variations in mode of formation and temperature of oceanic deep waters over the past 125 000 years marked changes in the deep water temperature of the different oceanic basins during the past 125 kyr are revealed by a detailed comparison of the oxygen isotopic composition ofbenthicforaminiferafrom sediment cores taken from the norwegian sea and the pacific atlantic and southern oceans the last interglacial deep water temperatures were similar to the modern ones at the 5e 5d transition around 115 kyr bp the deep water temperatures dropped below approximately 0 c in the pacific and southern indian oceans in the atlantic ocean the deep water temperature dropped in 2 successive steps at 115 and 75ky bp the global ocean deep water temperatures were in the 0 to 1 c range for the whole of the last ice age isotope stages 4 2

an effect of dissolved nutrient concentrations on alkenone based temperature estimates the ratio of 37 carbon diunsaturated to diunsaturated and triunsaturated alkenones uk 37 produced by some haptophytes is widely used as a proxy for past sea surface temperatures however our isothermal culturing experiments with emiliania huxleyi clone ccmp372 show uk 37 values to also vary with nutrient availability and cell division rate these results provide a reasonable explanation for large isothermal variation in uk 37 values of single coccolithophorid strains grown in culture they also suggest that alkenone based estimates of past sea surface temperatures may have been influenced by dissolved nutrient concentrations as well as by temperature

assessing the reliability of magnesium in foraminiferal calcite as a proxy for water mass temperatures though many studies on the mg contents in the calcitic tests of foraminifers exist the processes controlling its uptake are still a matter of debate laboratory cultures offer an excellent opportunity to reveal these mechanisms the mg concentrations within single chambers of the planktic foraminifer globigerinoides sacculifer brady maintained under controlled laboratory conditions were measured 1 at variable temperatures 19 5 29 5 c and constant salinity and 2 at variable salinity 22 45 and constant temperature the experimental results suggest that under natural conditions temperature is the leading mechanism controlling the mg ca ratio temperature and magnesium are related proportionally a temperature increase of ca 10 c gives rise to an increase of the magnesium concentrations of ca 130 drastic unnatural salinity changes dominate the effects of temperature a 110 change in the mg ca ratio was observed when salinity was elevated or reduced by more than ca 10 specimens which underwent gametogenesis reveal significantly higher mg concentrations than specimens that did not release gametes partition coefficients for mg in foraminiferal calcite are orders of magnitude lower than values from inorganically precipitated calcite when comparing observed mg ca ratios of foraminiferal tests with predicted mg ca ratios calculated according to empirical equations it becomes evident that foraminiferal tests are undersaturated with respect to mg for the water temperature they have experienced apparently foraminifers are capable of controlling their mg concentration the physiological processes presumably responsible for such depressed mg ca ratios appear to be temperature controlled as deduced from the close relationship of the observed mg ca ratios and water temperature this study demonstrates that variations in temperature and salinity are definitely reflected in the mg content of foraminiferal tests magnesium may thus serve as a paleo proxy for past surface water temperatures as long as postdepositional changes and salinity variations are of subordinate importance or can be excluded

depth ranges of alkenone production in the central pacific ocean we report analytical results of long chain c 37 c 39 alkenones in the surface sediments taken along a latitudinal transect at 175 e from 48 n to 15 s unsaturation degree of c 37 alkenones u k 37 indicated that alkenone temperature is the highest about 28 3 c in the tropical pacific and decreases toward 48 n about 10 1 c although the latitudinal trend of the alkenone temperature is generally similar to that of the observed sea surface temperature of the surface mixed layer the former exhibits markedly lower values than the latter does in the midlatitude 35 19 n on the basis of the comparisons between water column temperatures and alkenone temperatures in the surface sediments we estimated that in the midlatitudes alkenones are produced in the thermocline waters whereas in the high 48 40 n and low 10 n 2 s latitudes they are produced in the surface mixed layer this result is supported by the depth distribution of emiliania huxleyi and gephyrocapsa oceanica along a 155 w transect in the central pacific the latitudinal distribution of the alkenone production layers estimated from u k 37 is found to be consistent with that of the nitrate suggesting that the depth of alkenone production is mainly controlled by the nutrient supply from deeper waters alkenones in the sediments exhibited relatively large abundances in 43 27 n with a maximum at 30 n which may be explained by high productivity of haptophyte algae in kuroshio extension

comparison of imbrie kipp transfer function and modern analog temperature estimates using sediment trap and core top foraminiferal faunas we evaluate the reliability of statistical estimates of sea surface temperature sst derived from planktonic foraminiferal faunas using the modem analog method and the imbrie kipp method global core top faunas provide a calibration data set while modem sediment trap faunas are used for validation linear regression of core top predicted sst against atlas sst generated slopes close to one for both methods however the imbrie kipp transfer function temperature estimates had an intercept 1 3oc warmer than modem analog estimates and 1 7oc warmer than recorded atlas sst the rms error for the core top data set using the modem analog method 1 5oc was smaller than that of the imbrie kipp method 1 9oc sst errors for the sediment trap faunas were not statistically different from those of the core top data set regardless of method developing imbrie kipp transfer functions for limited regions reduced the rms variability but introduced residual structure not present in the global imbrie kipp transfer function dissolution simulations with the sediment trap sample which generated the warmest sst residual for both methods suggests that the loss of delicate warm water foraminifera from midlatitude sediments may be the cause of this thermal error we conclude that 1 the fauna structure of sediment trap and core top assemblages are similar 2 both methods estimate sst reliably for modem foraminifera flux assemblages but the modem analog method exhibits less bias and 3 both methods are relatively robust to samples with low communality but sensitive to selective faunal dissolution

oxygen isotopic composition of multiple species of planktonic foraminifera recorders of the modern photic zone temperature gradient abundances of 12 species of planktonic foraminifera collected in two plankton tows from the east tropical atlantic are compared to the chlorophyll content and the temperature of the sea water from which they were collected as expected from previous work in the tropics all dominant tropical species occur in greatest abundance within the photic zone many species occur in greatest abundances in the seasonal thermocline in association with the maximum chlorophyll concentration while a few algal symbiont bearing species occur in greatest abundance in the mixed layer the 18o measurements of planktonic foraminifera shells from core top sediment samples confirm the vertical stratification within the photic zone that is suggested by the relationship between hydrography and abundances found in the plankton tows and found in the statistical study by ravelo et al 1990 comparison between the measured 18o values of planktonic foraminifera with the predicted 18o profiles of the overlying water column at three core locations indicate that species abundances in the sediment record the seasonally integrated conditions of the photic zone and suggests that the abundance of a species in the sediment depends on whether the preferred ecological conditions of that species may be found within the photic zone of the overlying water column sometime during the year species which calcify below the photic zone have only trace relative abundances finally it appears that the total range of 18o values of the dominant species approximates the predicted annual 18o of calcite range in the upper 80 m of the water column

experimental tests for particle size dependent bioturbation in the deep ocean the potential for particle size dependent bioturbation rates was experimentally tested at 1 240 m in the santa catalina basin eastern pacific spherical glass bead tracers in five size classes 816 17 31 32 62 63 125 and 126 420 m were spread over the sediment surface and tube cored 997 d later downcore concentrations of glass beads were enumerated in each of the five size categories and page s l test was used to test the null hypothesis of equal vertical penetration of all size classes of tracer in all cores the null hypothesis was rejected finer tracers penetrated deeper into the sediment in two of the three cores vertical biodiffusivities were computed from concentration profiles of downcore tracers these also showed size dependence with biodiffusivities ranging from 1 cm2 yr for the 8 1 6 pm fraction to 0 1 cm2 yr for the 1 25 420 pm size class these data demonstrate that vertical bioturbation rates are particle size dependent in santa catalina basin the likely cause is preferential ingestion and downward transport of fine particles by deposit feeders

living planktic foraminifera in the central tropical pacific ocean articulating the equatorial cold tongue during la nina 1992 abstract in cold tongue conditions of august september 1992 living planktic foraminifera in the equatorial pacific tracked circulation featuresand phytoplankton abundance an equatorial assemblage associated with the cool and productive equatorial region contained g bulloides a species often associated with tropical coastal upwelling as well as the nonspinose herbivores g menardii g glutinata p obliquiloculata and n dutertrei previously associated with equatorial environments within surface subtropical waters poleward of 5 n and 5 s g sacculifer g ruber and g conglobatus dominated foraminiferal populations these species have successfully adapted to oligotrophic conditions by exploiting dinoflagellate endosymbionts high standing stocks of these species in equatorial regions suggest that they can also thrive within equatorial light levels and temperatures a deep southern assemblage dominated by nonspinose g conglomerata and g tumida and spinose g aequilateralis had a subsurface maximum at 80 200 m outside of active upwelling and outcropped to the surface at 1 s from el nino to cold tongue conditions equatorial fauna reflected higher primary productivity and an increase in the role of advection by the south equatorial current

error analysis of paleosalinity calculations a detailed error analysis is performed for the calculation of open ocean salinity changes from carbonate oxygen 18 proxy data measurement errors are generally negligible however errors due to the goodness of fit of various regressions used in the calculation are significant depending on the method used and on the proxies available error bars 1 for the salinity range from 0 6 to 1 8 in particular expected errors for the midlatitude and tropical salinity differences at the last glacial maximum are around 1 1 to 2 5 the largest errors occur because of the differences between temporal and spatial seawater oxygen 18 salinity relationships and through the use of nonconcurrent temperature measurements methods of improving paleosalinity estimates should focus on eliminating these large sources of uncertainty

ventilation of the subtropical north pacific the shallow salinity minimum abstract the shallow salinity minimum of the subtropical north pacific is shown to be a feature of the ventilated wind driven circulation subduction of low salinity surface water in the northeastern subtropical gyre beneath higher salinity water to the south causes the salinity minimum variation of salinity along surface isopycnals causes variations in density and salinity at the minimum a model of ventilated flow is used to demonstrate how the shallow salinity minimum can arise the model is modified to account for nonzonal realistic winds it is also extended to examine the three dimensional structure of the western shadow zone the boundary between the subtropical and subpolar gyres is given by the zero of the zonal integral of ekman pumping the western shadow zone fills the subtropical gyre at the base of the ventilated layers and decreases in extent with decreasing density for parameters appropriate to the north pacific the eastern shadow zone is of very limited extent observations of salini

response of the tropical atlantic thermocline to late quaternary trade wind changes we applied the modern analog technique to foraminiferal counts from three equatorial atlantic gravity cores to estimate paleothermocline depths in the eastern and western tropical atlantic during the past 250 kyr the eastern equatorial core geob 1105 4 is characterized by variations in the 23 kyr cycle whereas the western sediment cores show a dominant periodicity at the 41 kyr band the phase relationships with respect to insolation and ice volume suggest that thermocline fluctuations in the east are primarily driven by the intensity of the monsoon due to variations in low latitude insolation in contrast changes of the thermocline depth in the western tropical atlantic which lead global ice volume at the 41 kyr band by 3 4 kyr seem to depend on the strength of the se trade winds in response to the meridional temperature gradients in the south atlantic

sedimentary nitrogen isotopic ratio as a recorder for surface ocean nitrate utilization in two contrasting regions of the ocean the equatorial pacific and the southern ocean the 15n of core top sediments were strongly related to no3 in surface waters with distance from the equator in the equatorial pacific 15n increased from 7 to 16 as no3 decreased from 8 m to 0 1 m going from 60 to 30 s in the se indian ocean core top 15n increased from 5 to 11 as surface no3 decreased from 25 m to 0 1 m these results are strong evidence that sedimentary 15n in these regions is recording the increasing isotopic enrichment of near surface no3 with its depletion by phytoplankton in the case of the equatorial pacific 15n values for sinking particles collected at 150 m matched well the core top sediment values demonstrating little diagenetic alteration of the near surface generated isotopic signal these equatorial pacific data sets have variations with near surface no3 consistent with rayleigh fractionation kinetics for a fractionation factor u of 2 5 this value is substantially lower than previously found for temperate or polar regions perhaps as a result of differences in phytoplankton species assemblage or growth condition in the southern ocean south of the polar front comparison of 15n values for opal rich sediments south and sinking particles indicates an apparent 5 diagenetic enrichment relative to the surface generated signal that requires further investigation this exception aside our observations show that the surface water relationship of increasing 15n with increasing no3 depletion is generally transmitted to and preserved in the sediments an important requirement for further development and application of this important paleoceanographic tool

paleoproductivity in the equatorial indian ocean for the last 260 000 yr a transfer function based on planktonic foraminifera a principal component analysis pca of planktonic foraminifera in surface sediment of the northern equatorial indian ocean defines two major assemblages the first one dominated by globigerinoides sacculifer g ruber globigerinella aequilateralis and globoquadrina conglomerata characterizes non upwelling areas the second dominated by globigerina bulloides g falconensis and globigerinita glutinata characterizes upwelling areas the distribution of planktonic foraminiferal species in the area is mainly related to primary production pp the pca applied to core md 900963 samples defines an alternation of the two assemblages through time a non upwelling one similar to that present in the core tops and an upwelling assemblage which contains in addition neogloboquadrina dutertrei globorotalia menardii and g crassaformis equatorial indian ocean core top samples are introduced as additional rows in the pca calculated on core md 900963 samples and a transfer function is constructed correlating factorial coordinates of core tops within the range of changes occurring in core md 900963 with estimated pp values applied to the last 260 000 yr the transfer function indicates that the precession is the major orbital forcing on equatorial productivity changes and that annual pp increases by about 85 from interglacial to glacial interstadials these results are in agreement with an independent productivity index based on coccoliths direct impact of insolation on equatorial productivity could be explained by the link between southern oscillation and intensity of zonal winds which seem to lead the productivity of surface waters at the location of core md 900963

joint focal mechanism determination with source region station corrections using short period body wave amplitude data abstract we have developed a method that simultaneously determines focal mechanism solutions of many small earthquakes and source region station corrections for short period body wave amplitudes by inverting amplitude data of p sh and sv waves together with p wave polarity data the observed seismic waveform includes the effects of site amplification and attenuation along its ray path in addition to the radiation pattern of earthquake source the amplitude of seismograms at frequencies higher than a few hertz is extremely sensitive to heterogeneous structure near the ground surface consequently we need to know in detail the effects of site amplification and attenuation in order to estimate focal mechanisms by using short period waveforms however at present we do not know the detailed crustal structure with a resolution necessary for this estimation in the present study we assume that p and s wave attenuation factors along ray paths from hypocenters to each station can be expressed as a function of hypocentral distance backazimuth and incident angle based on this assumption we determined focal mechanism solutions of many earthquakes and the coefficients in the function for each station simultaneously by using p sh and sv wave amplitudes and p wave polarities we applied the present method to 170 aftershocks of the 1996 onikobe earthquake m 5 9 which occurred in the central part of northeastern japan we obtained focal mechanism solutions of many microearthquakes whose mechanism solutions could not be determined by using p wave polarity data alone p axes of almost all the obtained focal mechanism solutions are horizontal and oriented in the east west direction t axes are on average near vertical at the shallowest depth as the depth approaches 5 km the t axes become horizontal and then gradually become near vertical again

water isotopes in precipitation data model comparison for present day and past climates abstract variations of hdo and h2 18 o concentrations are observed in precipitation both on a geographical and on a temporal basis these variations resulting from successive isotopic fractionation processes at each phase change of water during its atmospheric cycle are well documented through the iaea wmo network isotope concentrations are in middle and high latitudes linearly related to the annual mean temperature at the precipitation site paleoclimatologists have used this relationship to infer paleotemperatures from isotope paleodata extractable from ice cores deep groundwater and other such sources for this application to be valid however the spatial relationship must also hold in time at a given location as the location undergoes a series of climatic changes progress in water isotope modeling aimed at examining and evaluating this assumption has been recently reviewed jouzel et al 1997 with a focus on polar regions and more specifically on greenland we extend this review in comparing the results of two different isotopic agcms nasa giss and echam and in examining with a more global perspective the validity of the above assumption i e the equivalence of the spatial and temporal isotope temperature relationships these results confirm the dominating role of local temperature changes on the paleo isotope signal in most regions however the exact calibration of this valuable paleothermometer is biased by for example the seasonality of precipitation and other factors we forced the two models by the climatic boundary conditions of the mild holocene at 6 kyr bp which only slightly differs from today s climate the isotope response on this weak forcing is quite heterogeneous the only robust common response is the intensification of the hydrological cycle in low latitudes and therefore isotopically more depleted precipitation in the tropics and subtropics we also examine recent progress made in modeling the relationship between the conditions prevailing in moisture source regions for precipitation and the deuterium excess of that precipitation

improving past sea surface temperature estimates based on planktonic fossil faunas a new method of past sea surface temperature sst reconstruction based on the modern analog technique prell 1985 and on the indirect approach bartlein et al 1986 has been developed the revised analog method ram applied to planktonic foraminifera this technique leads to significant improvements in modern sst reconstruction with respect to former methods our estimates are characterized by much lower residuals and a better coverage of the observed sst range moreover the error of ram estimates of past ssts is lower than that associated with former reconstructions particularly at middle and high latitudes in low latitudes cold season ssts reconstructed by ram during glacials are 1 3 c lower than previously estimated our results tend thus to reconcile paleoestimates of glacial temperatures based on planktonic microfossils and on continental data in the tropics

radiocarbon age differences between coexisting foraminiferal species radiocarbon age measurements on single species of foraminifera from a core on the ceara rise demonstrate the importance of the joint effect of bioturbation and variable rain abundance of foraminifera the relatively high mixed layer ages for pulleniatina obliquiloculata reflect at least in part an early holocene peak in its abundance while the relatively young ages for globorotalia menardii reflect the delay until mid holocene of its reappearance in the atlantic ocean these results clearly demonstrate that core top sediment samples need not be representative foraminifera falling from today s surface ocean rather at least on the ceara rise such samples consist of a composite of changing species groupings these results also reconfirm the pitfalls associated with attempts to reconstruct the radiocarbon age of deep ocean water on the basis of benthic planktonic foraminiferal age differences

interhemispheric synchrony of the last deglaciation inferred from alkenone palaeothermometry the relative timings of the last deglacial warming in the southern and northern hemispheres are not well constrained but are a crucial component in understanding the mechanisms of deglaciation1 a clearer picture of the degree of interhemispheric synchrony has been obscured by a dearth of high resolution temperature records that can be tied to the absolute calendar timescale moreover the quantification of tropical temperatures during the last glacial cycle is controversial2 8 here we apply the alkenone method of sea surface temperature reconstruction9 10 to several high resolution sediment cores recovered from the tropical indian ocean between 20 n and 20 s the inferred initial sea surface temperature warming 15 000 calendar years ago at 20 s is in phase with northern hemisphere sea this study and air11 temperature changes but lags antarctic warming12 14 by several millennia this finding along with the results of recent modelling studies15 16 provides strong support for the idea that changes in the ocean s global thermohaline circulation were not the only cause of interhemispheric climate teleconnection during the last deglaciation

seasonal changes in species composition numbers mass size and isotopic composition of planktonic foraminifera settling into the deep sargasso sea abstract planktonic foraminifera recovered from six successive sediment trap samples collected over fourteen months at a depth of 3200 m near bermuda show varied responses to seasonal changes in the near surface hydrography these include changes in species composition and within species changes in number of individuals collected per unit time average size and weight of individuals and in oxygen and carbon isotopic composition a total of seventeen species were identified and eleven were sufficiently abundant for isotopic analysis in at least some of the samples the accumulations on the sea floor of some of these species can be expected to contain a strong seasonal component in their oxygen isotopic composition which may be utilized in paleoclimatic and paleo oceanographic reconstructions best suited to this purpose are those species which form their tests in isotopic equilibrium with surface water and whose abundance is confined to a portion of the year only the best examples are pulleniatina o bliguiloculata globigerinoides conglobatus and neogloboquadrina dutertrei globigerinoides ruber is a good estimator of the average surface water temperature because it occurs in rather even abundance throughout the year hastigerina pelagica though very abundant in surface water is practically eliminated even before arrival on the sea floor by partial resorption and structural weakening of the tests during gametogenesis orbulina universa globorotalia truncaltulinoides and globorotalia hirsuta show morphological and istopic evidence for contibnued calcification in deeper water after initial test formation near ther surface globigerina bulloides represents the most striking example of oxygen isotopic disequilibrium with sea water

late quaternary paleochemistry of high latitude surface waters recent studies have stressed the role of high latitude nutrient levels and productivity in controlling the carbon isotopic composition of the deep sea and the co2 content of the atmosphere we undertook a study of the chemical composition of the polar planktonic foraminifer neogloboquadrina pachyderma s sinistral coiling from 30 late holocene samples and 49 down core records from the high latitude north and south atlantic oceans to evaluate the history of sea surface chemical change from glacial to interglacial time stable isotopic analysis of coretop samples from the atlantic pacific and southern oceans shows no significant correlation between the 13c of n pachyderma and either 13c or po4 in seawater conversely cd ca ratios in planktonic foraminifera are consistent with the po4 content of surface waters the level of maximum glaciation 18 000 yr b p identified by climap and 18o was chosen for mapping isopleths of 18o on n pachyderma s in the north atlantic reveal a pattern largely influenced by sea surface temperature s s t and generally support the s s t reconstruction of climap differences between the two suggest significantly lower salinity in north atlantic surface waters at high latitudes than in lower latitudes down core 13c records of n pachyderma confirm that low 13c values occurred in the northeast atlantic during the latest glacial maximum labeyrie and duplessy 1985 however a map of 13c for the 18 000 yr b p level for a much larger region in the north atlantic shows that minimum n pachyderma 13c occurred in temperate waters n pachyderma 13c decreased toward the southwest reaching a minimum of 1 at 37 n despite the variability seen in 13c records of n pachyderma none of our cores show significant temporal variability in cd ca from the combined cd ca and 13c data we can see no evidence for an upwelling gyre in the eastern north atlantic during the latest glacial maximum nor evidence that the southern and northern oceans had significantly different levels of preformed nutrients than today

biomarker temperature estimates for modern and last glacial surface waters of the california current system between 33 and 42 n sea surface temperature sst estimates were made using data for c37 39 alkenones analyzed in modern and glacial age intervals of sediment cores collected along an east west 42 n from 125 to 132 w and a north south 41 33 n transect of the california current system ccs the prymnesiophyte biomarker results suggest that surface waters warmed significantly throughout this region since the last glacial maximum lgm but the magnitude of warming varied spatially stratigraphic profiles from four sediment cores along the north south transect indicate the warming period was confined to the glacial interglacial transition 15 10 ka with sst reaching a maximum value at 10 ka and maintaining a uniformly high value throughout the holocene comparison of estimates derived from analysis of modern and lgm sediment intervals indicates the magnitude of the sst change was minimal for locations south of about 36 n 1 2 c and increased significantly 3 5 c north of this latitude using a simple heat balance model we calculate from the latitudinal gradient in sst that southward flow in the california current system during the lgm was about 60 of that measured today at 36 n our findings support the conclusion of others based on pollen data that coastal upwelling in the region of the northeast pacific off northern california was significantly reduced or even completely shutdown during the lgm

reconstruction of the last deglaciation deconvolved records of δ18o profiles micropaleontological variations and accelerator mass spectrometric14c dating bioturbation acts as a low pass filter in displacing and reducing the amplitudes of stratigraphic signals this often leads to a loss of high frequency events in the stratigraphic record in addition when considering an isotopic signal 18o 14c measured in stratigraphic carriers such as foraminifera bioturbation and carrier abundance changes can create artifacts which may be falsely interpreted as leads or lags in the paleoclimatic record

dinoflagellate cyst distribution in high latitude marine environments and quantitative reconstruction of sea surface salinity temperature and seasonality a data base of 179 reference sites documents the relations between the assemblages of organic walled dinoflagellate cysts and sea surface temperature salinity and seasonality throughout the north atlantic adjacent subpolar basins labrador sea baffin bay irminger and iceland basins and epicontinental environments off eastern canada estuary and gulf of st lawrence hudson bay principal component analyses show close relationships between dinoflagellate cyst data and sea surface conditions the first component 71 1 of the variance correlates with the winter temperature salinity and seasonal duration of sea ice cover whereas the second component 11 3 of the variance appears mainly related to summer temperature transfer functions using the best analogue method were tested by reconstructing modern sea surface conditions on the basis of the reference dinoflagellate cyst assemblages the correlation coefficient between instrumental averages and reconstructed values ranges from 0 87 august tem

alkenones and multiproxy strategies in paleoceanographic studies 1 we assess multiproxy strategies involving alkenone based and other paleoceanographic indicators in an effort to define uncertainties and to advance understanding of past oceanic and climatic changes looking to the future we recommend a parallel strategy of applying proxies to the geologic record while continuously seeking refinements in methods and understanding of mechanisms that control each proxy a multiproxy strategy increases confidence in results and provides oceanographic context for more effective interpretation of processes a combination of proxies allows derivation of additional properties such as upper ocean paleosalinity or paleo pco2 for a more complete view of the oceanographic and climate mechanisms involved in changing earth s environment

reconstructing sea surface temperature and salinity using δ 18 o and alkenone records the oxygen isotope 18o composition of foraminiferal tests from deep sea sediments is widely used as a palaeoclimate proxy but it includes contributions from sea surface temperature global ice volume and local salinity which are difficult to separate recently a new technique for deriving palaeotemperatures has been developed which is based on the abundance ratios of unsaturated alkenones in phytoplankton algae1 2 here we use a combination of oxygen isotope and alkenone records in a deep sea core from the juncture of the arabian sea and the bay of bengal to extract the salinity signal from the former record variations in salinity are related to the balance between evaporation and precipitation3 and are thus a sensitive indicator of climate change our 170 kyr salinity record enables us to reconstruct changes in the indian monsoon over this period considerably extending earlier studies which reached back to 18 kyr ago 4 8 like these previous studies we find that large variations in the monsoon occurred during the transition from the last glacial period to the present interglacial but our results also provide a view of the monsoon throughout the last glacial and demonstrate the potential of this approach for reconstructing palaeosalinity

simmax a modern analog technique to deduce atlantic sea surface temperatures from planktonic foraminifera in deep sea sediments we present a data set of 738 planktonic foraminiferal species counts from sediment surface samples of the eastern north atlantic and the south atlantic between 87 n and 40 s 35 e and 60 w including published climate long range investigation mapping and prediction climap data these species counts are linked to levitus s 1982 modern water temperature data for the four caloric seasons four depth ranges 0 30 50 and 75 m and the combined means of those depth ranges the relation between planktonic foraminiferal assemblages and sea surface temperature sst data is estimated using the newly developed simmax technique which is an acronym for a modern analog technique mat with a similarity index based on 1 the scalar product of the normalized faunal percentages and 2 a weighting procedure of the modern analog s ssts according to the inverse geographical distances of the most similar samples compared to the classical climap transfer technique and conventional mat techniques simmax provides a more confident reconstruction of paleo ssts correlation coefficient is 0 994 for the caloric winter and 0 993 for caloric summer the standard deviation of the residuals is 0 90 c for caloric winter and 0 96 c for caloric summer at 0 m water depth the sst estimates reach optimum stability standard deviation of the residuals is 0 88 c at the average 0 to 75 m water depth our extensive database provides sst estimates over a range of 1 4 to 27 2 c for caloric winter and 0 4 to 28 6 c for caloric summer allowing sst estimates which are especially valuable for the high latitude atlantic during glacial times an electronic supplement of this material may be obtained on adiskette or anonymous ftp from kosmos agu org login toagu s ftp account using anonymous as the username and guestas the password go to the right directory by typing cd append typels to see what files are available type get and the name of the file toget it finally type exit to leave the system paper 95pa01743 simmax a modern analog technique to deduce atlantic sea surfacetemperatures from planktonic foraminifera in deep sea sediments uwepflaumann josette duprat claude pujol and laurent d labeyrie diskette may be ordered from american geophysical union 2000florida avenue n w washington dc 20009 payment mustaccompany order

forward modeling of carbonate proxy data from planktonic foraminifera using oxygen isotope tracers in a global ocean model the distribution and variation of oxygen isotopes in seawater are calculated using the goddard institute for space studies global ocean model simple ecological models are used to estimate the planktonic foraminiferal abundance as a function of depth column temperature season light intensity and density stratification these models are combined to forward model isotopic signals recorded in calcareous ocean sediment the sensitivity of the results to the changes in foraminiferal ecology secondary calcification and dissolution are also examined simulated present day isotopic values for ecology relevant for multiple species compare well with core top data hindcasts of sea surface temperature and salinity are made from time series of the modeled carbonate isotope values as the model climate changes paleoclimatic inferences from these carbonate isotope records are strongly affected by erroneous assumptions concerning the covariations of temperature salinity and 18ow habitat imposed biases are less important although errors due to temperature dependent abundances can be significant

foraminiferal faunal estimates of paleotemperature circumventing the no analog problem yields cool ice age tropics the sensitivity of the tropics to climate change particularly the amplitude of glacial to interglacial changes in sea surface temperature sst is one of the great controversies in paleoclimatology here we reassess faunal estimates of ice age ssts focusing on the problem of no analog planktonic foraminiferal assemblages in the equatorial oceans that confounds both classical transfer function and modern analog methods a new calibration strategy developed here which uses past variability of species to define robust faunal assemblages solves the no analog problem and reveals ice age cooling of 5 o to 6oc in the equatorial current systems of the atlantic and eastern pacific oceans classical transfer functions underestimated temperature changes in some areas of the tropical oceans because core top assemblages misrepresented the ice age faunal assemblages our finding is consistent with some geochemical estimates and model predictions of greater ice age cooling in the tropics than was inferred by climate long range investigation mapping and prediction climap 1981 and thus may help to resolve a long standing controversy our new foraminiferal transfer function suggests that such cooling was limited to the equatorial current systems however and supports climap s inference of stability of the subtropical gyre centers

tropical pacific ocean thermocline depth reconstructions for the last glacial maximum we evaluate the relationship between ten surface ocean 0 300 m hydrographic parameters and the spatial distribution of factor analyzed core top planktonic foraminiferal abundances in the tropical pacific ocean 24 n 24 s for core tops 3800 m the spatial distribution of the first three faunal factor loadings 88 of the variance are most highly correlated to subsurface variability mixed layer depth thermocline depth and resistant species percent rsp however rsp is not related to dissolution but is related to thermocline depth factor i mixed layer species g glutinata g ruber and factor iii g ruber can be distinguished from each other by low abundances of g glutinata in factor iii both assemblages spatially comprise the deep mixed layer region of the western tropical and equatorial pacific ocean but are associated with distinct water mass properties a combination of factor i and iii loadings shows a higher correlation to thermocline depth r 0 70 factor ii loadings dominated by thermocline dwelling species n dutertrei are most significantly correlated with the thermocline depth r 0 73 most factors show only marginally significant correlation to sea surface temperatures ssts indicating that sst is not the primary forcing factor on the planktonic foraminiferal species distributions in the tropical pacific a new transfer function was calculated to predict tropical pacific thermocline depth from planktonic foraminifera abundances using the imbrie kipp method ikm standard deviation of residuals 22 m 1 an additional 5 m error is attributed to low species counts in the core top database the modern analog technique mat was also used to predict thermocline depth standard deviation of residuals 21 m while last glacial maximum lgm thermocline depth changes by ikm and mat were generally within error estimated changes were geographically uniform suggesting an oceanographic response to climate forcing we estimate that the thermocline depth of the lgm was shallower than present by 20 m south of 8 s possibly due to a shift in the south pacific anticyclone to the northeast both the ikm and mat estimate a steeper east west thermocline slope along the equator suggesting that zonal wind stress walker circulation was intensified during the lgm collectively the thermocline estimates for the lgm suggest an equatorward compression of the climate zones in both hemispheres

incorporation and preservation of mg in globigerinoides sacculifer implications for reconstructing the temperature and 18o 16o of seawater using bathymetric transects of surface sediments underlying similar sea surface temperatures but exposed to increasing dissolution we examined the processes which affect the relationship between foraminiferal mg ca and 18o we found that globigerinoides saccculifer calcifies over a relatively large range of water depth and that this is apparent in their mg content on the seafloor foraminiferal mg ca is substantially altered by dissolution with the degree of alteration increasing with water depth selective dissolution of the chamber calcite formed in surface waters shifts the shell s bulk mg ca and 18o toward the chemistries of the secondary crust acquired in colder thermocline waters the magnitude of this shift depends on both the range of temperatures over which the shell calcified and the degree to which it is subsequently dissolved in spite of this shift the initial relationship between mg ca and 18o determined by their temperature dependence is maintained we conclude that paired measurements of 18o and mg ca can be used for reconstructing 18owater though care must be taken to determine where in the water column the reconstruction applies

geologic time series from deep sea sediments time scales and distortion by bioturbation abstract in order to evaluate the time and frequency domain characteristics of geologic time series obtained from deep sea sediments two important problems must be considered first an accurate time scale must be established for the sediment records to be studied an accurate time scale is a basic requirement for such techniques as spectral and cross spectral analysis secondly the distortion of a geologic time series by sedimentation processes such as bioturbation must be considered if inferences are to be made about the mechanisms controlling climatic and oceanographic processes reflected in the geologic record recently it has been suggested that the periodic components in paleoclimatic records which can be related to variations in the earth s orbital parameters can be used as a means for providing very detailed control for late pleistocene sediment sections a time scale is estimated by tuning an individual frequency component in a climate record to an orbital parameter the tuning procedure commonly uses the technique of bandpass filtering which removes all frequency components except the one equivalent to an orbital parameter and then adjusting the geologic time scale so that the filtered record and orbital record align since bandpass filtering will produce a periodic record from any data set a question is raised as to the circularity of this tuning approach a series of numerical experiments using synthetic time series are used to determine if the tuning of a geologic record artificially induces improved correlation and increased periodic character in a climatic record these experiments indicate that the tuning does not artificially induce these effects thus it is suggested that the careful use of orbital tuning provides a powerful means of defining a geologic time scale the degree to which bioturbation distorts a paleoclimatic record is studied by comparing the spectra of oxygen isotopic records obtained from cores with sedimentation rates ranging from 1 to 12 cm 1000 yr 1 it is shown that the systematic change in the variance spectra of these records that is predicted by models of bioturbation cannot be observed for sedimentation rates greater than 2 cm 1000 yr 1 this can be explained in part if bioturbation is a function of sedimentation rates if this is the case then bioturbation must proceed to depth of tens to hundreds of centimeters however it seems likely that the degree to which bioturbation alters the climate signal preserved in deep sea sediment cores has been overestimated

upwelling and productivity changes inferred from a temperature record in the central equatorial pacific a series of c37 39 alkenones synthesized by prymnesiophyte algae is commonly preserved in marine sediments and can be used for estimating past sea surface temperatures ssts 1 2 here we present an alkenone analysis of sediments taken from the central equatorial pacific ocean core w8402a 14gc 0 57 n 138 57 w which shows that sst varied slightly 2 c but coherently with milankovitch insolation cycles over the past 250 kyr the in phase response of the sst to the precessional component of insolation indicates that this part of the sst time series may be driven by changes in local trade wind strength and the longer 100 kyr eccentricity component indicates a response to basin wide south pacific winds using a simple heat balance model we use our palaeotemperature record to constrain the upwelling rates that have occurred in the past similar sst records from the eastern pacific could constrain the horizontal advection component of the sst record and allow for better estimates of upwelling upwelling and palaeoproductivity then could be compared to determine whether changes in equatorial nutrient levels actually cause equivalent changes in productivity

coccolith sr ca as a new indicator of coccolithophorid calcification and growth rate 1 polyspecific coccolith separates from core top sediments in the eastern equatorial pacific show variations of 15 in sr ca ratios across the equatorial upwelling zone with sr ca highest at the equator and decreasing off axis these variations cannot be due to changes in the sr ca of seawater which varies by less than 2 in the surface ocean variations in sr ca of coccolith sediments are similar to variations in primary productivity and alkenone estimated coccolithophorid growth rates in overlying surface waters and to caco3 rain rates measured in sediment traps because of these relationships and because calcification rate exerts a strong control on sr ca in abiogenic calcites we suggest that the observed sr ca variations in coccoliths may be strongly controlled by coccolithophorid growth and calcification rates although temperature may also influence coccolith sr ca to a lesser degree changes in dissolution intensity and coccolith assemblages appear to exert a minor influence if any on coccolith sr ca in these sediment core tops if further work confirms relationships between coccolith sr ca and coccolithophorid productivity sr ca records of past changes in coccolithophorid productivity may be useful in reconstructing past variations in the rain ratio of organic to carbonate carbon an important control on deep ocean ph and partitioning of co2 between the atmosphere and ocean in addition coccolith sr ca might provide an independent record of past changes in coccolithophorid growth rates which in combination with data on the carbon isotopic fractionation in coccolithophorid organic matter may permit more reliable calculations of past dissolved co2 in the surface ocean

vertical distribution and isotopic fractionation of living planktonic foraminifera from the panama basin a model1 2 which explains the vertical and seasonal distribution of planktonic foraminifera was developed using data from the western north atlantic and is comprised of three tenets 1 the conditions in the photic zone upper 80 100 m exclusively dictate planktonic foraminifera species composition and abundance throughout the water column 2 species are vertically stratified within the photic zone according to their temperature preference depth distribution according to temperature preference has been proposed by several authors3 based on isotope analyses of sediments due to seasonal temperature variations seasonal variations in the 18o composition of seawater and species specific isotope fractionation rigorous proof of this hypothesis cannot be provided from sediment analyses alone 3 the chlorophyll maximum is a major food source zone which is preferentially exploited by foraminifera our data from the panama basin which are presented here are confirmation of this model the panama basin in the eastern equatorial pacific which has a shallow and steep thermocline was sampled for living planktonic foraminifera a multiple opening closing net and environmental sensing system mocness 4 was used to collect 13 sets of eight vertically stratified oblique samples we report here the quantitative distribution and stable isotopic composition of planktonic foraminifera from four mocness tows taken over 5 days during august 1979 rv knorr cruise 73 at 5 20 n 8 50 w each tow consisted of eight samples which integrated 12 5 m intervals from 0 to 100 m for moc 126 25 m intervals from 0 to 200 m for moc 127 100 150 m intervals from 0 to 1 000 m on moc 128 and 250 m intervals from 0 to 2 000 m on moc 131

early diagenesis of lipid biomarker compounds in north atlantic sediments near surface sediments 0 45 mm depth interval from the iceland basin 59 n 21 w 3070 m water depth and biscay abyssal plain 48 n 17 w 4105 m water depth were sectioned at millimeter scale resolution to assess alterations in key lipid biomarkers during early diagenesis inventories g cm 2 in the topmost 45 mm of biomarkers from presumed terrestrial sources c20 linear n alkanes n alkanoic acids n alkanols and from phytoplankton sources phytosterols long chain alkenones and alkenoates were 1 5 4 times more abundant in the iceland basin core than in the biscay abyssal plain core indicating greater sedimentary inputs and or preservation at the iceland basin site biomarker concentrations varied significantly over millimeter scale depth intervals pronounced subsurface concentration maxima were present at both sites at the biscay abyssal plain site steep concentration gradients in the uppermost few mm of the sediment column indicate extensive diagenetic losses at or near the sediment water interface strong covariance was seen in the concentrations of various compounds within each class e g long chain n alkanes n alkanols n alkanoic acids and long chain alkenones and alkyl alkenoates indicating that individual compounds within each class are associated with the same organic matrix and have similar degradation and mixing rates thus biomarker indices for assessment of land derived inputs cpi c29 c31 acl and sea surface temperature ipt remain largely unaltered by early diagenetic processes in oxic abyssal sediments in spite of extensive bioturbation and degradative losses within the uppermost few centimeters of the sediment column

comparison of foraminiferal coccolithophorid and radiolarian paleotemperature equations assemblage coherency and estimate concordancy the imbrie kipp method of paleotemperature estimation is rigorously tested by comparing atlantic temperature equations independently derived from the microfossils of three biotic groups the foraminifera coccolithophorida and radiolaria this method consists of two steps factor analysis of the modern sea bed data of the individual groups which resolves discrete biogeographic assemblages and regression analysis of the modern assemblage data with observed sea surface temperature data to obtain paleotemperature equations assemblage biogeography shows a simple subdivision into warm low latitude and cold high latitude for all biotic groups between biotic groups there is greater similarity among high latitude assemblages than low latitude ones correlating the assemblage data with observed sea surface temperatures to produce temperature distribution patterns shows differences of less than 2 c in their optimum and critical temperatures regression analysis produced accurate temperature equations for each biotic group all with standard errors of estimate of less than or equal to 2 c multiple correlation coefficients were all greater than 0 970 applying these equations to two multiple biotic data sets the modern and ice age sea bed data and comparing their temperature estimates using the standard error pooled shows over 87 concordancy for both data sets unlike the modern data the discordancy among temperature estimates of the ice age data shows a distinct geographic distribution its cause is believed to be oceanographic a difference in the water mass structure between the modern and ice age ocean

microbial degradation of the marine prymnesiophyte emiliania huxleyi under oxic and anoxic conditions as a model for early diagenesis long chain alkadienes alkenones and alkyl alkenoates to investigate the effect of bacterial diagenesis on the distributions of algal lipids the marine haptophyte emiliania huxleyi was incubated with estuarine sediment slurries under defined conditions oxic sulfate reducing and methanogenic rapid initial degradation of lipids corresponded to increased bacterial populations both of which subsequently declined under oxic conditions the algal c31 dienes were rapidly and completely degraded within 178 days extensive degradation of the characteristic c37 methyl alkenones occurred under all conditions up to 85 under oxic conditions however the u37k index remained essentially constant except for a slight increase at the longest oxic incubation time under anoxic conditions the alkyl alkenoates were preferentially degraded relative to the alkenones and changes in the aa36 index occurred these results demonstrate that lipids are part of the labile organic matter however they were generally degraded at multiple rates which slowed during incubation resulting in their partial preservation hence laboratory experiments conducted over only short periods cannot predict the preservation potential of lipid components furthermore preservation differed between sulfate reducing and methanogenic conditions so the roles of anaerobic processes need to be considered individually with regard to oxic vs anoxic preservation

structure and timing of the last deglaciation oxygen isotope evidence foraminiferal oxygen isotope data from 24 tropical atlantic sediment cores constrained by 77 14c dates are stacked to form a composite record of isotopic termination 1 this record indicates that most of the isotopic transition at the end of the last ice age occurred between 14 ka bp and 6 ka bp minor isotopic expression of deglaciation is permitted as early as 16 ka bp but the most rapid rate of change occurred between 14 ka bp and 12 ka bp three steps of maximum change are present although they are close to the statistical limits of detection in the composite record the clear presence of the steps in individual records suggests that they are real we estimate their timing at 14 12 ka bp termination 1 a 10 9 ka bp termination 1 b and 8 6 ka bp termination 1 c centering of the termination near 11 ka bp is consistent with the milankovitch hypothesis that high summer insolation caused deglaciation in detail however maximum rates of change prior to the 11 ka bp insolation extreme and the inferred steps require additional mechanisms controlling the tempo of glacial interglacial climate change steps equivalent to those in 18o have not been detected in ice margin retreat data steps in the isotopic transition if real may record thinning of the ice sheets not accompanied by loss of area alternation between near equilibrium and near stagnant ice sheet profiles during deglaciation is hypothesized perhaps due to calving and unstable down draw of the ice sheets followed by partial re equilibration significant problems remain the effects of temperature on the isotope record are only partially constrained presently available data allow only semi quantitative intercalibration of ice volume sea level and isotopic estimates of glaciation

photosynthetic fractionation of 13c and concentrations of dissolved co2 in the central equatorial pacific during the last 255 000 years carbon isotopically based estimates of co2 levels have been generated from a record of the photosynthetic fractionation of 13c is equivalent to epsilon p in a central equatorial pacific sediment core that spans the last approximately 255 ka contents of 13c in phytoplanktonic biomass were determined by analysis of c37 alkadienones these compounds are exclusive products of prymnesiophyte algae which at present grow most abundantly at depths of 70 90 m in the central equatorial pacific a record of the isotopic composition of dissolved co2 was constructed from isotopic analyses of the planktonic foraminifera neogloboquadrina dutertrei which calcifies at 70 90 m in the same region values of epsilon p derived by comparison of the organic and inorganic delta values were transformed to yield concentrations of dissolved co2 is equivalent to c e based on a new site specific calibration of the relationship between epsilon p and c e the calibration was based on reassessment of existing epsilon p versus c e data which support a physiologically based model in which epsilon p is inversely related to c e values of pco2 the partial pressure of co2 that would be in equilibrium with the estimated concentrations of dissolved co2 were calculated using henry s law and the temperature determined from the alkenone unsaturation index u k 37 uncertainties in these values arise mainly from uncertainties about the appropriateness particularly over time of the site specific relationship between epsilon p and 1 c e these are discussed in detail and it is concluded that the observed record of epsilon p most probably reflects significant variations in delta pco2 the ocean atmosphere disequilibrium which appears to have ranged from approximately 110 microatmospheres during glacial intervals ocean atmosphere to approximately 60 microatmospheres during interglacials fluxes of co2 to the atmosphere would thus have been significantly larger during glacial intervals if this were characteristic of large areas of the equatorial pacific then greater glacial sinks for the equatorially evaded co2 must have existed elsewhere statistical analysis of air sea pco2 differences and other parameters revealed significant p 0 01 inverse correlations of delta pco2 with sea surface temperature and with the mass accumulation rate of opal the former suggests response to the strength of upwelling the latter may indicate either drawdown of co2 by siliceous phytoplankton or variation of co2 si oh 4 ratios in upwelling waters

assessment of sea surface temperature at 42 n in the california current over the last 30 000 years assessment of changes in surface ocean conditions in particular sea surface temperature sst is essential to understand long term changes in climate especially in regions where continental climate is strongly influenced by oceanographic processes to evaluate changes in sst in the northeast pacific we have analyzed long chain alkenones of prymnesiophyte origin at 38 depths in a piston and associated trigger core collected beneath the contemporary core of the california current system at 42 n 270 km off the coast of oregon california the samples span 30 000 years of deposition at this location unsaturation patterns u37k in the alkenone series display a statistically significant difference p 0 001 between interglacial 0 44 0 02 n 11 and glacial 0 29 0 04 n 20 intervals of the cores detailed examination of other compositional features of the c37 c38 c39 alkenone series and a related c36 alkenoate series measured downcore suggests the published u37k temperature calibration u37k 0 034 t 0 039 defined for cultures of a strain of emiliania huxleyi isolated from the subarctic pacific provides best estimates of winter sst at our study site this inference is purely statistical and does not imply however that the phytoplankton source of these biomarkers is most productive in winter or at the ocean surface the temperature record for u37k implies 1 an 4 c shift occurred in winter sst from 7 5 1 1 c at the last glacial maximum to 11 7 0 7 c in the present interglacial period and 2 this warming trend was confined to the time frame 14 10 ka within the glacial to interglacial transition period these conclusions are corroborated entirely by results from an independent sst transformation of radiolarian species assemblage data obtained from the same core materials

how do radiolarian sediment assemblages represent surface ocean ecology in the central equatorial pacific ever since q mode factor analysis has been applied to microfossil data investigators have attempted to determine whether statistical groupings of species in deep sea sediments are ecologically meaningful we address this question for radiolaria using living death and sediment assemblages from the equatorial pacific of the seven sediment assemblages identified from a basin wide analysis four are important in the tropics eastern boundary and transitional sediment assemblages identify ecological environments similar to living assemblages the western pacific sediment assemblage does not appear to represent a natural grouping of species the dominant tropical sediment end member represents a combination of warm water species from subtropical and western pacific environments of the two the predominant signal in tropical sediments is that of the western pacific the implication of a sediment bias toward warm water species may be due to the lack of an important cold water indicator species lophophaena hispida in the sediment analysis

cadmium zinc copper and barium in foraminifera tests the concentrations of cadmium zinc copper and barium have been determined on 2 mg samples of single species foraminifera populations cleaning techniques were tested using north atlantic core tops and followed by a detailed downcore study for the last 30 000 years in south atlantic core v22 174 raw foram tests cleaned by crushing followed by ultrasonic removal of fine grained material and dissolved in a ph 5 5 acetate buffer contain appreciable amounts of trace elements associated with ferromanganese and alumino silicate contaminants a reductive complexing cleaning treatment reduces ferromanganese contamination by 1 2 orders of magnitude acetate buffers at ph 5 5 complex iron and raise the solubility of ferromanganese oxides these buffers are unsuitable for separating carbonate lattice bound trace elements from the fraction associated with ferromanganese phases improved mechanical and ultrasonic reductive cleaning combined with a mild dissolution in distilled water under 1 atm pco2 reduces contaminant levels another order of magnitude the cd and zn concentrations order 10 8 mole cd mole ca and 10 5 mole zn mole ca of species with low surface area show an increase with decreasing isotopic temperatures this increase is consistent with the increasing concentrations of these metals from low values in surface waters to higher values at depth the variance of cd and zn over the last 30 000 years in the central south atlantic is consistent with the probable variability of the dissolved trace elements at the calcification levels of the species analyzed cu and ba are irreproducible and probably sensitive to residual contaminant phases the trace element content of the tests differs from levels observed in a recent coprecipitation study foraminifera may be a significant vector in zinc cycling in the ocean

bioturbational mixing depth and carbon flux at the seafloor radiocarbon dating series bulk sediment and organic carbon flux from various atlantic deep sea regions reveal that the thickness of the bioturbated zone increases by 2 cm if food supply increases by 1 gcm 2yr 1 r 0 8 bulk sediment accumulation rates do not influence the depth of bioturbational mixing under normal pelagic sedimentary conditions we believe that this relationship between nutrient supply and benthic mixing can be used for a quantitative and time variable unmixing procedure to improve high resolution stratigraphic correlations and paleoclimatic interpretations of deep sea records

depth and seasonality of alkenone production along the california margin inferred from a core top transect alkenone unsaturation indices uk 37 of marine sediment could prove particularly useful on organic rich continental margins where carbonate dissolution hampers the use of other paleoclimatic proxies mccaffrey et al 1990 kennedy and brassell 1992 forty core top samples of recent sediment from a latitudinal transect 23 40 n along the california margin yield uk 37 values that correlate linearly with modern mean annual sea surface temperatures ssts in the range of 12 23 c reproducibility of the unsaturation value in closely spaced cores is near analytical error uk 37 data define a relationship to temperature nearly identical to the prahl et al 1988 laboratory cultures of emiliania huxleyi the close agreement is particularly significant in light of the nannofossil composition of the sediments where the abundance of the coccolith taxon gephyrocapsa oceanica known to synthesize alkenones equals or exceeds that of e huxleyi comparison with seasonal temperature variations at different depths indicates that little if any alkenone production occurs at depths 30 m along the continental margin water depths 2 km sediments in more pelagic locations exhibit small but consistent biases toward winter and or subsurface production similar to previously reported sediment trap and core top data from the oregon margin prahl et al 1993 doose et al 1997

alkenone and coccolithophorid species changes in late quaternary sediments from the walvis ridge implications for the alkenone paleotemperature method abstract sea surface temperatures ssts derived from the alkenone u37 record of quaternary sediments may be subject to bias if algae with different temperature sensitivities have contributed to the sedimentary alkenone record the alkenone derived sst records are usually based on a u37 temperature relationship which was measured in culture experiments using the coccolithophorid emiliania huxleyi f g prahl l a muehlhausen and d l zahnle 1988 further evaluation of long chain alkenones as indicators of paleoceanographic conditions geochim cosmochim acta 52 2303 2310 to assess possible effects of past species changes on the u37 temperature signal we have analysed long chain alkenones and coccolithophorids in a late quaternary sediment core from the walvis ridge and compared the results to sst estimates extracted from the 18o record of the planktonic foraminifer globigerinoides ruber alkenones and isotopes were determined over the entire 400 kyr core record while the coccolithophorid study was confined to the last 200 kyr when the most pronounced changes in alkenone content occurred throughout oxygen isotope stages 6 and 5 species of the genus gephyrocapsa were the predominating coccolithophorids e huxleyi began to increase systematically in relative abundance since the stage 5 4 transition became dominant over gephyrocapsa spp during stage 3 and reached the highest abundances in the holocene carbon normalized alkenone concentrations are inversely related to the relative abundances of e huxleyi and directly related to that of gephyrocapsa spp suggesting that species of this genus were the principal alkenone contributors to the sediments nevertheless sst values obtained from the u37 temperature relationship for e huxleyi compare favourably to the isotope derived temperatures the recently reported u37 temperature relationship for a single strain of gephyrocapsa oceanica j k volkman s m barrett s i blackburn and e l sikes 1995 alkenones in gephyrocapsa oceanica implications for studies of paleoclimate geochim cosmochim acta 59 513 520 produces unrealistically high sst values indicating that the temperature response of the examined strain is not typical for the genus gephyrocapsa this is supported by the c37 c38 alkenone ratios of the sediments which are comparable to average ratios reported for e huxleyi but significantly higher than for the g oceanica strain most notably the general accordance of the alkenone characteristics between sediments and e huxleyi persists through stages 8 to 5 and even in times that predate the first appearance of this species 268 ka h r thierstein k r geitzenauer and b molfino 1977 global synchroneity of late quaternary coccolith datum levels validation by oxygen isotopes geology 5 400 404 our results suggest that u37 temperature relationships based on e huxleyi produce reasonable paleo sst estimates even for late quaternary periods when this species was scarce or absent because other alkenone synthesizing algae e g of the genus gephyrocapsa responded similarly to temperature changes

the salinity contrast between the atlantic and pacific oceans during glacial time in today s ocean the salinity of low latitude surface waters in the pacific is on the average 1 per mil lower than in the atlantic oxygen isotope records for planktonic foraminifera suggest that an even larger salinity deficit may have existed for pacific surface water during glacial time if so the transport of water vapor from the atlantic to the pacific must have been as strong as or even stronger to balance the tendency toward salt buildup the atlantic would have had to export during glacial time waters saltier than it received from the other oceans

application of artificial neural networks to paleoceanographic data abstract artificial neural networks are computer systems that have the ability to learn a set of output or target vectors from a set of input vectors learning is achieved by self adjustment of a set of parameters to minimize the error between a desired output and the actual network output we have explored the potential of this approach in paleoceanography by application of a neural network algorithm to a problem involving prediction of sea surface water temperatures from relative abundances of planktonic foraminifer species in the southern indian ocean we employed a backpropagation bp network to assess how well it was able to predict the actual summer and winter surface water temperatures we compared the results with those obtained from statistical methods previously used for temperature predictions imbrie kipp transfer functions the modern analog technique and soft independent modelling of class analogy the efficiency of predictions was tested using the leaving one out technique in which each of the observations in the data set is left out one at a time while the remaining observations are used to generate a predictor the accuracy of the predictor is then tested on the observation left out by comparison with its actual value a set of tests using 1 2 3 4 5 and 10 neurons processing elements in a 3 layer bp network showed that a network with 3 neurons gave the smallest errors of prediction for both summer and winter temperatures 0 71 and 0 76 respectively corresponding errors for the statistical pattern recognition techniques ranged between 1 01 and 1 26 for summer temperatures and 1 05 1 13 for winter temperatures hence predictions of paleotemperatures from new data on planktonic foraminifer relative abundances in the southern indian ocean may be made with a precision of 0 7 0 8 c using the bp network and 1 0 1 3 c using the statistical pattern recognition procedures the bp network was thus the most successful among the methods employed here for temperature predictions artificial neural networks may therefore be seen as a viable alternative to more conventional approaches to data analysis in paleoceanography

paleoceanographic reconstructions from planktonic foraminifera off the iberian margin temperature salinity and heinrich events a quantitative analysis of planktonic foraminifera in a core from the iberian margin allows a reconstruction of the evolution of oceanographic parameters during the last glacial cycle with a resolution of 1000 years a principal component analysis performed on 19 species allows the identification of 11 intervals characterized by increased abundances of the subpolar species the youngest six of these intervals are correlated with the last 6 heinrich events hes the five cold events older than stage 4 are dated at 81 90 110 129 and 140 ka respectively paleotemperatures reconstructed using the modern analog technique indicate 4 c decreases during all even numbered isotopic stages and stage 3 during the hes temperature decreases reach 10 c and seawater 18o anomalies reach 1 temperature and salinity reconstructions indicate that the environment of the iberian margin has been under the combined influence of global factors such as the migration of the polar front and iceberg discharge and of regional factors such as the precipitation evaporation regime on both oceanic and continental area

faunal and alkenone reconstructions of subtropical north atlantic surface hydrography and paleotemperature over the last 28 kyr two techniques for estimating past variations in sea surface temperature sst have been used to investigate climatic change in biogeochemical oceanic flux study bofs core 31k 19 n 20 w from the eastern subtropical atlantic high resolution sst records for the last 28 kyr have been produced using planktonic foraminiferal assemblages based on the imbrie kipp transfer function technique and the uk 37 index derived from abundances of c37 alkenones biosynthesized by prymnesiophyte algae modern observations suggest that these indices reflect particular hydrographic conditions in the upper ocean the uk 37 index corresponds to the temperature at the time of maximum coccolith productivity typically late spring early summer in the study area today whereas the faunal transfer function is calibrated for seasonal maximum and minimum temperatures in general the faunal and biomarker paleotemperature records display comparable sst variations during the last glacial and deglacial but although the overall trends are similar differences exist in the magnitude and timing of these temperature changes most notably the faunal twarm and uk 37 sst estimates diverge by 3 c between 8 ka and 6 ka and this offset persists through the late holocene this difference cannot be adequately explained by uncertainties associated with either the calibration data sets or fluctuating preservation levels we therefore propose that the deviation in sst estimates is linked to a switch in the seasonal timing of maximum coccolith production from the summer in the glacial ocean to the late spring early summer in the modern ocean our results suggest that a dual approach to sst estimation based on faunal and biomarker proxies can provide a valuable means of evaluating mixed layer and productivity changes associated with the movement of oceanographic frontal zones during the late quaternary

planktonic foraminifera as recorders of past surface water stratification the 18 o difference between shallow and deep living planktonic foraminifera is a proxy for the stratification of surface waters in holocene sediments from the atlantic this difference increases from about 0 in subpolar regions to 3 in the tropics the 18 o values of the shallow dwellers globigerinoides sacculifer and neogloboquadrina pachyderma mainly reflect surface water conditions the calcification depth of the deep living species globorotalia truncatulinoides right coiling is affected by the stratification of the water column in the subtropics shell formation of g truncatulinoides right coiling begins in weakly stratified surface waters in the tropics the initial shell is secreted below the mixed layer this hydrographically induced difference in calcification depth allows the use of the isotopic difference between g truncatulinoides and the shallow species as a proxy for the stratification of surface waters the 18 o between g truncatulinoides and g sacculifer from tropical gravity core geob 1523 1 was significantly lower during isotope stage 2 this suggests that the glacial temperature stratification of western equatorial atlantic surface waters was significantly reduced relative to the holocene

climate impact of late quaternary equatorial pacific sea surface temperature variations magnesium calcium data from planktonic foraminifera in equatorial pacific sediment cores demonstrate that tropical pacific sea surface temperatures ssts were 2 8 0 7 c colder than the present at the last glacial maximum glacial interglacial temperature differences as great as 5 c are observed over the last 450 thousand years changes in sst coincide with changes in antarctic air temperature and precede changes in continental ice volume by about 3 thousand years suggesting that tropical cooling played a major role in driving ice age climate comparison of sst estimates from eastern and western sites indicates that the equatorial pacific zonal sst gradient was similar or somewhat larger during glacial episodes extraction of a salinity proxy from the magnesium calcium and oxygen isotope data indicates that transport of water vapor into the western pacific was enhanced during glacial episodes

effects of quaternary sea level cycles on strontium in seawater abstract the effects of quaternary sea level changes on the sr budget of the ocean are investigated using coupled numerical models of the seawater sr and ca budgets glacial interglacial sea level cycles influence the sr concentration of seawater directly through the periodic exposure and weathering of aragonite on continental shelves and indirectly by modulating the location and extent of carbonate deposition in the ocean as sea level recedes brief pulses of sr are added to the ocean from recrystallization of shelf aragonite this flux at its maximum is nearly ten times larger than the combined riverine and hydrothermal influx the large shelf recrystallization fluxes during glacial maxima produce rapid increases in the sr ca ratio of seawater despite the long residence time of sr in the ocean variations in the ratio of aragonitic vs calcitic sedimentation also influence on the sr content of seawater because the sr partitioning coefficient is higher in aragonite however this effect is minor compared to shelf aragonite recrystallization based on a variety of sensitivity tests the amplitude of sr ca variations ranges from 1 to 3 and is maximized by constant rates of total carbonate deposition extensive aragonite recrystallization and carbonate budgets which include dissolution of shelf carbonates such variation is sufficient to produce up to 1 5 c errors in paleotemperatures calculated from coral sr ca ratios since the last glacial maximum

paleoproductivity from benthic foraminifera abundance glacial to postglacial change in the west equatorial pacific surface productivity is correlated with the rate of accumulation of benthic foraminifera on the deep sea floor as a rule of thumb for each 1 mg of organic carbon arriving at the sea floor one benthic foram shell 150 m is deposited the correlation can be used to reconstruct organic flux to the sea floor in the past and hence the productivity of past oceans applying the appropriate equations to box core data from the ontong java plateau in the western equatorial pacific we found that productivity during the last glacial maximum exceeded present productivity by a factor of between 1 5 and 2 0 with intermediate values for the mid transition period accumulation of benthic foraminifera was depressed on top of the plateau during the glacial and transitional period presumably because increased winnowing removed part of the food supply

radiolarian based transfer functions for estimating mean surface ocean temperatures and seasonal range new radiolarian based transfer functions to estimate sea surface temperature sst and seasonal range are presented the transfer fonctions are based on the approach originated by imbrie and kipp 1971 the transfer functions differ from previous studies in the following three important ways 1 extensions to q mode factor analysis provide an objective method to cull species in the very diverse radiolarian population 2 a log transform of the relative abundance data is used to normalize the species percent data and 3 rather than writing equations for specific seasons which are not independent data sets statistically independent equations are developed to predict mean annual sea surface temperatures as well as seasonal temperature range one hundred and seventy surface sediment samples from the pacific ocean are used to generate the sst and season temperature range transfer functions all samples were counted using a standardized radiolarian taxonomy forty one radiolarian species were used in the final regression equation q mode factor analysis of this data set identified seven assemblages these assemblages the tropical transitional antarctic bering sea western pacific central gyre and eastern boundary current are named for the oceanographic regions where these assemblages are important the seven assemblages are used in a regression analysis to predict sst and seasonal temperature range the standard error of estimates for both mean sst and seasonal temperature range is 1 6 c comparison between radiolarian based ssts and sst estimates from alkenone uk37 in a 20 000 year long record from the northeast pacific shows excellent agreement comparison of mean sst estimates for the last glacial maximum lgm based on radiolarian and foraminifera in 10 eastern equatorial pacific also show excellent concordance these new lgm estimates suggest that the original climate long range investigation mapping and prediction climap reconstruction for this region underestimated surface ocean cooling

dike induced reverse faulting in a graben normal fault slip of the boundary faults of a graben is commonly attributed to dike induced stresses here however we report for the first time clear field evidence of a large dike induced reverse fault slip on a fault associated with a volcano tectonic graben the measured reverse faulting of at least 5 m occurs in the holocene rift zone of northern iceland the reverse slip has apparently occurred on an existing normal fault as a result of over pressure of a nearby 6 13 m thick 8 ka feeder dike a numerical model of the dike fault interaction supports our interpretation the results indicate that dikes particularly potential feeder dikes may cause large reverse slips on nearby normal faults this conclusion should improve the general understanding of geodetic deformation during volcanic unrest periods and may help forecast dike fed eruptions

palaeoclimatic signals recognized by chemometric treatment of molecular stratigraphic data abstract the high resolution stratigraphy of various marker compounds has been studied using gc hplc and gc ms in a 13 m gravity core recovered from the kane gap region eastern equatorial atlantic which provides a record of the glacial interglacial episodes over the last million years downhole variations in many presumed source specific components are observed e g in n alkanes from terrigenous land plants and dinosterol from dinoflagellates which may be due to perturbations or cyclicities resulting from climatic change fluctuations in the unsaturation of alkenones attributable to variations in water temperatures show correlations with the glacial interglacial cycles recorded in the 18 o values for planktonic foraminifera thereby providing a potential organic geochemical measure of past climates these molecular abundance data can be linked to the palaeotemperature record following computer treatments using principal component and spectral analyses molecular stratigraphy shows promise as a new chemostratigraphical tool where other means of stratigraphy fail for example through calcium carbonate dissolution

deep dwelling planktonic foraminifera of the northeastern pacific ocean reveal environmental control of oxygen and carbon isotopic disequilibria abstract we assess the utility of four species of living planktonic foraminifera as tracers of thermocline and intermediate water masses in the northern pacific ocean based on their water column distribution and shell isotopic composition assuming oxygen isotopic equilibria with the water column we infer apparent calcification depths this allows an estimate of apparent carbon isotopic disequilibria we then relax the assumption of oxygen isotopic equilibrium to examine habitat effects on kinetic disequilibrium processes in the california current left coiling neogloboquadrina pachyderma and globigerina calida calcify in the upper thermocline globorotalia scitula resides within the shallow salinity minumum potential density 25 1 26 7 while globoquadrina hexagona is associated with the deeper north pacific intermediate water 26 7 26 9 apparent carbon isotopic disequilibria corrected for oxygen isotopic disequilibria range from 1 0 1 9 in these asymbiotic species the carbon isotopic disequilibrium can be modeled as a single exponential function of temperature or a logarithmic function of potential food supply we infer that carbon isotopic disequilibrium increases with metabolic rate related to temperature and or food supply kinetic processes of oxygen and carbon isotopic disequilibria yields reasonable depth habitats if the slope of the oxygen carbon isotopic shift is about 0 35 consistent with culture data our finding of a link between environment metabolism and isotopic disequilibrium observed in oceanic settings suggests the potential to better reconstruct the structure and biological processes of the upper water column from geologic data

oxygen isotope records and salinity changes in the northeastern atlantic ocean during the last 18 000 years a comparison of the deglaciation 18o record of northeastern atlantic core su 81 18 with that calculated by adding the 18o changes due to sea surface temperature and ice volume variations shows that planktonic foraminifera have also recorded seawater 18o changes due to salinity local advection and evaporation precipitation e p changes using a simple ocean box model of meltwater dilution during the deglaciation we show that sea surface salinity covaried with temperature despite the injection of meltwater associated with the climate warming sea surface salinity was high when sea surface water was warm and low during cold events this implies that the combined effect of local e p changes and northward advection of saline subtropical water were the main factor responsible for the surface water salinity variations in the northeastern atlantic ocean during the last 18 000 years

neogloboquadrina pachyderma sinistral coiling as paleoceanographic tracers in polar oceans evidence from northeast water polynya plankton tows sediment traps and surface sediments the abundance and chemistry of the planktonic foraminifera neogloboquadrina pachyderma sinistral coiling have long been used as tools for monitoring polar surface ocean changes and for correlating these changes to atmospheric and thermohaline circulation fluctuations however due to its remote habitat very little is known about how modern n pachyderma s respond to changing environmental conditions in the polar seas modern samples of n pachyderma s from the northeast water polynya provide a means for studying how environmental conditions affect the vertical distribution and chemistry of this species highest abundances of n pachyderma s were associated with the chlorophyll maximum in the surface 20 80 m where they are exploiting their primary food source evidence suggests that the addition of a calcite crust modifies the calcite tests of some n pachyderma s between 50 and 200 m increasing shell density and modifying shell chemistry the shell mass of encrusted forms is 3 4 times greater than the nonencrusted forms between 50 and 200 m the oxygen isotope composition of n pachyderma s shells increase by 1 5 in response to local water column gradients the 13c values of n pachyderma s are basically invariant with depth in this region are consistently 1 0 depleted in comparison with the 13c for equilibrium calcite and remain basically constant during the shell thickening process mass balance calculations suggest that encrustation occurs at all depths but abundance counts suggest that the process occurs mostly at the depth of the main pycnocline sediment fluxes of n pachyderma s occur during a 2 week bloom event and decrease to almost zero below complete ice cover the decoupling of the processes controlling abundances and shell chemistry explain the discrepancies between transfer function and isotopically derived paleotemperature estimates of surface conditions in some oceanic settings the ability of 18o to record surface ocean conditions will depend on vertical water column gradients as evidenced by the differences in core top calibrations between the north and south atlantic

variation of foraminiferal sr ca over quaternary glacial interglacial cycles evidence for changes in mean ocean sr ca 1 records of sr ca changes in planktonic and benthic foraminifera from diverse hydrographic settings reveal coherent variability 5 1 between ocean basins and between surface and deep waters over the past 300 kyr there is a general increase in foraminiferal sr ca over the penultimate glaciation declining to minimum values during stage 5 and an increase in sr ca from stage 5 through stage 2 coincident changes in benthic foraminifera records from the atlantic and pacific basins imply that sr ca variations are not dominated by dissolution planktonic culturing data provide evidence that the downcore sr ca variations are not controlled by temperature changes and suggest only a small influence of salinity and ph variation common to the records is most readily explained by changes in mean ocean sr ca if fossil foraminifera reliably record higher glacial seawater sr ca coral sr paleothermometry would underestimate sea surface temperature during glacialepisodes

testing the effects of tropical temperature productivity and mixed layer depth on foraminiferal transfer functions statistical transfer functions relate living planktonic foraminiferal species of the central equatorial pacific to measured sea surface temperature integrated primary productivity and mixed layer depth the faunal estimates successfully reconstruct latitudinal patterns observed in both warm el nino february march 1992 and cool la nina august september 1992 seasonal settings predictions of mixed layer depth appear to be unbiased by temperature or productivity in our data set but tend to underestimate deep mixed layers interactions between productivity and temperature perhaps through their common influence on respiration and growth rates bias foraminiferal transfer functions for both properties paleoceanographic estimates may be improved by accounting for such biological processes that translate the environment into a faunal response preserved in the geologic record

what level of resolution is attainable in a deep sea core results of a spectrophotometer study a minolta cm 2022 spectrophotometer has been used to characterize downcore fluctuations in sediment lightness and color in core neap15k a 7 m core collected from the northeast atlantic ocean high resolution data series measured using a 4 mm diameter measurement spot and a 1 cm sampling interval were generated along two independent tracks down the core to investigate the statistical significance of fluctuations across the 2 20 cm depth range this small scale variability is characterized by abrupt changes in the lightness and color of the sediment that are several orders of magnitude greater than the instrumental precision our results establish that significant information is preserved at the 1 cm scale in spite of bioturbation effects these findings demonstrate that high resolution studies using conventional paleoclimatic proxies have the potential to recover meaningful century scale climate records in regions of the ocean where sedimentation rates exceed 10 cm per thousand years the coherency of these downcore records also implies that the spectrophotometer is a powerful instrument for establishing precise centimeter scale stratigraphic correlations between cores

combined coccolith foraminiferal and biomarker reconstruction of paleoceanographic conditions over the past 120 kyr in the northern north atlantic 59 n 23 w we present data for north atlantic core biogeochemical ocean flux study bofs 16k 59 n 23 w water depth 2370 m including coccolith flora 18o planktonic foraminiferal sea surface temperatures ssts by fa20 and simmax methods and alkenone based u37k and u37k ssts a good correlation exists between the abundances of cold water coccolith species and foraminifera and a broad correlation exists between coccolith and alkenone abundances except in the holocene reworked cretaceous coccoliths at the last glacial maximum are coincident with warm deviations of the u37k signal assessment of various calibrations of u37k and u37k with paleotemperature shows the inappropriateness of a global correlation we have produced a north atlantic u37k calibration on the basis of north atlantic data alone u37k 0 026t 0 186 which produces sst data for summer season at 0 m water depth comparable to the warm season foraminiferal ssts except during the intervals 26 36 58 65 and 100 120 ka when the alkenones indicate somewhat cooler surface waters

geological effects of the gulf stream system on the northern bermuda rise abstract the gulf stream system contains a clockwise rotating set of bottom currents which influence the sea bed in the northern north american basin it is possible to interpret the present day and historical record of current activity in this basin in terms of the deep flow of the gulf stream this interpretation provides a much more satisfactory and consistent explanation of the geologic record than previous interpretations based strictly on the influence of the classic abyssal circulation the present day circulation of the gulf stream actively resuspends large quantities of sediment on and near the northern bermuda rise and it is suggested that this resuspension may be due to the eddy field which is embedded in the westward flowing return flow during the late cenozoic the gulf stream system was responsible for depositing and shaping the major acoustic sedimentological units on the relatively smooth surface of the horizon a complex fine grained mont morillionite rich sediments derived from the chemically weathered saprolites of the hudson and st lawrence drainage basins were injected into the deep ocean basins by turbidity currents during the late paleogene and the neogene fine grained turbidites from the st lawrence spread southward down the southeastern sohm abyssal plain across the eastward flowing gulf stream and its westward flowing return flows portions of these fine grained sediments were entrained by the main and return flows and deposited downstream as acoustically non laminated accumulations on the corner and bermuda rises respectively the hudson river input was injected into the deep basin through the hudson canyon system the interaction of these fine grained turbidites with the northward flowing deep flow of the gulf stream system led to the formation of the gulf stream outer ridge here defined for the first time during the late neogene or early pleistocene the gulf stream outer ridge was partially eroded by the gulf stream system and portions subsequently covered by coarse grained pleistocene turbidites the coarse grained illite rich turbidites that flowed across the southeastern sohm abyssal plain also crossed the main and return flows of the gulf stream system the finer portions of these sediments were entrained and deposited as pleistocene acoustically laminated sediments on the plateaus of the bermuda and corner rises

modern and last glacial maximum sea surface δ18o derived from an atmospheric general circulation model the past isotopic contents of sea surface waters 6 cannot be measured directly although they would be a good indicator of ocean circulation through their relationship with sea surface salinities a method of 6 reconstruction is proposed based on the use of outputs from an atmospheric general circulation model including a full isotopic model using the outputs of the nasa giss isotopic gcm and a simple box model we have established that there is a strong correlation r 0 75 between atmospheric fluxes and s measured in the frame of geosecs program indicating that 6 is largely governed by atmospheric fluxes this justifies the use of the present day statistical relationship reflecting essentially the strong atmospheric forcing on sea surface water for different conditions to those prevailing during the last glacial maximum for this period over subtropical areas lower isotopic compositions are obtained in the atlantic ocean whereas higher values are obtained in the indian and pacific oceans thus reducing the isotopic contrast between the atlantic and pacific oceans the pacific and indian oceans show a similar isotopic pattern with the tropical s values accentuated by a marked decrease in the equatorial zone however whereas the predictions from the atlantic and indian oceans exhibit good agreement with proxy data derived from foraminifera important discrepancies exist in the pacific ocean

molecular stratigraphy a new tool for climatic assessment variations in sea surface temperatures over the past 500 000 years are inferred from the relative abundance behaviour of two organic compounds c37 alkenones over the upper 8 metres of a sediment core from the eastern equatorial atlantic this molecular record ascribed to contributions from prymnesiophyte algae correlates well with the variations in the 18 signal for the calcareous skeletons of certain planktonic foraminifera thus providing the first demonstration of a new stratigraphical technique which may be especially valuable where methods based on carbonate 18 fail

paleosalinity and δ18o a critical assessment in paleoceanography a traditional application of oxygen isotope ratios in fossil carbonate from deep sea cores concerns the reconstruction of paleotemperatures recently isotopic data have been increasingly employed in the reconstruction of paleosalinities as well this application involves a number of basic assumptions a critical review of which is presented here as the calculation of paleosalinity from 18o residuals assumes constant and linear surface water salinity s 18o relationships we investigate this basic assumption for areas with important and variable freshwater budget and or sea ice influences we show that it is particularly unwarranted to assume such temporally invariant linearity in temperate and subpolar seas because of the effects of freezing and melting more critically we argue that the determinant of many regions s 18o is advection not the local water balance so that the basic 18o of seawater in many regions of the world ocean would likely have changed in a manner somewhat different from that expected from the ice volume record although the differences may not be significant for the gross reconstruction of such features as past sea level we believe they do potentially bias paleosalinity reconstructions mostly toward high salinities to fully exploit the potential of oxygen isotope records as quantitative paleosalinity indicators both the spatial and temporal variabilities need to be constrained hence we recommend that 1 for any time slice of specific interest to paleoceanographic and paleoclimatological studies a coupled ocean atmosphere isotope model or at least an ocean isotope model driven by a paleoclimate isotope model should be used to define the distribution of the base mixing end member 18o of sea water 2 much further regional scale research is needed on flux rates and isotopic compositions of the various terms in the freshwater budget as well as on the variability in the various advective terms the latter variability may be assessed from reconstructions of past seaice distributions and of volume fluxes isotopic compositions of outflow from marginal seas and through sea straits passages

oxygen 18 salinity relationship simulated by an oceanic general circulation model the distribution of h218o in the ocean is simulated using an oceanic general circulation model gcm surface isotopic fluxes prescribed to this model are derived from an atmospheric gcm which ensures their consistency the oceanic gcm is initialized with a homogeneous composition and redistributes isotopic gradients so as to equilibrate with the atmosphere a good agreement is found between the observations and the simulation concerning i the interbasin h218o gradients especially the atlantic being more enriched than the pacific as well as the meridional gradients and ii the h218o salinity relationship

foraminiferal magnesium in globeriginoides sacculifer as a paleotemperature proxy foraminiferal magnesium shows increasing promise as a paleothermometer but the accuracy and precision are limited by biases introduced by partial dissolution salinity variations mg rich gametogenic calcite and contaminant phases we improved cleaning methods and reduced errors introduced by partial dissolution by sampling from well preserved cores in the equatorial atlantic and the caribbean sea with different dissolution histories all cores reveal a synchronous 25 increase in mg ca from the stage 2 3 boundary to the holocene core top indicating that dissolution is not a controlling factor modern temperatures estimated from core top mg ca are 24 5 25 0 c equal to mean annual water temperatures at 50 100 m we estimate that sea surface temperature increased by 2 6 c 1 3 from the last glacial maximum to the holocene holocene values were comparable to those during isotope stage 5e our data indicate that biases from contaminant phases and partial dissolution can be reduced this paleothermometer holds promise if uncertainties introduced by salinity variations and gametogenic calcite can be constrained

glacial interglacial changes in subantarctic sea surface temperature and δ18o water using foraminiferal mg laboratory culturing experiments with living globigerina bulloides indicate that mg ca is primarily a function of seawater temperature and suggest that mg ca of fossil specimens is an effective paleotemperature proxy using culturing results and a core top neogloboquadrina pachyderma calibration we have estimated glacial interglacial changes in sea surface temperature sst using planktonic mg ca records from core rc11 120 in the subantarctic indian ocean 43 s 80 e and core e11 2 in the subantarctic pacific ocean 56 s 115 w our results suggest that glacial sst was about 4 c cooler in the subantarctic indian ocean and 2 5 c cooler in the subantarctic pacific comparison of sst and planktonic 18o records indicates that changes in sst lead changes in 18o by on average 1 3 kyr the glacial interglacial temperature change indicated by the subantarctic mg ca records suggests that temperature accounts for 40 60 of the foraminiferal 18o change we have used the mg ca based sst estimates and 18o determinations to generate site specific seawater 18o records which suggest that seawater 18o was on average 1 more positive during glacial episodes compared with interglacial episodes

subtropical north atlantic temperatures 60 000 to 30 000 years ago a reconstruction of sea surface temperature based on alkenone unsaturation ratios in sediments of the bermuda rise provides a detailed record of subtropical climate from 60 000 to 30 000 years ago northern sargasso sea temperatures changed repeatedly by 2 to 5 c covarying with high latitude temperatures that were previously inferred from greenland ice cores the largest temperature increases were comparable in magnitude to the full glacial holocene warming at the site abrupt cold reversals of 3 to 5 c lasting less than 250 years occurred during the onset of two such events greenland interstadials 8 and 12 suggesting that the largest most rapid warmings were especially unstable

interhemispheric appraisal of the value of alkenone indices as temperature and salinity proxies in high latitude locations alkenone sediment data from the nordic seas and north atlantic are compared to those from sikes et al 1997 for the southern ocean to evaluate further uk37 and uk37 as proxies to estimate cold temperatures 10 c and the effect of salinity and temperature in the relative abundance of 37 4 to the total abundance of c37 alkenones 37 4 uk37 and uk37 are found to be equally viable as proxies but there are significant regional differences in their cold temperature dependence the measurement of 37 4 in cores from the north atlantic region can be used to identify situations when uk37 is not a reliable paleothermometer variations in salinity are probably responsible for changes in the sedimentary record of 37 4 and a preliminary calibration has been obtained for 37 4 f salinity this new relationship should be further confirmed through field or laboratory experiments but it paves the way to derive a molecular proxy to reconstruct paleosalinity in surface waters

planktonic foraminiferal cd ca paleonutrients or paleotemperature records of cd ca in planktonic foraminiferal calcite of globigerinoides bulloides in cores from the subantarctic region of the southern ocean show large glacial interglacial variations with lower cd ca by 0 06 0 10 mol mol 1 at glacial times interpretation of these records in terms of lower dissolved phosphate and inferred higher glacial nutrient utilization has significant implications for glacial atmospheric carbon dioxide pco2 draw down however box core top data for g bulloides in the north atlantic suggest that the incorporation of cd into planktonic foraminifera relative to seawater dcd is temperature sensitive dcd 0 637 exp 0 15t when the subantarctic planktonic cd ca records are corrected for this temperature dependence they show little or no glacial interglacial diferences if as seems likely this observation can be interpreted to indicate a minimal change 0 5 mol kg 1 in surface water phosphate concentrations then the explanation for lowered glacial pco2 must be looked for elsewhere