revised geochronology of the neogene calc alkaline volcanic suite in sierra de gata alboran volcanic province se spain 40 ar 39 ar step heating experiments were performed on biotites from seven andesites dacites rhyolites which represent the entire volcano stratigraphic range in a c 125 km 2 area in sierra de gata each sample rendered well defined plateau shaped incremental 39 ar release spectra which define a time span of c 12 10 5 ma for the volcanic activity there appears to have been a time gap in the volcanism separating a basal section of c 12 11 5 ma from a cover section of c 11 10 5 ma the two samples from the basal section constrain a weighed average age of 11 75 0 15 2 ma and the five samples from the cover section of 10 70 0 15 2 ma this contrasts with earlier claims of c 15 7 ma for the whole spectrum based mainly on k ar whole rock and groundmass experiments the c 12 10 5 ma age for the calc alkaline volcanism places it unequivocally after the late stage extensional tectonics c 24 17 ma this supports the currently available model for the alboran volcanic province which connects magma generation not to an active subduction zone of the collisional stage but rather to a late stage anatectic event in the betic ligurian lithosphere under influence of post collisional lithospheric slab detachment

mica deformation fabrics and the seismic properties of the continental crust abstract seismic anisotropy originating within the continental crust is used to determine kinematic flow lines within active mountain belts and is widely attributed to regionally aligned mica however naturally deformed micaceous rocks commonly show composite e g s c fabrics it is necessary therefore to understand how both varying mica content and differing intensities of multiple foliations impact on seismic interpretations in terms of deformation fields an outcrop analogue for granitic mid crustal deformed zones is used here to calibrate the seismic response against both parameters seismic responses are modelled using crystallographic preferred orientations for polymineralic micaceous granitic gneisses measured using electron back scatter diffraction the sample results are generalised by modelling the effects of variations in modal composition and the relative importance of deformation fabrics of variable orientation so called rock and fabric recipes the maximum p and s anisotropy are calculated at 16 6 and 23 9 for single foliation gneisses but for mixed i e s c foliation gneisses these values reduce to 5 8 and 7 5 respectively furthermore mixtures of multiple foliations generate significant variations in the geometry of the seismic anisotropy this effect coupled with the geographical orientation of fabrics in nature can generate substantial variations in the orientation and magnitude of seismic anisotropy especially for shear waves as measured for the continental crust using existing receiver function and teleseismic near vertical incidence methods thus maps of seismic anisotropy varying with depth in deforming continents need not imply necessarily depth varying deformation kinematics and tectonic decoupling

fabric related seismic anisotropy in upper mantle xenoliths evidence from measurements and calculations the seismic properties and their directional dependence have been measured in four mantle peridotites from picritic tuffs vitim baikal region russia geothermobarometric data suggest a source depth for the xenoliths corresponding to the spinel garnet transition zone 40 90km the experimental data include the measurement of p and s wave velocities and densities at confining pressures to 600 mpa and temperatures to 600 c and the determination of velocity anisotropy and shear wave splitting the measured velocities are compared with velocity calculations based on lattice preferred orientation lpo of olivine orthopyroxene the modal composition of the rocks and the single crystal stiffness coefficients macroscopic velocity anisotropy is strongly controlled by the lpo of olivine measured 600 mpa room temperature and calculated p wave anisotropies compare fairly well although the experimentally determined velocities are markedly lower than the calculated velocities the correspondence between measured and calculated shear wave splitting data is less pronounced this is attributed to grain boundary effects retrogressive reactions interstitial glass incomplete crack closure and to the fact that the lpo of the cpx fraction has not been included in the calculation the magnitude of p wave anisotropy corresponds to that observed in mantle peridotites exposed at the surface ivrea zone northern italy ronda southern spain

the tortonian salinity crisis of the eastern betics spain the late miocene depositional history of the lorca and fortuna basins both occupying an internal position in the eastern betics of spain is marked by a regressive sequence from open marine marls via diatomites and evaporites to continental sediments based on facies similarities these evaporites have often been correlated to the well known mediterranean evaporites of the messinian salinity crisis although this correlation was never substantiated by reliable chronological data in this paper we present an integrated stratigraphy of this regressive sequence which shows that the evaporites of the lorca and fortuna basins are entirely of late tortonian age and as such have no relation with the messinian salinity crisis the main phase of basin restriction resulting in deposition of diatomites and evaporites took place at 7 8 ma while the last marine deposits massive evaporites of the lorca basin are dated at 7 6 ma consequently this tortonian salinity crisis of the eastern betics had a duration of approximately 200 kyr while continental deposition prevailed throughout the entire messinian as also revealed by the fossil mammal record the tortonian salinity crisis of the eastern betics is obviously related to a local phase of basin restriction caused by uplift of the metamorphic complexes at the basin margins probably in concert with strike slip activity along sw ne trending fault systems the development of a submarine sill is of crucial importance for the increase in salinity because it allows marine waters to continuously enter the basin at the surface while it restricts or prevents the outflow of dense saline waters at depth furthermore we show that evaporite and diatomite cyclicity in these restricted basins is predominantly related to precession controlled circum mediterranean climate changes and that glacio eustatic sea level changes only play a minor role it is remarkable that the lithological sequence of the tortonian salinity crisis mimics in many aspects that of the messinian salinity crisis this suggests that the diatomaceous facies is an essential part of the lithological sequence associated with basin restriction fl 2000 elsevier science b v all rights reserved

modelling the anisotropic seismic properties of partially molten rocks found at mid ocean ridges abstract the problem of modelling the seismic properties of mid ocean ridge rocks of the axial magma chamber amc and the low velocity triangle lvt immediately below it has been addressed using two samples from oman ophiolite as examples the specimens are a layered gabbro from the lower oceanic crustal sequence and a harzburgite from the upper most mantle section at the palaeo ridge axis the seismic properties have been simulated at a temperature of 1200 c and pressure of 200 mpa so that the basalt melt is above its solidus various effective medium methods are discussed in the perspective of modelling rocks that have a strong background elastic anisotropy due to crystal preferred orientation cpo and an introduced anisotropy due to oriented melt filled inclusions calculations using various methods show a wide range of predicted melt fractions for a given seismic velocity the self consistent scheme scs and differential effective medium dem are compared in some detail a tensorial model was developed using a poro elastic method of gassman at low seismic frequency and a standard dem with isolated basalt inclusions at high frequency at low frequency the basalt pore fluid is considered to be everywhere connected and the pressure uniform whereas at high frequency basalt inclusions are isolated assuming the medium to be a standard linear solid the low and high frequency velocities were used to calculate the anisotropy of attenuation calculations with spherical basalt inclusions show that the seismic velocities decrease and attenuation increase with increasing melt fraction the symmetry of the background anisotropy due to cpo is preserved but gradually reduced with increasing melt fraction for the seismic velocities observed for the axial magma chamber amc with v p of 3 5 to 4 7 km s the model predicts 50 70 melt for the low velocity triangle lvt below the amc with v p of 4 8 5 6 km s the model predicts 35 50 melt predictions from the observed attenuations q 1 at the amc of 0 05 0 02 and in the lvt of 0 02 0 01 are around 60 and 45 melt respectively seismic anisotropy has been modelled with ellipsoidal basalt pancake shaped inclusions with their circular sections in the xy foliation plane only a 2 3 of ellipsoidal basalt inclusions are required to over print the anisotropy of the background medium there is a rapid decrease in v p and increase of q 1 for propagation normal to the foliation z with increasing axial ratio of the inclusions with increasing axial ratio the model predicts decreasing amounts of melt for given velocity v p in the z direction for the lvt only 15 25 melt is predicted for a 10 1 inclusion instead of the 35 50 of the spherical inclusion

the 3d quantitative lattice and shape preferred orientation of a mylonitised metagranite from monte rosa western alps combining neutron diffraction texture analysis and synchrotron x ray microtomography abstract two complementary 3d techniques neutron diffraction and synchrotron x ray microtomography sxr ct were used to compare the shape and lattice preferred orientations of a mylonitised metagranite from the monte rosa unit western alps italy the goal of using these techniques was to obtain two different orientation distribution functions although the two functions describe relatively independent characteristics of the rock fabric nonetheless they also exhibit close relationships to macroscopic fabrics and may be complementarily used to quantify rock fabrics and microstructures thereby highlighting 3d features that cannot be obtained with either technique if used independently we describe an approach that can be potentially useful in various disciplines e g structural geology rock mechanics tectonics and geophysics when a complete data set of preferred orientations and size distribution is needed micas display a strong orthorhombic symmetry between mesoscopic lineation and microscopic spo and lpo whereas quartz and feldspars are characterised by a monoclinic symmetry between mesoscopic lineation and lpo these observations suggest a rheological decoupling between the weak phase mica layers and the stronger quartz feldspar layers this mechanical decoupling occurred during the alpine subduction collision when the monte rosa unit was part of the insubric line system and accommodated large vertical strain

crystallographic preferred orientation magnetic and seismic anisotropy in rocks from the finero peridotite ivrea verbano zone northern italy interplay of anisotropy contributions from different minerals abstract mineral alignment can provide valuable information on a rock s geological history many structural tectonic or geodynamic studies rely on determining the preferred orientation of rock forming minerals either by direct texture determination or using anisotropy measurements as proxies robust interpretations of anisotropy require detailed understanding of its relationship with texture this study investigates the texture magnetic and seismic anisotropies of ultramafic rocks from the ivrea verbano zone ivz northern italy with a special focus on the interplay between anisotropy contributions carried by different minerals texture was obtained from electron backscatter diffraction magnetic anisotropy from low and high field anisotropy of susceptibility measurements and seismic anisotropy from p and s wave velocities along the three principal directions of the macroscopic fabric using 22 mm diameter cores texture based models of magnetic anisotropy agree well with corresponding measurements larger variability is observed for seismic anisotropy possible explanations are 1 velocities were measured in three directions insufficient to determine the full elasticity tensor and 2 seismic anisotropy depends on grain boundaries pores and cracks in addition to crystallographic preferred orientation the contributions to magnetic and seismic anisotropy of each constituent mineral can interfere positively leading to a larger overall anisotropy or negatively resulting in a weaker anisotropy seismic anisotropy is mostly controlled by olivine whereas magnetic anisotropy can be dominated by olivine pyroxene or hornblende this study illustrates that although the relationship between texture and anisotropy can be complex it is possible to quantitatively predict magnetic and to a lesser degree seismic anisotropy from texture data even though both magnetic and seismic anisotropies are common proxies for texture they are not coaxial and no simple relationship between the degree of magnetic and seismic anisotropy was found these results underline the importance of understanding different minerals contributions to anisotropy in upper mantle rocks

gneiss domes and extensional deformation in the highly mineralised archaean eastern goldfields province western australia abstract the recognition of large areas of gneiss within granitic complexes of the northeastern part of the eastern goldfields province of western australia based on analysis of regional aeromagnetic data has resulted in a re evaluation of the structural data for that region five magnetic domains have been established in the granitic complexes which are marginal to the main greenstone belts at least two of these domains have a distinctive domal form and also have internal domeshaped regions the ballard and laverton domains have extensive areas of layered gneissic and migmatitic rocks which flank the internal domes boundary relationships at the laverton and ballard domains show that the domes are concordant sheets and the metamorphic conditions of the boundary rocks imply that the sheets were intruded at a middle crustal level strain conditions in the boundary zones indicate that emplacement of the gneiss domains to the crustal level of the surrounding lower grade greenstones was initially along relatively gently dipping shear zones which were active during uplift structural relationships around both the domal granitic complexes and the later granite batholiths however show that regional shortening deformation events were not caused directly by the emplacement of any of the granitic rocks the tectonic hypothesis presented for the eastern goldfields is similar to that proposed for the formation of cordilleran metamorphic core complexes the uplift event responsible for the crustal extension required to allow the emplacement of the gneiss may have been driven by the same thermal input responsible for the generation of the voluminous granites intrusive into both the gneiss complexes and the surrounding greenstone belts

seismic velocity modelling of the carboneras fault zone se spain abstract the carboneras fault zone forms part of a major strike slip fault system in se spain striking ne sw and accommodating up to 40 km displacement it affects basement metamorphic rocks and unconformably overlying upper miocene sediments and volcanic rocks high resolution shallow seismic tomographic sections were made across the fault zone in two localities from the same areas fault rocks and their wallrocks were collected for laboratory seismic velocity measurements the laboratory data were corrected for the substantial effects of near surface crack damage by combining these results with geological cross sections forward velocity models for the fault zone were constructed to compare with field seismic measurements and hence to ground truth the inferences made from them these velocity depth relationships matched moderately well with those extracted from the in situ tomography results aspects of the in situ seismic sections matched features on the forward modelled sections but the comparisons showed that it is important to have some degree of foreknowledge of the geology to be able successfully to interpret seismic tomography sections as an exploration tool

pyroxene orientation within the upper mantle petrofabric analyses of orthopyroxene and olivine for a suite of rocks from the bay of islands ophiolite newfoundland show systematic relationships between the minerals9 fabrics the plane of the mohorovicic discontinuity determined from the contact of the gabbro and ultramafic sections and the spreading direction inferred from the attitude of the sheeted dikes the orthopyroxene c crystallographic axes maxima which are aligned subparallel to the spreading direction coincide with olivine a axes maxima the orthopyroxene b axes and olivine c axes also lie approximately within the plane of the mohorovicic discontinuity but parallel the ridge whereas the orthopyroxene a axes maxima and olivine b axes maxima are approximately perpendicular to the mohorovicic discontinuity using olivine and orthopyroxene elastic constants and their pressure derivatives velocities have been calculated from composite petrofabric data and contoured for varying proportions of olivine and pyroxene the results of these calculations show that within a vertical direction compressional wave velocities change only slightly with increasing pyroxene content whereas parallel to the mohorovicic discontinuity velocities decrease with increasing pyroxene content anisotropy decreases from 4 for a rock with 100 olivine to 2 6 for a rock with 50 olivine and 50 orthopyroxene also within the plane of mohorovicic discontinuity the maximum and minumum velocities occur at approximately the same azimuth for differing percentages of orthopyroxene a comparison of the calculated anisotropy and the observed seismic anisotropy off the coast of california shows a striking agreement from this comparison it is estimated that the percentage of orthopyroxene within the upper mantle of this region varies between 0 and 30

first results on the lpo derived seismic properties of iron ores from the quadrilatero ferrifero region southeastern brazil abstract determinations of the lpo derived seismic properties of iron ores were carried out in five samples with contrasting mineralogy hematite magnetite and quartz and deformed in different conditions all the samples are seismically quasi isotropic or weakly anisotropic which reflect i an absent or weak crystallographic preferred orientation cpo in some samples ii the high modal content of magnetite iii the relatively weak anisotropy of elastic stiffness of hematite single crystal such variables induce a low anisotropic seismic behavior even in high strained iron ores with strong preferred orientation of hematite a plane of seismic transversal isotropy parallel to the foliation of the aggregates is developed in hematite magnetite aggregates and in itabirites with strong cpo of hematites in these high strained aggregates some relationships between the crystallographic axes of hematite and the propagation velocities can be observed the magnitudes of p and s wave velocities derived of hematite cpo are lower than the values experimentally determined in iron ores such a difference probably reflects other microstructural variable which were not taken into account in the present contribution e g shape preferred orientation

late miocene magnetostratigraphy biostratigraphy and cyclostratigraphy in the mediterranean a new chronology for the late miocene of the mediterranean is presented by combining magnetostratigraphic biostratigraphic planktonic foraminifera and dinoflagellates and cyclo stratigraphic data long and continuous upper miocene sections on gavdos metochia section and sicily gibliscemi section display cyclic alternations of homogeneous marls and sapropels and can be correlated on the basis of their distinct cyclic patterns the metochia section yields a good paleomagnetic signal and the position of 17 polarity reversals can be determined the resulting polarity sequence allows an unambiguous correlation to the geomagnetic polarity time scale gpts the paleomagnetic signal in the gibliscemi section is too weak to determine a reliable polarity sequence except for the lowermost part of the section detailed biostratigraphic analysis results in the identification of 13 planktonic foraminiferal and 9 dinoflagellate bioevents which can all be accurately dated the tortonian messinian boundary defined by the first regular occurrence fro of the g conomiozea group is determined in chron c3br 1r with an age of 7 12 ma according to the gpts ck95 of cande and kent 1

an olivine fabric database an overview of upper mantle fabrics and seismic anisotropy we present a unique database of 110 olivine petrofabrics and their calculated seismic properties the samples come from a variety of the upper mantle geodynamic environments ophiolites subduction zones and kimberlites with a wide range of micro structures a phenomenological relationship is established between p and s wave seismic anisotropy and the degree of crystal alignment fabric strength seismic anisotropy increases rapidly at low fabric strength before reaching a near saturation level of 15 to 20 for p waves and 10 to 15 for s waves despite a large variation in the symmetry of fabric patterns the average seismic properties of the different fabric micro structural and geodynamic settings have similar anisotropies in both magnitude and symmetry hence it would seem possible to determine some measure of fabric strength from seismic anisotropy if the dimensions of the anisotropic region are known but not geodynamic environment or details of the petrofabric pattern a simple pattern of seismic anisotropy characterises the average sample of the database which has the following features the polarisation plane of the fastest s wave is parallel or sub parallel to the foliation plane the maximum shear wave splitting is parallel to the y structural direction in foliation plane and normal to the lineation the maximum of the p wave velocity is parallel to the high concentration of 100 axes which is sub parallel to the lineation the 100 orientation distribution has the greatest influence on the p wave seismic anisotropy the 100 and 001 orientation distributions have the greatest influence on the symmetry of s wave anisotropy although the magnitude of anisotropy is influenced by the distribution of all three principal axes although the database only contains olivine petrofabrics this statistical study clearly shows that seismic anisotropy can be used to deduce the orientation of the structural frame in the upper mantle 1998 elsevier science b v all rights reserved

palaeomagnetic chronology of the evaporitic sedimentation in the neogene fortuna basin se spain early restriction preceding the messinian salinity crisis abstract the magnetostratigraphic study of the evaporitic rio chicamo section 240 m in the neogene fortuna basin murcia southeast spain has identified the record of five magnetozones the most probable correlations with the standard geomagnetic polarity time scale gpts imply that the marine evaporitic sedimentation of this basin was not coeval with the messinian evaporites of the sorbas basin almeria southeast spain and the caltanissetta basin central sicily assigned to the reverse chron c3r late messinian by gautier et al 1994 the marine evaporites and diatomites from the fortuna basin are older late tortonian to early messinian than the evaporites of those basins the chronological framework for the sedimentation in the fortuna basin together with the isotopic data from the sulphates in these evaporitic units indicate the following 1 restriction and confinement in the basin initiated as early as uppermost tortonian leading to deposition of evaporites under mixed marine continental conditions 2 the subsequent sedimentation of marine evaporites and diatomites in this basin occurred in a period between the tortonian and messinian transition and the early messinian the onset of this sedimentation pre dates similar sediments of restricted marine environments in the eastern betics basins and possibly of the western mediterranean region also 3 episodes of restriction and reflooding in the basin would have occurred in response to periodic fluctuations of the oceanic level under local tectonic controls in the fortuna basin the global base level drop associated with the late messinian salinity crisis was recorded by the progradation of alluvial fans leading to thick clastic deposits overlying the youngest evaporites these observations hint to a the peculiar characteristics and sensitiveness of some of the marginal intramontane basins in the eastern betics to reflect structural controls framed in the late neogene global climatic changes and b the diachronism of the beginning of the marine evaporitic deposition in the mediterranean region linked to the salinity crisis during the messinian

revised isotopic 40ar 39ar age for the lamproite volcano of cabezos negros fortuna basin eastern betics se spain abstract a new isotopic age of 7 71 0 11 ma 1 has been obtained with the 40ar 39ar incremental heating technique on phlogopites from the miocene volcanic rocks lamproites of the fortuna basin in southeast spain this age is significantly older than earlier reported k ar ages but confirms recent magnetostratigraphic ages on the sedimentary sequences of the eastern betics because the volcanic rocks are intercalated in the stratigraphic sequence of the fortuna basin directly above the transition from evaporitic to continental sediments it implies that the fortuna evaporites are older than 7 71 ma and thus of tortonian age in addition it shows that the volcanism in the fortuna basin must be attributed to a late tortonian deformation phase and not to messinian tectonics consequently these results form an important step towards a consistent chronological framework for the sedimentary tectonic and paleogeographic evolution of the fortuna basin during the late miocene

sedimentary and diagenetic markers of the restriction in a marine basin the lorca basin se spain during the messinian abstract the lorca basin southeastern spain is part of a chain of small marginal neogene basins located in the structurally active betic area the upper miocene messinian sequence is composed of a thick diatomite bearing series tripoli unit overlain by the main evaporites analogous to the classical succession that records the main events during the salinity crisis in the mediterranean region the shallow restricted conditions of this region amplified the sedimentary responses to local and global forcings an integrated approach using sedimentology micropalaeontology stable isotope geochemistry and organic geochemistry has been applied to the tortonian messinian succession of the lorca basin in order to obtain a continuous record of the environmental changes the sediments record two major events which affected the whole mediterranean 1 high levels of productivity that led to the formation of the diatomite bearing deposits in the early messinian tripoli and 2 the messinian salinity crisis with its two major stages represented by the halite and gypsum units both mainly precipitated from marine derived brines the rapid reflooding of the mediterranean by normal marine waters at the base of the pliocene did not reach the lorca basin nor other basins of this part of the betic area instead continental sediments were deposited as a consequence of the regional uplift of se iberia which started close to the messinian pliocene boundary the most prominent feature of this basin concerns the record of its restriction by the time of the deposition of the tripoli unit which led to intercalations of precursor evaporitic layers consisting of ca sulphate deposited in sub aqueous and sabkha conditions interbedded with diatomites this alternation of evaporites and diatomites proves that the lorca basin was periodically restricted and reflooded by marine waters a possible cause for this being relative sea level fluctuations in the mediterranean this strengthens evidence of diachronism that suggests that the onset of the first messinian evaporitic deposition was not synchronous but was dependent on bathymetry and local tectonics high productivity during the early messinian in this basin is demonstrated by the thick deposits of diatomites however stagnation episodes may have occurred during this interval as suggested by the preservation of high amounts of organic matter organic rich shales and the extent of bacterial sulphate reduction which apparently occurred during early diagenesis the formation of organo sulphur compounds replacement of sulphates by carbonates and the high levels of elemental sulphur are by products of diagenetic processes occurring in a restricted hypersaline environment

using neutron diffraction to investigate the elastic properties of anisotropic rocks results from an olivine orthopyroxene mylonite 1 the penetrating power of neutrons means that neutron diffraction may be employed to determine the lattice parameters of mineral phases within samples over 1 cm in size we have exploited this fact to obtain high resolution measurements of the elastic strains experienced by olivine and orthopyroxene during room temperature uniaxial deformation experiments performed in a neutron beam line on a mylonite from the oman ophiolite specimens were loaded in three orthogonal directions with respect to the macroscopic fabric of the rock in each case the average olivine and orthopyroxene strains were the same even though the elastic stiffnesses of the two phases were different in comparison with the strains expected from the single crystal elastic stiffness tensors the average strains in the different lattice directions for each phase were found to be greater in the stiffer directions and lesser in the more compliant directions the overall effect of this tendency toward strain homogenization was for the measured elastic anisotropy of the rock to be significantly lesser than that given by voigt reuss averaging of the single crystal elastic properties according to the lattice preferred orientations of each phase the technique used to derive these conclusions potentially provides an important experimental method for the quantitative examination of nonfracture related controls on the elastic anisotropy of geological materials

seismic anisotropy in the morcles nappe shear zone implications for seismic imaging of crustal scale shear zones microstructures and textures of calcite mylonites from the morcles nappe large scale shearzone in southwestern switzerland develop principally as a function of 1 extrinsic physical parameters incl

peperite a review of magma sediment mingling the study of peperite is important for understanding magma water interaction and explosive hydrovolcanic hazards this paper reviews the processes and products of peperite genesis peperite is common in arc related and other volcano sedimentary sequences where it can be voluminous and dispersed widely from the parent intrusions it also occurs in phreatomagmatic vent filling deposits and along contacts between sediment and intrusions lavas and hot volcaniclastic deposits in many environments peperite can often be described on the basis of juvenile clast morphology as blocky or fluidal but other shapes occur and mixtures of different clast shapes are also found magma is dominantly fragmented by quenching hydromagmatic explosions magma sediment density contrasts and mechanical stress as a consequence of inflation or movement of magma or lava magma fragmentation by fluid fluid shearing and surface tension effects is probably also important in fluidal peperite fluidisation of host sediment hydromagmatic explosions forceful intrusion of magma and sediment liquefaction and shear liquification are probably the most important mechanisms by which juvenile clasts and host sediment are mingled and dispersed factors which could influence fragmentation and mingling processes include magma host sediment and peperite rheologies magma injection velocity volatile content of magma total volumes of magma and sediment involved total volume of pore water heated presence or absence of shock waves confining pressure and the nature of local and regional stress fields sediment rheology may be affected by dewatering compaction cementation vesiculation fracturing fragmentation fluidisation liquefaction shear liquification and melting during magma intrusion and peperite formation the presence of peperite intraclasts within peperite and single juvenile clasts with both sub planar and fluidal margins imply that peperite formation can be a multi stage process that varies both spatially and temporally mingling of juvenile clast populations formed under different thermal and mechanical conditions complicates the interpretation of magma fragmentation and mingling mechanisms

lithofacies diagenetic spectra and sedimentary cycles of messinian late miocene evaporites in se spain abstract messinian evaporites have been deposited within a number of connected basins that formed the so called betic strait in se spain during the late miocene pre syn and postevaporitic sedimentary successions may well be compared with other strata of the same age surrounding the mediterranean sea there is no evidence for a cataract like connection of these basins with a strong unidirectional flow regime before and during the formation of messinian evaporites as previously suggested the most frequently occurring gypsum lithofacies presumably related to shallow water depositional environments are crystalline selenitic gypsum grass like gypsum laminated gypsum and cross bedded gypsarenite only few real sabkha type chicken wire alabastrine gypsum have been identified evenly laminated gypsum together with graded gypsarenites turbidites gypsrudites debrites and slumps is restricted to basins or parts of basins with considerable paleoslopes evidence for diagenetic overprinting is abundant in all outcrop areas studied this includes the formation of giant gypsum twin crystals super cones and alabastrine nodular gypsum the formation of messinian evaporites in se spain is thought to be controlled by a superimposed third order sea level lowstand smaller sedimentary units fall well into the range of fourth to sixth order cyclic and rhythmic successions they are clearly related to basin dynamics or to autogenetic processes of the local facies zone facies dynamics none of the smaller scale cycles fourth and higher order as observed in outcrops are related to high frequency eustasy

viscoplastic self consistent and equilibrium based modeling of olivine lattice preferred orientations implications for the upper mantle seismic anisotropy anisotropy of upper mantle physical properties results from lattice preferred orientation lpo of upper mantle minerals in particular olivine we use an anisotropic viscoplastic self consistent vpsc and an equilibrium based model to simulate the development of olivine lpo and hence of seismic anisotropy during deformation comparison of model predictions with olivine lpo of naturally and experimentally deformed peridotites shows that the best fit is obtained for vpsc models with relaxed strain compatibility slight differences between modeled and measured lpo may be ascribed to activation of dynamic recrystallization during experimental and natural deformation in simple shear for instance experimental results suggest that dynamic re crystallization results in further reorientation of the lpo leading to parallelism between the main 010 100 slip system and the macroscopic shear thus modeled simple shear lpos are slightly misoriented relative to lpos measured in natural and experimentally sheared peridotites this misorientation is higher for equilibrium based models yet seismic properties calculated using lpo simulated using either anisotropic vpsc or equilibrium based models are similar to those of naturally deformed peridotites errors in the prediction of the polarization direction of the fast s wave and of the fast propagation direction for p waves are usually 15 moreover overestimation of lpo intensities in equilibrium based and vpsc simulations at high strains does not affect seismic anisotropy estimates because these latter are weakly dependent on the lpo intensity once a distinct lpo pattern has been developed thus both methods yield good predictions of development of upper mantle seismic anisotropy in response to plastic flow two notes of caution have nevertheless to be observed in using these results 1 the dilution effect of other upper mantle mineral phases in particular enstatite has to be taken into account in quantitative predictions of upper mantle seismic anisotropy and 2 lpo patterns from a few naturally deformed peridotites cannot be reproduced in simulations these abnormal lpos represent a small percent of the measured natural lpos but the present sampling may not be representative of their abundance in the earth s upper mantle

petrofabric derived seismic properties of a mylonitic quartz simple shear zone implications for seismic reflection profiling the link between petrofabric lpo and seismic properties of an amphibolite facies quartzofeldspathic shear zone is explored using sem ebsd the shear zone lpo develops by a combination of slip systems and dauphine twinning with a maximum parallel to lineation x and c maximum normal to mylonitic foliation xy the lpo are used to predict elastic parameters from which the three dimensional seismic properties of different shear zone regions are derived results suggest that lpo evolution is reflected in the seismic properties but the precise impact is not simple in general the p wave velocity vp minimum is parallel to the a axis maximum the direction of maximum shear wave splitting avs is parallel to mylonitic foliation and the vp maximum and avs minimum are parallel to the c axis maximum the seismic anisotropy predicted is significant and increases from shear zone wall rock to mature mylonite p wave anisotropy ranges from 11 13 fast and slow shear waves anisotropy range from 6 15 and the magnitude of shear wave splitting ranges from 9 16 nevertheless such anisotropy requires a considerable thickness of rock with this lpo before it becomes seismically visible i e 100 s m for local earthquakes 10 s m for controlled source experiments however reflections and mode conversions provide much better resolution particularly across tectonic boundaries the low symmetry and strong anisotropy due to the lpo suggest that multi azimuth wide angle reflection data may be useful in the determination of the deformation characteristics of deep shear zones a number of factors may produce elastic anisotropy in rocks including variations in the spatial distribution of mineral phases layering grain size and shape fabrics grain boundary properties and the presence of oriented pores or fractures e g kern wenk 1985 mainprice et al 2003 in addition because elastic properties vary with respect to direction in single crystals the majority of rock forming minerals are elastically anisotropic e g christensen 1966 thus deformation processes such as dislocation creep which produce strong crystal lattice preferred orientations lpo in anisotropic minerals may also induce bulk elastic anisotropy it is no surprise therefore that petrophysical properties such as seismic velocities are often highly anisotropic in bulk rock aggregates e g babuska cara 1991 understanding of the impact of microstructural variables on elastic anisotropy has been obtained typically from experimental measurements of elastic properties of minerals or theoretical models that incorporate microstructural variables e g burlini kern 1994 wendt et al 2003 experimental studies have focused primarily on the influence of fractures or lpo on the elastic properties of minerals and rocks in particular the seismic properties can be measured via direct laboratory methods at ambient or elevated temperatures and pressures e g kern 1982 although it is often difficult or impossible to obtain the complete three dimensional property orientation distribution from a single experiment however see pros et al 2003 furthermore experimental investigation of seismic properties usually involves rocks in which all microstructural fabric elements contribute effectively masking any lpo component an alternative approach is to calculate the seismic properties of a rock aggregate from individual crystal orientation measurements incorporating the single crystal elastic constants and the lpo for each mineral weighted according to its modal content e g mainprice humbert 1994 the seismic phase velocities and anisotropies then can be calculated in every direction e g mainprice silver 1993 recently the advent of electron backscattered diffraction ebsd in the scanning electron microscope sem has made it possible to measure lpo in statistically viable numbers from different minerals within a rock aggregate whilst maintaining a oneto one relationship with other microstructural elements e g mainprice et al 1993 lloyd 2000 mauler et al 2000 bascou et al 2001 in this contribution the seismic properties of an amphibolite facies mylonitic quartz shear zone are predicted by averaging the single crystal elastic properties according to the sem ebsd derived lpo in order to study the relationship between microstructure petrofabric and seismic properties this approach illustrates the usefulness of integrating geological studies of rock microstructures and particularly petrofabrics with geophysical studies of seismic properties to obtain a fuller understanding of geodynamic processes

a new method for calculating seismic velocities in rocks containing strongly dimensionally anisotropic mineral grains and its application to antigorite bearing serpentinite mylonites abstract seismic velocity is one of the most important sources of information about the earth s interior for its proper interpretation we must have a thorough understanding of the dependence of seismic velocity on microstructural elements including the modal composition the crystal preferred orientation cpo the grain shape the spatial distribution of mineral phases etc the conventional voigt reuss and hill averaging schemes take into account only the modal composition and the cpo the information about the earth s interior is thus poorly constrained for a better interpretation it is critical to have a calculation method which accounts for the grain shape and the spatial distribution of mineral phases etc we propose a calculation method which accounts for the grain shape of strongly dimensionally anisotropic minerals like micas and serpentines our method can be applied to a distributed geometrical orientation of mineral grains comparison was made between calculated and measured velocities in three antigorite serpentinite mylonites judging from the root mean square relative error our method provides velocities closer to measured values than the voigt reuss and hill averaging schemes the input of the grain shape considerably improves the prediction of seismic properties however large discrepancies 0 1 km s between measured and calculated velocities can be seen in some directions the discrepancies might come from microstructural elements which were not considered in the calculation layer structures and cracks

marine to non marine sedimentation in the upper miocene evaporites of the eastern betics se spain sedimentological and geochemical evidence abstract several neogene basins in the eastern betics contain a record of thick upper miocene evaporites the inner basins those located distal to the mediterranean coast include evaporite units ranging from the late tortonian to the early messinian whereas the marginal basins those located in the vicinity of the mediterranean coast include evaporite units corresponding to the late messinian that are linked to the salinity crisis the sedimentological and geochemical comparison of the evaporites in the inner and marginal basins enable us to show their differences in the modes of deposition under local structural controls and differentiated palaeogeography in the inner basins of the murcia alicante region a number of evaporite units have been differentiated whose gypsum lithofacies have 1 variable strontium contents with mean values primary gypsum between 1121 and 2380 ppm 2 isotopic compositions of sulphur 34 s ranging from those characteristic of the tertiary marine water 20 3 to 25 5 to those characteristic of the triassic sulphates 8 0 to 16 0 the latter suggesting recycling of the sulphate anion in meteoric waters intermediate values 17 4 to 19 6 are attributed to mixed mother brines and 3 strontium ratios 87 sr 86 sr comprised between 0 70804 and 0 70888 these values range from those of the tertiary marine water to those exceeding the triassic sulphates suggesting additional continental contributions from country rocks and hydrothermal solutions the comparison between the sulphur and strontium isotopic compositions of the sulphates together with the study of the biota present in the marls associated with the gypsum allows us to distinguish between marine continental and mixed units in the marginal basins of the eastern betics where single evaporite units characterized by selenitic gypsum prevail 1 the strontium contents are more homogeneous with mean values primary gypsum between 493 and 625 ppm 2 the isotopic compositions of oxygen 18 o and sulphur 34 s are comprised between 12 2 and 14 8 and between 22 0 and 23 5 respectively and 3 the strontium ratios 87 sr 86 sr vary from 0 70890 to 0 70895 all these isotopic values reveal a marine origin and the lack of contribution of significant continental water during the late messinian evaporite deposition in the betic strait these characteristics are similar to those of the lower evaporite

nonmarine evaporitic sedimentation and associated diagenetic processes of the southwestern margin of the ebro basin lower miocene spain abstract in the southwestern margin of the tertiary ebro basin northeastern spain several evaporitic units are found among distal alluvial fan deposits they are made up of bioturbated microlenticular primary gypsum secondary nodular and meganodular gypsum after anhydrite chert nodules and charophyte limestones these evaporites formed in shallow saline lakes along the basin margin during the early early miocene autol gypsum unit and the late early miocene ablitas gravalos and ribafrecha gypsum units the lakes were fed principally by deeply circulated groundwaters loaded with dissolved salts from the old evaporite formations mainly triassic rocks that make up the surrounding mountain chains shallow meteoric waters of low concentration also reached the lakes episodically concentration of these waters led to deposition of microlenticular gypsum and charophytic carbonates which were then intensely bioturbated early diagenetic chert nodules and nodular anhydrite also formed in the early stages of burial large anhydrite nodules meganodules overprinted these sedimentary and early di genetic deposits with more advanced burial the primary gypsum was profoundly anhydritized in some areas with subsequent exhumation the anhydritized zones were transformed to secondary gypsum marginal lakes acted as preconcentrators of drainage waters coming from the surrounding mountain chains causing early precipitation of low solubility salts as ca carbonates gypsum and silica the remaining dissolved salts then drained toward the basin center where gypsum anhydrite glauberite polyhalite and halite precipitated in contemporaneous high salinity lakes

from crystal to crustal petrofabric derived seismic modelling of regional tectonics this collection of papers presents recent advances in the study of deformation mechanisms and rheology and their applications to tectonics many of the contributions exploit new petrofabric techniques particularly electron backscatter diffraction to help understand the evolution of rock microstructure and mechanical properties

evaporite deposition and coeval volcanism in the fortuna basin neogene murcia spain abstract the neogene basins of the eastern betic mountains were placed in a marginal position with respect to the deep mediterranean basin during the tortonian to the messinian they contain thick gypsum anhydrite formations resulting from the upper miocene salinity crisis the evaporitic sedimentation reached its maximum extension and stratigraphic complexity in the fortuna basin which belongs to this geological setting five stratigraphic units are distinguished in the fortuna basin 1 lower gypsum 2 chicamo gypsum 3 chicamo diatomitic evaporitic cycles 4 ribera gypsum and 5 rambla salada gypsum units some of these units occur locally whereas others can be laterally correlated with those of the archena mula guadalentin corridor and lorca basins most of the gypsum units consist of nodular laminated secondary gypsum however primary selenitic laminated gypsarenites and fine grained microlenticular burrowed gypsum lithofacies are also present the evaporite units can also be characterized by the geochemical composition of the gypsum the sulphur and oxygen of the sulphate and the strontium isotopes which display a wide range of values the extreme values indicate precipitation from tertiary marine brines or from meteoric waters that recycled triassic sulphate anion and additional non marine contributions from country rocks and hydrothermal solutions the intermediate values are attributed to mixing between seawater and non marine parent brines the fortuna basin contains several outcrops of volcanic to subvolcanic igneous lamproites cabezos negros derramadores el tale these lamproites the so called fortunites crop out as individual domic volcanoes with lava flows cabezos negros or as intrusive subvertical dikes derramadores el tale there is good evidence of several magma sediment interactions that produced macro and microglobular peperitic lithofacies in the fortuna basin a peperite is produced when two liquids a hot magma and a fluidized water rich sediment interact and no mixing is possible due to the sharp contrast of viscosity between them this implies that the eruption was nearly coeval with the deposition of the host sediment that was water rich the latest evaporitic event rambla salada gypsum unit in the fortuna basin took place coevally to the emplacement of the cabezos negros dome and related lavic structures and the intrusion of the tale and derramadores dikes this paper illustrates the presence of peperitic lithofacies in the fortunites and discusses their implications in assigning an age to these evaporitic sediments which in turn allows us to date the evaporitic units of the fortuna lorca basins

fluidization of wet sediments during the emplacement and cooling of various igneous bodies during the emplacement and cooling of igneous bodies fluidization of wet sediment by water vapour may occur by heating or by pressure relief during the opening of fractures momentary fluidization causes sediment reconstitution and local transport continuous fluidization can result in substantial sediment displacement theoretical considerations show that fluidization due to heating is not likely to occur at depths where pressure is much greater than 312 bars studies of the emplacement of sills of andesite ayrshire fluid rhyolite ramsey island and viscous rhyolite moelwyn hills recognize a wide range of phenomena attributable to wet sediment fluidization and in places modify existing interpretations the transgressive bases of the subaqueously welded ash flow tuffs of the capel curig volcanic formation are consistent with emplacement attended by fluidization of the subjacent sediment evidently fluidization is a means by which large volumes of wet sediment can be replaced by igneous material with minimal disturbance of the remaining host also fluidization can result in exceptionally complex contact relationships between sedimentary host and intrusive rocks and can cause fractures formed during cooling to be thoroughly pervaded by sediment fluidization is commonly associated with the formation of peperites

shallow marine and continental conglomerates derived from coral reef complexes after desiccation of a deep marine basin the tortonian messinian deposits of the fortuna basin se spain some miocene basins in se spain show an unusual arrangement of sedimentary facies associated with desiccated deep basins tortonian reefs and deltaic deposits are located around the basin margins but younger messinian evaporites are exposed in central areas these messinian sediments contain thick conglomerates rich in coral debris although located hundreds of metres below the tortonian reefs they show subaerial features including mud cracks vertebrate tracks and rain pits in the coral reef derived conglomerates there are aragonitic coral fragments with aragonitic fibrous cement preserved by early cementation with calcium sulphate the existence of these conglomerates within the messinian evaporites helps to identify normal salinity and desiccation stages of the 9messinian salinity crisis event9

the influence of crenulation cleavage development on the bulk elastic and seismic properties of phyllosilicate rich rocks abstract the anisotropy of seismic wave propagation is strongly influenced by the mineralogy and microstructure of rocks phyllosilicates are elastically highly anisotropic and are therefore thought to be important contributors to seismic anisotropy in the continental crust crenulation cleavage is one of the most common microstructural fabrics found in multiply deformed phyllosilicate rich crustal rocks we calculated the bulk elastic properties and resulting wave velocities for rock samples that preserved three different stages of crenulation cleavage development an initial planar foliation a moderately developed crenulation cleavage and a well developed crenulation cleavage mineral orientation maps were obtained using electron backscatter diffraction and calculations were made using asymptotic expansion homogenization combined with the finite element method the difficulties involved with sample preparation and data acquisition of phyllosilicate rich rock samples are also discussed we compare our results to more conventional methods for calculating an aggregate stiffness matrix from a mineral orientation map namely voigt and reuss averages these averages do not account for grain scale interactions and therefore deviate from the results calculated using asymptotic expansion homogenization our results show that the rocks characterized by a planar foliation and a moderately developed crenulation cleavage are highly anisotropic with p wave anisotropies up to 30 9 and s wave anisotropies up to 34 2 whereas the rock characterized by a well developed crenulation cleavage is only mildly anisotropic with a p wave anisotropy of 15 5 and s wave anisotropy of 10 7 progressive development of the fabric also causes the orientations of p and s wave velocity maxima and s wave polarization directions to change markedly despite the high anisotropy imparted by a planar schistosity the variety of folds and fabrics typically found in phyllosilicate rich rocks within larger scale crustal volumes will tend to mute the anisotropy possibly to the point of appearing nearly isotropic

trace fossils and rhizoliths as a tool for sedimentological and palaeoenvironmental analysis of ancient continental evaporite successions abstract recognition of evaporite formations from continental tertiary basins of spain provides evidence that trace fossils including rhizoliths can be abundant in some saline lake systems and their study helps in palaeoenvironmental interpretation of ancient continental evaporite sequences six main types of trace fossils have been distinguished and include 1 networks of small rhizoliths 2 large rhizoliths 3 tangle patterned small burrows 4 isolated large burrows 5 l shaped traces and 6 vertebrate tracks rhizoliths were related to both marginal areas of hypersaline lakes and lakes of moderately high saline waters in these settings pedoturbation resulted from colonization by grasses and bushes of distinct lake subenvironments the activity of burrowing invertebrate faunas was especially intense in lakes of moderately concentrated brines from which gypsum was the main evaporite mineral deposited a specific gypsum lithofacies bioturbated gypsum deposits forming thick massive beds has a widespread occurrence in many of the basins tangle patterned small burrows and minor isolated large burrows constitute the typical trace fossil types within the gypsum the traces are interpreted as having been caused by burrowing insect larvae probably chironomids coleopterans and annelids the behaviour of these organisms in recent lake environments yields information about the salinity range of lake waters from which gypsum precipitated concentration values averaging 100 150 g l may be thus deduced though some organisms involved in the formation of the traces can tolerate higher salinities the combined analysis of lithofacies and trace fossils from the lacustrine evaporite sequences contributes to the study of distinct saline lake subenvironments as well as changes in the sedimentary evolution of the lake systems consequently trace fossils can provide valuable insight for palaeoenvironmental analysis of at least some evaporite formations that accumulated in continental settings

lattice preferred orientation and seismic anisotropy in sedimentary rocks summary although it is well known that sedimentary rocks can be seismically anisotropic there have been few detailed investigations of the underlying cause of such anisotropy here we investigate anisotropy due to the preferred orientation of minerals or lattice preferred orientation lpo in a suite of sedimentary rocks seismic properties are predicted by averaging single crystal elastic constants of minerals according to their crystal orientation and modal volume fraction in the rock aggregate both electron backscattered diffraction ebsd and x ray texture goniometry xtg are tested as quantitative techniques for measuring the lpo of sedimentary rocks although ebsd has promise for future lpo measurements in polymineralic sedimentary rocks problems currently remain in measuring low symmetry phases e g feldspars and very small clay or mica particles however the lpo of very fine grained phyllosilicates can be measured using xtg and the lpo of low symmetry minerals can be measured using manual ebsd pattern analysis here we use such a hybrid approach to estimate lpo in a suite of sedimentary samples the seismic properties calculated from lpo data show anisotropy values for p waves ranging from 1 5 per cent in sandstones to over 3 5 per cent in a siltstone to 12 per cent in a shale the effect of thin multilayering on long wavelength propagation in a siltstone is predicted by applying backus type averaging the layering does not enhance the anisotropy because of the small differences in density and in elasticity between the two layer types the lpo of phyllosilicates and to a lesser extent dolomite and siderite seem to contribute significantly to the seismic anisotropy of phyllosilicate rich rocks siltstones and shales the weak lpo of quartz in sandstones causes a few per cent anisotropy cumulatively our results suggest that field observations of seismic anisotropy have the potential to be used as an indicator of rock lithology

crustal radial anisotropy across eastern tibet and the western yangtze craton 1 phase velocities across eastern tibet and surrounding regions are mapped using rayleigh 8 65 s and love 8 44 s wave ambient noise tomography based on data from more than 400 program for array seismic studies of the continental lithosphere and chinese earthquake array stations a bayesian monte carlo inversion method is applied to generate 3 d distributions of vsh and vsv in the crust and uppermost mantle from which radial anisotropy and isotropic vs are estimated each distribution is summarized with a mean and standard deviation but is also used to identify highly probable structural attributes which include 1 positive midcrustal radial anisotropy vsh vsv across eastern tibet spatial average 4 8 1 4 that terminates abruptly near the border of the high plateau 2 weaker 1 0 1 4 negative radial anisotropy vsh vsv in the shallow crust mostly in the songpan ganzi terrane 3 negative midcrustal anisotropy 2 8 0 9 in the longmenshan region 4 positive midcrustal radial anisotropy 5 4 1 4 beneath the sichuan basin and 5 low vs in the middle crust 3 427 0 050 km s of eastern tibet midcrustal vs 3 4 km s perhaps consistent with partial melt is highly probable only for three distinct regions the northern songpan ganzi the northern chuandian and part of the qiangtang terranes midcrustal anisotropy provides evidence for sheet silicates micas aligned by deformation with a shallowly dipping foliation plane beneath tibet and the sichuan basin and a steeply dipping or subvertical foliation plane in the longmenshan region near vertical cracks or faults are believed to cause the negative anisotropy in the shallow crust underlying tibet

an experimental and numerical study of the microstructural parameters contributing to the seismic anisotropy of rocks 1 the elastic properties of rocks are influenced by several microstructural variables including the lattice preferred orientation and grain shape fabric of the mineral phases variations in the spatial distribution of the mineral phases the properties of the grain boundaries and the presence of porosity fractures consequently in principle directional variations in these variables can be inferred from seismic velocity anisotropy observations experimental seismic velocity measurements made on rocks of well characterized microstructure may be used to improve the quality of such interferences however since most rocks are microstructurally complex in order to interpret the measurements fully theoretical analyses which can accommodate all the relevant microstructural variables are required theoretical analyses of the requisite sophistication have only recently been developed we have tested one of these due to ponte castaneda and willis by using it to calculate the elastic properties of an upper mantle harzburgite and by then comparing the results with experimental velocity measurements to determine if the values of those microstructural variables which are difficult to quantify grain boundary properties fracture shape are physically realistic we find that they are and conclude that the ponte castaneda and willis analysis provides a powerful method for a more detailed assessment of the causes of elastic property anistropy in rocks than has previously been possible