with two major extinction episodes the first extinction episode with 46 of the species extinct occurs at and just below 10 15 cm a short hiatus at the base of a sandy shell hash and clay sand unit which was interpreted by bourgeois et al 1988 to represent a tsunami bed generated by the k t boundary bolide impact the top of this tsunami bed is about 17 20 cm below the k t boundary as defined by the first appearance of tertiary planktonic foraminifera the second extinction phase with 45 of the species extinct occurs 25 cm above the k t boundary zone p0 p1a boundary of the remaining seven surviving cretaceous species six gradually disappear during planktonic foraminiferal subzones p1a and basal p1b no species extinctions or major faunal assemblage changes are directly associated with the k t boundary iridium distribution is ambiguous with one peak in the upper part of the tsunami bed and a second peak at the micropaleontologically defined k t boundary relative abundances of dominant species are stable through the late maastrichtian and only minor abundance changes coincide with the first extinction episode or the k t boundary the first major faunal change in the dominant species group coincides with the second extinction episode and leads to decline and eventual extinction of this group in subzone p1a species disappearing at the two extinction episodes 46 and 45 constitute only a small percentage 8 and 5 of the individuals of the total planktonic foraminiferal population this suggests that weakened species with low numbers of individuals and sensitive to relatively minor environmental changes were primarily affected by these extinction episodes magnetostratigraphy indicates that the first extinction phase began about 310 000 years before the k t boundary and the second extinction phase occurred 50 000 years after the k t boundary this stepped pattern of species extinctions suggests a progressively stressed ecosystem in continental shelf settings which may be related to an observed sea level regression and global cooling the hypothesis of a global catastrophic mass extinction at the k t boundary caused by a large extraterrestrial impact is not supported by the brazos river planktonic foraminiferal data

paleoceanography of the cretaceous tertiary boundary event inferences from stable isotopic and other data we report the results of new stable oxygen and carbon isotope analyses on carbonate fine fraction whole rock and benthic foraminifers caco3 and coarse fraction percentage determinations and trace element sr analyses on carbonate constituents across the cretaceous tertiary k t boundary in deep sea drilling project dsdp sites 47 2 356 384 and 577 and compare them with published results from k t boundary sections in other dsdp sites we used the trace element data and scanning electron microscope examination to evaluate possible diagenetic alteration and relative preservation of the samples analyzed in this study the 18o data when interpreted as isotopic paleotemperatures indicate relative stable surface water and deepwater temperatures in the late maestrichtian followed by somewhat fluctuating temperatures in the early paleocene however there is no indication of either a significant warming or cooling at or following the k t boundary several sites do exhibit somewhat heavier 18o values by about 0 5 across the boundary which might suggest a 2 3 c cooling at most however we interpret these somewhat heavier 18o values as reflecting slightly better preservation of 18o of carbonate constitutents in relatively clay rich intervals e g lower diagentic potential characteristic of the k t boundary the 13c values of carbonate fine fraction and planktonic foraminifers indicate a major negative excursion in surface water total dissolved carbon across the boundary the surface water and deepwater 13c values from benthic foraminifers combined with calculated decreases in carbonate accumulation rates at all sites in the earliest paleocene are consistent with a major decrease in productivity across the k t boundary the decrease in caco3 accumulation rates is due not to increased rates of dissolution but to decreased production in surface waters the low productivity episode lasted at least 1 m y beyond the k t boundary crisis suggesting that hypothesized catastrophic events alone such as impact of an apollo object are not the only explanation for the observed long term decrease in productivity there is also an indication in the 13c curves from several sites that the surface water 13c decrease began in the latest maestrichtian suggesting that the decrease in productivity may have been independent of a hypothesized impact event

chicxulub impact predates k t boundary new evidence from brazos texas abstract multidisciplinary studies including stratigraphy sedimentology mineralogy and geochemistry of the new core mullinax 1 and outcrops along the brazos river and cottonmouth creek falls county texas reveal the complex history of the chicxulub impact the event deposit and the k t boundary event the k t boundary as identified by the negative 13c shift first occurrence of danian planktic foraminifera and palynomorphs occurs 80 cm above the event deposit in core mullinax 1 the underlying 80 cm interval was deposited in a shallow low oxygen environment during the latest maastrichtian as indicated by high stress microfossil assemblages small shells and burrows infilled with framboidal pyrite the underlying event deposit commonly interpreted as k t impact tsunami consists of a basal conglomerate with clasts containing chicxulub impact spherules repeated upward fining units of spherule rich sands followed by hummocky cross bedded and laminated sands which are burrowed by thalassinoides planolites and ophiomorpha and truncated by erosion this suggests a series of temporally separated storm events with re colonization of the ocean floor by invertebrates between storms rather than a series of waning tsunami generated waves the lithified clasts with impact spherules at the base of the event deposit provide strong evidence that the chicxulub impact ejecta layer predates the event deposit but was eroded and re deposited during the latest maastrichtian sea level lowstand the original chicxulub ejecta layer was discovered in a 3 cm thick yellow clay layer interbedded in undisturbed late maastrichtian clay and mudstones 40 cm below the base of the event deposit and near the base of planktic foraminiferal zone cf1 which spans the last 300 kyr of the maastrichtian the yellow clay consists of cheto smectite derived from alteration of impact glass as indicated by rare altered glass spherules with similar chemical compositions as reworked spherules from the event deposit and chicxulub impact spherules from ne mexico and haiti the brazos sections thus provide strong evidence that the chicxulub impact predates the k t boundary by about 300 kyr consistent with earlier observations in ne mexico and the chicxulub crater core yaxcopoil 1

the cretaceous tertiary boundary carbon and oxygen isotope stratigraphy diagenesis and paleoceanography at zumaya spain carbon and oxygen isotope analysis of 240 m of upper cretaceous and lower tertiary limestones and marlstones from zumaya spain has revealed three distinct negative carbon isotope excursions of up to 2 per mil occurring both before and during the cretaceous tertiary k t transition although diagenesis has affected these rocks to varying degrees during burial and lithification we believe that these excursions may reflect paleoceanographic changes sr ca electron microscopic and petrographic analysis have been used to assess the type and magnitude of diagenesis allowing us to distinguish samples with significantly altered isotopic values carbon isotopes of rocks at zumaya exhibit absolute values and ranges similar to semiconsolidated sediments of the same age oxygen isotopes of these rocks however exhibit a 1 2 per mil or more depletion defined here as a diagenetic overprint in comparison with values from semi consolidated sediments of the same age ammonite and inoceramid macrofossils disappear in this section 12 5 and 120 m below the k t boundary coincident with two distinct episodes of negative 13c values these may reflect localized paleoceanographic or ecological changes the last and largest of the isotope excursions corresponds with the k t boundary marl and mass extinctions of calcareous plankton the k t boundary carbon isotope excursion is one of three that took place during the last 1 million years of the cretaceous each one possibly being associated with biotic changes in the oceanic realm the k t boundary excursion coincides with iridium concentration and spherules of unidentified origin perhaps indicating that paleoceanographic change coincided with either extraterrestrial impacts or volcanic events that amplified their effects and accelerated biotic changes during times of stressed oceanic ecosystems

paleooceanography of the mesogean sea based on ostracods of the northern tunisian continental shelf between the late cretaceous and early paleogene a new method analysis used in the study of the el kef section north western tunisia led to the paleooceanographic reconstruction of the mesogean between late cretaceous and early paleogene several changes observed are in fact worthy of particular mention paleobathymetrically the area changed from an upper bathyal environment of about 400 m deep to an outer shelf domain of 100 50 m furthermore the oxygen minimum zone o m z became highly intense at a the cretaceous tertiary transition catastrophic event b the p1 p2 boundary intense thermic stratification and c between p4 and p6 very active paleoproductivity in this last episode the continental shelf environment was subjected to intense upwelling responsible for the formation of a prephosphatic environment at water sediment interface the paleooceanographic history of phosphates in the gafsa metlaoui basin is in fact in perfect stratigraphic and paleoenvironmental agreement with the paleobathymetric evolution of the kef region finally paleooceanographic communication between the mesogean and the north atlantic was at this period highly free because of lack of hydrologic relations between the north atlantic and the norwegian sea

the cretaceous tertiary boundary event in the north pacific planktonic foraminiferal results from deep sea drilling project site 577 shatsky rise a detailed micropaleontologic analysis of sediments from deep sea drilling project site 577 from the shatsky rise north pacific was undertaken to describe extinction and radiation patterns of plank tonic foraminifera in a continuous carbonate sequence spanning the cretaceous tertiary k t boundary a 15 m section containing the boundary was closely sampled and contained planktonic foraminiferal assemblages characteristic of the late maastrichtian abathomphalus mayaroensis zone through the danian globorotalia uncinata zone the cretaceous tertiary boundary was placed at the abrupt disappearance of almost all maastrichtian planktonic foraminifera coincident with these extinctions was the presence of a large number of microtektitelike spherules the most important faunal change in the late maastrichtian was an abrupt increase in the relative abundance of the high latitude species hedbergella monmouthensis together with the appearance of diminutive populations of guembelitria cretacea and globigerina eugubina approximately 20 000 years before the boundary these changes are interpreted as indicating a cooling of surface water conditions globigerina eugubina and g cretacea were the only planktonic foraminiferal species to survive the cretaceous tertiary boundary event at this locality the o 18 and c 13 values of g eugubina from below the k t boundary are nearly the same as those from above the boundary but in both cases the o 18 values indicate relatively cooler paleotemperatures than those from other coexisting planktonic foraminiferal species in addition the c 13 values of g eugubina are lighter than those of the other planktonic foraminifera such a relationship might suggest that g eugubina lived in cooler shallow intermediate water masses advected from higher latitudes during a latest maastrichtian cooling episode better preservation of planktonic foraminifera a progressive change in the c 13 of benthic foraminifera and a brief positive excursion in c 13 of the carbonate fine fraction and of planktonic foraminifera within 20 to 30 cm below the k t boundary all suggest important paleoceanographic changes that preceded the extinction event a large population of aberrant g eugubina and eoglobigerina was observed in the earliest danian these forms are characterized by the development of secondary apertures bullae and abnormal final chambers these abnormal morphotypes are considered to be ecophenotypic variants reflecting ecologic stress or instability in the earliest cenozoic marine environment

stable isotope toc and caco3 record across the cretaceous tertiary boundary at el kef tunisia we report the results of stable oxygen and carbon isotope analysis of carbonate fine fraction and benthic and planktic foraminifers caco3 and toc determinations of sediments across the cretaceous tertiary k t boundary at el kef tunisia we used grain size analysis of the fine fraction carbonate to determine possible compositional effects and smearslide and scanning electron microscope examinations to evaluate possible diagenetic alteration and microfossil preservation the data suggests the following sequence of events upper maastrichtian oxygen and carbon isotope signals indicate relatively warm temperatures a decreasing thermal gradient possibly related to a shallowing sea and relatively high surface water productivity a sharp cooling appears to begin just below the k t boundary the k t boundary is characterized by a sudden 2 negative shift in fine fraction 13c a slight 0 6 enrichment in benthic 13c and a reduction of about 40 in caco3 sedimentation these data imply strongly reduced surface water productivity as also observed in numerous deep sea sequences worldwide the lower danian planktic foraminiferal zones p0 p1a is marked by generally low productivity and unstable environmental conditions as indicated by generally low but fluctuating fine fraction 13c values and low 5 15 carbonate deposition at the base of subzone p1b caco3 benthic and fine fraction 13c values increase gradually and reach near pre k t boundary levels in subzone p1c indicating initial recovery after the k t boundary event about 300 000 400 000 years after the k t boundary the prolonged low productivity episode after the k t crisis and the pre k t boundary cooling associated with a major reduction in planktic foraminiferal diversity are difficult to explain by a single k t boundary bolide impact

mineralogy and phase chemistry of an ir enriched pre k t layer from the lattengebirge bavarian alps and significance for the ktb problem abstract three distinct iridium anomalies are exposed in the cretaceous tertiary boundary ktb section of the lattengebirge bavarian alps comprising a pelagic calcareous sequence from below a continental slope multiple ir anomalies are in contrast to most reported k t sections which are characterized by a single ir peak two of these ir spikes are contained in the 20 cm thick actual ktb termed clayey interval with the main peak of 4 4 ppb precisely at the boundary and the second peak of 2 8 ppb 10 cm above a third peak of 3 6 ppb was detected at 16 cm below the ktb in a thin turbiditic and coal bearing sandstone layer of upper maastrichtian age the distribution of ir anomalies provides evidence of episodic ir delivering events over an extended period of time whereas the worldwide distributed single spiked ktb layers are composed entirely of diagenetically altered materials various phases are discernible in the well preserved ir bearing pre k t layer 1 sandstone clastic minerals in a carbonate matrix 2 coal which is partly burned 3 sulfides chalcopyrite included in coal and 4 silicate melt glasses the glasses represent the first ones reported from a k t section and were formed by combustion metamorphism from sedimentary parent rocks of the coal as indicated by their major element chemistry and ree patterns phase chemistry of the layer components reveals ir concentrations of up to 110 ppb indicating that ir and chalcophile trace elements tre are primarily contained in the sulfides this carrier phase points to ir enrichment by processes unrelated to impact and its stratigraphic position demonstrates availability of ir for incorporation into sediments before the ktb the uptake of ir and chalcophile tre into the coal and subsequent combustion metamorphism occurred on the continent during a time interval of 14 000 9000 yr prior to the ktb as constrained by radiometric age determinations stratigraphy and sedimentation rates in the lattengebirge k t sediments no indications of shock are found the results suggest a volcanic origin for the multiple ir bearing horizons like the worldwide ktb layers they are concomitantly enriched in ir and chalcophile tre and hence have a common source the lattengebirge k t profile is largely continuous and was recently reexamined by micropaleontological methods contribution by d herm and k f weidich the preservation of multiple ir anomalies is attributed to high sedimentation rates of 1 75 cm kyr and the absence of carbonate dissolution and condensation of sediments usually encountered in the worldwide ktb layers

south pacific evidence for the long term climate impact of the cretaceous paleogene boundary event abstract the cretaceous paleogene k pg boundary is well represented across a range of depositional settings in new zealand trends in fossil assemblages and marine lithofacies indicate that the k pg event was followed by a pronounced and long term 1 myr perturbation in climate and ocean conditions these findings are supported by a tex86 derived sea surface temperature sst reconstruction across the k pg boundary at mid waipara river north canterbury the bayspar calibration indicates that sst was very stable in the uppermost cretaceous 20 c but abruptly warmed by 4 c in a 25 cm thick lowermost paleocene interval this interval is overlain by a 2 m thick interval in which sst abruptly cooled by 10 c and then progressively returned to 20 c the basal paleocene warm interval is associated with an acme in the dinoflagellate species trithyrodinium evittii and the succeeding cool interval is associated with an acme in palaeoperidinium pyrophorum biostratigraphic correlation of the shelfal mid waipara section to the pelagic k pg sections in marlborough reveals that a significant unconformity separates these two acme events with the t acme event occurring in the earliest paleocene and the p pyrophorum acme occurring 1 myr later and lasting 200 kyr a succession of dinoflagellate acme events within the intervening interval in the marlborough sections implies unstable climatic and environmental conditions in the lead up to the p pyrophorum acme and cooling event at 65 ma this event also coincides with a peak in biogenic silica accumulation in the marlborough sections we suggest that disruption to biogeochemical pathways at the k pg boundary caused long term climatic cooling in the southern pacific region

stable isotopic fractionation among particles in quaternary coccolith sized deep sea sediments oxygen and carbon isotopic ratios of individual grain size splits of the 38 m fraction of deep sea carbonate particles vary systematically with size over a range of 1 25 4 0 most splits are dominated by just a few coccolith taxa and other types of particles the 18o and 13c values of individual splits are linearly related to each other with a slope of 1 5 13c 18o in all holocene and glacial samples analyzed although the observed variability is less than predicted from culture experiments of individual components compositional variations can significantly influence the stable isotopic stratigraphies measured on the nannofossil fraction

terminal cretaceous environmental events the geologic record of terminal cretaceous environmental events indicates that iridium and other associated elements were not deposited instantaneously but during a time interval spanning some 10 000 to 100 000 years the available geologic evidence favors a mantle rather than meteoritic origin for these elements these results are in accord with the scenario of a series of intense eruptive volcanic events occurring during a relatively short geologic time interval and not with the scenario of a single large asteroid impact event

iridium anomaly at the cretaceous tertiary boundary in texas abstract a fifty fold increase in the iridium content precisely at the cretaceous tertiary boundary over background values has been found in the brazos river section in texas

stable isotope and foraminiferal changes across the cretaceous tertiary boundary at stevns klint denmark arguments for long term oceanic instability before and after bolide impact event abstract stable isotope and planktic and benthic foraminiferal analyses of the k t boundary transition at stevens klint denmark indicate a 100 500 kyr long period of instability in oceanic bottom water temperature and sea level during the latest maastrichtian from 2 7 m below and up to the k t boundary bottom water temperatures gradually cooled about 1 5 c as surface water temperatures remained constant at the k t boundary bottom water temperatures decreased additionally 3 c and then returned to pre boundary values just above the boundary interval coincident with the onset of the first temperature decrease there was a prominent sea level fall estimated between 50 100 m as observed in benthic and planktic foraminiferal assemblages as well as in a decreasing surface to bottom 13 c gradient about 40 cm below the iridium rich k t boundary clay sea level began to rise poor preservation of foraminifera above the k t boundary allows only tentative interpretation of danian events at stevns klint however sea level generally continued to rise interrupted by short sea level falls associated with the observed sea level changes are three important hiatuses at the contact between the white chalk and overlying grey white bryozoan chalk about 2 7 m below the k t boundary at or near the top of the fish clay zone pla parvularugoglobigerina eugubina missing and at the contact of the cerithium limestone and overlying bryozoan limestone about 60 cm above the k t boundary part of zone plc missing these unconformities are coeval with hiatuses observed in many continental shelf sections and indicate a global eustatic rather than regional isostatic response notable is that at stevns klint the episode of oceanic instability is registered over approximately the same stratigraphic interval in which supposed extraterrestrial amino acids occur a circumstance that may indicate a connection a gradual positive shift in 13 c is registered in both benthic and planktic foraminiferal assemblages in the upper maastrichtian at stevns klint the positive shift is followed by a prominent negative 13 c shift 1 3 at the k t boundary an upper maastrichtian positive 13 c excursion followed by a negative 13 c anomaly at or near the k t boundary has previously been observed in deep sea cores from the pacific ocean and the weddell sea antarctica implying a global event previous suggestions of a relation between the uppermost maastrichtian positive 13 c excursion and sea level variation are not supported by the data for stevns klint

trace elements stable isotopes and clay mineralogy of the elles ii k t boundary section in tunisia indications for sea level fluctuations and primary productivity abstract trace elements and stable isotopes in bulk rocks and foraminifera bulk rock and clay mineral compositions are used as palaeoproxies to evaluate sea level fluctuations climatic changes and variations in primary productivity across the k t transition at elles ii in tunisia from 1 m 33 kyr below to 1 m 70 kyr above the k t boundary results on clay minerals major and trace elements stable isotopes in bulk rock samples e g ca cu zn rb sr zr ba 13c and 18o and in foraminifera sr ca 13c 18o indicate that the latest maastrichtian last 33 kyr in tunisia was marked by a relatively warm but humid climate and a rising sea level the transgressive surface is marked by deposition of a foraminiferal packstone just below the k t boundary followed by maximum flooding across the k t boundary red layer and black clay layer humid warm conditions accompanied the maximum flooding along with increased total organic carbon values and rapidly decreasing primary productivity at the k t boundary an impact event ir anomaly ni rich spinels spherules exacerbated already stressed environmental conditions leading to the mass extinction of tropical planktic foraminifera increasingly more humid conditions prevailed within the lowermost danian zone p0 50 kyr culminating in a sea level lowstand near the top of p0 a slow recovery of the ecosystem in zone p1a coincided with a rising sea level and gradually less humid climatic conditions

stepwise mass extinctions and impact events late eocene to early oligocene abstract species ranges and relative abundances of dominant planktonic foraminifers of eight late eocene to early oligocene deep sea sections are discussed to determine the nature and magnitude of extinctions and to investigate a possible cause effect relationship between impact events and mass extinctions late eocene extinctions are neither catastrophic nor mass extinctions but occur stepwise over a period of about 1 2 million years four stepwise extinctions are identified at the middle late eocene boundary the upperglobigerapsis semiinvoluta zone theg semiinvoluta globorotalia cerroazulensis zone boundary and at the eocene oligocene boundary each stepwise extinction event represents a time of accelerated faunal turnover characterized by generally less than 15 species extinct and in itself is not a significant extinction event relative species abundance changes at each stepwise extinction event however indicate a turnover involving 60 of the population implying major environmental changes there microtektite horizons are present in late eocene sediments one in the upperg semiinvoluta zone 38 2 ma and two closely spaced layers only a few thousand years apart in the lower part of thegloborotalia cerroazulensis zone 37 2 ma each of the three impact events appears to have had some effect on microplankton communities however the overriding factor that led to the stepwise mass extinctions may have been the result of multiple causes as there is no evidence of impacts associated with the step preceding or the step following the deposition of the presently known microtektite horizons

response of infaunal macrobenthos to the sediment granulometry in a tropical continental margin southwest coast of india abstract surficial sediment samples collected from the continental margin of the southwest coast of india in july 2004 were examined for the grain size and soft bottom macrobenthic fauna to understand the sediment granulometry and its effect on the faunal distribution samples were collected using smith mcintyre grab from 20 to 200 m depth range consisting of mid shelf outer shelf and slope fine grained sediment located in the mid shelf and supported low faunal abundance polychaetes constituted the bulk of the fauna feeding guild changed with depth and sediment granulometry coexistence of deposit feeders and carnivores in outer shelf and deposit feeders and filter feeders in the slope region indicated the effective utilization of different food resources in general richness and diversity were high in the southern region depth wise the diversity and abundance were relatively high in the 50 75 m depth range correlation and bio env analysis showed that combination of different factors such as sediment texture sediment sorting and depth were found to influence the distribution of macrobenthos hence spatial variations observed in benthic community were presumably linked to the variations in sediment granulometry and the energy level conditions prevailing in the area

extended period of extinctions across the cretaceous tertiary boundary in planktonic foraminifera of continental shelf sections implications for impact and volcanism theories discussion and reply

geochemical evidence for suppression of pelagic marine productivity at the cretaceous tertiary boundary the normal biologically productive ocean is characterized by a gradient of the 13c 12c ratio from surface to deep waters here we present stable isotope data from planktonic and benthic micro fossils across the cretaceous tertiary boundary in the north pacific which reveal a rapid and complete breakdown in this biologically mediated gradient the fluxes of barium a proxy for organic carbon and caco3 also decrease significantly at the time of the major marine plankton extinctions the implied substantial reduction in oceanic primary productivity persisted for 0 5 myr before the carbon isotope gradient was gradually re established in addition the stable isotope and preservational data indicate that environmental change including cooling began at least 200 kyr before the cretaceous tertiary boundary and a peak warming of 3 c occurred 600 kyr after the boundary event

stable isotope composition of late cretaceous benthic foraminifera from the southern south atlantic biological and environmental effects abstract the stable carbon and oxygen isotope composition of different benthic foraminiferal species of the latest campanian and earliest maastrichtian from ocean drilling project hole 690c weddell sea southern south atlantic 1800 m paleowater depth have been investigated the total range of measured isotope values of all samples exceeds 4 for 13c and 1 1 for 18o carbon isotope values of proposed deep infaunal species are generally similar or only slightly lower when compared to proposed epifaunal to shallow infaunal species interspecific differences vary between samples probably reflecting temporal changes in organic carbon fluxes to the sea floor constantly lower 13c values for pullenia marssoni and pullenia reussi suggest the deepest habitat for these species the strong depletion of 13c values by up to 3 within lenticulinids may be attributed to a deep infaunal microhabitat strong vital effects or different feeding strategy when compared to other species or modern lenticulinids the mean 18o values reveal a strong separation of epifaunal to shallow infaunal and deep infaunal species epifaunal to shallow infaunal species are characterized by low 18o values deep infaunal species by higher values this result possibly reflects lower metabolic rates and longer life cycles of deep infaunal species or the operating of a pore water co32 effect on the benthic foraminiferal stable isotopes pyramidina szajnochae shows an enrichment of oxygen isotopes with test size comprising a total of 0 6 between 250 and 1250 m shell size although 13c lacks a corresponding trend these data likely represent the presence of changes in metabolic rates during ontogenesis these results demonstrate the general applicability of multi species stable isotope measurements of pristine cretaceous benthic foraminifera to reconstruct past microhabitats and to evaluate biological and environmental effects on the stable isotope composition

stable isotope evidence for gradual environmental changes and species survivorship across the cretaceous tertiary boundary high resolution 13c and 18o records have been generated from analyses of the planktonic foraminiferal species heterohelix globulosa and the benthonic foraminiferal taxon lenticulina spp from 3 m of a cored section spanning the cretaceous tertiary k t boundary at brazos river texas these are the first stable isotope records across the k t boundary based on monospecific and monogeneric foraminiferal samples they show a gradual decrease in 13c values of about 2 5 permil beginning at the k t boundary as defined by the first appearance of tertiary planktonic foraminifera and continuing 17 20 cm above the boundary approximately 40 000 years later gradual 13c depletion contrasts with the sudden 13c drop at the k t boundary observed in many deep sea sections the surface to bottom 13c gradient decreased to less than zero approximately 25 000 30 000 years after the k t boundary and remained negative for at least the next 140 000 years concomitant with change in 13c values is a gradual decrease of about 2 5 permil in 18c values which has not been observed at other localities this 18o depletion suggests changes in temperature and or salinity in the earliest paleocene gulf of mexico no extinction of foraminiferal species is associated with the k t boundary or the onset of 18o and 13c depletions instead two phases of cretaceous species extinctions occur one extinction phase is below the k t boundary and below the tsunami bed of bourgeois et al 1988 and may be linked to sea level regression and environmental perturbations the second extinction phase coincides with the minimum in 13c and 18o values in the early danian zone p0 pla and appears directly related to environmental changes reflected in the isotopic record h globulosa which is commonly present in maastrichtian and danian sediments exhibits significantly lower 18o 16o and 13c 12c ratios in tertiary sediments relative to specimens from maastrichtian sediments demonstrating the survival of this important cretaceous taxon after the k t boundary event

sedimentology and structure of the trench slope to forearc basin transition in the mesozoic of alexander island antarctica the mesozoic forearc of alexander island antarctica is one of the few places in the world where the original stratigraphic relationship between a forearc basin and an accretionary complex is exposed newlydiscovered sedimentary rocks exposed at the western edge of the forearc basin fill the kimmeridgian albian fossil bluff group record the events associated with the basin formation these strata are assigned to the newly defined selene nunatak formation bathonian and atoll nunataks formation bathonian tithonian within the fossil bluff group the selene nunatak formation contains variable thicknesses of conglomeratesand sandstones predominantly derived from the lemay group accretionary complex upon which it is unconformable the formation marks emergence and subsequent erosion of the inner forearc area it is conformably overlain by the1 km thick atoll nunataks formation characterized by thinly bedded mudstones and silty mudstones representing a marine transgression followed by trench slope deposition the atoll nunataks formation marks a phase of subsidence possibly in response to tectonic events in the accretionary prism that are known to have occurred at about the same time the atoll nunataks formation is conformably overlain by the himalia ridge formation a thick sequence of basin wide arc derived conglomerates this transition from fine to coarse grained deposition suggests that a well developed depositional trough and hence trench slope break had formed by that time the atoll nunataks formation therefore spans the formation of the forearc basin and marks the transition from trench slope to forearc basin deposition

extinction survivorship and evolution of planktic foraminifera across the cretaceous tertiary boundary at el kef tunisia an expanded sediment record at el kef shows that the k t boundary extinctions of planktic foraminifera extend over an interval from 25 cm below the geochemical boundary ir anomaly to 7 cm above species extinctions appear sequential with complex large ornate forms disappearing first and smaller less ornate forms surviving longer the 14 species extinctions below the boundary appear unrelated to an impact event cretaceous species survivorship is greater than previously assumed about 10 species survive 22 into subzone p1a globigerina eugubina all cretaceous survivors are small primitive forms which are generally smaller than their ancestors in cretaceous sediments species evolution after the k t event occurs in two pulses the first new paleocene species evolve in the basal black clay zone po immediately after the major cretaceous extinctions evolving species are small and primitive similar to cretaceous survivors the second pulse in species evolution occurs in the lower part of subzone p1b with the appearance of larger more diverse species the first major increase in carbonate sedimentation and productivity occurs at this time and signals the recoveyr of the ecosystem nearly 300 000 years after the k t event the species extinctions prior to the generally assumed impact event implied by the ir anomaly and the long recovery period of the ecosystem thereafter cannot be explained by a single impact but suggest that multiple causes may be responsible such as climatic changes volcanism a sea level drop production of warm saline bottom water and the chemical consequences associated with increased salinity

the cretaceous tertiary boundary event in ecuador reduced biotic effects due to eastern boundary current setting a multidisciplinary study of a new cretaceous tertiary k t boundary section near guayaquil ecuador reveals an unusually cool water low diversity planktic foraminiferal fauna and a high diversity radiolarian fauna similar to those found in southern high latitude k t sequences despite the fact that this section was deposited near the cretaceous equator the k t boundary is located by planktic foraminifera within a narrow interval bounded by last appearances of tropical cretaceous species and first appearances of tertiary species including parvularugoglobigerina eugubina as in southern high latitudes there is no major mass extinction of either planktic foraminifera or radiolarians at this level a major radiolarian faunal discontinuity occurs some 6 m higher in the section within foraminiferal zone plc some 300 500 kyr after the k t event 13c values from bulk carbonates show both high and low latitude characteristics similarly to low latitudes there is a 3 negative 13c excursion at the k t boundary which is generally interpreted as a major decrease in primary productivity but unlike the low latitudes recovery occurs within a few thousand years as compared with 300 500 kyr and suggests rapid nutrient influx from the antarctic region via a current similar to the humboldt current today similarly to high latitude k t sequences a negative 13c shift occurs in the early danian zone plb about 300 kyr after the k t boundary sedimentologic and mineralogic data indicate a late maastrichtian with relatively low biogenic quartz and high carbonate followed by increasing biogenic quartz 50 and decreasing carbonate 5 during the early danian this suggests intensified atmospheric and oceanic circulation and upwelling off ecuador during the early danian the k t transition is marked by increased volcanic activity continental erosion and terrigenous influx but this also occurs in the early danian zone at the p1ap1b zonal transition and is thus not unique to the k t boundary we suggest that the catastrophic biotic effects normally observed at the k t boundary in low latitudes are greatly reduced or absent in the eastern equatorial pacific because this region was dominated then as now by upwelling and current transport of nutrient rich waters from the antarctic ocean as a result the biotic patterns are characteristic of southern high latitudes whereas the 13c pattern combines ameliorated low latitude effects with predominantly high latitude trends

high resolution planktonic foraminiferal analysis from the cretaceous tertiary boundary at ain settara tunisia evidence of an extended mass extinction the ain settara section located in the kalaat senan area of north central tunisia spans the cretaceous tertiary k t boundary which is characterized by a red layer and a thin non bioturbated boundary clay sediment accumulation across the k t boundary at ain settara was probably interrupted by three short hiatuses and or condensed sedimentation the first hiatus occurs at the top of the cf1 zone the second hiatus condensation occurred just below the boundary clay and the third hiatus at the p0 p1a boundary in the earliest danian these hiatuses are marked by weak unconformities bioturbation and sudden disappearances appearances of species which are known to disappear evolve sequentially in continuous sections quantitative high resolution planktonic foraminiferal analysis across zones cf1 upper p0 and p1a 1 reveals an extended and selective mass extinction all 41 of the species which disappeared at or below the k t boundary are rare to very rare and primarily ecologically specialized keeled deeper dwelling tropical subtropical forms globotruncana globotruncanita gublerina planoglobulina rosita contusotruncana racemiguembelina their combined relative abundance varies between 10 and 15 of the total population at the end of the maastrichtian the k t crisis thus appears more catastrophic when viewed in tropical subtropical assemblages and based on analysis of larger species 200 m which preferentially includes the more specialized forms though in fact the k t mass extinction actually involved a relatively small part of the foraminiferal population in terms of relative abundance the pattern of extinction and changes in dominant population at ain settara appear to be very similar to the planktonic foraminiferal turnover of the other north central tunisian sections el kef elles the selective mass extinction pattern suggests that the catastrophic effects of the bolide impact superimposed those related to long term environmental changes such as variations in temperature sea level and associated water mass changes

global fire at the cretaceous tertiary boundary cretaceous tertiary k t boundary clays from five sites in europe and new zealand are 102 104 fold enriched in elemental c mainly soot which is isotopically uniform and apparently comes from a single global fire the soot layer coincides with the ir layer suggesting that the fire was triggered by meteorite impact and began before the ejecta had settled