shallow marine carbon and oxygen isotope and elemental records indicate icehouse greenhouse cycles during the early jurassic 1 for much of the mesozoic record there has been an inconclusive debate on the possible global significance of isotopic proxies for environmental change and of sequence stratigraphic depositional sequences we present a carbon and oxygen isotope and elemental record for part of the early jurassic based on marine benthic and nektobenthic molluscs and brachiopods from the shallow marine succession of the cleveland basin uk the invertebrate isotope record is supplemented with carbon isotope data from fossil wood which samples atmospheric carbon new data elucidate two major global carbon isotope events a negative excursion of 2 at the sinemurian pliensbachian boundary and a positive excursion of 2 in the late pliensbachian the sinemurian pliensbachian boundary event is similar to the slightly younger toarcian oceanic anoxic event and is characterized by deposition of relatively deepwater organic rich shale the late pliensbachian strata by contrast are characterized by shallow marine deposition oxygen isotope data imply cooling locally for both events however because deeper water conditions characterize the sinemurian pliensbachian boundary in the cleveland basin the temperature drop is likely of local significance in contrast a cool late pliensbachian shallow seafloor agrees with previous inference of partial icehouse conditions both the large scale long term and small scale short duration isotopic cycles occurred in concert with relative sea level changes documented previously from sequence stratigraphy isotope events and the sea level cycles are concluded to reflect processes of global significance supporting the idea of an early jurassic in which cyclic swings from icehouse to greenhouse and super greenhouse conditions occurred at timescales from 1 to 10 ma

surface area control of shallow cratonic to deep marine carbonate accumulation sites of calcium magnesium carbonate accumulation have been shifting from shallow shelf to deep marine settings since the late cretaceous during this time total area of flooded epicratonic shelf has decreased about 50 and areas of shelf carbonate deposition have declined from 27 106 km to present areas of 1 4 106 km while the maximum extent of platform carbonate accumulation has decreased from about 50 to 28 north latitude in terms of cratonic carbonate this decrease in tropical shelf area has resulted in a sixfold reduction in shoal water limestone accumulation from a cretaceous rate of 0 6 km m y to a present value of about 0 1 106 km m y over the same time period the global carbonate compensation depth has deepened by about 1 5 km attendant with a threefold areal increase of calcite ooze depositionn 40 to 130 106 km this expansion has resulted in an eightfold increase in pelagic limestone accumulation from a cretaceous rate of 0 05 106 km m y to a present rate of about 0 4 106 km m y transfer of accumulation from shallow cratonic to deep marine depositional settings records the central role of sedimentary environment surface area in predicating the differential partitioning of finite carbonate fluxes to phanerozoic global oceans

eocene bipolar glaciation associated with global carbon cycle changes the transition from the extreme global warmth of the early eocene greenhouse climate 55 million years ago to the present glaciated state is one of the most prominent changes in earth s climatic evolution it is widely accepted that large ice sheets first appeared on antarctica 34 million years ago coincident with decreasing atmospheric carbon dioxide concentrations and a deepening of the calcite compensation depth in the world s oceans and that glaciation in the northern hemisphere began much later between 10 and 6 million years ago here we present records of sediment and foraminiferal geochemistry covering the greenhouse icehouse climate transition we report evidence for synchronous deepening and subsequent oscillations in the calcite compensation depth in the tropical pacific and south atlantic oceans from 42 million years ago with a permanent deepening 34 million years ago the most prominent variations in the calcite compensation depth coincide with changes in seawater oxygen isotope ratios of up to 1 5 per mil suggesting a lowering of global sea level through significant storage of ice in both hemispheres by at least 100 to 125 metres variations in benthic carbon isotope ratios of up to 1 4 per mil occurred at the same time indicating large changes in carbon cycling we suggest that the greenhouse icehouse transition was closely coupled to the evolution of atmospheric carbon dioxide and that negative carbon cycle feedbacks may have prevented the permanent establishment of large ice sheets earlier than 34 million years ago between 55 and 34 million years ago earth switched from a warm greenhouse ocean climate system to the icehouse that we now enjoy frustratingly the few oceanographic datasets that exist for this key period are of low resolution tripati et al now present measurements of sediment and foraminiferal geochemistry that provide the first continuous high resolution records for this period the data suggest that northern hemisphere glaciation started 34 million years ago rather than between 10 and 8 million years ago as previously thought

tropical sea surface temperature reconstruction for the early paleogene using mg ca ratios of planktonic foraminifera 1 to understand the climate dynamics of hypothesized past greenhouse intervals it is essential to constrain tropical sea surface temperatures sst yet existing proxy records give conflicting results here we present the first mg ca based study of pre quaternary sst and investigate early paleogene late paleocene through late middle eocene 58 6 39 8 ma tropical temperatures using planktonic foraminifera belonging to the genus morozovella from ocean drilling program site 865 on allison guyot western central equatorial pacific ocean calcification temperatures similar to or warmer than modern tropical sst are calculated using a range of assumptions regarding diagenesis temperature calibration and seawater mg ca long term warming is observed into the early eocene 54 8 49 0 ma with peak sst between 51 and 48 ma and rapid cooling of 4 c beginning at 48 ma these findings are inconsistent with the 18o based sst previously estimated for this site

late eocene to early miocene ice sheet dynamics and the global carbon cycle paired benthic foraminiferal trace metal and stable isotope records have been constructed from equatorial pacific ocean drilling program site 1218 the records include the two largest abrupt 1 myr increases in the cenozoic benthic oxygen isotope record oi 1 in the earliest oligocene 34 ma and mi 1 in the earliest miocene 23 ma the paired mg ca and oxygen isotope records are used to calculate seawater 18o w calculated w suggests that a large antarctic ice sheet formed during oi 1 and subsequently fluctuated throughout the oligocene on both short 0 5 myr and long 2 3 myr timescales between about 50 and 100 of its maximum earliest oligocene size the magnitudes of these fluctuations are consistent with estimates of sea level derived from sequence stratigraphy the transient expansion of the antarctic ice sheet at mi 1 is marked in the benthic 18o record by two positive excursions between 23 7 and 22 9 ma each with a duration of 200 300 kyr bottom water temperatures decreased by 2 c over the 150 kyr immediately prior to both rapid 18o excursions however the onset of each of these phases of ice growth is synchronous within the resolution of the records with the onset of a 2 c warming over 150 kyr we suggest that the warming during these glacial expansions reflect increased greenhouse forcing prompted by a sudden decrease in global chemical weathering rates as antarctic basement silicate rocks became blanketed by an ice sheet this represents a negative feedback process that might have operated during major abrupt growth phases of the antarctic ice sheet

paleobotanical evidence for near present day levels of atmospheric co2 during part of the tertiary understanding the link between the greenhouse gas carbon dioxide co 2 and earth9s temperature underpins much of paleoclimatology and our predictions of future global warming here we use the inverse relationship between leaf stomatal indices and the partial pressure of co 2 in modern ginkgo biloba and metasequoia glyptostroboides to develop a co 2 reconstruction based on fossil ginkgo and metasequoia cuticles for the middle paleocene to early eocene and middle miocene our reconstruction indicates that co 2 remained between 300 and 450 parts per million by volume for these intervals with the exception of a single high estimate near the paleocene eocene boundary these results suggest that factors in addition to co 2 are required to explain these past intervals of global warmth

rapid stepwise onset of antarctic glaciation and deeper calcite compensation in the pacific ocean the ocean depth at which the rate of calcium carbonate input from surface waters equals the rate of dissolution is termed the calcite compensation depth at present this depth is 4 500 m with some variation between and within ocean basins the calcite compensation depth is linked to ocean acidity which is in turn linked to atmospheric carbon dioxide concentrations and hence global climate1 geological records of changes in the calcite compensation depth show a prominent deepening of more than 1 km near the eocene oligocene boundary 34 million years ago 2 when significant permanent ice sheets first appeared on antarctica3 4 5 6 but the relationship between these two events is poorly understood here we present ocean sediment records of calcium carbonate content as well as carbon and oxygen isotopic compositions from the tropical pacific ocean that cover the eocene oligocene boundary we find that the deepening of the calcite compensation depth was more rapid than previously documented and occurred in two jumps of about 40 000 years each synchronous with the stepwise onset of antarctic ice sheet growth the glaciation was initiated after climatic preconditioning7 by an interval when the earth s orbit of the sun favoured cool summers the changes in oxygen isotope composition across the eocene oligocene boundary are too large to be explained by antarctic ice sheet growth alone and must therefore also indicate contemporaneous global cooling and or northern hemisphere glaciation

quantitative reconstruction of middle and late eocene paleoclimate based on palynological records from the huadian basin northeastern china evidence for monsoonal influence on oil shale formation abstract the eocene was an interval of climate evolution when the extreme high temperatures of the earliest cenozoic gave way to a global cooling trend fine grained lacustrine sediments of eocene age from northeastern china represent an excellent archive to study long term environmental and climatic changes at high resolution the huadian basin is a cenozoic fault bounded basin in jilin province northeastern china though small in area it contains numerous oil shale and coal bearing layers which provide an abundant middle to late eocene palynoflora eighty five palynomorph genera and one hundred palynomorph species were identified in the huadian formation allowing to distinguish 4 palynozones the nearest living relatives of the recovered palynomorph taxa suggest the presence of subtropical evergreen and deciduous broad leaved forests during deposition of the huadian formation using the coexistence approach ca we calculated seven paleoclimatic parameters which indicate a subtropical warm and humid climate with a mean annual temperature above 13 6 c and a mean annual precipitation of at least 887 mm however the climate became cooler and drier during the transition from the lower oil shale member to the upper carbonaceous shale member palaeoclimatic data from the various middle and late eocene basins of northeastern china i e the huadian fushun yilan hunchun and jishu basins were compared with data from north american and european basins middle eocene climate in the northern hemisphere was generally warm and humid and the mean annual temperature and precipitation in northeastern china were similar to those in north america though slightly lower than those of europe similar trends in temperature and precipitation on different continents support the existence of a global mid eocene cooling event this paper is the first systematic study of middle to late eocene seasonality in the huadian basin our results show an apparent differentiation in both temperature and precipitation between summer and winter supporting the view that the east asian monsoon was established in northeastern china already during the middle to late eocene this middle and late eocene monsoon was likely driven by the development of pacific trade winds and an alternating seasonal high and low pressure system over siberia the climatic changes observed in our dataset especially the precipitation changes appear to have played an important role in controlling oil shale formation in the huadian basin a warmer and more humid climate with abundant precipitation and high subsidence rates formed a deeper huadian depositional lake high productivity and stable stratification provided the abundant organic matter and favorable preservation conditions necessary for oil shale accumulation

significant southern ocean warming event in the late middle eocene a prominent middle eocene warming event is identified in southern ocean deep sea cores indicating that long term cooling through the middle and late eocene was not monotonic at sites on maud rise and the kerguelen plateau a distinct negative shift in 1 8 o values 1 0 is observed ca 41 5 ma this excursion is interpreted as primarily a temperature signal with a transient warming of 4 c over 600 k y affecting both surface and middle bathyal deep waters in the indian atlantic region of the southern ocean this isotopic event is designated as the middle eocene climatic optimum and is interpreted to represent a significant climatic reversal in the midst of middle to late eocene deep sea cooling the lack of a significant negative carbon isotope excursion as observed during the paleocene eocene thermal maximum and the gradual rate of high latitude warming suggest that this event was not triggered by methane hydrate dissociation rather a transient rise in pco 2 levels is suspected possibly as a result of metamorphic decarbonation in the himalayan orogen or increased ridge arc volcanism during the late middle eocene

changes in calcareous nannofossil assemblages during the middle eocene climatic optimum clues from the central western tethys alano section ne italy we present a study focused on changes in calcareous nannofossil assemblages of the alano section during the middle eocene climatic optimum meco this warming event is characterized by a prominent perturbation both in oxygen and carbon stable isotopes around the chron c18r c18n transition ca 40 ma and lasting ca 500 600 kyr semi quantitative analyses on calcareous nannofossil assemblages have been carried out our results show that the meco interval coincides with a significant shift in the relative abundance of calcareous nannofossil taxa suggesting a relationship between biotic changes and stable isotope shifts paleoecological studies at species level and or based on morphometric criteria i e small placoliths sometimes show the opposite behaviour between changes observed at the genus level and those observed at lower taxonomic levels for instance a taxon thought to be better adapted to oligotrophic warm waters e g sphenolithus shows a prominent decrease if analyzed at genus level but an increase was instead recorded for s spiniger moreover taxa preferentially thriving in eutrophic cold waters as for instance small reticulofenestrids increase remarkably in abundance during this warming phase while medium large placoliths do not show any significant trend an increase in reworked mainly cretaceous specimens is also observed during the meco these lines of evidence are consistent with a transient enrichment in dissolved nutrients in warmer sea surface waters suggesting that an enhanced nutrient availability could have driven the make up of the calcareous nannofossil assemblages the increase in reworking may indicate an increase in terrigenous input due to increased chemical weathering likely produced by an enhanced hydrological cycle

upper cretaceous sequences and sea level history new jersey coastal plain we developed a late cretaceous sea level estimate from upper cretaceous sequences at bass river and ancora new jersey odp ocean drilling program leg 174ax we dated 11 14 sequences by integrating sr isotope and biostratigraphy age resolution 0 5 m y and then estimated paleoenvironmental changes within the sequences from lithofacies and biofacies analyses sequences generally shallow up section from middle neritic to inner neritic paleodepths as shown by the transition from thin basal glauconite shelf sands transgressive systems tracts tst to medial prodelta silty clays highstand systems tracts hst and finally to upper delta front quartz sands hst sea level estimates obtained by backstripping accounting for paleodepth variations sediment loading compaction and basin subsidence indicate that large 25 m and rapid 1 m y sea level variations occurred during the late cretaceous greenhouse world the fact that the timing of upper cretaceous sequence boundaries in new jersey is similar to the sea level lowering records of exxon production research company epr northwest european sections and russian platform outcrops points to a global cause because backstripping seismicity seismic stratigraphic data and sediment distribution patterns all indicate minimal tectonic effects on the new jersey coastal plain we interpret that we have isolated a eustatic signature the only known mechanism that can explain such global changes glacio eustasy is consistent with foraminiferal 18 o data either continental ice sheets paced sea level changes during the late cretaceous or our understanding of causal mechanisms for global sea level change is fundamentally flawed comparison of our eustatic history with published ice sheet models and milankovitch predictions suggests that small 5 10 10 6 km 3 ephemeral and areally restricted antarctic ice sheets paced the late cretaceous global sea level change new jersey and russian eustatic estimates are typically one half of the epr amplitudes though this difference varies through time yielding markedly different eustatic curves we conclude that new jersey provides the best available estimate for late cretaceous sea level variations

no extreme bipolar glaciation during the main eocene calcite compensation shift major ice sheets were permanently established on antarctica approximately 34 million years ago1 2 3 close to the eocene oligocene boundary at the same time as a permanent deepening of the calcite compensation depth in the world s oceans4 until recently it was thought that northern hemisphere glaciation began much later between 11 and 5 million years ago1 2 3 5 this view has been challenged however by records of ice rafting at high northern latitudes during the eocene epoch6 7 and by estimates of global ice volume that exceed the storage capacity of antarctica8 at the same time as a temporary deepening of the calcite compensation depth 41 6 million years ago9 here we test the hypothesis that large ice sheets were present in both hemispheres 41 6 million years ago using marine sediment records of oxygen and carbon isotope values and of calcium carbonate content from the equatorial atlantic ocean these records allow at most an ice budget that can easily be accommodated on antarctica indicating that large ice sheets were not present in the northern hemisphere the records also reveal a brief interval shortly before the temporary deepening of the calcite compensation depth during which the calcite compensation depth shoaled ocean temperatures increased and carbon isotope values decreased in the equatorial atlantic the nature of these changes around 41 6 million years ago implies common links in terms of carbon cycling with events at the eocene oligocene boundary4 and with the hyperthermals of the early eocene climate optimum3 10 11 our findings help to resolve the apparent discrepancy between the geological records of northern hemisphere glaciation6 7 8 and model results12 13 that indicate that the threshold for continental glaciation was crossed earlier in the southern hemisphere than in the northern hemisphere

application of benthic foraminiferal mg ca ratios to questions of cenozoic climate change abstract we investigate the evolution of cenozoic climate and ice volume as evidenced by the oxygen isotopic composition of seawater 18osw derived from benthic foraminiferal mg ca ratios to constrain the temperature effect contained in foraminiferal 18o values we have constructed two benthic foraminiferal mg ca records from intermediate water depth sites ocean drilling program sites 757 and 689 from the subtropical indian ocean and the weddell sea respectively together with the previously published composite record of lear et al science 287 2002 269 272 and the neogene record from the southern ocean of billups and schrag paleoceanography 17 2002 10 1029 2000pa000567 we obtain three almost complete representations of the 18osw for the past 52 myr we discuss the sensitivity of early cenozoic mg ca derived paleotemperatures and hence the 18osw to assumptions about seawater mg ca ratios we find that during the middle eocene 49 40 ma modern seawater ratios yield mg ca derived temperatures that are in good agreement with the oxygen isotope paleothermometer assuming ice free conditions intermediate waters cooled during the middle eocene reaching minimum temperatures by 40 ma the corresponding 18osw reconstructions support ice growth on antarctica beginning by at least 40 ma at the eocene oligocene boundary mg ca ratios and hence temperatures from weddell sea site 689 display a well defined maximum we caution against a paleoclimatic significance of this result and put forth that the partitioning coefficient of mg in benthic foraminifera may be sensitive to factors other than temperature throughout the remainder of the cenozoic the temporal variability among 18osw records is similar and similar to longer term trends in the benthic foraminiferal 18o record an exception occurs during the pliocene when 18osw minima in two of the three records suggest reductions in global ice volume that are not apparent in foraminiferal 18o records which provides a new perspective to the ongoing debate about the stability of the antarctic ice sheet maximum 18osw values recorded during the pleistocene at southern ocean site 747 agree well with values derived from the geochemistry of pore waters schrag et al science 272 1996 1930 1932 further highlighting the value of the new mg ca calibrations of martin et al earth planet sci lett 198 2002 193 209 and lear et al geochim cosmochim acta 66 2002 3375 3387 applied in this study we conclude that the application of foraminiferal mg ca ratios allows a refined view of cenozoic ice volume history despite uncertainties related to the geochemical cycling of mg and ca on long time scales

conflicting isotopic and biotic evidence for tropical sea surface temperatures during the tertiary abstract the biotic evidence from a varied group of shallow water organisms including mangroves zooxanthellate corals mainly reefal and larger foraminifera suggests that sea surface temperatures at low latitudes during the tertiary from at least the early eocene to the middle miocene were subtropical to tropical in nature and similar to temperatures prevailing at low latitudes at the present day 20 28 c in a recent paper shackleton 1984 the suggestion is made on the basis of oxygen isotope studies of foraminiferal shells that low latitude sea surface temperatures during the palaeogene and much of the neogene were invariably lower than those in similar regions today with a stable temperature of around 18 c this paper discusses the conflicting evidence for sea surface temperatures obtained from palaeontological and isotopic sources and suggests that palaeotemperatures derived from some isotopic studies are too low to account for the distribution and diversity of many tertiary tropical and subtropical biotas

middle eocene regional climate instability evidence from the western north atlantic high resolution 3 k y d 18 o records from middle eocene mixed layer dwelling planktonic foraminifera from the western north atlantic show pronounced 1 variability the magnitude of change is greater than that seen in open ocean pleistocene records but could not have been caused by ice volume and or sea level fluctuations instead the oxygen isotope shifts resulted primarily from large oscillations in sea surface temperatures and indicate that the regional paleoceanography of the middle eocene western north atlantic was not consistently warm or stable the large shifts in sea surface temperatures could reflect variations in the position of the gulf stream relative to blake nose or variations in upwelling intensity

evidence for a heavily glaciated antarctica during the late oligocene warming 27 8 24 5 ma stable isotope records from odp site 690 high 18o values 3 0 from a 9 kyr resolution benthic foraminiferal stable isotope record from the ocean drilling program odp site 690b located on the maud rise antarctica indicate a heavily glaciated antarctic continent during late oligocene 27 8 24 5 ma values ranging 2 5 3 0 during interglacial periods and 3 0 3 6 during glacial intervals are consistent with an ice sheet near or larger than modern size in addition this record does not exhibit the long term late oligocene warming trend seen in records from low latitude drill sites oxygen isotope values from 26 0 24 5 ma are comparable ranging between 2 5 and 3 3 to values that preceded the 18o event oi2b at 26 7 ma indicating no significant glacial collapse occurred during the late oligocene a gradient between ocean basins during the oligocene has already been linked to the development of a modern multi layered ocean and worked to bathe the low to mid latitude deep sea records with a warmer water mass we suggest this masked the significant antarctic glaciation in low latitude paleoceanographic records additionally we propose a resolution for conflicting lines of evidence from some antarctic proximal records suggesting significant glaciation and others suggesting reduced glaciation during the late oligocene by allowing a modern sized ice sheet to grow on an antarctic continent as more land surface area existed above sea level during this time this could allow at least some portions of the antarctic coastline to remain ice free during glacial minima while still maintaining modern or near modern ice volume

quaternary deep sea temperature histories derived from benthic foraminiferal mg ca abstract we have generated benthic foraminiferal mg ca records from eastern tropical atlantic core m16772 3 9 km and eastern tropical pacific core tr163 31p 3 2 km to assess the potential for using benthic mg paleothermometry to reconstruct quaternary bottom water temperature histories variations in mg ca records from both the atlantic and pacific show a significant correlation with climatic oscillations of the last 330 kyr shell mg ca peaks during interglacial episodes with marine isotope stage mis 5e mg ca nearly matching holocene values in both cores lower mg ca values occur during glacial intervals to estimate temperatures from downcore mg ca we have augmented the published cibicidoides sp mg ca temperature dataset rosenthal et al geochim cosmochim acta 61 1997 3633 3643 with new data to include the temperature range of deep waters applying the 10 9 change in mg ca per c defined by the expanded calibration to the deep atlantic data implies glacial interglacial shifts in deep water temperature of 2 4 c over the last 300 kyr temperature estimates are comparable to deep atlantic temperature changes proposed by labeyrie et al nature 327 1987 477 482 there is greater uncertainty in deriving temperatures from the tropical pacific core due to a limited uvigerina spp core top calibration set however glacial interglacial temperature oscillations appear to be on the order of 2 3 c in addition core tr163 31p records clear millennial scale mg ca and 18 o oscillations in mis 3 corresponding to temperature fluctuations of 0 5 c additional calibration studies are needed to address potential secondary effects on mg ca

tertiary oxygen isotope synthesis sea level history and continental margin erosion tertiary benthic and planktonic foraminiferal oxygen isotope records are correlated to a standard geomagnetic polarity time scale making use of improved chronostratigraphic control and additional oligocene isotope data synchronous changes in both benthic and planktonic 18o values which occurred in the oligocene to miocene 36 5 2 ma are interpreted in part to represent ice growth and decay the inferred ice growth events correlate with erosion on passive continental margins as interpreted from seismic and chronostratigraphic records this association is consistent with a link between oligocene to miocene erosional events and rapid 15 m m y glacioeustatic lowerings of about 50 m high benthic foraminiferal 18o values suggest the presence of continental ice sheets during much of the oligocene to recent 36 0 ma substantially ice free conditions probably existed throughout the paleocene and eocene 66 36 ma the mechanisms and rates of sea level change apparently were different between the early and late tertiary with glacioeustatic changes restricted to the past 36 m y pre oligocene erosion on passive continental margins was caused by eustatic lowerings resulting from global spreading rate changes we apply a model which suggests that large areas of the continental shelves were subaerially exposed during such tectonoeustatic lowstands stimulating slope failure and submarine erosion the different mechanisms and rates of eustatic change may have caused contrasting erosional patterns between the early and late tertiary on passive continental margins this speculation needs to be confirmed by examination of data from several passive margins

late eocene tropical sea surface temperatures a perspective from panama 1 we have reconstructed mean annual coastal temperatures and seasonality during the eocene priabonian 36 6 40 ma using oxygen isotope profiles of shallow marine aragonitic gastropod shells gatuncillo formation panama these data provide a unique opportunity to document low latitude coastal climates during a preglacial greenhouse period assuming shell oxygen isotope profiles primarily reflect changes in water temperature our results indicate water temperatures in a middle to outer shelf setting 20 50 m depth varied by 6 8 c and mean annual temperatures mat were 26 c these temperatures are in agreement with pollen based surface temperature reconstructions for the late eocene and are consistent with other eocene mollusk based tropical coastal temperature estimates but are at odds with the few eocene foraminiferal based estimates of mean annual tropical sea surface temperatures 17 22 c

rapid cenozoic glaciation of antarctica induced by declining atmospheric co2 the sudden widespread glaciation of antarctica and the associated shift towards colder temperatures at the eocene oligocene boundary 34 million years ago refs 1 4 is one of the most fundamental reorganizations of global climate known in the geologic record the glaciation of antarctica has hitherto been thought to result from the tectonic opening of southern ocean gateways which enabled the formation of the antarctic circumpolar current and the subsequent thermal isolation of the antarctic continent5 here we simulate the glacial inception and early growth of the east antarctic ice sheet using a general circulation model with coupled components for atmosphere ocean ice sheet and sediment and which incorporates palaeogeography greenhouse gas changing orbital parameters and varying ocean heat transport in our model declining cenozoic co2 first leads to the formation of small highly dynamic ice caps on high antarctic plateaux at a later time a co2 threshold is crossed initiating ice sheet height mass balance feedbacks that cause the ice caps to expand rapidly with large orbital variations eventually coalescing into a continental scale east antarctic ice sheet according to our simulation the opening of southern ocean gateways plays a secondary role in this transition relative to co2 concentration

tibetan uplift prior to the eocene oligocene climate transition evidence from pollen analysis of the xining basin uplift of the tibetan plateau and the himalayas since the onset of the indo asia collision is held responsible for asian aridifi cation and monsoon intensifi cation but may also have gradually cooled global climate leading to the 34 ma eocene oligocene transition to unravel the interplay between tibetan uplift and global climate proxy records of asian paleoenvironments constrained by accurate age models are needed for the paleogene period here we report the 38 ma appearance of high altitude vegetation recovered from palynological assemblages in precisely dated lacustrine sediments from the xining basin of the northeastern tibetan plateau region this result confi rms previous evidence for important regional uplift in the central and northern tibetan plateau regions during the early stage of the indo asia collision this is consistent with the idea that the associated increase in rock weathering and erosion contributed to lowering of atmospheric co 2 leading to the eocene oligocene transition

seismic and geochemical evidence for shallow gas in sediment on navarin continental margin bering sea marine seismic studies coupled with geochemical investigations demonstrate that hydrocarbon gases are ubiquitous in the near surface 250 m or 820 ft depth sediment of the navarin continental margin in the northern bering sea three types of acoustic anomalies appear to be related to the presence of gas in the sediment these anomalies are most prevalent in the northern half of the navarin basin acoustic anomalies attributed to gas hydrates and to diagenetic boundaries are present on seismic records of the lower slope between navarinsky and zhemchug canyons hydrocarbon gases methane through butanes are common in the surface 5 m or 17 ft depth sediment of the navarin continental margin methane the most abundant hydrocarbon gas is present in amounts ranging from 84 000 to 1 l l of wet sediment these concentrations are two to three orders of magnitude greater than the other hydrocarbon gases the highest concentrations of methane greater than 1 000 l l were measured in sediment of navarinsky canyon and over the central part of the navarin basin the source of methane is mainly biogenic but the hydrocarbon gas compositions in 17 of 141 cores suggest the presence of thermogenic gas most of these 17 cores are from the continental slope at water depths greater than 150 m 490 ft no direct correlation could be found between acoustic anomalies and gas concentrations in the sediment this lack of correlation is probably due to the limited penetration of the gravity corer and the spotty distribution of hydrocarbon concentrations

oxygen isotopes of marine mollusc shells record eocene elevation change in the pyrenees abstract constraining paleoaltimetry of collisional orogens is critical to understand the dynamics of topographic evolution and climate tectonics retroactions here we use oxygen stable isotope record on oyster shells preserved in marine foreland deposits to examine the past elevation of the pyrenees during the eocene our approach is based on the comparison with the paris basin an intracratonic basin not influenced by orogenic growth the finding of a shift of 1 5 between 49 and 41 ma indicating more negative 18oc in the south pyrenean foreland is interpreted to reflect the inflow of river water sourced from higher elevation in the pyrenees to test this and provide paleoelevation estimate we adopt a morphologic hydrological model accounting for the hypsometry of drainage basin our best fitting model shows that the pyrenees rose up to 2000 m this indicates that the pyrenees reached high elevation in the eocene thus providing new critical constraints on their long term orogenic development 18o of marine mollusc shells are proved potentially attractive for paleoelevation studies especially for mountain belts where elevated continental surfaces have not been preserved

cenozoic global sea level sequences and the new jersey transect results from coastal plain and continental slope drilling the new jersey sea level transect was designed to evaluate the relationships among global sea level eustatic change unconformity bounded sequences and variations in subsidence sediment supply and climate on a passive continental margin by sampling and dating cenozoic strata from coastal plain and continental slope locations we show that sequence boundaries correlate within 0 5 myr regionally onshore offshore and interregionally new jersey alabama bahamas implicating a global cause sequence boundaries correlate with 18o increases for at least the past 42 myr consistent with an ice volume glacioeustatic control although a causal relationship is not required because of uncertainties in ages and correlations evidence for a causal connection is provided by preliminary miocene data from slope site 904 that directly link 18o increases with sequence boundaries we conclude that variation in the size of ice sheets has been a primary control on the formation of sequence boundaries since 42 ma we speculate that prior to this the growth and decay of small ice sheets caused small amplitude sea level changes 20 m in this supposedly ice free world because eocene sequence boundaries also appear to correlate with minor 18o increases subsidence estimates backstripping indicate amplitudes of short term million year scale lowerings that are consistent with estimates derived from 18o studies 25 50 m in the oligocene middle miocene and 10 20 m in the eocene and a long term lowering of 150 200 m over the past 65 myr consistent with estimates derived from volume changes on mid ocean ridges although our results are consistent with the general number and timing of paleocene to middle miocene sequences published by workers at exxon production research company our estimates of sea level amplitudes are substantially lower than theirs lithofacies patterns within sequences follow repetitive predictable patterns 1 coastal plain sequences consist of basal transgressive sands overlain by regressive highstand silts and quartz sands and 2 although slope lithofacies variations are subdued reworked sediments constitute lowstand deposits causing the strongest most extensive seismic reflections despite a primary eustatic control on sequence boundaries new jersey sequences were also influenced by changes in tectonics sediment supply and climate during the early to middle eocene low siliciclastic and high pelagic input associated with warm climates resulted in widespread carbonate deposition and thin sequences late middle eocene and earliest oligocene cooling events curtailed carbonate deposition in the coastal plain and slope respectively resulting in a switch to siliciclastic sedimentation in onshore areas oligocene sequences are thin owing to low siliciclastic and pelagic input and their distribution is patchy reflecting migration or progradation of depocenters in contrast miocene onshore sequences are thicker reflecting increased sediment supply and they are more complete downdip owing to simple tectonics we conclude that the new jersey margin provides a natural laboratory for unraveling complex interactions of eustasy tectonics changes in sediment supply and climate change

implications of late eocene to early miocene clay mineral assemblages in mcmurdo sound ross sea antarctica on paleoclimate and ice dynamics abstract the clay mineral assemblages of upper eocene to lower miocene sediments recovered at the ciros 1 and mssts 1 drill sites on the mcmurdo sound shelf antarctica were analyzed in order to reconstruct the cenozoic antarctic paleoclimate and ice dynamics the assemblages are dominated by smectite and illite with minor amounts of chlorite and kaolinite the highest smectite amounts and best smectite crystallinities occur in the upper eocene part of ciros 1 below 425 445 mbsf they indicate that during their deposition chemical weathering conditions prevailed on the nearby continent large parts of east antarctica were probably ice free at that time but some glaciers reached the sea and contributed to the glaciomarine sedimentation in contrast only minor total amounts of smectite are present in oligocene and younger sediments due to the shift to mainly physical weathering on an ice covered antarctic continent however relative smectite percentages rise to more than 60 during two late oligocene intervals ca 27 5 26 2 and 25 0 24 5 ma and during one early miocene interval starting at ca 23 3 ma these intervals are characterized by ice masses coming probably from the south where volcanic rocks acted as a source as also indicated by the composition of the sand and gravel fractions during the other intervals the ice came from the west where the physical erosion of basement rocks and sedimentary rocks of the beacon supergroup in the transantarctic mountains provided high illite concentrations because the two drill sites are only 4 km apart their clay mineral records can be correlated this led to a new interpretation of the oligocene paleomagnetic data of the mssts 1 site and to a more detailed lithostratigraphic correlation of the miocene parts of the cores

eocene el nino evidence for robust tropical dynamics in the hothouse much uncertainty surrounds the interactions between the el nino southern oscillation enso and long term global change past periods of extreme global warmth exemplified by the eocene 55 to 35 million years ago provide a good testing ground for theories for this interaction here we compare eocene coupled climate model simulations with annually resolved variability records preserved in lake sediments the simulations show pacific deep ocean and high latitude surface warming of approximately 10 degrees c but little change in the tropical thermocline structure atmosphere ocean dynamics and enso in agreement with proxies this result contrasts with theories linking past and future hothouse climates with a shift toward a permanent el nino like state

cenozoic mass accumulation rates in the equatorial pacific based on high resolution mineralogy of ocean drilling program leg 199 1 we use continuous mineralogy logs derived from multisensor track physical properties data and reflectance spectroscopy to calculate high resolution carbonate opal and terrigenous mass accumulation rates mar for the eight sites cored during ocean drilling program leg 199 in the equatorial pacific the largest change in equatorial pacific sedimentation patterns of the last 55 myr occurs at the greenhouse icehouse transition shortly after the eocene oligocene boundary calcite compensation depth deepened dramatically the equatorial zone of opal accumulation narrowed and the intertropical convergence zone shifted to the equator during the paleogene the opal equatorial accumulation bulge extended to about 12 n whereas the neogene bulge extended only to about 7 n very low eocene carbonate mar was followed by much higher oligocene and early miocene mar with the carbonate equatorial bulge extending to 4 n terrigenous mars indicate the paleoposition of the intertropical convergence zone and a pliocene pleistocene increase in asian dust flux

benthic foraminiferal mg ca paleothermometry a revised core top calibration core top samples from different ocean basins have been analyzed to refine our current understanding of the sensitivity of benthic foraminiferal calcite magnesium calcium mg ca to bottom water temperatures bwt benthic foraminifera collected from hawaii little bahama bank sea of okhotsk gulf of california ne atlantic ceara rise sierra leone rise the ontong java plateau and the southern ocean covering a temperature range of 0 8 to 18 c were used to revise the cibicidoides mg ca temperature calibration the mg ca bwt relationship of three common cibicidoides species is described by an exponential equation mg ca 0 867 0 049 exp 0 109 0 007 bwt stated errors are 95 ci the temperature sensitivity is very similar to a previously published calibration however the revised calibration has a significantly different preexponential constant resulting in different predicted absolute temperatures we attribute this difference in the preexponential constant to an analytical issue of accuracy some genera notably uvigerina show apparently lower temperature sensitivity than others suggesting that the use of constant offsets to account for vital effects in mg ca may not be appropriate downcore mg ca reproducibility as determined on replicate foraminiferal samples is typically better than 0 1 mmol mol 1 2 s e thus considering the errors associated with the cibicidoides calibration and the downcore reproducibility bwt may be estimated to within 1 c application of the revised core top mg ca bwt data to cenozoic foraminiferal mg ca suggests that seawater mg ca was not more than 35 lower than today in the ice free ocean at 50 ma

levallois and non levallois blade production at shuidonggou in ningxia north china the shuidonggou site is one of the most important for prehistoric research in china yielding evidence of ancient human colonisations in north china during the late upper pleistocene situated in the ordos desert it was first discovered and excavated by teilhard de chardin during the first half of the 20th century he noted the originality of the lithic assemblages produced on blades and flakes comparable to the upper palaeolithic in western europe this open air site in loess context dates from ca 17 000 to 25 000 bp and may be earlier than 30 000 bp the principal objective of this paper is to present the technical aspects of the shuidonggou lithic assemblages using a technological approach based on the dynamic analysis of blanks and cores in a global overview of the chaine operatoire concept the goal is to understand the knapping strategies used were both levallois and non levallois methods used the importance of shuidonggou is thus linked with the question of the use of the levallois method

early oligocene ice sheet expansion on antarctica stable isotope and sedimentological evidence from kerguelen plateau southern indian ocean sedimentological and stable isotope data from a pelagic sequence recovered from the southern indian ocean provide the most convincing evidence to date for short term expansion of a large ice sheet on antarctica during the earliest oligocene 36 ma terrigenous debris identified as ice rafted in origin on the basis of textural compositional and size criteria is present at the same stratigraphic level as the ubiquitous early oligocene oxygen isotope shift the highest benthic foraminiferal 18o values 3 0 of the paleogene occur in samples from within the ice rafted debris interval these values are similar to those recorded by holocene benthic foraminifera implying that the ice sheet may have attained a volume similar to that of the present day ice sheet on antarctica the stratigraphic distribution of ice rafted debris and high oxygen isotope values indicate that these conditions persisted for roughly 100 ka

tertiary paleoceanic chemical variability unintended consequences of simple geochemical models five lines of concrete quantitative evidence about oceanic chemical composition during the past 65 m y can provide insights into the controlling processes and their temporal variations but the system constraints are not yet fully understood the calcium carbonate compensation depth mean carbon isotopic ratio and strontium isotopic ratio have all changed significantly during this time while changes in lithium to calcium and strontium to calcium ratios have been much smaller when these tracers are considered separately simple scenarios of changes in geochemical and geological factors can be used to explain the historical records these factors include 1 increases in continental chemical weathering rates and net continental fluxes to the oceans 2 changes in the isotopic composition of material weathered from continents to the oceans 3 decreases in the proportion of calcium carbonate deposited on continental shelves 4 changes in the deposition or weathering rates of certain types of sediments and 5 changes in hydrothermal circulation because these geochemical cycles are linked to each other and to others such as nutrients and global atmospheric carbon dioxide an explanation invoked for one tracer must satisfy the direction magnitude and timing of the patterns for all the tracers several simple scenarios for geochemical variations have been evaluated for their consequences both intended and unintended and compared to the historical records despite the attractiveness and possible justifications of some simple hypotheses for example decreases in organic carbon burial rates increases in carbonate weathering rates on the continents or increases in all continental weathering rates no one simple scenario appears to be consistent with both the timing and magnitude of the changes observed during the past 65 m y for all tracers considered the contradictions uncovered can be useful in defining what knowledge is crucial to further understanding of oceanic chemical history better knowledge is needed of absolute deep ocean sediment accumulation rates and their temporal variability of the extent and time scale of variability in the net carbon isotope input to the ocean from continental weathering of steady state fluxes for oceanic mass balances and the extent to which these mass balances approach steady state behavior and of the links and interactions between the geochemical cycles of various elements

evolution of early cenozoic marine temperatures the equator to high southern latitude sea surface and vertical temperature gradients are reconstructed from oxygen isotope values of planktonic and benthic foraminifers for the following five time intervals late paleocene early eocene early middle eocene late eocene and early oligocene paleotemperatures are calculated using standard oxygen isotope temperature equations with adjustments to account for 1 variations in sea water 18o related to changes in global ice volume over time and 2 latitudinal gradients in surface water 18o these reconstructions indicate that sea surface temperatures sst of the southern oceans in the early eocene were as high as 15 c whereas temperatures during the late paleocene and early middle eocene reached maximum levels of 10 12 c by the late eocene and early oligocene high latitude sst had declined to 6 and 4 c respectively for most of the early paleogene low latitude sub tropical temperatures remained constant and well within the range of holocene temperatures 24 ndash 25 c but by the late eocene and early oligocene declined to values in the range of 18 to 22 c the late paleogene apparent decline in tropical temperatures however might be artificial because of dissolution of near surface foraminifera tests which biased sediment assemblages toward deeper dwelling foraminifera moreover according to recent plate reconstructions it appears that the majority of sites upon which the late eocene and early oligocene tropical temperatures were previously established were located either in or near regions likely to have been influenced by upwelling global deepwater temperature on average paralleled southern ocean sst for most of the paleogene we speculate based on the overall timing and character of marine sea surface temperature variation during the paleogene that some combination of both higher levels of greenhouse gases and increased heat transport was responsible for the exceptional high latitude warmth of the early eocene

eocene oligocene transition in the southern ocean history of water mass circulation and biological productivity high resolution records of carbon and oxygen isotopes and benthic foraminiferal accumulation rates for the eocene oligocene section at ocean drilling program site 689 maud rise weddell sea paleodepth about 1500 m were used to infer variations in paleoproductivity in relation to changes in climate and ventilation of the deeper water column the benthic foraminiferal abundance and isotope records show short term fluctuations at periodicities of 100 and 400 ka implying orbitally driven climatic variations both records suggest that intermediate depth water chemistry and primary productivity changed in response to climate during the eocene productivity increased during cold periods and during cold to warm transitions possibly as a result of increased upwelling of nutrient rich waters in the oligocene in contrast productivity maxima occurred during intervals of low d18o values presumably warmer periods when a proto polar front moved to the south of the location of site 689 this profound transition in climate productivity patterns occurred around 37 ma coeval with rapid changes toward increasing variability of the oxygen and carbon isotope and benthic abundance records and toward larger amplitude d18o fluctuations therefore we infer that at this time temperature fluctuations increased and a proto polar front formed in conjunction with the first distinct pulsations in size of the antarctic ice sheet we speculate that this major change might have resulted from an initial opening of the drake passage at 37 ma at least for surface and intermediate water circulation

global implications of lower to middle eocene sequence boundaries on the new jersey coastal plain the icehouse cometh wedocumentninelower middleeocenesequencesonthenewjerseycoastalplainand comparethemwithglobal d 18 oandhaqetal records earlyeocenehiatusesdonotmatch d 18 ochanges anditisunlikelythattheyaretheresultofglacioeustasy consistentwithan ice free early eocene early middle eocene 49 43 ma evidence for a link between sequencesand d 18 oisequivocal andthepresenceoflargeicesheetsisuncertain beginning in the late middle eocene 43 42 ma concomitant increases in planktonic and benthic d 18 o records coincide with the timing of hiatuses on the new jersey coastal plain and a change from carbonate dominated to siliciclastic dominated sedimentation these represent the development of the antarctic ice cap and the beginning of the icehouse world of the 14 sequences predicted by haq et al for this interval 9 are resolvable on the new jersey margin and the other 5 appear to be combined with others we conclude that although ice volume changes controlled sequences since at least 42 ma mechanisms for sea level change prior to then are still not fully understood

equatorial heat accumulation as a long term trigger of permanent antarctic ice sheets during the cenozoic abstract growth of the first permanent antarctic ice sheets at the eocene oligocene transition eot 33 7 million years ago indicates a major climate shift within long term cenozoic cooling the driving mechanisms that set the stage for this glaciation event are not well constrained however owing to large uncertainties in temperature reconstructions during the eocene especially at lower latitudes to address this deficiency we used recent developments in coccolith biogeochemistry to reconstruct equatorial atlantic sea surface temperature sst and atmospheric pco2 values from pelagic sequences preceding and spanning the eot we found significantly more variability in equatorial ssts than previously reported with pronounced cooling from the early to middle eocene and subsequent warming during the late eocene thus we show that the antarctic glaciation at the eocene oligocene boundary was preceded by a period of heat accumulation in the low latitudes likely focused in a progressively contracting south atlantic gyre which contributed to cooling high latitude austral regions this prominent redistribution of heat corresponds to the emplacement of a strong meridional temperature gradient that typifies icehouse climate conditions our equatorial coccolith derived geochemical record thus highlights an important period of global climatic and oceanic upheaval which began 4 million years before the eot and superimposed on a long term pco2 decline drove the earth system toward a glacial tipping point in the cenozoic

paleocene and eocene kaolinite distribution in the south atlantic and southern ocean antarctic climatic and paleoceanographic implications abstract clay mineral associations of paleocene and eocene age have been examined in six drilled sequences from the southern south atlantic and southern ocean these sites are located to provide three depth transects across intermediate water masses widespread abundance of pedogenic smectite at all locations suggests globally warm climates and alternating wet and dry seasons on the adjacent continental margins including antarctica as was the case during the late cretaceous remarkably kaolinite is observed only in paleocene eocene sediments at the highest latitudes of these sites and must have originated from antarctica the restriction of kaolinite to the antarctic region is inferred to have resulted from especially higher rainfall there during the paleocene eocene relative to the lower latitude areas examined this inferred high rainfall is considered to have resulted from globally warm temperatures that increased poleward latent heat transport compensating for a strong heat deficit in the antarctic region relative to the tropics kaolinite was not observed in the latest cretaceous maastrichtian sediments of maud rise antarctica kaolinite first appears in the clay mineralogical assemblages in the earliest paleocene 64 to 64 5 ma at a time of relatively cool intermediate waters and before a warming trend of surface waters currents at intermediate water depths transported fine terrigenous sediments from the antarctica during the latest paleocene and early eocene 59 to 52 ma at a time when the oxygen isotopic strongly in east antarctica during the latest paleocene and early eocene 59 to 59 ma at a time when the oxygen isotopic data indicate maximum warmth of surface and intermediate waters of the southern ocean these are interpreted to reflect a paleocene maximum of antarctic rainfall this development peaked at 57 3 m close to the paleocene eocene boundary a time of maximum warmth based on oxygen isotopic data increased illite content and associated chlorite and random mixed layer clays at the end of the middle eocene 41 ma suggest local development of poorly weathered soils on antarctica favored by a cooling of the southern ocean coeval extension of kaolinite into shallower water depths and similar clay mineral associations in shallower and deeper sites indicate the development of cooler conditions led to an increasing influence of antarctic environments upon intermediate water masses at high latitudes

a review of tertiary climate changes in southern south america and the antarctic peninsula part 2 continental conditions abstract climate changes in southern south america and the antarctic peninsula during the tertiary show a strong correlation with ocean warming and cooling events which are in turn related to tectonic processes during periods of accelerated sea floor spreading and mid ocean ridge activity sea levels rose so that parts of the continents were flooded and forests were destroyed however this was balanced by the large scale release of co2 during volcanic outgassing and carbonate precipitation on the continental shelves which caused rising air temperatures and the poleward expansion of sub tropical and temperate forests cooling episodes generally caused an increase in the north south thermal gradient because of an equatorward shift in climate belts so that the westerly winds intensified and brought higher rainfall to the lower latitudes an increase in wind blown dust caused temperatures to drop further by reflecting sunlight back into space the rising andes range had a marked influence on climate patterns up to the middle miocene it was still low enough to allow summer rainfall to reach central and north central chile but after about 14 ma it rose rapidly and effectively blocked the spill over of moisture from the atlantic ocean and amazon basin at this time the cold humboldt current was also established which together with the andes helped to create the arid diagonal of southern south america stretching from the atacama desert to the dry steppes of patagonia this caused the withdrawal of subtropical forests to south central chile and the expansion of sclerophytic vegetation to central chile however at the same time it intercepted more rain from the northeast causing the effect of the south american monsoon to intensify in northwestern argentina and southern bolivia where forest communities presently occur in patagonia glaciation started as early as 10 5 ma but by 7 ma had become a prominent feature of the landscape and continued apparently uninterruptedly into the pleistocene the antarctic peninsula saw its first mountain glaciation between 45 and 41 ma with major ice sheet expansion commencing at about 34 ma isolated stands of nothofagus forests were still present in low lying areas suggesting that the glaciers were initially wet based but dry based glaciers were established at around 8 ma although temperatures rose briefly during the messinian pliocene transition causing sub antarctic flora to retreat to higher elevations of the transantarctic mountains the present cold polar conditions were finally established by about 3 ma

cenozoic deep sea temperatures and global ice volumes from mg ca in benthic foraminiferal calcite a deep sea temperature record for the past 50 million years has been produced from the magnesium calcium ratio mg ca in benthic foraminiferal calcite the record is strikingly similar in form to the corresponding benthic oxygen isotope 18o record and defines an overall cooling of about 12 c in the deep oceans with four main cooling periods used in conjunction with the benthic 18o record the magnesium temperature record indicates that the first major accumulation of antarctic ice occurred rapidly in the earliest oligocene 34 million years ago and was not accompanied by a decrease in deep sea temperatures