the composition and its impact on the methane sorption of lacustrine shales from the upper triassic yanchang formation ordos basin china abstract the organic geochemistry mineralogy and methane sorption of lacustrine shales of the upper triassic yanchang formation collected from the south eastern ordos basin were investigated to characterize them and clarify the effects of shale composition on their sorbed gas capacity these yanchang shales have recently been selected as a target area for shale gas exploration in typical terrestrial strata in china the two main sections of these shales containing type ii organic matters chang 7 and chang 9 have relatively high total organic carbon content toc of 2 10 the two shales also have similar mineralogies mainly comprising quartz clay minerals and feldspars both the chang 7 and chang 9 shales are generally in the oil window chang 9 is slightly more mature than chang 7 higher methane sorption capacity was observed for chang 9 than for chang 7 shales determined on a dried basis at 50 c methane sorption measurements were further performed on three samples from which the residual bitumen had been extracted and their corresponding kerogen fractions to gain insight into the effects of shale composition on methane sorption this was significantly higher in solvent extracted samples than in raw samples indicating that residual bitumen largely restricts methane sorption on such shales a positive correlation between the amount of clay minerals and methane sorption capacity of bulk rocks was evident suggesting that clay mineral content is relevant to methane sorption this result was also supported by the much higher methane sorption capacity of solvent extracted shales compared to the extracted kerogen from those shales when measured sorption data was normalized to toc values the effects of both residual bitumen and clay mineral on the methane sorption of bulk rocks have complicated the evaluation of methane sorption on organic matter in these mature shales

stable carbon isotopes of coal derived gases sourced from the mesozoic coal measures in china coal derived large scale gas fields derived from the mesozoic coal measures in china are mainly distributed in the middle lower jurassic coal measures in the tarim junggar and turpan hami basins in northwest china and the upper triassic xujiahe formation coal measure in sichuan basin central china in 2011 the annual production was 21 6 109 m3 and the proved geological reserves were 2485 109 m3 accounting for 21 and 30 of the total in china respectively based on analyses of gas composition and stable carbon isotopes ratios of 203 samples and stable carbon isotopes of 102 co2 samples the following conclusions were made a based on diagnostic plots using the stable carbon isotopic and molecular composition of gas samples alkane gas from the mesozoic coal measures in china is shown to be coal derived b according to the 13c2 vs c2h6 plot of a great number of oil derived and coal derived gases in china it is concluded that gases with 13c2 28 5 are coal derived and those with 13c2 28 5 are oil derived in most cases c among the natural gases from the mesozoic coal measures in china primary coal derived gases with normal carbon isotopic distribution pattern among the c1 c4 alkanes i e 13c1 13c2 13c3 13c4 are dominant d carbon isotopic pattern reversal mainly results from the mixing of coal derived gases having different maturities but the same source and secondly from microbial oxidation of propane e g mu 3 and mu 4 wells in the gumudi gas field junggar basin e co2 in the coal derived gases from the mesozoic coal measures in china has both biogenic and abiogenic origins the biogenic origin is dominant and the abiogenic co2 is mainly found in the kuqa depression in the tarim basin and western sichuan basin f isotopic differences between heavy hydrocarbon gases and methane become less with increasing maturity

geochemistry and sedimentology of the lower silurian longmaxi mudstone in southwestern china implications for depositional controls on organic matter accumulation abstract spatial and temporal changes of lithofacies and abundance of organic matter in mudstones control distribution of prospective unconventional petroleum reservoirs in a sedimentary basin lithofacies characterization is an essential prerequisite to understanding of organic matter accumulation depositional processes and water column chemistry this research combines geochemical analyses and detailed sedimentologic observations in order to investigate the depositional controls on organic matter abundance in the prolific black mudstone of the long 1 member of the lower silurian longmaxi formation in southwestern china six primary lithofacies deposited at variable marine water depths and under differing water column chemistry were identified from an 83 m long core based on microscopic observations of sediment texture and structure and biota and analyses of total organic carbon toc content mineralogy and trace element abundances our results show that toc content is well correlated to biogenic quartz content and the non detrital components of v u mo ni and cu suggesting the accumulation of organic matter in the studied mudstone was controlled by high paleoproductivity and anoxic water conditions the good correlations also suggest that the abundant organic matter was produced by algal blooms which are typically associated with radiolarian thrive because of the symbiotic relationship between algal and radiolarian the low mo toc ratios of the three lithofacies formed in deep anoxic environments were similar to the ratios of modern sediments deposited in anoxic euxinic environments suggesting moderate basin restriction during deposition the mudstone in the lower longmaxi formation may be part of the globally abundant organic rich mudstones of early silurian age whose depositional mechanism have yet to be fully explored the distribution of lithofacies in the studied interval shows an overall trend from deep water to shallow water depositional environments we developed a detailed depositional model to interpret the evolution of depositional environments of the lower longmaxi formation this study provides an example to how better characterize unconventional hydrocarbon systems through coupling of rigorous geochemical and sedimentological analysis

geochemical facies analysis of fine grained siliciclastics using th u zr rb and zr rb sr ratios abstract abundance of the trace elements zr rb sr th and u may provide insight into the sedimentological origin of fine grained siliciclastic sediments provided that the units are derived from similar source areas as demonstrated here with suites of the fine grained jurassic and cretaceous rocks from the barents sea and svalbard zr rb ratios can be interpreted to indicate grain size variations while zr rb sr values reflect variations in the siliciclastic versus carbonate contents the th u ratio can be applied as an indicator of the redox conditions in 3d plots such as presented here the interplay between these geochemical factors can be interpreted in terms of the sedimentological evolution of the depositional basin the geochemical facies analyses show that similar depositional conditions existed on the jurassic shelf in the two studied localities the succeeding prodeltaic cretaceous beds were generally coarser grained and deposited in ventilated depositional conditions

mesozoic cenozoic tectonic relationships between the kuqa subbasin and tian shan northwest china constraints from depositional records abstract stratigraphic profiles in the kuqa subbasin located along the southern flank of the tian shan northwest china display similar mesozoic cenozoic evolutionary sequences of compositional maturity exist in conglomerate clasts sandstone framework grains and detrital heavy minerals the similarity of these time series profiles resulted from orogenesis and intracontinental deformation of the provenance area the ancestral tian shan mineralogical maturities of conglomerates and sandstones increase from triassic to middle jurassic and decrease from upper jurassic lower cretaceous to tertiary this trend parallels a similar decrease in maturity in detrital heavy minerals zircon rutile and tourmaline dominate in middle upper triassic to middle jurassic sandstone whereas unstable hornblende and pyroxene dominate the heavy mineral suites in the tertiary especially in miocene and pliocene strata these compositional trends are coeval with gradual southward migration of alluvial depositional fronts and depositional depocenters from cretaceous to miocene since the pliocene large scale southward migration of alluvial depositional systems occurred while depositional depocenters migrated northward based on the mesozoic cenozoic depositional records the tectonic evolution of the tian shan kuqa subbasin may be divided into five phases 1 in early triassic following compression and uplift since permian gravelly braided river alluvial plain depositional systems developing in the kuqa subbasin characterized by sands of mixed orogenic provenance type derived from the ancestral tian shan 2 from middle triassic to middle jurassic sediment composition of the kuqa subbasin reflects arc orogen and mixed orogenic sand types with extensive planation of the ancestral tian shan and the development of relatively stable coal bearing depositional environments 3 renewed compression uplift of the tian shan occurred in late mesozoic especially in cretaceous with most detrital modes of the kuqa subbasin indicating provenance attributes akin to the south tian shan 4 further intensive compression uplift and probably southward basinward propagation of the south tian shan occurred during miocene and 5 supracrustal gravity gliding and collapse occurred in the tian shan kuqa subbasin probably due to intensive deep compression with rejuvenated uplift and probable southward basinward structural propagation of the south tian shan developing since pliocene observed changes in sediment composition and depositional environment since pliocene time were also controlled by frequent and abrupt climate changes in addition to intensive uplift of the tian shan moreover all depositional records in the kuqa subbasin seem to reflect west to east differences in provenance along the tian shan probably indicating greater exhumation depth in the western tian shan than that in the eastern tian shan since early cretaceous

heterogeneity of the lower silurian longmaxi marine shale in the southeast sichuan basin of china this study characterizes the vertical heterogeneity of the lower silurian longmaxi marine shale in the southeast sichuan basin based on core description thin sections observation geological chemistry data interrogation and qemscan image analysis lithofacies associations mineralogy graptolite species occurrence rock fabrics as well as toc total organic carbon and gas content change noticeably and regularly in the lower silurian longmaxi marine shale within sequence stratigraphic framework lithofacies associations mainly include in situ graptolite rich and siliceous shale in the transgressive systems tract tst micro offsite graptolite rich shale and shale interbedded with siltstone laminaes in the early highstand systems tract ehst and micro offsite graptolite rich and carbonate rich shale in the late highstand systems tract lhst the tst has a greater abundance of diplogratus than ehst and lhst and has a lesser level of monograptus which is conversely higher in the ehst and lhst the tst shale is silica rich while the lhst shale is generally clay rich the ehst shale is more balanced in its silica and clay content than the tst and lhst are the sedimentary structure and fabric of shale shows that shale is homogenous in the tst with laminaes well developed in the ehst but decreasing in the lhst toc and gas content are highest in the tst and decrease upward the tst with high toc high gas content high brittle minerals silica rich and anoxic suboxic to dysoxic sedimentary environment is the most potential shale gas target interval in the study area our research also shows that the toc mainly controls shale gas accumulation and that the redox conditions mainly control the preservation of organic matter the silica also plays a significant role in shale gas content due to its contribution to hydraulic fracturing finally the study proposes a depositional and heterogeneity model for the lower silurian longmaxi marine shale in the study area

a tale of shales the relative roles of production decomposition and dilution in the accumulation of organic rich strata middle upper devonian appalachian basin abstract a new consensus on the processes responsible for organic carbon burial in ancient epeiric seas has emerged more firmly grounded in the uniformitarian framework of modern oceanography and biogeochemistry this consensus recognizes the interdependent roles of sedimentation primary production and microbial metabolism in favor of earlier end member models e g production vs preservation in this study one of the classic stratigraphic sequences upon which the preservation end member was based is re interpreted in light of this new consensus the study employs an extensive new sedimentological biogeochemical database from cores drilled in western new york the database spans over 500 m and 15 my of devonian deposition in the appalachian basin and provides a framework for comparative study of organic matter burial the major conclusions are 1 few organic rich units were deposited under pervasive anoxic sulfidic water columns 2 establishment and breakdown of seasonal thermoclines on annual or longer timescales were the predominant mode of stratification and 3 under such conditions remineralization of bio limiting nutrients may have played a key role in organic matter burial by creating a eutrophication pump this pump may have augmented an already rising nutrient inventory such that productivity levels exceeded the threshold required for development of suboxic to anoxic conditions in sediments and episodically in bottom waters a final conclusion asserts that the master variable for organic matter accumulation was relative sea level change which exerted influence on clastic dilution preservation and production processes sea level rise events led to sediment starvation and organic carbon concentration in distal basin sediments as well as to decreased effectiveness of seasonal mixing and thus longer build up intervals for remineralized nutrients episodic mixing of nutrient enriched bottom waters led to enhanced production ultimately increased clastic sediment delivery and water column mixing during relative sea level fall diluted surface sediment organic content such that respiratory demand could be met by increased oxygen supply thus terminating deposition of strata enriched in organic carbon

sedimentary association of alternated mudstones and tight sandstones in china s oil and gas bearing basins and its natural gas accumulation abstract oil and gas resources are abundant in china s continental sedimentary basins where the main task of exploration has been finding oil for many years in recent years however new discoveries of large scale natural gas have been successively obtained the natural gas mainly exists in the sedimentary association of alternated mudstones and tight sandstones and is dominantly low permeability tight sand gas through the in depth study on gas reservoir analysis diagenetic evolution source rock distribution and hydrocarbon generating behavior natural gas generation and accumulation it is concluded that during the major subsiding stage of large scale lake basins the multicyclic subsiding process of the lake surface controls the development of high quality source rocks the wide distribution of sands and the superimposition of the two types of rocks in the vertical direction the lacustrine muddy source rocks are developed including mud shale carbonaceous mudstone and coal bed which are in the medium high evolution stage and produce mainly gas and the gas generation intensity is high through the analysis of the subsidence evolution processes of the carboniferous permian systems transitional marine continental facies in the ordos basin and the triassic xujiahe formation continental facies in the sichuan basin it is concluded that the widely distributed sandbodies of delta facies although with tight properties are interbedded with source rocks and easy to accumulate natural gases the natural gas is migrated and accumulated within small distance and is characterized by large area accumulation because of the strong hydrocarbon generation capacity big thickness and stable distribution of the underlying mud shale the potential of gas resources should not be underestimated the geocyclicity of china s continental sedimentary basins controls the sedimentary association of alternated mudstones and tight sandstones resulting in superimposed accumulations of shale gas and tight sand gas

the importance of shale composition and pore structure upon gas storage potential of shale gas reservoirs abstract the effect of shale composition and fabric upon pore structure and ch 4 sorption is investigated for potential shale gas reservoirs in the western canadian sedimentary basin wcsb devonian mississippian d m and jurassic shales have complex heterogeneous pore volume distributions as identified by low pressure co 2 and n 2 sorption and high pressure hg porosimetry thermally mature d m shales 1 6 2 5 vro have dubinin radushkevich d r co 2 micropore volumes ranging between 0 3 and 1 2 cc 100 g and n 2 bet surface areas of 5 31 m 2 g jurassic shales which are invariably of lower thermal maturity ranging from 0 9 to 1 3 vro than d m shales have smaller d r co 2 micropore volumes and n 2 bet surface areas typically in the range of 0 23 0 63 cc 100 g co 2 and 1 9 m 2 g n 2 high pressure ch 4 isotherms on dried and moisture equilibrated shales show a general increase of gas sorption with total organic carbon toc content methane sorption in d m shales increases with increasing toc and micropore volume indicating that microporosity associated with the organic fraction is a primary control upon ch 4 sorption sorption capacities for jurassic shales however can be in part unrelated to micropore volume the large sorbed gas capacities of organic rich jurassic shales independent of surface area imply a portion of ch 4 is stored by solution in matrix bituminite solute ch 4 is not an important contributor to gas storage in d m shales structural transformation of d m organic matter has occurred during thermal diagenesis creating and or opening up microporosity onto which gas can sorb as such d m shales sorb more ch 4 per weight percent wt toc than jurassic shales inorganic material influences modal pore size total porosity and sorption characteristics of shales clay minerals are capable of sorbing gas to their internal structure the amount of which is dependent on clay type illite and montmorillonite have co 2 micropore volumes of 0 78 and 0 79 cc 100 g n 2 bet surface areas of 25 and 30 m 2 g and sorb 2 9 and 2 1 cc g of ch 4 respectively dry basis a reflection of microporosity between irregular surfaces of clay platelets and possibly related to the size of the clay crystals themselves mercury porosimetry analyses show that total porosities are larger in clay rich shales compared to silica rich shales due to open porosity associated with the aluminosilicate fraction clay rich sediments low si al ratios have unimodal pore size distributions

geochemistry of shales from the archean 3 0 ga buhwa greenstone belt zimbabwe implications for provenance and source area weathering abstract phyllites from the archean 3 0 ga buhwa greenstone belt zimbabwe were deposited on a stable cratonic platform analyses of the phyllites generally define a single geochemical group based on major and trace element abundances the phyllites are strongly depleted in cao na2o and sr with respect to average archean upper crust by contrast k2o ba and rb are enriched several times relative to average archean upper crust reflecting basin scale k metasomatism transition metals are somewhat depleted whereas high field strength elements are typically enriched relative to average archean upper crust samples generally have fractionated lree patterns average cen smn 2 4 with small negative eu anomalies average eu eu 0 78 and generally flat hrees average gdn ybn 1 3 such geochemical characteristics suggest that the source dominantly consisted of tonalite with less common occurrences mafic volcanic rocks and granite mixing calculations which massbalance the rees and th sc suggest 70 tonalite 15 mafic volcanic rocks and 15 granite as possible proportions for the source of the phyllites a nearby early archean 3 5 ga continental nucleus preserves similar lithologies and is the probable source intense chemical weathering of the source terrane is indicated by premetasomatized chemical index of alteration values of 95 100 nearly complete depletion of cao and na2o and high al2o3 na2o ratios fine grained sediments of comparable age and presumed tectonic setting elsewhere in southern africa show similar geochemical characteristics implying that source area compositions and weathering intensities were similar these mature platformal deposits suggest a tectonically stable environment where intense chemical weathering took place at 3 0 ga across southern africa

influence of paleoenvironmental factors on preservation of organic matter in middle cretaceous greenhorn formation pueblo colorado sedimentological and geochemical studies of the upper cretaceous hartland shale and overlying bridge creek limestone members of the greenhorn formation reveal close associations between abundance of current induced sedimentary structures extent of bioturbation and type of preserved organic matter abundant hydrogen rich organic matter 4 5 wt and low sulfur to organic carbon ratios are characteristic of the laminated facies which lack current induced sedimentary structures sparse hydrogen poor organic matter 0 1 0 5 wt and relatively high sulfur to organic carbon ratios are characteristic of the bioturbated facies which contain numerous sedimentary structures indicative of currents the concentration of oxygen in the benthic environment and the degree of bio urbation of the sediment apparently were determined principally by the rate that oxygen was supplied advectively by currents rather than by the rate of oxygen consumption by decomposition thus paleoclimatic and paleo oceanographic factors that influenced mixing and current strength in the water column profoundly affected the amount and type of organic matter preserved in these units it is proposed that episodes of high river discharge lead to density stratification of the water column and in turn to quiescent oxygen depleted bottom water and high preservation of organic matter thus accounting for the intermittent widespread deposition of organic rich strata during maximum transgression and depth of the greenhorn sea the lateral association of voluminous deltaic deposits with dee water black shales in other elongate or restricted marine basins may have causes similar to those envisioned for the hartland shale and bridge creek limestone members

a detrital heavy mineral viewpoint on sediment provenance and tropical weathering in se asia abstract understanding heavy mineral preservation is important for interpreting generation pathways provenance and geochemistry of sediments despite this many assumptions about heavy mineral stability are based on ancient strata and few studies consider modern sediments particularly those in tectonically active tropical areas such as se asia we report new heavy mineral data on 69 river sand samples from the malay peninsula and sumatra in which one aim was to find provenance indicators specific to these areas identifications were performed using optical microscopy and confirmed with sem eds in the malay peninsula heavy minerals record granitic and contact metamorphic provenance variable amounts of zircon tourmaline hornblende andalusite epidote monazite rutile and titanite and minor amounts of pyroxene apatite anatase garnet diaspore colourless spinel cassiterite and allanite are typical of this source area the composition of assemblages from sumatra indicates contributions from two major sources the modern volcanic arc i and the basement ii abundant pyroxene particularly hypersthene up to 70 is diagnostic of the volcanic arc source vesuvianite garnet andalusite tourmaline chrome spinel rutile anatase and corundum are present only in small amounts

pore pressure migration along a normal fault system resolved by time repeated seismic tomography in this study we outline the space and time variations of body wave velocities during one of the best documented series of normal faulting earthquakes the 1997 umbria marche sequence in central italy we show the first ever observations of rock fracturing and fluid overpressure propagation along a fault system by using space time resolved variations of vp vs anomalies four dimensional variations that accompany earthquake migration and precede large aftershocks the vp vs increase observed before the mid october earthquakes was related to a pore pressure increase on fluid filled cracks in the volume around the fault we also document that such variations are measurable only by using s and p wave arrival times

depositional models for fine grained sediment in the western hellenic trench eastern mediterranean sediment in tectonically active topographically restricted settings of the western hellenic arc eastern mediterranean consists primarily of clayey silt and silty clay failure of metastable sediment temporarily stored on relatively steep slopes is triggered by earthquake tremors and eustatic oscillations redeposition of these materials by gravitative transport has resulted in markedly different lithofacies from site to site most piston cores include three late quaternary stratigraphic units that can be correlated with sections in other parts of the eastern mediterranean numerous radiocarbon age determinations enhance the correlation seven fine grained sediment types are identified in cores from eight distinct depositional environments some muds are closely related to specific environments slump and debris flow deposits on slope and high relief environments or to time well laminated mud during the latest pleistocene mid holocene or to both uniform and faintly laminated muds restricted to trench basins turbiditic and hemipelagic muds are common throughout the study area mud distribution patterns correlate closely with calculated sedimentation rates we propose two depositional models for these sediments the first emphasizes downslope transformations resulting in progressively reduced flow concentration during transport from slump and debris flow turbidity current low density turbidity current or turbid layer mechanisms the distal end member deposits settling from low concentration flows are thick rapidly emplaced fine grained uniform muds closely associated with faintly laminated muds these were ponded in flat trench basin plains planktonic and terrigenous fractions in the turbiditic finely laminated and uniform muds record mixing of materials of gravitative and suspension origin during redeposition this sequence prevails under conditions of minimal stratification of water masses as characterized by the present mediterranean in the second model developed for conditions of well developed water mass stratification well laminated rather than uniform mud prevails as the end product of low concentration flows these very finely laminated and graded muds record particle by particle settling from detached turbid layers concentrated along density interfaces they include material from turbid layers complemented by the normal rain of pelagic material stratification barriers resulted in region wide distribution of such deposits in both slope and trench environments

the ninole basalt implications for the structural evolution of mauna loa volcano hawaii lava flows of the ninole basalt the oldest rocks exposed on the south side of the island of hawaii provide age and compositional constraints on the evolution of mauna loa volcano and the southeastward age progression of hawaiian volcanism although the tholeiitic ninole basalt differs from historic lavas of mauna loa volcano in most major element contents e g variably lower k na si higher al fe ti ca ree and other relatively immobile minor elements are similar to historic and prehistoric mauna loa lavas and the present major element differences are mainly due to incipient weathering in the tropical environment new k ar whole rock ages from relatively fresh roadcut samples suggest that the age of the ninole basalt is approximately 0 1 0 2 ma although resolution is poor because of low contents of k and radiogenic ar originally considered the remnants of a separate volcano the ninole hills are here interpreted as faulted remnants of the old south flank of mauna loa deep canyons in the ninole hills eroded after massive landslide failure of flanks of the southwest rift zone have been preserved from burial by younger lava due to westward migration of the rift zone landslide induced depressurization of the southwest rift zone may also have induced phreatomagmatic eruptions that could have deposited widespread basaltic ash that overlies the ninole basalt subaerial presence of the ninole basalt documents that the southern part of hawaii island had grown to much of its present size above sea level by 0 1 0 2 ma and places significant limits on subsequent enlargement of the south flank of mauna loa

unconventional shale gas systems the mississippian barnett shale of north central texas as one model for thermogenic shale gas assessment shale gas resource plays can be distinguished by gas type and system characteristics the newark east gas field located in the fort worth basin texas is defined by thermogenic gas production from low porosity and low permeability barnett shale the barnett shale gas system a self contained source reservoir system has generated large amounts of gas in the key productive areas because of various characteristics and processes including 1 excellent original organic richness and generation potential 2 primary and secondary cracking of kerogen and retained oil respectively 3 retention of oil for cracking to gas by adsorption 4 porosity resulting from organic matter decomposition and 5 brittle mineralogical composition the calculated total gas in place gip based on estimated ultimate recovery that is based on production profiles and operator estimates is about 204 bcf section 5 78 10 9 m 3 1 73 10 4 m 3 we estimate that the barnett shale has a total generation potential of about 609 bbl of oil equivalent ac ft or the equivalent of 3657 mcf ac ft 84 0 m 3 m 3 assuming a thickness of 350 ft 107 m and only sufficient hydrogen for partial cracking of retained oil to gas a total generation potential of 820 bcf section is estimated of this potential approximately 60 was expelled and the balance was retained for secondary cracking of oil to gas if sufficient thermal maturity was reached gas storage capacity of the barnett shale at typical reservoir pressure volume and temperature conditions and 6 porosity shows a maximum storage capacity of 540 mcf ac ft or 159 scf ton

mesozoic sedimentary evolution of the northwest sichuan basin implication for continued clockwise rotation of the south china block we present new sedimentary data integrated into a regional mesozoic stratigraphic framework to provide a detailed picture of spatio temporal variations in deposition and depocenter migration of the northwest sichuan basin the mesozoic sedimentary evolution is utilized to interpret basin subsidence history and to unravel coeval basin margin tectonics the northwest sichuan basin together with the songpan ganzi terrane behaved as a passive margin south of the qinling paleo tethys from late paleozoic to early middle triassic times and then evolved into a peripheral foreland basin in response to collision of the north and south china blocks since the late middle triassic coeval with strong north south contraction of the songpan ganzi terrane in the late triassic sinistral transpressional deformation of the longmen shan belt led to flexural subsidence of the adjacent western sichuan basin renewed basin margin fold thrust activity triggered recurrence of flexural subsidence of the northwest sichuan basin since the middle jurassic with the depocenter eventually shifting to the northwestern corner of the basin in the early cretaceous sedimentary evolution of the northwest sichuan basin and the basin margin deformation imply that the south china block had been rotating clockwise relative to the north china block throughout the mesozoic with an interim period of early jurassic tectonic quiescence a model is advanced that invokes clockwise rotation of the south china block as a driver for tectonic evolution of both the basin and adjoining structural belts and provides an explanation for several salient features that are otherwise puzzling

sulige field in the ordos basin geological setting field discovery and tight gas reservoirs abstract the sulige gas field in central ordos basin is one of the largest gas fields in china with about 860 7 billion cubic meters bcm of proven gas reserve this field covers an area of about 500 km 2 with largely tight clastic reservoirs the upper carboniferous lower permian deltaic sandstones and upper permian lacustrine mudstones deposited in a stable cratonic tectonic setting form an effective petroleum system that is favorable for gas accumulation in large scale stratigraphic lithologic traps based on wire line log response drilling stem test and core data a generalized classification system was developed for the gas reservoirs of the sulige field thus type i and ii rocks are capable of gas production without natural and or artificial fracturing type iii rocks are capable of gas production after artificial fracturing and type iv rocks are too tight to produce at commercial rates even with artificial fracturing the discovery of the sulige field not only adds large gas reserve in the ordos basin but strongly indicates the overlook potential of both tight sandstone reservoir rock and relatively porous and permeable sweet spots in it

a compositional classification for grain assemblages in fine grained sediments and sedimentary rocks reply abstract a tripartite compositional classification is proposed for sediments and sedimentary rocks that have grain assemblages with greater than 50 percent of a weight or volume of particles smaller than 62 5 m 4 phi tarl terrigenous argillaceous contains a grain assemblage dominated by more than 75 percent of particles of extrabasinal derivation including grains derived from continental weathering and also volcanogenic debris carl calcareous argillaceous contains less than 75 percent of particles of extrabasinal derivation debris and among its intrabasinal grains contains a preponderance of biogenic carbonate particles including carbonate aggregates sarl siliceous argillaceous contains less than 75 percent of particles of extrabasinal derivation and contains a preponderance of biogenic siliceous particles over carbonate grains these three classes of fine grained particulate sediments and rocks effectively separate materials that have distinct depositional settings and systematic contrasts in organic matter content and minor grain types in the subsurface the grain assemblages that define these classes follow contrasting and predictable diagenetic pathways that have significant implications for the evolution of bulk rock properties and thus assigning a fine grained rock to one of these classes is an important first step for predicting its economic and engineering qualities for purposes of description these three class names can be joined to modifier terms denoting rock texture more precise compositional divisions specific grain types of notable importance and diagenetic features

characterization of depositional conditions for lacustrine oil shales in the eocene jijuntun formation fushun basin ne china abstract the strike slip fushun basin hosts a lacustrine oil shale interval of ca 50 300 m in the eocene lutetian jijuntun formation the oil shale deposits consist of the lower lean oil shale unit losu and the upper rich oil shale unit rosu in outcrop areas the identified depositional cycles of ca 8 10 m and 5 8 m in thickness record the stacking of massive and non laminated oil shales in the losu and fine and coarse laminated oil shales in the rosu respectively depositional conditions in the paleo jijuntun lakes were synoptically reconstructed based on sedimentary features trace element and organic geochemical proxies oxic to suboxic fresh water conditions were prevailing in the paleo jijuntun lakes during deposition of the losu and then evolved into oxygen deficient fresh to mildly brackish water conditions during deposition of the rosu as revealed by the concentrations of redox and salinity sensitive trace elements e g v ni v cr ni co and sr ba ratios and boron content in the oil shales warm to cool and humid to arid climate represented by e g sr cu and rb sr ratios could result in the deepening of water column from ca 20 30 m to ca 100 m and saline stratification superposed on pre existing thermal stratification in the paleo jijuntun lakes a systematical decrease approximately one order of magnitude in the concentrations of most trace elements except for boron and co in the coaly oil shale in the lowermost losu relative to those in the other oil shales in the jijuntun formation indicates the significant change of organic matter om input from higher plant especially coaly materials to aquatic plankton this is partly consistent with the variations of om input from terrestrial higher plant and aquatic organisms type ii kerogen in the losu to lacustrine algae type i kerogen in the rosu as revealed by biomarkers the slight to significant enrichment or depletion of few trace elements i e mn and mo in these immature to low mature oil shale deposits may be associated with low to moderate productivities of aquatic plankton and or incompletely oxygen free conditions in the paleo jijuntun lakes

mineralogical and geochemical compositions of late permian coals and host rocks from the guxu coalfield sichuan province china with emphasis on enrichment of rare metals abstract this paper reports the geochemical and mineralogical compositions of the late permian no 25 coal semi anthracite and its host rocks roof and floor strata from the guxu gulin xuyong coalfield sichuan province china the coal is characterized by medium sulfur content average 2 73 and has an average ash yield of 20 95 in contrast to other late permian coals from southwestern china that are enriched in sc v cr co ni and cu the no 25 coal does not contain an abundance of these transition elements but is rich in lithophile elements be y nb zr hf and u the elevated concentrations of trace elements in the no 25 coal were probably derived from the felsic intermediate rocks at the top of the emeishan basalt sequence rather than from the emeishan mafic basalts the floor strata of the no 25 coal can be divided into two sub sections the upper sub section of the sequence immediately below the no 25 coal consists of material with a felsic intermediate composition probably derived from terrigenous sources and the lower sub section is composed of mafic tuff the terrigenous mineral matter in the no 25 coal appears to have the same sediment source region as the upper sub section of the floor strata based on their similar geochemical compositions the roof strata of the no 25 coal are more quartzose and were probably derived from a different sediment source region the mineral matter in the coal is dominated by kaolinite and to a lesser extent calcite and pyrite the roof and floor strata each have quite different mineralogy with kaolinite dominant in the latter and illite kaolinite and quartz in the former pyrite contents are variable both in the coal and in the host rocks the floor strata and the coal have been affected by hydrothermal solutions leading to the enrichment of rare earth elements and yttrium rey nb ta zr hf and u the rey in the coal and floor strata as well as the nb ta zr hf and u in the floor strata represent potentially economic rare metal resources

multiple controls on the paleoenvironment of the early cambrian marine black shales in the sichuan basin sw china geochemical and organic carbon isotopic evidence abstract in order to understand the paleoenvironment of the early cambrian black shale deposition in the western part of the yangtze block geochemical and organic carbon isotopic studies have been performed on two wells that have drilled through the qiongzhusi formation in the central and southeastern parts of sichuan basin it shows that the lowest part of the qiongzhusi formation has high toc abundance while the middle and upper parts display relative low toc content redox sensitive element mo and trace elemental redox indices e g ni co v cr u th and v v ni suggest that the high toc layers were deposited under anoxic conditions whereas the low toc layers under relatively dysoxic oxic conditions the relationship of the enrichment factors of mo and u further shows a transition from suboxic low toc layers to euxinic high toc layers on the basis of the mo toc relationship the qiongzhusi formation black shales were deposited in a basin under moderately restricted conditions organic carbon isotopes display temporal variations in the qiongzhusi formation with a positive excursion of 13 c org values in the lower part and a continuous positive shift in the middle and upper parts all these geochemical and isotopic criteria indicate a paleoenvironmental change from bottom anoxic to middle and upper dysoxic oxic conditions for the qiongzhusi formation black shales the correlation of organic carbon isotopic data for the lower cambrian black shales in different regions of the yangtze block shows consistent positive excursion of 13 c org values in the lower part for each section this excursion can be ascribed to the widespread early cambrian transgression in the yangtze block under which black shales were deposited

the fluvial and lacustrine sedimentary systems and stratigraphic correlation in the upper triassic xujiahe formation in sichuan basin china the calcarenites and siliciclastic sandstones in the upper triassic xujiahe formation are key targets of the unconventional gas exploration in sichuan basin to resolve the long debated stratigraphic correlation of the interfingering lithostratigraphic members between the different exploration blocks a facies classification scheme integrating sedimentary structures in borehole images bhi and lithology from wireline logs is calibrated in the cored wells and extrapolated into the noncored wells three major sedimentary systems are recognized in xujiahe by mapping the facies trends and paleocurrent directions in the coarse grained sediments one system may dominate over the others at different times and or locations in the foreland basin in response to the orogenic movements in the surrounding mountains the longmen shan in the northwest of the study area is the main source provenance for the carbonate conglomerates and calcarenites meanwhile the systems in the northeast and southeast deposited the sandstone wedges alternating lacustrine swamp and fluvial sediments are penetrated in both proximal and distal areas in the basin although there is no indication of a basinwide lake in the xujiahe period abundant sandy shale breccia conglomerates containing large shale breccias plant materials and contorted shale blocks in association with thick foreset bedded sandstones suggest subaqueous gravity flows possibly because of the collapse of a multistoried delta front characterization of these dynamic sedimentary systems through multidisciplinary interpretation of the seismic data cores bhi and wireline logs is not only fundamental to the sedimentary analysis but also the exploration strategy in the areas with optimal juxtaposition of reservoir sandstones and coaly source rocks

geochemistry of the sinian cambrian gas system in the sichuan basin china abstract based on the outcrops core samples drilling cuttings seismic and geochemical data natural gases of the sinian cambrian gas system were derived from four sets of over mature high quality source rocks the cambrian qiongzhusi source rock is sapropelic with toc of 1 94 ro eq of 1 83 3 90 and a thickness of 140 m on average the sinian 620 541 ma doushantuo source rock is sapropelic with toc of 1 69 ro eq of 2 08 3 83 and a thickness of 11 m on average the 3rd member of the dengying fm is also sapropelic with toc of 1 43 ro eq of 3 16 3 21 and a thickness of 13 m on average the 2nd and 4th members of the dengying fm are dominated by algal dolomite with toc of exhibiting 0 39 ro eq of 1 97 3 46 and a thickness of 246 m on average most of the 13c2 values are lower than 28 and gas dryness is 99 indicating that the natural gas is oil derived with high maturity the high contents of isoparaffins and cycloparaffin suggest that natural gas in the sinian cambrian reservoir was originated from secondary oil cracking the cambrian longwangmiao gas was mainly derived from the cambrian qiongzhusi source rock and the gas within the sinian dengying formation mainly originated from the three sinian source rock layers the area with gas generation intensity superimposed the four sets of source rocks exceeding 6 109 m3 km2 covered 80 of the sichuan basin the proved reserves exceed 1 0 1012 m3 in the sinian cambrian gas system and the accumulated gas resource in the sinian cambrian gas system might exceed 5 1012 m3

sequence stratigraphic architectures and sand body distribution in cenozoic rifted lacustrine basins east china cenozoic rifted lacustrine basins in east china display three main basin types 1 basins with steeply dipping boundary fault whose hanging walls tilt along pivot points 2 basins with listric boundary faults whose hanging walls bend along flexural bending points and 3 basins formed by earlier extensional rifting with later strike slip movement superimposed the sequence development is intimately linked to the tectonic movements in the area where second order sequences are regionally correlatable from basin to basin and relate to the large scale tectonic movements in the region third order sequences are related to local tectonic activity and are correlatable within basins between subbasins and sometimes between neighboring basins detailed sequence stratigraphic analysis and mapping of depositional systems demonstrate that sand body distribution patterns are related to sequence stratigraphic frameworks for the three kinds of basins the positions of pivot point zones flexural bend zones and strike slip faults plus the syndepositional faults all control the distribution of depositional systems systems tract and sand bodies these controlling factors can be attributed to different structural and stratigraphic features that change the accommodation structural elements include boundary faults syndepositional faults and abrupt changes in dip stratigraphic controls include preexisting surfaces with local channelization paleobathymetric lows and onlap onto clinoform slopes the lowstand sand bodies deposited at the downdip end of these controlling factors constitute the current and future exploration targets for conventional reservoirs

preparation of polished thin sections from poorly consolidated regolith and sediment materials abstract good quality polished thin sections can be prepared from poorly consolidated wet fragile and friable regolith and sediment materials in a standard earth science thin section laboratory with only minor additional equipment materials are dried over an acetone bath impregnated with a polyester resin mix and cut and polished using minor modifications of standard hard rock thin sectioning equipment and techniques the sections produced are suitable for both optical and electron microscopy and electron probe microanalysis

provenance of tertiary sandstone in the northern qaidam basin northeastern tibetan plateau integration of framework petrography heavy mineral analysis and mineral chemistry abstract an exceptionally thick cenozoic sedimentary succession has developed in the qaidam basin of the northeastern tibetan plateau the provenance remains enigmatic thus more precise investigations are needed an integrated study of sandstone framework petrography heavy mineral analysis and mineral chemistry was adopted to perform provenance analysis of the tertiary sandstones in the northern qaidam basin no individual method exists that can provide comprehensive provenance interpretations on spatial and temporal variations based on three types of data three depositional areas can be distinguished sandstones of area a exhibit relatively high abundances of quartz garnet and zircon as well as relatively high textural maturity implying long distance sources multi composition garnets and tourmalines reveal derivations of metasedimentary rocks and intermediate acidic igneous rocks sandstones of area b are rich in metamorphic lithic fragments epidote and garnet a dominance of fe rich garnets with low mg low mn and variable ca contents and dravites demonstrates predominant derivation of metasedimentary rocks therefore the north qaidam and south qilian terranes are potential source areas for these two depositional areas additionally high metamorphic heavy mineral abundances in the upper formations imply increasing contributions of these two metamorphic belts during the tertiary tectonic uplift however sandstones of area c are characterized by relatively high abundances of feldspar igneous heavy minerals and high fe mn garnet which suggest a main source of igneous rocks the altun and qilian mountains are potential source regions furthermore increasing amounts of feldspar and igneous heavy minerals in the upper formations indicate a significant presence of igneous parent rocks which are most likely a response to the multi stage uplift events in the altun mountains since the early eocene

geochemistry of archean shales from the witwatersrand supergroup south africa source area weathering and provenance with a few exceptions shales from the archean witwatersrand supergroup 2800 ma in south africa are depleted in na ca lile ree and hfse compared to phanerozoic shales cr co and ni are enriched in all witwatersrand shales and fe and mg are high in shales from the west rand groups wrg and lower central rand group crg shales from the crg and uppermost wrg are enriched in na al lile ree hfse and transition metals relative to shales from the lower wrg chondrite normalized ree patterns for all witwatersrand shales are enriched in light ree and exhibit small to moderate negative eu anomalies a positive correlation of ree and al2o3 contents in the shales suggests that ree are contained principally in clay minerals relative to shales from the crg shales from the wrg exhibit depletions of na ca and sr a feature probably reflecting intense chemical weathering of their source rocks cia indices in witwatersrand shales are variable chiefly 70 98 even within the same shale unit such variations reflect chiefly variable climatic zones or rates of tectonic uplift in source areas with perhaps some contribution from provenance and element remobilization during metamorphism compared to present day upper continental crust all but the orange grove roodepoort and k8 shales appear to have been derived from continental sources depleted in lile ree and hfse and enriched in transition metals computer mixing models based on six relatively immobile elements th hf yb la sc co and four source rocks indicate that the relative proportions of granite basalt and komatiite increased with time in sediment source areas at the expense of tonalite the contributions of basalt and komatiite appear to reach a maximum during deposition of the booysens shale and granite during deposition of the k8 shales and possibly during deposition of the orange grove shales

geochemical characteristics of marine and terrestrial shale gas in china abstract although the annual production of shale gas in china was 13 10 8 m 3 in 2014 a systematic study on geochemical and isotopic characteristics of these unconventional gases has not been well addressed in the present study almost all shale gas samples available in china including marine shale gas from the wufeng longmaxi formation in the sichuan basin o 3 w s 1 l and terrestrial shale gas from chang 7 member t 3 y 7 in the ordos basin were collected and analyzed for their geochemical and isotopic compositions the shale gas from the wufeng longmaxi shale is dry gas with an average methane content of 98 38 and records a highest content of ch 4 in the world 99 59 which is consistent with the very high thermal maturity levels of the gas shales that have equivalent vitrinite reflectance eqvro values between 2 4 and 3 6 the 13 c 1 values are correspondingly heavy and record a heaviest 13 c 1 values 26 7 for the shale gases found in the world as well the average values of 13 c 1 13 c 2 and 13 c 3 for the wufeng longmaxi shale gas are 31 3 35 6 and 47 2 respectively displaying a complete carbon isotopic reversal i e 13 c 1 13 c 2 13 c 3 2 h ch4 and 2 h c2h6 has an average value of 148 and 173 respectively also yielding a hydrogen isotopic reversal i e 2 h ch4 2 h c2h6 the chang 7 shale has an average toc content of 13 81 with vitrinite reflectance vro values between 0 7 and 1 2 the chang 7 shale gas is wet gas with an average methane content of 84 90 and is rich in heavy gaseous hydrocarbons c 2 c 5 the respective values of 13 c 1 13 c 2 and 13 c 3 are 48 7 36 4 and 31 3 displaying a positive carbon isotopic distribution pattern i e 13 c 1 13 c 2 13 c 3 the average 2 h ch4 2 h c2h6 and 2 h c3h8 values are 256 244 and 188 respectively and are characterized by a positive distribution pattern i e 2 h ch4 2 h c2h6 2 h c3h8 the differences in gas wetness and carbon and hydrogen isotopic distribution patterns between the shale gases from the wufeng longmaxi and chang 7 shale are attributed to variations in thermal maturity levels co 2 is present in low content in both the wufeng longmaxi and chang 7 shale gases mostly less than 1 13 c values for the co 2 in the wufeng longmaxi formation are between 8 9 and 9 2 indicating an inorganic origin from the cracking of carbonate mineral in the shales under high temperatures in contrast 13 c values of the co 2 in the chang 7 shale gas range from 8 2 to 22 7 indicating an organic origin from the thermal degradation of organic matter helium in both the wufeng longmaxi and chang 7 shale gases is dominantly of curst origin in terms of their r ra ratios that vary from 0 01 to 0 08 positive carbon isotopic distribution pattern is typical of primitive thermogenic gas however it can be converted into complete or partial carbon isotopic reversal patterns due to secondary alteration the causes that yield carbon isotopic reversal include 1 mixing of gases with the same source but different thermal maturity levels 2 secondary cracking of oil or wet gas 3 formation water involved reactions 4 gas diffusion and 5 carbon isotope exchange between alkane gases at high temperature among them carbon isotopic exchange between alkane gases at high temperature is a key factor nine plots have been drawn based on the shale gases from china usa and canada among them the plot of 13 c 2 versus wetness demonstrates a lying s shape with two inflection points on the gas wetness axis the wetness value of 1 4 represents a critical point from pyrolytic gas primary cracking gas to cracking gas secondary cracking gas and whereas the wetness value of 6 marks the end of oil generation on the diagram of wetness versus 13 c shale gases with wetness values greater than 1 6 are characterized by positive carbon isotopic distribution pattern whereas a complete or partial carbon isotopic reversals are observed for shale gases with wetness values less than 1 6

climate and tectonic driven deposition of sandwiched continental shale units new insights from petrology geochemistry and integrated provenance analyses the western sichuan subsiding basin southwest china abstract how the depositional setting efficiently governs the characteristic sandwiched continental shale units remains uncertain which restricts an integrated assessment of organic rich fluvio lacustrine shale reservoirs and accurate estimation of potential natural gas resources here we present new results from petrological observations element geochemical fingerprinting and integrated analyses of heavy mineral basinal subsidence history and sandstone stratum ratio on typical and terrigenous sandwiched like depositional systems of the targeted upper triassic xujiahe formation in the western sichuan subsiding bain southwest china in view of the representative and environment sensitive indices we suggest that passive continental margin and continental island arc dominated by granite to granodiorite source are the major tectonic settings of the provenance and both a more warm humid climate characterized by intensified chemical weathering conditions and a calm tectonically quiescent setting are identified as two major drivers forcing the accumulation and preservation of organic matter in organic rich continental shale units finally a comprehensive depositional model is established for providing new insights into the linkage between palaeoclimatic conditions tectonic pulses and terrigenous clastic sedimentation both the cyclic palaeoclimate fluctuations and episodic tectonic activities are believed to have exerted a very considerable force on development of the unique sandwiched like stratigraphic framework and the coupling interactions between the tectono climatic evolution and fine grained sedimentation are thus also stressed

differentiating the effect of episodic tectonism and eustatic sea level fluctuations in foreland basins filled by alluvial fans and axial deltaic systems insights from a three dimensional stratigraphic forward model many studies of foreland basins have recognized a hierarchical organization in the stacking of sequences deposited by axial deltaic and alluvial fan systems the hierarchy is often explained in terms of the competing control of eustasy and pulsed tectonic subsidence and the different frequencies at which these processes operate unravelling the relative contributions of tectonic and eustatic controls on the sequence stacking pattern is a fundamental question in foreland basin analysis yet this is difficult because of the lack of independent stratigraphic evidence in this study a three dimensional numerical model is presented which aids in the interpretation of alluvial successions in foreland basins filled by transverse and axial depositional systems under conditions of variable tectonism and eustatic sea level change the tectono sedimentary model is capable of simulating the hierarchical stratigraphic response to both eustatic and tectonic forcing and is of higher resolution than previous models of foreland basin filling numerical results indicate that the onset of tectonic activity is reflected by rapid retrogradation of both depositional systems and by widespread flooding and onlap of carbonate sediments syntectonic fluvial patterns on the axial deltaic plain are dominated by bifurcating channels swiftly relocating in response to the general rise in relative sea level induced by flexural subsidence the resulting surface morphology of the axial delta is convex upwards syntectonic eustatic sea level fluctuations result in parasequence scale packages of retrograding and prograding fan and delta sediments bounded by minor flooding surfaces and type 2 sequence boundaries incised channels are rare within the syntectonic parasequences and are formed only during phases of tectonic quiescence when eustatic falls are no longer compensated by the subsidence component in the rise in relative sea level suites of amalgamating axial channels corresponding to multiple eustatic falls delineate the resulting type 1 unconformities coarse grained incised channel fills are found in the zone between the alluvial fan fringes and the convex upward body of the axial delta as the axial streams tend to migrate towards this zone of maximum accommodation

provenance of deep water reservoir sandstones from the jubarte oil field campos basin eastern brazilian margin the provenance of the maastrichtian deep water reservoir sandstones from the jubarte oil field campos basin eastern brazil was studied using an integrated approach that included quantitative petrography conventional heavy mineral analysis garnet mineral chemistry and zircon geochronology the reservoirs are predominantly coarse poorly sorted sandstones with feldspathic composition derived from uplifted basement terrains the fourth and fifth order depositional sequences analyzed show no major variations in composition or in provenance through time however variations in apatite tourmaline presents potential to be used as a parameter for sandstone correlation within the field the composition of heavy minerals indicates derivation from high temperature and low to medium pressure aluminous metapelitic rocks from granites and subordinate mafic rocks derived from the cabo frio tectonic domain and the oriental terrain of ribeira orogen characterizing a supply route from sw to ne the low ztr index as well as the absence of low grade stable heavy minerals and of metasedimentary rock fragments suggest that by the end of cretaceous all supracrustal low grade terrains had already been totally eroded and that plutonic infracrustal rocks were exposed similarly to the present situation the integration of the compositional and textural aspects suggests a tectonically active source area located relatively close to the basin the active tectonic uplift of the basement terrains provided a large volume of coarse poorly sorted sediments carried directly from mountain streams and alluvial fans to deep water the high frequency shifts in apatite tourmaline values support a direct derivation of the deep water sandstones from adjacent alluvial systems with short but differential exposure to weathering the voluminous deposition of such coarse grained and immature turbidites under the general transgressive conditions of the maastrichtian indicates a tectonic rather than eustatic control on their deposition with important implications for the exploration of similar reservoirs in campos basin and in similar basins of eastern brazilian margin

trace elements as palaeoenvironmental markers in strongly mature hydrocarbon source rocks the cretaceous la luna formation of venezuela abstract the late cretaceous la luna formation is the main hydrocarbon source rock formation in venezuela in the lake maracaibo area the formation shows a steep maturation gradient affecting sedimentary organic matter om and clay minerals related to local burial history and thrusting events the influence of the gradient is examined through geochemical organic and inorganic and mineralogical investigations carried out on samples from five cored boreholes in the maracaibo basin the analytical procedure comprises rock eval pyrolysis vitrinite reflectance measurement palynofacies observation major and trace element content determination performed on bulk rock samples or after a sequential leach protocol dop calculation and the examination and analysis of clay mineral assemblages the maturation gradient seems to have had no effect upon the distribution of the trace elements referred to as proxy indicators for palaeodepositional conditions of om rich sediments ba p v mo ni co cu cd cr and mn consequently trace elements appear to be reliable palaeoenvironmental markers they indicate that during the la luna fm deposition the water column must have had variable conditions with high primary production near the surface and the correlative development of euxinic conditions at the bottom this provides further arguments for an upwelling system affecting the northern platform of south america during late cretaceous time the relative scarcity of reactive iron in the depositional environment must have taken an active part in a process involving sulphur and acting on the environmental conditions as well as on om vulcanisation this process favours aliphatic om storage and may be relevant for many other om rich facies or hydrocarbon source rocks

controls on facies distribution and stratigraphic preservation in the ganges brahmaputra delta sequence abundant sediment supply and accommodation space in the bengal basin have led to the development of a major late quaternary delta sequence this sequence has formed in a tectonically active setting and represents an important example of a high energy marine and fluvial high yield continental margin deposit recent studies have detailed the delta s stratigraphy and development noting that tectonics and sediment supply control the ganges brahmaputra more significantly than in many other delta systems these ideas are developed here through a discussion of the effects that spatial and temporal variations in tectonics and sediment supply have had on deltaic processes and sequence character unique and differing stratigraphies are found within thedeltasystem suchthatfine grainedsedimentpreservationisfavoredinareasofactivetectonicprocessessuchasfolding block faulting and subsidence coarse grained deposits dominate the stratigraphy under the control of high energy fluvial processes and mixed fine coarse stratigraphies are found in areas dominantly influenced by eustatic sea level change overlaid upon these spatially varying stratigraphic patterns are temporal patterns related to episodic events e g earthquakes and rivers avulsions and long termchangesinclimate andsediment supply modelingisalsousedtoinvestigatethe influenceofavariable sedimentsupply on sequence character results show that the timing and magnitude of sediment input relative to sea level rise is a significant control on the subaerial extent of the delta and the relative dominance of alluvial and marine facies within the sequence d 2002 elsevier science b v all rights reserved

trace element behavior and redox facies in core shales of upper pennsylvanian kansas type cyclothems the black shale submember of core shales of pennsylvanian kansas type cyclothems is highly enriched in redox sensitive trace elements tes relative to the overlying gray shale submember as well as to many other modern and ancient organic rich deposits controls on trace element behavior in the black shale can be inferred from trace element enrichment factors efs relative to gray shale and the relationship of tes to total organic carbon toc most tes conformed to one of two patterns 1 mo u v zn and pb exhibited moderate efs and strong covariation with toc in samples having 10 wt toc and 2 cu ni cr and co exhibited low efs and moderate to strong covariation with toc in all samples these patterns are inferred to represent different responses to benthic redox conditions the first pattern is characteristic of tes of strong euxinic affinity i e those taken up in solid solution by fe sulfide or involved in other reactions catalyzed by free h2s and resident mainly in authigenic phases whereas the second pattern is characteristic of tes of weak euxinic affinity i e those not strongly influenced by the presence of free h2s and resident mainly in the organic carbon or detrital fractions of the sediment these inferences allowed development of a multiproxy technique for assessing redox facies in black shale samples euxinic conditions were considered to have existed if at least two of four redox indicator trace elements mo u v zn showed euxinic levels of enrichment and nonsulfidic anoxic conditions were inferred otherwise the validity of the procedure is indicated by 1 agreement among all four redox indicators for a large majority of samples 69 of 185 2 among samples yielding a mixed redox signal a systematic sequence of te enrichment v zn mo u and 3 for tes of weak euxinic affinity reduced variance among samples representing each redox facies sequential enrichment may be a response to differential redox thresholds for accumulation e g v or postdepositional remobilization of trace elements e g u and may provide a basis for finer assessment of redox conditions in low oxygen paleoenvironments than permitted by simple classification schemes the multiproxy procedure for redox facies analysis developed in this study is likely to be more reliable than widely used single proxy indicators based on trace elements e g mo authigenic u or v v ni or c s fe systematics e g s toc or dop d 2004 elsevier b v all rights reserved

geochemistry of the miocene oil shale hancili formation in the cankiri corum basin central turkey implications for paleoclimate conditions source area weathering provenance and tectonic setting abstract the geochemistry of oil shale units of hancili formation in the cankiri corum basin central turkey was studied using various chemical analyses the mineralogical composition of the samples were preliminarily investigated using pearson s correlation coefficients of selected elements indicating that the samples contain abundant clay minerals as well as k feldspar and carbonate the k 2 o al 2 o 3 and sio 2 al 2 o 3 ratios indicate that the major proportion of clay minerals is composed of smectite si al ti k na and fe reside in clay minerals while ca mg and mn are mostly associated with carbonates e g calcite and dolomite and phosphorous p is present as apatite the total ree content of the oil shale range from 19 to 113 ppm the chondrite normalized patterns of the oil shale show lree enrichments hree deficits negative eu anomalies and negligible ce anomalies in general major trace and rare earth element abundances suggest that the studied oil shale in the cankiri corum basin are mainly from the intermediate rocks mixed with small amounts of basic rocks and that their source rocks are mostly deposited in the continental collision setting the ree geochemistry of the oil shale suggests that these samples were derived from a consistent terrigenous source and the eu anomaly was inherited from the source rocks the paleoclimate index c value varies between 0 07 and 1 22 reflecting a generally semi arid to humid conditions in addition rb sr 0 22 and sr cu 9 09 ratios support the idea that warm and humid conditions prevailed during deposition of the hancili formation sr ba ratios 0 54 3 7 of the studied samples suggest a paleoenvironment with variable salinity the co variation among this factor and paleoclimate indicators suggest that variations in climatic conditions exerted a primary control on salinity the substantially low c value and rb sr ratio and significantly high ratios of sr cu and sr ba and also elevated carbonate content of four samples indicate that these samples were deposited during hot and arid periods and that the paleoclimate controlled the terrigenous sediment flux to the lake basin the chemical index of alteration cia a cn k ternary diagram and high th u ratios indicate that the parent rocks of the oil shale experienced moderate chemical weathering steady state

elements and phosphorus minerals in the middle jurassic inertinite rich coals of the muli coalfield on the tibetan plateau abstract the content modes of occurrence and origin of elements and phosphorus minerals in the jurassic coals of the muli coalfield on the tibetan plateau were investigated using optical microscopy field emission scanning electron microscopy in conjunction with energy dispersive x ray spectrometry x ray powder diffraction x ray fluorescence spectrometry and inductively coupled plasma mass spectrometry the muli coals l1 and l2 coals are of high volatile a bituminous to medium volatile bituminous rank characterized by low sulfur contents and are generally dominated by the inertinite group macerals predominantly semifusinite and fusinite the l1 coal contains abundant apatite 7 9 on average on an organic matter free basis and alumino phosphate minerals of goyazite gorceixite crandallite group 4 9 on average and accordingly the concentrations of elements f 253 g g on average p 2349 g g sr 526 g g and ba 790 g g are elevated as compared with common world hard coals the deposition of phosphorous bearing minerals in the muli coals was not derived from volcanic input penetration of ca and al rich solutions release of phosphorus from organic matter during plant decay and an appropriate sedimentary environment such as low ph low water table for peat and oxidizing conditions were critical factors in deposition of the phosphorus minerals

a review of anomalous rare earth elements and yttrium in coal abstract coal deposits have attracted much attention in recent years as promising alternative raw sources for rare earth elements and yttrium rey not only because the rey concentrations in many coals or coal ashes are equal to or higher than those found in conventional types of rey ores but also because of the world wide demand for rey in recent years has been greater than supply in addition to anomalies of enrichment or depletion of light medium and heavy rey in coal deposits normalized to upper continental crust post archean australian shale or north american shale composite anomalies of redox sensitive ce and eu and in some cases of non redox sensitive la gd and y could be used as geochemical indicators of the sediment source region sedimentary environment tectonic evolution and post depositional history of coal deposits factors controlling rey anomalies in coal deposits include the geochemistry of terrigenous source rocks ingress of hydrothermal fluids influence of marine environments percolating natural waters volcanic ashes and sedimentary environments of peat formation additionally the smoothness of a normalized rey distribution pattern provides a simple but reliable basis for testing the quality of rey chemical analyses for coal and other sedimentary rocks

detrital fine grained sediment contribution from taiwan to the northern south china sea and its relation to regional ocean circulation article i nfo results of clay mineralogy in 140 samples collected in major rivers and lakes in southwestern taiwan and on the seafloor off taiwan in the northeastern south china sea scs combined with clay mineral records of the pearl river drainage basin rivers in luzon and the south china shelf and slope are used to semi quantitatively evaluate the detrital fine grained sediment contribution of taiwan to the northern scs the clay mineral assemblage of the taiwan sourced sediments consists dominantly of illite average 56 and chlorite 41 with very scarce kaolinite and smectite their respective distribution from the rivers and lakes to the seafloor off taiwan does not show obvious basin wide differences linear correlations of illite chemistry index with illite crystallinity and of illite crystallinity with kaolinite present two end members of provenances the pearl river and taiwan for the south china shelf and slope assuming that kaolinite in the northern scs is provided completely from the pearl river the contribution of taiwan in clay minerals is evaluated as 29 to the south china shelf and 23 to the south china slope respectively accordingly the contribution of the pearl river to the south china shelf and slope is 52 and 31 respectively the luzon arc accounts for the rest of clay mineral components for the northern scs mainly by providing smectite the bashi strait crossed branches of the southward deep north pacific deep water and the northward surface kuroshio current in the western pacific may transport taiwan sourced suspended sediments westwards to the northern scs

linked sequence stratigraphy and tectonics in the sichuan continental foreland basin upper triassic xujiahe formation southwest china abstract intracontinental subduction of the south china block below the north china block in the late triassic resulted in formation of the transpressional sichuan foreland basin on the south china block the upper triassic xujiahe formation was deposited in this basin and consists of an eastward tapering wedge of predominantly continental siliciclastic sedimentary rocks that are up to 3 5 km thick in the western foredeep depocenter and thin onto the forebulge and into backbulge depocenters five facies associations a e make up the xujiahe formation and these are interpreted respectively as alluvial fan transverse and longitudinal braided river meandering river overbank or shallow lacustrine and deltaic deposits this study establishes a sequence stratigraphic framework for the xujiahe formation which is subdivided into four sequences sq1 2 3 and 4 sequence boundaries are recognized on the basis of facies tract dislocations and associated fluvial rejuvenation and incision and systems tracts are identified based on their constituent facies associations and changes in architectural style and sediment body geometries typical sequences consist of early to late transgressive systems tract deposits related to a progressive increase in accommodation and represented by facies associations a b and c that grade upwards into facies association d regionally extensive and vertically stacked coal seams define maximum accommodation and are overlain by early highstand systems tract deposits represented by facies associations d e and c late highstand systems tract deposits are rare because of erosion below sequence boundaries sequence development in the xujiahe formation is attributed to active and quiescent phases of thrust loading events and is closely related to the tectonic evolution of the basin the sichuan basin experienced three periods of thrust loading and lithospheric flexure sq1 lower sq2 and sq3 two periods of stress relaxation and basin widening upper sq 2 and sq3 and one phase of isostatic rebound sq4 paleogeographic reconstruction of the sichuan basin in the late triassic indicates that the longmen mountains to the west consisting of metamorphic sedimentary and pre neoproterozoic basement granitoid rocks was the major source of sediment to the foredeep depocenter subordinate sediment sources were the xuefeng mountains to the east to backbulge depocenters and the micang mountains to the northwest during the late history of the basin this study has demonstrated the viability of sequence stratigraphic analysis in continental successions in a foreland basin and the influence of thrust loading on sequence development

implications of elemental concentrations for provenance redox conditions and metamorphic studies of shales and limestones near pueblo co usa abstract major element and some trace element compositions including the ree of shales carbonate rich shales and limestones of late cretaceous age have been analyzed at two outcrops near pueblo co elemental ratios that are characteristic of the provenance of terrigenous debris that are the least variable with changing percent acid insoluble residue vs percent calcite are th cr la co la lu cn and eu eu the ce ce la sc and la cr ratios however are only constant when greater than 30 of a sample is composed of acid insoluble residue at less than 30 acid insoluble residue these elemental ratios increase markedly the th co and th sc ratios are fairly constant from nearly 0 to about 60 acid insoluble residue above 60 residue these ratios increase due to the high concentration of th in the graneros to hartland shales at everhart ranch the average of the th co th sc th cr la co la sc and la cr ratios are similar to those of the mcs mid continent shales and paas post archean australian shales thus these carbonate rich to carbonate poor rocks analyzed in this study contain terrigenous debris that has been derived from granitoids similar to those that supplied debris to the mcs and paas the ce ce ratios are lower and the mn mn log mn sample mn shales fe sample fe shales values are more positive in the more calcite rich bridge creek and ft hays limestones than in the other units suggesting that they formed in an oxidizing environment the ce ce are the highest and the mn values are the most negative in the graneros to hartland shales suggesting that they formed under more reducing conditions the elemental concentration of one sample relative to that of another sample over a few meters distance usually vary in small amounts e g medians of the ratios of the same elements between adjacent samples ranges from 1 06 to 1 70 however the ratio of elemental concentrations between adjacent samples can sometimes be quite large the least variation of elemental ratios between adjacent samples often occurs within the more carbonate poor shales the greatest variation occurs within the limestones thus trying to decipher local movement of elements due to metamorphism in similar carbonate shale limestone sequences should be done cautiously since local elemental variation due to sedimentary processes can be large

the geochemical characteristics and factors controlling the organic matter accumulation of the late ordovician early silurian black shale in the upper yangtze basin south china abstract organic rich black shale of the upper yangtze basin from the late ordovician and early silurian is considered an excellent source rock in south china the formation and preservation conditions of this resource are revealed by its geochemical characteristics in this study geochemical indices including redox indices v v ni v cr v sc and ni co and primary productivity indices p ti and ba al and paleoclimate clastic flux and sedimentary rate analyses are presented to investigate the accumulation mechanism of organic matter redox indices suggest that a stagnant anoxic environment predominated in the upper yangtze basin during accumulation of wufeng and longmaxi formations in contrast ventilated and oxygenated marine conditions pervaded the upper yangtze basin during deposition of linxiang and guanyinqiao formations the concentrations of v and u demonstrate that accumulation of organic matter was mainly controlled by redox conditions besides such factors as clastic fluxes fresh water inflows or a mixed deposition with a rapid sedimentary rate cannot be ignored due to their influences on organic matter enrichment and preservation however weak co variance relationship of toc content and productivity proxies including p ti and ba al demonstrates that the accumulation of organic matter was not controlled by primary productivity results of the present study suggest a depositional model that stresses the importance of tectonic movements and glacial events on the accumulation and preservation of organic matter the model shows that the upper yangtze basin was a semi restricted basin system influenced by the isolation of xuefeng but also it implies that oxygen depleted bottom water of the basin favored the accumulation and preservation of sedimentary organic matter resulting in the formation of organic rich black shale

development of tectonic cyclothems in rift pull apart and foreland basins sedimentary response to episodic tectonism the thickest part of asymmetric rift pull apart and foreland basin fills commonly consists of large scale hundreds to thousands of metres thick tectonically generated cyclothems of fine grained marine lacustrine or longitudinal fluvial deposits and coarse grained transverse braid plain or alluvial fan deposits the appearance of coarse clastics in these basin fills is typically noted as the time of tectonically rejuvenated source area uplift based on the conceptual tie between relief and coarse grain size and on the application of the davis theory of landform development we propose the opposite interpretation that the commencement of fine grained sedimentation above coarse grained deposits in a tectonic cyclothem is the best indicator of renewed tectonic activity this reinterpretation is more consistent with 1 modern examples 2 the consideration of source area and sedimentary basin geomorphology 3 the disparity between the reaction rates of the various environments to subsidence 4 the disparity between the rates of tectonic uplift and erosion and 5 the controls on elastic wedge progradation in our model extensive coarse grained clastic wedge progradation is an indicator of tectonically quiescent phases

structural and geochronological constraints on the mesozoic cenozoic tectonic evolution of the longmen shan thrust belt eastern tibetan plateau 1 the longmen shan thrust belt in the eastern margin of the tibetan plateau underwent deformation of d1 associated with the late triassic collision between the north and south china blocks followed by deformation of d2 and d3 related to the eastward growth of the tibetan plateau the d1 is marked by moderately tight folds f1 spaced cleavage s1 mineral lineation l1 multistage reactivated faults and top to the south thrusting this deformation initiated before 237 ma and ended at 208 ma the 193 159 ma d2 deformation is top to the southeast directed and normal ductile in nature and was associated with the formation of half graben basins the mesozoic deformation of the longmen shan belt was related to the subduction of the paleo tethys oceanic lithosphere followed by the south china block underneath the songpan ganze terrane the d1 was produced in the pro side of the overriding songpan ganze plate most probably driven by slab corner flow above the retreating south china block the d2 and extensional songpan ganze turbidite basin were produced by roll back and migration of the overriding plate above the retreating subduction zone this model for the deformation from d1 to d2 is similar to a mediterranean style model the d3 is characterized by se ward thrusting with stepwise migration of rapid denudation and dextral strike slip faulting during the late cretaceous to present therefore the longmen shan thrust belt involved mesozoic compressional and extensional events that were overprinted by the late cretaceous to cenozoic compressional event