could early cenozoic thermohaline circulation have warmed the poles the paleocene and eocene epochs provide examples of oceanographic conditions when the earth had a stable climate much warmer than that of the modern world lower cenozoic sediments thus provide a way to investigate how oceanographic processes might respond to extreme warming because high latitude sea surface temperatures were significantly warmer during the early cenozoic while tropical sea surface temperatures were similar to or somewhat less than modern there may have been a much higher poleward oceanic heat transport at that time shackleton and boersma 1981 barron 1987 sloan et al 1995 here i develop a simple ocean thermohaline model to demonstrate that poleward oceanic heat transport could strongly warm the polar regions only if the strength of vertical mixing vertical eddy diffusion in the oceans is sensitive to changes in oceanic density structure if this is true the early cenozoic oceans because they had significantly less density stratification could have had a thermohaline circulation as much as 3 times as strong as that of the modern ocean despite reduced temperature gradients the model also predicts that an optimum bottom water temperature exists for maximum poleward heat transport continued warming of the earth does not continue to increase oceanic heat transport to the poles the hypothesized sensitivity of oceanic vertical mixing to the density gradient should provide a positive feedback to both the transition to ice ages and to a future transition out of them a test of the sensitivity of vertical eddy diffusion to density gradients can be studied through map and depth transects in the horizontal direction high vertical diffusion would be marked by relatively strong bottom water temperature gradients away from bottom water source regions in the vertical direction high vertical diffusion should be indicated by very small temperature gradients

waxing and waning lyrical on hiatuses eocene quaternary indian ocean hiatuses as proxy indicators of water mass production the temporal distributions of cenozoic hiatuses in the indian ocean are reconsidered in the light of a new time framework developed by the paleoceanographic indian ocean synthesis on the basis of the temporal distribution of hiatus terminations eight 3 m y time slices were selected for plotting the paleogeographical distribution of hiatus terminations these distributions define areas of potential hiatus development which formed along flow paths of proto antarctic bottom water an analogue of modern antarctic bottom water and proto antarctic intermediate water an analogue of modern antarctic intermediate water expansion and contraction of these areas suggested changes in the volume of these water masses which modified the distibution patterns of erosive deepwater currents and corrosive bottom water consequently the spatial and bathymetric distribution of hiatus formation was altered age depth analysis of hiatuses from sites within post late eocene areas of potential hiatus development was used in conjunction with models of the behavior of unconformity boundaries within fluctuating water masses to construct waxing waning curves for proto antarctic bottom water and proto antarctic intermediate water these curves define volume changes in the production histories of these water masses which were related to the post late eocene glacial history of antarctica since the late oligocene the proto antarctic bottom water waned during intervals of increased glacial intensity whereas the proto antarctic intermediate water waxed during these intervals these relationships reversed during intervals of reduced glacial intensity including intervals where there is no evidence for antarctic glaciation this conflicts with interpretations made by other workers a comparison is made between the production histories of proto antarctric bottom water and northern component water an analogue of north atlantic deep water based on 13c for the miocene to pliocene

abyssal circulation and benthic foraminiferal changes near the paleocene eocene boundary a major change in cenozoic deep sea benthic foraminifera occurred in the atlantic indian and pacific oceans near the paleocene eocene boundary benthic foraminiferal abundance changes began at about 61 5 ma at pacific deep sea drilling project dsdp site 577 a major extinction event followed at 58 57 ma between zones p6a and p6b and a series of first appearances continued until circa 55 5 ma zone p6c these faunal changes occurred during a 6 c warming of pacific bottom water and may indicate that the primary cause was changing temperature other potential causes of the faunal turnover include global changes in surface ocean productivity and changing bottom water source regions comparison of benthic and planktonic 13c records requires no change in the ratio of oceanic phosphorous to carbon during the late paleocene to early eocene which weakens the case for but does not disprove a change in surface ocean productivity at this time interbasinal comparisons of benthic foraminiferal 13c records document that water with high 13c values filled the cape basin during the late paleocene and possibly the early eocene circa 61 57 ma but apparently did not extend into the western basins of the atlantic this pattern suggests a supply of antarctic source water for the cape basin and possible tectonic isolation of the western atlantic basins during at least part of the late paleocene carbon isotope comparisons show that bottom water supply to the cape basin was reduced in the early eocene eolian grain size data suggest that a decrease in zonal wind intensity occurred at the end of the paleocene these late paleocene climatic changes bottom water warming and decreased wind intensity correspond with evidence for an important global tectonic reorganization and extensive subaerial volcanism which may have contributed to climatic warming through increased supply of co2

breaking the glass ceiling for high resolution nd isotope records in early cenozoic paleoceanography abstract we report an optimized method for extracting neodymium nd from fossil fish teeth with a single stage column 125 l stem volume ln resin eichrom industries darien illinois for isotopic analysis by multi collector inductively coupled mass spectrometry mc icmps three reference materials basalt bcr 2 bhvo 2 phosphate fossil bone composite and splits of fossil fish teeth samples previously processed with existing two stage column methods were processed using the single stage column method 143 nd 144 nd values of reference materials agree within error with published values and the values for fish teeth correspond with sample splits processed with two stage columns precision to 0 23 e nd was achieved for 30 ng nd samples of reference materials and nd isotope measurements of fossil fish tooth sample replicates as small as 7 ng nd were reproducible within long term instrumental uncertainty we demonstrate the utility of the new method with the first high resolution nd isotope record spanning the 40 0 ma middle eocene climatic optimum which shows an excursion of 0 65 e nd during the peak warming at the study site ocean drilling program leg 119 site 738 30 kyr sample spacing from 40 3 to 39 6 ma ln resin is already used in standard methods for separating nd and nd isotopes are routinely measured by mc icpms with high efficiency inlet systems our innovation is a single small volume ln resin column for nd separation the streamlined approach results in a 10 increase in sample throughput

dissociation of oceanic methane hydrate as a cause of the carbon isotope excursion at the end of the paleocene isotopic records across the latest paleocene thermal maximum lptm indicate that bottom water temperature increased by more than 4 c during a brief time interval 104 years of the latest paleocene 55 6 ma there also was a coeval 2 to 3 excursion in the 13c of the ocean atmosphere inorganic carbon reservoir given the large mass of this reservoir a rapid 13c shift of this magnitude is difficult to explain within the context of conventional hypotheses for changing the mean carbon isotope composition of the ocean and atmosphere however a direct consequence of warming bottom water temperature from 11 to 15 c over 104 years would be a significant change in sediment thermal gradients and dissociation of oceanic ch4 hydrate at locations with intermediate water depths in terms of the present day oceanic ch4 hydrate reservoir thermal dissociation of oceanic ch4 hydrate during the lptm could have released greater than 1 1 to 2 1 1018 g of carbon with a 13c of approximately 60 the release and subsequent oxidation of this amount of carbon is sufficient to explain a 2 to 3 excursion in 13c across the lptm fate of ch4 in oceanic hydrates must be considered in developing models of the climatic and paleoceanographic regimes that operated during the lptm

metalliferous sediments and the scavenging residence time of nd near hydrothermal vents the isotopic composition of nd is uniform in metalliferous sediments formed at distances varying from 1000 km to within 10 km of the east pacific rise epr palaeoridge these data indicate that hydrothermal vent fluids despite having concentrations more than 500 times greater have no effect on the nd isotopic composition of seawater this implicates efficient scavenging of hydrothermal nd by particulates resulting in extremely short residence times 1 year close to the hydrothermal vents therefore nd isotopic studies of ancient seawater precipitates particularly metalliferous sediments cannot be used to delimit the magnitude of past hydrothermal circulation without independent constraints on local scavenging rates or residence times relative to those of modern oceans

seismic stratigraphic framework and depositional history for cretaceous and cenozoic contourite depositional systems of the mozambique channel sw indian ocean this study describes previously unrecognized contourite depositional systems cdss in the mozambique channel which constrain palaeoceanographic models for this area the stratigraphic stacking patterns record nine seismic units su1 to su9 separated by eight major discontinuities a to h oldest to youngest key seismic markers in cds evolutionary history occur during aptian albian 122 ma late cenomanian 94 ma early 38 2 36 2 ma and late 25 23 ma oligocene and early middle miocene 17 15 ma epochs these record onset 122 to 94 ma growth 94 to 25 23 ma maintenance 25 23 to 17 15 ma and burial 17 15 ma to the actual time stages for cdss cdss first develop during the onset stage which coincides with the opening and deepening of the african southern ocean gateway at 122 and 100 ma respectively the growth stage beginning in the late cenomanian 94 ma correlates with the opening and deepening of the equatorial atlantic gateway during the growth stage two major shifts in sedimentary stacking pattern occur which coincide with palaeoceanographic changes during the early 38 2 36 2 ma and late 25 23 ma oligocene these in turn coincide with the onset and local enhancement of antarctic water masses cds growth continued until the early middle miocene during the maintenance stage 17 15 ma most cds growth ceased at the end of the maintenance stage circulation of the north atlantic water mass into the southern hemisphere led to a deepening of antarctic water masses in the area

high resolution records of the late paleocene thermal maximum and circum caribbean volcanism is there a causal link two recently drilled caribbean sites contain expanded sedimentary records of the late paleocene thermal maximum a dramatic global warming event that occurred at ca 55 ma the records document significant environmental changes including deep water oxygen deficiency and a mass extinction of deep sea fauna intertwined with evidence for a major episode of explosive volcanism we postulate that this volcanism initiated a reordering of ocean circulation that resulted in rapid global warming and dramatic changes in the earth s environment

new evidence for subtropical warming during the late paleocene thermal maximum stable isotopes from deep sea drilling project site 527 walvis ridge the late paleocene thermal maximum lptm was a dramatic short term global warming event that occurred 55 ma warming of high latitude surface waters and global deep waters during the lptm has been well documented however current data suggest that subtropical and tropical sea surface temperatures ssts did not change during the event conventional paradigms of global climate change such as co2 induced greenhouse warming predict greater warming in the high latitudes than in the tropics or subtropics but nonetheless cannot account for the stable tropical subtropical ssts we measured the stable isotope values of well preserved late paleocene to early eocene planktonic foraminifera from south atlantic deep sea drilling project dsdp site 527 to evaluate the subtropical response to the climatic and environmental changes of the lptm planktonic foraminiferal 18o values at site 527 decrease by 0 94 from pre lptm to excursion values providing the first evidence for subtropical warming during the lptm we estimate that subtropical south atlantic ssts warmed by at least 1 4 c on the basis of possible changes in evaporation and precipitation the new evidence for subtropical sst warming supports a greenhouse mechanism for global warming involving elevated atmospheric co2 levels

neodymium isotopic reconstruction of late paleocene early eocene thermohaline circulation abstract high resolution fish tooth nd isotopic records for eight deep sea drilling project and ocean drilling program sites were used to reconstruct the nature of late paleocene early eocene deep water circulation the goal of this reconstruction was to test the hypothesis that a change in thermohaline circulation patterns caused the abrupt 4 5 c warming of deep and bottom waters at the paleocene eocene boundary the paleocene eocene thermal maximum petm event the combined set of records indicates a deep water mass common to the north and south atlantic southern and indian oceans characterized by mean nd values of 8 7 and different water masses found in the central pacific ocean nd 4 3 and caribbean sea nd 1 2 the geographic pattern of nd isotopic values before and during the petm suggests a southern ocean deep water formation site for deep and bottom waters in the atlantic and indian ocean basins the nd data do not contain evidence for a change in the composition of deep waters prior to the onset of the petm this finding is consistent with the pattern of warming established by recently published stable isotope records suggesting that deep and bottom water warming during the petm was gradual and the consequence of surface water warming in regions of downwelling

a new approach to the nd residence time in the ocean the role of atmospheric inputs concentrations of rare earth elements ree and nd isotopic ratios were analyzed for seawater filtered suspension and sediment trap samples collected in the tropical atlantic ocean eumeli program eutrophic mesotrophic and oligotrophic sites 20 n 18 21 w this is the first ree nd dataset on solution and different sized particles collected at the same site we present direct evidence of the nd isotopic exchange between particulate lithogenic fraction and seawater without significant mass transfer this exchange is probably one of the main factors that simultaneously constrains the nd concentration and isotopic ratio budget we propose a new approach to estimate the residence time of nd in the ocean nd based on isotopic exchange 200 yr nd 1000 yr the exchange requires a partial dissolution of lithogenic nd we estimate that the fraction of soluble nd proportion in atmospheric dust is of the order of 20 based on the isotopic ratios we suggest that the partial dissolution of atmospheric fallout is probably one of the main ree sources of the ocean

abrupt deep sea warming palaeoceanographic changes and benthic extinctions at the end of the palaeocene a remarkable oxygen and carbon isotope excursion occurred in antarctic waters near the end of the palaeocene 57 33 myr ago indicating rapid global warming and oceanographic changes that caused one of the largest deep sea benthic extinctions of the past 90 million years in contrast the oceanic plankton were largely unaffected implying a decoupling of the deep and shallow ecosystems the data suggest that for a few thousand years ocean circulation underwent fundamental changes producing a transient state that although brief had long term effects on environmental and biotic evolution

widespread and synchronous change in deep ocean circulation in the north and south atlantic during the late cretaceous modern thermohaline circulation plays a role in latitudinal heat transport and in deep ocean ventilation yet ocean circulation may have functioned differently during past periods of extreme warmth such as the cretaceous the late cretaceous 100 65 ma was an important period in the evolution of the north atlantic ocean characterized by opening ocean gateways long term climatic cooling and the cessation of intermittent periods of anoxia oceanic anoxic events oaes however how these phenomena relate to deep water circulation is unclear we use a proxy for deep water mass composition neodymium isotopes end to show that at north atlantic odp site 1276 deep waters shifted in the early campanian 78 83 ma from end values of 7 to values of 9 consistent with a change in the style of deep ocean circulation but 10 myr after a change in bottom water oxygenation conditions a similar but more poorly dated trend exists in end data from dsdp site 386 the campanian end transition observed in the north atlantic records is also seen in the south atlantic and proto indian ocean implying a widespread and synchronous change in deep ocean circulation although a unique explanation does not exist for the change at present we favor an interpretation that invokes late cretaceous climatic cooling as a driver for the formation of southern component water which flowed northward from the southern ocean and into the north atlantic and proto indian oceans

comparison of atlantic and pacific paleochemical records for the last 215 000 years changes in deep ocean circulation and chemical inventories abstract detailed cd ca and 13 c data have been obtained for benthic foraminifera from western north atlantic and equatorial pacific sediment cores in the modern ocean both tracers are closely linked to nutrient distributions the sedimentary records for both tracers indicate that bottom waters overlying the atlantic site have been nutrient depleted relative to those at the pacific site over the last 215 000 years from this evidence it is reasonable to infer that there has been a continuous net flux of nutrient depleted water from the western north atlantic into the pacific this exchange has undergone significant fluctuations with the export of nutrient depleted atlantic water diminishing by about a factor of two relative to the inflow from southern ocean sources over the last 215 000 years carbon isotope fluctuations in both regions are dominated by variable storage of isotopically light carbon on continents with a lesser contribution from these deep ocean circulation changes the cadmium signal in the north atlantic is dominated by changes in deep ocean circulation patterns cadmium shows less variability in the pacific which may reflect changes in the global average cadmium content or minor changes in deep pacific circulation patterns using these records to estimate global averages it appears that glacial ocean water had 22 more cd and 0 46 less 13 c than the modern ocean these numbers are estimates which may be revised as more data become available although they are not likely to be as much as 20 in error for cd or 0 2 for 13 c relative north atlantic deep water nadw formation rates are modulated with a significant 41 kyr periodicity linked to obliquity induced variations in high latitude insolation nadw lags 8 2 kyr behind insolation however

seismic and geologic evidence for early paleogene deepwater circulation in the western north atlantic previous studies of paleogeography global climate and foraminiferal stable isotopes have suggested that paleogene deepwater circulation was significantly different from that of today extracting details of deepwater history from the western north atlantic has been hampered by oligocene erosion and the lack of ideally located drill holes we report the discovery of a seismic disconformity on the sw bermuda rise that we have tied to a late paleocene erosional event in deep sea drilling project dsdp boreholes from this region distribution of this new seismic marker reflector ab indicates that it was formed by cyclonically circulating bottom water entering the western north atlantic from the south we attribute this vigorous deep circulation to a southern ocean source analogous to the effects of modern antarctic bottom water this interpretation is supported by isotopic comparisons that show the paleocene southern ocean was enriched in 13c relative to the pacific we distinguish reflector ab from the overlying reflector au on the basis of superposition and ages obtained at dsdp sites and piston cores using one of the cores we have estimated that the youngest age for reflector au is earliest oligocene 36 6 34 0 ma while its oldest age has been previously established as late eocene laminated sediments beneath reflector ab are enriched in organic carbon indicating that the early paleocene deep western north atlantic was occasionally anoxic these low oxygen levels may have been the result of sluggish deep circulation and or low latitude production of warm saline deep water wsdw sediments immediately above reflector ab show that deposition resumed on the western bermuda rise site 387 by the latest paleocene to earliest eocene biochron np10 57 2 0 6 ma while deposition resumed on the central bermuda rise site 386 during the late paleocene erosion nondeposition continued across much of the bermuda rise widespread resumption of pelagic deposition in the early eocene is consistent with 13c evidence for reduced southern ocean influence at this time however lower eocene sediments record well oxygenated conditions and 13c and 18o comparisons indicate that there were two early eocene deepwater sources the southern ocean and wsdw pak and miller this issue

variations to calcareous nannofossil caco 3 content during the middle eocene c21r h6 hyperthermal event 47 4 ma in the gorrondatxe section bay of biscay western pyrenees abstract the carbonate content of calcareous nannofossils is dependent on seawater composition one of the factors that affect seawater chemistry and consequently the degree of calcification in coccolithophores is temperature as seen in present day warming oceans the depth at which carbonates are dissolved calcite compensation depth ccd can rise due to an increase in hco 3 and decrease in ph leading to a major dissolution on the seabed and burndown similar processes have also been deduced for eocene hyperthermal events such as the petm and etm2 this study reports changes in coccolith carbonate mass from a hemipelagic setting gorrondatxe at 1500 m paleodepth during the core of a minor eocene hyperthermal event namely the c21r h6 event 47 44 47 32 ma image analysis techniques were used to determine differences in the carbonate mass of selected calcareous nannofossil taxa revealing species specific patterns the caco 3 mass of chiasmolithus solitus decreased by 50 over the course of the c21r h6 event and many specimens also lost their crossed central bars an additional indication of mass loss reticulofenestra sp 3 5 m showed a similar trend but the percentage of mass lost was lower toweius pertusus interpreted as being reworked mirrored the behaviour of chiasmolithus solitus suggesting that the caco 3 mass loss may have occurred on the seabed rather than in the water column in general it can be concluded that the lysocline rose to 1500 m paleobathymetry in the bay of biscay during the c21r h6 event formation of corrosive bottom water in the north atlantic ocean is regarded as being responsible for the rise in the lysocline

past co2 changes and tropical sea surface temperatures the relationship between past co2 variations and tropical climate change on time scales of millions of years is reviewed explanations for cretaceous and early cenozoic climate change often involve higher atmospheric co2 levels climate models predict that such increases should have been associated with warmer tropical sea surface temperatures ssts however sparse mid cretaceous 18o based sst estimates from low latitude calcareous plankton are 1 0 1 5 heavier than predicted initial evaluations indicate that changes in salinity may not alleviate model data discrepancies for calcareous 18o and that interpretation of altered latitudinal 18o gradients in terms of increased poleward heat transport due to warm saline bottom water wsbw formation would require very large levels of wsbw production at least 60 sv calcareous 18o records may not always record true sst patterns as 18o analyses from phosphatic groups which are less sensitive to diagenesis indicate ssts 5 c higher this latter conclusion is supported by a number of other fossil groups which indicate temperatures warmer than those estimated from calcareous 18o in order to more rigorously test the paleo co2 hypothesis and indeed the models used to forecast future climates it is desirable to intensify investigations of past climate change in low latitudes in order to determine whether these preliminary conclusions stand the test of further scrutiny

isotopic composition of neodymium in waters from the drake passage the isotopic composition of neodymium has been determined in seawaters from the drake passage the antarctic circumpolar current which controls interocean mixing flows through this passage the parameter e nd 0 which is a function of the ratio of neodymium 143 to neodymium 144 is found to be uniform with depth at two stations with a value which is intermediate between the values for the atlantic and the pacific and indicates that the antarctic circumpolar current consists of about 70 percent atlantic water cold bottom water from a site in the south central pacific has the neodymium isotopic signature of the waters in the drake passage by using a box model to describe the exchange of water between the southern ocean and the ocean basins to the north together with the isotopic results an upper limit of approximately 33 million cubic meters per second is calculated for the rate of exchange between the pacific and the southern ocean concentrations of samarium and neodymium were also determined and found to increase approximately linearly with depth these results suggest that neodymium may be a valuable tracer in oceanography and may be useful in paleo oceanographic studies

astronomically paced changes in deep water circulation in the western north atlantic during the middle eocene abstract north atlantic deep water nadw currently redistributes heat and salt between earth s ocean basins and plays a vital role in the ocean atmosphere co2 exchange despite its crucial role in today s climate system vigorous debate remains as to when deep water formation in the north atlantic started here we present datasets from carbonate rich middle eocene sediments from the newfoundland ridge revealing a unique archive of paleoceanographic change from the progressively cooling climate of the middle eocene well defined lithologic alternations between calcareous ooze and clay rich intervals occur at the 41 kyr beat of axial obliquity hence we identify obliquity as the driver of middle eocene 43 5 46 ma northern component water ncw the predecessor of modern nadw variability high resolution benthic foraminiferal 18 o and 13 c suggest that obliquity minima correspond to cold nutrient depleted western north atlantic deep waters we thus link stronger ncw formation with obliquity minima in contrast during obliquity maxima deep western boundary currents were weaker and warmer while abyssal nutrients were more abundant these aspects reflect a more sluggish ncw formation this obliquity paced paleoceanographic regime is in excellent agreement with results from an earth system model in which obliquity minima configurations enhance ncw formation

near infrared observation and microthermometry of pyrite hosted fluid inclusions pyrite occurs in many types of ore deposits although opaque to visible light some pyrite samples are sufficiently transparent in infrared light to reveal fluid inclusions and other internal features for a reconnaissance study 166 doubly polished thick sections of pyrite from 64 deposits worldwide were examined using an infrared microscope pyrite transparency varies between deposits with low temperature deposits showing the least transparency many samples transparent at room temperature gradually became opaque upon heating pyrite fourier transform infrared ftir spectra taken in the temperature range from 28 to 400 c demonstrate that the degradation of pyrite transparency with an increase in temperature is caused by a gradual shift of the main absorption edge of pyrite towards longer wavelengths recognizable fluid inclusions in pyrite are generally scarcer than fluid inclusions in quartz and microthermometric measurements are more difficult to obtain in the 64 occurrences studied about one quarter contained transparent fluid inclusions of the 37 analyzed fluid inclusions about two thirds yielded salinity measurements and about one quarter yielded homogenization temperatures microthermometric analysis on pyrite hosted fluid inclusions is possible however workable fluid inclusions are limited in occurrence

warming the fuel for the fire evidence for the thermal dissociation of methane hydrate during the paleocene eocene thermal maximum dramatic warming and upheaval of the carbon system at the end of the paleocene epoch have been linked to massive dissociation of sedimentary methane hydrate however testing the paleocene eocene thermal maximum hydrate dissociation hypothesis has been hindered by the inability of available proxy records to resolve the initial sequence of events the cause of the paleocene eocene thermal maximum carbon isotope excursion remains speculative primarily due to uncertainties in the timing and duration of the paleocene eocene thermal maximum we present new high resolution stable isotope records based on analyses of single planktonic and benthic foraminiferal shells from ocean drilling program site 690 weddell sea southern ocean demonstrating that the initial carbon isotope excursion was geologically instantaneous and was preceded by a brief period of gradual surface water warming both of these findings support the thermal dissociation of methane hydrate as the cause of the paleocene eocene thermal maximum carbon isotope excursion furthermore the data reveal that the methane derived carbon was mixed from the surface ocean downward suggesting that a significant fraction of the initial dissociated hydrate methane reached the atmosphere prior to oxidation

nd isotopic structure of the pacific ocean 70 30 ma and numerical evidence for vigorous ocean circulation and ocean heat transport in a greenhouse world the oceanic meridional overturning circulation moc is a crucial component of the climate system impacting heat and nutrient transport and global carbon cycling past greenhouse climate intervals present a paradox because their weak equator to pole temperature gradients imply a weaker moc yet increased poleward oceanic heat transport appears to be required to maintain these weak gradients to investigate the mode of moc that operated during the early cenozoic we compare new nd isotope data with nd tracer enabled numerical ocean circulation and coupled climate model simulations assimilation of new nd isotope data from south pacific deep sea drilling project and ocean drilling program sites 323 463 596 865 and 869 with previously published data confirm the hypothesized moc characterized by vigorous sinking in the south and north pacific 70 to 30 ma compilation of all pacific nd isotope data indicates vigorous distinct and separate overturning circulations in each basin until 40 ma simulations consistently reproduce south pacific and north pacific deep convection over a broad range of conditions but cases using strong deep ocean vertical mixing produced the best data model match strong mixing potentially resulting from enhanced abyssal tidal dissipation greater interaction of wind driven internal wave activity with submarine plateaus or higher than modern values of the geothermal heat flux enable models to achieve enhanced moc circulation rates with resulting nd isotope distributions consistent with the proxy data the consequent poleward heat transport may resolve the paradox of warmer worlds with reduced temperature gradients

an alternative model for caco3 over shooting during the petm biological carbonate compensation decreased caco3 content of deep sea sediments argues for rapid and massive acidification of the oceans during the paleocene eocene thermal maximum petm 56 ma bp in the course of the subsequent recovery from this acidification sediment caco3 content came to exceed pre petm levels known as over shooting past studies have largely attributed the latter to increased alkalinity input to the oceans via enhanced weathering but this ignores potentially important biological factors we successfully reproduce the caco3 records from walvis ridge in the atlantic ocean including over shooting using a biogeochemical box model replication of the caco3 records required 1 introduction of a maximum of 6500 gtc of co2 directly into deep ocean waters or 8000 gtc into the atmosphere 2 limited deep water exchange between the indo atlantic and pacific oceans 3 the disappearance of sediment bioturbation during a portion of the petm and 4 most central to this study a 50 reduction in net caco3 production during acidification in our simulations over shooting is an emergent property generated at constant alkalinity input no weathering feedback as a consequence of attenuated caco3 productivity this occurs because lower net caco3 production from surface waters allows alkalinity to build up in the deep oceans alkalinization thus promoting deep water super saturation restoration of caco3 productivity later in the petm particularly in the indo atlantic ocean leads to greater accumulation of caco3 ergo over shooting which returns the ocean to pre petm conditions over a time scale greater than 200 ka

paleocene to eocene benthic foraminiferal isotopes and assemblages implications for deepwater circulation early paleogene warm climates may have been linked to different modes and sources of deepwater formation warm polar temperatures of the paleocene and eocene may have resulted from either increased atmospheric trace gases or increased heat transport through deep and intermediate waters the possibility of increasing ocean heat transport through the production of warm saline deep waters wsdw in the tethyan region has generated considerable interest in addition general circulation model results indicate that deepwater source regions may be highly sensitive to changing basin configurations to decipher deepwater changes we examined detailed benthic foraminiferal faunal and isotopic records of the late paleocene through the early eocene 60 to 50 ma from two critical regions the north atlantic bay of biscay site 401 and the pacific shatsky rise site 577 these records are compared with published data from the southern ocean maud rise site 690 islas orcadas rise site 702 during the late paleocene similar benthic foraminiferal 18o values were recorded at all four sites this indicates uniform deepwater temperatures consistent with a single source of deep water the highest 13c values were recorded in the southern ocean and were 0 5 more positive than those of the pacific we infer that the southern ocean was proximal to a source of nutrient depleted deep water during the late paleocene upper paleocene reflector ab was cut on the western bermuda rise by cyclonically circulating bottom water also suggesting a vigorous source of bottom water in the southern ocean a dramatic negative excursion in both carbon and oxygen isotopes occurred in the latest paleocene in the southern ocean this is a short term 100 kyr globally synchronous event which also is apparent in both the atlantic and pacific records as a carbon isotopic excursion of approximately 1 faunal analyses from the north atlantic and pacific sites indicate that the largest benthic foraminiferal faunal turnover of the cenozoic was synchronous with the isotopic excursion lending support to the hypothesis that the extinctions were caused by a change in deepwater circulation we speculate that the southern ocean deepwater source was reduced or eliminated at the time of the excursion during the early eocene southern ocean 13c values remained enriched relative to the north atlantic and pacific however the southern ocean was also enriched in 18o relative to these basins we interpret that these patterns indicate that although the southern ocean was proximal to a source of cool nutrient depleted water the intermediate to upper deep water sites of the north atlantic and pacific were ventilated by a different source that probably originated in low latitudes i e wsdw

correlation between isotope records in marine and continental carbon reservoirs near the palaeocene eocene boundary changes in the isotope content of the large marine carbon reservoir can force shifts in that of the smaller carbon pools in the atmosphere and on land the carbon isotope compositions of marine carbonate sediments from the late palaeocene vary considerably exhibiting a sudden decrease close to the palaeocene eocene boundary which coincides with deep sea benthic extinctions1 and with changes in ocean circulation here we report that these fluctuations in the marine carbon isotope record are closely tracked by the terrestrial records provided by palaeosol carbonates and mammalian tooth enamel in using palaeosol carbonates to reconstruct the co2 content of the ancient atmosphere2 isotope shifts of this sort will have to be taken into account the sharp decrease in 13c 12c ratios in the late palaeocene provides a datum for precise correlation of marine and continental records and suggests that abrupt climate warming at this time may have played an important role in the evolution of land mammals

water mass exchange and variations in seawater temperature in the nw tethys during the early jurassic evidence from neodymium and oxygen isotopes of fish teeth and belemnites article i nfo oxygen and neodymium isotope analyses performed on biostratigraphically well dated fish remains recovered from the hettangian to toarcian of the paris basin were used to reconstruct variations of early jurassic seawater temperature and to track oceanographic changes in the nw tethys our results indicate a strong correlation between 18 o trends recorded by fish remains and belemnites confirming the paleoenvironmental origin of oxygen isotope variations interestingly temperatures recorded by pelagic fishes and nektobenthic belemnites and bottom dwelling fishes are comparable during the late pliensbachian sea level lowstand but gradually differ during the early toarcian transgressive episode recording a difference in water temperatures of 6 c during the bifrons zone this could suggest that the surface bottom water temperature difference was not large enough during regressive phases to be recorded by organisms living near the lower and upper part of the water column the globally unradiogenic nd budget of euro boreal waters through the early jurassic suggests that these waters were strongly affected by continental neodymium input from surrounding emerged areas and that exchange with more radiogenic waters from the tethys and panthalassa oceans remained limited this supports the existence of a southward directed current in the euro boreal area for most of the early jurassic the only exception is observed at the early late pliensbachian transition where a positive end excursion is recorded suggesting northward influx of low latitude tethyan or panthalassan waters which may have contributed to the warming of nw tethyan seawater recorded at this time the absence of a marked negative excursion in end concomitant with a negative 18 o shift recorded during the falciferum zone exaratum subzone argues against the influence of less radiogenic arctic water influxes with low 18 o values during this interval instead we suggest that

the age palaeoclimate palaeovegetation coal seam architecture mire types paleodepositional environments and thermal maturity of syn collision paralic coal from mukah sarawak malaysia abstract the mukah coal accumulated in the balingian formation where the time stratigraphic position is poorly defined by fauna though a probable late miocene age has always been assigned to this formation samples collected in the present study that yielded an abundance of casuarina pollen associated with occurrences of dacrydium stenochlaena palustris florschuetzia levipoli and also stenochlaena areolaris spores compare closely to zone pr9 of the palynological zonation of the malay basin and can be tied to depositional sequences of malay basin seismic sequences i2000 i3000 indicating an early miocene age for the studied coal the early miocene age shows that the mukah coal was formed during the collision between luconia block dangerous grounds with the borneo that lasted from late eocene to late early miocene the rapid increase of deposition base level caused by the collision is clearly reflected by the architecture of the mukah coal seams that were generally thin and also by the reverse order of the paleo peat bodies the studied coal samples contained large amounts of detrohuminite without the enrichment of liptinite group macerals usually explained by the dominance of herbaceous plants in the paleomires however the pollen assemblages recovered in the present study provide no support for a herbaceous swamp instead the peats were likely formed mainly from forest vegetation based on the recovery of dominant arboreal pollen assemblages in the present study palynomorph assemblages recovered in the present study with abundance of casuarina pollen associated with common occurrences of dacrydium strongly suggest kerangas vegetation and kerapah type peat swamps indicating a very wet climate the occurrence of rattan and pandanus pollens shows that the kerapah type peat swamps were locally bordered by rattan and pandanus swamps this shows that the prevailing use of coal petrography to discern the type of vegetation that was present in the peat forming mires may lead to wrong conclusions therefore a multi disciplinary approach must be applied for a more accurate and reliable spatial interpretation of the type of vegetation that was present in the peat forming mires consistent with the low sulphur content evidence from the palynomorph assemblages recovered from the coal seams shows that the coal forming peat was deposited in freshwater mires with little or no marine influence despite the fact that the accumulation of the mukah coal forming peat took place within a coastal plain setting moreover the fauna present in the host rock formation also suggested a brackish water environment of deposition

new chronology for the late paleocene thermal maximum and its environmental implications the late paleocene thermal maximum lptm is associated with a brief but intense interval of global warming and a massive perturbation of the global carbon cycle we have developed a new orbital chronology for ocean drilling program odp site 690 weddell sea southern ocean by using spectral analysis of high resolution geochemical records the lptm interval spans 11 precessional cycles yielding a duration of 210 to 220 k y the 13 c anomaly associated with the lptm has a magnitude of about 2 5 to 3 we show that about 2 of the excursion occurs within two steps that each were less than 1000 yr in duration the remainder developed through a series of steps over 52 k y the timing of these steps is consistent with a series of nearly catastrophic releases of methane from gas hydrates punctuated by intervals of relative equilibria between hydrate dissociation and carbon burial further we are able to correlate the records between odp sites 690 and 1051 western north atlantic on the scale of 21 k y cycles which demonstrates that the details of the 13 c excursion are recognizable between distant sites comparison of cycle records at sites 690 and 1051 suggests that sediment representing the interval 30 k y just prior to and at the onset of the lptm are missing in the latter location this unconformity probably resulted from slope failure accompanying methane hydrate dissociation within 10 k y of the start of the lptm

continental runoff and early cenozoic bottom water sources the dominance of warm saline bottom water during the mid cretaceous and the early cenozoic has been inferred from sea floor sediment records an interpretation supported by early ocean general circulation model experiments thermohaline circulation depends in part on upper ocean salinities however early ocean models neglected continental runoff a potentially critical factor in the salinity budget of the surface ocean our early eocene ocean model sensitivity tests show that model deep water sources can be enhanced diminished or turned off by varying the treatment of continental runoff in the atmosphere ocean moisture flux calculation failure to treat surface runoff adequately thus has important implications for the simulation of thermohaline flow and formation of warm saline bottom water variations in runoff could have led to rapid changes in the relative importance of high latitude versus subtropical deep water such as may have occurred during the late paleocene early eocene boundary interval 53 6 56 2 ma

closure of the central american isthmus and its effect on deep water formation in the north atlantic modern ocean thermohaline driven circulation influences global climate by transporting heat to high latitudes1 2 and by affecting the exchange of co2 between ocean and atmosphere3 north atlantic deep water nadw plays a key role in this circulation and quaternary climate cycles have been linked to changes in nadw flow4 general circulation model simulations indicate that before closure some 3 4 million years ago of the central american isthmus the narrow strip of land linking north and south america the direct flow of low salinity water from the pacific to the atlantic ocean would have led to a smaller nadw flow5 6 sedimentation patterns7 and nutrient proxies8 11 support these model results by indicating an increase in nadw flow around the time of isthmus closure but these records do not allow changes in different nadw sources to be distinguished and the overall effect of closure on global ocean circulation is poorly known here we present nd pb and sr isotope records preserved by a hydrogenous ferromanganese crust from the nadw flow path in the western north atlantic ocean these records indicate that the isotopic signal associated with nadw strengthened around 3 4 million years ago showing that deep water that formed in the labrador sea made a gradually increasing contribution to nadw flow these data taken together with those from the central pacific ocean12 indicate an increased nadw flow since isthmus closure and suggest that the closure established today s general pattern of ocean circulation

cadmium zinc copper and barium in foraminifera tests the concentrations of cadmium zinc copper and barium have been determined on 2 mg samples of single species foraminifera populations cleaning techniques were tested using north atlantic core tops and followed by a detailed downcore study for the last 30 000 years in south atlantic core v22 174 raw foram tests cleaned by crushing followed by ultrasonic removal of fine grained material and dissolved in a ph 5 5 acetate buffer contain appreciable amounts of trace elements associated with ferromanganese and alumino silicate contaminants a reductive complexing cleaning treatment reduces ferromanganese contamination by 1 2 orders of magnitude acetate buffers at ph 5 5 complex iron and raise the solubility of ferromanganese oxides these buffers are unsuitable for separating carbonate lattice bound trace elements from the fraction associated with ferromanganese phases improved mechanical and ultrasonic reductive cleaning combined with a mild dissolution in distilled water under 1 atm pco2 reduces contaminant levels another order of magnitude the cd and zn concentrations order 10 8 mole cd mole ca and 10 5 mole zn mole ca of species with low surface area show an increase with decreasing isotopic temperatures this increase is consistent with the increasing concentrations of these metals from low values in surface waters to higher values at depth the variance of cd and zn over the last 30 000 years in the central south atlantic is consistent with the probable variability of the dissolved trace elements at the calcification levels of the species analyzed cu and ba are irreproducible and probably sensitive to residual contaminant phases the trace element content of the tests differs from levels observed in a recent coprecipitation study foraminifera may be a significant vector in zinc cycling in the ocean

abrupt climate change and transient climates during the paleogene a marine perspective detailed investigations of high latitude sequences recently collected by the ocean drilling program odp indicate that periods of rapid climate change often culminated in brief transient climates with more extreme conditions than subsequent long term climates two examples of such events have been identified in the paleogene the first in latest paleocene time in the middle of a warming trend that began several million years earlier the second in earliest oligocene time near the end of a middle eocene to late oligocene global cooling trend superimposed on the earlier event was a sudden and extreme warming of both high latitude sea surface and deep ocean waters imbedded in the latter transition was an abrupt decline in high latitude temperatures and the brief appearance of a full size continental ice sheet on antarctica in both cases the climate extremes were not stable lasting for less than a few hundred thousand years indicating a temporary or transient climate state geochemical and sedimentolog

the geochemistry of rare earth elements in the amazon river estuary abstract the estuarine geochemistry of rare earth elements rees was studied using samples collected in the amazon river estuary from the amasseds amazon shelf sediment study cruise of august 1989 extensive removal of dissolved 0 22 m filtered trivalent rees from river water occurs in the low 0 6 salinity region removal by the salt induced coagulation of river colloids leads to fractionation among the ree iii series the order of removal is light rees middle rees heavy rees there also is the enhanced removal of ce relative to trivalent la and nd in the low salinity 0 6 zone and in the zone of high biological activity this is the first field observation of strong ce removal associated with coagulation of river colloids and biological productivity the argument is made that the decrease in the ce anomaly across a biological front is caused by biologically mediated oxidation of ce iii to ce iv coagulation of river colloids and biologically mediated oxidation of ce iii lead to fractionation of ree iii and redox modification of ce these processes result in the ree composition becoming fractionated relative to the amazon river water and crust and more evolved toward the ree composition of the oceans this study implies that reactions in estuaries play significant yet poorly understood roles in controlling the ree composition and ce anomaly of the oceans

coccolithophore productivity response to greenhouse event of the paleocene eocene thermal maximum abstract during the paleocene eocene thermal maximum petm rapid release of isotopically light c to the ocean atmosphere system elevated the greenhouse effect and warmed temperatures by 5 7 c for 105 yr the response of the planktic ecosystems and productivity to the dramatic climate changes of the petm may represent a significant feedback to the carbon cycle changes but has been difficult to document we examine sr ca ratios in calcareous nannofossils in sediments spanning the petm in three open ocean sites as a new approach to examine productivity and ecological shifts in calcifying plankton the large heterogeneity in sr ca among different nannofossil genera indicates that nannofossil sr ca reflects primary productivity driven geochemical signals and not diagenetic overprinting elevated sr ca ratios in several genera and constant ratios in other genera suggest increased overall productivity in the atlantic sector of the southern ocean during the petm dominant nannofossil genera in tropical atlantic and pacific sites show sr ca variations during the petm which are comparable to background variability prior to the petm despite acidification of the ocean there was not a productivity crisis among calcifying phytoplankton we use the pandora ocean box model to explore possible mechanisms for petm productivity change if independent proxy evidence for more stratified conditions in the southern ocean during the petm is robust then maintenance of stable or increased productivity there likely reflects increased nutrient inventories of the ocean increased nutrient inventories could have resulted from climatically enhanced weathering and would have important implications for burial rates of organic carbon and stabilization of climate and the carbon cycle

impact of dissolution on the sedimentary record of the paleocene eocene thermal maximum the input of massive amounts of carbon to the atmosphere and ocean at the paleocene eocene thermal maximum petm 55 53 ma resulted in pervasive carbonate dissolution at the seafloor at many sites this dissolution also penetrated into the underlying sediment column the magnitude of dissolution at and below the seafloor a process known as chemical erosion and its effect on the stratigraphy of the petm are notoriously difficult to constrain here we illuminate the impact of dissolution by analyzing the complete spectrum of sedimentological grain sizes across the petm at three deep sea sites characterized by a range of bottom water dissolution intensity we show that the grain size spectrum provides a measure of the sediment fraction lost during dissolution we compare these data with dissolution and other proxy records electron micrograph observations of samples and lithology the complete data set indicates that the two sites with slower carbonate accumulation and less active bioturbation are characterized by significant chemical erosion at the third site higher carbonate accumulation rates more active bioturbation and possibly winnowing have limited the impacts of dissolution however grain size data suggest that bioturbation and winnowing were not sufficiently intense to diminish the fidelity of isotopic and microfossil assemblage records

paleocean circulation during the last deglaciation a bipolar seesaw hughen et al 1998 have documented that during the first 200 years of younger dryas time the 14c content of atmospheric co2 increased by 50 and that during the remainder of this 1200 year duration cold event it steadily declined the initial increase in 14c c was likely the result of a reduction in the atlantic s conveyor circulation however were the subsequent radiocarbon decline due to the rejuvenation of this potent heat pump then it is difficult to understand why the climate conditions in the northern atlantic basin remained cold throughout the younger dryas modeling exercises by stocker and wright 1996 mikolajewicz 1998 and schiller et al 1998 show that if the conveyor is terminated the transfer of radiocarbon into the deep sea shifts to the southern ocean thereby stabilizing the atmospheric 14c c ratio paleoclimatic evidence from the antarctic continent suggests that this model based scenario might have been played out in the real world while the younger dryas cooling has been documented in many places around the world including new zealand denton and hendy 1994 sowers and bender 1995 using their 18o in o2 based correlation between the ice core 18o in ice records for antarctica and greenland have demonstrated that in antarctica the younger dryas was a time of maximum warming the point of this paper is that the steep rise in 18o rise in antarctic ice which commenced close to the onset of the younger dryas might have been caused by heat released to the atmosphere in response to an increase in deep sea ventilation in the southern ocean

implications for the creation of warm saline deep water late paleocene reconstructions and global climate model simulations a global warming trend began during the late paleocene that culminated in the early eocene with the highest global temperatures of the cenozoic we have reconstructed late paleocene surficial boundary conditions and modeled atmospheric conditions using the goddard institute for space studies general circulation model version ii giss gcm ii these experiments were conducted to test the hypothesis that warm saline deep water formed during the late paleocene and to understand atmospheric circulation near the beginning of a period of global warming the warming is attributed primarily to increased sea surface temperatures at high latitudes the sensitivity of the climate to ocean temperature was tested using two sea surface temperature distributions each delimited latitudinally by oxygen isotope values but with different east west gradients the simulations discussed here contain several features unique among warm climate experiments the first experiment p 1 used latitudinally constant zonal sea surface temperatures the zonally distributed sea surface temperatures strengthen the general circulation of the atmosphere in particular hadley cell circulation is intensified leading to extremes of precipitation in the equatorial region and extreme evaporation across subtropical oceans the unusual results prompted a second experiment with modern east west sea surface temperature gradients superimposed and referred to as p gradient p grad the east west gradients in the sea surface temperature field exert a strong influence on the general atmospheric circulation but the extreme zonality prevails under extreme zonal conditions it is possible to create a model where evaporation is in excess of precipitation by as much as 3 mm day if this occurred in restricted areas in a generally warmer ocean such as the late paleocene eastern tethys ocean and parts of the south atlantic ocean it should be possible to create very saline water which could become a component in warm saline deep water formation

oceanic calcium changes from enhanced weathering during the paleocene eocene thermal maximum no effect on calcium based proxies 1 during the paleocene eocene thermal maximum petm 55 myr ago prominent climatic and biogeochemical changes took place in the atmosphere ocean and on land for example deep sea temperatures rose by 5 c to 6 c while sea surface temperatures at high latitudes increased by up to 9 c in the sedimentary record the onset of the petm is marked by widespread dissolution of calcium carbonate on the seafloor in addition there is evidence for globally higher humidity precipitation and increased weathering during the petm both calcium carbonate dissolution and enhanced weathering probably affected the seawater calcium concentration here we investigate implications that possible changes in the ocean s calcium inventory may have had on boron calcium b ca and magnesium calcium mg ca ratios which are used as proxies for deep water carbonate chemistry and temperature respectively we also examine effects on 44ca of seawater which is used as an indicator for variations in the marine calcium cycle we focus on the magnitude of change in the ocean s calcium ion concentration as a result of the carbon perturbation which resulted in increased weathering fluxes and the dissolution of calcite on the ocean floor during the petm different ranges of carbon input scenarios and their effect on ocean chemistry were examined using the long term ocean atmosphere sediment carbon cycle reservoir loscar model we found that under the most plausible scenario the calcium ion concentration change ca2 was less than 0 7 and around 2 in the most extreme scenario our results show that b ca and mg ca proxies were not affected within analytical precision by changes in oceanic calcium due to weathering and carbonate dissolution during the petm the most extreme scenario ca2 2 would result in 4 mol kg 1 uncertainty in reconstruction of co32 the same scenario affects the temperature reconstruction by 0 2 c the effect on the ocean s calcium isotope budget was insignificant as well resulting in 44casw of less than 0 05

plate tectonics radiogenic isotopic tracers and paleoceanography the case of the manganese crusts in the pacific abstract hydrogenous ferromanganese crust deposits on seafloor and volcanic seamounts are archives of past isotopic compositions of the ocean isotopic compositions of long life radiogenic isotopes that are dissolved in the ocean such as nd and pb are mixtures of different erosion products continents volcanics arcs ridges etc transported by oceanic currents or winds isotopic studies on mn crusts are thus potential paleogeographic and paleoceanographic tracers however global paleogeography can drastically evolve over the period of growth of crust as well as the latitude longitude and water depth of the mn crust thus each crust sampled a succession of geographic sites related to its spatial evolution through time for this reason valid information about the past ocean isotopic composition can only be extracted from mn crust under the condition that the successive paleogeographic and paleodepth positions can be reconstructed for each mn crust we followed this approach for six hydrogenous mn crusts from the pacific ocean that have recorded pb and nd isotopic signals for the past 80 myr the evolution of the isotopic data was considered within a proper geodynamical framework that takes into account the paleopositions of the pacific plate and surrounding continents of the hot spots and ridges as well as the paths of the six crusts the differences and similarities between the pb and nd revealed by our analysis emphasize their complementarity as paleoceanographic tracers the nd isotopes are strongly influenced by the exchange between indian and pacific waters specifically by the progressive closure of the indonesian gateway the closed central pacific characteristics are defined from the extrapolation of the isotopic trend this highlights the important role played by erosion of volcanic arcs in the nd isotopic value of seawater our approach also stresses the influence of local volcanic activity ridges or active hot spot for lead isotopes

geochemical decoupling of water masses in the variscan oceanic system during late devonian times abstract neodymium isotope data obtained from conodonts collected in morocco and poland attest a geochemical decoupling of seawater in the variscan realm during the late devonian the water masses on the shelves were characterized by unradiogenic e nd values from about 7 to 12 the surface water in the bordering oceans the rheic ocean and the variscan sea yielded more radiogenic e nd values ranging from about 1 to 6 a compilation of nd and c isotope signatures from the moroccan meseta suggests that the shelf and the surface oceanic water differed also in their carbon isotope evolution the geochemical decoupling constrains a restricted water exchange between shelves and the ocean oceanic waters entered far into the shelf areas only during the semichatovae transgression in the frasnian zone 11 sea level fluctuations constituted the major force that modified circulation and thus controlled the mixing of shelf and surface oceanic seawater the nd conodont data reveal that the surface water of the variscan oceanic water resembled the seawater of the modern pacific ocean rather than those of the atlantic and indian oceans the geochemical character of the variscan oceanic water is consistent with the geotectonic regime of the variscan realm in late devonian and carboniferous times

the use of foraminifera as a record of the past neodymium isotope composition of seawater 1 we present new isotopic data for sedimentary planktonic foraminifera as well as for potential water column and sedimentary sources of neodymium nd which confirm that the isotopic composition of the foraminifera is the same as surface seawater and very different from deep water and sedimentary nd the faithfulness with which sedimentary foraminifera record the isotopic signature of surface seawater nd is difficult to explain given their variable and high nd ca ratios ratios that are often sedimentary foraminifera ratios that are often much higher than is plausible for direct incorporation within the calcite structure we present further data that demonstrate a similarly large range in nd ca ratios in plankton tow foraminifera a range that may be controlled by redox conditions in the water column cleaning experiments reveal in common with earlier work that large amounts of nd are released by cleaning with both hydrazine and diethylene triamine penta acetic acid but that the nd released at each step is of surface origin while further detailed studies are required to verify the exact location of the surface isotopic signature and the key controls on foraminiferal nd isotope systematics these new data place the use of planktonic foraminifera as recorders of surface water nd isotope ratios and thus of variations in the past supply of nd to the oceans from the continents via weathering and erosion on a reasonably sure footing

neodymium isotopic variations in north pacific modern silicate sediment and the insignificance of detrital ree contributions to seawater the neodymium isotopic composition of the silicate fraction of holocene pelagic sediments from the north pacific define two provinces a central north pacific province characterized by unradiogenic and remarkably homogeneous end 10 2 0 5 and a narrow circum pacific marginal province characterized by more radiogenic and variable end 4 2 3 8 the silicate fraction in the central north pacific is exclusively eolian based on prevailing wind patterns meteorological data and neodymium isotopic data the only significant sediment source is chinese loess leaching experiments on chinese loess confirm that leachable nd is isotopically indistinguishable from bulk and residual silicate nd silicates in the circum north pacific marginal province comprise eolian loess volcanic ash and hemipelagic sediments derived from volcanic arcs a compilation of pacific seawater and mn nodule end data shows no clear spatial variation except for a general decrease from surface to deep waters from 3 to 4 and slightly lower end in bottom waters along the western north pacific due to the incursion of antarctic bottom water the relative homogeneity of bottom water end which contrasts sharply with the distinctive variation in sediment end plus the large difference between the average end of bottom waters and the central north pacific eolian silicates 4 vs 10 suggests that any contribution of ree to seawater from eolian materials is insignificant furthermore leaching of ree from eolian particles as they sink though the water column must be insignificant because nd in shallow waters is more radiogenic than nd in deeper waters that there is no contrast in the nd isotopic composition of bottom waters that overlie the central and marginal sediment provinces suggests that the ash and hemipelagic sediments derived from pacific rim volcanic arcs also contribute minimal ree to seawater the elimination of eolian ash and hemipelagic sediments leaves only near shore riverine particulates as a possibly significant particulate source of ree to seawater

antarctic climate southern ocean circulation patterns and deep water formation during the eocene we assess early to middle eocene seawater neodymium nd isotope records from seven southern ocean deep sea drill sites to evaluate the role of southern ocean circulation in long term cenozoic climate change our study sites are strategically located on either side of the tasman gateway and are positioned at a range of shallow 500 m to intermediate deep 1000 2500 m paleowater depths unradiogenic seawater nd isotopic compositions reconstructed from fish teeth at intermediate deep indian ocean pelagic sites ocean drilling program odp sites 738 and 757 and deep sea drilling project dsdp site 264 indicate a dominant southern ocean sourced contribution to regional deep waters end t 9 3 1 5 iodp site u1356 off the coast of adelie land a locus of modern day antarctic bottom water production is identified as a site of persistent deep water formation from the early eocene to the oligocene east of the tasman gateway an additional local source of intermediate deep water formation is inferred at odp site 277 in the sw pacific ocean end t 8 7 1 5 antarctic proximal shelf sites odp site 1171 and site u1356 reveal a pronounced erosional event between 49 and 48 ma manifested by 2 end unit negative excursions in seawater chemistry toward the composition of bulk sediments at these sites this erosional event coincides with the termination of peak global warmth following the early eocene climatic optimum and is associated with documented cooling across the study region and increased export of antarctic deep waters highlighting the complexity and importance of southern ocean circulation in the greenhouse climate of the eocene

influence of the amazon river on the nd isotope composition of deep water in the western equatorial atlantic during the oligocene miocene transition highlights records of seawater endend are highly unradiogenic across the omt at ceara rise strong influence of amazon particulate nd on seawater endend at ceara rise point sourced riverine nd influences seawater far from continental shelf regional sedimentary nd flux can be confused with water mass mixing signals abstract dissolved and particulate neodymium nd are mainly supplied to the oceans via rivers dust and release from marine sediments along continental margins this process together with the short oceanic residence time of nd gives rise to pronounced spatial gradients in oceanic 143nd 144nd ratios endend however we do not yet have a good understanding of the extent to which the influence of riverine point source nd supply can be distinguished from changes in mixing between different water masses in the marine geological record this gap in knowledge is important to fill because there is growing awareness that major global climate transitions may be associated not only with changes in large scale ocean water mass mixing but also with important changes in continental hydroclimate and weathering here we present endend data for fossilised fish teeth planktonic foraminifera and the fe mn oxyhydroxide and detrital fractions of sediments recovered from ocean drilling project odp site 926 on ceara rise situated approximately 800 km from the mouth of the river amazon our records span the mi 1 glaciation event during the oligocene miocene transition omt 23 ma we compare our endend records with data for ambient deep atlantic northern and southern component waters to assess the influence of particulate input from the amazon river on nd in ancient deep waters at this site endend values for all of our fish teeth foraminifera and fe mn oxyhydroxide samples are extremely unradiogenic end 15end 15 much lower than the endend for deep waters of modern or oligocene miocene age from the north atlantic end 10end 10 and south atlantic end 8end 8 this finding suggests that partial dissolution of detrital particulate material from the amazon end 18end 18 strongly influences the endend values of deep waters at ceara rise across the omt we conclude that terrestrially derived inputs of nd can affect endend values of deep water many hundreds of kilometres from source our results both underscore the need for care in reconstructing changes in large scale oceanic water mass mixing using sites proximal to major rivers and highlight the potential of these marine archives for tracing changes in continental hydroclimate and weathering

sudden spreading of corrosive bottom water during the palaeocene eocene thermal maximum the palaeocene eocene thermal maximum was associated with warming and seafloor carbonate dissolution numerical simulations suggest that the spread of deep corrosive water from the north atlantic can explain the observed dissolution patterns

ocean and climate response to north atlantic seaway changes at the onset of long term eocene cooling abstract around the early middle eocene boundary the first occurrence of contourite drift sediments and widespread deep ocean erosion indicate changes in the north atlantic ocean circulation interestingly these changes coincide with the first steps of cenozoic cooling from the paleogene greenhouse climate towards the modern icehouse the cause for this ocean circulation reorganization is poorly understood since modern water mass tracers may have worked fundamentally different in the past and the paleoceanographic proxy record is limited in both time and space as a result it is challenging to reliably reconstruct the climatic and tectonic boundary conditions e g atmospheric greenhouse gas concentration and the depth and geometry of developing and closing passages between ocean basins in this study we attempt to identify thresholds in tectonic gateway passages and atmospheric co2 concentration using the fully coupled earth system model cosmos indeed the simulation of earth s past climates can unravel the physical processes driving deep water formation in a greenhouse world specifically we use cosmos to evaluate the impact of changes in the north atlantic gateways at the early middle eocene boundary on the north atlantic deep western boundary currents under low obliquity configuration we find that northern component waters start to form when the greenland scotland ridge reaches a threshold depth of deeper than 200 m while the arctic ocean is still shut off from the north atlantic in this scenario the relatively deep greenland scotland ridge allows for sufficient inflow of warm salty atlantic surface waters into the nordic seas to initiate convection during winter cooling opening the seaway towards the arctic leads to a cessation of northern component water formation as it allows for inflow of brackish surface waters into the northern nordic seas hindering northern component water formation

evidence for deep water production in the north pacific ocean during the early cenozoic warm interval the deep ocean circulation is responsible for a significant component of global heat transport in the present mode of circulation deep waters form in the north atlantic and southern oceans where surface water becomes sufficiently cold and dense to sink polar temperatures during the warmest climatic interval of the cenozoic era approximately 65 to 40 million years myr ago were significantly warmer than today and this may have been a consequence of enhanced oceanic heat transport however understanding the relationship between deep ocean circulation and ancient climate is complicated by differences in oceanic gateways which affect where deep waters form and how they circulate here i report records of neodymium isotopes from two cores in the pacific ocean that indicate a shift in deep water production from the southern ocean to the north pacific approximately 65 myr ago the source of deep waters reverted back to the southern ocean 40 myr ago the relative timing of changes in the neodymium and oxygen isotope records indicates that changes in cenozoic deep water circulation patterns were the consequence not the cause of extreme cenozoic warmth

evolution of nd and pb isotopes in central pacific seawater from ferromanganese crusts abstract hydrogenetic ferromanganese crusts incorporate elements from ambient seawater during their growth on seamounts by analysing nd pb and be isotope profiles within crusts it is possible to reconstruct seawater tracer histories depth profiles of 10be 9be ratios in three pacific ferromanganese crusts have been used to obtain growth rates which are between 1 4 and 3 8 mm ma nd and pb isotopes provide intact records of isotopic variations in pacific seawater over the last 20 ma or more there were only small changes in pb isotope composition in the last 20 ma this indicates a constant pb composition for the erosional sources and suggests further that erosional nd inputs may have been uniform too end values vary considerably with time and most probably reflect changes in ocean circulation the end values of the crusts not only vary as a function of age but also as a function of water depth from 25 to 0 ma crust va13 2 from 4 8 km water depth has a similar pattern of end variation to the two shallower crusts from 1 8 and 2 3 km but about 1 0 to 1 5 units more negative this suggests that end stratification in pacific seawater as demonstrated for the present day has been maintained for at least 20 ma each crust shows a decrease in end from 3 5 ma to the present which is interpreted in terms of an increase in the nadw component present in the pacific from 10 to 3 5 ma ago the crusts show an increase in end this suggests a decreasing role for a deep water source with end less than circum pacific sources in this regard the panamanian gateway restriction from 10 ma with final closure at 3 5 ma may have played an important role in reducing access of atlantic derived nd to the pacific

warm saline bottom water in the ancient ocean considerable isotopic evidence indicates that oceanic bottom water was much warmer in the geological past a simple convection model driven by multiple turbulent buoyant plumes and observations of present deep water formation have led to the development of a theory for the formation of warm saline bottom water it is suggested that changes in the size and configuration of marginal seas in net evaporation zones due to lithospheric plate motions and eustatic sea level change caused these seas to become sources of warm saline bottom water evidence from the palaeotemperature record and palaeogeography during the late cretaceous is used to reinforce the hypothesis climatic and chemical consequences of the formation of warm saline bottom water are discussed

the geochemical balance of the rare earth elements and neodymium isotopes in the oceans profiles of ree concentrations and neodymium isotope measurements in the western indian ocean are consistent with published data from the other major oceans ree concentrations show a strong hydrographic control the influence of intermediate water masses is particularly significant surface water concentrations vary with salinity paniculate rees are less than 5 of dissolved concentration except for ce where up to 20 of total rees are present as 0 4 m particles in contrast to dissolved profiles concentration profiles of paniculate rees including ce all increase with depth ree concentrations correlate with silica over all but the deepest waters although in detail correlations are complex the neodymium isotopic composition of indian ocean seawater avg nd 0 8 3 is intermediate between that for the atlantic and pacific oceans comparison of ree data from the major oceans shows that the hrees behave more like si than do the lrees sm nd ratios are near constant for all oceans whereas ernd ratios vary between the atlantic indian and pacific oceans the fractionation of the rees in surface seawaters can be explained by fractionation factors relative to silica from 0 12 for la to 0 05 for er use of a seven box model shows that the interoceanic variations in neodymium isotopic compositions and nd concentrations cannot be reconciled unless particle water exchange is invoked the degree of exchange required is consistent with particle residence times of 1 10 yr

evolution of early cenozoic marine temperatures the equator to high southern latitude sea surface and vertical temperature gradients are reconstructed from oxygen isotope values of planktonic and benthic foraminifers for the following five time intervals late paleocene early eocene early middle eocene late eocene and early oligocene paleotemperatures are calculated using standard oxygen isotope temperature equations with adjustments to account for 1 variations in sea water 18o related to changes in global ice volume over time and 2 latitudinal gradients in surface water 18o these reconstructions indicate that sea surface temperatures sst of the southern oceans in the early eocene were as high as 15 c whereas temperatures during the late paleocene and early middle eocene reached maximum levels of 10 12 c by the late eocene and early oligocene high latitude sst had declined to 6 and 4 c respectively for most of the early paleogene low latitude sub tropical temperatures remained constant and well within the range of holocene temperatures 24 ndash 25 c but by the late eocene and early oligocene declined to values in the range of 18 to 22 c the late paleogene apparent decline in tropical temperatures however might be artificial because of dissolution of near surface foraminifera tests which biased sediment assemblages toward deeper dwelling foraminifera moreover according to recent plate reconstructions it appears that the majority of sites upon which the late eocene and early oligocene tropical temperatures were previously established were located either in or near regions likely to have been influenced by upwelling global deepwater temperature on average paralleled southern ocean sst for most of the paleogene we speculate based on the overall timing and character of marine sea surface temperature variation during the paleogene that some combination of both higher levels of greenhouse gases and increased heat transport was responsible for the exceptional high latitude warmth of the early eocene

effect of the deepening of the tasman gateway on the global ocean 1 we examine the effect of the deepening of the tasman seaway at the end of the eocene in a climate model with realistic late eocene bathymetry and winds for this we have constructed an eocene numerical model based on the university of victoria climate model with wind forcing derived from a fully coupled eocene simulation the model climate state is characterized by an oceanic meridional overturning circulation moc involving southern hemisphere sinking and a northward atmospheric moisture transport across the equator the deepening of the tasman seaway in the presence of an open drake passage and the associated establishment of the antarctic circumpolar current acc have a limited climatic impact on antarctica nonetheless the antarctic deep sinking regions cool sufficiently to lead to a global deep ocean cooling of 3 c no initiation of northern component water is found indicating that this may require the development of a more mature acc previous studies suggest that the ross sea gyre cools the east coast of australia and expected the deepening of the tasman seaway to lead to a warming east of australia due to the introduction of warmer water from the australo antarctic gulf we here find that this warming is limited to close to the australian coast and that widespread cooling prevails further off shore

a dual layer chicxulub ejecta sequence with shocked carbonates from the cretaceous paleogene k pg boundary demerara rise western atlantic abstract an up to 2 cm thick chicxulub ejecta deposit marking the cretaceous paleogene k pg boundary the k t boundary was recovered in six holes drilled during odp leg 207 demerara rise tropical western atlantic stunning features of this deposit are its uniformity over an area of 30 km2 and the total absence of bioturbation allowing documentation of the original sedimentary sequence high resolution mineralogical petrological elemental isotopic sr nd and rock magnetic data reveal a distinct microstratigraphy and a range of ejecta components the deposit is normally graded and composed predominantly of rounded 0 1 to max 1 mm sized spherules spherules are altered to dioctahedral aluminous smectite though occasionally relict si al rich hydrated glass is also present suggesting acidic precursor lithologies spherule textures vary from hollow to vesicle rich to massive some show in situ collapse others include distinct fe mg ca ti rich melt globules and lath shaped al rich quench crystals both altered glass spherules and the clay matrix site 1259b display strongly negative e nd t 65 ma values 17 indicating uptake of nd from contemporaneous ocean water during alteration finally fe mg rich spherules shocked quartz and feldspar grains few lithic clasts as well as abundant accretionary and porous carbonate clasts are concentrated in the uppermost 0 5 0 7 mm of the deposit the carbonate clasts display in part very unusual textures which are interpreted to be of shock metamorphic origin the preservation of delicate spherule textures normal grading with lack of evidence for traction transport and sub millimeter scale compositional trends provide evidence for this spherule deposit representing a primary air fall deposit not affected by significant reworking the odp leg 207 spherule deposit is the first known dual layer k pg boundary in marine settings it incorporates compositional and stratigraphic aspects of both proximal and distal marine sites its stratigraphy strongly resembles the dual layer k pg boundary deposits in the terrestrial western interior of north america although there carbonate phases are not preserved the occurrence of a dual ejecta layer in these quite different sedimentary environments separated by several thousands of kilometers provides additional evidence for an original sedimentary sequence therefore the layered nature of the deposit may document compositional differences between ballistic chicxulub ejecta forming the majority of the spherule deposit and material falling out from the vapor ejecta plume which is concentrated in the uppermost part

a high resolution benthic stable isotope record for the south atlantic implications for orbital scale changes in late paleocene early eocene climate and carbon cycling abstract the late paleocene and early eocene were characterized by warm greenhouse climates punctuated by a series of rapid warming and ocean acidification events known as hyperthermals thought to have been paced or triggered by orbital cycles while these hyperthermals such as the paleocene eocene thermal maximum petm have been studied in great detail the background low amplitude cycles seen in carbon and oxygen isotope records throughout the paleocene eocene have hitherto not been resolved here we present a 7 7 million year myr long high resolution orbitally tuned benthic foraminiferal stable isotope record spanning the late paleocene and early eocene interval 52 5 60 5 ma from ocean drilling program odp site 1262 south atlantic this high resolution 2 4 kyr record allows the changing character and phasing of orbitally modulated cycles to be studied in unprecedented detail as it reflects the long term trend in carbon cycle and climate over this interval the main pacemaker in the benthic oxygen isotope 18 o and carbon isotope 13 c records from odp site 1262 are the long 405 kyr and short 100 kyr eccentricity cycles and precession 21 kyr obliquity 41 kyr is almost absent throughout the section except for a few brief intervals where it has a relatively weak influence during the course of the early paleogene record and particularly in the latest paleocene eccentricity paced negative carbon isotope excursions 13 c cies and coeval negative oxygen isotope 18 o excursions correspond to low carbonate caco 3 and coarse fraction cf values due to increased carbonate dissolution suggesting shoaling of the lysocline and accompanied changes in the global exogenic carbon cycle these negative cies and 18 o events coincide with maxima in eccentricity with changes in 18 o leading changes in 13 c by 6 5 kyr in the 405 kyr band and by 3 1 kyr in the higher frequency 100 kyr band on average however these phase lags are not constant with the lag in the 405 kyr band extending from 4 5 kyr to 21 2 kyr from the late paleocene to the early eocene suggesting a progressively weaker coupling of climate and the carbon cycle with time the higher amplitude 405 kyr cycles in the latest paleocene are associated with changes in bottom water temperature of 2 4 c while the most prominent 100 kyr paced cycles can be accompanied by changes of up to 1 5 c comparison of the 1262 record with a lower resolution but orbitally tuned benthic record for site 1209 in the pacific allows for verification of key features of the benthic isotope records which are global in scale including a key warming step at 57 7 ma

possible role of oceanic heat transport in early eocene climate increased oceanic heat transport has often been cited as a means of maintaining warm high latitude surface temperatures in many intervals of the geologic past including the early eocene although the excess amount of oceanic heat transport required by warm high latitude sea surface temperatures can be calculated empirically determining how additional oceanic heat transport would take place has yet to be accomplished that the mechanisms of enhanced poleward oceanic heat transport remain undefined in paleoclimate reconstructions is an important point that is often overlooked using early eocene climate as an example we consider various ways to produce enhanced poleward heat transport and latitudinal energy redistribution of the sign and magnitude required by interpreted early eocene conditions our interpolation of early eocene paleotemperature data indicate that an approximately 30 increase in poleward heat transport would be required to maintain eocene high latitude temperatures this increased heat transport appears difficult to accomplish by any means of ocean circulation if we use present ocean circulation characteristics to evaluate early eocene rates either oceanic processes were very different from those of the present to produce the early eocene climate conditions or oceanic heat transport was not the primary cause of that climate we believe that atmospheric processes with contributions from other factors such as clouds were the most likely primary cause of early eocene climate

flat meridional temperature gradient in the early eocene in the subsurface rather than surface ocean sea surface temperature estimates from the early eocene indicate an unusually flat meridional temperature gradient a re evaluation of the proxy used to derive these temperatures argues against this interpretation

sm nd in marine carbonates and phosphates implications for nd isotopes in seawater and crustal ages this study explores the possibility of establishing nd isotopic variations in seawater over geologic time calcite aragonite and apatite are examined as possible phases recording seawater values of nd modern biogenic and inorganically precipitated calcite and aragonite from marine environments were found to have nd concentrations of from 0 2 to 70 ppb showing that primary marine caco 3 contains little ree and that nd ca is not greatly enhanced relative to seawater during carbonate precipitation very young marine limestone and dolomite containing no continental detritus have 200 ppb nd all the carbonates are lree enriched 0 16 sm nd 0 45 modern and very young atlantic and pacific carbonates have nd in the range of shallow atlantic and pacific seawater respectively implying that they derive their ree from local seawater the nd in well preserved carbonate fossils is 4 10 4 ppb much greater than in their modern counterparts but like the high values found for carbonates in other studies we believe the high ree contents at the 500 ppb level in some detritusfree carbonates are due to ree rich fe hydroxide in on the carbonate in favorable cases such material may record seawater nd values however introduction of extraneous ree may obscure the original isotopic composition of pure caco 3 because of its very low intrinsic primary ree abundance modern biogenic apatite is also shown to have very low ree content 150 ppb nd but appears to quickly scavenge ree from seawater inorganically precipitated apatite from phosphorites has high concentrations of seawater derived ree young phosphorite apatite from the atlantic and pacific oceans has nd in the range of the seawater from these oceans older apatite samples of similar age from different localities bordering common oceans record similar values of nd t sedimentary apatite has sr t values in good agreement with the curves for 87 sr 86 sr of seawater as a function of time individual conodonts from a single formation yield the same sr t and nd t other workers have shown that sedimentary apatite preserves seawater ree patterns these characteristics suggest that sedimentary apatite can be used to determine nd t in ancient seawater the seawater values so inferred range between 1 7 and 8 9 over the last 700 my and lie in the range of modern seawater showing no evidence for drastic changes high values of seawater nd t in the triassic and latest precambrian may correlate with the breakup of large continental landmasses the initial nd t 15 0 of a 2 ae old phosphorite implies the presence of 1 5 ae old continental crust at 2 ae ago the approach outlined here can be used to constrain the age of the exposed crust as a function of time

a molybdenum isotope record of eocene thermal maximum 2 implications for global ocean redox during the early eocene during the early eocene a series of short term global warming events hyperthermals occurred in response to the rapid release of carbon into the oceans and atmosphere in order to investigate the response of ocean redox to global warming we have determined the molybdenum isotope compositions 98 95 mo of samples spanning one such hyperthermal eocene thermal maximum 2 etm 2 54 1ma from integrated ocean drilling program expedition 302 site m0004a in the arctic ocean the highest 98 95 mo in our sample set 2 00 0 11 corresponds to the development of local euxinia at site m0004a during the peak of etm 2 which we interpret as recording the global seawater 98 95 mo at that time the etm 2 seawater 98 95 mo is indistinguishable from a recent estimate of seawater 98 95 mo from an earlier hyperthermal paleocene eocene thermal maximum petm 55 9ma 98 95 mo 2 08 0 11 it is argued that the similarity in seawater 98 95 mo during etm 2 and the petm was caused by the development of transient euxinia in the arctic ocean during each hyperthermal that allowed sediments accumulating in this basin to capture the long term 98 95 mo of early eocene seawater our new data therefore place a minimum constraint on the magnitude of transient global seafloor deoxygenation during early eocene hyperthermals

coupled climate impacts of the drake passage and the panama seaway tectonically active gateways between ocean basins have modified ocean circulation over earth history today the atlantic and pacific are directly connected via the drake passage which forms a barrier to the time mean geostrophic transport between the subtropics and antarctica in contrast during the warm early cenozoic era when antarctica was ice free the drake passage was closed instead at that time the separation of north and south america provided a tropical seaway between the atlantic and pacific that remained open until the isthmus of panama formed in the relatively recent geological past ocean circulation models have previously been used to explore the individual impacts of the drake passage and the panama seaway but rarely have the two gateways been considered together and most explorations have used very simple atmospheric models here we use a coupled ocean ice atmosphere model gfdl s cm2mc to simulate the impacts of a closed drake passage both with and without a panama seaway we find that the climate response to a closed drake passage is relatively small when the panama seaway is absent similar to prior studies although the coupling to a dynamical atmosphere does increase the temperature change however with a panama seaway closing drake passage has a much larger effect due to the cessation of deep water formation in the northern hemisphere both gateways alter the transport of salt by ocean circulation with the panama seaway allowing fresh pacific water to be imported to the north atlantic and the drake passage preventing the flow of saline subtropical water to the circum antarctic a flow that is particularly strong when the panama seaway is open thus with a panama seaway and a closed drake passage the southern ocean tends to be relatively salty while the north atlantic tends to be relatively fresh such that the deep ocean is ventilated from the circum antarctic ensuing changes in the ocean heat transport drive a bi polar shift of surface ocean temperatures and the intertropical convergence zone migrates toward the warmer southern hemisphere the response of clouds to changes in surface ocean temperatures amplifies the climate response resulting in temperature changes of up to 9 c over antarctica even in the absence of land ice feedbacks these results emphasize the importance of tectonic gateways to the climate history of the cenozoic and support a role for ocean circulation changes in the glaciation of antarctica

nd isotope evidence for the evolution of the paleocurrents in the atlantic and tethys oceans during the past 180 ma the nd isotopic composition of atlantic and tethys seawater as deduced from marine phosphorites varied considerably during the past 180 ma the early tethys and central atlantic seawater from 180 to 160 ma ago early middle jurassic had a nd isotopic signature identical to that of the pacific end 6 suggesting that pacific seawater entered the newly forming tethys basin however with time continental runoff draining into the young basin became more important and led to a decrease in the nd isotopic composition and finally a decoupling from the pacific ocean during the late early cretaceous 120 90 ma ago atlantic and tethys seawater reached continental crust like nd isotopic composition values end 10 which could reflect high weathering rates induced by the warm and humid climate at that time in the time span between 80 and 50 ma late cretaceous early tertiary the nd isotopic composition of both tethys and atlantic seawater strongly increased towards pacific seawater values in the case of the atlantic ocean this change has been correlated with the opening of the south atlantic which enabled the more radiogenic pacific seawater to travel westwards around the southern edge of africa into the south and finally the north atlantic in the case of tethys seawater we have to assume that during this period large masses of pacific seawater entered the tethys again directly through the indian tethys seaway the renewed importance of this seaway might be related to the late cretaceous early tertiary first order global sea level highstand the most abrupt change towards lower more crust like values occurred in the early miocene 25 17 ma ago in the south and north atlantic as well as in the tethys during this period the143nd 144nd isotope ratios dropped from 0 5124 end 4 2 down to 0 5122 end 8 this change indicates a diminishing influx of pacif seawater into the atlantic and tethys oceans and can be correlated with the breakdown of the circum equatorial circulation patterns of the world oceans due to plate tectonics from 20 to 17 ma ago miocene the nd isotopic composition of the atlantic ocean increased again and reached values as high as 0 5123 end 6 6 whereas tethys seawater remained at low values this decoupling can be correlated with the incipient complete isolation of the tethys the nd isotopic composition was henceforth controlled by the continental runoff from surrounding land masses the major increase in the nd isotopic composition observed in the atlantic can be related to the opening of the drake passage and establishment of the circum antarctic current system this allowed pacific seawater to enter directly the south atlantic around antarctica a renewed drop in the nd isotopic composition of atlantic seawater during the late miocene can be related to the onset of north atlantic bottom water formation and its subsequent upwelling

rare earth element transport in the western north atlantic inferred from nd isotopic observations the isotopic composition of nd in the water column from several western north atlantic sites and formational areas for north atlantic deep water shows extensive vertical structure at all locations in regions where a thermocline is well developed large isotopic shifts 2 to 3 units are observed across the base of the thermocline regions without a thermocline are characterized by much more gradual shifts in isotopic composition with depth in general the data reveal an excellent correlation between the nd isotopic distribution in the western north atlantic water column and the distribution of water masses identified from temperature and salinity characteristics nadw as identified from t s properties is also characterized by a well defined isotopic composition having nd 0 13 5 0 5 this signature is associated with waters identified as nadw from high latitudes near formational areas in the labrador sea down to the equatorial region the isotopic signature of nadw would appear to be formed by a blend of more negative waters originating in the labrador sea nd 0 18 and more positive waters originating in the overflows from the norwegian and greenland seas nd 0 8 to 10 and is consistent with classical theories on the formation of nadw the isotopic signature of nadw is propagated southward to the equator where it is gradually being thinned out by mixing from above and below with more radiogenic nd associated with northward spreading antarctic intermediate and bottom waters the preservation of the isotopic signature of nadw over these large distances indicate that the ree undergo extensive lateral transport the isotopic composition of nd is largely conservative over the time scales of mixing within the atlantic in spite of the intrinsic nonconservative behavior of neodymium nd concentration gradients generally show surface waters to be depleted in nd relative to deep waters which must require vertical transport processes however isotopic differences in the water column preclude the local downward transport of ree from the surface into underlying deep waters as a simple explanation of the concentration gradient the apparent decoupling of ree in nadw from overlying local surface waters and the increasing concentration with depth provide a conflict with simple vertical transport mechanisms that is not yet resolved

the upper miocene of the southern north sea basin northern belgium a palaeoenvironmental and stratigraphical reconstruction using dinoflagellate cysts organic walled palynomorph assemblages from the kasterlee formation in northern belgium provide new insights into the late miocene depositional history and palaeoenvironments of the southernmost north sea basin ranges of key dinoflagellate cysts constrain the unit between 7 5 and 5 32 ma that is a latest tortonian to messinian age the palynomorph assemblage is characterized amongst others by geonettia clineae an opportunistic species that thrives in mesotrophic coastal embayments with a low sediment influx this environmental setting is corroborated by the notable presence of gramocysta verricula a species with preference for shallow marine environments the occurrence of species of the fresh water green alga pediastrum indicates manifest river discharge in a near shore environment or embayment the coastal depositional environment mirrored by the palynomorphs of the kasterlee formation succeeds the distinct transgressive and fully marine environments of the underlying diest formation in the campine area the results from the palynological study combined with lithological and geophysical data show that both upper miocene formations are two distinct depositional cycles separated by an erosional or regressive phase the upper boundary of the kasterlee formation is correlated with the me2 sequence boundary at 5 73 ma the kasterlee formation is herein formally moved from the lower pliocene series to the upper miocene series the coastal environment probably characterized by a shoaling phase recorded at the border of the southern north sea basin matches the global record of regressive phases in messinian sedimentary sequences which are linked to cooling and increasing global ice volume