fertilizing potential of volcanic ash in ocean surface water the fertilization potential of newly erupted and well preserved ash from the 2000 hekla eruption in iceland was measured for the first time by flow through experiments as previously shown 1 the north atlantic ocean including the subarctic seas surrounding iceland is the largest net sink of the world s oceans for atmospheric co 2 owing to biological drawdown during summer 2 almost complete consumption of phosphate in chlorophyll rich areas of the north atlantic ocean might limit primary production and 3 in the southern pacific ocean and parts of the equatorial pacific ocean iron might limit primary production we found through laboratory experiments that volcanic ash exposed to seawater initially releases large amounts of adsorbed phosphate 1 7 mmol g 21 h 21 iron 37 0 mmol g 21 h 21 silica 49 5 mmol g 21 h 21 and manganese 1 7 mmol g 21 h 21 dissolution of acid aerosols adsorbed to the surface of the ash caused the high initial release of major and trace elements because of the instantaneous dissolution of adsorbed components when newly erupted volcanic ash comes in contact with the ocean surface water macronutrients and bioactive trace metals are released fast enough to become available to support primary production

from greenhouse to icehouse organic walled dinoflagellate cysts as paleoenvironmental indicators in the paleogene abstract dinoflagellates are an important component of the extant eukaryotic plankton their organic walled hypnozygotic cysts dinocysts provide a rich albeit incomplete history of the group in ancient sediments building on pioneering studies of the late 1970s and 1980s recent drilling in the southern ocean has provided a wealth of new dinocyst data spanning the entire paleogene such multidisciplinary studies have been instrumental in refining existing and furnishing new concepts of paleogene paleoenvironmental and paleoclimatic reconstructions by means of dinocysts because dinocysts notably exhibit high abundances in neritic settings dinocyst based environmental and paleoclimatic information is important and complementary to the data derived from typically more offshore groups as planktonic foraminifera coccolithophorids diatoms and radiolaria by presenting case studies from around the globe this contribution provides a concise review of our present understanding of the paleoenvironmental significance of dinocysts in the paleogene 65 25 ma representing earth s greenhouse icehouse transition this episode holds the key to the understanding of extreme transient climatic change we discuss the potential of dinocysts for the reconstruction of paleogene sea surface productivity temperature salinity stratification and paleo oxygenation along with their application in sequence stratigraphy oceanic circulation and general watermass reconstructions

constraining cretaceous subduction polarity in eastern pacific from seismic tomography and geodynamic modeling interpretation of recent mantle seismic images below the america ignited a debate on the cretaceous subduction polarity in the eastern pacific ocean the traditional view is that the massive vertical slab wall under eastern north america resulted from an eastward farallon subduction an alternative interpretation attributes this prominent seismic structure to a westward subduction of the north american plate against a stationary intraoceanic trench here i design quantitative subduction models to test these two scenarios using their implied plate kinematics as velocity boundary conditions modeling results suggest that the westward subduction scenario could not produce enough slab volume as seismic images reveal as is due to the overall slow subduction rate 2 5 cm yr the results favor the continuous eastward farallon subduction scenario which with an average convergence rate of 10 cm yr prior to the eocene can properly generate both the volume and the geometry of the imaged lower mantle slab pile the eastward subduction model is also consistent with most cretaceous geological records along the west coast of north america

the role of event beds in the preservation of organic carbon in fine grained sediments analyses of the sedimentological processes operating during deposition of the whitby mudstone formation toarcian lower jurassic preserved in northeast england abstract geologists have recently observed that source rocks commonly contain a wide variety of microfabrics including diminutive ripples and burrows the existence of these fabrics challenges the assumption that persistent bottom water anoxia and low energy conditions are necessary prerequisites for enhanced organic carbon preservation in these units in order to enhance our understanding of the depositional and diagenetic processes responsible for organic carbon preservation in these strata the lower jurassic whitby mudstone formation which contains mudstones with up to 14 2 total organic carbon has been investigated using optical electron optical and geochemical methods four thinly bedded mudstone lithofacies were identified a silt bearing clay rich mudstones b clay rich mudstones c clay calcareous nannoplankton and organic carbon bearing mudstones and d cement rich mudstones internally individual beds are typically sharp based and normally graded they are either laminated partially bioturbated or homogenized where depositional fabrics are preserved pellets silt lags ripple lamination shell pavements wave enhanced sediment gravity flows of fluid mud and organo minerallic aggregates have been observed the presence of up to 14 2 toc in units that are sharp based and normally graded suggests that mass flows possibly generated by storms likely influenced sedimentation during deposition of these mudstones the abundant organo minerallic fabrics in these units indicates that at least some of the organic carbon was delivered to the seafloor as marine snow aggregates that likely formed in the water column following phytoplankton blooms homogenization of bed tops indicates that between sediment delivery episodes an infauna was able to colonize the seafloor implying that the bottom waters were at least partly oxygenated during these intervals these fabrics suggest that during deposition of the whitby mudstone formation organic carbon was being preferentially preserved below regions of high primary organic production the close association between sharp based graded beds and organo minerallic aggregates indicates that large volumes of organic carbon were delivered episodically to the seafloor and that conditions at the sediment water interface were episodically dynamic here organic carbon is likely to have been preferentially preserved because the frequency of depositional events was sufficiently high to minimize both oxidant diffusion into the sediment and organic carbon mineralization while bottom water anoxia may have developed during the phytoplankton blooms it was unlikely to have been persistent because the microfabrics present indicate that there was sufficient time and oxygen available for an infauna to disrupt the sediment between deposition events

oceanographic and eustatic control of carbonate platform evolution and sequence stratigraphy on the cretaceous valanginian campanian passive margin northern gulf of mexico an integrated sequence stratigraphic study based on outcrop core and wireline log data documents the combined impact of cretaceous eustacy and oceanic anoxic events on carbonate shelf morphology and facies distributions in the northern gulf of mexico the diverse facies and abundant data of the comanche platform serve as a nearly complete global reference section and provide a sensitive record of external processes affecting cretaceous platform development regional cross sections across the shoreline to shelf margin profile provide a detailed record of mixed carbonate siliciclastic strata for the hauterivian to lower campanian stages ca 136 to 80 ma the study window on the slowly subsiding passive margin allows the stratigraphic response to external forcing mechanisms to be isolated from regional structural processes three second order supersequences comprised of eight composite sequences are recognized in the valanginian barremian the aptian albian and the cenomanian campanian the valanginian barremian supersequence transitioned from a siliciclastic ramp to carbonate rimmed shelf and is a product of glacial ice accumulation and melting as well as variable rates of mid ocean ridge volcanism the aptian albian supersequence chronicles the drowning and recovery of the platform surrounding oceanic anoxic events 1a and 1b the cenomanian campanian supersequence similarly documents shelf drowning following oceanic anoxic event 1d after which the platform evolved to a deep subtidal system consisting of anoxic dysoxic shale and chalk in the time surrounding oceanic anoxic event 2 each period of oceanic anoxia is associated with composite sequence maximum flooding termination of carbonate shelf sedimentation and deposition of condensed shale units in distally steepened ramp profiles composite sequences unaffected by oceanic anoxic events consist of aggradational to progradational shelves with an abundance of grain dominated facies and shallow subtidal to intertidal environments because they are products of eustacy and global oceanographic processes the three supersequences and most composite sequences defined in the south texas passive margin are recognizable in other carbonate platforms and published eustatic sea level curves

gravity driven sediment transport on the continental shelf implications for equilibrium profiles near river mouths an analytical model is developed for equilibrium bathymetric profiles off river mouths associated with the shoreward convex upward portion of subaqueous deltas and clinoforms the model builds on recent field results demonstrating that gravity driven flux of suspended mud is important on shelves provided that wave induced suspension of sediment supports the requisite turbid hyperpycnal layer because the maximum sediment load is determined by the critical richardson number the results are independent of the properties of the suspended mud or the bed the model assumes the equilibrium state to represent a balance between the supply of sediment by a river at the coast and the downslope bypassing of sediment to deep water within wave supported turbid near bed layers progressive seaward increases in bed slope across the convex shelf profile allow the attenuation of wave agitation with depth to be compensated for by a downslope increase in the contribution of gravity the model is consistent with shelf profiles off the mouths of the eel california ganges brahmaputra bangladesh waiapu new zealand po italy and rhone france rivers the equilibrium profile is predicted to be a function of wave climate and riverine sediment supply only with deeper and broader profiles associated with decreasing sediment supply increasing wave height and or increasing wave period

the trace metal content of recent organic carbon rich sediments implications for cretaceous black shale formation organic carbon rich sediments are enriched in several redox sensitive and stable sulfide forming trace metals tm and form an important sink in global tm cycles in today s ocean such sediments are deposited in coastal upwelling areas like those in the gulf of california off peru or off the namibian coast and euxinic basins like the black sea in an attempt to distinguish both environments by their specific tm patterns some important conclusions may be drawn 1 the tm enrichment seen in both environments broadly is rather similar 2 upwelling sediments are often enriched in cd and p and depleted in co and mn 3 sapropels have a tendency towards higher enrichments in ba and mo s re as cu ni sb and fe reflecting the strong sulfidation in an anoxic water column 4 upwelling systems cover a broad range of environmental settings where the steepness of the slope the proximity of h2s to the sediment seawater interface and the intensity of bio accumulation and regeneration play an important role for tm accumulation 5 the tm content of anoxic basins is mainly controlled by tm availability in the water column and sedimentation rate 6 enhanced bio productivity is the main switch turning an oxygenated into an anoxic environment cretaceous black shales oae 2 exhibit tm signatures of both coastal upwelling areas and sapropels the strong enrichments in cd mo tl v cu ni bi and sb demonstrate that bio accumulation and presence of h2s in the water column and associated sulfidation processes persisted during this time interval in large parts of the proto atlantic the usefulness of ba as a paleoproductivity proxy is obscured by diagenesis the extreme accumulation in ag and zn requires either an additional tm source for instance hydrothermal input or a different tm seawater composition during the cretaceous the geochemical data suggest that the major driving force for the widespread occurrence of c t black shales seems to be the increase in volcanic activity and associated co2 input throughout the cretaceous the ocean atmosphere system operated in a mode different from today during this time interval after conversion of the nutrient co2 into organic matter the system switched back into the normal operational mode

the cenomanian turonian eagle ford group of south texas insights on timing and paleoceanographic conditions from geochemistry and micropaleontologic analyses abstract the interbedded organic rich marls and limestones of the eagle ford group of south texas were deposited on the shelf of the central texas platform during the upper cenomanian through the turonian micropaleontological analyses of thin sections and residue samples from subsurface cores taken in atascosa and karnes counties yielded 13 biostratigraphic datums which were integrated with calcareous nannofossil datums stable carbon isotopic and bulk inorganic geochemical analysis to gain an understanding of the paleoceanographic conditions of the study area and their relationship to regional and global events the paired thin section residue sampling was necessitated by poor recovery of planktonic foraminifera in washed samples which were however abundant in most thin sections lower eagle ford marls were deposited under euxinic conditions produced by a stratified water column periodic enhanced water column mixing increased oxygen levels and surface water primary productivity which promoted calcite diagenesis and generation of limestones containing calcispheres and radiolaria an oxygenated bottom water mass entered the basin in the uppermost cenomanian prior to the onset of oceanic anoxic event oae 2 causing a spike in benthic foraminiferal diversity and decreasing preservation of organic matter although the lower portion of the upper eagle ford is age equivalent to oae2 as indicated by positive shift in 13corg it contains less organic matter and evidence of more oxygen than the lower eagle ford so deposition of the eagle ford black shales is not contemporaneous to oae2

accumulation of organic carbon rich sediments in the late jurassic and cretaceous atlantic ocean a synthesis abstract organic carbon rich sediments black shales were deposited at some 40 deep sea drilling project dsdp sites in the atlantic ocean during late jurassic and cretaceous times in order to reconstruct the depositional environments of black shale formation we have studied in detail changes in the occurrence of black shales as well as the type and amount of organic matter in relation to changes in paleogeography paleooceanic circulation and paleoclimate we have calculated accumulation rates of marine and terrigenous organic carbon and combined these with organic carbon content sedimentation rate relationships to obtain information about paleoenvironments main factors causing the preservation and accumulation of organic carbon are 1 the supply of terrestrial organic matter 2 the supply of marine organic matter 3 the oxygenation of the deep water and 4 the bulk sedimentation rate changes in the importance of these different factors and changes in the interrelationships among them determine the complex system of black shale formation and their cyclic variations increased supply of terrestrial organic matter due to increased river discharge and humid climate in northeast america southwest europe and south africa were important in the hauterivian albian northwest and northern northeast atlantic and in the late jurassic aptian south atlantic in the latter anoxic deep water conditions due to restricted circulation in the nascent largely isolated basin as well as higher oceanic productivity may have reinforced the high preservation rates of marine organic matter during that time off northwest africa higher flux rates of marine organic matter were recorded in areas of higher productivity which may have been caused by fluvial nutrient supply during the hauterivian and by intensified upwelling during albian turonian times in general the depositional environment was oxygenated and the content of marine organic matter was a function of the sedimentation rate furthermore at some places redeposition by turbidity currents or slumps may have been important for the accumulation of organic matter in the deep sea basins the only episode of widespread anoxia in the western and eastern basins of the north atlantic may have occurred in the cenomanian turonian when high amounts of marine organic matter were also preserved in areas of low productivity and low sedimentation rates

phanerozoic large igneous provinces lips heatt haline euxinic acidic thermal transgression episodes and mass extinctions abstract the phanerozoic consists of three mutually exclusive climate states icehouse greenhouse and hothouse the greenhouse is the default state representing 70 of the phanerozoic it is characterized by a weak thermal mode pole driven deep water formation with little or no continental sea ice and weakly oxic cool water sinking near the poles nitrogen limitation characterizes greenhouse oceans in which ammonium may be the dominant bioavailable form of nitrogen the steady state greenhouse default must be forced to produce either of the other two states continent continent collision produces the intense chemical weathering that draws down atmospheric co2 and results in the icehouse state that comprises 20 25 of the phanerozoic icehouses have ice caps in contact with the ocean that produce icebergs and foster sea ice formation sea ice formation fills the ocean with highly oxic phosphorus limited icewater except for a thin layer of warm surface water in the tropics of the 23 most conspicuous mass extinctions of the phanerozoic including the late ediacaran 4 are associated with ice volume related regressions and 3 are problematic we suggest that the other 16 mass extinctions occurred when greenhouse climate was forced to hothouse climate large igneous provinces lips can trigger the heatt haline euxinic acidic thermal transgression mechanism which can force greenhouse climate to a hothouse climate state the rapid voluminous co2 emissions of lips cause a series of events that result in very slow but pronounced haline mode circulation mid latitude driven deep water formation that produces warm saline bottom water at very dry hot subtropical and middle latitudes this water upwells at the poles causing warm and moist equable climate hothouse development promotes deep sea anoxia that is generated in concert with co2 buildup and warming the spread of anoxia favors reduced nitrogen over nitrate and limited iron dust curtails nitrogen fixation this leads to dominance of primary productivity by primitive green algae and or cyanobacteria progression to euxinia that reaches the photic zone severely curtails primary productivity via poisoning even as availability of usable nitrogen plummets the result is eukaryotic mass extinction we suggest that the 16 phanerozoic mass extinctions referred to above resulted at least in part from the heatt process evidence for this relationship at 11 of the most severe extinctions is convincing data sets for the other 5 are strongly suggestive of heatt related mass extinction but do not yet have enough documentation to reliably characterize them as heatt episodes

origin of limestone marlstone cycles astronomic forcing of organic rich sedimentary rocks from the cenomanian to early coniacian of the cretaceous western interior seaway usa abstract we present an integrated multidisciplinary study of limestone marlstone couplets from a continuously cored section including parts of the upper buda limestone the entire eagle ford group boquillas formation and lower austin chalk from the shell iona 1 research borehole texas usa which provides a 8 million year myr distal clastic sediment starved intrashelf basin record of the early cenomanian to the earliest coniacian stages results show that despite variable yet minimal diagenetic overprints several unambiguous primary environmental signals are preserved and support greater water mass ventilation and current activity promoting increased silica carbonate productivity during the deposition of limestone beds compared to deposition of marlstone beds which reflect greater organic matter productivity and preservation furthermore our astronomical analyses demonstrate that the limestone marlstone couplets in the iona 1 core reflect climatic forcing driven by solar insolation resulting from integrated milankovitch periodicities in particular we propose that obliquity and precession forcing on the latitudinal distribution of solar insolation may have been responsible for the observed lithological and environmental variations through the cenomanian turonian and coniacian in this mid latitude epicontinental sea setting our data also suggests that rhythmic lithological alternations deposited in greenhouse periods in general may simply reflect climate driven cycles related to earth sun dynamics without the need to invoke significant sea level variations

geometry of upper cretaceous bentonite beds implications about volcanic source areas and paleowind patterns western interior united states four bentonite beds near the cenomanian turonian stage boundary ca 90 ma can be traced through much of the western interior of the united states isopach maps constructed for these bentonite beds indicate that volcanic source areas were positioned both northwest and southwest of the central u s western interior basin and also indicate both easterly and southeasterly paleowind directions volcanism of this age has not been reported previously in the southern source area

foraminiferal and nannofossil paleoecology and paleoceanography of the cenomanian turonian eagle ford shale of southern texas article i nfo the uppercretaceous of central texas isdominated by a broad shallow carbonate platformcalled thecomanche platform that occupies an important gateway between the epeiric western interior seaway wis of north america to the open marine gulf of mexico tethys we investigated the cenomanian turonian eagle ford shale on and adjacent to the comanche platform to determine whether the eagle ford shale has an affinity with the western interior and if so determine where the transition from western interior to open ocean is located we were also interested in the relationship if any between the organic rich facies of the eagle ford and oceanic anoxic event 2 oae2 our work is based on quantitative foraminiferal population counts and associated sedimentary particles including inoceramid prisms sand glauconite and pyrite grains calcareous nannofossil assemblages carbon isotopes and total organic carbon toc from three sites across a range of paleowater depths an outcrop in lozier canyon in terrell county west of langtry tx an outcrop at bouldin creek outside of austin tx and swift energy s fasken a 1h core in webb county tx the highest toc intheeagle ford occurs beforethe onset of oae2 6 at loziercanyon 7 atboth bouldincreek and the fasken core and then declines steadily through the rest of the section except for a small increase at the end of oae2 at lozier and a fairly large post oae2 increase at bouldin creek nannofossil paleoproductivity indicators zeugrhabdotusand biscutum track tocatbouldincreekandinthefaskencoreanddisplaysimilar trends to those observed inthe western interior seawayto the north benthic foraminiferalabundances increase astoc decreasesand the lithology shifts from laminatedblack shale to bioturbatedlight gray shale low oxygen tolerant infaunal neobulimina spp appear first and gradually increase in abundance epifaunal benthics appear soon after this oxygenation trend continues through the oae2 interval and the upper eagle ford contains a diverse epi and infaunal benthic foraminiferal assemblage and macrofossil assemblage this trend of decreasing toc and nannofossil paleoproductivity indicators coupled with increasing benthic foraminiferal abundance and diversity and seafloor oxygenation corresponds to rising sea level based on foraminiferal and nannofossil events toc trends and changes in lithology both platform sites have a strong affinity with the western interior with lozier canyon being the most similar the fasken core bears all the characteristics of an open ocean site except for the fact that peak toc occurs before oae2 this suggests that the oceanographic boundary between wis and tethys can be placed on the edge of the comanche platform productivity was likely driven by bathymetry induced upwelling caused by restriction between the wisand tethys during times of low sea level as sea level rose upwelling diminished and productivity decreased this explains why the fasken core adjacent to the platform margin and in the center of this upwelling zone displays the same toc trends as the platform sites organic carbon content in the seaway was controlled by stratification and enhanced preservation but this was also reduced by rising sea level which is why the two areas show parallel trends

catastrophic overturn of the earth s mantle driven by multiple phase changes and internal heat generation the effects of phase changes and strong internal heat generation may combine to bring about brief but extremely intense episodes of rapid thermal convection in the earth s mantle numerical calculations using realistic thermodynamic properties for the exothermic olivine spinel and endothermic spinel perovskite magnesiowustite phase transitions suggest the transition region of the earth s mantle may act as a capacitor for subducting slabs slab material accumulates in the transition region until a threshold level of thermal buoyancy is reached and is then rapidly discharged into the lower mantle in my calculations this occurs as a catastrophic burst of convection lasting 10 myr with elevated heat transfer rates lasting 100 myr such episodes may be analogs to superplume activity which has been hypothesized to give rise to an intense episode of intra plate volcanism and stabilize the geodynamo against reversals the topography on the two phase change boundaries is found to be negatively correlated with the correlation becoming more negative during periods of rapid convection furthermore the results of this study suggest the transition region of the earth s mantle could be 250 k cooler on average and consequently more viscous than the surrounding mantle

calcareous dunes of the united arab emirates and noah s flood the postglacial reflooding of the persian arabian gulf abstract aeolian dunes cover most of the united arab emirates and a large part of the eastern arabian peninsula although these sands as well as older aeolianites are largely composed of quartz there is a high percentage of detrital carbonate in them south of the persian arabian gulf for more than 40 km this percentage decreases inland these carbonate grains consist mainly of marine bioclastic fragments and calcareous ooids and were derived from the floor of the persian gulf which was exposed during low sea level of the last glacial period the postglacial rise in sea level rapidly reflooded the floor of the persian gulf cutting off the source for these aeolian sediments between 12 and 6 ka the sea transgressed more than 1000 km inundating the extended route of the tigris euphrates river and forcing people living on the exposed floor of the gulf to abandon their settlements because of the varying rate of eustatic sea level rise these waters at times flooded across the flat floor of the persian gulf at more than a kilometer per year we proposed that the stories of a great flood recorded in the bible as noah s flood and in babylonian history on clay tablets excavated in the tigris euphrates delta as the epic of gilgamesh are a record of this rapid postglacial flooding of the floor of the persian gulf

the role of oceanic plateau subduction in the laramide orogeny the cause of the laramide phase of mountain building remains uncertain conceptual models implicate the subduction of either ocean ridges or conjugates of the buoyant hess or shatsky oceanic plateaux independent verification of these models has remained elusive because the putative ridges or plateaux are no longer at the earth s surface inverse convection models have identified two prominent seismic anomalies on the recovered farallon plate here we combine inverse convection models with reconstructions of plate motions to show that these seismic anomalies coincide palaeogeographically with the restored positions of the shatsky and hess conjugate plateaux as they subducted beneath north america specifically the distribution of laramide crustal shortening events tracked the passage of the shatsky conjugate beneath north america whereas the effects of the hess conjugate subduction were restricted to the northern mexico foreland belt we propose that continued subduction caused the oceanic crust to undergo the basalt eclogite phase transformation during which the shatsky conjugate lost its extra buoyancy and was effectively removed increases in slab density and coupling between the overriding and subducting plates initially dragged the surface downward followed by regional scale surface rebound we conclude that laramide uplift resulted from the removal rather than emplacement of the shatsky conjugate

sedimentation in the tethyan pelagic realm during the cenomanian monotonous settling or active redistribution sea bottom processes of the pelagic realm are still not completely understood and represent an intriguing subject this paper focuses on the relationships between normal settling processes redistribution of sediments and oceanographic parameters in a pelagic setting during the cenomanian five key tethyian localities in the cenomanian umbria marche and belluno basins have been studied in order to understand the interplay among sea bottom processes that acted on the sea floor the dataset consists of the mm scale sedimentological description of the sections complemented by microfacies analysis on selected samples different sedimentological indications such as presence of intraclasts lined forams pervasive plane parallel lamination suggest a continuous reworking under action of bottom currents with varying intensity and direction all the identified facies are here illustrated in detail and organized in a comprehensive schematic facies framework the facies matrix that leads to recognize two depositional facies suites the settling dominated and the traction current dominated under different oxygenation conditions our results suggest that settling of biogenic and inorganic particles represents the main source of pelagic sediments but not the unique depositional process under the action of sea bottom currents of different intensity sediments are continuously redistributed on the sea floor all the collected evidences contribute to the proposal of a comprehensive depositional model for these reworked and redistributed fine grained sediments that represent true calcareous pelagic contourites the model suggests that the identified traction related facies can be used as a proxy for bottom current intensity and indirectly as an indicator of changing ventilation regimes at the sea floor through time

sedimentation rate dilution preservation and total organic carbon some results of a modelling study abstract a modelling exercise was undertaken to evaluate the positive preservational and negative diluent effects of sedimentation rate sr on the total organic carbon toc content of marine sediments and to use multiple regression analysis of modern data to predict toc data presented show the predicted marine toc using the carbon burial efficiency be versus sr relationship of betts and holland betts j n holland h d 1991 the oxygen content of ocean bottom waters the burial efficiency of organic carbon and the regulation of atmospheric oxygen palaeogeography palaeoclimatology palaeoecology global and planetary change section 97 5 18 calculated for a range of sr water depths primary productivities and four fixed be values the results suggest that the preservation effect of sr only enhances toc at 5 cm ka in oxic regimes after which dilution occurs if carbon supply is held constant above 35 cm ka there is no appreciable difference in toc regardless of whether the sea floor is anoxic or not below 10 cm ka there is a strong divergence in oxic and anoxic toc values observed positive correlations of sr and toc at 5 cm ka are largely an artefact of including sites from shallower depths and or higher productivities multiple regression analysis mra of modern marine sediment data suggests that once re scaled to allow for their non linear effect dissolved oxygen values may be a significant additional variable in determining the toc predicting an approximately 2 5 4 0 times higher toc in anoxic facies compared with fully oxic ones 4 ml l dissolved oxygen all other things being equal the mra also indicates a generally negative partial correlation between carbon delivery flux and be in modern sediments producing a significant moderating effect on the predicted toc