mechanical interactions between rigid particles in a deforming ductile matrix analogue experiments in simple shear flow abstract the mechanical interaction between two or more particles is investigated in newtonian simple shear flow the experimental models allow observation of both the particle rotation and the deformation pattern around the particles the finite and instantaneous strain patterns around rigid particles are strongly heterogeneous and asymmetric with high finite strain zones aligned to the direction of maximum finite stretch these correspond to local flow with low vorticity number heterogeneous strain patterns around rigid particles spread over a distance of 1 2 times the particle length and this distance increases with increasing bulk strain where rigid particles are more concentrated these patterns coalesce and the overall pattern is then strongly controlled by the particles and cannot be simply related to the external boundary conditions in rocks the characteristic asymmetric strain pattern around rigid isolated particles is a reliable shear criterion which becomes unreliable with high concentrations of rigid particles particle rotation is significantly disturbed when the distance between adjacent particles of equal size is shorter than their length that is only in very concentrated suspensions of rigid particles in a composite shape fabric the development of the sub fabric corresponding to the smaller minerals will be more disturbed

the motion of rigid ellipsoidal particles in slow flows abstract preferred orientations of fabric elements in tectonites are usually interpreted with reference to two continuum models namely those of march 1932 and jeffrey 1922 it is argued that the first of these is usually inappropriate if the fabric elements are rigid inhomogeneities embedded in a deformable matrix jeffrey s model is more applicable but until recently its use has been limited to problems involving axisymmetric particles and simple flow geometries in this paper jeffrey s equations have been solved numerically in order to investigate the behaviour of more general systems the motions of two particle shapes one a prolate spheroid the other a triaxial ellipsoid are considered in parallel for four specified flow geometries which involve pure or simple shear and combinations of both any departures from particle axisymmetry or from simple flow geometries have a significant effect on particle behaviour compared with that predicted by spheroid simple flow solutions

quantitative radiometric and biostratigraphic calibration of the pennsylvanian early permian cisuralian time scale and pan euramerican chronostratigraphic correlation a quantitative biostratigraphic and radiometric calibration is presented for the pennsylvanian through early permian global time scale based upon high precision isotope dilution thermal ionization mass spectrometer id tims u pb zircon ages for interstratified ash beds in the parastratotype sections of the southern urals of russia twenty four ash bed ages in three outer ramp and basinal sections of the pre uralian foredeep bracket the biotic definitions of global stages and regional substages from the base of the upper pennsylvanian kasimovian stage to the base of the lower permian artinskian stage four additional ash bed ages in two sections of the eastern slope of the urals constrain the global bashkirian and serpukhovian stages quantitative stratigraphic methods conop9 are applied to a compilation of over 2000 bioevents in 22 stratigraphic sections supplemented by our dated volcanic horizons to refine the pennsylvanian early permian global time scale significant shifts in the duration of several stages are demonstrated ranging from one to six million years compared with prior estimates the unprecedented density of radiometric calibration points for the pennsylvanian permian transition provides a high resolution 0 1 ma global chronostratigraphic standard for testing and improving biostratigraphic correlations across euramerica we integrate radiometric ages biostratigraphic correlation and cyclostratigraphic tuning of major cyclothems to the long period 404 ka eccentricity cycle to elucidate the tempo magnitude and forcing of eustatic changes and cyclothemic deposition associated with the waxing and waning of gondwanan ice sheets and establish a pan euramerican chronostratigraphic framework for most of pennsylvanian and early permian time

the pennsylvanian permian transition in the low latitude carbonate record and the onset of major gondwanan glaciation abstract recent studies suggest a marked expansion of glacial ice across much of gondwana beginning in the earliest permian because expansion of glacial ice results in a lowering of sea level the imprint of ice expansion should be evident worldwide as significant exposure event hiatuses or other evidence for sea level drop at or near the pennsylvanian permian boundary this literature review investigates the signature of an early permian expansion of gondwanan ice through examination of stratigraphic records from eight carbonate dominated palaeotropical regions across pangaea tropical carbonate environments are used because most form in tectonically quiescent regions and are sensitive indicators of eustatic change correlation between stratigraphic sections is achieved using the most current biostratigraphic and absolute time constraints available all studied sections show a sequence boundary or basinward shift in facies at or near the pennsylvanian permian boundary supporting the hypothesis of a significant expansion of glacial ice and global eustatic lowstand beginning in the early permian by contrast a series of mid sakmarian kungurian transgression events in the palaeotropics are interpreted to reflect the asynchronous deglaciation of gondwana the stratigraphic framework developed herein will allow for better correlations among stratigraphic records from gondwana and northern pangaea which will ultimately improve the understanding of how carbonate systems respond to global icehouse conditions such as during the late palaeozoic

development of the palaeogeography of pangaea from late carboniferous to early permian abstract old and new well and poorly known lithofacies data of moscovian and artinskian age in the area limited by the arctic sea and central africa the atlantic ocean and the ural mountains have been plotted on present day maps the facies mapped and related environments allow the recognition of a series of different palaeogeographic palaeotectonic units including the late carboniferous to early permian deep sea to palaeo tethyan ocean west siberia kazakhstan continent and uralian kazakhstan tienshan arc uralian foredeep up to the closing arms of the uralian ocean precaspian basin russian platform donets rift basin caucasian moesian dobrogean polish oslo basinal belt syn tectonic hercynian foreland basin intramontane post hercynian basins iran anatolian hellenic dinaric carnic basin branching into the hungarian seaway apennine basin branching into the cantabrian and south portuguese basins oman iraq levantine sicily deep basin and inferred oceanic sea way south peri tethyan platform basins east arabian cratonic basin and north african intracratonic basins the subsidence sedimentation trends of these units were correlated and compared through lithostratigraphic logs bathymetric curves and uncorrected cumulative stratigraphic curves the sets of original and processed data were used to test two different palaeodynamic models a pangaea a model static from late carboniferous to triassic and a mobile pangaea b model with different dextral displacements between laurussia and gondwanaland in the same time interval the best fit for our data requires a strike slip offset of about 800 km from moscovian to artinskian time this model implies a first quasi pangaea or pangaea b assembly at the carboniferous permian transition an ephemeral pangaea b break up driven by an early permian oblique rift across the mediterranean to caribbean areas and a final pangaea a assembly in the mid to late permian the two palinspastic maps describing the model have been cross checked by comparison with an independent set of biogeographic features of late carboniferous and early permian overall floral reptile and marine benthic organism distribution is consistent with the early permian trans pangaea seaway inferred from facies and palaeodynamic analyses

faunal turnover and changing oceanography late palaeozoic warm to cool water carbonates sverdrup basin canadian arctic archipelago abstract carbonate sedimentary rocks in the fosheim hamilton sub basin at the eastern end of the sverdrup basin contain a particularly sensitive record of changing palaeoceanography and faunal turnover during the northward movement of pangaea through the late palaeozoic carboniferous and earliest permian inner ramp carbonates are a photozoan association of colonial corals fusulinids algae and ooids with sparse heterozoan elements crinoids brachiopods and bryozoans based on modern analogues these biotic components reflect warm water oligotrophic marine environments contemporaneous mid ramp and basin biotas are dominated by a heterozoan fauna solitary corals crinoids bryozoans and brachiopods that grew in cooler deeper waters that may have been beneath a thermocline initial cooling began in the latest sakmarian with an influx of cool deep water and climatic deterioration allowing cool and warm waters to mix disrupting the thermocline and producing a sub tropical marine biota whose remains were reworked by storms and re deposited as tempestites faunas are heterozoan crinoids bryozoans brachiopods and sponges with photozoan elements colonial corals and symbiont bearing fusulinids prominent only in inner ramp facies by late artinskian these photozoan components are only present in shallowest basin margin environments artinskian subtropical waters contained somewhat elevated trophic resources that together with mixing of photozoan and heterozoan elements in the subtropical inner ramp produced the greatest faunal diversity seen in the sverdrup basin the biota was completely boreal in nature and warm shallow waters with a warm refuge biota were now supplemented by cool waters derived from the panthalassa ocean profound change took place in the kungurian coincident with localised uplift during the melville disturbance and increased siliciclastic input neritic storm dominated sediments are wholly heterozoan brachiopods bryozoans crinoids and sponges with no remaining photozoan elements nutrient levels are elevated but not eutrophic as indicated by phosphate and glauconite extensive bioerosion numerous infaunal foraminifers and an impressive and diverse shelly biota that during times of high siliciclastic input was replaced by a profuse zoophycos infauna brachiopod and bryozoan faunas are distinctly boreal continued cooling relatively high nutrients as indicated by abundant glauconite and phosphate and decreased siliciclastic input eventually resulted in an abundant heterozoan biota brachiopods bryozoans crinoids and sponges with local gigantism but reduced brachiopod and bryozoan diversity these middle permian rocks may be the coolest water deposits in the sverdrup basin the faunas are still part of a boreal arctic province with strong ties to cool water faunas of uralian basin the succession ends with late permian biosiliceous spiculitic cherts containing accessory heterozoan components brachiopods bryozoans and few crinoids these sediments in part coeval with evaporites and terrestrial red beds on the eastern european platform are interpreted to reflect a combination of cool waters elevated nutrients and mid latitude storminess

magmatic fabric acquisition mechanisms in a syenite results of a combined anisotropy of magnetic susceptibility and image analysis study the structural significance of the anisotropy of magnetic susceptibility ams and acquisition mechanisms of silicate and ferrimagnetic mineral fabrics are investigated in the archean lebel syenite intrusion ontario canada bulk mineral subfabrics are determined by intercept counting of mineral phases in classified digital images of thin sections cut parallel to the principal planes of the magnetic fabric ellipsoids of the samples intensities shapes and principal direction orientations of the resulting intercept ellipsoids are generally similar to the corresponding ams ellipsoids differences are due mainly to bimodal distribution of mineral fabrics observed on foliation planes of some samples showing pre full crystallization textures and structural overprinting in samples deformed after crystallization subfabrics of clinopyroxene and magnetite in samples showing pre full crystallization microstructure are investigated by measuring inertia tensors of individual grain shapes the resulting inertia tensor ellipsoids indicate that magnetic fabrics in these rocks are strongly correlated to the shape preferred orientation of magnetite which is similar to the overall petrofabric of the samples crystal size distributions of clinopyroxene and magnetite indicate that they formed during in situ crystallization and that magnetite probably appeared late in the crystallization and flow history of the magma analysis of preferred orientations of these grains suggests that the petrofabrics of the samples were acquired during flow with strongly interacting grains analogous to a logjam in a river the final characteristics of the ams and silicate petrofabric are the end points of a continuous crystallization and flow history in the magma rather than transient late features

correlation of upper carboniferous pennsylvanian and lower permian cisuralian marine deposits of the peri tethys abstract using available published data and our own unpublished materials a correlation is proposed of marine pennsylvanian middle and upper carboniferous and cisuralian lower permian deposits of some important regions where new data have been collected and or a new interpretation of existing data that were previously not included in the peri tethys stratigraphic correlation program has been given special emphasis was laid on the correlation within the pre caspian region most of the suggested correlations are based on fusulinid biostratigraphy magnetostratigraphic data are used to provide a precise correlation between marine and continental strata in southern urals donets basin central asia and northern caucasus

strain and fabric analyses based on porphyroclast interaction abstract two dimensional computer models of the interaction of elliptical clasts in a variety of kinematic conditions are used to study how clast imbrication and shape fabric development relate to strain and strain history the models provide templates for a known clast density and clast ellipticity that correlate clast imbrication angle of collision and clast shape fabric to strain and kinematics of deformed rocks modeling also shows that the mode of clast interaction plays a significant role in the accumulation of imbricated clasts and the development of shape fabric upon collision between clasts the trains formed can remain fixed or rotate if they rotate imbricated clasts can become independent when they are no longer forced together by the flow based upon the mode of clast and train rotation using the march rotation of passive lines and the jeffery rotation of rigid particles as end members three models are defined in an attempt to simulate the conditions of clast interaction under varying conditions the march fixed train march rotating train and jeffery rotating train models simulate solid state intermediate and magmatic conditions respectively modeling shows that the two march models produce similar results but the jeffery model of train rotation always produces a lower proportion of imbricated clasts and a much weaker shape fabric application of the modeling to the study of a syntectonic granite in the sierra nevada suggests that deformation was dominated by simple shear some k feldspar imbrication and fabric development took place initially in the magmatic stage and culminated in the solid state to produce a large proportion of imbricated k feldspar porphyroclasts which define a strong shape fabric this type of analysis provides a rationale to determine syn vs post emplacement deformation in the granite

shape fabrics of particles in low concentration suspensions 2d analogue experiments and application to tiling in magma abstract jeffery s equations ascribe a theoretical cyclic nature to the shape fabric of non interacting rigid particles immersed in a viscous fluid undergoing simple shear flow this theoretical behaviour is confirmed at low shear strains 5 first experiment 134 identical particles or 1 second experiment 178 particles with two size classes then become stable at 17 first experiment and at more than 50 second experiment of the population of particles due to the contribution of the tiled particles the shape fabric becomes asymmetrical in its orientation distribution with a maximum lying above the shear plane the latter result provides a new shear sense indicator in addition to the statistical determination of the tiled features the study also suggests that crystalline fabrics in magmas could be acquired at high melt fractions i e early in the crystallization history of the magma

strain insensitive preferred orientation of porphyroclasts in mont mary mylonites abstract the shape preferred orientation spo of porphyroclasts was determined in high temperature mylonites the porphyroclasts approach rhomboidal sillimanite or elliptical garnet plagioclase sillimanite shapes and exhibit aspect ratios r as high as 11 particles with r 3 are dominantly rhomboidal the long axis of the best fit ellipse defines a very strong spo inclined at 5 10 to the mylonitic foliation in an antithetic sense with respect to the shear direction this angle is independent of r the inclination of the long sides of rhomboidal sillimanite increases from 10 to 20 with decreasing r in contrast the short sides have a constant orientation of 15 to 17 irrespective of r and are parallel to extensional crenulation cleavage low aspect ratio mainly elliptical objects show low intensity spo close to the shear plane the two spos appear strain insensitive in the case of r r 3 a stable position is acquired this is not explained by any of the current theoretical and experimental models of spo

permian higher latitude bryozoan biogeography abstract bryozoans from gondwana and northern eurasia are within the higher latitude gondwana and boreal realms respectively and display a clear antitropical faunal distribution with lower diversity than tropical realms within these realms however faunas at highest latitudes are the least diverse and dominated by cosmopolitan genera further separate geological and oceanographic developmental histories of the boreal and gondwanan regions have resulted in the boreal realm showing much higher diversity than its southern counterpart gondwana was in a high latitude position during the permian experiencing the polar climatic conditions of the late palaeozoic ice age and the distribution of bryozoans show a distinct diversity decrease towards cold water high latitudes where the eurytopic fenestrates and trepostomes were the dominant groups the eastern australian margin with the least diverse faunas of the gondwanan realm is oriented north south as a narrow shelf hindering the migration of taxa into the southern coldest environments in contrast northern hemisphere mid to high latitude basins experienced cooling through the permian as pangaea moved northward and tectonics altered oceanographic circulation however glaciomarine deposits were not widespread even at highest latitudes the marine shelf of the northern eurasian margin was broad and oriented west east allowing establishment of widespread stable faunas in waters that became increasingly nutrient fed through the permian from cool water upwelling from the panthalassa ocean in the west this cool water mid latitude setting west east shelf and nutrient enrichment resulted in a boreal realm bryozoan fauna of over 100 genera more diverse than the gondwanan realm with only 61 genera antitropical taxa restricted to boreal and gondwanan realms only include diploporaria lyropora and metelipora however a number of other genera are more abundant outside the tropics even if they occur in all realms these genera include alternifenestella rectifenestella polypora polyporella shulgapora dyscritella stenopora streblascopora pinegopora maychella maychellina ramipora tabulipora and hexagonella the wide nutrient fed mid latitude shelf of the boreal realm also allowed development of a number of endemic taxa or taxa that are rare elsewhere including permoheloclema timanodictya permofenestella lyrocladia wjatkella parafenestralia triznella and gilmouropora in southern gondwana endemic taxa are limited to crockfordia and paramaychella however there is an abundance of evactinostella etherella and liguloclema that are distinctive of western australia

stable positions of rigid objects in non coaxial flow a study in vorticity analysis abstract distortions of a homogeneous fabric which occur around rigid objects in rocks deformed by non coaxial ductile flow are useful to determine the sense of shear but also contain information on other aspects of the flow rigid objects in a non coaxial flow fall into two categories those which are permanently rotating and those which can reach stable positions at high finite strain the orientation of such immobilized objects with respect to eigenvectors of instantaneous flow is a function of the vorticity number of the flow the ratio of instantaneous stretches and the axial ratio of the object in naturally deformed rocks immobilized rigid objects may be recognized from the geometry of the surrounding fabric tails of recrystallized material around porphyroclasts in a mylonite rotate towards parallellism with the extensional eigenvector of the flow and the shape of tails reflects the rotational behaviour of the porphyroclast the axial ratio of immobilized porphyroclasts and their orientation with respect to the tails can theoretically be used to determine the vorticity number of the flow and deviations from isochoric plane strain in practice such an analysis is as yet difficult but a tentative example is given of the way in which the vorticity number can be calculated from a population of feldspar porphyroclasts in a quartzite mylonite from the french pyrenees

a geomagnetic polarity timescale for the permian calibrated to stage boundaries the reverse polarity kiaman superchron has strong evidence for at least three or prob ably four normal magnetochrons during the early permian normal magnetochrons are during the early asselian base ci1r 1n at 297 94 0 33 ma late artinskian ci2n at 281 24 2 3 ma mid kungurian ci3n at 275 86 2 0 ma and roadian ci3r an at 269 54 1 6 ma the mixed polarity illawarra superchron begins in the early wordian at 266 66 0 76 ma the wordian capitanian interval is biased to normal polarity but the basal wuchiapingian begins the beginning of a significant reverse polarity magnetochron lp0r with an overlying mixed polarity interval through the later lopingian no significant magnetostratigraphic data gaps exist in the permian geomagnetic polarity record the early cisuralian magnetochrons are calibrated to a succession of fusulinid zones the later cisuralian and guadalupian to a conodont and fusulinid biostratigraphy and lopingian magnetochrons to conodont zonations age calibration of the magnetochrons is obtained through a bayesian approach using 35 radiometric dates and 95 confidence intervals on the ages and chron durations are obtained the dating control points are most numerous in the gzhelian asselian wordian and changhsingian intervals this significant advance should provide a framework for better correlation and dating of the marine and non marine permian

the development of δ clasts in non linear viscous materials a numerical approach abstract winged porphyroclasts are often used as kinematic or strain indicators in shear zones in particular it has been suggested that the geometry of clasts in mylonites can give information about the rheological behaviour of the matrix around the clast passchier et al 1993 we tested this hypothesis with a numerical finite element simulation of the flow field of a viscous matrix around a relatively rigid clast power law viscous flow properties of the matrix with stress exponents of 1 linear viscous 3 and 5 were tested as well as three different sets of approximately simple shear boundary conditions which are relevant to experimental and or natural situations the simulations show that the flow field is primarily determined by the boundary conditions the stress exponent is of secondary importance in general the different boundary conditions produce two types of flow fields about the rigid clast an eye shaped flow field and a bow tie shaped flow field the former is produced by boundary conditions that approximate simple shear applied at an infinite distance from the rigid clast and the latter is produced by boundary conditions which are equivalent to a shear box or ring shear apparatus although both the shear box and ring shear boundary conditions produce bow tie flow patterns the wing geometries which result from the flow patterns for these two cases can be significantly different the geometry of the wings that develop on a clast is a direct function of the flow field around the clast for linear and non linear rheologies only the ring shear boundary conditions produce wings that show stair stepping i e wings that are parallel but not in the same plane in natural shear zones clasts both with and without stair stepping are observed in comparing geologic observations with experimental or numerical modelling it is essential to understand which boundary conditions are appropriate

a geomagnetic polarity timescale for the carboniferous the geomagnetic polarity pattern for the carboniferous is incompletely known but with the best resolved parts in the serpukhovian and bashkirian hence data from both igneous and sedimentary units are also used in an additional polarity bias evaluation in the tournaisian to mid visean interval polarity is mainly derived from palaeopole type palaeomagnetic studies allowing identification of polarity bias chrons seven polarity bias chrons exist in the mississippian mi1nb to mi4nb with an additional 33 conventional magnetochrons and submagnetochrons mi4r to mi9r the moscovian and gzhelian polarity is best resolved in magnetostratigraphic studies from the donets basin and the southern urals dispute about the reliability of these data is ill founded since an assessment of supporting data from palaeopole type studies suggests that these datasets currently provide the best magnetic polarity data through the pennsylvanian polarity bias assessment indicates a normal polarity bias zone in the kasimovian in the pennsylvanian there are 27 conventional magnetochrons and submagnetochrons pe1n to ci1r and one normal polarity bias chron pe8nb the kiaman superchron begins in the mid bashkirian with clear data indicating brief normal polarity submagnetochrons within the superchron the magnetochron timescale is calibrated using 31 u pb zircon dates and a quantitative bayesian based age scaling procedure

facies analysis and depositional environments of permian carbonates of the venezuelan andes palaeogeographic implications for northern gondwana abstract upper palaeozoic strata in south america were deposited over cratonic areas and in intracratonic basins e g solimoes amazonas parana however in many areas such as venezuela and colombia they are rarely exposed through dense vegetation and the nature of the terrain so that the strata are poorly documented however these strata do have significant implications for the palaeogeography of the time this article reports on a study of the permian carbonates of the palmarito formation exposed throughout the venezuelan andes and discusses the succession of palaeoenvironments and the palaeogeography resulting from detailed field and lab work deposition took place on an extensive ramp which probably dipped gently northwards towards the open ocean much of the palmarito succession shows a general transgressive trend with a few thinner more regressive intervals likely a response to glaciation deglaciation cycles towards the end of the permian in the venezuelan andes region a major sea level fall led to extensive uplift and erosion resulting in a major disconformity between the upper guadalupian carbonates and overlying jurassic red beds the early palmarito tidal flat facies are noteworthy for their sub metre scale mud to sand cycles with incipient palaeosoil fabrics overlying mid outer ramp carbonate facies are characterised by thin storm beds and bioclastic lenses arranged into metre scale coarsening upward cycles succeeding shallow marine inner mid ramp bioclastic grain wacke stones are dominated by an open marine fauna of fusulinids calcareous algae crinoids bryozoans and brachiopods outer ramp facies are wacke mud stones with sponge spicules radiolarians and brachiopod fragments there are similarities between the permian deposits of venezuela and those recorded from guatemala and mexico to the north and from colombia and peru bolivia to the west and southwest where carbonate systems also dominate these facies were all part of a tropical foreland basin setting the mucuchachi basin which contrasts with the other late palaeozoic intracratonic basins in south america evidence provided here demonstrates that a seaway existed between laurentia and gondwana from the early permian through to the late early permian

experimental modelling of mantled porphyroclasts abstract mantled porphyroclasts are commonly used as sense of shear indicators in mylonites analogue experiments have been carried out to model the development of such objects rigid spheres mantled by a viscous plasticene putty mixture with power law behaviour were suspended in an optically transparent newtonian polymer matrix the samples were deformed between two cylinders one placed within the other and with coinciding axes this induces a non coaxial flow between the cylinders and allows the achievement of high finite strain the viscous mantle around the rigid sphere remained undeformed deformed into an ellipsoid or developed wings the final geometry depends mainly on the induced viscosity contrast between the mantle and the matrix which is a function of the flow induced stress on the surface of the mantle winged mantles only develop if the induced viscosity contrast between the mantle and the matrix polymer is sufficiently small if this critical induced viscosity contrast is exceeded the mantled sphere remains undeformed or obtains a stable ellipsoidal shape even at high finite strain shaped winged mantles only develop in simple shear flow if the mantle around a rigid sphere is thin

quartz textures from the simplon fault zone southwest switzerland and north italy quartz textures measured from monomineralic veins within the simplon fault zone show very similar patterns over a strike length of some 30 km the c axes form asymmetric kinked single girdles with variably developed vestiges of crossed girdle limbs the kinking of the girdle may be controlled by the two c axis orientations where double rhomb a slip is possible a strong a maximum lies between 20 and 30 to the lineation in the xz plane which seems too large to be the angle to the bulk shear plane straight single girdle patterns may be possible for strict simple shear in natural fault zones where deformation is in general heterogeneous on all scales kinked single girdles and type i crossed girdle textures are much more common perhaps because such textures provide more freedom to accommodate a general two dimensional strain

experimental determination of crystal melt partitioning of ga and ge in the system forsterite anorthite diopside the crystal liquid partitioning of ga and ge has been measured experimentally between forsterite diopside anorthite and spinel and melts in the pseudoternary system forsterite anorthite diopside at one atmosphere pressure and 1300 c gallium is incompatible with forsterite and diopside d ga 0 024 and 0 19 respectively is only slightly incompatible in anorthite d ga 0 86 and is highly compatible in spinel d ga 4 6 the partition coefficient for ge is within a factor of two of unity for forsterite diopside and anorthite d ge 0 62 1 4 and 0 51 respectively but ge is incompatible in spinel d ge 0 1 the coefficients for the exchange of ga and al and the exchange of ge and si between minerals and melts generally are within a factor of two of unity as is expected from the geochemical coherence of these element pairs in natural samples the application of our results to the interpretation of natural basaltic and mantle samples from the earth and basalts from the moon and the shergottite parent body demonstrates that it is possible to discriminate between different mantle source compositions using ga al and ge si ratios the ge variation among lunar mare basalts may be indicative of a heterogeneous lunar mantle the substantial depletion of ge in chassigny relative to the other snc meteorites may be evidence of either a heterogeneous shergottite parent body spb mantle or of different geochemical behavior for ge in the spb