lower triassic peritidal cyclic limestone an example of anachronistic carbonate facies from the great bank of guizhou nanpanjiang basin guizhou province south china abstract most shallow marine sections described from the lower triassic formed in mixed carbonate siliciclastic systems shallow marine limestones from an isolated carbonate platform the great bank of guizhou in the nanpanjiang basin south china provide a unique opportunity to examine a pure peritidal carbonate depositional system the platform had a low relief bank profile in the early triassic with oolite shoals at the margin shallow subtidal and peritidal deposits in the interior and pelagics debris flow deposits and turbidites on gentle basin margin slopes interior strata are 265 m thick beginning in the lowermost triassic with renalcis biostromes followed by lime mudstone oolite and cyclic peritidal limestone the cyclic limestone is olenekian in age 164 m thick and contains up to 83 cycles parasequences parasequences are 0 2 7 4 m thick and typically shallow upward from subtidal oolite grainstone and skeletal packstone facies followed by renalcis reef mounds or biostromes and capped by intertidal flaser bedded ribbon rock the skeletal packstone and reef mounds contain a low diversity biota of cyanobacteria echinoderms bivalves gastropods lingulid brachiopods spirorbids and ostracodes ribbon rock contains alternating lime mud and fine peloidal packstone and grainstone laminae scour surfaces ripple cross lamination lime mud drapes and minor prism cracks parasequence stacking patterns exhibit gradual increase and decrease of parasequence thickness defining a third order sequence boundary and several 4th order parasequence sets that correlate between interior sections parasequence stacking patterns similar to those of lower palaeozoic green house sequences and different from ice house sequences the lower triassic platform interior parasequences represent an anachronistic facies in that they are strikingly similar to the common renalcis mound ribbon rock parasequences of the lower palaeozoic and different from other permo triassic parasequences e g capitan shelf parasequences or loferites facies similarities such as renalcis mounds and flaser bedded intertidal ribbon rock reflect anomalous oceanic conditions resulting in low biodiversity and low intensity of bioturbation after the end permian extinction similarities in parasequence stacking patterns reflect low amplitude high frequency sea level fluctuations resulting from green house conditions common to the early palaeozoic and early triassic

palaeoenvironments and faunal recovery after the end permian mass extinction abstract strata of the lower triassic werfen formation dolomites northern italy record deposition in a wide range of palaeoenvironments from peritidal to outer ramp settings this enables accurate assessment of faunal recovery following the end permian mass extinction by eliminating facies related effects extinction of the shelly taxa appears to be rapid and occurs in the latest permian tesero oolite horizon disappearance of the various trace fossil taxa appears to be more gradual following the extinction the lower and middle griesbachian are characterised by laminated sediments containing low diversity bedding plane assemblages ichnological geochemical and sedimentological data show evidence of widespread low oxygen conditions normally oxygenated waters return in the late griesbachian and there is a moderate increase in tiering above and below the surface macrofaunal and ichnofossil diversity decrease markedly during the smithian with the appearance of more terrigenous strata possibly reflecting an increased run off and more brackish conditions complete recovery begins in the basal spathian with an increase in tiering above and below the substrate crinoids and ammonoids appear for the first time in the werfen formation and the ichnogenus rhizocorallium re appears global correlation is hindered by poor biostratigraphy in the dolomites region however on a broad scale it appears as though many of the palaeoenvironmental changes are repeated worldwide current available data suggest that the re appearance of some trace fossil taxa e g diplocraterion rhizocorallium may be globally synchronous

recent evolution of a bahamian ooid shoal effects of hurricane andrew hurricane andrew a category 4 hurricane having wind velocities of 240 km hr passed north of joulters cays bahamas in a westerly direction on august 23 1992 we documented three sedimentary facies in a 2 7 km 2 study area dominated by mobile ooid sands before the hurricane using aerial photographs surface observations and shallow coring the shoal crest at this locality had aggrading and northward prograding parallel to depositional strike washover bars composed of cross bedded well sorted ooid sands burrowed poorly sorted ooid sands were present seaward of the washover bars whereas poorly sorted ooids and mud occupied a stabilized area bankward of the actively migrating shoal and local areas between washover bars on the crest of the shoal the shoal was crosscut by tidal channels and older washover bars were being dissected by tidal currents although hurricane andrew profoundly changed surface features within the study area its effects will probably be only partly preserved the hurricane eroded washover bars and transported sediment seaward leaving a nearly flat shoal crest overlain by a laterally continuous decimeter thick lens of well sorted ooid sand that thins seaward and bankward post hurricane tidal currents deposited a centimeter thick discontinuous layer of carbonate mud over this lens of well sorted ooid sand and transported ooids seaward off the shoal the well sorted ooid sand layer will most likely be reworked when an actively migrating shoal crest is reestablished although some of this storm deposit may be preserved on the shoal crest where the ooid sand layer was deposited in areas of normally less agitated conditions ooids may also be preserved in finer grained sediments seaward of the shoal as suggested by previous studies mud deposits on the shoal crest may be preserved where buried beneath reestablished washover bars although some of this mud will be removed by reworking during diurnal tides

u pb zircon geochronology and tempo of the end permian mass extinction the mass extinction at the end of the permian was the most profound in the history of life fundamental to understanding its cause is determining the tempo and duration of the extinction uranium lead zircon data from late permian and early triassic rocks from south china place the permian triassic boundary at 251 4 0 3 million years ago biostratigraphic controls from strata intercalated with ash beds below the boundary indicate that the changhsingian pulse of the end permian extinction corresponding to the disappearance of about 85 percent of marine species lasted less than 1 million years at meishan a negative excursion in 13 c at the boundary had a duration of 165 000 years or less suggesting a catastrophic addition of light carbon

hunting for paleoclimatic periodicities in a geologic time series with an uncertain time scale an 8 m section of a mid cretaceous albian deep sea sediment core from piobbico italy contains 2 cycles m compositional oscillations as postdepositional chemical migration in the core is weak the relative amount of carbonate is a primary indicator of cretaceous paleoclimate variability we report results of spectral analysis of two series caco3 wt measurements taken at roughly 2 cm intervals and a more densely sampled photodensitometer record of light dark variation the uncertainty in the age depth relation i e unknown fluctuations in sedimentation rate hampers a detailed assessment of the suggested eccentricity correlation we fit for long term time scale greater than 75 kyr fluctuations in sedimentation rate by tracking the local frequency modulation of the dominant harmonic in the data series assuming the true input signal to be monochromatic we estimate uncertainty in the observed local frequency by means of a statistical jackknife we fit a smoothed cubic spline to the set of discrete frequency modulation estimates specifying a 2 n misfit criterion where n is the number of frequency estimates from this analysis we infer fluctuations of a factor of two in the sedimentation rate which occur predominately on a time scale of 400 kyr we generate tuned series using several candidate age depth relations from the carbonate and densitometer series the tuned carbonate series returns greater correlation with the modern milankovitch periodicities the 2 cycles m energy resolves principally into two harmonic components whose frequency ratio corresponds to an observational accuracy of 1 2 to that of the 97 0 and 127 6 kyr eccentricity oscillations at frequencies lower than 2 cycles m we find harmonic oscillations whose phase correlates with the beating envelope of the 2 cycles m energy in a manner consistent with the modern milankovitch insolation we also observe a sinusoidal oscillation of lower amplitude with period scaled by those of the presumed eccentricity oscillations of 39 2 1 1 kyr which agrees with the period of the modern obliquity cycle after correction for the effects of tidal friction oscillations corresponding to milankovitch precessional frequencies are not established owing possibly to low signal level and unknown short term deposition fluctuations the tuned densitometer series recovers few new periodic features although its inferred age depth relation correlates well with that of the carbonate series we calibrate the depth variable downcore to the orbital cycles to estimate r 5 0 0 15 m m y as the effective sedimentation rate

paleomagnetic constraints on the geodynamic history of the major blocks of china from the permian to the present paleomagnetic study of china and its environs has been the center of a major international effort for the last 10 years in this paper we critically review all available paleomagnetic poles of upper permian to tertiary age from the main blocks of china with the goal of placing constraints on models of the formation and the subsequent deformation of the region after selecting reliable poles by applying objective criteria we divide our analysis into first order motions of blocks and second order deformation within blocks for first order analysis apparent polar wander paths are constructed for the major blocks we discuss the compatibilities and contradictions between the geological and paleomagnetic records a sequence of paleogeographic configurations taking into account geological constraints but remaining within paleomagnetic uncertainties is presented in general the major blocks were probably in contact throughout the permian and triassic but the jurassic was the key age during which most of the movement toward china s present configuration took place our reconstructions include certain details which are suggested by the paleomagnetic record but whose geological signatures seem to have been hidden by subsequent events during the cretaceous chinese poles agree with poles from other continents transferred onto eurasia at the second order we observe that for almost each period with sufficient data the paleomagnetic poles are streaked along a small circle centered on the sampling region indicating that much of china has been affected by small 20 differential rotations this we interpret as deformation caused in part by the extrusion of the chinese blocks away from the indian collision the complete annotated list of poles is given as an appendix

timing of the permian triassic biotic crisis implications from new zircon u pb age data and their limitations abstract the most profound biotic crisis in the earth s history causing the near extinction of both terrestrial and marine life occurred at the end of the permian period about 253 myr ago and marks the paleozoic mesozoic era boundary the cause of this event is still a matter of vigorous debate with both brief and catastrophic as well as gradual mechanisms having been proposed similar to a recent landmark study this study uses the u pb method on zircons from the uppermost permian lowermost triassic ash fall deposits at meishan zhejiang province se china in order to examine time and rate constraints for these events the results of both this study and previous work show that for these ash layers the effects of pb loss are combined with varying amounts and sources of inheritance resulting in an age scatter which prohibits the extraction of a statistically robust age in many cases though the effects of pb loss on the zircons analyzed in this study were reduced by leaching the grains in hydrofluoric acid as opposed to commonly applied air abrasion prior to analysis the presence within a single ash layer of multiple generations of older xenocrysts in many cases only slightly older than the depositional age has made quantitative interpretation even more difficult when these combined phenomena bias individual zircon ages by less than a percent they are extremely difficult to deconvolute and if multi grain analyses are used can become impossible to recognize because of the resulting age averaging monte carlo simulations using actual measurements of individual zircon crystals show that age excursions due to pb loss and xenocrystic contamination for the meishan bentonites are easily homogenized to the point of undetectability when replicate analyses of multi grain zircon samples are compared thus this study uses only high precision analyses of single crystals whether from our work or that of previous studies three main conclusions have emerged first our data require a significant increase in the age of the permian triassic boundary by more than 2 myr compared to the previous study which shifts the age to a value older than 253 ma second neither our data nor those from previous work can confirm or negate the possibility of a very abrupt biotic crisis third even large suites of very high quality single zircon u pb analyses for these tuffs cannot in most cases yield objective reliable and robust dates with accuracies at the sub myr level though the temptation to perform arbitrary selection of subsets of the analyses for that purpose is almost irresistible the last conclusion is not an indictment of zircon u pb dating in general other rocks and other zircon populations can and do behave very differently and further technical advances will likely improve our ability to prepare grains or sub grains of adequately enhanced quality for analysis consequently the results of the present study strongly suggest that for problems requiring time scale accuracy inferences from zircon u pb dating must be based on sufficiently large suites of single crystal or crystal domain high precision analyses

evidence of astronomical forcing of the earth s climate in cretaceous and cambrian times abstract we have completed analyses of three sections of shallow marine sedimentary cycles that were deposited at about 80 ma and between about 510 ma and 530 ma in different parts of north america in spite of the antiquity of these strata and the differences in the age location and cycle types power spectra in all of the records have distinct spectral peaks with ratios that are consistent with forcing by eccentricity obliquity and climatic precession for two examples utah 530 ma and the southern canadian rockies 510 ma the spectra reveal prominent peaks corresponding to obliquity with a period closer to that estimated for early paleozoic time than for the modern these are the first results supporting recent calculations of changes in astronomical periods over geological time we were able to extract these intriguing results from rocks as old and as poorly dated as these only after applying a new method the gamma method which we have developed for scaling time in cyclic strata the results are evidence that astronomical forcing has left a robust signal in the geological record and that the astronomical periods observed in the geological data are consistent with recent calculations of the shifts in those periods over phanerozoic times

modeling 100 000 year climate fluctuations in pre pleistocene time series a number of pre pleistocene climate records exhibit significant fluctuations at the 100 000 year 100 ky eccentricity period before the time of such fluctuations in global ice volume the origin of these fluctuations has been obscure results reported here from a modeling study suggest that such a response can occur over low latitude land areas involved in monsoon fluctuations the twice yearly passage of the sun across the equator and the seasonal timing of perihelion interact to increase both 100 ky and 400 ky power in the modeled temperature field the magnitude of the temperature response is sufficiently large to leave an imprint on the geologic record and simulated fluctuations resemble those found in records of triassic lake levels

climate of the supercontinent pangea numerous climate models predict that the geography of the supercontinent pangea was conducive to the establishment of a megamonsoonal circulation in general geologic evidence supports the hypothesis of a megamonsoon that reached maximum strength in the triassic pangea in the late carboniferous had widespread peat formation in what is now central and eastern north america and europe and relatively dry conditions on the colorado plateau the equatorial region of the continent became drier through the end of the carboniferous by the permian the equatorial region of pangea was dry and indicators of aridity and rainfall seasonality became more widespread wind directions from colorado plateau eolian sandstones are consistent with an increasing influence of monsoonal circulation at this time in the triassic climate in the colorado plateau region became relatively wet though still seasonal and the few eolian sandstones indicate a major shift in wind direction at that time in addition sedimentation

time partitioning in cratonic carbonate rocks dissimilarity in relations between thickness duration and accumulation rate in holocene sections metre scale phanerozoic cycles and epoch interval phanerozoic sequences reflects variation in the distribution of depositional and hiatal time at different scales of observation modern accumulation rates are strongly dependent on duration of deposition lower rates correspond to longer durations phanerozoic cycle thicknesses are similar to those of holocene sections suggesting that both formed while filling similar amounts of accommodation space however accumulation rates of phanerozoic cycles and sequences are about two orders of magnitude less than in modern settings and they show neither strong dependence on duration of accumulation nor significant variation over phanerozoic time hence net accumulation is primarily controlled by regional subsidence rate these relations also allow for determination of that fraction of cycle period recorded as rock and that corresponding to hiatal time at intercycle boundaries depending on subsidence rate and amount of compaction most cratonic carbonate units accumulated over 3 to 30 of the time represented by sequences in which they occur

a test of the γ method for evaluating the periodicity of cyclical sediments abstract the method 1 uses thicknesses measured on facies in a set of cyclical sedimentary deposits to determine the facies effective accumulation rates and time intervals of accumulation to accomplish this the assumption is made that every cycle was accumulated over exactly the same interval of time the method has not been tested on a stratigraphic section where the correct answers were known a priori in particular the reliability of the method has not been determined when the assumption does not strictly hold the test constructed here begins with a synthetic time stratigraphic section of cyclical deposits and specified effective depositional rates for each facies generates a thickness section from these parameters and applies the method to the thickness section the method should recover the original time section and accumulation rates but it does not even when the coefficient of variation of the accumulation intervals is only 15

cycle symmetry and its causes cisco group virgilian and wolfcampian texas abstract 181 transgressive regressive cycles composed of nonmarine and marine carbonate and siliciclastic rocks of the cisco group on the eastern shelf texas display complex characteristics at both hemicycle and full cycle scales they are delineated on the basis of successive changes of depositional environments stratal boundary relations and stratigraphic position transgressive and regressive stratigraphic environment gradients are defined as the magnitude of environmental shift divided by thickness for each hemicycle they indicate the rates of lateral environmental shifts during transgression and regression cycle symmetry index is defined as the ratio between transgressive and regressive stratigraphic environment gradients it provides a measure of stratigraphic response to controlli g processes most cisco cycles are asymmetrical with steep transgressive and shallow regressive stratigraphic environment gradients indicating cyclic but asymmetrical variations of major allogenic processes over a cycle interval these systematic variations are delineated from climate sensitive rock types stratal thickness and sedimentary features the relative dominance of processes controlling accommodation i e glacio eustasy and basement subsidence versus those controlling sedimentation i e climate upland sediment yield and sediment supply at the depositional site determines cycle symmetry a formulated relation between cycle symmetry index i e stratigraphic response and rates of these processes demonstrates that transgressive sedimentation is controlled by sediment supply whe eas regressive sedimentation is controlled by accommodation this relation is potentially useful in quantitatively predicting stratigraphic responses to specific allogenic processes in cyclic sedimentation five cisco cycle types defined by the type of component lithofacies display the stratigraphic response mainly to noncyclic allogenic and autogenic processes the cycle types have varying magnitude thickness and symmetry they also vary in lateral extent and in abundance a process response model of cyclic sedimentation of the cisco group on the eastern shelf is established it emphasizes the interplay between autogenic and allogenic processes at the sub cycle scale understanding interactions among glacio eustasy climate shelf subsidence sediment supply and depositional dynamics during various stages of transgression and regression is central to a clearer comprehension of the observed variations in cycle characteristics

trace fossils and the aftermath of the permo triassic mass extinction evidence from northern italy abstract the duration of early triassic anoxia in the carbonate ramp settings of the werfen formation dolomites northern italy has been constrained using ichnofabric and sedimentological data this includes fine lamination and abundant pyrite framboids commonly reworked into lags by storm events the anoxic event spanned the entire griesbachian stage and extended from deep waters into extraordinarily shallow water settings evidence for oxygen deficiency can be found in mid and inner ramp facies the extent and duration of this event may at least partially explain the magnitude of the permo triassic mass extinction normal benthic conditions returned rapidly in the dienerian stage and pervasively bioturbated distal ramp facies testify to the ventilation of the deeper water areas of the region in post griesbachian times a post mass extinction radiation is not particularly well displayed in either trace fossil or body fossil diversity compilations from the dolomites moderate low levels of trace fossil diversity are maintained throughout the post griesbachian werfen formation whilst the body fossil data shows a moderate increase from the mid smithian stage there is thus a curious lag period spanning the dienerian to mid smithian when environmental conditions were apparently normal but the marine fauna failed to show any recovery

a model for atmospheric co 2 over phanerozoic time a new model has been constructed for calculating the level of atmospheric co sub 2 over phanerozoic time which is much simpler mathematically than the blag model but more complex geologically and biologically results suggest that there has been a notable pattern of varying atmospheric co sub 2 level over the past 570 my with high levels during the mesozoic and early paleozoic and low levels during the permo carboniferous and late cenozoic sensitivity analysis shows that within reasonable limits of the principal governing parameters this qualitative trend of varying co sub 2 is relatively insensitive to the actual values chosen for these parameters causes of the co sub 2 variation are multiple and no single geological or biological process can be called upon to explain all co sub 2 variation for all time the calculated trend of co sub 2 over time agrees well with independent estimations of paleoclimates thus the greenhouse theory of paleoclimate on a long geological time scale is supported by the results of the present study

turquoise trade of the ancestral puebloan chaco and beyond thousands of turquoise artifacts have been recovered from archaeological sites in chaco canyon and other ancestral puebloan formerly known as the anasazi sites across the san juan basin in northwestern new mexico suggesting that turquoise was an important commodity in these ancient trade networks although the well documented group of turquoise deposits in the cerrillos hill have been the main contender for the geological source of chacoan turquoise because they are the closest in proximity to the canyon recent studies show that turquoise was obtained through long distance trade networks that extended hundreds of kilometers to the west to investigate ancestral puebloan turquoise procurement strategies and trade networks we analyzed 74 turquoise artifacts from puebloan sites in the san juan basin and the virgin puebloan area in southern utah and the moapa valley in nevada by a technique we developed that identifies the geological source of turquoise artifacts using the isotope ratios of hydrogen and copper and a comparative database that contains the isotope fingerprints of 22 turquoise resource areas here we present geochemical evidence of multiple turquoise trade routes into chaco canyon linking turquoise from the san juan basin with deposits along the rio grande rift and resource areas in nevada and the mojave region of southeastern california by linking chacoan turquoise with the western turquoise resource areas our data supports the proposal that the virgin puebloan may have played an important role in the movement of turquoise shell and salt to the san juan basin our turquoise sourcing technique establishes the foundation for future turquoise provenance studies in additional regions beyond the american southwest including mexico south america china and persia the use of isotope ratios should be tested as unique discriminators for other complex minerals

milankovitch climatic signals in lower triassic olenekian peritidal carbonate successions nanpanjiang basin south china abstract meter scale peritidal carbonate strata from an isolated platform in the nanpanjiang basin of south china were tested for the presence of periodic or quasi periodic climatic signals these signals provide information on factors controlling cyclic sedimentation in the equatorial eastern tethys during the early triassic greenhouse period parasequences are composed of shallowing upward successions of subtidal facies including skeletal packstone and grainstone calcimicrobial boundstone and oolitic packstone and grainstone intertidal laminated lutite and ribbon rock and rare supratidal microbial laminite parasequence stacking patterns display three orders of cyclicity suggesting hierarchical stratigraphic relationships gamma analysis of kominz and bond earth planet sci lett 48 1990 233 244 was used to estimate facies dependent thickness time conversion factors i e s and to construct tuned and untuned time series for two stratigraphic sections spectra of these time series indicate the presence of quasi periodic signals with prominent short eccentricity 94 9 131 2 kyr short obliquity 35 8 kyr and long precessional index 21 2 kyr peaks and minor long eccentricity 412 9 kyr long obliquity 45 3 kyr short precessional index 17 7 kyr and constructional tone 9 7 kyr peaks when calibrated on the tuned spectra thus milankovitch climatic forcing probably greatly influenced sedimentation the calibration indicates that the subtidal facies has a sedimentation rate of 24 6 30 7 cm kyr and the intertidal supratidal facies has a rate of 2 7 6 0 cm kyr the estimated duration of deposition of the two sections is 1139 1423 kyr and corresponds to a stratigraphic completeness of 32 92 the completeness is much greater than that of icehouse stratigraphic records we speculate that variations in carbonate productivity and environmental conditions driven by milankovitch climatic forcing combined with low amplitude sea level fluctuations were likely major controls on cyclic sedimentation furthermore evolutional spectra of the two sections show that dominant milankovitch climatic forcings varied from short eccentricity obliquity to long precessional index during the course of sedimentation some spectral differences between the two sections suggest variations in depositional recording mechanisms of milankovitch climatic signals between platform interior and windward platform margin

high resolution upb dating of middle triassic volcaniclastics time scale calibration and verification of tuning parameters for carbonate sedimentation abstract we report high resolution single zircon u pb age data for middle triassic volcaniclastic intercalations in biostratigraphically calibrated pelagic successions of the southern alps the results require a redefinition of the chronometric scale for the middle triassic moreover they do not support current models relating cyclic sedimentation in platform carbonates of the dolomites to orbital tuning tight concordant age clusters were obtained for five volcaniclastic layers in three ammonoid biozones of late anisian to early ladinian age two layers in the nevadites secedensis zone yielded identical mean 206 pb 238 u ages of 241 2 0 8 0 8 ma and 241 2 0 8 0 6 ma errors given at the 95 confidence level a layer in the gredleri zone is dated at 238 8 0 5 0 2 ma and two horizons in the archelaus zone yield similar ages of 237 9 1 0 0 7 ma and 238 0 0 4 0 7 ma these results are significantly older than the age values of 233 235 ma assigned to the anisian ladinian boundary by several current time scales 1 4 moreover our estimate of 240 7 241 3 ma depending on biostratigraphic collocation for the anisian ladinian boundary casts doubts on the reliability of age values of 245 250 ma proposed by most time scales for the permian triassic boundary the occurrence of pelagic fossils in basinal sediments as well as in age equivalent shallow marine middle triassic platform carbonates in the dolomites allows the sedimentary sequences of both environments to be correlated the 800 m thick latemar platform western dolomites is characterized by cyclic stacking patterns which have been interpreted as results of milankovitch type high frequency low amplitude sea level fluctuations the 12 m y interval of platform growth postulated from the assignment of orbital periodicities to the platform carbonate cycles 5 6 is in conflict with a maximum time span of 4 7 m y allowed by the present zircon data

lower triassic large sea floor carbonate cements their origin and a mechanism for the prolonged biotic recovery from the end permian mass extinction precipitation of inorganic calcium carbonate is a common occurrence in both modern and ancient marine environments however synsedimentary growth of large 5 10 cm crystalline carbonate cements directly onto the sea floor has been thought to be limited to the proterozoic when seawaters were highly oversaturated with calcium carbonate compared to average phanerozoic values outer shelf to slope deposits of the lower triassic union wash formation in east central california deposited in oxygen restricted settings contain crystalline calcium carbonate cements that appear to have grown directly on the sea floor paleoenvironmental analyses indicate that these large calcium carbonate cements grew under conditions that were similar to those proposed for the precipitation of inorganic calcite in the black sea sulfate reduction of organic matter led to an increase in the amount of bicarbonate ion in deep waters and a concomitant increase in co 2 and alkalinity mixing with surface waters led to co 2 degassing and precipitation of cements from waters supersaturated with calcium carbonate the presence of these cements and associated facies thus provides evidence of harsh environmental conditions in the early triassic at the regional level which may have acted in concert with biotic effects of the end permian mass extinction as well as similar deleterious conditions e g shelf anoxia in other regions to produce a prolonged as well as temporally and geographically variable biotic recovery from this mass extinction