millennial scale sea surface temperature and patagonian ice sheet changes off southernmost chile 53 s over the past 60 kyr 1 glacial millennial scale paleoceanographic changes in the southeast pacific and the adjacent southern ocean are poorly known due to the scarcity of well dated and high resolution sediment records here we present new surface water records from sediment core md07 3128 recovered at 53 s off the pacific entrance of the strait of magellan the alkenone derived sea surface temperature sst record reveals a very strong warming of ca 8 c over the last termination and substantial millennial scale variability in the glacial section largely consistent with our planktonic foraminifera oxygen isotope 18o record of neogloboquadrina pachyderma sin the timing and structure of the termination and some of the millennial scale sst fluctuations are very similar to those observed in the well dated sst record from odp site 1233 41 s and the temperature record from drowning maud land antarctic ice core supporting the hemispheric wide antarctic timing of sst changes however differences in our new sst record are also found including a long term warming trend over marine isotope stage mis 3 followed by a cooling toward the last glacial maximum lgm we suggest that these differences reflect regional cooling related to the proximal location of the southern patagonian ice sheet and related meltwater supply at least during the lgm consistent with the fact that no longer sst cooling trend is observed in odp site 1233 or any sst chilean record this proximal ice sheet location is documented by generally higher contents of ice rafted debris ird and tetra unsaturated alkenones and a slight trend toward lighter planktonic 18o during late mis 3 and mis 2

timing of millennial scale climate change at siple dome west antarctica during the last glacial period using atmospheric methane and the isotopic composition of o2 as correlation tools we place the dd record of ice from the siple dome west antarctica ice core on a precise common chronology with the gisp2 greenland ice core for the period from 9 to 57 ka the onset of major millennial warming events in siple dome preceded major abrupt warmings in greenland and the pattern of millennial change at siple dome was broadly similar though not identical to that previously observed for the byrd ice core also in west antarctica the addition of siple dome to the database of well dated antarctic paleoclimate records supports the case for a coherent regional pattern of millennial scale climate change in antarctica during much of the last ice age and glacial interglacial transition

the sensitivity of the climate response to the magnitude and location of freshwater forcing last glacial maximum experiments abstract proxy records indicate that the locations and magnitudes of freshwater forcing to the atlantic ocean basin as iceberg discharges into the high latitude north atlantic laurentide meltwater input to the gulf of mexico or meltwater diversion to the north atlantic via the st lawrence river and other eastern outlets may have influenced the north atlantic thermohaline circulation and global climate we have performed last glacial maximum lgm simulations with the ncar community climate system model ccsm3 in which the magnitude of the freshwater forcing has been varied from 0 1 to 1 sv and inserted either into the subpolar north atlantic ocean or the gulf of mexico in these glacial freshening experiments the less dense freshwater provides a lid on the ocean water below suppressing ocean convection and interaction with the atmosphere above and reducing the atlantic meridional overturning circulation amoc this is the case whether the freshwater is added directly to the area of convection south of greenland or transported there by the subtropical and subpolar gyres when added to the gulf of mexico the amoc reduction is less for the smaller freshwater forcings but is not linear with the size of the freshwater perturbation the recovery of the amoc from a slow state is 200 years for the 0 1 sv experiment and 500 years for the 1 sv experiment for glacial climates with large northern hemisphere ice sheets and reduced greenhouse gases the cold subpolar north atlantic is primed to respond rapidly and dramatically to freshwater that is either directly dumped into this region or after being advected from the gulf of mexico greenland temperatures cool by 6 8 c in all the experiments with little sensitivity to the magnitude location or duration of the freshwater forcing but exhibiting large seasonality sea ice is important for explaining the responses the northern hemisphere high latitudes are slow to recover antarctica and the southern ocean show a bipolar response with warming and reduced sea ice this warming continues after the cessation of the freshwater forcing and shows a dependence on the duration of the freshwater forcing equatorward of the expanded sea ice the simulated temperature and salinity anomalies are sensitive to the amount of colder and fresher waters that are advected out of the subpolar north atlantic in the tropical atlantic the recovery of the intertropical convergence zone itcz from its more southerly position during the freshwater forcing is much more rapid than the recovery of the amoc and is more related to the recovery of low latitude surface temperatures than greenland temperature or sea ice these results have implications for using proxy records as indirect measures of the amoc

on the definition of seasons in paleoclimate simulations with orbital forcing 1 orbital forcing is a major driver of climate variability on timescales of 10 000 to 100 000 years changes in the orbital parameters cause variations in the length of the seasons by several days consequently models using a fixed present day calendar result in biased paleoseasons especially in boreal autumn when the vernal equinox is used as an anchor point the bias is estimated for temperatures and precipitation in a transient model simulation over the last 21 000 years and an accelerated simulation over the last 129 000 years the largest differences of up to 4 k occur over the continents in high latitudes precipitation estimates are mostly affected in the low latitudes the time dependent bias is large enough to modify the temporal characteristics of temperature and precipitation indices it is discussed to what extent the bias in one season is distorting comparisons between models and paleoproxies the bias has minor implications for proxy model comparisons in general however proxies of monsoon activity should be compared with fixed angular seasons for process studies and climate sensitivity studies the use of fixed angular seasons is imperative

340 000 year centennial scale marine record of southern hemisphere climatic oscillation in order to investigate rapid climatic changes at mid southern latitudes we have developed centennial scale paleoceanographic records from the southwest pacific that enable detailed comparison with antarctic ice core records these records suggest close coupling of mid southern latitudes with antarctic climate during deglacial and interglacial periods glacial sections display higher variability than is seen in antarctic ice cores which implies climatic decoupling between mid and high southern latitudes due to enhanced circum antarctic circulation structural and temporal similarity with the greenland ice core record is evident in glacial sections and suggests a degree of interhemispheric synchroneity not predicted from bipolar ice core correlations

four climate cycles of recurring deep and surface water destabilizations on the iberian margin centennial climate variability over the last ice age exhibits clear bipolar behavior high resolution analyses of marine sediment cores from the iberian margin trace a number of associated changes simultaneously proxies of sea surface temperature and water mass distribution as well as relative biomarker content demonstrate that this typical north south coupling was pervasive for the cold phases of climate during the past 420 000 years cold episodes after relatively warm and largely ice free periods occurred when the predominance of deep water formation changed from northern to southern sources these results reinforce the connection between rapid climate changes at mediterranean latitudes and century to millennial variability in northern and southern polar regions

atlantic pacific seesaw and its role in outgassing co2 during heinrich events 1 paleoproxy records indicate that a marked weakening of the atlantic meridional overturning circulation amoc during heinrich events was often accompanied by a notable atmospheric co2 increase however previous modeling studies display conflicting atmospheric co2 responses to an amoc shutdown here we use model simulations combined with paleoproxy records to show that depending on the deep and bottom water transport in the northern and southern pacific ocean during an amoc weakening the ocean can act either as a sink or a source of carbon results from idealized meltwater experiments as well as from a transient experiment covering heinrich stadial 4 suggest that a shutdown of the amoc during heinrich stadials 4 hs4 and 1 hs1 led to an enhancement of antarctic bottom water aabw and north pacific deep water npdw transport we show that enhanced deep and bottom water transport in the pacific ocean ventilates deep pacific carbon through the southern ocean thus contributing to a rise in atmospheric co2 this mechanism yields a good agreement between paleoproxy records and modeling results thus highlighting the possible establishment of an atlantic pacific seesaw during heinrich stadials enhanced aabw and npdw transport could account for most of the observed atmospheric co2 increase during hs4 and for about 30 of the atmospheric co2 increase during hs1

the role of vertical eddy flux in southern ocean heat uptake 1 the role of changing vertical eddy heat flux on southern ocean heat uptake is investigated in an idealized eddy permitting ocean model enhanced air sea heat flux drives deep reaching southern warming due to a reduction in the isopycnal meridional temperature gradient and therefore decreased upward eddy heat flux this mechanism is qualitatively similar in models with either permitted or parameterized eddies due to its dependence on the isopycnal temperature gradient rather than the dynamical response of the eddy field in contrast increased wind stress drives mid depth southern ocean cooling through an enhancement of the eddy field and resultant eddy heat divergence the transient cooling extends over multiple decades while the mean flow adjusts to balance the faster eddy response this wind driven cooling mechanism has not been captured by coarse resolution models with fixed eddy parameterizations and is a possible candidate for the recent cooling observed in the southern ocean

late quaternary sea ice history in the indian sector of the southern ocean as recorded by diatom assemblages abstract a modern analog technique mat5201 31 has been applied to fossil diatom assemblages to provide down core estimates of february sea surface temperatures ssts and of sea ice duration over the past 220 000 years at 56 40 s 160 14 e at the core location sea ice progression lagged the sst drop by 1 ka at interglacial glacial transitions and sea ice retreat was almost synchronous to the sst increase at glacial interglacial terminations sea ice increased continuously during glacial periods to reach its maximum extent at the end of glacial times although ssts were almost constant during glacials this indicates that ssts are the major parameter determining the advance and retreat of sea ice at transitions but that the sea ice advance during glacial conditions may be related to positive feedbacks of the ice on albedo air temperature and meridional wind stress the strong correlation r 0 75 between sea ice duration at the core location and the vostok co2 record argues for a control of antarctic sea ice extent on atmospheric co2 concentration via the modification of the ocean to atmosphere gas balance

dust and sea salt variability in central east antarctica dome c over the last 45 kyrs and its implications for southern high latitude climate a detailed record of non sea salt calcium a proxy for dust and sea salt sodium a proxy for sea salt covering the last 45 kyr is presented it shows that in the first part of the transition from the last glacial period to the holocene 18 15 kyr bp the changes in dust flux mainly reflect changes at the dust source namely vegetation cover and local climate the changes in the later part of the transition 12 11 kyr bp are similar in extent to the changes seen in sea salt and most likely reflect a reorganization of the atmospheric circulation during the last glacial period considerable variation of dust but not of sea salt is observed pointing to climatic changes in patagonia the main dust source for dome c a comparison of the glacial records from dome c and taylor dome suggests that similar influences controlled aerosol input at both sites during this period

dansgaard oeschger cycles interactions between ocean and sea ice intrinsic to the nordic seas dansgaard oeschger d o cycles are the most dramatic frequent and wide reaching abrupt climate changes in the geologic record on greenland d o cycles are characterized by an abrupt warming of 10 5 c from a cold stadial to a warm interstadial phase followed by gradual cooling before a rapid return to stadial conditions the mechanisms responsible for these millennial cycles are not fully understood but are widely thought to involve abrupt changes in atlantic meridional overturning circulation due to freshwater perturbations here we present a new high resolution multiproxy marine sediment core monitoring changes in the warm atlantic inflow to the nordic seas as well as in local sea ice cover and influx of ice rafted debris in contrast to previous studies the freshwater input is found to be coincident with warm interstadials on greenland and has a fennoscandian rather than laurentide source furthermore the data suggest a different thermohaline structure for the nordic seas during cold stadials in which relatively warm atlantic water circulates beneath a fresh surface layer and the presence of sea ice is inferred from benthic oxygen isotopes this implies a delicate balance between the warm subsurface atlantic water and fresh surface layer with the possibility of abrupt changes in sea ice cover and suggests a novel mechanism for the abrupt d o events observed in greenland ice cores

indium in cassiterite and ores of tin deposits abstract the results obtained with la icp ms by less abundant lighter 113 in isotope and epma show that in cassiterite of cassiterite quartz veins the indium contents do not exceed 160 ppm while cassiterite from sn sulfide veins is characterized by higher indium contents from 40 to 485 ppm sulfides of sn sulfide veins unlike sulfides of cassiterite quartz veins also have the highest indium contents fe sphalerite 100 25 000 ppm chalcopyrite up to 1000 ppm and stannite up to 60 000 ppm indium contents in the sn sulfide ore of the tigrinoe and pravourmiiskoe deposits obtained using sr xrf icp ms and atomic absorption methods range from 10 to 433 ppm with average values of 56 65 ppm indium rich sn sulfide mineralization in five large sn ag ore districts of the far east russia khingansky badzhalsky komsomolsky arminsky kavalerovsky provides the impetus for further exploration of deposits with sn sulfide mineralization as the most promising indium resources in russia empirical observations from geology and geochronology of cassiterite quartz and sn sulfide mineralization show that the combined contribution from granite and alkaline subalkaline mafic sources and multistage ore forming processes doubled indium resources of deposits being the main factors in the formation of high grade indium mineralization

an atlas of the distribution of calcium carbonate in sediments of the deep sea historical observations of the concentration of calcium carbonate in global deep sea sediments are compiled and compared with a new gridded field of seawater co3 concentration to reveal regional variations in the calcite lysocline the most obvious mode of variability of the calcite lysocline is the thickness of the lysocline defined here as the difference in overlying water carbonate saturation co3 between high and low calcite sediments with a thicker lysocline in the atlantic than in the pacific i attribute this variation to differences in the delivery rate of terriginous material a recent model for the lower glacial atmospheric pco2 proposed to change the relationship between the depth of the lysocline and the co3 of the water column by changing the rain rate ratio of organic carbon to calcite production the rain ratio model archer and maier reimer 1994 i search the data set for analogs to the proposed glacial world by looking for a link between the regional climate at the sea surface and the depth of the lysocline below the co3 at the carbonate compensation depth ccd in the tropics appears to be 10 20 mol kg 1 co3 more undersaturated than in high latitudes but this is smaller than the 40 mol kg 1 shift required by the model in addition the general resemblance of the glacial lysocline to the present day requires that the proposed shift in co3 at the ccd be globally uniform rather than locally variable as climate forcing would probably generate i conclude that the rain ratio model would probably require some globally uniform perturbation during glacial time such as a change in ocean si content if it is to explain the entire pco2 decrease observed in the glacial atmosphere finally i grid the sedimentary data to estimate that the inventory caco3 which is available to neutralize fossil fuel co2 is approximately 1600 gt carbon a quantity which may be exceeded by fossil fuel release in the next several centuries

a 70 kyr sea surface temperature record off southern chile ocean drilling program site 1233 1 we present the first high resolution alkenone derived sea surface temperature sst reconstruction in the southeast pacific ocean drilling program site 1233 covering the major part of the last glacial period and the holocene the record shows a clear millennial scale pattern that is very similar to climate fluctuations observed in antarctic ice cores suggesting that the southern hemisphere high latitude climate changes extended into the midlatitudes involving simultaneous changes in air temperatures over antarctica sea ice extent extension of the antarctic circumpolar current and westerly atmospheric circulation a comparison to other midlatitude surface ocean records suggests that this antarctic millennial scale pattern was probably a hemisphere wide phenomenon in addition we performed sst gradient reconstructions over the complete latitudinal range of the pacific eastern boundary current system for different time intervals during the last 70 kyr the main results suggest an equatorward displaced subtropical gyre circulation during marine isotope stages 2 and 4

a new constraint on the size of heinrich events from an iceberg sediment model abstract heinrich layers anomalously thick layers of ice borne sediment in the north atlantic ocean have long been associated with abrupt climate changes in glacial times however there is still no consensus on either the exact amount of ice needed to transport this sediment or how such a large volume of ice could be produced using an iceberg model that includes sediment we simulate the delivery of sediment to the north atlantic during such an event our model assumes that sediment is uniformly distributed within the ice with a concentration of 4 unlike sediment models which assume that the sediment lies in a single layer this model can carry sediment all the way from the western to the eastern north atlantic we use a variety of different estimates for the total volume of ice released to model the sediment layer thickness and we show that to best fit the observations 60 10 4 km 3 with a plausible range of 30 120 10 4 km 3 of ice needs to be released this is equivalent to a 0 04 sv 10 6 m 3 s 1 with a plausible range of 0 02 0 08 sv release of freshwater over the 500 yr of a typical heinrich event this is a smaller flux of water than is required to show a significant impact on the global climate in most current state of the art gcms

ice core evidence of abrupt climate changes ice core records show that climate changes in the past have been large rapid and synchronous over broad areas extending into low latitudes with less variability over historical times these ice core records come from high mountain glaciers and the polar regions including small ice caps and the large ice sheets of greenland and antarctica

millennial scale iceberg discharges in the irminger basin during the last glacial period relationship with the heinrich events and environmental settings high resolution records of coarse lithic content and oxygen isotope have been obtained in a piston core from the irminger basin the last glacial period is characterized by numerous periods of increased iceberg discharges originating partly from iceland and corresponding to millennial scale instabilities of the coastal ice sheets and ice shelves in the nordic area a comparison with midlatitude sediment cores shows that ice rafted material corresponding to the heinrich events was deposited synchronously from 40 to 60 n there are thus two oscillating systems every 5 10 kyr massive iceberg armadas are released from large continental ice caps whereas more frequent instabilities of the coastal ice sheets in the high latitude regions occur every 1 2 3 8 kyr at the time of the heinrich events the synchroneity of the response from all the northern hemisphere ice sheets attests the existence of strong interactions between the two systems

isotopic and hydrologic responses of small closed lakes to climate variability hydroclimate reconstructions from lake sediment oxygen isotope records and mass balance models abstract hydroclimate sensitivity simulations were conducted with a lake catchment hydrologic and isotope mass balance model adapted to two small closed lakes castor and scanlon located in the pacific northwest model simulations were designed to investigate the combined influences of persistent disequilibrium reddening and equifinality on lake water and sediment i e biogenic and endogenic carbonate mineral oxygen isotope 18 o values and to provide a basis for quantitative probabilistic climate reconstructions using lake sediment 18 o records simulation results indicate that within closed basin lakes changes in long term i e multi decadal precipitation amounts produce inconsistent responses in lake water and sediment 18 o values that are strongly influenced by lake basin outseepage and morphometry simulations of variable initial conditions in which randomly generated monthly climate data i e precipitation temperature and relative humidity were used to force the model during the equilibration period which precedes the application of instrumental climate data demonstrate that castor lake and scanlon lake have a somewhat limited isotopic memory of 10 years additional tests conducted using a monte carlo ensemble in which random climate data were used to force the model combined with 18 o analyses of water samples collected from 2003 to 2011 ad indicate that within small closed lakes in the pacific northwest november february precipitation is the strongest seasonal climatic control on sediment oxygen isotope values further a monte carlo based reconstruction of 20 year average november february precipitation amounts strongly correlates r 2 0 66 to instrumental values from the 20th century with all observed values falling within modeled 95 prediction limits indicating that probabilistic quantitative paleoclimate interpretations of lake sediment 18 o records are attainable

millennial scale propagation of atlantic deep waters to the glacial southern ocean the compilation of changes in the magnetic properties at various sites distributed along the path of the deepwater mass in north atlantic shows large amplitude short term fluctuations reflecting changes in the strength of the north atlantic deep water nadw these changes which suggest a two mode deep glacial circulation dynamic are perfectly concurrent with air temperature changes over greenland they also share a similar pattern with those reported in the nd isotope ratios from the deep cape basin during the same time period greenland interstadials were accompanied by increased flow speed of nadw and relatively more nadw reaching the southern ocean while during greenland stadials and heinrich events both the north atlantic flow speed of nadw and its presence in the south atlantic were reduced it is demonstrated that both proxies are tracing the same water mass and their reliability for monitoring changes in the deepwater circulation is therefore clearly established after using the climatically independent geomagnetic assisted stratigraphy to put the northern and southern hemisphere records on the same age scale the south atlantic record appears to lag changes in north atlantic flow speeds by approximately 860 220 years during the most prominent and best defined cycles interstadials 12 and 8 although future work is needed this significant offset provides a first observation and tentative quantification of the time needed for glacial northern component water to mix downward and to flow from the north to the south atlantic

contribution of enhanced antarctic bottom water formation to antarctic warm events and millennial scale atmospheric co2 increase abstract during marine isotope stage 3 the atlantic meridional overturning circulation amoc weakened significantly on a millennial time scale leading to greenland stadials ice core records reveal that each greenland stadial is associated with a warming over antarctica so called antarctic isotope maximum aim and that atmospheric co 2 increases with antarctic temperature during the long greenland stadials here we perform transient simulations spanning the period 50 34 ka b p with two earth system models loveclim and the uvic escm to understand the possible link between changes in the amoc changes in high latitude southern hemispheric climate and evolution of atmospheric co 2 we find that oceanic carbon releases due to the amoc resumption during stadial interstadial transitions lead to an atmospheric co 2 increase however the atmospheric co 2 increases observed during the first parts of aim12 47 6 ka b p and aim8 39 8 ka b p occur during periods of weak amoc hs5 and hs4 respectively and could instead be explained by enhanced antarctic bottom water transport enhanced antarctic bottom water formation is shown to effectively ventilate the deep pacific carbon and lead to co 2 outgassing into the atmosphere in addition changes in the amoc alone are not sufficient to explain the largest antarctic isotope maxima namely aim12 and aim8 stronger formation of antarctic bottom water during aim12 and aim8 would enhance the southern high latitude warming and lead to a better agreement with high southern latitude paleoproxy records the robustness of this southern warming response is tested using an eddy permitting coupled ocean sea ice model we show that stronger antarctic bottom water formation contributes to southern ocean surface warming by increasing the southern ocean meridional heat transport

comparison of organic uk 37 texh86 ldi and faunal proxies foraminiferal assemblages for reconstruction of late quaternary sea surface temperature variability from offshore southeastern australia several proxies have been developed to reconstruct past sea surface temperature sst but different proxies may reflect temperatures of different seasons and each proxy is characterized by certain uncertainties therefore a multiproxy approach is preferred to precisely reconstruct sst here we reconstruct sst of the ocean offshore southeastern australia murray canyons area for the last 135 ka using three independent organic proxies texh86 based on glycerol dialkyl glycerol tetraethers gdgts uk 37 based on alkenones and ldi based on long chain diols in addition to foraminiferal faunal assemblages the organic proxy records show similar trends with the highest temperature 21 c for uk 37 and texh86 and 25 c for ldi during the last interglacial and lowest temperature 8 c for texh86 10 c for uk 37 and 12 c for ldi during the last glacial maximum however the differences in absolute sst estimates obtained by the organic proxies varied over time with differences of up to 9 c between ldi and texh86 the seasonal sst reconstructions based on the modern analogue of foraminiferal assemblages also show similar trends as the organic proxies with highest temperatures during the last interglacial 23 c for the warmest month sst 20 c for mean annual and 18 c for the coolest month and lowest temperature during the last glacial maximum 14 c for the warmest month 11 c for mean annual and 9 c for the coolest month down core comparison between the reconstructed ssts of the organic and inorganic proxies shows that ldi inferred temperatures compare well with the temperature of the warmest month texh86 with the temperature of the coolest month and uk 37 with mean annual temperature an increase in texh86 sst estimates relative to those of other proxies during deglaciations and interglacials suggests that either winter temperatures rapidly warmed possibly due to an invigoration of the leeuwin current over the core site or there was a change in the growth season of the thaumarchaeota the source organism of gdgts our study shows the benefits of a multiproxy approach in the interpretation of sst proxies leading to a more robust knowledge of past ocean temperature changes

zooming in on heinrich layers theories explaining the origin of the abrupt massive discharges of ice rafted detritus ird into the glacial north atlantic the heinrich layers hls generally point to the laurentide ice sheet as the sole source of these events until it was found that the irds also originated from icelandic and european ice sheets bond and lotti 1995 snoeckx et al 1999 grousset et al 2000 this apparent contradiction must be reconciled as it raises fundamental questions about the mechanism s of hl origin we have analyzed two 12 cm thick hls in an ultrahigh resolution mode 1 2 century intervals in a mid atlantic ridge piston core the 18o record n pachyderma left coiling reveals strong excursions induced by the melting of the icebergs these excursions are associated with a strong decrease in the amount of planktic foraminafersand with a 3 c cooling of the surface waters counts of coarse detrital grains reveal that ird are deposited according to a typical sequence 1 volcanic glass 2 quartz and feldspars 3 detrital carbonate that implies a chronology in the melting of the differentpan atlantic ice sheets sr and nd isotopic composition confirm that in both heinrich layers h1 and h2 precursor ird came from first europe iceland followed then by laurentide derived ird an internal cyclicity can be identified during h1 and h2 about four to six major abrupt discharges occurred roughly on a century timescale the 13c and 15n records reveal that dominant inputs of continent derived organic matter are associated with ird within the hls hiding the plankton productivity signal