early jurassic late pliensbachian co2 concentrations based on stomatal analysis of fossil conifer leaves from eastern australia the stomatal index a measure of stomatal density of an extinct australian early jurassic araucariacean conifer species allocladus helgei jansson is used to reconstruct the atmospheric carbon dioxide concentration pco 2 in the early jurassic the fossil leaves are preserved in a single bed palynologically dated to late pliensbachian similar to 185 183 mya atmospheric pco 2 is estimated from the ratios between the stomatal index of a helgei and the stomatal indices of three modern analogs nearest living equivalent plants co2 concentration in the range of similar to 750 975 ppm was calibrated from the fossil material with a best estimated mean of similar to 900 ppm the new average pco 2 determined for the late pliensbachian is thus similar to although similar to 10 lower than previously inferred minimum concentrations of similar to 1000 based on data from the northern hemisphere but may help constrain pco 2 during this period our results are the first pco 2 estimates produced using jurassic leaves from the southern hemisphere and show that i paleo atmospheric pco 2 estimates are consistent at a global scale though more investigations of southern hemisphere material are required and ii the stomatal proxy method can now be used without the context of relative change in pco 2 when applying the correct methodology c 2014 the authors published by elsevier b v on behalf of international association for gondwana research less

organic carbon isotopic record across the triassic jurassic boundary in austria and its bearing on the cause of the mass extinction carbon isotope analyses of total organic carbon across the triassic jurassic boundary in the classic section of kendelbach austria show that a positive excursion in 13c values of organic carbon in the boundary marl correlates with a negative excursion in 13c values in carbonates in this section the change in isotope values is inferred to be the result of diagenesis with no evidence of any primary change that could relate to bioproductivity this and other evidence do not support the claim that there was a fall in productivity associated with the end triassic mass extinction possibly caused by bolide impact

early hettangian benthic planktonic coupling at doniford sw england palaeoenvironmental implications for the aftermath of the end triassic crisis abstract this paper presents a high resolution micropalaeontological study integrated with geochemical and sedimentological analyses of the triassic jurassic tr j transition at the doniford section sw england our analyses indicate the renewal of surface carbonate production in the blue lias formation early hettangian after the end triassic mass extinction based on the high abundance of surface carbonate producers schizosphaerellids which occurred in phase with development at sea floor of calcareous hyaline benthic foraminifers we deduce that a benthic pelagic coupling resulted in both the initial restoration of the biological carbonate pump and also a more efficient export production the presence of monospecific phytoplankton assemblages and benthic foraminiferal assemblages typical of poorly oxygenated environments suggest that the environmental stress continued after the end triassic maximal perturbation complete environmental recovery was prevented by a succession of alternating dysaerobic and anoxic phases that favoured the deposition of black shale sediments the hypothesis of a methane release mechanism as a trigger for the global carbon cycle perturbation and greenhouse conditions during the early jurassic is discounted based on evidence from the decoupled carbon isotope records of carbonate and organic matter apart from local control of a high amplitude sea level change across the tr j boundary the succession and nature of events at doniford are consistent with a scenario of global environmental and biotic changes triggered by the physical and chemical effects of the central atlantic magmatic province camp volcanism a super greenhouse climate in the aftermath of the end triassic mass extinction appears to be the results of the combination of the long term co2 accumulation in the atmosphere system due to the camp volcanic activity as well as the inefficiency of the biological pump due to reduced export production

dissociation of oceanic methane hydrate as a cause of the carbon isotope excursion at the end of the paleocene isotopic records across the latest paleocene thermal maximum lptm indicate that bottom water temperature increased by more than 4 c during a brief time interval 104 years of the latest paleocene 55 6 ma there also was a coeval 2 to 3 excursion in the 13c of the ocean atmosphere inorganic carbon reservoir given the large mass of this reservoir a rapid 13c shift of this magnitude is difficult to explain within the context of conventional hypotheses for changing the mean carbon isotope composition of the ocean and atmosphere however a direct consequence of warming bottom water temperature from 11 to 15 c over 104 years would be a significant change in sediment thermal gradients and dissociation of oceanic ch4 hydrate at locations with intermediate water depths in terms of the present day oceanic ch4 hydrate reservoir thermal dissociation of oceanic ch4 hydrate during the lptm could have released greater than 1 1 to 2 1 1018 g of carbon with a 13c of approximately 60 the release and subsequent oxidation of this amount of carbon is sufficient to explain a 2 to 3 excursion in 13c across the lptm fate of ch4 in oceanic hydrates must be considered in developing models of the climatic and paleoceanographic regimes that operated during the lptm

duration of and decoupling between carbon isotope excursions during the end triassic mass extinction and central atlantic magmatic province emplacement abstract changes in 13 c carb and 13 c org from marine strata occur globally in association with the end triassic mass extinction and the emplacement of the central atlantic magmatic province camp during the break up of pangea as is typical in deep time the timing and duration of these isotopic excursions has remained elusive hampering attempts to link carbon cycle perturbations to specific processes here we report 13 c carb and 13 c org from late triassic and early jurassic strata near levanto peru where intercalated dated ash beds permit temporal calibration of the carbon isotope record both 13 c carb and 13 c org exhibit a broad positive excursion through the latest triassic into the earliest jurassic the first order positive excursion in 13 c org is interrupted by a negative shift noted in many sections around the world coincident with the extinction horizon our data indicate that the negative excursion lasts 85 25 kyrs longer than inferred by previous studies based on cyclostratigraphy a 260 80 kyr positive 13 c org shift follows during which the first jurassic ammonites appear the overall excursion culminates in a return to pre perturbation carbon isotopic values over the next 1090 70 kyrs via chronologic isotopic and biostratigraphic correlation to other successions we find that 13 c carb and 13 c org return to pre perturbation values as camp volcanism ceases and in association with the recovery of pelagic and benthic biota however the initiation of the carbon isotope excursion at levanto predates the well dated camp sills from north america indicating that camp may have started earlier than thought based on these exposures or that the onset of carbon cycle perturbations was not related to camp

development of an equatorial carbonate platform across the triassic jurassic boundary and links to global palaeoenvironmental changes musandam peninsula uae oman abstract the triassic jurassic boundary is marked by one of the big five mass extinctions of the phanerozoic this boundary event was accompanied by several carbon cycle perturbations potentially induced by the opening of the central atlantic and associated volcanism and accompanied by an ocean acidification event continuous carbonate successions covering this interval of environmental change are however rare here data from a shallow marine equatorial mixed carbonate siliciclastic succession is presented that was studied on a regional scale four sections that are 48 km apart were examined on the musandam peninsula united arab emirates and sultanate of oman the system was analysed for its sedimentology vertical and lateral facies changes and stable carbon and oxygen isotopes strontium isotope analysis was used to determine the position of the triassic jurassic boundary horizon the studied ramp experienced an episode of demise during the late triassic followed by a restricted microbialite dominated ramp containing large amounts of siliciclastic facies during the latest triassic the diverse carbonate factory revived and flourished across the triassic jurassic boundary no clear evidence for a biocalcification crisis or an ocean acidification event across the triassic jurassic boundary is visible lateral facies heterogeneities can be observed across the studied interval attributed to hydrodynamic activity including tropical storms crossing the extensive shelf area although evidence for synsedimentary tectonic activity is present the vertical stacking pattern is largely controlled by changes in relative sea level the refined chronostratigraphy accompanied by the detailed environment of deposition analysis allows for a refinement of the regional palaeogeography the neritic equatorial carbonate ramp has archived a negative carbon isotope excursion preceding the triassic jurassic boundary that has also been reported from other study sites the lack of evidence for a biocalcification crisis across the equatorial triassic jurassic boundary indicates that the tethys did not experience a distinct global acidification event

the cadomian orogeny in the north armorican massif a brief review the north armorican massif nam of nw france is the type locality of the late precambrian cadomian orogenic belt the nam largely escaped reworking during the upper palaeozoic variscan cycle with the result that earlier geological relationships are commonly preserved intact a large part of the cadomian belt of the nam comprises variably deformed and metamorphosed supracrustal rocks of the brioverian succession barrois 1895 1896 1908 graindor 1957 cogne 1962 le corre 1977 rabu et al 1982 1983 chantraine et al 1982 the cadomian orogeny which takes its name from cadomus caen in normandy was defined by bertrand 1921 as the late precambrian orogeny which in the nam resulted in the folding and uplift of the brioverian succession prior to the deposition of lower palaeozoic red bed sequences events which have been ascribed to the cadomian orogeny span the period c 700 425 ma during which time the brioverian was heterogeneously deformed and metamorphosed and intruded by calc alkaline igneous complexes the evolution of the belt has been interpreted in terms of the gradual cratonization of calc alkaline arc complexes and syn orogenic sediments in an andean type continental margin brown et al 1990 dupret et al 1990 this contribution reviews briefly the geology of the cadomian belt of the nam fig 1 and outlines some of the more controversial debates concerning the distribution and status of precadomian basement the stratigraphy of the brioverian succession the nature of cadomian magmatism the kinematic significance of major structures and the geotectonic setting of the component parts of the belt

sudden productivity collapse associated with the triassic jurassic boundary mass extinction the end triassic mass extinction is one of the five most catastrophic in phanerozoic earth history here we report carbon isotope evidence of a pronounced productivity collapse at the boundary coincident with a sudden extinction among marine plankton from stratigraphic sections on the queen charlotte islands british columbia canada this signal is similar to though smaller than the carbon isotope excursions associated with the permian triassic and cretaceous tertiary events

carbon isotope stratigraphy in shallow water carbonates implications for cretaceous black shale deposition a barremian to albian succession on mount kanala part of a tethyan isolated carbonate platform was investigated for its 13c variations the limestone sequence is composed of a series of peritidal shallowing upward cycles with clear petrographic evidence for strong early diagenetic overprinting related to repeated subaerial exposure despite significant impact of diagenesis the observed changes in 13c can be very well correlated with deep water sections from different ocean basins and shallow water carbonate platforms in the middle east this lends further support to the applicability of 13c variations for stratigraphic purposes in shallow water limestones using the 13c signal time resolution in lower cretaceous platform carbonates can be significantly increased independent of bio zonations often hampered by ecological variability cyclostratigraphic analysis of the aptian part of the section shows that strong positive excursions of the cumulative departure from mean cycle thickness of the peritidal shallowing upward cycles coincide with global positive 13c excursions this and the fact that positive shifts in the 13c record are preserved within shallow water limestones provide evidence that black shale accumulation in the ocean basins occurred during sea level rise and flooding of platform tops integration of carbon isotope cyclo and sequence stratigraphic results from different carbonate platforms indicate that strong positive global 13c shifts and concurrent organic carbon burial during black shale deposition are ultimately caused by rapid rises of eustatic sea level hence the rate of change of eustatic sea level is considered to play a crucial role in black shale accumulation in the global ocean basins during the cretaceous

short paper cadomian terrane tectonics and magmatism in the armorican massif the north armorican composite terrane nw france is a collage of displaced terranes which result from the amalgamation of cadomian continental arcs and marginal basin complexes by sinistral transpression along a continental margin above a subduction zone early cadomian arc activity occurred at c 700 650 ma but terrane accretion did not occur until c 540 ma and post tectonic magmatism persisted well into the palaeozoic cadomian events thus span a considerably greater period than previously supposed

biogeochemical constraints on the triassic jurassic boundary carbon cycle event 1 the end triassic mass extinctions represent one of the five most severe biotic crises in earth history yet remain one of the most enigmatic ongoing debate concerns the environmental effects of the central atlantic magmatic province camp eruptions and their linkage with the mass extinction event across the triassic jurassic boundary there is conflicting paleo evidence for changes in atmospheric pco2 during the extrusion of the camp basalts studies on sediments from european and pacific localities have however identified a substantial negative isotopic anomaly up to 3 5 across the tr j boundary providing an important indicator of changes in the operation of the ancient global carbon cycle we sought to explain the paleo evidence by utilizing a carbon cycle model for the hothouse world of the end triassic that emphasizes the chemical weathering of silicate and carbonate rocks and the ocean carbonate chemistry we find that volcanic co2 outgassing fails to fully account for either a sufficient rise in atmospheric pco2 indicated by the stomata of fossil leaves or the sedimentary isotopic fingerprint instead the scenario that best fits all of the geologic evidence is a positive feedback loop in which warming due to a buildup of volcanically derived co2 triggers destabilization of seafloor methane hydrates and the catastrophic release of ch4 palfy et al 2001 we calculate that this carbon cycle perturbation was huge involving the release of 8000 9000 gt c as co2 during the camp basaltic eruptions and 5000 gt c as ch4 in the model the initial isotopic excursion is assumed to take place over 70 kyr while complete reequilibration of the ocean atmosphere system with respect to co2 is accomplished over 700 1000 kyr our results thus provide a preliminary theoretical explanation for the bioevents estimated pco2 changes and isotopic excursions observed in marine and continental sediments at this time

triassic climates state of the art and perspectives abstract the climate of the triassic period was characterized by a non zonal pattern dictated by a strong global monsoon system with effects that are most evident in the tethys realm this strong monsoonal regime is related to the aggregation of the pangaean supercontinent which by triassic time was already completed climate oscillations existed within this framework the harsh hot house climatic conditions that characterized the late permian and perhaps precipitated the end permian mass extinction were probably maintained during the early triassic and may account for the impoverished but distinctive faunal and floral lower triassic associations although metazoan reef builders were probably the most affected group carbonate production remained high at least in the western tethys realm the middle triassic was characterized locally by humid episodes although their geographical distribution has yet to be clarified the carnian pluvial event marks an episode of increased rainfall documented worldwide was the most distinctive climate change within the triassic different hypotheses have been proposed for its causes changes of atmospheric or ocean circulation driven by plate tectonics a peak of the global monsoon due to maximum continent aggregation or triggering by the eruption of a large igneous province subsequently the late carnian and norian seem to have been climatically stable although minor climatic changes have recently been described even from this time period finally the end triassic extinction event is also associated with climate change specifically warming and increased rainfall but this evidence comes mostly from the northern parts of the central atlantic magmatic province and the global pattern of climate change at the triassic jurassic boundary has still to be resolved many facets of triassic climate are intriguing and deserve further research however palaeoclimate studies on the triassic have so far been carried out only locally with different proxies those proxies will require inter calibration in order to depict correctly the temporal and geographical patterns of triassic climate

the cadomian granites of mancellia northeast armorican massif of france relationship to the st malo migmatite belt petrogenesis and tectonic setting abstract the north armorican shear zone nasz divides the cadomian belt of the armorican massif of france into two major terranes the north armorican composite terrane nact and the central armorican terrane cat the nact is a pastiche of displaced blocks and terranes st brieuc terrane st malo terrane and mancellian terrane which results from the amalgamation of cadomian continental arc and basin complexes by sinistral transpression along a continental margin above a southerly dipping subduction zone in the nact the neoproterozoic brioverian succession was deformed and metamorphosed during the cadomian orogeny and intruded by syn to post tectonic plutonic complexes the st malo migmatite belt is a syn tectonic suite of anatectic migmatites derived through partial melting of the brioverian succession using the t test on whole rock geochemical data there is no evidence to suggest that a sample of st malo diatexites comes from a population with a different mean than some samples of the brioverian succession sandstones resulting homogeneous diatexites anatectic granites of the core were emplaced syn kinematically into cadomian strike slip shear zones thus the age of anatexis of 540 ma is also the date of strike slip shearing and provides a minimum age for the sinistral transpression which amalgamated the terranes of the nact the mancellian granites to the southeast of the st malo migmatites were emplaced at 540 ma and are overlain unconformably by cambrian sediments overall geochemistry and a variety of specific geochemical parameters show that the mancellian granites are similar to the diatexites and anatectic granites of the st malo migmatite belt using the t test on whole rock geochemical data there is no evidence to suggest that the sample of mancellian granites comes from a population with a different mean than the sample of st malo diatexites additionally both suites of rocks are peraluminous they have similar distributions of rb sr and ba they have k rb ratios around 225 and they plot largely within the vag field using trace element discrimination diagrams for the interpretation of tectonic setting samples of the brioverian succession sandstones the st malo migmatites and the mancellian granites all exhibit similar primordial mantle normalized element patterns preliminary results of nd and sr isotope studies reveal a similar restricted range of values for nd between 4 0 and 7 3 and sr between 3 and 42 and depleted model ages in the range 1 7 to 1 5 ga tdmur for both mancellian granites and st malo migmatites isotopic features which set these rock types apart from other cadomian granites within the nact the st malo migmatite belt and the mancellian granites are coeval at 540 ma and both developed by anatexis at intermediate crustal depths of the brioverian succession within an inverted but only moderately overthickened behindarc basin in comparison with the st malo migmatites the mancellian granites represent farther travelled products of intracrustal melting but their geochemistry still preserves the characteristic signature of the source

foraminifera as indicators of methane rich environments a study of modern methane seeps in santa barbara channel california methane hydrates have been implicated as a possible forcing mechanism for rapid climate change during the late quaternary via the release of methane from marine reservoirs carbon isotopic excursions of foraminifera observed in high resolution sediment records from santa barbara basin odp site 893 have been interpreted as evidence of episodes of methane release during the late quaternary however the potential relationship between methane in the modern environment and its effect on the stable isotopic composition of benthic and planktonic foraminifera is not well understood short cores taken inside a 500 m diameter pockmark with active methane seeps in santa barbara channel ca usa yield information on the effect of high concentrations of environmental methane on foraminiferal assemblages and their stable isotopic composition these seeps reside at 120 m water depth in the eastern portion of the channel associated with faults and fractures in the miocene monterey formation planktonic foraminiferal assemblages and radiocarbon ages show that surface sediments are of late glacial age 25 300 calendar years this finding suggests an absence of holocene and deglacial sedimentation in the seep area likely due the formation of the pockmarks and subsequent winnowing or lack of sedimentation benthic foraminiferal assemblages are marked by high abundance of bolivina tumida a species previously observed during interstadial episodes and the early holocene in santa barbara basin interpreted to include episodes of high methane flux from the basin while oxygen isotopic values of both benthic and planktonic foraminifera appear normal for cool glacial conditions negative carbon isotopic values are seen in benthic foraminifera primarily in the near surface intervals in one interval 1 2 cm below surface both benthic and planktonic species record highly negative carbon isotopic values implying that isotopically light methane influenced the entire water column this spike is of similar or larger magnitude than several earlier observed spikes in the late quaternary record from odp site 893 single specimen isotopic analyses give an indication of the total range of carbon isotopic values recorded 0 01 to 25 23 for benthics 0 07 to 22 22 for planktonics in the spike interval since modern methane seeps are commonly associated with authigenic carbonate precipitation scanning electron microscopy was used to assess the possibility that post depositional alteration may have affected the isotopic composition of the test these experiments indicate that authigenic carbonate is absent and therefore unable to account for the highly negative carbon isotopic signatures these data improve our understanding of methane associated environments by showing that foraminiferal isotopic composition and assemblages may be used to discern the flux of methane from the oceanic reservoir in the geologic record

geochemistry and u pb and 40ar 39ar geochronology of the man of war gneiss lizard complex sw england pre hercynian arc type crust with a sudeten iberian connection the man of war gneiss is a variably deformed meta igneous body that ranges in composition from gabbro to tonalite and comprises part of the basal structural slice of the lizard ophiolite complex sw england u pb dating of zircon demonstrates that the parental magmas crystallized in the earliest ordovician 499t s 3 ma but 40 ar 39 ar step heating analysis of amphiboles suggests that at least the northernmost zone of the gneiss was subjected to an amphibolite grade metamorphic event at c 374 ma probably associated with thrust emplacement of the ophiolite the gneiss exhibits major trace and rare earth element variations in conformity with an origin through partial melting of an amphibolitic source containing hornblende and plagioclase probably with minor garnet and zircon the elemental abundances and variations are characteristic of granitoids formed in supra subduction zone environments a granitoid sill within the adjacent old lizard head series schists previously inferred to be related to the man of war gneiss is trondhjemitic and exhibits higher sio 2 tio 2 and mgo but lower zr v ba and sr contents and therefore is probably not genetically related to the latter the sill may record local melting during ophiolite emplacement the man of war gneiss probably represents a structural inlier of pre hercynian basement incorporated in the hercynian nappes of sw england during nnw directed thrusting we emphasize the geological and geochronological similarities between variably deformed granitoid units of the lizard complex the sudeten massif of southern poland and the allochthonous complexes of northern portugal and nw spain these granitoid rocks may represent dispersed remnants of tremadoc arcs that formed oceanward from the northern margin of gondwana this is further convincing evidence that at this time eastern avalonia was separated from northern gondwana by an ocean basin that may have been connected with the tornquist sea

interpreting carbon isotope excursions strangelove oceans large negative excursions in marine carbonate delta sup 13 c are commonly associated with period boundaries and mass extinctions explanations for these events must be consistent with limitations imposed by carbon isotope mass balance at steady state i e for excursions lasting more than 10 sup 5 yr the surface ocean delta sup 13 c is set by the organic fraction of the total carbon burial rate and the magnitude of the photosynthetic isotope effect the delta sup 13 c of the deep ocean and the surface to deep isotope gradient are set by both the organic fraction of the ocean s remineralized particulate flux and the magnitude of the isotope effect thus it is the carbon isotope composition of the deep ocean that is most reflective of internal oceanic processes the surface ocean records changes in the longer term throughput of carbon in the system the cessation of organic export from the surface ocean such as is presumed to have caused the strangelove ocean condition of the cretaceous tertiary k t boundary leads to an isotopically homogeneous ocean in decades to centuries if this condition persists the ocean s isotopic composition approaches that of the riverine weathering input in 10 sup 5 yr failure to approach this value during the k t event suggests continued production andmore burial of organic carbon dominantly in either terrestrial or shallow marine environments less

sea level change and facies development across potential triassic jurassic boundary horizons sw britain the late triassic to early jurassic aged succession of sw britain the penarth and lower lias groups comprises mudstone sandstone and limestone strata deposited in a variety of marine to non marine environments faunal and floral characteristics of these successions have led to the proposal that one location in sw england st audrie9s bay should serve as the global stratotype section and point gssp for the base of the hettangian stage and thus for the triassic jurassic tr j boundary the sections of sw britain have also been used previously to infer sea level change history and relate this to potential kill mechanisms associated with the tr j boundary mass extinction chemostratigraphic biofacies and lithofacies data are used here to suggest alternative models of sea level change in relation to possible tr j boundary horizons in the sections of sw britain a sea level lowstand surface of erosion is inferred to occur within the cotham member of the lilstock formation a unit deposited in an environment that was often subaerially exposed in contrast to previous interpretations the top surface of the overlying langport member here inferred to be deposited on a carbonate ramp of depositional or tectonic origin represents a drowning event of at least regional extent all horizons regarded as plausible levels at which to place the tr j boundary based on fossil distributions lie within strata deposited during relative sea level rise however it is doubtful whether the higher horizons proposed to mark the boundary faithfully record times of true biotic change on a global scale and additionally there is no positive evidence that sea level fall had any relation to the genesis of proposed tr j marker horizons it is unlikely that sea level fall played a significant role in the tr j boundary extinctions in either a local or a global context

nitrogen isotope record of a perturbed paleoecosystem in the aftermath of the end triassic crisis doniford section sw england 1 the triassic jurassic transition tj is characterized by successive perturbations of the carbon cycle during a time of biotic disruption as recorded by the carbon isotopic composition of organic matter 13corg the nitrogen isotopic composition of sedimentary organic matter 15norg constitutes a key parameter to explore the functioning of the ecosystem during carbon cycle perturbations and biological crises because it provide information on seawater redox conditions and or nutrient cycling here we report the first continuous 15norg record across the tj transition at the doniford bay section bristol channel basin uk combined with 13corg kerogen typology and carbon 13cmin and oxygen 18omin isotopic composition of bulk carbonates the end triassic is characterized by a major negative excursion both in 13corg and 13cmin very low toc total organic carbon wt and high 15norg values associated with a sea level lowstand a second 13corg negative excursion occurs during the lower hettangian this interval is characterized by phases of carbonate production increase alternated with phases of exceptional accumulations of type i organic matter up to 12 associated with lower 15norg and 13corg this alternation likely reflects a succession of nutrient input increase to the basin leading to enhanced productivity and eutrophication which promoted a primary production driven by organic walled prokaryotic organisms the following om export increase generates anaerobic conditions within the basin these events occur between periods of relatively good seawater column ventilation and nutrient recycling boosting the carbonate producer recovery ecosystems remain perturbed in the bristol channel basin during the aftermath of the end triassic crisis

phanerozoic large igneous provinces lips heatt haline euxinic acidic thermal transgression episodes and mass extinctions abstract the phanerozoic consists of three mutually exclusive climate states icehouse greenhouse and hothouse the greenhouse is the default state representing 70 of the phanerozoic it is characterized by a weak thermal mode pole driven deep water formation with little or no continental sea ice and weakly oxic cool water sinking near the poles nitrogen limitation characterizes greenhouse oceans in which ammonium may be the dominant bioavailable form of nitrogen the steady state greenhouse default must be forced to produce either of the other two states continent continent collision produces the intense chemical weathering that draws down atmospheric co2 and results in the icehouse state that comprises 20 25 of the phanerozoic icehouses have ice caps in contact with the ocean that produce icebergs and foster sea ice formation sea ice formation fills the ocean with highly oxic phosphorus limited icewater except for a thin layer of warm surface water in the tropics of the 23 most conspicuous mass extinctions of the phanerozoic including the late ediacaran 4 are associated with ice volume related regressions and 3 are problematic we suggest that the other 16 mass extinctions occurred when greenhouse climate was forced to hothouse climate large igneous provinces lips can trigger the heatt haline euxinic acidic thermal transgression mechanism which can force greenhouse climate to a hothouse climate state the rapid voluminous co2 emissions of lips cause a series of events that result in very slow but pronounced haline mode circulation mid latitude driven deep water formation that produces warm saline bottom water at very dry hot subtropical and middle latitudes this water upwells at the poles causing warm and moist equable climate hothouse development promotes deep sea anoxia that is generated in concert with co2 buildup and warming the spread of anoxia favors reduced nitrogen over nitrate and limited iron dust curtails nitrogen fixation this leads to dominance of primary productivity by primitive green algae and or cyanobacteria progression to euxinia that reaches the photic zone severely curtails primary productivity via poisoning even as availability of usable nitrogen plummets the result is eukaryotic mass extinction we suggest that the 16 phanerozoic mass extinctions referred to above resulted at least in part from the heatt process evidence for this relationship at 11 of the most severe extinctions is convincing data sets for the other 5 are strongly suggestive of heatt related mass extinction but do not yet have enough documentation to reliably characterize them as heatt episodes

environmental change during the triassic jurassic boundary interval of an equatorial carbonate platform sedimentology and chemostratigraphy of the ghalilah formation united arab emirates abstract the sedimentology and chemostratigraphy 13ccarb 13corg sr concentrations of the triassic jurassic tr j boundary interval has been investigated in detail in sections of the ghalilah formation exposed in wadi ghalilah wadi milaha and wadi naqab northeastern united arab emirates the sequence of events recorded across the tr j boundary interval in ras al khaimah reflects significant environmental change that can ultimately be related to camp volcanism uppermost triassic limestones of the sumra member rich in coral calcareous sponges and large size bivalves are interbedded with siliciclastic mudstones and deposited in an open lagoonal environment these are abruptly followed by oolites with intercalated calcareous mudstones of the sakhra member that are devoid of macrofossil thrombolitic microbialites that occur in the lowermost sakhra member are interpreted to reflect the demise of hypercalcifying marine biota during the tr j boundary interval the oolites of the sakhra member are capped by a subaerial exposure surface followed by peritidal deposits of the shuba member the available sparse biostratigraphic data of the ghalilah formation are critically discussed and support a position of the tr j boundary at the base of the sakhra member a negative excursion in 13corg occurs in the upper sumra member and possibly correlates with the late triassic spelae carbon isotope event the 13ccarb and 13corg values increase across the boundary interval and an extended positive excursion in 13ccarb occurs in the oolites of the sakhra member sr concentrations increase in the bioclastic limestones of the uppermost sumra member and peak in the oolites of the upper sakhra member high sr concentrations also occur at correlative stratigraphical levels in the lombardy basin italy and are interpreted as an early hettangian seawater signal reflecting the global scale reduction of biological aragonite precipitation and an increased continental weathering flux

pre early ordovician cadomian arc type granitoids the bolu massif west pontides northern turkey geochemical evidence the west pontides tectonic belt of northern turkey comprises a lower ordovician lower carboniferous transgressive sequence a stratigraphic basement to this paleozoic sequence is exposed in the bolu area the tectono stratigraphy of the basement closely resemble that of the cadomian belt of western europe three rock units forming the basement imply development of an andean type active continental margin during the pre early ordovician period high grade metamorphics the sunnice group granitoids the bolu granitoid complex and evolved felsic meta volcanic rocks the casurtepe formation are exposed unconformably beneath the lower ordovician fluvial clastics between the bolu yedigoller area to the north of bolu the bolu granitoid complex comprises a group of intrusive rocks of variable composition and size generated through multiple episodes of magmatism and is represented by two separate intrusive bodies within the study area the tullukiris pluton in the west and the kapikaya pluton in the east both plutons are mainly tonalite and granodiorite in composition more felsic and mafic compositional varieties also occur major and trace element chemical characteristics of the granitoids as well as biotite chemistry indicate that these are volcanic arc type granitoids and are products of an immature arc developed during early stages of a subduction furthermore textural and chemical characteristics of the plutons show that these are subvolcanic intrusions emplaced at shallow depths and are calc alkaline in composition the granitoidic plutons intrude the casurtepe formation the casurtepe formation is represented by arc type volcanics and volcaniclastics both the casurtepe formation and the granitoids represent subduction zone magmatism constructed on a continental crust represented by the sunnice group the history is very similar to cadomian active margins as exposed in western europe i e the north armorican and bohemia massifs and therefore the basement to the paleozoic of the west pontides is considered to be a preserved remnant of the cadomian belt

disentangling the hettangian carbon isotope record implications for the aftermath of the end triassic mass extinction 1 this study provides an organic carbon stable isotope 13corg record calibrated with detailed ammonite biostratigraphy following the end triassic biological crisis precise correlation between this crucial fossil group and the 13corg record is key to understanding feedbacks between biological and environmental events following mass extinction the latest triassic and hettangian 13corg record shows several negative and positive excursions the end triassic negative shift coinciding with the mass extinction interval is followed by a positive excursion in the earliest hettangian psiloceras spelae beds which marks the onset of recovery in the marine ecosystem this positive trend is interrupted by a second negative 13corg excursion in the p pacificum beds related to a minor ammonite extinction event this pattern of the 13corg curve culminates in the uppermost hettangian angulata zone major positive excursion this indicates that both the ecosystem and the carbon cycle remained in a state of perturbation for at least 2 ma although the recovery of some pelagic taxa already began at the base of jurassic the early and late hettangian positive 13corg excursions have been confused in several recent papers here we show that during the hettangian there are indeed two distinct positive 13corg excursions phases of anoxia and further pulses of central atlantic magmatic province volcanism during the hettangian might have inhibited the full recovery for that interval of time the main liasicus angulata organic positive cie carbon isotope excursion during the late hettangian might be related to gradual decreasing of pco2 due to protracted high organic burial and coincides with a second phase of recovery as indicated by a pulse of ammonoid diversification

extinction trajectories of benthic organisms across the triassic jurassic boundary abstract we analysed diversity and abundance patterns of benthic organisms across the triassic jurassic t j boundary based on the paleobiology database pbdb which compiles palaeontological collection data on a global scale while sepkoski s sepkoski j j jr 2002 a compendium of fossil marine animal genera bulletins of american paleontology 363 1 563 compendium on the stratigraphic ranges of marine animal genera suggests that the dominant macrobenthic groups of the late triassic experienced significant extinctions prior to the t j boundary a significant end triassic extinction peak is evident from pbdb s data this rhaetian extinction peak is found in both an analysis of the raw data of stratigraphic ranges and a sample standardized analysis of occurrence data 41 of all mesobenthic and macrobenthic genera crossing the norian rhaetian boundary became extinct within the rhaetian although this rate suffices to characterize the end triassic extinction as a true mass extinction against a middle triassic to middle jurassic background significantly reduced rhaetian origination rates add to the strong diversity depletion in the earliest jurassic as for other mass extinctions evidence for selective extinction is meagre when the analysis is limited to the boundary interval alone and when focused on taxonomic and ecological characteristics of individual genera when taxa are separated by environmental preferences however several determinants of extinction risk become evident suggesting that reef dwellers had a significantly higher extinction risk than level bottom dwellers taxa with an inshore preference were more strongly affected than offshore taxa taxa preferring carbonate substrates were more strongly hit than taxa preferring siliciclastic substrates and taxa preferentially inhabiting low latitudes had higher extinction rates than taxa more common at intermediate and high latitudes much of this selectivity is not independent and also seen in the intervals of background extinctions suggesting that the end triassic mass extinction represents an intensification of background extinctions but not a qualitatively different macroevolutionary regime one possible exception is related to preferences for depositional environments suggesting a selective rhaetian extinction in reefs and inshore settings

palaeoenvironmental interpretation of a triassic jurassic boundary section from western austria based on palaeoecological and geochemical data a section spanning the triassic jurassic boundary is described from near the village of loruns in the vorarlberg region of western austria at loruns the uppermost triassic is characterised by bedded carbonates of the kossen formation supporting a stenotopic fauna indicative of a shallow sub tidal environment of normal marine salinity the triassic jurassic boundary may be represented as a sequence boundary developed on top of a 1 1 m thick red mudstone of the lower schattwald shale which is interpreted to have been deposited in a marginal marine environment possibly a mud flat above the boundary beds the upper schattwald shale is characterised by thin bedded marl and dark limestone beds with an earliest hettangian macrofauna dominated by epifaunal filter feeding bivalves including ostreids mytilids and oxytomids which suggest a shallow subtidal salinity controlled environment typical of an interplatform lagoon carbonate production rejuvenated in the later early hettangian with development of the loruns oolite a shallow subtidal oolitic and oncolitic unit bearing echinoderms indicative of normal marine conditions low thu ratios from the remainder of the section are a result of reduced thorium in carbonate rich sediments and not from authigenic uranium in anoxic sediments in the boundary beds evidence for marine anoxia or dysoxia is absent where thu values determined by gamma ray spectrometry are above 5 the negative excursion in 13c and positive excursion in 18o in the boundary beds may be due to secondary geochemical effects due to organic diagenesis or the precipitation of caliche during paleosol development alternatively the excursions may reflect a primary geochemical signal recording short term decline in primary productivity comparison in 18o and 13c values between the kossen formation and lorfus oolite indicate no significant long term geochemical changes are evident in the section and suggest that any environmental perturbations were restricted to the boundary beds and possible sequence boundary

massive dissociation of gas hydrate during a jurassic oceanic anoxic event in the jurassic period the early toarcian oceanic anoxic event about 183 million years ago is associated with exceptionally high rates of organic carbon burial high palaeotemperatures and significant mass extinction heavy carbon isotope compositions in rocks and fossils of this age have been linked to the global burial of organic carbon which is isotopically light in contrast examples of light carbon isotope values from marine organic matter of early toarcian age have been explained principally in terms of localized upwelling of bottom water enriched in 12c versus 13c refs 1 2 5 6 here however we report carbon isotope analyses of fossil wood which demonstrate that isotopically light carbon dominated all the upper oceanic biospheric and atmospheric carbon reservoirs and that this occurred despite the enhanced burial of organic carbon we propose that as has been suggested for the late palaeocene thermal maximum some 55 million years ago the observed patterns were produced by voluminous and extremely rapid release of methane from gas hydrate contained in marine continental margin sediments

rising atmospheric co2 as a possible trigger for the end triassic mass extinction the end triassic mass extinction one of the five largest extinctions in earth history was a severe catastrophe in which 80 of all species were wiped out the cause of the extinction is controversial but any mechanism must account for mass extinction in both marine and terrestrial environments one smoking gun the eruption of the central atlantic magmatic province camp has prompted the hypothesis that co2 degassing to the atmosphere may have induced an environmental catastrophe at the end triassic in this study we use a numerical coupled ocean atmosphere climate model of the late triassic to determine environmental stresses associated with a rapid increase in atmospheric co2 a series of sensitivity experiments with co2 levels that bracket estimated end triassic pco2 estimates 2 8 pre industrial levels predict extreme environmental conditions on land increasing co2 from 2 to 8 pre industrial levels causes an increase in the number and severity of hot days and days without precipitation an exponential increase in continental area experiencing hot days and enhanced seasonal fluctuation in the ocean wind driven circulation decreases and meridional overturning diminishes by a factor of 4 leading to enhanced ocean stratification a three box model of the deep ocean predicts a decline of 85 mol l in deep ocean oxygen concentration with a 4 fold increase in atmospheric co2 consequently while terrestrial organisms would have been subject to severe heat and water stress marine fauna would have experienced oxygen deprivation additional sensitivity experiments indicate that variations in milankovitch orbital parameters may further contribute to faunal stress by intensifying continental heating and seasonal fluctuations in sum model results predict that rising atmospheric co2 would have significantly impacted both marine and continental environments providing a link between turnover on land and ocean during the late triassic

δ13c depth profiles from paleosols across the permian triassic boundary evidence for methane release stable carbon isotopic analyses of organic carbon 13 c in individual paleosol profiles from permian triassic sequences of antarctica reveal systematic isotopic variations with profile depth these variations are in many cases analogous to those in modern soils which are functions of redox conditions soil development and degree and type of microbial decay in modern soils these isotopic depth functions develop independently from vegetation changes c 3 versus c 4 vegetation and can be diagnostic of soil orders this study shows that soil intrinsic functions can be preserved in the 13 c values of paleosols as old as 260 ma and constitute valuable data for paleoecological interpretations a large carbon isotopic offset of as much as 10 in whole paleosol profiles across the permian triassic boundary indicates significant changes in the soil biogeochemistry and the soil atmosphere system early triassic paleosols are distinctive in their extremely low 13 c values to 42 and often show an anomalous 13 c depth distribution compared to both permian paleosols and modern soils highly depleted 13 c values as the ones in early triassic paleosols are suggested to be associated with microbial methane oxidation methanotrophy this hypothesis implies increased methane concentrations in the early triassic soil atmosphere system increased atmospheric methane was probably partly responsible for the global carbon isotopic shift documented in marine and terrestrial sediments across the permian triassic boundary

stable carbon isotopes of amorphous kerogens from phanerozoic sedimentary rocks amorphous kerogens from phanerozoic sedimentary rocks may be divided into two groups on the basis of their 13c values h amorphous kerogens have isotopic values in the range of 24 to 20 per mil and l amorphous kerogens have isotopic values in the range of 35 to 26 per mil the occurrence of amorphous kerogens in the intermediate isotopic range from one rock unit in the data set suggests a weak continuum may exist between these two groups phytoplankton and to a lesser extent zooplankton and bacteria are considered to be the precursors for both kerogen types a plausible explanation for this dichotomy may be found in the source of co2 utilized by phytoplankton which is considered to be controlled by environmental factors h amorphous kerogens are expected to occur in silled basins that are overlain by expansive well circulated deep 500 m water where the prevailing source of carbon in the photic zone is atmospheric derived co2 conversely l amorphous kerogens are expected to occur in restricted basins that are overlain by stratified shallow 200 m water where the prevailing source of carbon in the photic zone may be organic derived co2

carbon isotope anomaly and other geochemical changes at the triassic jurassic boundary from a marine section in hungary most mass extinctions are linked with carbon isotope excursions implying that biotic crises are coupled with changes in the global carbon cycle the isotopic evolution during the end triassic extinction is far less documented than that for the other major phanerozoic extinctions here we report a sharp and short lived 23 5 excursion in carbon isotope values for carbonate d 13 ccarb corresponding to a 22 excursion in the isotopic composition of marine organic matter d 13 corg and other geochemical

events around the triassic jurassic boundary in northern and eastern spain a review abstract more than 20 successions containing the triassic jurassic t j boundary were studied in five of the major geological units of spain the data are from outcrop cored boreholes and interpreted well logs a consistent 3 4 13 c org isotope excursion starting in the rhaetian and continuing in the hettangian was recorded in asturias climate changes in the t j transition show a warming episode in the early hettangian other climate changes are indicated by an increase in hygrophytic miospores above the t j boundary this reflects a more humid episode at the beginning of the hettangian the messejana dyke in southeastern iberia is part of the central atlantic magmatic province camp co 2 outgassing related to extensive magmatic activity in the camp is thought to be one of the possible factors responsible for the end triassic mass extinction no major sea level changes or unconformities were recorded at the t j boundary only in the asturias area was there a well defined shallow carbonate platform during the t j transition the other areas of eastern and northern spain were occupied by coastal playas and sabkhas that developed in arid climatic conditions the biotic crisis around the t j boundary is reflected in the palynomorph record in asturias seven species do not persist beyond the late rhaetian and only six appeared in the triassic jurassic transition however 22 taxa appeared in the early hettangian

climatic and oceanographic isotopic signals from the carbonate rock record and their preservation stable isotopic data from marine limestones and their constituent fossils and marine cements can provide quantitative evidence for changes in global climate and ocean circulation oxygen isotopic data can indicate changes in temperature and ocean composition whereas stratigraphic variation in carbon isotope ratios may reflect changes in the carbon cycle that can be linked to changes in oceanic productivity and atmospheric greenhouse gases terrestrial carbonates meteoric cements calcretes and speleothems similarly offer significant potential for understanding the evolution of terrestrial climates by providing evidence for the composition of rainwater and the nature of vegetative cover primary environmental isotopic signals may be obscured by the effects of post depositional diagenetic alteration cementation and replacement reactions can take place in a wide range of diagenetic environments the diagenetic history of an individual limestone is determined by a combination of its mineralogical diagenetic potential and depositional setting together with subsequent changes in relative sea level and burial history carbon isotopic values are less prone to alteration during diagenesis than oxygen values but shifts can be significant where organogenic carbon is incorporated linear covariation of carbon and oxygen values is not a reliable indicator of diagenetic alteration water rock interaction and fluid mixing may produce non linear distributions attempts to determine long term changes in climatic and oceanographie conditions through isotope stratigraphy of shallow water limestones must include an assessment of the diagenetic history of the materials analysed petrographic examination using conventional microscopy backed up where appropriate by cathodoluminescence and scanning electron microscopy together with elemental and strontium isotopic analysis can help to identify the effects of diagenetic alteration where material with a range of different degrees of alteration is preserved in the same sediment it may be possible to compare patterns of isotopic and elemental variation and to attempt to unravel the effects of diagenesis in order to determine primary environmental isotopic signals recent research has shown that these techniques can be successfully employed in both phanerozoic and precambrian sediments

parallel trends in organic and inorganic carbon isotopes across the permian triassic boundary stable carbon isotope ratios in both inorganic and organic reservoirs have been widely applied to model environmental and sedimentological changes on a global scale most studies dealing with major extinction events have used the record of inorganic carbon in this paper the authors report the relation between shifts in carbon 13 content of organic matter and coexisting carbonate fractions at a major extinction event the permian triassic boundary they found that both delta sup 13 c sub carb and delta sup 13 c sub org of the surface ocean varied dramatically across the boundary but the fractionation delta sup 13 c between organic matter and carbonate remained constant this result appreciably restricts the interpretation of changes in the carbon cycle during this critical interval the new data are best explained by a combination of two mechanisms for variation in delta sup 13 c sub carb 1 burial and erosion of organic carbon with a long time constant and 2 sequestration of organic carbon into shallow and deep oceanic reservoirs with a shorter time constant for application to their case the first mechanism is limited by possible buildup of marine pco sub 2 which would increase the isotopic fractionation factor the second mechanism is limited in application to short term transient variations in delta sup 13 c modelingmore of the carbon cycle and its variations of delta sup 13 c must take both mechanisms into account less

testing the tunable diode laser system in extreme environments measuring high and low co2 concentrations in both active volcanic and geothermal settings abstract measuring co2 emissions in geothermal and volcanic areas is sometimes difficult because of large areas to cover and sites often inaccessible measuring high levels of co2 concentration can provide information on hidden structure in geothermal areas and recording changes in co2 concentration on volcanic areas can help monitor the level of volcanic activity the purpose of this study was to use the tunable laser diode tdl absorption spectroscopy method to test levels of co2 concentrations at two extreme environments white island volcano the most active volcano of new zealand with large and concentrated gas fluxes and ngapouri geothermal area a small geothermal area in the taupo volcanic zone new zealand with relatively low and diffuse gas emissions in 2017 for the first time using tdl at white island co2 concentration measurements performed across the active fumarole fields had the highest co2 concentrations of 657 ppm tdl survey measurements were also conducted across fault strands near the ngapouri geothermal area and the results complemented co2 flux results obtained with the accumulation chamber method higher co2 concentrations were measured close to the mapped ngapouri splays with a maximum of 484 ppm the maximum co2 flux measured in the same area was 100 g m 2 day 1 however the highest co2 fluxes measured along the transects and by the mapped faults were less clear but the co2 concentrations increased closer to the fault splays advantages and disadvantages of using a tdl system have been described and compared to the accumulation chamber method the results from the tdl system demonstrated that co2 concentrations can be used as a tool with other geophysical tools for both detecting and highlighting geological structures where no obvious thermal activity is present and for monitoring purposes on active volcanoes

timing the end triassic mass extinction first on land then in the sea the end triassic marks one of the five biggest mass extinctions but current geologic time scales are inadequate for understanding its dynamics a tuff layer in marine sedimentary rocks encompassing the triassic jurassic transition yielded a u pb zircon age of 199 6 0 3 ma the dated level is immediately below a prominent change in radiolarian faunas and the last occurrence of conodonts additional recently obtained u pb ages integrated with ammonoid biochronology confirm that the triassic period ended ca 200 ma several million years later than suggested by previous time scales published dating of continental sections suggests that the extinction peak of terrestrial plants and vertebrates occurred before 200 6 ma the end triassic biotic crisis on land therefore appears to have preceded that in the sea by at least several hundred thousand years

carbon isotope evidence for cam photosynthesis in the mesozoic crassulacean acid metabolism cam photosynthesis a flexible adaptation to water stress has not been shown to occur before the pleistocene despite suggestions that cam first evolved in the mesozoic or earlier here we report on multiple 7 positive organic carbon isotope excursions d 13 corg 20 i n late triassic and early jurassic c 200 ma sedimentary rocks from an arid terrestrial ecosystem in south africa these excursions are interpreted as evidence of the episodic domin ance of cam plants in response to heightened aridity in the heartland of gondwana and hint at climatic instability in a greenhouse world

carbon cycle dynamics following the end triassic mass extinction constraints from paired δ13ccarb and δ13corg records 1 constraining the carbon isotopic changes associated with the end triassic mass extinction is key to understanding the causes of the extinction and dynamics of recovery from it yet the pattern and timing of 13c variation surrounding the extinction remain poorly constrained here we present close to 1000 new 13c measurements from six newly sampled sections in italy we observe a sharp negative excursion in 13ccarb coincident with the disappearance of the triassic fauna and two positive excursions above it the negative 13ccarb excursion in these sections does not occur in 13corg suggesting a possible diagenetic origin in contrast the interval of elevated 13c occurs in both carbonate and organic carbon suggesting that it is likely to be a primary feature the positive excursions in the lombardy basin southern alps and mt cefalo southern apennines appear to be time correlative on the basis of their position above the disappearance of characteristically triassic biota however it is less certain that they are time correlative with positive excursions in other sections worldwide as few options exist that honor both bio and chemostratigraphy nonetheless similarity to other events that are interpreted as global as well as carbon cycle considerations suggest that the isotopic enrichment is best interpreted to reflect a shift in the isotope composition of the global surface carbon reservoir our data indicate that perturbation of the global carbon cycle was not confined to the immediate vicinity of the extinction interval but rather persisted for substantial length of geologic time afterwards

u pb geochronology and sm nd isotopic composition of proterozoic gneisses channel islands uk gneissic units of the channel islands united kingdom have traditionally been considered to be palaeoproterozoic basement to the late neoproterozoic cadomia terrane based on lithological correlations and imprecise or ambiguous isotopic data a new precise u pb date of 2061 2 ma based on analyses of single zircons for the icart granitic orthogneiss of guernsey confirms a palaeoproterozoic age of its igneous protolith the nd depleted mantle model age t dm of this gneiss is 2220 ma only slightly older than its crystallization age indicating that it represents juvenile crust other gneisses from guernsey have similar t dm ages ranging from 2210 to 2370 ma suggesting that they are also exposures of juvenile palaeoproterozoic crust a component from a penetratively deformed orthogneiss from sark previously correlated with icartian gneisses on guernsey yields a u pb zircon date of 616 4 2 ma this crystallization age demonstrates that the protolith was a cadomian intrusion and that penetrative deformation and amphibolite facies metamorphism in the northern channel islands were cadomian in age the use of gneissic features as a means of invoking the antiquity of many other undated gneissic units in the region is thus considered unreliable the presence of 2170 7 ma zircon xenocrysts within the sark orthogneiss combined with its initial e nd 615 9 5 are strong evidence that pre cadomian basement was a significant source component and that documenting the extent and age of pre cadomian basement may be possible by indirect geochemical methods

carbon isotope stratigraphy and palynostratigraphy of the triassic jurassic transition in the tiefengraben section northern calcareous alps austria abstract the end triassic is characterized by enhanced rates of biotic turnover in both the marine and terrestrial realms carbon isotope anomalies have been reported worldwide that may indicate coeval global disturbances in the biogeochemical cycles here we present the results of an integrated study of the palynomorph assemblages and the carbon isotope composition of organic matter in the tiefengraben section near st wolfgang austria carbon isotope values from bulk organic matter show significant fluctuations through the triassic jurassic t j boundary interval with two prominent negative 13 c org excursions an initial negative carbon isotope excursion occurs at the base of the kendlbach formation tiefengraben member pre planorbis beds although triassic ammonoids and conodonts have their highest occurrence at the top of the underlying kossen formation the palynomorph and calcareous microfossil assemblages indicate still a rhaetian age for the lower part of the tiefengraben member high abundance of prasinophytes during the interval of the initial carbon isotope excursion may represent a bloom of green algae that flourished as a result of the disturbance of the marine ecosystems increased spore abundance together with the disappearance of distinctive late triassic pollen types e g ovalipollis rhaetipollis indicate vegetation changes on land that are contemporaneous with the marine biotic crisis a second negative carbon isotope excursion occurs in the middle part of the tiefengraben member based on palynological evidence the t j boundary may be drawn at about this level by the lowest occurrence of cerebropollenites thiergartii the established carbon isotope curve as well as palynostratigraphic and other biostratigraphic events can be correlated with st audrie s bay england

interpreting carbon isotope excursions carbonates and organic matter abstract variations in the carbon isotopic compositions of marine carbonate and organic carbon provide a record of changes in the fraction of organic carbon buried through time and may provide clues to changes in rates of weathering and sources of organic carbon paired carbonate and organic carbon isotope determinations provide a possibility of interpreting not only changes in the global carbon cycle through time but changes in atmospheric pco2 as well interpretations of these types of data are typically rather qualitative a quantitative basis is required to develop a better understanding of changes in the carbon cycle for this purpose we employ a simple model of the global carbon cycle which is subjected to a number of different perturbations each lasting 500 ky i e much longer than the residence times of carbon and phosphorus in the ocean atmosphere system in addition to standard considerations of carbon mass and isotopic fluxes to the ocean atmosphere system from weathering and volcanism and fluxes of organic carbon and carbonate carbon to sediments the model incorporates sensitivity of the photosynthetic carbon isotope effect to changes in pco2 the inclusion of this parameter leads to unexpected carbon isotope responses to forcing that causes increased rates of organic carbon burial a series of simple to more complex simulations illustrates the significant effects of varying differences between the carbon isotopic composition of sedimented carbonate and organic carbon b with constant b a 50 increase in organic carbon burial produces a parallel increase in carbonate and organic carbon isotopic compositions however the same simulation with b responsive to pco2 changes produces an initial parallel 13 c increase but this is followed by an even greater 13 c enrichment in organic carbon because pco2 falls in response to increased organic carbon burial the counterintuitive overall result of the enhanced organic carbon burial event is that the carbonate carbon isotopic composition actually decreases because of the more substantial increase in 13 c org in addition we illustrate the effects on carbon isotopic compositions of the oceanic inorganic carbon reservoir and buried organic matter of a 50 increase in volcanic co2 outgassing a 50 increase in weathering rate with coupled phosphate and riverine carbon flux responses a 50 decrease in shale associated organic carbon weathering a 50 decrease in silicate weathering rate and the possible effects of the rise in abundance of c4 plants in the late miocene to recent we compare the model simulated carbon isotopic responses for some of these experiments to paired carbonate and organic carbon records to illustrate how these records might be interpreted in light of the model response

carbon isotope excursions and microfacies changes in marine permian triassic boundary sections in hungary abstract several permian triassic boundary sections occur in various structural units within hungary these sections represent different facies zones of the western palaeotethys margin the gardony core in the ne part of the transdanubian range typically represents the inner ramp while the balvany section in the bukk mountains of northern hungary represents an outer ramp setting the two sections have different patterns for their 13 c values the balvany section shows a continuous change towards more negative 13 c values starting at the first biotic decline followed by a sharp quasi symmetric negative peak at the second decline the appearance of the 13 c peak has no relationship to the lithology and occurs within a shale with low overall carbonate content indicating that the peak is not related to diagenesis or other secondary influences instead the shift and the peak reflect primary processes related to changes in environmental conditions the continuous shift in 13 c values is most probably related to a decrease in bioproductivity whereas the sharp peak can be attributed to an addition of c strongly depleted in 13 c to the ocean atmosphere system the most plausible model is a massive release of methane hydrate the quasi symmetric pattern suggests a rapid warming cooling cycle or physical unroofing of sediments through slope failure and releasing methane hydrate the gardony 1 core shows a continuous negative 13 c shift starting below the p t boundary however the detailed analyses revealed a sharp 13 c peak in the boundary interval just below the major biotic decline although its magnitude doesn t reach that observed in the balvany section based on careful textural examination and high resolution stable isotope microanalyses we suggest that the suppression of the 13 c peak that is common in the oolitic boundary sections is due to combined effects of condensed sedimentation sediment reworking and erosion as well as perhaps diagenesis

tectonomagmatism in continental arcs evidence from the sark arc complex abstract the island of sark channel islands uk exposes syntectonic plutons and country rock gneisses within a precambrian cadomian continental arc this sark arc complex records sequential pulses of magmatism over a period of 7 ma ca 616 609 ma the earliest intrusion ca 616 ma was a composite sill that shows an ultramafic base overlain by a magma mingled net vein complex subsequently deformed at near solidus temperatures into the amphibolitic and tonalitic tintageu banded gneisses the deformation was synchronous with d 2 deformation of the paragneissic envelope with both intrusion and country rock showing flat top to the south ls fabrics later plutonism injected three homogeneous quartz diorite granodiorite sheets the creux moulin pluton 150 250 m ca 614 ma the little sark pluton 700 m 611 ma and the northern pluton 500 m 609 ma similar but thinner sheets in the south derrible hogsback dixcart and west port es saies brecqhou are interpreted as offshoots from the creux moulin pluton and little sark pluton respectively all these plutons show the same ls fabric seen in the older gneisses with rare magmatic fabrics and common solid state fabrics recording syntectonic crystallisation and cooling the cooling rate increased rapidly with decreasing crystallisation age 9 ma for the oldest intrusion to cool to lower amphibolite conditions 7 8 ma for the creux moulin pluton 5 6 ma for the little sark pluton and 2 the initiation of the d 2 event is suggested to have been a response to the intrusion of the tintageu magma which promoted a rapid increase in strain rate 10 14 s 1 that focussed extensional deformation into the sark area the increased rates of extension allowed ingress of the subsequent quartz diorite granodiorite sheets although strain rate slowly declined as the whole complex cooled during exhumation the regional architecture of syntectonic cadomian arc complexes includes flat lying sark type and steep guernsey type domains produced synchronously in shear zone networks induced by oblique subduction a pattern seen in other continental arcs such as that running from alaska to california