shallow marine carbon and oxygen isotope and elemental records indicate icehouse greenhouse cycles during the early jurassic 1 for much of the mesozoic record there has been an inconclusive debate on the possible global significance of isotopic proxies for environmental change and of sequence stratigraphic depositional sequences we present a carbon and oxygen isotope and elemental record for part of the early jurassic based on marine benthic and nektobenthic molluscs and brachiopods from the shallow marine succession of the cleveland basin uk the invertebrate isotope record is supplemented with carbon isotope data from fossil wood which samples atmospheric carbon new data elucidate two major global carbon isotope events a negative excursion of 2 at the sinemurian pliensbachian boundary and a positive excursion of 2 in the late pliensbachian the sinemurian pliensbachian boundary event is similar to the slightly younger toarcian oceanic anoxic event and is characterized by deposition of relatively deepwater organic rich shale the late pliensbachian strata by contrast are characterized by shallow marine deposition oxygen isotope data imply cooling locally for both events however because deeper water conditions characterize the sinemurian pliensbachian boundary in the cleveland basin the temperature drop is likely of local significance in contrast a cool late pliensbachian shallow seafloor agrees with previous inference of partial icehouse conditions both the large scale long term and small scale short duration isotopic cycles occurred in concert with relative sea level changes documented previously from sequence stratigraphy isotope events and the sea level cycles are concluded to reflect processes of global significance supporting the idea of an early jurassic in which cyclic swings from icehouse to greenhouse and super greenhouse conditions occurred at timescales from 1 to 10 ma

early jurassic late pliensbachian co2 concentrations based on stomatal analysis of fossil conifer leaves from eastern australia the stomatal index a measure of stomatal density of an extinct australian early jurassic araucariacean conifer species allocladus helgei jansson is used to reconstruct the atmospheric carbon dioxide concentration pco 2 in the early jurassic the fossil leaves are preserved in a single bed palynologically dated to late pliensbachian similar to 185 183 mya atmospheric pco 2 is estimated from the ratios between the stomatal index of a helgei and the stomatal indices of three modern analogs nearest living equivalent plants co2 concentration in the range of similar to 750 975 ppm was calibrated from the fossil material with a best estimated mean of similar to 900 ppm the new average pco 2 determined for the late pliensbachian is thus similar to although similar to 10 lower than previously inferred minimum concentrations of similar to 1000 based on data from the northern hemisphere but may help constrain pco 2 during this period our results are the first pco 2 estimates produced using jurassic leaves from the southern hemisphere and show that i paleo atmospheric pco 2 estimates are consistent at a global scale though more investigations of southern hemisphere material are required and ii the stomatal proxy method can now be used without the context of relative change in pco 2 when applying the correct methodology c 2014 the authors published by elsevier b v on behalf of international association for gondwana research less

opening of a trans pangaean marine corridor during the early jurassic insights from osmium isotopes across the sinemurian pliensbachian gssp robin hood s bay uk the hispanic corridor represents a significant phase of continental reorganisation of the early jurassic that eventually provided connectivity between the western tethyan and eastern pacific oceans along the central atlantic rift zone although the initiation of this marine corridor profoundly impacted oceanic circulation and marine faunal exchange patterns the timing of its formation hitherto remains poorly constrained with estimates spanning both the hettangian and sinemurian the sinemurian pliensbachian global stratotype section and point gssp at robin hood s bay uk comprises a succession of well exposed immature organic rich sediments only previously characterised by strontium oxygen and carbon isotope geochemistry new re and os isotope profiling indicates substantial variation in seawater chemistry at this time initial osmium isotope data become increasing unradiogenic 0 40 to 0 20 across the boundary providing evidence for a continual flux of unradiogenic os into the oceans during the latest sinemurian the initial unradiogenic 187os 188os values indicate the occurrence of low temperature hydrothermal activity associated with the formation of the hispanic corridor during the breakup of pangaea therefore combined with biogeography and faunal exchange patterns the os isotope data demonstrates that connectivity between the eastern pacific and tethyan oceans initiated during the latest sinemurian as a result this study better constrains the timing of establishment of the hispanic corridor which was previously limited to poorly defined biogeography

spatial variability of watermass conditions within the european epicontinental seaway during the early jurassic pliensbachian toarcian in order to constrain spatial variability in watermass conditions within the european epicontinental seaway prior to during and after the toarcian oceanic anoxic event carbon 13cbel 13ccarb and oxygen 18obel 18ocarb isotope records were obtained from three sections in the grands causses basin southern france these data were then compared with similar records along a north south transect across the european epicontinental seaway as the conclusions reached here strongly depend on the reliability of belemnite calcites as archives of palaeoceanographic changes an attempt was made to improve the understanding of isotope signals recorded in belemnite calcite intra rostral carbon and oxygen isotope data from six belemnite specimens belonging to the genus passaloteuthis were collected intra rostral carbon isotopes are influenced by vital effects whereas oxygen isotopes reflect relative changes in temperature and salinity palaeotemperatures calculated from 18obel isotope records from the grands causses basin confirm relatively low temperatures throughout the late pliensbachian similar cool water conditions have previously been shown in germany england spain and portugal a temperature increase of up to 6 c is observed across the pliensbachian toarcian boundary a pronounced negative shift of at least 3 vienna pee dee belemnite is recorded in bulk carbonate carbon during the lower harpoceras serpentinum zone typical of the toarcian oceanic anoxic event before and after the toarcian oceanic anoxic event a good correlation between 13ccarb and 13cbel exists indicating well ventilated bottom waters and normal marine conditions instead data for the toarcian oceanic anoxic event indicate the development of a strong north south gradient in salinity stratification and surface water productivity for the western tethyan realm this study thus lends further support to a pronounced regional overprint on carbon and oxygen isotope records in epicontinental seaways

toarcian carbon isotope shifts and nutrient changes from the northern margin of gondwana high atlas morocco jurassic palaeoenvironmental implications the early toarcian is marked by a global perturbation of the carbon cycle and major marine biological changes these coincide with a general decrease in calcium carbonate production and an increase in organic carbon burial and culminate in the so called toarcian oceanic anoxic event it is believed that the environmental crisis was triggered by the activity of the karoo ferrar large igneous province in order to further document the early toarcian palaeoenvironmental perturbations carbon isotope total organic matter calcareous nannofossils and phosphorus content of the amellago section in the high atlas rift basin of morocco were investigated this section is extremely expanded compared to the well studied european sections its position along the northern margin of the gondwana continent is of critical importance because it enables an assessment of changes of river nutrient input into the western tethyan realm the carbon isotope curve shows two negative excursions of equal thickness and amplitude at the pliensbachian toarcian boundary and at the transition from the polymorphum to the levisoni zone this confirms the supra regional nature of these shifts and highlights the possible condensation of the first boundary shift in european sections phosphorus content is used to trace palaeo nutrient changes and shows that the two negative carbon isotope shifts are associated with increased nutrient levels confirming that these episodes are related to enhanced continental weathering probably due to elevated greenhouse gases in the atmosphere in the high atlas basin the increase in nutrient levels at the pliensbachian toarcian boundary is moreover likely to be the main factor responsible for the coeval demise of the saharan carbonate platform a middle toarcian event centered on the boundary between the bifrons and gradata zones characterized by a positive carbon isotope excursion and nutrient level rise is documented in the amellago section

clay mineral assemblages of mesozoic pelagic and flysch sediments of the lombardian basin southern alps implications for palaeotectonics palaeoclimate and diagenesis clay mineral assemblages determined by x ray diffraction in the jurassic to lower cretaceous hemipelagic pelagic sediments and in the upper cretaceous flysch sequences of the lombardian basin southern alps record tectonic and possibly climatic changes in the source areas and to a lesser extent alterations during burial diagenesis

numerical paleoceanographic study of the early jurassic transcontinental laurasian seaway the forces governing marine circulation of a meridional transcontinental seaway is explored with the princeton ocean model the jurassic laurasian seaway which connected the low latitude tethys ocean with the arctic sea is modeled quantitatively the global ocean is found to have a profound influence on seaway dynamics a north south density difference and hence sea level difference of the global ocean was probably the main factor in forcing the seaway flow when the tethys waters were the denser water the net seaway flow was southward and conversely it was northward for denser arctic waters marine bioprovincial boundaries and sediment data indicate that the seaway probably was dominated by boreal faunal groups and reduced salinities several times in the jurassic the model results suggest that this can be explained by southward flowing seaway currents which may have been related to an oceanic thermohaline circulation where no northern high latitude deep convection occurred

mesozoic igneous activity in the maranha o province northern brazil 40ar 39ar evidence for separate episodes of basaltic magmatism low and high ti basaltic rocks of the maranha o province in northern brazil appear to be related to the opening of the atlantic ocean 40ar 39ar dating was carried out on powdered whole rock basalts both washed and unwashed in dilute nitric acid to document this relationship acid treatment does not alter the argon retention properties of retentive phases but is effective in removing alteration phases high ca k degassed at low laboratory temperatures our results identify that at least two periods of volcanic activity formed the maranha o province low ti basalts from the western sector are 200 190 ma and are related to the opening of the north atlantic high ti basalts from the eastern sector are 129 124 ma slightly younger than compositionally similar rocks in the serra geral flood basalt province of southern brazil and are related to the opening of the south atlantic other flood basalts such as the columbia river deccan rajmahal ferrar and siberian provinces were each predominantly formed in 1 2 ma the maranha o basalts remnants of separate igneous events spanning 70 ma should not be classed as a single flood basalt province the temporal complexities noted in the maranha o basaltic rocks appear to be related to the tracks of hotspots that led to the rifting of the atlantic ocean two sets of mesozoic basaltic rocks occur in southern africa india and south america resulting from events leading to the fragmentation and dispersal of sections of gondwanaland in each sub continent the two provinces were formed by events separated by 50 70 ma of these pairs only the maranha o and serra geral show geochemical similarities indicating compositionally distinct upper mantle source regions under sections of brazil separated by 3000 km

pyrite framboid evidence for oxygen poor deposition during the permian triassic crisis in kashmir abstract the khunamuh formation of the guryul ravine section in kashmir provides one of the most detailed deep water records of the end permian mass extinction in perigondwanan palaeolatitudes examination of pyrite framboid size distributions and sediment microfabric reveals a distinct change in the uppermost permian strata from nonlaminated pyrite free silty mudstones to finely laminated silty shales rich in framboidal pyrite around 1 m above the base of the formation the size frequency distribution of the framboids is identical to populations from severely oxygen restricted modern depositional environments this change to dysoxic benthic conditions coincides with the rapid demise of diverse permian brachiopod and bryozoan assemblages thus the link between extinction and anoxia is clearly seen at guryul ravine and it provides an interesting contrast to other perigondwanan sections developed in shallower water where both the onset of anoxia and the extinction occurred somewhat later in the earliest triassic

chronology of the central atlantic magmatic province implications for the central atlantic rifting processes and the triassic jurassic biotic crisis abstract the central atlantic magmatic province camp is among the largest igneous provinces on earth emplaced synchronously with or just prior to the triassic jurassic t j boundary ca 200 ma in great part due to the controversial connection between the occurrence of camp and the events of the t j boundary the demand for better constraints on the duration and eruptive chronology of this province has increased more than 100 new 40 ar 39 ar ages have been published in the last 15 years with more than half of these in the last 3 years a careful review and selection of available ages as well as the publication of 16 new ages from the carolinas newark basin usa french guyana and morocco are presented judicious selection yields a total of 58 accepted age determinations for camp magmatism ranging from 202 to 190 ma covering every part of the camp a more complete picture develops with intrusive camp magmatism commencing as early as 202 ma extrusive activity initiated abruptly 200 ma reaching peak volume and intensity around 199 ma on the african margin the main period of camp magmatism is confirmed as brief but is suggested to consist of at least two phases over 1 5 ma with magmatism commencing along the africa north american margins and slightly later along the south american margin two volumetrically minor but distinctive magmatic peaks centered at 195 and 192 ma are mirrored in data from all three continents and highlighted by our statistical approach models describing rifting and thermal input and magma production on these timescales are explored despite significant advances in our understanding of the chronology of camp more data of better quality and broader geographical coverage are needed to completely characterize the evolution of the camp and infer its geodynamic origin in addition lack of a well defined t j boundary age as well as the absence of a relevant basis for comparison between u pb and 40 ar 39 ar data for this time period remain limiting factors to unambiguously linking camp in time with the events of the t j boundary

doomed pioneers gravity flow deposition and bioturbation in marine oxygen deficient environments isolated horizons of thalassinoides and gyrolithes burrows appear in exclusive association with gravity flow deposits within sequences of nonbioturbated hernipelagic sedimentary rocks of the miocene monterey formation of california and the oligocene miocene san gregorio formation of baja california these burrowed levels are not associated with other ichnogenera such as zoophycos and chondrites we infer a causal relation between gravity flow deposition and the presence of thalassinoides and gyrolithes and suggest that these gravity flows entrained thalassinidean crustacea upon deposition in oxygen deficient environments the surviving borrowers reworked substantial quantities of aminated commonly organic rich sediments in an environment from which they were previously excluded the persistence of or the ecologically rapid return to oxygen depleted conditions limited the survival time and ecological complexity of the transported infaunal dwellers and rendered them doomed pioneers ecological and physiological data support this hypothesis thalassinidean crustacea have the capability to endure turbulent transport and survive up to 5 7 days of anoxia without being severely limited in their biological activities the accurate recognition of doomed pioneer trace fossil assemblages as ephemeral ecological phenomena in otherwise laminated successions may contribute to a better understanding and interpretation of paleo oxygen levels and basin history

hindcast of the wave conditions along the west iberian coast this paper describes the development of a wave prediction system for the west iberian coast the implemented wave prediction system is based on two state of the art spectral wave models wam for the ocean area and swan for the nearshore however because of its extended geographical space the swan model will include some generation effects in the coarse swan simulations complemented by wave transformation effects near the coast the system was validated by means of extended hindcast runs in various regions belonging to the continental portuguese coastal environment which were compared with buoy data focusing on the extreme energetic events and both direct comparisons and statistical results are presented

chemostratigraphy of the jurassic system applications limitations and implications for palaeoceanography current chemostratigraphical studies of the jurassic system primarily involve the use of one sedimentary component marine organic carbon one divalent transition metal substituted in carbonate manganese and two isotopic tracers strontium isotope ratios 87 sr 86 sr and carbon isotope ratios 13 c carb and 13 c org in carbonate and in organic matter other parameters such as mg ca and sr ca ratios in calcite oxygen isotope ratios 18 o in carbonate sulphur isotope ratios 34 s in carbonate hosted sulphate nitrogen isotope ratios 15 n org in organic matter osmium isotope ratios 187 os 188 os in black shales and neodymium isotope ratios 143 nd 144 nd in various mineral phases are also useful but at present give poor resolution because the database is incomplete or compromised by various factors stratigraphical patterns in total organic carbon toc can be of either local or regional significance depending on the lateral extent of the former nutrient rich and productive water mass divalent manganese follows a similar pattern being concentrated most probably as a very early diagenetic phase only in oxygen depleted waters that typically underlie zones of elevated organic productivity shifts in mg ca and sr ca ratios on the time scale of ammonite subzones seem largely to reflect temperature changes strontium isotope ratios from pristine skeletal calcite provide a global signal 13 c values from carbonates with minimal diagenetic overprint potentially do the same although small spatial differences in palaeo water mass composition may have been locally significant oxygen isotope determinations on carbonate rocks and fossils generally yield values that are too scattered to be stratigraphically useful because they reflect palaeotemperature the evaporation precipitation balance in sea water and the impact of any diagenesis involving an aqueous phase nitrogen isotope ratios in organic matter reflect the chemistry of ancient water masses as affected by nitrate utilization and denitrification and the stratigraphical pattern of this parameter is more likely to correlate only on a regional basis neodymium isotope ratios in sea water are also water mass dependent and greatly affected by regional sources and oceanic current systems preliminary data on sulphur isotope ratios in carbonates and osmium isotope ratios in organic rich shales both potentially offering global correlation indicate that these tracers may be valuable although the records at present are not sufficiently well established to allow high resolution regional correlation in all cases biostratigraphically well dated reference sections against which the relevant geochemical data have been calibrated are required in the first instance to date studies on the stratigraphical distribution of organic carbon have been principally carried out in both northern boreal and southern tethyan europe carbon isotope stratigraphy has been undertaken primarily but not exclusively on bulk pelagic sediments from the alpine mediterranean or tethyan domain and strontium isotope stratigraphy has been undertaken largely on calcitic skeletal material belemnites and oysters from northern and southern europe in many sections including those containing ammonites multi parameter chemostratigraphy can give resolution that exceeds that attainable by classic biostratigraphical means strontium isotope ratios in skeletal calcite are a particularly powerful tool for illustrating changes in sedimentary rate and revealing gaps in the stratigraphical record

continental weathering and climatic changes inferred from clay mineralogy and paired carbon isotopes across the early to middle toarcian in the paris basin abstract lower toarcian strata lower jurassic have been extensively studied with a view to understanding the oceanographic climatic and biological processes that drove the earth s system into an oceanic anoxic event oae for this time period the evolution of the european marine seaways is now relatively well constrained owing to multiple geochemical studies but investigations regarding climatic trends in the continental realm remain sparse in the present study we test the clay mineralogy as a continental climate sensitive proxy in the well documented sancerre core southern paris basin we compare variations in the kaolinite content with p co 2 fluctuations derived from paired carbon isotopes 13 c 13 c carb 13 c org taking advantage of the detailed chemostratigraphic palaeoenvironmental and sequence stratigraphy frameworks established for this core material the results indicate a substantial decrease in kaolinite abundance at the end of the pliensbachian which is compatible with a long term diminution in continental weathering and an inferred temperature decrease the early toarcian prior to the carbon cycle perturbation and deposition of black shale facies remained relatively cold with minima in both the proportion of kaolinite and reconstructed p co 2 the mineralogical and geochemical responses across the prominent negative carbon isotope excursion cie itself are not univocal the first of four steps that compose the negative limb of the cie at sancerre is associated with decreased kaolinite and p co 2 and increased carbonate oxygen isotope ratios taken together these trends are compatible with a transient cooling phase immediately preceding the onset of black shale deposition conversely the subsequent steps are marked by substantial enrichment in kaolinite that matches increased osmium isotope ratios measured in yorkshire providing compelling evidence for rapid increases in continental weathering and riverine runoff forced by intensification of greenhouse conditions during the cie relaxation in the intensity of continental weathering as suggested by resumed low kaolinite abundance is seen immediately after the cessation of co 2 input after the fourth step of the cie the interval spanning the upper portion of the early toarcian and the middle toarcian records a subsequent long term increase in the proportion of kaolinite synchronous with significant clay enrichment of the sediment continued greenhouse conditions even after the recovery from the carbon isotope perturbation and regional black shale deposition are likely related to sustained co 2 emission by karoo ferrar volcanism through the considered interval

paleoceanographic changes of the late pliensbachian early toarcian interval a possible link to the genesis of an oceanic anoxic event abstract secular records of the elemental and isotopic composition of belemnite calcite were studied in pliensbachian and toarcian sections from the yorkshire coast uk and southern germany to investigate oceanographic change during an interval prior to and including the toarcian oceanic anoxic event oae records from southern germany are correlated to the uk stratigraphy using strontium isotope stratigraphy the geochemical trends measured from belemnite calcite are consistent between the two sections and are interpreted in terms of temperature and salinity of the northwest european epi continental sea the data suggest that a dramatic environmental change coincided with the toarcian oae belemnite mg ca sr ca and na ca ratios increase by a factor of between 1 7 and 2 coincident with a 3 negative shift in 18o from the mid tenuicostatum zone until the lower falciferum zone of the uk ammonite biostratigraphy a period of 0 6 0 7 myr taken at face value the mg ca and 18o data argue for an abrupt warming of 6 7 c and substantial freshening during this interval global warming accompanied by an accelerated hydrological cycle and increased runoff is proposed to explain these changes prior to these events data from lower in the yorkshire section suggest a possible cooling accompanied by a shift to more saline waters during the period from the upper pliensbachian margaritatus zone to the toarcian lower tenuicostatum zone this earlier event may also have been important in causing density stratification in the northwest european epi continental sea

early to middle jurassic vegetation and climatic events in the qaidam basin northwest china abstract jurassic deposits are well exposed in the qaidam basin qinghai province northwest china and are regarded as one of the most completely developed early middle jurassic plant bearing sequences in northern china the early to middle jurassic palynoflora in this basin shows a high diversity of spores and pollen grains which are characterized by four palynological assemblage zones corresponding to the pliensbachian toarcian aalenian bajocian and bathonian in age vegetation reconstruction demonstrates four vegetation types upland coniferous forest in the pliensbachian coastal cheirolepidiacean forest in the toarcian lowland fern forest in the aalenian bajocian and a mixed forest in the bathonian nearest living relative analysis of the major plant groups shows that the early to middle jurassic vegetation in the qaidam basin not only consists of plants with tropical subtropical climate requirements but also those indicating temperate climatic conditions in addition bryophytes and fungi as well as cheirolepidiaceae which are generally considered to indicate warmer and or drier conditions are also documented in the palynofloras it is suggested that a temperate to subtropical climate generally prevailed during the early to middle jurassic in this basin however the vegetation features and the sedimentary data signify that an overall humid to semi humid phase was punctuated by warmer and locally dry and or arid episodes the two higher temperature and aridity events occurred in the toarcian and bathonian callovian periods in the qaidam basin these climatic events can be inferred by increase of relative abundance of classopollis pollen some tropical subtropical fern spores and the occurrences of variegated red beds and evaporite rocks these events may either be associated in some way with a transient global warming phenomenon due to an enhanced greenhouse effect or be linked with intensification of a potential monsoonal circulation such events finally caused a weakening and even arrested coal accumulation in the qaidam basin during the toarcian and the bathonian callovian intervals

geochemical arguments for identifying second order sea level changes in hemipelagic carbonate ramp deposits second order transgressive regressive t r cycles previously recognized using sedimentological criteria in lower jurassic hemipelagic deposits from northern spain are distinguishable based upon bulk rock organic geochemistry total organic carbon toc and hydrogen index hi and the stable carbon isotope compositions from belemnite rostra there is a coincidence between regressions and decreasing 13cbel toc and hi values and between transgressions and increasing 13cbel toc and hi values the 18o and mg ca records from the belemnite rostra are not always in phase with the t r cycles the 18obel record reveals however a prominent excursion towards higher values within the spinatum zone that correlates according to our results with a regression and with negative shifts in mg ca 13cbel and toc on the other hand an excursion in the 18obel towards lower values in the serpentinus zone also correlates with a peak transgression and with positive shifts in mg ca 13cbel and toc these two excursions have been identified in other european regions as geochemical perturbations of the same characteristics this suggests a link between second order relative sea level changes and variations in seawater geochemistry that may reflect local and regional palaeoceanographic perturbations in sea water temperature salinity and water circulation during the early jurassic terra nova 18 233 240 2006

rapid magma emplacement in the karoo large igneous province abstract understanding the dynamics of continental large igneous provinces lips relies on precise dating of basaltic rocks lip research has traditionally focused on dating lavas often neglecting the volumetrically important sill intrusions in underlying sedimentary basins here we present u pb zircon and baddeleyite ages for fourteen new samples of karoo lip sills and dykes spaced by as much as 1100 km across the half million square kilometer karoo basin the samples yield remarkably coherent ages ranging from 183 0 0 5 to 182 3 0 6 myr probability modeling indicates that basin scale emplacement took place within an interval of about 0 47 myrs less than 0 90 myrs with 95 confidence and could even have represented a single magma emplacement event combining the new ages with the estimated volume of sills in the karoo basin gives an emplacement rate of 0 78 km3 yr which is higher than previous estimates upper crustal magma storage may account for these high rates the results challenge the view that melt emplacement in a sedimentary basin is a prolonged process support a scenario of pulsating catastrophic events within a narrow time frame and strengthens the hypothesis linking lips and sill emplacement to global environmental crises

understanding the geological record of carbonate platform drowning across rifted tethyan margins examples from the lower jurassic of the apennines and sicily italy abstract in the geological record a drowning process is documented by various types of shallow water to pelagic or shallow water to mixed benthic pelagic carbonate transitions drowning unconformities are paraconformities to disconformities to angular unconformities and their drowning surfaces range from planar to highly irregular morphologies drowning successions display a mix of products of both the benthic and pelagic carbonate factories these successions can be also bounded by unconformities drowning unconformities and drowning successions are contrasted through a description and discussion of examples of escarpment bounded platforms from the jurassic of the northern apennines and subordinately from sicily and other tethyan sectors the areal distribution of drowning unconformities and successions is discussed with reference to a complex depositional system whose architecture was the product of the rift induced fragmentation of a regional hettangian carbonate megabank the examples in this study show drowning unconformities to be exclusive to intrabasinal highs while drowning successions are found both on highs and in hangingwall basins drowning unconformities with their long associated hiatuses and drowning successions are often seen to merge laterally into one another over very short distances on the same intrabasinal high the deposits of the drowning succession are sometimes missing on the top of the platform while they are found forming clinoforms along its flanks evidence that sediment could be permanently swept from the highs in these depositional systems at this stage

pangea s complex breakup a new rapidly changing stress field model over the years numerous proposals have been presented describing the relationship between the central atlantic magmatic province camp and the break up of pangea recent proposals have focused on refuting the original proposal of a mantle plume origin for the large igneous province and attendant dikes and instead propose an upper mantle or passive cause for the break up and camp in this paper we examine the fundamental assumption that the multiple dike orientations associated with the break up are geographically or temporally delimited new mapping and compilations of older local maps demonstrate that multiple dike orientations ranging from nw to ne trending were intruded throughout the western carolinas and are not geographically limited further new plagioclase 40 ar 39 ar dates indicate that all three orientations observed were emplaced within a 2 ma period c a 199 197 ma based on this information we propose that a rapidly rotating stress field must be responsible for the emplacement of multiple dike orientations in the carolinas and the break up of pangea and go on to propose several new tectonic models to account for this rotating stress field d 2005 elsevier b v all rights reserved

secular environmental precursors to early toarcian jurassic extreme climate changes the early toarcian oceanic anoxic event t oae about 183 myr ago was a global event of environmental and carbon cycle perturbations which deeply affected both marine biota and carbonate production nevertheless the long term environmental conditions prevailing prior to the main phase of marine extinction and carbonate production crisis remain poorly understood here we present a similar to 8 myr long record of early pliensbachian middle toarcian environmental changes from the lusitanian basin portugal in order to address the long term paleoclimatic evolution that ultimately led to carbonate production and biotic crises during the t oae paleotemperature estimates derived from the oxygen isotope compositions of well reserved brachiopod shells from two different sections reveal a pronounced similar to 5 degrees c cooling in the late pliensbachian margaritatus spinatum ammonite zones boundary this cooling event is followed by a marked similar to 7 10 degrees c seawater warming in the early toarcian that after a second cooling event in the mid polymorphum zone culminates during the t oae calcium carbonate caco3 contents the amount of nannofossil calcite and the mean size of the major pelagic carbonate producer schizosphaerella all largely covary with paleotemperatures indicating a coupling between climatic conditions and both pelagic and neritic caco3 production furthermore the cooling and warming episodes coincided with major marine regressions and transgressions respectively suggesting that the growth and decay of ice caps may have exerted a strong control on sea level fluctuations throughout the studied time interval this revised chronology of environmental changes shows important similarities with neogene and paleozoic episodes of deglacial black shale formation and thus prompts the reevaluation of ice sheet dynamics as a possible agent of mesozoic events of extinction and organic rich sedimentation c 2010 elsevier b v all rights reserved

pliensbachian environmental perturbations and their potential link with volcanic activity swiss and british geochemical records abstract the mechanisms leading to environmental and climate change prior to and anticipating the well studied toarcian oceanic anoxic event are not completely understood specifically the role of the continuing break up of pangea associated palaeogeographic rearrangements and the influence of volcanic activity are less well known therefore we studied the pliensbachian interval in the open marine hemipelagic section of the breggia gorge in southern switzerland to elucidate the potential impact of these major changes on the environment and climate we identified carbon isotope excursions towards lower values in whole rock carbonates dated from the sinemurian pliensbachian boundary davoei margaritatus and spinatum zones and possibly from the pliensbachian toarcian boundary using the whole rock oxygen isotope record and phosphorus content we associated these events with phases of increased runoff possibly related to climate warming we also established the first mercury hg record for the entire pliensbachian and in order to verify its validity we analysed an additional section located along the dorset coast in southern england the presence of hg spikes common in both sections may indicate the influence of episodes of increased volcanic activity the hg spike during the earliest pliensbachian may coincide with a late phase of the central atlantic magmatic province and or increased rifting linked with the opening of the hispanic corridor further significant maxima in hg contents are observed within the davoei and margaritatus zones and both phases may correspond to early volcanic activity of the karoo ferrar large igneous province further analyses are however needed to corroborate this interpretation and evaluate the importance of organic matter scavenging and detrital input in comparison to volcanic activity

pliensbachian toarcian ostracod biogeography in nw europe evidence for water mass structure evolution abstract this paper examines the role played by palaeoceanographic and climatic conditions on the palaeobiogeography of the pliensbachian toarcian ostracods early jurassic in the european epicontinental sea ees the influence of the palaeogeography ocean currents and sea level temperature and salinity variations on ostracod abundance diversity and migration patterns is reconstructed ostracod migration follows an anticlockwise circulation in the eastern side of the ees with a leading northeast southwest movement and the frequent arrival of tethyan faunas into the central and western parts of the ees during the pliensbachian a three fold classification of water masses based on salinity temperature lithological and fossil data is proposed the repeated inflow of tethyan ostracods into the ees ended by the earliest toarcian this ostracod event is related to the opening of the hispanic corridor and to the reorganization of the surface and deep circulations that may have generated a cold episode at the beginning of the toarcian

selective extinction among early jurassic bivalves a consequence of anoxia analyses of taxonomically standardized data sets demonstrate several statistically robust extinction patterns in early jurassic bivalve species from northwest europe and the andean basins of south america in both regions extinction intensities were significantly enhanced in late pliensbachian and early toarcian time as compared to all other time intervals the same intervals except for the early toarcian of south america also represent times of unusual extinction selectivity with infaunal taxa suffering distinctly more than epifaunal forms as infaunal suspension feeders are extremely rare components of early jurassic oxygen controlled macrofaunas these results are entirely compatible with sedimentological and geochemical data suggesting that widespread anoxia was a principal cause of the diversity crisis although many biotic traits that enhance survivorship during background times seem to be irrelevant during major mass extinctions patterns of survivorship selectivity may provide more distinct clues to the causes of less severe mass extinctions

update of the carbon and oxygen isotopic records of the early late pliensbachian early jurassic 187ma insights from the organic rich hemipelagic series of the lusitanian basin portugal abstract a high resolution carbon and oxygen isotopic bulk carbonate record from organic rich hemipelagic series of early late pliensbachian age 187 ma is presented for the lusitanian basin portugal and compared to the record of other sedimentary basins this dataset provides an excellent basis for discussing newly raised questions concerning the hypothesis of major carbon cycle perturbations prior to the toarcian oceanic anoxic event in addition to the recognition in the studied series of two positive carbon isotope excursions previously defined elsewhere corresponding to the ibex and margaritatus uppermost stokesi gibbosus subzones zones a third positive excursion is identified here for the first time at the davoei zone in the lusitanian basin these excursions are associated with organic rich facies intervals the younger excursion may be related to worldwide enhanced preservation of organic matter in the margaritatus zone we suggest that until these organic rich facies are well age constrained at a wider scale and high resolution carbon data are provided from other locations and that worldwide anoxia is proven this interval should be referred to as an organic matter preservation interval late pliensbachian ompi this period is probably linked with the complex chain of events that eventually led to the toarcian oceanic anoxic event

marine osmium isotope record across the triassic jurassic boundary from a pacific pelagic site the triassic jurassic t j boundary ca 200 ma represents one of the major mass extinction events of the phanerozoic however the cause of this event remains controversial because of a paucity of geological evidence in this study we present an isotopic record of osmium extracted from a bedded chert succession across the t j boundary in the kurusu section of japan deposited within a paleo pacific panthalassa deep basin the data show a gradual decrease in seawater 187 os 188 os values during the rhaetian followed by a sharp increase in the latest rhaetian and a subsequent stable phase across the t j boundary the decreasing trend of 187 os 188 os values during the rhaetian indicates a gradual increase in the relative supply rate of unradiogenic os from the mantle associated with emplacement of the central atlantic magmatic province the subsequent shift toward radiogenic values reflects an increased supply of radiogenic os due to enhanced continental weathering this interval marks more negative isotopic values of organic carbon the onset of radiolarian faunal turnover and conodont extinctions indicating that the rapid increase in continental weathering rate was closely linked to the perturbation of the carbon cycle and the t j biotic crisis

40ar 39ar ages and duration of the central atlantic magmatic province volcanism in morocco and portugal and its relation to the triassic jurassic boundary the central atlantic magmatic province camp is the world s largest known continental igneous province and is 15 contemporaneous with the triassic jurassic t j boundary that marks one of the five largest biological extinctions in the last 16 600 ma although constraints on the duration of the camp volcanism remain yet poorly defined the assumption that the camp 17 may have had a causal relationship with the climatic and biotic crisis was suggested marzoli a bertrand h knight k cirilli 18 s buratti n verati c nomade s renne p r youbi n martini r allenbach k neuwerth r rapaille c zaninetti l 19 bellieni g 2004 synchrony of the central atlantic magmatic province and the triassic jurassic boundary climatic and biotic 20 crisis geology 32 973 976 in this paper we present new 40ar 39ar ages on basaltic flows from moroccan central high atlas 21 oujda and argana and portuguese algarve and santiago do cacem basins where camp lava flows are interlayered with t j 22 sedimentary sequences 23 in the moroccan basins where the basalts were erupted across the t j boundary well defined 40ar 39ar plateau ages n 12 24 for more than 90 of the total erupted volume of camp basalts range from 197 8 0 7 ma to 201 7 2 4 ma and display a main 25 restricted peak at 199 1 1 ma providing a precise estimate of the 40ar 39ar age of the t j boundary concordant with the current 26 u pb age 199 6 0 3 ma palfy j mortensen j k carter e s smith p l friedman r m tipper h w 2000 timing the 27 end triassic mass extinction first on land then in the sea geology 28 39 42 the topmost lava flows recurrent unit yield a 28 significantly younger mean age of 196 6 0 6 ma highlighting late episodic eruption of camp magmas these late basalts 29 represent a small magma volume b10 of the total which was erupted most likely due to asthenospheric upwelling and 30 lithospheric extension within the t j central high atlas basins 31 in the portuguese basins stratigraphical and palynological studies of the associated continental sedimentary sequence 32 underlying the volcanic units suggest an age close to the t j boundary for the camp basaltic flows this is confirmed by new 33 40ar 39ar data for the portuguese basalts which provide the first accurate radio isotopic ages for lava flows in the european 34 camp with two plateau ages yielding a mean value of 198 1 0 4 ma these plateau ages plus three concordant mini plateau 35 ages suggest synchronous rifting and volcanism both in south western europe and morocco central high atlas and oujda basins in summary the eruptive history of the camp with an early extremely widespread and intense peak at 199 1 ma and a tail of 37 episodic eruption events until 196 6 ma is consistent with the biotic turnover at the t j boundary which was likely caused by 38 devastating effects of extensive volcanic eruptions

evidence for major environmental perturbation prior to and during the toarcian early jurassic oceanic anoxic event from the lusitanian basin portugal the timing and causal relationships between the pronounced negative c isotope excursion and paleoenvironmental perturbations associated with the toarcian oceanic anoxic event early jurassic remain unclear particularly because biotic crises and carbonate production decrease appear to have been initiated earlier than the main c isotope anomaly here we present a new quantification of late pliensbachian early toarcian calcareous nannofossils abundance and size from the peniche reference section portugal together with o and c isotope records of well preserved brachiopod shells from the same section the brachiopod shell 13c curve parallels that of bulk carbonate and records two pronounced negative isotopic excursions close to the pliensbachian toarcian boundary 2 and during the toarcian oceanic anoxic event 3 5 our results indicate that both c isotope negative excursions were characteristic of benthic and shallow water environments suggesting that these two carbon cycle perturbations affected all epioceanic reservoirs coeval shifts toward lower values of brachiopod oxygen isotope compositions and closely correlated northward migrations of mediterranean ammonite fauna suggest that both events coincided with major rises in seawater temperatures probably as a result of increased co2 levels and enhanced greenhouse conditions co2 induced changes in seawater chemistry likely affected the calcification potential of both neritic and pelagic systems as evidenced by synchronous drops of platform derived carbonate accumulation and drastic reductions in size 3 m of the main pelagic carbonate producer schizosphaerella we suggest that the early toarcian paleoenvironmental crisis occurred in two distinct episodes that were most likely related to two successive phases of intense volcanic degassing in the karoo ferrar province

potassium argon dating of fine grained basalts with massive ar loss application of the 40ar39ar technique to plagioclase and glass from the kirkpatrick basalt antarctica 40ar39ar incremental heating measurements are reported for separated plagioclase and matrix fractions and a glass sample of the kirkpatrick basalt from victoria land antarctica these results are used to address the limitations of whole rock analyses of glassy or very fine grained basalts the use of plagioclase for determining ages of such rocks the ar behavior of matrix glass and feldspar components the use of k cl ratios in interpretation of step heating results and the age of the kirkpatrick basalt the precise age of the kirkpatrick basalt has been a long standing problem the wide range of reported k ar dates has been attributed to loss of ar despite massive ar loss from the matrix plagioclase is shown to yield good 40ar39ar plateaus plateaus are observed for increments above 700 c and are defined not only by consistent apparent ages but also appropriately low k ca and high k cl ratios cl relations help identify ar released from small amounts of matrix which can seriously contaminate a plagioclase separate an age of 176 8 1 8 ma defines the time of formation of the youngest lava at mt frustum in north victoria land a glass sample from south victoria land gives the same age indicating that terrestrial basaltic glasses as old as jurassic do not inherently lose ar the step heating profile of glass with very fine crystals shows discordance which is an artifact of ar recoil during irradiation

carbon isotope record of the early jurassic toarcian oceanic anoxic event from fossil wood and marine carbonate lusitanian basin portugal thetoarcianoceanicanoxicevent oae intheearlyjurassic 183maago wascharacterizedbywidespreadnear synchronous deposition of organic rich shales in marine settings as well as perturbations to several isotopic systems characteristically two positive carbon isotope excursions in a range of materials are separated by an abrupt negative shift carbon isotope profiles from toarcian fossil wood collected in england and denmark have previously been shown to exhibit this large drop 7 i n 13 c values interpreted as due to an injection of isotopically light co2 into the ocean atmosphere system however the global nature of this excursion has been challengedonthebasisofcarbon isotopedatafromnektonicmarinemolluscs belemnites whichexhibitheavierthanexpectedcarbonisotope values here we present new data principally from fossil wood and bulk carbonate collected at centimetre scale from a hemipelagic section at peniche coastal portugal this section is low in organic carbon average toc 0 5 and the samples should not have suffered significant diagenetic contamination by organic carbon of marine origin the carbon isotope profile based on wood shows two positive excursions separated by a large and abrupt negative excursion which parallels exactly the profile based on bulk carbonate samples from the same section albeit with approximately twice the amplitude 8 in wood versus 3 5 in carbonate these data indicate thatthe negative carbon isotope excursion affected the atmosphereand by implication the global ocean as well the difference in amplitude between terrestrial organic and marine carbonate curves can be explained by greater water availability in the terrestrial environment during the negative excursion for which there is independent evidence from marine osmiumisotope records and plausibly changes in atmospheric co2 content for which independent evidence is also available the peniche succession is also notable for the occurrence of re deposited sediments their lowest occurrence coincides with the base of the negative excursionandtheirhighestoccurrencecoincideswithitstop thus slopeinstabilityandsedimentsupplycouldhavebeenstronglylinked to the global environmental perturbation an association that may misleadingly simulate the effects of sea level fall

northern and southern hemispheres ostracod palaeobiogeography during the early jurassic possible migration routes abstract the purpose of this paper is to review the palaeobiogeographical distribution of early jurassic ostracod species worldwide to establishing possible migration pathways between the north and south hemispheres in direction and timing and in particular to examine the existence of a seaway through central america the hispanic corridor from at least the pliensbachian toarcian a detailed taxonomic revision of over 270 early jurassic ostracod species from europe north africa south america asia and australia a revision of every figured specimen and or taxon included in each list of synonymous taxa has been undertaken each assemblage was subjected to a quantitative analysis this metric was calculated using the dice similarity index in order to ascertain the degree of similarity between ostracod assemblages from both hemispheres the obtained results indicate that there is a clear differentiation between australian and argentinean ostracod assemblages in relation to european ostracod assemblages the australian faunas are similar to western tethyan and central european assemblages probably indicating a communication route along the western tethys aided by the action of western currents moreover the argentinian ostracod assemblages exhibit a high degree of similarity with north western european portugal grand banks the fasnet basin and wales and north african assemblages through the detailed analysis of ostracod spatial and temporal distribution the coeval occurrence of taxa in argentina and western europe and the differences between australian and argentinian faunas and the pattern of ocean currents derived from climate models simulations it would infer the existence of the hispanic corridor

osmium isotope evidence for the regulation of atmospheric co2 by continental weathering the long term stability of earth9s climate throughout the phanerozoic stands in marked contrast to the dramatic fluctuations that have taken place on time scales as short as a few years reflecting the high efficiency of longer term climate regulation through negative feedbacks a fundamental mechanism is thought to involve control of co 2 in the ocean atmosphere system through continental weathering although unambiguous high resolution data supporting this hypothesis have hitherto not been available organic rich mud rocks from yorkshire england which were deposited during the toarcian oceanic anoxic event ca 181 ma early jurassic contain evidence of an exceptionally large excursion in the 187 os 188 os ratio of contemporaneous seawater from 0 4 to 1 0 the most likely explanation for this excursion is that it resulted from a transient increase in global continental weathering rates of 400 800 the os isotope excursion coincided with a well documented global 13 c excursion of 6 that affected all the major biospheric reservoirs of the time higher mean global temperatures caused global chemical weathering rates to increase substantially while in turn chemical weathering was very effective in reducing the elevated levels of atmospheric co 2 and the high temperatures to preexcursion levels

from rifting to drifting tectonic evolution of the south alpine upper crust from the triassic to the early cretaceous abstract the tectonic evolution of the south alpine rifted margin is discussed on the base of four palinspastic upper crustal profiles extension related to the movements between adria and europe began in the norian after variscan orogeny late carboniferous to middle permian orogenic collapse and continental scale wrenching from the late triassic to the early liassic stretching was mostly limited to the lombardian basin during this time extension was mainly controlled by four major listric faults symmetrically centred around the late carboniferous early permian collio grabens smaller faults which also started in the norian were progressively de activated during the late triassic after the middle liassic faulting in the lombardian basin gradually ceased and the site of extension shifted westwards i e towards the future site of crustal separation extension was then controlled by a set of west dipping normal faults oceanic crust was formed not later than 157 ma the overall extension along the profile which had a final length of 290 km was 52 km which corresponds to a stretching factor of 1 22 for the whole length of the preserved margin the strain rate is ca 1 10 16 s the sedimentation history suggests that the extension of the south alpine margin was a continuous process from the norian to the middle jurassic the changes in tectonic pattern are related to progressive hardening of the lithospheric segment undergoing slow extension

carbonate platform evidence of ocean acidification at the onset of the early toarcian oceanic anoxic event abstract the early toarcian oceanic anoxic event early jurassic 183 myr ago is associated with one of the largest negative carbon isotope excursion cie in the whole phanerozoic 3 7 estimates of the magnitude and rate of co 2 injection in the ocean atmosphere system are compatible with a scenario of ocean acidification many carbonate platforms drowned in the pliensbachian well before the early toarcian event in this paper we test the hypothesis of surface water ocean acidification by presenting data from a resilient carbonate platform the apennine carbonate platform of southern italy the studied sections document a dramatic shift of the carbonate factory from massive biocalcification to chemical precipitation lithiotis bivalves and calcareous algae palaeodasycladus mediterraneus which were the most prolific carbonate producers of pliensbachian carbonate platforms disappear during the first phase of the early toarcian cie before the most depleted values are reached we discuss the local versus supraregional significance of this shift and propose a scenario involving abrupt decline of carbonate saturation forced by co 2 release at the beginning of the early toarcian cie followed by a calcification overshoot driven by the recovery of ocean alkalinity attribution of the demise of carbonate platform hypercalcifiers to ocean acidification is supported by palaeophysiology and reinforced by experimental data on the detrimental effects of ocean acidification on recent shellfishes and calcareous algae

the evidence and implications of polar ice during the mesozoic abstract the mesozoic perhaps representing the longest period of warmth during phanerozoic earth history contains in general sparse and frequently equivocal evidence for polar ice although this time is undoubtedly punctuated by oscillations in climate whether sufficient to lead to polar cooling and the formation of polar ice an inviting mechanism to account for faunal and floral distribution patterns and large scale sea level change has been widely debated mesozoic evidence for glacial conditions includes abraded rock surfaces generally unsorted stone rich beds and the presence of dropstones rafted by ice within a finer grained host sediment faunal and floral evidence has also been utilised to determine the presence or absence of cold or sub freezing polar conditions together with more indirect evidence for glacial conditions derived from general circulation model gcm simulations of climate the analysis of clay mineral distributions glendonite abundance and palaeontological and sedimentological evidence for globally synchronous sea level change the extent of possible glacial environments during the mesozoic has been established by plotting published reports of glacial sediments on palaeogeographic reconstructions the general clustering of evidence at high palaeolatitudes suggests that the extent of polar ice during the mesozoic is likely to have been approximately one third the size of the present day based on such evidence a number of episodes of cold or sub freezing polar climates during the bajocian bathonian tithonian volgian valanginian and aptian are recognised evidence exists possibly also for a cold episode during the early jurassic pliensbachian although poorly constrained owing to limited biostratigraphical control the longevity of these events may be represented by a cold snap within a stage although undoubtedly the possible smearing of ages may have had the effect of lengthening and hence promoting the importance of these proposed events the climate regime of the earth during these times may be hypothesised to be characterised by a relatively steep pole to equator temperature gradient where low latitude regions are as warm or warmer than today the evidence to support such reasoning includes sharp increases in the areal distribution of both glendonites and deposits with affinities to glacial tillites and dropstones for these times coincidental falls of sea level arid events and an increased bipolarity of faunas at these times imparts further confidence that these events were of a magnitude to effect the earth as a whole

strontium isotopes in early jurassic seawater abstract the analysis of well preserved well dated belemnites and oysters from the jurassic of great britain has resulted in a well constrained detailed seawater strontium isotope curve for the early jurassic the preservation of fossil low mg calcite was monitored using mn fe 13 c and 18 o iron was the most useful indicator with about 75 of the samples containing more than 150 ppm fe showing 87 sr 86 sr ratios elevated relative to adjacent points on the curve high mn concentrations less often correlated with elevated 87 sr 86 sr ratios however low mn concentrations 87 sr 86 sr 13 c and 18 o proved to be insensitive to diagenesis as it affects 87 sr 86 sr the principal features of the strontium isotope curve include a rise to about 0 70772 in the latest triassic and earliest jurassic hettangian from the hettangian the curve begins a roughly linear descent through the sinemurian and pliensbachian following a small levelling off and increase in the late pliensbachian the curve falls rapidly to its early jurassic minimum of 0 70706 it then gently increases through the toarcian until the falciferum zone where it shows an apparently abrupt increase to 0 70719 before continuing its slow increase to 0 70728 in the aalenian bajocian middle jurassic this reversal of the downwards trend established in the sinemurian and pliensbachian had not been previously identified the sinemurian and pliensbachian section of the curve potentially allows correlation and dating to within 1 or 2 ammonite subzones 0 5 to 1 ma

chemical cyclicity and correlation of lower lias mudstones using gamma ray logs yorkshire uk natural gamma ray spectrometry on coastal sections from redcar and robin hood9s bay permits the radioactive characterization of five different mudstone units and the construction of an outcrop gamma ray log for the lower lias correlation of these five units with their equivalents in the gamma ray log of the felixkirk borehole located 40 km to the west has been established statistical comparison of tie points in the composite coastal section shows there to be a stratigraphic gap of 10 m between the two localities relative to the continuous section in the felixkirk borehole the distribution of th ppm k and u ppm are generally highly correlated with the total radioactivity however anomalies do occur a peak in the th k ratio can be related to an iron oolitic horizon marking a condensed sequence in the early mid sinemurian a sharp fall in the th k ratio followed by high u values coincides with the early pliensbachian transgression comparison with mineralogical clays and chemical si al and al k ratio v total organic carbon profiles of the same section allows for an evaluation of the significance of radioactive element distribution in terms of grainsize run off and oxygenation indicators a spline curve fitted through the total radioactivity data emphasizes low frequency cyclicity wavelengths of between 10 and 30 m in the outcrop section these cycles appear to be correlatable with cycles of comparable wavelengths in the low pass filtered gamma ray log of the felixkirk borehole sedimentological evidence confirmed high radioactivity peaks correspond to transgressive phases the gamma ray signal of the felixkirk borehole has also been analysed for high frequency cyclicity with an overall rate of accumulation of about 13m ma variation in the milankovitch band is marked by units 5 m or less in thickness evidence for eccentricity obliquity and precession cycles has been found both in borehole and in outcrop a typical shift from lower to higher frequencies occurs consistently in transgressive phases and is related to increased sedimentation rates

seafloor erosion and sea level change early jurassic blue lias formation of central england abstract minor bedforms within the mudstone dominated early jurassic hettangian saltford shale member liasicus up to angulata chronozone of the blue lias formation in central england indicate weak seafloor erosion in a mid to outer ramp setting distal storm flows below maximum storm wave base are proposed as the most likely generative mechanism for silty scour and gutter casts that enclose concentrations of well preserved schlotheimiid ammonites and arthropod trace fossils within the upper part of the saltford shale probably angulata chronozone a discrete layer of reworked and bioencrusted limestone nodules signifies an episode of more persistent seafloor erosion the immediately overlying strata transitional to the hettangian sinemurian rugby limestone member are relatively bioturbated and feature fossils of macrobenthos as well as shell concentrations resembling relatively proximal storm beds this suggests that the reworked nodule horizon marks sea level fall rather than stratigraphic condensation associated with sediment starvation the biostratigraphic evidence raises the possibility that this erosional episode correlates with a mid angulata chronozone hiatus documented from the wessex basin southwest england equally however it could be linked to contemporaneous movement on one or more nearby faults affecting the southern part of the english east midlands shelf

strontium isotope profile of the early toarcian jurassic oceanic anoxic event the duration of ammonite biozones and belemnite palaeotemperatures we profile 87sr 86sr 13c 18o sr ca mg ca and na ca in belemnites through pliensbachian and toarcian strata on the yorkshire coast uk which include the early jurassic oceanic anoxic event the 87sr 86sr profile shows that the relative duration of ammonite subzones differ by a factor of up to 30 the lower jurassic exaratum subzone is 30 times longer than the clevelandicum subzone because the exaratum subzone in yorkshire which contains the anoxic event is condensed by a factor of between 6 5 and 12 2 times relative to adjacent strata using our 87sr 86sr profile the resolution in correlation and dating attainable in the interval is between 1 5 m and 15 m of section and better than 0 25 myr in parts of the sequence this stratigraphic resolution equals that attainable with ammonites a new age model is provided for late pliensbachian and early toarcian time that is based on the 87sr 86sr profile through the sequence the sr ca mg ca na ca and 18o of belemnite carbonate covary suggesting that elemental ratios may be useful for palaeotemperature measurement our 13cbelemnite data splits into three the previously reported positive isotope excursion to 6 5 in the early toarcian we speculate that the excursion s resulted from addition to surface waters of isotopically heavy co2 via ebullition of methanogenic co2 from the sediment during early burial of organic rich 10 toc sediments

environmental controls on clay mineralogy of an early jurassic mudrock blue lias formation southern england we present a dataset including clay mineralogy gamma ray spectrometry organic matter content and magnetic susceptibility of the hettangian to lowest sinemurian successions of dorset and somerset southern uk blue lias formation bristol channel and wessex basins in both areas the clay assemblages comprise predominantly detrital illite kaolinite and illite smectite mixed layers clays probably originated from the erosion of the hercynian massifs the relative proportions of kaolinite and illite being modulated by arid humid climatic fluctuations the organic matter om content types ii to iv ranges up to 12 in both areas a clear stratigraphical trend in clay mineral assemblages is apparent in somerset whereas in dorset sharp contrasts between adjacent horizons and a greater dilution by carbonate mask the long term evolution correlations between both areas based on similar vertical trends in clay mineral abundance support the suggestion of a hiatus within the angulata zone of the dorset succession as expected the kaolinite illite ratio correlates with the th k ratio deduced from gamma ray spectrometry however significant departures from the correlation occur in om rich intervals suggesting that th may be partly adsorbed on to om particles surprisingly high magnetic susceptibility correlates with abundant kaolinite not with fe rich clays indicating either that kaolinite is accompanied by a soil inherited magnetisable phase possibly iron oxide or that illite rich rocks are more strongly diluted by carbonate than are kaolinite rich strata

high resolution magnetic stratigraphy at bosso stirpeto marche italy anomalous geomagnetic field behaviour during early pliensbachian early jurassic times abstract we report on a high resolution magnetostratigraphic analysis of a continuous 97 5 m thick upper sinemurian pliensbachian pelagic limestone section corniola formation exposed at bosso stirpeto marche italy where detailed ammonite and calcareous nannofossil biozonation is available the early pliensbachian carixian is notably expanded 74 35 m excluding few slumps implying an average sedimentation rate of 28 6 m myr both the carixian boundaries and three additional intra carixian ammonite zone boundaries are tied up with polarity magnetozones we find that a normal polarity characterizes the latest sinemurian and sinemurian carixian boundary while a reverse polarity punctuated by three short normal polarity magnetozones dominates the carixian in the lower carixian sediments two 3 39 4 65 m thick excluding the slumps intervals are characterized by persistent transitional between 45 n and 45 s virtual geomagnetic pole vgp latitudes but this seems not to be the result of mineral magnetic artefacts antipodal polarity averaging or sedimentary layer disturbance thus we suggest that in two 120 and 160 kyr long time intervals during the early carixian the vgps were predominantly confined at tropical equatorial latitudes of the earth such geomagnetic feature has never been documented before elsewhere in other time intervals and requires further paleomagnetic investigation of other expanded carixian section to be confirmed the magnetic polarity profile including the transitional direction intervals of bosso stirpeto may compare with that from similarly expanded carixian sections breggia switzerland and cores montcornet paris basin however the matching of magnetic polarity zones requires a significant aging of some parts of the magnetostratigraphic profile at both breggia and montcornet

high precision geochronology links the ferrar large igneous province with early jurassic ocean anoxia and biotic crisis abstract apparent synchrony between eruption emplacement of large igneous province lip magmas and mass extinction has led to the implication of magmatism as a primary trigger of global scale environmental change evaluating the efficacy of magmatism as a driver of global change depends on the relative timing of magmatism and environmental change and the magma effusion intrusion rate both of which can be constrained by high precision geochronology early jurassic pliensbachian toarcian global ocean anoxia and acidification carbon isotope perturbations and biotic crisis have been linked to synchronous eruption and emplacement of the karoo and ferrar lips to better constrain the timing and duration of ferrar magmatism we apply the single crystal chemical abrasion u pb id tims method to zircon crystals isolated from twenty ferrar lip sills and lavas and the dufek intrusion dates suggest that both intrusive and extrusive ferrar magmatism occurred over an interval of 349 49 kyr beginning with intrusive magmatism as early as 182 779 0 033 ma lava eruption was synchronous with and in some cases postdates intrusion when coupled with existing geochronology on the karoo province our dates confirm broad synchrony between karoo and ferrar magmatism though karoo magmatism began demonstrably prior to ferrar magmatism starting as early as 183 246 0 045 ma the short lived magmatic history of the ferrar lip makes it a plausible trigger for early jurassic environmental change

carbon isotope stratigraphy and carbonate production during the early middle jurassic examples from the umbria marche sabina apennines central italy abstract the carbon isotopic signature of carbonates depends on secular variations of organic carbon and carbonate carbon production burial rates a decrease in carbonate productivity makes the organic carbonate carbon ratio unstable up to the point that even minor variations in the organic carbon reservoirs can provoke carbon isotopic shifts the 13c positive shifts of the middle carixian early pliensbachian and the early bajocian recorded in the umbria marche sabina domain represent a good example of this mechanism both sedimentology and lithostratigraphy of pelagic platform basin carbonate systems in this area show that important changes in the source of carbonates correspond to the observed isotopic shifts the middle carixian event is in fact well correlatable to the drastic reduction of benthic carbonate production on rift related intrabasinal highs which then became pelagic carbonate platforms the early bajocian event is concomitant with the beginning of a long hiatus on the pelagic carbonate platforms and with a drop of the biodiversity of calcareous organisms followed by the onset of biosiliceous sedimentation in basins

40ar 39ar ages of the sill complex of the karoo large igneous province implications for the pliensbachian toarcian climate change 1 reliable geochronological results gathered so far n 76 have considerably constrained the timing of the emplacement of the karoo large igneous province lip yet strikingly missing from this dating effort is the huge southern sill complex cropping out in the 0 6 106 km2 main karoo sedimentary basin we present 16 new 40ar 39ar analyses carried out on fresh plagioclase and biotite separates from 15 sill samples collected along a n s trend in the eastern part of the basin the results show a large range of plateau and miniplateau ages 176 2 1 3 to 183 8 2 4 ma with most dates suggesting a 3 ma 181 184 ma duration for the main sill events the available age database allows correlation of the karoo lip emplacement with the pliensbachian toarcian second order biotic extinction the global warming and the toarcian anoxic event provided that adequate calibration between the 40k and 238u decay constant is made the mass extinction and the isotopic excursions recorded at the base of the toarcian appear to be synchronous with both the increase of magma emission of the karoo lip and the emplacement of the sills the co2 and so2 derived from both volcanic emissions as well as carbon rich sedimentary layers intruded by sills might be the main culprits of the pliensbachian toarcian climate perturbations we propose that the relatively low eruption rate of the karoo lip is one of the main reasons explaining why its impact on the biosphere is relatively low contrary to e g the camp triassic jurassic and siberia permo triassic lips

a short interval of jurassic continental flood basalt volcanism in antarctica as demonstrated by 40ar39ar geochronology a continental flood basalt province the ferrar group kirkpatrick basalt and ferrar dolerite crops out along 3000 km of the transantarctic mountains in antarctica and is temporally related to the break up of gondwanaland although a wide range of dates between 90 and 193 ma have been published for the kirkpatrick basalt it is now recognized that the young dates reflect non ideal behavior of ar in the matrix in order to refine the geochronology feldspar separates have been analyzed by the 40ar39ar incremental heating method the main objectives are to constrain the duration of extrusive activity and the timing of volcanism along the outcrop belt basalt samples have been studied from the three principal outcrop areas yielding the following apparent ages central transantarctic mountains 176 8 0 5 ma south victoria land 176 4 0 4 ma north victoria land 176 6 0 7 ma ages from different stratigraphic levels within each area and from the three different areas are not analytically distinct the data imply that the eruptive activity which produced the kirkpatrick basalt occurred within a short interval of less than about 1 m y at 176 6 1 8 ma over an area which included more than 1200 km of the transantarctic mountains the jurassic volcanism in antarctica represents a short episode of magmatism comparable in duration with other well dated continental flood basalt provinces the linearly extensive outcrop of the ferrar province and the rapid eruption of the lavas suggests that lithospheric stretching exerted a major control on magmatism the poorly constrained age of the bajocian bathonian boundary makes the previously suggested connection between ferrar volcanism and an extinction event at that boundary uncertain

a carbon isotope perturbation at the pliensbachian toarcian boundary evidence from the lias group ne england a perturbation in the carbon isotope record at the time of the pliensbachian toarcian boundary 184 ma in the early jurassic is reported based on new data from yorkshire england two sharp 13 c org negative excursions each with a magnitude of 2 5 and reaching minimum values of 28 5 are recorded in the bulk organic matter record in sediments of latest pliensbachian to earliest toarcian age a similar pattern of negative carbon isotope excursions has been observed at the stage boundary in the sw european section at peniche portugal in 13 c carbonate 13 c wood and 13 c brachiopod records the isotopic excursion is of interest when considering the genesis and development of the later toarcian oceanic anoxic event oae as well as the second order global extinction event that spans the stage boundary furthermore the isotope excursion potentially provides a chemostratigraphic marker for recognition of the stage boundary which is currently achieved on the basis of different ammonite faunas in the nw european and tethyan realms

sedimentary and biological response to sea level and palaeoceanographic changes of a lower middle jurassic tethyan platform margin southern alps italy abstract the sediment succession formed at the platform to basin transition along the western margin of a jurassic tethyan carbonate platform records a cyclicity in the order of 3 10 my these cycles are interpreted as due to sea level fluctuations associated to palaeoceanographic changes of the surface waters as inferred by the evolutionary dynamics of the calcareous nannofossils overimposed to these variations the skeletal composition of the platform succession records a longer term order of 50 my trend of progressive environmental deterioration related to the break up of pangea our case study deals with the venetian platform margin and the lombardian basin of the southern alps italy a lower to middle jurassic platform basin system of the western tethys four depositional sequences have been recognized in the lower to middle jurassic the local sea level curve derived from sequence analysis records a short lived on the venetian platform the skeletal sediment composition of the carbonate platform changed from sinemurian domerian photozoan to toarcian heterozoan assemblages dominated by suspension feeders this change appears due to increased trophic resources the older event of platform demise correlates to the sea level drop of the latest domerian the final drowning of the venetian platform occurred after the early aalenian drop in the sea level among the basin biota calcareous nannofossils represent the major pelagic carbonate producer since the beginning of the jurassic nevertheless the sinemurian bajocian deep sea carbonates of the lombardian basin consist mainly of allochthonous mud exported off platform with a low nannoplanktonic contribution moreover the platform demise correlates with condensation gaps and mass flows in the basin this relationship suggests that the growth history of the carbonate platform directly controlled the carbonate sedimentation in the adjacent basin the nannofloras recorded in the lower and middle jurassic successions of the lombardian basin consist of two different taxonomic groups the genus schizosphaerella a group of uncertain systematic affinity and several genera of coccolithophorids an inverse correlation between the abundance of schizospheres and coccoliths has been recorded throughout the whole interval investigated moreover during periods of platform and sea level fall schizosphaerella spp dropped in abundance whereas rates of coccolith diversification calculated according to roth s equations reached peak values our evidence shows that schizospheres could be oligotrophic forms while coccolithophorids on the contrary probably diversified during periods of increased nutrient resources the observed sea level falls are in phase with increased trophic resources and holds on up to the transgressive interval the biological response includes a dramatic drop of the platform carbonate productivity and increased corg accumulation on the sea floor the long term evolution of the sedimentary system records increasing eutrophication from liassic to dogger as reflected by the compositional changes of the carbonate producers

distribution of mercury in sediments from kagoshima bay japan and its relationship with physical and chemical factors kagoshima bay is located on the south coast of kyushu island japan submarine fumaroles present in the northern area have been identified as a natural source of mercury in the bay the aim of the present work is to study the spatial distribution of mercury in the bottom sediments of the bay and its relationship with major physicochemical properties that might affect the transport of mercury in the ecosystem surrounding this area sediment core samples were collected in the north and central areas in surveys performed during 2011 and 2013 the individual core samples were sliced and processed for the analysis of total mercury t hg chemical composition total organic carbon toc particle size and magnetic susceptibility the horizontal distribution of t hg indicates that fumaroles are the primary source of hg in the area the results indicate a key role of organic matter binding to hg in the area to the west of the fumaroles the relationship between hg and toc is characterized by two linear trends that correspond to the upper and lower sections of the cores from the physicochemical properties it was suggested that the two distinct linear relations might be caused by a change of the volcanic activity at the aira caldera which is located at the northern part of the bay the extent of the bay impacted by the hg generated from the hydrothermal vents has decreased in recent years and is limited to the vicinity of the emission point

early and mid jurassic molluscan biogeography and the establishment of the central atlantic seaway abstract a new analysis of lower and middle jurassic bivalve faunas of western north america and the southern andes in comparison to europe supported by evidence from other molluscs throws further light on the establishment of a central atlantic epicontinental seaway prior to the formation of a true oceanic strait between eastern north america and africa south america some restriction to free communication persisted until the early callovian but there was an episode of relatively free intermigration in the toarcian to early bajocian time interval which is associated with major rise of sea level one of the most significant consequences of this event was a spread into northwest europe of taxa which were previously confined to the pacific margins to occupy niches vacated as a result of an early toarcian extinction event

stepwise atmospheric carbon isotope excursion during the toarcian oceanic anoxic event early jurassic polish basin abstract during the mesozoic 250 64 ma intervals of about 0 5 myr were subject to severe environmental changes including high sea surface temperature and very low oxygen content of marine water these oceanic anoxic events or oaes occurred simultaneously with profound disturbance to the carbon cycle the carbon isotope anomaly in the early jurassic that marks the toarcian oceanic anoxic event t oae at 182 ma is characterized in marine sections by a series of dramatic steps towards lighter values herein we present new carbon isotope data from terrestrial organic matter phytoclast separates collected through a late pliensbachian middle toarcian coastal and marginal marine succession in the polish basin a setting where hinterland climate and sea level change are well recorded the results show that the shift to light carbon isotope values in the woody organic matter and therefore also in atmospheric carbon dioxide similarly occurred in major steps the steps are here correlated with those identified from marine organic matter where they have previously been attributed to 100 kyr eccentricity forcing of climate the results provide strong support for orbitally and climatically controlled release of isotopically light carbon from gas hydrates into the ocean atmosphere system in a series of rapid bursts additionally a link between the carbon isotope steps and shoreline movements can be demonstrated individual peaks of the negative excursion are mostly associated with facies indicative of sea level rise flooding surfaces however at the same time inferred higher atmospheric carbon dioxide content may be expected to have resulted in increased rainfall and temperature leading to accelerated weathering and erosion and consequently increased sediment supply progradation and regression causing some mismatches between isotope shifts and inferred sea level changes enhanced abundance of megaspores derived from hydrophilic plant groups and marked increase in kaolinite are coincident with the overall development of the negative isotope excursion the combined data suggest that each 100 kyr cycle in carbon isotope values was characterized by increasingly severe palaeoclimatic change culminating in extremely hot and humid conditions co incident with the peak of the final most negative carbon isotope excursion the chemostratigraphic correlation allows very precise dating of the late pliensbachian middle toarcian coastal and marginal marine sedimentary succession in the polish basin

broad terrane jurassic flood basalts across northeastern north america early jurassic tholeiitic lavas that flowed across mesozoic basins of northeastern north america were comagmatic as shown by their geochemistry petrography paleomagnetism radiometric ages and stratigraphy the basin basalts are correlated with diabase dikes that intersect the basins but also extend far outside them if the dikes represent feeders to fissure vents a vast flood basalt province must have extended across the rifted terranes of eastern north america in early jurassic time the initial member of the basalt flood was the most uniform and widespread among present basin remnants of the basalts but subsequent flows may have covered some areas farther from the basins other younger jurassic flood basalts have been described along submarine sections of the continental shelf and shelf break and beneath cretaceous coastal plain sediments in the southeastern united states across the inland mesozoic rift terranes the initial fissure eruptions produced a temporary basaltic plain perhaps 1600 km long and 200 to 400 km wide or roughly 500000 km 2 rivaling other great continental flood basalt provinces

the pliensbachian ammonite dayiceras dayiceroides and early jurassic paleogeography uptonia dayiceroides mouterde is placed in the genus dayiceras and its age established as latest jamesoni zone to possibly earliest domerian the species is abundant and associated with faunas of tethyan aspect along the northeastern pacific margin first occurrences in oregon and nevada and new occurrences in british columbia are reported localities at apparently high paleolatitudes are attributed to post early pliensbachian transcurrent fault displacements genetic continuity with a disjunct population in portugal is postulated via a central atlantic seaway here named the hispanic corridor connecting the eastern pacific and western tethys oceans the existence of this corridor during the pliensbachian is supported by several lines of independent paleobiogeographic evidence

high resolution chemostratigraphic records from lower pliensbachian belemnites palaeoclimatic perturbations organic facies and water mass exchange asturian basin northern spain abstract a very high resolution chemostratigraphic study of elemental stable isotope and strontium isotope ratios mg ca 13c 18o and 87sr 86sr performed on belemnites from two lower pliensbachian sections of the asturian basin northern spain is presented here for the first time the samples have been screened for diagenetic alteration using cathodoluminescence and elemental analyses a total of 162 well preserved belemnites analysed show a 13c range between 1 4 and 2 8 v pdb with the lowest values recorded in the jamesoni zone and the highest values in the ibex zone maximum 18o values 0 1 v pdb are recorded in the jamesoni zone while minimum values 3 1 v pdb are observed in the ibex zone the 13c temporal trend of raw and running average values shows a positive excursion during the ibex zone coinciding with development of organic facies this carbon isotope maximum seems to be reproduced in different basins around the world suggesting a probably global effect for this event the strontium isotope stratigraphy reveals a trend comparable to the reference curve with a steep descent from the uppermost part of the jamesoni zone to the davoei zone the occurrence of a reasonably good correlation between 18o and mg ca ratios suggests that both may be useful for the record of marine palaeotemperatures paired curves of averaged temperatures from both proxies indicate a near flat temporal trend of seawater temperatures during the jamesoni zone followed by warming for the ibex zone during the uppermost ibex to lowermost davoei zones the two curves show divergence this divergence may be consistent with a brief episode of influx of warmer and saltier waters from the southern equatorial oceans tethys panthalassa during the ibex davoei transition previously reported for other basins followed by a return to cooler temperatures during the davoei zone the latter suggests the interruption of the connection with the equatorial oceans in this basin resulting in a greater influence of cooler waters from the northeastern parts of the european epicontinental sea

evaluating the temporal link between the karoo lip and climatic biologic events of the toarcian stage with high precision u pb geochronology the karoo large igneous province k lip is considered to have substantially influenced global warming marine anoxia and concomitant marine extinction in the toarcian lower jurassic the sequence and duration of these events has been uncertain thus precluding direct comparison between sedimentary successions and the k lip two relatively narrow time intervals of the early toarcian one approximately within the lower portion of the h falciferum ammonite zone and the other near the pliensbachian toarcian boundary pl to b have received much attention because they are associated with carbon isotope excursions cies and marine extinctions potential causal mechanisms have been proposed such as the release of massive amounts of carbon to the atmosphere via a catastrophic magmatic intrusive episode related to the k lip here we test the timing with four new high precision ca id tims u pb zircon ages from the toarcian stage collected from tephra interstratified with ammonite bearing carbonates in southernmost peru we also present new u pb zircon and baddeleyite data from three sills and one rhyolite of the k lip in south africa our new data permit a substantial reinterpretation of the toarcian timescale the pliensbachian toarcian boundary pl to b a prominent global extinction level must be older than 183 5 ma on the basis of our oldest tephra the h falciferum cie equivalent to the so called toarcian oceanic anoxic event is bracketed by two ash fall bed dates between 183 22 0 26183 22 0 26 and 181 99 0 13 ma181 99 0 13 ma all 2 analytical and tracer errors the cie duration is estimated at approximately 300 ka on the basis of minimum error interpolation of ammonite zone boundaries the base of the h falciferum cie appears to correlate in time with the onset k lip sill emplacement dated by the oldest sill at 183 014 0 072 ma183 014 0 072 ma however sill emplacement appears to have lasted for a minimum of 2 million years at least until 181 31 0 19 ma181 31 0 19 ma which is in disagreement with a short duration of the h falciferum negative cie furthermore our data suggest that the timing of the main volume of the k lip may have been approximately 4 5 ma this prolonged and possibly pulsed magmatic activity of the k lip may be correlated with extinction pulses and climate changes in the middle and late toarcian stage each event occurring within a unique set of global environmental conditions

magnetic properties of fault rocks from the yingxiu beichuan fault constraints on temperature rise within the shallow slip zone during the 2008 wenchuan earthquake and their implications abstract rock magnetic measurements were conducted on fault rocks from the dagou village outcrop at shuiguan town pingwu county sichuan province china which is located on the yingxiu beichuan fault the main fault ruptured in the 2008 wenchuan m s 8 0 earthquake results revealed that magnetic behavior of fault gouge is possibly dominated by paramagnetic siderite and lepidocrocite as well as pyrrhotite thermomagnetic analysis indicated that these fe bearing minerals are readily decomposed once temperature over 250 400 c and form newly ferrimagnetic magnetite maghemite that would increase the magnetization of fault rocks consequently the paramagnetic nature and relatively low magnetization of fresh fault gouge suggest that the shallow fault plane has not been subjected to thermal event over 250 400 c during the wenchuan earthquake this inference can be confirmed by a kinetic model analysis these findings proposed that thermal pressurization was not likely to occur during the wenchuan earthquake at least at the shallow part of slip zone onset of an elastohydrodynamic lubrication mechanism was alternatively discussed using a model in which fault zone containing viscous gouge results indicated that the lubrication pressure could reach up to 30 2 mpa which can widen the gap between the fault surfaces and reduce the area of asperity contact this prediction well matches the reported injection veins within the coseismic shear zone and the largest ground motions associated with lower predominant frequencies and large stress drop during the wenchuan earthquake

black shales and carbon isotopes in pelagic sediments from the tethyan lower jurassic detailed sampling and analysis of jurassic pelagic limestones and marls from italy hungary and switzerland have enabled construction of an isotope stratigraphy across the pliensbachian toarcian boundary with resolution to the zonal level the oxygen isotope record is unremarkable the carbon isotopes however show two positive excursions one relatively minor during the pliensbachian margaritatus zone subnodosus subzone the other more major during the toarcian early falciferum zone where a maximum 13c value of 4 52 pdb is attained these intervals are known to be favoured periods of organic rich sedimentation in diverse parts of the globe and the isotopic excursions are interpreted as a response to abnormally high rates of storage of organic carbon in the sedimentary record a comparable phenomenon has been documented from the cenomanian turonian boundary in the cretaceous where it has been referred to the influence of an oceanic anoxic event some italian sections spanning this lower jurassic interval contain organic rich shales in the falciferum zone the isotopic signatures from their included locally manganiferous carbonate betray a considerable diagenetic overprint and they cannot therefore be incorporated in a composite isotopic curve carbon isotopes from the organic carbon itself are extremely negative falling to 33 pdb and in one section examined in detail correlate with the calcium carbonate content of the shales they may reflect a partial change to a non calcified planktonic biota during deposition of this lime poor interval possibly responding to upwelling and increased fertility of near surface waters the onset of upwelling may have been as early as spinatum tenuicostatum zone time that is at the pliensbachian toarcian boundary

the geochemical behavior and isotopic composition of hg in a mid pleistocene western mediterranean sapropel abstract the concentrations of mercury hg and other trace metals ni cu zn mo ba re u and the hg isotopic composition were examined across a dramatic redox and productivity transition in a mid pleistocene mediterranean sea sapropel sequence characteristic trace metal enrichment in organic rich layers was observed with organic rich sapropel layers ranging in hg concentration from 314 to 488 ng g avg 385 with an average enrichment in hg by a factor of 5 9 compared to organic poor background sediments which range from 39 to 94 ng g hg avg 66 comparison of seawater concentrations and sapropel accumulations of trace metals suggests that organic matter quantitatively delivers hg to the seafloor near complete scavenging of hg from the water column renders the sapropel hg isotopic composition representative of mid pleistocene mediterranean seawater sapropels have an average 202hg value of 0 91 0 15 n 5 1 sd and 199hg value of 0 11 0 03 n 5 1 sd background sediments have an average 202hg of 0 76 0 16 n 5 1 sd and 199hg of 0 05 0 01 n 5 1 sd which is indistinguishable from the sapropel values we suggest that the sapropel isotopic composition is most representative of the mid pleistocene tyrrhenian sea

precise re os ages of organic rich mudrocks and the os isotope composition of jurassic seawater rhenium and osmium isotope and abundance data have been obtained on precisely located samples from three suites of immature organic rich mudrocks from jurassic coastal outcrops in england the data provide accurate whole rock ages of 207 12 ma 181 13 ma and 155 4 3 ma for suites of hettangian toarcian exaratum subzone and kimmeridgian sensu anglico wheatleyensis subzone samples these new re os ages are indistinguishable within the assigned analytical uncertainties from interpolated depositional ages estimated from published geological timescales and establish the importance of the re os dating technique for chronostratigraphic studies early diagenetic pyrite nodules possess levels of re and os which are 1 2 orders of magnitude lower than in the enclosing organic rich mudrocks indicating that these elements had already been removed from sediment pore waters at the time of nodule formation thus the re os isotope system in these organic rich mudrocks has been closed since or from very soon after the time of sediment deposition because most of the re 98 and os 95 99 8 in the mudrocks is shown to be hydrogenous the 187os 188os i of the samples is interpreted to be that of contemporaneous seawater the data thereby provide the first estimates of the os isotope composition of jurassic seawater during the earliest jurassic hettangian the seawater 187os 188os ratio was extremely unradiogenic 0 15 it had increased to 0 8 at the end of the early jurassic toarcian 20 ma later while in the late jurassic kimmeridgian the seawater 187os 188os ratio was 0 59 the most likely explanation for the unradiogenic os isotope composition of hettangian seawater is that the contribution of unradiogenic os to the oceans from the hydrothermal alteration of oceanic crust greatly exceeded the input of radiogenic os from the continents at that time this interpretation is in line with observations suggesting that global weathering rates were low in the hettangian and that increased hydrothermal and volcanic activity preceded the break up of pangea the re os ratios of hettangian mudrocks and by inference of contemporaneous seawater are similar to those of mudrocks deposited at later times during the jurassic and argues against the unradiogenic os in hettangian seawater being derived from extraterrestrial meteoritic sources

bivalve palaeobiogeography and the hispanic corridor time of opening and effectiveness of a proto atlantic seaway abstract the hispanic corridor is an embryonic seaway between the eastern pacific and western tethyan oceans that has been postulated to have preceded middle jurassic drifting and the birth of the atlantic ocean by many millions of years in this study the distribution of pectinoid bivalve morphotypes is analysed to examine the origin of the hispanic corridor and its effectiveness during early jurassic times a comparison of pectinoid faunal similarities based on similarity coefficients between various regions at opposite ends of the corridor suggests that it opened progressively during early jurassic times however with this approach it is difficult to exclude alternative dispersal routes and to determine when faunal interchange began analysis of the percentage of pectinoid morphotypes that were 1 present at opposite sides of the corridor 2 simultaneously absent in the western pacific eastern tethys and 3 confined to relatively low palaeolatitudes provides evidence that the hispanic corridor developed from an effective barrier in earlier early jurassic hettangian to sinemurian times into a filter allowing the passage of a few morphotypes during later early jurassic pliensbachian and toarcian times the apparently two way faunal exchange through the hispanic corridor is consistent with the establishment of a megamonsoonal circulation for pangaea which may have caused seasonally changing directions of oceanic surface currents through the corridor

paleotemperature variations of early jurassic seawater recorded in geochemical trends of belemnites from the basque cantabrian basin northern spain abstract here we present new o isotope mg ca and sr ca data of early jurassic belemnites from the basque cantabrian basin of northern spain a succession deposited in a periodically anoxic restricted hemipelagic basin nearly 200 pliensbachian lower toarcian belemnites were collected and examined using optical cathodoluminescence and chemical techniques to constrain the effects of potential diagenetic alteration after a precise diagenetic screening of samples 176 belemnites were selected to provide records of changes in seawater geochemistry and temperature the records show a fairly good correlation of 18o with mg ca ratios r 0 65 and a weak correlation of 18o with sr ca ratios r 0 34 the oxygen isotope data if interpreted in terms of paleotemperature have revealed a period of relatively uniform and warm seawater temperatures during the early pliensbachian followed by a sharp temperature drop during the late pliensbachian earliest toarcian the onset of this cooler period occurred within the protogrammoceras celebratum subzone and the coolest seawater temperatures were reached at the end pliensbachian pleuroceras spinatum zone this was followed by a rapid seawater warming during the harpoceras serpentinus zone of the early toarcian in addition the data set provides new information regarding paleoceanographic conditions for anoxic events in a critical region of connection between the boreal and tethys realms it is the background to relatively high 18o values that prevailed during the anoxic episodes concerning the impact of the early toarcian anoxic event in northern spain the detected 18o and mg ca excursions reached their minimum and maximum respectively during the lower h serpentinus zone while the anoxic black shale interval developed earlier during the upper dactylioceras tenuicostatum lowermost h serpentinus zones

new geochemical evidence for the onset of volcanism in the central atlantic magmatic province and environmental change at the triassic jurassic boundary the late triassic early jurassic was a time of major global change however the fundamental processes driving these changes are less than clear we have determined the re and os abundances and os isotope compositions of marine mudrock samples that span the triassic jurassic boundary in the uk and have established that major isotopic and geochemical shifts in the composition of seawater took place in the latest triassic we argue that these shifts were caused by the sudden initiation of widespread igneous activity within the central atlantic magmatic province associated with rifting of the supercontinent pangea the os isotope composition of seawater responded rapidly to these events demonstrating that the seawater os isotope system has great potential in identifying the nature and precise timing of major environmental change

glendonites from an early jurassic methane seep climate or methane indicators abstract an early jurassic late pliensbachian section margaritatus to spinatum ammonite zone northeast of cremlingen germany revealed three horizons with abundant glendonites calcite pseudomorphs after ikaite caco3 6h2o as well as authigenic carbonates these pseudomorphs have previously been used as indicators for organic and phosphate rich paleoenvironments with near freezing bottom water temperatures stable isotope measurements clearly show that the ikaite glendonite was precipitated at a methane seep location with methanotrophic sulfate reduction as the triggering geochemical process for ikaite formation at the sulfate methane interface the termination of methane seepage probably led to the disintegration of the primary mineral ikaite and successive pseudomorph formation reconstructed paleo bottom water temperatures ca 10 c from belemnites and ostracods indicate temperatures well above the previously observed range of ikaite stability near freezing raising the question if methane seeps are distinct geochemical sites promoting ikaite formation at higher temperatures