environmental interpretation and a sequence stratigraphic framework for the terminal proterozoic ediacara member within the rawnsley quartzite south australia abstract fossils of the ediacara biota are confined to preservational windows in the ediacara member of the rawnsley quartzite pound subgroup from the flinders ranges south australia the base of the ediacara member is a type 1 sequence boundary incised into the partly lithified chace quartzite member of the rawnsley quartzite the ediacara member and the upper half of the rawnsley quartzite comprise the rawnsley depositional sequence bounded above by the early cambrian uratanna depositional sequence the rawnsley sequence developed over an erosional surface cut into the chace quartzite member with some 250 m of relief southeasterly directed palaeovalleys are filled with a sequence of massive sandstone and laminated siltstone passing up into well bedded sandstone at lowstand local channels were filled by massive sand the highstand systems tract consists of several parasequence sets of laminated siltstone and channelized amalgamated massive sandstone overlain by interbedded siltstone and sandstone grading up into well bedded clean sandstone impressions of soft bodied ediacaran organisms are preserved above the valley fill facies on sandstone partings within upward shoaling delta front environments between storm and fairweather wavebase the ediacara member is in places conformably overlain by up to 500 m of sandstone of the same lithofacies as those underlying the member distinctive microbial mat bound sand laminae described as petee structures are characteristic of the rawnsley quartzite above and below the ediacara member during deposition of the ediacara member colonization of the deeper substrates by microbial mat communities enabled preservation of the ediacara biota the erosional surface at the base of the ediacara member is one of at least four incision events recorded in the terminal proterozoic and early cambrian succession of the adelaide geosyncline the similarity of incision filling lithofacies of the rawnsley and uratanna sequences has in condensed sections led to confusion between the depositional sequences characteristic trace and body fossil assemblages provide the only clear distinction between depositional cycles spanning the proterozoic cambrian boundary

glacially influenced deep marine sedimentation of the late precambrian gaskiers formation newfoundland canada the late proterozoic conception group exposed on the avalon peninsula in newfoundland canada is a 4 km thick turbidite succession containing a conformable 300 m thick sequence of diamictites the gaskiers formation near the base massive and crudely stratified diamictites form beds up to 25 m thick which have a tabular geometry with slightly erosive basal contacts and are interbedded with mudstones and fine grained thin bedded turbidites these diamictites are interpreted as submarine debris flow deposits disrupted diamictites form strongly deformed units that contain large complexly folded rafts of mudstone and turbidite facies these diamictite units are interpreted as submarine slumps diamictites contain glacially striated and faceted clasts clasts and matrix are predominantly of volcanic provenance one outcrop shows interbedded volcanic agglomerate and diamictite and volcanic bombs can also be identified the interbedding of diamictites with turbidites and the stratigraphic context provided by the thick sequences of turbidites below mall bay formation and above drook formation indicate a deep marine slope setting of diamictite deposition diamictite facies record remobilization and downslope transfer of large volumes of unstable volcanic and glacial debris initially deposited in a shallower water marginal marine zone the regional tectonic framework suggests the conception group accumulated in a deep southward opening ensialic rift basin with active but waning volcanic centres to the north the gaskiers formation may be representative of other late precambrian glacially influenced diamictite sequences that were deposited around the north atlantic region and in europe these deep marine diamictite sequences characterized by debris flows turbidites and slump deposits can be contrasted with more extensive shallow marine shelf diamictite sequences found in association with dolomites and tidally influenced shallow water facies in other basinal settings

stratigraphy sedimentology and isotopic geochemistry of australian neoproterozoic postglacial cap dolostones deglaciation delta 13 c excursions and carbonate precipitation abstract thin d13c excursions in the geologic record they are interpreted to record a brief postglacial anomaly in ocean chemistry in australia the marinoan varanger equivalent 600 ma cap dolostone units exhibit many of the characteristics displayed by such deposits elsewhere around the globe including fine grained dolomitic mineralogy lateral persistenc at basinal scales thin laminae graded beds intervals with abundant marine cements crystal fans and a distinctive negative d13c isotopic signature of up to 5 pdb on the basis of these features the australian examples are interpreted here to be deeper water deposits below storm wave base resulting from an anomalous flux of inorganic carbonate to the sea floor during postglacial transgression detailed isotopic analysis of australian cap dolostones indicates d13c values ranging from 1 to 5 and gen rally becoming more depleted in 13c upsection trace element data indicate some diagenetic stabilization but textural evidence and the presence of similar profiles in different basins argue against a pervasive recrystallization event the range in d13c values between sections as well as more negative 13c values appear to correlate with greater paleobathymetry within basins this implies either 1 only partial preservation of the complete oceanic variation of d13c or 2 precipitation of this peculiar facies owes its genesis to basinal specific oceanographic processes such as proximi y of a given section to a postglacial upwelling zone in the later case d13c values would not represent whole ocean values stratigraphic constraints and paleoenvironmental interpretations suggest that much of this excursion lies within the geologically brief period of postglacial transgression this implies that the cause s of d13c variation likely operated on time scales significantly less than the residence time of carbon in the oceans 105 yr the continent wide and perhaps global nature of cap dolostones indicates that large volumes of carbonate were precipitated during the postglacial transgressive period such large scale carbonate precipitation over the hypothesized short time interval of postglacial transgression must have caused or have been the product of profound changes in the carbon cycle and global climate at tha time similar evidence for transgression and increased carbonate deposition in the holocene are attributed to the changing basin shape and ph of the oceans the coral reef hypothesis of berger 1982 cap dolostones may record a proterozoic equivalent of this process with the substitution of abiotic carbonate precipitation for skeletal precipitation by reef organisms

extinction of cloudina and namacalathus at the precambrian cambrian boundary in oman biostratigraphic carbon isotope and u pb zircon geochronological data from the ara group of oman indicate an abrupt last appearance of cloudina and namacalathus coincident with a large magnitude but short lived negative excursion in the carbon isotope composition of seawater that is globally coincident with the precambrian cambrian boundary u pb zircon age data from an intercalated ash bed directly define this negative excursion to be at 542 0 0 3 ma consistent with previous age constraints from siberia and namibia combined with the global biostratigraphic record these new data strengthen hypotheses invoking mass extinction within terminal proterozoic ecosystems at or near the precambrian cambrian boundary

integrated ediacaran chronostratigraphy wernecke mountains northwestern canada abstract terminal neoproterozoic ediacaran ca 600 543 ma strata of the upper part of the windermere supergroup are well exposed in the mackenzie mountains and the wernecke mountains of northwestern canada windermere strata in the mackenzie mountains contain an exceptional ediacaran biostratigraphic and isotopic c and sr record while the sequence stratigraphic record is subtle throughout this predominantly deep water succession coeval strata in the wernecke mountains can be correlated with the succession in the mackenzie mountains on a formational level in contrast to the deep water setting of the mackenzies succession the werneckes succession preserves a predominantly shallow water succession amenable to detailed sequence stratigraphy integrated lithostratigraphy chemostratigraphy biostratigraphy and sedimentology partitions the wernecke mountains succession into five depositional sequences and constrains correlation with strata in the mackenzie mountains the siliciclastic and carbonate sediments deposited along the margin of the proto pacific ocean record accumulation in continental slope neritic and terrestrial paleoenvironments distinctive temporal chemostratigraphic and biostratigraphic attributes allow these strata to be correlated with other ediacaran successions worldwide integrating sequence stratigraphy with these attributes is a robust yet under utilized correlation tool and is a step toward erecting a more detailed working neoproterozoic chronostratigraphy

magmatism along the southeast margin of the yangtze block precambrian collision of the yangtze and cathysia blocks of china the time and the environment of formation of igneous rocks along the southern margin of the yangtze continental block in southern anhui province and northeastern jiangxi province china are discussed sm nd dating for samples from two ophiolite suites give ages of about 1 ga late proterozoic granodiorites in the study area have ages of about 0 9 ga and have normal intrusive relations against banxi group metamorphic country rocks trace element abundances and initial nd isotope ratios for ophiolite and proterozoic granodiorites are consistent with formation in an island arc environment in contrast sr and nd isotopes for mesozoic granitoids of the region suggest that they are products of remelting of crustal sources similar to the basement of the yangtze block these relations do not support a recently proposed mesozoic overthrust tectonic model for southeast china but rather favor a late precambrian collision history for the yangtze and cathysia blocks

large scale slope instability at the southern margin of the ediacaran yangtze platform hunan province central china thirteen stratigraphical sections from the doushantuo formation hunan province central china indicate large scale mass wasting of the yangtze platform margin between the late neoproterozoic glaciation and the earliest cambrian numerous sedimentary discontinuities due to regional slides olistostromes and slumps have modified the stratigraphy between the shallow water carbonate platform margin and the siliciclastic slope slide blocks are predominantly gently deformed and are largely composed of shallow water dolomitized limestones slide sheets may reach a regional extent of up to 5000 km 2 and are embedded in anoxic shales at an unknown water depth

reply to the comment on astronomical constraints on the duration of the early jurassic pliensbachian stage and global climatic fluctuations earth planet sci lett 455 2016 149 165

sequestration of 12c in the deep ocean during the early wenlock silurian positive carbon isotope excursion abstract marine carbonates from three biostratigraphically well dated silurian sections from the mid continent of north america were analyzed for carbon isotopic 13 c carb study the early wenlock positive carbon isotope excursion ireviken excursion is recorded in three sections from tennessee iowa and ohio with values of 4 5 this global shift in the carbon isotopic ratio of marine waters began during a protracted extinction event ireviken event that spanned the llandovery wenlock boundary although several oceanographic models have been developed to account for the coincident changes in lithology biology and carbon isotope stratigraphy during this interval of the silurian their proposed causal connections among glaciation oceanography primary productivity and the global carbon cycle remain a matter of debate this investigation provides carbon isotopic and lithologic evidence that the ireviken excursion occurred during a time of relatively oligotrophic conditions a third order transgressive regressive cycle and increased carbonate production throughout the mid continent of north america the ireviken excursion is recorded in relatively pure carbonate sequences and is immediately preceded by a significant unconformity in each of the measured sections it is proposed that the ireviken excursion was the product of sequestration and burial of 12 c in deep water as a result of altered deep ocean circulation

50 myr recovery from the largest negative δ13c excursion in the ediacaran ocean sedimentary rocks deposited during the ediacaran period 630 542 ma contain carbonates whose carbon isotopic ratios show a marked negative excursion consisting of a precipitous drop from 5 to 12 followed by a sub linear recovery to positive 13c values isotopic ages u pb and thermal subsidence modelling are combined to constrain the excursion in time and indicate an onset at 600 ma and duration of recovery of approximately 50 myr the excursion is widely recognized in oman and has potential correlatives in ediacaran strata elsewhere and may thus represent a characteristic feature of the ediacaran period the amplitude of this carbon isotope excursion far exceeds those of other neoproterozoic anomalies the isotopic trend of negative excursion and long term recovery spanned at least one short lived glacial episode at 580 ma but appears unrelated to glaciation which indicates that negative anomalies in the neoproterozoic marine carbon isotope record are not directly or uniquely linked to ice ages

neoproterozoic arc related mafic intrusions along the northern margin of south china implications for the accretion of rodinia abstract south china has been considered as part of the rodinian supercontinent during neoproterozoic time although its paleogeographic position within this supercontinent is still a matter of debate the wangjiangshan and bijigou complexes along the northern margin of south china are among the largest mafic intrusions in china new shrimp zircon u pb results indicate that these two intrusions have crystallization ages of 820 ma and 780 ma respectively enrichment of large ion lithophile and light rare earth elements and depletion of high field strength elements in these intrusions suggest derivation from an active arc along a continental margin this interpretation of these intrusions as part of a continental arc assemblage is in contrast with the previous view that they were products of a neoproterozoic mantle plume that initiated the breakup of rodinia the presence of a neoproterozoic magmatic arc suggests that rodinian oceanic lithosphere was subducted beneath the present northern margin of south

the problems and potential of using animal fossils and trace fossils in terminal proterozoic biostratigraphy abstract despite the discovery of soft bodied megascopic fossils of late neoproterozoic age at numerous localities world wide there has been slow acceptance of their potential for intercontinental correlation the stratigraphic thickness of sediments separating individual occurrences of such fossils from the base of the cambrian is very varied basic questions have also been posed as to the classification of the organisms represented and hence their likely time significance recent geochronological studies support notions of a narrow time distribution well studied neoproterozoic sequences in eurasia eastern and western north america and southern australia show strikingly similar patterns of increase in the numbers and diversity of trace fossils and soft bodied megascopic remains up section though strata immediately preceding the cambrian are relatively barren other than for a sparse palynoflora and compressions of primitive plants trace fossils from australian sections relating to an early part of the ediacaran apparently overlap a time of abundance of large process bearing acritarchs and big leiosphaerids this overlap of early animal traces and distinctive acritarchs may prove to be of significant biostratigraphic importance rare discoveries of forms resembling rangea gurich in the flinders ranges of south australia precede the classical ediacara assemblage and may provide a possible correlation with occurrences of this genus in namibia the distinctive remains and trace fossils at this level constituting the rangeid hiemalora assemblage zone resemble a biota from the podolia region of the ukraine and show a similarity to finds in parts of the windermere supergroup of the northwest territories canada similarly the offshore frondose assemblage of newfoundland is comparable with the biota of charnwood forest england the type ediacara assemblage of the flinders ranges characterizing the dickinsonia costata assemblage zone is a climax biota with diverse taxa and large individual species as well as some 20 ichnogenera it closely correlates with a late redkinian or early kotlinian assemblage in the upper part of the section on the zimny gory coast of the white sea northern russia the trace fossils of these levels show that significant diversification began before the cambrian

the neoproterozoic of southwestern africa with emphasis on platform stratigraphy and paleontology abstract neoproterozoic sediments in southwestern africa occur in the pan african kaoko khomas gariep vanrhynsdorp and saldania belts they were deposited in response to rifting break up of a supercontinent formed at 1000 ma and subduction and collisions of the congo kalahari rio de la plata and malvinas plates these collisions led to the formation of a neoproterozoic cambrian supercontinent this paper deals with the geology of the platform successions of the kaoko khomas gariep and vanrhynsdorp belts deposition of the sediments occurring in these belts commenced 900 to 1000 ma ago and probably ended between 500 and 520 ma the sediments record wilson cycles that ended with the deposition of red beds palaeontological and carbon isotope studies on the damara sequence gariep complex nama group and vanrhynsdorp group make intra and inter basinal correlations possible prior to deposition of the nama group two or perhaps three glaciations took place over an extensive area in southwestern africa these being the kaigas chuos 725 700 ma numees 650 600 ma or 610 590 ma and possibly the varianto 745 725 ma glaciations the numees tillite is overlain by a stratigraphic unit containing pinkish dolomite during deposition of the nama group the minor vingerbreek 600 545 ma glaciation or cold water period occurred the major kaigas chuos and numees and minor vingerbreek glaciations correspond with low 13c isotope ratios and appear to have taken place at relatively low palaeolatitudes the riphean sediments were deposited predominantly during rifting and break up of a supercontinent during the late vendian to early cambrian deposition of the nama group in southern namibia and the penecontemporaneous vanrhynsdorp group in the republic of south africa took place in the nama foreland basin detrital micas indicate that deposition of the nama group took place between 635 and 530 ma the nama foreland basin which was connected to a major ocean to the south formed as a result of collisions between the congo kalahari and rio de la plata plates with the exception of the nama group little is known about the palaeontology of the neoproterozoic in southwestern africa the lower nama group is latest proterozoic in age it contains an ediacaran fauna a depauperate assemblage of organic walled microfossils and a relatively well diversified ichnofauna with brooksella diplocraterion and nereites which are atypical of vendian strata many trace fossils are exceptionally small the occurrence of the shelly fossil cloudina and probable calcified metaphytes in the lower nama group suggest that skeletalization in animals and metaphytes occurred almost simultaneously towards the end of the proterozoic the upper nama group is early cambrian in age as indicated by the occurrence of the trace fossil phycodes pedum the upper nama group dominated by red beds contains a low diversity ichnofauna with trace fossils of normal size bio and chemostratigraphy combined with sequence stratigraphy will probably establish how the prominent unconformities which occur in the neoproterozoic of southwestern africa are related to the periods of formation of the wonoka canyons in south australia

isotope stratigraphy of the ediacarian neoproterozoic iii of the adelaide rift complex australia and the overprint of water column stratification abstract this study establishes a high resolution 13c chemostratigraphic framework for the type ediacarian terminal proterozoic section in the adelaide rift complex a framework that contributes to the emerging global chronostratigraphic synthesis of a period that saw momentous changes in the earth s surface environment only 15 m of the 3 5 km thick type section consists of shallow water carbonates of the kind that have formed the basis of most previous studies of neoproterozoic chemostratigraphy however the organic 13corg record reveals a surprising richness of information and shows excellent utility in correlation between sections in the adelaide rift complex lateral variations in 13corg profiles correspond to expected diachronous patterns of basin fill with the addition of 87sr 86sr data correlation can also be made to the officer and amadeus basins consistent with known lithostratigraphic and sequence stratigraphic constraints sublittoral micritic carbonates of the upper nuccaleena formation cap dolostone and lower and middle wonoka formation show strong basinwide 13c depletion 13ccarb 3 to 10 despite compelling evidence for preservation of depositional 13ccarb such as good textural preservation evidence for sea floor lithification and in the wonoka formation pristine 87sr 86sr and low mn sr associated with the depleted carbonates are rare subaqueous evaporite relatively heavy 13corg and anomalously 13c depleted organic carbon of benthic microbial mat origin and a common cause salinity stratification of the water column is postulated the indicated palaeogeographic setting an evaporative mediterranean like basin tenuously connected to the world ocean is entirely consistent with previous suggestions of one or more messinian type desiccation events to explain very deep 1 km incised valleys or canyons in the adelaide rift complex and officer basin at horizons within the wonoka formation and correlates positive excursions in 13corg during basin stratification may in part be due to 12c depletion of surface waters by photosynthetic carbon fixation despite the proposed semi isolation of australian ediacarian basins from the world ocean major 13c excursions which can to some extent be differentiated by the monotonic rise in ediacarian marine 87sr 86sr appear to be correlatable to the upper windermere supergroup northwest canada

magmatic complexity on early mars as seen through a combination of orbital in situ and meteorite data abstract until recently mars was considered a basalt covered world but this vision is evolving thanks to new orbital in situ and meteorite observations in particular of rocks of the ancient noachian period in this contribution we summarise newly recognised compositional and mineralogical differences between older and more recent rocks and explore the geodynamic implications of these new findings for example the msl rover has discovered abundant felsic rocks close to the landing site coming from the wall of gale crater ranging from alkali basalt to trachyte in addition the recently discovered martian regolith breccia nwa 7034 and paired samples contain many coarse grained noritic monzonitic clasts demonstrably noachian in age and even some clasts that plot in the mugearite field olivine is also conspicuously lacking in these ancient samples in contrast to later hesperian rocks the alkali suite requires low degree melting of the martian mantle at low pressure whereas the later hesperian magmatism would appear to be produced by higher mantle temperatures various scenarios are proposed to explain these observations including different styles of magmatic activity i e passive upwelling vs hotspots a second petrological suite of increasing interest involves quartzo feldspathic materials that were first inferred from orbit in local patches in the southern highlands and in the lower units of valles marineris however identification of felsic rocks from orbit is limited by the low detectability of feldspar in the near infrared on the other hand the msl rover has described the texture mineralogy and composition of felsic rocks in gale crater that are granodiorite like samples akin to terrestrial ttg tonalite trondhjemite granodiorite suites these observations and the low average density of the highlands crust suggest the early formation of continental crust on mars although the details of the geodynamic scenario and the importance of volatiles in their generation are aspects that require further work

neoproterozoic rocks of the newfoundland avalon zone abstract a ca 15 km thick succession of volcanic and sedimentary neoproterozoic rocks are exposed within the avalon terrane of newfoundland petrologic and geochemical study of volcanic suites and sedimentological analyses indicate that most deposition took place in ensialic rift basins and associated continental arc settings on the avalon peninsula over 7500 m of volcaniclastic strata include initial submarine fan and slope deposits which pass upward into a prograded wedge of deltaic and fluvial deposits this flysch to molasse transition and associated folding and volcanism mark the neoproterozoic avalonian orogeny post orogenic erosion was followed by deposition of extensive cambrian siliciclastic deposits recent u pb zircon dating of many of the neoproterozoic volcanic units provides some constraints on both intra avalon and global correlations more precise dates are needed to improve correlation and better constrain the geologic history of this region glaciogenic diamictites of the gaskiers formation exposed on the avalon peninsula may eventually also prove useful for global correlation biostratigraphic study of the latest neoproterozoic lower cambrian deposits has resulted in ratification of the precambrian cambrian boundary stratotype in an exposure on the burin peninsula older neoproterozoic rocks contain well preserved ediacara type fossils and a low diversity suite of microfossils including acritarchs and carbonaceous filaments the latter of which have little biostratigraphic utility aside from work on the precambrian cambrian boundary section little or no chemostratigraphic magnetostratigraphic or sequence stratigraphic work has been completed on the neoproterozoic of the newfoundland avalon terrane

stratified oceans and oxygenation of the late precambrian environment a post glacial geochemical record from the neoproterozoic of w mongolia the late neoproterozoic 750 545 ma was a time of revolutionary environmental change recurrent glaciation and tectonic upheaval which culminated in the evolution of metazoans and animal biomineralization geochemical data are presented for a post glacial 700 ma limestone succession from w mongolia 87 sr 86 sr is used to constrain the timing of early diagenetic exchange stratigraphic trends to high d 13 c carb and d 13 c org mirror sea level fluctuations which we argue is consistent with the hypothesis that late precambrian ocean chemistry was controlled by vertical stratification repeated establishment of stratification 700 545 ma would have led to greater oxygen availability in the surface environment a causal link between this oxygenation and the further evolution of animals is proposed

integrated correlation of the vendian to cambrian arroyo del soldado and corumba groups uruguay and brazil palaeogeographic palaeoclimatic and palaeobiologic implications abstract the corumba group of sw brazil and the arroyo del soldado group asg of uruguay are correlated on the basis of litho bio and chemostratigraphy both units represent marine sedimentation with alternating siliciclastics and carbonates developed on a stable continental shelf in the corumba basin sedimentation began in the varangerian represented by the glaciomarine puga formation a series of sea level fluctuations coupled with climatic changes are recorded up section while uppermost deposits of the asg are of lowermost cambrian age sedimentation ceased in the latest vendian in the corumba basin an assemblage of six species of organic walled microfossils dominated by bavlinella faveolata and soldadophycus bossii three species of vendotaenids and two species of skeletal fossils cloudina and titanotheca is described from the corumba group the vendotaenid eoholynia corumbensis sp nov is described from siltstones of the guaicurus formation an important diversity of skeletal fossils in the corumba arroyo del soldado and nama groups points to favourable vendian palaeoclimatic conditions in sw gondwana preliminary carbon isotopic data show a series of alternating positive and negative excursions corroborating the upper vendian age indicated by fossils for both units previously reported strontium isotopic data are also consistent with this age it is postulated that the corumba and asgs were deposited onto the same shelf which opened to the east the rio de la plata superterrane craton extends farther to the north than previously expected or it was already amalgamated with the amazonian craton by vendian times collision of the platform with the parana block caused closure of the basin during the cambrian early ordovician finally models of neoproterozoic glaciations based on enhanced bioproductivity driven by high nutrient availability are discussed

integrated chronostratigraphy of the vendian system of siberia implications for a global stratigraphy integrated 13 c chemostratigraphy and sequence stratigraphy are developed for a succession of vendian strata nokhtuisk section on the southern margin of the siberian platform the carbonates exhibit secular variations in 13 c and at least three major depositional sequences that encompass the last c 20 million years

integrated ediacaran sinian chronostratigraphy of south china abstract the ediacaran period was a critical time in the history of life and earth understanding the complex interactions between geological and biological events during this interval requires high resolution chronostratigraphy thanks to its uniquely favorable palaeogeographic setting south china is an ideal region for constructing a framework for global chronostratigraphic correlation of ediacaran strata here continuous ediacaran successions contain both siliciclastic and carbonate rocks that range from shallow to deep marine and contain rich fossil assemblages showing a variety of preservation styles as part of the present study 62 reference sections distributed throughout the yangtze platform were investigated analyses of the sedimentary facies and sequence stratigraphy of more than 40 sections revealed four major sequences in the shallow marine facies three major sequence boundaries occur respectively in the middle and upper parts of the doushantuo formation and in the middle part of the dengying formation subdivision and correlation of the ediacaran successions of the yangtze platform based on sequence stratigraphy is congruent with the carbon isotope chemostratigraphy of 12 reference sections 1075 samples the sequence boundary sb2 in the middle part of the doushantuo formation is suggested here as the lower xiadongian upper yangtzean series boundary of the ediacaran which coincides with several globally recognizable events namely 1 the end of the neoproterozoic glaciations 2 the first appearance of animals 3 the sudden increase in the diversity of acanthomorphic acritarchs and 4 a negative 13 c excursion the ediacaran system of south china may be subdivided into five stages furthermore the criteria for defining these stages may be applicable throughout the world also the composite carbon isotope profile of the ediacaran of south china can be used as a global reference for chronostratigraphic subdivision and correlation in addition to the globally recognizable negative 13 c excursion in the cap carbonate at the base of the ediacaran the negative 13 c excursion in the uppermost doushantuo wonoka shuram interval represents another globally correlatable major excursion the positive 13 c excursion immediately following the uppermost doushantuo excursion and ending at 548 ma is also useful for global correlation current ediacaran chronostratigraphy and global correlations indicate that the upper doushantuo wonoka shuram negative 13 c excursion ranges from ca 560 ma to 551 ma and therefore coincides with the evolutionary renovation of life feedback between evolutionary innovation and geochemical cycling was the key mechanism for this unique and most strongly negative 13 c excursion in earth history our chronostratigraphic correlations also imply that the earliest known metazoan biotas namely the weng an and characteristic ediacaran biotas do not constitute two temporally separate evolutionary lineages as proposed previously but represent two parallel evolutionary pathways preceding the cambrian explosion of animal life

eumetazoan fossils in terminal proterozoic phosphorites phosphatic sedimentary rocks preserve a record of early animal life different from and complementary to that provided by ediacaran fossils in terminal proterozoic sandstones and shales phosphorites of the doushantuo formation south china contain eggs egg cases and stereoblastulae that document animals of unspecified phylogenetic position small fossils containing putative spicules may specifically record the presence of sponges microfossils recently interpreted as the preserved gastrulae of cnidarian and bilaterian metazoans can alternatively be interpreted as conventional algal cysts and or egg cases modified by diagenetic processes known to have had a pervasive influence on doushantuo phosphorites regardless of this interpretation evidence for doushantuo eumetazoans is provided by millimeter scale tubes that display tabulation and apical budding characteristic of some cnidaria especially the extinct tabulates like some ediacaran remains these small benthic colonial fossils may represent stem group eumetazoans or stem group cnidarians that lived in the late proterozoic ocean

latest proterozoic stratigraphy and earth history the end of the proterozoic eon was a time of pronounced biological biogeochemical climatic and tectonic change new bio and chemostratigraphic data provide an improved framework for stratigraphic correlation making possible a deeper understanding of latest proterozoic earth history and providing tools for a chronostratigraphic division of late proterozoic time

late neoproterozoic cap carbonates mackenzie mountains northwestern canada precipitation and global glacial meltdown the 3 27 m thick cap carbonate overlying marinoan ice brook formation glacigene sediments and keele formation carbonate and terrigenous clastic rocks consists of two distinctive stratigraphic units a lower splintery buff weathering microcrystalline dolostone of extensive lateral uniformity comprises mm laminated peloidal sediment with local low angle hummocky like cross stratification micro ridges and synsedimentary tepees all elongated per pendicular to depositional strike this dolostone is unconformably overlain by an upper limestone that exhibits pro nounced facies variation from inboard peloidal lime grainstone and mudstone to shelf edge cementstone to outboard lime wackestone and mudstone calcite cementstones range from isolated crystal fans in laminated limestone to huge decimetre scale crystal arrays to hemispherical and elongate crystal stromatolites wholly composed of acicular crystals that form decametre scale reeflike structures crystal stromatolites are precipitates and replaced microbiolites that con structed biostromes and bioherms like those on many flat topped reef rimmed platforms the calcite crystals have all the physical and chemical attributes of neomorphosed aragonite this aragonite extensively replaced sediment and microbiolite just below the sea floor and grew upward into the overlying water column such interpreted massive synsedimentary replacement is rare in geological history and attests to the highly saturated state of the immediate postglacial ocean all sediment is interpreted to have been caco3 originally low and constant 18 o values reflect diagenetic modification of these carbonates although chemical attributes such as sr and c isotopes in some lithologies are near pristine lower dolostones virtually identical to most other coeval marinoan caps worldwide were part of a global precipitation event of remarkable similarity upper limestones are a more local phenomenon deposited during sea level rise in an aragonitic sea returning to equilibrium after global glaciation low 87 sr 86 sr ratios and varying 13 c values with carbonate sedimentary facies indicate that both units must have formed relatively rapidly prior to significant flu vioglacial runoff or that the influence of this runoff on the chemistry of seawater along continental shelves was mini mal the cap carbonate is thus interpreted to have formed in two steps 1 during initial marine ice melting accompanied by oceanic overturn and upwelling preceding continental margin rebound and 2 during initial stages of sea level rise accompanying continental deglaciation while confirming brief but extensive carbonate precipitation from an ocean highly perturbed by global glaciation the rocks also suggest that this event did not permanently affect either late neoproterozoic ocean chemistry or the contained marine biosphere 1262

enigmatic nature of thick sedimentary carbonates depleted in 13c beyond the canonical mantle value the challenges to our understanding of the terrestrial carbon cycle carbon and oxygen isotope measurements of 66 samples from the 60 m thick variegated marble in the upper allochthon of the norwegian caledonides have a mean 13ccarb of 8 4 0 9 v pdb and a mean 18o of 20 2 2 2 v smow the variegated marble is overlain by 150 m thick pale grey marble characterised by mean 13ccarb of 6 5 0 8 n 25 and underlain by dark grey marbles with a mean 13ccarb of 4 8 1 1 n 61 this tripartite unit of an poorly constrained age but between neoproterozoic and early silurian discontinuously developed over a distance of 500 km is likely to represent one of the largest isotopically anomalous sedimentary carbonate formations yet reported the marbles depleted in 13c beyond the canonical mantle value of 6 show no obvious evidence of post sedimentary repartitioning of carbon isotopes several other carbonate formations deposited within approximately 680 540 ma time interval chenchinskaya nikolskaya and torginskay in siberia ingta in nw canada shuram in central oman trezona and wonoka in south australia are several hundred meters thick developed over a distance of hundreds of kilometres and all show a similar depletion in 13c beyond the mantle value for reasons that are not well understood the existence of these carbonates represents a challenging problem for our current understanding of global carbon geodynamics changes in the ratio of reduced oxidised carbon sequestered in sediments a methane hydrate release or zero biological productivity if applied separately cannot explain carbon isotope characteristics and formation of these carbonates we tentatively propose that several factors associated with unusual geodynamic and palaeoclimatic scenarios developed between 600 and 540 ma might have been involved in the extreme lowering of the isotopic composition of carbon entering the global earth surface environment this period was marked by the retreat of neoproterozoic glaciers and break up of the supercontinent rodinia the late postglacial warming might have induced a massive release of methane hydrates extremely enriched in 12c the death of rodinia was marked by unusually rapid approximately 20 cm year motion of newly formed continental plates suggesting vigorous mantle convection and an enhanced restructuring of the lowest compartments of the earth this could provide a flux of 12c rich material from the isotopically light asthenosphere mantle source 13c 25 to 15 to the surface considerable reconfiguration of the continental and sea areas of the earth might have triggered enhanced weathering of previously deposited 12c rich organic matter in presenting this working hypothesis we also question the completeness of our understanding of the terrestrial carbon cycle and the popular assumption that the isotopic composition of carbon entering the global earth surface environment was always around 6

carbon isotope geochemistry and palaeontology of neoproterozoic to early cambrian siliciclastic successions in the east european platform poland a well preserved stratigraphic record of the organic carbon isotopic composition across the precambrian cambrian transition has been obtained from a sequence of entirely detrital rocks underlying the lublin slope east european platform poland the observed 13 c pattern for organic carbon is comparable to isotope data determined for coeval carbonate platform sequences elsewhere these results underline the truly global nature of these secular variations within the carbon cycle during the terminal proterozoic and early cambrian largely independent of host lithology and facies the direct combination of micropalaeontological and geochemical results from sedimentary organic matter allows a detailed interpretation of the isotope record as probably caused by secular changes in the net balance of burial and erosion rates of repositories of organic carbon furthermore these variations appear to be directly correlatable with changes in the diversity and abundance of the biota and radiation extinction events

palaeoenvironment and carbon isotope stratigraphy of upper proterozoic carbonates of the yangtze platform the 13c values for phanerozoic marine carbonates display secular trends mainly in the range 1 to 2 1 these have been interpreted as primary features reflecting changes in the carbon isotope composition of dissolved bicarbonate in seawater brought about largely by variations in the proportions of carbon being sequestered in the oxidized and reduced carbon reservoirs1 2 carbon isotope trends are not as well established for the precambrian but there are indications that upper proterozoic sequences contain carbonates with unusually high 13c values3 9 here we present the results of the first carbon isotopic study of the upper proterozoic carbonate strata from the type locality of the sinian system in the yangtze gorges sections near yichang south china and discuss their implications for accumulation of organic matter we also compare the results for these chinese strata with 13c trends in other upper proterozoic cambrian sequences and assess the extent to which such isotopic data can be used to make stratigraphic correlations between widely spaced sequences

sequence stratigraphy and the interpretation of neoproterozoic earth history abstract the application of sequence stratigraphy to neoproterozoic successions is important for improving the resolution of time correlation within individual sedimentary basins and potentially at a global scale the methodology is illustrated in this paper by reference to two contrasting examples from the flinders ranges adelaide geosyncline of south australia where the younger part of the neoproterozoic to earliest cambrian succession 770 ma to 540 ma has been divided into thirteen unconformity bounded depositional sequences one of the most prominent sequence boundaries at or near the base of the wonoka formation is characterized by a series of buried canyons as much as 1 km deep high resolution sequence stratigraphic studies at umberatana syncline continue to support the view that the canyons were cut subaerially and filled by fluvial and shallow water sediments in contrast to the wonoka canyons sequence boundaries interpreted at the base of the nuccaleena formation seacliff sandstone and near the top of the abc range quartzite are relatively subtle with only limited evidence for erosion and valley incision four sequence boundaries at the level of the sturtian and marinoan varanger glacial deposits and in the vicinity of the precambrian cambrian boundary are thought to correlate with surfaces in the amadeus basin of central australia other prominent sequence boundaries including the wonoka canyons and surfaces within the upper part of the wonoka formation and at the base of the ediacara member of the rawnsley quartzite correspond with a relatively condensed section in the amadeus basin and their lateral persistence beyond the adelaide geosyncline is therefore difficult to evaluate given the lack of precision in biostratigraphy and isotope geochemistry in neoproterozoic rocks and in a marked departure from phanerozoic practice we recommend placement of a terminal proterozoic gssp at a sequence boundary a prime candidate in australia is the sequence boundary at the base of the nuccaleena formation seacliff sandstone immediately above the marinoan glacial rocks in the adelaide geosyncline and its likely correlative at or near the base of the gaylad sandstone in the amadeus basin

chemical composition of seawater in neoproterozoic results of fluid inclusion study of halite from salt range pakistan and amadeus basin australia abstract data on chemical composition of brines in primary inclusions of marine halites and on mineralogy of marine evaporites and carbonates lead to the conclusion that during the phanerozoic two long term cycles of chemical composition of seawater existed during each of those cycles seawater dominantly a na k mg ca cl ca rich type changed to a na k mg cl so 4 so 4 rich type recrystallised halite from the uppermost neoproterozoic salt range formation ca 545 ma in pakistan contains solitary inclusions indicating so 4 rich brines this supports the concept derived from the study on primary fluid inclusions from the neoproterozoic ara formation of oman so 4 rich seawater existed during latest neoproterozoic time ca 545 ma in contrast samples of recrystallised halite from the bitter springs formation 840 830 ma in australia contain inclusion brines that are entirely ca rich indicating that basin brines and seawater were ca rich during deposition of central australian evaporites these combined data supported by the timing of aragonite and calcite seas suggest that during the proterozoic significant oscillations of the chemical composition of marine brines and seawater occurred which are similar to those known to exist during the phanerozoic it is suggested that ca rich seawater dominated for a substantial period of time more than 200 ma at 650 ma this was replaced by so 4 rich seawater finally returning to ca rich seawater at 530 ma

how earth s atmosphere evolved to an oxic state a status report the evolution of the earth s atmosphere is essentially the story of atmospheric oxygen virtually every realm of the earth sciences biology geology geochemistry oceanography and atmospheric science is needed to piece together an understanding of the history of oxygen over the past decade new data from these fields has shown that there were two significant increases in atmospheric o2 levels at around 2 4 2 3 and 0 8 0 6 billion years ago respectively throughout earth history oceanic sulfate concentrations appear to have increased in accord with greater o2 levels while levels of methane a strong greenhouse gas may have inversely mirrored o2 both oxic transitions occurred in eras characterized by bsnowball earthq events and significant disturbances in the carbon cycle perhaps associated with increases in o2 and losses of methane to understand what controlled the oxygenation of the atmosphere it is necessary to determine how o2 is consumed on geologic time scales through reaction with reductants released from the earth s crust and mantle there was apparently a long delay between the appearance of oxygenic photosynthesis and oxygenation of the atmosphere and a plausible explanation is that excess reductants scavenged photosynthetic o2 from the early atmosphere however a quantitative understanding of how and why o2 became abundant on our reducing planet is still lacking thus the study of the early atmosphere remains a frontier field with much to be discovered d 2005 elsevier b v all rights reserved

integrated stratigraphy of the upper neoproterozoic succession in yunnan province of south china re evaluation of global correlation and carbon cycle abstract this study provides a chemostratigraphic and sequence stratigraphic framework of a relatively unfossiliferous sub cambrian marine sedimentary succession in yunnan province of south china our results allow its global stratigraphic correlation and provide an improved understanding of marine carbon cycle during the late neoproterozoic the succession has a basal glacial diamictite nantuo formation and comprises two large scale depositional cycles towards the precambrian cambrian pc c boundary each of which changes from siliciclastic to carbonate sediments with environments ranging from shallow subtidal to evaporitic supratidal in the absence of biostratigraphic control attribution of the tillite has remained equivocal between the 710 ma sturtian and 635 ma marinoan glaciations a compilation of known paleomagnetic and other geochronologic constraints suggests that the nantuo glaciation in south china was at least diachronous in which the nantuo tillite in yunnan belongs to the older glaciation stratigraphic patterns of the diagenetically screened 13c variation and depositional sequences during the carbonate dominated interval show a striking similarity with those of the upper cryogenian and entire terminal proterozoic carbonates at widely separated other localities rather than the terminal proterozoic alone supporting the view that deposition of the nantuo tillite in yunnan reflects the sturtian rather than marinoan glaciation further considerations of the 13c results provide three important implications for the late neoproterozoic marine carbon cycle first comparison of different 13c profiles suggests considerable variability in the absolute values of carbonate on both intra and inter basinal scales which differs profoundly from their relative homogeneity in marine phanerozoic counterparts and may therefore reflect lateral isotopic heterogeneity in the oceanic carbonate reservoir during the late neoproterozoic second an empirical correlation between the 13c and relative sea level changes was applied to evaluate hypothesized explanations for 13c temporal variation in surface sea yielding short term inverse and long term positive relationships the short term trend marks periods of the negative 13c excursions and is compatible to most of the existing arguments for the 13c events on the other hand mechanisms causing the long term trend remain enigmatic in the absence of comparable data from other localities our observation however suggests that at least two different mechanisms operated marine carbon cycle during the late neoproterozoic third the negative 13c anomaly characterizing the period following the marinoan glaciation worldwide was not coincident between kerogen and carbonate but occurs as a lagged drop in yunnan where a 7 depletion in kerogen preceded an 3 depletion in carbonate their lagged trends likely reflect different sources as kerogen and carbonate signals are considered to monitor surface and deeper waters respectively the negative 13c event would therefore have occurred in surface water followed by a smaller 13c depletion through the entire water column due to vertical mixing between surface and deeper waters at the studied site this mechanism supports the proposed hypothesis that injection of the 13c depleted atmospheric co2 into the surface sea deriving ultimately from quantitative dissociation of methane hydrate in terrestrial permafrost during the post glacial warming contributed to the negative 13c anomaly

u pb zircon ages of granites from the southern margin of the yangtze block timing of neoproterozoic jinning orogeny in se china and implications for rodinia assembly abstract neoproterozoic jinningian bendong granodiorite and sanfang and yuanbaoshan granites occurred in northern guangxi southern margin of the yangtze block se china and were generally considered to be of orogenic origin that is the collision between the yangtze and huanan blocks during the jinning orogeny these granites were intruded into the mesoproterozoic sibao metamorphic basement and covered unconformably by the neoproterozoic danzhou metasediments they are dominantly peraluminous asi 1 18 1 29 and have low initial end values of 4 8 to 7 6 indicating derivation from a supracrustal source with strong enrichment in rb k and th and relatively low zr hf and higher rare earth elements they are similar to post collision granites zircon u pb ages of 819 9 826 10 and 824 4 ma were obtained for the bendong granodiorite and the sanfang and yuanbaoshan granites respectively by both shrimp and conventional dating methods the age result precludes the existence of any late mesoproterozoic grenville age granitic magmatism in the southern margin of yangtze block together with previous age determinations of ophiolites along the southern margin of the yangtze block the jinning orogeny is referred to the neoproterozoic orogeny which took place between 1 0 and 0 80 ga and likely ended at 0 82 ga the granite formation age of 0 82 ga also supports the basal boundary age of 0 80 ga for the post orogenic sinian system which is probably stratigraphically correlated with the adeladean system in south australia as the link between australia east antarctica and laurentia in the configuration of the supercontinent rodinia the collision between the yangtze and huanan blocks during the neoproterozoic jinning orogeny probably marks the termination of the rodinia assembly

secular variations in precambrian seawater chemistry and the timing of precambrian aragonite seas and calcite seas an extension of the seawater secular variation model that successfully predicted the observed timing of phanerozoic mgso 4 vs kcl marine evaporites and aragonite seas vs calcite seas has been applied to the prediction of the secular variations in the major ion chemistry of seawater and aragonite seas vs calcite seas during the precambrian testing of the predictions was based on those precambrian seafloor carbonate precipitates that have been interpreted by others to have formed originally as aragonite of 16 examples of precambrian seafloor aragonite 14 fall within the 6 periods of aragonite seas predicted for the late archean proterozoic by the model 1 falls on the transition between an aragonite sea and calcite sea and 1 falls in a period of calcite seas this strong correlation supports the following predictions of the model 1 precambrian seawater was a saline nacl water with ca hco 3 since at least the late archean 2 the major ion compositions of precambrian seawater chemistry and their secular variations are in the same ranges as those of phanerozoic seawater 3 the mg ca mole ratio in seawater has controlled the types of caco 3 polymorphs that have precipitated from earth9s oceans throughout the phanerozoic and most if not all of the precambrian

adakitic granites within the ne jiangxi ophiolites south china geochemical and nd isotopic evidence geochemical and nd isotopic data are reported for the ca 970 ma albite granites within the neoproterozoic ne jiangxi ophiolite south china these granites are high in al2o3 15 17 na2o 7 3 8 5 mg 43 62 sr 383 920 ppm sr y 166 444 and y yb 12 14 but low in k2o 0 2 0 6 tio2 0 3 p2o5 0 1 furthermore they display consistently high morb like initial end values of 4 6 to 6 7 at ca 970 ma these geochemcial and isotopic characters are similar to those of the modern adakites compared with the modern adakites the xiwan albite granites are depleted in middle to heavy ree with y yb ratio of 12 14 which can be attributed to residual amphibole and garnet in the source geological and geochemical features suggested that the granites were generated by low degrees of partial melting of subducted spilitized oceanic crust at pressures high enough to stabilize garnet and amphibole these are the first adakitic granites identified within the ne jiangxi ophiolite their presence shows that granitic rocks that intrude ophiolites can be generated not only during the processes of sea floor spreading oceanic crust shearing and obduction of fragmented oceanic lithosphere as previously thought but also during the process of subduction of oceanic lithosphere the shrimp u pb zircon age of 968 23 ma for the xiwan adakitic granite geochimica 23 1994 117 should be re interpreted as the timing of subduction of oceanic crust rather than as the age of oceanic crustal formation as previously interpreted