new absolute time scale for the quaternary climate in the chinese loess region by grain size analysis continuous loess sequences in china provide not only information for paleoclimatic reconstructions but also permit the establishment of a reliable absolute time scale for the quaternary an empirical relationship is developed between the grain size of the loess and the sedimentation rate in a short well dated reference section step 1 this relationship is extrapolated to the complete quaternary section step 2 after derivation of the sedimentation rate by measuring the grain size in all the layers of the sequence the duration of deposition of each layer is obtained by dividing thickness by sedimentation rate and subsequently the age of each point in the sequence is calculated by adding together all the duration values of the overlying layers the chronology of the extrapolated part of the section obtained in this way is independent of dates provided by other methods and may also be checked by them

u pb dating of monazite and its application to geological problems monazite is an underutilized mineral in u pb geochronological studies of crustal rocks it occurs as an accessory mineral in a wide variety of rocks including granite pegmatite felsic volcanic a

1 500 year cycle in the arctic oscillation identified in holocene arctic sea ice drift decadal to centennial scale variability has been identified in the arctic oscillation but less is known about variations on the millennial scale a record of sea ice drift from off the alaskan coast shows a 1 500 year cycle in the phase of the arctic oscillation

experimental resetting of the u th pb systems in monazite abraded fragments 200 400 m of a large chemically homogeneous and non metamict brazilian monazite crystal characterised by a concordant u pb ages of 474 1 ma 208pb 206pb 19 5 were hydrothermally treated at varying temperatures with solutions of different compositions product monazites were analysed with scanning electron microscope sem electron microprobe emp secondary ion mass spectrometer sims and isotope dilution thermal ionisation mass spectrometer id tims experiments with pure water over a temperature range of 800 1200 c at 700 mpa and durations ranging from 5 to 60 days showed that even at 1200 c any dissolution and recrystallization of new monazite is confined to the outermost surface of the grain neither pb diffusion at the emp scale nor significant discordancy were observed we performed experiments at 800 and 1000 c for different durations using different fluid compositions at quartz saturation a 10 wt cacl2 fluid a 10 wt srcl2 fluid a 10 wt nacl fluid and a fluid containing nbs 982 pb standard 208pb 206pb 1 for all runs emp traverses revealed no pb diffusion profiles significant overgrowths of newly formed monazite are documented by sem analyses they occurred only in the 1000 c experiments when either cacl2 or pb bearing fluids were present in the cacl2 experiment two zones could be distinguished within the crystal a core possessing the initial monazite composition and a rim consisting of newly formed monazite produced by dissolution precipitation which was enriched in ca and pb free id tims dating of single grains treated with srcl2 and cacl2 solutions at 1000 c are significantly discordant experiments employing the nbs pb standard produced sub concordant monazite for which the 207pb 206pb apparent age has become older than prior to the experiment 544 ma at 800 c and 495 ma at 1000 c the newly grown monazite rim had obviously incorporated pb from the fluid none of our reaction products contained a detectable diffusion profile the only resetting mechanism we detected involved dissolution precipitation the extent of the dissolution precipitation process depends on fluid composition and is a more efficient mechanism than diffusion for controlling the resetting of monazite in natural rocks

vein calcite dating reveals pyrenean orogen as cause of paleogene deformation in southern england an improved method of u pb dating of vein calcite formed during deformation is used to determine the age and cause of folding along the south coast of england fractures arising from folding of late cretaceous chalk of southern england occurred 34 7 1 7 myr ago underlying jurassic strata have veins within fractures with ages of 55 48 42 39 37 34 31 and 25 ma with 34 31 ma being the tectonic culmination folding was slightly younger than the age of the youngest strata in the overlying solent group suggesting that folding terminated basin sedimentation this age of north south shortening is inconsistent with attribution to intraplate forces from the mainly younger alps but is plausibly a result of the pyrenean orogen which evolved from 50 to 28 myr ago with a late eocene culmination a modified method for carbonate laser ablation inductively coupled plasma mass spectrometry u pb dating is presented that uses measured 232 th and 208 pb as a better monitor of common pb and it has distinct advantages over existing methods initial common lead determined on samples conforms closely to model compositions calculated by earlier workers with free regressions giving the most robust dates the modified method is applicable to structural geology carbonate diagenesis and to dating of carbonate relevant to palaeo environmental and archaeological studies supplementary material details of sample locations and characteristics photographs of sample localities microscopic images of veins details of the experimental procedure and u pb data for all samples and reference materials are available at https doi org 10 6084 m9 figshare c 3997086

persistent solar influence on north atlantic climate during the holocene surface winds and surface ocean hydrography in the subpolar north atlantic appear to have been influenced by variations in solar output through the entire holocene the evidence comes from a close correlation between inferred changes in production rates of the cosmogenic nuclides carbon 14 and beryllium 10 and centennial to millennial time scale changes in proxies of drift ice measured in deep sea sediment cores a solar forcing mechanism therefore may underlie at least the holocene segment of the north atlantic9s 1500 year cycle the surface hydrographic changes may have affected production of north atlantic deep water potentially providing an additional mechanism for amplifying the solar signals and transmitting them globally

linking hematite u th he dating with the microtextural record of seismicity in the wasatch fault damage zone utah usa techniques directly dating fault slip are few limiting the ability to interpret the rock record of seismicity hematite is commonly found in fault zones amenable to u th he dating and slip surface hematite may be reset by shear heating events and or recrystallization glossy hematite coated fault surfaces in the wasatch fault footwall damage zone utah usa exhibit evidence of hematite cataclasis and preserve pliocene hematite u th he dates apatite u th he and fission track data from the host gneiss indicate footwall unroofing through 2 km by ca 4 5 ma internally reproducible but disparate hematite u th he dates 4 5 ma and younger from isolated locations on a single fault surface do not reflect ambient cooling we hypothesize that these dates and associated iridescence and annealed crystal texture document rapid cooling from friction generated heat during small seismic slip events between ca 4 5 and 2 5 ma thus hematite u th he dating offers the potential to decipher thermal anomalies in the rock record associated with slip on 10 5 10 6 yr time scales

atmospheric variability over the 14 7 kyr bp stadial interstadial transition in the north atlantic region as simulated by an agcm the echam4 t42 atmospheric general circulation model was applied to study the change in atmospheric variability in the north atlantic region over the similar to14 7 kyr cal bp climatic transition from greenland stadial 2a gs 2a end of pleniglacial to greenland interstadial le gi le start late glacial the following three climates are simulated 1 present day 2 gs 2a and 3 gi le we focus on climatic parameters near the earth s surface temperature precipitation and sea level pressure results on two different temporal scales are analysed seasonal and daily the seasonal fields show that the main change over the 14 7 kyr bp transition occurred in winter we calculated daily standard deviations of temperature and pressure about the seasonal means and the high pass filtered less than six days variability of pressure the largest change in atmospheric variability occurred in northwest europe here the daily temperature variability decreased by 50 whereas storm activity also decreased substantially these changes are related to a northward shift of the atlantic sea ice margin at 14 7 kyr bp leading to a northward relocation of the atlantic storm track in the gs 2a experiment a strong storm track was located over northwest europe where frequent depressions produced alternations of northerly air flow below 30 degreesc and southerly air flow close to 0 degreesc this strong daily atmospheric variability decreased in gi le because the storm track had a sw ne orientation over the atlantic towards iceland the decrease in atmospheric variability at 14 7 kyr bp probably contributed to landscape stabilization for instance through decreasing eolian transport

influence of atlantic meridional overturning circulation on the east asian winter monsoon east asian summer monsoon precipitation varied on millennial timescales during the last glacial period sediment records and climate modelling suggest that the winter monsoon was also affected by millenial scale variability and that the abrupt changes were driven by changes in the strength of the atlantic meridional overturning circulation

dating brittle tectonic movements with cleft monazite fluid rock interaction and formation of ree minerals 1 two millimeter sized hydrothermal monazites from an open fissure cleft that developed late during a dextral transpressional deformation event in the aar massif switzerland have been investigated using electron microprobe and ion probe the monazites are characterized by high th u ratios typical of other hydrothermal monazites deformation events in the area have been subdivided into three phases d1 main thrusting including formation of a new schistosity d2 dextral transpression and d3 local crenulation including development of a new schistosity the two younger deformational structures are related to a subvertically oriented intermediate stress axis which is characteristic for strike slip deformation the inferred stress environment is consistent with observed kinematics and the opening of such clefts therefore the investigated monazite bearing cleft formed at the end of d2 and or d3 and during dextral movements along nnw dipping planes interaction of cleft filling hydrothermal fluid with wall rock results in rare earth element ree mineral formation and alteration of the wall rock the main newly formed ree minerals are y si y nb ti minerals and monazite despite these mineralogical changes the bulk chemistry of the system remains constant and thus these mineralogical changes require redistribution of elements via a fluid over short distances centimeter low grade alteration enables local redistribution of ree related to the stability of the accessory phases this allows high precision isotope dating of cleft monazite 232th 208pb ages are not affected by excess pb and yield growth domain ages between 8 03 0 22 and 6 25 0 60 ma monazite crystallization in brittle structures is coeval or younger than 8 ma zircon fission track data and hence occurred below 280 c

monte vulture volcano basilicata italy an analysis of morphology and volcaniclastic facies the earliest activity of monte vulture central italy included ignimbrites but the bulk of the volcano was built up by plinian airfall deposits contemporaneous remobilisation of these deposits formed an apron of lahars around the base of the main cone the volcano was constructed on a ridge the valley to the east and tributaries to the north and south became sediment traps for volcaniclastic materials emplaced by fluvial reworking and directly from volcanic activity to the west the valley was swept clear by active downcutting instability of the west flank as a result of this erosion was probably a contributory cause of major gravitational sector collapse on the volcano s flank terminating the main cone building phase the resultant scar is an amphitheatre shaped hollow called here the valle dei grigi previous workers have attributed this feature to coalescing calderas formed by engulfment the last volcanic phase was the production of the monticchio calderas and associated phreatomagmatic explosions producing airfall and surge deposits because most of the activity at vulture has been repeated plinian eruptions producing similar assemblages of products detailed stratigraphy of the volcano is difficult to accomplish to characterise vulture in terms of its products various facies are identified and interpreted in relation to volcanic processes distance from vent and environmental conditions

contrasting impacts of the arctic oscillation on surface air temperature anomalies in southern china between early and middle to late winter abstractin the boreal winter the arctic oscillation ao evidently acts to influence surface air temperature sat anomalies in china this study reveals a large intraseasonal variation in the relationship between the winter ao and southern china sat anomalies specifically a weak in phase relationship occurs in december but a significant out of phase relationship occurs in january and february the authors show that the linkage between the ao and southern china sat anomalies strongly depends on the ao associated changes in the middle east jet stream mejs and that such an ao mejs relationship is characterized by a significant difference between early and middle to late winter in middle to late winter the azores center of high pressure anomalies in the positive ao phase usually extends eastward and yields a significantly anomalous upper level convergence over the mediterranean sea which can excite a rossby wave train spanning the arabian sea and intensify the mejs in early winter however the azo

contrasting atmospheric and climate dynamics of the last glacial and holocene periods our present climate is relatively stable compared to that of the last glacial maximum about 20 000 years ago palaeoclimate records obtained from ice cores1 2 and deep sea sediment cores3 for the last glacial period show abrupt temperature changes on timescales of a few hundred years which have been attributed to cycles of ice build up and release associated with large ice sheets dansgaard oeschger cycles and heinrich events 3 and their coupling to ocean circulation4 5 but little is known about the dynamics of the atmosphere during the last glaciation ice sheets influence atmospheric circulation and studies using general circulation models have suggested stormier more variable atmospheric dynamics during the last glacial maximum than today6 9 here we report the results of an analysis of temporal trends over the past 91 000 years in the oxygen isotope signatures of a high resolution ice core record from greenland1 2 this analysis provides direct evidence that atmospheric circulation during the last glaciation was more turbulent than it is today

large holocene summer temperature oscillations and impact on the peopling of the northeastern tibetan plateau summer temperatures on the tibetan plateau tp significantly affect stability of glaciers that provide steady water resources to nearly half of the world population however lack of reliable long term proxy records greatly impedes understanding of regional temperature sensitivity to climate forcings here we present a 16ka long alkenone based summer temperature record from lake qinghai northeastern tp that demonstrates major regional temperature response to changes in summer insolation and atlantic meridional overturning circulation during the holocene and late glacial importantly we find a period of sustained summer temperature decline 4 degrees c between 5 and 3 5ka which coincides with expansion of barents sea ice coverage and is likely driven by intensification of the westerlies this unusually long and pronounced regional cooling event likely delayed permanent human settlements on the high altitude regions 3000m of the tp by at least 500years

oxygen isotope thermometry of quartz calcite veins unraveling the thermal tectonic history of the subgreenschist facies morcles nappe swiss alps combined structural analysis and oxygen isotope thermometry of syntectonic quartz calcite fibrous veins can be used to correlate the thermal history of deformed rocks with specific structural and tectonic events results are presented for the morcles nappe in the western helvetic alps switzerland where mineral parageneses illite crystallinity and fluid inclusion chemistry record an apparent peak metamorphic temperature gradient that increased across the morcles nappe from anchizonal conditions in the foreland to epizonal conditions in its hinterland root zone twenty seven quartz calcite veins were analyzed in this study in order to determine the temperatures of veining during formation and deformation of the nappe peak metamorphic temperatures ranged from 260 to 290 c in the shallower foreland localities and to 330 to 350 c in the deeper more hinterland localities at the end of s1 foliation formation related to large scale folding temperatures gradually decreased throughout the nappe during subsequent development of the s2 foliation and s3 crenulation cleavage uplift and erosion of the overlying nappe pile resulted in slow cooling of the morcles nappe during the waning stages of the alpine orogeny the dominant foliation forming deformation of the morcles nappe occurred at elevated temperatures over the course of 10 to 15 ma combined structure oxygen isotope analyses of quartz calcite veins yield better temperature and temporal constraints on the thermal histories of subgreenschist vein bearing tectonites than do other geothermometers

oxygen 18 16 variability in greenland snow and ice with 10 3 to 105 year time resolution the 3 km long greenland ice sheet project 2 gisp2 ice core presents a 100 000 year detailed oxygen isotope profile covering almost a full glacial interglacial cycle measuranents of isotopic fluctuations in snow frost and atmospheric water vapor samples collected during summer field seasons up to 20 0 are compatible with the large and abrupt 80 160 changes observed in accumulated tim snow pit 15 80 profiles from the gisp2 summit area however show rapid smoothing of the 180 160 signal near the surface beyond about 2 m depth the smoothedi5180 signal is fairly well preserved and can be interpreted in terms of average local weather conditions and climate the longer climate fluctuations also have regional and often global significance in the older part of the record corresponding to marine isotope stages mis 5a to 5d the effect of orbital climate forcing via the 19 and 23 kyr precession cycles and the 41 kyr obliquity cycle is obvious from the end ofmis 5a at about 75 000 years b p till the end of the glacial at the younger dryas preboreal transition at 11 650 years b p the o180 160 record shows frequent rapid switches between intermediate interstadial and low stadial values fourier spectra of the oscillations that are superimposed on the orbitally induced changes contain a strong periodicity at 1 5 kyr a broad peak at 4 0 kyr and additional shorter periods detailed comparison of the gisp2 180 160 record with the vostok antarctica 15d record pacific ocean foraminiferal 180 160 grande pile france tree pollen and insolation indicates that a counterpart to many of the rapid 180 160 fluctuations of gisp2 can be found in the other records and that the gisp2 isotopic changes clearly are the local expression of climate changes of worldwide extent correlation of events on the independent gisp2 and specmap time scales for the interval 10 000 50 000 years b p shows excellent chronometric agreement except possibly for the event labeled 3 1 the glacial to interglacial transition evidently started simultaneously in the arctic and the antarctic but its development and its expression in greenland isotopes was later suppressed by the influence of meltwater especially from the barents sea ice sheet on deep water formation and ocean circulation meltwaters from different ice sheets bordering the north atlantic also influenced ocean circulation during the bolling allerod interstadial complex and the younger dryas and led to a distinct development of european climate and greenland 180 160 values the holocene interval with long term stable mean isotopic values contains several fluauations with periods from years to millennia dominant is a 6 3 year oscillation with amplitude up to 3 to 4 0 periodicities of 11 and 210 years also found in the solar modulated records of the cosmogenic isotopes 1obe and 14c suggest solar processes as the cause of these cycles depression of180 160 values cooling by volcanic eruptions is observed in stacked gisp215 80 records but the effect is small and not likely to trigger major climate changes

xrd based 40ar 39ar age correction for fine grained illite with application to folded carbonates in the monterrey salient northern mexico abstract due to their minute size 40ar 39ar analysis of illite faces significant analytical challenges including mineral characterization and especially effects of grain size and crystallography on 39ar recoil quantifying the effects of 39ar recoil requires the use of sample vacuum encapsulation during irradiation which permits the measurement of the fraction of recoiled 39ar as well as the 39ar and 40ar retained within illite crystals that are released during step heating total gas ages tga are calculated by using both recoiled and retained argon which is functionally equivalent to k ar ages while retention ages ra only involve retained ar in the crystal natural applications have shown that tga fits stratigraphic constraints of geological processes when the average illite crystallite thickness ict is smaller than 10 nm and that ra matches these constraints for icts larger than 50 nm we propose a new age correction method that takes into account the average ict and corresponding recoiled 39ar for a sample with x ray corrected ages xca lying between total gas and retention ages depending on ict this correction is particularly useful in samples containing authigenic illite formed in the anchizone with typical ict values between 10 and 50 nm in three samples containing authigenic illite from cretaceous carbonates in the monterrey salient in northern mexico there is a range in tgas among the different size fractions of 46 49 36 43 and 40 52 ma while ras range from 54 64 47 52 and 53 54 ma respectively xca calculations produce tighter age ranges for these samples of 52 5 56 45 5 48 5 and 49 52 5 ma respectively in an apparent age vs ict or 2m 1illite plot authigenic illite grains show a slope that is in general slightly positive for tga slightly negative for ra but close to zero for xca with thinner crystallites showing more dispersion than thicker ones in order to test if dispersion is due to a different formation history or the result of retention capability degassing spectra were modeled for site xca averages and overall xca average modeling shows that local site age average best match the measured spectra instead of a global average age indicating that illite growth reflects local deformation and is not the result of regional metamorphism modeling also shows that ar degassing spectra are very sensitive to grain size such that age interpretation based on ar plateaus is meaningless for most fine grained clays

general characteristics of temperature variation in china during the last two millennia three alternate china wide temperature composites covering the last 2000 years were established by combining multiple paleoclimate proxy records obtained from ice cores tree rings lake sediments and historical documents five periods of temperature variation can be identified a warm stage in ad 0 240 a cold interval between ad 240 and 800 a return to warm conditions from ad 800 1400 including the medieval warm period between ad 800 1100 the cool little ice age period between 1400 1920 and the present warm stage since 1920 regional temperature variation is found during ad 800 1100 when warm conditions occurred in eastern china and in the northeastern tibetan plateau and in ad 1150 1380 when the southern tibetan plateau experienced a warm interval in contrast evidence for cool conditions during the lia is more consistent among the proxy records the temperature reconstructions for china and the northern hemisphere show good agreement over the past millennium

continuous record of microparticle concentration and size distribution in the central greenland ngrip ice core during the last glacial period 1 a novel laser microparticle detector used in conjunction with continuous sample melting has provided a more than 1500 m long record of particle concentration and size distribution of the ngrip ice core covering continuously the period approximately from 9 5 100 kyr before present measurements were at 1 65 m depth resolution corresponding to approximately 35 200 yr particle concentration increased by a factor of 100 in the last glacial maximum lgm compared to the preboreal and sharp variations of concentration occurred synchronously with rapid changes in the 18o temperature proxy the lognormal mode of the volume distribution shows clear systematic variations with smaller modes during warmer climates and coarser modes during colder periods we find 1 7 m diameter during lgm and 1 3 m during the preboreal on timescales below several 100 years and the particle concentration exhibit a certain degree of independence present especially during warm periods when generally is more variable using highly simplifying considerations for atmospheric transport and deposition of particles we infer that 1 the observed changes of in the ice largely reflect changes in the size of airborne particles above the ice sheet and 2 changes of are indicative of changes in long range atmospheric transport time from the observed size changes we estimate shorter transit times by roughly 25 during lgm compared to the preboreal the associated particle concentration increase from more efficient long range transport is estimated to less than one order of magnitude

evidence for massive discharges of icebergs into the north atlantic ocean during the last glacial period sediments in the north atlantic ocean contain a series of layers that are rich in ice rafted debris and unusually poor in foraminifera1 here we present evidence that the most recent six of these heinrich layers deposited between 14 000 and 70 000 years ago record marked decreases in sea surface temperature and salinity decreases in the flux of planktonic foraminifera to the sediments and short lived massive discharges of icebergs originating in eastern canada the path of the icebergs clearly marked by the presence of ice rafted detrital carbonate can be traced for more than 3 000 km a remarkable distance attesting to extreme cooling of surface waters and enormous amounts of drifting ice the cause of these extreme events is puzzling they may reflect repeated rapid advances of the laurentide ice sheet perhaps associated with reductions in air temperatures yet temperature records from greenland ice cores appear to exhibit only a weak corresponding signal moreover the 5 10 000 yr intervals between the events are inconsistent with milankovitch orbital periodicities raising the question of what the ultimate cause of the postulated cooling may have been

a high resolution stalagmite record of the holocene east asian monsoon from mt shennongjia central china high resolution oxygen isotope 18o profiles of six stalagmites from sanbao cave in hubei province central china established with 1413 oxygen isotope data and 65 230th ages provide a continuous history of east asian summer monsoon easm intensity for the period from 13 0 2 thousand years before present ky bp relative to ad 1950 the 18o record includes four distinct stages in the evolution of the easm 1 an abrupt transition 11 5 ky bp into the holocene 2 a period of gradual increase in monsoon intensity 11 5 9 5 ky bp 3 the maximum humid period 9 5 6 5 ky bp and 4 a period of gradual decline in monsoon intensity 6 5 0 2 ky bp comparison of sanbao with regional records of comparable resolution reveals that the timing of the beginning and end of the holocene optimum as defined by the minimum in 18 o was similar in the indian and east asian monsoon systems this supports the idea that shifts in the monsoon tied to shifts in the mean position of the inter tropical convergen

loess chronology of the middle and upper pleistocene in tadjikistan the loess paleosol sequences of central asia are continuous terrestrial records of the quaternary period and enable detailed comparison with paleoclimatic archives such as marine and ice core records in order to reconstruct regional and global paleoclimatic and paleoecological development during the past 130 000 years thermoluminescence tl and infrared stimulated luminescence irsl dating methods are applied to the extensively studied loess paleosol sequence of the section at darai kalon chashmanigar tadjikistan in order to determine a more accurate chronological framework and climatostratigraphic reconstruction for the last interglacial glacial cycle luminescence dating suggests that the loess above the first pedocomplex from the top pc1 accumulated during the last glacial period a high accumulation rate of up to 1 20 m per 1000 years was determined for the last glacial loess especially for the uppermost 5 8 m pc1 formed during the last interglacial period oxygen isotope stage 5 the loess between pc1 and pc2 is designated to be of penultimate glacial deposition age infrared stimulated luminescence and tl age estimates are in agreement to 80 000 years before present bp indicating a long distance transport of the aeolian dust prior to deposition the upper numerical age limit range is between 300 000 and 450 000 years however reliable dating of the loess older than 130 000 years is not possible due to age scatter between samples and an inadequate increase of paleodose with depth this high resolution dating study underlines the importance of the section at darai kalon and indicates that it is one of the most continuous loess paleosol records of the northern hemisphere the chronological results are particularly important for the reconstruction of the human evolution in central asia suggesting much older age estimates than previously obtained for most of the archeological key sites associated with pc5 and pc4 in tadjikistan

penetration of atlantic westerly winds into central and east asia abstract the geographical position of the convergence zone where the western atlantic climate system meets the asian winter monsoonal system depends on their relative strength these individual strengths are determined by the intensities of the air pressure gradients over the north atlantic and the siberian high pressure cell respectively since the factors that forced those gradients varied throughout glacial interglacial cycles the location of the convergence zone should have moved accordingly both the grain size characteristics of wind blown sediments and climate modelling prove that the atlantic influence extended remarkably far eastward at times the northeastern tibetan plateau was at the cross road of western and monsoonal influences during the last glacial this region was dominated by an atlantic signal with millennial scale climatic oscillations that are similar to the north atlantic marine and greenland ice core records in contrast that same region was only under monsoonal influence during the last interglacial it implies that the atlantic winds penetrated more vigorously eastward in full glacial conditions than in interglacial conditions

holocene climate variability archived in the puruogangri ice cap on the central tibetan plateau two ice cores 118 4 and 214 7 m in length were collected in 2000 from the puruogangri ice cap in the center of the tibetan plateau tp in a joint us chinese collaborative project these cores yield paleoclimatic and environmental records extending through the middle holocene and complement previous ice core histories from the dunde and guliya ice caps in northeast and northwest tibet respectively and dasuopu glacier in the himalaya the high resolution puruogangri climate record since ad 1600 details regional temperature and moisture variability the post 1920 period is characterized by above average annual net balance contemporaneous with the greatest 18 o enrichment of the last 400 years consistent with the isotopically inferred warming observed in other tp ice core records on longer timescales the aerosol history reveals large and abrupt events one of which is dated 4 7 kyr bp and occurs close to the time of a drought that extended throughout the tropics and may have been associated with centuries long weakening of the asian indian african monsoon system the puruogangri climate history combined with the other tp ice core records has the potential to provide valuable information on variations in the strength of the monsoon across the tp during the holocene

u th dating of striated fault planes direct dating of brittle fault activity is of fundamental importance to tectonic reconstructions and paleoseismic studies one way to address this issue is by constraining the timing of fault striations but this requires a better understanding of the striation formation mechanism and associated mineralization we present results from a microstructural geochemical and geochronological study of calcite precipitates associated with striated fault planes from the dead sea fault zone in northern israel we recognize four types of coexisting calcite precipitates including calcite cement in dilation breccia calcite in striated groove morphology calcite gouge associated with hydraulic fracturing and pressure solution and calcite coating of the fault surface carbon oxygen isotopes 87sr 86sr ratios and rare earth element and yttrium rey patterns indicate various precipitation mechanisms associated with formation of syntectonic calcite cement and striations coseismic calcite gouge and interseismic calcite coating precipitates in the fault zone using u th dating of samples from three adjacent fault planes we delineate four welldefined deformation ages in the period from 220 to 60 ka we conclude that these ages constrain the timing of activity along the dead sea fault zone in northern israel and argue that a similar methodological approach could potentially shed light on the timing of deformation in other brittle fault zones

upstream subtropical signals preceding the asian summer monsoon circulation in this study the authors address several issues with respect to the antecedent signals of the large scale asian summer monsoon that were earlier identified by webster and yang in particular they revisit the changes in the subtropical upper tropospheric westerlies preceding the monsoon depict the detailed structure of the monsoon s antecedent signals and investigate the physical processes from the signals to the monsoon they also explore the teleconnection of these signals to various large scale climate phenomena and emphasize the importance of the upstream location of the signals relative to the tibetan plateau and the monsoon before a strong weak asian summer monsoon the 200 mb westerlies over subtropical asia are weak strong during the previous winter and spring a significant feature of these signals is represented by the variability of the middle east jet stream whose changes are linked to the arctic oscillation north atlantic oscillation el

monazite xenotime garnet equilibrium in metapelites and a new monazite garnet thermometer prograde suites of pelitic rocks were examined with electron microprobe introduction and laser ablation inductively coupled plasma mass spectrometry to monazite ce la th po4 plays an important role in determine the systematics of element partitioning between coexisting studies of igneous and metamorphic petrogenesis foremonazite xenotime and garnet monazite grains that grew in most monazite is used to date specific events in a equilibrium with xenotime are enriched in y and dy compared with petrogenetic sequence e g parrish 1990 harrison et al monazite that grew in xenotime absent assemblages y and heavy 1997 hawkins bowring 1999 foster et al 2000 rare earth element contents of monazite coexisting with xenotime monazite may contain a large percentage of the sample increase with rising temperature monazite xenotime y gd and rare earth element ree budget and thus exert an y dy partitioning is systematic within a metamorphic grade and important influence on the evolution of melt composition increases slightly with increasing metamorphic grade suggesting wark miller 1993 bea 1996 the thermobarometric that monazite xenotime pairs approached partitioning equilibrium potential of monazite coexisting with xenotime has been garnet and monazite in both xenotime bearing and xenotime absent recognized leading to calibration of monazite geoassemblages show a strong r 0 94 systematic relationship thermometers gratz heinrich 1997 1998 heinrich between inverse temperature and ln keq for the net transfer equiet al 1997 andrehs heinrich 1998 in addition the librium yag oh ap 25 4 qtz 5 4 grs 5 4 an recognition that nearly all lead in monazite is radiogenic 3ypo4 mnz 1 2h2o suggesting that garnet and monazite parrish 1990 montel et al 1994 has led to development crystallized in compositional equilibrium the following temand application of electron microprobe monazite dating perature keq relationship for the equilibrium above has been derived techniques suzuki adachi 1991 montel et al 1996 williams et al 1999 t c 1 45p bars 447772 32052 567 40 rln keq 273 15 full realization of monazite as a thermochronometer requires detailed understanding of the specific reactions responsible for its formation previous studies of monazite with a precision of some 30 c for temperature estimates our petrogenesis have focused on monazite compositional observations suggest that major and accessory phases interact in a zonation zhu o nions 1999a 1999b monazite coupled fashion during metamorphism and also approach a state growth kinetics ayers et al 1999 behavior of monazite of compositional equilibrium as reactions proceed during hydrothermal alteration poitrasson et al 1996 crowley ghent 1999 and melting events watt 1995 or to a limited extent the influence of major phase mineral assemblage in monazite reactivity zhu

influence of pre tectonic carbonate facies architecture on deformation patterns of syntectonic turbidites an example from the central mexican fold thrust belt abstract the mexican fold thrust belt in central mexico excellently exposes relatively well preserved syntectonic deposits that overlay rocks with lateral lithostratigraphic changes across the belt we consider the deformational effects of these changes by investigating the geometry kinematics and strain distribution within syntectonic turbidites which are deposited on top of albian cenomanian shallow and deep water carbonate layers field observations and detailed structural analysis at different stratigraphic and structural levels of the late cretaceous syntectonic formation are compared with the deformation as a function of lithological and structural variations in the underlying carbonate units to better understand the effect of these lithostratigraphic variations on deformation kinematics strain distribution and propagation of deformation from our kinematic analyses we conclude that the syntectonic strata are pervasively affected by folding in all areas and that deformation partitioning localized shear zones at the boundaries of this unit particularly along the contact with massive carbonates at the boundaries with massive platformal carbonates the turbidites are strongly deformed by isoclinal folding with a pervasive sub horizontal axial plane cleavage and 70 60 shortening in contrast contacts with thinly bedded carbonate layers basinal facies do not show strain localization and have horizontal shortening of 50 40 that is accommodated by buckle folds with a less pervasive steeply dipping cleavage the mechanical properties variations in the underlying pre tectonic units as a function of changes in lithostratigraphy fundamentally control the deformation in the overlying syntectonic strata which is an effect that could be expected to occur in any deformed sedimentary sequence with such variations

the role of the indian summer monsoon and the mid latitude westerlies in himalayan glaciation review and speculative discussion new dates for late quaternary glaciations in the himalayas show that during the last glacial cycle glaciations were not synchronous throughout the region rather in some areas glaciers reached their maxima at the global glacial maximum of c 18 20 ka bp whereas in others glaciers were most extensive at c 60 30 ka bp comparison of these data with palaeoclimatic records from adjacent regions suggest that on millennial timescales himalayan glacier fluctuations are controlled by variations in both the south asian monsoon and the mid latitude westerlies

the variation of summer monsoon precipitation in central china since the last deglaciation abstract two stalagmites c996 1 and c996 2 collected from the jiuxian cave in the shaanxi province in central china have been studied with u series dating and stable isotope analysis thirty eight 230 th dating results showed that the stalagmite c996 1 was continuously deposited through the last 8 5 ka bp thousand years before present present 1950 ad and c996 2 was deposited through the last 19 ka bp excluding two growth hiatuses between 8 3 and 5 7 ka bp and 15 4 and 11 9 ka bp with a relatively stable boundary condition we interpret the 18 o of speleothem calcite as most indicative of the amount of summer monsoon precipitation although temperature and other factors might have some minor impact the 18 o records show notable changes within the last glacial maximum lgm resembling other east asian monsoon records such as those from the hulu and sanbao caves suggesting that significant monsoonal climate changes occurred in eastern asia as far north as the qinling mountains during the lgm interval a comparison of our records to precisely dated contemporaneous speleothem records from other caves shows that the increasing trend of 18 o during the holocene commenced as early as 7 5 ka bp in the low latitude monsoonal area i e the hoti cave while at higher latitudes this shift occurred later such as 7 0 ka bp in the dongge cave 5 3 ka bp in the heshang cave 4 7 ka bp in the sanbao cave and 4 5 ka bp in the jiuxian cave these results imply an asynchronous change of the summer monsoon precipitation occurred in east asia during the holocene the asynchrony may be related to the responses of a coupled tropical and subtropical monsoon system to changes of the insolation and the differences in thermal forcing which result from the complex geographical configuration the variation of sea surface temperature sst in the western tropical pacific may also have important impacts on the summer monsoon precipitation changes in central and northern china because it affects the northwestern pacific subtropical high a monsoon front regulator more robust tests are needed to confirm this phenomenon and to evaluate the contribution of different factors in detail

paleotemperature variability in central china during the last 13 ka recorded by a novel microbial lipid proxy in the dajiuhu peat deposit the asian summer monsoon is a very important climatic component affecting the land ecosystem on the eastern asian continent here we assess microbe derived lipid biomarker evidence from a well date

towards an orbital time scale for chinese loess deposits abstract in this study we analyzed the grain size of the baoji loess soil sequence at 10 cm intervals results show that grain size variations are very sensitive to loess soil alternations with loess units being much coarser than soils such a change in loess soil grains is interpreted as the result of the glacial interglacial cyclic variations in the intensity of the winter monsoon winds out of siberia the grain size record is thus employed as a proxy indicator of the winter monsoon circulation and tuned to the orbital records calculated recently by berger and loutre 1991 under the control of major magnetic reversals the tuning is independent of any correlation with 18o signals in the deep sea sediments the resulting grain size time scale is tightly constrained as suggested by the following facts 1 the filtered obliquity and precession components from the grain size data on the orbital time scale closely match the theoretical orbital records 2 ages of the major magnetic reversals estimated from the grain size time scale are in good agreement with the k ar dated ages 3 there is close coherence between the baoji grain size time series and the orbital variations at the orbital frequency bands over the entire 0 2 5 ma period and 4 the grain size record on the orbital time scale shows a close similarity to the orbitally tuned dsdp site 607 and odp site 677 18o records examination of time dependent characteristics of the grain size record suggests that there are two major shifts of dominant periodicities in the long term monsoonal cycles one occurring at about 0 8 ma bp and the other around 1 7 ma bp

late cenozoic eolian deposition in the north pacific asian drying tibetan uplift and cooling of the northern hemisphere a newly constructed record of eolian dust accumulation from the central north pacific shows that dust deposition increased by an order of magnitude quite rapidly at 3 6 ma we associate this sudden drying with the uplift of at least the northern portion of the tibetan plateau shutting off the indian ocean moisture source to central and western china this ten fold increase in atmospheric dust loading appears to be associated with the 1 m y long shift toward heavy 18o values that occurred at 3 6 2 6 ma the dust grain size record of wind intensity begins its late cenozoic coarsening a million years before the drying event at 4 5 ma the northern hemisphere cooling that results in intensification of the subpolar westerly winds may have as its ultimate cause the drawdown of atmospheric co2 in the latest miocene and the early pliocene closing of the panamanian seaway

the nature origin and accumulation of loess abstract loess can be defined simply as a terrestrial clastic sediment composed predominantly of silt size particles which is formed essentially by the accumulation of wind blown dust there are three fundamental requirements for its formation 1 a sustained source of dust 2 adequate wind energy to transport the dust and 3 a suitable accumulation site most loess has been modified to some degree by local reworking bioturbation and syn depositional weathering but a process of loessification is not necessary for a dust deposit to qualify as loess the terms primary loess and secondary loess have previously been used to described wind deposited loess and redeposited loess respectively but it is more accurate to describe material reworked and redeposited by non aeolian processes as loess derived colluvium or loess derived alluvium during the quaternary loess formed in three main situations 1 mid continental shield areas beyond the limits of ice sheets periglacial loess 2 on the margins of high mountain ranges perimontane loess and 3 on the semi arid margins of some lowland deserts peridesert loess peridesert loess is relatively poorly developed partly due to the limited efficiency of silt generating mechanisms in low land deserts compared with glaciation but also important is the tendency in arid areas for dust to be dispersed over a wide area and to be rapidly reworked after deposition particularly in areas which experience frequent climatic changes the remarkably thick loess of china and central asia results from an unusual combination of conditions which has persisted for much of the last 2 3 million years namely rapid uplift of the tibetan plateau and surrounding mountain ranges high rates of sediment production and supply to adjacent basins a strong northwesterly and westerly wind regime and the existence of effective dust traps downwind of the source regions

evolution of the irminger and east icelandic current systems through the holocene revealed by diatom based sea surface temperature reconstructions abstract sediment core md99 2269 from the northern shelf of iceland has been studied to assess the stability of the east icelandic irminger current system during the holocene the 25 4 m long holocene section was studied with a 40 years average resolution the chronology is based on the combination of 24 14c ams dates and two tephra layers diatoms are utilized to quantify the development and variability of the august sea surface temperature sst for the last 11 5 cal kyr bp three different transfer function methods have been used to reconstruct august sst at the site weighted average partial least squares wa pls maximum likelihood ml and imbrie and kipp i k the combined use of the three methods allows the august sst reconstruction with a higher confidence level than with using only one statistical technique these three reconstructions generate very similar august sst trends through the holocene the onset of the holocene climate optimum is characterized at the site by a rapid august sst increase at 10 4 cal kyr bp of almost 4 c the holocene climate optimum is recorded between 10 4 and 4 7 cal kyr bp the august ssts were around 2 c warmer during the major part of the holocene compared with the august ssts for the later half of the holocene combining the diatom record with the benthic foraminifera records from the same core enables us to reconstruct the evolution of both surface and bottom water masses during the holocene this reconstruction shows dominance of the arctic waters throughout the water column at the onset of the holocene and subsequent increase of the influence of the atlantic water especially during the holocene climate optimum this strong dominance of atlantic water tends to decrease between 4 7 and 2 2 cal kyr bp especially in the upper part of the water column since 2 2 cal kyr bp the trend is reversed suggesting an increased influence of atlantic water at least in the upper water column

chinese loess record of monsoon climate during the last glacial interglacial cycle the thick loess paleosol succession of central china contains a detailed record of changes in east asian monsoon climate since the late miocene epoch the alternating loess paleosol stratigraphy closely resembles the marine oxygen isotope record implying that episodic dust deposition and pedogenesis are in phase with global ice volume fluctuations and controlled by variations in solar radiation reaching the land surface deposits equivalent to marine isotope stages mis 5 through 1 have been dated by 14c 10be luminescence and magnetic susceptibility and grain size models malan loess mis 4 2 decreases in thickness southeastward from 30 m in the western loess plateau to 5 m east of xi an downwind asian dust is found in japan the north pacific ocean and the greenland ice sheet where it has a chemical signature that points to a primary source in western china during glacial times the mean dust flux in the central loess plateau reached 0 35 mm year whereas in interglacial times it fell to 0 1 mm year times of high dust influx and reduced soil development coincided with strengthened winter monsoon conditions which are inferred from variations in loess grain size times of decreased dust accumulation and strong pedogenesis marked by high values of magnetic susceptibility represent times of strengthened summer monsoon conditions high frequency fluctuations in dust influx during deposition of the malan loess include peaks that likely correlate with north atlantic heinrich events the younger dryas oscillation is recorded in chinese eolian and organic deposits by a shift from cool humid late glacial conditions to cold and dry conditions followed by a return to milder humid climate at the beginning of the holocene warm moist climate associated with a strong summer monsoon characterized the first half of the holocene epoch when a widespread paleosol complex developed on the loess plateau increased dust deposition during the middle to late holocene marked a shift to cooler drier conditions

structural analysis clay mineralogy and k ar dating of fault gouges from centovalli line central alps for reconstruction of their recent activity abstract between the cities of domodossola and locarno the complex centovalli line tectonic zone of the central alps outlines deformation phases over a long period of time probably starting 30 ma ago and under variable p t conditions the last deformation phases developed gouge bearing faults with a general e w trend that crosscuts the roots of the alpine canavese zone and the finero ultramafic body kinematic indicators show that the general motion was mainly dextral associated with back thrusting towards the s the on the basis of the k ar ages and with a thermal gradient of 25 30 c km the studied fault zones were located at a depth of 4 7 km if they were active until now as observed in field the exhumation was approximately 2 5 3 0 km for the last 12 ma with a mean velocity of 0 4 mm y comparison with available models on the recent alpine evolution shows that the tectonic activity in the area relates to a continuum of the back thrusting movements of the canavese line and or to several late extensional phases of the rhone simplon line the centovalli val vigezzo zone therefore represents a major tectonic zone of the central western alps resulting from different interacting tectonic events

loess stratigraphy of central asia palaeoclimatic and palaeoenvironmental aspects abstract the loess palaeosol succession of central asia is comparable with that of the loess plateau in north china palaeomagnetic investigations and palaeontological studies in south tadjikistan suggest a date of 2 2 5 ma for the oldest loess indicating that dust storms became frequent in the region since 2 2 5 ma bp under the prevalently arid and semi arid environments of central asia aeolian processes had a gradually increasing influence on subaerial sedimentation during the pleistocene however atmospheric aeolian processes in central asia have mainly developed in accordance with pleistocene climatic cyclicity without extremely high intensification during the late pleistocene as implied by the previous tl dating results the identification of loess and palaeosol horizons with respective glaciations and interglacials is sometimes disputable nevertheless the available data in spite of limited evidence characterise well developed palaeosols of the middle and late pleistocene as warm and wet intervals associated with interglacials palynological studies of loess sections show that loess and palaeosol horizons have palynological spectra that are sometimes difficult to interpret interregional loess palaeosol correlation with glacial interglacial events as well as with oxygen isotope records should be supplied by multidisciplinary investigations

late pleistocene and holocene aeolian dust deposition in north china and the northwest pacific ocean abstract rates of dust deposition in the north pacific and the central loess plateau of china show a poor correlation during the last 30 000 yr although in both cases the dust was derived from deserts in northern china loess accumulation rates were high at the time of the last glacial maximum while dust flux to the north pacific was low at this time maximum dust flux to the north pacific is recorded in the mid holocene but holocene rates of loess accumulation have been low these differences are shown to reflect the different nature of the wind conditions responsible for dust transport to the loess plateau and the north pacific dust transport responsible for formation of the loess occurred mainly in the lower 1 5 km of the atmosphere and was accomplished by cold low level northwesterly winds associated with cold waves emanating from the mongolian anticyclone at present such conditions occur quite frequently in winter but during the coldest phases of the pleistocene they probably also occurred in the spring and summer long range dust transport from northern china to the north pacific requires that the dust is lifted to high levels above 3 km where it can be incorporated into the strong mid latitude westerlies strong vertical motions of the atmosphere occur most frequently in the spring when the mongolian anticyclone begins to weaken and frontal depressions move across the deserts of northern china such frontal depressions were probably more frequent during the climatic optimum of the mid holocene and during previous interglacials changes in continental aridity have probably played a minor role in controlling the magnitude of the dust flux to the north pacific

mid to late holocene climate change an overview the last 6000 years are of particular interest to the understanding of the earth system because the boundary conditions of the climate system did not change dramatically in comparison to larger glacial interglacial changes and because abundant detailed regional palaeoclimatic proxy records cover this period we use selected proxy based reconstructions of different climate variables together with state of the art time series of natural forcings orbital variations solar activity variations large tropical volcanic eruptions land cover and greenhouse gases underpinned by results from general circulation models gcms and earth system models of intermediate complexity emics to establish a comprehensive explanatory framework for climate changes from the mid holocene mh to pre industrial time the redistribution of solar energy due to orbital forcing on a millennial timescale was the cause of a progressive southward shift of the northern hemisphere nh summer position of the intertropical convergence zone itcz this was accompanied by a pronounced weakening of the monsoon systems in africa and asia and increasing dryness and desertification on both continents the associated summertime cooling of the nh combined with changing temperature gradients in the world oceans likely led to an increasing amplitude of the el nin o southern oscillation enso and possibly increasingly negative north atlantic oscillation nao indices up to the beginning of the last millennium on decadal to multi century timescales a worldwide coincidence between solar irradiance minima tropical volcanic eruptions and decadal to multi century scale cooling events was not found however reconstructions show that widespread decadal to multi century scale cooling events accompanied by advances of mountain glaciers occurred in the nh e g in scandinavia and the european alps this occurred namely during the little ice age lia between ad w1350 and 1850 when the lower summer insolation in the nh due to orbital forcing coincided with solar activity minima and several strong tropical volcanic eruptions the role of orbital forcing in the nh cooling the southward itcz shift and the desertifi cation of the sahara are supported by numerous model simulations other simulations have suggested that the fingerprint of solar activity variations should be strongest in the tropics but there is also evidence that changes in the ocean heat transport took place during the lia at high northern latitudes with possible additional implications for climates of the southern hemisphere sh

fold dating a new ar ar illite dating application to constrain the age of deformation in shallow crustal rocks we propose a deformation dating method that combines xrd quantification and ar chronology of submicroscopic illite to determine the absolute ages of folds that contain clay bearing layers two folds in the frontal segment of the mexican fold thrust belt mftb which was deformed from late cretaceous to eocene are used to illustrate the method and its future potential variations in mineral composition illite polytype crystallite size cs and ar total gas ages were analyzed in the limbs and hinge of two mesoscopic folds this analysis examines potential effects of strain variation on illitization and the ar isotopic system along folded layers versus possible regional thermal overprints the ar total gas ages for 9 samples in fold 1 vary between 48 4 and 43 9 ma the of 2m1 detrital illite vs ar total gas ages tightly constrains the age of folding at 43 5 0 3 ma nine ages from three samples in fold 2 range from 76 2 to 62 7 ma which results in a folding age of 63 9 2 2 ma both ages are in excellent agreement with more broadly constrained stratigraphic timing the method offers a novel approach to radiometric dating of clay bearing folds formed at very low grade metamorphic conditions and has the potential to constrain dates and rates of regional and local deformation along and across foreland orogenic belts

a 300 kyr record of aridity and wind strength in southwestern africa inferences from grain size distributions of sediments on walvis ridge se atlantic abstract the terrigenous fraction of sediments recovered from walvis ridge se atlantic ocean reveals a history of southwestern african climate of the last 300 kyr end member modelling of a data set of grain size distributions n 428 results in three end members the two coarsest end members are interpreted as eolian dust the third end member as hemipelagic mud the ratio of the two eolian end members reflects the eolian grain size and is attributed to the intensity of the se trade winds trade winds were intensified during glacials compared to interglacials changes in the ratio of the two eolian end members over the hemipelagic one are interpreted as variations in southwestern african aridity late quaternary southwestern african climate was relatively arid during the interglacial stages and relatively humid during the glacial stages owing to meridional shifts in the atmospheric circulation system during glacials the polar front shifted equatorward resulting in a northward displacement of the zone of westerlies causing increased rainfall in southwestern africa the equatorward shift of the polar front is coupled with an increase of the meridional pressure gradient leading to enhanced atmospheric circulation and increased trade wind intensity

interpreting temporal patterns in the late quaternary dust flux from asia to the north pacific abstract a comparative study of the literature on the late quaternary accumulation of aeolian dust in china japan and the pacific ocean shows three different temporal patterns of dust signals the main dust sources in asia the deserts and desert margins contain large amounts of wind suspensible allochthonous material commonly an increase in dust accumulation is taken as an indicator of increased aridity in the interior of asia differences among the signals of asian desert dust accumulation in different depositional areas indicate that this interpretation requires critical evaluation the dust supply of the desert regions was maximal during the pleistocene glacial maxima the widespread assumption that these stages were the most arid periods is not necessarily valid additional factors likely to lead to temporal and regional differences in dust accumulation are 1 eustatic sea level changes associated with changes in the amount of exposed shelf material and changes in the extent of sea ice affecting atmospheric changes 2 the frequency of meteorological situations allowing long range dust transport 3 the strength of the dust transporting winds 4 changes in the wet deposition rate and 5 the presence of a dust trapping vegetation cover temporal variations in dustiness in different depositional areas are the result of specific combinations of these factors simplified assumptions concerning the reasons for dust variability may lead to incomplete or even erroneous palaeoecological conclusions

microprobe monazite geochronology understanding geologic processes by integrating composition and chronology abstractmonazite is a light rare earth element lree bearing phosphate mineral that is present in a wide variety of rock types has an extremely variable composition reflecting host rock conditions and is a robust geochronometer that can preserve crystallization ages through a long history of geological events monazite crystals typically contain distinct compositional domains that represent successive generations of monazite which in turn can provide a detailed record of the geologic history of its host rocks the electron microprobe can be used to characterize the geometry of compositional domains analyze the composition of each domain and when carefully configured determine the u th total pb age for domains as small as 5 m in width these data allow the monazite to be linked with and place timing constraints on silicate processes in the host rocks current applications span a broad range of geologic processes in igneous metamorphic hydrothermal and sedimentary rocks

calibration of modelled mixing patterns in loess grain size distributions an example from the north eastern margin of the tibetan plateau china genetically meaningful decomposition unmixing of sediment grain size distributions is accomplished with the end member modelling algorithm unmixing of the loess grain size distributions of a late quaternary loess palaeosol succession from the north eastern tibetan plateau indicates that the loess is a mixture of three end members representing very fine sandy coarse silty and medium silty loess the unmixing approach potentially enables the unravelling of sediment fluxes from multiple dust sources opening the way to significant advances in palaeoclimatic reconstructions from loess grain size distribution data however as laser diffraction size analysis is a volume based technique the proportional contributions of the modelled end members might deviate significantly from weight proportions hence calibration of the end member volume proportions to weight proportions must be established before one can calculate the source specific dust fluxes this paper reports the findings of a sediment mixing experiment which enables calibration of the modelled mixing patterns established for the tibetan loess palaeosol succession 2005 international association of sedimentologists

isotopic dating of the migration of a low grade metamorphic front during orogenesis the southern margin of the pilbara craton in northwestern australia underwent regional heating folding and thrusting as well as extensive fluid flow during collision in the paleoproterozoic however the precise timing of this event is uncertain previous geochronologic studies of archean basement rocks have yielded a wide range of younger radiometric dates from ca 2 4 ga to ca 2 0 ga interpreted to record multiple hydrothermal alteration events in situ u pb geochronology of authigenic monazite and xenotime in very low grade archean metasedimentary rocks from across the craton suggests that the pilbara was affected by at least two cryptic thermotectonic events the first between ca 2430 ma and ca 2400 ma and the second between ca 2215 ma and ca 2145 ma the older event is restricted to three localities in the west and its cause is unknown the younger event affected most of the craton 100 000 km 2 spanning a 70 m y period from ca 2215 ma nearest the collisional margin in the south to ca 2145 ma toward the craton interior in the north the widespread geographic and stratigraphic distribution of ca 2 2 ga phosphates suggests that fluid flow was pervasive this event was probably driven by the northward advancing ophthalmian fold and thrust belt that developed during protracted collision the associated low grade metamorphic front migrated over 350 km at an average rate of 5 0 mm yr placing important constraints on the rate and duration of deformation and metamorphism in orogenic settings

climatic and local effects on stalagmite δ13c values at lianhua cave china abstract carbon isotopes in speleothems may serve as indicators of vegetative change climatic conditions and karst processes in many recent studies of chinese stalagmites however carbon isotopes have often been neglected or underutilized in interpreting paleoenvironments here we present a continuous decadal scale 13 c record 819 measurements of the mid to late holocene from a precisely dated 10 230 th dates aragonite stalagmite from lianhua cave hunan province china compared to coeval stalagmites from other chinese caves the average 13 c value 3 6 of stalagmite a1 is higher by 2 7 variations in the 13 c values 0 1 to 6 0 reflect changes in both vegetative productivity and inorganic processes which respond to climatic processes the 13 c record of stalagmite a1 can be subdivided into three intervals 1 warm humid stage 6 6 to 3 8 ka 2 transitional stage 3 8 to 1 6 ka and 3 cool arid stage 1 6 ka to present comparisons with other stalagmite and paleoclimatic records demonstrate that these intervals are generally consistent with changes in regional vegetation and climatic conditions

newly formed illite preserves fluid sources during folding of shale and limestone rocks an example from the mexican fold thrust belt abstract we combine structural fluid inclusion microthermometry illite crystallinity x ray diffraction xrd and o and h stable isotope analyses of authigenic illite to determine the source of local fluids interacting with rock during folding in anchizonal shales of the mexican fold thrust belt mftb a well exposed train of mesoscopic asymmetrical folds in a sequence of cretaceous limestones interbedded with shale was targeted for this study we test the hypothesis that syn folding vein minerals and clay minerals were formed from the same fluids by comparing the 2 h composition of inclusion fluids in calcite and quartz from veins and from illite concentrates from sheared shale layers and the sources of that fluid five clay size fractions 2 m were separated from eight shale samples in the 40 clay grain size fractions analyzed illite calcite kaolinite smectite chlorite and minor quartz were identified by xrd analysis most samples show different proportions of various clay minerals except for the finer fractions in two of the samples bl3 and bl4 were illite is the only clay phase present the discriminating potential of 18 o values of clay is generally masked by the abundance of calcite in all samples in contrast samples containing chlorite and smectite show very low values in 2 h 75 9 to 53 9 while samples containing illite and kaolinite or pure illite show relatively high 2 h values 33 1 to 50 1 the latter fall within the 2 h range 39 to 49 determined in fluid inclusions of syntectonic veins indicating isotopic equilibrium between water veins fillings and illitic clay during deformation according to fractionation factors at these temperatures 220 250 c the 2 h values and fluid inclusion salinities in the sampled rocks indicate that water active during folding was partly marine and partly meteoric and that the amount of such pore water represented a small fraction of the deformed rock volume our study demonstrates that the h isotopic composition of anchizonal illitic clays commonly present in exhumed fold thrust belts can be used to determine the source s of fluids that were active during deformation

periodicities of palaeoclimatic variations recorded by loess paleosol sequences in china abstract palaeoclimatic periodicity recorded by chinese loess paleosol sequence has been investigated for a number of years however conclusions from previous investigations are still controversial and interpretation of cycle evolution is quite equivocal in this study two typical loess paleosol sequences 148 and 191 m in thickness respectively in the central chinese loess plateau are sampled 3872 samples total and measured for grain size distribution and magnetic susceptibility in order to reconstruct the palaeoclimatic changes over the past three million years on the basis of a new sensitive proxy indicator of palaeoclimate and a newly developed independent time scale not orbitally tuned two time series of asian dust storm variations which are highly related to the palaeoclimate system changes are obtained wavelet and spectrum analyses indicate that there are approximately 400 200 100 66 57 41 31 27 and 22 kyr cycles in these typical loess paleosol records some orbital driven cycles are weak and are not well presented in the new time series while some non orbital cycles are found since the eccentricity frequencies of the solar irradiance of approximately 400 and 100 kyr are preserved in these palaeoclimatic sequences the lack of relatively short time orbital cycles of 41 kyr obliquity and 22 kyr precession cycles in part of the two time series may be explained by the relatively low time resolution of the loess paleosol deposits through an astronomical estimate the obliquity and precession cycles should leave stronger footprints on records of palaeoclimatic variations at the middle latitudes of the northern hemisphere the presence of non orbital cycles may be explained by unstable dust deposition processes and pedogenic processes in the paleosol units which could misrepresent or obliterate the imprint of the solar irradiance frequency this conclusion may indicate that one should be cautious when investigating specific palaeoclimatic changes e g at sub orbital time scales recorded in loess deposits especially in the paleosol units

absolute ages of multiple generations of brittle structures by u pb dating of calcite direct dating of brittle structures is challenging especially absolute dating of diagenesis followed by a series of superimposed brittle deformation events we report 22 calcite u pb ages from tec

the history and variability of the east asian paleomonsoon climate abstract changes in the east asian paleomonsoon reflect interactions between the global atmosphere ocean land and ice systems and are also an expression of their combined effect within the boundary conditions imposed by the east asian continent and solar radiation the history of the east asian monsoon is an alternation between dominance by the dry cold winter and warm humid summer monsoons high resolution eolian sequences preserved in the chinese loess plateau reveal that the east asian monsoon may have commenced at least 7 2 ma ago they also provide evidence indicating that the pulsed uplift of the tibetan plateau at about 3 4 and 7 2 ma may have played an important role in inducing climate change the palaeoclimatic records of the last glacial cycle show high frequency variability on time scales of 1000 year or even shorter and instability of the east asian paleomonsoon system the high frequency variability could be due to a non linear response to orbital forcing or a result of the coupling processes between different components of the global system cold air activity in northern high latitudes the trans equatorial air streams from the southern hemisphere and possibly enso may have played an important role in east asian monsoon variability the synchroneity of all the palaeoclimatic events along the polar equator polar pep transect is still an open question correlation of limited palaeoclimatic records for the last 30 kyr obtained from east asia and australia suggests that the trans equatorial air streams driven by the monsoon and trade winds may have had an influence on opposite hemispheres

holocene environmental and climatic changes inferred from wulungu lake in northern xinjiang china abstract sedimentological geochemical and palynological data from wulungu lake in northern xinjiang china are used to reconstruct environmental and climate changes since 9550 cal yr bp high abundance of sparganium and poaceae low md median diameter and 13 c organic values indicate aridity between 9550 and 6730 cal yr bp high md and 13 c organic values and the prevalence of desert steppe and steppe vegetation between 4200 and 560 cal yr bp indicate that effective moisture increased after 6730 cal yr bp peaking at 4200 and 560 cal yr bp low md values a negative excursion of 13 c org and the transition from steppe to desert vegetation since 560 cal yr bp reflect a decrease in effective moisture during the latest holocene late holocene human activities were indicated by sharp increase in the abundance of pediastrum then variations in carbonate contents indicate that temperature was generally high between 9550 and 7740 cal yr bp low between 7740 and 6730 cal yr bp intermediate between 6730 and 560 cal yr bp and low during the last 560 yr regional comparison indicates that the asian monsoon did not extend to wulungu lake and westerlies were the main factor in determining the moisture availability during the holocene

bedding parallel veins and their relationship to folding abstract laminated bedding parallel veins hosted in turbiditic sandstone shale sequences from central victoria australia consist of stacked millimetre thick sub parallel sheets of quartz separated by micaceous layers wall rock slivers and pressure solution seams they have very high length to thickness ratios are laterally continuous over tens to hundreds of metres and have relatively uniform thickness compared to other vein types they are intimately associated with and folded by chevron folds and the quartz grain shape elongation lineation is commonly orthogonal to mesoscopic and macroscopic fold hinge lines the bedding parallel veins have two morphological forms type i are thin commonly 5 10 cm laminated veins which have complex microstructures dominated by phyllosilicate inclusion surfaces related to oblique opening along bedding with varying rates of deposition opening relative to shear displacement slip along the bedding surfaces more common are type ii thicker generally

late quaternary dust flow on the chinese loess plateau abstract the dust flux of over 25 g cm2 103yr was reached in the central part of the chinese loess plateau during the last glacial maximum this is more than three times higher than during the last interglacial and early glacial time the grain size of the pleniglacial dust reached a peak shortly after 20 000 years ago and testifies to the occurrence of strong winds and frequent dust storms

high resolution multi proxy climate records from chinese loess evidence for rapid climatic changes over the last 75 kyr the loess paleosol sequence in loess layer l1 malan loess is investigated in three regions of the western chinese loess plateau nine pedogenic layers are found in l1 and three proxy climate indices magnetic susceptibility ms grain size gs and caco3 content are measured at intervals of 0 2 kyr in order to recover records of monsoon climate variations time series of ms gs and caco3 content document the high resolution history of summer and winter monsoon climate variations over the last 75 kyr the records show a high degree of similarity to the warm interstadials recorded in ice cores from greenland and the antarctic and with heinrich events in the north atlantic during the last glacial cycle bond cycles are also recorded by the chinese loess records overall our results indicate that numerous rapid changes in climate occurred in china during the last glacial cycle but that the range of climate variations was smaller than recorded in greenland

comparison of laser grain size analysis with pipette and sieve analysis a solution for the underestimation of the clay fraction classically the grain size of soil and sediment samples is determined by the sieve method for the coarse fractions and by the pipette method based on the stokes sedimentation rates for the fine fractions results from the two methods are compared with results from laser diffraction size analysis which is based on the forward scattering of monochromatic coherent light from a point of view of laboratory efficiency the laser sizing technique is far superior accuracy and reproducibility are shown by measurements on certified materials it appears that laser grain size measurements of certified materials correspond very well with the certificated measurements tests were also done on a set of randomly selected sediments of fluvial aeolian and lacustrine origin except for the 2 m clay fraction there is a coarsening of the mean diameter of one to two size classes 0 25 caused by the non sphericity of the particles the platy form of the clay particles induces considerable differences eight size classes between pipette and laser measurements the 2 m grain size defined by the pipette method corresponds with a grain size of 8 m defined by the laser particle sizer for the studied sediments using a higher grain size level for the clay fraction when laser analysis is applied enables workers in the geological and environmental field to compare classical pipette analysis with a laser sizing technique

susceptibility measurements optical and x ray analysis to explain the origin of archaeological magnetic anomalies in tavoliere lowland southern italy since 2002 a non invasive investigation integrating aerial photography and high resolution magnetometry has been carried out for reconstructing extensive ancient settlements in tavoliere lowland southern italy relevant magnetic anomalies were detected in all the surveyed sites allowing a precise mapping of the buried structures over more than 150 ha next to this research susceptibility measurements pxrd xrf and optical analysis were also performed in order to explain the origin of the notable magnetization contrast between the anthropogenic structures and the embedding materials generating the measured signals this last study was accomplished in 2006 in monte s vincenzo site a vast neolithic village where the remotely sensed data were also used to guide some direct inspection trial archaeological excavations brought to light parts of c shaped compounds providing complete information on the geometry and location of the sources of magnetic signals profiting by the archaeological feedback the susceptibility contrast between the soil filling the ditches and the calcareous substratum was assessed in situ a synthetic model based on this information was created and compared with the experimental data the infilling material was also sampled for laboratory analysis the presence of several magnetic minerals pyroxenes monometric magnetite haematite was ascertained furthermore optical analyses showed different types of volcanic and igneous products such as pumices melanite garnets and lava fragments geomorphological and archaeometric evidence allowed us to relate these materials to activity of the mt vesuvius volcano eventually their possible spatial distribution was inferred from recent studies on ash transportation and deposition during explosive activity

correlation between climate events in the north atlantic and china during the last glaciation episodes of massive iceberg release heinrich events 1 3 into the north atlantic ocean during the last glaciation were associated with recurring episodes of unusually cold north atlantic surface water bond cycles 4 and cold air temperatures over greenland dansgaard oeschger events 5 6 four of the youngest of these cold events have also been reported in climate records from sites outside the north atlantic region7 but until now the entire suite has been identified only in north atlantic marine sediments greenland ice core records and tentatively in french lake sediments8 here we examine grain size data from chinese loess and intercalated accretionary palaeosols of last glacial age for evidence of similar climate signals remote from the north atlantic region we see grain size maxima with ages that match those of the last six heinrich events which we interpret as an indication of the changing strength of the east asian winter monsoon which largely controls the transport and deposition of central asian aeolian dust thus it seems that these heinrich events have left their signature in the chinese loess record this is consistent with simulations of the glacial climate9 which imply that the climates of the north atlantic and china were linked by the effect of westerly winds

fracture controlled paleohydrology in a map scale detachment fold insights from the analysis of fluid inclusions in calcite and quartz veins abstract this study uses fluid inclusions in quartz and calcite veins to characterize the fracture controlled paleohydrology of a map scale evaporite cored detachment fold in the sierra madre oriental of northeastern mexico field observations indicate that the veins are tectonic in origin and that they formed in a general sequence that corresponds to four broad stages of progressive folding we collected samples from each vein stage in various structural and stratigraphic positions across the fold after determining the mineral paragenesis and origin of inclusions in each sample we used standard microthermometric techniques to measure the homogenization temperatures t h salinities and eutectic temperatures of the available two and three phase aqueous inclusions neither t h salinity nor eutectic temperature varied systematically with inclusion origin or mineral type the data are also not significantly correlated with structural position or vein type but are strongly partitioned by stratigraphy suggesting that the area was a vertically stratified hydrologic system consisting of three regional paleohydrostratigraphic units an upper unit comprised the indidura formation through difunta group and is characterized by t h near 150 c and salinity t h near 150 c and salinities near 12 or 22 wt nacl equivalent the lower unit comprised the zuloaga and la casita formations and is characterized by an average t h near 225 c and salinities in three groups near 12 22 or 36 wt nacl equivalent the preservation of multiple distinct fluid types in many veins suggests that fracture development during folding and uplift created a second paleohydrologic system that overprinted the vertically stratified system fracture controlled fluid migration in this second system occurred in periodic repeated and spatially variable pulses

synchroneity of tropical and high latitude atlantic temperatures over the last glacial termination a high resolution western tropical atlantic sea surface temperature sst record from the cariaco basin on the northern venezuelan shelf based on mg ca values in surface dwelling planktonic foraminifera reveals that changes in sst over the last glacial termination are synchronous within 30 to 90 years with the greenland ice sheet project 2 air temperature proxy record and atmospheric methane record the most prominent deglacial event in the cariaco record occurred during the younger dryas time interval when ssts dropped by 3 to 4 c a rapid southward shift in the atmospheric intertropical convergence zone could account for the synchroneity of tropical temperature atmospheric methane and high latitude changes during the younger dryas

structural traverse across the sierra madre oriental fold thrust belt in east central mexico the exposed structural geometry of the sierra madre oriental foreland fold thrust belt is quantified for an 130 km long strip along the moctezuma river 21 n lat east central mexico the strip extends from the belt s leading edge in the east to its most internal continuous outcrops in the west where the cordilleran structures disappear beneath cenozoic volcanic rocks the style of deformation is controlled mainly by the geometry and lithology of two major cretaceous carbonate banks el doctor and valles san luis potosi the long dimensions of which parallel the cordilleran structural trend the exposed shortening is concentrated on the platform margins 5 km on the eastern edge of the el doctor bank and 10 to 12 km on either edge of the valles san luis potosi platform and is characterized by thrust and fold nappes the thrust faults cut across the platform margin carbonates on 20 inclined tectonic ramps that were partly steepened by imbrication or by subsequent folding but pass in the overlying mechanically weak rocks nearly parallel to bedding the interiors of the platforms appear relatively undeformed whereas the regions between the two platforms zimapan basin and between the eastern edge of the valles san luis potosi platform and the foreland are composed of flexural slip folds resulting from decoupling along several incompetent layers the exposed bulk shortening measures 41 4 km or 25 for the entire traverse retrodeformable sections of the subsurface structure down to basement result in a bulk shortening of 90 1 km or 40 the subsurface deformation model for the western part of the traverse is thin skinned and has geometry similar to that on the surface the model is very speculative in the eastern part where the areal shortening calculated for thin skinned models is much larger than is the exposed linear shortening balance was attained by inferring a blind thrust on an upper detachment in the late cretaceous which has a shortening of 20 to 30 km it could also be attained however by intrabasement decoupling in a depth of 10 to 20 km deformation is brittle in the eastern part of the belt east of the valles san luis potosi platform whereas igneous intrusion controlled higher ductility characterizes the western part of the foreland fold thrust belt

teleconnections between the subtropical monsoons and high latitude climates during the last deglaciation the major deglacial intensification of the southwest monsoon occurred at 11 450 150 calendar years before present synchronous with a major climate transition as recorded in greenland ice an earlier event of monsoon intensification at 16 000 150 calendar years before present occurred at the end of heinrich layer 1 in the atlantic and parallels the initial rise in global atmospheric methane concentrations and the first abrupt climate changes in the antarctic thus the evolution of the monsoonal and high latitude climates show teleconnections but hemispheric asymmetries superimposed on abrupt events the monsoonal climate shows high frequency variability of 1785 1450 and 1150 year oscillations and abrupt climate change seems to occur when at least two of these oscillations are in phase

extending the radiocarbon calibration beyond 26 000 years before present using fossil corals fossil coral is an excellent archive to extend the radiocarbon 14c calibration beyond tree ring records however published coral data older than 26 000 years before present are too disparate for practical calibration we propose an explanation for these discrepancies trace amounts of secondary calcite and organic matter in fossil corals shift the 14c ages toward younger ages in a series of acid leaching experiments to simulate the standard cleaning procedure prior to 14c analysis we measure up to a 300 enrichment of diagenetic calcite in corals due to the solubility differences between calcite and aragonite in model calculations we show the 14c age offsets produced by acid leaching could be hundreds to thousands of years when typical amounts of calcite are present in samples we demonstrate the necessity and our ability to detect 0 2 calcite in aragonite by x ray diffraction and apply 0 2 calcite as our a priori criterion for our coral samples the estimated age offsets of samples with 0 2 calcite fall within the reported analytical uncertainty of 14c dating in addition we present 14c results from an extended hydrogen peroxide h2o2 pretreatment for coral samples to remove organic matter our data show that treated samples yield consistent or older 14c dates compared to non treated samples these rigorous but necessary screening and cleaning techniques provide precise reproducible and accurate radiocarbon calibration data

proxy based temperature reconstruction in china for the holocene abstract the temperature variation in china is closely related to the dynamics of global climate change in order to reveal its possible connections with global climate during the holocene we present a nationwide temperature reconstruction in china for the past 12 000 years based on multiple proxies with three statistical methods including empirical orthogonal function composite plus scale and simple arithmetic average our reconstruction shows that the late 20th century temperature in china is the highest at least over the past millennium although the low temperature in the period of 10 000 12 000 yr bp was mainly related to the north atlantic cool conditions the reconstructed china s temperature followed solar forcing variations more closely than climatic influence from the north atlantic the asian monsoon was also closely connected to temperature change in china over the holocene

the association of folds and veins in shear zones abstract paired hook shaped asymmetric folds with shared limbs cut by axial planar veins dikes or fractures are common in glaciers and rocks the sense of offset across the vein or fracture is characteristically opposite to that expected from the sense of fold asymmetry the kinematics of development of the folds and the relationship of the folds to the fractures or veins can be understood by considering the nature of glacial flow and by utilizing simple clay experiments in zones of simple shear dilational fractures may form at about 45 to the shear zone boundaries the perturbation of strain around such a fracture during its development and subsequent rotation and closure under continued deformation causes layers or pre existing foliation cut by the fracture to become folded thus folding is a consequence of the fracturing and not vice versa the precise shape of the fold depends on the nature of the perturbation and particularly whether or not the fracture remains for a time open or fluid filled and thus has walls unable to sustain a shear stress during vein rotation paired hook folds provide evidence for non coaxial strain and are good sense of shear indicators however not all folds with veins parallel to their axial surfaces form in the way described in this paper in some cases vein emplacement occurs late during fold development or post dates folding in these cases offsets along the veins are consistent with fold asymmetry

u pb zircon and monazite geochronology of variscan magmatism related to syn convergence extension in central northern portugal abstract the viseu area is located in the central iberian zone of the iberian variscan belt and hosts numerous post thickening collision related granitoids intruded into upper and middle crustal levels the present paper reports high precision u pb zircon and monazite ages for four plutons of the viseu area the syn kinematic granitoids of maceira 314 5 ma casal vasco 311 1 ma and junqueira 307 8 0 7 ma and the late kinematic biotite monzogranites of cota 306 9 ma this points to a synchronous emplacement of the different syn kinematic plutons shortly followed by the intrusion of the late kinematic granites and shows that the upper carboniferous plutonism occurred within a short time span of ca 10 million years the ascent of granite magmas took place after an extensional tectonic event d 2 and is coeval with dextral and sinistral crustal scale transcurrent shearing d 3 field and petrographical evidence suggest a narrow time span between peak t metamorphic conditions and the intrusion of granitic melts which implies very fast uplift rates accommodated through active tectonic exhumation magma compositions evolve through time reflecting an increasing involvement of mid crustal sources and the underplating effect of an upwelling asthenospheric mantle at the base of a thinning and stretching continental crust

asynchronous holocene optimum of the east asian monsoon abstract the spatial and temporal distribution of summer monsoon precipitation or effective moisture during the holocene has been reconstructed on the basis of geological data including lake levels pollen profiles and loess paleosol records in addition the summer july precipitation increment effective precipitation and monsoon strength index have been obtained from numerical modeling experiments both geological data and numerical modeling indicate that the holocene optimum as defined by peak east asian summer monsoon precipitation was asynchronous in central and eastern china reaching a maximum at different times in different regions e g ca 10 000 8000 yr ago in northeastern china 10 000 7000 yr ago in north central and northern east central china ca 7000 5000 yr ago in the middle and lower reaches of the yangtze river and ca 3000 yr ago in southern china in southwestern china the maximum appeared ca 11 000 yr ago but probably was related to the maximum landward extension of the indian summer monsoon the regional shift in the maximum precipitation belt from northwest to southeast over the past 10 000 yr is interpreted as a response to changing seasonality related to orbital forcing of the climate the southeastward shift of the east asian summer monsoon maximum is consistent with the progressive weakening of the summer monsoon as the summer solar radiation anomaly decreased progressively through the holocene and the east asian monsoon index declined while the early maximum in southwestern china matches the maximum of the indian monsoon index

a textural and geochemical guide to the identification of hydrothermal monazite criteria for selection of samples for dating epigenetic hydrothermal ore deposits hydrothermal monazite is one of the most reliable geochronometers for u pb dating of epigenetic or hydrothermal ore deposits because its blocking temperature at ca 700 c is higher than that of most metamorphic conditions although igneous monazite is routinely used for age dating igneous rocks only a few ore deposits have been dated by hydrothermal monazite this is due to the similar morphology of hydrothermal and igneous monazite which prevents the reliable distinction of hydrothermal monazite in particular we demonstrate that hydrothermal monazite can be distinguished from igneous monazite by its unique geochemical signature its local abundance and to common association with hydrothermal mineral assemblages our data and the data of others reported in the literature suggest that the low tho 2 content of hydrothermal monazite 0 1 wt is distinct from that of igneous monazite 3 to 5 wt and may be used to determine their genesis

microprobe monazite geochronology putting absolute time into microstructural analysis abstract high resolution compositional mapping and dating of monazite on the electron microprobe is a powerful addition to microstructural analysis and an increasingly important tool for tectonic analysis microprobe monazite geochronology can be an efficient reconnaissance tool for evaluating metamorphic and deformational age domains but more importantly its in situ nature and high spatial resolution offer an entirely new level of structurally and texturally specific geochronologic data that can be used to put absolute time constraints on p t d paths constrain the rates of metamorphic and deformational processes and provide new links between metamorphism and deformation microprobe geochronology is particularly applicable to three persistent microstructural microtextural problem areas 1 constraining the chronology of metamorphic assemblages 2 constraining the timing of deformational fabrics and 3 interpreting other geochronological results although some monazite generations can be directly tied to metamorphism or deformation at present the most common constraints rely on monazite inclusion relations in porphyroblasts that in turn can be tied to the deformation and or metamorphic history microprobe mapping and dating allow geochronology to be incorporated into the routine microstructural analytical process resulting in a new level of integration of time t into p t d histories

low temperature alteration of monazite fluid mediated coupled dissolution precipitation irradiation damage and disturbance of the u pb and th pb chronometers abstract low temperature alteration of monazite is documented in three centimeter sized monazite crystals from norway arendal madagascar ambato and sri lanka the three crystals have different chemical compositions especially in their u th y and pb contents and have 208 pb 232 th ages ranging from 491 to 900 ma optical microscope om scanning electron microscope sem and transmission electron microscope tem images and electron microprobe analyses epma show that all three preserve a similar patchy texture this texture is interpreted as resulting from an alteration reaction in which unaltered monazite mnz1 reacts to form a secondary th u y depleted high th u monazite mnz2 accompanied by thorite huttonite thsio 4 thorianite tho 2 and xenotime ypo 4 the proportions of which are dependent upon the initial composition of the monazite mnz1 images reveal variably intense internal fracturing with cracks filled with th rich fe rich phases monazite xenotime thermometry demonstrates that the pristine monazites mnz1 interacted with a low temperature fluid the alteration process is interpreted to follow a mechanism of fluid mediated coupled dissolution precipitation chemical dating with the electron microprobe shows no th u pb age differences between primary and secondary monazites except in the case of the ambato monazite in which altered domains yield older 750 ma apparent ages than the pristine mnz1 domains u pb and th pb isotope dating using la icp ms yields ages consistent with electron probe dates for pristine mnz1 zones however disturbance of these systems in the altered monazite domains leads to variable age results for these depending on sample in the case of sri lanka and arendal only 208 pb 232 th dates provide a reasonable estimate of the age of alteration which are constrained to be 450 and 864 ma respectively u pb systems are disturbed due to common pb contamination up to 40 and u fractionation relative to th during alteration responsible for depletion of u in altered monazites and increase of th u in contrast for the ambato monazite both the u pb and th pb systems were affected and yield inconsistent older dates for altered zones this is attributed to significant common pb contamination up to 80 which affects all pb isotopes and explains why electron probe ages are erroneous th u silicate contamination during measurement resulting from the presence of a numerous nano phases and nano fractures filled with th u silicates that are visible only under tem also contributes to the anomalously old ages for these disturbed mnz2 domains these results demonstrate the important role of radiation damage effects in particular swelling induced fracturing and the essential role of porosity and cracks which allow fluid charged with elements migration through monazite during low temperature alteration

evidence from wavelet analysis for a mid holocene transition in global climate forcing a strong mid holocene transition has been identified by wavelet analyses in several sea ice cover records from the circum antarctic area ice core records taylor dome byrd and tropical marine records the results are compared with those previously published in a synthesis of north atlantic records and with 4 new records from the norwegian and icelandic seas and from a coastal site in ireland these new records confirm the previous pattern for the north atlantic area extend this pattern nearly to the arctic circle and include a continental record we further tested the possibility of extending this scheme using continental records from south america the holocene pattern proposed here confirms the importance of external forcing during the early holocene solar activity 1000 years cyclicity and 2500 years during the entire holocene even if the signal is disturbed by meltwater fluxes the second part of the holocene is then marked by the gradual appearance of internal forcing thermohaline circulation around 1500 years associated with a stabilisation of the signal coupling between ocean and atmosphere seems to play a fundamental role in the observed frequencies which vary accordingly in the atlantic circum antarctic and pacific areas the north atlantic area seems to be the instigator of thermohaline circulation as shown by its sensitivity to meltwater discharges during the early holocene even though each sector is independent with regards to its frequency content around 1600 years for atlantic area around 1250 years for antarctica the holocene methane pattern still under debate ruddiman w f 2003a orbital insolation ice volume and greenhouse gases quaternary science review 22 1597 1629 ruddiman w f 2003b the anthropogenic greenhouse era began thousands of years ago climatic change 61 261 293 could be explained by a more efficient thermohaline circulation around the mid holocene with an anthropogenic effect initiated at not vert similar2500 bp as shown by the inter hemispheric gradient

in situ th pb dating of monazite in fibrous veins direct dating of veins and deformation in the shallow upper crust of the mexican orogen abstract few methods exist for directly dating orogenic events in the upper crust here we report in situ dates from 10 m diameter monazite grown in quartz calcite fibrous veins which precipitated at very low grade metamorphic conditions about 250 c in volcaniclastic and calcareous rocks of the early cretaceous trancas fm in the zimapan basin central mexico our integrated study includes regional and local structural and kinematic analysis of vein and folds detailed textural and mineralogical characterization of vein bearing minerals and texturally controlled th pb geochronologic analysis of monazite by la mc icpms we find that monazite in the veins preferentially crystallized at the interface between vein forming calcite and quartz fibers as well as at the vein host rock interface monazite ages range from 154 to 68 ma with the youngest sub population yielding a weighted mean age of 76 8 0 8 ma coincident with the age of basin wide folding as earlier constrained by ar ar illite dating the oldest monazite ages coincide with the timing of deposition of the volcaniclastic host rock given that veins are ubiquitous in shallow crustal rocks this approach to dating of veins with enclosed monazite has great potential to improve the constraints on temporal resolution of fluid rock interaction during of deformation

a high resolution absolute dated late pleistocene monsoon record from hulu cave china oxygen isotope records of five stalagmites from hulu cave near nanjing bear a remarkable resemblance to oxygen isotope records from greenland ice cores suggesting that east asian monsoon intensity changed in concert with greenland temperature between 11 000 and 75 000 years before the present yr b p between 11 000 and 30 000 yr b p the timing of changes in the monsoon as established with 230th dates generally agrees with the timing of temperature changes from the greenland ice sheet project two gisp2 core which supports gisp2 s chronology in this interval our record links north atlantic climate with the meridional transport of heat and moisture from the warmest part of the ocean where the summer east asian monsoon originates

continental scale temperature variability during the past two millennia past global climate changes had strong regional expression to elucidate their spatio temporal pattern we reconstructed past temperatures for seven continental scale regions during the past one to two millennia the most coherent feature in nearly all of the regional temperature reconstructions is a long term cooling trend which ended late in the nineteenth century at multi decadal to centennial scales temperature variability shows distinctly different regional patterns with more similarity within each hemisphere than between them there were no globally synchronous multi decadal warm or cold intervals that define a worldwide medieval warm period or little ice age but all reconstructions show generally cold conditions between ad 1580 and 1880 punctuated in some regions by warm decades during the eighteenth century the transition to these colder conditions occurred earlier in the arctic europe and asia than in north america or the southern hemisphere regions recent warming reversed the long term cooling during the period ad 1971 2000 the area weighted average reconstructed temperature was higher than any other time in nearly 1 400 years

constraints on fluid evolution during metamorphism from u th pb systematics in alpine hydrothermal monazite abstract the timing and duration of hydrothermal activity during orogenesis are difficult to constrain because such systems are open and multistage using mm sized monazite crystals from two alpine clefts from the central alps switzerland we demonstrate that combined u th pb isotopic systematics of hydrothermal monazite can constrain both timing and fluid evolution during crystallization our data highlight four major characteristics of the cleft monazites i extreme th u ratios ii significant common pb in the u system up to 39 206 pb iii excess 206 pb up to 54 and iv precise and reliable th pb ages comparison of our results with literature data indicates that th u in monazite is a remarkable discriminant of geological conditions capable of distinguishing metasedimentary magmatic and hydrothermal origin hydrothermal monazite crystals are characterized by th u ratios up to 629 among the highest values ever reported extreme th u ratios in monazite enhance incorporation of 230 th a short lived intermediate product in the 238 u 206 pb decay chain generating 206 pb excess which if not accounted for results in 206 pb 238 u ages that are too old for example in the samples investigated here by as much as 300 for the two zoned monazite crystals studied in detail 208 pb 232 th ages are reliable for the different compositional domains visible in back scattered electron bse images 232 th 208 pb ages for the older domains 15 2 0 3 ma and 14 1 0 3 ma respectively are consistent with the structural relationships of the hydrothermal veins indicating early retrograde genesis the youngest rim age at 13 5 0 4 ma for the blauberg crystal marks termination of monazite precipitation the resolvable age difference is interpreted to reflect pulsed monazite growth over an extended period of hydrothermal activity in both crystals the outer rims have the highest 206 pb excess confirming a two stage crystallization two scenarios are envisaged to account for the 206 pb excess evolution in the first increasing 206 pb excess is caused by a modification of the th u fractionation between monazite and fluid due to an evolution of the fluid towards more oxidizing conditions that favor partitioning of hexavalent u into the fluid alternatively it is possible that 230 th increased with time in the fluid in this second case monazite growth would have occurred in a closed system from a fluid that was initially in disequilibrium with the 238 u 206 pb decay chain and progressively equilibrated t

apatite monazite and xenotime in metamorphic rocks this chapter focuses on phosphates that are significant in metamorphic rocks a quick survey of phosphate mineral descriptions at a commercial mineral web site revealed over 500 phosphate mineral names remarkably only three are common in metamorphic rocks apatite monazite and xenotime and this chapter is restricted to discussion of these minerals apatite monazite and to a lesser extent xenotime have enjoyed intensive study during the previous half century following world war ii considerable study was made of minerals that contain fissionable materials and the sometimes large concentrations of u and th in monazite culminated in a number of seminal papers on the occurrence of that mineral e g overstreet 1967 during the 1970s and early 1980s the study of apatite and monazite turned towards their role as a sink for rees and other trace elements in rocks e g watson 1980 watson and capobianco 1981 throughout this period monazite and to some extent xenotime enjoyed attention as a geochronometer e g parrish 1990 and through today this attention has continued to grow accessory minerals such as monazite xenotime and apatite have come to the forefront of research in metamorphic petrology in recent years for two reasons first it has recently been recognized that trace elements in metamorphic rocks and especially trace element zoning in garnet and other major phases contain considerable detailed information about the reaction history a rock has experienced coupled with the fact that diffusion of many trace elements in metamorphic minerals is in general considerably slower than diffusion of major elements in those same minerals the possibility has recently emerged of recovering details of metamorphic petrogenesis that were previously unattainable inasmuch as accessory minerals play a dominant role in the mass budget of many trace elements attention has naturally turned to their paragenesis it has also recently been discovered that

remote sensing techniques for reconstructing a vast neolithic settlement in southern italy abstract the combined application of remote sensing techniques is often the most effective way for deepening the knowledge on very large archaeological sites several hectares in particular geophysics and aerial photography could yield very detailed information on buried structures not only outlining their location but also in many cases defining their planimetry moreover the accurate geocoding of different data sets and the use of gis for their integration allow to extract the most comprehensive information from a combined study in this paper the results of a highly integrated non intrusive investigation are presented the study site is located in the tavoliere southern italy and is part of a very important and rich archaeological landscape the remains recovered on the ground by the archaeologists indicate the presence of different phases of frequentation mainly datable from the neolithic to the medieval age the main purpose of the combined study was to locate and identify the buried features with a specific interest for the prehistoric time the final high resolution and geocoded images allowed for a general recognition of the layered structures and a more complete reconstruction of the neolithic village