the permo triassic transition in spitsbergen δ13corg chemostratigraphy fe and s geochemistry facies fauna and trace fossils new 13 c org analyses of two boundary sections between the late permian kapp starostin formation and the early triassic vardebukta formation of western spitsbergen confirm field evidence that their contact is a conformable one thus contrary to previous reports some spitsbergen sections contain a complete record of the environmental and faunal changes during the crisis interval of the end permian mass extinction no environmental deterioration is recorded in the late permian until near the end of the terminal changxingian stage whereupon the abundant siliceous sponge fauna of the kapp starostin formation disappears along with the deep burrowing fauna responsible for the zoophycus trace fossil a low diversity dysaerobic trace fossil assemblage is briefly developed before a transition to finely laminated pyritic facies immediately beneath the permo triassic boundary analysis of the s c ratios from the laminated strata suggests that free h 2 s was present in the water column euxinic conditions even in relatively nearshore settings subject to storm sandstone deposition the mass extinction crisis in spitsbergen is therefore coincident with the extensive development of oxygen poor conditions in the water column and compares closely both in timing and nature with the crisis seen in lower latitude tethyan settings however the subsequent aftermath and recovery in the boreal sections of spitsbergen was more rapid than in tethys thus a shoreface sandstone body within the dienerian stage contains an appreciable diversity of fauna by the standards of the early triassic including bryozoans calcareous algae and deep infaunal bivalves that suggests the marine ecosystem recovery began earliest in higher palaeolatitudes

middle late permian mass extinction on land the end permian mass extinction has been envisaged as the nadir of biodiversity decline due to increasing volcanic gas emissions over some 9 million years we propose a different tempo and mechanism of extinction because we recognize two separate but geologically abrupt mass extinctions on land one terminating the middle permian guadalupian at 260 4 ma and a later one ending the permian period at 251 ma our evidence comes from new paleobotanical paleopedological and carbon isotopic studies of portal mountain antarctica and comparable studies in the karoo basin south africa extinctions have long been apparent among marine invertebrates at both the end of the guadalupian and end of the permian which were also times of warm wet greenhouse climatic transients marked soil erosion transition from high to low sinuosity and braided streams soil stagnation in wetlands and profound negative carbon isotope anomalies both mass extinctions may have resulted from catastrophic methane outbursts to the atmosphere from coal intruded by feeder dikes to flood basalts such as the end guadalupian emeishan basalt and end permian siberian traps

the occurrence of giant bivalve alatoconchidae from the yabeina zone upper guadalupian permian in european tethys abstract the permian gigantic bivalve family alatoconchidae forms a member of the tropical shallow marine fauna intimately associated with the tethyan warm water adapted verbeekinidae fusulines such as neoschwagerina and yabeina the velebit mountains in central croatia is one of the nine areas in the world that yielded alatoconchidae as first reported early in the 1970 s in addition to the neoschwagerina zone wordian middle guadalupian originally described we newly found alatoconchidae from the yabeina zone capitanian upper guadalupian from the brusane area in the central velebit mountains alatoconchidae occur in three stratigraphic levels of the velebit formation composed of black fusuline algal wackestone packstone with yabeina although fragmented the alatoconchidae shell reach sizes over 40 cm long and possess unique morphology with a lateral flange plus a prominent prismatic external layer in the double layered shell structure our results confirm for the first time in europe and thus in the western tethyan domain that the stratigraphic range of the gigantic bivalve family extends up to the capitanian as well as in the superocean panthalassa as no occurrence has been reported from the overlying lopingian upper permian alatoconchidae likely became extinct globally at the end of the guadalupian i e through the guadalupian lopingian boundary mass extinction

biotic responses to volatile volcanism and environmental stresses over the guadalupian lopingian permian transition biotic extinction during the guadalupian lopingian g l transition is actively debated with its timing validity and causality all questioned here we show based on detailed sedimentary paleoecologic and geochemical analyses of the penglaitan section in south china that this intra permian biotic crisis began with the demise of a metazoan reef system and extinction of corals and alatoconchid bivalves in the late guadalupian a second crisis among nektonic organisms occurred around the g l boundary mercury concentration total organic carbon hg toc ratios show two anomalies the first hg toc peak broadly coincides with the reef collapse and a positive shift in 199hg values during a lowstand interval which was followed by microbial proliferation a larger hg toc peak is found just above the g l boundary and speculatively represents a main eruption episode of the emeishan large igneous province elip this volatile volcanism coincided with nektonic extinction a negative 13ccarb excursion anoxia and sea level rise the temporal coincidence of these phenomena supports a cause andeffect relationship and indicates that the eruption of the elip likely triggered the g l crisis

morphological disparity of ammonoids and the mark of permian mass extinctions the taxonomic diversity of ammonoids in terms of the number of taxa preserved provides an incomplete picture of the extinction pattern during the permian because of a strongly biased fossil record the analysis of morphological disparity the variety of shell shapes is a powerful complementary tool for testing hypotheses about the selectivity of extinction and permits the recognition of three distinct patterns first a trend of decreasing disparity ranging for about 30 million years led to a minimum disparity immediately before the permian triassic boundary second the strongly selective capitanian crisis fits a model of background extinction driven by standard environmental changes third the end permian mass extinction operated as a random nonselective sorting of morphologies which is consistent with a catastrophic cause

variable density flow and solute transport simulation of regional aquifers containing a narrow freshwater saltwater transition zone variable density flow and solute transport simulation of aquifer systems containing narrow transition zones between freshwater and saltwater requires particular attention to certain aspects of the numerical method and its application to be successful typically only cases involving wide transition zones have been simulated with variable density transport models possibly because of inaccuracies in the modeling approaches used the major components of a successful approach are threefold first functionally consistent approximation of terms involved in fluid velocity calculations is necessary in the case of galerkin finite element methodology a significant modification is required to the standard approach in order to achieve consistency second the simulator must be verified in a particular series of tests the usual tests using henry s problem for verification of density dependent transport simulators are inadequate to check for consistency of the velocity approximations and for the accuracy of simulating flow driven by bouyancy forces third adequately fine spatial discretization is required when applying the simulator for spatial stability of the numerical transport solution and to allow accurate representation of narrow transition zones and the effects of low transverse dispersivity the effectiveness of this approach is demonstrated through simulation of the flow of fresh and saline groundwater in the layered basalt aquifer of southern oahu hawaii the transition zone in this regional flow system is narrow except near the discharge area where it is broadly dispersed simulation of this common situation with an inconsistent approximation gives grossly incorrect results while simulation with a consistent model provides a robust tool for analysis of system hydrology

palaeoenvironmental change during the end guadalupian permian mass extinction in sichuan china abstract the end guadalupian mass extinction has been investigated in sichuan province sw china in the south of the province the platform carbonates of the maokou formation are overlain by the emeishan flood basalts a possible factor in the extinction event and in the north of the province the formation is succeeded by shallow marine carbonates of the wuchiaping formation late permian the extinction event is primarily recorded by the loss of fusulinaceans and possibly by species level turnover amongst calcareous algae the high diversity middle permian microfossil assemblages are last seen beneath a surface recording widespread emergence and karstification in northern sichuan emergence occurred early in the capitanian stage and the succeeding strata record restricted hypersaline deposition that preceded the deposition of a thick ash horizon the wangpo bed these mid capitanian arid conditions are replaced by humid conditions towards the end of the stage as indicated by the development of a widespread coal seam in southern sichuan only a thin development of this humid coaly facies is seen developed atop the maokou karstic surface and below the oldest flood basalt the guadalupian interval saw the development of large c isotope excursions in the carbonate record these include a positive then negative swing late in the capitanian and a newly discovered negative spike superimposed on an early capitanian heavy interval this spike may be a global phenomenon but the magnitude 8 may have been exaggerated by an increased contribution from light respired c derived from soils during relative sea level fall a plethora of environmental factors approximately coincide with the extinction event including regression acidic volcanism and flood basalt volcanism making it difficult to unravel the relative significance of each

an upper permian permineralized plant assemblage in volcaniclastic tuff from the xuanwei formation guizhou province southern china and its palaeofloristic significance a new permineralized fossil plant assemblage is described from volcaniclastic tuff collected in the upper permian wuchiapigian to changhsingian xuanwei formation at shanjiaoshu mine guizhou province china the assemblage is fragmentary but contains a small sphenopsid strobilus a partial strobilus of a lepidodendralean lycopsid pinnae of the filicalean fern anachoropteris and a filicalean non laminate fertile pinna rachis the marattialean ferns eoangiopteris scolecopteris and psaronius hooked stems of probable gigantopterid affinity and two kinds of cardiocarpalean ovules this represents the first indisputable evidence of anachoropteris from the permian of china and contrasts with previous evidence from europe and north america that indicates this genus became extinct during earliest permian times the assemblage highlights the persistence of plants from wetland communities and mire ecosystems into the upper permian of southern china and adds further support to the presence of the ameriosinian phytogeographical realm this represents the first record of a plant assemblage preserved in volcaniclastic sediments from the upper permian of southern china and in combination with other recently discovered plant assemblages in similar deposits in southern china suggests volcanism to be an important factor in facilitating permineralized plant preservation in this realm although the source of the volcanism that produced the tuff is unknown its age and location are consistent with the emishan large igneous province lip of southwest china

constraining the cause of the end guadalupian extinction with coupled records of carbon and calcium isotopes abstract a negative c 13 excursion in carbonate sediments near the guadalupian lopingian middle late permian boundary has been interpreted to have resulted from a large carbon cycle disturbance during the end guadalupian extinction event ca 260 ma however the carbon isotope data alone are insufficient to uniquely determine the type and magnitude of perturbation to the global carbon cycle calcium isotopes can be used to further constrain the cause of a carbon isotope excursion because the carbon and calcium cycles are coupled via caco3 burial in this study we present coupled carbon and calcium isotope records from three guadalupian lopingian g l sections in china penglaitan and chaotian and turkey koserelik tepe the c 13 and ca 44 40 records differ among our studied sections and do not co vary in the same manner no section shows c 13 and ca 44 40 changes consistent with massive rapid volcanic co2 emissions or methane clathrate destabilization additionally many sections with large 3 changes in c 13 exhibit o 18 evidence for diagenetic alteration only one section exhibits a large excursion in the ca 44 40 of limestone but the absence of a similar excursion in the ca 44 40 of conodont apatite suggests that the limestone excursion reflects a mineralogical control rather than a perturbation to the global calcium cycle hence we interpret the large isotopic changes observed in some sections to have resulted from local burial conditions or diagenetic effects rather than from a large carbon and calcium cycle disturbance perturbations to the global carbon and calcium cycles across the g l transition were much less intense than the disturbances that occurred across the subsequent permian triassic boundary this finding is consistent with the much smaller magnitude of the end guadalupian extinction relative to the end permian

mixed carbonate siliciclastic microfacies from permian deposits of western gondwana evidence of gradual marine to continental transition or episodes of marine transgression abstract at the end of the paleozoic several intracratonic basins developed in gondwana including the parana basin in western gondwana permian sedimentary units include the passa dois group which encompasses four formations the irati serra alta teresina and rio do rasto and represents a transition from marine to continental depositional environments its strata correlate extensively from argentina to south africa and the irati and teresina formations in particular present mixed carbonate siliciclastic successions this interval has been speculated to have formed under several different paleoenvironmental scenarios however permian gondwana basin microfacies with no open sea influence have rarely been studied in addition in these basins there is a scarcity of micropaleontological studies and geochronological calibration besides an absence of marine index fossils in view of this a comprehensive microfacies study for the unit is developed with a large and representative surface and subsurface sample analysis of the passa dois group divided into three large geographic domains north central and south of the parana basin brazil thin sections distributed among the four units were analyzed with an emphasis on carbonate layers where the microfossils have a better chance to be recognized the data were interpreted within a revised biochronostratigraphic framework and integrated with bivalves macroflora palynology conchostracans and vertebrates biozones microfacies analysis resulted in the recognition of 13 microfacies four siliciclastic eight carbonate and one siliceous chert we observed a predominance of fine siliciclastic microfacies rich in organic matter in the southern domain rudaceous carbonate microfacies in the central domain with diverse allochemicals and the greater diversity of bioclasts and an increase on siliciclastic sediments influx in the northern domain of the basin where only the irati and teresina formations occur a shortage of microfossils was observed in the south domain where the carbonate microfacies are less varied than those to the north in the central domain coarse grained carbonates are present bivalves ostracods and sponge spicules are the main bioclasts on rudstones and grainstones from the irati and teresina formations and have been interpreted as allochthonous to parautochthonous the association of detrital and authigenic glauconite to bioaccumulations of sponge spicules is interpreted as episodes of marine transgression

radiation and extinction patterns in permian floras from north china as indicators for environmental and climate change abstract permian continental sequences from north china contain previously unrecognized episodes of plant radiation and elevated extinction the earliest extinction in the lower shihhotse formation roadian guadalupian records a 45 floral species loss and is tentatively correlated with global extinctions amongst dinocephalian reptiles two younger extinctions are dated by correlating the illawara reversal and palaeomagnetic polarity sequences from shanxi province against global palaeomagnetic history missing data from the shanxi sequence are evaluated using a novel approach estimating likely maximum and minimum sequence changes that provide age estimates for post illawara events in north china the second extinction in the middle upper shihhotse formation is more significant and is dated to the mid capitanian with a loss of 56 of plant species coinciding with two phases of volcanism of the emeishan large igneous province in south china previously linked to the mid capitanian marine mass extinction the youngest extinction in the upper upper shihhotse formation late capitanian to mid wuchapingian is catastrophic and represents the end of range in the sequence changes in sedimentary facies suggest it to be related to global climatic warming and drying other viable causal mechanisms for the extinction episodes include plate motion and collision global climate change volcanism and biological competition

facies analysis and sea level change at the guadalupian lopingian global stratotype laibin south china and its bearing on the end guadalupian mass extinction abstract the guadalupian lopingian boundary stratotype at penglaitan and the nearby tieqiao section near laibin south china record a series of major environmental changes within the jiangnan basin during a mid permian biotic crisis the sequence stratigraphic petrographic and palaeontological record of these sections has been studied and the associated strontium isotopic fluctuations have been assayed mass extinction of fusulinid foraminifers is most clearly associated in time with onset of volcanism and a relative sea level fall that led to the establishment of mid ramp conditions laibin limestone in settings that were previously dominated by radiolarian mudstones the regression also coincides with a low point of 87 sr 86 sr ratios the lowstand deposits contain mafic scoriaceous grains that record pyroclastic volcanism probably centred in the emeishan flood basalt province 800 km to the west of laibin thus unusually violent eruptions associated with flood basalts in this province may have contributed to the environmental stresses responsible for the extinction event subsequent environmental changes included transgression spread of dysoxic waters indicated by populations of small pyrite framboids and a major negative c isotope excursion all these phenomena have been previously related to the end guadalupian extinction but they in fact post date the crisis because a post extinction fauna of foraminifers is encountered at this time

high resolution dynamics of early jurassic marine extinctions the case of pliensbachian toarcian ammonites cephalopoda abstract the pliensbachian toarcian interval was marked by major environmental disturbances and by a second order mass extinction here we reappraise the taxonomic spatiotemporal and selective dynamics of extinctions over the whole interval by analysing a high resolution dataset of 772 ammonite species from nw tethyan and arctic domains on average 40 65 of ammonite species disappeared during each subchronozone but higher extinction pulses reaching 70 90 prevailed from the margaritatus to the dispansum chronozone the main extinctions corresponding to the gibbosus pliensbachian toarcian boundary semicelatum bifrons variabilis and dispansum events differed in their dynamics suggesting episodes of ecological stress related to climate change regression disturbance in the carbon cycle or anoxia the multi pulsed volcanic activity in the karoo ferrar province could well have triggered these ecological changes in addition ammonites experienced a morphological bottleneck during the gibbosus event 1 ma before the early toarcian diversity collapse typically drops in richness were related both to high extinctions and to declines in origination rates this feature could result from strengthened ecological stresses related to the temporal overlap of environmental disturbances after the early toarcian crisis the recovery of ammonites was rapid 2 ma and probably influenced by a coeval marine transgression supplementary material figures showing a comparison of extinction and origination patterns based on different datasets and variations of the morphospace occupation are available at http www geolsoc org uk sup18381

paleomagnetic constraints on the geodynamic history of the major blocks of china from the permian to the present paleomagnetic study of china and its environs has been the center of a major international effort for the last 10 years in this paper we critically review all available paleomagnetic poles of upper permian to tertiary age from the main blocks of china with the goal of placing constraints on models of the formation and the subsequent deformation of the region after selecting reliable poles by applying objective criteria we divide our analysis into first order motions of blocks and second order deformation within blocks for first order analysis apparent polar wander paths are constructed for the major blocks we discuss the compatibilities and contradictions between the geological and paleomagnetic records a sequence of paleogeographic configurations taking into account geological constraints but remaining within paleomagnetic uncertainties is presented in general the major blocks were probably in contact throughout the permian and triassic but the jurassic was the key age during which most of the movement toward china s present configuration took place our reconstructions include certain details which are suggested by the paleomagnetic record but whose geological signatures seem to have been hidden by subsequent events during the cretaceous chinese poles agree with poles from other continents transferred onto eurasia at the second order we observe that for almost each period with sufficient data the paleomagnetic poles are streaked along a small circle centered on the sampling region indicating that much of china has been affected by small 20 differential rotations this we interpret as deformation caused in part by the extrusion of the chinese blocks away from the indian collision the complete annotated list of poles is given as an appendix

mesozoic overthrust tectonics in south china whether south china was a platform or a para platform after the mid paleozoic deformation or whether the mountains of huanan south china form a mesozoic collision type orogen depends upon whether the ophiolite melange in the yangtze region is precambrian basement or was overthrust onto a foreland thrust belt during the mesozoic this paper presents evidence of tectonic windows under the melange and basement klippes above the melange in the yangtze region

late paleozoic macrofloral assemblages from weibei coalfield with reference to vegetational change through the late paleozoic ice age in the north china block abstract based on investigations of seven stratigraphic sections in the weibei coalfield a typical coal basin in the north china block the succession of late paleozoic plant macrofossil assemblages from the benxi or penchi in old spelling taiyuan shanxi lower shihhotse and upper shihhotse formations were redefined these zones are the paripteris spp linopteris spp conchophyllum richthofenii assemblage benxi fm neuropteris pseudovata lepidodendron posthumii assemblage taiyuan and lower shanxi fms emplectopteridium alatum emplectopteris triangularis cathaysiopteris whitei assemblage upper shanxi and lower shihhotse fms gigantonoclea lagrelii fascipteris hallei lobatannularia heianensis assemblage upper shihhotse fm as a result of this biostratigraphic reanalysis it has become clear that biostratigraphic boundaries do not exactly correlate to lithostratigraphic boundaries as has been thought the biostratigraphy of the terrestrial deposits in the north china block were correlated to the iugs global chronostratigraphy the more precise chronostratigraphic constraints that were obtained as a result of this study make it possible to more precisely correlate the vegetational successions to the concurrent waxing and waning of the late paleozoic ice sheets

middle permian u pb zircon ages of the glacial deposits of the atkan formation ayan yuryakh anticlinorium magadan province ne russia their significance for global climatic interpretations abstract the atkan formation in the ayan yuryakh anticlinorium magadan province northeastern russia is of great interest because of the occurrence of deposits of apparent dropstones and ice rafted debris that have been previously interpreted as glacial two high precision u pb zircon ages one for an intercalated volcanic tuff 262 5 0 2 ma and the other for a boulder clast 269 8 0 1 ma within a diamictite of the atkan formation constrain the age of the atkan formation as guadalupian middle permian sedimentologic study of the atkan formation casts doubt on the glacial nature of the diamictites deposition of rocks of the atkan formation temporally correlates with the capitanian interglacial event in the southern hemisphere that recently was calibrated with high precision ca tims the previously proposed climate proxy record based upon warm water foraminifera which corresponds closely to global climate fluctuations is compared with the glacial record of eastern australia and indicates that the capitanian was a time of globally warm climate the sedimentology of atkan formation the record of diversification of both fusulinids and rugosa corals global sea water temperature and sea level fluctuations agree well with high latitude paleoclimate records in northeastern russia and eastern australia major components of the atkan formation the volcanic rocks are syngenetic with the sedimentation process the volcanic activity in the nearby regions during middle late permian was quite extensive

the carbon isotope excursion on gssp candidate section of lopingian guadalupian boundary an isotopic stratigraphically well documented outcrop in penglaitan guangxi province south china has been proposed as a candidate gssp for the lopingian guadalupian boundary correlatable outcrops from the west wing tieqiao section and east wing penglaitan section of the laibin syncline exhibit synchronous excursions in carbon isotopes the isotopic excursions 13c show the best placement of the boundary may lie at the base of bed 6k which coincides with the clarkina postbitteri conodont zone and with eustatic change 13c increases during the uppermost guadalupian jinogondolella granti conodont zone from the top of 3c to the base of 6i a 13c peak value of 5 is located at the transition between these two conodont zones and is suggested as a proxy for the transition from transgression to regression a gradual depletion of carbon isotopes occurs in the c postbitteri zone from bed 6e to 7b and this gradual 13c excursion also suggests the sequences around the guadalupian lopingian boundary at the candidate section are conformable during the middle later c postbitteri zone a 3 5 dramatic 13c depletion is recorded at the tieqiao section but only a 2 depletion at the deeper facies penglaitan section synchronous with conodont zones that mark eustatic changes

timing of collision of the north and south china blocks controversy and reconciliation the qinling orogen was formed by the joining of the north and south china blocks but the timing of their integration has been debated for more than a decade the controversies obviously stem from different approaches to reconstruction of the integration history two contrasting lines of evidence yield two different ages for collision of the north and south china blocks middle paleozoic and late triassic the shangdan suture within the qinling was regarded in previous studies as the trace along which the north and south china blocks collided our studies however demonstrate that there are two sutures within the qinling the well documented shangdan suture and the newly discovered mianlue suture we show in this paper that the late proterozoic to early mesozoic evolution of the qinling involved interactions between the north china block the north and south qinling orogens and the south china block the middle paleozoic collision along the shangdan suture as constrained by some evidence accreted only the south qinling orogen to the southern part i e the north qinling of the north china block contemporaneous rifting of the south china block and subsequent drifting separated the south qinling from the south china block during the middle to late paleozoic the separation of the south from the north china blocks is supported by other evidence in particular geomagnetic data evidently it was the late triassic collision of the south china block with the south qinling orogen along the mianlue suture that led to final integration of the north and south china blocks

a temporal link between the emeishan large igneous province sw china and the end guadalupian mass extinction abstract previous studies have suggested that there were two mass extinction events in the late permian one that occurred at the permo triassic p t boundary 251 ma and a second smaller mass extinction that occurred 5 8 myr earlier at the end of the guadalupian many workers have argued that there is a causal relationship between large scale volcanic activity and mass extinctions the major mass extinction event at the p t boundary coincides with the outpouring of huge quantities of lava that formed the siberian flood basalt province in russia courtillot et al earth planet sci lett 166 1999 177 195 and wignall earth sci rev 53 2001 1 33 suggested that the earlier late permian mass extinction coincided with the eruption of the lavas that formed the emeishan flood basalt efb province in sw china however the age of eruption of the efb lavas is poorly constrained using the sensitive high resolution ion microprobe to analyze zircons we have established the age of the xinjie intrusion believed to be a feeder to the main phase of efb volcanism to be 259 3 ma hence the formation of the efb is coincident with a proposed extinction event at 256 259 ma this result supports a temporal link between the emeishan large igneous province and the end guadalupian mass extinction

global climate perturbations during the permo triassic mass extinctions recorded by continental tetrapods from south africa several studies of the marine sedimentary record have documented the evolution of global climate during the permo triassic mass extinction by contrast the continental records have been less exploited due to the scarcity of continuous sections from the latest permian into the early triassic the south african karoo basin exposes one of the most continuous geological successions of this time interval thus offering the possibility to reconstruct climate variations in southern laurasia from the middle permian to middle triassic interval both air temperature and humidity variations were estimated using stable oxygen 18op and carbon 13cc isotope compositions of vertebrate apatite significant fluctuations in both 18op and 13cc values mimic those of marine records and suggest that stable isotope compositions recorded in vertebrate apatite reflect global climate evolution in terms of air temperature oxygen isotopes show an abrupt increase of about 8 c toward the end of the wuchiapingian this occurred during a slight cooling trend from the capitanian to the permo triassic boundary ptb at the end of the permian an intense and fast warming of 16 c occurred and kept increasing during the olenekian these thermal fluctuations may be related to the emeishan south china and siberian volcanic paroxysms that took place at the end of the capitanian and at the end of the permian respectively vertebrate apatite 13cc partly reflects the important fluctuations of the atmospheric 13c values the differences with marine curves being likely due to the evolution of local humidity both the oxygen and carbon isotope compositions indicate that the ptb was followed by a warm and arid phase that lasted 6 ma before temperatures decreased during the late anisian toward that of the end permian environmental fluctuations occurring around the ptb that affected both continental and marine realms with similar magnitude likely originated from volcanism and methane release

illawarra reversal the fingerprint of a superplume that triggered pangean breakup and the end guadalupian permian mass extinction abstract the permian magnetostratigraphic record demonstrates that a remarkable change in geomagnetism occurred in the late guadalupian middle permian ca 265 ma from the long term stable kiaman reverse superchron throughout the late carboniferous and early middle permian to the permian triassic mixed superchron with frequent polarity changes in the late permian and triassic this unique episode called the illawarra reversal probably reflects a significant change in the geodynamo in the outer core of the planet after a 50 million years of stable geomagnetism the illawarra reversal was likely led by the appearance of a thermal instability at the 2900 km deep core mantle boundary in connection with mantle superplume activity the illawarra reversal and the guadalupian lopingian boundary event record the significant transition processes from the paleozoic to mesozoic modern world one of the major global environmental changes in the phanerozoic occurred almost simultaneously in the latest guadalupian as recorded in 1 mass extinction 2 ocean redox change 3 sharp isotopic excursions c and sr 4 sea level drop and 5 plume related volcanism in addition to the claimed possible links between the above listed environmental changes and mantle superplume activity i propose here an extra explanation that a change in the core s geodynamo may have played an important role in determining the course of the earth s surface climate and biotic extinction evolution when a superplume is launched from the core mantle boundary the resultant thermal instability makes the geodynamo s dipole of the outer core unstable and lowers the geomagnetic intensity being modulated by the geo and heliomagnetism the galactic cosmic ray flux into the earth s atmosphere changes with time the more cosmic rays penetrate through the atmosphere the more clouds develop to increase the albedo thus enhancing cooling of the earth s surface the illawarra reversal the kamura cooling event and other unique geologic phenomena in the late guadalupian are all concordantly explained as consequences of the superplume activity that initially triggered the breakup of pangea the secular change in cosmic radiation may explain not only the extinction related global climatic changes in the end guadalupian but also the long term global warming cooling trend in earth s history in terms of cloud coverage over the planet

emeishan large igneous province sw china in recent years there have been major advances in our understanding of the emeishan large igneous province lip of sw china following publication of a number of lip focused investigations of the terrain and associated rocks this paper reviews the current state of knowledge the volcanic and upper intrusive portion of the province is relatively small 0 3 106 km3 even when offset fragments eroded sections and buried portions are included in the volume calculation the most reliable radiometric age dates zircon u pb shrimp from an associated layered intrusive body several kilometers in area indicate generation at 259 ma consistent with the end guadalupian end middle permian stratigraphic age in addition several ar ar dating studies have been carried out mainly on the volcanic rocks with a number of reported dates 253 251 ma late permian but a consensus is emerging that these ages are problematic because they are in conflict with the stratigraphic data possibly due to a monitor standard miscalibration the ar ar investigations have also yielded a large number of secondary ages which are clustered at 175 142 98 and 42 ma and these are inferred to record sub regional tectonic events that affected the western yangtze block as east asia was assembled and later deformed by india s collision indentation into asia magnetostratigraphic data and field observations suggest that the bulk of the volcanic sequence formed within 1 2 my the geochemistry of the volcanic rocks and bio lithostratigraphic studies of the underlying maokou formation suggests a mantle plume generated the province the basalts can be classified into low and high ti groups with different parental magmas the low ti basalts are confined to the western part of the province and are overlain by the high ti basalts the low ti magmas formed at shallow mantle depths in the spinel garnet field transition zone 60 80 km whereas the high ti magmas formed by low degrees of partial melting within the deeper garnet stability field this observation suggests a deepening of the melting column as the lithosphere thickened due to under plating and a transition from peak basalt generation to the waning stage outstanding issues which might focus future studies are also outlined

mass extinctions and sea level changes abstract review of sea level changes during the big five mass extinctions and several lesser extinction events reveals that the majority coincide with large eustatic inflexions the degree of certainty with which these eustatic oscillations are known varies considerably thus the late ordovician and end cretaceous extinctions are associated with unequivocal major regressions demonstrated from numerous widespread regions in contrast the multiple high frequency sea level changes reported for the frasnian famennian crisis based on the supposed depth preferences of conodont taxa have little support from sequence stratigraphic analyses which reveals the interval to be one of highstand the end permian mass extinction has long been related to a severe first order lowstand of sea level newell n d 1967 revolutions in the history of life geol soc am spec pap 89 63 91 based primarily on the widespread absence of latest permian ammonoid markers but field evidence reveals that the interval coincides with a major transgression newell s hypothesis that marine extinctions are related to shelf habitat loss during severe regression remains tenable for the end guadalupian and end triassic extinction events but not for other crises rapid high amplitude regressive transgressive couplets are the most frequently observed eustatic changes at times of mass extinction with the majority of extinctions occurring during the transgressive pulse when anoxic bottom waters often became extensive the ultimate cause of the sea level changes is generally unclear a glacioeustatic driving mechanism can only be convincingly demonstrated for the end ordovician and end devonian events at other times it is speculated that they may relate to the widespread regional doming and subsequent collapse caused by the impingement of superplumes and ultimate eruption on the base of the lithosphere

permo triassic magnetostratigraphy in china the type section near taiyuan shanxi province north china summary a palaeomagnetic study has been made of samples collected from the permo triassic type section near taiyuan shanxi province in the north china block no results were obtained from the upper carboniferous shanxi and taiyuan formations results from the permian lower and upper shihezi and shiqianfeng formations and from the lower triassic liujiagou formation were restricted mainly to the red shale and red mudstone horizons that were preferentially sampled for this study after thermal demagnetization the following pole positions were obtained lower permian lower shihezi formation n 11 samples 20 9 n 1 4 e with dp 6 1 and dm 12 2 upper permian combined upper shihezi and shiqianfeng formations n 89 samples 47 8 n 357 4 e with dp 2 3 and dm 4 3 lower triassic liujiagou formation n 25 samples 50 0 n 351 o e with dp 3 7 and dm 7 0 the sequence crosses the younger boundary of the permo carboniferous reversed kiaman superchron and the polarity sequence observed suggests that this superchron ended in mid ufimian times a minimum of 13 polarity zones seven normal and six reverse then follow before the permo triassic boundary this is in excellent agreement with currently available observations worldwide

the middle permian capitanian mass extinction on land and in the oceans abstract a middle permian mass extinction first discovered in 1994 has become known as the end guadalupian event in the literature however recent studies of foraminifera and brachiopod range truncations in conodont dated sections on the south china block have shown that the losses occur below this level in the middle of the capitanian stage extinctions were suffered by several other groups notably the corals whilst the mollusc record is more enigmatic a major bivalve crisis has been reported in some studies the giant alatoconchids being notable victims but not others gastropods were unaffected by the crisis whilst a roughly contemporaneous ammonoid mass extinction may have occurred in the early wuchiapingian a few million years after the main marine losses compilation of data from plant species in south china reveals a significant 24 loss suggesting that the capitanian crisis also occurred on land an intra capitanian extinction of 56 of plant species in north china block sequences may also have coincided with these losses correlation of these marine and terrestrial extinction events using the palaeomagnetic record provides two alternatives either turnover amongst plant species is contemporaneous with the marine extinction and the eruption of the emeishan flood basalt province in southwest china or plant losses post date the marine extinction and instead coincide with the waning phase of the igneous province current understanding of the major dinocephalian extinction suggests this event occurred during the preceding stage the wordian but future improvements in both sampling and dating this tetrapod crisis may reveal a synchronicity of plant animal and marine invertebrate extinctions the clear temporal link of the capitanian marine extinction with emeishan volcanism suggests that these flood basalt eruptions triggered the crisis a contemporaneous major negative c isotope excursion suggests that like many other mass extinction events methane release from hydrates may also be implicated however in the best dated chinese sections the main excursion is found to slightly post date the extinction which occurs at the end of an unusual and unexplained interval of exceptionally heavy 13c values other usual suspects for mass extinctions either lack geological and palaeontological evidence e g marine anoxia and global cooling or do not precisely correlate with the extinction e g major eustatic regression

new constraints on the onset age of the emeishan lip volcanism and implications for the guadalupian mass extinction abstract the onset of the middle permian emeishan large igneous province elip is commonly implicated in the guadalupian mass extinction one of the largest phanerozoic extinction events yet the contribution of the elip to this biotic event remains unresolved because of a lack of appropriate age constraints in this study we examined claystone beds overlying the cherty limestone of the maokou formation and underlying the flood basalts of the elip that were emplaced around the guadalupian lopingian boundary integrated petrographic mineralogical elemental and isotopic features indicate that the studied claystones contain significant components from mafic volcanic ash that was likely associated with the emplacement of the elip zircons from the claystones yield u pb ages of 262 5 ma which predates the subaerial eruptive phase of the elip 259 1 260 4 ma but is comparable to the j altudaensis conodont biostratigraphic zone 263 ma middle capitanian stage which is contemporaneous with the emplacement of early stage emeishan subaqueous pillow basalts and mafic volcaniclastics our data provide a crucial new constraint on the lower age limit for the onset of the elip which was likely associated with violent submarine eruptions and thus could have contributed to the loss of marine fauna during the guadalupian mass extinction

high precision u pb zircon age constraints on the guadalupian in west texas usa abstract the guadalupian epoch was characterized by major changes in paleogeography paleoclimate and biodiversity yet the paucity of precise and accurate radioisotopic dates from the guadalupian stages in their type area guadalupe mountains national park in west texas has rendered their calibration inadequate in this study we report high precision u pb zircon geochronology by the ca id tims method from three ash beds 2 internal errors only in the rader member of the bell canyon formation at the back ridge section 262 127 0 097 ma mswd 0 89 n 3 the lower pinery member of the bell canyon formation at the frijole section 264 23 0 13 ma mswd 0 89 n 8 and the basal south wells member of the cherry canyon formation at the monolith canyon section 266 525 0 078 ma mswd 0 62 n 5 the bayesian interpolation statistics method is used to establish an age stratigraphy model that estimates the base of the capitanian to be 264 28 0 16 ma serving as the best age estimate for the capitanian stage at present in addition we review the existing geochronology from the guadalupian series in west texas and seek to propose more precise temporal estimates of guadalupian geological and biological events these data constrain the high frequency sequences of the cherry canyon and bell canyon formations in the guadalupe mountains national park area accordingly the base of the wordian is estimated at 266 9 0 4 ma and the illawarra geomagnetic polarity reversal in west texas at 267 4 0 4 ma to 266 5 0 3 ma the global end guadalupian extinction began in the conodont zone of jinogondolella altudaensis above the base of the reef trail member of the bell canyon formation and might continue to the clarkina postbitteri postbitteri zone in the earliest wuchiapingian the conodonts display a rapid evolutionary rate during this interval this constrains the biotic crisis from ca 260 ma to 259 ma based on our conodont age estimation the emplacement of the emeishan large igneous province elip in south china has been constrained to ca 260 ma to 257 4 ma based on zircon u pb geochronology by the ca id tims method overlapping with the end guadalupian extinction which provides support for the temporal relationship between them additionally the elip persisted into the early wuchiapingian and may have hampered ecosystem restoration during the post extinction interval

end guadalupian extinction of the permian gigantic bivalve alatoconchidae end of gigantism in tropical seas by cooling abstract the unique permian bivalve family alatoconchidae has aberrant shell forms and extraordinary size up to 1 m representing the largest bivalve group in the paleozoic their occurrence is reported sporadically from lower middle permian shallow marine carbonates in 9 areas in the world tunisia croatia oman iran afghanistan thailand malaysia the philippines and japan that cover low latitudes of both the tethyan and panthalassan domains alatoconchids almost always occurred in close association with large tested fusulines verbeekinidae and or rugose corals waagenophyllidae of the typical tethyan assemblage suggesting their preferential adaptation to shallow warm water tropical environments this tropical trio alatoconchidae verbeekinidae and waagenophyllidae became extinct either during the late guadalupian or around the guadalupian lopingian boundary g lb their intimate association and occurrence range suggest that these 3 taxonomically distinct clades may have shared not only a common habit but also a common cause of extinction the shell structure of alatoconchids suggests their symbiosis with photosynthetic organisms algae cyanobacteria in order to maintain their large body size that required high energy consuming metabolism in contrast to smaller forms the alatoconchidae attained their largest size in the wordian middle guadalupian probably maximizing the benefits of photosymbiosis the subsequent extinction of the warm water adapted tropical trio both in tethys and panthalassa positively supports the explanation that a critical cooling took place on a global scale including low latitude oceans the end of the gigantism in fusulines and bivalves in the capitanian late guadalupian was likely caused by the collapse of photosymbiotic systems during a temporary temperature drop of seawater kamura cooling event coupled with eutrophication that was detrimental to the tropical fauna adapted particularly to oligotrophic conditions gigantism of bivalves occurred several times in the phanerozoic e g siluro devonian permian triassic early jurassic and jurassic creataceous mostly in warm periods the sea level change in the phanerozoic apparently synchronized with the intermittent rise and decline of bivalve gigantism suggesting that the photosymbiosis related gigantism in low latitudes may serve as a potential monitor of global warming cooling in the past

massive dissociation of gas hydrate during a jurassic oceanic anoxic event in the jurassic period the early toarcian oceanic anoxic event about 183 million years ago is associated with exceptionally high rates of organic carbon burial high palaeotemperatures and significant mass extinction heavy carbon isotope compositions in rocks and fossils of this age have been linked to the global burial of organic carbon which is isotopically light in contrast examples of light carbon isotope values from marine organic matter of early toarcian age have been explained principally in terms of localized upwelling of bottom water enriched in 12c versus 13c refs 1 2 5 6 here however we report carbon isotope analyses of fossil wood which demonstrate that isotopically light carbon dominated all the upper oceanic biospheric and atmospheric carbon reservoirs and that this occurred despite the enhanced burial of organic carbon we propose that as has been suggested for the late palaeocene thermal maximum some 55 million years ago the observed patterns were produced by voluminous and extremely rapid release of methane from gas hydrate contained in marine continental margin sediments

the mid capitanian middle permian mass extinction and carbon isotope record of south china abstract conodont c isotope and fossil and facies data are presented for the capitanian middle permian mass extinction record seen in platform carbonates maokou and wuchiaping formations of south china where limestones interdigitate with the volcanic succession of the emeishan large igneous province the maokou formation provides an extinction record marked by the loss of keriothecal walled fusulinaceans and a turnover in calcareous algae in sections within the emeishan province this crisis occurs at the base of the oldest record of volcanism from the jinogondolella altudaensis conodont zone of mid capitanian age around the periphery of the emeishan province this extinction level lies within the upper part of the maokou formation at a level where platform carbonate deposition was frequently interrupted by thick volcanic ash depositional events the assemblages of the uppermost maokou formation are characterised by typical late permian taxa although these levels still lie within the middle permian guadalupian series disaster taxa such as earlandia and diplosphaerina are locally prolifically abundant in the aftermath of the mass extinction the crisis is particularly noteworthy amongst photosynthetic taxa such as calcareous algae and fusulinaceans that probably harboured photosymbionts therefore a kill mechanism involving cooling from explosive volcanism and potentially acid rain from sulphate aerosols appears appropriate a composite 13ccarb curve calibrated against a high resolution conodont biostratigraphy reveals a major intra capitanian negative excursion of 5 superimposed on typically heavy 4 5 middle permian values this curve can also be recognised in panthalassan seamount carbonates of japan although this requires reassignment of apparently upper permian limestones to the middle permian in both china and japan the capitanian mass extinction occurs during the early stage of this major intra capitanian negative excursion assuming typical platform carbonate accumulation rates the records of the maokou formation suggest 13ccarb values fell at 0 01 kyr suggesting a catastrophic origin such as gas hydrate destabilisation is unlikely although a volcanic source is possible

capitanian late guadalupian permian global brachiopod palaeobiogeography and latitudinal diversity pattern a global database containing 3365 occurrences 821 species and 251 genera of the capitanian late guadalupian permian brachiopod faunas from 24 stations has been analyzed by cluster analysis using the jaccard and otsuka coefficients and the probabilistic index of similarity nonmetric multidimensional scaling and minimum spanning tree two supergroups three groups and six subgroups are revealed and interpreted as representing respectively two biotic realms the palaeoequatorial and gondwanan realms two regions and six provinces an additional realm the boreal realm based on the fauna from spitsbergen also appears recognizable although it also shows considerable similarities with southwestern north america and the northern margin of gondwana as revealed by the statistical analysis the palaeoequatorial realm can be further subdivided into the north america region and the asian tethyan region the six biotic provinces are the cathaysian province in the palaeotethys and mesotethys the greenland svalbard province in the arctic region the austrazean province in eastern australia and new zealand the grandian province in western north america and the two transitional zones the himalayan province in the southern temperate zone and the sino mongolian japanese province in the northern temperate zone polynomial regression analysis and rarefaction analysis indicate that the generic diversities of brachiopod faunas during the capitanian peaked in the palaeoequatorial cathaysian province and the two transitional zones himalayan province and sino mongolian japanese province but fell dramatically in the polar regions the generic diversity of the palaeoequatorial grandian province is apparently lower than in the two transitional zones of temperate palaeolatitudes suggesting that the generic diversity of capitanian brachiopod faunas does not exhibit a strict negative correlation with palaeolatitudes this in turn would suggest that biogeographical determinants such as geographical barriers inhabitable area and ocean currents other than latitude related temperature control may also have played an important role in the dispersal of some brachiopods and the characterization of some local provinces and high diversities the capitanian global brachiopod palaeobiogeography is generally comparable with those in the wuchiapingian and changhsingian but with some notable differences these include 1 that the grandian province of the capitanian in western north america vanished after the end guadalupian regression 2 that the western tethyan province of the lopingian could not be distinguished in the capitanian and 3 that the austrazean province was larger in area than either in the wuchiapingian or in the changhsingian

permian bimodal magmatism in the southern margin of the central asian orogenic belt beishan xinjiang nw china petrogenesis and implication for post subduction crustal growth abstract previous studies show that permian bimodal magmatism is widespread in the tianshan region the southern part of the central asian orogenic belt in northern xinjiang nw china we have found that such bimodal magmatism extended farther to the south in the beishan region our new zircon u pb age data show that the dolerite and granite dykes in the poyi area of the region were emplaced at 270 ma 20 myr after subduction ended in the region the dated dolerite dyke is characterized by pronounced negative nb ta anomalies high end t from 4 3 to 5 1 and low initial 87sr 86sr ratios from 0 7051 to 0 7060 for whole rocks plus high ehf t from 8 96 to 13 0 and elevated 18o from 5 8 to 6 5 for zircon crystals which indicate a subduction modified mantle source and moderate degrees of crustal contamination 25 myr and show no age progression in a single direction which are inconsistent with the results of mantle plume magmatism whole rocks from the permian granite dyke in the poyi area are characterized by strong negative nb ta anomalies negative end t from 2 4 to 1 6 and high initial 87sr 86sr from 0 7080 to 0 7088 magmatic zircon crystals from the granite dyke have ehf t from 0 86 to 5 64 and 18o from 6 5 to 7 2 the isotope compositions of the granite dyke are within the ranges of the pre permian crustal rocks in the region indicating a predominantly crustal source based on these data we propose that partial melting in the crust was induced by underplating of mantle derived mafic magmas some of which were emplaced in the upper parts of the crust to form the broadly coeval dolerite dykes and mafic ultramafic intrusions the results from this study support the view that post subduction bimodal magmatism is important for continental crustal growth and differentiation

timing and magnitude of tetrapod extinctions across the permo triassic boundary a review of the tetrapod amphibian and amniote record across the permo triassic boundary ptb indicates a global evolutionary turnover of tetrapods close to the ptb there is also a within guadalupian tetrapod extinction here called the dinocephalian extinction event probably of global extent the dinocephalian extinction event is a late wordian or early capitanian extinction based on biostratigraphic data and magnetostratigraphy the extinction precedes the illawara reversal so it is not synchronous with the end guadalupian marine extinction the russian ptb section documents two tetrapod extinction events one just before the dinocephalian extinction event and the other at the base of the lystrosaurus assemblage however generic diversity across the latter extinction remains essentially the same despite a total evolutionary turnover of tetrapod genera the chinese and south african sections document the stratigraphic overlap of dicynodon and lystrosaurus in the karoo basin the lowest occurrence of lystrosaurus is in a stratigraphic interval of reversed magnetic polarity which indicates it predates the marine defined ptb so as previously suggested by some workers the lowest occurrence of lystrosaurus cannot be used to identify the ptb in nonmarine strata correlation of the marine ptb section at meishan southern china to the karoo basin based primarily on magnetostratigraphy indicates that the main marine extinction preceded the ptb tetrapod extinction event the ecological severity of the ptb tetrapod extinction event has generally been overstated and the major change in tetrapod assemblages that took place across the ptb was the prolonged and complex replacement of therapsids by archosaurs that began before the end of the permian and was not complete until well into the triassic the tetrapod extinctions are not synchronous with the major marine extinctions at the end of the guadalupian and just before the end of the permian so the idea of catastrophic causes of synchronous ptb extinctions on land and sea should be reconsidered

permo carboniferous paleogeography and coal accumulation and their tectonic control in the north and south china continental plates abstract permo carboniferous strata in north china and south china were essentially controlled by paleogeography paleoclimate and plate tectonics during that time north china and south china were separate microcontinents located on opposite sides of the equator thus the characteristics of their coal deposits differ substantially in north china the coal seams were initially deposited on a north sloping epicontinental basin during the middle carboniferous by the middle of the late permian the locus of coal formation had shifted from the north to the south as a result of the uplift of the northern margin due to continental collision with the siberian plate as the paleoplate was situated in the low northern latitudes moist tropical climate and favorable geographic setting allowed the extensive development of late carboniferous and earliest permian peat swamps on the northern alluvial fluvial plain and central paralic regimes more significantly two thick coal sequences were formed in the transition belt between the alluvial apron and fluvial plain and the shoreline area where high groundwatertable fed by both rainwater and groundwater favored the formation of thick peat in swamps with northward drift the paleoplate entered the subtropic semiarid and arid climatic belt between the late early permian and early late permian coal formation was restricted to the paralic delta plain where locally oceanic wet climate and high groundwatertable prevailed following this the subduction of the paleo tethys beneath the southern margin of north china led to the upwarp of the southern margin and kept the delta system growing vertically for a considerable period so that it kept pace with shoreline fluctuations on the southern area the result was that multicycle deltaic coals were well developed at this stage in south china coal was formed in the coastal zone of an epeiric and shelf sea which connected the marinal basins the basins were frequently influenced by plate marginal tectonic movements and continental rifting related to back arc extension as a result coal formation was often interrupted by sea level fluctuations early carboniferous coal was deposited during the short regressions during the widespread transgression mainly on the restricted marine paralic plain where clastic deposition was active in the middle and late carboniferous no coal was formed because the paleoplate had drifted into a subtropic arid belt early permian coal accumulated at first in the northeast and later in the southwest due to tectonic influences in the late permian relatively thick and extensive coal was formed even though it was during a transgressive period in both the western and eastern margins under the equatorial hot humid conditions in general the seam geometry and quality particularly ash and sulfur of the coal was directly controlled by the geography and the changes in the depositional environments however the fluctuation in coal formation and the migration of thicker coal zones was indirectly controlled by paleoclimate and the sea level fluctuations in response to plate tectonic influences

methane release from igneous intrusion of coal during late permian extinction events abstract unusually large and locally variable carbon isotope excursions coincident with mass extinctions at the end of the permian period 253 ma and guadalupian epoch 260 ma can be attributed to methane outbursts to the atmosphere methane has isotopic values 13c low enough to reduce to feasible amounts the carbon required for isotopic mass balance the duration of the carbon isotopic excursions and inferred methane releases are here constrained to 10 000 yr by counting annual varves in lake deposits and by estimating peat accumulation rates on paleogeographic maps the most marked carbon isotope excursions form linear arrays back to plausible methane sources end permian siberian traps and longwood bluff intrusions of new zealand and end guadalupian emeishan traps of china intrusion of coal seams by feeder dikes to flood basalts could create successive thermogenic methane outbursts of the observed timing and magnitude but these are unreasonably short times for replenishment of marine or permaf

carbon isotope anomaly and other geochemical changes at the triassic jurassic boundary from a marine section in hungary most mass extinctions are linked with carbon isotope excursions implying that biotic crises are coupled with changes in the global carbon cycle the isotopic evolution during the end triassic extinction is far less documented than that for the other major phanerozoic extinctions here we report a sharp and short lived 23 5 excursion in carbon isotope values for carbonate d 13 ccarb corresponding to a 22 excursion in the isotopic composition of marine organic matter d 13 corg and other geochemical

multiple sulfur isotope records at the end guadalupian permian at chaotian china implications for a role of bioturbation in the phanerozoic sulfur cycle abstract a recent study on quadruple sulfur isotopes 32s 33s 34s and 36s of sedimentary pyrite suggested that the end guadalupian extinction was caused by shoaling of the sulfidic deep water this scenario is based on the assumption that sulfur isotopic compositions of pyrite from hosting sediments were controlled by benthos activities thus by the redox conditions of the sedimentary environments nonetheless the relationship between the sulfur isotope records and redox conditions reconstructed from litho and bio facies are poorly known in order to examine the effect of bioturbation in sediments quadruple sulfur isotopic compositions of sedimentary pyrite from the end guadalupian succession in chaotian south china were analyzed black mudstones of deep water facies immediately below the extinction horizon have consistently high 33s values of ca 0 079 clearly suggesting a sulfate reduction in the anoxic water column our new data are consistent with the emergence of a sulfidic deep water mass prior to the end guadalupian extinction the upwelling of the toxic deep water may have contributed to the extinction in contrast shallow marine bioclastic limestones with burrows deposited under oxic conditions have negative 33s values this anomalous isotopic signal indicates the mixing of two distinct types of pyrite one generated during the sulfate reduction in an open system and the other in a closed system we interpret that bioturbation supplied sulfate in the sediments and promoted sulfate reduction and in situ sulfide precipitation within the sediments the negative 33s values of oxic sediments in chaotian are inconsistent with the previous model and demonstrate that the sedimentary sulfur cycle associated with bioturbation was more complicated than previously thought our study also implies that more generally the role of bioturbation in increasing seawater sulfate concentration in the phanerozoic may have been overestimated in the previous studies because bioturbation may have enhanced sulfide burial or sulfur output from the oceans

stable isotope record implicates aridification without warming during the late capitanian mass extinction abstract the late capitanian mass extinction 260 million years ago represents one of the greatest biotic perturbations of the phanerozoic and was the earliest mass extinction to affect terrestrial tetrapods and ecosystems in the past this extinction has been largely associated with taxonomic loss and ecological restructuring in marine environments but more recently it has also been recognised in terrestrial ecosystems though various environmental mechanisms have been proposed for the former little evidence has yet been presented for the cause of terrestrial extinctions we determined the stable oxygen and carbon isotope compositions of dentine apatite from twenty eight specimens of the dicynodont therapsid diictodon feliceps to investigate the potential role of climate in driving terrestrial tetrapod extinctions studied specimens were recovered from a 270 m stratigraphic interval constraining the peak in tetrapod extinction rates in the uppermost abrahamskraal formation in the well sampled main karoo basin of south africa our results demonstrate a positive excursion of 13c values coinciding with the extinction peak that is followed by a return to pre extinction 13c values suggesting a local increase in aridity at the time of the extinction for the same time interval the 18o values did not demonstrate statistically significant changes suggesting constant temperature in the south african paleoenvironment this unusual increase in aridity but not in temperature has been interpreted as the possible result of orogenesis in the cape fold mountain source along the southern margin of gondwana

the cretaceous tertiary biotic transition mass extinctions are recognized through the study of fossil groups across event horizons and from analyses of long term trends in taxonomic richness and diversity both approaches have inherent flaws and data that once seemed reliable can be readily superseded by the discovery of new fossils and or the application of new analytical techniques herein the current state of the cretaceous tertiary k t biostratigraphical record is reviewed for most major fossil clades including calcareous nannoplankton dinoflagellates diatoms radiolaria foraminifera ostracodes scleractinian corals bryozoans brachio pods molluscs echinoderms fish amphibians reptiles and terrestrial plants macrofossils and palynomorphs these reviews take account of possible biasing factors in the fossil record in order to extract the most comprehensive picture of the k t biotic crisis available results suggest that many faunal and floral groups ostracodes bryozoa ammonite cephalopods bivalves archosaurs were in decline throughout the latest maastrichtian while others diatoms radiolaria benthic foraminifera brachiopods gastropods fish amphibians lepidosaurs terrestrial plants passed through the k t event horizon with only minor taxonomic richness and or diversity changes a few microfossil groups calcareous nannoplankton dinoflagellates planktonic foraminifera did experience a turnover of varying magnitudes in the latest maastrichtian earliest danian however many of these turnovers along with changes in ecological dominance patterns among benthic foraminifera began in the latest maastrichtian improved taxonomic estimates of the overall pattern and magnitude of the k t extinction event must await the development of more reliable systematic and phylogenetic data for all upper cretaceous clades

emeishan basalts sw china and the end guadalupian crisis magnetobiostratigraphic constraints abstract a magnetostratigraphic investigation of the permian emeishan lip large igneous province was carried out on a composite section in ebian county close to the type area in sichuan sw china the main succession of twelve flows 175 m thick carries a normal polarity whilst the one reliable site from the overlying 30 m thick volcanic waning sequence is marked by a reverse polarity the data enable a correlation to be proposed with an emeishan basalt sequence in western guizhou c 400 km to the se from our knowledge of the geomagnetic field9s reversal behaviour during the permian it suggests that the main lava pile along the eastern half of the emeishan basalt outcrop belt was erupted within a half to one million years using magnetobiostratigraphic data from the adjacent south china platform the normal polarity magnetozone is correlated with the normal polarity chron associated with the upper part of the maokou limestones constrained by conodont data the main emei basalts appear to be at least two biozones older 1 1 5 ma than the mid late permian boundary it is possible however that the emei basalt waning zone sequence which represents an explosive volcanic phase might be coeval with the end guadalupian biotic crisis thus arguments implicating emei basalt volcanism as the causal mechanism behind this major global event have to accommodate the new relative age constraints

volcanism mass extinction and carbon isotope fluctuations in the middle permian of china the 260 million year old emeishan volcanic province of southwest china overlies and is interbedded with middle permian carbonates that contain a record of the guadalupian mass extinction sections in the region thus provide an opportunity to directly monitor the relative timing of extinction and volcanism within the same locations these show that the onset of volcanism was marked by both large phreatomagmatic eruptions and extinctions amongst fusulinacean foraminifers and calcareous algae the temporal coincidence of these two phenomena supports the idea of a cause and effect relationship the crisis predates the onset of a major negative carbon isotope excursion that points to subsequent severe disturbance of the ocean atmosphere carbon cycle

fusuline biotic turnover across the guadalupian lopingian middle upper permian boundary in mid oceanic carbonate buildups biostratigraphy of accreted limestone in japan abstract two sections in upper middle to lower upper permian shallow water limestones at kamura and akasaka in southwest japan were analyzed for detailed lithostratigraphy and biostratigraphy both sections represent ancient seamount capping carbonate buildups developed on a basaltic basement in a mid oceanic environment the occurrence of abundant tethyan fusulines allows the recognition of well defined biostratigraphic zonation in both sections and their mutual correlation the upper guadalupian middle permian lepidolina yabeina zone is overlain conformably by the lower lopingian upper permian codonofusiella reichelina zone with a 13 m thick transitional interval barren of index taxa the guadalupian lopingian g l boundary is marked by the first appearance datum fad of the lopingian codonofusiella reichelina assemblage in both sections this study recognizes for the first time the g l boundary horizon in a mid oceanic shallow water environment in addition the shallow water carbonates in the study sections record the extinction of the middle permian large sized fusuline family verbeekinidae at the g l boundary in mid panthalassa as well as in shallow water tethyan shelf areas demonstrating positively that the g l boundary mass extinction occurred on a global scale the abrupt elimination of large shelled fusulines followed by the domination of small shelled fusulines may indicate that environmental stress occurred at the end of guadalupian the dying out of symbiotic algae may have caused the selective extinction of the large shelled fusulines

progress problems and prospects an overview of the guadalupian series of south china and north america abstract the guadalupian epoch is marked by the formation of the pangean supercontinent global sea level change rifting and drifting of the cimmerian continents formation of large igneous provinces and dramatic biotic changes a high resolution biostratigraphic chemostratigraphic and high precision geochronologic framework of this critical transition is fundamental to understanding these events extensive studies of the latest cisuralian and guadalupian series in both south china and north america reveal the same conodont lineages but the conodont interval zones based on jinogondolella within the guadalupian series are slightly diachronous high precision u pb geochronological studies ca id tims method calibrate the base of the guadalupian series base roadian at 273 01 0 14 ma a previously reported age from an ash bed overlying the emeishan flood basalts 259 51 0 21 ma is adopted for the guadalupian lopingian boundary glb based on recently published geochronology and bayesian age modeling from the guadalupian series the base of the capitanian is constrained at 264 28 0 16 ma and the base of the wordian is interpolated to be 266 9 0 4 ma the illawarra reversal is of early middle wordian age both north america and south china possess a distinct negative 13ccarb excursion of 3 5 at the latest kungurian and early roadian lk er cie which coincides with the early stages of a significant 3rd order sea level rise the large end guadalupian 13ccarb negative excursion may have been affected by post depositional diagenesis or a warming event associated with the emeishan volcanism the 87sr 86sr ratios in both regions declined from the latest kungurian to the late capitanian but have different ratios and reveal several fluctuations in the middle guadalupian measured 18oapatite values suggest that the delaware basin was 3 4 c cooler than the eastern yangtze block analysis of a new high resolution database of marine taxa indicates only a minor pre lopingian diversity drop from 261 04 ma to 259 98 ma which coincides with the peak emeishan volcanism the widely perceived end guadalupian mass extinction in north america is evidently masked by and possibly an artefact of a stratigraphic truncation effect due to rapid lithofacies changes from limestone to laminated evaporites with the closure of the west texas basins

permo triassic boundary superanoxia and stratified superocean records from lost deep sea pelagic cherts of japan and british columbia canada recorded a long term and worldwide deep sea anoxic oxygen depleted event across the permo triassic or paleozoic and mesozoic boundary 251 2 million years ago the symmetry in lithostratigraphy and redox condition of the boundary sections suggest that the superocean panthalassa became totally stratified for nearly 20 million years across the boundary the timing of onset climax and termination of the oceanic stratification correspond to global biotic events including the end guadalupian decline the end permian extinction and mid triassic recovery

permian tectonic framework and palaeogeography of se asia abstract the principal continental lithospheric terranes now comprising se asia and that existed in the permian are the south china indochina super terrane and the sibumasu simao west burma and sw borneo semitau terranes the simao terrane is here regarded a separate terrane derived from south china by back arc spreading in the lower carboniferous rather than as an extension of indochina the main palaeo tethys ocean in thailand is identified as being represented by the chiang mai and sra kaeo sutures and the eastern boundary of the sibumasu terrane is thus interpreted to lie farther west in thailand than previously inferred the nan uttaradit suture is interpreted as representing a marginal back arc basin and contiguous with the ailaoshan and jinshajiang sutures in sw china the south china indochina super terrane and the simao terrane were located within the palaeo tethys in equatorial latitudes during the permian where they together with north china exhibit cathaysian floras and faunas the sibumasu terrane was located on the nw australian margin of gondwana until the sakmarian major shifts in faunal affinities from gondwana province faunas to an independent sibumasu province and then to assimilation into the cathaysian province records the separation and rapid northward drift of sibumasu after the late sakmarian the principal permian palaeogeographic models for the region are assessed for internal consistencies and conflicts

re evaluating plume induced uplift in the emeishan large igneous province numerical and fluid dynamic modelling predicts that mantle plumes should generate a broad domal uplift 1 000 km wide 500 to 1 000 m high preceding volcanism in large igneous provinces the emeishan large igneous province southwest china has been offered as the best example of plume induced uplift where kilometre scale pre and syn volcanic relief was interpreted to develop in response to the impingement of a plume head here we document voluminous mafic hydromagmatic deposits and submarine extrusions that formed during the initiation and early stages of the emeishan large igneous province these deposits were previously interpreted to be alluvial fan sediments shed from a pre volcanic domal high the abundance of such deposits consisting of variable proportions of marine limestone and basaltic fragments strongly suggests that the bulk of this province was emplaced at sea level evidence for dynamic pre volcanic uplift as predicted by plume models is lacking and such a lack may be the more general case any positive relief that developed was more likely the result of the formation of a volcanic edifice and rapid accumulation of the volcanic pile thick alluvial fan sediments from the core of the emeishan large igneous province have been considered as critical field evidence in support of plume induced pre volcanic doming and uplift these sediments are now reinterpreted as mafic hydromagmatic deposits emplaced at sea level precluding dynamic pre volcanic uplift as predicted by mantle plume models