return of the coral reef hypothesis basin to shelf partitioning of caco3 and its effect on atmospheric co2 differences in the rate of coral reef carbonate deposition from the pleistocene to the holocene may account for the quaternary variation of atmospheric co sub 2 volumes of carbonate associated with holocene reefs require an average deposition rate of 2 0 times 10 sup 13 mol yr for the past 5 ka in light of combined riverine mid ocean ridge and ground water fluxes of calcium to the oceans of 2 3 times 10 sub 13 mol yr the current flux of calcium carbonate to pelagic sediments must be far below the pleistocene average of 1 2 times 10 sub 13 mol yr the authors suggest that sea level change shifts the locus of carbonate deposition from the deep sea to the shelves as the normal glacial interglacial pattern of deposition of quaternary global carbonates to assess the impact of these changes on atmospheric co sub 2 a simple numerical simulation of the global carbon cycle was developed atmospheric co sub 2 as well as calcite saturation depth and sediment responses to these carbonate deposition changes are examined atmospheric co sub 2 changes close to those observed in the vostok ice core approximately 80 ppm co sub 2 for the quaternary are observed as well as the approximate depth changes in percent carbonate of sediments measured in themore pacific ocean over the same time interval less

atmospheric oxygen 18 and sea level changes past isotopic composition of atmospheric oxygen 18oatm can be inferred from the analysis of air bubbles trapped in ice caps the longest record covers the last 420 ka thousand of years at the vostok site in east antarctica it shows a strong modulation by the precession and striking similarities but also noticeable differences with the deep sea core oxygen 18 record from which changes in the oxygen content of sea water 18osw and in sea level can be derived indeed 18oatm is driven by complex fractionation processes occuring during respiration and photosynthesis both 18oatm and its difference with respect to 18osw the dole effect are influenced by factors such as the ratio of oceanic and terrestrial productivities which may have significantly changed between different climates also the response time of 18oatm to oceanic changes should be taken in consideration but this parameter itself depends on biospheric activity we review the various aspects of the link between the 18oatm and the 18osw signals we also examine the approach followed by shackleton science 2000 for deriving sea level change from the 18oatm vostok record assuming that the phase between this record and insolation changes is constant and that the dole effect is a fraction of the precessional component of the 18oatm signal glaciological constraints on the vostok chronology and the complexity of the dole effect show that those two assumptions are quite probably too simplistic

u th ages obtained by mass spectrometry in corals from barbados sea level during the past 130 000 years the study of the sea level record during the last glacial cycle has primarily proceeded indirectly by means of oxygen isotope measurements on foraminifera from deep sea sediments1 2 the direct approach of dating sea level indicators stagnated during the past decade mainly because the samples required to complete our knowledge of the past glaciations are below the present day sea level3 7 using the 14c ages of acropora palmata samples collected by drilling offshore the island of barbados fairbanks8 presented the first detailed chronology for the last deglaciation this radiocarbon chronology is limited to the past 30 kyr because of the short half life of 14c 5 730 yr we must therefore rely on other dating methods to obtain information for the whole last glacial cycle during the past four years 230th 234u dating of corals by thermal ionization mass spectrometry has been shown to be significantly more precise and accurate than the classical counting method9 14 we have used this technique to measure u th ages in coral samples from the barbados collection and from subaerially exposed outcrops see also ref 15 here we present results bearing on the sea level record for the past 130 000 years we conclude that the last deglaciation started 3 000 years earlier than previously thought and confirm that there were two surges in melt water8 at about 11 kyr and 14 kyr bp before present

extending the vostok ice core record of palaeoclimate to the penultimate glacial period the ice core record of local temperature dust accumulation and air composition at vostok station antarctica now extends back to the penultimate glacial period 140 200 kyr ago and the end of the preceding interglacial this yields a new glaciological timescale for the whole record which is consistent with ocean records temperatures at vostok appear to have been more uniformly cold in the penultimate glacial period than in the most recent one concentrations of co2 and ch4 correlate well with temperature throughout the record

glacial interglacial variability in denitrification in the world s oceans causes and consequences the late quaternary history of water column denitrifcation of the eastern pacific margins and the arabian sea is reconstructed using sedimentary 15n measurements the 15n values in six piston cores raised from these regions show remarkably similar cyclic variations being heavy 9 10 5 during the interglacials and 2 3 lighter during the glacials this implies that denitrification in these regions decreased substantially during the glacial periods the glacial decline in denitrification is attributed to reduced upwelling and flux of organic material through the oxygen minimum zone since water column denitrification in these areas accounts for about half of the fixed nitrogen loss in the modern ocean the inferred decrease in denitrification should have increased the oceanic nitrate inventory during glacial periods because nitrate is a limiting nutrient oceanic productivity and attendant changes in co2 may therefore have been modulated on glacial interglacial timescales by variations in the oceanic no3 content

palaeoclimatological and chronological implications of the vostok core dust record the2 083 m vostok ice core recovered by the soviet antarctic expeditions has provided much information of climatic and environmental interest for a period covering a full glacial inter glacial cycle1 6 here we present and discuss the dust record obtained down to 2 202 m the final depth to which this core was extended in 1986 first we document the fact that major changes in aeolian deposits as recorded in the vostok core appear to be of global significance and confirm the existence of a link between high latitude aeolian deposits and the earth s orbital parameters7 8 second we propose atmospheric dust as a strati graphic marker to compare timing with other records of palaeocli mate and use the magnetic susceptibility profile measured along the rc11 120 indian ocean core9 for this purpose assuming that major dust events correspond to common aeolian inputs this approach indicates that the vostok and marine records were roughly in phase at the previous glacial interglacial transition

a tropical mechanism for northern hemisphere deglaciation 1 we investigate the role of the tropics in the melting and reforming of the laurentide ice sheet on glacial timescales using an atmospheric general circulation model it is found that warming of tropical sea surface temperatures ssts from glacial boundary conditions as observed at the end of glacial periods causes a large increase in summer temperatures centered over the ice sheet forming regions of canada this highlatitude response to tropical change is due to relatively small changes in the circulation of the extratropical atmosphere which lead to changes in the vertical profiles of temperature and moisture in the extratropical atmosphere the maximum perturbation in the summer radiative balance over the laurentide ice sheet 25 w m 2 due to the changes in the local atmospheric water vapor inventory is much larger than that induced by glacial to interglacial changes in atmospheric co2 these changes via an atmospheric bridge between the tropics and extratropics represent a mechanism for deglaciations which is consistent with timing constraints in contrast a cold perturbation to tropical sst for interglacial boundary conditions results in only very small changes in the delivery of water vapor to the laurentide region and therefore almost no cooling over the canadian region this implies that tropical ssts could play a more important role in melting ice sheets in the northern hemisphere than in reforming them possibly providing a mechanism which could help to explain the rapidity of deglaciation relative to glacial inception

younger dryas style cooling events at glacial terminations i vi at odp site 658 associated benthic δ13c anomalies constrain meltwater hypothesis high resolution planktonic and epibenthic stable isotope records from ocean drilling program site 658 off northwest africa provide a basis for a detailed study of glacial terminations i vi during the last 650 000 years the duration of the terminations was about one half to one quarter of an orbital precession cycle 5800 10 700 years when its amplitude was high at low amplitudes the terminations lasted longer than half an obliquity cycle 29 000 years marked climatic rebounds similar to the younger dryas each with a duration of 1000 2500 years subdivided all six terminations into distinct steps a b and c important parts of the deglacial steps were as brief as 700 1000 years the speed of climatic change suggests that special associations existed between orbital forcing and inherent instability of the ice sheets in harmony with published models the more rapid pulses of glacial meltwater incursions to the northern north atlantic led to one or more brief short term shut downs of north atlantic deep water formation this process is reflected by pronounced benthic 13c minima that precisely coincide in most cases with the end of the 18o deglaciation steps and immediately terminate with succeeding younger dryas style cooling events thus we conclude that the rebounds resulted from a short term antecedent estuarine circulation regime in the north atlantic except for the younger dryas itself which succeeded the allerod with its well ventilated atlantic deepwater circulation and hence continues to be an enigma

climate records covering the last deglaciation the oxygen 18 oxygen 16 ratio of molecular oxygen trapped in ice cores provides a time stratigraphic marker for transferring the absolute chronology for the greenland ice sheet project gisp ii ice core to the vostok and byrd ice cores in antarctica comparison of the climate records from these cores suggests that near the beginning of the last deglaciation warming in antarctica began approximately 3000 years before the onset of the warm bolling period in greenland atmospheric carbon dioxide and methane concentrations began to rise 2000 to 3000 years before the warming began in greenland and must have contributed to deglaciation and warming of temperate and boreal regions in the northern hemisphere

complementary constraints from carbon 13c and nitrogen 15n isotopes on the glacial ocean s soft tissue biological pump a three dimensional process based model of the ocean s carbon and nitrogen cycles including 13c and 15n isotopes is used to explore effects of idealized changes in the soft tissue biological pump results are presented from one preindustrial control run pictrl and six simulations of the last glacial maximum lgm with increasing values of the spatially constant maximum phytoplankton growth rate max which accelerates biological nutrient utilization mimicking iron fertilization the default lgm simulation without increasing max and with a shallower and weaker atlantic meridional overturning circulation and increased sea ice cover leads to 280 pg more respired organic carbon corg storage in the deep ocean with respect to pictrl dissolved oxygen concentrations in the colder glacial thermocline increase which reduces water column denitrification and with delay nitrogen fixation thus increasing the ocean s fixed nitrogen inventory and decreasing 15nno3 almost everywhere this simulation already fits sediment reconstructions of carbon and nitrogen isotopes relatively well but it overestimates deep ocean 13cdic and underestimates 15nno3 at high latitudes increasing max enhances corg and lowers deep ocean 13cdic improving the agreement with sediment data in the model s antarctic and north pacific oceans modest increases in max result in higher 15nno3 due to enhanced local nutrient utilization improving the agreement with reconstructions there models with moderately increased max fit both isotope data best whereas large increases in nutrient utilization are inconsistent with nitrogen isotopes although they still fit the carbon isotopes reasonably well the best fitting models reproduce major features of the glacial 13cdic 15n and oxygen reconstructions while simulating increased corg by 510 670 pg compared with the preindustrial ocean these results are consistent with the idea that the soft tissue pump was more efficient during the lgm both circulation and biological nutrient utilization could contribute however these conclusions are preliminary given our idealized experiments which do not consider changes in benthic denitrification and spatially inhomogenous changes in aeolian iron fluxes the analysis illustrates interactions between the carbon and nitrogen cycles as well as the complementary constraints provided by their isotopes whereas carbon isotopes are sensitive to circulation changes and indicate well the three dimensional corg distribution nitrogen isotopes are more sensitive to biological nutrient utilization

multi stage reef development on barbados during the last interglaciation by mapping the vertical and lateral distribution of reefal facies on the west and south coast of barbados we have produced a revised model of reef development for the last interglaciation we find that reef architecture around barbados has significant complexity including evidence for wave exposure related variations in reef geometry and at least 3 stages of reef development that were controlled by variations in sea level during the main stage of development an acropora palmata dominated reef crest aggraded 22 m in response to a minimum sea level rise of 20 m during stage 2 a sea cave was cut 3 4 m above the fossil reef crest possibly indicating that reef growth was terminated before sea level reached the highstand similar sequences elsewhere in the caribbean indicate that this early reef demise may not be a local phenomenon several reefs apparently stopped growing between 2 and 4 m and only in sheltered areas did they reach the highstand at 6 m as recorded by intertidal notches this pattern of reef demise has previously been related to rapid sea level rise at the end of the interglacial but stratigraphic data are equivocal the final stage of reef development on barbados occurred when sea level began to fall this fall was rapid leaving a thin but widespread veneer of reef crest deposits over the proximal reef front and discontinuous intertidal and shallow subtidal deposits capping the distal reef front although further dating is required to differentiate these three stages our only reliable u th tims date indicates that almost 50 of the exposed reef had accreted by 129 ka giving an estimate of 15 ka for the main aggradational stage furthermore reports of relict reef crests buried beneath these exposed deposits indicate that our revised model is incomplete and that earlier stages of reef growth occurred during the last interglaciation these earlier stages imply that sea level was at an interglacial level for as long as 20 ka supporting the devils hole record of interglacial duration unfortunately these estimates could not be verified directly because most of our u th data show major stratigraphic age reversals attributed to diagenesis this pattern is also evident in all other well dated reefal units in the caribbean and leads us to conclude that only diagenetically screened precise stratigraphically consistent coral dates can be used to directly estimate the duration of the last interglaciation

climate correlations between greenland and antarctica during the past 100 000 years the ice cores recovered from central greenland by the grip1 2 and gisp23 projects record 22 interstadial warm events during the part of the last glaciation spanning 20 105 kyr before present the ice core from vostok east antarctica records nine interstadials during this period4 5 here we explore links between greenland and antarctic climate during the last glaciation using a high resolution chronology derived by correlating oxygen isotope data for trapped o2 in the gisp2 and vostok cores we find that interstadials occurred in east antarctica whenever those in greenland lasted longer than 2 000 years our results suggest that partial deglaciation and changes in ocean circulation are partly responsible for the climate teleconnection between greenland and antarctica ice older than 115 kyr in the gisp2 core shows rapid variations in the 18o of o2 that have no counterpart in the vostok record the age depth relationship and thus the climate record in this part of the gisp2 core appears to be significantly disturbed

interhemispheric synchrony of the last deglaciation inferred from alkenone palaeothermometry the relative timings of the last deglacial warming in the southern and northern hemispheres are not well constrained but are a crucial component in understanding the mechanisms of deglaciation1 a clearer picture of the degree of interhemispheric synchrony has been obscured by a dearth of high resolution temperature records that can be tied to the absolute calendar timescale moreover the quantification of tropical temperatures during the last glacial cycle is controversial2 8 here we apply the alkenone method of sea surface temperature reconstruction9 10 to several high resolution sediment cores recovered from the tropical indian ocean between 20 n and 20 s the inferred initial sea surface temperature warming 15 000 calendar years ago at 20 s is in phase with northern hemisphere sea this study and air11 temperature changes but lags antarctic warming12 14 by several millennia this finding along with the results of recent modelling studies15 16 provides strong support for the idea that changes in the ocean s global thermohaline circulation were not the only cause of interhemispheric climate teleconnection during the last deglaciation

the effect of vertical nutrient redistribution on surface ocean δ13c processes that shift nutrients from mid to lower ocean depths may or may not increase the ocean s vertical carbon pump redistribution of 13c produced by these processes is compared in two box models a vertical three box ocean and a thirteen box ocean in the former there is no 13c fractionation laterally between surface waters and the ocean nutrient and 13c distributions are linearly correlated this correlation is not changed when these tracers become redistributed and if the model surface ocean is nutrient limited the surface 13c cannot change in the 13 box ocean there is a transfer of negative 13c from the cold surface water through the atmosphere into the warm ocean its 13c is therefore lower than it would be as a result of the carbon pump by itself if a middepth nutrient depletion occurs because of lower nutrients in antarctic waters the warm surface 13c increases if the vertical nutrient shift occurs because of ocean circulation or biological recycling changes the warm surface water 13c change depends on the ratio of its vertical co2 fluxes i e exchange of atmospheric co2 versus upwelling total co2 and net biological production if this ratio remains about the same then little change occurs in surface 13c and the 13c of pacific deep water decreases about 0 3 in this case no change in the average ocean 13c is required to explain observations from sediment data this would imply that the ice age land biota carbon mass was about the same as that of today the vertical co2 flux ratio could be an important consideration if greater wind driven upwelling is a factor in the nutrient redistribution

evolution of atlantic pacific δ13c gradients over the last 2 5 m y the evolution of interocean carbon isotopic gradients over the last 2 5 m y is examined using high resolution 13c records from deep sea cores in the atlantic and pacific oceans over much of the northern hemisphere ice ages relative reductions in north atlantic deep water production occur during ice maxima from 2 5 to 1 5 ma glacial reductions in nadw are less than those observed in the late pleistocene glacial suppression of nadw intensified after 1 5 ma earlier than the transition to larger ice sheets around 0 7 ma at a number of times during the pleistocene 13c values at dsdp site 607 in the north atlantic were indistinguishable from eastern equatorial pacific 13c values from approximately the same depth odp site 677 indicating significant incursions of low 13c water into the deep north atlantic atlantic pacific 13c values converge during glaciations between 1 13 1 05 m y 0 83 0 70 m y and 0 46 0 43 m y this represents a pseudo periodicity of approximately 300 kyr which cannot easily be ascribed to global ice volume or orbital forcing this partial decoupling at low frequencies of the 18o and 13c signals at site 607 indicates that variations in north atlantic deep water circulation cannot be viewed simply as a linear response to ice sheet forcing

surface water temperature changes in the high latitudes of the southern hemisphere over the last glacial interglacial cycle a set of numerical equations is developed to estimate past sea surface temperatures sst from fossil antarctic diatoms these equations take into account both the biogeographic distribution and experimentally derived silica dissolution the data represent a revision and expansion of a floral data base used previously and includes samples resulting from progressive opal dissolution experiments factor analysis of 166 samples 124 holocene core top and 42 artificial samples resolved four factors three of these factors depend on the water mass distribution one subantarctic and two antarctic assemblages factor 4 corresponds to a dissolution assemblage inclusion of this factor in the data analysis minimizes the effect of opal dissolution on the assemblages and gives accurate estimates of sst over a wide range of biosiliceous dissolution a transfer function dtf 166 34 4 is derived from the distribution of these factors versus summer sst its standard error is 1 c in the 1 to 10 c summer temperature range this transfer function is used to estimate sst changes in two southern ocean cores 43 s and 55 s which cover the last climatic cycle the time scale is derived from the changes in foraminiferal oxygen and carbon isotopic ratios the reconstructed sst records present strong analogies with the air temperature record over antarctica at the vostok site derived from changes in the isotopic ratio of the ice this similarity may be used to compare the oceanic isotope stratigraphy and the vostok time scale derived from ice flow model the oceanic time scale if taken at face value would indicate that large changes in ice accumulation rates occurred between warm and cold periods

late pleistocene variability of arabian sea summer monsoon winds and continental aridity eolian records from the lithogenic component of deep sea sediments the modern indian ocean summer monsoon is driven by differential heating between the asian continent and the indian ocean to the south this differential heating produces a strong pressure gradient which drives southwest monsoon winds during june july and august satellite and meteorological observations aerosol measurements sediment trap studies and mineralogical studies indicate an atmospheric mode of transport for modern lithogenic sediments in the northwest arabian sea analyses of lithogenic grain size and mass accumulation rate mar records from the owen ridge indicate that eolian transport has been the primary mode of transport for the past 370 kyr visual inspection shows that the mar record is positively correlated with global ice volume as indicated by the marine 18o record in contrast the grain size record varies at a much higher frequency showing little correlation to either the mar or the 18o records spectral analyses confirm these relationships indicating that the lithogenic grain size and mar records are coherent only over the precession band whereby the grain size leads the mar by 124 8 kyr we conclude that an eolian transport mechanism is the only mechanism that allows for this phase difference and at the same time is supported by comparison of the grain size and mar with independent eolian records we use lithogenic grain size as a paleoclimatic indicator of summer monsoon wind strength and lithogenic mar as a paleoclimatic indicator of source area aridity these interpretations are supported by comparison of the lithogenic records to independent indicators of wind strength globigerina bulloides upwelling record and aridity a loess record from central china such comparisons indicate high coherence and zero phase relationships our work supports the findings of previous studies which have documented the link between monsoon strength and the earth s axial precession cycles both the lithogenic mar and the grain size records have high coherency with precessional insolation maximum lithogenic mar source area aridity is in phase with 18o global ice volume and leads maximum precessional insolation by 88 6 kyr we attribute this lead to the influence of glacial conditions on the aridity and therefore the deflation potential of the source areas maximum lithogenic grain size summer monsoon wind strength lags maximum precession by 148 9 kyr we attribute this lag both to the influence of global and or local ice volume and to the availability of latent heat from the southern hemisphere indian ocean the two of which combine to determine the strength of the indian ocean monsoon

high precision u series dating of corals from western australia and implications for the timing and duration of the last interglacial abstract u series ages using methods of thermal ionisation mass spectrometry tims are reported for last interglacial fossil reefs along the stable coastal margin of western australia thorium isotope ratios were measured with superior precision using methods of charge collection high levels of precision in the measurement of both uranium and thorium isotopes has reduced the age uncertainty due to analytical errors excluding the uncertainty in the decay constants by a factor of four over the precisions reported by many earlier tims workers uncertainties in 234u t determined from both 230th 238u and 234u 238u are also significantly smaller than previously reported allowing samples which have undergone diagenetic exchange of uranium and thorium to be more easily identified strict criteria were adopted to screen the new western australian data reliable ages range from 127 to 122 ka published tims observations from other localities have been assessed using the same strict criteria when these are combined with glacio hydro isostatic sea level models they indicate that the last interglacial period occurred from at least 130 to 117 ka however these age constraints are largely determined from single data points and need to be verified with additional ages before considering them to be robust estimates for the timing of onset and termination of the last interglacial globally the main episode of reef growth appears to be confined to a narrow interval occurring from 127 to 122 ka in direct agreement with the narrow range in ages obtained from the western australian sites this may indicate that the last interglacial was of short duration extending from 127 to 122 ka only alternatively this interval may reflect a major reef building event in the middle of a longer duration 130 117 ka interglacial interval

cold surface ocean ventilation and its effect on atmospheric co2 the potential for greater air sea exchange rates in the northern atlantic to decrease atmospheric co sub 2 during the ice ages is examined using a simple model of the solubility pump this potential is shown to depend on whether the modern ocean s region of sinking cold water is requilibrating with atmospheric co sub 2 at a rate comparable to the poleward transport of warm surface water if this is the case it is possible that greater ice age polar ventilation may have produced as much as 60 of the decrease observed in ice cores in this scenario the cold surface water co sub 2 partial pressure does not covary with the atmosphere but instead would remain approximately constant 36 refs 8 figs 1 tab

comparison of atlantic and pacific paleochemical records for the last 215 000 years changes in deep ocean circulation and chemical inventories abstract detailed cd ca and 13 c data have been obtained for benthic foraminifera from western north atlantic and equatorial pacific sediment cores in the modern ocean both tracers are closely linked to nutrient distributions the sedimentary records for both tracers indicate that bottom waters overlying the atlantic site have been nutrient depleted relative to those at the pacific site over the last 215 000 years from this evidence it is reasonable to infer that there has been a continuous net flux of nutrient depleted water from the western north atlantic into the pacific this exchange has undergone significant fluctuations with the export of nutrient depleted atlantic water diminishing by about a factor of two relative to the inflow from southern ocean sources over the last 215 000 years carbon isotope fluctuations in both regions are dominated by variable storage of isotopically light carbon on continents with a lesser contribution from these deep ocean circulation changes the cadmium signal in the north atlantic is dominated by changes in deep ocean circulation patterns cadmium shows less variability in the pacific which may reflect changes in the global average cadmium content or minor changes in deep pacific circulation patterns using these records to estimate global averages it appears that glacial ocean water had 22 more cd and 0 46 less 13 c than the modern ocean these numbers are estimates which may be revised as more data become available although they are not likely to be as much as 20 in error for cd or 0 2 for 13 c relative north atlantic deep water nadw formation rates are modulated with a significant 41 kyr periodicity linked to obliquity induced variations in high latitude insolation nadw lags 8 2 kyr behind insolation however

influence of variable rates of neritic carbonate deposition on atmospheric carbon dioxide and pelagic sediments short term imbalances in the global cycle of shallow water calcium carbonate deposition and dissolution may be responsible for much of the observed pleistocene change in atmospheric carbon dioxide content however any proposed changes in the alkalinity balance of the ocean must be reconciled with the sedimentary record of deep sea carbonates the possible magnitude of the effect of shallow water carbonate deposition on the dissolution of pelagic carbonate can be tested using numerical simulations of the global carbon cycle boundary conditions can be defined by using extant shallow water carbonate accumulation data and pelagic carbonate deposition dissolution data on timescales of thousands of years carbonate deposition versus dissolution is rarely out of equilibrium by more than 1 5 x 10 13 mole yr 1 results indicate that the carbonate chemistry of the ocean is rarely at equilibrium on timescales less than 10 ka this disequilibrium is probably due to sea level induced changes in shallow water calcium carbonate deposition dissolution an interpretation that does not conflict with pelagic sedimentary data from the central pacific

glacial interglacial co2 change the iron hypothesis several explanations for the 200 to 280 ppm glacial interglacial change in atmospheric co2 concentrations deal with variations in southern ocean phytoplankton productivity and the related use or nonuse of major plant nutrients an hypothesis is presented herein in which arguments are made that new productivity in today s southern ocean 7 4 1013g yr 1 is limited by iron deficiency and hence the phytoplankton are unable to take advantage of the excess surface nitrate phosphate that if used could result in total southern ocean new production of 2 3 1015 g c yr 1 as a consequence of fe limited new productivity holocene interglacial co2 levels preindustrial are as high as they were during the last interglacial 280 ppm in contrast atmospheric dust fe supplies were 50 times higher during the last glacial maximum lgm because of this fe enrichment phytoplankton growth may have been greatly enhanced larger amounts of upwelled nutrients may have been used and the resulting stimulation of new productivity may have contributed to the lgm drawdown of atmospheric co2 to levels of less than 200 ppm background information and arguments in support of this hypothesis are presented

mass spectrometric 230th 234u 238u dating of the devils hole calcite vein the devils hole calcite vein contains a long term climatic record but requires accurate chronologic control for its interpretation mass spectrometric u series ages for samples from core dh 11 yielded 230 th ages with precisions ranging from less than 1 000 years 2 for samples younger than 140 ka thousands of years ago to less than 50 000 years for the oldest samples 566 ka the 234 u 238 u ages could be determined to a precision of 20 000 years for all ages calcite accumulated continuously from 566 ka until 60 ka at an average rate of 0 7 millimeter per 10 3 years the precise agreement between replicte analyses and the concordance of the 230 th 238 u 234 u 238 u ages for the oldest samples indicate that the dh 11 samples were closed systems and validate the dating technique in general

uranium series dating of marine and lacustrine carbonates of the possible uranium series dating schemes the most important and most widely applied to marine carbonates is 230th dating with 231pa dating playing an increasingly important role for this reason this review will focus on these two methods 230th dating also referred to as u th dating or 238u 234u 230th dating involves calculating ages from radioactive decay and ingrowth relationships among 238u 234u and 230th 232th is also typically measured as a long lived essentially stable index isotope over the time scales relevant to 230th dating at present 230th dating can in principle be used to date materials as young as 3 years and in excess of 600 000 years edwards et al 1987a 1993 edwards 1988 see stirling et al 2001 for an example of dating corals in excess of 600 000 years old 231pa dating also referred to as u pa dating involves calculating ages from the ingrowth of 231pa from its grandparent 235u at present 231pa dating can be used to date materials as young as 10 years and as old 250 000 years edwards et al 1997 230th dating covers all of the 231pa time range and more with somewhat higher precision and is therefore the method of choice if a single method is applied however the combination of 231pa and 230th dating is of great importance in assessing possible diagenetic mobilization of the pertinent nuclides and thereby the accuracy of the ages allegre 1964 ku 1968 even if the primary age exceeds the 250 000 year limit of 231pa dating the combined methods can be used to assess the degree to which the samples have remained closed over the past 250 000 years e g edwards et al 1997 thus

response of global deep water circulation to earth s climatic change 135 000 107 000 years ago the response of deep ocean circulation to major climatic events of the past 135 000 years is inferred using carbon 13 analyses of benthic foraminifera from the major ocean basins the results demonstrate that the circulation of the world ocean deep water is very sensitive to climate and that it changes drastically during climatic transitions

a 135 000 year vostok specmap common temporal framework the object of the present study is to introduce a means of comparing the vostok and marine chronologies our strategy has been to use the 18o of atmospheric o2 denoted 18oatm from the vostok ice core as a proxy for the 18o of seawater denoted 18osw our underlying premise in using 18oatm as a proxy for 18osw is that past variations in 18osw an indicator of continental ice volume have been transmitted to the atmospheric o2 reservoir by photosynthesizing organisms in the surface waters of the world s oceans we compare our record of 18oatm to the 18osw record which has been developed from studies of the isotopic composition of biogenic calcite 18oforam in deep sea cores we have tied our 18oatm record from vostok to the specmap timescale throughout the last 135 kyr by correlating 18oatm with a 18osw record from v19 30 results of the correlation indicate that 77 of the variance is shared between these two records we observed differences between the 18oatm and the 18osw records during the coldest periods which indicate that there have been subtle changes in the factors which regulate 18oatm other than 18osw our use of 18oatm as a proxy for 18osw must therefore be considered tentative especially during these periods by correlating 18oatm with 18osw we provide a common temporal framework for comparing phase relationships between atmospheric records from ice cores and oceanographic records constructed from deep sea cores our correlated age depth relation for the vostok core should not be considered an absolute vostok timescale we consider it to be the preferred timescale for comparing vostok climate records with marine climate records which have been placed on the specmap timescale we have examined the fidelity of this common temporal framework by comparing sea surface temperature sst records from sediment cores with an antarctic temperature record from the vostok ice core we have demonstrated that when the southern ocean sst and antarctic temperature records are compared on this common temporal framework they show a high degree of similarity we interpret this result as supporting our use of the common temporal framework for comparing other climate records from the vostok ice core with any climate record that has been correlated into the specmap chronology

the southern ocean surface between marine isotope stages 6 and 5d shape and timing of climate changes summer sea surface temperature ssst and sea ice extent obtained at millennial to centennial resolution are presented for seven cores recovered in the atlantic and western indian antarctic zone from termination ii and the last interglacial s s i e marine isotope substage mis 5e the diatom based ssst estimates show that during the late mis 6 intensified export of cold waters from the weddell sea resulted in sssts close to 0 c in the central and eastern atlantic sector due to northward expansion of the winter sea ice edge by 3 5 latitude the sea ice seasonality was reduced such conditions have great potential for efficient year round reduction in air sea gas exchange and glacial co2 draw down the warming at termination ii started at 132 131 ka marked by rapid retreat of the sea ice edge the ssst increased within a few thousands of years to reach maximum interglacial summer temperatures ranging between 2 5 and 3 5 c in the earliest mis 5e 128 125 ka besides a distinct cold reversal around 129 5 ka the warming was punctuated by short lived temperature rebounds with amplitudes of 1 1 5 c occurring at 200 300 yr frequency thus in the range of the periodicity of solar input increased chaetoceros spp abundance suggests meltwater events as the primary cause of the coolings the ssst optimum characterised by strongly enhanced biogenic sedimentation rates ended at ca 125 ka with the full re establishment of the global conveyor belt and beginning of the northern hemisphere climatic optimum at this time sssts decreased stepwise and stabilised on values slightly warmer than today showing in the following period of mis 5e only low amplitude oscillations during mis 5d a northward expansion of the sea ice field took place but sssts only slightly colder than modern ones and a weakened meridional temperature gradient indicate that the southern ocean did not fall in a true glacial mode the tight correlation between southern ocean ssst and winter sea ice records and vostok atmospheric temperature and co2 records support the idea that the antarctic winter sea ice and southern ocean temperature exert a primary control on the atmospheric ocean co2 exchanges and hence on global climate reduction of the antarctic sea ice field and increase of ssst at the onset of termination ii could have been triggered by precessional changes influencing southern high latitude summer insolation positive feedback mechanisms reduction of surface albedo and release of co2 into the atmosphere and changes in global ocean circulation affected by a collapse or strong reduction in north atlantic deep water nadw production could have induced further reinforcement of the southern ocean warming

deglacial changes in ocean circulation from an extended radiocarbon calibration temporal variations in the atmospheric concentration of radiocarbon sometimes result in radiocarbon based age estimates of biogenic material that do not agree with true calendar age this problem is particularly severe beyond the limit of the high resolution radiocarbon calibration based on tree ring data which stretches back only to1 2 about 11 8 kyr before present bp near the termination of the younger dryas cold period if a wide range of palaeoclimate records are to be exploited for better understanding the rates and patterns of environmental change during the last deglaciation extending the well calibrated radiocarbon timescale back further in time is crucial several studies attempting such an extension using uranium thorium dated corals3 4 5 and laminae counts in varved sediments6 7 8 9 show conflicting results here we use radiocarbon data from varved sediments in the cariaco basin in the southern caribbean sea to construct an accurate and continuous radiocarbon calibration for the period 9 to 14 5 kyr bp nearly 3 000 years beyond the tree ring based calibration a simple model compared to the calculated atmospheric radiocarbon concentration and palaeoclimate data from the same sediment core suggests that north atlantic deep water formation shut down during the younger dryas period but was gradually replaced by an alternative mode of convection possibly via the formation of north atlantic intermediate water

the role of shelf nutrients on glacial interglacial co2 a negative feedback 1 in the past 800 thousand years and before industrialization the largest variations in atmospheric co2 concentration pco2 occurred in connection with the glacial cycles that characterized earth s climate over this period one curious feature of at least the last four glacial interglacial cycles is that atmospheric pco2 reached about the same upper limit of 280 ppm during peak interglacial periods and about the same lower limit of 180 ppm during peak glacial periods here we show using a numerical model of earth system that enhanced shelf sediment weathering during glacial sea level lowstands tends to raise pco2 even after carbonate compensation and thus stabilize pco2 from further reduction this is because not all nutrients from weathering will be utilized by biology but more importantly because the spatial distributions of carbon and phosphorus from weathering become decoupled in such a way that carbon is preferentially stored in the upper ocean and phosphorus in the deep ocean in addition the c p ratios in continental margin sediments are generally much higher than the redfield ratio due to preferential remineralization of phosphorus in shelf sediment diagenesis when these factors are accounted for in our model the input of organic matter which corresponds to the observed negative shift in ocean 13c during glacial periods raises pco2 by approximately 14 ppm the same mechanisms operating in the opposite directions during interglacial highstand tend to lower pco2 and stabilize it from further increase the impact of sea level driven continental shelf exposure and submersion of co2 is therefore a negative feedback that may have contributed to limiting the variation of pleistocene pco2 to the observed 100 ppm range

carbon 13 in pacific deep and intermediate waters 0 370 ka implications for ocean circulation and pleistocene co2 stable isotopes in benthic foraminifera from pacific sediments are used to assess hypotheses of systematic shifts in the depth distribution of oceanic nutrients and carbon during the ice ages the carbon isotope differences between 1400 and 3200 m depth in the eastern pacific are consistently greater in glacial than interglacial maxima over the last 370 kyr this phenomenon of bottom heavy glacial nutrient distributions which boyle proposed as a cause of pleistocene co2 change occurs primarily in the 1 100 and 1 41 kyr 1 milankovitch orbital frequency bands but appears to lack a coherent 1 23 kyr 1 band related to orbital precession averaged over oxygen isotope stages glacial 13c gradients from 1400 to 3200 m depth are 0 1 greater than interglacial gradients the range of extreme shifts is somewhat larger 0 2 to 0 5 in both cases these changes in pacific 13c distributions are much smaller than observed in shorter records from the north atlantic this may be too small to be a dominant cause of atmospheric pco2 change unless current models underestimate the sensitivity of pco2 to nutrient redistributions this dampening of pacific relative to atlantic 13c depth gradient favors a north atlantic origin of the phenomenon although local variations of pacific intermediate water masses can not be excluded at present

production and accumulation of calcium carbonate in the ocean budget of a nonsteady state present day production of caco3 in tne world ocean is calculated to be about 5 billion tons bt per year of which about 3 bt accumulate in sediments the other 40 is dissolved nearly half of the carbonate sediment accumulates on reefs banks and tropical shelves and consists largely of metastable aragonite and magnesian calcite deep sea carbonates predominantly calcitic coccoliths and planktonic foraminifera have orders of magnitude lower productivity and accumulation rates than shallow water carbonates but they cover orders of magnitude larger basin area twice as much calcium is removed from the oceans by present day carbonate accumulation as is estimated to be brought in by rivers and hydrothermal activity 1 6 bt suggesting that outputs have been overestimated or inputs underestimated that one or more other inputs have not been identified and or that the oceans are not presently in steady state one missing calcium source might be groundwater although its present day input is probably much smaller than that of rivers if as seems likely caco3 accumulation presently exceeds terrestial and hydrothermal input this imbalance presumably is offset by decreased accumulation and increased input during lowered sea level shallow water accumulation decreases by an order of magnitude with a 100 m drop in sea level while groundwater influx increases because of heightened piezometric head and the diagenesis of metastable aragonite and magnesian calcite from subaerially exposed shallow water carbonates

a critical review of marine sedimentaryδ13corg pco2 estimates new palaeorecords from the south china sea and a revisit of other low latitude δ13corg pco2 records in an attempt to understand better the local biogeochemistry of the south china sea scs and to unravel the contribution of this marginal low latitude basin to changes in atmospheric co2 concentrations we analyzed the carbon isotopic composition of organic matter 13corg in four sediment cores from throughout the scs covering the last 220 kyr higher values around 19 5 to 20 5 mark glacial stages while lower values around 21 to 22 5 are characteristic of interglacials following well established procedures the 13corg records are converted to local pco2 estimates on the basis of these and other low latitude 13corg pco2 estimates from the literature we present a critical evaluation of the use of 13c of bulk sedimentary organic matter to hindcast past changes in local co2 aq three crucial pitfalls are identified 1 given the present inability to quantify precisely the time varying amount of terrigenous corg input to marine sediments absolute values of pco2 estimates based on bulk sedimentary corg are questionable 2 none of the low latitude sedimentary 13corg pco2 records shows the expected correlation between temporal changes in upwelling intensity and co2 estimates most likely due to the antagonistic influences of co2 aq and phytoplankton growth rate on 13corg 3 a detailed comparison of marine 13corg pco2 records with the vostok co2 record reveals significant differences in phasing specifically at the end of the last deglaciation and during the oxygen isotope stage 5 4 transition however in areas where equilibrium between oceanic and atmospheric co2 occurs for example the scs and the mediterranean the timing of changes in 13corg should agree with the co2 record from ice cores if 13corg is a reliable proxy for changes in co2 aq taken together the compilation of records presented here cautions the use of 13corg as an unambiguous tracer of dissolved molecular co2 in the surface ocean and calls for a re evaluation of the role of the low latitude ocean on temporal changes in atmospheric co2

reef shallowing is a critical control on benthic foraminiferal assemblage composition on nearshore turbid coral reefs abstract declining water quality represents a major threat to the coral reefs of australia s great barrier reef gbr due to their close proximity to river point sources reefs situated on the inner shelf of the gbr are widely perceived to be most susceptible to the increased discharge of nutrients and sediments from coastal catchments many of which have been modified since european settlement however the impact and magnitude of water quality change on the gbr s inner shelf reefs remains unclear much of the uncertainty can be attributed to a paucity of long term records with which to assess ecological and environmental change over appropriate reef building timescales here we present benthic foraminiferal palaeo records from three proximal nearshore turbid zone reefs located within the central region of the gbr bayesian age depth modelling was used to identify the core intervals corresponding to the timing of european settlement in the region c 1850 ce enabling the investigation of 1 the composition and variability of benthic foraminiferal assemblages during reef shallowing towards sea level and 2 whether any signal of increased nutrient and sediment inputs as the result of historical land use change can be discerned on the most nearshore reefs of the central gbr multivariate analyses identified two assemblage groups delineated by a significant increase in the relative abundance of pararotalia spp up core our results suggest that post european settlement associated increases in nutrient and sediment inputs are unlikely to have driven the observed shifts in benthic foraminiferal assemblage composition rather we interpret changes in the composition of benthic foraminiferal assemblages as being linked to changes in hydrodynamic energy light availability and the carbonate content of reef matrix sediments during reef shallowing towards sea level our findings support the hypothesis that nearshore turbid zone reefs have a higher resistance to increased nutrient and sediment inputs than those located further offshore towards the inner mid shelf boundary of the gbr

the δ13c of equatorial atlantic surface waters implications for ice age pco2 levels carbon isotopic records of nutrient depleted surface water place constraints on the past fertility of the oceans and on past atmospheric pco2 levels the best records of nutrient depleted 13c are obtained from planktonic foraminifera living in the thick mixed layers of the western equatorial and tropical atlantic ocean we have produced a composite stacked globigerinoides sacculifer 13c record from the equatorial atlantic which exhibits significant spectral power at the 100 000 and 41 000 year milankovitch periods but no power at the 23 000 year period similar to the record presented by shackleton and pisias 1985 surface deep ocean 13c produced with the g sacculifer record leads the 18o ice volume record however the glacial interglacial amplitudes of 13c differ between our record and shackleton and pisias 1985 record although large changes in 13c occur in the equatorial atlantic during early stages of the last three glacial cycles surface deep 13c at glacial maxima 18o stage 2 late stage 6 and late stage 8 was only about 0 2 greater than during the subsequent interglacial our results imply that nutrient driven pco2 changes account for about one third of the pco2 decrease observed in ice cores and consequently 13c should not be used as a proxy pco2 index enough variance in the ice core pco2 records remains to be explained that conclusions about pco2 and ice volume phase relationships should also be reexamined as much as 40 ppm pco2 change still has not been accounted for by models of past physics and chemistry of the ocean

protactinium 231 dating of carbonates by thermal ionization mass spectrometry implications for quaternary climate change measurement of protactinium 231 231pa in carbonates by thermal ionization mass spectroscopy yields 231pa ages that are more than 10 times more precise than those determined by decay counting carbonates between 10 and 250 000 years old can now be dated with 231pa methods barbados corals that have identical 231pa and thorium 230 230th ages indicate that the timing of sea level change over parts of the last glacial cycle is consistent with the predictions of the astronomical theory two devils hole calcite subsamples record identical 231pa and 230th ages suggesting that the chronology of this climate record is accurate

the sequence of events surrounding termination ii and their implications for the cause of glacial interglacial co2 changes events surrounding termination ii as preserved in the vostok ice core provide a number of clues about the mechanisms controlling glacial to interglacial climate change antarctic temperature and the atmosphere s co2 content increased together over a period of 8000 years this increase is bounded by a drop in dust flux at its onset and by a drop in the 18o of trapped air at its finish a similar lag between dust flux and foraminiferal 18o is seen in a southern ocean marine record suggesting that the 18o in air trapped in vostok ice is a valid proxy for ice volume the synchronous change of atmospheric co2 and southern hemisphere temperature thus preceded the melting of the northern hemisphere ice sheets this observation coupled with the fact that nutrient reorganization in the north atlantic occurs with or after the sea level rise eliminates many scenarios proposed to explain the co2 rise including those which rely on sea level change conveyor related nutrient redistribution or north atlantic cooling southern ocean scenarios become the front runners but the most popular mechanism iron fertilization has two problems in explaining the co2 rise before termination ii first much of the dust demise occurs prior to the change in co2 so if iron is the villain a threshold value of its supply must be called upon above which productivity does not continue to increase second the co2 rise continues for some 4 5 kyr after the dust flux has fallen to close to zero these problems may be solved if the increased iron supply in dust caused higher rates of nitrogen fixation during the glacial periods in this case the residence time of oceanic nitrate of a few thousand years would enable decreasing productivity to be a global rather than a local phenomenon and would explain the slow rampup of atmospheric co2

the cause of the glacial to interglacial atmospheric co2 change a polar alkalinity hypothesis in an attempt to create a scenario for the cause of the glacial to interglacial co2 change recorded in air trapped in polar ice we call on an increase in the alkalinity of polar surface waters in this way we circumvent a major deficiency of the polar nutrient scenarios of sarmiento and toggweiler 1984 siegenthaler and wenk 1984 and knox and mcelroy 1984 namely our scenario does not require a drop in the nutrient content of polar surface waters in conformity with the demonstration by boyle 1988a b that the cadmium content of planktonic foraminifera from polar regions did not decrease from late glacial to holocene time the rise in alkalinity required by our model is a natural consequence of the demise during glacial time of north atlantic deep water as a major force in ocean circulation and of the nutrient maximum deepening of boyle 1988b rather than being original our hypothesis builds on the concept basic to the polar nutrient hypotheses namely that the co2 partial pressure in polar waters controls that for both the atmosphere and warm surface ocean it also requires the alkalinity increase in surface waters produced by boyle s nutrient deepening

the dole effect and its variations during the last 130 000 years as measured in the vostok ice core we review the current understanding of the dole effect the observed difference between the delta sup 18 o of atmospheric o sub 2 and that of seawater and its causes extended the record of variations in the dole effect back to 130 kyr before present using data on the delta sup 18 o of o sub 2 obtained from studying the vostok ice core and discuss the significance of temporal variations the dole effect reflects oxygen isotope fractionation during photosynthesis respiration and hydrologic processes evaporation precipitation and evapotranspiration our best prediction of the present day dole effect 20 8 per thousand is considerably lower than the observed value 23 5 per thousand and we discuss possible causes of this discrepancy during the past 130 kyr the dole effect has been 0 05 per thousand lower than the present value on average the standard deviation of the dole effect from the mean has been only per thousand and the dole effect is nearly unchanged between glacial maxima and interglacial periods the small variability in the dole effect suggests that relative rates of primary production in the land and marine realms have been relatively constant most periodic variability in the dole effect is in the precession band suggesting that changes in this global biogeochemical termmore reflects variations in low latitude land hydrology and productivity or possibly variability in low latitude oceanic productivity 65 refs 4 figs 3 tabs less

a northern lead in the orbital band north south phasing of ice age events abstract re analysis of existing data sets shows that they are fully consistent with northern insolation control of ice age cycles and do not provide strong support for alternate models invoking tropical or southern controls the coldest time of the last 100 ka in central greenland was nearly synchronous with the minimum in summer insolation about 24 ka bp thousand years before 1950 approximately one third of the total termination i warming since then was achieved over the almost 10 ka before the abrupt warming into the bolling which some workers have interpreted as the start of the warming southern warming as recorded in the byrd station antarctica ice isotopic record lagged northern warming co2 rise was roughly synchronous with southern warming methane rise may have been delayed a little as was sea level rise and the change in the isotopic composition of atmospheric oxygen was delayed significantly the data for the extrema just before termination ii are consistent with occurrence of the same phasing as for termination i but with somewhat different progression of the two terminations once initiated perhaps because of differences in the forcing

metabasites with eclogite facies relics from variscides in sardinia italy a review metabasites with eclogite facies relics occur in northern sardinia as massive to strongly foliated lenses or boudins embedded within low to medium grade rocks anglona and migmatites ne sardinia u pb zircon dating yielded 453 14 457 2 and 460 5 ma as the protolith ages 400 10 and 403 4 ma have been interpreted as the ages of the hp event and 352 3 and 327 7 ma as the ages of the main variscan retrograde events a pre eclogite stage is documented by the occurrence of tschermakite zoisite relics within garnet porphyroblasts punta de li tulchi and an edenite andesine inclusion within a relict kyanite porphyroblast golfo aranci four main metamorphic stages have been distinguished in the eclogite evolution 1 eclogite stage revealed by the occurrence of armoured omphacite relics within garnet porphyroblasts the golfo aranci eclogites also include kyanite mg rich garnet and pargasite 2 granulite stage producing orthopyroxene and clinopyroxene plagioclase symplectites replacing omphacite at golfo aranci the symplectitic rims around relict kyanite consist of sapphirine anorthite corundum and spinel 3 amphibolite stage leading to the formation of amphibole plagioclase kelyphites between garnet porphyroblasts and pyroxene plagioclase symplectites and to the growth of cummingtonite on orthopyroxene tschermakite to mg hornblende plagioclase cummingtonite ilmenite titanite and biotite are coexisting phases 4 greenschist to sub greenschist stage defined by the appearance of actinolite chlorite epidote ss titanite sericite and prehnite the following p t ranges have been estimated for the different stages eclogite stage 550 700 c 1 3 1 7 gpa granulite stage 650 900 c 0 8 1 2 gpa clustering in the range 1 0 1 2 gpa amphibolite stage 550 740 c 0 3 0 7 gpa greenschist stage 300 400 c 0 2 0 3 gpa comparable ranges characterise the other variscan massifs in europe eclogite stage t 530 800 c p from 0 7 1 1 to 1 7 0 3 gpa granulite stage t 760 870 c and p from 1 1 1 4 to 7 2 9 9 gpa clustering around 1 0 1 2 gpa whole rock chemistry sardinian eclogites are n to t morb european ones n to e morb or calc alkaline

pore fluid constraints on the temperature and oxygen isotopic composition of the glacial ocean pore fluids from the upper 60 meters of sediment 3000 meters below the surface of the tropical atlantic indicate that the oxygen isotopic composition 18 o of seawater at this site during the last glacial maximum was 0 8 0 1 per mil higher than it is today combined with the 18 o change in benthic foraminifera from this region the elevated ratio indicates that the temperature of deep water in the tropical atlantic ocean was 4 c colder during the last glacial maximum extrapolation from this site to a global average suggests that the ice volume contribution to the change in 18 o of foraminifera is 1 0 per mil which partially reconciles the foraminiferal oxygen isotope record of tropical sea surface temperatures with estimates from barbados corals and terrestrial climate proxies

iron in ice cores from law dome a record of atmospheric iron deposition for maritime east antarctica during the holocene and last glacial maximum total dissolvable iron tdfe was measured in sections of ice cores recovered from law dome on the coast of wilkes land east antarctica these samples include ice dating from the last glacial maximum lgm the last deglaciation and the early and mid holocene as well as samples from the anthropocene that have been dated with seasonal to annual resolution combining our tdfe concentration data with estimates of the ice accumulation rate we estimate the atmospheric iron deposition for law dome and the adjacent southern ocean during these periods our results indicate that the atmospheric iron deposition flux to this region during the lgm 8 mol fe m 2 yr 1 was an order of magnitude higher than the average holocene deposition flux 0 8 mol fe m 2 yr 1 this holocene flux estimate is significantly higher than recent estimates of atmospheric iron deposition based on the analysis of iron in samples of the dome c epica ice core implying that there are significant meridional gradients in eolian iron flux to the antarctic region our data also suggest that there have been significant variations in atmospheric iron deposition to law dome and adjacent ocean waters over seasonal to decadal timescales during the past century analysis of ice samples dating from calendar years 1927 to 1928 indicates an anomalously high flux of tdfe to the law dome region amounting to around half the maximum lgm flux possibly as a result of severe drought conditions on the australian continent given that chronic iron deficiency is thought to limit phytoplankton production in much of the ocean around antarctica such large secular variations in atmospheric iron supply are likely to have had profound impacts on year to year primary production and ecosystem structure in antarctic waters

relation between low latitude insolation and δ18o change of atmospheric oxygen for the last 200 kyrs as revealed by mediterranean sapropels the isotopic ratio of atmospheric o2 18oatm deduced from ice cores displays large fluctuations during climatic cycles these are caused principally by changes in the oxygen isotopic ratio of sea water 18osw and changes in the biosphere and in the hydrological cycle as both 18oatm and 18osw coincide closely over the last 135 kyr bp it is generally believed that 18oatm is driven mainly by 18osw here we focus on the major discrepancy which arises between those two signals during the prior isotopic glacial stage 6 around 175 kyr bp discrepancy which calls into question the role of changes in 18osw as the driving mechanism for 18oatm we present arguments based on the occurrence and pollen content of mediterranean sapropels for another source of the 18oatm change insolation at low latitudes via hydrosphere biosphere activity

paleocean circulation during the last deglaciation a bipolar seesaw hughen et al 1998 have documented that during the first 200 years of younger dryas time the 14c content of atmospheric co2 increased by 50 and that during the remainder of this 1200 year duration cold event it steadily declined the initial increase in 14c c was likely the result of a reduction in the atlantic s conveyor circulation however were the subsequent radiocarbon decline due to the rejuvenation of this potent heat pump then it is difficult to understand why the climate conditions in the northern atlantic basin remained cold throughout the younger dryas modeling exercises by stocker and wright 1996 mikolajewicz 1998 and schiller et al 1998 show that if the conveyor is terminated the transfer of radiocarbon into the deep sea shifts to the southern ocean thereby stabilizing the atmospheric 14c c ratio paleoclimatic evidence from the antarctic continent suggests that this model based scenario might have been played out in the real world while the younger dryas cooling has been documented in many places around the world including new zealand denton and hendy 1994 sowers and bender 1995 using their 18o in o2 based correlation between the ice core 18o in ice records for antarctica and greenland have demonstrated that in antarctica the younger dryas was a time of maximum warming the point of this paper is that the steep rise in 18o rise in antarctic ice which commenced close to the onset of the younger dryas might have been caused by heat released to the atmosphere in response to an increase in deep sea ventilation in the southern ocean

the role of vertical chemical fractionation in controlling late quaternary atmospheric carbon dioxide the 30 decrease in atmospheric carbon dioxide during glacial maxima must be driven by some change in the chemical circulation of the ocean here a new model for late quaternary co2 variability is presented which resolves some problems occurring in previous models including the timing of carbon dioxide response and changes in the oxygen content of the deep ocean the primary driving factor in this model is a rearrangement of chemical distributions in the ocean whereby labile nutrients and metabolic co2 are concentrated in deep waters rather than in intermediate waters as observed in the modern ocean this new bottom heavy chemical structure does not affect atmospheric carbon dioxide directly instead co2 induced acidity lowers the deep ocean carbonate ion concentration and temporarily increases carbonate dissolution rates oceanic alkalinity then rises until the deep ocean carbonate ion is restored to its steady state value the resulting increase in oceanic alkalinity draws co2 out of the atmosphere into the ocean alkalinity and atmospheric co2 lag several thousand years behind the change in oceanic chemical structure this delayed response is determined by the limited rate of continental weathering and deep ocean carbonate dissolution relative to the oceanic alkalinity inventory it is proposed that characteristic deglacial and preglacial states of the ocean are leading factors driving glacial interglacial climate changes this concept reinterprets the carbon isotope contrast between surface water and deep waters 13c p b as due to a shift of light metabolic carbon from intermediate waters into deep waters the process is illustrated here by a simple equilibrium five box ocean model the observed intermediate depth nutrient depletion is not sufficient in itself to determine which of several possible mechanisms are operating and some mechanisms are not as effective in changing atmospheric co2 as others the largest response is seen from deepening the regeneration cycle of organic carbon the least response is seen from converting north atlantic deep water into intermediate water

the coral record of last interglacial sea levels and sea surface temperatures abstract the rise and fall of the last interglacial li sea levels and sea surface temperatures ssts are evaluated using u series dating combined with sr ca ratios in corals from both stable and tectonically uplifted sites along the stable coastal margin of western australia an extensive series of li coral reefs occur at heights of 2 3 m above present day sea level these corals have a very tight cluster of 234u 230th ages ranging from 129 1 to 119 1 ka as well as a narrow range of initial 234u values of 150 5 similar to modern seawater bahamas which is also a stable site has an essentially identical pattern of u series ages from 130 1 to 120 1 ka barbados and huon peninsula are tectonically active sites where the li terraces are found at elevations of 50 and 200 m respectively u series ages from corals exposed in the lower footwall of these uplifted reefs allow better constraints to be placed on the rate of sea level rise which initiated the li corals from the huon peninsula constrain sea level at 80 10 m at 131 2 ka and from barbados at 30 5 m at 129 1 ka combined with constraints from stable sites these observations require an exceedingly rapid rise in sea level of 30 50 m per 1000 years at 130 1 ka this indicates that large scale catastrophic melting of the once massive continental ice sheets occurred in phase with the rapidly increasing northern hemisphere nh summer insolation consistent with the orbital forcing being the main driver of glacial interglacial climate change there is also some evidence from huon peninsula although still not conclusive for a precursor oscillation in sea level during the penultimate deglaciation that may have been within 20 m of present day levels at 135 ka ssts for the li porites corals from the huon peninsula and western australia have mean annual temperatures and seasonal ranges that are remarkably similar to present day patterns the tropical site of huon peninsula has ssts of 29 1 c which is indistinguishable from the ssts given by modern corals at ningaloo reef in western australia similar mean annual 24 c and summer maximum ssts of 27 29 c are found in both li and modern corals the only significant difference is the 1 c cooler winter minimum ssts of 21 c for the li compared to present day minimums of 22 c li ssts from these southern hemisphere sh sites were thus very similar or at most only slightly cooler than today despite sea levels being up to 4 m higher this maybe indicative of asymmetric warming of the earth with the increased nh insolation during the li period being responsible for the extensive melting of the mainly nh based ice sheets and hence higher global sea levels the observation of relatively high sea levels in the li together with the rapid pulses of sea level rise indicates that the potential now exists for greenhouse warming to initiate increases in sea level of at least several metres on relatively short time scales 102 years

duration and structure of the past four interglaciations reanalysis and additional dating of the devils hole 18o paleotemperature record confirm that the last interglaciation in the great basin the continental analog of marine isotopic substage 5e lasted 22 000 yr consistent with the vostok paleotemperature record which suggests a duration of 19 000 yr for this event in antarctica the three preceding interglaciations in the devils hole record analogs of marine isotopic substages 7e 9c and 11c range from 20 000 to 26 000 yr in duration a 20 000 yr duration for the last interglaciation is consistent with tims uranium series dated sea level high stands thus the widely held view that interglaciations were of 11 000 to 13 000 yr duration and constituted only about 10 of mid to late pleistocene climatic cycles needs reexamination the warmest portion of each interglaciation in the devils hole time series is marked by a 18o plateau signifying apparent climatic stability for periods of 10 000 to 15 000 yr duration

antarctic dome c ice core dust at 18 k y b p isotopic constraints on origins we have determined the source area from which dusts from the last glacial maximum lgm section of the dome c ice core were derived by comparing their strontium and neodymium isotopic ratios with those of samples from potential source areas the87sr 86sr and143nd 144nd isotope ratios of the dusts deposited 18 k y b p at the east antarctic dome c site were compared with potential antarctic australian southern african and south american sources the isotope ratios clearly define the patagonian provenance of the dust with the other potential source areas being at most minor contributors contributions by volcanic ash and tephra to the dust sample were also determined to be minimal based on the patterns of rare earth elements knowing the source of the dusts places constraints on the aeolian trajectory by which it was transported to antarctica and this serves as a test of the simulation of southern hemispheric circulation by atmospheric global circulation models during the lgm

the δ18o of atmospheric o2 from air inclusions in the vostok ice core timing of co2 and ice volume changes during the penultimate deglaciation one important question about the co2 climate connection is how increasing atmospheric pco2 levels affect climate and thereby the mass balance of continental ice sheets a record of atmospheric co2 variations over the last 160 000 years has recently been constructed by analyzing the trapped gas in the vostok ice core barnola et al 1987 the relationship between changes in atmospheric co2 and the size of the continental ice sheets has been difficult to ascertain because the co2 record is obtained from ice cores while the ice volume record has been constructed from the stable isotopic composition of biogenic caco3 in deep sea sediment cores in order to compare these two records in a more precise manner we present a record of the isotopic composition 18o of atmospheric o2 trapped in the vostok ice core and propose that it may be considered a proxy for the 18o of seawater and hence ice volume having a record of atmospheric co2 along with a continental ice volume proxy in trapped air in the same ice core allows us to compare the timing of changes in these two parameters with little uncertainty in the relative ages of important events our results suggest that during the penultimate glacial termination atmospheric co2 began to increase at least 3 kyr before the initial introduction of meltwater to the oceans possible errors in the relative age depth curve of the vostok ice core and uncertainties in the influence of biological and hydrologic processes on the 18o of atmospheric o2 introduce some uncertainty into our conclusions however our results are in general agreement with the observed phase relationship between atmospheric co2 and ice volume imbrie et al 1984 imbrie et al 1989 inferred from changes in the 13c difference between contemporaneous planktonic and benthic forams deposited in deep sea cores and the specmap ice volume record

the distribution of 230th234u ages in corals and the number of last interglacial high sea stands abstract the 104 available 230 th 234 u analyses of unrecrystallized corals from stable emerged terraces indicate that the last interglacial period occurred approximately 125 000 yr ago an estimate is made of the exact duration of this period by accounting for the surprisingly small distribution width observed among the 80 most reliable analyses this distribution width is compared with those obtained for model populations generated by assuming various characteristic analytical errors and various lengths of the last interglacial period the results show that 1 if there was only a single rise in sea level it probably lasted no more than 12 000 yr in agreement with previous estimates and 2 if there were two separate rises of sea level the gap between them must have been less than 7500 yr and not 12 200 as proposed by some authors

precise timing of the last interglacial period from mass spectrometric determination of thorium 230 in corals the development of mass spectrometric techniques for determination of 230 th abundance has made it possible to reduce analytical errors in 238 u 234 u 230 th dating of corals even with very small samples samples of 6 x 10 8 atoms of 230 th can be measured to an accuracy of 3 percent 2 and 3 x 10 10 atoms of 230 th can be measured to an accuracy of 0 2 percent the time range over which useful age data on corals can be obtained now ranges from about 50 to about 500 000 years for young corals this approach may be preferable to 14 c dating the precision with which the age of a coral can now be determined should make it possible to critically test the milankovitch hypothesis concerning pleistocene climate fluctuations analyses of a number of corals that grew during the last interglacial period yield ages of 122 000 to 130 000 years the ages coincide with or slightly postdate the summer solar insolation high at 65 n latitude which occurred 128 000 years ago this supports the idea that changes in pleistocene climate can be the result of variations in the distribution of solar insolation caused by changes in the geometry of the earth s orbit and rotation axis

the last interglacial ocean the final effort of the climap project was a study of the last interglaciation a time of minimum ice volume some 122 000 yr ago coincident with the substage 5e oxygen isotopic minimum based on detailed oxygen isotope analyses and biotic census counts in 52 cores across the world ocean last interglacial sea surface temperatures sst were compared with those today there are small sst departures in the mid latitude north atlantic warmer and the gulf of mexico cooler the eastern boundary currents of the south atlantic and pacific oceans are marked by large sst anomalies in individual cores but their interpretations are precluded by no analog problems and by discordancies among estimates from different biotic groups in general the last interglacial ocean was not significantly different from the modern ocean the relative sequencing of ice decay versus oceanic warming on the stage 6 5 oxygen isotopic transition and of ice growth versus oceanic cooling on the stage 5e 5d transition was also studied in most of the southern hemisphere the oceanic response marked by the biotic census counts preceded led the global ice volume response marked by the oxygen isotope signal by several thousand years the reverse pattern is evident in the north atlantic ocean and the gulf of mexico where the oceanic response lagged that of global ice volume by several thousand years as a result the very warm temperatures associated with the last interglaciation were regionally diachronous by several thousand years these regional lead lag relationships agree with those observed on other transitions and in long term phase relationships they cannot be explained simply as artifacts of bioturbational translations of the original signals

organic carbon paleo pco2 and marine ice core correlations and chronology here we present evidence that marine organic matter 13 c measurements can closely reproduce the vostok ice core co 2 record and in addition can be used to evaluate the absolute vostok chronology and the transfer of that chronology between the marine and terrestrial realm our data supports recent speculations that the base of the vostok ice core 2755 m is still within oxygen isotope stage 7 in agreement with recent orbitallytuned ice core chronologies

age scale of the air in the summit ice implication for glacial interglacial temperature change the air occluded in ice sheets and glaciers has in general a younger age defined as the time after its isolation from the atmosphere than the surrounding ice matrix because snow is first transformed into open porous firn in which the air can exchange with the atmosphere only at a certain depth firn ice transition the pores are pinched off and the air is definitely isolated from the atmosphere the firn ice transition depth is at around 70 m under present climatic conditions at summit central greenland the air at this depth is roughly 10 years old due to diffusive mixing whereas the ice is about 220 years old this results in an age difference between the air and the ice of 210 years this difference depends on temperature and accumulation rate and did thus not remain constant during the past we used a dynamic firn densification model to calculate the firn ice transition depth and the age of the ice at this depth and an air diffusion model to determine the age of the air at the transition past temperatures and accumulation rates have been deduced from the 18o record using time independent functions we present the results of model calculations of two paleotemperature scenarios yielding a record of the age difference between the air and the ice for the greenland ice core project grip and the greenland ice sheet project two gisp2 ice cores for the last 100 000 years during the holocene the age difference stayed rather stable around 200 years while it reached values up to 1400 years during the last glaciation for the colder scenario the model results are compared with age differences obtained independently by matching corresponding climate events in the methane and 18o records assuming a very small phase lag between variations in the greenland surface temperature and the atmospheric methane the past firn ice transition depths are compared with diffusive column heights obtained from 15n of n2 measurements the results of this study corroborate the large temperature change of 20 to 25 k from the coldest glacial to holocene climate found by evaluating borehole temperature profiles

calibration of the c 14 timescale over the past 30 000 years using mass spectrometric u th ages from barbados corals uranium thorium ages obtained by mass spectrometry from corals raised off the island of barbados confirm the high precision of this technique over at least the past 30 000 years comparison of the u th ages with 14c ages obtained on the holocene samples shows that the u th ages are accurate because they accord with the dendrochronological calibration before 9 000 yr bp the 14c ages are systematically younger than the u th ages with a maximum difference of 3 500 yr at 20 000 yrbp the u th technique thus provides a way of calibrating the radiocarbon timescale beyond the range of dendrochronological calibration

marine core evidence for reduced deep water production during termination ii followed by a relatively stable substage 5e eemian we present oxygen and carbon isotope records of benthic foraminifera from the glacial stage 6 through interglacial substage 5e eemian sections of several cores from the subpolar north atlantic the cores range in water depth from 1451 to 2658 m in one core we generated estimates of sea surface temperature sst and of ice rafted detritus ird delivery for all of stage 5 we reconstruct bathymeric profiles of 13c for stage 6 termination ii and three time slices of substage 5e the 13c profiles indicate that local deep water geometry during stage 6 was similar to that of the last glaciation with glacial north atlantic intermediate water gnaiw overlying deeper waters partially of southern origin an anomalously large peak in ird coupled with planktonic 18o evidence for iceberg melting immediately precedes termination ii and is otherwise similar to stage 2 and 3 heinrich events during the termination low 13c values are observed in cores near and above 2 km providing evidence of reduced gnaiw production in association with deglacial melting in the shallowest cores low 13c values persist into early substage 5e indicating that the southward retreat of southern source waters was not completed until well after the beginning of the substage in contrast to termination i ssts remained cold until the end of the deglaciation this may be why there is little evidence from marine and terrestrial sequences for a pronounced climate reversal on termination ii despite what is now clear evidence of a significant reduction in ocean ventilation the faunal data suggest that ssts during early 5e were about 7 c warmer than during the glaciation sst rose several degrees from early to middle substage 5e peaked in middle substage 5e at about 10 c above glacial values and then gradually declined by about 5 c these changes were linked to variations in water mass configuration as interpreted from benthic 13c evidence most of the evidence suggests that oscillations superimposed on the gradual sst trend were 1 2 c in contrast to the larger sst changes 3 4 c documented for substage 5d

patagonian origin of glacial dust deposited in east antarctica vostok and dome c during glacial stages 2 4 and 6 abstract the source area of continental dust deposited at both vostok and dome c sites east antarctica during the glacial stages stage 2 18 ka last glacial maximum stage 4 60 ka and stage 6 160 ka of the last two climatic cycles has remained constant the isotopic composition 87 sr 86 sr and 143 nd 144 nd of the ice core dust has been compared with the isotopic composition of the potential source areas antarctica new zealand southern africa australia and south america this comparison reveals the southern south american provenance of the dust for all three glacial periods as has already been shown for the lgm 1 we show that the patagonian loess and the marine shelf sediments from the argentine continental shelf which was variably emerged during glacial periods display different isotopic compositions and that the composition of the patagonian loess best matches the signature of the ice core dust the identification of the patagonian region as the source of the windblown dust deposited over east antarctica during all the latest glacial periods permits a better understanding of paleo atmospheric circulations of the last climatic cycles and a better constraint on the parametrization of dust sources for paleoatmospheric general circulation models

vostok ice core provides 160 000 year record of atmospheric co2 direct evidence of past atmospheric co2 changes has been extended to the past 160 000 years from the vostok ice core these changes are most notably an inherent phenomenon of change between glacial and interglacial periods besides this major 100 000 year cycle the co2 record seems to exhibit a cyclic change with a period of some 21 000 years

direct u th dating of marine sediments from the two most recent interglacial periods a knowledge of the age of marine sediments is necessary to determine the timing of events and rates of processes in the marine realm and the relationships among marine and other climatically sensitive records the establishment of an accurate chronology for pleistocene marine sediments beyond the range of radiocarbon dating approximately the past 45 kyr has therefore been a goal of palaeoceanographers for decades early attempts1 2 based on measurements of the radionuclides 230th and 231pa were beset with problems and subsequent studies focused on tying fluctuations in marine sediment oxygen isotope records to events such as the formation of coral reef terraces and changes in the earth s magnetic polarity3 4 and tuning the resultant chronologies to the earth s orbitally driven insolation variations5 8 but these chronologies especially the age and duration of the last interglacial period have been challenged by several studies9 12 raising questions about the fundamental cause of pleistocene climate fluctuations here we report the direct u th dating of aragonite rich marine sediments from the bahamas and present an accurately dated marine oxygen isotope record for the last two interglacials we obtain dates of 120 127 kyr bp for the last interglacial and 189 190 kyr bp for the late stage 7 interglacial these dates are in accord with the general theory of orbitally forced climate fluctuations and demonstrate the potential of our direct dating approach for developing an absolute chronology for the pleistocene marine oxygen isotope record

cadmium and delta13c paleochemical ocean distributions during the stage 2 glacial maximum changes in heat and salt transport by ocean currents have been implicated in ice age climate cycles weyl 1 968 newell 1 974 broecker et al 1 990b in addition to the direct physical effects of the ocean on climate the ocean carbon system controls atmospheric co2 and the co2 fluctuations documented in ice core bubbles barnola et a1 1 987 neftel et a1 1 988 are thought to be a significant factor in climate oscillations hansen et al 1 984 dramatic changes in oceanic circulation patterns and carbon system chemistry have occurred during the late quaternary glacial interglacial global climate cycles boyle keigwin 1 982 curry lohmann 1 983 shackleton pisias 1 984 boyle keigwin 1 987 duplessy et al 1 988 curry et al 1 988 broecker et al i 990a these changes in the ocean system may be significant driving forces in the progression of ice age co2 cycles toggweiler sarmiento 1 985 ennever mcelroy 1 985 wenk siegenthaler 1 985 boyle 1 988a b broecker peng 1 990 the oceanic distributions of c513c cd and other carbon system linked properties are controlled by the interaction between biological uptake and decomposition with the general circulation of the ocean because records of past oceanic cd and c5 1 3c are preserved in shells of planktonic and benthic foraminifera

the dynamics of the marine nitrogen cycle across the last deglaciation 1 we use a geochemical box model to investigate the changes in marine n fixation and denitrification required to match the observed sedimentary 15n changes between 30 kyr b p and the late holocene this is achieved by optimizing a set of seven parameters that describe the strengths of three ocean internal n feedbacks and the response of the oceanic n cycle to four external forcings scenarios that best match the 15n constraints indicate a strong transient decrease in n fixation in the early deglacial in response to the decrease in iron input by dust around 15 kyr b p n fixation rebounds primarily in response to an abrupt increase in water column denitrification caused by an expansion of anoxia benthic denitrification is not well constrained by our model but tends to increase in sync with water column denitrification as a result of the transient imbalance between n fixation and denitrification we infer a glacial to interglacial decrease in the marine n inventory of between 15 and 50 the model diagnoses this reduction in order to simultaneously fit the data from all ocean basins requiring it to reduce the degree by which water column denitrification in the oxygen minimum zones is influencing the 15n of nitrate of the whole ocean dilution effect our optimal solution suggests a glacial n cycle that operated at nearly the same rates as that in pre industrial times but sensitivity cases with substantially lower rates fit the data only marginally worse an important caveat of our study is the assumption of an unchanging ocean circulation an initial sensitivity experiment shows that this affects primarily the magnitude of the change in the n inventory while the diagnosed deglacial dynamics with global marine n fixation taking a dip before the onset of denitrification remains a robust result

size dependence of iron solubility of asian mineral dust particles 1 asian mineral dust was sampled at hokkaido northern japan in spring 2004 and 2006 iron solubility of the bulk aerosol the size segregated aerosol 0 45 4 7 m we suggest that an iron solubility of around 0 4 is typical for asian mineral dust of large particles transported to hokkaido in the high nutrient low chlorophyll region of the western subarctic north pacific near the asian continent where the mineral dust deposition is dominated by large particles the iron solubility of the mineral dust entering the ocean is around 0 4

productivity response in the north canary basin to climate changes during the last 250 000 yr a multi proxy approach we present results from the investigation of the primary productivity record over the last 250 kyr in the north canary basin 30 n off northwest africa two distinct productive systems interfere in this area the oligotrophic open ocean and the upwelling filament off cape ghir that occasionally carries offshore cool nutrient rich waters the following geochemical and micropaleontological paleoproductivity proxies have been used in our study calcium carbonate barium excess baexcess total organic carbon toc and diatoms time series analysis of these proxies indicates that paleoproductivity in the north canary basin underwent important changes following precession and eccentricity cycles while the precessional signal appears to be mainly related to trade wind strength superimposed peaks in baexcess toc and diatom records point to large productivity events at terminations i ii and iii lowering of the north atlantic sea surface temperatures by melt water discharges which in turn strengthened the azores high pressure center and increased trade wind velocities is postulated as the mechanism to explain the enhancement of the coastal upwelling and associated filaments at terminations additionally the canary current may play a role in transmitting cold melt waters and nutrients from higher latitudes to the north canary basin

a 150 000 year climatic record from antarctic ice during much of the quaternary the earth s climate has undergone drastic changes most notably successive glacial and interglacial episodes the past 150 kyr includes such a climatic cycle the last interglacial the last glacial and the present holocene interglacial a new climatic time series for this period has been obtained using 18 o data from an antarctic ice core

ice core sample measurements give atmospheric co 2 content during the past 40 000 yr recent measurements1 2 on ice samples from camp century greenland 77 10 n 61 08 w byrd station antarctica 80 01 s 110 31 w and dome c 74 40 s 125 10 e suggest that during the late part of the last glaciation the atmospheric co2 concentration was significantly lower than during the holocene further investigation of this natural increase of the atmospheric co2 concentration in the past should aid our understanding of the climatic implications of the man made co2 increase since the beginning of industrialization3 here we report new and precise measurements of the co2 concentration of the air occluded in bubbles of ice samples from camp century and byrd station using a new dry extraction technique the extracted gases were analysed with an ir laser spectrometer irls samples from 22 different depths were analysed from each core the samples are distributed over a depth interval corresponding approximately to the past 40 000 yr in addition results for ice samples from selected depth horizons from a colder region north central greenland 74 37 n 39 36 w and from a warmer region dye 3 greenland 65 11 n 43 50 w are given based on these results we estimate the trend of the atmospheric co2 concentration during the past 40 000 yr

ice core evidence for the extent of past atmospheric co2 change due to iron fertilisation 1 an extended high resolution ice core record of dust deposition over the past 60 ka from dome c antarctica is presented the data are in conflict with the idea that changes in aeolian iron input into the southern ocean were the major cause for the 80 ppm glacial interglacial co2 increase during the deglaciation the co2 increase shows a linear relationship with the fall of the logarithm of the nss ca2 flux a proxy for dust deposition however the very large variations in the nss ca2 flux related to the glacial antarctic warm events a1 to a4 were accompanied by small co2 variations only our data based analysis suggests that decreased southern ocean dust deposition caused at most a 20 ppm increase in co2 at the last glacial interglacial transition rapid decreases in dust deposition to the northern pacific could have been responsible for a maximum of 8 ppm in addition

deep sea sedimentary analogs for the vostok ice core 1 many applications of the vostok ice core depend critically on the ability to make stratigraphic ties to marine records in the adjacent southern ocean here we present oxygen isotopic records from high accumulation rate sites in the south atlantic sector of the southern ocean collected for the purpose of complementing the recently extended d record from the vostok ice core the combination of several planktonic foraminiferal 18o records from northern subantarctic piston cores demonstrates that all of the millennial scale oscillations expressed in the vostok ice core over the last 60 ky are also present in marine records the observations also support the assumption that the millennial scale oscillations common to both marine and ice archives are synchronous thus providing a rationale for extending the marine ice core comparison through the last 400 000 years making use of a marine drilled core odp site 1089 by aligning the phase of these common abrupt events we anchor the vostok chronology to an orbitally tuned marine sediment chronology a refinement that allows examination of a variety of paleoclimatological issues such as the relationship between deep ocean variability and antarctic polar climate for example this exercise suggests that over at least the 4 major deglaciation events the primary orbital scale changes in the chemistry and most likely the temperature of the deep southern ocean were synchronous with changes in atmospheric pco2 and polar air temperatures we also find that the deuterium excess in the ice core resembles marine foraminiferal 13c records and that the deuterium excess is synchronous with an anomalous foraminiferal 18o signal the residual between normalized versions of vostok d and foraminiferal 18o these observations demand a tight link between the vostok isotopic record and the air sea interaction of the subantarctic zone

four climate cycles in vostok ice core author s petit jr basile i leruyuet a raynaud d lorius c jouzel j stievenard m lipenkov vy barkov ni kudryashov bb davis m saltzman e kotlyakov v

age dating and the orbital theory of the ice ages development of a high resolution 0 to 300 000 year chronostratigraphy using the concept of orbital tuning a continuous high resolution deep sea chronostratigraphy has been developed spanning the last 300 000 yr the chronology is developed using a stacked oxygen isotope stratigraphy and four different orbital tuning approaches each of which is based upon a different assumption concerning the response of the orbital signal recorded in the data each approach yields a separate chronology the error measured by the standard deviation about the average of these four results which represents the best chronology has an average magnitude of only 2500 yr this small value indicates that the chronology produced is insensitive to the specific orbital tuning technique used excellent convergence between chronologies developed using each of five different paleoclimatological indicators from a single core is also obtained the resultant chronology is also insensitive to the specific indicator used the error associated with each tuning approach is estimated independently and propagated through to the average result the resulting error estimate is independent of that associated with the degree of convergence and has an average magnitude of 3500 yr in excellent agreement with the 2500 yr estimate transfer of the final chronology to the stacked record leads to an estimated error of 1500 yr thus the final chronology has an average error of 5000 yr