the δ15n of nitrate in the southern ocean consumption of nitrate in surface waters we report nitrogen isotope data for nitrate from transects of hydrocast and surface samples collected in the eastern indian and pacific sectors of the southern ocean focusing here on the data from the upper water column to study the effect of nitrate consumption by phytoplankton the 15n of nitrate increases by 1 2 from deep water into the antarctic summertime surface layer due to kinetic isotopic fractionation during nitrate uptake estimation of the nitrate uptake isotope effect from antarctic depth profiles yields values in the range of 5 6 in east indian sector and 4 5 in the east pacific sector surface transect data from the pacific sector also yield values of 4 5 the major uncertainty in the profile based estimation of the isotope effect involves the 15n of nitrate from the temperature minimum layer below the summertime antarctic surface layer which deviates significantly from the predictions of simple models of isotope fractionation for the subantarctic surface it is possible to distinguish between nitrate supplied laterally from the surface antarctic and nitrate supplied vertically from the subantarctic thermocline because of the distinctive relationships between the 15n and concentration of nitrate in these two potential sources our subantarctic samples collected during the summer and fall indicate that nitrate is supplied to the subantarctic surface largely by northward transport of antarctic surface water isotopic data from the pacific sector of the subantarctic suggest an isotope effect of 4 5 indistinguishable from the antarctic estimates in this sector

glacial interglacial variability in denitrification in the world s oceans causes and consequences the late quaternary history of water column denitrifcation of the eastern pacific margins and the arabian sea is reconstructed using sedimentary 15n measurements the 15n values in six piston cores raised from these regions show remarkably similar cyclic variations being heavy 9 10 5 during the interglacials and 2 3 lighter during the glacials this implies that denitrification in these regions decreased substantially during the glacial periods the glacial decline in denitrification is attributed to reduced upwelling and flux of organic material through the oxygen minimum zone since water column denitrification in these areas accounts for about half of the fixed nitrogen loss in the modern ocean the inferred decrease in denitrification should have increased the oceanic nitrate inventory during glacial periods because nitrate is a limiting nutrient oceanic productivity and attendant changes in co2 may therefore have been modulated on glacial interglacial timescales by variations in the oceanic no3 content

evidence from diatom bound nitrogen isotopes for subarctic pacific stratification during the last ice age and a link to north pacific denitrification changes higher diatom bound d 15 n 70 wt lower opal content and 1200 ppm lower biogenic barium taken together and with constraints on sediment accumulation rate these results suggest a reduced supply of nitrate to the surface due to stronger stratification of the upper water column of the bering sea during glacial times with more complete nitrate consumption resulting from continued iron supply through atmospheric deposition this finding extends the body of evidence for a pervasive link between cold climates and polar ocean stratification in addition we hypothesize that more complete nutrient consumption in the glacial age subarctic pacific contributed to the previously observed ice age reduction in suboxia and denitrification in the eastern tropical north pacific by lowering the nutrient content of the intermediate depth water formed in the subpolar north pacific in the deglacial interval of the bering sea record two apparent peaks in export productivity are associated with maxima in diatom bound and bulk sediment d 15 n the high d 15 n in these intervals may have resulted from greater surface nutrient consumption during this period however the synchroneity of the deglacial peaks in the bering sea with similar bulk sediment d 15 n changes in the eastern pacific margin and the presence of sediment lamination within the bering sea during the deposition of the productivity peaks raise the possibility that both regional and local denitrification worked to raise the d 15 n of the nitrate feeding bering sea surface waters at these times

unchanged nitrogen isotopic composition of organic matter in the south china sea during the last climatic cycle global implications the 15n of surface and down core sediments spanning the last 20 200 kyr from the entire south china sea scs ranges only from 3 0 to 6 5 with no correlation with discernible paleoclimatic oceanographic changes detailed profiles of the uppermost sediment column including fluff samples indicate a minor diagenetic overprint of 0 3 1 2 at the sediment water interface the absence of any correlation with reconstructed glacial interglacial changes in primary production terrigenous input and or sea level related basin configuration is attributed to a complete consumption of nitrate during primary production in this marginal basin during at least the last 140 000 years this in turn implies that the 15n of the nitrate used during primary production remained approximately constant during the last climatic cycle the proposed scenario infers an unchanged nitrogen isotopic composition of the western pacific subsurface nitrate between glacial and interglacial stages as well as during terminations and thus constrains proposed changes in the oceanic n inventory

sedimentary nitrogen isotopic ratio as a recorder for surface ocean nitrate utilization in two contrasting regions of the ocean the equatorial pacific and the southern ocean the 15n of core top sediments were strongly related to no3 in surface waters with distance from the equator in the equatorial pacific 15n increased from 7 to 16 as no3 decreased from 8 m to 0 1 m going from 60 to 30 s in the se indian ocean core top 15n increased from 5 to 11 as surface no3 decreased from 25 m to 0 1 m these results are strong evidence that sedimentary 15n in these regions is recording the increasing isotopic enrichment of near surface no3 with its depletion by phytoplankton in the case of the equatorial pacific 15n values for sinking particles collected at 150 m matched well the core top sediment values demonstrating little diagenetic alteration of the near surface generated isotopic signal these equatorial pacific data sets have variations with near surface no3 consistent with rayleigh fractionation kinetics for a fractionation factor u of 2 5 this value is substantially lower than previously found for temperate or polar regions perhaps as a result of differences in phytoplankton species assemblage or growth condition in the southern ocean south of the polar front comparison of 15n values for opal rich sediments south and sinking particles indicates an apparent 5 diagenetic enrichment relative to the surface generated signal that requires further investigation this exception aside our observations show that the surface water relationship of increasing 15n with increasing no3 depletion is generally transmitted to and preserved in the sediments an important requirement for further development and application of this important paleoceanographic tool

millennial scale oscillation of denitrification intensity in the arabian sea during the late quaternary and its potential influence on atmospheric n2o and global climate the intensity of denitrification in the arabian sea during the last 65 kyr is reconstructed using high resolution 15 n records of three sediment cores in conjunction with other geochemical tracers for water column oxygenation and productivity the results reveal a close link to the greenland ice core record with low or absent water column denitrification during the last glacial maximum the stadials and at the time of the heinrich events including the younger dryas in contrast denitrification was high during the holocene and the interstadials the intensification of denitrification is related to stronger sw monsoonal upwelling which enhances organic matter flux and degradation resulting in a strengthening of the midwater oxygen deficiency such a combination of enhanced upwelling and denitrification has also been implied for the eastern tropical north pacific etnp where these events occur during the holocene and to some extent during the interstadials too today the arabian sea and the etnp together contribute substantially to the global marine water column denitrification and a significant fraction of the ocean atmosphere n 2 o flux originates from these areas changes in n 2 o emissions from these areas could thus have effected the recently described stadial interstadial variations in the atmospheric concentration of this greenhouse gas as deduced from ice cores moreover denitrification is the major sink for oceanic nitrate and provides a primary control for the oceanic nutrient inventory which in turn influences global primary productivity and co 2 sequestration by the biological pump short term switches between a nondenitrification mode and a denitrification mode in these marine regions therefore have an impact on global climate

importance of wind driven sea ice motion for the formation of antarctic intermediate water in a global climate model an ocean atmosphere sea ice model is used to show the importance of wind driven sea ice motion in the formation of antarctic intermediate water aaiw the model is able to reasonably simulate a tongue of low salinity aaiw even when the direct momentum transfer from wind to the ocean is neglected provided that the wind stress is applied to sea ice in contrast when the wind stress exclusively drives the ocean the model fails to capture the properties of aaiw the growth and subsequent offshore transport of sea ice acts as a freshwater conduit from near shore regions where aabw is formed to subpolar regions where aaiw is formed sea ice dynamics are also shown to be important in the simulation of a local salinity minimum at intermediate depths in the southern indian ocean and a local salinity maximum in the western weddell sea

deglacial pattern of circulation and marine productivity in the upwelling region off central south chile abstract a high resolution sea surface temperature and paleoproductivity reconstruction on a sedimentary record collected at 36 s off central south chile geob 7165 1 36 33 s 73 40 w 797 m water depth core length 750 cm indicates that paleoceanographic conditions changed abruptly between 18 and 17 ka comparative analysis of several cores along the chilean continental margin 30 41 s suggests that the onset and the pattern of deglacial warming was not uniform off central south chile due to the progressive southward migration of the southern westerlies and local variations in upwelling marine productivity augmented rather abruptly at 13 14 ka well after the oceanographic changes we suggest that the late deglacial increase in paleoproductivity off central south chile reflects the onset of an active upwelling system bringing nutrient rich oxygen poor equatorial subsurface water to the euphotic zone and a relatively higher nutrient load of the antarctic circumpolar current during the last glacial maximum when the southern westerlies were located further north productivity off central south chile in contrast to off northern chile was reduced due to direct onshore blowing winds that prevented coastal upwelling and export production

increased glacial age ventilation of the chilean margin by antarctic intermediate water antarctic intermediate water is an oxygen rich water mass that spreads throughout the southern hemisphere oceans marine sediment chemistry indicates that the water mass was produced at higher rates and had higher oxygen concentrations during the last glacial maximum antarctic intermediate water is at present a water mass that brings oxygen to intermediate depths throughout the southern hemisphere oceans models have suggested that intermediate waters had higher concentrations of oxygen during the last glacial period1 2 consistent with globally reduced denitrification3 and increased production of antarctic intermediate water4 however some palaeoceanographic reconstructions5 6 have indicated that production decreased in the southeast pacific ocean at this time here we analyse the concentrations of re and mn the sedimentary concentrations of which are controlled by the amount of dissolved oxygen at the sea floor from three sediment cores located along the chilean margin for the past 30 000 years our results from the cores which bracket the present day water column extent of antarctic intermediate water show that the depth range of well oxygenated antarctic intermediate water increased off chile during the last glacial maximum dissolved oxygen content began to decrease approximately 17 000 years ago coincident with rapid antarctic warming and a poleward shift of the southern westerly winds7 our estimates of productivity from accumulation rates of organic carbon and opal do not co vary with the seafloor oxygen variations ruling out local control of seafloor oxygenation we conclude that the data are best explained by a combination of increased oxygenation and increased flux of antarctic intermediate water during the last glacial maximum

glacial interglacial modulation of the marine nitrogen cycle by high latitude o2 supply to the global thermocline 1 an analysis of sedimentary nitrogen isotope records compiled from widely distributed marine environments emphasizes the global synchrony of denitrification changes and provides evidence for a strong temporal coupling of these variations to changes in nitrogen fixation as previously inferred we explain the global coherence of these records by a simple physical control on the flux of dissolved oxygen to suboxic zones and the coupling to fixation via the supply of phosphorus to diazotrophs in suitable environments according to our hypothesis lower glacial stage sea surface temperature increased oxygen solubility while stronger winds in high latitude regions enhanced the rate of thermocline ventilation the resultant colder rapidly flushed thermocline lessened the spatial extent of denitrification and consequently n fixation during warm periods sluggish circulation of warmer less oxygen rich thermocline waters caused expansion of denitrification zones and a concomitant increase in n fixation local fluctuations in export productivity would have modulated this global signal

millennial scale variations in hydrography and biogeochemistry in the eastern equatorial pacific over the last 100 kyr abstract in this study we use records of nitrogen isotope ratios 15n uk 37 temperature estimates organic carbon and opal percentages from high resolution sediment cores located in the eastern equatorial pacific eep to explore the mechanisms linking millennial scale changes in low latitude sea surface temperature water column denitrification and surface productivity to the timing of northern or southern polar climate during the last 100 000 yr our results support a hypothesis that the southern hemisphere and its connection to the low latitudes via shallow subsurface ocean circulation has a primary influence on the biogeochemistry of the eep in addition our results suggest that during the last glacial stage denitrification rates fluctuated on millennial timescales in response to water column ventilation rather than upstream oxidant demand in intermediate depth waters however due to the poor age constraints available for marine isotopic stage mis 3 the eep sedimentary data presented here could support two conflicting mechanisms one driven by enhanced intermediate overturning circulation in the southern ocean during heinrich events antarctic warm events implying that subsurface flow rates control thermocline ventilation and a second one consistent with more sluggish intermediate circulation during antarctic warm events and giving a central role to the temperature control on oxygen solubility in southern ocean surface waters

intensification of the northeast pacific oxygen minimum zone during the bolling allerod warm period although climate records from several locations around the world show nearly synchronous and abrupt changes the nature of the inferred teleconnection is still poorly understood on the basis of preserved laminations and molybdenum enrichments in open margin sediments we demonstrate that the oxygen content of northeast pacific waters at 800 m depth during the bolling allerod warm period 15 13 kyr was greatly reduced existing oxygen isotopic records of benthic and planktonic foraminifera suggest that this was probably due to suppressed ventilation at higher latitudes of the north pacific comparison with ventilation records for the north atlantic indicates an antiphased pattern of convection relative to the north pacific over the past 22 kyr perhaps due to variations in water vapor transport across central america

northeastern pacific oxygen minimum zone variability over the past 70 kyr impact of biological production and oceanic ventilation 1 during the last glacial period the oxygen minimum zone omz within the northeastern pacific ocean strengthened and weakened on a millennial time scale demonstrating a tight linkage with northern high latitude climate although the precise mechanisms responsible remain unknown core md02 2508 retrieved off baja california was analyzed for major and trace elements br ca ti fe mn and sr using a xrf scanner and redox sensitive trace elements cu ni cd as v cr mo and u using the icp ms the trace element content the fe ti ratio and br based organic carbon exhibit higher values during the holocene and during warm dansgaard oeschger events than during the last glacial maximum lgm stadials and heinrich h events a principal component analysis of the element al ratio indicated that the following two main factors controlled the chemical composition of the sediments 1 export production as represented by organic carbon that was lower during cold periods and 2 regional intermediate water oxygenation as represented by u and mo variability that was not supported by a change in export production the latter suggests that intermediate water oxygenation improved during h events but slightly deteriorated during late marine isotope stage mis 3 and mis 2 a local biogeochemical effect forced by atmospheric processes impacted the lgm and h events in the same manner whereas regional intermediate oceanic circulation varied in an opposite manner during the lgm and h events possibly as a result of the global reorganization of intermediate water circulation during the lgm

major shifts in nutrient and phytoplankton dynamics in the north pacific subtropical gyre over the last 5000 years revealed by high resolution proteinaceous deep sea coral δ15n and δ13c records abstract the north pacific subtropical gyre npsg is the largest continuous ecosystem on earth and is a critical component of global oceanic biogeochemical cycling and carbon sequestration we report here multi millennial scale sub decadal resolution records of bulk stable nitrogen 15 n and carbon 13 c isotope records from proteinaceous deep sea corals data from three kulamanamana haumeaae specimens from the main hawaiian islands extend the coral based time series back 5000 yrs for the npsg and bypass constraints of low resolution sediment cores in this oligotrophic ocean region we interpret these records in terms of shifting biogeochemical cycles and plankton community structure with a main goal of placing the extraordinarily rapid ecosystem biogeochemical changes documented by recent coral records during the anthropocene in a context of broader late holocene variability during intervals where new data overlaps with previous records there is strong correspondence in isotope values indicating that this older data represents a direct extension of anthropocene records these results reveal multiple large isotopic shifts in both 15 n and 13 c values similar to or larger in magnitude to those reported in the last 150 yrs this shows that large fluctuations in the isotopic composition of export production in this region are not unique to the recent past but have occurred multiple times through the mid to late holocene however these earlier isotopic shifts occurred over much longer time intervals millennial vs decadal timescales further the 15 n data confirm that the extremely low present day 15 n values recorded by deep sea corals 8 are unprecedented for the npsg at least within the past five millennia together these records reveal centennial to millennial scale oscillations in npsg biogeochemical cycles further these data also suggest a number of independent biogeochemical regimes during which 15 n and 13 c trends were synchronous similar to recent coral records or distinctly decoupled we propose that phytoplankton species composition and nutrient source changes are the dominant mechanisms controlling the coupling and de coupling of 15 n and 13 c values likely primarily influenced by changing oceanographic conditions e g stratification vs entrainment the decoupling observed in the past further suggests that oceanographic forcing and ecosystem responses controlling 15 n and 13 c values of export production have been substantially different earlier in the holocene compared to mechanisms controlling the present day system

biological productivity during sapropel s5 formation in the eastern mediterranean sea evidence from stable isotopes of nitrogen and carbon we determined 15n 14n ratios in modern surface and sapropel s5 sediments of the mediterranean sea to clarify differences in the nutrient regime associated with sapropel formation in the modern situation high 15n of unused nitrate 15 20 remaining in the surface waters during the winter phytoplankton bloom evidences p limitation of biological production in winter 15n of surface sediments decrease towards the east of the basin 5 to 2 5 this is a consequence of either eastward increasing nitrogen fixation during the summer months or of particulate matter being supplied predominantly by the p limited winter bloom very low 1 1 15n values in sapropel s 5 from four locations require a very light source of nutrient n assimilated at a minimum of ten times the modern export flux because the isochronous records show no spatial gradient in 15n we exclude both ekman type upwelling and direct riverine discharge as likely sources of nutrients our data are consistent with an anti estuarine thermohaline circulation in the upper 500m during s5 time allowing for the trapping of nutrients in the eastern basin the most likely scenario for s5 is that phosphorus release from a relatively shallow redox boundary resulted in an imbalanced supply of n p 16 1 to the photic zone the result was a slow assimilation of carbon during summer stratification and extensive n2 fixation providing the majority of the export flux from a n limited system

abrupt cooling of antarctic surface waters and sea ice expansion in the south atlantic sector of the southern ocean at 5000 cal yr b p antarctic surface waters were warm and ice free between 10 000 and 5000 cal yr b p as judged from ice rafted debris and microfossils in a piston core at 53 s in the south atlantic this evidence shows that about 5000 cal yr b p sea surface temperatures cooled sea ice advanced and the delivery of ice rafted detritus ird to the subantarctic south atlantic increased abruptly these changes mark the end of the hypsithermal and onset of neoglacial conditions they coincide with an early neoglacial advance of mountain glaciers in south america and new zealand between 5400 and 4900 cal yr b p rapid middle holocene climate changes inferred from the taylor dome ice core antarctica cooling and increased ird in the north atlantic and the end of the african humid period the near synchrony and abruptness of all these climate changes suggest links among the tropics and both poles that involved nonlinear response to gradual changes in northern hemisphere insolation sea ice expansion in the southern ocean may have provided positive feedback that hastened the end of the hypsithermal and african humid periods in the middle holocene

n2o and ch4 variations during the last glacial epoch insight into global processes 1 greenhouse gas measurements along polar ice cores provide important insight into the former composition of the atmosphere its natural variations and the responses to fast climatic changes in the past we present high resolution nitrous oxide n2o and methane ch4 records measured along two ice cores from central greenland covering part of marine isotope stages 3 and 4 in the last glacial epoch the n2o data confirm the hypothesis that n2o shows variations in phase to fast climatic changes observed in the northern hemisphere the so called dansgaard oeschger d o events variations exist not only for events with a long duration 1500 years and more but also for the shorter ones the comparison with ch4 unveils interesting differences between the response of ch4 and n2o to d o events while the average amplitudes of ch4 oscillations associated with d o events are similar to those of the northern hemisphere summer insolation the magnitude of the n2o concentration change instead correlates with the duration of the d o events the records give further insight into the timing of concentration changes at the beginning of d o events they show that for long lasting events the n2o concentration starts to increase before both the sharp increase in the ch4 concentration and the temperature reconstructed for greenland

glacial interglacial differences in circulation and carbon cycling within the upper western north atlantic we investigated glacial interglacial changes in the circulation and carbon cycling in the western north atlantic subtropical gyre using hydrographic data and downcore records of the stable isotopic compositions of individual shells of bahamian benthic foraminifera potential temperature salinity depth relations show that modern thermocline 200 1000 m and deep 1000 2000 m waters in the providence channels bahamas originate in the sargasso sea and are typical of the subtropical gyre gradients in the stable isotopic compositions of late holocene planulina and cibicidoides species from the bank margins 400 to 1500 m depth reflect temperature nutrient and isotopic gradients of modern subtropical gyre waters the difference between the 18o of glacial maximum and late holocene foraminifera is 2 1 for the upper 900 m of the water column and 1 6 for deeper waters indicating that these waters were 4 c and 2 c cooler respectively during glacial time the glacial temperature gradient dt dz was similar to today while the base of the thermocline was 100 m shallower these results differ significantly from our earlier results from multiple shell 18o analyses which implied upper thermocline waters were only 1 c cooler and dt dz was greater during the glacial maximum the difference occurs because bioturbation adversely affects multiple shell analyses of glacial aged samples from shallow water depths at all depths above 1500 m foraminiferal 13c are greater during the glacial maximum than the late holocene by at least 0 1 to 0 2 as much as 0 6 in the lower thermocline indicating that nutrient concentrations throughout the thermocline were reduced and there was no oxygen minimum zone during the glacial maximum this suggests greater more uniform ventilation of the thermocline results of single and multiple shell 13c analyses of glacial age foraminifera compare favorably because samples most affected by mixing correspond to water depths where the glacial interglacial change of 13c was small cooler upper ocean waters during the glacial maximum reflect cooler temperatures at the ocean surface where isopycnal surfaces outcrop including large areas of the subtropical ocean a shallower thermocline base is consistent with southward migration of the northern edge of the subtropical gyre or increased mode water production enhanced thermocline ventilation is consistent with more vigorous winds and all isopycnal surfaces outcropping in the area of ekman downwelling

expansion of pelagic denitrification during early pleistocene cooling bioavailable nitrogen is removed from the oceans in oxygen deficient benthic and pelagic environments by denitrification future warming is predicted to reduce ocean oxygenation and to cause hypoxic regions to expand potentially accelerating denitrification a compilation of high resolution sedimentary nitrogen isotope delta n 15 records from the eastern tropical pacific north pacific and the arabian sea and a global multi site survey are presented as evidence for weak pelagic denitrification at the end of the pliocene warm period mean delta n 15 values increased in the major oxygen minimum zones omzs between 2 1 and 1 5 ma pelagic denitrification strengthened during a period of long term global cooling despite solubility driven increases in initial oxygen contents of antarctic intermediate and subantarctic mode waters ventilating the omzs this trend is opposite to the predicted mean trend for a cooling ocean as well as to the observed glacial interglacial variation several alternatives to explain the shift are proposed including a rise in net respiration a progressive increase in the ventilation age of the deep ocean associated with million year scale secular cooling and a shoaling of the remotely ventilated thermocline to shallow depths corresponding to the zone of peak subsurface respiration given no evidence for a net increase in production we assert that large scale climate driven changes in ocean circulation regulate long timescale variations in the extent of pelagic denitrification additional data and modeling are required to fully explain the observations c 2013 elsevier b v all rights reserved

on the late pleistocene holocene sapropel record of climatic and oceanographic variability in the eastern mediterranean sapropels and intercalated marls in a piston core from the eastern mediterranean are chemically and mineralogical distinct kaolinite smectite and total s contents fe a1 ba a1 co a1 mo a1 and v a1 are higher whereas quartz mg calcite illite contents si a1 ti a1 k a1 rb a1 and zr a1 are lower in the sapropels missing and ghost sapropels are identified by mineralogical and chemical properties that are not prone to diagenesis primary production was higher ba a1 and bottom water and or interstitial oxygenation was lower co a1 mo a1 ni a1 and v a1 during sapropel formation wind speeds quartz clay si a1 and zr a1 and bottom water salinities mg calcite calcite were higher during periods of marl formation sapropels represent a fundamentally different sedimentary facies whose formation is linked to changes in the hydrological balance in the basin driven by precessionally modulated changes in monsoon strength and subtropical precipitation changes which altered circulation production and sediment source areas

atypical δ 15 n variations at the southern boundary of the east pacific oxygen minimum zone over the last 50 ka abstract we report a nitrogen isotope record odp site 1233 from the southern chile margin at 41 s the site is located slightly south of the southern boundary of the peru chile upwelling system and the associated oxygen minimum zone off peru and northern chile we show that our nitrogen isotope record from the time interval 0 50 calendar kiloyears before present ka b p bears an atypical pattern both in shape and timing when compared with records obtained from either the continental margin of the eastern pacific or the subantarctic zone saz of the southern ocean the 15 n values at site 1233 are relatively high throughout the record varying between 9 and 13 the major features are a pronounced 15 n increase at the beginning of the deglaciation a maximum from 19 to 10 ka b p thereafter a large decrease during the early holocene and millenial scale oscillations showing an antarctic timing we propose that the record results from an amalgam of low latitude and high latitude processes low latitude processes including a stronger advection signal of heavy nitrates from the denitrifying zones off peru and northern chile would explain the timing of the deglaciation rise and the heaviest values found over this interval excluding the antarctic cold reversal period the overall differences between site 1233 and records from peru and northwest american margins suggest however that the origin of the 15 n signal off chile is largely controlled by hydrologic and climatic changes in the southern ocean we propose that the interplay between nutrient demand in the saz and latitudinal shifts of hydrologic fronts controlled both the concentrations and the isotopic signature of the remaining nitrate delivered to the chile margin then the glacial surface waters of the southern chile margin were likely lower in nitrate concentration and bear a higher 15 n than during interglacial periods

denitrification under glacial and interglacial conditions a physical approach 1 recent analysis of sedimentary 15n records over the last 200 000 years has shown an expansion of water column denitrification zones during warmer periods and a shrinkage of these oxygen poor regions during glacial periods two different mechanisms could be responsible for driving the changes in the denitrification records variations in local productivity leading to a change in remineralization rates and or changes in the ocean circulation and ocean temperature resulting in variations of the physical supply of dissolved oxygen here we focus on the supply mechanism by using a fully coupled atmosphere ocean sea ice land surface scheme model the university of victoria earth system climate model to examine oxygen supply under varying physical conditions while maintaining an invariant biological oxygen utilization scheme we show that circulation changes can be the cause for the observed changes in dissolved oxygen in the glacial ocean lower temperatures and enhanced formation of antarctic intermediate water and north pacific intermediate water during glacial periods increase the physical supply of oxygen and therefore decrease water column denitrification in our last glacial maximum simulations the change in water characteristics in the eastern tropical pacific is important enough to reduce denitrification by 46 to 65 compared to present day conditions depending on the wind fields used as boundary conditions the consequences of our findings could be substantial for the near future with a warming climate denitrification zones could expand leading to changes in the biological pump and the flux of n2o into the atmosphere

last glacial holocene change in intermediate water ventilation in the northwestern pacific abstract the modern north pacific is the terminus for deep water circulation while no deep water mass is formed today the region is the source of north pacific intermediate water 300 800 m formed primarily in the sea of okhotsk however the source and strength of intermediate water in the glacial north pacific was likely different from the present intermediate water here we present microfossil evidence of late quaternary ventilation changes associated with changes in intermediate water intermediate water ventilation decreased drastically at the glacial termination when it switched to the modern circulation system the ventilation change appears to have been widespread and synchronous in the north pacific glacial microfossil assemblages indicate that there was relatively strong ventilation of intermediate water which seems to have been cold and well oxygenated as if produced by brine rejection during the formation of sea ice on the basis of the glacial distribution of microfossils in the north pacific we suggest that intermediate water was derived from the bering sea during the glacials rather than the sea of okhotsk

a review of nitrogen isotopic alteration in marine sediments key points use of sedimentary nitrogen isotopes is examined on average sediment 15n 14n increases approx 2 per mil during early burial isotopic alteration scales with water depth abstract nitrogen isotopes are an important tool for evaluating past biogeochemical cycling from the paleoceanographic record however bulk sedimentary nitrogen isotope ratios which can be determined routinely and at minimal cost may be altered during burial and early sedimentary diagenesis particularly outside of continental margin settings the causes and detailed mechanisms of isotopic alteration are still under investigation case studies of the mediterranean and south china seas underscore the complexities of investigating isotopic alteration in an effort to evaluate the evidence for alteration of the sedimentary n isotopic signal and try to quantify the net effect we have compiled and compared data demonstrating alteration from the published literature a 100 point comparison of sediment trap and surface sedimentary nitrogen isotope values demonstrates that at sites located off of the continental margins an increase in sediment 15n 14n occurs during early burial likely at the seafloor the extent of isotopic alteration appears to be a function of water depth depth related differences in oxygen exposure time at the seafloor are likely the dominant control on the extent of n isotopic alteration moreover the compiled data suggest that the degree of alteration is likely to be uniform through time at most sites so that bulk sedimentary isotope records likely provide a good means for evaluating relative changes in the global n cycle

composition and architecture of braided and sheetflood dominated ephemeral fluvial strata in the cambrian ordovician potsdam group a case example of the morphodynamics of early phanerozoic fluvial systems and climate change abstract two fluvial facies associations braided and ephemeral fluvial are recognized in strata of the cambrian ordovician potsdam group in the ottawa embayment and quebec basin in northeastern north america braided fluvial sedimentation was dominated by the migration of coarse grained sandy dunes and rare unit bars and local gravels that built up low relief 0 4 5 m thick downstream accreting compound bars in very wide and shallow braided channels rare meter scale confluence scours incision and filling of decimeter thick bypass channels and thin 7 cm overbank deposition also occurred ephemeral fluvial sedimentation was dominated by the progradation of lobate terminal splays most of which were deflated and or reworked into thin 10 95 cm sheets by eolian processes during the long recurrence intervals between floods these strata were locally incised by rare 0 3 1 9 m thick scour filling high energy supercritical bedform strata and decimeter thick bypass channels both braided and ephemeral fluvial deposits consist of meter scale stacked high order stratal units separated by horizontal laterally extensive surfaces recording the recurring buildup avulsion and finally abandonment of channel belts in braided fluvial strata of the potsdam the dominance of thin 2 m elongated compound bars with low relief 5 bar margins and internal accretion surfaces 15 suggest that braided channels and in channel compound bars expanded laterally with negligible increase in flow depth during periods of increased discharge in the absence of bank stabilizing vegetation similar to other examples of the pre vegetated sheet braided style however in areas where bedrock topography inhibited the lateral expansion of channels thicker compound braid bars 1 2 3 5 m with higher relief accretion surfaces up to 35 like those observed in post silurian and modern systems preferentially formed in relatively deep channels ephemeral fluvial deposits here are similar to ephemeral examples throughout geologic history in that they mostly comprise poorly confined sheet like terminal splays that accumulated in topographic lows however compared to several post silurian examples strata in the potsdam exhibit considerably more eolian reworking of splays and preservation of supercritical bedform strata a manifestation of greater rates of surface water infiltration due to a lack of sheltering by rooted plants and propensity for unconfined flooding finally in the upper part of the potsdam two regional ephemeral fluvial units are interstratified with two braided fluvial units providing evidence for shifts in regional climate the sharp areally extensive surfaces that separate these fluvial systems are interpreted to approximate time lines and therein provide a means for relative and absolute chronostratigraphic correlation these changes are correlated with documented late cambrian to earliest ordovician global climate fluctuations with semiarid conditions and related ephemeral fluvial systems corresponding to global cooling events at ca 491 and 487 ma

latitudinal variations in intermediate depth ventilation and biological production over northeastern pacific oxygen minimum zones during the last 60 ka abstract mechanisms affecting past variability in the oxygen minimum zone omz in the eastern tropical north pacific etnp are poorly known we analyzed core md02 2524 obtained from the nicaragua margin in the present etnp omz for major and minor elements titanium ti brome br silicon si potassium k and calcium ca using an x ray fluorescence xrf core scanner and redox sensitive trace elements uranium u molybdenum mo and nickel ni determined by icp ms the u and mo content was higher during the deglaciation than during the holocene and the last glacial maximum whereas enrichment was not observed for ni an element closely associated with organic matter high resolution xrf scanning indicated that the ca based carbonate content had millennial scale variability inversely correlated with br based organic matter and si k based opal content during the last glacial period the available data suggest no clear regional trend in biological productivity during the last deglaciation but significant local variability in the coastal eastern equatorial pacific the trace element enrichment and the lack of a concomitant increase in biogenic phases indicated that an enhanced etnp omz at least between 15 n and 12 n at a water depth of 500 900 m was principally caused by a reduced oxygen supply driven by oceanic circulation to the nicaragua basin during the deglaciation the observed patterns can be interpreted as the distinct changes in the oxygenation state of northern and southern water masses at intermediate depths we also found evidence for a decoupling between local productivity and pore water oxygenation for several millennial scale events during marine isotopic stage 3 indicating that remote oxygen consumption and or oceanic ventilation impacted omz intensity multi millennial scale variations of the productivity at papagayo upwelling cell displayed an opposite trend from productivity at the costa rica dome in relation with the latitudinal shift of the inter tropical convergence zone itcz latitudinal variations of the omz intensity reflected the relative influence of the northern and southern intermediate water masses whose oxygenation was driven by high latitude climates and productivity over the intermediate water pathway

melting of the patagonian ice sheet and deglacial perturbations of the nitrogen cycle in the eastern south pacific local 230 th normalized biogenic vertical fluxes from the chilean continental margin they document in detail the sharp transition from relatively low wcd rates during the last glacial maximum lgm to high ones during the deglaciation and holocene but give no evidence that the glacial interglacial difference of wcd could have been caused by changes in local primary productivity furthermore we found no evidence that changes in ventilation due to samw formation could explain the nitrogen isotope record we present evidence for an alternative mechanism related to the melting of the patagonian ice sheet pis which is consistent with recent published proxy data and the regional physical oceanography

the taylor dome antarctic 18o record and globally synchronous changes in climate abstract the 18 o 16 o profile of a 554 m long ice core through taylor dome antarctica shows the climate variability of the last glacial interglacial cycle in detail and extends at least another full cycle taylor dome shares the main features of the vostok record including the early climatic optimum with later cool phase of the last interglacial period in antarctica taylor dome 18 o fluctuations are more abrupt and larger than those at vostok and byrd station although still less pronounced than those of the greenland gisp2 and grip records the influence of the atlantic thermohaline circulation on regional ocean heat transport explains the partly north atlantic character of this antarctic record under full glacial climate marine isotope stage 4 late stage 3 and stage 2 this marine influence diminished and taylor dome became more like vostok varying degrees of marine influence produce climate heterogeneity within antarctica which may account for conflicting evidence regarding the relative phasing of northern and southern hemisphere climate change

upwelling intensity and filament activity off morocco during the last 250 000 years abstract the high productive upwelling area off morocco is part of one of the four major trade wind driven continental margin upwelling zones in the world oceans while coastal upwelling occurs mostly on the shelf biogenic particles derived from upwelling are deposited mostly at the upper continental slope nutrient rich coastal water is transported within the cape ghir filament region at 30 n up to several hundreds of kilometers offshore both upwelling intensity and filament activity are dependent on the strength of the summer trades this study is aimed to reconstruct changes in trade wind intensity over the last 250 000 years by the analysis of the productivity signal contained in the sedimentary biogenic particles of the continental slope and beneath the cape ghir filament detailed geochemical and geophysical analyses toc carbonate c n 13corg 15n 13c of benthic foraminifera 18o of benthic and planktic foraminifera magnetic susceptibility have been carried out at two sites on the upper continental slope and one site located further offshore influenced by the cape ghir filament a second offshore site south of the filament was analyzed toc magnetic susceptibility to distinguish the productivity signal related to the filament signal from the general offshore variability higher productivity during glacial times was observed at all four sites however the variability of productivity during glacial times was remarkably different at the filament influenced site compared to the upwelling influenced continental slope sites in addition to climate related changes in upwelling intensity zonal shifts of the upwelling area due to sea level changes have impacted the sedimentary productivity record especially at the continental slope sites by comparison with other proxies related to the strength and direction of the prevailing winds si al ratio as grain size indicator pollen the productivity record at the filament influenced site reflects mainly changes in trade wind intensity our reconstruction reveals that especially during glacial times trade wind intensity was increased and showed a strong variability with frequencies related to precession

comparative evolution of material flux through two dsdp successions from central atlantic and gulf of mexico preliminary results of a new approach to sedimentary dynamics in pelagic environments abstract a method for gaining knowledge of sedimentary fluxes is applied to early cretaceous sequences containing high frequency sedimentary cycles the cycles are used to determine the relative fluctuations of 1 the sedimentation rate and 2 carbonate and silicate terrigenous fluxes expressed as linear values proportional to the real fluxes visual and automatic image analysis of black and white core photographs have been used to calculate the masses of different materials deposited in equal time intervals and to determine the distribution of the material within lithological units of cores according to a scale of grey intensities characters of these distributions allow definition of a flux variability index assumed to be negatively correlated to ocean continent distance related itself to sea level at dsdp sites 534 western atlantic off florida and 535 gulf of mexico the valanginian hauterivian interval has been chosen for determining the relative variations of carbonate and silicate terrigenous linear fluxes their variability and their distribution within lithological cycles these data provide information about the relative importance of carbonate sources lands platforms and plankton and their evolution and of other forcings upon planktonic productivity such as supply of nutrients from the continents and upwelling by comparing the data in the two sites it is possible to detect common climate and eustasy and local factors tectonics and upwelling which have controlled the material fluxes compared with site 534 site 535 was supplied by more numerous active and close carbonate sources and less active but closer terrigenous sources at the two sites carbonate flux was controlled by common factors sea level being the most prominent one terrigenous flux was submitted to more local controls this new method for investigating pelagic deposits should be tested on other deep sea sedimentary sequences

glacial and holocene stable isotope distributions in the southeastern indian ocean we have reconstructed glacial interglacial variations in cibicidoides wuellerstorfi 13c and 18o in the southeastern indian ocean using depth transects of cores from off western and southern australia we compare these new results with published stable isotope records to constrain glacial interglacial changes in indian ocean chemistry and circulation the strong last glacial maximum lgm deep water 13c depletions previously observed for the northeastern indian ocean did not extend throughout the low latitude glacial indian ocean we observe only a small lgm 13c decrease off southern australia in marked contrast to the strong lgm 13c depletions observed in many cores from the atlantic and western indian sectors of the southern ocean it is not yet clear whether the very low lgm 13c values in the deep northern and southwestern indian ocean are an artifact of surface ocean productivity or whether they reflect real gradients in deep water chemistry

alkenone sea surface temperature in the southern ocean for the last two deglaciations a piston core taken from the tasman plateau in the southern ocean has been studied for organic compounds to reconstruct the late pleistocene marine environments here we report paleo sea surface temperature sst for the last two deglaciations using the unsaturation degree of alkenones u k 37 preserved in the marine sediments the u k 37 record indicates that the sst was at least 4 c lower than the present sst at the last glacial maximum lgm and the amplitude of paleo sst is at most 5 2 c from the penultimate glacial mis 6 to the last interglacial warm period the eemian our results also demonstrate that the eemian warm period in the southern ocean lasted only 3 000 years followed by a sharp cooling at around 120 kyr bp the sharp cooling in the southern ocean seemed to occur a few millennia 2 3 kyrs before the beginning of continental ice sheet growth

molecular fossil evidence for anaerobic ammonium oxidation in the arabian sea over the last glacial cycle anaerobic ammonium oxidation anammox has been recognized as an important process converting fixed nitrogen to n2 in many marine environments thereby having a major impact on the present day marine nitrogen cycle however essentially nothing is known about the importance of anammox in past marine nitrogen cycles in this study we analyzed the distribution of fossil ladderane lipids derived from bacteria performing anammox in a sediment core from the northern arabian sea concentrations of ladderane lipids varied between 0 3 and 5 3 ng g 1 sediment during the past 140 ka with high values observed during the holocene intervals during the last glacial and during the penultimate interglacial maxima in ladderane lipid abundances correlate with high total organic carbon 4 6 and elevated 15n 8 values anammox activity therefore seems enhanced during periods characterized by an intense oxygen minimum zone omz low concentrations of ladderanes 0 5 ng g 1 sediment indicating low anammox activity coincide with periods during which the omz was severely diminished since anammox activity covaried with omz intensity it may play an important role in the loss of fixed inorganic nitrogen from the global ocean on glacial interglacial timescales which was so far attributed only to heterotrophic denitrification

euxinia and primary production in late cretaceous eastern equatorial atlantic surface waters fostered orbitally driven formation of marine black shales 1 oceanic anoxic events oae in the cretaceous represent major perturbations in the global climate and ocean system characterized by widespread deposition of organic carbon in the ocean the causes and effects of these events are poorly constrained mainly because of the lack of high resolution marine records here we report the distribution of molecular markers from a millennial scale record of coniacian santonian black shale oae 3 from ocean drilling program site 959 in the deep ivorian basin in the eastern equatorial atlantic highly branched isoprenoids and alkenone derived organic compounds indicate that diatoms and calcareous nanoplankton were important primary producers changes in redox sensitive trace metal accumulation and biomarkers of green sulfur bacteria provide evidence for extreme variations in redox conditions with intervals of lower photic zone euxinia pze accordingly oxygen in the coniacian santonian tropical atlantic was absent as during the cenomanian turonian boundary oae 2 but over more restricted geographic area and more limited time intervals we hypothesize that pze was a common phenomenon typical in large areas of tropical continental margins these conditions fostered sequestration of atmospheric co2 and thus helped cause the positive excursion in 13c of carbonate documented in higher latitude marine records

plio pleistocene denitrification in the eastern tropical north pacific intensification at 2 1 ma 1 global climate has changed substantially over the past 4 million years ma toward on average colder conditions and higher amplitude oscillation between glacial and interglacial periods corresponding changes in marine biogeochemistry could have linked oceanic circulation changes to the global carbon cycle but remain poorly understood we report a high resolution 4 ma long 15n record from ocean drilling program site 1012 on the california margin which monitors denitrification intensity in one of the principal oxygen minimum zones omzs of the open ocean the 15n record demonstrates that eastern tropical north pacific etnp denitrification was weak for much of the late pliocene though there was no apparent change associated with northern hemisphere glaciation nhg at 2 7 ma denitrification strengthened substantially by 2 in 15n at 2 1 ma since 2 1 ma intense denitrification in the etnp occurred during interglacial periods and was generally very climate sensitive we infer that two oceanic changes the shoaling of the thermocline in the eastern pacific and thus the strengthened walker circulation and the development of a modern like frontal system in high latitude southern ocean around 2 1 ma provided favorable conditions for intensification of etnp denitrification that was also likely mirrored south of the equator intermediate water circulation changes likely created the poorly ventilated zones susceptible to the suboxic condition required by denitrification 2 1 ma thus marks a critical point for the reorganization of the ocean s nitrogen cycle in which open ocean denitrification became a significant loss term during interglacial phases of climate given linkage between the ocean s n and c cycle etnp denitrification changes probably contributed to plio pleistocene climatic changes

sources of fine sized organic matter in north atlantic heinrich layers δ13c and δ15n tracers organic carbon oc and total nitrogen tn concentrations and stable isotope ratios d13c d15n of fine 50 m size fractions of deep sea sediments from the central north atlantic were employed to identify changes in sources of organic matter over the past 50 ka bp ambient glacial sediments are characterised by values that reflect mixtures of marine and terrestrial inputs averages 1s oc tn 7 6 0 8 d13c 22 8 1 0 d15n 5 5 0 6 d13c oc and tn concentrations shift to higher values during the holocene indicating a gradual decrease of fine terrigenous supply to the north atlantic the unchanged d15n record between last glacial and holocene stages indicates that the central north atlantic region remained oligotrophic at least during the past 50 ka bp but additional studies are required to support this result in terms of nitrogen oceanic budget during the phases of enhanced ice rafted detrital supply corresponding to prominent heinrich events hl1 hl2 hl4 and hl5 fine sized sedimentary organic matter has lower oc and tn concentrations contrasting sharply with those of ambient glacial sediments lower d13c down to 28 and d15n down to 1 6 values and high oc tn ratios up to 14 7 1 1 are found for hl1 hl2 and with lesser extent for hl4 these values reflect enhanced detrital supply originating from poorly differentiated soil horizons that characterise periglacial climate conditions and from organic matter bearing rock sources of the underlying geological basement during hl5 only the d13c offset records the input of fine size ice rafted organic matter gradually changing soil development conditions during the time interval covering hl5 to hl1 marine isotope stages 5 to 2 as well as varying erosion levels have been hypothesized on the basis of constant d13c increasing oc tn and decreasing d15n values

a dynamic concept for eastern mediterranean circulation and oxygenation during sapropel formation we propose that intermittent bottom water ventilation occurred throughout periods of sapropel deposition and that the recently reported sapropel interruptions represent centennial scale episodes of enhanced frequency intensity of that process in essence the modern high frequency variability in deep water formation affected by climatic variability over the northern basins on seasonal to longer time scales prevailed also at times of sapropel deposition although the overall ventilation state was much reduced this concept is supported by detailed multiple species isotope records for three aegean cores the presence of abundant globorotalia truncatulinoides within especially sapropels s7 and s8 in the western levantine basin observations of three rapid benthic repopulations within sapropel s6 in the deep western levantine basin a report of continuous benthic presence through sapropel s1 at intermediate deep locations offshore libya and further supporting information from the literature in the aegean records concomitant abundance of low oxygen tolerant benthic foraminifera and presence of the more oxyphilic benthic foraminifer uvigerina mediterranea with surface similar 13c values indicate repeated deep water re oxygenation events throughout the deposition of s1 the observations of a continuous benthic presence through s1 offshore from libya imply that no persistent anoxia developed at mid depth levels in that region which is far removed from direct deep ventilation influences the abundance of deep mesopelagic g truncatulinoides through several sapropels from the western levantine basin also suggests the presence of bio available oxygen at many hundreds of meters of depth moreover the rapid intermittent benthic repopulations within sapropels from the deep eastern mediterranean imply that bottom water anoxia was spatially restricted and or of a highly intermittent nature the short time scales of these repopulation events are incompatible with titration of an extensively anoxic water column and subsequent re establishment of water column anoxia we suggest that where anoxic azoic conditions were present they most likely were restricted to a veneer at the sediment water interface the extent of such an anoxic blanket depends on the balance between advective oxygen supply into the deep sea and biological and chemical oxygen demand the demand functions imply a decoupling of oxygenation from water mass advection allowing export production and corg posting rates to the sea floor to delimit the extent of the anoxic blanket in both space and time low productivity regions would develop no anoxic blanket allowing for the observed persistence of deep dwelling planktonic and bottom dwelling benthic faunas

nitrogen isotope and chlorin paleoproductivity records from the northern south china sea remote vs local forcing of millennial and orbital scale variability abstract variations in nitrogen isotopic composition 15n and total chlorin accumulation rate ar are employed as proxies to reconstruct oceanic nitrate inventory the balance between denitrification and n fixation and paleoproductivity in a rapidly accumulating sediment drift deposit beneath the western pacific warm pool for the last 145 kyr subsurface and deep waters of the northern south china sea scs are sourced from the shallow kuroshio current kc and pacific intermediate water respectively their relative importance in determining sedimentary 15n and paleoproductivity have been altered by changes in equatorial circulation summer and winter monsoon intensity and relative sea level the location and basin configuration of the marginal scs renders it especially sensitive to such changes assuming complete annual nitrate utilization low 15n values during glacial stages are interpreted as a reflection of reduced remote denitrification in the eastern tropical north pacific etnp source waters while much of marine isotope stage mis 3 and the last interglacial were characterized by high denitrification however intervals of anomalously low 15n values are interpreted as reflecting the contribution from regional n fixation in west pacific surface waters transmitted to the site by the shallow kc unusually the holocene is characterized by declining 15n values and an inverse correlation with organic matter content since ca 8 2 ka millennial scale variations during mis 3 indicate higher frequency variations in both etnp denitrification and local n fixation which may be coherent with a hemispheric response to dansgaard oeschger events recorded at high latitudes for much of the last 145 kyr paleoproductivity was decoupled from 15n and instead seems to reflect the extent of the global nitrate inventory stimulated by elevated dust fertilization and regional mixed layer deepening associated with the relative intensity of the se asian winter monsoon despite evaluation of possible conflicting influences on the record of each proxy we interpret our data as clear evidence of glacial interglacial changes in marine nutrient inventory across the whole of the north pacific with a corresponding biogeochemical response and important implications for global co2 drawdown via an invigorated biological pump the relative importance of local regional and global contributions to our records appears to be strongly modulated by relative sea level controlling trans and extra basinal circulation in the scs

variations of oxygen minimum and primary productivity recorded in sediments of the arabian sea abstract two deep sea sediment cores from the northeastern and the southeastern arabian sea were studied in order to reconstruct the palaeoenvironments of the past glacial cycles core 136kl was recovered from the high productivity area off pakistan within the modern oxygen minimum zone omz by contrast modern primary productivity at the site of md900963 close to maldives is moderate and bottom waters are today well oxygenated for both cores we reconstructed the changes in palaeoproductivity using a set of biomarkers alkenones dinosterol and brassicasterol the main result is that primary productivity is enhanced during glacial stages and lowered during interstadials the proxies associated with productivity show a 23 kyr cyclicity corresponding to the precession related insolation cycle palaeoredox conditions were studied in both cores using a new organic geochemical parameter c35 c31 n alkane ratio developed by analysing surface sediments from a transect across the omz off pakistan the value of this ratio in core 136kl shows many variations during the last 65 kyr indicating that the omz was not stable during this time it disappeared completely during heinrich and the younger dryas events pointing to a connection between global oceanic circulation and the stability of the omz the c35 c31 ratio determined in sediments of core md900963 shows that bottom waters remained rather well oxygenated over the last 330 kyr which is confirmed by comparison with authigenic metal concentrations in the same sediments a zonally averaged circulation biogeochemical ocean model was used to explore how the intermediate indian ocean responds to a freshwater flux anomaly at the surface of the north atlantic as suggested by the geochemical time series both the abundance of southern ocean water and the oxygen concentration are significantly increased in response to this freshwater perturbation

multiple late quaternary episodes of exceptional diatom production in the gulf of alaska abstract hole 887b of the ocean drilling program odp comprises a 44 m 750 kyr long continuous section recovered from the patton murray rise an elevated plateau that is largely isolated from turbidite deposition the patton murray area is centered under the alaska gyre a region characterized by the domal upwelling of nutrient rich waters marked increases in productivity and rapid settling of biogenic matter are suggested throughout the section by the episodic accumulation of diatomaceous oozes up to 1 m thick that are accompanied by barium enrichments significant 13corg maxima in the major diatomaceous bands suggest that mixed layer co2 aq may have been drawn down significantly during some of the productivity events the episodes of enhanced productivity at site 887 occur synchronously with short lived minima in planktonic foram 18o suggesting a direct link to low salinity or less likely warming events in the gulf of alaska there is no obvious explanation for the events but they may be related to seasonal incursions of meltwater from alaska we speculate that episodic input of meltwater or dust borne iron from asian or alaskan sources may have promoted the extraordinary diatom production events recorded in the sedimentary record

denitrification in continental shelf sediments has major impact on the oceanic nitrogen budget denitrification rates in sediments within the oxygen deficient waters off mexico and from the gulf of maine were investigated on the basis of interstitial nutrient profiles nitrate fluxes into the sediments were calculated from gradients across the sediment water interface and vertical molecular diffusion coefficients and averaged 0 151 mexico and 0 0920 gulf of maine pmol no 3 cm 2 s 1 these are minimum values since these gradients may have been underestimated in the gulf of maine bottom water irrigation by macrobenthos increases the nitrate supply well above this estimate in addition only 15 22 of the expected ammonium is present in gulf of maine sediments perhaps because of removal by a rapid coupling of nitrification with denitrification this large apparent loss of the regenerated ammonium appears to be ubiquitous in shelf sediments with oxygenated bottom water the global denitrification rate in continental shelf sediments was reassessed to be 50 tg n yr 1 1 tg 1012 g demonstrating that sediments are an important sink for oceanic nitrogen globally current nitrogen losses from the oceans may exceed inputs by 60 90 tg n yr 1 over the glacial interglacial cycle the global sedimentary denitrification rate probably varied commensurately with the changing continental shelf area an oscillating oceanic nitrogen budget over these time scales could occur given the sequence of 1 scouring and dumping of terrestrial nitrogen into the oceans during glacial advance 2 removal of oceanic combined nitrogen to the atmosphere by denitrification following glacial retreat and 3 reincorporation of this n into terrestrial biomass during the interglacial period

glacial interglacial variability in the eastern tropical north pacific oxygen minimum zone recorded by redox sensitive trace metals 1 changes in the intensity of the oxygen minimum zone omz in the eastern tropical north pacific over the past 140 kyr are recorded as enrichments and depletions of redox sensitive metals in sediments of two piston cores one within and one below the modern omz from the continental margin off mazatlan mexico 22 41 n 106 28 w concentrations of al 7 7 0 6 ti 0 37 0 03 fe 3 1 0 25 mn 320 31 ppm and ba 560 82 ppm in core nh15p within the omz at 420 m water depth were relatively constant over the last 110 kyr in contrast concentrations of cd 4 8 2 ppm cu 29 8 9 1 ppm u 9 1 3 7 ppm mo 12 1 5 0 ppm v 138 2 51 9 ppm and re 45 8 25 5 ppb were all at least 30 higher in interglacial stages compared to glacial stages concentrations of al 7 4 0 3 ti 0 35 0 03 fe 3 5 0 4 and mn 385 77 ppm in core nh22p below the omz at 2025 m water depth were comparable to those in core nh15p while concentrations of ba 1662 292 ppm were about a factor of three higher in contrast concentrations of cd 0 9 0 3 ppm u 6 6 0 9 ppm mo 3 2 1 2 ppm v 81 8 10 1 ppm and re 25 4 12 ppb were lower in sediments of comparable age than the concentrations of these same metals in the omz core and the differences in their concentrations over glacial interglacial cycles were less pronounced than those in shallower core comparison of the nonlithogenic fraction of metals in the sediments with their estimated contribution from plankton suggests that organic matter is probably the major source of cu ba and perhaps cd to the sediment whereas the indirect effects of organic carbon and low bottom water oxygen concentrations on sediment redox state appear to be more important controls on the distributions u re mo and v changes in the depth at which re and mo precipitated in the sediments and in the re mo ratio suggest that the redox state of the surface sediment and overlying water at both core depths varied over time re and mo removal depths were shallower and re mo ratios were lower at the omz site than in deeper water suggesting that a more reducing environment prevailed over time at the shallower site although the redox state of the waters and sediment at both sites varied over glacial interglacial cycles the omz likely was never anoxic in the last 140 kyr this variability in redox state could be attributed to changes in regional export productivity changes in ocean circulation or a combination of both processes a paleoproductivity reconstruction from biogenic ba data suggests that glacial productivity was considerable lower than it was during interglacial stages model results suggest that the oxygen penetration depth an indicator of sediment redox state changed less than 1 cm as a result of the change in productivity changes in oxygen penetration depth estimated from re and u removal depths are significantly larger suggesting that changes in ventilation are a more important control on sediment redox state overall trace metal results confirm the tight coupling between ocean circulation marine productivity and global change

interior hydrography and circulation of the glacial pacific ocean abstract the deep water of the pacific ocean is a key component of the global climate system on the time scale of late pleistocene glaciation and deglaciation despite its importance the deep pacific during the last glacial maximum has received relatively little attention compared to the deep atlantic in part because the pacific poorly preserves carbonate sediments on the sea floor here we review the current state of knowledge of the deep hydrography and circulation of the glacial pacific by examining available nutrient proxy data including some new 13 c and 18 o data measured on benthic foraminifera planulina wuellerstorfi from the vicinity of japan available benthic 13 c and 18 o and radiocarbon data from the pacific support the presence of a deep hydrographic boundary at around 2000 m during the last glacial maximum paleoceanography 3 1988 343 paleoceanography 7 1992 273 paleoceanography 13 4 1998 323 the deep hydrographic divide in the glacial pacific is similar to what is inferred in the atlantic quaternary research 18 1982 218 paleoceanography 3 1988 317 paleoceanography 3 1988 343 annual reviews of earth planetary sciences 20 1992 245 science 259 1993 1148 the indian nature 333 1988 651 paleoceanography 13 1998 20 and the southern ocean paleoceanography 11 1996 191 suggesting that this is a global phenomenon during the glacial time the upper water mass has a distinctly enriched 13 c compared to the deeper water mass whose possible origins are discussed

the impact of ocean deoxygenation on iron release from continental margin sediments in the oceans high nitrate low chlorophyll regions such as the peru humboldt current system and the adjacent eastern equatorial pacific1 primary productivity is limited by the micronutrient iron within the peruvian upwelling area bioavailable iron is released from the reducing continental margin sediments2 the magnitude of this seafloor source could change with fluctuations in the extension or intensity of the oxygen minimum zones3 4 here we show that measurements of molybdenum uranium and iron concentrations can be used as a proxy for sedimentary iron release and use this proxy to assess iron release from the sea floor beneath the peru upwelling system during the past 140 000 years we observe a coupling between levels of denitrification as indicated by nitrogen isotopes trace metal proxies for oxygenation and sedimentary iron concentrations specifically periods with poor upper ocean oxygenation are characterized by more efficient iron retention in the sediment and a diminished iron supply to the water column we attribute efficient iron retention under more reducing conditions to widespread sulphidic conditions in the surface sediment and concomitant precipitation of iron sulphides we argue that iron release from continental margin sediments is most effective in a narrow redox window where neither oxygen nor sulphide is present we therefore suggest that future deoxygenation in the peru upwelling area would be unlikely to result in increased iron availability whereas in weaker oxygen minimum zones partial deoxygenation may enhance the iron supply

revisiting nutrient utilization in the glacial antarctic evidence from a new method for diatom bound n isotopic analysis holocene in the indian sector is smaller than in previous measurements these data suggest no change in the degree of nitrate utilization in the atlantic sector and at most a 20 increase from 25 to 45 in the indian sector the new measurements suggest that during the last ice age in the atlantic sector of the antarctic the atmospheric source of biologically available iron was not so great as to become significant relative to the iron supply from below given the apparent spatial variability in the degree of nitrate drawdown more work is required to develop an adequate picture of the glacial antarctic nutrient field index terms 4806 oceanography biological and chemical carbon cycling 4845 oceanography biological and chemical nutrients and nutrient cycling 4894 oceanography biological and chemical instruments and techniques 9310 information related to geographic region antarctica

southern ocean control on the extent of denitrification in the southeast pacific over the last 70 ka abstract temporal changes in oceanic denitrification the bacterial reduction of nitrate under suboxic conditions highlight the potential importance of n inventory changes and the production of n 2 o on the climate system at the same time the cause of the globally observed variation in denitrification remains unclear high resolution benthic foraminiferal oxygen isotope and bulk sediment nitrogen isotope records from odp site 1234 on the chile margin record integrated denitrification changes within the peru chile upwelling system over the last 70 ka denitrification changes in the southeast pacific are coherent with antarctic climate changes recorded by the byrd ice core 18 o record and lead northern hemisphere climate events the southern hemisphere character of the chile margin 15 n record suggests that episodes of reduced denitrification in the se pacific represent times when more oxygen was supplied as the result of changes in the ventilation and preformed nutrient content of subantarctic mode water samw which forms in the subantarctic zone of the southern ocean and feeds into the low latitude thermocline

asynchronous alkenone and foraminifera records from the benguela upwelling system abstract radiocarbon stratigraphy is an essential tool for high resolution paleoceanographic studies age models based on radiocarbon ages of foraminifera are commonly applied to a wide range of geochemical studies including the investigation of temporal leads and lags the critical assumption is that temporal coupling between foraminifera and other sediment constituents including specific molecular organic compounds biomarkers of marine phytoplankton e g alkenones is maintained in the sediments to test this critical assumption in the benguela upwelling area we have determined radiocarbon ages of total c37 c39 alkenones in 20 samples from two gravity cores and three multicorer cores the cores were retrieved from the continental shelf and slope off namibia and samples were taken from holocene deglacial and last glacial maximum core sections the alkenone radiocarbon ages were compared to those of planktic foraminifera total organic carbon fatty acids and fine grained carbonates from the same samples interestingly the ages of alkenones were 1000 to 4500 yr older than those of foraminifera in all samples such age differences may be the result of different processes bioturbation associated with grain size effects lateral advection of recycled material and redeposition of sediment on upper continental slopes due to currents or tidal movement are examples for such processes based on the results of this study the age offsets between foraminifera and alkenones in sediments from the upper continental slope off namibia most probably do not result from particle selective bioturbation processes resuspension of organic particles in response to tidal movement of bottom waters with velocities up to 25 cm s recorded near the core sites is the more likely explanation our results imply that age control established using radiocarbon measurements of foraminifera may be inadequate for the interpretation of alkenone based proxy data observed temporal leads and lags between foraminifera based data and data derived from alkenone measurements may therefore be secondary signals i e the result of processes associated with particle settling and biological activity

phosphorus accumulation in marine sediments and the oceanic phosphorus cycle ideas about key factors in the oceanic mass balance of dissolved reactive phosphate have changed substantially i present an integrated overview of these here with an emphasis on evaluating the burial sinks for p and defining areas needing further research the major source of reactive p to the ocean is river input reactive p is delivered to the oceanic sediment water interface primarily in particulate organic matter p scavenged by hydrothermal iron rich oxyhydroxide particles with uptake in proportion to deep water phosphate concentrations represents a substantially smaller flux to the sediment water interface diagenetic transformations are important influences on the form of reactive p burial in marine sediments p burial occurs with organic carbon burial and as p associated with iron rich oxyhydroxide particles and coatings formation of authigenic p rich phases presumably apatite at the expense of organic p and oxide associated p is significant in open ocean marine sediments the authigenic p sink may represent a substantially larger portion of the sedimentary burial than indicated by previous estimates focused on p burial in organic rich continental margin sediments

nitrogen isotope and productivity variations along the northeast pacific margin over the last 120 kyr surface and subsurface paleoceanography 1 glacial interglacial changes in sedimentary 15n over the last 120 kyr display a remarkably similar pattern in timing and amplitude in core records extending from the denitrification zone in the eastern tropical north pacific etnp where subsurface denitrification is active to the oregon margin where no denitrification occurs today low 15n values 4 6 generally characterize glacial stages 2 and 4 and higher 15n values 7 10 are representative of the holocene millennial scale periods within stage 3 and stage 5 the inferred synchroneity of 15n variations along the entire margin implies that the nitrate isotopic signal produced in the oxygen poor subsurface waters in the etnp is rapidly advected northward and recorded at sites far beyond the boundaries of the modern denitrification zone similar to 15n primary production indicators percent corg ba al and percent opal show glacial interglacial as well as millennial scale variations along the ne pacific margin with higher primary production during warm periods however the relative phasing between 15n and paleoproduction tracers within individual records changes latitudinally whereas 15n and primary production vary approximately synchronously in the midlatitudes production lags 15n in the etnp by several kiloyears this lag calls for a new understanding of the processes driving denitrification in the etnp we suggest that oxygen input by the equatorial undercurrent as well as local organic matter flux controls denitrification rates in the etnp moreover the differences in relative timing point to a time transgressive development of upwelling favorable winds along the ne pacific margin after the last glaciation with those in the north developing several kiloyears earlier

stable nitrogen isotope analysis of the upper devonian palynomorph tasmanites abstract bulk samples are commonly used in stable n isotope studies to infer climate changes however due to uncertainties in the composition of bulk samples the inconsistency of diagenetic alteration and the variation of dominant oceanic features such as n fixation and denitrification the isolation of specific sedimentary n fractions has become a crucial step to understanding the nitrogen cycle this paper describes the extraction techniques and the stable nitrogen isotope analysis on a nano ea irms of the palynomorph tasmanites spp 80 200 m found in upper devonian famennian black shales from kentucky usa tasmanites is a widely occurring and long ranging prasinophyte unicellular green algae genus palynomorphs such as tasmanites are highly resistant to most forms of decay it is therefore suggested that the 15n signature of this palynomorph may be a useful unaltered indicator of baseline isotopic change in future palaeoclimate studies the greatly reduced sample size accepted by the nano ea irms makes this technique a viable complement to bulk sediment analyses the results using the nano ea irms demonstrate that the 15n signature of the bulk organic samples differ significantly from that of the isolated tasmanites spp three distinct isotopic relationships were observed from the three different sample localities these include parallel changes in the 15n values of bulk samples and extracted tasmanites spp variation in the 15n of bulk samples with no corresponding change recorded in tasmanites spp and opposing 15n changes recorded between the bulk samples and the extracted tasmanites spp this inconsistent isotopic variation further emphasises the complexity of the nitrogen cycle possible explanations for the observed variation include changes in the rate of n fixation and denitrification due to climate change incomplete nitrification and variation in the bulk organic content

centennial to millennial scale changes in oxygenation and productivity in the eastern tropical south pacific during the last 25 000 years oxygen minimum zones omz have expanded in all tropical oceans during the last 50 years resulting in habitat contraction and considerable changes in marine biogeochemistry however for a better understanding of the omz dynamics under the current climate change two questions are relevant 1 how do the magnitude and temporal changes in oceanic dissolved oxygen of the last few decades compare to the natural variability on longer timescales and 2 what were the local and remote factors driving omz changes in the past in the present study we use a stacked record covering the last 25 kyr from the eastern tropical south pacific etsp omz to reconstruct changes in oxygenation and productivity we use a suite of proxies including the presence of laminations redox sensitive metals u mo re ni and cu total organic carbon and 15 n measurements water column denitrification and sediment redox conditions show pronounced centennial to millennial scale variability during the last 25 kyr with oxygenation levels as low as at present global cold periods at different timescales such as the last glacial maximum 23 19 kyr bp and the little ice age 1500 1850 ad were associated with a weak omz and low export production while warm intervals such as the deglaciation part of the medieval climate anomaly and the last 100 years are associated with a stronger omz and high export production water column denitrification and sediment redox conditions were strongly coupled during the last 25 kyr bp apart from one remarkable exception during the antarctic cold reversal sediments were less reducing but the water column denitrification was high resulting in a strong but shallow omz this may have been produced by an enhanced antarctic intermediate water flow contrary to our expectations and modeling predictions for the next few decades we observe a weak etsp omz during the warm mid holocene which may have been the result of a stronger walker circulation that brought oxygen rich waters to intermediate depths off peru via equatorial undercurrents in combination with other paleoceanographic reconstructions our results show that oxygenation variability in the etsp omz was influenced by ocean circulation changes in the tropical pacific high latitude oceanographic and climatic changes and local productivity

the dynamics of the marine nitrogen cycle across the last deglaciation 1 we use a geochemical box model to investigate the changes in marine n fixation and denitrification required to match the observed sedimentary 15n changes between 30 kyr b p and the late holocene this is achieved by optimizing a set of seven parameters that describe the strengths of three ocean internal n feedbacks and the response of the oceanic n cycle to four external forcings scenarios that best match the 15n constraints indicate a strong transient decrease in n fixation in the early deglacial in response to the decrease in iron input by dust around 15 kyr b p n fixation rebounds primarily in response to an abrupt increase in water column denitrification caused by an expansion of anoxia benthic denitrification is not well constrained by our model but tends to increase in sync with water column denitrification as a result of the transient imbalance between n fixation and denitrification we infer a glacial to interglacial decrease in the marine n inventory of between 15 and 50 the model diagnoses this reduction in order to simultaneously fit the data from all ocean basins requiring it to reduce the degree by which water column denitrification in the oxygen minimum zones is influencing the 15n of nitrate of the whole ocean dilution effect our optimal solution suggests a glacial n cycle that operated at nearly the same rates as that in pre industrial times but sensitivity cases with substantially lower rates fit the data only marginally worse an important caveat of our study is the assumption of an unchanging ocean circulation an initial sensitivity experiment shows that this affects primarily the magnitude of the change in the n inventory while the diagnosed deglacial dynamics with global marine n fixation taking a dip before the onset of denitrification remains a robust result

investigating the history of east asian monsoon and climate during the last glacial interglacial period 0 140 000 years mineralogy and geochemistry of odp sites 1143 and 1144 south china sea abstract monsoon climate is an important component of the global climatic system a comprehensive understanding of its variability over glacial interglacial time scales as well as of its effects on the continent and in the ocean is required to decipher links between climate continental weathering and productivity a detailed multiproxy study including bulk and clay mineralogy grain size analysis phosphorus geochemistry sedex extraction organic matter characterization and nitrogen stable isotopes was carried out on samples from odp sites 1143 and 1144 leg 184 south china sea covering the past 140 000 years we tentatively reconstruct the complex sedimentation and climatic history of the region during the last glacial interglacial cycle when sea level variations linked to the growth and melting of ice caps interact with monsoon variability during interglacial periods of high sea level summer monsoon was strong and humid and warm climate characterized the adjacent continent and islands clay minerals bear signals of chemical weathering during these intervals high calcite and reactive phosphorus mass accumulation rates mars indicate high productivity especially in the southern region of the basin during glacial intervals strong winter monsoon provided enhanced detrital input from the continent as indicated by high detrital mar glacial low sea level resulted in erosion of sediments from the exposed sunda shelf to the south and clay mineral variations indicate that warm and humid conditions still prevailed in the southern tropical areas enhanced supply of nutrients from the continent both by river and eolian input maintained high primary productivity reduced circulation during these periods possibly induced active remobilization of nutrients such as phosphorus from the sediments intense and short cold periods recorded during glacial and interglacial stages correlate with loess records in china and marine climatic records in the north atlantic confirming a teleconnection between low and high latitude climate variability

surface nitrate utilization in the bering sea since 180 ka bp insight from sedimentary nitrogen isotopes we present high resolution records of sedimentary nitrogen 15nbulk and carbon isotope ratios 13cbulk from piston core so201 2 85kl located in the western bering sea the records reflect changes in surface nitrate utilization and terrestrial organic matter contribution in submillennial resolution that span the last 180 kyr the 15nbulk record is characterized by a minimum during the penultimate interglacial indicating low nitrate utilization 62 80 despite the relatively high export production inferred from opal concentrations along with a significant reduction in the terrestrial organic matter fraction mterr this suggests that the consumption of the nitrate pool at our site was incomplete and even more reduced than today 84 15nbulk increases from marine isotope stage mis 5 4 and culminates during the last glacial maximum which indicates that nitrate utilization in the bering sea was raised during cold intervals mis 5 4 5 2 4 and almost complete during mis 3 and 2 93 100 this is in agreement with previous hypotheses suggesting that stronger glacial stratification reduced the nutrient supply from the subeuphotic zone thereby increasing the iron to nutrient ratio and therefore the nitrate utilization in the mixed surface layer large variations in 15nbulk were also recorded from 180 to 130 ka bp mis 6 indicating a potential link to insolation and sea level forcing and its related feedbacks millennial scale oscillations were observed in 15nbulk and 13cbulk that might be related to greenland interstadials

holocene climate variability in antarctica based on 11 ice core isotopic records a comparison is made of the holocene records obtained from water isotope measurements along 11 ice cores from coastal and central sites in east antarctica vostok dome b plateau remote komsomolskaia dome c taylor dome dominion range d47 km105 and law dome and west antarctica byrd with temporal resolution from 20 to 50 yr the long term trends possibly reflect local ice sheet elevation fluctuations superimposed on common climatic fluctuations all the records confirm the widespread antarctic early holocene optimum between 11 500 and 9000 yr in the ross sea sector a secondary optimum is identified between 7000 and 5000 yr whereas all eastern antarctic sites show a late optimum between 6000 and 3000 yr superimposed on the long time trend all the records exhibit 9 aperiodic millennial scale oscillations climatic optima show a reduced pacing between warm events typically 800 yr whereas cooler periods are associated with less frequent warm events pacing 1200 yr

nitrogen cycling on the namibian shelf and slope over the last two climatic cycles local and global forcings 1 in the light of new surface sediment 15n data collected over the namibian shelf and slope we examined glacial interglacial variations of n inventory in the area of luderitz 25 6s by deciphering 15n signals of three cores distributed from the upper to the lower continental slope the lower slope cores display low 15n during cold periods and high 15n during climatic optima akin to many other records from the world ocean whereas the upper slope core displays a high frequency low amplitude 15n signal without obvious glacial interglacial variability this dissimilarity results from the segregation of the upwelling structure in two cells decoupling nutrient dynamics of the shelf from those beyond the shelf edge the 15n signal of the coastal cell is relatively constant irrespective of wind strength variations and shows that nitrate was never depleted in the surface water for the deeper cores comparisons between n isotopic signals and indicators of paleoproductivity total organic carbon and upwelling intensity sea surface temperature and dust grain size reveal that over milankovitch cycles nitrate delivery to the photic zone was driven by the nutrient richness of the south atlantic central water depending in turn on aghulas water inflow and denitrification at a global scale rather than by atmospheric forcing we propose that the 15n signals of the deeper cores do not only mirror changes in relative nitrate utilization as it seems the case over annual timescales but are arguably influenced by global ocean changes in middepth nitrate 15n

interpretation of the nitrogen isotopic signal variations in the mauritanian upwelling with a 2d physical biogeochemical model 1 a physical biogeochemical model is used to simulate the evolution of the 15n signal during the last glacial interglacial transition in sedimentary cores offshore from the mauritanian upwelling the biological model is a classical nitrogen based trophic chain model which also computes the nitrogen isotope fractionation the 2d physical primitive equation model simulates the coastal upwelling circulation and is applied for different sea level scenarios the effect of the sea level rise inducing the shelf immersion seems to be a main factor explaining the organic nitrogen flux and isotopic signal variations along the last deglaciation this effect is modulated by an upwelling seasonality that may have been much longer at the last glacial maximum around 10 11 months instead of 4 5 months at present between 15 and 5 5 kyr ago 60 of the sedimentary 15n variations could be explained by this local shelf immersion effect this reconstruction also reproduces the strong isotopic fall occurring between 5 5 kyr and the present

glacial deep water properties in the west equatorial pacific bathyal thermocline near a depth of 2000 m abstract the stable isotope stratigraphy of planulina wullerstorfi in three box cores from ontong java plateau in the western equatorial pacific shows that there existed a bathyal thermocline near the depth of 2000 m during glacial time waters below the boundary were colder by about 1 c those above were about the same as now the deep waters were slightly enriched and the upper waters depleted in nutrients compared with present values the differences in 13 c to the present after correcting for the global change are of the order of 0 1 more positive above 2000 m and 0 1 more negative below corresponding to changes in phosphate of the order of 0 1 mol kg less phosphate above and more below the boundary

climatically linked oscillations in arabian sea denitrification over the past 1 m y implications for the marine n cycle water column and core top 15n data show that arabian sea denitrification produces large nitrogen isotopic enrichments that are regionally recorded with fidelity in the sediments these results facilitate interpretation of a 1 m y 15n record for ocean drilling program site 722b on the owen ridge in terms of climatically linked oscillations in denitrification at the major orbital periods as at present denitrification was greatest during interglacial periods and apparently was not active during most glacial intervals cross spectral analysis of 15n with foraminiferal 18o global climate sea level index and lithogenic grain size monsoon strength index suggests forcings by changes in hydrography and productivity acting through the extent and intensity of the oxygen minimum zone the data suggest that denitrification may be an internal forcing mechanism for climate change during major glacial interglacial transitions through influence on marine n inventory and atmospheric co2 however compensation or amplification may occur from other sinks sediment denitrification or sources nitrogen fixation

glacial interglacial changes in subantarctic sea surface temperature and δ18o water using foraminiferal mg laboratory culturing experiments with living globigerina bulloides indicate that mg ca is primarily a function of seawater temperature and suggest that mg ca of fossil specimens is an effective paleotemperature proxy using culturing results and a core top neogloboquadrina pachyderma calibration we have estimated glacial interglacial changes in sea surface temperature sst using planktonic mg ca records from core rc11 120 in the subantarctic indian ocean 43 s 80 e and core e11 2 in the subantarctic pacific ocean 56 s 115 w our results suggest that glacial sst was about 4 c cooler in the subantarctic indian ocean and 2 5 c cooler in the subantarctic pacific comparison of sst and planktonic 18o records indicates that changes in sst lead changes in 18o by on average 1 3 kyr the glacial interglacial temperature change indicated by the subantarctic mg ca records suggests that temperature accounts for 40 60 of the foraminiferal 18o change we have used the mg ca based sst estimates and 18o determinations to generate site specific seawater 18o records which suggest that seawater 18o was on average 1 more positive during glacial episodes compared with interglacial episodes

synchroneity of oxygen minimum zone intensity on the oman and pakistan margins at sub milankovitch time scales abstract in this paper we present evidence for sub milankovitch variability in monsoon intensity from the oman and pakistan margins northern arabian sea a new high resolution geochemical record from the oman margin combined with microfossil data shows high frequency variations in sea surface productivity caused by changes in the intensity of summer monsoon induced upwelling the local oxygen minimum zone omz which presently impinges on the oman margin was reconstructed using laminations redox sensitive elements and aragonite preservation comparison with a pakistan margin record shows that omz intensity varied synchronously across the basin omz intensity varies together with summer monsoon strength being weakest during periods of minimum summer monsoon intensity correlating the pattern of summer monsoon variability with that of the winter monsoon inferred from proxy records in the northeastern arabian sea suggests a reversed relationship between summer and winter monsoon strength furthermore the oman and pakistan margin records confirm earlier results suggesting a link between high northern latitude climate as reconstructed from greenland ice cores and monsoonal climate

nitrogen isotopic variations in the gulf of california since the last deglaciation response to global climate change high resolution records of the nitrogen isotopic composition of organic matter 15norg opal content and opal accumulation rates from the central gulf of california reveal large and abrupt variations during deglaciation and gradual holocene changes coincident with climatic changes recorded in the north atlantic homogenous sediments with relatively low 15norg values and low opal content were deposited at the end of the last glacial period during the younger dryas event and during the middle to late holocene in contrast laminated sediments deposited in the two deglacial stages are characterized by very high 15norg values 14 and opal accumulation rates 29 41 mg cm 2 yr 1 abrupt shifts in 15norg were driven by widespread changes in the extent of suboxic subsurface waters supporting denitrification and were amplified in the central gulf record due to variations in upwelling vertical mixing and or the latitudinal position of the intertropical convergence zone

a global marine fixed nitrogen isotopic budget implications for holocene nitrogen cycling 1 a nitrogen stable isotopic model was constructed in order to constrain the holocene marine fixed nitrogen budget the primary sources and sinks considered were riverine and atmospheric sources nitrogen fixation sedimentary and water column denitrification and sediment burial the source budget was found to be insensitive to changes in nitrogen fixation rates and thus could not be used to constrain this term however the isotopic value of fixed nitrogen losses was very sensitive to the amount of sedimentary denitrification if the isotopic value of marine fixed nitrogen has not changed during the holocene as supported by sedimentary records then in order to balance the isotopic value of sinks and sources approximately 280 tg n yr 1 of sedimentary denitrification is required if such a high rate of denitrification has been sustained throughout the holocene it implies that present day estimates of marine nitrogen fixation are grossly underestimated it also implies that the marine nitrogen budget has a residence time of less than 2000 years

age dating and the orbital theory of the ice ages development of a high resolution 0 to 300 000 year chronostratigraphy using the concept of orbital tuning a continuous high resolution deep sea chronostratigraphy has been developed spanning the last 300 000 yr the chronology is developed using a stacked oxygen isotope stratigraphy and four different orbital tuning approaches each of which is based upon a different assumption concerning the response of the orbital signal recorded in the data each approach yields a separate chronology the error measured by the standard deviation about the average of these four results which represents the best chronology has an average magnitude of only 2500 yr this small value indicates that the chronology produced is insensitive to the specific orbital tuning technique used excellent convergence between chronologies developed using each of five different paleoclimatological indicators from a single core is also obtained the resultant chronology is also insensitive to the specific indicator used the error associated with each tuning approach is estimated independently and propagated through to the average result the resulting error estimate is independent of that associated with the degree of convergence and has an average magnitude of 3500 yr in excellent agreement with the 2500 yr estimate transfer of the final chronology to the stacked record leads to an estimated error of 1500 yr thus the final chronology has an average error of 5000 yr