origin and consequences of cyclic ice rafting in the northeast atlantic ocean during the past 130 000 years deep sea sediment cores recovered from the northeast atlantic ocean were examined in order to elucidate the influence of the earth s orbital parameters on major ice rafting analyses of coarse grained ice rafted debris and planktonic foraminifers revealed a strong reaction to the precession signal since 130 000 yr b p dropstone layers have been deposited each half period of a precessional cycle 11 000 1000 yr ice rafting occurs during times of winter minimum summer maximum insolation and summer minimum winter maximum insolation in the first case high summer insolation forces meltwater discharge from the ice sheets into the polar seas which subsequently enhances formation of sea ice during the winter in the second case growth of continental ice enhances iceberg production which also leads to a salinity reduction of surface seawater both situations result in a southward penetration of polar water thus the marine record of dropstones documents ice rafting not only during weichselian stades but also during cold events within interstades the regularity of ice rafting yields a useful framework to calibrate and elucidate climatic changes not only in the region of the north atlantic ocean but also in remote areas such as the pacific ocean and the antarctic

unified structure in quaternary climate the quaternary climate record exhibits a structure of superimposed aperiodic oscillations starting at the 11 yr sunspot cycle and spaced by powers of 2 in period through the major 90 000 yr glacial cycle climate cycles that do not fall in this structure typically correspond to harmonics of the structure oscillations the inclusion of the known solar cycles and the presence of increased abundances of cosmogenic radionuclides at many structure periods suggest that the structure is related to long period solar variability

facies analysis and sea level change at the guadalupian lopingian global stratotype laibin south china and its bearing on the end guadalupian mass extinction abstract the guadalupian lopingian boundary stratotype at penglaitan and the nearby tieqiao section near laibin south china record a series of major environmental changes within the jiangnan basin during a mid permian biotic crisis the sequence stratigraphic petrographic and palaeontological record of these sections has been studied and the associated strontium isotopic fluctuations have been assayed mass extinction of fusulinid foraminifers is most clearly associated in time with onset of volcanism and a relative sea level fall that led to the establishment of mid ramp conditions laibin limestone in settings that were previously dominated by radiolarian mudstones the regression also coincides with a low point of 87 sr 86 sr ratios the lowstand deposits contain mafic scoriaceous grains that record pyroclastic volcanism probably centred in the emeishan flood basalt province 800 km to the west of laibin thus unusually violent eruptions associated with flood basalts in this province may have contributed to the environmental stresses responsible for the extinction event subsequent environmental changes included transgression spread of dysoxic waters indicated by populations of small pyrite framboids and a major negative c isotope excursion all these phenomena have been previously related to the end guadalupian extinction but they in fact post date the crisis because a post extinction fauna of foraminifers is encountered at this time

power spectrum of sea level change over fifteen decades of frequency 1 the power spectrum of relative sea level change has been estimated over more than 15 orders of magnitude in frequency from a frequency of 1 591 ma to a frequency of 1 5 s although there are still regions of the spectrum where data sampling and duration do not allow the power to be calculated most notably between periods of 100 1000 years the general shape of the spectrum is that in which the power depends on the square of the reciprocal frequency apart from periods between 1 and 100 years where the power spectrum falls off less steeply with increasing frequency a spectrum in which power depends on reciprocal frequency squared is the same spectrum as that calculated from a random walk signal of finite length there are some causes that have defined frequencies such as those associated with tides and the milankovitch cycles of the ice ages but there is also a continuum of relative sea level change that requires other causes the implications of this are discussed in the light of global change and heating of the lithosphere from the bottom

millennial scale climatic cycles in the early pliocene pollen record of ptolemais northern greece early pliocene lacustrine sediments from the ptolemais basin northern greece exhibit a climatically induced cyclicity which can be correlated with the orbital cycle of precession superimposed on precession controlled cycles palynological time series data reveal a higher order climatic cyclicity with periodicities of 10 2 5 and 1 5 ka these millennial scale vegetation changes are likely to reflect changes of the soil moisture gradient on mountain slopes caused by fluctuations in orographic winter precipitation such fluctuations corroborate the concept of a nao like north atlantic climatic teleconnection during early pliocene times the periodicities are similar to those of climate oscillations inferred from quaternary records the occurrence of millennial scale cyclicity in a time interval when the northern hemisphere was essentially ice free implies an ultimate forcing mechanism that operated independently of changes in the thermohaline circulation in the atlantic ocean the cycles are likely to be related to long period variations in solar activity

a long geoclimatic record from the permian a 260 000 year continuous annual geoclimatic time series has been compiled from the varved permian castile and bell canyon formations of the delaware basin southeastern new mexico and southwestern texas the last 200 000 years of the record was obtained from calcite laminated anhydrite and anhydrite laminated halite which formed as a result of seasonal and annual deposition in the evaporite basin the time series is based on measured thickness of individual varves analyses of calcium sulfate calcium carbonate and organic matter were made on 50 year intervals in the evaporite part of the sequence time series of the major components were examined by using smoothed graphic plots variance spectra and moving correlation coefficients the longest oscillation recorded in the series that may be of climatic origin has a period of about 100 000 years the calcium sulfate record contains 9 11 distinct oscillations with an average period of about 20 000 years the strongest oscillation has a preferred spectral period of 2700 years and is recorded throughout the series as thickness changes in calcium sulfate as events controlling halite deposition and as episodes of basin freshening a broad spectral response near a period of about 200 years reflects changes in sulfate carbonate and halite thickness shorter periods do not have consistent spectra the time series contains no preferred periods that have not already been identified in previously described records the climatic changes appear to be the result of a deterministic response to orbital effects at the longer periods and stochastic processes at the shorter periods an unusually strong response near 2700 years is associated with episodic freshening of the basin this period has been well established in the holocene paleoclimatic record and its presence in the permian suggests a deterministic origin

carbon and sulfur isotopic fluctuations associated with the end guadalupian mass extinction in south china abstract concentrations of total organic matter toc carbon isotopic compositions of carbonate and organic matter 13 c carb 13 c org and sulfur isotopic compositions of carbonate associated sulfate 34 s sulfate across the guadalupian lopingian g l boundary were analyzed from identical samples of tieqiao section laibin guangxi province south china the 13 c carb values show a positive excursion from 0 45 to the peak of 3 80 in the laibin limestone member of the maokou formation followed by a drastic drop to 2 60 in the lowest heshan formation then returned to about 1 58 similar to the trends of the 13 c carb values 13 c carb org values also show a positive excursion followed by a sharp negative shift the onset of a major negative carbon isotope excursion postdates the end guadalupian extinction that indicates subsequent severe disturbance of the ocean atmosphere carbon cycle the first biostratigraphic 34 s sulfate values during the g l transition exhibit a remarkable fluctuation a dramatic negative shift followed by a rapid positive shift ranging from 36 88 to 37 41 these sulfate isotopic records suggest that the ocean during the g l transition was strongly stratified forming an unstable chemocline separating oxic shallow water from anoxic euxinic deep water chemocline excursions together with subsequent rapid transgression and oceanic anoxia were likely responsible for the massive diversity decline of the g l biotic crisis

the carbon isotope excursion on gssp candidate section of lopingian guadalupian boundary an isotopic stratigraphically well documented outcrop in penglaitan guangxi province south china has been proposed as a candidate gssp for the lopingian guadalupian boundary correlatable outcrops from the west wing tieqiao section and east wing penglaitan section of the laibin syncline exhibit synchronous excursions in carbon isotopes the isotopic excursions 13c show the best placement of the boundary may lie at the base of bed 6k which coincides with the clarkina postbitteri conodont zone and with eustatic change 13c increases during the uppermost guadalupian jinogondolella granti conodont zone from the top of 3c to the base of 6i a 13c peak value of 5 is located at the transition between these two conodont zones and is suggested as a proxy for the transition from transgression to regression a gradual depletion of carbon isotopes occurs in the c postbitteri zone from bed 6e to 7b and this gradual 13c excursion also suggests the sequences around the guadalupian lopingian boundary at the candidate section are conformable during the middle later c postbitteri zone a 3 5 dramatic 13c depletion is recorded at the tieqiao section but only a 2 depletion at the deeper facies penglaitan section synchronous with conodont zones that mark eustatic changes

a neogene seawater sulfur isotope age curve from calcareous pelagic microfossils abstract until now our knowledge of the sulfur isotopic composition of seawater through geologic time has depended on stable isotopic analysis of sulfate from evaporites owing to the sporadic occurrence of evaporites through time the secular sulfur isotope age curve contains many gaps with little or no data in order to fill in some of these gaps particularly the neogene we have analyzed the sulfur isotopic composition of carbonate associated sulfate in carbonate tests of planktonic foraminifera other investigators have shown that sulfate may occur in biogenic calcites either lattice bound as micro fluid inclusions in adsorbed phases or as protein polysaccharides whatever the origin the sulfur isotopic composition of this sulfate appears to be representative of that of the water in which the organism lived as shown by results on recent calcareous foraminifera and macrofossils using this approach for study of miocene to recent pelagic marine sediments supplemented by new data for miocene marine evaporites from the gulf of suez we have found that the 34 s of seawater has decreased about 2 5 over the past 25 m y and that most of the decrease has occurred over the past 5 m y parallelling a decrease in the 13 c of dissolved oceanic bicarbonate from the same interval sedimentary redox models based on isotope records suggest that organic carbon and sulfide burial have both decreased over the past 5 m y alternatively an increase in weathering rates over the past 5 m y would not require a decrease in organic carbon or sulfide burial as long as the isotopic effect of the increased river input exceeds the isotopic effect of the burial of the reduced species in either case the net result would be a decrease in atmospheric p o 2

a temporal link between the emeishan large igneous province sw china and the end guadalupian mass extinction abstract previous studies have suggested that there were two mass extinction events in the late permian one that occurred at the permo triassic p t boundary 251 ma and a second smaller mass extinction that occurred 5 8 myr earlier at the end of the guadalupian many workers have argued that there is a causal relationship between large scale volcanic activity and mass extinctions the major mass extinction event at the p t boundary coincides with the outpouring of huge quantities of lava that formed the siberian flood basalt province in russia courtillot et al earth planet sci lett 166 1999 177 195 and wignall earth sci rev 53 2001 1 33 suggested that the earlier late permian mass extinction coincided with the eruption of the lavas that formed the emeishan flood basalt efb province in sw china however the age of eruption of the efb lavas is poorly constrained using the sensitive high resolution ion microprobe to analyze zircons we have established the age of the xinjie intrusion believed to be a feeder to the main phase of efb volcanism to be 259 3 ma hence the formation of the efb is coincident with a proposed extinction event at 256 259 ma this result supports a temporal link between the emeishan large igneous province and the end guadalupian mass extinction

permian palaeogeographic evolution of the jiangnan basin south china abstract the most striking geographic feature of the permian of south china is the jiangnan basin which intimately reflects the interplay between the yangtze and cathaysia blocks geographic and sedimentological evolution suggests that the jiangnan basin superposed on a precambrian collisonial megasuture and a folded early paleozoic deep basin was an extensional intracratonic basin it opened in the longlinian and became more passive and restricted in the latest maokouan the remarkably similar geographic patterns of the jiangnan basin in the early and late palaeozoic suggest that the yangtze and cathaysia blocks were coherent during the paleozoic

an isotopic study of biogeochemical relationships between carbonates and organic carbon in the greenhorn formation carbon isotopic compositions of total carbonate inoceramid carbonate micritic carbonate secondary cements total organic carbon and geoporphyrins have been measured in 76 different beds within a 17 m interval of a core through the greenhorn formation an interbedded limestone and calcareous shale unit of cretaceous age cenomanian turonian from the western interior seaway of north america results are considered in terms of variations in the processes of primary production which led to the biosynthesis of the molecular precursors of the geoporphyrins and in secondary processes those mediating the transformation of primary organic material into sedimentary total organic carbon it is shown that the porphyrin isotopic record reflects primary isotopic variations more closely than the toc isotopic record and that in these sediments toc is enriched in 13c relative to its primary precursor by 0 6 to 2 8 this enrichment is attributed to isotope effects within the consumer foodweb and is associated with respiratory heterotrophy variations in this secondary enrichment are correlated with variations in the isotopic composition of marine carbonate this correlation is attributed to effects of environmental changes on the marine foodweb these may have included increased atmospheric oxygen associated with the cenomanian turonian oceanic anoxic event the isotopic fractionation associated with fixation of carbon by primary producers is observed to have varied by 1 5 during the interval of deposition it is suggested that this change is due to a variation in the makeup of the community of primary producers and or to a decrease in the atmospheric abundance of co2 during the oceanic anoxic event

mass extinctions and sea level changes abstract review of sea level changes during the big five mass extinctions and several lesser extinction events reveals that the majority coincide with large eustatic inflexions the degree of certainty with which these eustatic oscillations are known varies considerably thus the late ordovician and end cretaceous extinctions are associated with unequivocal major regressions demonstrated from numerous widespread regions in contrast the multiple high frequency sea level changes reported for the frasnian famennian crisis based on the supposed depth preferences of conodont taxa have little support from sequence stratigraphic analyses which reveals the interval to be one of highstand the end permian mass extinction has long been related to a severe first order lowstand of sea level newell n d 1967 revolutions in the history of life geol soc am spec pap 89 63 91 based primarily on the widespread absence of latest permian ammonoid markers but field evidence reveals that the interval coincides with a major transgression newell s hypothesis that marine extinctions are related to shelf habitat loss during severe regression remains tenable for the end guadalupian and end triassic extinction events but not for other crises rapid high amplitude regressive transgressive couplets are the most frequently observed eustatic changes at times of mass extinction with the majority of extinctions occurring during the transgressive pulse when anoxic bottom waters often became extensive the ultimate cause of the sea level changes is generally unclear a glacioeustatic driving mechanism can only be convincingly demonstrated for the end ordovician and end devonian events at other times it is speculated that they may relate to the widespread regional doming and subsequent collapse caused by the impingement of superplumes and ultimate eruption on the base of the lithosphere

paleomagnetism of the upper devonian catskill formation from the southern limb of the pennsylvania salient possible evidence of oroclinal rotation multiple components of magnetization were isolated in the natural remanent magnetiza tion of samples of the upper devonian catskill formation red beds taken from the southern limb of the pennsylvania salient the dominant ther mally distributed component sf previously thought to predate folding is demonstrably syn folding in origins the mean direction for sf based on data from the current study and a pre vious study is declination inclination 161 6o 7 9 o a95 3 9 o pole position 127 3oe 43 1on a95 3 1 o n 14 sites although the remagnetization is clearly synfolding in most areas the relative ages of folding and remagne tization vary locally a subordinate high unblocking temperature component ht has a mean tilt corrected direction of 160o 36 o a95 16 o pole position 123 5oe 26 ion a95 15 4 o s n m 7 samples comparison of ht with the prefolding magnetization isolated in the northern limb of the salient suggests that the paleolatitude of this part of north america was about 16os and that part of the curvature of the salient was acquired during orogenesis

application of the trace element and isotope geochemistry of strontium to studies of carbonate diagenesis carbonate rocks and natural waters exhibit a wide range in the concentration and isotopic composition of strontium this wide range and the quantifiable covariation of these parameters can provide diagnostic tools for understanding processes of fluid rock interaction careful consideration of the uncertainties associated with trace element partitioning sample heterogeneity and fluid rock interaction mechanisms is required to advance the application of the trace element and isotope geochemistry of strontium to studies of diagenesis goundwater evolution ancient seawater chemistry and isotope stratigraphy a principal uncertainty involved in the application of sr concentration variations to carbonate systems is the large range of experimental and empirical results for trace element partitioning of sr between mineral and solution this variation may be a function of precipitation rate mineral stoichiometry crystal growth mechanism fluid composition and temperature calcite and dolomite in ancient limestones commonly have significantly lower sr concentrations 20 70 p p m than would be expected from published trace element distribution coefficient values and sr ca ratios of most modern sedimentary pore waters this discrepancy probably reflects the uncertainties associated with determining distribution coefficient values as techniques improve for the analytical measurement and theoretical modelling of sr concentration and isotopic variations the petrological analysis of carbonate samples becomes increasingly important the presence of even small percentages of non carbonate phases with high rb concentrations and high 87 sr86 sr values such as clay minerals can have significant effects on the measured 87 sr 86 sr values of carbonate rocks due to the decay of 87rb to 87 sr for example a permian marine limestone with 50 p p m sr and 1 p p m rb will have a present day 87 sr 86 sr value that is 2 10 4 higher than its original value this difference is an order of magnitude greater than the analytical uncertainty and illustrates the importance of assessing the need for and accuracy of such corrections a quantitative evaluation of the effects of water rock interaction on sr concentrations and isotope compositions in carbonates strengthens the application of these geochemical tracers geochemical modelling that combines the use of trace elements and isotopes can be used to distinguish between different mechanisms of water rock interaction including diffusive and advective transport of diagenetic constituents in meteoric pore fluids during the recrystallization of carbonate minerals quantitative modelling may also be used to construct diagnostic fluid rock interaction trends that are independent of distribution coefficient values and to distinguish between mixing of mineral end members and fluid rock interaction

contrasting atmospheric and climate dynamics of the last glacial and holocene periods our present climate is relatively stable compared to that of the last glacial maximum about 20 000 years ago palaeoclimate records obtained from ice cores1 2 and deep sea sediment cores3 for the last glacial period show abrupt temperature changes on timescales of a few hundred years which have been attributed to cycles of ice build up and release associated with large ice sheets dansgaard oeschger cycles and heinrich events 3 and their coupling to ocean circulation4 5 but little is known about the dynamics of the atmosphere during the last glaciation ice sheets influence atmospheric circulation and studies using general circulation models have suggested stormier more variable atmospheric dynamics during the last glacial maximum than today6 9 here we report the results of an analysis of temporal trends over the past 91 000 years in the oxygen isotope signatures of a high resolution ice core record from greenland1 2 this analysis provides direct evidence that atmospheric circulation during the last glaciation was more turbulent than it is today

late quaternary cyclic aridity in tropical australia abstract during the numerous quaternary sea level fluctuations the vast gulf of carpentaria in northern australia was more often a large lacustrine basin than a shallow sea recovery of aeolian quartz particles in a core spanning the last 40 000 calibrated years of sedimentation identifies a 2 600 year cyclic pattern of aridity the most pronounced period peaks around 21 500 calibrated years bp corresponding to the onstart of the period of lowest global sea level and glacial advance in new zealand the following peak of aeolian dust activity in carpentaria just precedes the termination of the low sea level stand at 19 300 calibrated years bp the timing of aeolian activity in northern australia does not coincide with heinrich events he 1 to 3 recognised in the atlantic ocean nor with the cyclicity of chilean glacial activity thus suggesting that separate forces engender those different phenomena

milankovitch theory viewed from devils hole variations in the oxygen isotope content 18o of late quaternary deep sea sediments mainly reflect changes in continental ice mass1 and hence provide important information about the timing of past ice ages because these sediments cannot yet be dated directly beyond the range of radiocarbon dating 40 50 kyr ages for the 18o record have been generated2 3 by matching the phase of the changes in 18o to that of variations in the earth s precession and obliquity adopting this timescale yields a close correspondence between the time varying amplitudes of these orbital variations and those of a wide range of climate proxies4 lending support to the milankovitch theory that the earth s glacial interglacial cycles are driven by orbital variations recently winograd et al 5 reported a record of 18o variations in a fresh water carbonate sequence from devils hole nevada dated by u th disequilibrium6 they concluded that the timing of several of the features in the record which reflects changes in the temperature of precipitation over nevada as well as changes in the isotopic composition of the moisture source5 7 showed significant deviations from that predicted by milanko vitch theory here we demonstrate that applying the devils hole chronology to ocean cores requires physically implausible changes in sedimentation rate moreover spectral analysis of the devils hole record shows clear evidence of orbital influence we therefore conclude that transfer of the devils hole chronology to the marine record is inappropriate and that the evidence in favour of milankovitch theory remains strong

nonlinear variability of the climatic system from singular and power spectra of late quaternary records stable isotope records from seven marine cores and one ice core provide invaluable information on the intricate behavior of the climatic system over time scales of 104 to 105 years these records in conjunction with a simple coupled climate model help us understand major mechanisms of paleoclimatic variability the time intervals covered by the records include the last glacial interglacial cycle in spite of the difference in the nature of the records common features are revealed by advanced spectral analysis tools the dominant features are the presence of orbital frequencies on the one hand and a low number of internal degrees of freedom on the other the climatic system appears therefore to act on the quaternary time scales considered as a forced nonlinear oscillator the internal mechanisms giving rise to the aperiodic oscillations include ice albedo feedback precipitation temperature feedback and interactions between the ice sheets and the bedrock

methane release from igneous intrusion of coal during late permian extinction events abstract unusually large and locally variable carbon isotope excursions coincident with mass extinctions at the end of the permian period 253 ma and guadalupian epoch 260 ma can be attributed to methane outbursts to the atmosphere methane has isotopic values 13c low enough to reduce to feasible amounts the carbon required for isotopic mass balance the duration of the carbon isotopic excursions and inferred methane releases are here constrained to 10 000 yr by counting annual varves in lake deposits and by estimating peat accumulation rates on paleogeographic maps the most marked carbon isotope excursions form linear arrays back to plausible methane sources end permian siberian traps and longwood bluff intrusions of new zealand and end guadalupian emeishan traps of china intrusion of coal seams by feeder dikes to flood basalts could create successive thermogenic methane outbursts of the observed timing and magnitude but these are unreasonably short times for replenishment of marine or permaf

interpreting carbon isotope excursions carbonates and organic matter abstract variations in the carbon isotopic compositions of marine carbonate and organic carbon provide a record of changes in the fraction of organic carbon buried through time and may provide clues to changes in rates of weathering and sources of organic carbon paired carbonate and organic carbon isotope determinations provide a possibility of interpreting not only changes in the global carbon cycle through time but changes in atmospheric pco2 as well interpretations of these types of data are typically rather qualitative a quantitative basis is required to develop a better understanding of changes in the carbon cycle for this purpose we employ a simple model of the global carbon cycle which is subjected to a number of different perturbations each lasting 500 ky i e much longer than the residence times of carbon and phosphorus in the ocean atmosphere system in addition to standard considerations of carbon mass and isotopic fluxes to the ocean atmosphere system from weathering and volcanism and fluxes of organic carbon and carbonate carbon to sediments the model incorporates sensitivity of the photosynthetic carbon isotope effect to changes in pco2 the inclusion of this parameter leads to unexpected carbon isotope responses to forcing that causes increased rates of organic carbon burial a series of simple to more complex simulations illustrates the significant effects of varying differences between the carbon isotopic composition of sedimented carbonate and organic carbon b with constant b a 50 increase in organic carbon burial produces a parallel increase in carbonate and organic carbon isotopic compositions however the same simulation with b responsive to pco2 changes produces an initial parallel 13 c increase but this is followed by an even greater 13 c enrichment in organic carbon because pco2 falls in response to increased organic carbon burial the counterintuitive overall result of the enhanced organic carbon burial event is that the carbonate carbon isotopic composition actually decreases because of the more substantial increase in 13 c org in addition we illustrate the effects on carbon isotopic compositions of the oceanic inorganic carbon reservoir and buried organic matter of a 50 increase in volcanic co2 outgassing a 50 increase in weathering rate with coupled phosphate and riverine carbon flux responses a 50 decrease in shale associated organic carbon weathering a 50 decrease in silicate weathering rate and the possible effects of the rise in abundance of c4 plants in the late miocene to recent we compare the model simulated carbon isotopic responses for some of these experiments to paired carbonate and organic carbon records to illustrate how these records might be interpreted in light of the model response

sulfur isotopic evidence for chemocline upward excursions during the end permian mass extinction the latest permian was a time of major change in ocean chemistry accompanying the greatest mass extinction of the phanerozoic to examine the nature of these changes samples from two well studied marine sections that span the permian triassic boundary have been analyzed the meishan and shangsi sections located in southern china isotopic analysis of the carbonate associated sulfate in these samples provides a detailed record of several isotopic shifts in 34scas approaching and across the ptb ranging from 30 to 15 vcdt with repeated asynchronous fluctuations at the two locations we interpret the patterns of isotopic shifts in conjunction with other data to indicate a shallow unstable chemocline overlying euxinic deep water which periodically upwelled into the photic zone these chemocline upward excursion events introduced sulfide to the photic zone stimulating a bloom of phototrophic sulfur oxidizing bacteria we hypothesize that elemental sulfur globules produced by these organisms and 34s depleted pyrite produced in the euxinic water column were deposited in the sediment later oxidation led to incorporation as cas this created the large changes to the 34scas observed in the latest permian at these locations

evidence for general instability of past climate from a 250 kyr ice core record recent results1 2 from two ice cores drilled in central greenland have revealed large abrupt climate changes of at least regional extent during the late stages of the last glaciation suggesting that climate in the north atlantic region is able to reorganize itself rapidly perhaps even within a few decades here we present a detailed stable isotope record for the full length of the greenland ice core project summit ice core extending over the past 250 kyr according to a calculated timescale we find that climate instability was not confined to the last glaciation but appears also to have been marked during the last interglacial as explored more fully in a companion paper3 and during the previous saale holstein glacial cycle this is in contrast with the extreme stability of the holocene suggesting that recent climate stability may be the exception rather than the rule the last interglacial seems to have lasted longer than is implied by the deep sea specmap record4 in agreement with other land based observations5 6 we suggest that climate instability in the early part of the last interglacial may have delayed the melting of the saalean ice sheets in america and eurasia perhaps accounting for this discrepancy

volcanism mass extinction and carbon isotope fluctuations in the middle permian of china the 260 million year old emeishan volcanic province of southwest china overlies and is interbedded with middle permian carbonates that contain a record of the guadalupian mass extinction sections in the region thus provide an opportunity to directly monitor the relative timing of extinction and volcanism within the same locations these show that the onset of volcanism was marked by both large phreatomagmatic eruptions and extinctions amongst fusulinacean foraminifers and calcareous algae the temporal coincidence of these two phenomena supports the idea of a cause and effect relationship the crisis predates the onset of a major negative carbon isotope excursion that points to subsequent severe disturbance of the ocean atmosphere carbon cycle

10 be and delta 2 h in polar ice cores as a probe of the solar variability s influence on climate and discussion by using the technique of accelerator mass spectrometry it is now possible to measure detailed profiles of cosmogenic cosmic ray produced 10 be in polar ice cores recent work has demonstrated that these profiles contain information on solar activity via its influence on the intensity of galactic cosmic rays arriving in the earth s atmosphere it has been known for some time that as a result of temperature dependent fractionation effects the stable isotope profiles delta 2 o and delta 2 h in polar ice cores contain palaeoclimate information thus by comparing the 10 be and stable isotope profiles in the same ice core one can test the influence of solar variability on climate and this independent of possible uncertainties in the absolute chronology of the records we present here the results of such a comparison for two antarctic ice cores one from the south pole covering the past ca 1000 years and one from dome c covering the past ca 3000 years