magnetic properties of coastal loess on the midao islands northern china implications for provenance and weathering intensity abstract loess deposits are widely distributed over the islands in the bohai gulf and neighboring regions of northern china the coastal loess located to the east of the chinese loess plateau clp is believed to have a local source from exposed marine sediments and a distant source from inner arid regions in asia in this study magnetic geochemical and diffuse reflectance spectroscopic analyses were conducted on the loess to explore its relationship with the loess on the clp and its paleoclimatic implications we find that the coastal loess shows similar geochemical composition background susceptibility and magnetic enhancement to loess on the clp magnetic minerals characteristic of pedogenesis are more important in the paleosol layer with fine ferrimagnetic minerals abundant in paleosol layer sb1 and hematite in paleosol layer sb2 geochemical evidence suggests that weathering intensity in paleosol sb2 is similar to or even stronger than in paleosol sb1 pedogenic enhancement of magnetic susceptibility in the study area is not so strong which may be due to enhanced hematite formation as opposed to ferrimagnetic mineral production and preservation

origin of maghaemite in chinese loess deposits aeolian or pedogenic maghaemite and magnetite common ferrimagnetic minerals in surficial soils have physical properties which are similar except for the thermal instability of the former utilising this exception a study of thermomagnetic properties has been made to systematically separate these two magnetic components in loess and palaeosol samples from the upper parts of the luochuan section of the central chinese loess plateau this investigation has shown that although maghaemite thermally unstable component occurs in greater amounts in palaeosols ms 0 0187 am2 kg 1 1 1 than in loess units ms 0 0156 am2 kg 1 1 1 in relative terms its contribution to the ferrimagnetic component of magnetisation is higher in the loess units ms 32 2 2 0 than the soils ms 23 5 3 7 such an observation suggests that much of the maghaemite component originates in the aeolian source area with some addition of pedogenic maghaemite occurring in the palaeosols

spectrum of pore types and networks in mudrocks and a descriptive classification for matrix related mudrock pores matrix related pore networks in mudrocks are composed of nanometer to micrometer size pores in shale gas systems these pores along with natural fractures form the flow path permeability network that allows flow of gas from the mudrock to induced fractures during production a pore classification consisting of three major matrix related pore types is presented that can be used to quantify matrix related pores and relate them to pore networks two pore types are associated with the mineral matrix the third pore type is associated with organic matter om fracture pores are not controlled by individual matrix particles and are not part of this classification pores associated with mineral particles can be subdivided into interparticle interp pores that are found between particles and crystals and intraparticle intrap pores that are located within particles organic matter pores are intrap pores located within om interparticle mineral pores have a higher probability of being part of an effective pore network than intrap mineral pores because they are more likely to be interconnected although they are intrap om pores are also likely to be part of an interconnected network because of the interconnectivity of om particles in unlithifed near surface muds pores consist of interp and intrap pores and as the muds are buried they compact and lithify during the compaction process a large number of interp and intrap pores are destroyed especially in ductile grain rich muds compaction can decrease the pore volume up to 88 by several kilometers of burial at the onset of hydrocarbon thermal maturation om pores are created in kerogen at depth dissolution of chemically unstable particles can create additional moldic intrap pores

anthropogenic influences on changes in the sediment load of the yellow river china during the holocene using data on formation of the loess plateau of central china loess palaeosol sequences pollen analysis historical geography and long term experimentation on rates of soil erosion it is demonstrated that current serious erosion on the loess plateau is mainly due to human destruction of the natural vegetation and irrational land use these two modifications greatly reduce soil infiltration capacity and resistance of the soil to erosion the increase of soil erosion began ca 5000 bp at which time a hunting and pastoral life began to change gradually to a sedentary life centred around cultivation using the volume of holocene loessic sediments on the continental shelf of the bohai yellow and east china seas it is estimated that the present sediment load of the lower yellow river is at least three times greater than it was during the holocene although human induced soil erosion in the loess plateau began earlier it was not until the tang dynasty about 1000 bp that it began to increase rapidly ac

potbellies wasp waists and superparamagnetism in magnetic hysteresis because the response of a magnetic substance to an applied field depends strongly on the physical properties of the material much can be learned by monitoring that response through what is known as a magnetic hysteresis loop the measurements are rapid and quickly becoming part of the standard set of tools supporting paleomagnetic research yet the interpretation of hysteresis loops is not simple it has become apparent that although classic single domain pseudo single domain and multidomain loops described in textbooks occur in natural samples loops are frequently distorted having constricted middles wasp waisted loops or spreading middles and slouching shoulders potbellies such complicated loops are often interpreted in oversimplified ways leading to erroneous conclusions the physics of the problem have been understood for nearly half a century yet numerical simulations appropriate to geological materials are almost unavailable in this paper we discuss results of numerical simulations using the simplest of systems the single domain superparamagnetic sd sp system examination of the synthetic hysteresis loops leads to the following observations 1 wasp waisting and potbellies can easily be generated from populations of sd and sp grains 2 wasp waisting requires an sp contribution that saturates quickly resulting in a steep initial slope and potbellies require low initial slopes the sp contribution approaching saturation at higher fields the approach to saturation is dependent on volume hence the cube of grain diameter therefore there is a very strong dependence of hysteresis loop shape on the assumed threshold size 3 we were unable to generate potbellies using an sp sd threshold size as large as 30 nm and wasp waists cannot be generated using a threshold size as small as 8 nm the occurrence of both potbellies and wasp waists in natural samples is consistent with a room temperature threshold size of some 15 nm 5 4 simulations using a threshold size of 15 20 nm with populations dominated by sp grain sizes that is with a small number of sd grains produce synthetic hysteresis loops consistent with measured hysteresis loops and transmission electron microscopic observations from submarine basaltic glass 5 simulations and measurements using two populations with distinct coercivity spectra can also generate wasp waisted loops a relatively straightforward analysis of the resulting loops can distinguish the latter case from wasp waisting resulting from sp sd behavior

enhancement mechanisms of magnetic susceptibility in the chinese red clay sequence 1 little is known about the mechanisms of magnetic susceptibility enhancement for the red clay sequence on the chinese loess plateau clp in comparison to the overlying loess paleosol sequence here we present a rock magnetic study of the red clay sediments from the central clp our results show that frequency dependence of fd lf hf where lf and hf are measured at 470 hz and 4700 hz respectively lf and susceptibility of anhysteretic remanent magnetization arm are linearly correlated within the red clay sequence this linear correlation indicates that the pedogenic magnetic minerals of the red clay have a rather uniform grain size distribution as in the loess paleosol sequence and the grain size is independent of the degree of pedogenesis nevertheless red clay sediments are slightly more enriched in superparamagnetic magnetic particles than the overlying loess paleosol sediments as indicated by the higher slope of the regression line between fd and lf

partly pedogenic origin of magnetic variations in chinese loess quaternary sequences of interbedded aeolian silts loess and buried soils palaeosols potentially provide one of the best terrestrial records of past climates1 5 magnetic susceptibility variations in loess and palaeosol sequences from china are strongly correlated with climate induced fluctuations of oxygen isotope ratios in deep sea sediments2 4 6 8 as an explanation of this correlation it has been suggested that the recorded variations in magnetic susceptibility depend primarily on the degree of dilution by non magnetic bulk loess constituents of a uniform magnetic assemblage derived from remote but unknown sources6 8 it has also been suggested that such a model involving changes in the accumulation rate of loess superimposed on a constant flux of magnetic particles provides a relative geological timescale through the control of loess deposition by astronomically modulated climate fluctuations7 here we report a preliminary test of this model using rock magnetic properties especially sensitive to variations in magnetic grain size our results show that palaeosols are characterized by much finer magnetic grain size assemblages than are the intervening loess units this suggests that a simple model based on constant magnetic influx and dilution by variable amounts of non magnetic loess is inadequate our magnetic measurements establish the close comparability of the fine grained magnetic minerals in the palaeosol samples to those in contemporary soils and thus point to a partially pedogenic origin for the magnetic mineral assemblages in the palaeosols

loess deposits from the tajik depression central asia magnetic properties and paleoclimate abstract continuous accumulation of dust during the quaternary has formed widespread loess deposits in southern tajikistan the magnetic susceptibility variations of these aeolian sediments have recorded the paleoclimatic fluctuations in a similar direct and complete way to the well studied sediments from the central loess plateau in china 11 susceptibility measurements were carried out in situ at intervals of 10 cm along seven partly overlapping sections in the loess paleosol sequence of karamaidan ca 100 km east of dushanbe nearly 250 oriented samples were taken for rock magnetic investigations careful field observation revealed a total actual loess thickness of ca 100 m for a composite profile with thirteen intervening pedocomplexes pc standard demagnetization techniques yielded a characteristic component of natural remanent magnetization nrm which was used to obtain a well defined magnetostratigraphy the section covers a total timespan of approximately 1 m y including the brunhes and the youngest part of the matuyama polarity chron the susceptibility variations correlate excellently with those of the chinese loess record at xifeng 22 although minor differences in the relative amplitude of the susceptibility signal occur close correlation with the astronomically tuned oxygen isotope record 26 enables refined dating of the loess sequence at karamaidan and demonstrates the global significance of the recorded paleoclimatic variations especially with respect to paleoprecipitation on land during the quaternary

rock magnetism and geochemistry of two plio pleistocene chinese loess palaeosol sequences implications for quantitative palaeoprecipitation reconstruction abstract stratigraphic and spatial variations in the magnetic properties of chinese loess are widely accepted as reflecting changes in the intensity of soil forming processes over time and space recently several workers have used statistical correlations between the magnetic susceptibility and related parameters of modern loess plateau soils and modern climate to generate transfer functions to reconstruct past temporal and spatial trends in precipitation here we try to assess the viability of this approach by conducting magnetic and geochemical measurements of two long 2 5 my loess palaeosol sequences from different locations on the modern precipitation gradient across the loess plateau one site duanjiapo is located on the southern humid margin of the plateau and the other site luochuan is located in a drier modern environment some 160 km further north our results indicate discrepancies between magnetic and geochemical indicators of weathering and soil forming intensity and that any attempt to predict palaeoprecipitation at duanjiapo using published approaches would be significantly in error overall our results indicate a complex response of magnetic mineral transformations to climate including the production of both ferrimagnetic and antiferromagnetic minerals within the same climatic interval together with the destruction of magnetic material within some of the palaeosols therefore we suggest considerable caution should be exercised in generating quantitative climatic reconstructions from a single magnetic parameter

east asian summer monsoon intensity inferred from iron oxide mineralogy in the xiashu loess in southern china abstract the xiashu loess in comparison to the well studied loess sequences in the chinese loess plateau clp provides a good opportunity for studying east asian monsoon variations from a southern china perspective here we present a study of the iron oxide mineralogy of the xiashu loess using integrated geochemical and diffuse reflectance spectroscopy drs measurements as well as magnetic data our results show that the free iron oxide fe d to total iron fe t ratio fe d fe t hematite hm to goethite gt ratio hm gt and saturation isothermal remanent magnetization sirm to magnetic susceptibility ratio sirm all indicate particularly strong summer monsoons during the formation of paleosols ps5 and ps4 equivalent to marine isotope stage 13 and 11 respectively however magnetic susceptibility and fe d fe t are not consistently reliable indicators of summer monsoon intensity for the whole section our results indicate that a multi proxy approach can give a more reliable summer monsoon intensity reconstruction the summer monsoon shows a cooling trend and a declining of precipitation from 0 5 to 0 3 ma after which it becomes warmer and wetter towards the top of paleosol ps1 equivalent to mis 5 however ps1 was formed under a relatively cooler temperature and wetter soil conditions in comparison to ps5 and ps4 such supra orbital variations in the east asian summer monsoon superimposed on the effects of glacial interglacial cycles in southern china are also reflected in the 0 4 0 5 ma cycle of marine carbon isotopes in the global ocean possibly indicating a strong link between terrestrial weathering and the global carbon cycle

color reflectance of chinese loess and its implications for climate gradient changes during the last two glacial interglacial cycles 1 to examine the relationship between color changes of loess deposits and paleoclimate conditions a north south transect consisting of twelve loess sections were studied color reflectance was measured on loess paleosol samples from the loess transect which accumulated over the last two glacial interglacial cycles the redness value a shows an overall southward increase for both loess and soil units coinciding with the pattern of a southerly increase in pedogenic development and the present north south climatic gradient the redness of loess deposits is linearly correlated with latitude values implying that this parameter is an efficient proxy for the weathering intensity of loess deposits the gradient of weathering intensity is much steeper during interglacials than in glacials by comparison of color records for different time interval

grain size and accumulation rate records from late cenozoic aeolian sequences in northern china implications for variations in the east asian winter monsoon and westerly atmospheric circulation we attempt to reconstruct the history of westerly and monsoonal circulations in northern china using variations in sediment grain size and accumulation rate at four loess sections in the central chinese loess plateau the initiation of aeolian accumulation at about 7 6 ma in the main part of the chinese loess plateau probably marked the onset of the monsoonal circulation both the monsoonal and westerly circulations weakened from 7 6 to 5 2 ma subsequently the monsoonal circulation strengthened progressively from 5 2 ma to the present in addition the westerly circulation strengthened from 5 2 to 0 6 ma but then weakened thereafter and especially during the last 0 6 ma comparison of our aeolian records and the deep sea sediment record suggests that the strengthening trends of the monsoonal and westerly circulations were associated with the progressive development of global ice sheets during the late cenozoic abrupt changes of both the monsoon and westerly circulations occurred at 7 6 3 4 and 1 2 0 9 ma together with a weakening trend of the westerly circulation in the last 0 6 ma and are interpreted as the consequence of the episodic uplift of the tibetan plateau spatial differences in the grain size characteristics amongst the four sections suggest that the circulation intensity and variability decreased from west to east across the loess plateau due to the topographic effect of the tibetan plateau in addition some spatial differences may have been the result of local topographic effects c 2008 elsevier b v all rights reserved

magnetic enhancement is linked to and precedes hematite formation in aerobic soil 1 soil formation usually increases magnetic susceptibility most often by increasing the concentrations of magnetite and maghemite which are two ferrimagnetic iron oxides here we provide evidence that magnetic enhancement in aerobic soils not affected by detrital magnetic inputs or thermal transformation of other iron oxides is mostly due to the formation of maghemite which is later transformed into hematite the iron oxide that gives red color to soil we show that the maghemite hematite ratio is influenced by the particular environment and the degree of soil development so it constitutes an effective tool for paleoenvironmental and planetary studies

coherent tilt signals observed in the shumagin seismic gap detection of time dependent subduction at depth repeated surveys of short level lines in the shumagin islands alaska reveal coherent tilt signals associated with subduction of the pacific plate beneath the north american plate in the shumagin seismic gap ten years of steady tilt down toward the trench is interrupted during 1978 1980 by a rapid episode of reverse tilt the normal tilt represents surface deformation as subduction occurs with the plate boundary locked to at least 60 km depth using all available tilt sea level and seismic data the authors interpret the tilt reversal as due to an episodic reverse slip of ca 80 cm magnitude on the plate boundary between ca 70 km and ca 20 km depth downdip from the main seismogenic zone which remains locked this event causes an increase of stress on the locked main thrust zone the authors speculate that such events may be a regular process at subduction zones that great plate boundary earthquakes may be more common during their occurrence and that their onset may be detectable early enough to give warning of an increase in probability for the occurrence of a great earthquake 51 references 10 figures 1 table

how abundant is pedogenic magnetite abundance and grain size estimates for loessic soils based on rock magnetic analyses 1 the upper soil horizons of many modern and ancient soils are enriched in fine grained pedogenic ferrimagnetic minerals we use three grain size and concentration dependent proxies anhysteretic remanent magnetization isothermal remanent magnetization ratios coercivity spectra derived from alternating field demagnetization of saturation isothermal remanent magnetization and hysteresis properties to quantify the abundance and grain size of the pedogenic magnetic component our analyses of modern loessic soils from the midwestern united states show that relatively small additions 2 10 vol of the total ferrimagnetic component of fine grained coarse superparamagnetic to fine pseudosingle domain magnetite or maghemite are sufficient to explain the changes in concentration and grain size dependent properties observed in the upper soil horizons furthermore the pedogenic components of all studied sites display a narrow range of magnetic properties which argues for a common origin of these particles over a wide range of climatic conditions

environmental magnetism of pleistocene sediments in the north pacific and ontong java plateau temporal variations of detrital and biogenic components 1 an environmental magnetic study was conducted to investigate temporal variations of the sources of magnetic minerals in the pacific ocean using sediment cores of pleistocene age the proportion of interacting i to noninteracting n i single domain components was estimated from first order reversal curve diagrams and the proportion of middle m to low l coercivity components was determined from decomposition of isothermal remanent magnetization irm acquisition curves the i and m components are interpreted to be carried by terrigenous maghemite while the n i and l components represent biogenic magnetite an inverse correlation between the ratio of anhysteretic remanent magnetization susceptibility arm to saturation irm sirm and the i n i ratio was confirmed for sediments across wide expanses in the pacific ocean this implies that arm sirm can be used to estimate the relative abundances of biogenic and terrigenous components in sediments in the north pacific the relative abundance of the i and m components increases in glacial periods variations of arm sirm and s ratio s 0 1t resemble each other and decrease in the same time intervals these variations reflect increases of terrigenous input in glacial periods as eolian dust on the ontong java plateau in the western equatorial pacific on the other hand minima in arm sirm and s 0 1t occur at glacial to interglacial transitions and the relative abundance of the i and m components increases in these periods terrigenous material in this region is considered to be transported mainly from the new guinea and solomon islands by the equatorial undercurrent the higher proportion of the terrigenous component at glacial to interglacial transitions is coeval with carbonate preservation maxima reported from the ontong java plateau suggesting a linkage between the two

rock magnetic characterization of early redoxomorphic diagenesis in turbiditic sediments from the madeira abyssal plain rock magnetic measurements of two sediment cores from the madeira abyssal plain map north atlantic are used to investigate post depositional changes in the concentration grain size and composition of magnetic minerals in the sediments that have occurred within organic rich turbidite horizons the changes are associated with an initial stage of suboxic reductive diagenesis following depletion of porewater o2 and a later stage of oxidative diagenesis associated with the slow descent of an oxidation front through the sediment as a result of diffusion of o2 from the overlying sea water the turbidites are of late quaternary age 18o stages 1 3 and derive both from different sites on the nw african continental margin and from the flanks of the canary islands thus the turbidites are variable compositionally especially in terms of carbonate detrital magnetic mineral and organic carbon content diagenetic changes in these sediments have been identified using solid phase geochemical data u mn corg and caco3 reported previously in more than one study rock magnetic parameters of the sediments when expressed on a carbonate free basis reveal that significant depletion of detrital ferrimagnetic iron fe2 fe3 oxide grains has occurred within organic rich turbidites during redoxomorphic diagenesis normalized quotients of magnetic parameters also show that reductive diagenesis is a ferrimagnetic grain size selective process but it has a minimal effect on the canted antiferromagnetic fe3 oxides in the sediment such components if present therefore become relatively enriched in magnetic assemblages as the ferrimagnetic grains are dissolved progressively and bulk magnetic concentration is thus depleted there is clear evidence in both cores for the existence of ultrafine ferrimagnetic grains at depth within the suboxic zone of the organic rich turbidites beneath both active and fossil oxidation fronts these grains are most probably associated with populations of live magnetotactic bacteria which commonly inhabit such organic rich horizons and play a part in the chain of bacterially mediated reactions normally associated with suboxic diagenesis these results show that simple and rapid rock magnetic techniques can be used to characterize early diagenetic processes involving iron phases in deep sea sediments at least as effectively as more laborious time consuming and sample destructive geochemical measurements

the magnetic properties of loess and paleosol samples from the chinese loess plateau spanning the last 22 million years abstract magnetic measurements susceptibility isothermal and anhysteretic remanence and quotients derived from these are presented for a suite of loess and paleosol samples from sites on the chinese loess plateau the three sites xifeng dongwan and qinan qa i together span most of the last 22 million years the results provide the first multi parameter magnetic measurements from pre pleistocene loess paleosol sequences that began accumulation in the early miocene mass specific measurements have been corrected for carbonate concentrations which peak in the loess layers and range up to 57 all the magnetic properties recorded indicate variability on both orbital and supra orbital timescales the changing magnetic properties allow the record to be divided into a sequence of eight sample groups that broadly parallel the main supra orbital changes in magnetic susceptibility the pre pleistocene parts of the record include intervals mainly late miocene and pliocene during which loess as well as paleosol layers are characterized by high values for properties such as frequency dependent susceptibility fd usually associated with strong weathering most of the miocene record prior to 8 5 ma with the exception of a brief interval from ca 14 4 to 15 9 ma shows reduced values for indicators of pedogenic ferrimagnetic concentrations in both the loess and paleosol layers as well as a low amplitude of variability between loess and paleosol values the palaeoenvironmental implications of this part of the sequence are unclear since they hinge on the type of model of pedogenic magnetic mineral formation adopted high field remanence measurements indicate that the coercivity of the antiferromagnetic minerals represented declined progressively throughout the whole period in both the loess and the paleosol samples though there is no unambiguous evidence for long term diagenetic alteration of the magnetic properties on timescales beyond the orbital ones that drive the loess paleosol alternations the present results suggest caution in applying existing climofunctions based on magnetic susceptibility to deposits spanning the whole of the last 22 ma

magnetic properties and geochemistry of the xiashu loess in the present subtropical area of china and their implications for pedogenic intensity variations in the magnetic susceptibility of chinese loess have been used to indicate pedogenic intensity and therefore past climate across the chinese loess plateau clp however the relationship between climate and magnetic properties has not been fully resolved and therefore a study of loess sections distributed over a wider climatic region is timely in this study we have investigated a 22 1 m loess section named the xiashu loess at dagang china by integrating both rock magnetic and geochemical proxies this loess profile is situated in a modern subtropical climate region with annual mean precipitation and temperature of 1100 mm and 15 4 c respectively and therefore has experienced a stronger weathering intensity due to its lower latitude higher temperature and rainfall geochemical and magnetic evidence indicate the same source area for the xiashu loess as for loess in northern china the magnetic mineral assemblage of the xiashu loess is dominated by a higher concentration of superparamagnetic sp single domain sd magnetite maghemite grains in strongly weathered paleosols than in the loess layers consistent with the production of fine grained ferrimagnetic minerals during pedogenic processes nevertheless compared to loess in the clp the xiashu loess shows 1 reduced contrasts in magnetic susceptibility hard isothermal remanent magnetization hirm and remanence of coercivity bcr between loess and paleosols units which indicates that the loess units have undergone stronger pedogenic alterations 2 lower peak values of hirm and in paleosols in addition the ratios sirm arm sirm where sirm and arm are saturation isothermal remanent magnetization and the susceptibility of anhysteretic remanent magnetization respectively and bcr are found to be significantly correlated with the quotient cao na2o mgo tio2 a geochemical indicator of pedogenic intensity overall it seems that pedogenic processes in the xiashu loess lead to a relative increase in fine grained ferrimagnetic sp sd grains but depletion of anti ferromagnetic minerals magnetic and geochemical proxies indicate strengthened east asia summer monsoon during marine isotope stages 13 11 and 5 which is in good agreement with the records from the clp and the south china sea 2007 elsevier b v all rights reserved

lack of correlation between paleoprecipitation and magnetic susceptibility of chinese loess paleosol sequences we have conducted a detailed mineral magnetic study of loess unit 8 l8 and paleosol unit 8 s8 from three localities jingbian yichuan and duanjiapo along a n s transect in the chinese loess plateau as expected the low field magnetic susceptibility has higher values in s8 and lower values in l8 similarly superparamagnetic particle concentrations increase in s8 with increasingly humid cli mates along the n s transect which suggests that pedogenic magnetic enhancement is related to climate however in s8 at duanjiapo is so low that there is no correlation between and the degree of pedogenesis in this loess paleosol cycle it therefore appears that is not consistently the most suit able indicator of paleoclimate in chinese loess paleosol se quences our results indicate that there are complexities in the mineral magnetic response to pedogenesis which could invalidate interpretation of the record of chinese loess paleosol sequences in terms of paleoprecipitation

summer monsoon variations over the last 1 2 ma from the weathering of loess soil sequences in china the loess soil sequence in northern china contains a near continuous record of quaternary paleoclimate magnetic susceptibility and grain size have so far been the only proxies available to address the long term changes of the east asian paleomonsoon extending back to more than one million years in this study the ratio of cbd citrate bicarbonate dithionite extractable free fe2o3 fed a measure of iron liberated by chemical weathering versus the total fe2o3 available fet was measured on samples at 10 cm intervals taken from two loess sections deposited over the last 1 2 ma variations of this index are highly consistent with other pedological indicators but in addition provide a quantitative measurement of the degree of pedogenesis in the loess plateau since chemical weathering in the region mainly depends upon summer precipitation and temperature weathering intensity primarily reflects changes in the east asian summer monsoon the new proxy has been used to document a series of summer monsoon changes of global significance which are not necessarily recorded by magnetic susceptibility

testing competing hypotheses for soil magnetic susceptibility using a new chemical kinetic model a chemical kinetic model is presented for the formation and accumulation of secondary ferrimagnetic minerals sfms in soil constructed using experimentally determined rate constants and validated against field data the primary objective is to critically assess the significance of competing causal mechanisms and disputed environmental controls under temperate conditions four findings are important in relation to current application of soil magnetic susceptibility data first transformation of hydrous ferric oxide to magnetite should dominate sfm formation controlled primarily by parent material ferrous silicate concentration and climate second abiotic reactions should account for most of the sfm production the most significant impact of high fe2 concentrations created by dissimilatory iron reducing bacteria is enhanced export of iron from the soil in runoff third the model predicts a correlation between hematite and magnetite concentrations weakening field support for direct transformation of hydrous ferric oxide to maghemite fourth magnetic susceptibility enhancement should increase strongly with weathering duration

a rapid method for magnetic granulometry with applications to environmental studies we have developed a rapid method of characterizing the fine scale variation sub micron to hundreds of microns m in the grain size of magnetite in long sediment cores this method is a new rock magnetic tool and can be readily applied to the following disciplines 1 environmental studies 2 hydrology 3 petrology and 4 geomagnetism the method consists of a comparative plot of the depth variation of two magnetic parameters the first parameter low field less than 0 1 millitesla mt or 1 oe susceptibility in a steady field is plotted on the abscissa the second parameter anhysteretic remanent magnetization arm imparted by a smoothly decreasing af of peak value 100 mt 1 000 oe in the presence of a weak steady field 0 01 0 1 mt or 0 1 1 oe is plotted on the ordinate for a sediment column in which the magnetic mineral is magnetite a plot of the two magnetic parameters shows transitions in the average magnetic grain size with depth as clearly discernible changes in the slope of a regression line fit to the individual points arm

geochemistry of the xining xifeng and jixian sections loess plateau of china eolian dust provenance and paleosol evolution during the last 140 ka abstract loess and paleosol samples from three distant sections xining xifeng jixian of the chinese loess plateau were analyzed for chemical and nd sr isotopic compositions in order to obtain information about the paleoclimatic variation during the last 140 ka these three sections represent three different climatic conditions from arid in the west xining to more humid in the east jixian across the loess plateau isotopic analyses show that all the three sections display a restricted range of 143 nd 144 nd ratios or e nd 10 0 5 indicating the dominance of relatively young and uniform upper crustal sources for the eolian dust the loess and paleosol samples have typical upper crustal 87 sr 86 sr ratios 0 714 0 718 and their variation can partly be attributed to different carbonate silicate ratios in the samples ree data from the three sections are indistinguishable from each other they show typical upper crust patterns characterized by la yb n 10 and eu eu 0 65 the high degree of chemical and isotopic homogeneity suggests that the dust source region must have undergone multiple recycling and thorough sedimentary mixing processes various chemical indicators have been used to monitor the pedogenetic intensity in these sections although results for the jixian section agree reasonably well with the known climatic conditions on the loess plateau the other two sections yield results not in agreement with some well accepted proxies like magnetic susceptibility or grain size distribution some chemical proxy indicators established in our previous work on the luochuan section such as the systematic u depletion and negative ce anomalies in ree patterns in soils are not clearly recorded in the present case the discrepancy between different climatic proxies could be related to the effective soil water budget temperature as well as the rate of development of each proxy

rock magnetism of late neogene and pleistocene deep sea sediments relationship to sediment source diagenetic processes and sediment lithology we use bivariate scatter plots to illustrate variations in selected rock magnetic properties low field susceptibility anhysteretic and isothermal remanence of late neogene and pleistocene deep sea sediments from 16 sites in the arctic ocean north atlantic equatorial atlantic and north pacific ocean and the arabian sea our intention is to examine the ability of the rock magnetic properties to differentiate the sediments according to factors such as lithology geographical area and the dominant mode of terrigenous sedimentation which at these sites is via ice rafting via bottom currents or via eolian processes overall correlations between sediment magnetic properties and gross lithology is poor and factors such as the source and transport path of terrigenous sediment and detrital magnetic minerals together with the action of reductive diagenetic processes are the major controls on the magnetic properties on the bivariate scatter plots sites with major ice rafted contributions tend to have high sedimentary ferrimagnetic mineral concentrations relatively coarse ferrimagnetic grain sizes and scattered sample point distributions in contrast sites where we infer significant bottom current supply of terrigenous material have tightly grouped sample point distributions carbonate sediments in which the terrigenous component is supplied by eolian processes tend to have a broad range of magnetic mineral concentration caused by glacial interglacial fluctuations in carbonate accumulation and eolian activity sediments containing significant volcanogenic material have high concentrations of relatively coarse grained ferrimagnetic material reductive diagenesis is a significant determinant of sediment magnetic properties in high productivity areas and has the effect of preferentially removing the fine grained ferrimagnetic fraction causing a coarsening of the ferrimagnetic grain size distribution and a rise in the antiferromagnetic ferrimagnetic ratio

mineral magnetic variation of the jingbian loess paleosol sequence in the northern loess plateau of china implications for quaternary development of asian aridification and cooling a high resolution mineral magnetic investigation has been carried out on the jingbian loess paleosol sequence at the northern extremity of the chinese loess plateau results show that the magnetic assemblage is dominated by large pseudo single domain and multidomain like magnetite with associated maghemite and hematite variations in the ratios of sirm100mt sirm sirm100mt sirm30mt and sirm100mt sirm60mt sirm is the saturation isothermal remanent magnetization sirmnmt represents the residual sirm after an n mt alternating field demagnetization have been used to document regional paleoclimate change in the asian interior by correlating the mineral magnetic record with the composite 18o record in deep sea sediments the long term up section decreasing trend in those ratios in both loess and paleosol units has been attributed to a long term decrease in the relative contributions of eolian hematite during glacial extrema and of pedogenic hematite during interglacial extrema respectively which reveals a long term decreasing trend in chemical weathering intensity in both glacial stage source region the gobi and deserts in northwestern china and interglacial stage depositional area the loess plateau region we further relate this long timescale variation to long term increasing aridification and cooling during both glacial extrema in the dust source region and interglacial extrema in the depositional area over the quaternary period changes in those ratios are most likely due to quaternary aridification and cooling driven by ongoing global cooling expansion of the arctic ice sheet and progressive uplift of the himalayan tibetan complex during this period

climatic interpretation of the luochuan and lingtai loess sections china based on changing iron oxide mineralogy and magnetic susceptibility abstract hematite and goethite estimated from diffuse reflectance spectra and magnetic susceptibility ms have been determined from both the luochuan and lingtai loess sections of the loess plateau of central china changing concentrations of these iron oxides and ms were used to determine paleoclimatic change based on a model that relates pedogenic production of hematite and magnetite to precipitation we propose two precipitation phases on the loess plateau during the last 2 6 ma from the wucheng red clay boundary up to paleosol s5 mis 13 precipitation on the loess plateau was moderate probably not frequently exceeding 450 mm yr and highly seasonal from s5 to the present precipitation during interglacial times has gradually increased to the present levels of 600 650 mm yr for the localities examined throughout the pleistocene spanning both glacial and interglacial conditions hematite to goethite ratios display a consistent decrease this decrease suggests that precipitation on the loess plateau has been getting less seasonal and or has been occurring during times when temperature was lower in addition to these long term changes it also appears that iron oxide records from the loess plateau exhibit 400 500 ka cycles from the wucheng red clay boundary to s5 these 400 500 ka cycles may be analogous to similar length cycles recorded in 13 c marine records in the south china sea and may be linked through weathering and silica production as a result of the asian monsoon

what do the hirm and s ratio really measure in environmental magnetism the hard isothermal remanent magnetization hirm and the s ratio are widely used in environmental magnetism to quantify the absolute and relative concentrations respectively of antiferromagnetic minerals hematite and goethite in mineral mixtures we demonstrate that synthetic al substituted hematite and goethite exhibit a wide range of coercivities which significantly influences the hirm and s ratio these parameters are therefore not necessarily straightforward indicators of the absolute and relative concentrations of hematite goethite to circumvent this problem we propose a new parameter the l ratio which is the ratio of two remanences after alternating field af demagnetization of an irm imparted in a 1 t field with a peak af of 100 mt and 300 mt irmaf 300mt irmaf 100mt these parameters are easily measured using modern vibrating sample or alternating gradient magnetometers changes in hirm only reflect changes in the absolute concentration of hematite and or goethite if the l ratio is relatively constant conversely l ratio fluctuations indicate variable coercivities that possibly reflect changes in the source of hematite goethite corresponding hirm and s ratio variations should be interpreted with caution in such cases the l ratio can be determined using equivalent terms depending on available instrumentation and measurement protocols for example the hirm is equivalent to irmaf 300mt likewise 0 5 sirm irm 100mt where irm 100mt represents the remanent magnetization obtained by first saturating the sample in a high field and then applying a back field of 100 mt is equivalent to irmaf 100mt the hirm 0 5 sirm irm 100mt ratio is therefore a suitable substitute for the l ratio when measurements are made with a long core magnetometer the newly proposed l ratio is straightforward to measure on a wide range of instruments and can provide significant new insights and reduce ambiguities associated with interpretation of two widely used parameters in environmental magnetism the hirm and s ratio

toward the discrimination of fine grained ferrimagnets by magnetic measurements in lake and near shore marine sediments the magnetic properties of low field susceptibility frequency dependent susceptibility fd and susceptibility of anhysteretic remanent magnetisation arm are used to define sets of natural soil and sediment samples within which by the criteria of king et al 1982 and maher 1988 the modal ferrimagnetic grain diameter is less than 0 07 0 1 m within this sample set two distinct groups with low and high values respectively for the quotients arm and arm fd are defined the first group includes sediment samples from sites where published studies propose a detrital origin for the fine grained ferrimagnetic content where catchment samples are available for comparison they fall within the same envelope as do clays from palaeosol samples within chinese loess this envelope of low quotient values also overlaps with the values for the fine grained synthetic magnetite samples within maher s 1988 new mt series the high quotient envelope of values includes sediments from the adriatic sea and clays from saltmarsh and shallow water marine sediments in nw britain in these cases no catchment source is postulated for the fine grained magnetite the size range of magnetite in this set appears to be almost exclusively stable single domain ssd and a bacterial origin seems likely sample sets from estuarine environments between river inflow sites and the open sea show intermediate values which in the case of the potomac are ordered by distance down river although at this stage magnetic measurements alone cannot discriminate between bacterial and fine grained detrital ferrimagnets in sediments they hold out some promise of doing so provided the distinctions proposed here can be substantiated by transmission electron microscopy