a combined in situ oxygen silicon isotopic and fluid inclusion study of a chert sample from onverwacht group 3 35ga south africa new constraints on fluid circulation abstract cherts have been extensively used as a proxy of precambrian environmental conditions of the earth cherts from the onverwacht group 3 5 3 3 ga south africa are considered as well preserved and have been used as a paleo oceanic thermometer especially by using the oxygen isotope composition of the chert nevertheless there are several lines of evidence size and number of the quartz veins that fluids circulated through these cherts after their deposition these cherts are composed mainly of microquartz with large quartz veins 100 m and iron carbonates as ankerites a combined study of oxygen silicon and fluid inclusions study have been performed on one chert sample from the onverwacht group in order to assess the effect of these fluid circulations on the chert oxygen and silicon isotopic compositions in situ oxygen and silicon isotopic compositions on microquartz and vein quartz were measured at high spatial resolution using a multicollector cameca 1270 ion probe crpg cnrs nancy moreover fluid inclusions present in the quartz veins are considered to determine the origin and conditions of the fluid circulation three types of primary fluid inclusions carbonic lc aqueous carbonic fluids lc w and aqueous fluid lw have been observed the temperatures of this fluid circulation were determined by microthermometry and using quartz carbonate pair thermometry at between 200 c and 300 c fluid pressures range from 100 mpa to 30 mpa which correspond to depths ranging from 4 to 1 km this evolution could be related to an exhumation associated with a dilution and cooling process this fluid circulation could be associated to the gold bearing fluid responsible of the sheba fairview ore system dated at 3074 6 ma the results of the isotopic study show that these fluid circulations homogenised the oxygen isotope composition but not the entire silicon isotope composition of the microquartz the 18 o value calculated for the fluid show that it equilibrated with carbonate rocks and is similar to the composition of the gold bearing fluid the silicon isotope composition of the microquartz allows determination of the initial 30 si of the microquartz precursor this precursor has been precipitated from a hydrothermal fluid hence a combined 18 o 30 si and fluid inclusion study allows the conditions of the fluid circulation to be constrained and the origins of chert to be determined

quasi biennial fluctuations in sea level pressures over the northern hemisphere abstract an investigation is made into the presence of quasi biennial oscillations qbos in sea level pressure fields over the northern hemisphere using 55 years 1925 79 of seasonally averaged sea level pressure anomalies a series of analyses has been performed in order to systematically isolate and describe the qbos a standard empirical orthogonal function eof analysis of the seasonal anomalies reveals significant nonrandomness at qbo periods the data were then band pass filtered in order to focus on the qbo and a second eof analysis was performed finally a new complex eof analysis technique was applied to the data complex eofs have the advantage of permitting both standing and propagating modes the qbo variance in six standard eofs is essentially confined to four eofs in the filtered data set and compressed into three complex eofs the latter account for 56 of the filtered variance the dominant mode of the complex eof analysis was common to all analyses and has been found in many other s

structure and evolution of the kerguelen heard plateau indian ocean deduced from seismic stratigraphy studies abstract the structure and evolution of the kerguelen heard plateau the northern domain of the kerguelen gaussberg ridge is derived from stratigraphic interpretation of multichannel seismic profiles the kerguelen heard plateau was created between 130 and 100 ma at or near an active spreading center in the gap between the antarctica australia plate and the india plate from the early late cretaceous about 100 ma to the eocene 42 45 ma the kerguelen heard plateau was a shallow marine structure continuously subsiding at a rate of about 20 m ma 1 and covered by pelagic and shelf sediments at 42 45 ma the kerguelen heard plateau and broken ridge were clearly separated by sea floor spreading at the southeast indian ridge from 42 45 ma to the miocene a major gap of sedimentation occurred later the kerguelen heard plateau was covered by pelagic sediments interbedded with thick clastic sedimentary layers coming essentially from kerguelen island

the paleoclimatology of lake baikal a diatom synthesis and prospectus abstract the paleoclimatic archive held in lake baikal sediments is of significant importance given the lake s position in one of the world s most continental regions where there are few continuous high quality records spanning the quaternary here i review diatom and associated biogenic silica records from lake baikal sediments and provide a paleoclimatic synthesis of changes at various timescales over the quaternary i initially highlight major climatic and hydrological aspects of lake baikal as understanding the contemporary system both regionally and within the lake are fundamental to understanding past change interpreted from the sedimentary archive in this respect special attention is given to factors that can affect the integrity of the diatom record most notably dissolution processes these mechanisms are likely to have had a relatively greater impact on the preservation of diatom valves during glacial periods because of overall lower diatom productivity lower diatom numbers and relative increased dissolution during cold periods explains the lack of diatoms and low biogenic silica concentrations found in the lake sediments during glacial periods the biogenic record highlights the nature of the 100 ka cycle especially during the last 800 ka although there is also a strong precessional component further work is needed to reassess biological responses in lake baikal with respect to different orbital forcing mechanisms together with their impacts on evolution and speciation of diatoms the biological record from lake baikal confirms that the last interglacial in central asia lasted approximately 10 5 ka productivity in the lake as inferred from diatom biovolume accumulation rates exhibits millennial scale variability with the occurrence of centennial scale reductions in diatom biomass throughout the last interglacial period the most severe reduction in diatom biomass at c 120 ka bp is concurrent with millennial scale cooling in the north atlantic region links to changes in north atlantic ocean thermohaline circulation via teleconnections are also evident in the nature of the abrupt ecological changes in the lake throughout the last 60 ka linked to ice rafting into the north atlantic otherwise known as heinrich events new robust radiocarbon chronologies for sediments deposited during the late glacial and holocene in lake baikal allow detailed multi decadal records to be constructed for the last 14 000 years cooling events associated with millennial scale cycles are also apparent in the lake baikal record and both the diatom record and oxygen isotope record of the diatom silica highlight that biological responses to these abrupt events are almost simultaneous comparisons made between lake baikal records with others worldwide highlights that many of the holocene cooling events are associated with melt water outburst from the laurentide ice sheet and changes in solar insolation during the last 1000 years snow cover on lake baikal has been inferred from past diatom assemblages and is closely linked to weakening of the north atlantic oscillation allowing increasing intensity of the siberian high to develop and during the 17th and 18th centuries in the last 150 years diatom species have been shown to be sensitive indicators of recent warming however impacts from future global warming will be complex and are likely to impact not only on the balance between endemic and cosmopolitan diatoms throughout the lake but on the balance between siliceous and non siliceous algae and sources of primary productivity

could bacteria have formed the precambrian banded iron formations banded iron formations bifs are prominent sedimentary deposits of the precambrian but despite a century of endeavor the mechanisms of their deposition are still unresolved interactions between microorganisms and dissolved ferrous iron in the ancient oceans offer one plausible means of mineral precipitation in which bacteria directly generate ferric iron either by chemolithoautotrophic iron oxidation or by photoferrotrophy on the basis of chemical analyses from bif units of the 2 5 ga hamersley group western australia we show here that even during periods of maximum iron precipitation most if not all of the iron in bifs could be precipitated by iron oxidizing bacteria in cell densities considerably less than those found in modern fe rich aqueous environments those ancient microorganisms would also have been easily supported by the concentrations of nutrients p and trace metals v mn co zn and mo found within the same iron rich bands these calculations highlight the potential importance of early microbial activity on ancient metal cycling

genetic modelling for banded iron formation of the hamersley group pilbara craton western australia abstract the banded iron formation bif of the hamersley group pilbara craton western australia particularly from the well studied dales gorge member is unique in its lateral stratigraphic and petrological continuity throughout an area exceeding 60 000 km 2 enabling reasonable estimates for the annual input of components to the depository in the model of this paper varying supply of materials for the medley of mesoband types particularly of iron and silica in the oxide bif can be accommodated by the interaction of two major oceanic supply systems 1 surface currents and 2 convective upwelling from mid oceanic ridge mor or hot spot activity both modified by varied input of pyrochastic material 1 the surface currents were saturated in silica and carried minimal iron due to photic precipitation but were periodically recharged by storm mixing precipitation from them gave rise to the banded chert rich horizons including the varves whose regular and finely laminated iron silica distribution resulted from seasonal meteorological influences 2 precipitation from convection driven upwelling of high iron solution from mor or hot spot activity periodically overwhelmed the delicate seasonal patterns of 1 to produce the iron dominated mesobands a wide range of intermediate mesoband types resulted where the deep water supply was modified by varied mor activity or by partial blocking of upwelling waters by surface currents such as by the present el nino during these periods of oxide dominated bif silica was deposited from saturated solution mainly by evaporative concentration and iron by oxidation due to photolysis and photosynthetically produced oxygen superimposed on these supply differences was the varying effect of fine aluminous ash from dominantly northern distal volcanic sources changing the meteorological and depositional conditions occasional input of extremely fi ash during bif precipitation produced mesoband cm scale variations involving increased carbonate silicate precipitation sustained volcanic periods resulted in s macroband deposition chert carbonate silicate bif with shale gradually returning to the dominant hematite magnetite chert bif as the volcanic input waned during volcanic periods the normally high capacity of sunlight to precipitate ferric iron directly by photolytic oxidation of ferrous iron and by photosynthetic production of oxygen was modified by turbidity in the atmosphere aerosols and dust and in the water colloids from reactive ash s surface precipitated ferric hydroxyoxide redissolved in the presence of decaying organic matter in the subphotic zone augmenting the iron content of the zone precursor ferrous carbonates and silicates were precipitated when the iron concentration of this sub photic zone exceeded their respective solubilities during volcanism the increased availability of nutrients particularly phosphorus to surface waters increased the organic contribution despite lower light values leading to an almost total absence of ferric iron oxides in the s macrobands i e no magnetite or hematite cooling of warm silica saturated sea water during these periods of olcanic winter increased the ratio of precipitation of silica to iron which however was still controlled by seasonal conditions intermediate concentrations of organic matter insufficient to totally convert the ferric compounds either during precipitation or diagenesis resulted in overgrowths of magnetite on hematite and eventually in the substantial conversion of hematite to magnetite where higher temperatures were achieved during low grade regional metamorphism changes in sea level to explain facies changes in bif are not required in this model but are not excluded the preferred conditions are for a very low oxygen to anoxic atmosphere a much higher level of mor activity than at present the presence of photosynthetic plankton the absence of si silica secreting organisms and a deep sea water temperature higher than 20 c however none of these conditions is essential to the model a narrow carbonate bank is postulated for part of the fortescue river valley area during marra mamba iron formation times basal hamersley group with bif precipitation on either side the reef is postulated to have grown northward becoming a major shallow water carbonate platform on the pilbara continent during upper marra mamba iron formation and wittenoom dolomite times but ceased to play an important role in subsequent periods

geochemical implications of rare earth element patterns in hydrothermal fluids from mid ocean ridges abstract rare earth element data are reported for vent fluids collected from eight deep sea hydrothermal areas including samples from sediment hosted and bare rock hydrothermal systems the morb normalized ree patterns from these diverse settings are remarkably similar to each other but distinctly different than seawater or basalt being lree enriched and possessing a strikingly positive eu anomaly the ree concentrations making up these patterns vary widely however both on a spatial and temporal basis when plotted against ionic radii these fluid trends are remarkably linear and show the same fractionation patterns exhibited by plagioclase during magma segregation this analysis suggests that the partitioning of the ree between fluid and rock during high temperature hydrothermal alteration of morb is dominated by crystochemical exchange during dissolution and recrystallization reactions at the exposed surfaces of plagioclase phenocrysts a comparison of ree ionic radii in eight coordination indicate that the partitioning of 3ree and 2eu are dominated by chemical substitution for ca 2 and sr 2 respectively these considerations predict that the total 3ree content of vent fluid varies in a systematic way during the transition from an rich morb plagioclase to ab rich hydrothermal plagioclase and that these parameters can be used as indicators of the average extent of alteration inside active hydrothermal systems

classification seasonality and persistence of low frequency atmospheric circulation patterns abstract orthogonally rotated principle component analysis rpca of northern hemisphere 1 month mean 700 mb heights is used to identify and describe the seasonality and persistence of the major modes of interannual variability the analysis is detailed and comprehensive in that 1 a high resolution approximately equal area 358 point grid is used for the virtually maximum possible 35 year period of record 2 a positive bias in the nmc data base in the early 1950s in the subtropics is largely eliminated for the first time and 3 homogeneous separate analyses of each month of the year are carried out detailing the mouth to month changes in the dominant circulation patterns winter results are similar to those of other recent rpca and teleconnection studies except that some less obvious patterns are identified and further detail of the better known patterns is provided two north south dipole patterns are found over the pacific ocean west pacific oscillation and east pacific pattern and over the atla

natural variations of δ30si ratios during progressive basalt weathering hawaiian islands abstract silicon stable isotopes can be used to trace the biogeochemical pathways of si as it moves from its continental sources to its sink in ocean sediments along the way si is incorporated into clay minerals taken up by plants where it forms plant opal and leached into rivers the major land to ocean conduit compared to igneous rocks the waters that drain continents are enriched in heavy si isotopes but the mechanisms that control fractionation have not been elucidated we studied si isotope fractionation along a 4 million yr basaltic soil chronosequence on the hawaiian islands using the natural context of these samples in combination with laboratory experiments we demonstrate that the isotopic composition of dissolved si in weathering systems is determined by the combined effects of rock disintegration clay mineral neosynthesis and si biocycling weathering preferentially releases 28si into solution whereas secondary mineral formation preferentially removes 28si from solution in humid environments leached soils have lost large amounts of this soluble si thus creating a net loss of 30si from the entire soil system as soils develop and greater fractions of si reside in neoformed clay minerals 30sibulk soil values change progressively toward more negative values basalt 30si values are about 0 5 but older soils have 30si values up to 2 5 the difference between the solid and solution 30si values remains more or less constant with progressive weathering and therefore soil water from older soils has a more negative 30si composition in the upper horizons of the hawaiian soils this weathering driven 30si shift is modified by the addition of unweathered primary minerals via dust carrying 30si values of about 0 5 and by biocycling of si via plants producing negative 30si values in phytoliths and positive 30si values in soil solutions derived from upper horizons due to the high concentrations of dissolved si in these near surface layers rivers have more positive 30si values than predicted based on the weathering status of the lower horizons when combined with published 30si values from large rivers worldwide we find that the results from hawaii point to weathering control of si isotopes delivered to the oceans and thus to an important continent ocean linkage that warrants further investigation

interdecadal variations of the thermohaline circulation in a coupled ocean atmosphere model abstract a fully coupled ocean atmosphere model is shown to have irregular oscillations of the thermohaline circulation in the north atlantic ocean with a time scale of approximately 50 years the irregular oscillation appears to be driven by density anomalies in the sinking region of the thermohaline circulation approximately 52 n to 72 n combined with much smaller density anomalies of opposite sign in the broad rising region the spatial pattern of see surface temperature anomalies associated with this irregular oscillation bears an encouraging resemblance to a pattern of observed interdecadal variability in the north atlantic the anomalies of sea surface temperature induce model surface air temperature anomalies over the northern north atlantic arctic and northwestern europe

stratigraphic changes of ge si ree y and silicon isotopes as insights into the deposition of a mesoarchaean banded iron formation in order to determine the origin of silicon si in banded iron formation bif we have undertaken a multi tracer study combining ree y data ge si ratios and si isotopes d 30 si on stratigraphically resolved layers from a 2 95 ga bif from the pongola supergroup south africa si in both si rich and fe rich layers has a common origin represented by a seawater reservoir strongly influenced by continent derived freshwaters 10 and very limited o 0 1 high t hydrothermal fluids as indicated by eu anomalies and y ho ratios the coevolution of d 30 si signatures of si and fe rich

another continental pool in the terrestrial silicon cycle silicon is the second most abundant element on earth and is involved in important terrestrial and marine biogeochemical processes however its terrestrial cycle is not well quantified and there is a missing reservoir in the budget of silicon isotopes water in seas and rivers is enriched in silicon 30 compared with igneous rocks suggesting that there is an unknown continental reservoir that is depleted in silicon 30 now with the help of a new generation mass spectrometer basile doelsch et al have obtained in situ measurements of silicon isotopes in quartz from sandstones in southern france the results showing greater silicon 30 depletion than in any previously reported terrestrial samples suggest that silicified rocks formed from quartz precipitates in soils and groundwaters can account for the missing reservoir silicon is the second most abundant element on earth it is an important nutrient for phytoplankton1 and is readily absorbed by terrestrial vegetation2 it also assists the removal of carbon dioxide from the atmosphere through the weathering of silicates3 but the continental cycle of silicon is not well known and only a few studies have attempted to use silicon stable isotopes 28si 29si and 30si 4 5 6 7 8 9 10 11 12 13 to quantify the continental silicon reservoirs dissolved silicon in sea and river waters forms a reservoir of mean isotopic value 1 1 refs 7 10 it is enriched in 30si with respect to the igneous rocks reservoir which has a mean isotopic value of 0 3 refs 4 9 this enrichment can only be produced by a major fractionation during weathering and should result in the formation of a continental 30si depleted reservoir such a reservoir however has not been identified to date here we analyse silicon isotopes of in situ quartz from a sandstone series in france using a new generation secondary ion mass spectrometry apparatus we show that quartz that precipitates as siliceous cements forms a strongly 30si depleted reservoir with isotopic values down to 5 7 a more negative value than any previously published for terrestrial samples our findings suggest that quartz re precipitation plays an important role in the biogeochemical cycle of silicon

sea ice anomalies observed in the greenland and labrador seas during 1901 1984 and their relation to an interdecadal arctic climate cycle two independent ice data sets from the greenland and labrador seas have been analyzed for the purpose of characterizing interannual and decadal time scale sea ice extent anomalies during this century sea ice concentration data for the 1953 1984 period revealed the presence of a large positive anomaly in the greenland sea during the 1960s which coincided with the great salinity anomaly an upper ocean low salinity water mass that was observed to travel cyclonically around the northern north atlantic during 1968 1982 this ice anomaly as well as several smaller ones propagated into the labrador sea and then across to the labrador and east newfoundland coast over a period of 3 to 5 years a complex empirical orthogonal function analysis of the same data also confirmed this propagation phenomenon an inverse relation between sea ice and salinity anomalies in the greenland labrador sea region was also generally found an analysis of spring and summer ice limit data obtained from danish meteorological institute charts for the period 1901 1956 indicated the presence of heavy ice conditions i e positive ice anomalies in the greenland sea during 1902 1920 and in the late 1940s and generally negative ice anomalies during the 1920s and 1930s only limited evidence of the propagation of greenland sea ice anomalies into the labrador sea was observed however probably because the data were from the ice melt seasons on the other hand several large ice anomalies in the greenland sea occurred 2 3 years after large runoffs in the early 1930s and the late 1940s from northern canada into the western arctic ocean similarly a large runoff into the arctic during 1964 1966 preceded the large greenland sea ice anomaly of the 1960s these facts together with recent evidence of climatic jumps in the northern hemisphere tropospheric circulation suggest the existence of an interdecadal self sustained climate cycle in the arctic in the greenland sea this cycle is characterized by a state of large sea ice extent overlying an upper layer of cool relatively fresh water that does not convectively overturn which alternates every 10 15 years with a state of small sea ice extent and relatively warm saline surface water that frequently overturns

si isotope systematics of meteorites and terrestrial peridotites implications for mg si fractionation in the solar nebula and for si in the earth s core abstract high precision si isotope ratios have been measured for a series of meteorites and terrestrial samples using high resolution multi collector icp ms our results differ from those reported in an earlier study georg et al 2007 si in the earth s core nature 447 1102 1106 in two important aspects first our data set reveals systematic differences in 30 si between different chondrite groups that are correlated with their mg si elemental ratio second in agreement with the previous study 30 si for the terrestrial samples are higher than values for chondrites but the difference between the bulk silicate earth bse and the carbonaceous chondrites 30 si bse c arbonaceous chondrites 0 08 0 04 1 standard deviation is about a factor of 2 smaller than previously reported the 30 si versus mg si trend defined by the chondrite groups can be explained by reaction of olivine with a sio rich vapor to form enstatite starting from a carbonaceous chondrite composition in contrast the difference between the bse and carbonaceous chondrites must reflect a different process and can be explained by incorporation of si into the earth s core during metal silicate equilibration in a deep magma ocean the observed si isotope fractionation is consistent with the temperatures and pressures of metal silicate equilibration derived from siderophile element abundances in the earth s mantle

micro scale tracing of fe and si isotope signatures in banded iron formation using femtosecond laser ablation we have detected micrometre scale differences in fe and si stable isotope ratios between coexisting minerals and between layers of banded iron formation bif using an uv femtosecond laser ablation system connected to a mc icp ms in the magnetite carbonate chert bif from the archean old wanderer formation in the shurugwi greenstone belt zimbabwe magnetite shows neither intra nor inter layer trends giving overall uniform d 56 fe values of 0 9 but exhibits intra crystal zonation bulk iron carbonates are also relatively uniform at near zero values however their individual d 56 fe value is highly composition dependent both siderite and ankerite and mixtures between both are present and d 56 fe end member values are 0 4 for siderite and 0 7 for ankerite the data suggest either an early diagenetic origin of magnetite and iron carbonates by the reaction of organic matter with ferric oxyhydroxides catalysed by fe iii reducing bacteria or more likely an abiotic reaction of organic carbon and fe iii during low grade metamorphism si isotope composition of the old wanderer bif also shows significant variations with d 30 si values that range between 1 0 and 2 6 for bulk layers these isotope compositions suggest rapid precipitation of the silicate phases from hydrothermal rich waters interestingly fe and si isotope compositions of bulk layers are covariant and are interpreted as largely primary signatures moreover the changes of fe and si isotope signatures between bulk layers directly reflect the upwelling dynamics of hydrothermal rich water which govern the rates of fe and si precipitation and therefore also the development of layering during periods of low hydrothermal activity precipitation of only small amounts of ferric oxyhydroxide was followed by complete reduction with organic carbon during diagenesis resulting in carbonate chert layers during periods of intensive hydrothermal activity precipitation rates of ferric oxyhydroxide were high and subsequent diagenesis triggered only partial reduction forming magnetite carbonate chert layers we are confident that our micro analytical technique is able to detect both the solute flux history into the sedimentary bif precursor and the bif s diagenetic history from the comparison between coexisting minerals and their predicted fractionation factors

discovering the anomalously cold mediterranean winters during the maunder minimum this work presents an attempt to reconstruct the mediterranean italy climate across one of the coldest interval ad 1645 1715 of the little ice age lia characterized by a prolonged episode of low solar acitivty known as maunder minimum mm lia was characterized by marked climatic variability over this part of southern europe particularly during the mm using a model based on adding subregional details to regional scale reconstruction we estimated for this period a mean winter temperature of 1 c lower than in the baseline period 1961 1990 8 c and the anomaly further lowered down to about 4 c in the winter of 1683 1684 in addition the interannual variability of extreme low temperatures makes the mm an outstanding climatic period there is also some consistency of the empirical evidence with the modelling results that for high resolution wintertime seasonal reconstruction central mediterranean sub regional area shows a colder climate than that represented by coarser simulation of europe

the silica cycle in the precambrian abstract whereas the modem silica cycle is heavily dependent on the biology of silica secreting organisms such as the diatoms the precambrian silica cycle was dominated by inorganic reactions among dissolved silica clay and zeolite minerals and organic matter there is no evidence for deposition of a layered amorphous silica but abundant evidence for diagenetic silicification in the neoproterozoic the time period chosen for this analysis the influx of silica to the neoproterozoic ocean would have been governed as today by the balance among tectonism weathering and hydrothermal input the evidence of neoproterozoic rocks favors tectonic and weathering regimes not very dissimilar to those of the early phanerozoic and hydrothermal inputs significantly altered at certain periods one flux would have been very different the present diffusional influx of silica from interstitial waters into the oceans would have been altered to an efflux from the oceans to interstitial waters reactions of dissolved silica with inorganic phases would have controlled silica concentrations at a level of about 60 ppm this figure is based on experimental determinations of solubility and silica sorption on clay minerals and zeolites as silica in interstitial waters was lowered by opal ct precipitation a diffusional efflux from the ocean into the sediment was set up silicification would have started in early diagenesis as opal ct precipitated from interstitial waters diffusion of silica from overlying seawater declined as the sediment was buried a few hundred meters and the diffusion path lengthened during this still relatively shallow burial silicification continued but this time powered by hydrologie transport of dissolved silica from coastal plain sediments during transgressions and regressions thus the major removal of silica from the neoproterozoic ocean took place by diagenetic reactions

role of atmospheric circulation with respect to the interannual variability in the date of snow cover disappearance over northern latitudes between 1988 and 2003 1 this paper analyzes the main spatial patterns in the dates of snow cover disappearance variability over northern latitudes between 1988 and 2003 the dates of snow cover disappearance were calculated using satellite passive microwave data from the special sensor microwave imager spatial and temporal patterns were obtained using principal components analysis in the s mode we identified eight components each representing a large region characterized by homogeneous interannual variability in the dates of snow cover disappearance we found that atmospheric circulation summarized by means of teleconnection indices had an important impact on the date of snow cover disappearance for most of these regions a role is played by the arctic oscillation in western siberia the spring east atlantic west russian pattern in central siberia and the pacific north

quasi biennial and quasi decadal variations in snow accumulation over northern eurasia and their connections to the atlantic and pacific oceans abstract spatial and temporal characteristics of winter snow depth variation over northern eurasia and their connections to sea surface temperatures ssts and associated atmospheric circulation anomalies surface air temperatures and precipitation are examined by using 60 yr 1936 95 of station data records this study found that snow depth variation over the region east of the caspian sea and west of china explaining 10 1 of total snow depth variance has a quasi biennial variability of about 2 5 yr the snow depth variation over central european russia and western central siberia explaining 8 1 of the total snow depth variance has a quasi decadal variability of about 11 8 yr the snow depth variation over the northern ural mountains explaining 7 5 of the total snow depth variance has variability of about 8 and 14 yr the quasi biennial snow depth variation is associated with ssts over the northern north pacific and tropical western atlantic extending into the gulf of mexico the associated at

on the relationship between tropical and north pacific sea surface temperature variations abstract empirical orthogonal function analysis of winter sea surface temperature sst anomalies over the pacific domain 60 n 20 s reveals an el nino southern oscillation enso mode that is linked to the eastern north pacific and a north pacific mode that is linearly independent of enso the north pacific mode exhibits maximum amplitude and variance explained along 40 n west of 170 w ssts in this region have decreased by 1 5 c from 1950 to 1987 the cooling in winter has been associated with a strengthening of the overlying westerly winds

a teleconnection study of interannual sea surface temperature fluctuations in the northern north atlantic and precipitation and runoff over western siberia abstract the spatial distributions of northern north atlantic sea surface temperature and the high latitude northern hemisphere sea level pressure anomalies averaged over six consecutive warm sst winters 1951 1956 and six consecutive cold sst winters 1971 1976 are examined three slp anomaly difference i e warm cold winters centers significant at the 5 level are observed over the northern north atlantic europe and western siberia this anomaly pattern is consistent in principle with what was identified in a related analyses by palmer and sun who used composite data from selected winter months the slp difference centers over the northern north atlantic and western siberia are in phase the impact of the latter center upon the runoff from the underlying oh and yenisey rivers and especially the teleconnection between sst anomalies in the northern north atlantic and runoff of those two rivers via the atmosphere are investigated the temporal cross correlation analyses of 50 years 1930 1979

the role of sea ice and other fresh water in the arctic circulation salinity stratification is critical to the vertical circulation of the high latitude ocean we here examine the control of the vertical circulation in the northern seas and the potential for altering it by considering the budgets and storage of fresh water in the arctic ocean and in the convective regions to the south we find that the present day greenland and iceland seas and probably also the labrador sea are rather delicately poised with respect to their ability to sustain convection small variations in the fresh water supplied to the convective gyres from the arctic ocean via the east greenland current can alter or stop the convection in what may be a modern analog to the halocline catastrophes proposed for the distant past the north atlantic salinity anomaly of the 1960s and 1970s is a recent example it must have had its origin in an increased fresh water discharge from the arctic ocean similarly the freshening and cooling of the deep north atlantic in recent years is a likely manifestation of the increased transfer of fresh water from the arctic ocean into the convective gyres finally we note that because of the temperature dependence of compressibility a slight salinity stratification in the convective gyres is required to efficiently ventilate the deep ocean

characteristics of winter precipitation variation over northern central eurasia and their connections to sea surface temperatures over the atlantic and pacific oceans abstract this study reveals spatial and temporal characteristics of precipitation variability and their teleconnections to sea surface temperatures ssts over the atlantic and pacific oceans by analyzing 68 yr of recent precipitation records over the former soviet union in addition to a general increasing trend of about 0 4 mm yr 1 or 6 decade 1 over much of the study region three major modes of precipitation variation are identified a quasi biennial variation of 2 3 yr is found over the region surrounding the caspian and aral seas an el nino timescale precipitation variation of 4 5 yr is present over southern central siberia and is associated with eastern tropical pacific ssts a quasi decadal timescale variation of about 11 12 yr is evident over central european russia this quasi decadal precipitation variation is closely linked to a major sst anomaly pattern of alternating latitudinal belts over the atlantic and sst variations over the equatorial pacific ocean these associations to ssts are str

enso like interdecadal variability 1900 93 a number of recent studies have reported an enso like eof mode in the global sea surface temperature sst field whose time variability is marked by an abrupt change toward a warmer tropical eastern pacific and a colder extratropical central north pacific in 1976 77 the present study compares this pattern with the structure of the interannual variability associated with the enso cycle and documents its time history back to 1900 the analysis is primarily based on the leading eofs of the sst anomaly and anomaly deviation fields in various domains and the associated expansion coefficient or principal component time series which are used to construct global regression maps of sst sea level pressure slp and a number of related variables the use of anomaly deviations i e departures of local sst anomalies from the concurrent global mean sst anomaly reduces the influence of global mean sst trends upon the structure of the eofs and their expansion coefficient time series an important auxiliary time series used in this study is a southern oscillation index based on marine surface observations by means of several different analysis techniques the time variability of the leading eof of the global sst field is separated into two components one identified with the enso cycle related variability on the interannual timescale and the other a linearly independent residual comprising all the interdecadal variability in the record the two components exhibit rather similar spatial signatures in the global sst slp and wind stress fields the sst signature in the residual variability is less equatorially confined in the eastern pacific and it is relatively more prominent over the extratropical north pacific the corresponding slp signature is also stronger over the extratropical north pacific and its counterpart in the cold season 500 mb height field more closely resembles the pna pattern the amplitude time series of the enso like pattern in the residual variability reflects the above mentioned shift in 1976 77 as well as a number of other prominent features including a shift of opposite polarity during the 1940s

spells of low frequency oscillations and weather regimes in the northern hemisphere abstract the low frequency variability in the midlatitudes is described through an analysis of the oscillatory phenomena in order to isolate nearly periodic components of the atmospheric flow the multichannel version of the singular spectrum analysis m ssa is developed and applied to an nmc 32 year long set of 700 hpa geopotential heights in the same way that principal component analysis identifies the spatial patterns dominating the variability m ssa identifies dynamically relevant space time patterns and provides an adaptive filtering technique three major low frequency oscillations lfos are found with periods of 70 days 40 45 days and 30 35 days the 70 day oscillation consists of fluctuations in both position and amplitude of the atlantic jet with a poleward propagating anomaly pattern the 40 45 day oscillation is specific to the pacific sector and has a pronounced pacific north american pna structure in its high amplitude phase the 30 35 day mode is confined over the atlantic region

rare earth element systematics of the chemically precipitated component in early precambrian iron formations and the evolution of the terrestrial atmosphere hydrosphere lithosphere system irrespective of provenance age and metamorphic grade the chemically precipitated component in early precambrian 2 3 ga iron formations ifs displays smyb cn 1 which reflects the corresponding ratios of contemporaneous seawater in conjunction with end if end shale jacobsen and pimentel klose 1988a b this rare earth element ree signature reveals that the ree distribution in early precambrian ifs must be explained by mixing between a marine bottom and a surface water component and that the rees and by analogy the fe cannot be derived from weathering of a continental source eusm n ratios of detritus free ifs are controlled by the marine bottom water component where eusm cn 1 results from ree input from high temperature high t hydrothermal fluids which received their ree signature during high t alteration of oceanic crust at spreading centres decreasing eusm cn of ifs with decreasing depositional age reflect the vaning importance of high t compared to low t 200 c hydrothermal fluids hence oceanic crust alteration for the ree budget of marine bottom waters and are related to decreasing upper mantle temperatures smyb n ratios of detritus free ifs are controlled by the marine surface water component whose ree distribution is affected by the same processes which operate today in the entire ocean mixing calculations reveal that smyb cn in early precambrian marine surface waters was significantly lower than it is today to explain this difference two mechanisms are discussed on the basis of higher pco2 and lower po2 levels of the precambrian atmosphere 1 1 higher co32 in precambrian river and coastal waters and 2 2 redox cycling of the rees at an oceanwide chemocline which separated anoxic and oxic water masses however these processes are synergetic and could have operated in unison the ree distribution in precambrian ifs is described as a result of mixing in a multicomponent system where high t and low t hydrothermal fluids contributed to the marine bottom water and ree input from the dissolved ree pool in river waters after some modification in estuaries dominated the ree distribution in marine surface waters after mixing of bottom and surface waters their combined ree load was quantitatively scavenged onto precipitating iron oxihydroxides or iron carbonates and deposited with the chemically precipitated component after addition of variable amounts of clastic detritus this eventually resulted in the ree distribution observed in precambrian ifs

yttrium and rare earth elements in fluids from various deep sea hydrothermal systems rare earth element ree and yttrium y concentrations were measured in fluids collected from deep sea hydrothermal systems including the mid atlantic ridge mar i e menez gwen lucky strike tag and snakepit the east pacific rise epr i e 13 n and 17 19 s and the lau vai lili and manus vienna woods pacmanus desmos back arc basins bab in the south west pacific in most fluids y is trivalent and behaves like ho chondrite normalized y ree y reen concentrations of fluids from mar epr and two bab sites i e vai lili and vienna woods showed common patterns with lree enrichment and positive eu anomalies ree analysis of plagioclase collected at lucky strike strengthens the idea that fluid ree contents are controlled by plagioclase phenocrysts other processes however such as ree complexation by ligands cl f so42 secondary phase precipitation and phase separation modify ree distributions in deep sea hydrothermal fluids ree speciation calculations suggest that aqueous ree are mainly complexed by cl ions in hot acidic fluids from deep sea hydrothermal systems ree concentrations in the fluid phases are therefore influenced by temperature ph and duration of rock fluid interaction unusual y reen patterns found in the pacmanus fluids are characterized by depleted lree and a positive eu anomaly the demos fluid sample shows a flat y reen pattern which increases regularly from lree to hree with no eu anomaly these manus basin fluids also have an unusual major element chemistry with relatively high mg so4 h2s and f contents which may be due to the incorporation of magmatic fluids into heated seawater during hydrothermal circulation ree distribution in pacmanus fluids may stem from a subseafloor barite precipitation and the ree in demos fluids are likely influenced by the presence of sulfate ions

geochemistry of late archaean stromatolites from zimbabwe evidence for microbial life in restricted epicontinental seas we report comprehensive trace element and sr isotope data for microbial carbonates from the archaean mushandike limestone masvingo greenstone belt zimbabwe the stromatolites have very coherent ree y patterns and share the essential shale normalised characteristics of other archaean marine precipitates positive la and gd anomalies absence of a negative cc anomaly and a strongly superchondritic y ho ratio mixing models constrain the maximum amount of shale contamination to 0 25 1 and calculated detritus free carbonate ree y systematics require precipitation from seawater in terms of light ree over heavy ree depletion however the studied samples are very different from all other known archaean marine precipitates in shale normalised plots the mushandike samples yield a negative slope a very restricted regional input source of the dissolved load is indicated because normalisation with locally occurring tonalite gneiss ree y data yields a pattern closely resembling typical shale normalised archaean marine chemical sediments the disappearance of a negative eu anomaly when patterns are normalised with local tonalite gneiss strengthens this interpretation sr isotope ratios are strongly correlated with trace element contents and ratios which explains the modest scatter in sr isotope ratios as representing minor clastic contamination importantly even the least contaminated samples have very radiogenic initial sr 87 sr 86 ratios 0 7184 implying sr input from an ancient high rb sr source such as the early archaean gneisses of south central zimbabwe a local ancient 3 5 3 8 ga source is also indicated by previously published pb isotope datasets for the mushandike stromatolites this is entirely compatible with the occurrence of 3 7 3 8 ga zircons in quartzites and metapelites from comparably old greenstone belts within less than 150 km of the studied locality comparison of the pb isotope ratios of the mushandike stromatolites with 2 7 and 2 6 ga old stromatolites from the neighbouring belingwe greenstone belt demonstrates differences in initial isotope composition that relate to the extent of exchange with the open ocean the development of numerous basins on old continental crust with water masses variably restricted from the open ocean suggests a lack of strong vertical topography on this late archaean craton c 2004 elsevier b v all rights reserved

a pan atlantic decadal climate oscillation sea surface temperature sst variabilities on time scales of 10 14 years have been documented in various parts of the atlantic ocean here we present observational evidence that these regional variabilities are part of a coherent pan atlantic decadal oscillation pado characterized by zonal bands of sst and wind anomalies stacked in the meridional direction with alternate polarities from the south atlantic all the way to greenland we propose that the interaction of wind evaporation and sst is key to establishing this interhemispherical pado based on results from a new ocean atmosphere coupling model forced by extratropical wind forcing the model successfully reproduces the observed decadal oscillation in both sst and wind velocity over the tropics this decadal extratropical forcing of the tropics is in sharp contrast to the well known tropics to extratropics teleconnection that operates on interannual time scales in association with el nino southern oscillation enso

a modeling study of the relative roles of tropical and extratropical sst anomalies in the variability of the global atmosphere ocean system abstract in three parallel experiments an atmospheric general circulation model has been subjected to observed monthly varying sea surface temperature ssi conditions in each of the following domains near global ocean goga run tropical pacific toga run and midlatitude north pacific moga run four independent realizations were obtained for the model response to the sequence of sst anomalies during the 1946 88 period in each of the above regions the principal modes of coupling between the imposed sst forcing and the simulated northern hemisphere wintertime 5 1 5 mb height field in various experiments have been identified using a singular value decomposition svd procedure the leading svd mode for the goga experiment is qualitatively similar to that based on observational data although the amplitudes of the simulated height anomalies are notably lower than the observed value the sst pattern of this mode resembles that associated with el nino events the accompanying 5 1 5 mb height anomaly i

global scale modes of surface temperature variability on interannual to century timescales using 100 years of global temperature anomaly data we have performed a singular value decomposition of temperature variations in narrow frequency bands to isolate coherent spatio temporal modes of global climate variability statistical significance is determined from confidence limits obtained by monte carlo simulations secular variance is dominated by a globally coherent trend with nearly all grid points warming in phase at varying amplitude a smaller but significant share of the secular variance corresponds to a pattern dominated by warming and subsequent cooling in the high latitude north atlantic with a roughly centennial timescale spatial patterns associated with significant peaks in variance within a broad period range from 2 8 to 5 7 years exhibit characteristic el nino southern oscillation enso patterns a recent transition to a regime of higher enso frequency is suggested by our analysis an interdecadal mode in the 15 to 18 years period range appears to represent long term enso variability this mode has a sizeable projection onto global average temperature and accounts for much of the anomalous global warmth of the 1980s a quasi biennial mode centered near 2 2 years period and a mode centered at 7 to 8 years period both exhibit predominantly a north atlantic oscillation nao temperature pattern a potentially significant decadal mode centered on 11 to 12 years period also exhibits an nao temperature pattern and may be modulated by the century scale north atlantic variability

do archean chemical sediments record ancient seawater rare earth element patterns rare earth elements ree concentrations of archean and proterozoic chemical sediments are commonly used as proxies to study secular trends in the geochemistry of precambrian seawater in addition similarities in the ree signatures of archean chemical sediments and modern seawater have led researchers to argue that some archean rocks originated as biochemical precipitates i e microbial carbonates in shallow marine e g peritidal environments however terrestrial waters including river water and groundwater also commonly exhibit ree fractionation patterns that resemble modern seawater here we present the seawater like ree data for ground

river fluxes of dissolved silica to the ocean were higher during glacials ge si in diatoms rivers and oceans two centric marine diatom species thalassiosira oceanica and thalassiosira antarctica were grown in batch cultures to determine the incorporation of germanium ge and silicon si into siliceous shells opal the results were modeled as ge si isotope fractionation during exponential growth diatoms take up and incorporate ge si from solution without major discrimination against ge during stationary phase growth near silica limitation the antarctic species t antarctica discriminates slightly against ge but integrated ge si opal produced over the latter portion of the growth cycle is indistinguishable from the initial solution ratio these results confirm experiments using radioactive 68ge that showed absence of fractionation during diatom silica uptake azam and volcani 1981 in contrast to two box ocean models that invoke 50 ge discrimination by diatoms to explain the observed excess surface ocean germanium concentration murnane and stallard 1988 froelich et al 1989 and late pleistocene ocean sediment ge si opal records mortlock et al 1991 runs of a 10 box ocean ge and si model pandora with 50 discrimination reproduce the excess surface ocean ge but introduces curvature into the deep ocean ge versus si relationship that is not observed in the oceans thus 50 fractionation is not supported by either cultures or models if diatoms do not fractionate ge si then late pleistocene ge si opal variations in piston cores are caused not by changes in local biosiliceous production and silica utilization mortlock et al 1991 but rather by whole ocean changes in ge si seawater the marine ge si opal record of the last 450 kyr can be modeled as transient oceanic responses to instantaneous continental climate transitions consistent with the chemical weathering model of murnane and stallard 1990 glacial periods are characterized by lower continental weathering intensity lower ge si riv and two fold higher dissolved silica river fluxes marine ge si opal records thus contain a history of ocean silica chemistry that reflect rapid global changes in continental weathering

trace rare earth element and oxygen isotopic systematics for the genesis of banded iron formations evidence from kushtagi schist belt archaean dharwar craton india abstract the ree distribution pattern shapes free 5 92 and 27 87 ppm in chert and hematite respectively positive eu anomalies eu eu 3 25 and 2 1 and la n yb n ratios 0 75 and 0 87 of the chert and hematite layers of the oxide facies bifs of kushtagi schist belt indicate that these constituents were derived from hydrothermal solutions generated and emplaced at an archaean ocean ridge however their oxygen isotopic composition have been modified by mixing with the ambient ocean water and diagenetic reactions 18o values 13 9 17 4 c and 8 6 to 3 3 in chert and hematite respectively yield 150 250 c temperature in the diagenetic and lowest greenschist facies field the mixing model of hydrothermal solutions with ocean water of 1 1000 ratio will not significantly change the oxygen isotope ratio of the ambient ocean water therefore while the trace element data have retained hydrothermal signatures oxygen isotopic signatures are imprinted by diagenetic processes

spatial patterns of atmosphere ocean interaction in the northern winter abstract the variability of monthly mean sea surface temperature sst anomalies over the extratropical north atlantic and pacific and its relation to atmospheric circulation anomalies over the northern hemisphere during wintertime is investigated by applying eigenvector analysis to a 39 year dataset and correlating the time series of the resulting expansion coefficients with the hemispheric 500 mb height and sea level pressure fields in agreement with previous studies the simultaneous correlation between the tone series of the expansion coefficient of the first empirical orthogonal function eof 1 of north pacific sea surface temperature sst and the hemispheric 500 mb height field resembles the pacific north american pattern and the corresponding pattern for atlantic sst resembles the north atlantic oscillation in the vicinity of the conters of action of thew patterns the sst fluctuations associated with these modes explain on the order of half the variance of 500 mb height and slightly less of

silicon isotopes in 3 8 ga west greenland rocks as clues to the eoarchaean supracrustal si cycle we report mc icp ms si isotopic measurements 29si recalculated as 30si on micro subsamples at 500 m scale from several major rock types of the 3 8 ga old isua greenstone belt igb southern west greenland and surrounding eoarchaean terrains with a large overall range of variations 2 80 30si 0 68 they demonstrate strong involvement of surface fluids enriched with dissolved si the resistance of si isotopes to metamorphic resettings and metasomatic overprints is also established metabasaltic pillows and metasediments display similar 30si enriched signatures suggesting that emergent surfaces of the eoarchaean protocrust were composed of slightly weathered hydrothermally altered mafic ultramafic bodies isua magnetite quartz banded iron formation bif is strongly depleted in 30si relative to all coeval rocks this depletion supports rayleigh controlled precipitation from seafloor vented hydrothermal fluids in contrast banded quartz pyroxene rocks from akilia island some 150 km southwest of the igb which some authors have identified as bif related yield quartz with si isotopic composition 30si 0 36 similar to metamorphic derived quartz 30si 0 50 this supports their derivation from tectonic reworking of ultramafic protoliths penetrated by metamorphic silica and is at variance with their proposed role as harboring earliest biogenic tracers