lead mobilization during tectonic reactivation of the western baltic shield abstract lead isotope data from sulfide deposits of the western part of the baltic shield define mixing lines in the 206 pb 204 pb 207 pb 204 pb diagram lead from two types of sulfide deposits have been investigated 1 1 exhalative and volcanogenic deposits that are syngenetic with their host rocks 2 2 vein deposits the syngenetic deposits locally show a very wide range of lead isotopic compositions that reflect a variable addition of highly radiogenic lead while the vein deposits although they have radiogenic lead isotopic compositions exhibit only limited isotopic variations in different provinces of the shield both types of deposits fall on the same lead mixing array the slope of the lead mixing lines varies as a function of the age of basement rocks and the age of the tectonic event which produced the lead mobilization and therefore relates the source rock age with the age of lead mobilization calculated mixing ages fall into several short time periods that correspond either to orogenic events or to major phases of continental rifting the orogenic events are the ca 360 430 ma caledonian ca 900 1100 ma sveconorwegian and the ca 1800 1900 ma svecofennian orogenic cycles the rifting events correspond to the formation of the ca 280 ma oslo rift and the ordovician ca 450 ma graben system in the area of the present gulf of bothnia each mixing age indicates that lead was mobilized probably as a consequence of mild thermal disturbances and that the crust was permeable to lead migration the data show that the geographic distribution of sulfide deposits with highly radiogenic lead isotopic compositions coincides with old graben systems orogenic belts and orogenic forelands on the baltic shield the ages of vein deposits and their geographic distribution demonstrate multiple tectonic reactivation of the interior of the baltic shield in response to orogenic events at its margin

dating the oldest terrestrial rocks fact and fiction abstract this paper is a review of well documented geochronological and related isotopic evidence for the age and total crustal residence time of the oldest known terrestrial rocks mainly using rb 1bsr sm 1bnd and u 1bpb decay schemes the oldest known stable sialic crust of true continental character predominantly composed of calc alkaline orthogneisses was produced during major mantle differentiation some 3 7 3 5 ga ago and is represented on several continents enclaves of older supracrustal rocks as well as a major remnant of a volcano sedimentary sequence of greenstone belt affinity dated at 3 8 ga are preserved within the surrounding gneisses in southern west greenland recent ionmicroprobe evidence for 4 1 ga old detrital zircon grains in a younger early archaean metasedimentary sequence in western australia is also discussed several cases are reviewed where claims for early archaean 3 4 ga dates are believed to be erroneous and to result from oversimplistic and incorrect interpretation of isotopic data some of the geological and geochemical mechanisms which have given rise to claims for spuriously old sm 1bnd u 1bpb and pb pb dates are critically discussed to supplement published data we present several new sets of whole rock sm 1bnd and pb pb isotopic data from west greenland labrador zimbabwe and eastern india relevant to the overall topic of this review

tectonic evolution of northeastern siberia and adjacent regions abstract previous models for the tectonic evolution of northeastern siberia have proposed the existence of a kolyma plate composed of the kolyma and omolon massifs of presumed precambrian age lithologic similarities between the siberian platform and the cherskiy mountains and the presence of oceanic and island arc type deposits in the kolyma indigirka interfluve suggest that no such plate exists the eastern margin of the siberian plate is suggested to lie along a line between the ulakhan sis range the alazeya uplift and the arga tas range the cherskiy mountains and the verkhoyansk fold belt are parts of the siberian plate the paleozoic deposits of the omolon massif are unlike those found in the cherskiys or siberia paleomagnetic data from the omolon massif are discordant from data from siberia it is suggested that the omolon massif represents a microplate which accreted onto siberia in the jurassic ophiolites in central chukotka are of the same emplacement age as in the western brooks range and may have been emplaced at the initiation of the rotation of arctic alaska geometric and limited stratigraphic data suggest that the east siberian sea may be floored by oceanic crust left by an incomplete closure between arctic alaska siberia and omolon the tectonic position of the prikolymsk massif remains ambiguous

magma sources for mesozoic anorogenic granites of the white mountain magma series new england usa the magma sources for granitic intrusions related to the mesozoic white mountain magma series in northern new england usa are addressed relying principally upon nd isotopes many of these anorogenic complexes lack significant volumes of exposed mafic lithologies and have been suspected of representing crustal melts sm nd and rb sr isotope systematics are used to evaluate magma sources for 18 felsic plutons with ages ranging from about 120 to 230 ma the possibility of crustal sources is further examined with analyses of representative older crust including paleozoic granitoids which serve as probes of the lower crust in the region multiple samples from two representative intrusions are used to address intrapluton initial isotopic heterogeneities and document significant yet restricted variations 1 in end overall mesozoic granite plutons range in end t from 4 2 to 2 3 with most 2 to 0 and in initial 87sr 86sr from 0 7031 to 0 709 the isotopic variations are roughly inversely correlated but are not obviously related to geologic geographic or age differences older igneous and metamorphic crust of the region has much lower nd isotope ratios with the most radiogenic paleozoic granitoid at end 180 ma of 2 8 these data suggest mid proterozoic separation of the crust in central northern new england moreover the bulk of the mesozoic granites cannot be explained as crustal melts but must have large mantle components the ranges of nd and sr isotopes are attributed to incorporation of crust by magmas derived from midly depleted mantle sources crustal input may reflect either magma mixing of crustal and mantle melts or crustal assimilation which is the favored interpretation the results indicate production of anorogenic granites from mantle derived mafic magmas

nd isotopic evidence for juvenile crust in the carolina terrane southern appalachians nd isotopic analyses of whole rock samples from the older portion of the carolina terrane one of the largest terranes in the appalachian orogen demonstrate that part of this terrane is composed of juvenile mantle derived crust these data suggest that the terrane may not have originally been built upon old evolved basement material but rather may have been built upon oceanic crust a recent study by other workers demonstrates a more crustally evolved nd isotopic signature for younger components of the carolina terrane these data may indicate that the terrane interacted with evolved crust at a later time possibly by amalgamation with a more evolved crustal fragment before final accretion to laurentia rather than indicating a primary old basement a juvenile nature for the older portion of the terrane contrasts with models that suggest it is an evolved crustal fragment that formed in a continental margin setting a scenario proposed to explain the high proportion of felsic volcanic rocks within the terrane it is herein suggested that carolina is a chemically evolved but isotopically juvenile crustal fragment because it remained in an oceanic setting for an unusually long time in this regard the carolina terrane is similar to some of the large accreted terranes in the canadian cordillera such as wrangellia and alexander the presence of juvenile crust in the carolina terrane documents that at least part of the southern appalachian orogen is not composed solely of reactivated pre existing continental crust the importance of this part of the orogen in terms of the volume of juvenile phanerozoic crustal material in north america may be larger than previously thought however until additional major appalachian terranes have been isotopically characterized the volume of juvenile crust in the whole orogen remains unknown the isotopic make up of a terrane can be an important aspect of terrane analysis as different terranes may have significantly different isotopic compositions while even widespread pieces of a single terrane should have very similar isotopic characteristics the nd isotopic data for the carolina terrane form the beginning of an isotope database for terranes in the southern appalachians

isotopic composition of neodymium in waters from the drake passage the isotopic composition of neodymium has been determined in seawaters from the drake passage the antarctic circumpolar current which controls interocean mixing flows through this passage the parameter e nd 0 which is a function of the ratio of neodymium 143 to neodymium 144 is found to be uniform with depth at two stations with a value which is intermediate between the values for the atlantic and the pacific and indicates that the antarctic circumpolar current consists of about 70 percent atlantic water cold bottom water from a site in the south central pacific has the neodymium isotopic signature of the waters in the drake passage by using a box model to describe the exchange of water between the southern ocean and the ocean basins to the north together with the isotopic results an upper limit of approximately 33 million cubic meters per second is calculated for the rate of exchange between the pacific and the southern ocean concentrations of samarium and neodymium were also determined and found to increase approximately linearly with depth these results suggest that neodymium may be a valuable tracer in oceanography and may be useful in paleo oceanographic studies

neodymium isotopes as tracers in marine sediments and aerosols north atlantic nd and sm concentrations and nd isotopic compositions were measured on the detrital fraction of deep sea surface sediments and on aerosols sampled over the north atlantic and mediterranean sea the data expressed asend 0 and as model ages ranged from 14 5 end 0 4 9 and from 0 01 to 2 21 ga respectively two areas where the sediments contain relatively less radiogenic nd are to the west off north africa and eastward of the canadian shield this distribution is consistent with other tracers in suggesting that a significant fraction of the sediments are derived from aeolian material transported by major wind systems saharan dust transported in the equatorial trade winds belt and north american soil material transported in the latitudes of the westerlies between these aeolian dominated belts along an axis from the azores to gibraltar and the mediterranean lies a zone of more radiogenicend 0 values in sediments and aerosols influenced by the recent volcanism of this region previously reported distributions of nd isotopes in bottom formed iron manganese crusts and coatings are similar to distributions of nd isotope values in detrital sediments and aerosols this suggests that the detrital fraction has undergone partial dissolution and desorption in the water column and or in the pore waters of near surface sediments and that a significant proportion of nd in the authigenic ferromanganese phases is derived from this source and may therefore not represent strictly dissolved seawater nd isotope ratios useful as watermass tracers

sediments in arctic sea ice implications for entrainment transport and release despite the arctic sea ice cover s recognized sensitivity to environmental change the role of sediment inclusions in lowering ice albedo and affecting ice ablation is poorly understood sea ice sediment inclusions were studied in the central arctic ocean during the arctic 91 expedition and in the laptev sea east siberian arctic region expedition 1992 results from these investigations are here combined with previous studies performed in major areas of ice ablation and the southern central arctic ocean this study documents the regional distribution and composition of particle laden ice investigates and evaluates processes by which sediment is incorporated into the ice cover and identifies transport paths and probable depositional centers for the released sediment in april 1992 sea ice in the laptev sea was relatively clean the sediment occasionally observed was distributed diffusely over the entire ice column forming turbid ice observations indicate that frazil and anchor ice formation occurring in a large coastal polynya provide a main mechanism for sediment entrainment in the central arctic ocean sediments are concentrated in layers within or at the surface of ice floes due to melting and refreezing processes the surface sediment accumulation in central arctic multi year sea ice exceeds by far the amounts observed in first year ice from the laptev sea in april 1992 sea ice sediments are generally fine grained although coarse sediments and stones up to 5 cm in diameter are observed component analysis indicates that quartz and clay minerals are the main terrigenous sediment particles the biogenous components namely shells of pelecypods and benthic foraminiferal tests point to a shallow benthic marine source area apparently sediment inclusions were resuspended from shelf areas before and incorporated into the sea ice by suspension freezing clay mineralogy of ice rafted sediments provides information on potential source areas a smectite maximum in sea ice sediment samples repeatedly occurred between 81 n and 83 n along the arctic 91 transect indicating a rather stable and narrow smectite rich ice drift stream of the transpolar drift the smectite concentrations are comparable to those found in both laptev sea shelf sediments and anchor ice sediments pointing to this sea as a potential source area for sea ice sediments in the central arctic ocean sea ice clay mineralogy is significantly different from deep sea clay mineral distribution patterns the contribution of sea ice sediments to the deep sea is apparently diluted by sedimentary material provided by other transport mechanisms

remobilisation of the continental lithosphere by a mantle plume major trace element and sr nd and pb isotope evidence from picritic and tholeiitic lavas of the noril sk district siberian trap russia the late permian to early triassic siberian traps have been sampled by drill core core sg 9 and from surface exposure section 1f in the noril sk region of the siberian platform russia combined major trace element and nd sr and pb isotope data on selected samples through the siberia trap offer new chemostratigraphic criteria for the identification and characterisation of two fundamentally different magma types and 9 of the 11 formations of lava developed near noril sk a lower sequence of sub alkalic basalts tholeiites and picritic basalts upwards these are the ivakinsky syverminsky and gudchichinsky formations are overlain by an upper sequence of picritic basalts and tholeiites interbedded with tuffs upwards these are the khakanchansky tuklonsky nadezhdinsky morongovsky mokulaevsky and kharayelakhsky formations the gudchichinsky and tuklonsky formations contain both picritic and tholeiitic lavas the tuklonsky formation tholeiites and picrites have moderate gd yb 1 6 1 8 low tio2 0 45 0 95 wt a significant negative ta and nb anomaly nb la 0 42 0 57 and unradiogenic nd nd chur to 4 6 in contrast both the gudchichinsky formation tholeiites and picrites have high gd yb 2 3 3 1 and tio2 1 2 2 3 wt no significant nb or ta anomaly nb la 0 8 1 1 and radiogenic nd nd chur to 7 3 the low ti and nb la high la sm and unradiogenic nd isotope signatures of the picritic tuklonsky formation lavas and the tholeiitic lavas of the upper sequence are characteristic of magmas strongly influenced by material from the continental lithosphere whereas the high ti and nb la low la sm and radiogenic nd isotope signatures of the lower sequence are more comparable to deeper asthenospheric mantle plume generated lavas similar to oceanic island basalts the lavas overlying the tuklonsky formation have mg numbers of 0 63 to 0 68 and are more evolved than the tuklonsky mg number 0 62 and have more radiogenic nd chur tuklonsky 0 03 to 4 66 mokulaevsky 0 60 to 1 61 but have many of the incompatible trace element features of the tuklonsky sky type magma these lavas show a progressive upwards decline in sio2 55 49 wt la sm 4 6 2 0 and ur sr 67 to 13 which has previously been attributed to a decrease in the proportion of crustal material contributed to the magma this paper explores and alternative model where a component of the crustal contribution might be derived from within an ancient region of the mantle lithosphere as recycled sediment rather than from the overlying continental crust

lead isotopic composition of hercynian granitic k feldspars constrains continental genesis lead isotope compositions have been determined in many k feldspars from granitic rocks emplaced during the variscan hercynian orogeny sensu lato around 300 myr in various parts of europe and the eastern us the ratios show a regular geographical pattern with contours arched around southern france and parallel to the atlantic coast of the us this distribution parallels predriftpalaeogeographical zones during the palaeozoic the lead isotope pattern of variscan granitic rocks is similar to that of some orogenic volcanic suites but is better explained by crustal melting than by an hercynian mantle crust material mixing the continental crust from these areas must be older than 3 000 myr large scale fluid circulation in the crust during orogenic processes apparently explains the observed geographical patterns of lead isotopes

a lead isotopic study of circum antarctic manganese nodules abstract lead isotope ratios in manganese nodules from the circum antarctic ocean display systematic geographical variations eastward in the direction of current movement from south of australia they progressively decrease in the pacific sector and into the western atlantic sector until 30 w from this longitude lead isotope ratios increase in the eastern atlantic sector and reach their highest values in the indian sector near 110 e south of western australia they abruptly decrease these two lead isotope domains correspond closely to the circum antarctic neodymium isotope domains previously recognized by albarede and goldstein 1992 however the intraocean isotopic variations are much clearer for pb than nd reflecting the shorter oceanic residence time of pb 102 y compared with nd 103 y and confirming that pb is a much more sensitive marine tracer throughout the circum antarctic ocean the lead isotopic changes follow the pattern of present day oceanic circulation the pb shows an overall continental signature which is strongest in the indian sector the most probable candidate as the source of the continental signal is north atlantic deep water nadw which enters the circum antarctic in the south atlantic as nadw mixes with circumpolar water lead isotope ratios increase eastward in the indian sector reflecting progressive loss of the pacific derived pb signal the abrupt decrease of lead isotope ratios between the indian and pacific sectors appears to be a consequence of addition of pacific seawater through the pacific lead isotope ratios gradually decrease eastward approaching values of east pacific rise metalliferous sediments ocean ridge basalts and south pacific mn nodules this trend results from an increasing influence of pacific ocean water containing a component derived from pacific volcanism the pacific signature persists into the argentine basin in the southwest atlantic ocean reflecting significant input of water from the drake passage northward into the atlantic the pacific pb component is seen in the atlantic and indian oceans near southern africa as well as in the atlantic and indian sectors of the circum antarctic lead and neodymium isotopes correlate in the atlantic indian sectors but not in the pacific sector reflecting differences in residence times and modes of water mass mixing the renewal of circum antarctic water occurs on a timescale which is short compared to the residence time of nd but long compared to pb as a result dissolved pb is subject to considerable changes over the timescale of circumpolar current movement while nd is less easily affected nadw is added locally in the south atlantic and moves eastward as a water mass as nadw mixes with circumpolar water cpw through the indian sector changes affecting nd pb in nadw and cpw occur in tandem and neodymium and lead isotopes are correlated through the pacific sector gradual addition of pacific seawater occurs over a large region and nd pb relationships are not coupled because simple isotopic mixing systematics are not conserved there neodymium and lead isotopes vary independently the consistency of lead isotope variations with present day ocean bottom water circulation is remarkable considering that the mn nodules as sampled reflect the integrated flux of pb over 105 106 y the oceanic mixing time is 103 y the residence time for pb is 102 y and the circulation time of the circumantarctic ocean is 30 y processes occurring over such different timescales can show such a relationship only if the system is stable over the longest time interval thus on average element sources and ocean circulation through the pleistocene have been similar to the present day despite significant perturbations during glacial periods

sr and nd isotopic analysis of phosphorite sedimentation through one miocene high frequency depositional cycle on the north carolina continental shelf abstract a well developed seismic litho and biostratigraphic data base with good models for the formation and deposition of phosphate rich sediments exist for the upper cenozoic sediments on the north carolina continental margin this provides a unique opportunity to evaluate the potential of utilizing strontium and neodymium isotopic analyses to help unravel a complex genetic history of phosphate formation and deposition thirty one samples from three vibracores in onslow bay supplied hand picked concentrate subsamples of five phosphate grain types and thirty one concentrate subsamples of phosphate peloids for stratigraphic analysis all subsamples were analyzed for their sr isotope composition while only thirteen were analyzed for nd isotopes the 31 peloid samples represent three different stratigraphic units and include 1 holocene surficial sands with highly variable concentrations and types of reworked phosphate 2 pleistocene moldic carbonates with minor concentrations of black peloidal phosphate and 3 miocene mid burdigalian frying pan sequence unit 1 fps 1 of the pungo river formation with very high concentrations of multiple types of phosphate grains that decrease upsection and change grain types with changing lithofacies the latter unit represents deposition during one high frequency sea level cycle stratigraphic analysis utilized one grain type phosphate peloids for comparative purposes with the depositional model of riggs and mallette 1990 the sr and nd data cluster into significant categories that are coincident with these three major stratigraphic units sr and nd isotope compositions of selected phosphate grains from three phosphate rich depositional sequences are utilized to 1 date the initial miocene transgression of unit fps 1 of the pungo river formation 2 decipher processes of formation and deposition of major phosphate grain types through one miocene sea level cycle including the processes of in situ formation versus reworking 3 develop a sr and nd chronostratigraphy for evaluating changing patterns of continental margin sedimentation through high frequency depositional cycles 4 determine effects of reworking and weathering on the isotope signals between miocene pleistocene and holocene sediments 5 evaluate the suitability of utilizing sr and nd isotopes for detailed chronostratigraphic analysis of phosphorite sedimentation and 6 refine our understanding of the upper cenozoic evolutionary history of north carolina s continental margin

stratigraphy sedimentology chronology and palaeohydrology of quaternary lacustrine deposits at madigan gulf lake eyre south australia abstract madigan gulf is a large bay at the southern end of lake eyre north a major ephemerally flooded playa in arid central australia at the southwestern margin of a vast 1 300 000 km2 internal drainage basin the stratigraphy and chronology of the quaternary sequence in the gulf is described from 8 cores and a cliff exposure at the gulf margin a number of depositional environments are recognised and their distinctive sedimentary components are described facies recognised include deep and shallow water lacustrine environments dominated by surface water processes and dry or ephemerally flooded playa environments dominated by groundwater controlled processes sedimentary components include terrigenous clastics from river inflow and shoreline erosion carbonates of detrital inorganic or biological origin and gypsum and halite evaporites carbonates and gypsum evaporites precipitated within the basin are frequently reworked as clastic components the establishment of a preliminary chronology for the sequence by the application of thermoluminescence uranium thorium disequilibrium amino acid racemization and radiocarbon dating techniques has allowed a reconstruction of the last 130 ka of lake eyre palaeohydrology the wettest phase occurred during the last interglacial early in oxygen isotope stage 5 when an enlarged lake eyre was up to 25 m deep subsequently there has been a number of dry periods separating successively less effective wet phases culminating in the deposition of a substantial halite salt crust around the time of the glacial maximum the dry interludes are characterised by deflation of salts and sediment from the basin a process controlled by lowering of the watertable the record from madigan gulf demonstrates the dramatic and repetitive impact of lake deflation on the quaternary record of lake eyre in the early holocene a minor but mostly perennial lacustrine event was terminated at about 3 4 ka when the modern ephemeral playa regime was established the major catchment of lake eyre is located in the monsoon watered areas of northern australia as demonstrated by large floodings of the modern ephemeral regime major lacustrine episodes must indicate enhanced monsoon precipitation in northern australia in the holocene the lake has not risen to levels achieved during the early stage 5 lacustral phase indicating a marked reduction in the effectiveness of the monsoon in the present interglacial by comparison with its predecessor

does intermediate spreading rate oceanic crust result from episodic transition between magmatic and magma dominated faulting enhanced spreading the costa rica rift example ocean bottom seismograph and multichannel streamer wide angle seismic data are jointly analysed and compared with reflection images bathymetric maps and potential field data to reveal the detailed structure of layer 2 of the oceanic crust formed at the intermediate spreading costa rica rift crr separate modelling of each wide angle data set independently reveals a gradual increase in p wave velocity with distance hence crustal age from the ridge axis with a model derived from their joint inversion in turn displaying a pattern of shorter wavelength structural complexity in addition to a background flow line trend normalizing against a ridge located reference velocity depth model reveals that off axis velocity perturbations are correlated with trends in basement roughness and uplift regions of rougher and uplifted basement correlate with slower layer 2 velocity 0 5 km s 1 faster than at the ridge axis and thinner sediment cover while smoother basement and locations where sediment cover forms a continuous seal over the oceanic basement are mirrored by regions of relatively higher velocity 1 0 1 4 km s 1 faster than at the crr these velocity variations are interpreted to reflect periodic changes in the degree of magma supply to the ridge axis using a combination of global and shipboard magnetic data we derive a spreading history model for the crr which shows that for the past 5 ma spreading has been asymmetric comparing the seismic model structure with variations in full spreading rate over this period reveals a correlation between periods of slower spreading and slower layer 2 velocity basement roughness and uplift and faster spreading higher velocity and smoother basement structure zones of slower velocity also correlate with lows in the residual mantle bouguer anomaly interpreted as most likely reflecting corresponding regions of lower density in the lower crust or upper lithospheric mantle using odp borehole 504b as ground truth we show that periods of faster spreading are associated with phases of magmatic accretion interspersed by phases of increased asymmetric tectonic extension that likely facilitates fluid flow to the deeper crust and results in metamorphic alteration manifest as the modelled density anomalies overall our study shows that the mode of crr crustal formation is sensitive to relatively small changes in full spreading rate within the range of 50 72 mm yr 1 that tips the balance between magmatic and magma dominated crustal formation and or tectonic stretching as characterized by significant variation in the fabric and physical properties of layer 2 we further hypothesize that this inherited structure has a direct influence on the subsequent evolution of the crust through secondary alteration we conclude that descriptive phrases like ocean crust formed at an intermediate spreading rate should no longer be used to describe an actual crustal formation process or resulting crustal structure as over the full range of intermediate spreading rates a fine tipping point dictates an episodic transition between primarily magmatic accretion and magma dominated crustal formation coupled with enhanced faulting with their asymmetry recorded in either ridge flank

improved chronostratigraphic reference curve of late neogene seawater 87sr 86sr we present a reference curve of seawater 87 sr 86 sr variation through the past 7 m y based on 455 samples of planktonic foraminifera from ocean drilling program odp site 758 in the indian ocean this single site curve is superior to extant curves because of several features 1 a continuous sedimentary section free of disturbances 2 a well determined and precise chronostratigraphy that is calibrated to numeric age on the basis of continuous magnetostratigraphy and a refined astronomical time scale 3 a high temporal resolution sample interval averages 15 ka 4 an improved analytical reproducibility and 5 a uniformly high sample quality the gross structure of the site 758 curve is generally similar to that observed in previous work but the increased temporal resolution and decreased analytical scatter of the curve provide improved chronostratigraphic resolution at the 95 confidence level uncertainties on age estimates range from 0 60 m y in the lower pleistocene and upper miocene to 2 03 m y in the middle pliocene moreover this detailed record identifies two periods of steplike increases in seawater 87 sr 86 sr 6 10 to 5 80 ma and 1 46 to 1 13 ma that are characterized by rates of change of 150 10 6 m y these features if verified at other sites indicate abrupt changes in the sr mass balance of the ocean and may be used as precise event markers in late neogene marine sections

isotope geochemistry of quaternary deposits from the arid lands in northern china abstract quaternary deposits of various types lacustrine desert sand river loess and loess like deposits from the southwestern tarim basin north tianshan northeast china and the central loess plateau exhibit an nd 0 range from 5 to 12 8 and a 147 sm 144 nd range from 0 110 to 0 140 their nd depleted mantle model ages are between 1 50 and 1 92 ga with a mean value of 1 7 ga th sc ratios vary over a wide range from 0 1 to 2 comparison of these geochemical signatures with those of the old australian shales and modern pacific ocean dust suggests a continuous input of mantle derived material into the crust over geological time the deposits from the north tianshan show clearly different chemical and isotopic features with significantly higher sm nd high 143 nd 144 nd low 87 sr 86 sr and low la lu and th sc ratios relative to those in the deposits from the other areas this indicates a geological control on the local source which has an overall young age and an enrichment of basic components the ce 0 values of two loess samples from the central loess plateau are 1 8 and 3 9 corresponding to depleted mantle model ages of 2 2 and 3 4 ga like the rb sr system the evolution of the la ce isotopic system in the crust may be to some extent decoupled from the sm nd system due to la ce fractionation by sedimentary processes the loess deposits and the desert sand are not distinguishable in isotopic composition but show somewhat different chemical compositions we conclude that the loess can have originated from desert processes since the difference in the chemistry of the desert sand and loess may result from mineral sorting during desert processes and aeolian transportation the loess deposits on the central loess plateau chemically and isotopically resemble the desert loess deposits in the southwestern tarim basin but do not resemble those of the north tianshan accordingly the loess on the plateau may have a source region in the tarim basin but clearly not in the north tianshan

the incorporation of rare earth elements in modern coral we report measurements of rare earth elements rees which show that these trace elements are being incorporated in modern coral in proportion to their seawater concentrations four bermuda north rock coral species diploria strigosa diploria labyrinthiformis montastrea annularis and porites astreoides and two tarawa atoll samples of the species hydnophora microconos were analyzed by ti idms following cleaning techniques to isolate the lattice bound rees based on the replicate analyses of the same piece of diploria strigosa excellent reproducibility was achieved the ree ca ratios 0 1 3 nmol mol of the bermuda and tarawa corals are similar to those of cd ca the trace metal with the lowest seawater concentration used in coral studies with the exception of ce the distribution coefficients e g dnd nd coral nd seawater ca seawater ca coral between bermuda coral lattice and sargasso seawater have fairly flat patterns across the ree series the values of d range from 1 to 3 like those reported for other trace elements in corals this suggests but does not prove that rees are incorporated in the aragonite lattice of these corals the shale normalized ree patterns of the tarawa corals also have seawater like distributions however no local seawater data are available to calculate values of d two bermuda species d labyrinthiformis and p astreoides have values of d for ce that are high with respect to the d values of la and nd implying that there is preferential uptake of ce into the lattice this may be related to the fact that ce is the only ree with an active redox chemistry in seawater there is considerable interest in using the chemical and isotopic composition of coral as indicators of climatic variations the combination of ree ca ratios and neodymium isotopic composition of coral has the potential to help understand important natural processes a primary application could be directed toward a tracer for river water discharge in tropical regions and by inference a proxy for rainfall climate variation and weathering history this application would exploit the fractionated composition of rees in river water as a terrigenous signature in coastal corals

contrasts in arctic shelf sea ice regimes and some implications beaufort sea versus laptev sea the winter ice regime of the 500 km from the mainland than in the beaufort sea as a result the annual freeze up does not incorporate old deep draft ice and with a lack of compression such deep draft ice is not generated in situ as on the beaufort sea shelf the laptev sea has as much as 1000 km of fetch at the end of summer when freezing storms move in and large 6 m waves can form also for the first three winter months the polynya lies inshore at a water depth of only 10 m turbulence and freezing are excellent conditions for sediment entrainment by frazil and anchor ice when compared to conditions in the short fetched beaufort sea we expect entrainment to occur yearly different from the intensely ice gouged beaufort sea shelf hydraulic bedforms probably dominate in the laptev sea corresponding with the large volume of ice produced more dense water is generated in the laptev sea possibly accompanied by downslope sediment transport thermohaline convection at the midshelf polynya together with the reduced rate of bottom disruption by ice keels may enhance benthic productivity and permit establishment of open shelf benthic communities which in the beaufort sea can thrive only in the protection of barrier islands indirect evidence for high benthic productivity is found in the presence of walrus who also require year round open water by contrast lack of a suitable environment restricts walrus from the beaufort sea although over 700 km farther to the south we could speculate on other consequences of the different ice regimes in the beaufort and laptev seas but these few examples serve to point out the dangers of exptrapolating from knowledge gained in the north american arctic to other shallow arctic shelf settings

provenance of dust in the pacific ocean eolian dust preserved in deep sea sediment cores provides a valuable indicator of past atmospheric circulation and continental paleoclimate in order to identify the provenance of eolian dust nd and sr isotopic compositions and rb sr and rare earth element ree concentrations have been determined for the silicate fractions of deep sea sediments from the north and central pacific ocean different regions of the pacific ocean are characterized by distinct air borne inputs producing a large range in end 10 to 1 stsr 86sr 0 705 0 721 la yb 5 15 eun eu 0 6 1 0 and sr nd 4 33 the average nd isotopic composition of pacific deep sea sediments eno 6 is more radiogenic than the average from the atlantic ena 8 in contrast the average 1475m 14and ratio for pacific sediments 0 114 is identical to that of atlantic sediments and to that of global average riverine suspended material the values of ena and 147sm 144nd are positively correlated for the pacific samples but negatively correlated for atlantic samples reflecting a fundamental difference between the dominant components in the end members with radiogenic nd island arc components in the pacific and lree enriched intraplate ocean island components in the atlantic samples from the north central pacific have distinctive unradiogenic end values of 10 87sr 86sr 0 715 high la yb 12 and low eun eu 0 6 and sr nd 3 6 these data are virtually identical to the values for loess from asia and endorse the use of these sediments as indicators of asian paleoclimate and paleowind directions island arc contributions appear to dominate in the northwest pacific resulting in higher end 1 to 1 and lower 87sr 86sr 0 705 and la yb 5 sediments from the eastern pacific tend to have intermediate sr and nd isotopic compositions but regionally variable sr nd and ree patterns they appear to be derived from the west margin of the north and south american continents rather than from asia our results confirm that dust provenance can be constrained by isotopic and geochemical analyses which will facilitate reconstructions of past atmospheric circulation and continental paleoclimate

strontium neodymium and lead isotope variations of authigenic and silicate sediment components from the late cenozoic arctic ocean implications for sediment provenance and the source of trace metals in seawater proven ance changes of silicate sediment deposited during the late cenozoic 5 0 ma on the alpha ridge central arctic ocean are determined from variations in strontium lead and neodymium isotope compositions whereas strontium and lead isotope compositions are relatively invariant from 5 to 1 7 ma end values start to increase at 3 ma subsequently s7sr 86sr and 2 6pb z 4pb ratios progressively increase and end values progressively decrease from 1 7 ma to the present day from these isotope variations three different endmember compositions for sediment source regions are defined the two endmember compositions defined by sediment that was deposited by sea ice from 5 to 1 7 ma are consistent with a significant component being derived from the east siberian shelf the progressive change in isotope compositions from 1 7 to 0 ma correlates with an increase in coarse detritus deposited by icebergs over this time period the isotope data are consistent with a progressive increase in the proportion of sediment that was deposited in the central arctic ocean since 1 7 ma having been derived from the northern canada or queen elizabeth island region changes in the strontium neodymium and lead isotope compositions of arctic seawater are determined by analyzing the oxide fractions of fe mn micronodules strontium isotope compositions of the microno dule oxide fractions are similar to published late cenozoic seawater data and indicate that 97 of the sr is seawater derived but minute contributions of sr from silicate detritus prohibit using the hydrogenous fractions for chronostratigraphic purposes neodymium and lead isotope compositions of the micronodule oxide fractions which reflect those of arctic seawater follow the isotope variations of the silicate components throughout the late cenozoic these relations indicate that river water can not be the primary source of rare earth elements and pb to the dissolved reservoir in arctic seawater and that ice rafted detritus by dissolution or exchange processes is an important source of trace elements to seawater in ice covered oceans copyright 1997 elsevier science ltd

rare earth elements and neodymium isotopes in ferromanganese oxide coatings of cenozoic foraminifera from the atlantic ocean abstract an evaluation has been made of the method of establishing the ree contents and patterns and nd isotopic compositions of sea water over cenozoic time from their record in the femn oxide coatings of foraminiferal calcite using 0 60 ma samples from the rio grande rise dsdp site 357 it has been established that the ree contents of the coatings are generally similar to those of recent samples however in the cenozoic samples the surface coatings have been diagenetically modified under suboxic conditions resulting in a distinctly different ree pattern although the original 143 nd 144 nd ratios appear to have been preserved the nd isotopic curve for cenozoic sea water in the s atlantic shows clear temporal trends although these are not so extreme as to show 143 nd 144 nd ratios outside the range observed in modem sea water with the principal exception of the oldest samples there is an approximate inverse relationship between the nd and sr isotopic compositions of the foraminifera it is suggested that the changes reflect both global changes in the relative proportions of nd and sr derived from continental input and from the weathering of volcanic debris together with short term and local variations to which the sr curve is insensitive reflecting the different response times of the two elements to changes in oceanic input functions the nd isotope curve appears to be a potentially useful tracer of ocean palaeochemistry

the pliocene record in the central arctic ocean abstract pliocene sediment from the central arctic ocean was reported first some 25 years ago although the basis of the pliocene age was tenuous none of the data subsequently presented have invalidated the original pliocene age report new data confirm the earliest report as well as establish the presence of older miocene sediment the pliocene sediment recovered from the central arctic ocean to date includes only 2 3 m of silty lutite consisting largely of illite kaolinite and chlorite with lesser amounts of expandable clays abundant fe mn micronodules but few fossils the pliocene age is based on extrapolation of sedimentation rates from paleomagnetic boundaries arenaceous foraminifera and 87 sr 86 sr isotope ratios obtained from fe mn micronodules and compared to established seawater 87 sr 86 sr isotope ratios for this time notably absent in all except the upper part of the central arctic ocean pliocene sediment is coarser grained glacially ice rafted debris ird or any indication of measurable surface water productivity early interpretations of the arctic ocean record included the concept that sea ice was present during the pliocene and that the ice cover existed more or less continually to the present late cenozoic warming events that may have temporarily removed all or part of the arctic ocean s ice were thought to be restricted to the pleistocene more recently published data suggest that the pliocene arctic ocean was a warmer perhaps ice free ocean general circulation modeling experiments with all or parts of the arctic ice cover removed are cited in support of pliocene data generated primarily from the arctic ocean s margins that have suggested a warmer ocean while there is important evidence for a warmer pliocene earth the data to support significant warming in the central arctic ocean remains ambiguous reevaluation of part of the data used to support supposed pliocene warming intervals on the arctic ocean s margins suggests that at least some of the implied pliocene warming events may have actually occurred during the pleistocene the central arctic ocean s pliocene record studied to date indicates only that the ocean had very low surface water productivity and extremely low sedimentation rates both consistent with the presence of an ice cover there is little evidence of organic activity of any kind however the sum of the data obtained is equivocal concerning the affect of a warmer earth on the central arctic ocean and the presence or absence of sea ice

formation and evolution of the surface mixed layer and halocline of the arctic ocean fresh water from summer ice melt and the total freshwater content of the arctic ocean water column above the thermocline are estimated from vertical profiles of temperature and salinity observed on the i b oden 1991 cruise the seasonal ice melt ranges from 0 5 m to slightly above 1 m and is moderately uniform over the observation area regions of lower melting are seen over the morris jesup plateau the freshwater content is calculated relative to the salinity just above the thermocline north of the barents sea the freshwater content increases toward the interior of the arctic ocean showing that fresh water is advected from other regions into the observation area regions of different freshwater content are separated by fronts over the nansen gakkel ridge over the lomonosov ridge and in the western eurasian basin between waters derived from the eurasian and canadian basins denser water homogenized north of the barents sea is recognized by a temperature minimum layer the absence of the temperature minimum near the nansen gakkel ridge indicates that heat is transferred from the atlantic layer over a longer time than the shortest route would allow this observation can be explained if the layer circulates together with the atlantic layer i e toward the east and returns above the nansen gakkel ridge and along the amundsen basin north of the laptev sea this water formed north of the barents sea becomes covered by low salinity shelf water the increased freshwater content limits the winter convection so it no longer reaches the thermocline and an intermediate halocline is formed the halocline in the eurasian basin consists of water originating from winter convection in the arctic ocean north of the barents sea which then circulates around the basin such a formation mechanism also explains the observed distribution of low no water the strong density increase limits vertical exchange and the vertical diffusion coefficient in the halocline is small 1 10 6 m2 s 1 the increased temperature of the halocline shows that the heat lost upward by the atlantic layer mainly by double diffusive convection is trapped below the mixed layer

sm nd in marine carbonates and phosphates implications for nd isotopes in seawater and crustal ages this study explores the possibility of establishing nd isotopic variations in seawater over geologic time calcite aragonite and apatite are examined as possible phases recording seawater values of nd modern biogenic and inorganically precipitated calcite and aragonite from marine environments were found to have nd concentrations of from 0 2 to 70 ppb showing that primary marine caco 3 contains little ree and that nd ca is not greatly enhanced relative to seawater during carbonate precipitation very young marine limestone and dolomite containing no continental detritus have 200 ppb nd all the carbonates are lree enriched 0 16 sm nd 0 45 modern and very young atlantic and pacific carbonates have nd in the range of shallow atlantic and pacific seawater respectively implying that they derive their ree from local seawater the nd in well preserved carbonate fossils is 4 10 4 ppb much greater than in their modern counterparts but like the high values found for carbonates in other studies we believe the high ree contents at the 500 ppb level in some detritusfree carbonates are due to ree rich fe hydroxide in on the carbonate in favorable cases such material may record seawater nd values however introduction of extraneous ree may obscure the original isotopic composition of pure caco 3 because of its very low intrinsic primary ree abundance modern biogenic apatite is also shown to have very low ree content 150 ppb nd but appears to quickly scavenge ree from seawater inorganically precipitated apatite from phosphorites has high concentrations of seawater derived ree young phosphorite apatite from the atlantic and pacific oceans has nd in the range of the seawater from these oceans older apatite samples of similar age from different localities bordering common oceans record similar values of nd t sedimentary apatite has sr t values in good agreement with the curves for 87 sr 86 sr of seawater as a function of time individual conodonts from a single formation yield the same sr t and nd t other workers have shown that sedimentary apatite preserves seawater ree patterns these characteristics suggest that sedimentary apatite can be used to determine nd t in ancient seawater the seawater values so inferred range between 1 7 and 8 9 over the last 700 my and lie in the range of modern seawater showing no evidence for drastic changes high values of seawater nd t in the triassic and latest precambrian may correlate with the breakup of large continental landmasses the initial nd t 15 0 of a 2 ae old phosphorite implies the presence of 1 5 ae old continental crust at 2 ae ago the approach outlined here can be used to constrain the age of the exposed crust as a function of time