seepage beneath water retaining structures founded on spatially random soil the effect of stochastic soil permeability on confined seepage beneath water retaining structures has been studied random field concepts for the generation of soil permeability properties with a fixed mean standard deviation and spatial correlation structure have been combined with finite element methods to perform monte carlo simulations of the seepage problem analyses have been performed for a dam with two cut off walls the results of parametric studies to gauge the effect of the standard deviation and correlation structure of the permeability on the output statistics relating to seepage quantities exit gradients and uplift pressures are presented in all cases comparison is made with results that would be achieved on a deterministic basis flow rates and other quantities are shown to be affected significantly by the standard deviation and the correlation structure of soil permeability l article etudie l influence de la permeabilite d un sol stochastique sur l infiltration confinee existant sous

an experimental micromechanical study of sand grain contacts behavior from different geological environments abstract grain scale tests can provide useful information about geological materials interface properties and to understand the possible role of geological environments on their behavior this paper presents an experimental micromechanical study investigating the behavior of two quartz sands at the grain scale namely river sand and beach sand which are obtained from two different geological environments the results of the study are compared with leighton buzzard sand lbs quartz grains with the latter material being extensively examined in previous research works basic characterization of the grains is conducted in terms of chemical composition particle shape and roughness it was observed that the grains of the beach sand are relatively rougher and less rounded compared to the river sand grains a custom built new generation micromechanical apparatus was used to quantify the micromechanical behavior of the sand grains at their contacts from the two different materials it was observed that both materials showed a similar range of young s moduli which are obtained from hertzian fitting the river sand grains showed fairly steady state behavior during shearing which was not very obvious for the grains of the beach sand this different observation in steady state was attributed partly to grain morphology effects the stiffness degradation of both sands followed similar trends the average value of the inter particle coefficient of friction for river sand and beach sand grains are about 0 15 and 0 22 respectively whereas for lbs grains the inter particle coefficient of friction lies in between that of river sand and beach sand the high roughness and morphology of the beach sand grains are factors which have contributed to the observed trends and the differences between the variable types of sands

magnetic polarity stratigraphy of a plio pleistocene marine sequence of north island new zealand abstract thick sequences of relatively undisturbed plio pleistocene sediments in the wanganui basin north island new zealand consist of well exposed silts clayey silts sandstones rare limestones and several tephras oriented specimens were collected from a section more than 2500 m thick and palaeomagnetic measurements were made using a c demagnetisations in fields up to 35 mt with the aid of tephrochronology the age of the upper sequence is now well established and falls within the matuyama epoch the lower two thirds of the section except for the basal 500 m is predominantly normally magnetised and is interpreted as a very extended sequence of the gauss epoch the lowest 500 m then represents the gilbert epoch the plio pleistocene boundary as defined at vrica italy falls within the upper part of the section studied in the upper nukumaruan stage for the first time a reliable correlation is made with the international boundary using as intermediaries the palaeomagnetic and tephrostratigraphy of deep sea cores from the southwest pacific as a result of the high deposition rate of the order of 1 2 m ky and the apparent lack of unconformities the temporal resolution is high short lived magnetic events are detected especially in the lower matuyama and upper gauss epochs these generally correlate well with events reported from other extended sections

sedimentary pyrite formation an update sedimentary pyrite formation during early diagenesis is a major process for controlling the oxygen level of the atmosphere and the sulfate concentration in seawater over geologic time the amount of pyrite that may form in a sediment is limited by the rates of supply of decomposable organic matter dissolved sulfate and reactive detrital iron minerals organic matter appears to be the major control on pyrite formation in normal non euxinic terrigenous marine sediments where dissolved sulfate and iron minerals are abundant by contrast pyrite formation in non marine freshwater sediments is severely limited by low concentrations of sulfate and this characteristic can be used to distinguish ancient organic rich fresh water shales from marine shales under marine euxinic conditions sufficient h2s is produced that the dominant control on pyrite formation is the availability of reactive iron minerals calculations based on a sulfur isotope model indicate that over phanerozoic time the worldwide average organic carbon to pyrite sulfur ratio of sedimentary rocks has varied considerably high cs ratios during permo carboniferous time can be explained by a shift of major organic deposition from the oceans to the land which resulted in the formation of vast coal swamps at that time low cs ratios compared to today during the early paleozoic can be explained in terms of a greater abundance of euxinic basins combined with deposition of a more reactive type of organic matter in the remaining oxygenated portions of the ocean the latter could have been due to lower oceanic oxygen levels and or a lack of transportation of refractory terrestrial organic matter to the marine environment due to the absence of vascular land plants at that time

potbellies wasp waists and superparamagnetism in magnetic hysteresis because the response of a magnetic substance to an applied field depends strongly on the physical properties of the material much can be learned by monitoring that response through what is known as a magnetic hysteresis loop the measurements are rapid and quickly becoming part of the standard set of tools supporting paleomagnetic research yet the interpretation of hysteresis loops is not simple it has become apparent that although classic single domain pseudo single domain and multidomain loops described in textbooks occur in natural samples loops are frequently distorted having constricted middles wasp waisted loops or spreading middles and slouching shoulders potbellies such complicated loops are often interpreted in oversimplified ways leading to erroneous conclusions the physics of the problem have been understood for nearly half a century yet numerical simulations appropriate to geological materials are almost unavailable in this paper we discuss results of numerical simulations using the simplest of systems the single domain superparamagnetic sd sp system examination of the synthetic hysteresis loops leads to the following observations 1 wasp waisting and potbellies can easily be generated from populations of sd and sp grains 2 wasp waisting requires an sp contribution that saturates quickly resulting in a steep initial slope and potbellies require low initial slopes the sp contribution approaching saturation at higher fields the approach to saturation is dependent on volume hence the cube of grain diameter therefore there is a very strong dependence of hysteresis loop shape on the assumed threshold size 3 we were unable to generate potbellies using an sp sd threshold size as large as 30 nm and wasp waists cannot be generated using a threshold size as small as 8 nm the occurrence of both potbellies and wasp waists in natural samples is consistent with a room temperature threshold size of some 15 nm 5 4 simulations using a threshold size of 15 20 nm with populations dominated by sp grain sizes that is with a small number of sd grains produce synthetic hysteresis loops consistent with measured hysteresis loops and transmission electron microscopic observations from submarine basaltic glass 5 simulations and measurements using two populations with distinct coercivity spectra can also generate wasp waisted loops a relatively straightforward analysis of the resulting loops can distinguish the latter case from wasp waisting resulting from sp sd behavior

experiments on piping in sandy gravels tests on internally unstable sandy gravels show that a significant proportion of the sand content is washed out by piping at hydraulic gradients far lower than the critical gradient given by a classical theory the probable explanation is that a major part of the overburden load is carried on a framework of gravel particles leaving the sand under relatively small pressures by contrast piping of the sand from stable sandy gravels occurs at approximately the full theoretical gradient the tests broadly confirm kenney s criterion for the internal stability of granular materials des essais realises sur des graves sableuses a instabilite interne importante montrent qu une proportion non negligeable du sable est lessivee pour des gradients hydrauliques bien inferieurs au gradient critique donne par les theories classiques l explication la plus probable est que la majeure partie de la surcharge des couches subjacentes est transmise au reseau des particules graveleuses le sable n etant alors plus soumis qu

source of stable remanence in chromite ores rock magnetic investigations of both the natural chromite ores and their purified chromite concentrate mg 6fe 4cr1 4al 6o4 were carried out these include measurement of natural and saturation remanent magnetism and their stability with respect to alternating field and thermal demagnetisation irm acquisition studies saturation magnetisation versus temperature studies and high field 1000 mt hysteresis characteristics from these studies it was observed that the medium high coercivity component of remanence is associated with the chromite minerals and is carried largely or entirely by them therefore it is concluded that chromites carry permanent magnetisation of palaeomagnetic significance however this result is in sharp contrast to the assumption in the literature that the spinels of the above composition are non magnetic the study has also demonstrated that the magnetic properties of artificial fe cr spinels do not conform to their natural analogues reasons for the discrepancy have been postulated

rates of weathering rind formation on costa rican basalt weathering rind thicknesses were measured on 200 basaltic clasts collected from three regionally extensive alluvial fill terraces qt 1 qt 2 and qt 3 preserved along the pacific coast of costa rica mass balance calculations suggest that conversion of unweathered basaltic core minerals plagioclase and augite to authigenic minerals in the porous rind kaolinite allophane gibbsite fe oxyhydroxides is iso volumetric and ti and zr are relatively immobile the hierarchy of cation mobility ca na k mg si al fe p is similar to other tropical weathering profiles and is indicative of differential rates of mineral weathering anorthite albite hypersthene orthoclase apatite alteration profiles across the cm thick rinds document dissolution of plagioclase and augite and the growth of kaolinite with subsequent dissolution of kaolinite and precipitation of gibbsite as weathering rinds age the rate of weathering rind advance is evaluated using a diffusion limited model which predicts a parabolic rate law for weathering rind thickness rr as a function of time t rr t and an interface limited model which predicts a linear rate law for weathering rind thickness as a function of time rr kappt in these rate laws is a diffusion parameter and kapp is an apparent rate constant the rate of advance is best fit by the interface model terrace exposures are confined to the lower reaches of streams draining the pacific slope near the coast where the stream gradient is less than 3 m km and terrace deposition is influenced by eustatic sea level fluctuations geomorphological evidence is consistent with terrace deposition coincident with sea level maxima when the stream gradient would be lowest assigning the most weathered regionally extensive terrace qt 1 mean rind thickness 6 9 0 6cm to oxygen isotope stage ois 7 ca 240 ka and assuming that at time 0 rind thickness 0 it is inferred that terrace qt 2 rr 2 9 0 1 cm is coincident with stage 5e ca 125 ka and that qt 3 rr 0 9 0 1 cm is consistent with ois 3 ca 37 ka these assignments yield a value of kapp of 8 6 10 13 cm s 1 r 2 0 99 only this value satisfies both the existing age controls and yields ages coincident with sea level maxima using this value elemental weathering release fluxes across a weathering rind from qt 2 range from 6 0 10 9 mol si m 2 s 1 to 2 5 10 11 mol km 2 s 1 the rate of rind advance for the costa rican terraces is 2 8 10 7 my r 1 basalt rind formation rates in lower temperature settings described in the literature are also consistent with interface controlled weathering with an apparent activation energy of about 50 kj mol 1 rates of rind formation in costa rica are an order of magnitude slower than reported for global averages of soil formation rates copyright 2004 elsevier ltd

scale issues in weathering studies a review of the major scale issues in weathering studies reveals concerns over the fundamental spatio temporal distributions of weathering phenomena as well as issues of upscaling microscope based observations and linking different scales of observations in explanations of landform development various strategies are proposed which can be used to tackle these issues many rooted in non linear dynamical systems ideas as an initial step spatio temporal scale distributions are estimated here for weathering processes landforms and controls based on a range of empirical data two case studies of phytokarst in grand cayman and blistering and scaling of building stones are presented to illustrate the types of data that might be used to establish more convincing scale linkages in weathering investigations

origin of the torlesse terrane and coeval rocks south island new zealand the carboniferous to lower cretaceous torlesse terrane and haast schist derivatives constitute the major part of the complexly deformed facies of the eastern province of new zealand strata consist mainly of quartzofeldspathic graywacke and mudstone intercalated with minor but widely distributed conglomerate and volcanics with associated chert and limestone clastic rocks were deposited largely by sediment gravity flow mechanisms in a deep marine environment also present are a few highly fossiliferous shallow marine and terrestrial deposits of limited areal extent which rest unconformably on or in fault contact with torlesse flysch several periods of deformation are recognized and melange is present on both local and regional scales metamorphism ranges from zeolite to greenschist facies the bulk of the rocks fall into five areally extensive and mutually exclusive fossil zones of the following ages permian atomodesma middle triassic early late triassic torlessia late triassic monotis and late jurassic early cretaceous contacts between major fossil zones are mainly tectonic petrographic analysis permits subdivision of torlesse sandstones into five major petrofacies that correspond in age to the five major fossil zones the sandstone petrofacies mainly arkosic together with the composition of conglomerate clasts mainly indurated torlesse rocks indicate that the source terrane was a continental volcano plutonic arc probably part of gondwanaland coupled with autocannibalistic reworking of older uplifted torlesse rocks in contrast to the quartzofeldspathic nature of the torlesse coeval sedimentary rocks of the eastern province are volcanogenic they are thought to represent related forearc basin maitai murihiku terranes and trench complex caples terrane deposits derived from a volcanic island arc brook street terrane three petrofacies are established for maitai murihiku and caples sandstones the petrofacies indicate a common evolving immature to submature volcanic island arc source for these terranes a reconstruction of new zealand s eastern and western provinces is proposed in permian and triassic times the torlesse was deposited in trench slope or borderland basins along a trench transform margin fronting a continental volcano plutonic arc source western province gondwanaland deposition was spasmodic but voluminous and was accompanied by concurrent deformation and accretion resulting in parallel belts of torlesse rock younging outward from the gondwanaland margin at the same time the brook street terrane volcanic arc and associated terranes were forming to the west of the torlesse site separated from gondwanaland by a marginal sea in latest triassic or early jurassic times the torlesse was rafted into the volcanic arc system via transform faulting approximately parallel to the gondwana margin the collision event resulted in tectonic thickening of torlesse and caples rocks at the plate interface and metamorphism to haast schist the source was then dominated by older partly metamorphosed torlesse terrane newly uplifted along the collision front closing of the marginal sea behind the brook street terrane in late jurassic early cretaceous times resulted in juxtapositioning with the western province gondwanaland along the median tectonic line

a new zealand late miocene magnetostratigraphy glacioeustatic and biostratigraphic correlations magnetostratigraphy is described for a sequence of predominantly hemipelagic marine mudstone 2200 m thick representing the late miocene and earliest pliocene from the mangapoike river section eastern north island new zealand together with the early pliocene magnetostratigraphy previously described from mangapoike it now provides a 3000 m thick magnetostratigraphic reference section for new zealand ranging in age from 10 5 ma to 3 5 ma thirteen magnetozones are recognised in the 2200 m described here and all but the highest are confidently correlated with the polarity timescale from the base of chron 11 to chron 7 correlation of the highest normal magnetozone to the timescale is ambiguous and two possible interpretations are presented both of which imply a previously unrecognised latest miocene unconformity the inferred unconformity is supported by biostratigraphy it is shown that the integration of biostratigraphy lithostratigraphy and magnetostratigraphy can discern diastems of the order of 104 years magnetostratigraphy and 13c data also indicates a diastem between 6 30 ma to 5 41 ma at the miocene pliocene angular unconformity at mangapoike these two unconformities and a distinct lithological change at the base of the late miocene are synchronous with deep sea benthic 18o records and unconformities expected from postulated eustatic sea level changes a coherent correlation model for new zealand on shore magnetostratigraphic biostratigraphic and isotopic data conflicts with the two magnetostratigraphic interpretations proposed for dsdp site 594 150 km east of new zealand both of which are probably incorrect

determining mineral weathering rates based on solid and solute weathering gradients and velocities application to biotite weathering in saprolites abstract chemical weathering gradients are defined by the changes in the measured elemental concentrations in solids and pore waters with depth in soils and regoliths an increase in the mineral weathering rate increases the change in these concentrations with depth while increases in the weathering velocity decrease the change the solid state weathering velocity is the rate at which the weathering front propagates through the regolith and the solute weathering velocity is equivalent to the rate of pore water infiltration these relationships provide a unifying approach to calculating both solid and solute weathering rates from the respective ratios of the weathering velocities and gradients contemporary weathering rates based on solute residence times can be directly compared to long term past weathering based on changes in regolith composition both rates incorporate identical parameters describing mineral abundance stoichiometry and surface area weathering gradients were used to calculate biotite weathering rates in saprolitic regoliths in the piedmont of northern georgia usa and in luquillo mountains of puerto rico solid state weathering gradients for mg and k at panola produced reaction rates of 3 to 6 10 17 mol m 2 s 1 for biotite faster weathering rates of 1 8 to 3 6 10 16 mol m 2 s 1 are calculated based on mg and k pore water gradients in the rio icacos regolith the relative rates are in agreement with a warmer and wetter tropical climate in puerto rico both natural rates are three to six orders of magnitude slower than reported experimental rates of biotite weathering

chemical weathering in a tropical watershed luquillo mountains puerto rico ii rate and mechanism of biotite weathering abstract samples of soil saprolite bedrock and porewater from a lower montane wet forest the luquillo experimental forest lef in puerto rico were studied to investigate the rates and mechanisms of biotite weathering the soil profile at the top of a ridge in the rio icacos watershed consists of a 50 100 cm thick layer of unstructured soil above a 600 800 cm thick saprolite developed on quartz diorite the only minerals present in significant concentration within the soil and saprolite are biotite quartz kaolinite and iron oxides biotite is the only primary silicate releasing significant k and mg to porewaters although biotite in samples of the quartz diorite bedrock is extensively chloritized chlorite is almost entirely absent in the saprolite phyllosilicates phyllosilicate grains are present as 200 1000 m wide books below about 50 cm depth x ray diffraction xrd and electron microprobe analyses indicate that the phyllosilicate grains contain a core of biotite surrounded by variable amounts of kaolinite lattice fringe images under transmission electron microscope tem show single layers of biotite altering to two layers of kaolinite suggesting dissolution of biotite and precipitation of kaolinite at discrete boundaries some single 14 a layers are also observed in the biotite under tem the degree of kaolinitization of individual phyllosilicate grains as observed by tem decreases with depth in the saprolite this tem work is the first such microstructural evidence of epitaxial growth of kaolinite onto biotite during alteration in low temperature environments the rate of release of mg in the profile calculated as a flux through the soil normalized per watershed land area is approximately 500 mol hectare 1 yr 1 1 6 10 9 molmg msoil 2 s 1 this rate is similar to the flux estimated from mg discharge out the rio icacos 1000 mol hectare 1 yr 1 or 3 5 10 9 molmg msoil 2 s 1 indicating that scaling up from the soil to the watershed is possible for mg release the rate of mg release from biotite normalized to brunauer emmett teller bet surface area is calculated using a mass balance equation which includes the density and volume of phyllosilicate grains porewater chemistry and flux and soil porosity the mean rates of biotite weathering calculated from k and mg release rates are approximately 6 and 11 10 16 molbiotite mbiotite 2 s 1 respectively significantly slower than laboratory rates 10 12 to 10 11 molbiotite mbiotite 2 s 1 the discrepancy in scaling down from the soil to the laboratory is probably explained by 1 differences in weathering mechanism between the two environments 2 higher solute concentrations in soil porewaters 3 loss of reactive surface area of biotite in the saprolite due to kaolinite and iron oxide coatings and or 4 unaccounted for heterogeneities in flow path through the soil

geochemical and sedimentological control of the magnetic properties of hemipelagic sediments owing to their high sedimentation rates and wide areal extent hemipelagic sediments along continental borderlands are potentially important high resolution recorders of geomagnetic secular variation to assess this possibility we studied suboxic hemipelagic muds from the oregon continental slope and anoxic laminated diatomaceous oozes from the gulf of california these sediments were rapidly deposited with average sedimentation rates of 121 and 135 cm kyr respectively bulk sediment sedimentological and geochemical analyses indicate that the two areas represent contrasting depositional regimes the remanence in both environments resides in fine grained magnetite particles although minor amounts of hematite were observed in the topmost gulf of california sediments despite first order differences the sediments from both areas show similar downcore patterns of systematic increases in solid sulfur mainly as pyrite dramatic decreases in natural nrm anhysteretic and isothermal remanent magnetization intensities and accompanying shifts in the magnetic stabilities these changes are consistent with reduction and dissolution of the ferrimagnetic iron oxides with depth due to early diagenesis of organic matter the magnetic grain size distribution first appears to rapidly coarsen downcore as the smallest and most abundant grains are removed then slowly grows finer as the remaining particles dissolve no evidence was observed for authigenic formation of magnetite provided sufficient concentration and stability of the detrital magnetic particles paleomagnetic directions can survive this dissolution diagenesis however relative paleointensity determinations based on normalization of nrm by concentration in related parameters will give erroneous estimates of paleofield behavior in such diagenetically altered sediments

large tectonic rotation of part of new zealand in the last 5 ma abstract detailed paleomagnetic data from the wairoa syncline a middle miocene to the present forearc basin on the east coast of the north island new zealand show that the rate of clockwise rotation for the last 5 ma has been 7 8 ma of which less than 1 5 ma can be explained by apparent polar wander due to motion of the australian or pacific plates this rotation is similar to a present day rate of 7 ma determined from geodetic data between 5 and 20 ma ago the rate of tectonic rotation is poorly determined and may be between 0 and 2 ma the change in the rate of rotation of the wairoa syncline around 5 ma is probably related to a markedly different tectonic style in the new zealand region within the last 5 ma associated with a change in position of the euler poles of rotation for the pacific australian plates

fossil bacterial magnetite in deep sea sediments from the south atlantic ocean the magnetostratigraphy of deep sea sediment cores has proven to be a powerful and high resolution method of dating and comparing sedimentary records in contrast to this widespread application relatively few attempts have been made to analyse and identify the mineralogy grain size and origin of the carrier of the remanent magnetization1 2 it is widely assumed that dominant ferrimagnetic minerals in deep sea sediments are of lithogenic origin that is that they derive from oceanic or continental detritus volcanic ashfalls micrometeorites hydrothermal precipitation or chemical mineralization processes a very different view was taken by kirschvink and lowenstam3 who suggested that fossil remnants of magnetite mineralizing organisms in particular magnetotactic bacteria might play an important part in the magnetization of sediments deposited in certain detritus poor aquatic systems we have used rock magnetic diagnostic methods to characterize the magnetic phases in deep sea sediments from the south atlantic these phases were then extracted and studied with the electron microscope our results indicate that fossil bacterial magnetite is the main carrier of the natural remanent magnetization in sediments ranging in age from quarternary to eocene different types of bacterial magnetosomes were detected most of them occurring in chains of identical particles and nearly all of them falling into the theoretically determined4 size range of single domain magnetitite

diagenesis in anoxic sediments from the california continental borderland and its influence on iron sulfur and magnetite behavior solid phase and pore water profiles of compounds containing iron and sulfur have been determined by wet chemical magnetic and x ray diffraction techniques in three california continental borderland basins the observed profiles have been fit by simple reaction diffusion models in order to determine reaction rates and constrain budgets for iron and sulfur more than 95 of the solid phase reduced sulfur is pyrite and down core profiles are well fit by a model in which net sulfate reduction rates decrease exponentially with depth net sulfate reduction rates determined from models fit to solid phase reduced sulfur measurements and pore water sulfate profiles yield results that are consistent depth integrated sulfate reduction rates for modern sediments in san pedro santa catalina and san nicolas basins are 11 4 6 3 and 6 3 8 8 mol cm 2yr 1 respectively measurements of solid phase iron species indicate that surficial sediments are enriched in easily reducible ferric oxyhydroxides the enrichment is maintained by a combination of oxidation of fe2 diffusing upward from underlying anoxic sediments as well as input of fresh sediment enriched in ferric oxyhydroxides the three primary sources for iron converted to pyrite and the sequence in which they are utilized are ferric oxyhydroxides magnetite and other crystalline oxides and exchangeable iron in phyllosilicates the majority 50 80 of the iron converted to pyrite is from the silicates and budgetary calculations indicate the amount of iron released from san pedro basin silicates agrees within 35 with the amount of magnesium removed from pore water to solid phases fe2 is enriched in near surface pore waters because rates of dissolved iron production by oxyhydroxide reduction exceed rates of sulfate reduction and pyrite formation at depth pore waters are sulfidic because rates of sulfate reduction exceed rates of iron release from silicates sulfide produced at depth diffuses upward until it reaches sediments with available iron causing a step like increase in solid phase sulfur concentration over 90 of the magnetite present in surficial sediments is dissolved at depth due to reaction with h2s a model is developed to predict the depth at which magnetite dissolution should occur based on sulfate reduction rates and the flux of ferric oxyhydroxides the results of this model predict the onset of dissolution at depths of 5 40 cm in different basins and agree well with the observed depths of magnetite dissolution

pleistocene unconformity bounded shelf sequences wanganui basin new zealand correlated with global isotope record abstract eleven successive unconformity bound sequences in the castlecliff section wanganui basin each typically composed of a lower variably conglomeratic 0 1 2 m thick shell bed and an upper 5 20 m thick barren siltstone are identified in the stratotype of the local new zealand middle pleistocene castlecliffian stage based on magnetostratigraphy the section is correlated with the published benthonic oxygen isotope curve for dsdp core 552a from the north atlantic each of the sequences accumulated during one of the odd numbered interglacial isotope stages in the interval 31 to 11 inclusive the unconformities developed during intervening glacial ages when the shelf was exposed through glacio eustatic lowering the correlation provides a geochronologic framework for assessment of the eustatic contribution to the generation of the sequences in a situation where the paleoshorelines and related shelf sequences are preserved and for which an independent approximation of the sea level history is available in the form of an oxygen isotope curve

multiscale modeling of flood induced piping in river levees a three dimensional transient fully coupled fluid particle model is utilized to simulate flood induced piping under river levees and taking into account the effects of soil fluid structure interactions the porous soil medium is modeled as a mixture of two phases namely the fluid phase water and the particulate solid phase the fluid is idealized as a continuum by using an averaged form of navier stokes equations that accounts for the presence of the solid particles these particles are modeled at a microscale using the discrete element method the interphase momentum transfer is modeled using an established relationship that accounts for the dynamic change in porosity and possible occurrence of nonlinear losses the hydraulic structure levee is modeled as an impervious rigid block and its motion is described by a combination of external and internal forces from the surrounding fluid and solid particles a computational simulation is conducted to investigate the response of a granular deposit when su

magnetostratigraphic chronology of late miocene to early pliocene biostratigraphic and oceanographic events in new zealand successions of uplifted shallow marine sediments in new zealand were among the first to provide evidence of latest miocene climatic deterioration and were also among the first onshore successions where late miocene to early pliocene magnetostratigraphic records were established a revised chronology of late miocene to early pliocene events has been determined from new magnetostratiigraphic results from two important successions at blind river and upton brook south island new zealand lat 41 45 s long 174 05 e magnetostratigraphic results from upton brook are the fast from strata containing the kapitean index mollusks and provide the first reliable estimate of the age of the tongaporutuan kapitean boundary a coherent chronology from blind river and upton brook indicates that two synchronous low sea level and cool paleoclimatic events occurred in the late miocene kapitean stage this inference is supported from other well known coeval successions in the new zealand region the revised new zealand chronology supports recent determinations from the mediterranean that indicate a two stage messinian salinity crisis and a 5 2 ma age for the miocene pliocene boundary data from new zealand the mediterranean and ocean cores around the world suggest that these latest miocene events are related to glacio eustatic sea level fluctuations a 6 05 ma age for the first occurrence datum of globorotalia conomiozea indicates that significant diachroneity exists in the placement of this datum between the southwest pacific and the mediterranean confirming the observation that g conomiazea is unsuitable for correlation between ocean basins

magnetite dissolution diachronous greigite formation and secondary magnetizations from pyrite oxidation unravelling complex magnetizations in neogene marine sediments from new zealand detailed rock magnetic and electron microscope analyses indicate that the magnetic signature of neogene marine sediments from the east coast of new zealand is dominated by the authigenic iron sulphide greigite the greigite is present as a mixed population of stable single domain and superparamagnetic grains which is consistent with authigenic growth from solution this growth can result from pyritization reactions soon after deposition which also leads to dissolution of most detrital magnetite however where constrained by field tests our data suggest that remanence acquisition can occur 1 myr after deposition and can vary in timing at the outcrop scale strong viscous overprints result from oxidation of the iron sulphides probably during percolation of oxic ground water this process can sometimes destroy any ancient remanent magnetization this complex magnetic behaviour particularly the presence of late forming magnetizations carried by greigite means that the remanence in new zealand cenozoic sediments and in similar sediments elsewhere cannot be assumed to be primary without confirmation by field tests the reversals test should be employed with caution in such sediments as patchy remagnetizations can lead to false polarity stratigraphies

ferrimagnetic cr and mn spinels in sediments residual magnetic minerals after diagenetic dissolution ferrimagnetic cr fe and mn fe spinels are the dominant remanence carrying phases in the late triassic lunde formation these have largely been identified by magnetic mineral extraction from the sediments combined with microscopy the extensive removal of most of the originally deposited magnetic fe ti oxides during diagenesis has left the cr fe and mn fe spinels as a mineral residue which is resistant to dissolution the rock magnetic signature of these minerals is not sufficiently known to be able to identify these minerals on the basis of their magnetic properties alone

magnetic mineral diagenesis abstract reduction oxidation redox reactions occur during burial because sediments contain reactive mixtures of oxidised and reduced components diagenetic chemical reactions represent the approach of all sedimentary components toward equilibrium and control the long term stability of sedimentary iron bearing minerals magnetic minerals are sensitive indicators of sedimentary redox conditions and of changes in these conditions through time with diagenetic effects ranging from subtle to pervasive despite the importance of magnetic mineral diagenesis in paleomagnetism rock magnetism and environmental magnetism and the usefulness of these subjects in the earth and environmental sciences there is no systematic single published treatment of magnetic mineral diagenesis this paper is an attempt to provide such a treatment for the full range of diagenetic environments magnetic mineral diagenesis during early burial is driven largely by chemical changes associated with organic matter degradation in a succession of environments that range from oxic to nitrogenous to manganiferous to ferruginous to sulphidic to methanic where the free energy yielded by different oxidants decreases progressively in each environment in oxic environments the most important diagenetic processes involve surface oxidation of detrital minerals and precipitation of fe3 bearing minerals from solution in ferruginous environments the most reactive detrital and authigenic iron oxides undergo dissolution often mediated by dissimilatory iron reducing bacteria which releases fe2 that becomes available for other reactions the fe2 in solution can diffuse upward where it is oxidised to form new authigenic iron oxyhydr oxide minerals or it can become bioavailable to enable magnetotactic bacteria to biomineralise magnetite generally at the base of the overlying nitrogenous zone alternatively dissimilatory iron reducing bacteria can produce extracellular magnetite within ferruginous environments in sulphidic environments iron bearing detrital mineral assemblages undergo more radical alteration hydrogen sulphide which is a byproduct of bacterial sulphate reduction or of anaerobic oxidation of methane reacts with the fe2 released from iron mineral dissolution or directly with solid iron oxyhydr oxide minerals to form iron sulphide minerals mackinawite greigite and pyrite authigenic growth of ferrimagnetic greigite has important implications for paleomagnetic recording secondary iron sulphide formation can also occur as a result of anaerobic oxidation of methane methane migration through sediments in association with biogenic or thermogenic methane production or in association with gas hydrate dissociation can disrupt the diagenetic steady state and give rise to greigite and monoclinic pyrrhotite formation that remagnetises sediments most of the above described diagenetic processes occur below 50 c with continuing burial above 50 c but at sub metamorphic temperatures magnetic minerals can undergo further thermally induced chemical changes that give rise to a wide range of mineralogical transformations that affect the magnetic record of the host sediment these changes include remagnetisations magnetic analysis can provide much valuable information concerning diagenesis in environmental processes the range of processes discussed in this paper should assist researchers in analysing sediment magnetic properties for which the assessment of diagenetic effects has become a necessary component

constitutive mass balance relations between chemical composition volume density porosity and strain in metasomatic hydrochemical systems results on weathering and pedogenesis relations characterizing the chemical physical and mechanical changes resulting from metasomatic hydrochemical processes are developed using mass balance models which formally link chemical composition to bulk density mineral density volumetric properties porosity and amount of deformation strain rigorous analysis of aqueous solute transport effects is then made possible in a variety of porous media flow environments including chemical weathering pedogenesis soil formation diagenesis ore deposition and enrichment and metamorphism application of these linear constitutive relations to chemical weathering profiles shows that immobile and locally mobile chemical elements with masses conserved on the scale of soil profiles can be accurately identified from analysis of appropriate data arrays and then used as natural geochemical tracers to infer the nature and extent of hydrochemical weathering processes and volume changes during pedogenesis assumptions commonly made in the past about the supposed immobility of certain elements e g ti and zr become unnecessary quantitative differentiation between the effects of residual and supergene fractionation is then easily made these methods are applied to ni rich laterites developed by weathering of ultramafic rocks showing that during ordinary residual enrichment ni is concentrated by as much as 4 protolith peridotite concentrations this occurs simply by silicate mineral dissolution and removal of chemical elements other than ni e g mg with a corresponding reduction in saprolite density and increase in bulk porosity without significant deformation in contrast laterites with mineable concentrations of ni which are similarly undeformed such as the nickel mountain mine in riddle oregon have experienced in addition to residual enrichment strong supergene enrichment by fractionation of ore elements between a leached zone from which ni is extracted and a complementary enriched zone positioned farther along the direction of ground water flow soil forming processes in podzol chronosequences developed on sandy beach terraces of the mendocino coast of california involved soil column collapse of 60 percent by dissolution of silicate minerals in the albic horizon of al and fe leaching and 70 percent dilation expansion in the overlying organic rich layer by root growth the amount of erosion based upon paleosurface reconstructions using the excess mass of fe al pb ga and cu in the zone of supergene enrichment spodic horizon below the ground water table indicates that subsurface erosion by dissolutional collapse is three times that of surficial erosion finally using published chemical data for ti zr and cr on major bauxite deposits in australia where erosion rates are thought to be low we infer that there may have been major amounts of dissolutional collapse to explain the upwards increase of detrital zircon and rutile in weathering profiles

magnetite diagenesis in marine sediments from the oregon continental margin the magnetochemistry of sediments from the oregon continental margin is examined to determine the effects of iron sulfur diagenesis on the paleomagnetic record magnetic mineral dissolution and transformation into iron sulfides are a common feature in these suboxic to anoxic lutites these processes are evidenced in rapid decreases in natural remanent magnetization intensities and stabilities systematic changes in other rock magnetic properties and increases in solid phase sulfur concentrations with depth hysteresis measurements are used to evaluate downcore changes in magnetite concentration and grain size magnetite abundances decrease downcore from initial values of about 0 1 and nominal grain diameters lie within a narrow pseudosingle domain range of 0 08 to 0 6 m a first order surface area reaction model da dt ka is proposed to explain the magnetite dissolution mechanism where a is the total magnetite surface area and k is the rate constant the solution of this equation predicts that the surface area and concentration decrease exponentially and the concentration in addition depends on grain size application of this model in two cores where grain size varies with depth successfully explains the downcore profiles of both concentration and surface area despite extensive magnetite destruction magnetic directions in such sediments appear to reliably record long wavelength trends of the geomagnetic field

erosion of deccan traps determined by river geochemistry impact on the global climate and the 87sr 86sr ratio of seawater abstract the impact of the deccan traps on chemical weathering and atmospheric co2 consumption on earth is evaluated based on the study of major elements strontium and 87sr 86sr isotopic ratios of the main rivers flowing through the traps using a numerical model which describes the coupled evolution of the chemical cycles of carbon alkalinity and strontium and allows one to compute the variations in atmospheric pco2 mean global temperature and the 87sr 86sr isotopic ratio of seawater in response to deccan trap emplacement the results suggest that the rate of chemical weathering of deccan traps 21 63 t km2 yr and associated atmospheric co2 consumption 0 58 2 54 106 mol c km2 yr are relatively high compared to those linked to other basaltic regions our results on the deccan and available data from other basaltic regions show that runoff and temperature are the two main parameters which control the rate of co2 consumption during weathering of basalts according to the relationship f r f c 0 exp ea r 1 t 1 298 where f is the specific co2 consumption rate mol km2 yr rf is runoff mm yr c0 is a constant 1764 mol l ea represents an apparent activation energy for basalt weathering with a value of 42 3 kj mol determined in the present study r is the gas constant and t is the absolute temperature k modelling results show that emplacement and weathering of deccan traps basalts played an important role in the geochemical cycles of carbon and strontium in particular the traps led to a change in weathering rate of both carbonates and silicates in carbonate deposition on seafloor in sr isotopic composition of the riverine flux and hence a change in marine sr isotopic composition as a result deccan traps emplacement was responsible for a strong increase of atmospheric pco2 by 1050 ppmv followed by a new steady state pco2 lower than that in pre deccan times by 57 ppmv implying that pre industrial atmospheric pco2 would have been 20 higher in the absence of deccan basalts pco2 evolution was accompanied by a rapid warming of 4 c followed after 1 myr by a global cooling of 0 55 c during the warming phase continental silicate weathering is increased globally since weathering of continental silicate rocks provides radiogenic sr to the ocean the model predicts a peak in the 87sr 86sr ratio of seawater following the deccan traps emplacement the amplitude and duration of this spike in the sr isotopic signal are comparable to those observed at the cretaceous tertiary boundary the results of this study demonstrate the important control exerted by the emplacement and weathering of large basaltic provinces on the geochemical and climatic changes on earth

temporal trends of magnetic dissolution in the pelagic realm gauging paleoproductivity abstract magnetic hysteresis data from the western equatorial pacific suggest that the preservation of magnetic remanence in pelagic carbonates is controlled by paleoproductivity hysteresis excursions 100 k y intervals are linked here to greater magnetic dissolution associated with increased glacial organic carbon supply changes in the redox boundary coupled to glacial terminations result in anomalous magnetic features which are preserved in the sedimentary record these high frequency variations are superimposed on a longer term signal of magnetic dissolution which may reflect decreased productivity since the miocene

the effect of land plants on weathering rates of silicate minerals abstract land plants and their associated microbiota directly affect silicate mineral weathering in several ways by generation of chelating ligands by modifying ph through production of co2 or organic acids and by altering the physical properties of a soil particularly the exposed surface areas of minerals and the residence time of water in laboratory experiments far from equilibrium 1 mm oxalate a strong chelator of al has a negligible effect on the dissolution rate of alkali feldspars but some effect on calcic feldspars and olivine by analogy to oxalate the overall effect of organic ligands on the weathering rate of silicate minerals in nature is likely to be small except perhaps in microenvironments adjacent to roots and fungal hyphae the effect of ph on silicate mineral dissolution rate depends on ph below ph 4 5 the rate increases with decreasing ph in the circumneutral region the rate is ph independent and at ph values above around 8 the rate increases with increasing ph vegetation should thus cause an increase in weathering rate through the ph effect only where the ph is below 4 5 as an overall generalization the effect of plants on weathering rate through changes in soil solution chemistry is probably small for granitic rocks it may be greater for more mafic rocks it is the release of ca and mg from mafic rocks that has the greatest influence on the global co2 budget the effect of changes in soil physical properties on weathering rate can be major by binding fine particles plants can greatly increase weathering rates in areas of high physical erosion where erosion rates are lower the effect of plants is less clear on long timescales plants may decrease chemical weathering by binding secondary products and isolating unweathered minerals from meteoric water a major unknown in estimating the effect of the advent of land plants on weathering rates is the nature thickness particle size distribution permeability of the regolith on the pre silurian continents the indirect effect of vegetation through changing the regional distribution of precipitation may be as important as the direct effects

kinetics of weathering and diagenesis weathering and diagenesis are discussed from a kinetic standpoint such a discussion depends upon an intimate interplay between field measurements laboratory experiments and mathematical theory because of the accessibility of soils and sediments models based on laboratory measurements and theoretical calculations can be used along with field data to calculate rate parameters which are otherwise difficult to measure in the laboratory also theoretical models can be tested in the field ways in which chemical kinetics can be applied to geological problems in the surficial environment are discussed and the author recomends extensive future study of such problems jmt

determination of critical head in soil piping one of the main mechanisms of failure of levees is a phenomenon called piping which generally begins with the formation of a sand boil at the leeward side of the levee and has been frequently observed to proceed upstream along the base of the levee through a slit formation the issue of most important concern is to estimate the critical head that could promote the occurrence of piping considering the flow through porous media and coupling it with bernoulli s equation and a critical tractive stress condition a model is developed for the critical head using appropriate transformations the proposed model takes on a form which supports bligh s empirical findings another model based on critical velocity is also developed to estimate the critical head the functional form of these two models is evaluated using the critical head versus porosity data from a number of laboratory studies conducted in the netherlands these models were found to perform better than did terzaghi s model

influence of porosity on piping models of levee failure a piping model based on darcy s law is developed an analysis of data pertaining to different soil particle sizes and varying porosity shows that the choice of the permeability function is critical for the piping model the permeability relations which depend only on the grain size are of limited value

high resolution magnetostratigraphy of mid pliocene 3 3 3 0 ma shallow marine sediments whanganui basin new zealand

magnetic ilmenite hematite detritus in mesozoic tertiary placer and sandstone hosted uranium deposits of the rocky mountains mesozoic and tertiary sandstones throughout the rocky mountains region of the united states contain a de trital fe ti oxide mineral that is generally regarded as unusual and is preserved wherever these sandstones have escaped destructive diagenesis this mineral a medial ilmenite hematite solid solution is highly magnetic and has sometimes been mistaken for magnetite we have encountered this mineral in paleomagnetic studies and in investigations of sandstone hosted uranium deposits and cretaceous shoreline placer deposits it is known to occur elsewhere in intermediate volcanic rocks consistent with quenching from hypersolvus high temperature conditions the detrital occurrences we describe are of economic importance in uranium deposits where they are among the reductants that precipitate uranium and in cretaceous placer deposits whose exploitation would require a separation procedure tailored to this mineral the distribution of detrital hematite ilmenite sandstones in cretaceous rocks suggests a contemporaneous volcanic source in the northern rocky mountains

accretion of asian dust to hawaiian soils isotopic elemental and mineral mass balances hawaiian soils contain a mixture of material derived from in situ weathering of parent material plus atmospheric inputs including sea salt aerosols and asian dust we use soil mineralogy and radiogenic isotope geochemistry sr and nd to evaluate the impact of asian dust on a chronosequence of hawaiian soils dust becomes an important constituent of soils 20 ky and older near surface 50 cm depth horizons contain as much as 30 quartz a mineral absent from local parent material basaltic sr and nd isotope signatures in these horizons have been completely overprinted by asian dust signatures with 87sr 86sr ratios as high as 0 723 and end values as low as 7 ree patterns in these soils are indistinguishable from that of average upper continental crust quartz abundance and nd isotopes provide two independent tracers of long term dust additions to the chronosequence soils the two tracers indicate a minimum long term average dust accretion rate of 125 mg cm 2 ky 1 at the 150 ka chronosequence site roughly a factor of three higher than holocene dust accumulation rates estimated from north pacific sediment cores we find that the mass of dust preserved in these soil profiles does not increase with age in soils 150 ka and older requiring a loss mechanism for accreted dust on the basis of the geomorphic stability of these sites observed preferential loss of dust derived mica relative to quartz and estimates of soil si leaching rates we argue that chemical weathering is the dominant loss mechanism for dust from these soils dust has a profound effect on the budgets of elements that are susceptible to leaching losses dust becomes the dominant source of soil nutrients si and p in the oldest most intensely weathered soils we calculate a dust derived p input flux of 0 8 mg cm 2 ky 1 and a dust derived si input flux of 35 mg cm 2 ky 1 si leaching fluxes are high 1400 mg cm 2 ky 1 in the youngest 2 ka soils and drop systematically with soil age to a value that closely balances the dust derived si input flux by 4100 ka extremely refractory elements such as nb which are concentrated in soils by residual enrichment processes are much less readily impacted by dust addition although dust has had a pronounced impact on sr and nd isotopic budgets and on soil mineral composition at the 150 ka site dust cannot have contributed 4 of the total nb contained in this soil profile

palaeomagnetic location of the jaramillo subchron and the matuyama brunhes transition in the castlecliffian stratotype section wanganui basin new zealand abstract magnetostratigraphy is described for the lower part of the castlecliff section in wanganui basin new zealand based on analysis of multiple samples from 37 horizons the castlecliff section is the stratotype of the middle pleistocene castlecliffian stage and comprises eleven unconformity bound sequences which accumulated at inner shelf depths during interglacials a range of rock magnetic experiments undertaken on representative lithologies within the section show that the bulk of the remanence in all specimens is carried by ferrimagnetic mineral close to magnetite in composition in the stable single domain or pseudo single domain size range however at some sites post depositional chemical changes appear to have produced small amounts of another ferrimagnetic mineral chiefly within the superparamagnetic single domain size range resulting in hard secondary components of magnetization nevertheless at most sites the primary component of remanence was clearly identified by stepwise demagnetization four magnetozones are identified and these can be correlated to the magnetic polarity time scale using existing biostratigraphic constraints the section sampled spans the interval from below the jaramillo subchron to above the matuyama brunhes boundary the matuyama brunhes transition extends over 10 5 m of section within the upper westmere siltstone virtual geomagnetic pole positions describe an equatorial excursion in an otherwise far sided transition path these represent the first published data on the occurrence of the matuyama brunhes boundary on land in new zealand

magnetostratigraphic lithostratigraphic and tephrostratigraphic constraints on lower and middle pleistocene sea level changes wanganui basin new zealand wanganui basin north island new zealand contains a complex sedimentary record of lower and middle pleistocene sea level changes palaeomagnetic results allow identification of the matuyama brunhes transition the jaramillo subchron and the cobb mountain subchron correlations of rhyolitic tuff horizons across the basin are consistent with magnetostratigraphic correlations between sections isothermal plateau fission track itpft ages of 1 05 0 05 ma and 1 63 0 15 ma on two tuffs potaka pumice and pakihikura pumice respectively are consistent with the interpreted magnetostratigraphy and also with the astronomically tuned timescale of odp site 677 magnetostratigraphy and itpft ages allow correlation of sedimentary cycles at wanganui with odd numbered oxygen isotope stages 17 31 in deep sea cores the stratotype section for the new zealand castlecliffian stage is shown to be incomplete relative to other studied sections in the basin below stage 31 the character of the cyclothems changes at wanganui from marine dominated to a greater representation of non marine and estuarine strata this change may be partly related to a change in amplitude and frequency of climatic cycles identified in oxygen isotope records but the primary cause is likely to be increased basinal uplift

biogenic silica storage in soils the role of plants in soil development has become of crucial interest in quantifying global weathering processes on the volcanic reunion island indian ocean a 15 cm thick phytolith rich horizon biogenic opal a developed at the expense of trachytic ashes between 3820 85 and 335 90 yr b p then 97 138 t km 2 yr of sio 2 were biogeochemically recycled from the weathering of parent rocks through a past forest of bamboos nastus borbonicus this rate is in the same range as the present chemical weathering rates of silica in the area considered to be among the highest in the world these results demonstrate that the storage of biogenic silica in soils may be significant and may retard the output of silica to rivers and ocean

basalt weathering across scales abstract weathering of silicate minerals impacts many geological and ecological processes for example the weathering of basalt contributes significantly to consumption of atmospheric carbon dioxide co2 and must be included in global calculations of such consumption over geological timeframes here we compare weathering advance rates for basalt wd where d and indicate the scale at which the rate is determined and surface area measured respectively from the laboratory to the watershed scales data collected at the laboratory weathering rind soil profile and watershed scales show that weathering advance rate of basalt is a fractal property that can be described by a fractal dimension dr 2 3 by combining the fractal description of rates with an arrhenius relationship for basalt weathering we derive the following equation to predict weathering advance rates at any spatial scale from weathering advance rates measured at the bet scale w d k 0 a d r 2 e e a r t here k0 is the pre exponential factor 1 29 107 mm3 mm 2 yr 1 ea is the activation energy 70 kj mol 1 and a is a spatial constant related to the scale of measurement of bet surface area 10 7 mm the term a d r 2 is the roughness the roughness fractal dimension can be conceptualized as a factor related to both the thickness of the reaction front and the specific surface area within the reaction front however the above equation can also be written in terms of a surface fractal dimension and the hypothetical average grain radius these fractal dimensions provide insight into reaction front geometry and should vary with lithology once the surface area discrepancy has been accounted for using this method we find a one to two order of magnitude range in weathering advance rates measured at any scale or temperature that can be attributed to factors such as changes in erosional regime parent lithology mechanism climate composition of reacting fluid and biological activity our scaled equation when used to predict global basalt co2 consumption based upon global lithologic maps yields an uptake flux 1 75 1013 mol co2 yr 1 within the predicted error of fluxes estimated based upon riverine measurements

palaeomagnetism of sukinda chromites and their geological implications summary thirty eight oriented samples were collected from seven sites over the precambrian sukinda chromite ore between 85 43 e 21 01 n and 85 50 e 21 03 n which is in the form of a plunging syncline on isolating the primary component of magnetization and affecting the necessary tectonic correction four sites a b c f were found to possess a reverse magnetic polarity d 210 i 22 with k 122 and 95 6 and one site e was found to bear a normal polarity d 49 i 16 with k 474 and 95 2 the remaining two sites d and g were rejected the former because of scatter in directions and the latter due to overprinting by a dominant secondary magnetization induced by lateritization on comparison of vgps evaluated for these chromite deposits with those of other precambrian rocks almost of a similar age it is seen that these chromites are probably older than the gwalior traps whose age is 1830 200 ma from the rock magnetic and microscopic examination it is deduced that the massive chromites of the sukinda valley have not been affected magnetically to any great extent by serpentinization though their host rocks are serpentinized ultramafics consistent directions of remanent magnetism point to the fact that these deposits crystallized in fairly stable conditions characteristic of the stratiform type of chromite deposits therefore leading us to infer the sukinda chromites to be of that type these palaeomagnetic data when subjected to the fold test show the primary remanence to pre date the tectonic disturbance and hence prove these chromites to have consolidated prior to the regional tectonic activity of the area

rock magnetic properties and paleomagnetic behavior of neogene marine sediments from northern chile neogene sediments from la portada and bahia inglesa formations located at mejillones peninsula and caldera port northern chile carry multicomponent magnetizations which can lead to misidentification of the characteristic paleomagnetic vector and consequently errors in chronostratigraphic and structural interpretation of the strata here we present a complete rock magnetic and paleomagnetic behavior study of neogene sediments from la portada and bahia inglesa formations isothermal remanent magnetization thermal magnetic susceptibility magnetic hysteresis and x ray diffractometer experiments are combined with paleomagnetic alternating field and thermal demagnetization data to determine magnetization history remanent magnetizations generally comprises three components a low blocking temperature tb component below 150 c close to the present day field in direction interpreted as a thermoviscous component an intermediate tb component between 150 c and 290 c overprinted by the low and the high tb components considered as the survival of the characteristic detrital magnetization and a high tb component above 290 c thought to be of diagenetic origin detrital magnetite titanomagnetite and low titanium maghemite are identified as the main carrier of the magnetic remanence rock magnetic results of a minor group of samples at both locations detected the presence of a high coercivity mineral possibly hematite interpreted to carry the high tb component and to represent oxidation of minerals in postdepositional processes

diagenetic formation of ferrimagnetic iron sulphide minerals in rapidly deposited marine sediments south island new zealand abstract detailed magnetostratigraphic studies of late neogene siliciclastic sediments of the awatere group south island new zealand 41 45 s 174 05 e have revealed a wide range of palaeomagnetic behaviour examination of rock magnetic properties was undertaken using conventional palaeomagnetic techniques and thermomagnetic x ray diffraction and electron microprobe analyses these analyses indicate that the ferrimagnetic iron sulphide minerals greigite and pyrrhotite are responsible for a stable and intense magnetic remanence in fine grained sediments whereas titanomagnetite is the only remanence bearing mineral identified in coarser grained sediments which are less strongly and less stably magnetised than the fine grained sediments detrital titanomagnetite grains are likely to have undergone dissolution during early diagenesis as a result of iron sulphide formation which occurs commonly in rapidly deposited anoxic sediments that support active sulphate reduction and h 2 s formation preservation of greigite and pyrrhotite is inferred to result from the arrest of the pyritisation process probably due to the low permeability of the fine grained sediments and consumption of available h 2 s before full reaction to pyrite occurred relative palaeomagnetic instability and weak remanence intensities in coarser grained sediments is likely to be due to low titanomagnetite concentrations resulting from titanomagnetite dissolution

reconstruction of a toposequence on volcanic material in the honje mountains ujung kulon peninsula west java abstract soil formation on weathered acid tuffs was studied in the national park of the ujung kulon peninsula west java indonesia in a toposequence in the honje mountains five principal types of materials layers were distinguished based on micromorphology mineralogy and chemistry the deepest part of all profiles corresponds to a saprolite derived from tertiary and pleistocene volcanic deposits locally showing the influence of pedoplasmation the overlying layer also contains saprolite fragments but later pedogenic processes are indicated by striated b fabrics and strong clay illuviation in most profiles formation of plinthite partly postdates clay illuviation a transition layer separates this part of the profile from the top layer which is characterised by a more open microstructure an undifferentiated b fabric and the presence of pumice gravel feldspars and pyroxenes originating from the krakatau ash fall after the uplift of the mio pliocene banten tuffs deep ferrallitic weathering was followed by a period of erosion during which stone lines were formed hitherto these have been attributed to occasional coarser tephra falls in a subsequent period of stability weathering and processes of pedoplasmation clay illuviation and plinthitisation were active during the eruption of the nearby mount krakatau in 1883 the area was covered by a layer of fresh ash which affected the composition and microfabric of the top layer leading to more andic properties no important erosion event followed the ash fall

rock magnetism of lower middle pleistocene marine sediments wanganui basin new zealand rock magnetic studies were carried out in order to identify the remanence carrying minerals and the domain state of magnetic grains in lower middle pleistocene marine sediments from the wanganui basin southwestern north island new zealand isothermal remanent magnetization irm acquisition and stepwise thermal demagnetization of a three axis composite irm suggest that titanomagnetite or titanomaghaemite is the dominant remanence carrier in these sediments other rock magnetic data suggest that these grains occur in a range of sizes in the superparamagnetic to pseudo single domain range which helps account for the wide range of observed palaeomagnetic behaviour isolated occurrences of ferrimagnetic iron sulphides cannot be ruled out

chemical weathering in the krishna basin and western ghats of the deccan traps india rates of basalt weathering and their controls rates of chemical and silicate weathering of the deccan trap basalts india have been determined through major ion measurements in the headwaters of the krishna and the bhima rivers their tributaries and the west flowing streams of the western ghats all of which flow almost entirely through the deccan basalts samples n 63 for this study were collected from 23 rivers during two consecutive monsoon seasons of 2001 and 2002 the total dissolved solid tds in the samples range from 27 to 640 mg l 1 the rivers draining the western ghats that flow through patches of cation deficient lateritic soils have lower tds average 74 mg l 1 whereas the bhima except at origin and its tributaries that seem to receive na cl and so4 from saline soils and anthropogenic inputs have values in excess of 170 mg l 1 many of the rivers sampled are supersaturated with respect to calcite the chemical weathering rates cwr of selected basins which exclude rivers supersaturated in calcite and which have high cl and so4 are in range of 3 to 60 t km 2 y 1 this yields an area weighted average cwr of 16 t km 2 y 1 for the deccan traps this is a factor of 2 lower than that reported for the narmada tapti wainganga ntw systems draining the more northern regions of the deccan the difference can be because of i natural variations in cwr among the different basins of the deccan ii selection of river basin for cwr calculation in this study and iii possible contribution of major ions from sources in addition to basalts to rivers of the northern deccan traps silicate weathering rates swr in the selected basins calculated using dissolved mg as an index varies between 3 to 60 t km 2 y 1 nearly identical to their cwr the ca mg and na mg in these rivers after correcting for rain input are quite similar to those in average basalts of the region suggesting near congruent release of ca mg and na from basalts to rivers comparison of calculated and measured silicate ca in these rivers indicates that at most 30 of ca can be of nonsilicate origin a likely source being carbonates in basalts and sediments the chemical and silicate weathering rates of the west flowing rivers of the deccan are 4 times higher than the east flowing rivers this difference is due to the correspondingly higher rainfall and runoff in the western region and thus reemphasises the dominant role of runoff in regulating weathering rates the silicon weathering rate swr in the krishna basin is 15 t km 2 y 1 within a factor of 2 to those in the yamuna bhagirathi and alaknanda basins of the himalaya suggesting that under favourable conditions intense physical weathering high runoff granites and the other silicates in the himalaya weather at rates similar to those of deccan basalts the co2 consumption rate for the deccan is deduced to be 3 6 105 moles km 2 y 1 based on the swr the rate though is two to three times lower than reported for the ntw rivers system it still reinforces the earlier findings that in general basalts weather more rapidly than other silicates and that they significantly influence the atmospheric co2 budget on long term scales

rock magnetic evidence for the dissolution and authigenic growth of magnetic minerals within anoxic marine sediments of the california continental borderland the rock magnetic properties of marine sediments from the california continental borderland san pedro santa catalina and san nicolas basins have been studied in order to quantitatively assess the effects of sediment diagenesis on magnetic minerals previous studies have noted that the natural remanent magnetization in these sediments primarily carried by detrital magnetite decays to 10 or less of its surface value soon after deposition this decrease is caused by magnetite dissolution related to sediment diagenesis and is unrelated to paleoclimatic variations or changes in the regional influx of detrital magnetic material detailed rock magnetic measurements show that shifts to softer remanent coercivity and differences in the rate and degree of magnetic intensity loss with depth can be related to the dissolution process the shift to softer remanent coercivity is related to a coarsening of the magnetic mineral grain sizes with depth due to preferential dissolution of the finest grained magnetic material the intensity decreases which are linearly proportional to magnetite concentration decreases indicate that dissolution occurs with rate constants ranging from 0 3 to 1 6 kyr 1 the rate constants sulfide concentrations and magnetite grain size estimates from the borderland are consistant with previous studies of magnetite dissolution our results demonstrate the importance of both sulfide and magnetite surface area in the dissolution process anomalous peaks in viscous remanence within the sediments suggest the authigenic growth of greigite and its subsequent transformation to pyrite

strong tectonic and weak climatic control of long term chemical weathering rates the relationships among climate physical erosion and chemical weathering have remained uncertain because long term chemical weathering rates have been difficult to measure here we show that long term chemical weathering rates can be measured by combining physical erosion rates inferred from cosmogenic nuclides with dissolution losses inferred from the rock to soil enrichment of insoluble elements we used this method to measure chemical weathering rates across 22 mountainous granitic catchments that span a wide range of erosion rates and climates chemical weathering rates correlate strongly with physical erosion rates but only weakly with climate implying that by regulating erosion rates tectonic uplift may significantly accelerate chemical weathering rates in granitic landscapes

chemical denudation rates of the western canadian orogenic belt the stikine terrane we report in this paper major element and sr isotopic ratio analyses for 19 rivers draining the stikine province in the western canadian cordillera dissolved solutes suspended sediments and river sands were analyzed the aim of the paper is to calculate chemical denudation rates for this uplifted accretionary prism mainly dominated by volcanics and volcanic derived sedimentary rocks the major chemical features of the stikine rivers are their dilute character and the excess of ca mg and sr in the dissolved load with regards to na molar ca na ratios from 2 to 14 mean value of 5 4 are observed although the region is dominated by silicate rocks suspended sediments show ca na ratios close to 0 4 isotopically most of the rivers investigated display lower sr isotopic ratios in the dissolved load compared to the suspended load which is very unusual to account for the excess of cations three different hypotheses are tested by an inversion method allowing us to determine the origin of each major solute the first scenario assumes that the excess of ca and mg is due to the dissolution of unradiogenic carbonates the second scenario supposes that the excess of base cations is derived from the preferential dissolution of ca and mg rich minerals such as amphiboles in the third scenario all solutes are assumed to derived from silicate weathering the cationic weathering rates of silicates although imprecise are in the order of 2 5 tons km2 year for the two first hypotheses if all solutes are taken into account denudation rates are between 9 and 15 tons km2 year on a global scale these numbers are among the lowest found for rivers draining basaltic rocks they are however found to be consistent with the global law for chemical weathering rates established for basaltic rocks showing that chemical denudation rate are linearly correlated to runoff and depend on temperature according to an arrhenius law the rivers draining the complex assemblage of volcanic and volcanic derived rocks in the subduction collision geological context of the stikine province thus respond similarly to the other volcanic provinces of the world this does not seem to be true for associated co2 consumption rates the abundance of sulfate ions in the dissolved load possibly derived from oxidative weathering of sulfides may indeed provide a non negligible part of the protons necessary for chemical weathering within canada the stikine geologic province is one whose silicates weather at a high rate the order of chemical weatherabilty of canadian geological province from the lowest to the highest is established as follows granites shales of the rockies volcanics of the western cordillera shales of the interior platform carbonates

dissolution and pyritization of magnetite in anoxie marine sediments concentrations of magnetite were determined with depth in sediments of varying h2s content taken from long island sound foam nwc and sachem sites and from a site in the rapidly depositing subaqueous portion of the mississippi delta for the three long island sound sites dissolution of magnetite during burial is clearly demonstrated and for all four sites the rate of magnetite dissolution is proportional to the concentration of dissolved pore water sulfide by combining magnetite depth distributions with sedimentation rate data and measurements of dissolved sulfide we find that magnetite dissolution is well described by the following rate law dcmagdt 1 1 10 5c0 5bcmagamag where cmag is the concentration of magnetite grams per gram of sediment cs is the concentration of dissolved sulfide mm and amag is the specific surface area of magnetite in the sediment cm2 per gram of magnetite this equation means that for a typical range of magnetite surface areas and dissolved sulfide concentrations the half life of magnetite in anoxic marine sediments ranges from about 50 to 1000 years sem observations of magnetite grains from the different sediment sites reveal that magnetite dissolution may be accompanied by extensive replacement by pyrite this only occurs if magnetite is in contact with high concentrations of h2s 1 mm for relatively long periods of time several hundred years with low concentrations of h2s 1 mm magnetite dissolution occurs without identifiable pyrite replacement we suggest that this feature of magnetite diagenesis may prove to be a useful paleosulfide indicator

magnetic mineral diagenesis in suboxic sediments at bettis site w n ne pacific ocean the effects of iron diagenesis on paleomagnetism and rock magnetism were examined in suboxic sediments from bettis site w n in the ne pacific ocean as part of the oxidative decomposition of organic matter ultrafine grained authigenic magnetites are produced immediately above the iron reduction zone this zone is commonly observed in deep sea sediments as a prominent color change from brown to greenish grey the magnetite authigenesis is evidenced by systematic increases in natural magnetic intensities and stabilities and by comparable shifts in other rock magnetic properties the magnetites are composed of relatively pure fe3o4 and fall within a restricted size range of 0 06 0 12 m which is nominally single domain some of these finest grained magnetites are rapidly destroyed during burial upon entering the zone of iron reduction leaving a relatively coarser population magnetite dissolution appears to continue with depth according to a first order surface area reaction process when at steady state iron reduction is independent of sulfide formation in these sediments because solid sulfur profiles show no increase at depth and most of the sulfur occurs as barite despite a well constrained carbonate stratigraphy comparisons of paleomagnetic directions between nearby cores show little agreement suggesting that the directions are composed of a complex mixture of remanences acquired at different depths subsurface magnetic peaks may represent paleoredox markers preserved by non steady state redox conditions caused by climatically induced variations in organic matter flux and sedimentation rates

diagenesis of magnetic minerals in recent haemipelagic sediments rapidly deposited sediments from marine and lake environments are being used increasingly to study decadal to millennial fluctuations in the earth s magnetic field the objectives are to gain more fundamental understanding of the geodynamo and to establish a new dating technique for sediments while lacustrine sections are generally restricted to temperate latitude glacial lakes 20 000 yr old rapidly deposited marine sediments along continental margins potentially offer continuous high resolution yet long term records of geomagnetic secular variation however to interpret the sedimentary magnetic record accurately geochemical processes that affect the reliability of the magnetic signal must be understood we now report downcore magnetic profiles from undisturbed kasten cores taken in rapidly deposited laminated sediments from the gulf of california and in bioturbated haemipelagic muds on the oregon continental slope which give apparently reliable directions but show dramatic decreases in the intensities of natural nrm and artificial arm irm remanences with depth downcore porewater and solid sulphur analyses show concave down decreases in porewater sulphate and systematic increases in pyrite and metastable monosulphides the maximum curvature of the sulphide profile occurs directly below the high magnetization zone combined with other compositional and mineralogical analyses these data suggest that due to oxidative decomposition of organic matter magnetites and other iron oxides become progressively reduced and subsequently sulphidized and pyritized with depth iron reduction seems to occur before sulphide formation changes in magnetic stability parameters are consistent with selective dissolution of the finer sized grains causing downcore coarsening of the magnetic fraction

mineral neoformation in pore spaces during alteration and weathering of andesitic rocks in humid tropical indonesia abstract the morphology chemistry and mineralogy of minerals newly formed in voids products of weathering of andesitic rocks were studied using optical and submicroscopic techniques on thin sections combined with scanning electron microscopy sem energy dispersion x ray analysis edxra and x ray diffraction analysis on subsamples samples were taken from the core the outer core and the soft outer layers of weathered andesitic boulders in the cigudeg area west java about 75 km south of jakarta indonesia with udic moisture and isohyperthermic temperature regime the neoformed minerals observed in planar voids and cavities comprise 1 1 phyllosilicates goethite and gibbsite and juxtaposed coatings of halloysite mixed layer phyllosilicates goethite and gibbsite the mineral sequences observed confirm former studies on the groundmass of the boulder in the first weathering layer an absolute accumulation of gibbsite takes place further away from the core the gibbsite is redissolved and replaced by illuvial phyllosilicate clay the possibility of inheritance of the 2 1 layer silicates from a hydrothermal alteration is discussed the sharp boundaries in the juxtaposed coatings point to a stepwise sequential rather than a gradual evolution of the microenvironment

distributed deformation due to coupling across a subduction thrust mechanism of young tectonic rotation within the south wanganui basin new zealand paleomagnetic data from pliocene sedimentary strata in the south wanganui basin new zealand document clockwise tectonic rotation west of and increasing toward the main zone of deformation axial tectonic belt associated with the australia pacific plate boundary zone in the north island of new zealand measured rotation with respect to the australian plate increases from 1 4 3 9 80 km west of the axial tectonic belt to 6 5 2 0 and 13 2 3 1 at 45 km and 20 km west of the axial tectonic belt respectively these measurements indicate that 1 deformation associated with plate convergence occurs across a wide region up to 270 km west of the hikurangi trench and 2 in the past 2 5 m y at least 30 km of transcurrent motion and 10 km of shortening at the plate boundary have been accommodated within the south wanganui basin by distributed shear west of the plate boundary zone proper the data support a model suggesting that the wanganui basin is a lithospheric flexure basin driven by high friction at the plate interface this strain in the south wanganui basin and inferred high friction across the plate interface at the basin9s eastern margin have occurred since 2 5 ma

wasp waisted hysteresis loops mineral magnetic characteristics and discrimination of components in mixed magnetic systems rock magnetic studies of complex systems that contain mixtures of magnetic minerals or mixed grain size distributions have demonstrated the need for a better method of distinguishing between different magnetic components in geological materials hysteresis loops that are constricted in the middle section but are wider above and below the middle section are commonly observed in mixed magnetic assemblages such wasp waisted hysteresis loops have been widely documented particularly with respect to rare earth permanent magnets basaltic lava flows remagnetized paleozoic carbonate rocks and an increasingly wide range of other rocks our modelling combined with a review of previous work indicates that there are several conditions that give rise to as well as magnetic properties that are characteristic of wasp waisted hysteresis loops first at least two magnetic components with strongly contrasting coercivities must coexist this condition can arise from either mixtures of grain sizes of a single magnetic mineral or a combination of magnetic minerals with contrasting cocrcivities or a combination of these two situations second materials that give rise to wasp waisted hysteresis loops will have relatively high ratios of the coercivity of remanence to coercive force b cr b c because b0 is controlled by the soft low coercivity component whereas bcris controlled by the hard high coercivity component third values of b cr b c 10 usually only occur for strongly wasp waisted loops when the low coercivity component comprises an overwhelmingly large fraction of the total volume of magnetic grains fourth a given mixture of superparamagnetic and single domain sd grains is more likely to give rise to wasp waisted hysteresis loops than an equivalent mixture of sd and multidomain grains fifth our results provide empirical confirmation that the total magnetization of a material is the sum of the weighted contributions of each component in the absence of significant magnetic interaction between particles thus to contribute significantly to wasp waisted behavior a mineral magnetic component must give rise to a significant portion of the total magnetization of the rock as a result minerals with weak magnetic moments such as hematite need to occur in large concentrations to cause wasp waistedness in materials that also contain ferrimagnetic minerals we outline a method for determining the magnetic components that can give rise to wasp waisted hysteresis loops this method is based on high and low temperature magnetic measurements that are used to identify the dominant remanence bearing mineral s and on mineral magnetic techniques that are used to discriminate between different magnetic domain states the method is illustrated with several examples from archaeological geological and synthetic materials

stability of remanence and paleomagnetic studies of some chromite ores from barramiya and allawi occurrences eastern desert egypt abstract rock magnetic investigations were carried out on natural precambrian chromite ore at two occurrences in the eastern desert egypt a medium high coercivity component of remanence of reversed polarity can be defined the mean direction of the five sites studied is d 198 i 44 with k 55 and 95 10 ore microscopic and magnetic examinations indicate the absence of magnetite and it is shown that the chromite mineral ferrimagnetic phase could be the carriers of the high stable nrm the result of paleopole position of these precambrian chromites are presented and discussed in the context of its age and the apparent polar wander path apwp of africa

progressive dissolution of titanomagnetites at odp site 653 tyrrhenian sea abstract magnetic properties microscopy and ferrous ferric iron ratio document increasing down core alteration of titanomagnetite to iron sulfide at odp site 653 leg 107 tyrrhenian sea changes in magnetic properties are interpreted to indicate a grain size increase in titanomagnetite to 40 m below seafloor bsf and a grain size decrease from this level to about 150 m bsf as dissolution affects first the fine grained and then the coarser grained magnetite the availability of dissolved sulfate from underlying messinian evaporites may account for the sulfide supply at depth and hence for the prolonged dissolution process dissolution at leg 107 sites adjacent to site 653 is less pronounced possibly by the availability of organic matter that can be metabolised by sulfate reducing bacteria