major types and time space distribution of mesozoic ore deposits in south china and their geodynamic settings the ore deposits of the mesozoic age in south china can be divided into three groups each with different metal associations and spatial distributions and each related to major magmatic events the first event occurred in the late triassic 230 210 ma the second in the mid late jurassic 170 150 ma and the third in the early mid cretaceous 120 80 ma the late triassic magmatic event and associated mineralization is characterized by peraluminous granite related w sn nb ta mineral deposits the triassic ore deposits are considerably disturbed or overprinted by the later jurassic and cretaceous tectono thermal episodes the mid late jurassic magmatic and mineralization events consist of 170 160 ma porphyry skarn cu and pb zn ag vein deposits associated with i type granites and 160 150 ma metaluminous granite related polymetallic w sn deposits the late jurassic metaluminous granite related w sn deposits occur in a ne trending cluster in the interior of south china such as in the nanling area in the early mid cretaceous from about 120 to 80 ma but peaking at 100 90 ma subvolcanic related fe deposits developed and i type calc alkaline granitic intrusions formed porphyry cu mo and porphyry epithermal cu au ag mineral systems whereas s type peraluminous and or metaluminous granitic intrusions formed polymetallic sn deposits these cretaceous mineral deposits cluster in distinct areas and are controlled by pull apart basins along the south china continental margin based on mineral assemblage age and space time distribution of these mineral systems integrated with regional geological data and field observations we suggest that the three magmatic mineralization episodes are the result of distinct geodynamic regimes the triassic peraluminous granites and associated w sn nb ta mineralization formed during post collisional processes involving the south china block the north china craton and the indo china block mostly along the dabie sulu and songma sutures jurassic events were initially related to the shallow oblique subduction of the izanagi plate beneath the eurasian continent at about 175 ma but i type granitoids with porphyry cu and vein type pb zn ag deposits only began to form as a result of the breakup of the subducted plate at 170 160 ma along the nne trending qinzhou hangzhou belt also referred to as qin hang or shi hang belt which is the neoproterozoic suture that amalgamates the yangtze craton and cathaysia block a large subduction slab window is assumed to have formed in the nanling and adjacent areas in the interior of south china triggering the uprise of asthenospheric mantle into the upper crust and leading to the emplacement of metaluminous granitic magma and associated polymetallic w sn mineralization a relatively tectonically quiet period followed between 150 and 135 ma in south china from 135 ma onward the angle of convergence of the izanagi plate changed from oblique to parallel to the coastline resulting in continental extensional tectonics and reactivation of regional scale ne trending faults such as the tan lu fault this widespread extension also promoted the development of ne trending pull apart basins and metamorphic core complexes accompanied by volcanism and the formation of epithermal cu au deposits granite related polymetallic sn w deposits and hydrothermal u deposits between 120 and 80 ma with a peak activity at 100 90 ma

a palaeoenvironmental record of the southern hemisphere last glacial maximum from the mount cass loess section north canterbury aotearoa new zealand

absolute timing of sulfide and gold mineralization a comparison of re os molybdenite and ar ar mica methods from the tintina gold belt alaska new re os molybdenite dates from two lode gold deposits of the tintina gold belt alaska provide direct timing constraints for sulfide and gold mineralization at fort knox the re os molybdenite date is identical to the u pb zircon age for the host intrusion supporting an intrusive related origin for the deposit however 40ar 39ar dates from hydrothermal and igneous mica are considerably younger at the pogo deposit re os molybdenite dates are also much older than 40ar 39ar dates from hydrothermal mica but dissimilar to the age of local granites these age relationships indicate that the re os molybdenite method records the timing of sulfide and gold mineralization whereas much younger 40ar 39ar dates are affected by post ore thermal events slow cooling and or systemic analytical effects the results of this study complement a growing body of evidence to indicate that the re os chronometer in molybdenite can be an accurate and robust tool for establishing timing relations in ore systems

influence of the tropics and southern westerlies on glacial interhemispheric asymmetry latitudinal variations in the location of the southern westerly wind belt have been associated with millennial scale climate variations during the last glacial period a reconstruction of sea surface temperatures off the southern coast of australia suggests that these climate variations also drove changes in the location of the oceanic subtropical front

quantifying global warming from the retreat of glaciers records of glacier fluctuations compiled by the world glacier monitoring service can be used to derive an independent estimate of global warming during the last 100 years records of different glaciers are made comparable by a two step scaling procedure one allowing for differences in glacier geometry the other for differences in climate sensitivity the retreat of glaciers during the last 100 years appears to be coherent over the globe on the basis of modeling of the climate sensitivity of glaciers the observed glacier retreat can be explained by a linear warming trend of 0 66 kelvin per century

highly evolved juvenile granites with tetrad ree patterns the woduhe and baerzhe granites from the great xing an mountains in ne china abstract in ne china voluminous granitoids were emplaced in late paleozoic and mesozoic times we report here sr nd o isotopic and elemental abundance data for two highly evolved granitic plutons woduhe and baerzhe from the great xing an mountains they show a rather juvenile sr nd isotopic signature and a spectacular tetrad effect in their ree distribution patterns as well as non charac charge and radius controlled trace element behavior the emplacement ages are constrained at 130 4 ma for the woduhe and 122 5 ma for the baerzhe granites by rb sr and sm nd isotope analyses both granites are also characterized by low but imprecise initial 87sr 86sr ratios of about 0 703 the nd sr isotope data argue for their generation by melting of dominantly juvenile mantle component with subordinate recycled ancient crust this is largely compatible with the general scenario for much of the phanerozoic granitoids emplaced in the central asian orogenic belt the parental magmas for both the woduhe and baerzhe granites have undergone extensive magmatic differentiation during which intense interaction of the residual melts with aqueous hydrothermal fluids probably rich in f and cl resulted in the non charac trace element behavior and the tetrad effect of ree distribution both the woduhe and baerzhe granites show the characteristic trace element patterns of rare metal granites but their absolute abundances differ by as much as two orders of magnitude the oxygen isotope compositions of the two granites have been severely disturbed significant 18o depletion in feldspar but not so much in quartz suggests that the hydrothermal alteration took place in a temperature condition of 300 500 c this subsolidus hydrothermal alteration is decoupled from the late stage magma fluid interaction at higher temperatures despite the two distinct and intense events of water rock interaction the rb sr and sm nd geochronological systems seem to have maintained closed hence suggesting that the two events occurred shortly after the plutonic emplacements

re os ages for the erdenet and tsagaan suvarga porphyry cu mo deposits mongolia and tectonic implications the erdenet and tsagaan suvarga deposits are the two largest known porphyry cu mo deposits in mongolia replicate re os analyses of molybdenite from these deposits yield ages of 240 7 0 8 and 240 4 0 8 ma for erdenet and 370 1 1 2 and 370 6 1 2 ma for tsagaan suvarga 2 errors the re os age of erdenet is significantly older and that of tsagaan suvarga is slightly older than published 40ar 39ar ages for sericite associated with mineralization in these deposits 207 4 5 0 and 364 9 7 0 ma respectively these re os results suggest that in the hydrothermal environment 40ar 39ar ages may be partly to significantly reset whereas re os ages record and maintain the age of primary mineralization events these re os ages indicate that porphyry mineralization at erdenet and tsagaan suvarga are related to porphyritic intrusions representing the youngest event during regional magmatism in northern and southern mongolia respectively the re os age of erdenet marks the final stage of arc magmatism in northern mongolia followed by late permian collision between the mongolian north china and siberian blocks the re os age of tsagaan suvarga indicates that devonian arc magmatism in southern mongolia was active at the present latitude of 44 n at least until 370 ma

the evolution of the patagonian ice sheet from 35 ka to the present day patice abstract we present patice a gis database of patagonian glacial geomorphology and recalibrated chronological data patice includes 58 823 landforms and 1 669 geochronological ages and extends from 38 s to 55 s in southern south america we use these data to generate new empirical reconstructions of the patagonian ice sheet pis and subsequent ice masses and ice dammed palaeolakes at 35 ka 30 ka 25 ka 20 ka 15 ka 13 ka synchronous with the antarctic cold reversal 10 ka 5 ka 0 2 ka and 2011 ad at 35 ka the pis covered of 492 6 x103 km2 had a sea level equivalent of 1 496 mm was 350 km wide and 2090 km long and was grounded on the pacific continental shelf edge outlet glacier lobes remained topographically confined and the largest generated the suites of subglacial streamlined bedforms characteristic of ice streams the pis reached its maximum extent by 33 28 ka from 38 s to 48 s and earlier around 47 ka from 48 s southwards net retreat from maximum positions began by 25 ka with ice marginal stabilisation then at 21 18 ka which was then followed by rapid irreversible deglaciation by 15 ka the pis had separated into disparate ice masses draining into large ice dammed lakes along the eastern margin which strongly influenced rates of recession glacial readvances or stabilisations occurred at least at 14 13 ka 11 ka 6 5 ka 2 1 ka and 0 5 0 2 ka we suggest that 20th century glacial recession a 1 is occurring faster than at any time documented during the holocene

in situ la mc icp ms and id tims u pb geochronology of cassiterite in the giant furong tin deposit hunan province south china new constraints on the timing of tin polymetallic mineralization abstract the furong deposit located in southern hunan province china is a newly discovered giant tin deposit spatially associated with the a type qitianling granite the petrogenetic link between the giant furong tin deposit and the qitianling granite batholith remains controversial because of the lack of precise dating for the tin polymetallic mineralization here we report for the first time in situ u pb data on cassiterite obtained by la mc icp ms and the results are compared to id tims data the in situ la mc icp ms analyses of the cassiterites provide a reliable age constraint for tin polymetallic mineralization in the furong deposit yielding an isochron age of 159 9 1 9 ma at 95 confidence level mswd 18 which is indistinguishable from the id tims 206 pb 238 u weighted mean age of 158 2 0 4 ma the in situ u pb ages corroborate the ar ar dates published for the furong tin deposit which indicate that the mineralization is coeval with the emplacement of the qitianling granite batholith these results provide further evidence of a close temporal link between the pluton s emplacement and tin mineralization in the furong area the data obtained clearly demonstrate that in situ la mc icp ms u pb dating of cassiterite is a robust geochronometer for direct dating of tin polymetallic mineralization

cretaceous ongonites topaz bearing albite rich microleucogranites from ongon khairkhan central mongolia products of extreme magmatic fractionation and pervasive metasomatic fluid rock interaction abstract ongonites were defined at their type locality at ongon khairkhan central mongolia as pristine magmatic topaz bearing albite quartz keratophyres with up to 4 wt f and containing phenocrysts of albite k feldspar quartz and rare mica and topaz hosted in a groundmass composed of the same minerals however detailed petrographic and sem eds studies indicate that these rocks underwent considerable subsolidus exchange with deuteric fluids as evidenced by the presence of albitic plagioclase ab 100 and end member orthoclase or 100 secondary li fe rich mica zinnwaldite enriched in rare metals sn w ta nb pitted feldspars containing fluid inclusions and disseminated fluorite the 120 ma old dyke rocks emplaced at a high structural level in the crust are strongly peraluminous leucogranites characterized by high al and alkalis that are also enriched in rb cs ga and ta depleted in mg ca zr ba sr and eu and have anomalous k rb rb sr zr hf and nb ta ratios compared to the average continental crust however the suite has nd isotopic ratios nd 120 1 similar to those of contemporaneous a type granites of the mongolian transbaikalian igneous province of the central asian orogenic belt the inferred primary 18 o 6 to 7 and pb isotopic values are consistent with a granitic parent magma and interaction with orthomagmatic fluids the ongonites and constituent minerals record 1 an extensive and protracted crystal fractionation history in part due to the presence of volatiles particularly f which depressed the solidus temperature of the felsic rocks and extended its duration of crystallization and 2 subsolidus exchange with fluids which includes late flux of heated meteoric water as indicated by modified whole rock 18 o values 0 5 to 2 7 the interaction of the ongonites with internally derived orthomagmatic fluids is considered to result in enrichment and or redistribution of several incompatible elements but not to have greatly modified their original major element chemistry which indicates that this suite represents the last stages of fractionation of a highly differentiated f rich granitic magma the escape of these evolved melts from the apical part of the underlying pluton is now represented by the ongonite dykes late stage magmatic water rich fluids enriched in incompatible elements including nb ta sn and w were responsible for the late to post magmatic alteration and associated w mineralization

lamellar magnetism and exchange bias in billion year old titanohematite with nanoscale ilmenite exsolution lamellae i mineral and magnetic characterization

high frequency holocene glacier fluctuations in new zealand differ from the northern signature understanding the timings of interhemispheric climate changes during the holocene along with their causes remains a major problem of climate science here we present a high resolution 10be chronology of glacier fluctuations in new zealand s southern alps over the past 7000 years including at least five events during the last millennium the extents of glacier advances decreased from the middle to the late holocene in contrast with the northern hemisphere pattern several glacier advances occurred in new zealand during classic northern warm periods these findings point to the importance of regional driving and or amplifying mechanisms we suggest that atmospheric circulation changes in the southwest pacific were one important factor in forcing high frequency holocene glacier fluctuations in new zealand

the timing and nature of the last glacial cycle in new zealand abstract this paper constitutes a review of the last otiran glaciation in new zealand spanning marine isotope stages mis 4 2 we highlight the nature of glaciation which is characterised by exceptional sedimentation relatively mild maritime climatic conditions and the widespread presence of water associated with proglacial settings these conditions produce glacial systems characterised by extensive outwash fans and relatively small terminal moraines extensive recent geochronological work allows us to recognise at least eight glacial advances during the otiran these occurred at 65 3 25ka 47 5 3 ka 38 5 2 ka 31 5 3 ka 26 5 2 ka 20 5 2 ka 17 2 ka and 13 1 ka which we term the otira 1 to 8 advances respectively though the analytical uncertainty ranges for some of these advances overlap all are independently distinguished through moraine morphologic relationships and or stratigraphic relationships in outcrop major advances appear to be associated with climate influences such as periods of southern hemisphere insolation minima 65ka and 31 5 ka advances the last glacial maximum cooling lgm 20 5 ka and periods of antarctic cooling 13ka the timing of greatest glacial extent in the last glacial cycle is not simultaneous across new zealand the mis 4 advance was the greatest in the southern south island while the mis 3 2 advances 26 5 ka were greatest in the central south island in the northern south island and the north island mis 4 mis 3 2 and the last glacial maximum appear to be equivalent in extent we attribute these spatio temporal variations in the timing of maximum glaciation to precipitation changes related to a northward shift in the track of the westerlies

fractionation of zr and hf in cassiterite abstract analytical data on zr and hf in cassiterite samples from various genetic types of deposits are reported two genetic groups of cassiterites can be distinguished by their zr hf ratios which are 5 and 30 for samples from pegmatites and hydrothermal vein mineralizations respectively relating these zr hf ratios to those in zircons and common rocks 43 it is derived that the difference of zr hf is 0 2 assuming a rayleigh fractionation model it is proposed to make use of the zr hf ratio as a geochemical indicator of the mode of formation of the cassiterite in cases when this is not clear from the geologic setting such as in placer deposits

timing of the descent into the last ice age determined by the bipolar seesaw we present planktonic foraminiferal fauna and isotope records from the se atlantic that highlight the nature of millennial scale variability over the last 100 kyr we derive an hypothesis driven age model for our records based on the empirical link between variations in greenland temperature ocean circulation and carbonate preservation in the deep se atlantic our results extend earlier findings of an anti phase seesaw relationship between north and south for the largest abrupt events of marine isotope stage mis 3 2 and the last deglaciation in particular we find that heinrich stadials were paralleled by inferred southward shifts of the thermal subtropical front these were followed by pronounced rebounds of the front with the return to interstadial conditions in the north our results also shed light on the mechanism of glaciation in contrast to the last deglaciation which was a globally symmetric change superposed by interhemispheric asynchronicity we find that the descent into full glacial conditions at the onset of mis 4 70 ka displayed interhemispheric synchrony we suggest that this globally synchronous descent into glacial mis 4 was preconditioned by orbital changes but that the timing was ultimately determined by abrupt changes in ocean atmosphere circulation patterns i e the bipolar seesaw

climatic evolution in the australian region over the last 94 ka spanning human occupancy and unveiling the last glacial maximum abstract the quaternary is well known for being a period of the geological record that saw significant and alternating climatic fluctuations here we concentrate on the last 94 millennia that saw australia and its surrounding seas undergo significant environmental changes importantly also it is during that this period of time includes the arrival and settlement of humans in australia following on from marine isotopic stage 4 mis4 that saw over the period of 71 59 ka bp a significant eustatic sea level drop 100 m low sea surface temperatures as well as glacial conditions on land australia experienced wet conditions again but eventually progressively entered into a glacial phase by then humans had arrived on this large continent and later the megafauna progressively became extinct this paper describes in detail the climate over this period based principally on the high resolution record of two marine sediment cores located offshore of the southern australian margin and that are then compared with known events on land as well as other deep sea cores particular emphasis is placed on the period that spans the last glacial maximum lgm the extent of which thus far had been poorly defined in the australian region emphasis is placed on the period from 34 to 14 ka to demonstrate that 1 the lgm defined here as the period 24 to 18 ka was not always extremely dry and cold and 2 that people were able to live in inland australia as water existed in places despite generally cold conditions we also show using a series of ten maps at 2 ka intervals over the 34 14 ka period the waxing and waning of oceanic fronts such as the subtropical and subantarctic fronts link sea surface temperatures sst with periods of glacial expansion in the australian alps and tasmania as well as the south island of new zealand and the extent of the leeuwin current down to south of australia aeolian dust was transported at sea over the main core site from 26 to 18 ka period pointing to arid conditions in australia but this period was punctuated by two significant reductions in dust transport to both core sites coinciding with a retreat of the subantarctic front away from the australian southern coastline and slight sst shifts for a few centuries at 24 and 22 21 ka bp at the peak of the cold phase from 23 to 18 4 ka summer sst were of the order of 9 c below that experienced during the middle of the holocene at about 6 ka bp a similar temperature drop was also experienced offshore the northwestern corner of western australia periglacial activity dates for the australian mainland and tasmania pool around 22 ka on either side of the 24 ka event the chain of lakes in the willandra lakes retained water and human activity was registered in the area elsewhere in australia water was present to sustain human populations during the cold and dry times it is postulated here that northern australia was at times quite wet especially during mis4 the cessation of the lgm is set on 18 4 ka from offshore southern australia as confirmed for the deep sea cores by several proxies and more likely at 18 ka inland finally we document that it took two millennia for glacial conditions to end in the australian region as registered in our deep sea core records well after the lowest global sea level 20 6 and 20 ka respectively started to rise there is also evidence of another very cold period determined on the australian mainland tasmania and the south island of new zealand centred around 27 ka after which time warmer conditions occurred before the start of the lgm this is matched with our deep sea records with very cold conditions and changes in oceanographic conditions

precise determination of phanerozoic zircon pb pb age by multicollector sims without external standardization 1 zircon has long been recognized as the best geochronometer and the most important timekeeper in geosciences modern microbeam techniques such as sims and la icpms have been successfully applied to in situ u pb zircon age determinations at spatial resolutions of 20 30 m or less matrix matched calibration by external standardization of well characterized natural zircon references is a principal requirement for precise microbeam u pb zircon age determination due to fractionation effects between pb and u which usually result in an external age error exceeding 1 alternatively zircons with a closed u pb system can be directly dated by measurement of 207pb 206pb isotopic ratio without external standardization which has been a common practice for zircons older than 1 0 ga but not for relatively young 1 0 ga and particularly phanerozoic ones because of limitations of analytical precision we describe in this paper a method of 207pb 206pb measurement on phanerozoic zircons using a new generation of large radius magnetic sector multicollector cameca ims 1280 sims in combination with multicollector mode a nuclear magnetic resonance nmr magnet controller and oxygen flooding techniques we achieve precisions of 207pb 206pb ratio of 0 1 and 0 1 0 2 propagating to pb pb age errors 0 4 and 1 3 excluding u decay constant uncertainties for zircons of latest neoproterozoic and late paleozoic to mesozoic age respectively therefore the multicollector sims is capable of direct determination of zircon pb pb ages as young as mesozoic age with uncertainties of geological significance this technique is useful for direct dating of zircons in thin sections moreover it has significance for dating of some other u rich minerals i e baddeleyite and zirconolite that are not suitable for sims u pb dating by external standardization

ice age terminations 230th dated oxygen isotope records of stalagmites from sanbao cave china characterize asian monsoon am precipitation through the ends of the third and fourthmost recent ice ages as a result am records for the past four glacial terminations can now be precisely correlated with those from ice cores and marine sediments establishing the timing and sequence of major events in all four cases observations are consistent with a classic northern hemisphere summer insolation intensity trigger for an initial retreat of northern ice sheets meltwater and icebergs entering the north atlantic alter oceanic and atmospheric circulation and associated fluxes of heat and carbon causing increases in atmospheric co2 and antarctic temperatures that drive the termination in the southern hemisphere increasing co2 and summer insolation drive recession of northern ice sheets with probable positive feedbacks between sea level and co2

interhemispheric atlantic seesaw response during the last deglaciation the asynchronous relationship between millennial scale temperature changes over greenland and antarctica during the last glacial period has led to the notion of a bipolar seesaw which acts to redistribute heat depending on the state of meridional overturning circulation within the atlantic ocean here we present new records from the south atlantic that show rapid changes during the last deglaciation that were instantaneous within dating uncertainty and of opposite sign to those observed in the north atlantic our results demonstrate a direct link between the abrupt changes associated with variations in the atlantic meridional overturning circulation and the more gradual adjustments characteristic of the southern ocean these results emphasize the importance of the southern ocean for the development and transmission of millennial scale climate variability and highlight its role in deglacial climate change and the associated rise in atmospheric carbon dioxide

ice sheets and sea level of the last glacial maximum this paper outlines the general issues regarding ice sheets and sea level of the last glacial maximum lgm which formed the basis of an epilog project workshop papers in this special issue of quaternary science reviews provide a comprehensive assessment of these issues from the perspective of geological reconstructions of ice sheet extent records of sea level change ice sheet modelling geophysical models of glacial isostatic adjustment and geochemical proxies of ice volume this new assessment has substantially narrowed the uncertainties in the total changes in ice sheets and sea level and their proxies suggesting a net decrease in eustatic sea level at the lgm ranging from 120 to 135 m r 2001 elsevier science ltd all rights reserved

the last glacial maximum at 44 s documented by a 10be moraine chronology at lake ohau southern alps of new zealand abstract determining whether glaciers registered the classic last glacial maximum lgm 26 500 19 000 yrs ago coevally between the hemispheres can help to discriminate among hypothesized drivers of ice age climate here we present a record of glacier behavior from the southern alps of new zealand during the local lgm llgm we used 10 be surface exposure dating methods and detailed glacial geomorphologic mapping to produce a robust chronology of well preserved terminal moraines deposited during the llgm near lake ohau on central south island we then used a glaciological model to estimate a llgm glacier snowline and atmospheric temperature from the ohau glacier record seventy three 10 be surface exposure ages place culminations of terminal moraine construction and hence completions of glacier advances to positions outboard of present day lake ohau at 138 600 10 600 yrs 32 520 970 yrs ago 27 400 1300 yrs ago 22 510 660 yrs ago and 18 220 500 yrs ago recessional moraines document glacier recession into the lake ohau trough by 17 690 350 yrs ago exposure of an ice molded bedrock bench located inboard of the innermost llgm moraines by 17 380 510 yrs ago indicates that the ice tongue had receded about 40 of its overall length by that time comparing our chronology with distances of retreat suggests that the ohau glacier terminus receded at a mean net rate of about 77 m yr 1 and its surface lowered by 200 m between 17 690 and 17 380 yrs ago a long term continuation of ice retreat in the ohau glacier catchment is implied by moraine records at the head of irishman stream valley a tributary of the ohau glacier valley the irishman stream cirque glacier advanced to produce a set of lateglacial moraines at 13 000 500 yrs ago implying that the cirque glacier was less extensive prior to that advance we employed a glaciological model fit to these mapped and dated llgm moraines to derive snowline elevations and temperature parameters from the ohau glacier record the modeling experiments indicate that a snowline lowering of 920 50 m and temperature depression of 6 25 0 5 c below modern values allows for the ohau glacier to grow to an equilibrium position within the lgm moraine belt taken together with a glaciological simulation reported from the irishman stream valley snowlines and temperatures increased by at least 520 m and 3 6 c respectively between 18 000 and 13 000 yrs ago climate parameters derived from the ohau glacier reconstruction are similar to those derived from glacier records from patagonia to air temperature indicators from antarctica as well as to sea surface temperature and stratification signatures of the southern ocean we think that the best explanation for the observed southern llgm is that southern winter duration modulated southern ocean sea ice which in turn influenced southern ocean stratification and made the surface ocean cooler orbitally induced cooling of the southern ocean provides an explanation for the llgm in the southern alps having been coincident with the northern lgm we argue further that the global effect of north atlantic stadials led to disturbance of southern ocean stratification southward shifts of the subtropical front and retreat of southern alps glaciers collapse of southern ocean stratification during heinrich stadial 1 along with attendant sea surface warming triggered the onset of the last glacial termination in the southern alps of new zealand

trace and rare earth elements in cassiterite sources of components for the tin deposits of the mole granite australia trace and rare earth elements have been determined for cassiterite from deposits associated with the mole granite and hosted by granite metasediments and metavolcanics the ree of cassiterite is controlled by the ree of the the ore fluid and the rocks through which this fluid circulated the ree distribution factor and lree hree value of cassiterite is strongly influenced by the associated mineral assemblage the fluid chemistry and the crystal chemical characteristics of the host mineral cassiterite from deposits hosted by granite have trace and rare earth element characteristics similar to those determined for the mole granite cassiterite from deposits hosted by metasediments or acid volcanics have most trace and rare earth element characteristics similar to those of the enclosing rocks and some characteristics similar to the mole granite the ore fluid had chemical components derived from the parental granite and components acquired by passage through the metamorphosed aureole

mismatch of glacier extent and summer insolation in southern hemisphere mid latitudes here we address a long standing puzzle of ice age climate called the fly in the ointment of the milankovitch theory using geomorphic mapping and 10be surface exposure dating we show that five moraine belts were formed during maxima of the last ice age by the pukaki glacier in new zealand s southern alps they afford ages of 41 76 1 09 ka 35 50 1 26 ka 27 17 0 68 ka 20 27 0 60 ka and 18 29 0 49 ka these five maxima spanned an entire precessional cycle in summer insolation intensity at the latitude of the southern alps a similar mismatch between summer insolation and glacier extent also characterized the chilean lake district in the mid latitudes of south america thus in apparent contrast to northern ice sheets linked by milankovitch to summer insolation at 65 n latitude the behavior of southern mid latitude glaciers was not tied to local summer insolation intensity instead glacier extent between 41 76 ka and 18 29 ka as well as during the last termination was aligned with southern ocean surface temperature and with atmospheric carbon dioxide

near synchronous interhemispheric termination of the last glacial maximum in mid latitudes isotopic records from polar ice cores imply globally asynchronous warming at the end of the last glaciation however 10be exposure dates show that large scale retreat of mid latitude last glacial maximum glaciers commenced at about the same time in both hemispheres the timing of retreat is consistent with the onset of temperature and atmospheric co2 increases in antarctic ice cores we suggest that a global trend of rising summer temperatures at the end of the last glacial maximum was obscured in north atlantic regions by hypercold winters associated with unusually extensive winter sea ice

magnetic mean field modelling of solid solutions theoretical foundations and application to the hematite ilmenite system k fabian 1 v p shcherbakov 2 3 s a mcenroe 4 p robinson1 and b p burton5 1geological survey of norway n 7491 trondheim norway e mail karl fabian ngu no 2geophysical observatory borok of russian academy of sciences borok yaroslvaskaya oblast 152742 russia 3institute of geology and petroleum technologies kazan volga region federal university russia 4norwegian university of science and technology n 7491 trondheim norway 5nist 100 bureau drive gaithersburg md 20878 usa

reconstructing climate from glaciers glaciers offer the potential to reconstruct past climate over timescales from decades to millennia they are found on nearly every continent and at the last glacial maximum glaciers were larger in all regions on earth the physics of glacier climate interaction are relatively well understood and glacier models can be used to reconstruct past climate from geological evidence of past glacier extent this can lead to significant insights regarding past present and future climate for example glacier modeling has demonstrated that the near ubiquitous global pattern of glacier retreat during the last few centuries resulted from a global scale climate warming of 1 c consistent with instrumental data and climate proxy records climate reconstructions from glaciers have also demonstrated that the tropics were colder at the last glacial maximum than was originally inferred from sea surface temperature reconstructions future efforts to reconstruct climate from glaciers may provide new constraints on climat

the last glacial termination a major puzzle of paleoclimatology is why after a long interval of cooling climate each late quaternary ice age ended with a relatively short warming leg called a termination we here offer a comprehensive hypothesis of how earth emerged from the last global ice age a prerequisite was the growth of very large northern hemisphere ice sheets whose subsequent collapse created stadial conditions that disrupted global patterns of ocean and atmospheric circulation the southern hemisphere westerlies shifted poleward during each northern stadial producing pulses of ocean upwelling and warming that together accounted for much of the termination in the southern ocean and antarctica rising atmospheric co2 during southern upwelling pulses augmented warming during the last termination in both polar hemispheres

environmental processes of the ice age land oceans glaciers epilog knowledge of the state of the earth at the last glacial maximum lgm an interval around 21 000 years ago is an important benchmark for understanding the sensitivity of global environmental systems to change much progress in understanding climates of the lgm has occurred in the 20 years since the end of the climap project of the 1970s climate long range investigation mapping and prediction here we review this progress based on presentations and discussion at a rst open science meeting of the epilog project environmental processes of the ice age land oceans glaciers held in delmenhorst germany may 1999 we outline key controversies and document protocols for epilog contributions so that a new synthesis of the lgm earth can emerge as an open project of the world s community of scientists 2001 elsevier science ltd all rights reserved

temperature change is the major driver of late glacial and holocene glacier fluctuations in new zealand advance and retreat of temperate glaciers is largely controlled by changes in temperature and precipitation but the relative importance of these drivers is debated numerical modeling of a new zealand glacier reveals that temperature is the dominant control on glacier length we find that a glacial advance dated to ca 13 000 yr b p requires a cooling event of 3 4 c this mid latitude southern hemisphere cooling is similar in magnitude to the antarctic cold reversal in the vostok ice core record and likely to be a response to the same climate signal

the anatomy of long term warming since 15 ka in new zealand based on net glacier snowline rise the timing and magnitude of postglacial climatic changes around the globe provide insights into the underlying drivers of natural climate change using geomorphologic mapping of moraines 10 be surface exposure dating snowline reconstructions and numerical modeling we quantified glacier behavior during late glacial 15 11 5 ka and holocene the past 11 5 k y time in the ben ohau range new zealand glaciers were more extensive during the antarctic cold reversal acr than subsequently and the margins underwent a punctuated net withdrawal over the holocene numerical modeling experiments that achieve the best fit to the moraines suggest that air temperature during the acr was between 1 8 c and 2 6 c cooler than today with similar 20 prescribed precipitation after the acr a net snowline rise of 100 m through the younger dryas stadial 12 9 11 7 ka was succeeded by a further long term or net rise of 100 m between 11 k y and 500 yr ago glacier snowline records in new zealand show generally coherent late glacial and holocene climate trends however the paleoclimate record in the southwest pacific region shows important differences from that in the northern hemisphere

last glacial maximum climate in new zealand inferred from a modelled southern alps icefield abstract we present a simulation of the new zealand southern alps icefield at the last glacial maximum lgm c 30 000 20 000 calendar years ago ka in an attempt to constrain the climate of that period we use a 500 m resolution ice sheet model parameterised using empirical glaciological climatological and geological data specific to the model domain to simulate the entire southern alps icefield we find that an lgm cooling of at least 6 6 5 c is necessary to bring about valley glaciers that extend beyond the mountains however climate topography thresholds related to the elevation and hypsometry of individual catchments control the gradient of the rate of glacier expansion in the domain and in order to remain within geologically reconstructed lgm limits we find that the lgm cooling was most likely associated with a precipitation regime up to 25 drier than today wetter than present scenarios give rise to equilibrium line depressions and ice extents that are incompatible with empirical evidence these results perhaps indicate that either the westerly air masses affecting new zealand during the lgm were drier than today or that they were weaker or zonally displaced with respect to present

late cretaceous granitic magmatism and sn mineralization in the giant yinyan porphyry tin deposit south china constraints from zircon and cassiterite u pb and molybdenite re os geochronology the yinyan porphyry tin deposit in western guangdong is spatially associated with quartz porphyry and granite porphyry la icp ms zircon u pb dating defined an emplacement age of 78 5 0 4 ma for the quartz porphyry and 79 2 0 9 ma for the granite porphyry la icp ms cassiterite u pb dating yielded tera wasserburg lower intercept ages of 78 5 0 6 78 6 1 2 and 78 2 0 7 ma for cassiterite from a cassiterite sulfide vein cassiterite sulfide ore and a cassiterite topaz quartz stringer respectively re os dating of molybdenite from seven different veins yielded an isochron age of 77 0 0 5 ma all these new age data are indistinguishable within analytical uncertainty and therefore indicate a genetic relationship between the sn mineralization and the porphyry magmatism in the yinyan deposit the ree tetrad effect and very low nb ta and zr hf ratios indicate that the quartz porphyry and the granite porphyry are highly evolved the u pb dated cassiterite is enriched in fe w and u and in high field strength elements hfses such as zr hf nb and ta the high fe nb and ta contents may be responsible for the dark luminescence of cassiterite in cl images the zr hf ratio of cassiterite may potentially be used to distinguish the mineralization type cassiterite from pegmatites has lower zr hf ratios 5 6 in comparison with granite greisen related 9 30 cassiterite cassiterite from the early hydrothermal stage typically contains higher amounts of ti nb ta zr and hf than that from the late hydrothermal stage in combination with published geochronological data of other sn w deposits in the western guangdong province two sn w metallogenic events at ca 85 and 77 80 ma have been identified these two metallogenic events are part of a larger scale 75 100 ma sn w mineralization event in south china which we suggest was probably related to the subduction of the neo tethyan oceanic plate

re os ages for archean molybdenite and pyrite kuittila kivisuo finland and proterozoic molybdenite kabeliai lithuania testing the chronometer in a metamorphic and metasomatic setting seven 187re 187os ages were determined for molybdenite and pyrite samples from two well dated precambrian intrusions in fennoscandia to examine the sustainability of the re os chronometer in a metamorphic and metasomatic setting using a new 187re decay constant 1 666 10 11y 1 with a much improved uncertainty 0 31 we determined replicate re os ages for molybdenite and pyrite from the kuittila and kivisuo prospects in easternmost finland and for molybdenite from the kabeliai prospect in southernmost lithuania these two localities contain some of the oldest and youngest plutonic activity in fennoscandia and are associated with newly discovered economic au mineralization ilomantsi finland and a cu mo prospect kabeliai lithuania two re os ages for vein hosted kabeliai molybdenite average 1486 5 ma in excellent agreement with a 1505 11 ma u pb zircon age for the hosting kabeliai granite pluton the slightly younger age suggests the introduction of cu mo mineralization by a later phase of the kabeliai magmatic system mean re os ages of 2778 8 ma and 2781 8 ma for kuittila and kivisuo molybdenites respectively are in reasonable agreement with a 2753 5 ma weighted mean u pb zircon age for hosting kuittila tonalite these re os ages agree well with less precise ages of 2789 290 ma for a rb sr whole rock isochron and 2771 75 ma for the average of six sm nd tdm model ages for kuittila tonalite three re os analyses of a single pyrite mineral separate from the same sample of kuittila pluton that yielded a molybdenite separate provide individual model ages of 2710 27 2777 28 and 2830 28 ma re 17 4 12 1 and 8 4 ppb respectively with a mean value of 2770 120 ma in agreement with the kuittila molybdenite age the re and 187os abundances in these three pyrite splits are highly correlated r 0 9994 and provide a 187re 187os isochron age of 2607 47 ma with an intercept of 21 ppt 187os mswd 1 1 it appears that the re os isotopic system in pyrite has been reset on the millimeter scale and that the 21 ppt 187os intercept reflects the in situ decay of 187re during the 160 to 170 m y interval from 2778 ma time of molybdenite pyrite deposition to 2607 ma time of pyrite resetting when the re os data for molybdenites from the nearby kivisuo prospect are plotted together with the kuittila molybdenite and pyrite data a well constrained five point isochron with an age of 2780 8 ma and a 187os intercept 2 4 3 8 ppt of essentially zero results mswd 1 5 we suggest that the pyrite isochron age records a regional metamorphic and or hydrothermal event possibly the time of au mineralization a proposed re os age of 2607 ma for au mineralization is in good agreement with radiometric ages by other methods that address the timing of archean au mineralization in deposits worldwide so called late au model molybdenite in contrast provides a robust re os chronometer retaining its original formation age of 2780 ma despite subsequent metamorphic disturbances in archean and proterozoic time

the lanthanide tetrad effect and its correlation with k rb eu eu sr eu y ho and zr hf of evolving peraluminous granite suites lanthanide tetrad effects are often observed in ree patterns of more highly evolved variscan peraluminous granites of mid eastern germany central erzgebirge western erzgebirge fichtelgebirge and northern oberpfalz the degree of the tetrad effect te1 3 is estimated and plotted vs k rb sr eu eu eu y ho and zr hf the diagrams reveal that the tetrad effect develops parallel to granite evolution and significant tetrad effects are strictly confined to highly differentiated samples mineral fractionation as a cause for the tetrad effect is not supported by a calculated rayleigh fractionation which also could not explain the fractionation trends of sr eu and eu eu the strong decrease of eu concentrations in highly evolved rocks suggests that eu fractionates between the residual melt and a coexisting aqueous high temperature fluid mineral fractionation as a reason for the tetrad effect is even more unlikely as ree patterns of accessory minerals display similar tetrad effects as the respective host rocks the accessory minerals inherit the ree signature of the melt and do not contribute to the bulk rock tetrad effect via mineral fractionation these results point in summary to significant changes of element fractionation behavior in highly evolved granitic melts ionic radius and charge which commonly control the element distribution between mineral and melt are no longer the exclusive control the tetrad effect and the highly fractionated trace element ratios of y ho and zr hf indicate a trace element behavior that is similar to that in aqueous systems in which chemical complexation is of significant influence this distinct trace element behavior and the common features of magmatic hydrothermal alteration suggest the increasing importance of an aqueous like fluid system during the final stages of granite crystallization the positive correlation of te1 3 with bulk rock fluorine contents hints at the importance of ree fluorine complexation in generating the tetrad effect as the evolution of a ree pattern with tetrad effect m type implies the removal of a respective mirroring ree pattern w type the tetrad effect identifies open system conditions during granite crystallization

a 10be chronology of lateglacial and holocene mountain glaciation in the scoresby sund region east greenland implications for seasonality during lateglacial time abstract thirty eight new cosmogenic 10 be exposure ages from the scoresby sund region of east greenland indicate that prominent moraine sets deposited by mountain glaciers date from 780 to 310 yr approximately during the little ice age from 11 660 to 10 630 yr at the end of the younger dryas cold interval or during preboreal time and from 13 010 to 11 630 yr during lateglacial time equilibrium line altitudes elas interpreted from lateglacial to early holocene moraines indicate summertime cooling between 3 9 and 6 6 c relative to today s value much less than the extreme younger dryas cooling registered by greenland ice cores mean annual temperatures of 15 c colder than today s value this apparent discrepancy between paleotemperature records supports the contention that younger dryas cooling was primarily a wintertime phenomenon 10 be ages of lateglacial and holocene moraines show that mountain glaciers during the little ice age were more extensive than at any other time since the early holocene epoch in addition 10 be ages of lateglacial moraines show extensive reworking of boulders with cosmogenic nuclides inherited from prior periods of exposure consistent with our geomorphic observations and cosmogenic exposure dating studies in other arctic regions

probability of moraine survival in a succession of glacial advances emplacement of glacial moraines normally results in obliteration of any older moraines deposited by less extensive glacial advances a process we call obliterative overlap a probability analysis of the likely impact of obliterative overlap on the completeness of the glacial record assumes that moraines were deposited at various distances from their glacial source areas randomly over time assuming randomness and obliterative overlap after 10 glacial episodes the most likely number of surviving moraines is only three the record of the pleistocene is in agreement with the probability analysis the 10 glaciations during the past 0 9 m y inferred from the deep sea record resulted in moraine sequences in which only two or three different aged moraine belts can generally be distinguished

cassiterite potential for direct dating of mineral deposits and a precise age for the bushveld complex granites u pb and pb isotopic measurements of cassiterite from the 200 ma tin deposits of belitung indonesia and 2100 ma zaaiplaats deposit in south africa demonstrate that cassiterite can be used to directly date mineral deposits rather than associated minerals such as zircon and rutile a precise u pb age of 2099 3 ma has been determined for cassiterites hosted in granites from the bushveld complex on conventional 207 pb 204 pb 206 pb 204 pb plots the data for the indonesian deposits give an age apparently older than that obtained from u pb plots perhaps indicative of inheritance of pb from an older source

warming and glacier recession in the rakaia valley southern alps of new zealand during heinrich stadial 1 abstract the termination of the last ice age featured a major reconfiguration of earth s climate and cryosphere yet the underlying causes of these massive changes continue to be debated documenting the spatial and temporal variations of atmospheric temperature during deglaciation can help discriminate among potential drivers here we present a 10be surface exposure chronology and glaciological reconstruction of ice recession following the last glacial maximum lgm in the rakaia valley southern alps of new zealand innermost lgm moraines at big ben have an age of 17 840 240 yrs whereas ice marginal moraines or ice molded bedrock surfaces at distances up valley from big ben of 12 5 km lake coleridge 25 km castle hill 28 km double hill 43 km prospect hill and 58 km reischek knob have ages of 17 020 70 yrs 17 100 110 yrs 16 960 370 yrs 16 250 340 yrs and 15 660 160 yrs respectively these results indicate extensive recession of the rakaia glacier which we attribute primarily to the effects of climatic warming in conjunction with geomorphological maps and a glaciological reconstruction for the rakaia valley we use our chronology to infer timing and magnitude of past atmospheric temperature changes compared to an overall temperature rise of 4 65 c between the end of the lgm and the start of the holocene the glacier recession between 17 840 and 15 660 yrs ago is attributable to a net temperature increase of 4 0 c from 6 25 to 2 25 c accounting for 86 of the overall warming approximately 3 75 c 70 of the warming occurred between 17 840 and 16 250 yrs ago with a further 0 75 c 16 increase between 16 250 and 15 660 yrs ago a sustained southward shift of the subtropical front stf south of australia between 17 800 and 16 000 yrs ago coincides with the warming over the rakaia valley and suggests a close link between southern ocean frontal boundary positions and southern mid latitude climate most of the deglacial warming in the southern alps occurred during the early part of heinrich stadial 1 hs1 of the north atlantic region because the stf is associated with the position of the westerly wind belt our findings support the concept that a southward shift of earth s wind belts accompanied the early part of hs1 cooling in the north atlantic leading to warming and deglaciation in southern middle latitudes

the southern glacial maximum 65 000 years ago and its unfinished termination abstract glacial maxima and their terminations provide key insights into inter hemispheric climate dynamics and the coupling of atmosphere surface and deep ocean hydrology and cryosphere which is fundamental for evaluating the robustness of earth s climate in view of ongoing climate change the last glacial maximum lgm 26 19 ka ago is widely seen as the global cold peak during the last glacial cycle and its transition to the holocene interglacial dubbed termination 1 t1 as the most dramatic climate reorganization during this interval climate records show that over the last 800 ka ice ages peaked and terminated on average every 100 ka 100 ka world however the mechanisms pacing glacial interglacial transitions remain controversial and in particular the hemispheric manifestations and underlying orbital to regional driving forces of glacial maxima and subsequent terminations remain poorly understood here we show evidence for a full glacial maximum in the southern hemisphere 65 1 2 7 ka ago and its unfinished termination our 10 be chronology combined with a model simulation demonstrates that new zealand s glaciers reached their maximum position of the last glacial cycle during marine isotope stage 4 mis 4 southern ocean and greenhouse gas records indicate coeval peak glacial conditions making the case for the southern glacial maximum about halfway through the last glacial cycle and only 15 ka after the last warm period mis 5a we present the hypothesis that subsequently driven by boreal summer insolation forcing a termination began but remained unfinished possibly because the northern ice sheets were only moderately large and could not supply enough meltwater to the north atlantic through heinrich stadial 6 to drive a full termination yet the unfinished termination left behind substantial ice on the northern continents about 50 of the full lgm ice volume and after another 45 ka of cooling and ice sheet growth the earth was at inter hemispheric last glacial maximum configuration when similar orbital forcing hit maximum size northern ice sheets and ushered in t1 and thus the ongoing interglacial this argument highlights the critical role of full glacial conditions in both hemispheres for terminations and implies that the southern hemisphere climate could transition from interglacial to full glacial conditions in about 15 000 years while the northern hemisphere and its continental ice sheets required half a glacial cycle

millennial scale pulsebeat of glaciation in the southern alps of new zealand abstract we undertook geomorphological mapping in conjunction with 10be surface exposure dating in a previously unstudied sector of the left lateral moraine sequence of the ice age pukaki glacier in the southern alps of new zealand the mapping and dating approach enabled the identification of six distinct moraine belts that were formed during maxima of glacier extent during the last glaciation the chronology implies that ice recession occurred during northern hemisphere heinrich stadials while expansion occurred between heinrich stadials the ages of the moraine belts identified here are 44 000 1000 yrs 41 800 1100 yrs 36 450 940 yrs 26 730 740 yrs 20 030 460 yrs and 18 000 400 yrs this moraine chronology is consistent with previous dating results from other sectors of the pukaki moraine sequence except that the c 44 000 yr old moraine belt has not previously been detected elsewhere in the pukaki moraines collectively with previously published 10be chronologies from the pukaki glacier and the adjacent ohau glacier valley the results demonstrate that there were several millennial scale episodes of ice advance to full glacial extent and subsequent ice recession during marine isotope stages 3 and 2 this millennial scale pulsebeat of oscillations of the pukaki and ohau glaciers in sympathy with the north atlantic heinrich episodes is further emphasized by rapid ice recession in the southern alps early in the last glacial termination coeval with the onset of heinrich stadial 1 hs 1 in the northern hemisphere that this pattern is widespread in mid latitudes of the southern hemisphere is highlighted by similar chronologies of glacier variation for andean ice lobes in the chilean lake district of south america

multiple glacial maxima of similar extent at 20 45 ka on mt usborne east falkland south atlantic region abstract the pattern timing and origin of southern hemisphere climate change during the last glaciation remains a pressing problem with implications for the role of orbital forcing in ice age cycles here we present geomorphological and cosmogenic exposure age data from east falkland in the south atlantic region that show onset of glacial conditions by marine isotope stage 4 60 70 ka with expansion of ice to its maximum extent of the last glaciation at least seven geomorphological units marked by multiple crests on composite moraines indicate glacier expansion on mt usborne the highest peak of east falkland from 20 to 45 ka glaciers fluctuated on a millennial timescale with near maximum conditions being reached repeatedly overall ice extent appears to have shrunk slightly through time with evidence of glaciation at 20 ka preserved only in the highest elevation cirques this long glacial maximum is inconsistent both with local orbital control and orbital forcing as expressed in the traditional milankovitch hypothesis the timing of millennial glacier expansions occurred between northern hemisphere heinrich stadials and resembles that documented for new zealand glaciers suggesting at least a trans pacific expression we postulate that periodic recessions corresponded with southward expansion of the southern westerlies during heinrich stadials and warming air and ocean temperatures over the south atlantic region

high precision 10be chronology of moraines in the southern alps indicates synchronous cooling in antarctica and new zealand 42 000 years ago millennial scale temperature variations in antarctica during the period 80 000 to 18 000 years ago are known to anti correlate broadly with winter centric cold warm episodes revealed in greenland ice cores however the extent to which climate fluctuations in the southern hemisphere beat in time with antarctica rather than with the northern hemisphere has proved a controversial question in this study we determine the ages of a prominent sequence of glacial moraines in new zealand and use the results to assess the phasing of millennial climate change forty four 10be cosmogenic surface exposure ages of boulders deposited by the pukaki glacier in the southern alps document four moraine building events from marine isotope stage 3 mis 3 through to the end of the last glacial maximum 18 000 years ago lgm the earliest moraine building event is defined by the ages of nine boulders on a belt of moraine that documents the culmination of a glacier advance 42 000 years ago at the pukaki locality this advance was of comparable scale to subsequent advances that from the remaining exposure ages occurred between 28 000 and 25 000 at 21 000 and at 18 000 years ago collectively all four moraine building events represent the lgm the glacier advance 42 000 years ago in the southern alps coincides in antarctica with a cold episode shown by the isotopic record from the epica dome c ice core between the prominent a1 and a2 warming events therefore the implication of the pukaki glacier record is that as early as 42 000 years ago an episode of glacial cold similar to that of the lgm extended in the atmosphere from high on the east antarctic plateau to at least as far north as the southern alps 44 s such a cold episode is thought to reflect the translation through the atmosphere and or the ocean of the anti phased effects of northern hemisphere interstadial conditions to the southern half of the southern hemisphere regardless of the mechanism any explanation for the cold episode at 42 000 years ago must account for its widespread atmospheric footprint not only in antarctica but also within the westerly wind belt in southern mid latitudes

a high resolution absolute dated late pleistocene monsoon record from hulu cave china oxygen isotope records of five stalagmites from hulu cave near nanjing bear a remarkable resemblance to oxygen isotope records from greenland ice cores suggesting that east asian monsoon intensity changed in concert with greenland temperature between 11 000 and 75 000 years before the present yr b p between 11 000 and 30 000 yr b p the timing of changes in the monsoon as established with 230th dates generally agrees with the timing of temperature changes from the greenland ice sheet project two gisp2 core which supports gisp2 s chronology in this interval our record links north atlantic climate with the meridional transport of heat and moisture from the warmest part of the ocean where the summer east asian monsoon originates

climate sensitivity of a high precipitation glacier in new zealand the sensitivity of glaciers to climatic change is key information in assessing the response and sea level implications of projected future warming new zealand glaciers are important globally as an example of how maritime glaciers will contribute to sea level rise a spatially distributed energy balance model is applied to brewster glacier new zealand in order to calculate glacier mass balance run off and sensitivity to climate change the model successfully simulates four annual mass balance cycles close to half 52 of the energy available for melt on the glacier is supplied by turbulent heat fluxes with radiation less important except during the winter model sensitivity to temperature change is one of the largest reported on earth at 2 0 m w e a 1 8c 1 in contrast a 50 change in precipitation is required to offset the mass balance change resulting from a 18c temperature change meltwater run off sensitivity is also very high increasing 60 with a 18c warming the extreme sensitivity of mass balance to temperature change suggests that significant ice loss will occur with even moderate climate warming

glacier retreat in new zealand during the younger dryas stadial the younger dryas a period of sudden cooling in the northern hemisphere about 12 900 years ago is perhaps the best known example of abrupt climate change but the global extent of the younger dryas is a topic of intense debate particularly in the record of glacial behaviour in new zealand a new reconstruction of the growth and retreat patterns of glaciers in the southern alps in new zealand at the time of the younger dryas supports the suggestion that temperature reductions in the north caused warming and glacial retreat in the southern hemisphere through a series of climate feedbacks the younger dryas during which northern hemisphere temperatures cooled drastically in just a few years is perhaps the best known example of abrupt climate change but its global extent is under debate particularly in the record of glacial behaviour in new zealand these authors present evidence for glacial retreat in new zealand during the younger dryas supporting the hypothesis that northern hemisphere climate changes caused southern hemisphere warming through a series of climate feedbacks millennial scale cold reversals in the high latitudes of both hemispheres interrupted the last transition from full glacial to interglacial climate conditions the presence of the younger dryas stadial 12 9 to 11 7 kyr ago is established throughout much of the northern hemisphere but the global timing nature and extent of the event are not well established evidence in mid to low latitudes of the southern hemisphere in particular has remained perplexing1 2 3 4 5 6 the debate has in part focused on the behaviour of mountain glaciers in new zealand where previous research has found equivocal evidence for the precise timing of increased or reduced ice extent1 2 3 the interhemispheric behaviour of the climate system during the younger dryas thus remains an open question fundamentally limiting our ability to formulate realistic models of global climate dynamics for this time period here we show that new zealand s glaciers retreated after 13 kyr bp at the onset of the younger dryas and in general over the subsequent 1 5 kyr period our evidence is based on detailed landform mapping a high precision 10be chronology7 and reconstruction of former ice extents and snow lines from well preserved cirque moraines our late glacial glacier chronology matches climatic trends in antarctica southern ocean behaviour and variations in atmospheric co2 the evidence points to a distinct warming of the southern mid latitude atmosphere during the younger dryas and a close coupling between new zealand s cryosphere and southern high latitude climate these findings support the hypothesis that extensive winter sea ice and curtailed meridional ocean overturning in the north atlantic led to a strong interhemispheric thermal gradient8 during late glacial times in turn leading to increased upwelling and co2 release from the southern ocean9 thereby triggering southern hemisphere warming during the northern younger dryas

scaling time integrated in situ cosmogenic nuclide production rates using a continuous geomagnetic model abstract spatial and temporal variations in earth s magnetic field affect the corresponding time integrated distribution of in situ cosmogenic nuclide cn production rates these effects can be quantified by the effective vertical cutoff rigidity r c a measure of the energy required for primary cosmic rays to penetrate the geomagnetic field and interact with the atmosphere at a given location recent cn production rate scaling models are based on atmospheric cosmic ray measurements parameterized using r c estimates derived from detailed modern geomagnetic field representations which include both dipole and non dipole field contributions however published methods for quantifying time integrated geomagnetic effects on cn production rate scaling rely on various geocentric dipolar approximations to r c driven by separate records of paleomagnetic pole position and paleointensity therefore applying dipolar paleomagnetic records spanning millennial time scales which explicitly ignore past non dipole effects to scaling models derived using modern geomagnetic field representations may lead to systematic errors in any calculated results a recently published continuous geomagnetic model covering the last 7 kyr cals7k 2 m korte and c g constable continuous geomagnetic field models for the past 7 millennia 2 cals7k 2005 geochem geophys geosyst 6 q02h16 doi 10 1029 2004gc000801 may allow reduction of such errors by bridging the gap between detailed modern geomagnetic and simplified paleomagnetic models we have developed a new model framework describing temporal and spatial variation in r c for 0 7 ka and earlier based on cals7k 2 which explicitly accounts for non dipole field effects while attempting to mitigate systematic scaling biases scaling factors derived using the new r c framework predict significant longitudinal variability in time integrated cn production while predictions using dipolar geomagnetic approximations do not one can test these predictions using in situ cosmogenic 14 c in situ 14 c in quartz due to its short half life 5 73 kyr 14 c attains secular equilibrium between production and decay after approximately 25 kyr of exposure at which point its measured concentration is only a function of its integrated average production rate initial in situ 14 c results from samples at secular equilibrium from 38 n and 3 5 km in tibet and eastern california are consistent with the longitudinal variability predicted by the new framework

interactions between deformation and fluids in the frontal thrust region of the nantroseize transect offshore the kii peninsula japan results from iodp expedition 316 sites c0006 and c0007 integrated ocean drilling program iodp expedition 316 sites c0006 and c0007 examined the deformation front of the nankai accretionary prism offshore the kii peninsula japan in the drilling area the frontal thrust shows unusual behavior as compared to other regions of the nankai trough drilling results integrated with observations from seismic reflection profiles suggest that the frontal thrust has been active since 0 78 0 436 ma and accommodated 13 to 34 of the estimated plate convergence during that time the remainder has likely been distributed among out of sequence thrusts further landward and or accommodated through diffuse shortening unlike results of previous drilling on the nankai margin porosity data provide no indication of undercompaction beneath thrust faults furthermore pore water geochemistry data lack clear indicators of fluid flow from depth these differences may be related to coarser material with higher permeability or more complex patterns of faulting that could potentially provide more avenues for fluid escape in turn fluid pressures may affect deformation well drained sand rich material under the frontal thrust could have increased fault strength and helped to maintain a large taper angle near the toe recent resumption of normal frontal imbrication is inferred from seismic reflection data associated decollement propagation into weaker sediments at depth may help explain evidence for recent slope failures within the frontal thrust region this evidence consists of seafloor bathymetry normal faults documented in cores and low porosities in near surface sediments that suggest removal of overlying material overall results provide insight into the complex interactions between incoming materials deformation and fluids in the frontal thrust region

radiocarbon chronology of the last glacial maximum and its termination in northwestern patagonia abstract we examine the timing and magnitude of the last glacial maximum lgm and the last glacial termination lgt in northwestern patagonia situated in the middle latitudes of south america our data indicate that the main phase of the lgt began with abrupt warm pulses at 17 800 and 17 100 cal yrs bp accompanied by rapid establishment of evergreen temperate rainforests and extensive deglaciation of the andes within 1000 years this response shows that south american middle latitude temperatures had approached average interglacial values by 16 800 cal yrs bp the temperature rise in northwestern patagonia coincides with the beginning of major warming and glacier recession in the southern alps of new zealand at southern mid latitudes on the opposite side of the pacific ocean from this correspondence the warming that began at 17 800 cal yrs bp appears to have been widespread in middle latitudes of the southern hemisphere accounting for at least 75 of the total temperature recovery from the lgm to the holocene moreover this warming pulse is coeval with the first half of the heinrich stadial 1 hs1 in the north atlantic region hs1 featured a decline of north atlantic meridional overturning circulation a southward shift of the westerly wind belt in both hemispheres and of the intertropical convergence zone as well as a weakening of the asian monsoon along with the initiating trigger identifying the mechanisms whereby these opposing climate signals in the two polar hemispheres interacted whether through an oceanic or an atmospheric bipolar seesaw or both lies at the heart of understanding the lgt

the role of collisional tectonics in the metallogeny of the central andean tin belt abstract the inner arc of the central andes broadly corresponding to the eastern cordillera is the location of a rich tertiary and triassic sn w ag base metal metallogenic province commonly referred to as the bolivian tin belt we propose that the tertiary metallogeny which generated most of the tin ores was a direct consequence of discrete collisions between the south american plate and the nazca slab and sub slab mantle during the ongoing andean orogeny evidence supporting this proposal include 1 the coincidence of the tin province and the inner arc in a marked hump in the andean orogen which may represent tectonic indentation 2 the symmetry of the tin province with respect to the bolivian orocline the axis of which corresponds to the direction of highest compression 3 the relative symmetry of the magmatism and tin mineralization with respect to this axis 4 the concurrent timing of mineralization and compressional pulses 5 the similar host rock geochemistry and ore lead isotope data testifying to a common crustal reservoir and 6 the striking similarity of the igneous suites associated with the ore deposits to those from typical collisional orogens a number of studies have called upon a persistent tin anomaly to explain the metallogeny of the region we propose instead that the latter is better explained by periodic compressional interaction between the farallon nazca oceanic plate and the south american continent this led to the generation of peraluminous magmas which during fractional crystallization exsolved the fluids responsible for the voluminous sn w mineralization

nature and origin of lamellar magnetism in the hematite ilmenite series grains consisting of finely exsolved members of the hematite ilmenite solid solution series such as are present in some slowly cooled middle proterozoic igneous and metamorphic rocks impart unusually strong and stable remanent magnetization tem analysis shows multiple generations of ilmenite and hematite exsolution lamellae with lamellar widths ranging from millimeters to nanometers rock magnetic experiments suggest remanence is thermally locked to the antiferromagnetism of the hematite component of the intergrowths yet is stronger than can be explained by canted antiferromagnetic caf hematite or coexisting paramagnetic pm fe ti ordered r 3 ilmenite alone in alternating field demagnetization to 100 mt many samples lose little remanence indicating that the nrm is stable over billions of years this feature has implications for understanding magnetism of deep rocks on earth or on planets like mars that no longer have a magnetic field atomic scale simulations of an r 3 ilmenite lamella in a caf hematite host based on empirical cation cation and spin spin pair interaction parameters show that contacts of the lamella are occupied by contact layers with a hybrid composition of fe ions intermediate between fe2 rich layers in ilmenite and fe3 rich layers in hematite structural configurations dictate that each lamella has two contact layers magnetically in phase with each other and out of phase with the magnetic moment of an odd non self canceling fe3 rich layer in the hematite host the two contact layers and the odd hematite layer form a magnetic substructure with opposite but unequal magnetic moments a lamellar ferrimagnetism made possible by the exsolution because it is confined to magnetic interaction involving the moments of just three ionic layers associated with each individual exsolution lamella lamellar magnetism is unique and quite distinct from conventional ferrimagnetism simulation cells indicate that the magnetic moments of contact layers are locked to the magnetic moments of adjacent af hematite layers and are parallel to the basal plane 001 thus lamellar magnetism is created at the temperature of chemical exsolution and is a chemical remanent rather than thermal remanent magnetization however in thermal demagnetization experiments too short for lamellar resorption demagnetization temperatures are those of the caf hematite considerably higher than temperatures of original lamellae formation internal crystal structure cannot dictate that the contact layers of different lamellae will form magnetically in phase with each other to give the highest net magnetic moment but magnetic moments of lamellae can be made to form in phase by the external force of the magnetizing field at the time of exsolution a thesis of this paper is that an external magnetic field can dictate the magnetic moments and hence the chemical location of ilmenite lamellae in a hematite host and that once in place neither the location nor the magnetic moment will be easily disturbed in an ilmenite host the external magnetic field cannot control the chemical location of a hematite lamella which is dictated by the enclosing ilmenite but once lamellae have formed the field can dictate their magnetic moments these moments however are not locked chemically to the host resulting in lower coercivity the effectiveness of the external force in single crystals is dictated by their orientation with respect to the magnetizing field in grains with 001 oriented parallel to the field it would be effective in producing in phase magnetic moments and very strong remanence in grains with 001 normal to the field the field would be less effective in producing in phase magnetic moments hence producing weak remanence the most intense lamellar magnetism per formula unit occurs with in phase magnetization high lamellar yields and the largest number of lamellae per unit volume i e smallest lamellar size compared to the magnetic moment per formula unit m pfu and magnetic moment per unit volume m v of end member magnetite m pfu 4 b m v 480 ka m and hematite m pfu 0 0115 b m v 2 1 ka m results for some atomic models reasonably tied to natural conditions are m pfu 0 46 1 36 b and m v 84 250 ka m

a beryllium 10 chronology of late glacial moraines in the upper rakaia valley southern alps new zealand supports southern hemisphere warming during the younger dryas interhemispheric differences in the timing of pauses or reversals in the temperature rise at the end of the last ice age can help to clarify the mechanisms that influence glacial terminations our beryllium 10 10be surface exposure chronology for the moraines of the upper rakaia valley of new zealand s southern alps combined with glaciological modeling show that late glacial temperature change in the atmosphere over the southern alps exhibited an antarctic like pattern during the antarctic cold reversal the upper rakaia glacier built two well defined closely spaced moraines on reischek knob at 13 900 120 1 310 yrs when including a 2 1 production rate pr uncertainty and 13 140 250 370 yrs ago in positions consistent with mean annual temperature approximately 2 c cooler than modern values the formation of distinct widely spaced moraines at 12 140 200 320 and 11 620 160 290 yrs ago on meins knob 2 km up valley from the reischek knob moraines indicates that the glacier thinned by 250 m during heinrich stadial 0 hs 0 coeval with the younger dryas 12 900 to 11 600 yrs ago the glacier inferred temperature rise in the upper rakaia valley during hs 0 was about 1 c because a similar pattern is documented by well dated glacial geomorphologic records from the andes of south america the implication is that this late glacial atmospheric climate signal extended from 79 s north to at least 36 s and thus was a major feature of southern hemisphere paleoclimate during the last glacial termination

glacier advance in southern middle latitudes during the antarctic cold reversal the geographic extent of cooling associated with the antarctic cold reversal is unclear dating of glacial moraines in new zealand suggests that the cooling extended into the southern mid latitudes possibly as a result of the northward migration of the southern subtropical front

multiple glacial advances in the rangitata valley south island new zealand imply roles for southern hemisphere westerlies and summer insolation in mis 3 glacial advances stratigraphic evidence and extensive optically stimulated luminescence osl geochronology from an 18 km long reach of the middle rangitata valley south island new zealand provide evidence for at least six distinct glacial advances during the last glacial cycle these include four well constrained marine oxygen isotope stage mis 3 and 2 advances at ca 38 ka ca 27 ka ca 21 ka and at 18 ka as well as less well constrained advances in mis 4 and or early mis 3 ice occupied a farther downvalley reach of the rangitata from 38 ka to after 18 ka indicating that near full glacial conditions persisted for most of the last 20 ka of the last glaciation though the glacier still fluctuated significantly as reflected by the numerous distinguishable advances global or regional cooling alone cannot explain the persistence of near maximum glacial conditions for this extended period nor can it explain the occurrence of the largest advances ca 32 ka instead we invoke the northward expansion of the westerlies during mis 3 as the cause for the early widespread glaciation wherein enhanced westerly flow under moderate cooling maximised glacial extents local insolation favoured extended mis 3 glaciation until ca 32 ka increasing summer insolation gradually reduced glacial extents after ca 28 ka