controls on the 87sr 86sr composition of seawater from the middle eocene to oligocene hole 689b maud rise antarctica a 87sr 86sr isotope curve of the middle eocene to oligocene was produced from analysis of foraminifera in ocean drilling program hole 689b maud rise near the coast of antarctica sediments from the hole are well preserved with no evidence of diagenetic alteration the sequence is nearly complete from 46 3 to 24 8 ma with an average sampling interval of 166 kyr excellent magnetostratigraphy in hole 689b allows calibration to the geomagnetic polarity time scale of cande and kent 1992 marine strontium isotopic ratios were nearly stable from 46 3 to 35 5 ma averaging near 0 70773 after which they began to increase a slow increase began after 40 4 ma rising at a rate of only about 8 10 6 m y from base values of 0 707707 from 35 5 ma to 24 8 ma the average slope increased to 40 10 6 m y the slope remained constant at least until 24 8 ma when the record becomes discontinuous owing to unconformities we evaluate several possible controls on the marine strontium isotope curve that could have led to the observed growth in 87sr 86sr ratios near the eocene oligocene boundary three mechanisms are considered including the onset of antarctic glaciation increased mountain building in the himalayan tibetan region and decreased hydrothermal activity none of the mechanisms alone seems to adequately explain the increased 87sr 86sr ratios during the oligocene glaciation as a weathering agent was too episodic and probably began too late to explain the upturn in marine 87sr 86sr ratios there is evidence that uplift in the himalayan tibetan region began in the miocene much too late to control oligocene strontium isotope ratios lastly hydrothermal flux changes since the eocene were apparently not great enough alone to account for the rise in marine 87sr 86sr ratios we suggest that a combination of causes such as decreased hydrothermal activity perhaps followed by increased glaciation and mountain building might best explain the growth of the marine 87sr 86sr curve during the oligocene

surface area control of shallow cratonic to deep marine carbonate accumulation sites of calcium magnesium carbonate accumulation have been shifting from shallow shelf to deep marine settings since the late cretaceous during this time total area of flooded epicratonic shelf has decreased about 50 and areas of shelf carbonate deposition have declined from 27 106 km to present areas of 1 4 106 km while the maximum extent of platform carbonate accumulation has decreased from about 50 to 28 north latitude in terms of cratonic carbonate this decrease in tropical shelf area has resulted in a sixfold reduction in shoal water limestone accumulation from a cretaceous rate of 0 6 km m y to a present value of about 0 1 106 km m y over the same time period the global carbonate compensation depth has deepened by about 1 5 km attendant with a threefold areal increase of calcite ooze depositionn 40 to 130 106 km this expansion has resulted in an eightfold increase in pelagic limestone accumulation from a cretaceous rate of 0 05 106 km m y to a present rate of about 0 4 106 km m y transfer of accumulation from shallow cratonic to deep marine depositional settings records the central role of sedimentary environment surface area in predicating the differential partitioning of finite carbonate fluxes to phanerozoic global oceans

change from late tertiary compression to quaternary extension in southern tibet during the india asia collision field studies in southern tibet show that subsequent to folding resulting from the india asia collision 50 40 ma reverse faults and backthrusts formed as a result of nne ssw and nnw sse trending compressions they affect conglomerates of oligocene miocene age and are probably contemporaneous with shearing on the himalayan main central thrust and folding of paleogene basins along the northern border of southern tibet 25 16 ma rift systems postdate compressional structures they were active during the pleistocene and probably during the pliocene 5 2 ma change from a compressional to an extensional regime in tibet probably occurred during the late miocene 10 5 ma this change is tentatively correlated with uplift inferred by chinese workers from paleogene to present day variations of the tibetan vegetation recent and active faulting in the high plateau results from a wnw ese striking extension this is in agreement with tibetan focal mechanisms the himalayan lowlands are subjected to a nne ssw trending compression as demonstrated by superficial deformations and seismicity therefore the horizontal maximum compressive stress trajectory is roughly parallel to india asia convergence hmax being 1 in the lowlands and 2 in the high plateau this change results from the increase of the vertical principal stress value due to the weight of the elevated mass zz is 3 in the lowlands and 1 in the high plateau thus the third principal stress axis is 2 in the lowlands and 3 in the high plateau allowing extension to occur in the wnw ese direction extensional tectonics are significantly different in southern and northern tibet southern tibet being constrained between the himalayan syntaxes the e w extensional principal deviatoric stress value 3 is of rather small magnitude and the n s trending 2 value is extensional as demonstrated by analysis of recent faults normal components prevail along all the azimuths in the field this favors formation of rift systems of large axial extension on the contrary north of the himalayan syntaxes northern tibet flows easily eastward the e w extensional principal deviatoric stress value 3 is of higher magnitude and the n s stress 2 is compressional as shown by inversion of focal mechanism data this favors strike slip components on faults which deviate from the n s direction as expressed in the field by shorter n s trending graben linked with normal strike slip faults these faults permit some n s shortening in northern tibet without thickening in response to india asia collision in high plateaus which are subjected to lateral compression such as the andean altiplano and tibet the extensional direction is basically controlled by the convergence direction being roughly orthogonal to the latter

late cenozoic uplift of mountain ranges and global climate change chicken or egg the high altitudes of most mountain ranges have commonly been ascribed to late cenozoic uplift without reference to when crustal thickening and other tectonic processes occurred deep incision and recent denudation of these mountain ranges abundant late cenozoic coarse sediment near them and palaeobotanical evidence for warmer climates where high mountain climates today are relatively cold have traditionally been interpreted as evidence for recent uplift an alternative cause of these phenomena is late cenozoic global climate change towards lower temperatures increased alpine glaciation a stormier climate and perturbations to humidity vegetative cover and precipitation

enhanced cenozoic chemical weathering and the subduction of pelagic carbonate the observed trend of increasing oceanic 87sr 86sr ratios during the late cenozoic led raymo et al 1 to propose that chemical weathering rates increased at this time as a result of enhanced weatherability of silicate rocks they suggested that this was due in turn to continential uplift primarily in the himalayas and the andes because weathering involves the reaction of silicates with atmospheric carbon dioxide considerations of changes in weathering rates must take into account the need to balance the global carbon cycle to maintain this balance on timescales greater than 106yr enhanced weathering requires an increased flux of co2 into the atmosphere2 without such an increased flux weathering rates could not increase and one is then forced to search for other explanations for the observed 87sr 86sr trend such as a changing riverine strontium isotope composition3 6 here i assume that the strontium isotope record does indeed reflect enhanced weathering in the late cenozoic but propose that its cause may have been an increased co2 flux arising from the recycling of pelagic sedimentary carbon at subduction zones since the jurassic sedimentary carbonate accumulation has shifted from primarily cratonic to primarily pelagic environments7 11 because sea floor spreading transports pelagic carbonate to and recycles it through metamorphic environments in subduction zones this shift to pelagic carbonate accumulation would provide the increased co2 flux needed to increase weathering rates12 13

influence of late cenozoic mountain building on ocean geochemical cycles in a steady state ocean input fluxes of dissolved salts to the sea must be balanced in mass and isotopic value by output fluxes for the elements strontium calcium and carbon rivers provide the primary input whereas marine biogenic sedimentation dominates removal dissolved fluxes in rivers are related to rates of continental weathering which in turn are strongly dependent on rates of uplift the largest dissolved fluxes today arise in the himalayan and andean mountain ranges and the tibetan plateau during the past 5 m y uplift rates in these areas have increased significantly this suggests that weathering rates and river fluxes may have increased also the oceanic records of carbonate sedimentation level of the calcite compensation depth and delta sup 13 c and delta sup 87 sr in biogenic sediments are consistent with a global increase in river fluxes since the late miocene the cooling of global climate over the past few million years may be linked to a decrease in atmospheric co sub 2 driven by enhanced continental weathering in these tectonically active regions

strontium isotopic variations in jurassic and cretaceous seawater a high resolution seawater strontium isotope curve has been generated through the analysis of well dated and well preserved belemnites and oysters from the middle and upper jurassic and the lower cretaceous of great britain analysis of fe and mn concentrations in these fossils has yielded criteria for eliminating samples that are diagenetically altered the strontium isotope curve remains relatively flat through the aalenian and early bajocian rapidly descends through the late bajocian and bathonian and reaches a minimum in the callovian and oxfordian it then begins a rapid increase in the kimmeridgian and portlandian that continues through much of the early cretaceous the curve levels off in the barremian suddenly dips downwards in the aptian and recovers gradually through the albian the strontium isotopic variations are sufficiently large and the data are presented with sufficient stratigraphic detail to allow precise correlation to the classic ammonite zones and lithologic sections of great britain using the techniques of strontium isotope stratigraphy model results indicate that much of the variation in seawater 87sr86sr between 120 and 40 ma can be explained by changing the intensity of mid ocean ridge hydrothermal fluxes proportionally to estimated mid ocean ridge crustal generation rates it is also possible that the variations during the rest of the mesozoic and the permian are primarily reflections of changing hydrothermal inputs the model results have several important implications first they provide an example in which the variations in the strontium isotope curve are not necessarily driven by changes in fluvial inputs second they suggest that from at least the aptian through the eocene variations in continental weathering were minimal this heightens the importance of the rapid rise in seawater 87sr86sr beginning 40 ma as a significant transition to an extended period of increasing fluvial 87sr fluxes continuing to the present finally the results suggest that several documented short term excursions towards lower 87sr86sr in the latest triassic pliensbachian toarcian callovian oxfordian aptian albian and cenomanian turonian are interpretable as pulses of seafloor hydrothermal activity if so the strontium isotope record offers a means of constraining the timing duration and magnitude of known or proposed hydrothermal events in the geological record

strontium isotopes and rubidium in the ganga brahmaputra river system weathering in the himalaya fluxes to the bay of bengal and contributions to the evolution of oceanic87sr 86sr the concentrations of rb and sr and87sr 86sr isotopic ratios have been measured in the dissolved load of the ganga brahmaputra g b river system the ganga was sampled extensively from its source at gangotri in the higher himalaya to patna on the alluvial plains the brahmaputra was sampled in its stretch in assam in india the average sr concentration in the ganga at patna is 1 2 mol l and that in the brahmaputra at goalpara is 0 73 mol l the mean87sr 86sr ratios are 0 7239 and 0 7192 respectively the87sr 86sr in the ganga source waters the alaknanda the bhagirathi and their tributaries range between 0 7300 and 0 7986 considerably higher than the global average runoff value of 0 7119 the high87sr 86sr in the ganga source waters result from the intense weathering of precambrian granites and gneisses enriched in radiogenic sr the sr isotope systematics of the ganga waters is dominated by silicate weathering whereas carbonate weathering plays a significant role in their major ion chemistry the g b system transports about 910 million moles of dissolved sr annually to the bay of bengal with an average87sr 86sr of 0 7213 the sr transported by the g b system is about 2 7 of the global dissolved sr flux to the oceans via rivers model calculations reveal that the g b system has contributed significantly to the sr isotope evolution of seawater during the past 20 ma the flux of rb through the g b system is 24 million moles per year this is about 5 of the global river supply of rb to the oceans nearly twice the contribution of water via the g b system to the oceans our study suggests that the marine geochemistries of sr and rb and possibly u may have been influenced considerably by the himalayan orogeny

the effect of land plants on weathering rates of silicate minerals abstract land plants and their associated microbiota directly affect silicate mineral weathering in several ways by generation of chelating ligands by modifying ph through production of co2 or organic acids and by altering the physical properties of a soil particularly the exposed surface areas of minerals and the residence time of water in laboratory experiments far from equilibrium 1 mm oxalate a strong chelator of al has a negligible effect on the dissolution rate of alkali feldspars but some effect on calcic feldspars and olivine by analogy to oxalate the overall effect of organic ligands on the weathering rate of silicate minerals in nature is likely to be small except perhaps in microenvironments adjacent to roots and fungal hyphae the effect of ph on silicate mineral dissolution rate depends on ph below ph 4 5 the rate increases with decreasing ph in the circumneutral region the rate is ph independent and at ph values above around 8 the rate increases with increasing ph vegetation should thus cause an increase in weathering rate through the ph effect only where the ph is below 4 5 as an overall generalization the effect of plants on weathering rate through changes in soil solution chemistry is probably small for granitic rocks it may be greater for more mafic rocks it is the release of ca and mg from mafic rocks that has the greatest influence on the global co2 budget the effect of changes in soil physical properties on weathering rate can be major by binding fine particles plants can greatly increase weathering rates in areas of high physical erosion where erosion rates are lower the effect of plants is less clear on long timescales plants may decrease chemical weathering by binding secondary products and isolating unweathered minerals from meteoric water a major unknown in estimating the effect of the advent of land plants on weathering rates is the nature thickness particle size distribution permeability of the regolith on the pre silurian continents the indirect effect of vegetation through changing the regional distribution of precipitation may be as important as the direct effects

silicate rock weathering and atmospheric soil co2 uptake in the amazon basin estimated from river water geochemistry seasonal and spatial variations abstract using the data of the camrex project 1982 1984 on the water geochemistry of the amazon river and its main tributaries it was possible to assess the silicate rock weathering processes and the associated consumption of atmospheric soil co2 taking into account seasonal and spatial variations this study confirms the important role of the andes in the fluvial transport of dissolved and particulate material by the amazon and it shows for the first time that the silicate weathering rate and atmospheric soil co2 consumption are higher in the andes than in the rest of the amazon basin the seasonal variations exhibit the significant role of runoff as a major factor controlling silicate weathering processes and show that the chemical erosion rates vary greatly from low discharge to high discharge the average weathering rate estimated for the whole amazon basin 15 m my is comparable to other estimations made for other tropical equatorial environments a comparison between physical and chemical weathering rates of silicate rocks for the amazon basin and for each tributary basin show that in the andes and in the amazon trough the soil thicknesses are decreasing whereas in the shield the soil profiles are deepening

low temperature alteration of the upper oceanic crust and the alkalinity budget of seawater abstract while the input of river alkalinity into seawater is relatively well known the complementary acidity production is poorly understood using the major element budget of seafloor alteration of the upper 500 m of 120 ma old oceanic crust at dsdp odp sites 417a 417d and 418a in the central western atlantic we estimate the acidity flux associated with the low temperature weathering of the upper oceanic crust the acidity flux is calculated based on major element fluxes and charge balance considerations the relevant chemical fluxes from seawater to the upper crust are 4 1 0 1 1 4 1 4 2 2 0 6 and 12 2 1011 mol yr 1 for k mg na and silicate ca respectively the associated acidity flux is 3 5 3 1011 eq yr 1 relative to continental weathering these fluxes are significant for k and silicate ca but are minor for na mg and acidity thus riverine fluxes of alkalinity are not significantly balanced by acidity fluxes from low temperature upper ocean crust alteration

himalayan tectonics weathering processes and the strontium isotope record in marine limestones the time evolution of the isotopic composition of seawater strontium the ratio of strontium 87 to strontium 86 over the last 500 million years has the form of an asymmetric trough the values are highest in the cambrian and recent 0 7091 and lowest in the jurassic 0 7067 superimposed on this trend are a number of smaller oscillations consideration of the geochemical cycle of strontium and the dynamics of weathering shows that only himalayan style continental collisions can influence the isotope ratio on the scale observed the contemporary himalayan orogeny is by far the largest since the late precambrian pan african event that produced the high in the cambrian

direct effects of co2 and temperature on silicate weathering possible implications for climate control a critical uncertainty in models of the global carbon cycle and climate is the combined effect of organic activity temperature and atmospheric co2 on silicate weathering here we present new dissolution rates of anorthite and augite which indicate that silicate weathering in organic rich solutions is not directly affected by soil co2 but is very sensitive to temperature apparently co2 accelerates silicate weathering indirectly by fertilizing organic activity and the production of corrosive organic acids the weathering dependencies highlight the ability of silicate weathering to act as a global thermostat and damp out climate change when used as input in steady state carbon cycle and climate models

pyrite and organic matter in phanerozoic normal marine shales data have been obtained from our own chemical analyses and from the literature for the concentrations of organic carbon c and pyrite sulfur s in over 600 samples of cambrian to recent normal marine shales normal marine refers to deposition in oxygenated bottom water as evidenced by the presence of benthic fossils and or indicators of bioturbation all samples were selected to minimize 1 1 loss of c and or s due to weathering at the outcrop by emphasizing the use of drill core material 2 2 analytical errors and non diagenetic effects by avoiding sediments low in c or s content such as sandstones 3 3 fe limitation of pyrite formation by avoiding limestones cherts and euxinic shales 4 4 metamorphic loss of c relative to s by avoiding rocks obviously subjected to even low grade metamorphism our results indicate that 1 there is generally a good positive linear correlation between organic c and pyrite s for normal marine shales of all ages and 2 the mean cs ratio for normal marine shales has varied over time devonian to tertiary shales exhibit mean cs weight ratios 1 8 0 5 somewhat lower than quaternary sediments meancs 2 8 this we believe is due to preferential c loss relative to s during biogenic methanogenesis plus diagenetic heating distinctly lower mean c s values for the cambrian and ordovician 0 5 0 1 cannot be explained solely in terms of diagenetic c loss and instead must represent low original ratios the low original ratios we suggest were due mainly to the absence of bacterially refractory organic matter added to the marine environment by rivers at that time because the major source of such material vascular land plants had not yet evolved this along with a possibly lower degree of bioturbation contributed to enhanced pyrite formation and preservation and thus lower early paleozoic cs ratios

a model for atmospheric co 2 over phanerozoic time a new model has been constructed for calculating the level of atmospheric co sub 2 over phanerozoic time which is much simpler mathematically than the blag model but more complex geologically and biologically results suggest that there has been a notable pattern of varying atmospheric co sub 2 level over the past 570 my with high levels during the mesozoic and early paleozoic and low levels during the permo carboniferous and late cenozoic sensitivity analysis shows that within reasonable limits of the principal governing parameters this qualitative trend of varying co sub 2 is relatively insensitive to the actual values chosen for these parameters causes of the co sub 2 variation are multiple and no single geological or biological process can be called upon to explain all co sub 2 variation for all time the calculated trend of co sub 2 over time agrees well with independent estimations of paleoclimates thus the greenhouse theory of paleoclimate on a long geological time scale is supported by the results of the present study

k ar and ar ar geochronology of the himalayan collision in nw pakistan constraints on the timing of suturing deformation metamorphism and uplift mica and hornblende k ar and ar ar data are presented from each of the three crustal components of the himalayan collision zone in north pakistan the asian plate the kohistan island arc and the indian plate together with u pb and rb sr data published elsewhere these new data 1 date the age of suturing along the northern suture which separates kohistan from asia at 102 85 ma 2 establish that the basic magmatism in kohistan which postdates collision along the northern suture predates 60 ma and that the later granite magmatism spanned a range of 60 25 ma 3 show that uplift amounts within kohistan are greater toward the nanga parbat syntaxis than away from it and that rate of uplift near the syntaxis increased over the last 20 ma to a current figure of about 5 5 mm a year 4 show that much of southern kohistan had cooled to below 500 c by 80 ma and that the major deformation which imbricated kohistan probably predated 80 ma and certainly predated 60 ma and was related to the kohistan asia collision rather than the kohistan india one 5 imply that uplift along the hunza shear in the asian plate together with imbrication of the metamorphics in its hanging wall took place at about 10 ma and was associated with breakback thrusting in the hanging wall of the main mantle thrust 6 suggest that the indian plate has a lengthy pre himalayan history with an early metamorphism at about 1900 ma major magmatism at 500 550 ma and early jurassic lithospheric extension or inversion and 7 show that the indian plate rocks were metamorphosed shortly after the collision within kohistan which occurred at circa 50 ma and subsequently cooled back through 500 c at circa 38 ma and 300 c at 30 35 ma with ages of cooling through 200 and 100 c as determined by fission track data locally controlled by nanga parbat related uplift tectonics

geochemical evidence supporting t c chamberlin s theory of glaciation in 1899 t c chamberlin proposed that the co sub 2 content of the atomsphere decreased during times of enhanced continental erosion ultimately resulting in glacial epochs he ascribed the increase in the rate of chemical weathering relative to the rate of supply of co sub 2 from earth s interior to increased orogenic activity and globally higher average elevations which promoted rapid chemical erosion of silicates the oceanic record of strontium isotopes preserved in marine sediment supports his suggestion that glacial climates during the phanerozoic are in part linked to increases in the rate of global chemical erosion relative to outgassing from earth s interior further the close correspondence of the major tectonic episodes of the late cenozoic to times of increased continental erosion and glaciation suggests that chamberlin s hypothesis of the cause of glacial periods should be revived

himalayan uplift and osmium isotopes in oceans and rivers previous studies have shown that 187 os 188 os in seawater has become increasingly radiogenic over the last 40 ma in a manner analogous to strontium this rapid rise in the marine 187 os 188 os over the last 17 ma has been attributed to an increase in the bulk silicate weathering rates resulting from the rise of the himalayas and or selective weathering and erosion of highly radiogenic organic rich ancient sediments the key test of this hypothesis is the 187 os 188 os and the total osmium concentration of the himalayan rivers we report the concentration and isotopic composition of osmium in the ganges the brahmaputra and the indus rivers the 187 os 188 os of the ganges close to its source at kaudiyal 30 05 n 78 50 e is 2 65 and os 45 fm kg a second sample of the lower reaches of the ganges at patna 25 30 n 85 10 e gives 187 os 188 os 1 59 and os 171 fm kg the 187 os 188 os of the brahmaputra at guwahati 26 10 n 91 58 e is 1 07 and os 52 fm kg a sample of the indus besham 34 55 n 72 51 e has a 187 os 188 os of 1 2 and os 59 fm kg we infer that the himalayas do not provide either a high flow of osmium or a highly radiogenic osmium component to the oceans the overall trend for osmium and strontium could be explained by a regularly increasing input of global continental weathering sources but the himalayas themselves appear not to be the dominant source

late pleistocene dip slip faulting along the dunajec fault west carpathians insights from alluvial sediments abstract this paper presents vertical movement along the dunajec fault during the late pleistocene and suggests quaternary tectonic reactivation of diagonal strike slip faults and their transformation into dip slip faults in the west carpathians optically stimulated luminescence osl dating of pleistocene alluvial sediments of the dunajec and the ochotnica rivers was employed to determine the time range of deposition of these sediments vertical and spatial distribution of the obtained osl ages imply that the alluvial sediments were affected by the dunajec fault which appears to have acted as a scissor fault during the late pleistocene the results contribute to the discussion on the recent evolution of the carpathians and may support the concept of extensional collapse of the orogen

reevaluation of early oligocene eocene and paleocene seawater strontium isotope ratios using outcrop samples from the u s gulf coast the cenozoic strontium isotope 87sr 86sr variation in seawater is largely defined using deep sea drilling project dsdp samples examination of non dsdp results particularly for the paleogene suggest that the original seawater curve of burke et al 1982 may lie above the true seawater ratio during this time to investigate this possibility we analyzed the 87sr 86sr for 230 paleogene rock and shell samples from the 83 sites in alabama mississippi and louisiana many of the samples are from classic sections on which the gulf coast paleogene stratigraphy was originally defined multiple analyses of samples from these units show very little scatter and in most cases precise agreement is obtained among geographically separated collection sites we believe that analysis of multiple samples from a unit of established age collected at more than one site yields results that most accurately define the actual seawater sr isotope ratio at any given time results from these units define a seawater variation line that tracks well within the range of dsdp data but is generally below the original seawater line of burke et al 1982 it is often assumed that samples from continental settings will exchange with high ratio sr thereby raising 87sr 86sr values our gulf coast samples which are derived from a continental setting yield individual 87sr 86sr values that are both higher and lower than the estimated contemporaneous seawater ratio an analysis of our gulf coast data and dsdp results show that the direction of isotopic exchange cannot be confidently predicted for individual samples based solely on their derivation from either continental or oceanic settings

geological evolution of seawater boron isotopic composition recorded in evaporites the abundance of boron isotopes in ancient marine carbonates can be used to estimate oceanic ph that reflects atmospheric co 2 levels this proxy requires that the boron isotopic composition of seawater at the time the carbonate has formed is known and thus the past changes in seawater chemistry here we report the boron isotopic composition of selected ancient marine halites and modern sea salts the signal interpreted as marine reveals a clear evolution of the boron isotopic composition of seawater to 8 variations over the cenozoic comparison between this reconstructed curve and the mg ca ratio reveals a high level of consistency that will help to better define oceanic geochemical cycles

glacial interglacial variability of atmospheric co2 due to changing continental silicate rock weathering a model study an 11 box model of the oceanic carbon cycle including sedimentary processes is used to explore the role chemical weathering of continental silicate rocks might play in driving atmospheric co2 levels on glacial interglacial timescales histories for the consumption of co2 by silicate rock weathering processes are derived from the marine ge si record taking the major uncertainties in the knowledge of the ge and si cycles into account several histories for the evolution of the riverine dissolved silica fluxes are calculated from this record the investigation of the systematics between riverine dissolved silica and bicarbonate fluxes under different weathering regimes leads us to the tentative conclusion that although there is no correlation between dissolved silica and total bicarbonate concentrations in the major rivers there may exist a negative correlation between weathering intensity and the ratio of dissolved silica to bicarbonate derived from silicate weathering alone with this correlation as a working hypothesis it is possible to interpret the dissolved silica fluxes in terms of equivalent co2 consumption rates the calculated histories indicate that glacial rates of co2 consumption by chemical silicate rock weathering could have been twice and possibly up to 3 5 times as high as they are today when used to force the carbon cycle model they are responsible for glacial interglacial pco2 variations in the atmosphere of typically 50 60 ppm and up to 95 110 ppm these variations are superimposed to a basic oscillation of 60 ppm generated by the model mainly in response to coral reef buildup and erosion processes the total pco2 signal has an amplitude of about 80 90 ppm and up to 125 135 ppm although these large amplitudes indicate that silicate weathering processes should be taken into account when studying glacial interglacial changes of co2 in the atmosphere it also raises new problems such as too high co2 levels during the period from 110 70 kyr b p requiring further study

estimating ancient sediment fluxes original phanerozoic sediment flux rates can be approximated by fitting an exponential decay curve to the observed massjage distribution of sediments then multiplying the ratio of the observed mass to the exponential decay curve mass by the zero age flux rate predicted by the exponential decay curve applied to the massjage distribution of existing phanerozoic sediments the reconstruction method indicates that original global sediment flux rates varied cyclically by a factor of up to three this implies significant changes in the rates of uplift and mountain building and global plate tectonic activity

paleoatmospheric consequences of co2 released during early cenozoic regional metamorphism in the tethyan orogen the eocene was the warmest epoch of the cenozoic with published estimates of eocene atmospheric co2 content ranging from two to six times the current value calculations of co2 consumption by silicate weathering show that co2 fluxes to the atmosphere of ca 1018 myr could account for inferred paleocene eocene atmospheric co2 contents and the resulting greenhouse effect would have contributed to eocene warmth extensive portions of the tethyan orogen underwent regional metamorphism culminating in the eocene prograde metamorphism may have been contemporaneous with the late paleocene global warming we calculated the amount of metamorphic co2 produced at depth in the himalayan orogen with data on the timing of the india asia collison duration of prograde regional metamorphism and proportions and bulk compositions of metamorphic co2 source rocks if co2 was generated at a constant rate over a 10 myr period of prograde metamorphism in the himalayan orogen we estimate that ca 1018 1019 moles myr of metamorphic co2 were produced at depth significant expulsion of metamorphic co2 to the atmosphere may have occurred by focused fluid flow along shear zones such as the extensive main central thrust in the himalayan orogen an additional ca 1018 myr could have been contributed by eocene regional metamorphism in the mediterranean tethys i e from the alps to turkey the extensive metamorphism associated with the india asia collision and the closing of tethys may have contributed to co2 greenhouse warming in the early to mid cenozoic

the cenozoic evolution of the strontium and carbon cycles relative importance of continental erosion and mantle exchanges the past variations of the seawater 87sr86sr isotopic ratio are related to changes in the relative contribution of the mantle sr input to the ocean and the sr supply from continental weathering recently it has been postulated that the cenozoic increase in the seawater 87sr86sr isotopic ratio was associated with the uplift of the himalayan and andean mountains at that time these orogenies may have changed the sr isotopic ratio of the continental rocks undergoing weathering as a result of extensive metamorphism increased the river flux of sr through enhanced weathering in these regions and possibly caused the global climatic cooling trend of the cenozoic a model of the major geochemical cycles coupled to an energy balance climate model is used to explore the possible causes of the mesozoic cenozoic fluctuations in the seawater 87sr86sr isotopic ratio the contribution of the mantle exchanges at mid ocean ridges of the recycling of seafloor carbonates through plate margin volcanism and of the alteration of seafloor basalts to the fluctuations of the seawater 87sr86sr isotopic ratio are studied finally this model tentatively describes the impact of the himalayan orogeny on the geochemical cycles of sr and c some possible effects of the extensive metamorphism associated with the india asia collision and of the himalayan uplift are modelled the model reproduces the cenozoic increase of the seawater 87sr86sr isotopic ratio however the impact of the himalayan orogeny on the c cycle appears to be limited and insufficient to generate the global climatic cooling of the cenozoic rather in the model the cenozoic cooling is mostly due to the reduction of the co2 emission from mid ocean ridge volcanism and to changes in the chemical weathering rates in the rest of the world excluding the himalayas

potential for desiccation of geosynthetic clay liners used in barrier systems abstractthe potential for the desiccation of a geosynthetic clay liner gcl forming part of a single composite landfill liner is evaluated a thermohydromechanical model is used to identify conditions likely to cause desiccation simulations for typical landfill conditions show that the potential risk of desiccation exists even at relatively low temperatures i e 35 c it is found that the water content of the gcl prior to waste placement the liner temperature the overburden stress the grain size and water content of the subsoil and the depth to aquifer all affect the potential for desiccation the results suggest that the placement of gcls directly over coarse grained soils or drainage layers should be evaluated carefully this study highlights the need for more research into the potential for gcl desiccation and in particular the need to establish water retention curves for different gcls over a range of stresses and degrees of hydration before heating so that the effect of stress and hystere

modelling the phanerozoic carbon cycle and climate constraints from the 87sr 86sr isotopic ratio of seawater a numerical model describing the coupled evolution of the biogeochemical cycles of carbon sulfur calcium magnesium phosphorus and strontium has been developed to describe the long term changes of atmospheric carbon dioxide and climate during the phanerozoic the emphasis is on the effects of coupling the cycles of carbon and strontium various interpretations of the observed phanerozoic history of the seawater 87sr 86sr ratio are investigated with the model more specifically the abilities of continental weathering volcanism and surface lithology in generating that signal are tested and compared it is suggested that the observed fluctuations are mostly due to a changing weatherability over time it is shown that such a conclusion is very important for the modelling of the carbon cycle indeed it implies that the conventional belief that the evolution of atmospheric carbon dioxide and climate on a long time scale is governed by the balance between the volcanic input of co2 and the rate of silicate weathering is not true rather carbon exchanges between the mantle and the exogenic system are likely to have played a key role too further the increase of the global weathering rates with increasing surface temperature and or atmospheric co2 pressure usually postulated in long term carbon cycle and climate modelling is also inconsistent with the new model other factors appear to have modulated the weatherability of the continents through time such as mountain building and the existence of glaciers and ice sheets based on these observations a history of atmospheric carbon dioxide and climate during phanerozoic time consistent with the strontium isotopic data is reconstructed with the model and is shown to be compatible with paleoclimatic indicators such as the timing of glaciation and the estimates of cretaceous paleotemperatures