shallow marine carbon and oxygen isotope and elemental records indicate icehouse greenhouse cycles during the early jurassic 1 for much of the mesozoic record there has been an inconclusive debate on the possible global significance of isotopic proxies for environmental change and of sequence stratigraphic depositional sequences we present a carbon and oxygen isotope and elemental record for part of the early jurassic based on marine benthic and nektobenthic molluscs and brachiopods from the shallow marine succession of the cleveland basin uk the invertebrate isotope record is supplemented with carbon isotope data from fossil wood which samples atmospheric carbon new data elucidate two major global carbon isotope events a negative excursion of 2 at the sinemurian pliensbachian boundary and a positive excursion of 2 in the late pliensbachian the sinemurian pliensbachian boundary event is similar to the slightly younger toarcian oceanic anoxic event and is characterized by deposition of relatively deepwater organic rich shale the late pliensbachian strata by contrast are characterized by shallow marine deposition oxygen isotope data imply cooling locally for both events however because deeper water conditions characterize the sinemurian pliensbachian boundary in the cleveland basin the temperature drop is likely of local significance in contrast a cool late pliensbachian shallow seafloor agrees with previous inference of partial icehouse conditions both the large scale long term and small scale short duration isotopic cycles occurred in concert with relative sea level changes documented previously from sequence stratigraphy isotope events and the sea level cycles are concluded to reflect processes of global significance supporting the idea of an early jurassic in which cyclic swings from icehouse to greenhouse and super greenhouse conditions occurred at timescales from 1 to 10 ma

ross ice shelf oxygen isotopes and west antarctic climate history the ross ice shelf 18o profile at station j 9 covers at least the last 30 000 yr it identifies the depth in the core of ice from i the last glacial interglacial transition 266 to 286 m and ii the 1000 m surface elevation about 140 m various processes contribute to the 18o change observed in the core i climatic warming mainly caused by a decrease in winter sea ice extent around antarctica of about 6 latitude early in the glacial interglacial transition ii decreasing ice sheet thickness later in the glacial interglacial transition and during the holocene and iii decreases in elevation and effective distance from the open ocean as the source of the ice in the core shifts along the flow line toward j 9 average 18o values of the last 3000 yr imply a fairly stable climate yet shorter 102 to 103 yr 18o climatic oscillations up to 6 are seen in both the holocene and the glacial portion of the record

spatial variability of watermass conditions within the european epicontinental seaway during the early jurassic pliensbachian toarcian in order to constrain spatial variability in watermass conditions within the european epicontinental seaway prior to during and after the toarcian oceanic anoxic event carbon 13cbel 13ccarb and oxygen 18obel 18ocarb isotope records were obtained from three sections in the grands causses basin southern france these data were then compared with similar records along a north south transect across the european epicontinental seaway as the conclusions reached here strongly depend on the reliability of belemnite calcites as archives of palaeoceanographic changes an attempt was made to improve the understanding of isotope signals recorded in belemnite calcite intra rostral carbon and oxygen isotope data from six belemnite specimens belonging to the genus passaloteuthis were collected intra rostral carbon isotopes are influenced by vital effects whereas oxygen isotopes reflect relative changes in temperature and salinity palaeotemperatures calculated from 18obel isotope records from the grands causses basin confirm relatively low temperatures throughout the late pliensbachian similar cool water conditions have previously been shown in germany england spain and portugal a temperature increase of up to 6 c is observed across the pliensbachian toarcian boundary a pronounced negative shift of at least 3 vienna pee dee belemnite is recorded in bulk carbonate carbon during the lower harpoceras serpentinum zone typical of the toarcian oceanic anoxic event before and after the toarcian oceanic anoxic event a good correlation between 13ccarb and 13cbel exists indicating well ventilated bottom waters and normal marine conditions instead data for the toarcian oceanic anoxic event indicate the development of a strong north south gradient in salinity stratification and surface water productivity for the western tethyan realm this study thus lends further support to a pronounced regional overprint on carbon and oxygen isotope records in epicontinental seaways

the flux of small near earth objects colliding with the earth asteroids with diameters smaller than approximately 50 100 m that collide with the earth usually do not hit the ground as a single body rather they detonate in the atmosphere these small objects can still cause considerable damage such as occurred near tunguska siberia in 1908 the flux of small bodies is poorly constrained however in part because ground based observational searches pursue strategies that lead them preferentially to find larger objects a tunguska class event the energy of which we take to be equivalent to 10 megatons of tnt was previously estimated to occur every 200 300 years with the largest annual airburst calculated to be approximately 20 kilotons kton tnt equivalent ref 4 here we report satellite records of bolide detonations in the atmosphere over the past 8 5 years we find that the flux of objects in the 1 10 m size range has the same power law distribution as bodies with diameters 50 m from this we estimate that the earth is hit on average annually by an object with approximately 5 kton equivalent energy and that tunguska like events occur about once every 1 000 years

lower jurassic epicontinental carbonates and mudstones from england and wales chemostratigraphic signals and the early toarcian anoxic event sections through lower jurassic epicontinental carbonates from southern britain junction bed and equivalent show a positive carbon isotope excursion 13ccarbonate detectable in bulk rock in the falciferum zone of the lower toarcian isotopic data from organic matter in more clay rich sections from wales and north east england together with determinations on belemnite calcite indicate that highest 13c values are localized in the upper exaratum subzone of the falciferum zone levels of particular enrichment in organic carbon were developed in the early to mid exaratum subzone and hence pre date this 13c maximum these phenomena reflect the impact of the early toarcian oceanic anoxic event in the british area similar isotopic trends have been recorded in other toarcian sections from tethyan europe and are interpreted as reflecting the chemistry of sea water on the assumption of isotopic correlation between the english and tethyan sections the 13c maximum would be everywhere dated as latest exaratum subzone in terms of the north european ammonite scheme absolute oxygen isotope values in carbonates probably reflect both early diagenetic cementation and later temperature related burial diagenesis although a palaeotemperature maximum is tentatively identified as characterizing the early falciferum zone subsequent climatic deterioration may have been triggered by drawdown of co2 related to regional excess carbon burial during the oceanic anoxic event using the positive 13c excursion as a correlative level in sections from different faunal provinces britain italy and spain implies that lower toarcian zonal stratigraphy is diachronous between northern and southern europe there is evidence for partitioning of water masses between the north european shelf and the tethyan continental margin during the early jurassic

chemostratigraphy of the jurassic system applications limitations and implications for palaeoceanography current chemostratigraphical studies of the jurassic system primarily involve the use of one sedimentary component marine organic carbon one divalent transition metal substituted in carbonate manganese and two isotopic tracers strontium isotope ratios 87 sr 86 sr and carbon isotope ratios 13 c carb and 13 c org in carbonate and in organic matter other parameters such as mg ca and sr ca ratios in calcite oxygen isotope ratios 18 o in carbonate sulphur isotope ratios 34 s in carbonate hosted sulphate nitrogen isotope ratios 15 n org in organic matter osmium isotope ratios 187 os 188 os in black shales and neodymium isotope ratios 143 nd 144 nd in various mineral phases are also useful but at present give poor resolution because the database is incomplete or compromised by various factors stratigraphical patterns in total organic carbon toc can be of either local or regional significance depending on the lateral extent of the former nutrient rich and productive water mass divalent manganese follows a similar pattern being concentrated most probably as a very early diagenetic phase only in oxygen depleted waters that typically underlie zones of elevated organic productivity shifts in mg ca and sr ca ratios on the time scale of ammonite subzones seem largely to reflect temperature changes strontium isotope ratios from pristine skeletal calcite provide a global signal 13 c values from carbonates with minimal diagenetic overprint potentially do the same although small spatial differences in palaeo water mass composition may have been locally significant oxygen isotope determinations on carbonate rocks and fossils generally yield values that are too scattered to be stratigraphically useful because they reflect palaeotemperature the evaporation precipitation balance in sea water and the impact of any diagenesis involving an aqueous phase nitrogen isotope ratios in organic matter reflect the chemistry of ancient water masses as affected by nitrate utilization and denitrification and the stratigraphical pattern of this parameter is more likely to correlate only on a regional basis neodymium isotope ratios in sea water are also water mass dependent and greatly affected by regional sources and oceanic current systems preliminary data on sulphur isotope ratios in carbonates and osmium isotope ratios in organic rich shales both potentially offering global correlation indicate that these tracers may be valuable although the records at present are not sufficiently well established to allow high resolution regional correlation in all cases biostratigraphically well dated reference sections against which the relevant geochemical data have been calibrated are required in the first instance to date studies on the stratigraphical distribution of organic carbon have been principally carried out in both northern boreal and southern tethyan europe carbon isotope stratigraphy has been undertaken primarily but not exclusively on bulk pelagic sediments from the alpine mediterranean or tethyan domain and strontium isotope stratigraphy has been undertaken largely on calcitic skeletal material belemnites and oysters from northern and southern europe in many sections including those containing ammonites multi parameter chemostratigraphy can give resolution that exceeds that attainable by classic biostratigraphical means strontium isotope ratios in skeletal calcite are a particularly powerful tool for illustrating changes in sedimentary rate and revealing gaps in the stratigraphical record

electrical resistivity sounding of the east antarctic ice sheet electrical resistivity soundings using a schlumberger array have been carried out at dome c east antarctica 74 39 s 124 10 e elevation 3400 m to sound the entire 3500 m depth of the ice sheet changes in density and temperature are largely separated in the ice at dome c so activation energies for both firn and ice could be determined we find an activation energy of 0 25 ev in both solid ice and firn between 15 c and 58 c a common value of the activation energy points to a single transport regime in which the charge carriers and conduction paths are the same in firn and ice to evaluate the variation of resistivity with density we have considered five dielectric mixture models that fit the available data on the high frequency dielectric constant of firn only looyenga s equation fits the field data for dc resistivity in the upper 900 m of the ice sheet where impurity concentrations are known from core samples we find no correlation between resistivities and the concentrations of salts or acids instead we find it likely that resistivities are correlated with the crystal size hence with the holocene wisconsin boundary in the ice column a pronounced increase in resistivity to a value comparable with that in temperate glacier ice occurs deep within the ice sheet we attribute this to a large increase in the size and irregularity of the ice crystals which destroys the continuity of the impurity shells surrounding the ice crystals that we believe supply the conduction paths shabtaie and bentley 1994a high resistivity does not imply removal of the impurities from the system moderate concentrations of impurities can be accommodated by locating them in disconnected domains

paleoceanographic changes of the late pliensbachian early toarcian interval a possible link to the genesis of an oceanic anoxic event abstract secular records of the elemental and isotopic composition of belemnite calcite were studied in pliensbachian and toarcian sections from the yorkshire coast uk and southern germany to investigate oceanographic change during an interval prior to and including the toarcian oceanic anoxic event oae records from southern germany are correlated to the uk stratigraphy using strontium isotope stratigraphy the geochemical trends measured from belemnite calcite are consistent between the two sections and are interpreted in terms of temperature and salinity of the northwest european epi continental sea the data suggest that a dramatic environmental change coincided with the toarcian oae belemnite mg ca sr ca and na ca ratios increase by a factor of between 1 7 and 2 coincident with a 3 negative shift in 18o from the mid tenuicostatum zone until the lower falciferum zone of the uk ammonite biostratigraphy a period of 0 6 0 7 myr taken at face value the mg ca and 18o data argue for an abrupt warming of 6 7 c and substantial freshening during this interval global warming accompanied by an accelerated hydrological cycle and increased runoff is proposed to explain these changes prior to these events data from lower in the yorkshire section suggest a possible cooling accompanied by a shift to more saline waters during the period from the upper pliensbachian margaritatus zone to the toarcian lower tenuicostatum zone this earlier event may also have been important in causing density stratification in the northwest european epi continental sea

analysis of a crater forming meteorite impact in peru 1 the fireball producing a crater forming meteorite fall near carancas peru on 15 september 2007 has been analyzed using eyewitness seismic and infrasound records the meteorite impact which produced a crater of 13 5 m diameter is found to have released of order 1010 j of energy equivalent to 2 3 tons of tnt high explosives based on infrasonic measurements our best fit trajectory solution places the fireball radiant at an azimuth of 82 relative to the crater with an entry angle from the horizontal of 63 from entry modeling and infrasonic energetics constraints we find an initial energy for the fireball to be in the 0 06 0 32 kton tnt equivalent the initial velocity for the meteoroid is restricted to be below 17 km s from orbit considerations alone while modeling suggests an even lower best fit velocity close to 12 km s the initial mass of the meteoroid is in the range of 3 9 tons at impact modeling suggests a final end mass of order a few metric tons and impact velocity in the 1 5 4 km s range we suggest that the formation of such a substantial crater from a chondritic mass was the result of the unusually high strength and corresponding low degree of fragmentation in the atmosphere of the meteoritic body additionally the high altitude of the impact site 3800 m a s l resulted in an almost one order of magnitude higher impact speed than would have been the case for the same body impacting close to sea level

paleoenvironmental conditions recorded by 87sr 86sr δ13c and δ18o in late pliensbachian toarcian jurassic belemnites from bulgaria the late pliensbachian toarcian jurassic sedimentological paleontological and geochemical belemnite 87sr 86sr 13c and 18o record is examined in two eastern tethyan bulgarian locations this interval contains the well known early toarcian ocean anoxic event t oae and its manifestation and temporal context is examined in bulgaria many of the features seen in south western europe are identified collapse of carbonate platform productivity at the pliensbachian toarcian boundary the t oae a short pulse of euxinic deposition in the falciferum zone an early toarcian rapid warming event seen in the belemnite 18o record that peaked around the falciferum bifrons zone boundary the long recognized positive 13c excursion in the late falciferum zone is also seen but a precursor sharp 13c negative excursion seen around the tenuicostatum falciferum zone boundary in most organic carbon records is not seen in the belemnite data a curious absence noted from other belemnite records subsequent perturbations in 87sr 86sr 13c and 18o suggest that there may be more global isotopic excursions in the early jurassic on the other hand belemnite sr isotope values from bulgaria are in accord with those recorded in western europe and hence demonstrating its value as a chronostratigraphic tool

frequency dependent acoustic seismic coupling of meteor shock waves simultaneous infrasonic and seismic observations of meteor shock waves have been recorded at a collocated array in southwestern ontario canada analysis of signals from seven events that exhibited acoustic seismic coupling representing 0 6 of the meteor flux detected using other systems suggests signifi cant filtering and amplitude enhancement indicative of a frequency dependent acous tic transfer function the acoustic response at the site possesses the properties of an 10 hz high pass filter on incident shock waves with ground motions up to an order of magnitude larger than theoretical predictions in terms of energy the air to ground energy coupling efficiency is measured at 1 3 0 8 above this cutoff overall cou pling efficiencies however are much lower between 0 0007 and 0 071 as the dominant frequencies of the incident shock waves typically 0 1 10 hz are weak or nonexistent in the seismic signals such strong frequency dependent effects suggest that without detailed knowledge of the site and its influences on the subsequent ground motion transformation of seismic data to produce pseudopressure data for the purposes of quantitative source energy estimation may be unreliable for seismom eters located within thick overburden

the carancas meteorite impact crater peru geologic surveying and modeling of crater formation and atmospheric passage the recent carancas meteorite impact event caused a worldwide sensation an h4 5 chondrite struck the earth south of lake titicaca in peru on september 15 2007 and formed a crater 14 2 m across it is the smallest youngest and one of two eye witnessed impact crater events on earth the impact violated the hitherto existing view that stony meteorites below a size of 100 m undergo major disruption and deceleration during their passage through the atmosphere and are not capable of producing craters fragmentation occurs if the strength of the meteoroid is less than the aerodynamic stresses that occur in flight the small fragments that result from a breakup rain down at terminal velocity and are not capable of producing impact craters the carancas cratering event however demonstrates that meter sized stony meteoroids indeed can survive the atmospheric passage under specific circumstances we present results of a detailed geologic survey of the crater and its ejecta to constrain the possible range of impact parameters we carried out numerical models of crater formation with the isale hydrocode in two and three dimensions depending on the strength properties of the target the impact energies range between approximately 100 1000 mj 0 024 0 24 t tnt by modeling the atmospheric traverse we demonstrate that low cosmic velocities 12 1 4 kms 1 and shallow entry angles 20 are prerequisites to keep aerodynamic stresses low 10 mpa and thus to prevent fragmentation of stony meteoroids with standard strength properties this scenario results in a strong meteoroid deceleration a deflection of the trajectory to a steeper impact angle 40 60 and an impact velocity of 350 600 ms 1 which is insufficient to produce a shock wave and significant shock effects in target minerals aerodynamic and crater modeling are consistent with field data and our microscopic inspection however these data are in conflict with trajectories inferred from the analysis of infrasound signals

stable isotope records δ18o and δ13c of lower middle jurassic belemnites from the western balkan mountains bulgaria palaeoenvironmental application stable o and c isotope data of 110 upper pliensbachian lower bajocian belemnites have been obtained and used to attempt a reconstruction of palaeotemperature and its variation in two epicontinental depositional environments from the western balkan mountains bulgaria the samples were collected from 3 sections with high resolution ammonite subdivision initially taphonomic cathodoluminescence and geochemical analyses were used for evidence of diagenetic alteration non luminescent parts of the belemnite rostra have been sampled for isotope analyses and 76 samples having d 18 o 0 5 pdb fe 950 ppm and sr mn ratio 80 were used for palaeotemperature interpretations the o and c isotope data generally exhibit little stratigraphical variability with minor fluctuations however there are prominent positive c isotope excursions and coeval negative o isotope shifts detected in the lower toarcian tenuicostatum falciferum and bifrons zones the o isotope data interpreted in terms of palaeotemperature revealed relatively high seawater temperatures during the toarcian aalenian and early bajocian with detectable temperature rises during the early toarcian maximum value of 29 6 c both c isotope maxima and o isotope minima are used as evidence of the early toarcian anoxic event reported from many localities of the same age and in similar facies in western europe in the study the latter is recognized as 3 episodes which are closely related with the seawater temperature maxima this isotope record pattern is considered as a consequence of a global tethyan transgression during the early toarcian 2008 published by elsevier ltd

water mass exchange and variations in seawater temperature in the nw tethys during the early jurassic evidence from neodymium and oxygen isotopes of fish teeth and belemnites article i nfo oxygen and neodymium isotope analyses performed on biostratigraphically well dated fish remains recovered from the hettangian to toarcian of the paris basin were used to reconstruct variations of early jurassic seawater temperature and to track oceanographic changes in the nw tethys our results indicate a strong correlation between 18 o trends recorded by fish remains and belemnites confirming the paleoenvironmental origin of oxygen isotope variations interestingly temperatures recorded by pelagic fishes and nektobenthic belemnites and bottom dwelling fishes are comparable during the late pliensbachian sea level lowstand but gradually differ during the early toarcian transgressive episode recording a difference in water temperatures of 6 c during the bifrons zone this could suggest that the surface bottom water temperature difference was not large enough during regressive phases to be recorded by organisms living near the lower and upper part of the water column the globally unradiogenic nd budget of euro boreal waters through the early jurassic suggests that these waters were strongly affected by continental neodymium input from surrounding emerged areas and that exchange with more radiogenic waters from the tethys and panthalassa oceans remained limited this supports the existence of a southward directed current in the euro boreal area for most of the early jurassic the only exception is observed at the early late pliensbachian transition where a positive end excursion is recorded suggesting northward influx of low latitude tethyan or panthalassan waters which may have contributed to the warming of nw tethyan seawater recorded at this time the absence of a marked negative excursion in end concomitant with a negative 18 o shift recorded during the falciferum zone exaratum subzone argues against the influence of less radiogenic arctic water influxes with low 18 o values during this interval instead we suggest that

evidence for a meteoritic origin of the september 15 2007 carancas crater on september 15th 2007 around 11 45 local time in peru near the bolivian border the atmospheric entry of a meteoroid produced bright lights in the sky and intense detonations soon after a crater was discovered south of lake titicaca these events have been detected by the bolivian seismic network and two infrasound arrays operating for the comprehensive nuclear test ban treaty organization situated at about 80 and 1620 km from the crater the localization and origin time computed with the seismic records are consistent with the reported impact the entry elevation and azimuthal angles of the trajectory are estimated from the observed signal time sequences and backazimuths from the crater diameter and the airwave amplitudes the kinetic energy mass and explosive energy are calculated using the estimated velocity of the meteoroid and similarity criteria between orbital elements an association with possible parent asteroids is attempted the favorable setting of this event provides a unique opportunity to evaluate physical and kinematic parameters of the object that generated the first actual terrestrial meteorite impact seismically recorded

a meteorite crater on earth formed on september 15 2007 the carancas hypervelocity impact on september 15 2007 a bright fireball was observed and a big explosion was heard by many inhabitants near the southern shore of lake titicaca in the community of carancas peru a 13 5 m crater and several fragments of a stony meteorite were found close to the site of the impact the carancas event is the first impact crater whose formation was directly observed by several witnesses as well as the first unambiguous seismic recording of a crater forming meteorite impact on earth we present several lines of evidence that suggest that the carancas crater was a hypervelocity impact an event like this should have not occurred according to the accepted picture of stony meteoroids ablating in the earths atmosphere therefore it challenges our present models of entry dynamics we discuss alternatives to explain this particular event this emphasizes the weakness in the pervasive use of average parameters such as tensile strength fragmentation behavior and ablation behavior in current modeling efforts this underscores the need to examine a full range of possible values for these parameters when drawing general conclusions from models about impact processes

oxygen isotopes in meteoric calcite cements as indicators of continental paleoclimate because meteoric water 18 o values decrease with decreasing ambient temperature and increasing latitude 18 o values of meteoric calcite cement should exhibit a similar relation with paleolatitude and be an indicator of continental paleotemperatures to test this we compiled isotopic and paleolatitude data for 20 meteoric cements and nine speleothems ranging in age from devonian to modern and in paleolatitude from 3 5 to 83 mean 18 o values for meteoric cements and speleothems both show the same negative correlation with paleolatitude the 18 o vs latitude trend for these carbonates is almost identical to that predicted for modern inland environments but differs from the trend for coastal environments this suggests that the ground water controlling the ultimate composition of meteoric cement is derived predominantly from inland recharge if it is assumed that the modern meteoric water 18 o vs temperature relation is valid for the past and that insignificant evaporation occurred prior to carbonate precipitation then coastal and inland paleotemperatures can be calculated from the 18 o values of meteoric calcite 18 o mcl and seawater 18 o sw by using the equations t coastal 13 3 32 6 0 231 0 0613 18 o mcl 18 o sw and t inland 17 8 16 2 0 572 0 1233 18 o mcl 18 o sw where t is temperature in c calcite precipitated from coastal meteoric water at temperatures between 0 and 25 c will exhibit a narrow range in 18 o 6 to 4 where 18 o sw 0 the 18 o of calcite precipitated from inland meteoric water will be sensitive to paleotemperature ranging from 14 to 5 where 18 o sw 0 for temperatures of 0 to 25 c

warm palaeotemperatures from high late jurassic palaeolatitudes falkland plateau ecological environmental or diagenetic controls abstract oxygen and carbon isotopes have been determined from late jurassic oxfordian tithonian belemnites and inoceramid bivalves from two deep sea drilling project dsdp sites located on the falkland plateau mean belemnite 18o values derived from well preserved skeletal material were 1 29 from dsdp site 330 and 1 45 from dsdp site 511 assuming a seawater smow value of 1 0 mean palaeotemperatures calculated from the oxygen isotopic composition are 17 2 c and 17 9 c respectively the inoceramid bivalves yielded much lighter 18o values mean 3 58 petrographic and geochemical evidence points to the inoceramid bivalves being altered by diagenesis which accordingly accounts for the observed differences in isotopic values vital effects or the importation of belemnites or inoceramids from another area are considered not to account for the observed isotopic trends the palaeotemperatures interpreted from the belemnites are significantly warmer than other recent estimates of late jurassic temperature from oxygen isotope studies and climate model predictions from similar southern palaeolatitudes we suspect our apparent warmer temperatures are because of a combination of increased freshwater runoff depleting surface waters with respect to 18o and related to the semi enclosed nature of the depositional basin retaining warmth relative to the open ocean of similar latitudes

primary and diagenetic isotopic signals in fossils and hemipelagic carbonates the lower jurassic of northern spain stable isotope and trace element analyses of 230 jurassic pliensbachian toarcian samples from northern spain have been performed to test the use of geochemical variations in fossils belemnites and brachiopods and whole rock hemipelagic carbonates as palaeoceanographic indicators although the succession analysed reinosa area westernmost basque cantabrian basin has been subject to severe thermal alteration during burial diagenesis the samples appear to be well preserved the degree of diagenetic alteration of the samples has been assessed through the application of integrated petrographic chemical and cathodoluminescence analyses it is demonstrated that brachiopods and whole rock carbonates although widely used for palaeoceanic studies do not retain their primary marine geochemical composition after burial diagenesis in contrast there is strong evidence that belemnite rostra preserve original isotopic values despite pervasive diagenesis of the host rock well preserved belemnite shells non luminescent to slightly luminescent typically show stable isotope values of 4ae3 to 0ae7 d 13 c 0ae7 to 3ae2 d 18 o and trace element contents of 950 l gg 1 sr and sr mn ratios 80 this study suggests that the degree to which diagenesis has affected the preservation of an original isotopic composition may differ for different low mg calcite fossil shells and hemipelagic bulk carbonates behaviour that should be considered when marine isotopic signatures from other ancient carbonate rocks are investigated multiple non luminescent contemporaneous belemnite samples passed the petrographic and geochemical tests to be considered as palaeoceanic recorders yet their d 13 c and d 18 o values exhibited moderate scatter such variability is likely to be related to the palaeoecological behaviour of belemnites and or highfrequency secular variations in sea water chemistry superimposed on the longterm isotopic trend a pronounced positive carbon isotope excursion up to 4ae3 is documented in the early toarcian serpentinus biozone which correlates with the toarcian d 13 c maximum reported in other european and tethyan regions

warming driven mass extinction in the early toarcian early jurassic of northern and central spain correlation with other time equivalent european sections abstract causes of the major mass extinction recorded during the early toarcian early jurassic are controversial many authors have concluded that the mass extinction is caused by the widespread oceanic anoxia derived from a postulated early toarcian oceanic anoxic event etoae supposedly synchronous in all basins and global in extent another group of papers links the mass extinction with a major climate change that occurred synchronously with the mass extinction the results of the study of five sections of the uppermost pliensbachian and lower middle toarcian deposits located in northern and central spain are presented detailed ammonite based biostratigraphy coupled with stable isotope analysis of belemnite calcite and bulk carbonates as well as total organic carbon toc analyses have been performed in all sections records of the vertical distribution of mainly benthic fossils have been compiled in four of the studied sections results obtained in the spanish outcrops have been compared and correlated with other european sections the excellent mutual relation between the patterns of the early toarcian progressive warming and the concomitant progressive losses of species evidences a cause and effect relationship between the increase of temperature and the mass extinction from an uppermost pliensbachian cooling interval warming started at the lower toarcian tenuicostatum zone increase of average seawater palaeotemperature is associated with a progressive and substantial drawdown in the number of species of nektonic planktonic and benthic organisms representing the extinction interval a prominent increase in seawater temperature occurred around the lower toarcian tenuicostatum serpentinum zonal boundary average temperatures at the serpentinum zone increased about 7 c marking the extinction boundary the high temperatures continued during the middle toarcian bifrons chronozone representing the repopulation interval the anoxia linked to the postulated etoae cannot be the responsible for the mass extinction because it has been synchronously recorded in the oxygenated environments of many european and northern african platforms deposition of laminated organic rich black shale facies above 5 wt toc indicating anoxic environments was mostly confined geographically to the western europe euxinic basin and mainly deposited after the extinction event during the interval of faunal recovery

a review of the broad pattern of jurassic sea level changes and their possible causes in the light of current knowledge abstract an assessment is made of the current state of research into jurassic sea level changes based on new insights into depositional patterns in relation to these changes and new stratigraphic information from several widely separated regions across the world the bearing of this information on alternative models respectively involving sea level rise interrupted by stillstands or falls is then evaluated the gross pattern appears to be one of more or less gradual rise of sea level through the period interrupted by episodes of comparative stillstand rather than eustatic fall and several episodes of significant regression are shown to be the result of regional tectonics major episodes of eustatic rise took place in the early hettangian early sinemurian early pliensbachian early toarcian early and late bajocian middle callovian and late oxfordian to kimmeridgian a significant episode of rapid and very extensive regression possibly global took place at the end of the triassic but other regressive episodes in the late aalenian bathonian late oxfordian kimmeridgian and tithonian are clearly only regional in extent there is no evidence for glacioeustasy and most if not all of the regional or global changes recognised can readily be related to plate tectonics the events at the triassic jurassic boundary seem to be the result of mantle plume activity centred on the central atlantic region

preservation of delta 18 o and delta 13 c in belemnite rostra from the jurassic early cretaceous successions stratigraphic collection of 263 belemnite rostra guards from jurassic to lower cretaceous sediments in the moscow area of russia northern germany england new zealand and morocco were analyzed to determine temporal variations in their delta 18 o and delta 13 c as a proxy for isotopic composition of surface seawater internal structures of the rostra were studied using cathodoluminescence and sem techniques their trace element fe mn mg and sr and the stable carbon and oxygen isotope compositions the average stratigraphic resolution is about 1 ma these samples represent a broad range of paleolatitudes and paleoceanographic settings ranging from 42 degrees n to 82 degrees s covering boreal to subtropical brackish to open marine shelf paleoenvironments the rostra originally contained domains enriched in organic matter that were later replaced by luminescent diagenetic calcite thereby generating an impression of seasonal growth rings diagenetic calcite accounts for up to 6 8 percent of the rostrum the trace element content of the rostra range from 227 to 3935 ppm for mg 379 to 1514 ppm for sr and up to 305 and 3662 ppm for mn and fe respectively however selective drilling of only primary calcitic domains resulted in 90 percent of all analyzed samples to fall within the range of trace element values typical for modern low mg calcite shells the chemical and textural data suggest that the primary calcite of the rostra is well preserved as is its isotopic signature the delta 13 c and delta 18 o measurements define oscillating temporal bands of about 3 to 4 per mil width around more or less modern marine values of 2 and 1 per mil respectively oxygen isotopes in the well preserved rostra most likely reflect temperature variations within a approximately 14 or 8 degrees c range the observed 3 to 4 per mil spread of values between contemporaneous specimens which is comparable to the scatter of data reported for modern low mg calcitic brachiopod shells probably reflects the diversity of local ecosystems although some of the spread may be due to real short term temporal variations within single biozones the delta 13 c values of the rostra define a band similar to that of the oxygen isotopes and the temporal oscillations of both isotope curves are commonly in phase the above dataset complemented by the results of jones jenkyns and hesselbo 1994 and jones and others 1994 yields a composite delta 18 o and delta 13 c variations in belemnite guards for the entire jurassic early cretaceous interval for delta 18 o the oscillating band indicates that the most negative values occur at times of independently postulated global and or regional anoxic events such as those in the toarcian and kimmeridgian as well as the aptian these oaes appear to be characterized by up to 10 degrees c higher seawater temperatures than the intervening background times the delta 13 c record shows 13 c depletion for the kimmeridgian event but enrichment for the other two suggesting that the delta 13 c temporal oscillations and oaes are not simply a reflection of surficial productivity due to operation of the biological pump but rather of changing oceanic circulation patterns due to variations in latitudinal surface temperature gradients

the early toarcian jurassic anoxic event stratigraphic sedimentary and geochemical evidence detailed paleogeographic studies in the southern alps suggest that an oxygen minimum model is appropriate for interpreting conditions on tethyan continental margins advection of manganese in this low oxygen layer may explain the local occurrence of carbonate ores of this element carbon sulfur and iron sulfur ratios although showing considerable scatter suggest that bottom waters at this time were locally euxinic containing free hydrogen sulfide this oceanic anoxic event was preceded by significant faunal turnover of ammonites in tethys and accompanied by widespread extinction of benthos in northern europe in response to the lateral spread of anoxic bottom waters during transgression similar changes may be recognized in other parts of the world other anoxic events may have taken place during the jurassic but documentation is as yet meagre furthermore models for such phenomena remain largely speculative although upwelling and increased planktonic productivity commencing in pre toarcian time are favored for the falciferum zone event documented here from author

black shales and carbon isotopes in pelagic sediments from the tethyan lower jurassic detailed sampling and analysis of jurassic pelagic limestones and marls from italy hungary and switzerland have enabled construction of an isotope stratigraphy across the pliensbachian toarcian boundary with resolution to the zonal level the oxygen isotope record is unremarkable the carbon isotopes however show two positive excursions one relatively minor during the pliensbachian margaritatus zone subnodosus subzone the other more major during the toarcian early falciferum zone where a maximum 13c value of 4 52 pdb is attained these intervals are known to be favoured periods of organic rich sedimentation in diverse parts of the globe and the isotopic excursions are interpreted as a response to abnormally high rates of storage of organic carbon in the sedimentary record a comparable phenomenon has been documented from the cenomanian turonian boundary in the cretaceous where it has been referred to the influence of an oceanic anoxic event some italian sections spanning this lower jurassic interval contain organic rich shales in the falciferum zone the isotopic signatures from their included locally manganiferous carbonate betray a considerable diagenetic overprint and they cannot therefore be incorporated in a composite isotopic curve carbon isotopes from the organic carbon itself are extremely negative falling to 33 pdb and in one section examined in detail correlate with the calcium carbonate content of the shales they may reflect a partial change to a non calcified planktonic biota during deposition of this lime poor interval possibly responding to upwelling and increased fertility of near surface waters the onset of upwelling may have been as early as spinatum tenuicostatum zone time that is at the pliensbachian toarcian boundary

elemental and oxygen isotope composition of early jurassic belemnites salinity vs temperature signals well preserved calcitic belemnite samples from the basque cantabrian basin of northern spain have been analyzed to improve our current understanding of the chemistry of seawater as an index of paleoceanographic changes during the early jurassic a period punctuated by times of oceanic anoxia and global mass extinctions because the oxygen isotope composition of calcite depends not only on temperature but also on salinity we present here a combination of sr ca mg ca and 18o analyses that helped us to evaluate both effects separately comparison between the temporal records and cross plots of these geochemical parameters shows a good correlation of mg ca with 18o and a weak correlation of sr ca with 18o comparison of our belemnite 18o record with coeval o isotope profiles from other paleogeographic domains suggests the existence despite differences in the absolute isotopic values of a major negative shift during the serpentinus zone that is regionally reproducible this event is linked to the early toarcian ocean anoxic event oae and suggests the existence of global changes in paleoclimatic and paleoceanographic conditions that are reflected largely in the geochemical composition of seawater compared to our results however other early toarcian 18o data reported from northern european basins are generally depleted 1 3 1 6 in contrast mg ca ratios display similar values these differences in 18o data suggest a salinity component for the northern european data and provide evidence for a north to south salinity gradient within the north european interior boreal seaway during the early jurassic this study suggests that the secular variation of mg ca is a useful proxy for discriminating between temperature and salinity effects on the oxygen isotope composition of fossil shells and highlights the prospect of using the mg ca ratios of belemnite calcite to calculate paleotemperatures independently of salinity the findings of our study may help to calibrate 18o curves in other basins by removing the salinity component of their 18o records which may help to calculate water density gradients between the jurassic seas of northern and southern europe

paleotemperature variations of early jurassic seawater recorded in geochemical trends of belemnites from the basque cantabrian basin northern spain abstract here we present new o isotope mg ca and sr ca data of early jurassic belemnites from the basque cantabrian basin of northern spain a succession deposited in a periodically anoxic restricted hemipelagic basin nearly 200 pliensbachian lower toarcian belemnites were collected and examined using optical cathodoluminescence and chemical techniques to constrain the effects of potential diagenetic alteration after a precise diagenetic screening of samples 176 belemnites were selected to provide records of changes in seawater geochemistry and temperature the records show a fairly good correlation of 18o with mg ca ratios r 0 65 and a weak correlation of 18o with sr ca ratios r 0 34 the oxygen isotope data if interpreted in terms of paleotemperature have revealed a period of relatively uniform and warm seawater temperatures during the early pliensbachian followed by a sharp temperature drop during the late pliensbachian earliest toarcian the onset of this cooler period occurred within the protogrammoceras celebratum subzone and the coolest seawater temperatures were reached at the end pliensbachian pleuroceras spinatum zone this was followed by a rapid seawater warming during the harpoceras serpentinus zone of the early toarcian in addition the data set provides new information regarding paleoceanographic conditions for anoxic events in a critical region of connection between the boreal and tethys realms it is the background to relatively high 18o values that prevailed during the anoxic episodes concerning the impact of the early toarcian anoxic event in northern spain the detected 18o and mg ca excursions reached their minimum and maximum respectively during the lower h serpentinus zone while the anoxic black shale interval developed earlier during the upper dactylioceras tenuicostatum lowermost h serpentinus zones

seismic ground motions from a bolide shock wave 1 an intensely brilliant bolide accompanied by an audible sonic boom occurred on the night of 3 november 2003 2150 lt or 4 november 2003 0350 ut in northeastern arkansas the sonic boom was well recorded by 22 three component stations of the center for earthquake research and information cooperative seismic network arrival times and wave polarizations were used to reconstruct the acoustic wave front propagating across the network and to estimate trajectory parameters of the bolide a grid search location technique constrains the trajectory and gives a reference height of 50 100 km above the southern edge of the network an azimuth of propagation of 270 290 toward the northwest and a plunge of 38 48 downward the trajectory and date of the bolide event are consistent with a taurid shower meteor transient ground motions from the sonic boom were studied using plane wave cagniard dehoop and propagator matrix theory for an incident pressure pulse impinging on a layered elastic earth model general characteristics of the vertical and radial polarization and wave frequency content require acoustic coupling within a thin 10 m near surface layer with low p wave 0 25 km s and s wave 0 125 km s velocities ground motions are generally confined to this near surface layer are not sensitive to deeper earth structure within the mississippi embayment unconsolidated sediments and display both leaky mode pl a type of dispersed p type seismic wave and locked mode rayleigh wave propagation acoustic wave ground motion coupling studies may be a useful way to analyze near surface site responses to determine velocity structure in earthquake shaking hazard studies

strontium isotope profile of the early toarcian jurassic oceanic anoxic event the duration of ammonite biozones and belemnite palaeotemperatures we profile 87sr 86sr 13c 18o sr ca mg ca and na ca in belemnites through pliensbachian and toarcian strata on the yorkshire coast uk which include the early jurassic oceanic anoxic event the 87sr 86sr profile shows that the relative duration of ammonite subzones differ by a factor of up to 30 the lower jurassic exaratum subzone is 30 times longer than the clevelandicum subzone because the exaratum subzone in yorkshire which contains the anoxic event is condensed by a factor of between 6 5 and 12 2 times relative to adjacent strata using our 87sr 86sr profile the resolution in correlation and dating attainable in the interval is between 1 5 m and 15 m of section and better than 0 25 myr in parts of the sequence this stratigraphic resolution equals that attainable with ammonites a new age model is provided for late pliensbachian and early toarcian time that is based on the 87sr 86sr profile through the sequence the sr ca mg ca na ca and 18o of belemnite carbonate covary suggesting that elemental ratios may be useful for palaeotemperature measurement our 13cbelemnite data splits into three the previously reported positive isotope excursion to 6 5 in the early toarcian we speculate that the excursion s resulted from addition to surface waters of isotopically heavy co2 via ebullition of methanogenic co2 from the sediment during early burial of organic rich 10 toc sediments