the present day formation of apatite in mexican continental margin sediments abstract results of pore water and sediment analyses from the western mexican continental margin strongly suggest the present day formation of apatite the interstitial water phosphate and fluoride profiles indicate chemical removal at a depth which corresponds to a large maximum in the phosphorus content of the sediments apatite is identified within this maximum via x ray diffraction but is elsewhere undetectable in the core radioisotopic thorium uranium and radium data support the conclusion that this deposit is modern the present day depositional environment is consistent with those reported by other workers for phosphorite formation with the exception that pore water magnesium is not depleted below its seawater value

appendix meteorites a brief tutorial there are four broad categories of meteorites chondrites achondrites irons and stony irons these are subdivided into meteorite groups the basic unit of meteorite classification although no formal guideline is in place for the minimum number of meteorites needed to define a group common practice is that there should be five or more members in a group a defined meteorite group is thought to be derived from a single asteroid however some groups are genetically related and are derived from a common parent asteroid chondrites are primitive stony meteorites rocks whose compositions are little changed since their formation in the solar nebula there are fourteen defined groups of chondrites and they make up the vast majority of meteorites falling to earth in the current epoch achondrites are stony meteorites of two broad types some are primitive materials like chondrites but most are the products of igneous differentiation there are ten defined groups of achondrites of which seven are differentiated types irons are also the products of asteroidal differentiation having crystallized from metallic melts separated from chondritic precursors there are thirteen defined groups of iron meteorites stony irons are also differentiated materials and both the rocky and metallic phases were formed by igneous processes on asteroids there are two defined groups of stony iron meteorites in addition to those that fit into groups there are many meteorites that are unique or for which there are less than five examples these ungrouped meteorites make up a substantial fraction of meteorites recovered to date

the mid cretaceous earth paleogeography ocean circulation and temperature atmospheric circulation a reconstruction of the global paleogeography of the mid cretaceous 100 m y ago including adjustment of continental outlines to account for microplate movements cmstal shortening and accretion in mid cretaceous and later orogenic regions is described and a map presented on the modified continents coastlines and significant mountain ranges are added this paleogeography is used as a framework for a reconstruction of ocean surface circulation and temperature distribution then the main features of the atmospheric circulation are deduced using the paleogeography and ocean temperatures as boundary conditions relative to the present these features are a much weaker westerly wind belt and greater seasonality of wind patterns leading to more extreme surface climates over the continents slightly equatorward positions of the subtropical anticyclones and monsoonal regimes over the continental margins bordering tethys and the central atlantic a comparison of the results with climatic evidence from t

linking phosphogenic episodes on the southeast u s margin to marine δ13c and δ18o records the relative abundance of phosphorite as a function of age was estimated for the southeastern united states using 87sr 86sr derived ages the sr derived ages define seven phosphogenic episodes on the northeast florida platform phosphorus burial rate estimates for the southeastern united states margin range from 2 to 12 109 mol p yr 1 and phosphorus accumulation rates range from 1 to 3 mol cm 2 yr 1 similar to modern phosphogenic margins the estimated amount of organic carbon burial ranges from 1 to 12 1016 mol c sufficient to shift the ocean 13c by 0 1 to 0 6 on long time scales 1 m y phosphogenesis in the southeastern united states corresponds to increased organic carbon burial positive 13c shifts and rising sea level negative 18o shifts on shorter time scales 1 m y the correlation of phosphogenesis to positive 13c and 18o shifts suggests a different relation between phosphogenesis organic carbon burial eustasy and climate transitions during the miocene

compositions of large metal nodules in mesosiderites links to iron meteorite group iiiab and the origin of mesosiderite subgroups large mesosiderite metal nodules were studied petrographically and by neutron activation their large sizes minimized the effects of silicate contamination and dilution by fe reduced from feo the remarkable mixture of subequal amounts of metal and basaltic and pyroxenitic silicates in mesosiderites can be explained by the accretion of a core like metal mass from one asteroid onto the surface of another asteroid our data show that the accreted mass had a composition roughly similar to that of the iiiab iron meteorite core consistent with other evidence of close genetic links between these and other related groups the siderophile compositional pattern the very limited compositional range the inferred large projectile target ratio and the electrical interconnectedness of mesosiderite metal indicate that the bulk of the metal was molten when accreted mesosiderites have been divided into plagioclase and tridymiterich subgroup a and orthopyroxene rich subgroup b on the basis of modal silicate mineralogy roughly the same subgroups are defined by metal compositions au as ni and cu are generally higher and w lower in subgroup a than in subgroup b in our sample set a widmanstatten pattern is only observed in nodules from subgroup a a plausible model is that subgroup a best preserves the compositions of the target regolithic silicates and accreted core subgroup b is comprised of these materials together with a minor amount of coremantle materials consisting of olivine and refractory ni poor metal the independent covariation of ga re and ir may in part reflect fractionations during impact heating events the anomalous mesosiderite reckling peak a79015 is strongly depleted in refractory siderophiles and slightly enriched in volatile siderophiles such evolved metal requires a formation distinct from common mesosiderite metal

oxygen isotope studies of carbonaceous chondrites abstract the carbonaceous chondrites display the widest range of oxygen isotopic composition of any meteorite group as a consequence of the interaction of primordial isotopic reservoirs in the solar nebula these isotopic variations can be used to identify the reservoirs and to determine conditions and loci of their interactions we present a comprehensive set of whole rock analyses of cv co ck cm cr ch and ci chondrites as well as selected components of some of these meteorites a simple model is developed which describes the isotopic behavior during parent body aqueous alteration processes the process of thermal dehydration also produces a recognizable effect in the oxygen isotopic composition

forcing mechanisms for mid cretaceous black shale formation evidence from the upper aptian and lower albian of the vocontian basin se france calcareous nannoplankton palynomorph benthic foraminifera and oxygen isotope records from the supraregionally distributed niveau paquier early albian age oceanic anoxic event 1b and regionally distributed niveau kilian late aptian age black shales in the vocontian basin se france exhibit variations that reflect paleoclimatic and paleoceanographic changes in the mid cretaceous low latitudes to quantify surface water productivity and temperature changes nutrient and temperature indices based on calcareous nannofossils were developed the nutrient index strongly varies in the precessional band whereas variations of the temperature index reflect eccentricity since polar ice caps were not present during the mid cretaceous these variations probably result from feedback mechanisms within a monsoonal climate system of the mid cretaceous low latitudes involving warm humid and cool dry cycles a model is proposed that explains the formation of mid cretaceous black shales through monsoonally driven changes in temperature and evaporation precipitation patterns the lower albian niveau paquier which has a supraregional distribution formed under extremely warm and humid conditions when monsoonal intensity was strongest bottom water ventilation in the vocontian basin was diminished probably due to increased precipitation and reduced evaporation in regions of deep water formation at low latitudes surface water productivity in the vocontian basin was controlled by the strength of monsoonal winds the upper aptian niveau kilian which has a regional distribution only formed under a less warm and humid climate than the niveau paquier low latitude deep water formation was reduced to a lesser extent and or on regional scale only the threshold for the formation of a supraregional black shale was not reached the intensity of increases in temperature and humidity controlled whether black shales developed on a regional or supraregional scale at least in the vocontian basin the increased preservation of organic matter at the sea floor was more significant in black shale formation than the role of enhanced productivity

oxygen isotope studies of achondrites abstract oxygen isotope abundances provide a powerful tool for recognizing genetic relationships among meteorites among the differentiated achondrites three isotopic groups are recognized l snc mars 2 earth and moon and 3 hed howardites eucrites diogenites the hed group also contains the mesosiderites main group pallasites and silicates from iiiab irons the angrites may be marginally resolvable from the hed group within each of these groups internal geologic processes give rise to isotopic variations along a slope 1 2 fractionation line as is well known for terrestrial materials variations of 17o from one planet to another are inherited from the inhomogeneities in the solar nebula as illustrated by the isotopic compositions of chondrites and their constituents among the undifferentiated achondrites five isotopic groups are found 1 aubrites 2 winonaites and iab iiicd irons 3 brachinites 4 acapulcoites and lodranites and 5 ureilites the isotopic compositions of aubrites coincide with the earth and moon and also with the enstatite chondrites these bodies apparently were derived from a common reservoir the isotopic composition of which was established at the chondrule scale by nebular processes isotopic similarities between chondrites and achondrites are seen only for the following instances 1 enstatite chondrites and aubrites 2 h chondrites and he irons and 3 l or ll chondrites and iva irons the isotopic data also support the following genetic associations 1 winonaites and iab iiicd irons 2 acapulcoites and lodranites and 3 ureilites and dark inclusions of c3 chondrites an attempt to reconcile the whole planet isotopic compositions of earth mars and the eucrite parent body with mixing models of their chemical compositions failed it is not possible to satisfy both the chemical and isotopic compositions of the terrestrial planets using known primitive solar system components

depositional sequences of the duwi sibâiya and phosphate formations egypt phosphogenesis and glauconitization in a late cretaceous epeiric sea

did the rifting of the atlantic ocean cause the cretaceous thermal maximum the cretaceous thermal maximum was a major turning point in the history of earth s climate this interval of peak warmth in the turonian has been attributed to very high atmospheric pco2 resulting from rapid outgassing rates although crustal cycling rates peaked in the aptian albian interval on the basis of coupled ocean atmosphere model simulations of the middle cretaceous we hypothesize that the formation of an atlantic gateway could have contributed to the cretaceous thermal maximum differences between prerifting and postrifting climate experiments demonstrate substantial regional oceanographic changes in the north and south atlantic basins that are consistent with oxygen isotopic evidence used to infer a cretaceous thermal maximum the model results help reconcile the paleoclimate record inferred from foraminiferal d 18 o with our understanding of climate dynamics and cretaceous tectonism

cenomanian phosphorites in the former soviet union abstract cenomanian nodular phosphorites are widespread over vast areas of the precambrian east european platform eep they are found in various parts of the cenomanian forming thicker and richer beds close to the cenomian turonian boundary they are encountered nearly ubiquitously but are concentrated on synsedimentary highs in thin and condensed sequences with numerous hiatuses all of the economic deposits are confined to the paleohighss phosphorite pavements made of amalgamated roworked and concentrated concretions are typical of the condensed sequences more complete successions occur in the adjacent lows where upper cenomanian sediments have been proved phosphorite in the lows are found as in situ concretions either scattered irregularly or aligned in rows and spaced rather regularly calculations show that some 25 gt of p 2 o 5 was buried during the cenomanian a positive 13 c anomaly was found to coincide with a thin layer of sandy to silty chalk containing phosphatic intraclasts the layer lies directly on the youngest and thickest pavement the anomaly is believed to represent oceanic anoxic event 2 oae 2 on the eep consequently 1 phosphorite pavement is most probably of upper cenomanian age and 2 phosphogenesis is related to oae 2 there is no black shale amidst the upper cenomanian on the eep and sea level variation during that time might be responsible for both the spatial and temporal differentiation of phosphorites and black shales the former were deposited during transgressive phases whereas the latter correspond to subsequent sea level highstand the extent of spatial differentiation might be preconditioned by the scale of difference between corresponding sea levels an upwelling scenario is hardly probable to explain the origin of the cenomanian phosphorite of the eep a river input mechanism is more probable as it was advocated by bushinsky

carbon and phosphorus cycling in anoxic sediments of the saanich inlet british columbia abstract uncertainty currently exists about the removal of carbon c and phosphorus p from the oceanic reservoir especially in low oxygen settings in this paper the cycling of c and p is examined in sediments from the anoxic saanich inlet cored by ocean drilling program odp leg 169s in 1996 at two sites although c org p org ratios are high and increase with depth in the saanich inlet this effect is due largely to a remobilization of p from an organic matter sink to an authigenic sink reducible sedimentary components act as temporary shuttles in this process even in this anoxic setting with the ultimate burial sink for the remobilized p being carbonate fluorapatite the effective c org p reactive molar ratio appears to be about 150 200 indicating some preferential loss of p compared to c during organic matter degradation but not approaching previously reported values of over 3000 in black shales reactive p accumulation rates in this basin range from 10 000 60 000 mol cm 2 kyr greatly exceeding the range of 500 8000 mol cm 2 kyr found in most continental margin settings including regions of modern phosphogenesis the initiation of marine sedimentation in the saanich inlet occurred after deglaciation and the high rates of p burial seen here may provide an end member example of the effects of sea level and margin sedimentation on the distribution of p within the marine p cycle

formation of mesosiderites by low velocity impacts as a natural consequence of planet formation mesosiderites are an enigmatic class of stony iron meteorites composed of roughly equal amounts of pyroxenitic and basaltic silicates and metallic iron nickel olivine is rare we suggest here that during the period of planet formation mesosiderites originated by the low velocity collisions of large metallic core fragments with the surface of a differentiated asteroid size body relative velocities of the asteroids native to this region were low 1 km s 1 because it was distant from massive protoplanets however a few differentiated asteroids were destroyed by high velocity collisions with interlopers perturbed by protoplanets into highly eccentric orbits these collisions reduced mantles and crusts to small silicate fragments but left cores in the form of large durable metal fragments mesosiderite like pyroxenite basalt metal mixtures were formed when large core fragments accreted at low velocities to the regolith of an intact asteroid the metal contents of other regolithic regions remained low most of the olivine in mesosiderite and howardite breccias we attribute to the mantles of the disrupted parent bodies the low 12 20 mg g 1 olivine contents indicate that the amount of debris accreted from disrupted asteroids was small relative to the volumes of the regoliths

the assessment of ree patterns and 143nd 144nd ratios in fish remains abstract the ree content and isotopic composition of sr and nd have been determined in fish teeth ranging in age from the trias to the present and from various localities mostly around the atlantic these measurements have been carried out on selachian and teleost remains from the same locality in togo and show no appreciable difference which suggests with the help of a mass balance calculation of the ce anomaly that diagenetic effects are not responsible for the ree enrichment of biogenic phosphates one group of fossil teeth has about 3 times the ree abundances of shale and a shale normalized pattern with a minimum at sm it is thought to reflect deposition in the open sea environment a second group has ree concentration about 10 times higher than the first group with either a regular light ree enrichment or more frequently a maximum in the middle ree both being probably indicative of deposition in estuarine or near shore conditions the shape of the ree spectra and the size of the ce anomaly can be used semi quantitatively to determine the depth of deposition the results presented here on late cretaceous eocene fish teeth samples from morocco reflect an increasing influx of deep waters with a lowla yb ratio and strong negative ce anomaly which agrees well with the evolution of sediment chemistry and microfauna associations in contrast nd is typical of the water mass in which the fish debris decayed examples of nearly isolated basins identified with nd isotopes include the south atlantic prior to the lutetian nd 13 5 the miocene persian gulf nd 3 1 and bolivia during the late cretaceous nd 12 8 togo and guinea bissau results suggest that in the south atlantic the meridional oceanic circulation had not started before 45 ma ago combination of ree and nd data suggests that the assignment of jurassic cretaceous samples measured so far to open sea water masses is still ambiguous

biostratigraphy and paleoceanography of the cretaceous seaway between norway and greenland abstract the narrow seaway between greenland and norway in cretaceous time was over 1500 km long and 300 km wide and partly of bathyal water depth during aptian through campanian it received a large volume of fine grained siliciclastic sediments with intercalated gravity flow sandstone wedges as a conduit for heat transport between the low latitudes and polar region atlantic watermasses particularly affected the eastern norwegian margin of this seaway despite its high latitude setting calcareous and few siliceous planktonic microfossils thus play an important role in regional stratigraphy and facies analysis and a majority of fossil events correlate to nw european basins the eastern margin sedimentary succession may be subdivided in several broad lithologic units 1 thin multicolored marly sediments of hauterivian barremian age with a shallow marine falsogaudryina nodosariid ostracod assemblage 2 dark mudstones and minor sands aptian early cenomanian in age with an upper bathyal agglutinated assemblage and monotypic hedbergella floods 3 thick mudstone facies with thin slope apron turbidite sands and an impoverished benthic planktonic assemblage of late cenomanian coniacian age deposited in an upper bathyal oxic dysaerobic environment where turonian sedimentation rates are low a planktonic foraminiferal assemblage with whiteinella hedbergella dicarinella and marginotruncana occurs 4 grayish laminated mudstones santonian campanian in age with local sands in the north a low diversity middle to upper bathyal benthic planktonic foraminiferal assemblage and an inoceramus prisms and radiolarian diatom flood a campanian agglutinated foraminiferal bloom also is known from the atlantic oceanic realm 5 more marly sediments of maastrichtian age with a low diversity planktonic benthic foraminiferal assemblage using the distribution of 1755 foraminiferal and dinoflagellate microfossil events in over 30 exploration wells a rasc ranking and scaling probabilistic zonation served as a template to build a cretaceous zonal model with 19 assemblage and interval zones including over 100 events variance analysis ranks 72 events according to reliability in correlation three new index taxa include uvigerinammina una and ammoanita globorotaliaeformis albian and fenestrella bellii campanian widespread planktonic flood events occur in late albian through early cenomanian early mid turonian late santonian earliest campanian and mid maastrichtian the result of northwards shifts of warmer water masses and disruptions in water stratification in the dysaerobic basins an earliest cretaceous hiatus separates jurassic from cretaceous strata ongoing block faulting coupled to thermal subsidence and global sealevel rise increased water depth in aptian albian time from neritic to bathyal and created sand accommodation space in dysaerobic restricted settings in cenomanian coniacian time sedimentation rates in the central basin increased 10 fold whereas paleo waterdepth did not deepen this relatively brief less than 10 m y tectonic episode resulting in deposition of deep water sands is tentatively linked to stress re orientation in the rockall area a widespread upper maastrichtian danian hiatus the result of shoulder uplift reflects break up prior to the onset of paleogene seafloor spreading in the norwegian sea

oxygen isotopic composition and chemical correlations in meteorites and the terrestrial planets recent models attempting to explain non mass dependent oxygen isotopic anomalies in meteorites and planets posit that they may have originated within the gas phase of the solar nebula which suggests the potential for correlations of non mass dependent oxygen isotopic anomalies with other chemical fractionations generated during cooling and condensation of the nebula we have examined three specific issues possible correlations of 17o with i oxidation state ii bulk chondrite chemistry and iii bulk planetary properties isolated grains and chondrules from several carbonaceous chondrite groups exhibit good to weak positive correlations between 17o and olivine fayalite content and whole rock ureilite samples show a positive correlation of 17o with olivine fayalite content these are consistent with oxidation of fe metal by 17o 18o enriched oxygen in the precursor materials that formed these objects in contrast oxygen isotopic and major element compositions of ferromagnesian phases in ordinary chondrite chondrules and in bulk chondrites do not show a correlation thus there is no compelling evidence that oxidation of nebular materials was tightly linked to gas species carrying anomalous o using average chondrite group compositions we demonstrate that significant negative correlations of refractory lithophile element mg and refractory siderophile element ni with 17o exist refractory inclusions cais and aoas are modally rare in many chondrite types that exhibit substantial range in 17o thus the refractory component in these chondrites must occur in a crypto component e g material dissolved in chondrule melts during chondrule formation significant positive correlations of moderately volatile elements mg with 17o are not simply explained by incomplete mixing of 16o enriched refractory grains but are broadly consistent with nebula based mechanisms of non mass dependent oxygen isotope fractionation the estimated compositions of the primitive mantles of the earth mars and 4 vesta have some compositional redox and isotopic properties that vary with heliocentric distance however 17o does not vary monotonically in this sequence indicating a decoupling of planetary o isotopic composition from other compositional characteristics

an apparent contradiction in the role of phosphorus in cenozoic chemical mass balances for the world ocean little is known about the fluxes to and from the ocean during the cenozoic of phosphorus p a limiting nutrient for oceanic primary productivity and organic carbon burial on geologic timescales previous studies have concluded that dissolved river fluxes increased worldwide during the cenozoic and that organic carbon burial decreased relative to calcium carbonate burial and perhaps in absolute terms as well to examine the apparent contradiction between increased river fluxes of p assuming p fluxes behave like the others expected to drive increased organic carbon burial and observations indicating decreased organic carbon burial we determined p accumulation rates for equatorial pacific sediments from ocean drilling program leg 138 sites in the eastern equatorial pacific and leg 130 sites on the ontong java plateau in the western equatorial pacific although there are site specific and depth dependent effects on p accumulation rates there are important features common to the records at all sites p accumulation rates declined from 50 to 20 ma showed some variability from 20 to 10 ma and had a substantial peak from 9 to 3 ma centered at 5 6 ma these changes in p accumulation rates for the equatorial pacific are equivalent to substantial changes in the p mass balance however the pattern resembles neither that of weathering flux indicators 87sr 86sr and ge si ratios nor that of the carbon isotope record reflecting changes in organic carbon burial rates although these p accumulation rate patterns need confirmation from other regions with sediment burial significant in global mass balances e g the north pacific and southern ocean it appears that p weathering inputs to the ocean are decoupled from those of other elements and that further exploration is needed of the relationship between p burial and net organic carbon burial

a new approach to the nd residence time in the ocean the role of atmospheric inputs concentrations of rare earth elements ree and nd isotopic ratios were analyzed for seawater filtered suspension and sediment trap samples collected in the tropical atlantic ocean eumeli program eutrophic mesotrophic and oligotrophic sites 20 n 18 21 w this is the first ree nd dataset on solution and different sized particles collected at the same site we present direct evidence of the nd isotopic exchange between particulate lithogenic fraction and seawater without significant mass transfer this exchange is probably one of the main factors that simultaneously constrains the nd concentration and isotopic ratio budget we propose a new approach to estimate the residence time of nd in the ocean nd based on isotopic exchange 200 yr nd 1000 yr the exchange requires a partial dissolution of lithogenic nd we estimate that the fraction of soluble nd proportion in atmospheric dust is of the order of 20 based on the isotopic ratios we suggest that the partial dissolution of atmospheric fallout is probably one of the main ree sources of the ocean

expected characteristics of cometary meteorites recent developments in our understanding of comets provide insights into the topic of cometary meteorites these developments include the identification of comet asteroid transition objects such as 4015 wilson harrington and 3200 phaethon information on the composition of cometary solids and new ideas on the collisional history of jupiter family comets in this work we revisit this question and we conclude that comets do indeed yield macroscopic meteorites which either have not been found or have not been recognized we also consider the expected characteristics of cometary meteorites with an emphasis on those that may help identify and differentiate them from other types of meteorites if cometary meteorites have preserved the main characteristics of cometary dust the mineralogy would be dominated by highly unequilibrated anhydrous silicates and the chemistry would be nearly chondritic but with a high abundance of c and n on the other hand if an unknown process produced extensive aqueous alteration in the material that formed cometary meteorites they would resemble or could even be ci carbonaceous chondrites we do not expect cometary meteorites to have chondrules so far no single meteorite looks unequivocally cometary however we have identified xenoliths in ordinary chondrite regolith breccias that meet most of our criteria for a cometary origin and deserve further study

late cretaceous upwelling system along the southern tethys margin israel interrelationship between productivity bottom water environments and organic matter preservation organic rich upper cretaceous sequences in israel were deposited in an extensive highly productive upwelling linked system which prevailed along the southern tethys margin and lasted for 19 m y santonian to late maastrichtian an understanding of the spatial and temporal characteristics of this system was gained through detailed paleontological and geochemical analyses of subsurface sequences in two basins in israel representing an outer shefela and an inner zin facies belt the nature of the upwelling system and its effect on the sedimentary record is related to two basic environmental parameters namely paleoproductivity intensity and oxygen levels at the bottom the assessment of these parameters and their interrelationship has been performed through the development of paleontological foraminiferal criteria which are independent of the organic matter content following the establishment of these criteria it is concluded that the productivity reached its maximum intensity during the late campanian which was also the time of most notable differentiation between the center of the upwelling system in the inner belt and the less intense conditions in the outer basin this distribution is expressed in varied lithology organic rich carbonates phosphorites and siliceous rocks at the core of upwelling and a uniform lithology organic rich carbonates at the margin of this system the uniform lithology of the maastrichtian in both basins composed of organic rich carbonates is ascribed to a gradual weakening of productivity the bottom conditions in the inner belt during the late campanian the time of maximum surface productivity were near anoxic changing to more aerated dysaerobic conditions during the early maastrichtian in the outer belt a more aerated bottom dysaerobic prevailed throughout the late campanian to late maastrichtian the elevated organic matter content in both basins reflects the overall environment of high productivity its actual variations however seem to be unrelated to changes in surface productivity and bottom oxygen levels

sedimentology and palaeogeography of the regressive transgressive kurnub group early cretaceous of jordan abstract the early cretaceous kurnub group of jordan consists of three regressive transgressive fluvial marine depositional sequences in northern jordan recorded here for the first time whereas continental clastics dominated central and southern jordan deposition of the kurnub group started in the late neocomian above a regional angular unconformity by basal conglomerate and sandstone facies association of an alluvial braidplain origin during this time the tethys seaway was located to the north and northwest of jordan which afterwards during the barremian advanced in a south and southeastward direction flooding north jordan and giving rise to a tidal flat coastal swamp sequence following a subsequent regression of the sea unconfined braidplain deposits covered the area the most extensive transgression of the tethys inundated the region during the late aptian and early albian where a mixed siliciclastic carbonate sequence with interbedded inner shelf carbonates and tidal marsh coastal swamp black shales and lignites was deposited the next and last regression took place in the middle albian where a thin meandering river clastic sequence was deposited finally shallow marine sedimentation resumed over the region during the remaining time of the kurnub group which at the same time prepared for the subsequent regional cenomanian transgression upon comparison with global eustatic curves these three incursions of the tethys sea in jordan are to a great extent in accordance with the global sea level fluctuations the various formations of the kurnub group and their informal units that are established here for the first time can readily be correlated with equivalent deposits in adjacent countries the distribution of the shorelines of the barremian aptian and albian on both sides of the dead sea transform offers new evidence for 100 km northward displacement of the arabian plate against the sinai palestine plate

past co2 changes and tropical sea surface temperatures the relationship between past co2 variations and tropical climate change on time scales of millions of years is reviewed explanations for cretaceous and early cenozoic climate change often involve higher atmospheric co2 levels climate models predict that such increases should have been associated with warmer tropical sea surface temperatures ssts however sparse mid cretaceous 18o based sst estimates from low latitude calcareous plankton are 1 0 1 5 heavier than predicted initial evaluations indicate that changes in salinity may not alleviate model data discrepancies for calcareous 18o and that interpretation of altered latitudinal 18o gradients in terms of increased poleward heat transport due to warm saline bottom water wsbw formation would require very large levels of wsbw production at least 60 sv calcareous 18o records may not always record true sst patterns as 18o analyses from phosphatic groups which are less sensitive to diagenesis indicate ssts 5 c higher this latter conclusion is supported by a number of other fossil groups which indicate temperatures warmer than those estimated from calcareous 18o in order to more rigorously test the paleo co2 hypothesis and indeed the models used to forecast future climates it is desirable to intensify investigations of past climate change in low latitudes in order to determine whether these preliminary conclusions stand the test of further scrutiny

isotopic composition of neodymium in waters from the drake passage the isotopic composition of neodymium has been determined in seawaters from the drake passage the antarctic circumpolar current which controls interocean mixing flows through this passage the parameter e nd 0 which is a function of the ratio of neodymium 143 to neodymium 144 is found to be uniform with depth at two stations with a value which is intermediate between the values for the atlantic and the pacific and indicates that the antarctic circumpolar current consists of about 70 percent atlantic water cold bottom water from a site in the south central pacific has the neodymium isotopic signature of the waters in the drake passage by using a box model to describe the exchange of water between the southern ocean and the ocean basins to the north together with the isotopic results an upper limit of approximately 33 million cubic meters per second is calculated for the rate of exchange between the pacific and the southern ocean concentrations of samarium and neodymium were also determined and found to increase approximately linearly with depth these results suggest that neodymium may be a valuable tracer in oceanography and may be useful in paleo oceanographic studies

glacial and interglacial wind regimes over the eastern subtropical atlantic and north west africa analysis of aeolo marine dust deposits in the subtropical eastern atlantic enables the strength of the major wind patterns during the late quaternary to be evaluated and gives an insight into the climate of north africa

the compositional classification of chondrites ii the enstatite chondrite groups we present new data from a neutron activation analysis of four enstatite chondrites including the taxonomically important st sauveur and discuss the classification of enstatite chondrites the enstatite chondrites can be divided into two compositionally distinct sets in one set abundances of nonrefractory siderophiles and moderately volatile chalcophiles and alkalis are 1 5 2 0 higher than in the other a well resolved compositional hiatus separates these two sets the differences in composition are as great as those between the groups of ordinary chondrites and therefore it appears best to treat these sets as separate groups by analogy with the symbols used for ordinary chondrites we propose to designate the high fe high siderophile group eh and the low fe low siderophile group el known members of the eh group belong to petrologic types 4 and 5 whereas all el members are petrologic type 6 within the eh group no correlation is observed between petrologic type and abundance of nonrefractory siderophiles or moderately volatiles or alkalis two physical properties show only modest overlap between the eh and el groups cosmic ray ages for eh chondrites are 0 5 7 ma while those for el chondrites are 4 18 ma relative to bjurbole i xe formation intervals are 1 3 0 6 ma for eh chondrites and 2 9 0 5 ma for el chondrites the weight of the chemical and physical evidence indicates that the eh and el groups formed separate bodies at similar distances from the sun the available evidence for shallowater and happy canyon two strongly recrystallized silicate rich meteorites containing 40 mg g fe ni indicates that the former is an enstatite clan chondrite altered by loss of sulfide and plagioclase rich melts whereas the latter is intermediate in composition between el chondrites and the chondritic silicates in the pine river iab anomalous meteorite

the calcium riverine and hydrothermal isotopic fluxes and the oceanic calcium mass balance calcium isotope ratios relative to seawater were studied in natural waters in order to constrain the ca isotopic flux to the oceans and to discuss the oceanic ca budget this study includes the analysis of 1 ca isotopes in continental waters at the regional scale of the upper rhine valley and 2 the determination of the 44ca values of some major rivers and hydrothermal vents the data indicate that the global 44ca variability of the studied waters with a maximal range of 1 is limited and must be linked to mass fractionation processes at the scale of a small watershed aubure vosges france the 44ca river flux changes due to the variation of the proportion of waters resulting from chemical alteration of rocks and biologically fractionated soil solutions ca isotopes could therefore be an important tool to quantify the impact of the plants and the biosphere on the river water chemistry at the regional scale of the rhine valley as well as at the global scale of world rivers the 44ca variability of river samples ranges from 0 5 to 1 without any relationship with the lithology of the watershed or the climate similarly the 44ca value of hydrothermal vents is also uniform and close to the mean value of river waters consequently the 44ca flux to the ocean should remain rather constant through time with a mean of 1 1 0 2 this value confirms that the ca budget of the present day seawater is in steady state this was not necessarily the case in the past non steady state periods should have been due to intensity variations of incoming and outcoming ca fluxes rather than to the variations in their isotopic signatures

phosphogenesis carbon isotope stratigraphy and carbonate platform evolution along the lower cretaceous northern tethyan margin we distinguish three different stages in the evolution of the tithonian late jurassic to aptian early cretaceous northern tethyan carbonate platform 1 carbonate production in the coral oolite mode late tithonian to early valanginian early barremian to early aptian 2 carbonate production in the crinoid bryozoan mode early valanginian haute rivian late aptian and 3 platform retrogradation and destruction condensation and phosphogenesis that is platform drowning early valanginian to early hauterivian middle hauterivian late hauterivian to early barremian early to early late aptian and latest aptian to earliest albian transitions from the coral oolite mode to the crinoid bryozoan mode and consequently to platform drowning may have been driven by increases in nutrient levels on the shelf phases of relative sea level rise in times of carbonate production in the coral oolite mode are named constructive because of the observed platform regeneration following phases of widespread emersion during late sea level highstands in contrast phases of relative sea level rise in times of platform drowning are termed destructive the 13 c stratigraphies obtained from valanginian hauterivian and aptian albian hemipelagic successions beyond the platform correlate well with the early cretaceous pelagic 13 c record positive excursions in the pelagic 13 c record correspond in time to episodes of platform drowning this suggests the existence of a coupling mechanism between changes in the global carbon cycle and platform drowning in our view the early cretaceous crises in carbonate platform growth were the consequence of reinforced greenhouse conditions which may have been triggered by episodes of extensive flood basalt volcanism strong greenhouse conditions may have induced the following chain of feedback mechanisms enabling the biosphere to return to normal conditions climate warming sea level rise accelerated water cycle intensified weathering nutrient mobilization platform destruction increased productivity increased phosphogenesis and carbon burial weakened greenhouse conditions

a petrologic study of the iab iron meteorites constraints on the formation of the iab winonaite parent body abstract we have studied iab iron meteorites and their silicate bearing inclusions to elucidate the origin of their parent body we have divided iab irons into five categories which best describe the inclusions and other properties of the irons these are 1 sulfide rich irons such as mundrabilla that contain a significant volume fraction of troilite with or without associated silicates 2 irons with non chondritic silicate inclusions such as basaltic inclusions in caddo county 3 irons with rounded troilite and or graphite inclusions sometimes containing embedded angular silicate inclusions 4 irons with angular silicate inclusions similar to those of the winonaites where silicates may comprise up to 40 vol of the rock and 5 irons with phosphate bearing inclusions such as the brianite bearing iab san cristobal similarities in mineralogy mineral and oxygen isotopic compositions suggest that iab irons and winonaites are almost certainly from a common parent body iiicd irons may also have originated on this parent body although evidence supporting this suggestion is less convincing previous models for the origin of iab irons propose that they are either products of selective impact melting in the megaregoliths of a chondritic asteroid or products of partial melting and fractional crystallization during formation of a sulfur rich core the former model suffers from the fact that impact is incapable of causing preferential melting of metal and sulfide on a large scale and pooling of these selective melts into sizable bodies the latter model does not readily explain the occurrence of often fragmentary angular silicate clasts in a metallic fe ni host we propose a new model for the origin of iab irons that incorporates aspects of both previous models we suggest that a chondritic possibly heterogeneous parent body was heated by a non collisional heat source which caused partial but not complete melting of the body after peak temperatures were reached and cooling and crystallization had begun a major impact catastrophically fragmented this body and the debris gravitationally reassembled scrambling the parent body lithologies we suggest that the impact caused extensive mixing of molten metallic fe ni and solid silicate material resulting in the formation of iab irons with silicate inclusions whereas winonaites represent metamorphosed rocks and partial melt residues of the precursor silicate lithologies high temperatures of some of the reassembled debris and deep burial resulted in continued fractionation and formation of the 2

stratigraphic evidence for an early collision between northwest india and asia the collision of india with asia1 had a profound influence on late cretaceous and cenozoic oceanography2 climate3 fauna extinctions4 and the motion of at least some of the earth s litho spheric plates5 as the collision ended a period of rapid indo asian convergence6 a precise knowledge of its timing when the crust of the neo tethys ocean was completely subducted7 at some point along the plate boundary is important for understanding its wider consequences but current estimates of the collision age range from 65 to 38 myr before present6 8 11 here we report the results of extensive biostratigraphic analyses from waziristan and kurram in northwest pakistan which show that accretionary prism and trench strata were first thrust onto the northwest indian passive margin after 66 myr but before 55 5 myr after this time volcanic arc fragments the accretionary prism trench material and imbricates of the north indian slope were raised to shallow water depths and overlapped by upper palaeocene shallow water carbonates and shales12 14 indicative of post collision thrusting in this region finally both the suture and the indian craton were overlapped by continuous unconformable upper lower eocene shallow marine strata demonstrating that suturing was complete by 49 myr

formation of mesosiderites by fragmentation and reaccretion of a large differentiated asteroid we propose that mesosiderites formed when a 200 400 km diameter asteroid with a molten core was disrupted by a 50 150 km diameter projectile to test whether impacts can excavate core iron and mix it with crustal material we used a low resolution smoothed particle hydrodynamics computer simulation for 50 300 km diameter differentiated targets we found that significant proportions of scrambled core material and hence potential mesosiderite metal material could be generated for near catastrophic impacts that reduce the target to 80 of its original diameter and about half of its original mass the proportion of scrambled core material would be about 5 vol equivalent to 10 vol of mesosiderite like material the paucity of olivine in mesosiderites and the lack of metal poor or troilite rich meteorites from the mesosiderite body probably reflect biased sampling mesosiderites may be olivine poor because mantle material was preferentially excluded from the metal rich regions of the reaccreted body molten metal globules probably crystallized around small cool fragments of crust hindering migration of metal to the core if mantle fragments were much hotter and larger than crustal fragments little metal would have crystallized around the mantle fragments allowing olivine and molten metal to separate gravitationally the rapid cooling rates of mesosiderites above 850 c can be attributed to local thermal equilibration between hot and cold ejecta very slow cooling below 400 c probably reflects the large size of the body and the excellent thermal insulation provided by the reaccreted debris we infer that our model is more plausible than an earlier model that invoked an impact at 1 km s to mix projectile metal with target silicates if large impacts cannot effectively strip mantles from asteroidal cores as we infer we should expect few large eroded asteroids to have surfaces composed purely of mantle or core material this may help to explain why relatively few olivine rich a type and metal rich asteroids m type are known some s type asteroids may be scrambled differentiated bodies

oxygen isotope studies of ordinary chondrites several stages in the evolution of ordinary chondritic meteorites are recorded in the oxygen isotopic composition of the meteorites and their separable components chondrules fragments clasts and matrix the whole rock isotopic compositions reflect the iron group of the meteorite h l or ll isotopic uniformity of h3 to h6 and l3 to l6 are consistent with closed system metamorphism within each parent body ll3 chondrites differ slightly from ll4 to ll6 implying a small degree of opensystem aqueous alteration and carbon reduction on the scale of individual chondrules the meteorites are isotopically heterogeneous allowing recognition of the solar nebular processes of chondrule formation chondrules for all classes of ordinary chondrites are derived from a common population which was separate from the population of chondrules in carbonaceous or enstatite chondrites chondrules define an isotopic mixing line dominated by exchange between 16o rich and 16o poor reservoirs the oxygen isotopic compositions of chondrites serve as fingerprints for identification of genetic association with other meteorite types achondrites and iron and for recognition of source materials in meteoritic breccias

a petrologic and isotopic study of lodranites evidence for early formation as partial melt residues from heterogeneous precursors abstract we have conducted petrologic chemical and isotopic studies of lodranites in an attempt to constrain their genesis lodran gibson y 791491 y 791493 y 74357 y 8002 y 75274 mac 88177 lew 88280 eet 84302 fro 90011 and que 93148 are classified as lodranites lodranites and acapulcoites are indistinguishable on the basis of oxygen isotopic compositions but are distinct in average grain sizes of their mafic silicates with lodranites being significantly coarser grained lodranites exhibit a diverse range of petrologic and mineralogic features they range widely in mafic silicate compositions fa3 13 plagioclase 0 11 4 vol fe ni metal 0 5 20 vol and troilite 0 2 5 3 vol contents and shock levels s1 s4 they appear to have experienced high peak temperatures and rapid cooling in the temperature range recorded by metallographic cooling rates i e 700 350 c the only dated lodranite gibson cooled to ar closure temperatures at 4 49 0 01 ga lodranites formed from chemically and isotopically heterogeneous precursors in which the mineral and oxygen isotopic compositions were correlated heating of their parent body to temperatures between 1050 1200 c resulted in formation of fe ni fes and basaltic partial melts depletions of troilite and or plagioclase in most lodranites testify to the removal of some of these partial melts although melt migration was complex lodranites appear to have experienced a complex cooling history of slow cooling at high temperatures followed by rapid cooling at intermediate temperatures possibly related to breakup of the parent body lodranites were liberated from their parent body during 1 3 impact events with most having cosmic ray exposure ages of 5 5 7 ma the acapulcoites are samples from the same parent body but were heated to lower temperatures and thus experienced lower degrees of partial melting

impact versus internal origins for mesosiderites mesosiderites are very intimately mixed stony iron breccias including little recrystallized and highly recrystallized varieties i iii and a subgroup iv with melted matrix all mesosiderite breccias contained some material that was hot as indicated by pigeonite that inverted at 1150 c subgroup iv contained silicate and metal liquids at temperatures of at least 1300 c and 1350 c respectively cooling rates are not rigorously defined but are approximately 1 year in the high temperature range and 1 m y below 500 c the latter cooling requires a depth of 40 km in an asteroid with a radius of 400 km or less if porous low conductivity surface material is present cratering with metal projectiles appears incapable of generating mesosiderites a normal impact produces rapidly cooled metal poor breccias impacts on a crust in which metal silicate segregation had taken place could generate stony iron breccias but burial under an insulating blanket would be necessary to obtain slow cooling disruption and reassembly of two colliding bodies and accretion of differentiated planetesimals could form stony iron breccias at depth but as with the previous two models the easiest way to explain the low olivine of mesosiderites is to postulate derivation from olivine poor chondritic material two internal processes turbulent metal crust mixing during core formation and crustal blocks sinking into the core provide a deep location and withhold olivine from the breccia however these mechanisms do not explain how the silicate and metal liquids in subgroup iv otherwise interpreted as impact melt rocks could have failed to segregate in a deep slowly cooled environment no single model for mesosiderite origins is wholly satisfactory

mid cretaceous ocean circulation results from model sensitivity studies a series of ocean general circulation model gcm experiments for mid cretaceous continental paleogeography with atmospheric forcing prescribed from atmospheric gcm experiments are utilized to investigate the nature of the mid cretaceous ocean circulation the experiments illustrate a tethys system of clockwise currents and predominant eastward flow in marked contrast with earlier reconstructions this result is apparently robust for changes in bathymetry and in the degree of planetary warmth changes in sea level have the largest potential to produce alternative circulation characteristics two major current systems outside of tethys dominate the model simulation the site of bottom water formation is the north pacific however in a sensitivity experiment for a warmer climate the eastern tethys became a site of deep water formation

a petrologic chemical and isotopic study of monument draw and comparison with other acapulcoites evidence for formation by incipient partial melting abstract we have conducted petrologic chemical and isotopic studies of acapulcoites acapulco monument draw yamato 74063 alh a77081 alh a81261 alh a81315 alh 78230 alh a81187 and alh 84190 in an attempt to constrain their genesis acapulcoites have distinctly different oxygen isotopic compositions than silicate inclusions in iab and iiicd irons winonaites and ureilites and thus formed on a different parent body oxygen isotopic compositions which are slightly heterogeneous within the group overlap with lodranites indicating a likely origin on a common parent body these groups can be distinguished on the basis of mafic silicate grain size all acapulcoites have mafic silicate compositions intermediate between e and h chondrites roughly chondritic mineralogies achondritic equigranular textures micrometer to centimeter sized veins of fe ni fes which cross cut silicate phases rapid metallographic cooling rates at 600 400 c 103 105 c myr and trapped noble gas abundances comparable to type 3 4 ordinary chondrites they exhibit variable mafic silicate zoning abundance of fe ni fes veins ree abundances and patterns and possibly cosmic ray exposure ages 5 7 ma momument draw and yamato 74063 retain rare relict chondrules phosphates are associated with fe ni fes veins or form separate veins in monument draw and acapulco heating and cooling of acapulcoites occurred very early in the history of the solar system as evidenced by the 39ar 40ar ages of 4 51 ga these ages appear distinctly younger than the likely formation time for acapulco of 4 557 ga but are older than analogous 39ar 40ar ages for most chondrites acapulcoites formed from a precursor chondrite which differs from known chondrites in mineral and oxygen isotopic compositions heating to 950 1000 c resulted in melting at the fe ni fes cotectic but silicates did not melt silicate textures resulted from extensive solid state recrystallization heating was by noncollisional sources e g 26al electromagnetic induction despite uncertainties owing to a lack of data acapulcoites may have experienced a three stage thermal history of slow cooling at high temperature rapid cooling at intermediate temperatures and slow cooling at low temperatures possibly resulting from breakup and gravitational reassembly of the parent body the complex thermal history is also reflected in disequilibrium ree abundances one or at most two impact events 7 ma and possibly 5 ma ago are consistent with the cosmic ray exposure ages of all four acapulcoites for which cosmogenic noble gas data exist

crystal chemical controls on rare earth element concentrations in fossil biogenic apatites and implications for paleoenvironmental reconstructions abstract fossil biogenic apatites display rare earth element ree patterns which have been proposed to reflect environmental and biological controls on past seawater composition these patterns can be separated in two groups 1 patterns that are similar to those of open ocean and epicontinental waters and 2 patterns that exhibit a strong enrichment in intermediate ree bell shaped patterns because ree trapping in biogenic apatites occurs mostly post mortem it is essential to understand the crystal chemical inorganic factors that can influence the fractionation of ree between apatite and water a model is proposed by which partition coefficients of ree between apatite and water for a substitution mechanism can be extrapolated from mineral melt partition data to seawater or sedimentary basin conditions these are compared with available experimental partition coefficients for ree adsorption mechanism and used to discuss ree patterns in fossil biogenic apatites calculations of ree patterns for apatites at equilibrium with water show that the bell shaped patterns in fossil apatites can be explained by fractionation with seawater or continental fluids at low temperature under crystal chemical control involving a substitution mechanism and in the context of extensive or late diagenesis in that case the equilibrium composition of the fluid cannot be unequivocally determined from observed ree concentrations in fossil apatites this type of sample is inappropriate to discuss the past environmental or biological controls on ree concentrations in the ocean other sample compositions suggest little to moderate alteration of the original oceanic to freshwater pattern through the adsorption mechanism in the context of weak or early diagenesis and may be used with caution for that purpose

deep water in the late maastrichtian ocean 1 stable isotopic data from benthic foraminifera indicate the occurrence of at least three deepwater masses in the late maastrichtian ocean given mean oceanic 18ow of 1 0 the temperature of the coolest intermediate depth waters was 5 7 c that of the deepest waters was 10 c and that of the warmest intermediate waters was 13 15 c the cool intermediate depth water mass probably originated in the high latitude southern ocean the deepest waters originated at least partly in the northern atlantic the source region for the warmest intermediate depth water mass is unknown although much of the late maastrichtian deep water was probably preconditioned for winter sinking by low or middle latitude evaporation no more than 11 of late maastrichtian deep water could have been directly actuated by low latitude sea surface evaporation at least in the southern atlantic and indian oceans heat transport by upwelling of deep water was not the primary cause of mild sea surface and coastal temperatures

oxygen isotopic compositions of enstatite chondrites and aubrites oxygen isotopic compositions have been measured for ten eh chondrites eight el chondrites and nine aubrites the mean 18o and 17o values are 5 31 and 2 74 5 57 and 2 96 5 24 and 2 70 respectively within the eh group more equilibrated meteorites are fractionated toward higher heavy isotope abundances than the less equilibrated meteorites small departures of individual meteorites from a common mass fractionation occur for some of the eh samples the aubrites may be genetically related to either the eh or el group or to both almost all of the measured isotopic compositions are indistinguishable from the terrestrial oxygen isotope fractionation line suggesting a genetic relationship among the earth the moon and the enstatite the meteorites

a new metal rich chondrite grouplet abstract a new grouplet of primitive metal rich chondrites here called the cb c carbonaceous b bencubbinite chondrites has been recognized it includes bencubbin weatherford hammadah a1 hamra hh 237 and queen alexandra range que 94411 paired with que 94627 their mineral compositions as well as their oxygen and nitrogen isotopic compositions indicate that they are closely related to the cr and ch chondrites all of which are members of the more inclusive cr clan cb chondrites have much greater metal silicate ratios than any other chondrite group widely increasing the range of metal silicate fractionation recorded in solar nebular processes they also have the greatest moderately volatile lithophile element depletions of any chondritic materials metal has compositional trends and zoning patterns that suggest a primitive condensation origin in contrast with metal from other chondrite groups cb chondrites as well as other cr clan chondrites have much heavier nitrogen higher 15n 14n than that in other chondrite groups the primitive characteristics of the cb chondrites suggest that they contain one of the best records of early nebular processes another chondrite grosvenor mountains 9555 1 is petrographically similar to the cb chondrites but its mineral and oxygen and nitrogen isotope compositions indicate that it formed from a different nebular reservoir

partial melting and melt migration in the acapulcoite lodranite parent body we review petrologic evidence that the acapulcoites and lodranites formed by 1 vol to probably 20 vol whole rock partial melting of a chondritic precursor material at low degrees of partial melting only fe ni fes cotectic melting occurred migration distances for partial melts were short resulting in the formation of acapulcoites with essentially chondritic troilite and plagioclase contents but achondritic textures at high degrees of partial melting both fe ni fes and basaltic plagioclase pyroxene partial melts formed and the melts may have migrated out of the source rock the partial melt residues which are more or less depleted in fe ni fes and plagioclase are the lodranites melt migration was complex most acapulcoites which experienced relatively low degrees of partial melting lost little if any of the partial melt one acapulcoite lew 86220 represents a unique case in which fe ni fes and basaltic partial melts appear to have migrated from a lodranite source region into a cooler acapulcoite region where they were trapped in cases of the relatively high degrees of partial melting experienced by lodranites melts may have been partly selectively or totally removed from the rocks and fe ni fes and or basaltic partial melts may have been removed to different degrees and may in fact have been trapped on occasion in greater than chondritic proportions we model vein and dike formation and melt migration by calculating the excess pressures and vein and dike sizes for varying degrees of partial melting our calculations are broadly consistent with observations indicating that melt migration is inefficient at low degrees of partial melting and extremely efficient at high degrees of partial melting although the size of the acapulcoite lodranite parent body and the volatile contents of the chondritic precursor rocks are poorly constrained the lack of basaltic rocks in the world s meteorite collections complementary to the lodranites suggests that basaltic partial melts may have been accelerated off the body by explosive volcanism of the type envisioned by wilson and keil 1991 and ejected into space the diversity of rocks from the acapulcoite lodranite parent body may provide a basis for better understanding the diverse range of spectral subtypes recognized among the s type asteroids

the phosphorus cycle phosphogenesis and marine phosphate rich deposits abstract phosphorus in the form of phosphate is an essential nutrient and energy carrier on many different levels of life and a key element in mediating between living and lifeless parts of the biosphere one of the most important aspects of the phosphorus cycle is its vital role in governing productivity thereby interacting with the exogenic part of the carbon cycle which in turn is important in regulating earth s climate phosphorus is a prime element to be traced in earth s history because it allows for the reconstruction of long term feedback mechanisms between climate environment and ecology and of global change as such marine sedimentary phosphate deposits are particularly suited to study aspects of the phosphorus cycle because in the case of ubiquity their origin may result from a general acceleration of the global phosphorus cycle sources of sedimentary phosphate are microbial breakdown of buried organic matter and redox driven phosphate desorption from iron and manganese oxyhydroxides dissolved sea water phosphate represents an additional source which may become important in the formation of phosphatic hardgrounds the main locus of phosphogenesis is near the sediment water interface but phosphogenesis also occurs at greater sediment depths current induced winnowing and transport processes along the sea floor concentrate phosphate precipitates into deposits which exhibit internal stratification patterns typical for the prevailing hydraulic energy regime in a sequence stratigraphic context phosphate deposits preferentially occur along marine or maximum flooding surfaces consequent sedimentary reworking may result in the transfer of phosphates to highstand or lowstand deposits bio chemical weathering on continents represents the most significant source of bioavailable phosphorus this implies that long term changes in marine phosphorus levels and with these changes in marine ecology productivity rates and ratios of exported carbonate carbon and organic carbon are a response to changes in continental weathering rates a compilation of marine sedimentary phosphorus burial rates for the last 160 myr suggests that natural variations have occurred that span one order of magnitude for the late jurassic cretaceous and most of the paleogene the phosphorus cycle appears to have been accelerated in times of climate warming which was most likely due to the spreading of zones of humid climate and more intense continental weathering in the neogene the phosphorus cycle appears to have responded to changes in glacially induced weathering this suggests that uniform interpretations with respect to the emplacement of major phosphorite deposits should be treated with caution integrated analyses of the sedimentary and biogeochemical context of phosphorite occurrences may help to identify paleoenvironmental conditions as well as to improve our understanding of periods of enhanced phosphate accumulation periods which were usually characterized by steep gradients in the development of climate and environment with regard to the complexity of feedback mechanisms between the phosphorus cycle and the biosphere the present day input rates of phosphate into the world s oceans should be of great concern they are more than doubled by anthropogenic means and affect ecological systems on a rapidly increasing scale

isotopic evidence for palaeotemperatures and depth stratification of middle cretaceous planktonic foraminifera from the pacific ocean

oxygen isotopes in phosphatic fish remains from israel paleothermometry of tropical cretaceous and tertiary shelf waters the isotopic composition of oxygen in phosphate was measured on 24 fossil fishes from israel and jordan ranging in age from cretaceous to eocene from these the first paleotemperatures were calculated for shallow water cretaceous paleotropics the results were compared to those of fish from other mediterranean localities and to late cretaceous marine reptiles from israel 18o in the fish average 18 0 in the early cretaceous 17 8 in the cenomanian 18 3 in the coniacian 18 2 in the santonian 19 4 in the campanian 20 1 in the maastrichtian and 18 4 in the early eocene such variations suggest a warm cenomanian turonian cooling towards the end of the cretaceous and warming up again in the eocene the deduced temperatures for the cretaceous range between 20 c and 34 c which is about 10 higher than cretaceous water surface temperatures in northern europe apatite from marine reptile skeletons yields similar 18o to coexisting fish the good agreement between these and previously known paleotemperature data give further credence to the validity of paleotemperatures obtained by isotopic analysis of oxygen in phosphates the relatively large thermal gradient between middle and low paleolatitudes favors barron s 1983 coolest cretaceous model

brachinites igneous rocks from a differentiated asteroid we have done petrologic studies of brachinites allan hills alh 84025 elephant moraine eet 99402 and eet 99407 bulk geochemical studies of eet 99402 and eet 99407 ar ar studies of brachina and eet 99402 and a xe isotopic study of brachina textural mineral compositional and bulk compositional evidence show that eet 99402 and eet 99407 are paired alh 84025 eet 99402 and eet 99407 have igneous textures petrofabric analyses of alh 84025 and eet 99407 demonstrate the presence of lineations and probable foliations of olivine grains that support formation as igneous cumulates mineral minor element chemistry and bulk rock incompatible lithophile element contents of the brachinites are distinct from those of acapulcoite lodranite clan meteorites a suite of high grade metamorphic rocks and anatectic residues the differences demonstrate a higher blocking temperature of equilibration for the brachinites and that cumulus plagioclase is present in eet 99402 eet 99407 and probably alh 84025 thus indicating an igneous origin brachinites are differentiated ultramafic achondrites and are not part of a suite of primitive achondrites we infer that their parent asteroid is a differentiated body brachina has an excess of 129xe correlated with reactor produced 128xe demonstrating that short lived 129i was present at the time of formation this plus literature data attests to early formation of the brachinites within a few ma of the formation of chondrites ar ar age data show that brachina and eet 99407 were degassed about 4 13 ga ago possibly by a common impact event eet 99402 and eet 99407 show petrographic evidence for shock including possible conversion of plagioclase to maskelynite followed by devitrification brachina is unshocked making a direct association between the ar ar age and textures ambiguous

classification of mafic clasts from mesosiderites implications for endogenous igneous processes we have analyzed thirteen igneous pebbles from the vaca muerta eet87500 and bondoc mesosiderites by electron microprobe and instrumental neutron activation and combined these data with literature data for forty three analyzed mesosiderite clasts we classify these well characterized clasts into the following five principal groups 1 1 polygenic and monogenic cumulates 39 are coarse grained gabbros that are highly depleted in incompatible elements relative to h chondrites they formed at moderate depth either as residues of low degree partial melting of pre existing cumulate eucrites or as cumulates from parent melts similar to cumulate eucrites 2 2 polygenic basalts 30 are finer grained rocks with positive europium anomalies la lu ratios 1 and lower rare earth element abundances than basaltic eucrites it seems likely that these rocks were formed near their parent body surface by remelting mixtures of major amounts of basaltic eucrites and lesser amounts of cumulate eucrites 3 3 quench textured rocks comprise two compositional groups a those which resemble basaltic eucrites 5 and b those which resemble cumulate eucrites 2 the quench textured rocks are probably monogenic they formed most likely when small scale impacts at their parent body surface totally melted small amounts of basaltic or cumulate eucrite material 4 4 monogenic basalts 11 resemble basaltic eucrites and formed by endogenous igneous processes on the mesosiderite parent body mpb the monogenic basalts and those quench textured rocks that resemble basaltic eucrites in composition plot subparallel to the nuevo laredo trend eucrites on diagrams of incompatible element concentration vs mg previous work has shown that the nuevo laredo trend eucrites were probably produced by fractional crystallization it seems likely that the monogenic basalts from the mpb had a similar origin 5 5 ultramafic rocks are cumulates consisting mainly of large crystals of orthopyroxene 9 or olivine 4 orthopyroxenite clasts closely resemble diogenites and were formed most likely by endogenous igneous processes olivine crystals vary significantly in major element composition some may be endogenous but others may have been derived from the disrupted mantle of a different parent body

anatomy and origin of a cretaceous phosphorite greensand giant egypt late cretaceous epicontinental phosphorites porcelanites cherts dark coloured shales glauconitic sandstones and bioclastic and fine grained carbonate rocks in egypt are examined in terms of their overall depositional and diagenetic framework and stable isotopic and organic geochemical characteristics two main depositional realms are interpreted and correlated through sequence stratigraphic analysis 1 a shallow hemipelagic environment accompanying initial stages of marine transgression and conducive to the formation of organic carbon rich shales biosiliceous sediments and thick phosphorites and 2 a relatively high energy depositional regime accompanying sea level fall during which deltas advanced glauconites were reworked seaward and prograding oyster banks became periodically exposed to episodes of fresh water diagenesis thereby promoting solution collapse phenomena in associated cherts lenticular to massive phosphorites are viewed as the result of current winnowing and concentration of authigenic grains initially precipitated in associated reducing shales and biosiliceous sediments in eastern egypt the phosphorites form winnowed lag layers some of which may have been redeposited down slope in structural lows in the west these sands were concentrated into giant phosphorite sand waves built by reworking of penecontemporaneously deposited phosphatic muds during marine transgression carbon isotopic results substantiate interpretations from modern deposits for limitation of phosphate mineral precipitation with depth in sediments as a result of lattice poisoning however direct desorption of phosphorus to pore waters from detrital iron oxyhydroxide phases also may have been important in the cretaceous setting the iron reduced in this process being available for incorporation in glauconites the main locus for authigenic glauconite precipitation appears to be where iron fluxes from regions of lateritic weathering were highest and near the boundary between oxygenated and reduced waters this study suggests a model for the common coexistence of glauconites and phosphorites in the geological record although upwelling is often advocated as the origin of nearly all giant phosphorite deposits we suggest that some of these may have been strongly influenced by fluvially derived phosphorus borne on particulates and desorbed from these compounds upon flocculation and or reduction in bottom waters or pore waters

a comparative study of opaque phases in qingzhen eh3 and macalpine hills 88136 el3 representatives of eh and el parent bodies opaque minerals in the qingzhen eh3 and macalpine hills mac 88136 el3 enstatite chondrites were studied and compared with other eh and el chondrites all opaque minerals usually occur in multi sulfide metal clasts and nodules in the matrix between chondrules el goresy et al 1988 the higher abundance of opaque minerals the occurrence of niningerite and various alkali sulfides e g caswellsilverite phases a and b djerfisherite are diagnostic criteria for eh chondrites while alabandite is characteristic for el chondrites in addition eh chondrites are characterized by enrichments of si in both kamacite and perryite and alkali elements in sphalerite and chalcopyrite the mn contents of daubreelite and sphalerite are lower in eh than in el chondrites these are consistent with lower oxygen fugacity and higher h2s fugacity of eh than el chondrites in contrast the discovery of sphalerite and zn rich daubreelite in mac 88136 indicates that their absence in el6 chondrites is probably related to thermal metamorphism in the parent body schreibersite microspherules are commonly enclosed in most sulfides in qingzhen but are absent in mac 88136 they were once molten and probably predated all sulfide host phases the petrographic setting and chemical compositions of the sulfide hosts of the schreibersite microspherules in eh3 chondrites are consistent with formation by condensation the earliest sulfide condensates oldhamite and niningerite occupy the interiors of the clasts and nodules whereas the rims consist of troilite and djerfisherite in addition in qingzhen some other troilite djerfisherite and sphalerite assemblages coexist with perryite they were produced by sulfurization of metallic fe ni in the nebula in mac 88136 sulfurization of si bearing fe ni metal is less pronounced and it produced troilite schreibersite and less abundant perryite two kinds of normal zoning and a reverse zoning trends of niningerite and both normal and reverse zoning of sphalerite were found in clasts and nodules in qingzhen the coexistence of normal and reverse zoning profiles in niningerite grains in the same meteorite strongly suggests that they formed before accretion in the parent body because an asteroidal metamorphic or an impact event in the parent body would have erased these contrasting profiles and destroyed the textural settings in contrast alabandite in mac 88136 shows only normal zoning with the fes content decreasing to 9 3 mol toward troilite indicating very slow cooling at low temperature

the k kakangari chondrite grouplet abstract the kakangari lew 87232 and lea co 002 chondrites have a similar set of petrologic and oxygen isotopic characteristics that distinguishes them from other chondrite groups they are here established to constitute a single chondrite grouplet the k after kakangari chondrites the k chondrites have 1 high matrix abundances 33 77 vol as do carbonaceous chondrites 2 metal abundances 6 10 vol that are similar to the h group ordinary chondrites 3 average mafic silicate compositions average kakangari olivine fa2 2 enstatite fs4 4 that indicate an oxidation state intermediate between h and e chondrites 4 matrix that differs from that in other chondrite groups in being enstatite rich with compositions more mg rich average fs3 than those in the chondrules 5 refractory lithophile element abundances

allan hills 85085 a subchondritic meteorite of mixed nebular and regolithic heritage abstract allan hills 85085 is a tiny 12 g meteorite whose closest relatives are the renazzo and al rais chondrites and the subchondritic host material in the bencubbin meteorite its bulk composition is generally chondritic but siderophile abundances are tens of per cent higher and abundances of moderately volatile elements factors of 2 4 lower than in known authentic chondrites in addition to this unusual composition alh85085 has an extremely small particle size metal that shows no evidence of metamorphic equilibration and a very high abundance of pyroxenitic lithic particles chondrules are rare and small most are pyroxenitic and chemically similar to the lithic particles previous workers have inferred that most or all of these strange features of alh85085 resulted from nebular processes but we suggest that melting vaporization outgassing condensation and size sorting in a cloud of impact ejecta offer a more viable alternative until additional similar materials have been discovered and characterized it seems safest to infer nebular properties and processes on the basis of the record in chondrites regarding which there is little doubt that nebular processes were dominant

inconstant ancient seas and life s path seawater composition has changed over geological time geochemists now realize has biological evolution changed along with it a paper in this issue of science p 1222 suggests that oscillations in the chemical composition of the world ocean likely driven by the varying tempo of plate tectonics might have helped trigger a number of important evolutionary events

formation of ureilites by nebular processes oxygen isotopic data are presented for 23 ureilites including 14 antarctic meteorites they show a much greater range in isotopic composition than those previously studied most noteworthy is the fact that unlike other achondrite groups the ureilites do not fall on a mass dependent isotopic fractionation trend but rather fall along an extrapolation of the 16o mixing line defined by components of allende and other c3 chondrites correlations between isotopic and chemical data imply that the isotopic and chemical variations are due primarily to processes in the solar nebula and not to igneous processes within a parent body the ureilite parent body accreted with isotopic and chemical heterogeneities which were not much modined by subsequent parent body processes the precursor materials were related in some way to the c3 carbonaceous chondrites

extreme polar warmth during the cretaceous greenhouse paradox of the late turonian δ18o record at deep sea drilling project site 511 1 oxygen isotope data for upper turonian planktonic foraminifera at deep sea drilling project site 511 falkland plateau 60 s paleolatitude exhibit an 2 excursion to values as low as 4 66 vienna peedee belemnite standard pdb coincident with the warmest tropical temperature estimates yet obtained for the open ocean the lowest planktonic foraminifer 1 8 o values suggest that the upper ocean was as warm as 30 32 c this is an extraordinary temperature for 60 s latitude but is consistent with temperatures estimated from apparently coeval mollusc 1 8 o from nearby james ross island 65 s paleolatitude glassy textural preservation a well defined depth distribution in site 511 planktonics low sediment burial temperature 32 c and lack of evidence of highly depleted pore waters argue against diagenesis even solid state diffusion as the cause of the very depleted planktonic values the lack of change in benthic foraminifer 1 8 o suggests brackish water capping as the mechanism for the low planktonic 1 8 o values however mixing ratio calculations show that the amount of freshwater required to produce a 2 shift in ambient water would drive a 7 psu decrease in salinity the abundance and diversity of planktonic foraminifera and nannofossils high planktonic benthic ratios and the appearance of keeled foraminifera argue against lower than normal marine salinities isotope calculations and climate models indicate that we cannot call upon more depleted freshwater 1 8 o to explain this record without more late turonian data especially from outside the south atlantic basin we can currently only speculate on possible causes of this paradoxical record from the core of the cretaceous greenhouse

a nonmagmatic origin of group iie iron meteorites abstract new neutron activation data on 10 elements in 12 iie and iie related irons lead to a reclassification of several irons seymchan and lonaconing are removed from iie and leshan added four iie members are designated iie an to call attention to some anomalous properties the eight normal iie members define element ni trends generally similar to those in the nonmagmatic group iab the small negative slopes on w ni and ir ni diagrams are strongly indicative of a nonmagmatic origin of the iie irons we propose that iie irons like iab irons originated as individual pools of impact produced melt in the near surface region of a chondritic parent body the positive as ni and au ni trends are the only evidence suggesting fractional crystallization but their slopes are lower than those in magmatic group iiiab and only slightly higher than those of cu and sb in iab we suggest that the s and c contents of the iie precursor materials were much lower than those of the iab precursors thus higher temperatures were required to generate enough metallic melt to segregate into pools these higher temperatures are also reflected in the nonchondritic compositions of the silicate inclusions

chemical classification of iron meteorites xi multi element studies of 38 new irons and the high abundance of ungrouped irons from antarctica abstract we report concentrations of 14 elements in the metal of 38 iron meteorites and a pallasite the meteorites are classified based on these data and on structural observations three samples are paired with previously classified irons thus these additional 35 irons raise the number of well classified independent iron meteorites to 598 one yamato iron contains 342 mg g ni the second highest ni content in an iab iron after oktibbeha county two small irons from western australia appear to be metal nodules from mesosiderites several of the new irons are from antarctica of 24 independent irons from antarctica 8 are ungrouped the fraction 0 333 is much higher than the fraction 0 161 among all 598 classified irons statistical tests show that it is highly improbable 2 9 probability that the antarctic population is a random sample of the larger population the difference is probably related to the fact that the median mass of antarctic irons is about two orders of magnitude smaller than that of non antarctic irons it is doubtful that the difference results from fragmentation patterns yielding different size distributions favoring smaller masses among ungrouped irons more likely is the possibility that smaller meteoroids tend to sample a larger number of asteroidal source regions perhaps because small meteoroids tend to have higher ejection velocities or because small meteoroids have random walked a greater increment of orbital semimajor axis away from that of the parent body

european cretaceous shorelines stage by stage abstract inferred shorelines are presented for the twelve cretaceous stages for the area of europe and adjacent seas contained between approximately 35 and 65 n and between 15 w and 25 e there is a brief stage by stage commentary and a bibliography of source materials

biological control of calcium isotopic abundances in the global calcium cycle measurements of 44ca 40ca expressed as 44ca were made on igneous rocks and on shell and bone material from modern organisms to investigate the magnitude and origins of calcium isotopic fractionation in nature the results document a span of 4 in 44ca measured with the double spike technique to a precision of 0 15 volcanic rocks including basalt and rhyolite show little variability and cluster near 44ca 0 0 2 systematic analysis of biological samples indicates that biological processing of calcium discriminates against heavy isotopes and that biological fractionation is the primary generator of calcium isotopic fractionation in nature preliminary data suggest that calcium becomes isotopically lighter as it moves through food chains calcium carbonate shells of marine microorganisms and deep sea carbonate ooze have 44ca about 1 0 lower than seawater this fractionation causes seawater to be enriched in heavy calcium 44ca 0 9 relative to igneous rocks marine organisms consequently are isotopically heavier than their terrestrial counterparts at similar trophic level the calcium isotopic composition of living and fossil organisms may record information on diet and environment

evolution of tethyan phosphogenesis along the northern edges of the arabian african shield during the cretaceous eocene as deduced from temporal variations of ca and nd isotopes and rates of p accumulation abstract the evolution of tethyan phosphogenesis during the cretaceous eocene is examined to try to explain fluctuations of phosphogenesis through time and whether or not they reflect long term changes in ocean circulation or in continental weathering twenty seven time stratigraphic phosphate levels in various tethyan sites covering a time span of about 90 myr from the hauterivian to the eocene were analyzed for 44 ca 42 ca and 143 nd 144 nd in their carbonate fluorapatite cfa fraction p and ca accumulation rates and bulk sedimentation rates were quantified throughout the cretaceous eocene negev sequence to examine how changes in 44 ca 42 ca and 143 nd 144 nd are reflected in the intensity of phosphogenesis a clear cut change occurs in e nd t and 44 ca and in the rates of p and ca accumulation and bulk sedimentation through the time analyzed e nd t is much lower in the hauterivian lower cenomanian 12 8 to 10 9 than in the upper cenomanian eocene 7 8 to 5 9 much lower 44 ca values occur in the hauterivian turonian 0 22 to 0 02 than in the coniacian eocene 0 23 to 0 40 p accumulation rates in the negev steeply increase from 2 k yr 1 in the albian coniacian to 1500 mol cm 2 k yr 1 in the campanian whereas a strong decrease is concomitantly recorded in the rates of ca accumulation and bulk sedimentation in addition distinct e nd t values are shown by the phosphorites of the negev 6 7 to 6 4 and egypt 9 1 to 7 6 during the campanian and by those of the negev 7 8 to 6 3 and north africa 10 1 to 8 9 during the maastrichtian eocene the culmination of p accumulation rates in the negev during the campanian occurring with a high in e nd t and 44 ca and a low in sedimentation rates indicates that paleoceanographic and paleogeographical factors mostly governed phosphorite accumulation in this area the abrupt e nd t rise after the cenomanian is attributed to increased incursion of pacific radiogenic water masses into the tethys driven by the late cretaceous global sea level rise the connection between north and south atlantic the global post santonian cooling and the progressive widening of the caribbean threshold all acting in combination to significantly intensify the tethyan circumglobal current tcc it also reflects a weakening of the continental nd signal due to a reduction of exposed landmasses caused by increased flooding of continental shelves high 44 ca values at those times also point to a decrease in weathering ca 2 fluxes and expansion of carbonate sedimentation in shelves both enriching seawater with isotopically heavy ca 2 deep ocean circulation intensified by the post santonian cooling of high latitudes increased p inventory in the tethys basin whereas the strengthened tcc and the folded shelf likely resulted in coastal and topographically induced upwelling supplying p rich intermediate waters to southeastern tethys shelves only in the paleocene eocene following major changes in global circulation produced by narrowing of tethys and widening of the atlantic did phosphogenesis shifts its locus of high intensity to the western atlantic tethys and west african atlantic coasts this change in paleocirculation is expressed by distinctly differing e nd t in the middle east and the north and west african phosphorites suggesting different oceanic p sources and current systems for these two major groups of phosphorites our nd isotope results further suggest a weaker tcc during the mid cretaceous becoming more intense in late cretaceous times they also point to the north pacific ocean as major source of deep water formation for the intermediate deep waters in the tethys basin during the late cretaceous

petrologic geochemical and experimental constraints on models of chondrule formation abstract the petrologic and geochemical properties of chondrules as well as results of experimental studies provide strong constraints on chondrule formation models nebular formation is indicated by the non mass fractionated oxygen isotopic compositions of bulk chondrules chondrule formation from a melt is required by the prototypical spheroidal shapes and the presence of euhedral phenocrysts and glassy mesostases incomplete melting is indicated by the abundance of porphyritic chondrules which experiments demonstrate require relict nuclei and coarse relict grains the length of time that chondrules were hot is constrained by their retention of relict grains and moderately volatile elements rapid cooling of chondrules after formation is supported by the presence of zoned phenocrysts isotopic anomalies and dynamic crystallization experiments it is clear from the presence of relict grains enveloping compound chondrules and igneous rims that many chondrules were heated again after cooling the heating mechanism responsible for chondrule formation seems to have operated at varying intensities over large regions of the inner solar nebula for at least the time it took ambient nebular temperatures to cool from above 900 to below 600 k the chondrule formation mechanism provided a repeatable source of energy capable of highly localized melting characteristic of flash heating the occurrence of ferroan microchondrules with low melting temperatures within some chondrule rims indicates that chondrule formation did not occur exclusively in high temperature regions near the sun as required in bipolar outflow models mechanisms for forming chondrules that are consistent with the constraints include various flash heating models nebular lightning magnetic reconnection flares gas dynamic shock waves and radiative heating

origin and age of phosphorite from the south central florida platform relation of phosphogenesis to sea level fluctuations and δ13c excursions abstract francolite carbonate fluorapatite from predominantly peloidal phosphorite grains in the miocene hawthorn group from the babcock deep core southwestern florida is highly substituted with an average composition of ca4 61na0 22mg0 14k0 05sr0 02 po4 2 23 co3 0 62 so4 0 12 f 1 04 13c values of 1 0 7 8 pdb of the francolite co3 indicate a substantial contribution of c from an organic source the sulfur isotopic composition of francolite so4 is depleted to slightly enriched relative to miocene seawater and suggests that phosphogenesis occurred during early burial diagenesis in organicrich sediments above or in the zone of sulfate reduction the uniformly high sr na mg so4 and co3 contents of the francolite the 18o values of the francolite co3 0 2 4 2 pdb and the inclusion of pyrite and organic matter in phosphorite grains suggest that the francolite has had minimal chemical alteration since its formation phosphorite from the babcock deep core has sr 87 86 ratios that range from 0 708148 0 708880 and sr derived ages that range from late oligocene 25 6 0 7 ma to early late miocene 9 2 1 4 ma the sr derived ages of relatively fragile calcareous benthic foraminifers are consistently younger than associated hard tightly cemented phosphorite and support textural evidence of extensive reworking the age of the host sediment ranges from early miocene to pliocene and its depositional history is related to sea level fluctuations approximately three quarters of the total phosphorite in the babcock deep core formed during or within 2 my before the major early to mid miocene positive 13cshift as recorded at dsdp site 588 southwest pacific one third of the total phosphorite formed just prior to the carbon shift in the short interval between 21 9 and 20 4 ma these results indicate that reworked phosphorite deposits may provide a proxy of organic carbon cycling on continental shelves that correspond to sealevel fluctuations and to variations in the 13crecord

acapulco and lodran like achondrites petrology geochemistry chronology and origin we have performed petrologic and geochemical studies of five primitive achondrites alha81187 and alha81261 acapulco like eet 84302 transitional but acapulco like and lew 88280 and mac 88177 lodran like we have also performed 39ar 40ar chronology on alha81187 alha81261 and eet 84302 lew 88280 and mac 88177 contain more ferroan olivines orthopyroxenes clinopyroxenes and chromites than do the acapulco like achondrites plagioclase is present in only alha81187 alha81261 and eet 84302 its composition does not track that of the mafic silicates eet 84302 with the most calcic plagioclase contains olivine and pyroxene with an mg intermediate between alha81187 and alha81261 similarly spinels in eet 84302 have the same mg as those in alha81187 while pyroxenes in the former are more ferroan than in the latter acapulco like achondrites have sm sc ratios between 0 8 1 5 times h chondrites and na sc ratios are between 0 81 0 times h chondrites indicating that silicate partial melts have not been lost from these rocks siderophile and chalcophile elements are fractionated and show a trend of increasing ir ni ratios with decreasing se co ratios this variation is consistent with fractionation by partial melting in the fe ni s system eet 84302 is very depleted in se and troilite is a accessory phase indicating essentially total loss of the low temperature fe ni s melt in contrast the lodran like achondrites are depleted in the highly incompatible lithophile elements relative to more compatible elements sm sc ratios are 0 2 0 7 times and na sc ratios are 0 04 0 18 times h chondrites these data are consistent with a model for formation of the lodran like achondrites as partial melting residues however the low ir ni and high se co ratios in two lodran like achondrites suggest the metal troilite in these rocks is dominated by the low melting fraction in the fe ni s system this metal troilite was added to the silicates after partial melting depleted them in a basaltic fraction the ar ar release spectra yield good plateau ages of 4 507 0 024 ga alha81187 4 511 0 007 ga alha81261 and 4 519 0 017 ga eet 84302 in good agreement with previously determined ar ar ages for other acapulco like achondrites together the ar ar ages demonstrate that metamorphism on the acapulco lodran parent body occurred 4 51 0 02 ga ago roughly 50 ma after its formation the geochemical and petrologic evidence on the acapulco and lodran like achondrites suggest that heating on the parent body was localized and heterogeneous in space and time the parent body was probably not subjected to parent body wide magmatism in contrast to the case for 4 vesta and the hed meteorites

the compositional classification of chondrites vii the r chondrite group bulk compositional and petrographic data clearly define the new r rumuruti group of chondrites consisting of rumuruti the only fall alh85151 acfer 217 carlisle lakes dar al gani 013 pca91002 pca91241 y 75302 y 793575 and y 82002 compositional petrographic rare gas and 0 isotopic data strongly suggest that pca91002 and pca91241 are paired the yamato specimens are probably not paired the matrices of the known r chondrites have experienced similar minor degrees of metamorphism petrographic types are 3 8 3 9 with the exception of alh85151 3 6 all except carlisle lakes contain equilibrated r5 r6 clasts petrographically the r chondrites are characterized by a low chondrule matrix modal abundance ratio high states of oxidation reflected by abundant nio bearing olivine with fa37 40 relatively small chondrules mean apparent diameters of 400 abundant up to 11 wt sulfides mainly pyrrhotite and pentlandite and negligible amounts of metallic fe ni refractory lithophile abundances are 0 95 x cl intermediate between those in ordinary chondrites oc and ci chondrites abundances of the volatile elements se and zn are greatly enhanced relative to oc the r chondrites are clearly distinguished from other chondrite groups on the basis of al mn and zn mn abundance ratios the oxygen isotopic data plot roughly along a slope 12 line with whole rock 17o values higher than for any other chondrite group rumuruti acfer 217 alh85151 pca91002 and pca91241 have light dark structures and solar wind implanted rare gases indicating that they are regolith breccias the yamato specimens also have light dark structures and are inferred to be regolith breccias carlisle lakes lacks solar rare gases and is unbrecciated based on similarities in refractory lithophile abundances 00 95 x ci oxygen isotope compositions 17o 0 and refractory inclusion abundances 0 1 vol none have been reported the r chondrites probably belong to a noncarbonaceous superclan of chondrites that also includes ordinary and enstatite chondrites the high oxidation state high matrix chondrule modal abundance ratio relatively low abundance of droplet chondrules and high 17o composition suggest that the r chondrites formed at greater heliocentric distances than the oc

paucity of sulfide in a large slab of esquel new perspectives on pallasite formation the 0 7 ton esquel meteorite found in patagonia before 1951 is a typical main group pallasite in most respects we examined petrographically a slab 1 m long having an area of 3000 cm2 that shows the typical pallasitic texture with fragmental olivine phase abundances in vol are olivine 66 metal 32 schreibersite 0 76 troilite 0 46 and chromite 0 31 esquel can be divided into four lithologies 1 pallasitic matrix consisting of olivine fragments embedded in metal 81 2 large 5 cm olivine nodules having low metal contents 18 3 massive metal 0 3 and 4 zones dominated by fes and fine olivine 0 7 main group pallasites appear to have formed by the intrusion of a highly evolved low ir high ni au and s metallic magma into fragmented olivine this model implies that fes should be abundant in main group pallasites and we had speculated that examination of an exceptionally large slab might reveal a high troilite content we found instead an exceptionally low fes content new compositional data confirm that esquel has a lower au content than other main group pallasites having similar ir contents literature data based however on relatively small sections suggest that high au pallasites have higher s contents than esquel but have lower s contents than expected from a trapped melt model we conclude that a relatively complex model is required to explain the origin of main group pallasites after intrusion the degree of crystallization of the metallic magma varied from location to location but in almost all cases an fes rich liquid either escaped or formed fes rich pallasitic rocks that are underrepresented in the meteorite inventory

preservation of seawater sr and nd isotopes in fossil fish teeth bad news and good news abstract we analyzed 87sr 86sr ratios in foraminifera pore fluids and fish teeth for samples ranging in age from eocene to pleistocene from four ocean drilling program sites distributed around the globe site 1090 in the cape basin of the southern ocean site 757 on the ninetyeast ridge in the indian ocean site 807 on the ontong java plateau in the western equatorial pacific and site 689 on the maud rise in the southern ocean sr isotopic ratios for dated foraminifera consistently plot on the global seawater sr isotope curve for sites 1090 757 and 807 sr isotopic values of the pore fluids are generally less radiogenic than contemporaneous seawater values as are values for fossil fish teeth in contrast pore fluid 87sr 86sr values at site 689 are more radiogenic than contemporaneous seawater and the corresponding fish teeth also record more radiogenic values thus sr isotopic values preserved in fossil fish teeth are consistently altered in the direction of the pore fluid values furthermore there is a correlation between the magnitude of the offset between the pore fluids and the seawater curve and the associated offset between the fish teeth and the seawater curve these data suggest that the hydroxyfluorapatite of the fossil fish teeth continues to recrystallize and exchange sr with its surroundings during burial and diagenesis therefore sr chemostratigraphy can be used to determine rough ages for fossil fish teeth in these cores but cannot be used to fine tune age models in contrast to the sr isotopic system our nd concentration data combined with published isotopic and rare earth element data suggest that fish teeth acquire nd during early diagenesis while they are still in direct contact with seawater the concentrations of nd acquired at this stage are extremely high relative to the concentrations in surrounding pore fluids as a result nd isotopes are not altered during burial and later diagenesis therefore fossil fish teeth from a variety of marine environments preserve a reliable and robust record of deep seawater nd isotopic compositions from the time of deposition

sm nd in marine carbonates and phosphates implications for nd isotopes in seawater and crustal ages this study explores the possibility of establishing nd isotopic variations in seawater over geologic time calcite aragonite and apatite are examined as possible phases recording seawater values of nd modern biogenic and inorganically precipitated calcite and aragonite from marine environments were found to have nd concentrations of from 0 2 to 70 ppb showing that primary marine caco 3 contains little ree and that nd ca is not greatly enhanced relative to seawater during carbonate precipitation very young marine limestone and dolomite containing no continental detritus have 200 ppb nd all the carbonates are lree enriched 0 16 sm nd 0 45 modern and very young atlantic and pacific carbonates have nd in the range of shallow atlantic and pacific seawater respectively implying that they derive their ree from local seawater the nd in well preserved carbonate fossils is 4 10 4 ppb much greater than in their modern counterparts but like the high values found for carbonates in other studies we believe the high ree contents at the 500 ppb level in some detritusfree carbonates are due to ree rich fe hydroxide in on the carbonate in favorable cases such material may record seawater nd values however introduction of extraneous ree may obscure the original isotopic composition of pure caco 3 because of its very low intrinsic primary ree abundance modern biogenic apatite is also shown to have very low ree content 150 ppb nd but appears to quickly scavenge ree from seawater inorganically precipitated apatite from phosphorites has high concentrations of seawater derived ree young phosphorite apatite from the atlantic and pacific oceans has nd in the range of the seawater from these oceans older apatite samples of similar age from different localities bordering common oceans record similar values of nd t sedimentary apatite has sr t values in good agreement with the curves for 87 sr 86 sr of seawater as a function of time individual conodonts from a single formation yield the same sr t and nd t other workers have shown that sedimentary apatite preserves seawater ree patterns these characteristics suggest that sedimentary apatite can be used to determine nd t in ancient seawater the seawater values so inferred range between 1 7 and 8 9 over the last 700 my and lie in the range of modern seawater showing no evidence for drastic changes high values of seawater nd t in the triassic and latest precambrian may correlate with the breakup of large continental landmasses the initial nd t 15 0 of a 2 ae old phosphorite implies the presence of 1 5 ae old continental crust at 2 ae ago the approach outlined here can be used to constrain the age of the exposed crust as a function of time

phosphorus accumulation rates in a miocene low oxygen basin the monterey formation pismo basin california abstract phosphorus p limits oceanic productivity on long time scales and therefore determining changes in oceanic p accumulation through time is important for modeling oceanic paleoproductivity we determined p concentrations and accumulation rates at shell beach california a section of phosphatic rich marine sedimentary rocks which includes the widespread phosphatic and siliceous facies of the monterey formation phosphorus concentrations had wide ranges in the major lithologies found in these facies with values in phosphatic shales ranging from 0 36 to 3 9 wt compared to 0 02 to 0 42 wt in dolomitic and siliceous strata phosphorus accumulation rates in mol p cm 2 yr 1 for all values reported here showed significant variability with both sample lithology and position in the section phosphorus accumulation rates were much higher in phosphatic shale strata 1 5 29 than in dolomitic and siliceous strata 0 1 3 1 in both facies furthermore p accumulation rates were generally higher in phosphatic shale strata of the upper siliceous facies 3 1 29 compared to the lower phosphatic facies 1 5 14 mean p accumulation rates calculated using linear sedimentation rate models for each facies and observations of the relative amount of phosphatic shale dolomite and siliceous strata are comparable between the portions of phosphatic and siliceous facies studied this indicates that the two facies with their faunal and sedimentological characteristics considered to reflect major oceanic and climatic changes during the middle miocene are similar in terms of p burial total p accumulation rates are also comparable to other phosphogenic miocene and modern environments we modeled variable sedimentation rates to examine the sensitivity of mean p accumulation rates to the linear sedimentation rate assumption increasing shale sedimentation rates to values above those estimated by linear models yields higher mean p accumulation rates in both facies though they remain comparable in terms of net p burial modeling also revealed that for increased shale sedimentation rates in each facies siliceous sedimentation must be about three times faster than dolomitic strata sedimentation

petrology and geochemistry of d orbigny geochemistry of sahara 99555 and the origin of angrites petrology and geochemistry of d orbigny geochemistry of sahara 99555 and the origin of angrites

formation of metal and silicate globules in gujba a new bencubbin like meteorite fall gujba is a coarse grained meteorite fall composed of 41 vol large kamacite globules 20 vol large light colored silicate globules with cryptocrystalline barred pyroxene and barred olivine textures 39 vol dark colored silicate rich matrix and rare refractory inclusions gujba resembles bencubbin and weatherford in texture oxygen isotopic composition and in having high bulk 15n values 685 the 3he cosmic ray exposure age of gujba 26 7 ma is essentially identical to that of bencubbin suggesting that they were both reduced to meter size fragments in the same parent body collision the gujba metal globules exhibit metal troilite quench textures and vary in their abundances of troilite and volatile siderophile elements we suggest that the metal globules formed as liquid droplets either via condensation in an impact generated vapor plume or by evaporation of preexisting metal particles in a plume the lower the abundance of volatile elements in the metal globules the higher the globule quench temperature we infer that the large silicate globules also formed from completely molten droplets their low volatile element abundances indicate that they also formed at high temperatures probably by processes analogous to those that formed the metal globules the coarse grained bencubbin weatherford gujba meteorites may represent a depositional component from the vapor cloud enriched in coarse and dense particles a second class of bencubbin like meteorites represented by hammadah al hamra 237 and que 94411 may be a finer fraction derived from the same vapor cloud

a petrologic and isotopic study of winonaites evidence for early partial melting brecciation and metamorphism we have conducted detailed petrologic chemical and isotopic studies of winonaites to ascertain the genesis of this group of meteorites winonaites have reduced mineral compositions and mineralogy and oxygen isotopic compositions distinct from primitive achondrite groups other than silicate inclusions in iab and iiicd irons however winonaites differ from iab and iiicd irons in that they lack the metallic matrices of the latter and consist mostly of silicates on the basis of these criteria winona mount morris wisconsin tierra blanca pontlyfni y 74025 y 75300 y 8005 and que 94535 are winonaites and y 75305 and y 75261 may be winonaites winonaites are fine to medium grained mostly equigranular rocks pontlyfni and mount morris wisconsin contain what appear to be relict chondrules several winonaites contain mm sized areas that differ substantially in grain size and or silicate mineralogy from the surrounding matrix fe ni fes veins are common in many winonaites mineral compositions are intermediate between e and h chondrites and reduced sulfides are observed in low feo winonaites bulk major element compositions are roughly chondritic although ree elements are fractionated the 39ar 40ar ages of three winonaites range from 4 40 ga mount morris wisconsin to 4 54 ga pontlyfni cosmic ray exposure ages are 20 80 ma trapped noble gases in these winonaites resemble those in enstatite chondrites we suggest that the winonaites formed from a chondritic precursor material unlike that of known chondrites in mineral and oxygen isotopic compositions and this material may have been heterogeneous in composition extensive heating caused metamorphism and partial melting of both fe ni fes and silicate material impact brecciation during cooling mixed lithologies with different thermal histories and subsequent metamorphism produced recrystallization grain growth and reduction of mafic silicates the 39ar 40ar ages indicate that cooling may have been more rapid than observed in iab irons although later resetting may have occurred

the iab iron meteorite complex a group five subgroups numerous grouplets closely related mainly formed by crystal segregation in rapidly cooling melts abstract we present new data for iron meteorites that are members of group iab or are closely related to this large group and we have also reevaluated some of our earlier data for these irons in the past it was not possible to distinguish iab and iiicd irons on the basis of their positions on element ni diagrams but we now show that plotting the new and revised data yields six sets of compact fields on element au diagrams each set corresponding to a compositional group the largest set includes the majority 70 of irons previously designated ia we christened this set the iab main group the remaining five sets we designate subgroups within the iab complex three of these subgroups have au contents similar to the main group and form parallel trends on most element ni diagrams the groups originally designated iiic and iiid are two of these subgroups they are now well resolved from each other and from the main group the other low au subgroup has ni contents just above the main group two other iab subgroups have appreciably higher au contents than the main group and show weaker compositional links to it we have named these five subgroups on the basis of their au and ni contents the three subgroups having au contents similar to the main group are the low au l subgroups the two others the high au h subgroups the ni contents are designated high h medium m or low l thus the old group iiid is now the slh subgroup the old group iiic is the slm subgroup in addition eight irons assigned to two grouplets plot between sll and slm on most element au diagrams a large number 27 of related irons plot outside these compact fields but nonetheless appear to be sufficiently related to also be included in the iab complex many of these irons contain coarse silicates having similar properties most are roughly chondritic in composition the mafic silicates show evidence of reduction during metamorphism in each case the silicate o isotopic composition is within the carbonaceous chondrite range 17o 0 3 in all but four cases these are within the so called iab range 0 30 17o 0 68 fine silicates appear to be ubiquitous in the main group and low au subgroups this requires that viscosities in the parental melt reached high values before buoyancy could separate these the well defined main group trends on element au diagrams provide constraints for evaluating possible models we find the evidence to be most consistent with a crystal segregation model in which solid and melt are essentially at equilibrium the main arguments against the main group having formed by fractional crystallization are a the small range in ir and b the evidence for rapid crystallization and a high cooling rate through the iron stability field the evidence for the latter are the small sizes of the iron crystals parental to the widmanstatten pattern and the limited thermal effects recorded in the silicates including retention of albitic plagioclase and abundant primordial rare gases in contrast crystal segregation in a cooling metallic melt and related processes such as incomplete melting and melt migration can produce the observed trends in the main group we infer that this melt was formed by impact heating on a porous chondritic body and that the melt was initially hotter than the combined mix of silicates and metal in the local region the melt cooled rapidly by heat conduction into the cooler surroundings mainly silicates we suggest that the close compositional relationships between the main group and the low au subgroups are the result of similar processes instigated by independent impact events that occurred either at separate locations on the same asteroid or on separate but compositionally similar asteroids

nd isotope evidence for the evolution of the paleocurrents in the atlantic and tethys oceans during the past 180 ma the nd isotopic composition of atlantic and tethys seawater as deduced from marine phosphorites varied considerably during the past 180 ma the early tethys and central atlantic seawater from 180 to 160 ma ago early middle jurassic had a nd isotopic signature identical to that of the pacific end 6 suggesting that pacific seawater entered the newly forming tethys basin however with time continental runoff draining into the young basin became more important and led to a decrease in the nd isotopic composition and finally a decoupling from the pacific ocean during the late early cretaceous 120 90 ma ago atlantic and tethys seawater reached continental crust like nd isotopic composition values end 10 which could reflect high weathering rates induced by the warm and humid climate at that time in the time span between 80 and 50 ma late cretaceous early tertiary the nd isotopic composition of both tethys and atlantic seawater strongly increased towards pacific seawater values in the case of the atlantic ocean this change has been correlated with the opening of the south atlantic which enabled the more radiogenic pacific seawater to travel westwards around the southern edge of africa into the south and finally the north atlantic in the case of tethys seawater we have to assume that during this period large masses of pacific seawater entered the tethys again directly through the indian tethys seaway the renewed importance of this seaway might be related to the late cretaceous early tertiary first order global sea level highstand the most abrupt change towards lower more crust like values occurred in the early miocene 25 17 ma ago in the south and north atlantic as well as in the tethys during this period the143nd 144nd isotope ratios dropped from 0 5124 end 4 2 down to 0 5122 end 8 this change indicates a diminishing influx of pacif seawater into the atlantic and tethys oceans and can be correlated with the breakdown of the circum equatorial circulation patterns of the world oceans due to plate tectonics from 20 to 17 ma ago miocene the nd isotopic composition of the atlantic ocean increased again and reached values as high as 0 5123 end 6 6 whereas tethys seawater remained at low values this decoupling can be correlated with the incipient complete isolation of the tethys the nd isotopic composition was henceforth controlled by the continental runoff from surrounding land masses the major increase in the nd isotopic composition observed in the atlantic can be related to the opening of the drake passage and establishment of the circum antarctic current system this allowed pacific seawater to enter directly the south atlantic around antarctica a renewed drop in the nd isotopic composition of atlantic seawater during the late miocene can be related to the onset of north atlantic bottom water formation and its subsequent upwelling

early diagenesis of organic matter in peru continental margin sediments phosphorite precipitation abstract pore water chemistry total dissolved co 2 nh 4 no 3 no 2 po 4 si oh 4 ca mg fe mn so 4 h 2 s and f and titration alkalinity solid phase chemistry c org p org c tot n tot f si opal and s ii and sediment characteristics porosity dry bulk density and formation factors were determined on a centimeter scale spacing in the upper 20 40 cm of sediments under intense upwelling areas on the peru continental shelf these data demonstrate that carbonate fluorapatite cfa is precipitating from pore waters in the upper few centimeters of a gelatinous mud with high organic carbon content up to 20 c org very high porosity 0 96 ml cm 3 and very low dry bulk density 3 dissolved phosphate concentrations at the sediment water interface range from 20 to 100 m orders of magnitude higher than bottom water concentrations and much higher than predicted from regeneration of organic matter the mechanism of this interfacial phosphate release is unclear but is apparently uncoupled from carbon and nitrogen metabolism and thus may be linked either to dissolution of fish debris or to the presence of a microbial mat in surficial sediments fluoride is incorporated into cfa by diffusion from the overlying seawater and carbonate ions are provided from pore water alkalinity magnesium concentrations in this reaction zone are not significantly different from those of seawater suggesting that magnesium depletion is not a necessary prerequisite for cfa precipitation the environment of precipitation is interface linked rather than driven by organic diagenesis of phosphorus deeper in the sediment most of the cores display a wide range of diagenetic characteristics below the immediate interfacial region but almost all show the precipitation signature near the interface this interface linked early diagenetic porewater environment for the precipitation of cfa explains many of the geochemical characteristics of phosphorites and provides a testable model to compare the modern phosphogenic analog with ancient phosphorite deposits two of the cores display very high solid phase phosphorus and fluoride contents reflecting the presence of apparently modern pelletal apatites