middle miocene ocean climate transition high resolution oxygen and carbon isotopic records from deep sea drilling project site 588a southwest pacific high resolution stable isotopic records are presented for the epi benthic foraminifer cibicidoides the inferred shallow dwelling planktonic globigerinoides quadrilobatus and the inferred deep dwelling planktonic globoquadrina dehiscens from the middle miocene 16 12 ma of deep sea drilling project site 588a lord howe rise southwest pacific high resolution multiple species oxygen and carbon isotopic data define the timing and character of the well known middle miocene climatic oceanographic transition with a resolution comparable to quaternary records the benthic foraminiferal 18o record is marked by several large fluctuations from 16 to 14 8 ma followed by a series of rapid 50 kyr 18o increases that suggest a new state of the ocean climate system after 14 8 ma the total middle miocene benthic oxygen isotopic increase of 1 2 is largely incorporated in two steps an increase of 0 8 from 14 5 to 14 0 ma and a second increase of 0 7 from 13 45 to 12 45 ma each step is comprised of a series of marked 18o increases indicative of rapid east antarctic ice sheet growth and contemporaneous deepwater cooling a strong covariance of 0 7 between the benthic and deep dwelling planktonic species from 14 5 to 14 0 ma including a rapid increase from 14 1 to 14 05 ma suggests a 0 7 increase in the 18o composition of seawater 18osw because of east antarctic ice sheet growth comparison of the 18o record of gs quadrilobatus suggests that surface waters warmed at this site by 3 c from 14 1 to 13 6 ma carbon isotopic time series for each species generally covary throughout the early to middle miocene interval 16 12 ma confirming that 13c variations in this interval largely represent reservoir changes high resolution 13c data allow improved resolution of the latter five of six 13c maxima within the well known early to middle miocene carbon isotopic excursion the monterey carbon isotopic excursion from 17 0 to 13 5 ma this is useful for global correlation the last of these maxima ends with a 1 decrease centered from 13 9 to 13 7 ma 300 kyr after the 18o increase considered to reflect east antarctic ice growth covariance between benthic 18o and 13c from 16 to 13 8 ma suggests a sensitive relation between global carbon cycling and the ocean climate system prior to 13 8 ma episodic increases in organic carbon burial may have contributed to deep sea benthic 13c maxima and synchronous global cooling the positive relationship ended at 13 8 ma indicative of changing relations between global carbon cycling and the ocean climate system brought on by the increased stability of the east antarctic ice sheet after a major growth phase from 14 5 to 14 0 ma

phosphorites co rich mn nodules and fe mn crusts from galicia bank ne atlantic reflections of cenozoic tectonics and paleoceanography a wide variety of marine mineral deposits were recovered from 750 to 1400 m water depths on galicia bank iberian margin mineral deposits include 1 carbonate fluorapatite phosphorite slabs and nodules that replaced limestone and preserved original protolith fabric 2 ferromanganese vernadite crusts with high mn and fe mn fe 1 contents and thick stratabound layers consisting mainly of mn up to 27 mno and fe 15 fe2o3 which impregnated and replaced the phosphorite 3 co rich mn nodules are composed of romanechite and todorokite laminae mn rich layers up to 58 mno contain up to 1 8 co 4 goethite nodules with fe up to 67 fe2o3 have low mn and trace metals we interpret this mineralization paragenesis to be related to major changes in oceanographic and tectonic regimes three phosphatization generations formed hardgrounds dated by 87sr 86sr isotopes as late oligocene early miocene and latest early miocene during the latest early miocene the hardground was fractured and breached due to regional intraplate tectonism which was coeval with a widespread regional erosional unconformity the stratabound layers and co rich manganese nodules were derived from low temperature geothermally driven hydrothermal fluids with fluid conduits along reactivated faults during middle and late miocene the introduction of vigorous deep water flow from the arctic generated growth of hydrogenetic ferromanganese crusts finally growth of diagenetic fe rich nodules late pliocene was promoted by the introduction of hypersaline mediterranean outflow water into the atlantic ocean

phosphogenesis and weathering of shelf sediments from the southeastern united states implications for miocene δ13c excursions and global cooling the enormous phosphorite deposits of the southeastern united states indicate intense upwelling but contain small amounts of organic carbon the authors propose that deposition of organic rich sediment on continental shelves in the southeastern united states and elsewhere during marine transgressions in the late oligocene and early to middle miocene resulted in global positive delta sup 13 c shifts and the formation of early diagenetic phosphorite multiple reworking and supergene weathering from subaerial exposure during miocene marine regressions oxidized most of the organic carbon and resulted in the return of delta sup 13 c to its preexcursion value the estimated phosphorite content of the southeastern united states requires sufficient organic carbon burial 10 sup 15 kg carbon to support a 1 per thousand delta sup 13 c excursions sea level fluctuations organic carbon burial phosphogenic episodes and possibly global cooling during the cenozoic

cenozoic ice volume history development of a composite oxygen isotope record to view cenozoic ice volume and ocean temperature history a composite 18 o time series was constructed for tropical shallow dwelling planktonic foraminifers and for deep water benthic foraminifers we conclude that cenozoic benthic 18 o primarily reflect considerable deep ocean temperature variation and that tropical planktonic 18 o afford the best record of cenozoic ice volume the planktonic composite indicates the presence of a significant ice budget for the past 40 m y the difference between the benthic and planktonic 18 o composites suggests that low latitude production of warm saline bottom water dominated tertiary thermohaline circulation

minimal influence of recrystallization on middle miocene benthic foraminiferal stable isotope stratigraphy in the eastern equatorial pacific stable carbon and oxygen isotopes 13c and 18o of foraminiferal tests are amongst the most important tools in paleoceanography but the extent to which recrystallization can alter the isotopic composition of the tests is not well known here we compare three middle miocene 16 13 ma benthic foraminiferal stable isotope records from eastern equatorial pacific sites with different diagenetic histories to investigate the effect of recrystallization to test an extreme case we analyzed stable isotope compositions of benthic foraminifera from integrated ocean drilling program site u1336 for which the geochemistry of bulk carbonates and associated pore waters indicates continued diagenetic alteration in sediments 14 7 ma despite this diagenetic overprinting the amplitudes and absolute values of the analyzed u1336 stable isotopes agree well with high resolution records from better preserved sites u1337 and u1338 nearby our results suggest that although benthic foraminiferal tests of all three sites show some degree of textural changes due to recrystallization they have retained their original stable isotope signatures the good agreement of the benthic foraminiferal stable isotope records demonstrates that recrystallization occurred extremely rapidly 100 kyr after deposition this is confirmed by the preservation of orbital cyclicities in u1336 stable isotope data and 18o values being different to inorganic calcite that would precipitate from u1336 pore waters during late recrystallization the close similarity of the benthic foraminiferal stable isotope records between the sites allows the well resolved paleomagnetic results of site u1336 to be transferred to sites u1337 and u1338 improving the global geological timescale

equatorial pacific deep sea benthic foraminifera faunal changes before the middle miocene polar cooling data on the composition of benthic foraminiferal faunas at deep sea drilling project site 575 in the eastern equatorial pacific ocean were combined with benthic and planktonic carbon and oxygen isotope records and caco 3 data changes in the composition of the benthic foraminiferal faunas at site 575 predated the middle miocene period of growth of the antarctic ice cap and cooling of the deep ocean waters by about 2 m y and thus were not caused by this cooling as has been proposed the benthic faunal changes may have been caused by increased variability in corrosivity of the bottom waters possibly resulting from enhanced productivity in the surface waters

tertiary oxygen isotope synthesis sea level history and continental margin erosion tertiary benthic and planktonic foraminiferal oxygen isotope records are correlated to a standard geomagnetic polarity time scale making use of improved chronostratigraphic control and additional oligocene isotope data synchronous changes in both benthic and planktonic 18o values which occurred in the oligocene to miocene 36 5 2 ma are interpreted in part to represent ice growth and decay the inferred ice growth events correlate with erosion on passive continental margins as interpreted from seismic and chronostratigraphic records this association is consistent with a link between oligocene to miocene erosional events and rapid 15 m m y glacioeustatic lowerings of about 50 m high benthic foraminiferal 18o values suggest the presence of continental ice sheets during much of the oligocene to recent 36 0 ma substantially ice free conditions probably existed throughout the paleocene and eocene 66 36 ma the mechanisms and rates of sea level change apparently were different between the early and late tertiary with glacioeustatic changes restricted to the past 36 m y pre oligocene erosion on passive continental margins was caused by eustatic lowerings resulting from global spreading rate changes we apply a model which suggests that large areas of the continental shelves were subaerially exposed during such tectonoeustatic lowstands stimulating slope failure and submarine erosion the different mechanisms and rates of eustatic change may have caused contrasting erosional patterns between the early and late tertiary on passive continental margins this speculation needs to be confirmed by examination of data from several passive margins

stable isotopes in large herbivore tooth enamel capture a mid miocene precipitation spike in the interior pacific northwest abstract stable carbon and oxygen isotopes of fossil ungulate tooth enamel were used to investigate the paleoclimate of the pacific northwest from the mid oligocene through pleistocene particularly targeting the mid miocene climatic optimum mmco we specifically test whether precipitation as inferred from tooth enamel 13c values relative to the 13c values of atmospheric co2 13c increased with increasing partial pressure of atmospheric co2 pco2 analysis emphasized water dependent equids rhinos and proboscideans but several artiodactyls and castor were also analyzed as available values of 13c 19 5 in the lower john day 27 and 18 ma and mascall 15 16 ma localities imply relatively high mean annual precipitation map ca 550 800 mm yr values of 13c

paleoceanographic significance of neogene benthic foraminiferal changes in a southwest pacific bathyal depth transect temporal changes in benthic foraminiferal assemblages were quantitatively examined 63 m fraction in four southwest pacific deep sea neogene sequences in a depth transect between approximately 1300 and 3200 m to assist in evaluating paleoceanographic history the most conspicuous changes in benthic foraminiferal assemblages occurred in association with paleoclimatic changes defined at least in part by oxygen isotopic changes the largest centered at 15 ma early middle miocene is represented by an increase in the relative frequencies ofepistominella exigua which underwent a major upward depth migration at that time this was contemporaneous with the well known positive oxygen isotopic shift in the early middle miocene in sites 588 and 590 most of the increase in relative abundances ofe exigua occurred during the middle to later part of the 18o shift following major growth of the east antarctic ice sheet later assemblage changes occurred at 8 5 and 6 5 ma these associations indicate that the benthic foraminiferal assemblages in this depth transect largely adjusted to changes in deep waters related to antarctic cryospheric evolution in general the neogene benthic foraminiferal assemblages in this region underwent little change during the last 23 million years this faunal conservatism suggests that deep sea environments underwent relatively little change in the southwest pacific during much of the neogene although paleoceanographic changes did occur partly in response to high latitude cryospheric evolution these were not of sufficient magnitude to create major deep sea faunal changes in this part of the ocean the benthic foraminiferal assemblages are dominated by individuals smaller than 150 m most taxonomic turnover occurred in the larger 150 m size fractions

a new geomagnetic polarity time scale for the late cretaceous and cenozoic we have constructed a magnetic polarity time scale for the late cretaceous and cenozoic based on an analysis of marine magnetic profiles from the world s ocean basins this is the first time since heirtzler et al 1968 published their time scale that the relative widths of the magnetic polarity intervals for the entire late cretaceous and cenozoic have been systematically determined from magnetic profiles a composite geomagnetic polarity sequence was derived based primarily on data from the south atlantic anomaly spacings in the south atlantic were constrained by a combination of finite rotation poles and averages of stacked profiles fine scale information was derived from magnetic profiles on faster spreading ridges in the pacific and indian oceans and inserted into the south ariantic sequence based on the assumption that spreading rates in the south atlantic were smoothly varying but not necessarily constant a time scale was generated by using a spline function to fit a set of nine age calibration points

response of deep ocean circulation to initiation of northern hemisphere glaciation 3 2 ma carbon isotopic records from benthic foraminifera are used to map patterns of deep ocean circulation between 3 and 2 million years ago the interval when significant northern hemisphere glaciation began the 18o and 13c data from four atlantic sites 552 607 610 and 704 and one pacific site 677 show that global cooling over this interval was associated with increased suppression of north atlantic deep water nadw formation however the relative strength of nadw production was always greater than is observed during late pleistocene glaciations when extreme decreases in nadw are observed in the deep north atlantic our data indicate that an increase in the equator to pole temperature gradient associated with the onset of northern hemisphere glaciation did not intensify deepwater production in the north atlantic but rather the opposite occurred this is not unexpected as it is the warm high salinity characteristic rather than the low temperature of thermocline waters that is critical to the deepwater formation process in this region today

vertical distribution and isotopic fractionation of living planktonic foraminifera from the panama basin a model1 2 which explains the vertical and seasonal distribution of planktonic foraminifera was developed using data from the western north atlantic and is comprised of three tenets 1 the conditions in the photic zone upper 80 100 m exclusively dictate planktonic foraminifera species composition and abundance throughout the water column 2 species are vertically stratified within the photic zone according to their temperature preference depth distribution according to temperature preference has been proposed by several authors3 based on isotope analyses of sediments due to seasonal temperature variations seasonal variations in the 18o composition of seawater and species specific isotope fractionation rigorous proof of this hypothesis cannot be provided from sediment analyses alone 3 the chlorophyll maximum is a major food source zone which is preferentially exploited by foraminifera our data from the panama basin which are presented here are confirmation of this model the panama basin in the eastern equatorial pacific which has a shallow and steep thermocline was sampled for living planktonic foraminifera a multiple opening closing net and environmental sensing system mocness 4 was used to collect 13 sets of eight vertically stratified oblique samples we report here the quantitative distribution and stable isotopic composition of planktonic foraminifera from four mocness tows taken over 5 days during august 1979 rv knorr cruise 73 at 5 20 n 8 50 w each tow consisted of eight samples which integrated 12 5 m intervals from 0 to 100 m for moc 126 25 m intervals from 0 to 200 m for moc 127 100 150 m intervals from 0 to 1 000 m on moc 128 and 250 m intervals from 0 to 2 000 m on moc 131

high resolution strontium isotope stratigraphy and biostratigraphy of the miocene monterey formation central california detailed biostratigraphic and sr isotope studies on two outcrop sections of the miocene monterey formation of california demonstrate the applicability of the sr isotope method for detailed chronostratigraphic correlation multidisciplinary biostratigraphic ages generally agree with sr isotopic ages determined by correlating 87sr 86sr ratios with a standard 87sr 86sr versus age curve constructed of data from deep sea drilling project sites 575 and 590 diagenetic modification of sr isotopic ratios of the monterey formation was negligible strontium isotopes provide age resolutions of 0 1 to 0 2 ma in the lower miocene small faults and slump structures are identified as reversals within a general trend of increasing 87sr 86sr biostratigraphy yields the more definitive age assignments in the younger siliceous rocks where diatoms in particular have more utility than the corresponding flat and polytonal portion of the isotopic curve strontium isotopic correlation of the basal monterey formation with deep sea drilling project site 575 indicates that monterey deposition commenced at 17 85 0 10 ma within planktic foraminiferal zone n6 and calcareous nannofossil zone cn2 concomitant with an increase in slope of the sea water 87sr 86sr versus age curve this event dates 0 35 0 10 m y before the beginning of the pronounced shift of 13c and 1 4 m y before the shift of 18o observed at site 575 it is evident that sr isotope stratigraphy is a valuable supplement to biostratigraphy the techniques are complementary in refining chronostratigraphic interpretations

coupled southern ocean cooling and antarctic ice sheet expansion during the middle miocene the middle miocene climate transition 14 million years ago was characterized by a dramatic increase in the volume of the antarctic ice sheet the driving mechanism of this transition remains under discussion with hypotheses including circulation changes declining carbon dioxide in the atmosphere and orbital forcing southern ocean records of planktic foraminiferal mg ca have previously been interpreted to indicate a cooling of 6 7 c and a decrease in salinity that preceded antarctic cryosphere expansion by up to 300 000 years this interpretation has led to the hypothesis that changes in meridional heat and vapour transport along with an early thermal isolation of antarctica from extrapolar climates played a fundamental role in triggering ice growth here we revisit the middle miocene southern ocean temperature evolution using clumped isotope and lipid biomarker temperature proxies our records indicate that the southern ocean cooling and the associated salinity decrease occurred in phase with the expansion of the antarctic ice sheet we demonstrate that the timing and magnitude of the southern ocean temperature change seen in previous reconstructions can be explained if we consider ph as an additional non thermal control on foraminiferal mg ca ratios therefore our new dataset challenges the view of a thermal isolation of antarctica preceding ice sheet expansion and suggests a strong coupling between southern ocean conditions and antarctic ice volume in times of declining atmospheric carbon dioxide antarctic ice volume expansion in the middle miocene coincides with southern ocean cooling according to biomarker and clumped isotope temperature records from south of tasmania

carbon and oxygen isotopic disequilibria of recent deep sea benthic foraminifera abstract the carbon and oxygen isotopic compositions of 149 samples of benthic foraminifera from deep sea core tops indicate that none of the nine species studied secrete calcium carbonate in isotopic equilibrium with ambient bottom water uvigerina pyrgo murrhina and oridorsalis tener are the closest to 18o equilibrium with average deviations about 0 4 while planulina wuellerstorfi and p murrhina are the closest to 13c equilibrium with average deviations about 1 p wuellerstorfi shows the most systematic relationship between 13c and bottom water apparent oxygen utilization the intraspecific variabilities in 18o and 13c suggest that estimates of bottom water paleotemperatures can be made to a precision of 0 7 c while estimates of past apparent oxygen utilization aou can be made to 35 mol kg based on intraspecific comparisons of the recent samples with fossils no temporal changes in the degree of either 18o or 13c disequilibrium have been detected for planulina wuellerstorfi uvigerina oridorsalis tener and globocassidulina subglobosa

magnetostratigraphy of cenozoic deposits in the western qaidam basin and its implication for the surface uplift of the northeastern margin of the tibetan plateau abstract thick cenozoic deposits in the northwestern qaidam basin record erosion of the altyn tagh and high terrain west of that basin and presumably the concurrent growth of the northeastern tibetan plateau a detailed magnetostratigraphic study of the huatugou section northwestern qaidam basin reveals that this section spans the period from 30 to 11 ma magnetostratigraphic and sedimentological studies indicate that the accumulation rate abruptly increased near 15 ma the acceleration in sedimentation rate suggests enhanced tectonic deformation in the qaidam basin since 15 ma that may have begun simultaneously with accelerated deformation along the altyn tagh kunlun and haiyuan faults which contributed to the growth history of the qaidam basin and its surroundings since 15 ma

early and middle miocene stable isotopes implications for deepwater circulation and climate the middle miocene 18o increase represents a fundamental change in the ocean atmosphere system which like late pleistocene climates may be related to deepwater circulation patterns there has been some debate concerning the early to early middle miocene deepwater circulation patterns specifically recent discussions have focused on the relative roles of northern component water ncw production and warm saline deep water originating in the eastern tethys our time series and time slice reconstructions indicate that ncw and tethyan outflow water two relatively warm deepwater masses were produced from 20 to 16 ma ncw was produced again from 12 5 to 10 5 ma another feature of the early and middle miocene oceans was the presence of a high 13c intermediate water mass in the southern hemisphere which apparently originated in the southern ocean miocene climates appear to be related directly to deepwater circulation changes deep waters warmed in the early miocene by 3 c 20 to 16 ma and cooled by a similar amount during the middle miocene 18o increase 14 8 to 12 6 ma corresponding to the increase 20 ma and subsequent decrease 16 ma in the production of ncw and tethyan outflow water large 0 6 relatively rapid 0 5 m y 18o increases in both benthic and planktonic foraminifera i e the mi zones of miller et al 1991a and wright and miller 1992a were superimposed in the long term deepwater temperature changes they are interpreted as reflecting continental ice growth events seven of these m y glacial interglacial cycles have been recognized in the early to middle miocene two of these glacial interglacial cycles mi3 and mi4 combined with a 2 to 3 c decrease in deepwater temperatures to produce the middle miocene 18o shift

mid miocene isotope stratigraphy in the deep sea high resolution correlations paleoclimatic cycles and sediment preservation mid miocene pelagic sedimentary sections can be correlated using intermediate and high resolution oxygen and carbon isotopic records of benthic foraminifera precision of a few tens of thousands of years is readily achievable at sites with high sedimentation rates for example deep sea drilling project sites 289 and 574 the mid miocene carbon isotope records are characterized by an interval of high 13c values between 17 and 13 5 ma the monterey excursion of vincent and berger 1985 upon which are superimposed a series of periodic or quasi periodic fluctuations in 13c values these fluctuations have a period of approximately 440 kyr suggestive of the 413 kyr cycle predicted by milankovitch theory vincent and berger proposed that the monterey excursion was the result of increased organic carbon burial in continental margins sediments the increased 13c values called 13c maxima superimposed on the generally high mid miocene signal coincide with increases in 18o values suggesting that periods of cooling and or ice buildup were associated with exceptionally rapid burial of organic carbon and lowered atmospheric co2 levels it is likely that during the monterey excursion the ocean atmosphere system became progressively more sensitive to small changes in insolation ultimately leading to major cooling of deep water and expansion of continental ice we have assigned an absolute chronology based on biostratigraphic and magneto biostratigraphic datum levels to the isotope stratigraphy and have used that chronology to correlate unconformities seismic reflectors carbonate minima and dissolution intervals intervals of sediment containing 13c maxima are usually better preserved than the overlying and underlying sediments indicating that the 13c values of tco2 in deep water and the corrosiveness of seawater are inversely correlated this again suggests that the 13c maxima were associated with rapid burial of organic carbon and reduced levels of atmospheric co2 the absolute chronology we have assigned to the isotopic record indicates that the major mid miocene deepwater cooling ice volume expansion took 2 m y and was not abrupt as had been reported previously the cooling appears abrupt at many sites because the interval is characterized by a number of dissolution intervals the cooling was not monotonic and the 2 m y interval included an episode of especially rapid cooling as well as a brief return to warmer conditions before the final phase of the cooling period the increase in 18o values of benthic foraminifera between 14 9 and 12 9 ma was greatest at deeper water sites and at sites closest to antarctica the data suggest that the 18o value of seawater increased by no more than about 1 1 per mil during this interval and that the remainder of the change in benthic 18o values resulted from cooling in antarctic regions of deepwater formation equatorial planktonic foraminifera from sites 237 and 289 exhibit a series of 0 4 per mil steplike increases in 13c values only one of these increases in planktonic 13c is correlated with any of the features in the mid miocene benthic carbon isotope record

relations between monterey formation deposition and middle miocene global cooling naples beach section california an oxygen and carbon isotopic stratigraphy has been established for the miocene monterey formation 18 to 8 ma at naples beach santa barbara county california correlation to the deep sea climatic record provides a test of the monterey hypothesis which suggests that organic carbon rich deposition in the monterey formation fostered middle miocene global cooling through drawdown of atmospheric partial co 2 oxygen isotopic correlation of the naples beach section to the deep sea record suggests that increased organic carbon rich deposition coincided closely with deep water cooling and major east antarctic ice sheet growth from 14 5 to 14 1 ma and with a 13 c maximum in deep sea records these results support a corollary of the monterey hypothesis that episodic organic carbon rich deposition within the monterey formation contributed to deep sea 13 c maxima and to synchronous global cooling

tertiary ice sheet dynamics the snow gun hypothesis we observe strong negative correlation between tertiary low to mid latitude planktonic foraminiferal 18o and the difference between these data and coeval benthic foraminiferal 18o late quaternary data do not show this correlation coupling statistical model 18o comparisons and evidence for antarctic ice and ocean temperature variation we infer that tertiary ice volume recorded by tropical planktonic 18o increased as the deep ocean warmed because the isotopic signatures of deepwater temperature variation and ice volume change were of opposite sign the sum of these signals in tertiary benthic 18o became lost in the noise this renders low correlation between tertiary planktonic and benthic 18o time series compared to late quaternary data we contend that tertiary ice sheet growth was commonly driven by warming of deep water from low to mid latitude marginal seas snow gun hypothesis in contrast late quaternary ice sheets grew as deep water formed at high latitude cooled because tectonic forcing and orbital forcing at low latitude primarily controlled production and temperature variations of this warm saline deep water these influences largely dictated tertiary ice volume fluctuations through the tertiary we infer ice volume fluctuations to be an important component of sea level history on timescales between 103 and 107 years

miocene stable isotope record a detailed deep pacific ocean study and its paleoclimatic implications deep sea drilling project site 289 in the western equatorial pacific has yielded an extremely detailed record of the carbon and oxygen isotopic changes in the miocene deep ocean the isotopic record reflects major changes in paleoclimate and paleoceanography probably dominated by a major phase of antarctic ice cap growth the transition from a relatively unglaciated world to one similar to today occurred between 16 5 x 10 6 and 13 x 10 6 years before the present with the greatest change occurring between approximately 14 8 x 10 6 and 14 0 x 10 6 years before the present

detailed record of the neogene sr isotopic evolution of seawater from dsdp site 590b a detailed study of strontium isotope variations in neogene marine carbonate sediments from deep sea drilling project site 590b using techniques that allow the 87sr 86sr ratio to be determined to better than 0 00001 gives a high resolution record of the sr isotopic evolution of seawater the data show that the rate of change of the marine 87sr 86sr ratio has varied significantly even on time scales as short as 1 m y periods of particularly rapid growth appear to follow major marine regressions and probably reflect an increase in the delivery of radiogenic sr from the continents coupled with a decreased submarine carbonate dissolution rate greater carbonate compensation depth periods of relatively slowly changing 87sr 86sr follow major marine transgressions on the basis of correlations with the marine oxygen isotope record and the times of major continental glacier growth it is inferred that the effects of sea level variations are modified by climatic factors that affect the intensity of continental weathering and runoff the effects of sea floor generation rate variations are not discernible for the neogene the maximum attainable stratigraphic resolution using sr isotopes is between 0 1 and 2 m y for this time period

miocene deepwater oceanography a global synthesis of miocene benthic foraminiferal carbon and oxygen isotopic and faunal abundance data indicates that miocene thermohaline circulation evolved through three regimes corresponding approximately to early middle and late miocene times there is evidence for major qualitative differences between the circulation of the modern ocean and the miocene ocean prior to 11 ma the 13c 12c ratios of the benthic foraminifera cibicidoides are interpreted in terms of water mass aging i e the progressive depletion of dissolved o2 and lowering of 13c values as the result of oxidation of organic matter as water flows further from its sources at the surface of the oceans both isotopic and faunal data indicate that the early miocene regime from 22 to 15 ma was the most different from today s during that interval intermediate and deep waters of both the atlantic and the pacific oceans aged in a northward direction and the intermediate waters of the indian the south atlantic and the south pacific oceans were consistently the youngest in the global ocean we speculate that early miocene global thermohaline circulation may have been strongly influenced by the influx of warm saline water tethyan indian saline water from the tethys into the northern indian ocean the isotopic and faunal data suggest that flow from the tethyan region into the indian ocean diminished or terminated at about 14 ma isotopic and faunal data give no evidence for north atlantic deep water nadw formation prior to about 14 5 ma with the exception of a brief episode in the early miocene from 14 5 to 11 ma nadw formation was weak and circumpolar and antarctic water flooded the deep south atlantic and south pacific as the antarctic ice cap grew from about 10 ma to the end of the miocene thermohaline circulation resembled the modern circulation in many ways in latest miocene time 6 to 5 ma circulation patterns were very similar to today s except that nadw formation was greatly diminished the distribution pattern of siliceous oozes in miocene sediments is consistent with our proposed reconstruction of thermohaline circulation major changes which occurred in circulation during the middle miocene were probably related to the closing of the tethys and may have contributed to rapid middle miocene growth of the antarctic ice cap appendices 1 4 6 and 7 are available withentire article on microfiche order fromamerican geophysical union 2000 floridaavenue n w washington dc 20009 document 88p 002 5 00 payment mustaccompany order

miocene benthic foraminiferal isotope records a synthesis abstract 18 o 16 o and 13 c 12 c ratios of miocene benthic foraminifera from a number of atlantic pacific and indian ocean dsdp sites 71 77b 206 208 238 279 289 296 329 357 and 366a have been compiled these provide a rather detailed history of miocene deep water especially in the pacific ocean bottom water temperatures rose during the early miocene and then declined rapidly during the middle miocene this decline was accompanied by an increase in antarctic glaciation late miocene bottom temperatures and antarctic ice volumes are inferred to be similar to today s but exhibited some fluctuation the early miocene ocean was less thermally stratified at intermediate and abyssal depths while the late miocene deep ocean had a thermal structure generally similar to the modern ocean foraminiferal carbon isotope ratios at most of the sites varied quasi sympathetically throughout the miocene these variations must reflect comparable variations in the mean 13 c 12 c of marine hco 3 however the causes of such variations are not yet clear

stable isotope paleoaltimetry a critical review stable isotope paleoaltimetry makes use of systematic trends in the distribution and isotopic composition of modern precipitation with climate and topography and of the potential to estimate the isotopic composition of paleoprecipitation from authigenic in situ formed minerals to illustrate the usefulness as well as potential limitations of this method we review 1 processes controlling the isotopic composition of modern precipitation 2 stable isotope data from modern precipitation across regions of high topography and 3 stable isotope data from authigenic minerals that have been used to infer paleotopography from this we conclude that stable isotope studies of authigenic minerals can permit useful inferences on paleotopography with uncertainties that critically depend on a detailed understanding of local to global scale paleoclimate during the time interval of interest

variations in the strontium isotopic composition of seawater during the neogene the authors report 261 strontium isotopic analyses of well preserved planktonic foraminifers from three deep sea drilling project sites 519 588 and 607 these samples cover the period from 24 ma to present with an average of approximately one sample per 100 ka the combination of high sample density and uniformity of analytical procedures has produced a well defined record of changes in the sup 87 sr sup 86 sr of seawater during the neogene the record can be viewed as a series of essentially linear segments with slopes ranging from as high as 6 times 10 sup minus 5 m y to as low as 0 m y the times associated with major inflections in the curve do not appear to correspond to simple geologic phenomena such as eustatic cycles but are probably controlled by a combination of tectonic and climatic factors that influenced the abundance and isotopic composition of terrestrial strontium input to the oceans the strontium isotopic data are consistent with a progressive increase in the chemical weathering rates of the continents during the neogene probably related to repeated glaciations increased exposure of continents by lowered sea level and increased continental relief resulting from high rates of tectonic uplift

unlocking the ice house oligocene miocene oxygen isotopes eustasy and margin erosion oxygen isotope records and glaciomarine sediments indicate at least an intermittent presence of large continental ice sheets on antarctica since the earliest oligocene circa 35 ma the growth and decay of ice sheets during the oligocene to modern ice house world caused glacioeustatic sea level changes the early eocene was an ice free greenhouse world but it is not clear if ice sheets existed during the middle to late eocene doubt house world benthic foraminiferal 18o records place limits on the history of glaciation suggesting the presence of ice sheets at least intermittently since the earliest oligocene the best indicator of ice growth is a coeval increase in global benthic and western equatorial planktonic 18o records although planktonic isotope records from the western equatorial regions are limited subtropical planktonic foraminifera may also record such ice volume changes it is difficult to apply these established principles to the cenozoic 18o record because of the lack of adequate data and problems in stratigraphic correlations that obscure isotope events we improved oligocene to miocene correlations of 18o records and erected eight oxygen isotope zones oi1 oi2 mi1 mi6 benthic foraminiferal 18o increases which are associated with the bases of zones oil circa 35 8 ma oi2 circa 32 5 ma and mil circa 23 5 ma can be linked with 18o increases in subtropical planktonic foraminifera and with intervals of glacial sedimentation on or near antarctica our new correlations of middle miocene benthic and western equatorial planktonic 18o records show remarkable agreement in timing and amplitude we interpret benthic planktonic covariance to reflect substantial ice volume increases near the bases of zones mi2 circa 16 1 ma mi3 circa 13 6 ma and possibly mi5 circa 11 3 ma possible glacioeustatic lowerings are associated with the 18o increases which culminated with the bases of zone mi4 circa 12 6 ma and mi6 circa 9 6 ma although low latitude planktonic 18o records are required to test this these inferred glacioeustatic lowerings can be linked to seismic and rock disconformities for example we link 12 oligocene early late miocene inferred glacioeustatic lowerings with 12 of the sequence boundaries inferred eustatic lowerings of haq et al 1987

a mechanism for the recurrence of wintertime midlatitude sst anomalies abstract in the early 1970s namias and born speculated that ocean temperature anomalies created over the deep mixed layer in winter could be preserved in the summer thermocline and reappear at the surface in the following fall or winter this hypothesis is examined using upper ocean temperature observations and simulations with a mixed layer model the data were collected at six ocean weather stations in the north atlantic and north pacific concurrent and lead lag correlations are used to investigate temperature variations associated with the seasonal cycle in both the observations and the model simulations concurrent correlations between the surface and subsurface temperature anomalies in both the data and the model indicate that the penetration of temperature anomalies into the ocean is closely tied to the seasonal cycle in mixed layer depth high correlations extend to relatively deep shallow depths in winter summer lead lag correlations in both the data and the model at some of the stations

origin and age of phosphorite from the south central florida platform relation of phosphogenesis to sea level fluctuations and δ13c excursions abstract francolite carbonate fluorapatite from predominantly peloidal phosphorite grains in the miocene hawthorn group from the babcock deep core southwestern florida is highly substituted with an average composition of ca4 61na0 22mg0 14k0 05sr0 02 po4 2 23 co3 0 62 so4 0 12 f 1 04 13c values of 1 0 7 8 pdb of the francolite co3 indicate a substantial contribution of c from an organic source the sulfur isotopic composition of francolite so4 is depleted to slightly enriched relative to miocene seawater and suggests that phosphogenesis occurred during early burial diagenesis in organicrich sediments above or in the zone of sulfate reduction the uniformly high sr na mg so4 and co3 contents of the francolite the 18o values of the francolite co3 0 2 4 2 pdb and the inclusion of pyrite and organic matter in phosphorite grains suggest that the francolite has had minimal chemical alteration since its formation phosphorite from the babcock deep core has sr 87 86 ratios that range from 0 708148 0 708880 and sr derived ages that range from late oligocene 25 6 0 7 ma to early late miocene 9 2 1 4 ma the sr derived ages of relatively fragile calcareous benthic foraminifers are consistently younger than associated hard tightly cemented phosphorite and support textural evidence of extensive reworking the age of the host sediment ranges from early miocene to pliocene and its depositional history is related to sea level fluctuations approximately three quarters of the total phosphorite in the babcock deep core formed during or within 2 my before the major early to mid miocene positive 13cshift as recorded at dsdp site 588 southwest pacific one third of the total phosphorite formed just prior to the carbon shift in the short interval between 21 9 and 20 4 ma these results indicate that reworked phosphorite deposits may provide a proxy of organic carbon cycling on continental shelves that correspond to sealevel fluctuations and to variations in the 13crecord

miocene equatorial and southwest pacific paleoceanography from stable isotope evidence abstract stable isotope results from seven miocene deep sea drilling projects in the equatorial and southwest pacific ocean previously correlated using carbon isotope stratigraphy have been examined discussed and interpreted in terms of the development of the miocene pacific ocean the most obvious features of the benthonic foraminiferal stable isotopic records are a major increase in 18o 1 0 during the middle miocene a series of long term oscillations 2 3 my of amplitude 0 5 0 75 and a decrease in 13c values 0 5 1 0 during the latest miocene planktonic foraminiferal 18o records show different trends for high and low latitude regions in the equatorial pacific planktonic 18o values actually decrease during the miocene whereas in the higher southern latitudes planktonic 18o values become more positive in response to cooling surface waters planktonic 13c records show opposite trends to 18o with the high latitude values becoming more negative relative to the tropical regions the development of the miocene pacific ocean in terms of its vertical and horizontal thermal structure and isotopic composition is well illustrated by examining changes in the isotopic difference between planktonic and benthonic foraminifera 18ob p benthonic planktonic is a measure of the thermal structure of the water column 18oph pl high latitude low latitude planktonic values is a measure of the latitudinal temperature gradient 13cb p is an indirect measure of nutrient concentrations in the water column and 13cph pl measures differences in surface water nutrient concentrations between high and low latitude 18ob p increases during the miocene with the greatest increase occurring in the middel miocene at about 14 ma by the latest miocene the isotopic gradient at site 289 in the equatorial pacific approaches the present day isotopic gradient about 4 5 an increase in 18oph pl during the miocene suggests that the latitudinal temperature gradient increased by about 6 c to a value of 12 c in the latest miocene between sites 289 equator and 281 subantarctic 13cb p and 13cph pl values are relatively constant through the early miocene but begin to increase during the middle miocene bottom water 13c values respond similarly at all sites but surface water 13c values exhibit different trends because higher latitude values begin to decrease this decrease perhaps suggests that phosphate concentrations may have increased due to increased upwelling as the circum antarctic circulation system evolved its present day characteristics the isotopic data compiled in this paper suggest that the southwest pacific was responding uniformly to some global or at least pacific wide control during the early miocene in the middle miocene the response became more complex as the low and high latitudes began to show independent trends the changes in the thermal vertical and latitudinal structure probably occurred in respons to the build up of the east antarctic ice sheet intensification of bottom water circulation and an increase in zonal circulation in surface waters in the southern hemisphere the changes in 13c vertical and latitudinal gradients are due to some complex interaction of sea level continental hypsometry climate and biological processes coupled with oceanic circulation changes a strong correlation between estimated sea level changes and 13c values suggests that transgressions and regressions play a critical role in controlling the flux of oxidized organic carbon enriched in12c from the continental shelves and epicontinental seas to the open ocean

the middle devonian basins of western norway sedimentary response to large scale transtensional tectonics abstract the devonian basins of western norway were formed during late to post orogenic extension of overthickened caledonian crust the basins are situated in the hanging wall of the extensional nordfjord sogn detachment zone nsdz and display extensional half graben geometries in sections parallel to the local direction of principal extension based on overall facies configurations paleocurrent patterns and intrabasinal structures we infer an anticlockwise rotation of the syndepositional extension direction from nw se in the south solund basin to wsw ene in the north hornelen basin the axes of folds that are roughly parallel to the local extension direction are rotated correspondingly the kvamshesten basin is located between the solund and hornelen basins sedimentological and structural data show evidence of an early southeastwards tilt direction followed by a more eastwards tilt and associated e w flowing paleodrainage correspondingly nw se trending folds and reverse faults are superposed by e w trending ones at low to intermediate stratigraphic levels the variations in apparent tilt direction for the basins together with variations in intrabasinal structure is interpreted to reflect an anticlockwise rotation of the regional syndepositional strain field the above observations and inferences indicate that the devonian basins in western norway formed in a strain field dominated by regional transtension accommodated by extension along the nsdz and sinistral strike slip along orogen parallel shear zones and faults to the north of the basins alternatively nw directed extension preceded the introduction of a sinistral strike slip component the models are in accordance with recent work carried out in the footwall of the nsdz and illustrates the tectono sedimentary response to a complex interplay between extension and strike slip that appears to have been fundamental in the late stage disintegration of the caledonian orogen