the great extinction that never happened the demise of the dinosaurs considered the concept of a sudden extinction of the dinosaurs consequent upon the impact of some extraterrestrial object is so dramatic that it has taken hold upon the imaginations of many scientists as w

isotope systematics and shock wave metamorphism iii k ar in experimentally and naturally shocked rocks the haughton impact structure canada this is a report on the first comparative study of the effects of experimental and natural shock on the k ar system first mineral separates from a 451 plus minus 1 ma old gneiss experimentally shocked up to 60 gpa were investigated by stepwise heating sup 40 ar sup 39 ar technique compared with an unshocked samples the shocked samples have lower sup 40 ar sup 39 ar ages and the diffusion properties have changed depending on peak shock pressure and mineralogic composition total resetting of the k ar clock did not occur secondly to compare these results with the effects of natural shock samples from the approximately 23 ma old haughton impact crater devon island canada with different shock stages were investigated up to shock stage 3 no total resetting of the k ar clock was observed but severe argon losses depending on shock pressure result in sup 40 ar sup 39 ar plateau ages which are incorrect in terms of the true crater age yet they provide an upper limit to the time of the cratering event

tracking ancient magmatism and cenozoic topographic growth within the northern andes forearc constraints from detrital u pb zircon ages a comparison of detrital zircon ages from the cenozoic forearc basins in sw ecuador nw peru and those derived from the amotapes massif offers a singular opportunity to shed some light on the evolution of the nw andean margin of south america an extensive set of pre andean u pb zircon ages older than late cretaceous was obtained from 18 detrital samples coming from the talara zorritos progreso and gulf of guayaquil tumbes forearc basins as well as from two metasedimentary rocks of the amotapes massif u pb age analysis on detrital zircon grains allows a general source to sink scenario to be determined for this section of the andes these analyses give consistent insights into the early topographic growth during the modern andean orogeny the occurrence of proto andean magmatic periods in the western margin of gondwana and the evolution of the amotapes massif within the geodynamical setting of northwestern south america zircon ages at ca 320 ma and neoproterozoic clusters for the amotapes metasediments show significant similarities along the strike of the metamorphic belt thus defining a common metasedimentary origin and can be compared with previously dated rocks from the eastern cordillera of peru these strong similarities demonstrate the presence of a wide polyphased metamorphic belt that includes the western parts of the eastern cordillera the northern section of the occidental cordillera of peru and the amotapes massif detrital sediments of the forearc are marked by a major gap in early cretaceous jurassic ages and the minor presence of ordovician famatinian orogeny and carboniferous permian 340 285 ma ages the age spectrum is not compatible with sediment input from the eastern andes and suggests that the external areas of the andean chain e g the western cordillera were already uplifted prior to or immediately after forearc initiation during the paleocene thus representing a pervasive drainage divide throughout all of the cenozoic the amotapes massif or other terrains sharing the same age affinities e g the olmos terrane occidental cordillera of peru are likely to represent the best potential sources for pre andean zircon grains in the forearc age clusters in both source and sink at ca 600 ma 570 560 ma and 520 ma most likely define magmatic periods and may represent first order constraints for the difficult correlation between proto andean magmatic and orogenic periods to the north and south of the huancabamba deflection it is unlikely that the neoproterozoic zircon grains came from the pan african braziliano belts thus suggesting the onset of significant magmatic activity in this section of the andes at around 570 560 ma and probably ca 600 ma the 520 ma cluster is compatible with the most prominent magmatic period in the southern andes related to the end of the pampean orogeny thus suggesting the existence of a regional proto andean magmatic arc during early cambrian times

low temperature thermochronology of the northern cordillera real ecuador tectonic insights from zircon and apatite fission track analysis the post early cretaceous tectonic development of the northern andean segment north of 5 s is loosely constrained by a series of partially and fully reset k ar ages new apatite and zircon fission track data from three traverses across the cordillera real of ecuador reveal distinct periods of accelerated crustal cooling during the cenozoic fission track ages range from 65 to 14 ma zircon and 44 to 8 ma apatite with apatite mean track lengths ranging from 14 6 to 12 1 m these results record rapid cooling rates during 43 30 ma 23 15 ma and 10 0 ma occurring at temperatures below 275 c the events reflect up to 9 km of crustal exhumation in various regions of the cordillera in response to relative changes in the kinematics of the farallon nazca and south american plates the exhumation history of the cordillera real was not continuous but rather evolved during separate phases these phases persisted for 10 myr and are partly coincident with tectonic phases of the central andes although extend for longer time periods possibly as a result of isostatically driven crustal exhumation large spatial variations in the zircon and apatite fission track data within the cordillera real indicate that local fault bounded massifs have experienced different thermal histories since 43 ma major variations are not restricted to the regional scale and exist within individual terranes faulted slivers within terranes demonstrate highly variable exhumation histories suggesting that deformation was not dominated by terrane bounding faults additionally n s variations in exhumation depths suggest that ne sw trending faults have been active since 10 9ma

stratigraphic responses to a major tectonic event in a foreland basin the ecuadorian oriente basin from eocene to oligocene times the eocene to oligocene sediments of the ecuadorian oriente basin record two kinds of second order stratigraphic response to the tectonic evolution lower eocene shows evidences of local scale syntectonic deposits this tectonic activity can be related to right lateral convergent movements inverting pre cretaceous extensional structures upper eocene and oligocene sediments are integrated as the expression of an isostatic rebound characterizing a basin scale syntectonic deposition this response is evidenced by a reciprocal architecture of the depositional sequences identified in the sedimentary formations these data have allowed us to propose a new geodynamic model for the paleogene evolution of the oriente basin

isotope systematics and shock wave metamorphism i u pb in zircon titanite and monazite shocked experimentally up to 59 gpa this study reports the first u pb isotope analyses on experimentally shocked zircon titanite and monazite extracted from proterozoic granitoid rocks in all three types of minerals shock waves produce drastic changes in the crystal lattices causing strong lowering of birefringence turbidization and decolorization of the individual grains moreover x ray patterns indicate transition of the crystals into polycrystalline aggregates of 10 5 mm block size precisely dated grains with concordant or nearly concordant ages were embedded in kbr and shocked at 35 47 5 and 59 gpa u pb isotope analyses on these grains show that shock metamorphism does not fractionate pb isotopes within the analytical precision of 0 1 as far as chemical fractionation is concerned there is no difference in degree of concordancy between shocked and unshocked monazite and small degrees 2 of relative upb fractionation in shocked zircon and titanite are due to time integrated pb loss and not to the shock experiment in consequence the data document that shock wave metamorphism alone does not measurably effect the u pb chronometer questioning the view that lower intercept ages of discordant u pb data reflect shock induced re equilibration of the chronometer in moderately to highly shocked rapidly cooling rocks

mode and timing of terrane accretion in the forearc of the andes in ecuador the volcanic basement of the ecuadorian western cordillera pallatanga formation and san juan unit is made up of mafi c and ultramafi c rocks that once formed an oceanic plateau radiometric ages from these rocks overlap with a hornblende 40 ar 39 ar plateau age of 88 1 6 ma age obtained for oceanic plateau basement rocks of the pinon formation in coastal ecuador and with ca 92 88 ma ages reported for oceanic plateau sequences in the caribbean and western colombia these results suggest that the oceanic plateau rocks of the western cordillera and fl at forearc in ecuador are derived from the late cretaceous caribbean colombia oceanic plateau intraoceanic island arc sequences rio cala group overlie the plateau in the western cordillera and yield crystallization ages that range between ca 85 and 72 ma the geochemistry and radiometric ages of island arc lavas from the rio cala group combined with the age range and geochemistry of their turbiditic volcaniclastic products indicate that the arc was initiated by westward subduction beneath the caribbean plateau they are coeval with island arc rocks of coastal ecuador las orquideas san lorenzo and cayo formations and colombia ricaurte arc these island arc

simple bouguer gravity anomaly field and the inferred crustal structure of continental ecuador the simple bouguer gravity anomaly field of continental ecuador corresponds closely to the physiographic provinces of the country the sierra which includes the andes and their foothills is characterized by a pronounced low with values to 292 mgal which reflects the deep andean root bouguer anomalies over the oriente become less negative away from the sierra chiefly in response to progressive thinning of continental crust eastward the costa between the sierra and the pacific shore in the north has the most positive on land bouguer anomalies 162 mgal so far known in the western hemisphere this part of the costa is underlain by an ancient oceanic plate now welded to the northwestern corner of the otherwise continental south american plate

evidence from crater ages for periodic impacts on the earth recent evidence has indicated that the impact of a comet or asteroid may have been responsible for mass extinction at the ends of both the cretaceous1 and the eocene2 4 quantitative analysis by raup and sepkoski5 showed that mass extinctions occur with a 26 myr period similar to the period seen in qualitative pelagic records by fischer and arthur6 to account for the possibility of periodic comet showers davis et al 7 proposed that such showers could be triggered by an unseen solar companion star as it passes through perihelion on a moderately eccentric orbit to test a prediction implicit in this model we examined records of large impact craters on the earth we report here that most of the craters occur in a 28 4 myr cycle within measurement errors this period and its phase are the same as those found in the fossil mass extinctions the probability that such agreement is accidental is 1 in 103

an autochthonous geological model for the eastern andes of ecuador abstract we describe a traverse across the cordillera real and sub andean zone of ecuador poorly known areas with very little detailed mapping and very little age control the spine of the cordillera comprises deeply eroded triassic and jurassic plutons the roots of a major arc emplaced into probable palaeozoic pelites and metamorphosed volcanic rocks the w flank comprises a jurassic submarine basaltic andesitic volcanic sequence which grades up into mixed jurassic cretaceous volcanic and sedimentary rocks of the inter andean valley the sub andean zone on the e flank of the cordillera comprises a newly recognized cretaceous basin of cleaved mudrocks quartz arenites and limestones east of the syndepositional cosanga fault the cretaceous basin thins into a condensed sequence that is indistinguishable from the rocks of the adjacent hydrocarbon bearing oriente basin the principal penetrative deformation of the cordillera real was probably latest cretaceous palaeocene it telescoped the magmatic belts but shortening was largely partitioned into the pelites between plutons the plutons suffered inhomogenous deformation some portions completely escaped tectonism the pelites conserve two foliations the earliest comprises slaty cleavage formed under low or sub greenschist conditions the later is a strong schistosity defined by new mica growth it largely transposed and obliterated the first both foliations may have developed during a single progressive deformation we find inappropriate recent terrane models for the cordillera real and sub andean zone of ecuador instead we find remarkable similarities from one side of the cordillera to the other including a common structural history in place of sutures we find mostly intrusive contacts between major plutons and pelites triassic to cretaceous events occurred on the autochthonous western edge of the archaean guyana shield the latest cretaceous paleocene deformation is interpreted as the progressive collision of an oceanic terrane s with the south american continent young fault movements have subsequently juxtaposed different structural levels through the cordillera real orogen

the mera lahar deposit in the upper amazon basin transformation of a late pleistocene collapse at huisla volcano central ecuador abstract the sub andean zone east of the cordillera real ecuador and out to the amazon basin s western margin has been the depository of voluminous lahars related to volcanic activity in the andean highlands these lahars arrived to the sub andean zone via gravitational transport through narrow river canyons and emplaced volumes surpassing several cubic kilometers over robust inundation zones this paper discusses the origin flow route depositional zone terrace formation and geomorphic significance of the most important lahar deposit yet mapped in this region that of the mera lahar which likely formed from a late pleistocene collapse of huisla volcano followed by impounding by temporary dams behind drainage blocking debris avalanche deposits dad then subsequent rupture of the blockage the actual deposit of the mera lahar has a thickness between 30 and 70 m is mainly comprised of dad breccia is matrix supported c 70 of reddish gray color and is well consolidated based on geochemical and petrographic similarities huisla volcano s dad is the best candidate for the lahar s source huisla volcano is located some 90 km up valley of the bulk of mera lahar s mapped deposit clasts of mera lahar rocks and huisla s dad breccias have 57 61 wt sio2 corresponding to andesites of the calc alkaline series with mean values of 1 1 5 wt for k2o the mapped mera lahar deposit has an actual volume estimated in 1 2 km3 compared to its original estimated volume of 5 4 km3 cross sectional widths of 1 5 to 4 5 km span and extend laterally beyond the actual pastaza river channel where the lahar s deposition produced high standing isolated surfaces that are notable local geomorphic features of the upper sub andean zone the flow modeling program laharflow employing the modern landscape as the topographic base adequately simulates the flow route and inundation zones of the mera lahar

the sudbury structure controversial or misunderstood the origins of the sudbury structure and associated igneous complex have been controversial most models call for a major impact event followed by impact induced igneous activity although totally igneous models are still being proposed much of the controversy is due in our opinion to a misunderstanding of the size of the original sudbury structure by analogy with other terrestrial impact structures the spatial distribution of shock features and huronian cover rocks at the sudbury structure suggest that the transient cavity was 100 km in diameter which places the original final structural rim diameter in the range of 150 200 km theoretical calculations and empirical relationships indicate that the formation of an impact structure of this size will result in 104 km3 of impact melt more than sufficient to produce a melt body the size of the igneous complex present volume 4 8 103 km3 for the igneous complex to be an impact melt sheet it must have a composition similar to that of the target rocks evidence for this has been presented previously for sr and nd isotopic data which suggest a crustal origin here we also present new evidence from least squares mixing models that the average composition of the igneous complex corresponds to a mix of archean granite greenstone terrain with possibly a small component of huronian cover rocks this is a geologically reasonable mix based on the interpreted target rock geology and the geometry of melt formation in an impact event of this size the igneous complex is differentiated which is not a characteristic of previously studied terrestrial impact melt sheets this can be ascribed however to its great thickness and slower cooling that large impact melt sheets can differentiate has important implications for how the lunar samples and the early geologic history of the lunar highlands are interpreted if this working hypothesis is accepted namely that both the sudbury structure and the igneous complex are impact in origin then previous hybrid impact igneous hypotheses can be discarded and the sudbury structure can be studied specifically for the constraints it provides to large scale cratering and the formation of basin sized multiring impact structures

new geological and geochronological data from the colombian andes continental growth by multiple accretion the regional geology of colombia consists of a composite palaeozoic to cenozoic sedimentary basin overlying precambrian shield rocks which are exposed in the eastern cordillera magdalena valley and at least part of the extensive llanos plains a palaeozoic metamorphic schist belt with abundant post metamorphic igneous rocks comprises the central cordillera a mesozoic volcanic suite extends from the western flank of the central cordillera and accounts for the bulk of the western cordillera a cenozoic sedimentary sequence probably overlying a late cretaceous oceanic crust and fore arc complex forms the pacific coastal plain the continental edge of central and southern colombia is interpreted as a composite margin made up of successively accreted oceanic island arc related sequences of palaeozoic early mesozoic and late cretaceous ages the present day cycle which began in the miocene is not associated with island arc volcanism

age measurement of the submarine montagnais impact crater seven laser generated 40ar 39ar age spectra of melt rocks from the newly described submarine montagnais crater are presented while the age spectra are not completely straight forward to interpret the evidence is very strong that the impact occurred approximately 51 m y ago thus the montagnais event is associated with neither the k t nor the north american tektite events such an age is also totally out of phase with the 26 32 m y cycles proposed recently for the meteorite impact and extinction records as it falls roughly midway between two of the most precisely dated points in such proposed cycles the k t boundary and the north american tektite event

distinguishing between in situ and accretionary growth of continents along active margins abstract active continental margins represent both sites of crustal loss by tectonic erosion and gain by juvenile magmatism and oceanic arc plateau accretion estimating the gain component depends on distinguishing between growth of margins by either accretion of oceanic crust or juvenile magmatic addition during extension distinguishing between these allochthonous and autochthonous models is frequently ambiguous due to difficulties in interpreting the tectonic origin of mafic rocks we present a detailed geochronological and isotopic study constraining the evolution of the continental margin of northwest south america during 190 113 ma semi continuous slab rollback resulted in crustal thinning juvenile magmatism and ultimately the removal of continental slivers negating previous hypotheses that the margin evolved by the accretion of an island arc however basic crustal growth estimates along with comparisons between rocks exposed in northern peru and the northern andes imply that uneven losses of continental crust occurred along northwest south america for mesozoic exposures and that the accretion of the caribbean large igneous province clip onto nw south america probably played a crucial role in maintaining and preserving mesozoic continental crust north of the huancabamba deflection

geology mineralization and geochronological constraints of the mirador cu au porphyry district southeast ecuador the mirador porphyry cu au district is located in the southernmost sector of the northern andean cordillera in zamora chinchipe province southeastern ecuador the district contains two significant porphyry cu au ag mo deposits mirador and mirador norte and an interconnected series of narrow mineralized structures known collectively as chancho the principal mineralization in the porphyries is disseminated to blebby chalcopyrite developed primarily in potassic alteration with overlying chalcocite supergene enrichment zones prior to radiometric dating presented in this study these deposits were considered late jurassic based on close similarity and therefore assumed age equivalence with the well dated panantza san carlos and sutzu porphyry copper deposits located 40 km to the north new u pb zircon ages confirm a middle jurassic age for granodiorite of the zamora batholith at this location 163 8 1 9 ma and late jurassic ages for subvolcanic intrusions 156 2 1 0 and 153 1 1 3 ma re os molybdenite ages average 156 1 0 ma and indicate coeval mineralization between mirador and mirador norte mineralization and related sub volcanic igneous activity are closely associated at mirador and represent the same temporal event recorded at panantza san carlos and sutzu as well as coeval porphyry skarn and epithermal au mineralization extending at least 80 km south defining a north south cu au metallogenic belt spanning over 120 km

metallogenic features of miocene porphyry cu and porphyry related mineral deposits in ecuador revealed by re os 40ar 39ar and u pb geochronology mineralization and alteration events at ten miocene porphyry cu and porphyry related epithermal mineral deposits in southern central and northern ecuador were dated by means of molybdenite re os biotite and alunite 40ar 39ar and titanite u pb geochronology most of these hydrothermal events show a spatio temporal correlation with porphyry intrusion emplacement as constrained by zircon u pb ages the total age range for these events spans the 23 5 6 1 ma period without displaying systematic along or across arc age distribution trends while epithermal deposits tend to be spatially associated with volcanic rocks of a similar age porphyry cu deposits in ecuador are frequently spatially associated with deeper seated basement units and batholith scale precursor intrusive systems assembled over 5 m y time periods in most cases formation of the porphyry cu deposits is related to the youngest magmatic hydrothermal event in a given area postdating batholith construction at a regional scale the majority of miocene deposits occurs in southern ecuador where areally extensive post mineralization late miocene to recent volcanic sequences with the potential to conceal mineralization at depth are lacking only few miocene deposits occur in northern central ecuador where they mainly crop out in the western cordillera west of the productive present day volcanic arc the surface distribution of post mineralization arc volcanism reflects along arc variations in subducting slab geometry porphyry cu and epithermal deposits in ecuador define a miocene metallogenic belt broadly continuous with its coeval counterpart in northern central peru although both belt segments were formed in an overall similar tectonomagmatic and metallogenic setting their respective metal endowments differ significantly

palaeocene oceans and climate an isotopic perspective abstract the early cenozoic was a time of climatic and oceanographic transition from the cretaceous greenhouse world to the icehouse world of the neogene 18 o measurements shed light on ocean temperature and possible polar ice fluctuations during this interval while 13 c measurements monitor fluctuations in ocean productivity deep water circulation and atmospheric co 2 the major features from 18 o analysis of the early cenozoic are general cooling of surface waters with some evidence for transient cooling across the k t boundary surface water temperatures were at a cenozoic maximum in the early eocene whereas deep waters cooled then warmed during the palaeocene the 13 c of bulk carbonates is at a minimum at the start of the cenozoic due to the profound crisis in ocean surface water productivity associated with the extinctions of marine plankton at the cretaceous tertiary boundary thereafter 13 c values increase in bulk carbonates as well as planktonic and benthonic foraminifera to their cenozoic maximum in the late palaeocene c 60 ma after which time they again decrease over an interval of c 4 5 m y to a cenozoic low in the early eocene the increase in 13 c values characteristic of the palaeocene period is probably related to a combination of increasing surface water productivity and accelerated burial of organic carbon conversely the decline in 13 c into the early eocene is probably related to a decrease in ocean productivity and a deceleration in the rate of organic carbon burial benthic 13 c comparisons suggest that deep waters appear to have been predominantly formed in the high southern latitudes with the exception of a short lived interval near the palaeocene eocene boundary possibly associated with a transient climatic anomaly the late palaeocene thermal maximum the thermal change of palaeocene deep waters may be related to the changing productivity of surface waters by controlling atmospheric co 2 flux in a similar way to that proposed for the control of the pleistocene glacial cycles

transected folds from the western part of the bala lineament wales abstract fold cleavage relationships are described in the cadair idris area of the lower palaeozoic welsh basin which includes the western part of the bala lineament many fold hinges are transected by the broadly contemporaneous caledonian lower devonian cleavage transection angles are amongst the highest yet described from the welsh basin there is a close relationship between fold strike and sense and amount of transection n s folds are clockwise transected ne folds have an axial planar cleavage whilst ene folds are anticlockwise transected similar relationships occur throughout the central welsh basin a model of progressive deformation is described whereby weak regional transpression is modified by local factors viscosity contrasts are recognized as one of the most important controls on the timing of fold development and the amount of transection

rb sr dating of the impact melt from east clearwater quebec the rb sr composition of eight melt rock and three basement samples from the east clearwater impact structure quebec and two basement samples from the west clearwater structure has been determined the whole rock 87sr 86sr ratios of the melt samples 0 7167 0 7253 are within the range of the basement samples 0 7054 0 7322 and provide further evidence that the melt rocks represent shock melted basement a mineral isochron obtained from a relatively coarse grained melt rock gives an age of 287 26 ma for the crystallization age of the melt this is equivalent to k ar whole rock ages of 285 30 ma and 300 30 ma and a rb sr age of 266 15 ma obtained on melt rocks from west clearwater and confirms the previously generally held assumption that the east and west clearwater structures resulted from the simultaneous impact of two bodies at 285 300 ma ago

seismic characteristics and identification of negative flower structures positive flower structures and positive structural inversion negative and positive flower structures and positive inverted structures imply specific modes of formation and their distinctive characteristics make them important criteria for the identification of certain structural styles a negative flower structure from the andaman sea consists of a shallow synform bounded by upward spreading strands of a wrench fault that have mostly normal separations paralleling monoclines and oblique en echelon normal faults flank the divergent wrench fault a positive flower structure from the ardmore basin oklahoma consists of a shallow antiform displaced by the upward diverging strands of a wrench fault that have mostly reverse separations en echelon folds are present on either side of this convergent wrench fault flower structures may resemble extensional or contractional fault blocks on individual seismic profiles flower structures are identified by their unique internal fault and fold architecture by their association with a straight and throughgoing zone of deformation and by their lack of a consistent sense of separation or regional upthrown side positive structural inversion at the rambutan oil field south sumatra basin has formed a shallow anticlinorium and has partly uplifted the underlying graben deeper fault segments bounding the graben have retained their normal fault profiles but at shallow levels some of these faults have reverse separations similar changes of separation with depth may be produced by strike slip but sets of faults with listric profiles and nearby blocklike trend patterns identify the inversion as a dip slip event where correlation of reflections is uncertain or deep control is unobtainable positive inverted structures may also resemble contrational fault blocks detached normal fault assemblages and certain negative inverted structures

allochthonous terranes in the andes of ecuador and northwestern peru in ecuador and northwestern peru the andes and adjacent country particularly on the pacific side are composed of at least five distinctive geologic terranes the terranes are distinguished from one another and from cratonic south america to the east by dissimilar basements cover rocks intrusive rocks and bouguer gravity anomaly fields the pinon terrane occupying most of coastal ecuador has a basaltic basement characterized by the largest known on land positive bouguer anomalies in the western hemisphere the tahuin terrane occupies most of northwestern peru and the southwestern corner of ecuador the terrane has an especially complex basement and is the site of generally positive bouguer anomalies the small biron terrane has an unusual basement composed in part of cordierite gneiss and amphibolite that give consistent late cretaceous k ar mineral ages the wedge shaped chaucha terrane lies in part on the western andean slope between the oceanic pinon terrane on the north and the continental bir

39ar 40ar dating of mesosiderites evidence for major parent body disruption 4 ga ago 39ar 40ar ages were measured on 17 samples of 14 different mesosiderites and indicate major degassing of ar by one or more thermal events less than 4 0 ga ago three samples gave release patterns of constant age whereas the other samples typically showed 200 400 ma increases in 39ar 40ar age with increasing gas extraction temperature these stepwise releases indicate ages of 3 4 3 8 ga 1 ga 109 a averaged ages for individual meteorites are 3 45 3 82 ga no substantial evidence exists in the temperature releases for 39ar 40ar ages older than 4 0 ga and the ar ages appear to be in contradiction to 244pu fission track ages previously reported for a few mesosiderites the ar ages probably date the event that caused disturbance in previously reported rb sr sm nd and pb pb ages of estherville and other mesosiderites data on release of ar as a function of extraction temperature were used in arrhenius plots to estimate activation energies for ar diffusion of 18 52 kcal mol these values were then used to calculate closure temperatures against ar loss of 2 340 c and 180 600 c for assumed cooling rates of 1 c ma and 1 c a respectively the ar data suggest that for certain assumed models of mesosiderite formation the 39ar 40ar ages may date the time of formation of those metal textures in mesosiderites which have led others to calculate cooling rates of 1 c ma models which call for metal silicate mixing 4 5 ga ago followed by cooling at 1 c ma from temperatures 1150 c seem unlikely single event models which produce the silicate metal mixture at high temperatures rapidly cool the objects to temperatures of 500 c followed by cooling of 1 c ma and are not consistent with the ar data unless the thermal event occurred 500 c and left them deeply buried to undergo slow cooling

strontium and neodymium isotopic characteristics of a heterolithic breccia in the basement of the sudbury impact structure canada abstract rb sr and sm nd measurements were undertaken on footwall breccia samples originating from levack township in the north range of the sudbury structure the granitic to quartzdioritic matrix of this heterolithic breccia which contains shocked rock and mineral fragments yields a rb sr isochron age of 1 825 0 021 ga isr 0 70356 0 00005 2 errors based on the analysis of 3 6 mm thick adjacent whole rock slabs from a large hand specimen this age is interpreted as a cooling age after the thermal metamorphism of the footwall breccia by the 1 85 ga old sudbury igneous complex which had caused temperatures in excess of 1000 c in the matrix near the contact mafic rock fragments in this breccia were excluded from the sr isotope exchange at that time the sm nd system of the identical small whole rock samples was only partly disturbed by the sudbury igneous complex the data points scatter around a 2 05 0 49 ga regression line without age significance plagioclase k feldspar and mafic mineral phases of the breccia matrix combined with the corresponding whole rocks display a range in rb sr ages from 1 67 0 08 ga to 1 430 0 015 ga obviously associated with metasomatic processes in the footwall breccia during the declining penokean metamorphism strontium and neodymium model parameters of the footwall breccia matrix near levack show little variation esrt 16 33 to 18 07 endt 10 69 to 11 79 t 1 86 ga and mean tnddm 2 74 0 04 ga based on these results bedrocks exposed in the south range and rocks now forming the sedimentary filling of the sudbury basin can be excluded as major components in the matrix of the analyzed footwall breccia the convergence of neodymium model ages with u pb ages on zircons from the levack gneiss which forms the crystalline basement adjacent to the footwall breccia in the levack area support an exclusively local origin for matrix and fragments of this breccia it is proposed that the footwall breccia is part of the uplifted floor of the sudbury crater

s c mylonites two types of foliations are commonly developed in mylonites and mylonitic rocks a s surfaces related to the accumulation of finite strain and b c surfaces related to displacement discontinuities or zones of relatively high shear strain there are two types of s c mylonites type i s c mylonites described by berthe et al typically occur in deformed granitoids they involve narrow zones of intense shear strain which cut across mylonitic foliation type ii s c mylonites described here have widespread occurrence in quartz mica rocks involved in zones of intense non coaxial laminar flow the c surfaces are defined by trails of mica fish formed as the result of microscopic displacement discontinuities or zones of very high shear strain the s surfaces are defined by oblique foliations in the adjacent quartz aggregates formed as the result of dynamic recrystallization which periodically resets the finite strain clock these oblique foliations are characterized by grain elongations alignments of segments of the grain boundary enveloping surfaces and by trails of grains with similar c axis orientations examples of this aspect of foliation development in mylonitic rocks are so widespread that we suggest the creation of a broad class of s c tectonites and a deviation from the general tradition of purely geometric analysis of foliation and time relationships kinematic indicators such as those discussed here allow the recognition of kilometre scale zones of intense non coaxial laminar flow in crustal rocks and unambiguous determination of the sense of shear

magmatic dominated fluid evolution in the jurassic nambija gold skarn deposits southeastern ecuador the jurassic approximately 145 ma nambija oxidized gold skarns are hosted by the triassic volcanosedimentary piuntza unit in the sub andean zone of southeastern ecuador the skarns consist dominantly of granditic garnet ad20 98 with subordinate pyroxene di46 92hd17 42jo0 19 and epidote and are spatially associated with porphyritic quartz diorite to granodiorite intrusions endoskarn is developed at the intrusion margins and grades inwards into a potassic alteration zone exoskarn has an outer k and na enriched zone in the volcanosedimentary unit gold mineralization is associated with the weakly developed retrograde alteration of the exoskarn and occurs mainly in sulfide poor vugs and milky quartz veins and veinlets in association with hematite fluid inclusion data for the main part of the prograde stage indicate the coexistence of high temperature 500 c to 600 c high salinity up to 65 wt eq nacl and moderate to low salinity aqueous carbonic fluids interpreted to have been trapped at pressures around 100 120 mpa corresponding to about 4 km depth lower temperature 510 300 c and moderate to low salinity 23 2 wt eq nacl aqueous fluids are recorded in garnet and epidote of the end of the prograde stage the microthermometric data th from 513 c to 318 c and salinity from 1 0 to 23 wt eq nacl and 18o values between 6 2 and 11 5 for gold bearing milky quartz from the retrograde stage suggest that the ore forming fluid was dominantly magmatic pressures during the early retrograde stage were in the range of 50 100 mpa in line with the evidence for co2 effervescence and probable local boiling the dominance of magmatic low saline to moderately saline oxidizing fluids during the retrograde stage is consistent with the depth of the skarn system which could have delayed the ingression of external fluids until relatively low temperatures were reached the resulting low water to rock ratios explain the weak retrograde alteration and the compositional variability of chlorite essentially controlled by host rock compositions gold was precipitated at this stage as a result of cooling and ph increase related to co2 effervescence which both result in destabilization of gold bearing chloride complexes significant ingression of external fluids took place after gold deposition only as recorded by 18o values of 0 4 to 6 2 for fluids depositing quartz below 350 c in sulfide rich barren veins low temperature 300 c meteoric fluids 18owater between 10 0 and 2 0 are responsible for the precipitation of late comb quartz and calcite in cavities and veins and indicate mixing with cooler fluids of higher salinities about 100 c and 25 wt eq nacl the latter are similar to low temperature fluids 202 74 5 c with 18o values of 0 5 to 3 1 and salinities in the range of 21 1 to 17 3 wt eq cacl2 trapped in calcite of late veins and interpreted as basinal brines nambija represents a deep equivalent of the oxidized gold skarn class the presence of co2 in the fluids being partly a consequence of the relatively deep setting at about 4 km depth as in other au bearing skarn deposits not only the prograde stage but also the gold precipitating retrograde stage is dominated by fluids of magmatic origin

u pb re os and 40ar 39ar geochronology of the nambija au skarn and pangui porphyry cu deposits ecuador implications for the jurassic metallogenic belt of the northern andes new u pb re os and 40ar 39ar dates are presented for magmatic and hydrothermal mineral phases in skarn and porphyry related ores from the nambija and pangui districts of the subandean zone southeastern ecuador nambija has been one of the main gold producing centers of ecuador since the 1980s due to exceptionally high grade ores average 15 g t but frequently up to 300 g t au pangui is a recently discovered porphyry cu mo district the geology of the subandean zone in southeastern ecuador is dominated by the i type subduction related jurassic zamora batholith which intrudes triassic volcanosedimentary rocks the zamora batholith is in turn cut by porphyritic stocks which are commonly associated with skarn formation and or porphyry style mineralization high precision u pb and re os ages for porphyritic stocks u pb zircon associated prograde skarn u pb hydrothermal titanite and retrograde stage skarn re os molybdenite from veins postdating gold deposition of the nambija district are all indistinguishable from each other within error 145 ma and indicate a late jurassic age for the gold mineralization previously gold mineralization at nambija was considered to be early tertiary based on k ar ages obtained on various hydrothermal minerals the new jurassic age for the nambija district is slightly younger than the 40ar 39ar and re os ages for magmatic hydrothermal minerals from the pangui district which range between 157 and 152 ma mineralization at nambija and pangui is associated with porphyritic stocks that represent the last known episodes of a long lived jurassic arc magmatism 190 to 145 ma a jurassic age for mineralization at nambija and pangui suggests that the northern andean jurassic metallogenic belt which starts in colombia at 3 n extends down to 5 s in ecuador it also adds a new mineralization style au skarn to the metal endowment of this belt

geological history of the cretaceous ophiolitic complexes of northwestern south america colombian andes abstract the western cordillera of colombia was formed by intense alpine type nappe forming folding and thrusting the cretaceous 80 120 ma b p tholeiitic material of the western cordilleran nappes has been obducted onto the paleozoic and precambrian polymetamorphic micaschists and gneiss of the central cordillera near yarumal the antioquia batholith 60 80 ma b p intrudes both obducted cretaceous oceanic material and the polymetamorphic basement rock of the central cordillera therefore nappe emplacement and obduction onto the central cordillera occurred during late senonian to early paleocene the nappes travelled from northwest to southeast so that the highest unit the rio calima nappe therefore has the most northwestern source whereas the lowest units originated from a more southeastward direction sedimentological analysis of the volcanoclastic and sandy turbidite material from each unit suggests a marginal marine environment during cretaceous times the opening of this marginal sea from now on called the colombia marginal basin probably originated by detachment of a block from the south american continent related to the farallon south america plate convergence in the popayan area southern colombia the central cordilleran basement exhibits glaucophane schist facies metamorphism this high pressure low temperature metamorphism is of early cretaceous 125 ma b p age and is related to an undated metaophiolitic complex the ophiolitic material originating from the western cordilleran is thrust over both the blueschist belt and the metaophiolitic complex these data suggest that the occidente colombiano suffered at least two phases of ophiolitic obduction during mesozoic time

seismological evidence on the geometry of the orogenic system in central northern ecuador south america analysis of the spatial distribution of seismicity beneath central ecuador from a temporary network gives new insights on two main points of the ecuadorian tectonics major structures in the ecuadorian andes are east dipping late jurassic to paleogene sutures reactivated by present day compression the oceanic plate is plunging continuously down to a depth of about 200 km with a dip of 25 35 we also show that the coastal plain acts as a buttress transmitting stresses to the andes beneath which deformation is concentrated

geodynamic evolution of the northern and central andes during early to middle mesozoic times a tethyan model the early to middle mesozoic sedimentary and magmatic history of the northern and central andes i e the nne trending colombian ecuadorian segment and the nw trending peruvian segment exhibits a spatially contrasted evolution involving several successive tectonic and geodynamic settings the late triassic to late liassic period began with a widespread marine transgression from the latest triassic the colombian marine shelf was progressively destroyed by southward propagating extensional tectonic activity but marine sedimentation continued in peru during this time no significant magmatic activity is recorded except in the emerging colombian area this period is interpreted as the result of rifting of a tethyan oceanic arm which separated the colombian and palaeo mexican margins from latest liassic an important calc alkaline magmatic arc developed along the emergent colombian segment further south the north peruvian shelf probably emerged but marine sedimentation continued in southern peru during middle and early late jurassic times the colombian segment was characterized by important magmatic activity and by coarse clastic continental sedimentation along the peruvian segment a turbiditic trough emergent areas and continental basins were created and the scarcity of calc alkaline magmatism suggests that only very local subduction took place this period is regarded as one of the southeastward subduction beneath the colombian segment and of tethyan oceanic crust originating in the newly formed colombian oceanic arm this pattern would have induced a chiefly left lateral transform motion along the peruvian segment by kimmeridgian tithonian times the palaeogeographic framework had drastically changed along the colombian segment magmatic activity ceased and continental accretions occurred along dextral strike slip sutures in peru tectonic activity was recorded by the creation of a new turbiditic trough and by the resumption of detrital sedimentation in the coastal area arc related volcanism indicated that subduction took place beneath this segment this geodynamic change is interpreted as the result of a sharp decrease in the spreading activity of the tethyan ridges and replacement by pacific spreading centres inducing a roughly northeastward convergence direction

isotope systematics and shock wave metamorphism ii u pb and rb sr in naturally shocked rocks the haughton impact structure canada minerals and whole rocks from crystalline fragments collected in the allochthonous polymict breccia of the 23 ma old haughton impact crater on devon island arctic canada were analysed for u pb k and rb sr in order to constrain degrees of shock wave induced perturbations in these systems the results show that shock wave metamorphism at 50 gpa with onset of total melting does not significantly affect the u pb chronometers in monazite and zircon monazite preserved its age of crystallization during high grade metamorphism at 1928 2 2 1 2 0 ma 2 errors as dated by the upper intercept of 2 9 discordant monazites the same analyses yield a lower intercept age of 277 5 35 1 35 0 ma in the concordia diagram demonstrating that discordancy is not a direct effect of shock wave metamorphism but a product of time integrated pb diffusion prior to the impact event which occurred 23 ma ago this constrains maximal shock induced pb loss to less than 3 including possible alteration related pb diffusion from the shock damaged grains in 1903 1 1 4 1 1 ma old monazite from an unshocked reference gneiss recent pb loss also reaches 3 corroborating the occurrence of weak alteration related upb fractionation the data substantiate that u pb discordancy patterns are not a reliable chronometer to date impact events small rock fragments and a coherent block of shock stage i to iii vi consist of heterogeneous unequilibrated rb sr sub systems on the 10 m scale with drastically varying isr shock related rbsr fractionation is very limited and in the large block stage iii three biotite fractions yield an rb sr isochron age of 1791 34 ma 2 which is undistinguishable from the 1814 8 ma age of biotite in the unshocked basement gneiss in contrast to this m3 sized fragment rb sr systematics in a fist size sample of shock stage iii do not yield any reliable age information due to small scale 1 cm3 isotopic disequilibrium it appears that such small scale disequilibrium is essentially due to a take up of radiogenic 87sr in feldspar glass from biotite during shock wave passage this prevents dating of the impact events by the rb sr internal isochron method and it can be concluded that total rock melting is the first condition necessary to reset the rb sr chronometer in shocked crystalline rocks

cretaceous and tertiary terrane accretion in the cordillera occidental of the andes of ecuador new field geochronological geochemical and biostratigraphical data indicate that the central and northern parts of the cordillera occidental of the andes of ecuador comprise two terranes the older pallatanga terrane consists of an early to late cretaceous oceanic plateau suite late cretaceous marine turbidites derived from an unknown basaltic to andesitic volcanic source and a tectonic melange of probable late cretaceous age the younger macuchi terrane consists of a volcanosedimentary island arc sequence derived from a basaltic to andesitic source a previously unidentified regionally important dextral shear zone named the chimbo toachi shear zone separates the two terranes regional evidence suggests that the pallatanga terrane was accreted to the continental margin the already accreted cordillera real in campanian times producing a tectonic melange in the suture zone the macuchi terrane was accreted to the pallatanga terrane along the chimbo toachi shear zone during the late eocene probably in a dextral shear regime the correlation of cretaceous rocks and accretionary events in the cordillera occidental of ecuador and colombia remains problematical but the late eocene event is recognised along the northern andean margin

age cooling history and origin of post collisional leucogranites in the karakoram batholith a multi system isotope study u pb dating on zircon and monazite from different varieties of leucogranites in the karakoram batholith reveals two distinct pulses of plutonism at 25 5 0 3 0 8 and 21 4 0 3 0 6 ma in both granites these minerals contain inherited components documenting the presence of precambrian material in the magma source a crustal origin of the granites and long crustal residence times of the source rocks are confirmed by highly negative epsilon i nd strongly positive epsilon i sr and t dm nd in excess to 1 ga a biotite gneiss and a granitic dike from the karakoram metamorphic complex south of the batholith yield very similar epsilon i nd epsilon i sr t dm nd in a pb evolution diagram initial isotopic compositions for both the granites and the rocks from the metamorphic complex plot far above the reference field for morb documenting very close affinity to the eurasian tibetan continental crust the striking similarity of isotope signatures between leuco

new 40ar 39ar dating of the clearwater lake impact structures quebec canada not the binary asteroid impact it seems abstract the two clearwater lake impact structures quebec canada are generally interpreted as a crater doublet formed by the impact of a binary asteroid here arguments are presented that raise important questions about the proposed double impact scenario new 40 ar 39 ar dating of two virtually fresh impact melt rock samples from the 36 km west clearwater lake impact structure yielded two statistically robust early permian plateau ages with a weighted mean of 286 2 2 2 2 6 ma 2 mswd 0 33 p 0 57 in contrast 40 ar 39 ar results for two chloritized melt rocks from the 26 km east clearwater lake impact structure produced disturbed age spectra suggestive of a distinct extraneous argon component although individually weakly robust age spectra corrected for the trapped argon component and inverse isochron plots for the east clearwater melt rocks consistently yielded apparent ages around 460 470 ma no permian signal was found in either of these melt aliquots our new 40 ar 39 ar results reproduce earlier 40 ar 39 ar plateau ages 283 ma and 465 ma respectively for the two impact structures by bottomley et al 1990 and are in conflict with a previous statistically non robust rb sr age of 287 293 26 ma for east clearwater the combined cluster of apparent ages of 460 470 ma derived from four different samples across the impact melt sheet is very unlikely to represent a false age effect due to the incorporation of extraneous argon into the melt instead it strongly favors a middle ordovician age for the east clearwater impact and impact induced hydrothermal chloritization moreover the clearwater impact structures are characterized by different natural remanent magnetizations testifying to separate geologic histories an effect unexpected in the case of a permian double impact whereas the west clearwater impact affected ordovician carbonates incorporated into the impact breccia drill core reports from the 1960s concluded that clasts of ordovician sedimentary rocks are seemingly absent in the impact breccia lens of the east clearwater lake impact structure which is overlain by 100 m of post impact sandstones shales and carbonates no resolvable impactor contamination has so far been detected in the west clearwater impact melt rocks whereas east clearwater carries a distinct ordinary possibly l chondritic impactor signature in its melt rocks east clearwater lake might thus represent one among a long list of ordovician impact structures in north america and northern europe that were presumably formed in response to the l chondrite asteroid breakup event 470 ma ago paleogeographic reconstructions show that the ordovician east clearwater impact probably occurred in a near coastal to shallow marine setting while the permian west clearwater impact hit continental pangaea along with the new 40 ar 39 ar data the paleomagnetic sedimentologic and geochemical findings suggest that the close spatial arrangement of the two clearwater lakes is most likely pure coincidence the two impact structures seem to represent a false doublet struck by impacts separated by 180 million years in time the new results for the clearwater lake impact structures have major implications for the reliable identification of doublet impact craters and the rate of binary asteroid impacts on earth and on other planetary bodies in the inner solar system

special paper major gold deposits and belts of the north and south american cordillera distribution tectonomagmatic settings and metallogenic considerations a compilation of economically viable gold concentrations containing 10 moz in the north and south american cordillera reveals the existence of 22 discrete belts in addition to five major isolated deposits most formed over the last 150 m y the gold concentrations are attributed to eight widely recognized deposit types of which porphyry sediment hosted and high sulfidation epithermal are economically the most important individual gold belts are typically several tens to hundreds of kilometers long dominated by single deposit types and metallogenically active for relatively brief periods 5 20 m y many of the gold belts and major isolated deposits were generated under extensional or transtensional tectonic conditions in either arc or back arc settings nevertheless the two main high sulfidation epithermal gold belts were generated in thickening or already thickened crust during low angle subduction eight other gold belts or districts also accompanied compression or transpression with two of them the main orogenic gold belts occupying fore arc sites there is a strong suggestion that the preeminent cordilleran gold concentrations formed either during or immediately following prolonged contraction the major gold deposits and belts occur along the craton edge as well as in adjoining accreted terranes but almost all are of postaccretionary timing many of the gold belts and isolated deposits were localized by crustal scale faults or lineaments which may be either parallel or transverse to the cordilleran margin the gold concentrations accumulated during active subduction commonly in close spatial and temporal association with intermediate to felsic medium to high k calc alkaline igneous rocks by contrast the low sulfidation epithermal gold deposits accompany bimodal volcanic pulses of calc alkaline tholeiitic or alkaline affinity however a gold alkaline rock association is uncommon a genetic link between gold mineralization and coeval magmatism is widely accepted for most of the deposit types the exceptions being the sediment hosted and orogenic gold deposits notwithstanding the small cumulative extent of the gold concentrations relative to the entire cordilleran margin there is a marked tendency for two or more belts or isolated deposits of different ages and genetic types to occur in close proximity within relatively restricted arc including fore and back arc segments in the case of the western united states for example six belts and four isolated major deposits make up a particularly prominent cluster if fortuity is discounted this clustering or pairing of gold concentrations must imply a predisposition of certain arc segments to gold mineralization an analogous situation is evident for other metals particularly copper and tin the reason for the recurrent generation of major deposits and belts dominated by one or more metals remains uncertain although heterogeneously distributed metal preconcentrations favorable redox conditions or other parameters somewhere above the subducted slab between the mantle wedge and upper crust are widely contemplated possibilities elucidation of the reason s for this metallogenic inheritance at the scale of limited arc segments poses an important and challenging series of research questions as well as being critical to the planning of potentially successful greenfield exploration programs

origin of the sudbury complex by meteoritic impact neodymium isotopic evidence samarium neodymium isotopic data on whole rocks and minerals of the sudbury complex in canada gave an igneous crystallization age of 1840 21 x 10 6 years the initial epsilon neodymium values for 15 whole rocks are similar to those for average upper continental crust falling on the crustal trend of neodymium isotopic evolution as defined by shales the rare earth element concentration patterns of sudbury rocks are also similar to upper crustal averages these data suggest that the sudbury complex formed from melts generated in the upper crust and are consistent with a meteoritic impact

the geology and mesozoic collisional history of the cordillera real ecuador abstract the geology of the metamorphic rocks of the cordillera real of ecuador is described in terms of five informal lithotectonic divisions we deduce that during the mesozoic repeated accretionary events occurred and that dextral transpression has been of fundamental importance in determining the tectonic evolution of this part of the northern andes the oldest event recognised of probable late triassic age may be related to the break up of western gondwana and generated a regional belt of s type plutons during the jurassic major calc alkaline batholiths were intruded following this in latest jurassic to early cretaceous time a volcano sedimentary terrane of possible oceanic or marginal basin origin the alao division and the most westerly gneissic chaucha arenillas terrane were accreted to continental south america the accretion of the oceanic western cordillera took place in latest cretaceous to earliest tertiary time this latter event coincided with widespread thermal disturbance as evidenced by the large number of young k ar mineral ages recorded from the cordillera real

geomorphic evidence of active deformation and uplift in a modern continental wedge top foredeep transition example of the eastern ecuadorian andes abstract the eastern ecuadorian andes appear as a fold and thrust belt adjacent to a continental foredeep represented by one of the world s largest tropical alluvial megafans the pastaza megafan debouching into the amazonian lowland the apex of the pliocene pleistocene megafan situated in the present day wedge top subandean zone has been cut by an erosion surface the western part of which has been uplifted of 500 m along the frontal thrust forming a poorly dissected plateau the mera plateau this erosion surface erased most of the previous fluvial landscape but preserved a large thrust related anticlinal hinge deforming less erodible underlying strata the mirador fold and smaller sized anticlines this surface has been then incised by two antecedent major rivers the pastaza and the napo and few tributaries the plateau edge is marked by a series of large scale gently sloping landslides clustered along a 70 km long concave eastward line associated with the frontal thrust fault the newly formed immature rivers issued from the landslides or sourced within east dipping remnants of the erosion surface downstream of the landslide line constitute the greatest part of the streams feeding the ecuadorian amazonian basin at 70 to 100 km from the landslide line the drainage abruptly changes from highly immature to mature with a well defined hinge line representing the outer limit of landslide and tectonic control the diversions of the pastaza river indicate ongoing fold growth since at least the late pleistocene in the eastern cordillera and the early holocene in the mera plateau the preserved terraces of the pastaza valley are all degradational and are ascribed to periods of tectonic seismic activity alternating with periods of tectonic quiescence or decreased seismic activity rather than to climatic events 14c dating of the plateau erosion surface and of the upper pastaza terraces indicates that the minimum average incision rate since 18 000 years bp varies locally in the upper pastaza valley from 0 5 to 0 67 cm year 1 increasing from 18 000 years bp to now a comparison of these incision rates with fold and thrust fault uplift rates indicates that incision in the upper pastaza valley was a result of rapid uplift up to 1 cm year 1 along the mirador fold and thrust which caused a restoration of the local equilibrium profile of the upper reach combined with smaller local fault uplift along the westernmost thrust faults the uplift of the whole mera plateau with respect to the upper amazonian basin gives a minimum average uplift rate of 2 8 cm year 1 since 18 000 years bp the overall uplift of the mera plateau and the eastern cordillera is likely to have been caused by a regional scale low angle thrust ramp emerging as the frontal thrust fault

terrestrial impact structures impact structures are the dominant landform on planets that have retained portions of their earliest crust the present surface of the earth however has comparatively few recognized impact structures this is due to its relative youthfulness and the dynamic nature of the terrestrial geosphere both of which serve to obscure and remove the impact record although not generally viewed as an important terrestrial as opposed to planetary geologic process the role of impact in earth evolution is now receiving mounting consideration for example large scale impact events may have been responsible for such phenomena as the formation of the earth s moon and certain mass extinctions in the biologic record the importance of the terrestrial impact record is greater than the relatively small number of known structures would indicate impact is a highly transient high energy event it is inherently difficult to study through experimentation because of the problem of scale in addition sophisticated finite element code calculations of impact cratering are gen erally limited to relatively early time phenomena as a result of high com putational costs terrestrial impact structures provide the only ground truth against which computational and experimental results can be com pared these structures provide information on aspects of the third dimen sion the preand postimpact distribution of target lithologies and the nature of the lithologic and mineralogic changes produced by the passage of a shock wave they also provide data for cratering rate estimates and in some cases on the nature of the impacting body in this review emphasis is placed on the nature of terrestrial impact structures the criteria for their identification and their contribution to

the nature and provenance of accreted oceanic terranes in western ecuador geochemical and tectonic constraints western ecuador consists of a complex tectonic melange of oceanic terranes accreted to the continental margin from late cretaceous to eocene time new geochemical data from these accreted terranes arising from a 5 year british geological survey mapping programme indicate that they comprise rocks from a variety of oceanic tectonic settings from thickened and relatively unsubductable oceanic plateau basalts through island arc tholeiites with occasional more calc alkaline lavas to back arc basin basalt sequences this study has enabled us to construct a new geodynamic model for the cretaceous tertiary evolution of the northern andes and has placed important new constraints on the extent of oceanic plateau sequences in colombia and around the caribbean the age and nature of sediments combined with evidence for the age of peak metamorphism suggests that a prolonged 15 20 ma accretionary event occurred in late cretaceous time and involved the collision of an oceanic plateau represented by the pallatanga unit with the continental margin this accreted unit can be correlated with similar oceanic plateau sequences from the western cordillera of colombia and those within and around the caribbean region the naranjal and macuchi island arcs and the associated la portada back arc basin developed along the accreted margin from late campanian to eocene time and these arcs accreted to the continental margin along with oceanic plateau material represented by the pinon unit and pedernales esmeraldas sequences during eocene time the development of island arcs which separate the two accretionary events implies that the most westerly coastal oceanic plateau sequences both in ecuador pinon and pedernales esmeraldas and in colombia gorgona and serrania de baudo cannot belong to the caribbean colombian oceanic plateau ccop it therefore appears that at least two different oceanic plateaux are preserved within the accreted oceanic terranes of the northern andes it is possible that the ccop formed over the galapagos hotspot as previously proposed but the more westerly coastal plateau was derived from a more southerly hotspot source region such as sala y gomez in the se pacific

geochemistry of the melt and country rocks of the lake st martin impact structure manitoba canada impact melt and country rocks from the 23 km diameter lake st martin structure in manitoba were analysed for major and trace element abundances and for rb sr isotopic compositions our aim was to better understand the formation of the melt rocks in this probable impact structure to search for traces of the meteoritic projectile to date the melt sheet in order to improve the chronological record of impact events on the earth s surface and to constrain the target from which the melt rocks could have formed major element analyses are consistent with the observation by simonds and mcgee 1979 that many of the melt rocks from lake st martin are chemically homogenized to a degree similar to that of melt bodies from other impact structures however some samples are of slightly different composition this can be explained by post impact hydrothermal alteration particularly near the present erosion surface chemical exchange between melt bearing breccia and basement rock near the bottom of the melt sheet or limited mixing of different target lithologies so called pseudotachylites from the central uplift of the structure are chemically diverse and do not always represent the composition of their host rock we conclude that such samples are not pseudotachylite but probably represent injected impact breccia rees and other lithophile elements are well homogenized in the melt in comparison with the country rock variation there is a slight enrichment of the siderophile elements co and au and of cr in the melt rocks but further analyses are required to verify whether this is caused by a small contribution from the meteoritic projectile the melt rocks are also homogenized isotopically when compared with the spread of isotopic ratios determined for the country rocks the melt rock isotopic composition however can only be achieved by mixing of various granitoid country rock types with another component of high 87rb86sr ratio furthermore the melt rocks are isotopically reequilibrated whole rock rb sr isotope data yield an age of 212 4 43 ma isr 7132 3 at 2 level whole rock and mineral separate data yield an age of t 219 32 ma isr 7131 3 this age consistent with previously reported k ar ages of 200 25 and 250 25 ma is thought to be the best approximation to the age of the melt rocks and thus of the impact event however the 2 error of 32 ma is too high to allow this age to become a significant addition to the data base of well constrained impact ages for analysis of periodicity in the cratering record an age of t 2785 3 157 ma 2 for isr 6997 11 was obtained for the basement rocks of the lake st martin structure but the true meaning of this age is still unclear while the age obtained is comparable to other superior province data it appears that the lake st martin country rock data define a mixing line the new chemical and isotopic results are consistent with an impact origin for the lake st martin structure harmonic least squares mixing calculations suggest that the melt rocks were formed from ca 80 monzonitic and 15 granitic basement plus a small addition of ca 6 carbonate rock this is in good agreement with the results by simonds and mcgee 1979 and favors their suggestion that carbonaterich target rocks even when they form the upper portion of the target stratigraphy do not significantly take part in impact melt formation but are largely removed in a co2 rich vapor phase

the geological history of northwestern south america from pangaea to the early collision of the caribbean large igneous province 290 75ma abstract northwestern south america preserves a record of the assembly of western pangaea its disassembly and initiation of the far western tethys wilson cycle subsequent pacific margin magmatism and ocean plateau continent interaction since the late cretaceous numerous models have been presented for various time slices although they are based on either spatially restricted datasets or dates that are inaccurate estimates of the time of crystallisation here we review a very large quantity of geochronological geochemical thermochronological sedimentological and palaeomagnetic data that collectively provide tight constraints for geological models these data have been collected over a trench pacific parallel distance of 1500 km colombia and ecuador and reveal important temporal trends in rifting and subduction the temporal framework for our model constraints are obtained from robust concordant zircon u pb ages of magmatic rocks during 290 75 ma the late cretaceous thermal history of the margin

the metamorphic basement of ecuador the metamorphic rocks of ecuador once thought to constitute a uniform and ancient basement belong to several distinct units of widely differing ages compositions and metamorphic histories the largest area of metamorphic rocks constitutes an unbroken belt on the eastern andean slope from the colombian to the peruvian border the bulk of the rocks in this belt are of cretaceous age and were metamorphosed in the greenschist facies under a barrovian facies series rocks in the extreme north and those south of lat 3 15 s are different and may be of paleozoic age a smaller terrain on the western andean slope in southwestern ecuador is yet more varied it includes four metamorphic terrains the polymetamorphic piedras group of precambrian age the low pressure tahuin group of paleozoic age the high pressure raspas formation of cretaceous age and a low pressure terrain of uncertain age north of the la palma fault several isolated outcrops of metamorphic rocks in ecuador are of uncertain significance

rb sr sm nd k ca o and h isotopic study of cretaceous tertiary boundary sediments caravaca spain evidence for an oceanic impact site isotopic ratios and trace element abundances were measured on samples of ir enriched clay at the cretaceous tertiary boundary and in carbonate and marl from 5 cm below and 3 cm above the boundary samples were leached with acetic acid to remove carbonate and with hydrochloric acid leachates and residues were measured the sr nd o and h isotopic compositions of the boundary clay residues are distinct from those of the stratigraphically neighboring materials the data indicate that most of the clay material was derived from a terrestrial source with relatively low87sr 86sr and high143nd 144nd ratios the 18o data suggest that the detritus has been modified by submarine weathering k ca and rb sr systematics as well as o isotope ratios of k feldspar spherules within the boundary clay suggest that they are predominantly authigenic and may have formed after the time of deposition however sm nd and rb sr isotopic data indicate that the spherules contain relict material that provides information on the nature of the original detritus the isotopic evidence for foreign terrestrial detritus in the boundary clay the low rare earth element concentrations and high ni concentration support the hypothesis of a terminal cretaceous asteroidal impact that produced a global layer of fallout the data are most easily explained if the impact site was on oceanic crust rather than continental crust and if a substantial fraction of the fallout was derived from relatively deep within the lithosphere 3 km this would probably require a single large impactor

a review of criteria for the identification of magmatic and tectonic foliations in granitoids abstract foliations in granitoids can form by magmatic flow submagmatic flow high temperature solid state deformation and moderate to low temperature solid state deformation a review of previous work suggests that no single criterion can consistently distinguish foliations in granitoids formed by flow during ascent diapiric emplacement and expansion emplacement during regional deformation or regional deformation post dating emplacement however a magmatic origin is favoured for foliations defined by the alignment of igneous commonly euhedral minerals particularly where the foliation is parallel to internal or external pluton contacts foliations formed during expansion or ballooning of diapirs may be strictly magmatic in origin although some studies suggest that solid state deformation also may occur if so we would hope to find evidence of deformation of crystal melt systems and that the solid state deformation occurred at high temperatures the inference of syntectonic foliations is most convincing where magmatic and high temperature solid state foliations are subparallel these foliations are continuous with regionally developed foliations in the wall rocks synkinematic porphyroblasts are present in the wallrocks and igneous minerals have the same age as metamorphic minerals associated with the regional cleavage a strictly tectonic origin for foliations in granitoids is favoured when the foliation is defined by metamorphic minerals no alignment of igneous minerals occurs the foliation is locally at high angles to pluton wallrock contacts and the foliation is continuous with a regionally developed cleavage

on the significance of crater ages new ages for dellen sweden and araguainha brazil samples of a few grams in weight from the impact melt at the dellen crater sweden and the araguainha dome brazil were analyzed by rb sr and sm nd techniques for dellen pure labradorite orthopyroxene and glass separates from a clast free impact melt rock with holohyaline ground mass yield an internal rb sr isochron with 89 0 2 7 ma isr 0 83571 0 00007 2 compared to ar ar plateau ages of 102 3 2 ma and 109 6 2 0 ma published for total melt rocks various whole rock values not plotting on this rb sr isochron indicate primary variations in 87sr86sr over the melt sheet the age of the araguainha dome brazil is bracketed by the rb sr model age of 243 19 ma isr 0 7226 0 0005 for altered cordierite in the impact melt and by the internal rb sr isochron age of 449 9 ma isr 0 7140 0 0007 for an uplifted granite shock stage ib in melt rocks from both impact structures 143nd144nd was not homogenized during total rock melting sm nd data either scatter around the primary isochron araguainha or point to a partial resetting dellen this data array may be caused by tiny refractory ree rich inclusions in the main mineral phases which dominate the sm nd system of the impact melt rocks the significant difference between the new isochron age for dellen and ar ar ages show that the data base for analysis of periodicity in cratering record most probably lack precision and accuracy

a perspective on the evidence for periodic cometary impacts on earth abstract recent suggestions of periodic cometary showers coincident with mass extinctions have prompted a review of the terrestrial cratering record from the point of view of completeness of search and crater retention the record used to argue for statistical periodicities is incomplete and may not be representative estimates of crater ages are of variable accuracy and precision and in some cases different dating methods yield discordant results it is possible to define through time series analysis a number of periodicities of different magnitude 29 m y 21 m y 18 5 m y 13 5 m y and phase depending on which craters are considered the most representative sample of the record arguing against periodic cometary showers is the observation that estimates of the average cratering rate in recent time and observations on apollo bodies are equivalent in addition siderophile element data from impact melt rocks suggest a variely of projectile types were responsible for relatively large terrestrial craters given these observations it is concluded that statements regarding periodic cometary showers are not categorical and require evidence beyond arguments based on time series analyses of an incomplete cratering record

the araguainha astrobleme central brazil the following facts have supported the origin of the araguainha circular structure in central brazil by a meteoritic impact 1 the almost circular contour 2 the impact morphologic sequence including a central uplift ring walls and a basin rim of escarpments 3 outcrops of suevites and mixed breccias 4 the evidence of shock metamorphism 5 the presence of shatter cones and 6 negative anomalies of the total intensity of the magnetic field at the center of the ring structure

geochronological control for the main tectonic magmatic events of ecuador abstract a chronological outline of the principal tectonic magmatic events of ecuador is presented based upon approximately 100 k ar and rb sr age determinations eight magmatic episodes are recognized in southwestern ecuador evidence of plutonic and metamorphic activity in the late precambrian and in the middle to late triassic is found large granitic batholiths of middle to late jurassic age associated with widespread acidic volcanism are traceable along the eastern flank of the andes into colombia early cretaceous volcanism and plutonism is recognized only in southern ecuador although apparently equivalent units continue southwards into the coastal cordillera of peru a great orogenic belt characterized by metamorphism plutonism and volcanism was established in the late cretaceous and continued through the paleogene it is traceable into peru and colombia the macuchi fm of the western cordillera along with the pin on fm and associated sediments of the coastal zone represent the remnants of an island arc and the adjacent oceanic floor respectively that collided with the south american plate during the eocene feininger 1981 in the neogene quartz dioritic intrusions were emplaced in the western cordillera as well as in the cordillera de muelleturo although apparently at different times in the late oligocene and miocene acidic volcanism is noted in the southern ecuadorian andes but not in the north in the quaternary andesitic volcanism and large stratovolcanoes characterize the northern andes while widespread rhyolitic ashflow activity is noted in the southern andes in ecuador the post triassic magmatic episodes show a westerly migration similar to that found in colombia but opposite to that noted in peru

rb sr analyses of apollo 16 melt rocks and a new age estimate for the imbrium basin lunar basin chronology and the early heavy bombardment of the moon rb sr model ages on 7 impact glass bombs and internal rb sr isochrons for two crystalline impact melt rocks from the apollo 16 collection have been determined the post cayley glass bombs with model ages between 4 75 0 45 ae and 3 97 0 08 ae can be classified according to their calculated single stage 87rb86sr i ratios 67728 67946 and 67627 8 point to a kreep free precursor terrain the descartes highlands whereas 63566 67567 67627 10 and 67629 are derived from the more heterogeneous cayley plains the very feldspar rich impact melt rock 65795 which is compositionally similar to the group of feldspathic microporphyritic melt breccias fm suite yields a crystallization age of 3 81 0 04 ae 2 87rb 1 42 11yr and isr of 69929 3 in the subophitic impact melt rock 60635 5 two ages were recorded one isochron with 3 87 0 02ae and isr of 0 69920 3 gives the crystallization age of a fine grained internal clast at 3 75 0 03 ae this fragment was incorporated into the host lithology of 60635 which is a member of the anorthositic noritic melt rock anmr group this group has a crystallization age of about 3 75 ae the anmr rocks and several samples of apollo 14 crystalline impact melt rocks belong to a suite of young crystalline impact melt rocks ranging in age from 3 71 to 3 81 ae these ages are in conflict with the canonical age of the imbrium event 3 85 ae it is argued that the young apollo 14 and 16 melt rocks cannot represent solid exotic fragments or melt splashes ejected from post imbrium local or distant craters instead these rocks are derived from coherent impact melt sheets of pre imbrian craters with diameters larger than 5 7 km they are interpreted as clasts of the fra mauro and cayley formation breccia deposits and therefore their ages are used as an upper limit for the age of the imbrium event we suggest that the imbrium basin and the related fra mauro and cayley formations were formed 3 77 0 02 ae ago and could be even as young as 3 75 ae as a consequence we adopt 3 92 0 03 ae 3 87 0 03 ae and 3 84 0 04 ae as ages for the nectaris serenitatis and crisium basins respectively in agreement with the relative crater densities measured on the ejecta blankets of these basins wilhelms 1984 the proposed age sequence leads to an average formation interval for the observed 12 13 nectarian basins of 7 to 14 m y leaving 30 pre nectarian basins of unknown age these facts suggest that there is no late terminal lunar cataclysm in the sense of a culmination of the lunar impact rate at 3 8 ae ago rather the observations are compatible with a steeply and steadily decreasing flux of impactors hartmann 1980 in the sense of an early heavy bombardment which started at the time of the moon s accretion and terminated around 3 75 ae ago

along strike variations in the thermal and tectonic response of the continental ecuadorian andes to the collision with heterogeneous oceanic crust oblique to strike geological segmentation in the andean chain has been previously recognised at various scales and is commonly attributed to changes in the convergence vectors of the oceanic and continental plates as well as the upperplate expressions of differing along strike subducted slab age strength and composition we present new white mica and biotite 40 ar 39 ar and zircon and apatite fission track data from several traverses across the cordillera real of ecuador in the northern andes that reveal distinct along strike differences in the timing of accelerated crustal cooling during the cenozoic the data record elevated cooling rates from temperatures of v380 c during v65 55 and v43 30 ma from all sampled regions of the cordillera real and at v15 ma and since v9 ma in the northern cordillera real each cooling period was probably driven by exhumation in response to the accretion and subduction of heterogeneous oceanic crust elevated cooling rates of up to v30 20 c myr were initiated during the palaeocene and eocene early oligocene along the entire contemporaneous margin of ecuador and were driven by the accretion of the oceanic pallatanga terrane and pin on macuchi block respectively onto northwestern south america both of these geological provinces originated at the southern parts of the leading and trailing boundaries of the caribbean plateau and accreted onto the margin during the approximately northeastward migration of the plateau into its current position within ecuador the development of higher topography and elevated cooling rates of up to 50 c myr at v15 ma and since v9 ma are restricted to the region north of 1 30ps and is situated above the postulated subducted flatslab section of the aseismic carnegie ridge plate convergence rate calculations suggest the carnegie ridge collided with the ecuador trench at v15 ma which caused the pre existing coastal provinces to displace to the northeast subsequently driving extension and marine ingressions in southern ecuador and compression and uplift in northern ecuador fl 2001 elsevier science b v all rights reserved

geochemical evolution of the quaternary chachimbiro volcanic complex frontal volcanic arc of ecuador abstract the chachimbiro volcanic complex cvc is a composite volcano located in the frontal part of the ecuadorian quaternary arc four periods of activity can be differentiated in chachimbiro 400 ka long volcanic history named ch1 405 7 20 0 298 6 32 9 ka ch2 121 75 23 2 36 08 2 8 ka ch3 36080 280 22730 120 ybp and ch4 5 760 30 ybp respectively the magmatic suite ranges in composition from andesites to rhyodacites and displays systematic increases of sio2 sr y la yb incompatible elements e g lree mree lile and depletion of hree with time these geochemical features coupled with radiogenic isotope data and textural observations e g several resorption and overgrowth cycles in plagioclase phenocrysts suggest an open system evolution for cvc including typical crustal magmatic processes such as recharge assimilation and fractional crystallisation to better constrain the magmatic crustal processes of the cvc we use a multi model approach including three open system models rfc recharge fractional crystallisation afc assimilation fractional crystallisation and ec rafc energy constrained recharge assimilation fractional crystallisation different simulations have been developed to best fit cvc s geochemistry including trace elements sr y ratios and sr isotopes which suggest predominant fractional crystallisation and variable assimilation as the main processes explaining the bulk of the geochemical data of cvc this is consistent with an overall thermal decline of the magmatic system through time the genetic model here presented involves the input of a magmatic recharge component matured in the low mid crust through dominant fractionation of amphibole garnet into intermediate crustal reservoir s where magma undergoes extensive fc

partitioning of oblique convergence in the northern andes subduction zone migration history and the present day boundary of the north andean sliver in ecuador along the ecuadorian margin oblique subduction induces deformation of the overriding continental plate for the last 15 ma both exhumation and tectonic history of ecuador suggest that the northeastward motion of the north andean sliver nas was accompanied by an eastward migration of its eastern boundary and successive progressively narrowing restraining bends here we present geologic data earthquake epicenters focal mechanisms gps results and a revised active fault map consistent with this new kinematic model all data sets concur to demonstrate that active continental deformation is presently localized along a single major fault system connecting fault segments from the gulf of guayaquil to the eastern andean cordillera although secondary faults are recognized within the cordillera they accommodate a negligible fraction of relative motion compared to the main fault system the eastern limit is then concentrated rather than distributed as first proposed marking a sharp boundary between the nas the inca sliver and the subandean domain overthrusting the south american craton the nas limit follows a northeast striking right lateral transpressional strike slip system from the gulf of guayaquil isla puna to the andean cordillera and with the north south striking transpressive faults along the eastern andes eastward migration of the restraining belt since the pliocene abandonment of the sutures and reactivation of north south striking ancient fault zones lead to the final development of a major tectonic boundary south and east of the nas favoring its extrusion as a continental sliver accommodating the oblique convergence of the nazca oceanic plate toward south america

adakite like volcanism of ecuador lower crust magmatic evolution and recycling in the northern andes of ecuador a broad quaternary volcanic arc with significant across arc geochemical changes sits upon continental crust consisting of accreted oceanic and continental terranes quaternary volcanic centers occur from west to east along the western cordillera frontal arc in the inter andean depression and along the eastern cordillera main arc and in the sub andean zone back arc the adakite like signatures of the frontal and main arc volcanoes have been interpreted either as the result of slab melting plus subsequent slab melt mantle interactions or of lower crustal melting fractional crystallization and assimilation processes in this paper we present petrographic geochemical and isotopic sr nd pb data on dominantly andesitic to dacitic volcanic rocks as well as crustal xenolith and cumulate samples from five volcanic centers pululagua pichincha ilalo chacana sumaco forming a nw se transect at about 0 latitude and encompassing the frontal pululagua pichincha main ilalo chacana and back arc sumaco chains all rocks display typical subduction related geochemical signatures such as nb and ta negative anomalies and lile enrichment they show a relative depletion of fluid mobile elements and a general increase in incompatible elements from the front to the back arc suggesting derivation from progressively lower degrees of partial melting of the mantle wedge induced by decreasing amounts of fluids released from the slab we observe widespread petrographic evidence of interaction of primary melts with mafic xenoliths as well as with clinopyroxene and or amphibole bearing cumulates and of magma mixing at all frontal and main arc volcanic centers within each volcanic center rocks display correlations between evolution indices and radiogenic isotopes although absolute variations of radiogenic isotopes are small and their values are overall rather primitive e g end 1 5 to 6 87sr 86sr 0 7040 0 70435 rare earth element patterns are characterized by variably fractionated light to heavy ree la ybn 5 7 34 and by the absence of eu negative anomalies suggesting evolution of these rocks with limited plagioclase fractionation we interpret the petrographic geochemical and isotopic data as indicating open system evolution at all volcanic centers characterized by fractional crystallization and magma mixing processes at different lower to mid crustal levels as well as by assimilation of mafic lower crust and or its partial melts thus we propose that the adakite like signatures of ecuadorian rocks e g high sr y and la yb values are primarily the result of lower to mid crustal processing of mantle derived melts rather than of slab melts and slab melt mantle interactions the isotopic signatures of the least evolved adakite like rocks of the active and recent volcanoes are the same as those of tertiary normal calc alkaline magmatic rocks of ecuador suggesting that the source of the magma did not change through time what changed was the depth of magmatic evolution probably as a consequence of increased compression induced by the stronger coupling between the subducting and overriding plates associated with subduction of the aseismic carnegie ridge

late glacial and holocene avulsions of the rio pastaza megafan ecuador peru frequency and controlling factors the geomorphological study by means of remote sensing imagery of the rio pastaza megafan ecuador and northern peru reveals the traces of numerous avulsions one hundred and eight avulsion sites have been defined the location of these sites the available radiocarbon ages as well as historical maps of the seventeenth century enable us to propose an evolution history of the migration and avulsions of the rio pastaza since the last glacial maximum the first avulsions of the rio pastaza occurred after the lgm in a zone close to and roughly parallel to the sudandean front where the developed avulsion gave a distributive pattern to the ancient stream of the rio pastaza in an area located between the modern rio morona and pastaza where they caused the rio pastaza to develop a fan like distributary pattern this is interpreted as a response to thrust related forelimb tilt progressively shifting eastward the rio pastaza and the apex of the megafan this sequence of events ended with the great diversion of the rio pastaza towards the modern rios corrientes and tigre avulsions occurred in the tigre corrientes area between 9200 and 8 500 years cal bp afterwards the rio pastaza was diverted to its present day north south course this last significant avulsion occurred before ad 1691 in the area located between the modern rio morona and pastaza avulsion frequency probably overestimated ranges between 100 and 200 years in the rios tigre and corrientes area avulsion frequency probably underestimated ranges from 300 to 400 years regional tectonics is likely to have triggered most of the avulsions in the morona pastaza area but its influence is restricted to this area the factors controlling the avulsions in the tigre corrientes area are less clear because the frequently described hydrologic driven avulsion as observed in areas characterized by contrasted hydrologic cycles are inconsistent with the characteristics of the hydrologic cycles of the rio pastaza

rbsr systematics of rocks related to the ries crater germany abstract rb sr whole rock biotite ages of crystalline basement rocks from ries crater are 323 8ma initial 87 sr 86 sr rat are 0 7081 0 0007 these values compare perfectly with those for moldanubian rocks exposed in the bayerischer wald and schwarzwald it is demonstrated that impact related shock pressures up to 15 gpa and temperatures as high as 300 c did not disturb the rb sr isotopic systems of the rocks comparison of sr isotopic compositions of tertiary upper freshwater molasse sediments with those of moldavites suggests that such sediments can be regarded as source material of these tektites our data for components of the sediments show that a mixture of clay weathered crystalline rocks and secondary carbonates in addition to detrital quartz can explain the observed range of 87 sr 86 sr ratios in moldavites a similar comparison of moldavites with bentonites from the tertiary molasse definitely rules out a genetical relationship between these two materials we regard liquid gas filled bubbles in bentonite glasses as proof of their volcanic nature

sediment budget of the napo river amazon basin ecuador and peru the upstream downstream sediment budget along the napo river 100 520 km2 6300 m3 s 1 was studied in the andean foothills of ecuador at the west of the amazon basin a comparative study was made during four hydrological cycles 2001 2005 for three hydrological stations located upstream and during one hydrological cycle 2004 2005 for the fourth one located near the mouth of the napo river region of iquitos in peru this analysis showed an unusual increase in the concentration of suspended sediment recorded for the western part of the amazon plain like the runoff 81 l s 1 km2 which is a world s maximum the erosion rate 1160 t km 2 year 1 i e 47 of total suspended solid tss export at the exit of ecuador one of the highest for a floodplain basin is the result of a stepper slope than in the rest of the andean foothills where typically sedimentation phenomena are predominant and can be explained in part by a greater tectonic activity similar phenomenes were evidenced in small mountainous rivers in new guinea milliman and syvitski 1992 milliman 1995 on the headwaters of the napo river drainage basin the tectonic uplift causes the pastaza megafan s existence this progressively diverts the course of napo river towards north and also provokes the remobilization of fine fluvial deposits moreover this geodynamic trend is completed by the impact of volcanic eruption earthquakes and landslides the combination of these phenomena so common in the region has provided a large sediment transfer not only at present but also in the past as can be confirmed by the presence of incised terraces mainly formed by volcanic materials then these results were compared with a similar study carried out further south in the madeira basin at the bolivian foothills these studies show the spatio temporal variability of the relation between sediment transfer and geodynamic processes at the andean piedmont copyright 2009 john wiley sons ltd