the posidonia shale lower toarcian of sw germany an oxygen depleted ecosystem controlled by sea level and palaeoclimate abstract the lower toarcian posidonia shale is famous for its excellently preserved fossils and its high amount of organic matter up to 16 both quality of preservation and accumulation of organic matter have been explained by permanent anoxic bottom water conditions high resolution geochemical sedimentological and palaeoecological investigations of various sections of the posidonia shale in sw germany however indicate that oxygen availability was variable and ranged from short oxygenated periods to longer term anoxia the benthic macrofauna consists of nine fossil communities and was used in combination with geochemical data to reconstruct a time averaged oxygen curve anoxic conditions prevailed during the deposition of the toarcian black shales they were however punctuated by various short periods weeks to years with oxygenated bottom water conditions sedimentological e g distinctiveness of microlamination siliciclastic content and geochemical parameters e g organic matter content isotopic signatures 18o and 13c molecular redox parameters pristane phytane ratio arylisoprenoids exhibit a remarkable covariation and seem to be controlled by sea level fluctuations maximum oxygen depletion and an extreme negative shift of 13corg values 34 occurred during the early falciferum zone this is explained by the recycling of 12c enriched carbon derived from remineralization of organic matter on and within the substrate during low sea level stand and a highly elevated redox boundary including photic zone anoxia the subsequent transgression permitted enhanced water exchange with the tethyan ocean and caused improvement of living conditions at the end of the falciferum zone other important factors controlling the depositional environment are the overall palaeogeographic situation and climate the early jurassic is the latest period before break up of pangaea and probably was ruled by a strong meridional atmospheric circulation system with pronounced seasonal changes of prevailing trade and monsoon wind systems an estuarine circulation with a positive water balance and surface water with slightly reduced salinity in the summer alternated with an anti estuarine circulation and a negative water balance in the winter during the summer months a stratified water column with anoxic conditions below the halocline developed 18o data indicate low salinity in the surface water during the monsoon influenced summer high productivity was then located in the photic zone and the corresponding isotopically light 18o signal was fixed in the calcareous nannoplankton during the winter months a saline circulation system brought oxygen to the benthic environment favouring temporary benthic colonization especially during times of relative sea level high stand

extinction survival and recovery of corals from the triassic to middle jurassic time recognizing extinction events and determining their cause at the triassic jurassic t j transition and near the pliensbachian toarcian lower jurassic boundary is a field of growing interest we provide arguments for these events through a literature based new evaluation of coral diversity from triassic to dogger and a new palaeobiogeographical map the t j extinction of corals is clearly related to the breakdown of reef environments origination curves show that hettangian the lowest jurassic stage was not only a survival phase but already rather a recovery phase post extinction evolution of reefs and their survival only in the northernmost margin of the tethys support the hothouse hypothesis for the t j extinction event during pliensbachian many new taxa appear but mostly solitary corals not really framebuilders many of these taxa do not occur anymore during the following stages the new increase in diversity is related to the development of bajocian middle jurassic reefs

dynamics of a stepped carbon isotope excursion ultra high resolution study of early toarcian environmental change abstract in the toarcian early jurassic 183 myr ago the ocean atmosphere system was subject to one of the largest perturbations of the carbon cycle in the last 250 myr known as the toarcian oceanic anoxic event t oae this event was accompanied by a 6 negative carbon isotope excursion cie caused by massive injection of isotopically light carbon into the ocean atmosphere system possibly from destabilisation of gas hydrates this study reveals the pacing and sequence of events leading up to the cie and to widespread deposition of organic rich sediments the very high resolution isotopic record from exceptionally well preserved carbonate and organic matter from the paris basin enables recognition of increased co 2 levels 130 kyr in advance of the major negative cie an accelerated increase in the p co 2 is registered 25 kyr before the onset of this negative excursion and was so rapid and so intense that it led to a water column undersaturated with respect to calcium carbonate in the paris basin undersaturation is expressed as a dramatic drop in the accumulation of the biogenic calcite produced by the surface dwelling calcifiers these environmental perturbations representing precursor phases of co 2 injection predate the first step towards relatively light carbon isotopes in carbonate and organic matter and are tentatively attributed to karoo ferrar magmatism this negative shift was registered slightly earlier in terrestrial carbon than marine carbonate subsequent global warming is credited with liberating isotopically light carbon and ultimately fostered anoxia in the paris basin the response of these cumulative inputs of carbon to the earth system isotopic and sedimentological evidence indicates continuously elevated phytoplanktonic productivity throughout the first step of the negative cie suggesting that the biological pump accelerated the drawdown of excess carbon leading to temporary recovery of carbonate sedimentation 45 kyr after the first step of the cie this re establishment of the saturation state of the water column was only fleeting before the later stepwise release of isotopically light carbon

identification of dissolution patterns in nannofossil assemblages a high resolution comparison of synchronous records from ceara rise odp leg 154 1 fossil nannoplankton assemblages are controlled by both initial plankton production and dissolution throughout the water column and on the seafloor it is usually assumed that dissolution can be identified by subjective visual assessment of preservation state we have tested this by a quantitative comparison of mid pliocene nannofossil assemblages in two closely located odp sites ceara rise sites 926 and 929 both with apparently good preservation but located respectively above and below the lysocline we demonstrate that despite an absence of obvious qualitative preservation differences dissolution has removed perhaps 80 of the assemblage in the sub lysocline site 929 this has produced consistent distortions in the assemblages and artificially enhanced abundance variations patterns of individual species the results provide strong cautions for palaeoceanographic interpretation of nannofossil data and allow us to uniquely extract a dissolution variation record and provide a detailed ranking of dissolution susceptibility of pliocene nannofossils

carbon isotope records of the early jurassic toarcian oceanic anoxic event from the valdorbia umbria marche apennines and monte mangart julian alps sections palaeoceanographic and stratigraphic implications the toarcian oceanic anoxic event ca 183 ma coincides with a global perturbation marked by enhanced organic carbon burial and a general decrease in calcium carbonate production probably triggered by changes in the composition of marine plankton and elevated carbon dioxide levels in the atmosphere this study is based on high resolution sampling of two stratigraphic successions located in valdorbia umbria marche apennines and monte mangart julian alps italy which represent expressions of the toarcian oceanic anoxic event in deep water pelagic sediments these successions are characterized by the occurrence of black shales showing relatively low total organic carbon concentrations compared with coeval strata in northern europe generally 2 and low hydrogen indices on this basis they are similar to other toarcian black shales described from the tethyan region the positive and negative carbon isotope records from the two localities permit a high resolution correlation such that ammonite biostratigraphy information from valdorbia can be transferred to those parts of the monte mangart section that lack these fossils spectral analyses ofd 13 corg values and of caco3 percentages from the sedimentary records of both the valdorbia and monte mangart sections reveal a strong cyclic pattern best interpreted as an eccentricity signal which hence implies a duration of ca 500 kyr for the negative carbon isotope excursion based on the carbon isotope curves obtained the high resolution correlation between the italian successions and a section in yorkshire northern europe confirms the supposition that the apparent mismatch between the dating of the toarcian oceanic anoxic event in the boreal and tethyan realms is an artefact of biostratigraphy

an attempt to constrain the age duration and eruptive history of the karoo flood basalt naude s nek section south africa we have carried out paleomagnetic sampling of a similar to 750 m sequence of the karoo large igneous province naude s nek pass south africa k ar dating cassignol gillot has been performed on four samples from the 650 m upper unit mean age 179 2 1 8 ma and a sample from the lower unit 184 8 2 6 ma a succession of two phases of volcanism is suggested the lower 25 flows 115 m thick have recorded a reversed polarity the next 23 flows 135 m thick are transitional and contribute a detailed record of the van zijl 1962 jurassic reversal the upper 38 flows 500 m thick have normal polarity directional groups dgs of lava flows with quasi identical remanence directions indicate eruption durations too short to have recorded geomagnetic secular variation and hence are interpreted as single eruptive events altogether 19 dgs and 10 sheet lobes yield a sequence of 29 distinct directions this could correspond to a total eruptive activity shorter than 3000 years less than one per mil of the total duration over which the section was emplaced we obtain a new paleomagnetic pole for south africa at similar to 180 ma lambda 75 2 degrees n phi 276 4 degrees e a 95 5 8 degrees n 19 which is consistent with earlier reports

mapping and geochemical characterization of the toarcian organic matter in the mediterranean tethys and middle east organic matter from toarcian outcrops and boreholes in several basins around the mediterranean sea and middle east has been studied rock eval pyrolysis elemental analyses of kerogens and gas chromatography of chloroform extracts within these different basins have been used to determine the amount petroleum potential and type of the organic matter the results have been used to compile a mapping of the organic matter for the toarcian stage which shows heterogeneities in the distribution and type of organic matter 1 1 marine organic matter type ii occurs in different environments of deposition whereas high contents 5 total organic carbon correspond to thick deposits within the west european realm great britain north sea paris basin and germany the organic matter is less abundant in the mediterranean area where lower concentrations 1 2 toc preserved in lower toarcian thin levels are limited only to restricted basins northern italy greece 2 2 the predominance of continental organic matter type iii along the northern margin of the tethys corresponds to a deltaic environment 3 3 there is a predominance of altered organic matter within the carbonated platforms around the mediterranean tethys these results supplemented with the data issuing from the literature add a geochemical dimension to the paleogeography of the tethys

chemostratigraphy of the jurassic system applications limitations and implications for palaeoceanography current chemostratigraphical studies of the jurassic system primarily involve the use of one sedimentary component marine organic carbon one divalent transition metal substituted in carbonate manganese and two isotopic tracers strontium isotope ratios 87 sr 86 sr and carbon isotope ratios 13 c carb and 13 c org in carbonate and in organic matter other parameters such as mg ca and sr ca ratios in calcite oxygen isotope ratios 18 o in carbonate sulphur isotope ratios 34 s in carbonate hosted sulphate nitrogen isotope ratios 15 n org in organic matter osmium isotope ratios 187 os 188 os in black shales and neodymium isotope ratios 143 nd 144 nd in various mineral phases are also useful but at present give poor resolution because the database is incomplete or compromised by various factors stratigraphical patterns in total organic carbon toc can be of either local or regional significance depending on the lateral extent of the former nutrient rich and productive water mass divalent manganese follows a similar pattern being concentrated most probably as a very early diagenetic phase only in oxygen depleted waters that typically underlie zones of elevated organic productivity shifts in mg ca and sr ca ratios on the time scale of ammonite subzones seem largely to reflect temperature changes strontium isotope ratios from pristine skeletal calcite provide a global signal 13 c values from carbonates with minimal diagenetic overprint potentially do the same although small spatial differences in palaeo water mass composition may have been locally significant oxygen isotope determinations on carbonate rocks and fossils generally yield values that are too scattered to be stratigraphically useful because they reflect palaeotemperature the evaporation precipitation balance in sea water and the impact of any diagenesis involving an aqueous phase nitrogen isotope ratios in organic matter reflect the chemistry of ancient water masses as affected by nitrate utilization and denitrification and the stratigraphical pattern of this parameter is more likely to correlate only on a regional basis neodymium isotope ratios in sea water are also water mass dependent and greatly affected by regional sources and oceanic current systems preliminary data on sulphur isotope ratios in carbonates and osmium isotope ratios in organic rich shales both potentially offering global correlation indicate that these tracers may be valuable although the records at present are not sufficiently well established to allow high resolution regional correlation in all cases biostratigraphically well dated reference sections against which the relevant geochemical data have been calibrated are required in the first instance to date studies on the stratigraphical distribution of organic carbon have been principally carried out in both northern boreal and southern tethyan europe carbon isotope stratigraphy has been undertaken primarily but not exclusively on bulk pelagic sediments from the alpine mediterranean or tethyan domain and strontium isotope stratigraphy has been undertaken largely on calcitic skeletal material belemnites and oysters from northern and southern europe in many sections including those containing ammonites multi parameter chemostratigraphy can give resolution that exceeds that attainable by classic biostratigraphical means strontium isotope ratios in skeletal calcite are a particularly powerful tool for illustrating changes in sedimentary rate and revealing gaps in the stratigraphical record

an organic geochemical profile of the toarcian anoxic event in northern italy abstract a suite of black shales calcareous shales and limestones representing the toarcian anoxic event jurassic 192 ma was collected from a 14 m length of core taken from the belluno trough northern italy and examined in detail to assess variations in depositional environment during this interval geochemical and optical data indicate organic matter of algal and bacterial origin with only trace contribution from terrestrial sources detailed biological marker data interpreted with the aid of multivariate statistics demonstrate fluctuations in primary producers and bacterial populations during black shale deposition the onset of the anoxic event was not abrupt but characterized by an apparent gradual development of anoxia and consequent enhanced organic matter preservation different hopane biomarkers proved especially useful in recognizing preservation potential in the section and correlate well with other preservation indicators increased oxygenation at the end of the event may have been associated with changes in primary productivity

secular environmental precursors to early toarcian jurassic extreme climate changes the early toarcian oceanic anoxic event t oae about 183 myr ago was a global event of environmental and carbon cycle perturbations which deeply affected both marine biota and carbonate production nevertheless the long term environmental conditions prevailing prior to the main phase of marine extinction and carbonate production crisis remain poorly understood here we present a similar to 8 myr long record of early pliensbachian middle toarcian environmental changes from the lusitanian basin portugal in order to address the long term paleoclimatic evolution that ultimately led to carbonate production and biotic crises during the t oae paleotemperature estimates derived from the oxygen isotope compositions of well reserved brachiopod shells from two different sections reveal a pronounced similar to 5 degrees c cooling in the late pliensbachian margaritatus spinatum ammonite zones boundary this cooling event is followed by a marked similar to 7 10 degrees c seawater warming in the early toarcian that after a second cooling event in the mid polymorphum zone culminates during the t oae calcium carbonate caco3 contents the amount of nannofossil calcite and the mean size of the major pelagic carbonate producer schizosphaerella all largely covary with paleotemperatures indicating a coupling between climatic conditions and both pelagic and neritic caco3 production furthermore the cooling and warming episodes coincided with major marine regressions and transgressions respectively suggesting that the growth and decay of ice caps may have exerted a strong control on sea level fluctuations throughout the studied time interval this revised chronology of environmental changes shows important similarities with neogene and paleozoic episodes of deglacial black shale formation and thus prompts the reevaluation of ice sheet dynamics as a possible agent of mesozoic events of extinction and organic rich sedimentation c 2010 elsevier b v all rights reserved

duration of the early toarcian carbon isotope excursion deduced from spectral analysis consequence for its possible causes abstract the marked 3 8 negative carbon isotope excursion associated with the early toarcian oceanic anoxic event oae 183 myr ago in the early jurassic period is thought to represent one of the most important perturbations of the c cycle in the last 200 myr however the origin of this excursion remains strongly debated primarily due to uncertainties in the estimation of its duration which ranges from 200 kyr to 1 myr here we present a new orbital calibration of the early toarcian carbon isotope excursion based on spectral analyses of two independent datasets generated from the sedimentary record of two hemipelagic sections from portugal peniche and sw germany dotternhausen in order to better constrain the timescale and hence the origin of this excursion these analyses reveal that orbital cycles exert a strong influence on both the calcium carbonate content in portugal and on the greyscale of black shales in germany which allow us to propose a duration of 1 9 myr for the early toarcian and of 900 kyr for the entire carbon isotope excursion the shift towards lower carbon isotope values lasted 150 kyr and carbon isotope values remained low for 450 kyr the subsequent increase of carbon isotope values lasted 300 kyr this calibration suggests that the sustained input of isotopically light carbon at the origin of the excursion occurred over 600 kyr and thus dismisses causal mechanisms implying relatively small source reservoirs such as the massive dissociation of methane hydrates in the light of our new cyclostratigraphic timescale the massive input of isotopically light carbon associated with the emplacement of the karoo ferrar basaltic province appears as the most likely cause of the toarcian global carbon isotope excursion we also show that the c isotope perturbation coincided with a transition from precession eccentricity dominated cycles to obliquity eccentricity dominated cycles suggesting that the oae was marked by a fundamental change in the response of the climate system which allowed the obliquity signal normally better recorded at high latitudes to be a dominant forcing factor of short term sedimentary cycles at tropical latitudes

a volcanic co2 pulse triggered the cretaceous oceanic anoxic event 1a and a biocalcification crisis the aptian oceanic anoxic event 1a oae1a ca 120 ma ago is one of the most prominent of a series of geologically brief intervals in the cretaceous characterized by the deposition of organic carbon rich sediments oaes reflect major perturbations in the global carbon cycle evidenced by sedimentary carbon isotope records however the triggering mechanisms for oaes remain controversial here we present a bulk rock and molecular marine and terrestrial bio markers c isotope record at unprecedented time resolution from the cismon section of northern italy that shows that oae1a conditions were reached over a period of several thousands of years through a stepwise perturbation of the carbon cycle the documented sequence of events is most compatible with a trigger associated with increased co 2 emissions possibly leading to a doubling of p co 2 which in turn caused larger c isotope fractionation in marine and terrestrial organisms and a major biotic crisis in the calcareous nannoplankton our data also show that a release of isotopically light carbon from partial methane hydrate dissociation probably played a minor role in the oae1a carbon cycle perturbation

new chronology for the late paleocene thermal maximum and its environmental implications the late paleocene thermal maximum lptm is associated with a brief but intense interval of global warming and a massive perturbation of the global carbon cycle we have developed a new orbital chronology for ocean drilling program odp site 690 weddell sea southern ocean by using spectral analysis of high resolution geochemical records the lptm interval spans 11 precessional cycles yielding a duration of 210 to 220 k y the 13 c anomaly associated with the lptm has a magnitude of about 2 5 to 3 we show that about 2 of the excursion occurs within two steps that each were less than 1000 yr in duration the remainder developed through a series of steps over 52 k y the timing of these steps is consistent with a series of nearly catastrophic releases of methane from gas hydrates punctuated by intervals of relative equilibria between hydrate dissociation and carbon burial further we are able to correlate the records between odp sites 690 and 1051 western north atlantic on the scale of 21 k y cycles which demonstrates that the details of the 13 c excursion are recognizable between distant sites comparison of cycle records at sites 690 and 1051 suggests that sediment representing the interval 30 k y just prior to and at the onset of the lptm are missing in the latter location this unconformity probably resulted from slope failure accompanying methane hydrate dissociation within 10 k y of the start of the lptm

an isotopic study of biogeochemical relationships between carbonates and organic carbon in the greenhorn formation carbon isotopic compositions of total carbonate inoceramid carbonate micritic carbonate secondary cements total organic carbon and geoporphyrins have been measured in 76 different beds within a 17 m interval of a core through the greenhorn formation an interbedded limestone and calcareous shale unit of cretaceous age cenomanian turonian from the western interior seaway of north america results are considered in terms of variations in the processes of primary production which led to the biosynthesis of the molecular precursors of the geoporphyrins and in secondary processes those mediating the transformation of primary organic material into sedimentary total organic carbon it is shown that the porphyrin isotopic record reflects primary isotopic variations more closely than the toc isotopic record and that in these sediments toc is enriched in 13c relative to its primary precursor by 0 6 to 2 8 this enrichment is attributed to isotope effects within the consumer foodweb and is associated with respiratory heterotrophy variations in this secondary enrichment are correlated with variations in the isotopic composition of marine carbonate this correlation is attributed to effects of environmental changes on the marine foodweb these may have included increased atmospheric oxygen associated with the cenomanian turonian oceanic anoxic event the isotopic fractionation associated with fixation of carbon by primary producers is observed to have varied by 1 5 during the interval of deposition it is suggested that this change is due to a variation in the makeup of the community of primary producers and or to a decrease in the atmospheric abundance of co2 during the oceanic anoxic event

carbon isotope record of the early jurassic toarcian oceanic anoxic event from fossil wood and marine carbonate lusitanian basin portugal thetoarcianoceanicanoxicevent oae intheearlyjurassic 183maago wascharacterizedbywidespreadnear synchronous deposition of organic rich shales in marine settings as well as perturbations to several isotopic systems characteristically two positive carbon isotope excursions in a range of materials are separated by an abrupt negative shift carbon isotope profiles from toarcian fossil wood collected in england and denmark have previously been shown to exhibit this large drop 7 i n 13 c values interpreted as due to an injection of isotopically light co2 into the ocean atmosphere system however the global nature of this excursion has been challengedonthebasisofcarbon isotopedatafromnektonicmarinemolluscs belemnites whichexhibitheavierthanexpectedcarbonisotope values here we present new data principally from fossil wood and bulk carbonate collected at centimetre scale from a hemipelagic section at peniche coastal portugal this section is low in organic carbon average toc 0 5 and the samples should not have suffered significant diagenetic contamination by organic carbon of marine origin the carbon isotope profile based on wood shows two positive excursions separated by a large and abrupt negative excursion which parallels exactly the profile based on bulk carbonate samples from the same section albeit with approximately twice the amplitude 8 in wood versus 3 5 in carbonate these data indicate thatthe negative carbon isotope excursion affected the atmosphereand by implication the global ocean as well the difference in amplitude between terrestrial organic and marine carbonate curves can be explained by greater water availability in the terrestrial environment during the negative excursion for which there is independent evidence from marine osmiumisotope records and plausibly changes in atmospheric co2 content for which independent evidence is also available the peniche succession is also notable for the occurrence of re deposited sediments their lowest occurrence coincides with the base of the negative excursionandtheirhighestoccurrencecoincideswithitstop thus slopeinstabilityandsedimentsupplycouldhavebeenstronglylinked to the global environmental perturbation an association that may misleadingly simulate the effects of sea level fall

global and local forcing of early toarcian seawater chemistry a comparative study of different paleoceanographic settings paris and lusitanian basins 1 the early toarcian was characterized by two large perturbations to the carbon cycle a positive trend associated with increased organic matter burial and ocean anoxia and a pronounced negative carbon isotope excursion cie we contrast the geochemical evolution in the carbonate phases of two successions one from the paris basin sancerre core comprising black shales the other from the lusitanian basin peniche section with very minor lithological expression of bottom water anoxia our aim was to identify whether these carbon cycle perturbations were related and differentiate between the common global versus regional expressions of the biogeochemical response and ocean chemistry our results highlight contrasts in timing of different phases of anoxia in both locations through the widely documented negative cie widespread anoxic conditions were not a necessary prerequisite for generating a pronounced cie as required by the recycling so called kuspert model the production of carbonate simultaneously dropped during the 13c negative shift in both locations likely in response to lowered seawater saturation rate induced by substantial absorption of co2 from the atmosphere the recovery interval was accompanied by a rapid reestablishment of seawater alkalinity and primary and carbonate productivity in epicontinental seas as evidenced by high 13c and sr ca in contrast with the more open ocean regime in the lusitanian basin our results confirm that parallels can be draw between the ocean productivity response and feedback during the toarcian cie and the petm both events are characterized by ocean acidification and reduced pelagic calcification followed by a peak in nearshore coccolith productivity which could have helped the recovery from the perturbation

synchrony between early jurassic extinction oceanic anoxic event and the karoo ferrar flood basalt volcanism a well known second order mass extinction took place during the pliensbachian and toarcian stages of the early jurassic first recognized as a minor pliensbachian peak in the global extinction rate it has alternatively been interpreted as a regional response to the early toarcian oceanic anoxic event detailed studies established it as a global long term event spanning five successive ammonoid zones here we present a revised time scale based on highprecision u pb ages resolved to the zone level which suggests that elevated extinction rates were sustained for about 4 m y and peak extinction occurred at 183 ma recent isotopic dating of flood basalts from the southern gondwanan karoo and ferrar provinces documents a culmination in volcanic activity ca 183 ma the onset of volcanism is recorded as an inflection and start of a rapid rise of the seawater 87 sr 86 sr curve the synchrony of voluminous flood basalt eruptions and biotic crises as already noted for three of the major mass extinctions permits a causal relationship which in this case may be mediated by widespread oceanic anoxia

osmium isotope evidence for the regulation of atmospheric co2 by continental weathering the long term stability of earth9s climate throughout the phanerozoic stands in marked contrast to the dramatic fluctuations that have taken place on time scales as short as a few years reflecting the high efficiency of longer term climate regulation through negative feedbacks a fundamental mechanism is thought to involve control of co 2 in the ocean atmosphere system through continental weathering although unambiguous high resolution data supporting this hypothesis have hitherto not been available organic rich mud rocks from yorkshire england which were deposited during the toarcian oceanic anoxic event ca 181 ma early jurassic contain evidence of an exceptionally large excursion in the 187 os 188 os ratio of contemporaneous seawater from 0 4 to 1 0 the most likely explanation for this excursion is that it resulted from a transient increase in global continental weathering rates of 400 800 the os isotope excursion coincided with a well documented global 13 c excursion of 6 that affected all the major biospheric reservoirs of the time higher mean global temperatures caused global chemical weathering rates to increase substantially while in turn chemical weathering was very effective in reducing the elevated levels of atmospheric co 2 and the high temperatures to preexcursion levels

massive dissociation of gas hydrate during a jurassic oceanic anoxic event in the jurassic period the early toarcian oceanic anoxic event about 183 million years ago is associated with exceptionally high rates of organic carbon burial high palaeotemperatures and significant mass extinction heavy carbon isotope compositions in rocks and fossils of this age have been linked to the global burial of organic carbon which is isotopically light in contrast examples of light carbon isotope values from marine organic matter of early toarcian age have been explained principally in terms of localized upwelling of bottom water enriched in 12c versus 13c refs 1 2 5 6 here however we report carbon isotope analyses of fossil wood which demonstrate that isotopically light carbon dominated all the upper oceanic biospheric and atmospheric carbon reservoirs and that this occurred despite the enhanced burial of organic carbon we propose that as has been suggested for the late palaeocene thermal maximum some 55 million years ago the observed patterns were produced by voluminous and extremely rapid release of methane from gas hydrate contained in marine continental margin sediments

calcareous nannoplankton changes across the early toarcian oceanic anoxic event in the western tethys 1 calcareous nannoplankton were profoundly affected by environmental perturbations coincident with the early toarcian oceanic anoxic event t oae we quantify the abundance of nannofossils across the t oae at three locations in western europe where the event is marked by a prominent negative carbon isotope excursion cie data were treated by statistical analysis and the shannon diversity index was applied in order to describe nannofossil assemblage changes related to paleoenvironmental evolution in the basal toarcian before the t oae high proportions of taxa with an affinity for low temperature e g p liasicus t patulus bussonius occurred this observation is consistent with interpretations of published oxygen isotope records during the t oae the lowest abundance of nannofossils is observed but there is a peak of a coccolith calyculus from an organism that probably thrived in low saline surface waters depleted of nitrate at the end of the perturbation the lowest diversities of nannofossils occurred and assemblages are dominated by crepidolithus crassus a deep dweller this interval corresponded to progressive reoxygenation of deep water and the reoccupation of the deep photic zone by nannoplankton the highest abundance of nannofossils is recorded above the cie and testifies to the recovery of the entire nannoplankton community the t oae was widespread perhaps global and probably linked to major changes in the atmosphere and hydrosphere however the record of this event varies in the basins surrounding the western tethys suggesting regional imprints on the global signal the regional variability may attest to establishment of effective connections between the arctic and tethys oceans which allowed cool low saline water formed at high latitudes to stream toward the western tethys

first record of the early toarcian oceanic anoxic event from the southern hemisphere neuquen basin argentina abstract the first record of the early toarcian oceanic anoxic event c 183 ma from the southern hemisphere is described from the neuquen basin argentina identified chemostratigraphically on the basis of a relative increase in marine organic carbon and a characteristic negative carbon isotope excursion 13 c org in bulk rock and fossil wood the negative excursion of 6 in bulk organic carbon falling to 31 3 crosses the boundary of the tenuicostatum hoelderi andean ammonite zones equivalent to the tenuicostatum falciferum serpentinum zones of europe these data indicate that the early toarcian oceanic anoxic event was a global phenomenon supplementary material a detailed stratigraphic log chemostratigraphic data and nannofossil data are available at http www geolsoc org uk sup18411

phytoplankton evidence for the timing and correlation of palaeoceanographical changes during the early toarcian oceanic anoxic event early jurassic the causes and duration of the early toarcian anoxic event are controversial integration of data from calcareous and organic phytoplankton provides a biochronological framework that allows precise correlations across the western tethys in particular the carinolithus superbus nannofossil zone can be used to correlate the levels enriched in organic matter and the related 13 c negative excursion although a variable duration is given in the literature for this negative excursion it is likely that it lasted between 520 and 650 ka increased atmospheric p co 2 related to excess volcanic emissions magmatic activity in the karoo and ferrar provinces had an impact on climate and ocean chemistry and marked the inception of a biotic crisis affecting many organisms the beginning of the crisis within shallow carbonate platforms documented at southern latitudes predates the levels enriched in organic matter dinoflagellate cysts experienced a decrease in abundance in the c superbus zone until they temporarily disappeared the nannoplankton crisis was twofold a decrease in size and low calcified specimens are observed in addition to a drastic decrease in absolute abundance the increased atmospheric p co 2 as a result of the magmatic activity and temporarily amplified by transient methane release could have been the trigger for the biocalcification crisis which first affected the probably more reactive neritic system and eventually the nannoplankton community

how the quaternary climatic change affects present hydrogeological system on the chinese loess plateau a case study into vertical variation of permeability of the loess palaeosol sequence abstract this article systematically investigated permeability porosity carbonate mass percentage and magnetic susceptibility of representative loess palaeosol layers from l1 to s4 on the chinese loess plateau based on analysing a sequence on the luochuan yuan tableland as a case study the results of in situ permeability measurements illustrate that average infiltration rate of loess layers is higher than that of palaeosol layers and that average time for the loess layers to reach quasi steady infiltration is longer than that of palaeosol layers in addition loess layers have higher porosity than palaeosols on average and it is suggested as a major reason why the loess layers have a higher permeability on average despite complex nature of different types of the interspaces higher porosity i e more interspaces for storing moisture water of the loess layers is largely determined by lower intensity of pedogenesis of loess which is in turn ascribed to the colder drier palaeoclimatic conditions the difference of permeability between loess and palaeosol layers facilitates the loess units more likely to be aquifers in this regard the quaternary climatic change theory can make a contribution to hydrogeology of the chinese loess plateau and the regional climatostratigraphy can be regarded as a baseline for local water resource positioning and revegetation in such a semi arid area

hydrothermal venting of greenhouse gases triggering early jurassic global warming abstract the climate change in the toarcian early jurassic was characterized by a major perturbation of the global carbon cycle the event lasted for approximately 200 000 years and was manifested by a global warming of 6 c anoxic conditions in the oceans and extinction of marine species the triggering mechanisms for the perturbation and environmental change are however strongly debated here we present evidence for a rapid formation and transport of greenhouse gases from the deep sedimentary reservoirs in the karoo basin south africa magmatic sills were emplaced during the initial stages of formation of the early jurassic karoo large igneous province and had a profound influence on the fate of light elements in the organic rich sedimentary host rocks total organic carbon contents and vitrinite reflectivity data from contact aureoles around the sills show that organic carbon was lost from the country rocks during heating we present data from a new type of geological structures termed breccia pipes rooted in the aureoles within the shale of the western karoo basin the breccia pipes are cylindrical structures up to 150 meters in diameter and are mainly comprised of brecciated and baked black shale thousands of breccia pipes were formed due to gas pressure build up during metamorphism of the shales resulting in venting of greenhouse gases to the toarcian atmosphere mass balance calculations constrained by new aureole data show that up to 1800 gt of co2 was formed from organic material in the western karoo basin about 15 times this amount of co2 27 400 gt may have formed in the entire basin during the intrusive event u pb dating of zircons from a sill related to many of the pipes demonstrates that the magma was emplaced 182 5 0 4 million years ago this supports a causal relationship between the intrusive volcanism the gas venting and the toarcian global warming

calcareous nannoplankton response to surface water acidification around oceanic anoxic event 1a ocean acidification induced by atmospheric co2 may be a major threat to marine ecosystems particularly to calcareous nannoplankton we show that during the aptian 120 million years ago oceanic anoxic event 1a which resulted from a massive addition of volcanic co2 the morphological features of calcareous nannofossils traced the biological response to acidified surface waters we observe the demise of heavily calcified nannoconids and reduced calcite paleofluxes at the beginning of a pre anoxia calcification crisis ephemeral coccolith dwarfism and malformation represent species specific adjustments to survive lower ph whereas later abundance peaks indicate intermittent alkalinity recovery deepwater acidification occurred with a delay of 25 000 to 30 000 years after the dissolution climax nannoplankton and carbonate recovery developed over 160 000 years under persisting global dysoxia anoxia

40ar 39ar ages of the sill complex of the karoo large igneous province implications for the pliensbachian toarcian climate change 1 reliable geochronological results gathered so far n 76 have considerably constrained the timing of the emplacement of the karoo large igneous province lip yet strikingly missing from this dating effort is the huge southern sill complex cropping out in the 0 6 106 km2 main karoo sedimentary basin we present 16 new 40ar 39ar analyses carried out on fresh plagioclase and biotite separates from 15 sill samples collected along a n s trend in the eastern part of the basin the results show a large range of plateau and miniplateau ages 176 2 1 3 to 183 8 2 4 ma with most dates suggesting a 3 ma 181 184 ma duration for the main sill events the available age database allows correlation of the karoo lip emplacement with the pliensbachian toarcian second order biotic extinction the global warming and the toarcian anoxic event provided that adequate calibration between the 40k and 238u decay constant is made the mass extinction and the isotopic excursions recorded at the base of the toarcian appear to be synchronous with both the increase of magma emission of the karoo lip and the emplacement of the sills the co2 and so2 derived from both volcanic emissions as well as carbon rich sedimentary layers intruded by sills might be the main culprits of the pliensbachian toarcian climate perturbations we propose that the relatively low eruption rate of the karoo lip is one of the main reasons explaining why its impact on the biosphere is relatively low contrary to e g the camp triassic jurassic and siberia permo triassic lips

the isotopic signature of the global riverine molybdenum flux and anoxia in the ancient oceans despite important biological and biogeochemical consequences of extensive ocean anoxic events their identification is controversial the marine isotope geochemistry of molybdenum can help quantify the past oxygenation state of the ocean if the riverine input of mo isotopes is known analysis of a set of rivers that account for 28 of global river runoff suggests more variable mo isotopic ratios in rivers that are also isotopically enriched in the heavy isotopes suggesting near total anoxia in the proterozoic ocean and during mesozoic ocean anoxic events despite its important biological and biogeochemical consequences1 2 3 the identification of extensive oceanic anoxia in the geological record is controversial in particular global anoxia is difficult to distinguish from spatially restricted anoxia in the deep ocean or in tectonically isolated basins such as the modern black sea the marine isotope geochemistry of molybdenum mo can help quantify the past oxygenation state of the ocean4 5 6 7 8 9 10 11 12 13 14 because to first approximation under oxic conditions lighter isotopes of mo are preferentially removed to sediments whereas in euxinic conditions quantitative removal leads to no fractionation however the isotopic composition of the mo input from rivers the main contributor of mo to the oceans is poorly constrained and had been assumed to be isotopically comparable to the narrow range found in a small dataset of continental rocks4 5 6 7 8 9 10 11 12 13 14 here we present an isotopic analysis of mo in a set of rivers that together account for 22 of the global riverine water discharge we find a broad range of variability in the mo isotopic composition of these rivers with almost all samples enriched in the heavy isotopes compared with continental rocks our data remove key uncertainties associated with the marine mo isotope budget14 and strongly suggest near total anoxia in the mid proterozoic ocean8 as well as during mesozoic ocean anoxic events13

polar record of early jurassic massive carbon injection abstract the toarcian oceanic anoxic event t oae ca 182 myr early jurassic represents one of the best recognized examples of greenhouse warming decreased seawater oxygenation and mass extinction the leading hypothesis to explain these changes is the massive injection of thermogenic or gas hydrate derived 13 c depleted carbon into the atmosphere resulting in a 3 per mil negative carbon isotope excursion cie accelerated nutrient input and dissolved oxygen consumption in the oceans nevertheless the lack of a precisely dated record of the t oae outside low latitudes has led to considerable debate about both its temporal and spatial extent and hence concerning its underlying causes here we present new isotopic and lithological data from three precisely dated n siberian sections which demonstrate that mass extinction and onset of strong oxygen deficiency occurred near synchronously in polar and most tropical sites and were intimately linked to the onset of a marked 6 negative cie recorded by bulk organic carbon rock eval pyrolysis data from siberia and comparisons with low latitudes show that the cie cannot be explained by the extent of stratification of the studied basins or changes in organic matter sourcing and suggest that the negative cie reflects rapid 13 c depleted carbon injection to all exchangeable reservoirs sedimentological and palynological indicators show that the injection coincided with a change from cold abundant glendonites and exotic boulder sized clasts to exceptionally warm conditions dominance of the thermophyllic pollen genus classopollis in the arctic which likely triggered a rapid possibly partly glacioeustatic sea level rise comparisons with low latitude records reveal that warm climate conditions and poor marine oxygenation persisted in continental margins at least 600 kyr after the cie features that can be attributed to protracted and massive volcanic carbon dioxide degassing our data reveal that the t oae profoundly affected arctic climate and oceanography and suggest that the cie was a consequence of global and massive 13 c depleted carbon injection

interpreting carbon isotope excursions carbonates and organic matter abstract variations in the carbon isotopic compositions of marine carbonate and organic carbon provide a record of changes in the fraction of organic carbon buried through time and may provide clues to changes in rates of weathering and sources of organic carbon paired carbonate and organic carbon isotope determinations provide a possibility of interpreting not only changes in the global carbon cycle through time but changes in atmospheric pco2 as well interpretations of these types of data are typically rather qualitative a quantitative basis is required to develop a better understanding of changes in the carbon cycle for this purpose we employ a simple model of the global carbon cycle which is subjected to a number of different perturbations each lasting 500 ky i e much longer than the residence times of carbon and phosphorus in the ocean atmosphere system in addition to standard considerations of carbon mass and isotopic fluxes to the ocean atmosphere system from weathering and volcanism and fluxes of organic carbon and carbonate carbon to sediments the model incorporates sensitivity of the photosynthetic carbon isotope effect to changes in pco2 the inclusion of this parameter leads to unexpected carbon isotope responses to forcing that causes increased rates of organic carbon burial a series of simple to more complex simulations illustrates the significant effects of varying differences between the carbon isotopic composition of sedimented carbonate and organic carbon b with constant b a 50 increase in organic carbon burial produces a parallel increase in carbonate and organic carbon isotopic compositions however the same simulation with b responsive to pco2 changes produces an initial parallel 13 c increase but this is followed by an even greater 13 c enrichment in organic carbon because pco2 falls in response to increased organic carbon burial the counterintuitive overall result of the enhanced organic carbon burial event is that the carbonate carbon isotopic composition actually decreases because of the more substantial increase in 13 c org in addition we illustrate the effects on carbon isotopic compositions of the oceanic inorganic carbon reservoir and buried organic matter of a 50 increase in volcanic co2 outgassing a 50 increase in weathering rate with coupled phosphate and riverine carbon flux responses a 50 decrease in shale associated organic carbon weathering a 50 decrease in silicate weathering rate and the possible effects of the rise in abundance of c4 plants in the late miocene to recent we compare the model simulated carbon isotopic responses for some of these experiments to paired carbonate and organic carbon records to illustrate how these records might be interpreted in light of the model response

expression of the early toarcian negative carbon isotope excursion in separated carbonate microfractions jurassic paris basin abstract the causes of the pronounced negative excursion in carbon isotope values that was recorded during the early toarcian oceanic anoxic event t oae are still under debate particularly with regard to the local versus global pattern of the excursion and the extent to which recorded signals are under a diagenetic control in this study we employ a novel microseparation technique in order to investigate the isotopic and mineralogical characteristics of different size fractions of the carbonate content from a toarcian section recovered from the sancerre couy borehole southern paris basin beyond the recognition of a 6 13 c excursion in the bulk carbonate content our data also demonstrate that biogenic particles such as coccoliths and inorganic grains precipitated as early diagenetic phases including dolomite both record the excursion with the same magnitude although several black shales occur through the paris basin toarcian section it is only that associated with the onset of the oae that coincides with a large negative carbon isotope excursion taken together these observations indicate that during this event the entire water column was characterized by homogeneous carbon isotope values such a pattern is incompatible with the idea that the negative excursion was generated simply through the upwelling of bottom waters enriched in re mineralized organic carbon cf the kuspert model since this would have required a strong vertical gradient in the water column additionally the paris basin data show that the decrease in carbonate 13 c values during the oae occurred in several discrete steps each of some 2 as has previously been found for organic carbon substrates in other european sections the stepped nature of the isotopic profile which is part of a stratigraphic signature previously ascribed to milankovitch forcing is compatible with regular pulsed input of light carbon into the whole atmosphere ocean system from a climatically sensitive source such as gas hydrate or from thermal methanogenesis of organic rich sediments in the karoo ferrar large igneous province contrasts in the amplitude of the negative carbon isotope excursion on a regional scale remain an important unexplained aspect of the toarcian record

black shale deposition atmospheric co2 drawdown and cooling during the cenomanian turonian oceanic anoxic event 1 oceanic anoxic event 2 oae2 spanning the cenomanian turonian boundary ctb represents one of the largest perturbations in the global carbon cycle in the last 100 myr the 13ccarb 13corg and 18o chemostratigraphy of a black shale bearing ctb succession in the vocontian basin of france is described and correlated at high resolution to the european ctb reference section at eastbourne england and to successions in germany the equatorial and midlatitude proto north atlantic and the u s western interior seaway wis 13c offset between 13ccarb and 13corg is shown to be a good pco2 proxy that is consistent with pco2 records obtained using biomarker 13c data from atlantic black shales and leaf stomata data from wis sections boreal chalk 18o records show sea surface temperature sst changes that closely follow the 13c pco2 proxy and confirm tex86 results from deep ocean sites rising pco2 and sst during the late cenomanian is attributed to volcanic degassing pco2 and sst maxima occurred at the onset of black shale deposition followed by falling pco2 and cooling due to carbon sequestration by marine organic productivity and preservation and increased silicate weathering a marked pco2 minimum 25 fall occurred with a sst minimum plenus cold event showing 4 c of cooling in 40 kyr renewed increases in pco2 sst and 13c during latest cenomanian black shale deposition suggest that a continuing volcanogenic co2 flux overrode further drawdown effects maximum pco2 and sst followed the end of oae2 associated with a falling nutrient supply during the early turonian eustatic highstand

sedimentation de la matiere organique dans le nord est du bassin de paris consequences sur le depot des argilites carbonees du toarcien inferieur organic matter sedimentation in the northeast of the paris basin consequences on the deposition of the lower toarcian black shales abstract a borehole realised by the agence nationale pour la gestion des dichets radioactifs andra near the village of montcomet aisne in the paris basin allowed to core about 1 km of jurassic series the organic matter om associated to the drilled series has been characterised by various well proven methods rock eval pyrolysis palynofacies study and saturated hydrocarbon analysis the series received variable but notable amounts of inputs of om of terrestrial origin during all the jurassic these inputs probably originated from the ardennes massif near the study area the conditions of preservation of these inputs being poor during the early jurassic improved markedly at the beginning of the domerian and then apparently remained rather constant at least up to the callovian during three distinct and rather well limited periods important amounts of algae derived om added to the background of terrestrial om the most important and the best known of these episodes corresponds to the black shales of the base of the lower toarcian lateral equivalent of the well known schistes carton these results suggest that in the paris basin the deposition of om rich sediments occurred during episodes of high planktonic production happening when medium conditions were favourable to om preservation the quantitative and qualitative fluctuations of the om all along the studied series accompany and describe three of the large transgression regression cycles recently evidenced in the paris basin guillocheau 1991 late carnian toarcian aalenian bathonian and callovo oxfordian one episode of accumulation of planktonic om appears to have occurred in each of these cycles in the neighbourhood of transition transgression regression in the present state of knowledge only the confinement behind sills in a structured basin seems capable of explaining the triggering of episodes of planktonic production in the paris basin these conditions of confinement appear to have mainly resulted from a notable structuration of the platforms and of the adjacent troughs due to 1 subsidence during the tectonic cycles and 2 to distensive tectonic activity during tectono eustatic cycles

astronomical forcing and chronology of the early toarcian early jurassic oceanic anoxic event in yorkshire uk 1 during the early toarcian 183 ma ago a high rate of organic carbon burial globally over a brief interval of time has led to the recognition of a major oceanic anoxic event oae a pronounced negative excursion in the carbon isotope composition of marine organic matter marine carbonate and terrestrial plant material is a key feature of this event but the precise timescale and cause s of this isotopic anomaly are debated associated with the negative carbon isotope excursion is evidence for a coeval rise in seawater palaeotemperature an increase in continental weathering rates and the mass extinction of marine invertebrate species the early toarcian oae provides evidence for the earth s response during rapid climate change and critical to our understanding of the event is a high resolution timescale that allows us to quantify the rates duration and lead lag times of environmental processes in this study we present 2743 new high resolution organic carbon sulphur and carbonate concentration data from samples of well preserved organic rich mudrocks spanning the early toarcian oae in yorkshire uk we have used these data to document the geochemical changes and significantly extend and refine the astronomical timescale across this event our detailed analysis of the relationship between astronomical forcing and carbon isotope changes in both yorkshire and a section from peniche portugal indicates that astronomical forcing paced the timing of major shifts in 13c and hence climate in both sections our analyses also demonstrate that there was a marked increase in the relative strength of astronomical forcing recorded at the onset of the oae and that the recorded nature of astronomical forcing changed during the event both the yorkshire and peniche cyclostratigraphies suggest that one astronomical forcing parameter paced environmental change through the 13c event and that this parameter was obliquity or precession

the significance of an early jurassic toarcian carbon isotope excursion in haida gwaii queen charlotte islands british columbia canada abstract during the early toarcian there was a significant disruption in the short term active carbon reservoir as revealed by carbon isotope records which show a broad positive shift that is interrupted by a large 5 7 negative excursion 13 c org carbon isotope excursion co occurs with the deposition of organic rich shales in many areas this perturbation in carbon isotopes is thought to be indicative of severe climate change and marine anoxia the two leading hypotheses as to the cause of this event invoke either global or regional controls here we present carbon isotope data from haida gwaii british columbia canada showing a significant perturbation within a temporally constrained early toarcian succession that was deposited in the northeastern paleo pacific ocean these data reinforce the concept that the short term active carbon reservoir was affected globally and assist with the correlation of ammonite zonal schemes between western north america and europe the 13 c org data show a broad positive shift that is interrupted by a sharp and pronounced negative excursion of 7 8 5 in 13 c wood in the early toarcian kanense zone this negative excursion also coincides with increasing total organic carbon toc from 0 4 to 1 2 these data suggest that the early toarcian carbon isotope perturbation was indeed global and imprinted itself on all active global reservoirs of the exchangeable carbon cycle deep marine shallow marine atmospheric

basinal restriction black shales re os dating and the early toarcian jurassic oceanic anoxic event 1 profiles of mo total organic carbon toc through the lower toarcian black shales of the cleveland basin yorkshire united kingdom and the posidonia shale of germany and switzerland reveal water mass restriction during the interval from late tenuicostatum zone times to early bifrons zone times times which include that of the putative early toarcian oceanic anoxic event the degree of restriction is revealed by crossplots of mo and toc concentrations for the cleveland basin which define two linear arrays with regression slopes ppm of 0 5 and 17 the slope of 0 5 applies to sediment from the upper semicelatum and exaratum subzones this value which is one tenth of that for modern sediments from the black sea mo toc regression slope 4 5 reveals that water mass restriction during this interval was around 10 times more severe than in the modern black sea the renewal frequency of the water mass was between 4 and 40 ka the mo toc regression slope of 17 applies to the overlying falciferum and commune subzones the value shows that restriction in this interval was less severe and that the renewal frequency of the water mass was between 10 and 130 years the more restricted of the two intervals has been termed the early toarcian oceanic anoxic event but is shown to be an event caused by basin restriction local to nw europe crossplots of re os and mo against toc show similar trends of increasing element concentration with increase in toc but with differing slopes together with modeling of 187 os 188 os and d 98 mo the element toc trends show that drawdown of re os and mo was essentially complete during upper semicelatum and exaratum subzone times mo toc regression slope of 0 5 drawdown sensitized the restricted water mass to isotopic change forced by freshwater mixing so that continental inputs of re os and mo via a low salinity surface layer created isotopic excursions of up to 1 3 in d 98 mo and up to 0 6 for 187 os 188 os restriction thereby compromises attempts to date toarcian black shales and possibly all black shales using re os chronology and introduces a confounding influence in the attempts to use d 98 mo and initial 187 os 188 os for palaeo oceanographic interpretation

stepwise atmospheric carbon isotope excursion during the toarcian oceanic anoxic event early jurassic polish basin abstract during the mesozoic 250 64 ma intervals of about 0 5 myr were subject to severe environmental changes including high sea surface temperature and very low oxygen content of marine water these oceanic anoxic events or oaes occurred simultaneously with profound disturbance to the carbon cycle the carbon isotope anomaly in the early jurassic that marks the toarcian oceanic anoxic event t oae at 182 ma is characterized in marine sections by a series of dramatic steps towards lighter values herein we present new carbon isotope data from terrestrial organic matter phytoclast separates collected through a late pliensbachian middle toarcian coastal and marginal marine succession in the polish basin a setting where hinterland climate and sea level change are well recorded the results show that the shift to light carbon isotope values in the woody organic matter and therefore also in atmospheric carbon dioxide similarly occurred in major steps the steps are here correlated with those identified from marine organic matter where they have previously been attributed to 100 kyr eccentricity forcing of climate the results provide strong support for orbitally and climatically controlled release of isotopically light carbon from gas hydrates into the ocean atmosphere system in a series of rapid bursts additionally a link between the carbon isotope steps and shoreline movements can be demonstrated individual peaks of the negative excursion are mostly associated with facies indicative of sea level rise flooding surfaces however at the same time inferred higher atmospheric carbon dioxide content may be expected to have resulted in increased rainfall and temperature leading to accelerated weathering and erosion and consequently increased sediment supply progradation and regression causing some mismatches between isotope shifts and inferred sea level changes enhanced abundance of megaspores derived from hydrophilic plant groups and marked increase in kaolinite are coincident with the overall development of the negative isotope excursion the combined data suggest that each 100 kyr cycle in carbon isotope values was characterized by increasingly severe palaeoclimatic change culminating in extremely hot and humid conditions co incident with the peak of the final most negative carbon isotope excursion the chemostratigraphic correlation allows very precise dating of the late pliensbachian middle toarcian coastal and marginal marine sedimentary succession in the polish basin

rapid warming and salinity changes of cretaceous surface waters in the subtropical north atlantic paleomarine carbon isotopic records reveal occasional and rapid release of greenhouse gases into the atmosphere the regional consequences on surface ocean properties and time relationships between the atmosphere and the ocean however are still far from understood we observe a sudden 1 5 shift in leaf wax n alkane 13c values at the onset of oceanic anoxic event oae 1b from early albian sediments off northwest africa deep sea drilling project site 545 that is best explained by the rapid release of isotopically light carbon into the cretaceous atmosphere this 1 5 shift in the n alkanes precedes a negative isotope excursion of similar magnitude observed in marine carbonate organic matter and algal steranes a tex86 based record of sea surface temperature sst confirms almost instantaneous warming by 3 5 c along with the marine isotope shifts at site 545 paralleled by an 2 c tex86 sst increase and a freshening of surface water salinity from 43 to 41 at blake nose ocean drilling program site 1049 multiproxy evidence indicates that once established these warm ssts prevailed and were stable during oae 1b suggesting that the emission of 13c depleted carbon started abruptly but then continued over tens of thousands of years the sst cooled by 1 2 c at the end of the event not reaching pre excursion levels the new records provide evidence for a time lag best estimate 1 3 k y between atmospheric and oceanic processes that we interpret as a direct response to changes in the atmospheric greenhouse gas concentrations followed by propagation into the ocean and subsequent heating of surface waters

a global perturbation to the sulfur cycle during the toarcian oceanic anoxic event abstract the mesozoic era was punctuated by intervals of widespread anoxia within the ocean termed oceanic anoxic events or oaes the chemostratigraphy of these intervals also contains evidence of transient perturbations to many biogeochemically important elemental cycles here we present high resolution sulfur isotope data from three stratigraphic sections spanning the toarcian oceanic anoxic event t oae of the early jurassic all sections show a similar increase in the sulfur isotope ratio of sulfate parallel to an overall positive excursion in carbon isotopes during the oae interval based on forward box modeling the sulfate s isotope excursion can be generated by transiently increasing the burial rate of pyrite in marine sediments likely deposited under euxinic i e anoxic and sulfidic conditions in the water column in addition modeling shows that prolonged recovery of the 34 s of seawater sulfate at least 8 ma after the initial rise associated with the oae was due to the relatively long residence time of sulfate in the jurassic ocean estimates from our modeling put the toarcian marine sulfate concentrations at 4 to 8 mm the similarity of the sulfur isotope records from the north european epicontinental or epeiric sea and tethyan continental margin suggests that local modification of the marine sulfur isotope signal was minimal a point explored with isotope mixing models importantly our results indicate that the sulfur isotope excursion reflects a globally significant perturbation in the sulfur cycle and that pyrite burial in the north european epeiric seaway alone cannot account for the excursion this study along with recent work from other phanerozoic intervals of widespread marine oxygen deficiency confirms that the sulfur cycle can be perturbed significantly by enhanced pyrite burial during periods of prolonged oceanic anoxia euxinia

holocene mass wasting on upper non polar continental slopes due to post glacial ocean warming and hydrate dissociation 1 incorporating both late post glacial bottom water warming and eustatic sealevel rise into a mh methane hydrate stability model explains why at least some major submarine landslides e g the storegga slide norwegian margin may have been triggered by mh dissociation during the early holocene rising sealevels not during the lowest sealevels of the lgm last glacial maximum 18 20 ka in the case of storegga failure may have been initiated either below the upper slope or under the shelf for fresh pore water especially with admixed ethane at water depths below ca 800m persistent low bottom water temperatures allowed the sealevel rise to thicken the mh stability zone over time ruling out holocene initiation of failure mh release by holocene mass wasting cannot have initiated deglaciation

molybdenum isotope evidence for global ocean anoxia coupled with perturbations to the carbon cycle during the early jurassic relatively brief periods of severe paleoenvironmental change during the jurassic and cretaceous were associated with the widespread accumulation of organic rich marine deposits termed oceanic anoxic events oaes these intervals involved abrupt global warming of 5 10 c higher rates of continental weathering elevated extinction rates and large scale perturbations to the global carbon cycle the major oaes also overlapped temporally the emplacement of large igneous provinces however despite being known as oaes the extent of seawater anoxia at those times is undefined and the causative processes remain unclear here we show how changes in seawater molybdenum isotope ratios a proxy for seawater anoxia during the toarcian early jurassic oae define the onset and expansion of oxygen deficient conditions our data also place constraints on the areal extent of marine anoxia during the event and demonstrate that anoxia expanded and contracted periodically broadly in line with precession driven changes in 13 corg despite their intermittent occurrence over geological history oaes have an important contemporary relevance because the magnitude and high rates of environmental change then were broadly similar to those occurring at the present day