a theoretical treatment of paleointensity determination experiments on rocks containing pseudo single or multi domain magnetic particles a phenomenological theory of thermoremanent magnetization trm is applied to model the possible results of paleointensity determination experiments using the thellier method it is shown that intrinsic curvature of the arai plot for samples containing pseudo single or multi domain particles can be attributed exclusively to the presence of remanences which are unblocked below their blocking temperature thus the thermal demagnetization tail of partial trm ptrm is not a direct measure for a sample s tendency to yield a curved arai plot here it is proposed to use the advancing decay of a ptrm t1 t2 which during heating occurs already below the lower temperature t1 t2 as a more reliable pre selection criterion in addition the effect of an average magnetostatic interaction on the thellier experiment turns out to be negligible an extended thellier method which compares the thermal demagnetization of natural remanent magnetization with that of an artificial trm according to the applied trm theory should result in a perfectly linear modified arai plot even for pseudo single or multi domain samples if no alteration or viscous effects occur

a reversal of the earth s magnetic field recorded in mid miocene lava flows of gran canaria paleointensities 1 an extensive paleointensity study was carried out on an approximately 14 1 myr old reverse to normal transition of the geomagnetic field a total of 188 samples from a volcanic sequence on gran canaria canary islands were subjected to thellier type paleointensity determinations the paleodirectional results of this sequence are reported by leonhardt et al 2002 a modified thellier technique which facilitates the recognition of md tails and the formation of new magnetic remanences with higher blocking temperatures than the actual heating step was used on the majority of the samples we obtained reliable paleointensity results for 35 of the 87 sampled lava flows in general the obtained field intensities are lower than expected for the mid miocene this observation is very likely related to a long term reduction of the field close to transitions very low paleointensities with values 5 t were obtained during an excursion preceding the actual transition and also close to significant changes of the local field directions these are interpreted as nondipolar components becoming dominant for short periods and provoking a rapid change of field directions during the transition 15 successive lava flows recorded similar local field directions corresponding to a cluster of virtual geomagnetic poles close to south america chronologically within this cluster the paleointensity increases from about 9 to 28 t followed by a decrease back to approximately 9 t this variation of paleointensity between lava flows with similar direction indicates independent records of the geomagnetic field and gives strong evidence for a stable transitional state that lasted a significant period

medieval drought in the upper colorado river basin 1 new tree ring records of ring width from remnant preserved wood are analyzed to extend the record of reconstructed annual flows of the colorado river at lee ferry into the medieval climate anomaly when epic droughts are hypothesized from other paleoclimatic evidence to have affected various parts of western north america the most extreme low frequency feature of the new reconstruction covering a d 762 2005 is a hydrologic drought in the mid 1100s the drought is characterized by a decrease of more than 15 in mean annual flow averaged over 25 years and by the absence of high annual flows over a longer period of about six decades the drought is consistent in timing with dry conditions inferred from tree ring data in the great basin and colorado plateau but regional differences in intensity emphasize the importance of basin specific paleoclimatic data in quantifying likely effects of drought on water supply

rare earth major and trace element composition of monterey and dsdp chert and associated host sediment assessing the influence of chemical fractionation during diagenesis abstract chert and associated host sediments from monterey formation and deep sea drilling project dsdp sequences were analyzed in order to assess chemical behavior during diagenesis of biogenic sediments the primary compositional contrast between chert and host sediment is a greater absolute sio2 concentration in chert often with final sio2 98 wt this contrast in sio2 and si al potentially reflects precursor sediment heterogeneity diagenetic chemical fractionation or both sio2 concentrations and si al ratios in chert are far greater than in modern siliceous oozes however and often exceed values in acid cleaned diatom tests compositional contrasts between chert and host sediment are also orders of magnitude greater than between multiple samples of the host sediment calculations based on the initial composition of adjacent host observed porosity reductions from host to chert and a postulated influx of pure sio2 construct a chert composition which is essentially identical to observed sio2 values in chert thus precursor heterogeneity does not seem to be the dominant factor influencing the current chert composition for the key elements of interest in order to assess the extent of chemical fractionation during diagenesis we approximate the precursor composition by analyzing host sediments adjacent to the chert the sio2 concentration contrast seems caused by biogenic sio2 dissolution and transport from the local adjacent host sediment and subsequent sio2 reprecipitation in the chert along with sio2 other elements are often added with respect to al to monterey and dsdp chert during silicification although absolute concentrations decrease the two monterey quartz chert nodules investigated in contrast to the opal ct and quartz chert lenses formed primarily by extreme removal of carbonate and phosphate thereby increasing relative sio2 concentrations dsdp chert formed by both carbonate phosphate dissolution and sio2 addition from the host manganese is fractionated during chert formation resulting in mno al 2 o 3 ratios that no longer record the depositional signal of the precursor sediment ree data indicate only subtle diagenetic fractionation across the rare earth series ce ce values do not change significantly during diagenesis of either monterey or dsdp chert eu eu decreases slightly during formation of dsdp chert la n yb n is affected only minimally as well during formation of one monterey opal ct chert lens ree al ratios show subtle distribution changes at gd and to a lesser extent near nd and ho ree compositional contrasts between diagenetic states of siliceous sediment and chert are of a vastly smaller scale than has been noted between different depositional environments of marine sediment indicating that the paleoenvironmental ree signature is not obscured by diagenetic overprinting

late brunhes polarity excursions mono lake laschamp iceland basin and pringle falls recorded at odp site 919 irminger basin abstract component natural remanent magnetizations derived from u channel and 1 cm3 discrete samples from odp site 919 irminger basin indicate the existence of four intervals of negative inclinations in the upper brunhes chronozone according to the age model based on planktic oxygen isotope data these excursional intervals occur in sediments deposited during the following time intervals 32 34 ka 39 41 ka 180 188 ka and 205 225 ka these time intervals correspond to polarity excursions detected elsewhere known as mono lake laschamp iceland basin and pringle falls the isotope based age model is supported by the normalized remanence paleointensity record that can be correlated to other calibrated paleointensity records for the 0 500 ka interval such as that from odp site 983 for the intervals associated with the mono lake and laschamp excursions virtual geomagnetic poles vgps reach equatorial latitudes and mid southerly latitudes respectively for intervals associated with the iceland basin and pringle falls excursions repeated excursions of vgps to high southerly latitudes indicate rapid directional swings rather than a single short lived polarity reversal the directional instability associated with polarity excursions is not often recorded probably due to smoothing of the sedimentary record by the process of detrital remanence drm acquisition

characterization of the magnetic fabric of rocks abstract an inextensive system of magnetic susceptibility anisotropy factors is suggested which is sufficient in the majority of practical applications for characterizing the magnetic fabric of rocks the system involves three newly devised factors the corrected anisotropy degree the shape factor and the difference shape factor the first of these characterizes the quantity of anisotropy somewhat better than the commonly used anisotropy degree the shape factor characterizes the quality of anisotropy i e the shape of the susceptibility ellipsoid in a convenient way its definition is based on a certain analogy between the anisotropy ellipsoid and the strain ellipsoid the difference shape factor can replace the shape factor when only the differences between the principal susceptibilities are given while the mean susceptibility is unknown

evidence suggesting extremely rapid field variation during a geomagnetic reversal abstract large systematic variations in direction of high temperature remanence as a function of vertical position occur in a basalt flow from the miocene volcanic sequence at steens mountain oregon that has provided a detailed record of a geomagnetic reversal these may have been caused by an impulsive change in the transitional field as the flow cooled during the reversal if this is true the short time required for the flow to cool by conduction and acquire its thermoremanent magnetization implies astonishingly high rates of change of the geomagnetic field at least 3 and 300 gammas per day

the steens mountain oregon geomagnetic polarity transition 2 field intensity variations and discussion of reversal models we carried out an extensive paleointensity study of the 15 5 0 3 m y miocene reversed to normal polarity transition recorded in lava flows from steens mountain south central oregon one hundred eighty five samples from the collection whose paleodirectional study is reported by mankinen et al this issue were chosen for paleointensity investigations because of their low viscosity index high curie point and reversibility or near reversibility of the strong field magnetization curve versus temperature application of the thellier stepwise double heating method was very successful yielding 157 usable paleointensity estimates corresponding to 73 distinct lava flows after grouping successive lava flows that did not differ significantly in direction and intensity we obtained 51 distinguishable complete field vectors of which 10 are reversed 28 are transitional and 13 are normal the record is complex quite unlike that predicted by simple flooding or standing nondipole field models it begins with an estimated several thousand years of reversed polarity with an average intensity of 31 5 8 5 t about one third lower than the expected miocene intensity this difference is interpreted as a long term reduction of the dipole moment prior to the reversal when site directions and intensities are considered truly transitional directions and intensities appear almost at the same time at the beginning of the transition and they disappear simultaneously at the end of the reversal large deviations in declination occur during this approximately 4500 1000 year transition period that are compatible with roughly similar average magnitudes of zonal and nonzonal field components at the site the transitional intensity is generally low with an average of 10 9 4 9 t for directions more than 45 away from the dipole field and a minimum of about 5 t the root mean square of the three field components x y and z are of the same order of magnitude for the transitional field and the historical nondipole field at the site latitude however a field intensity increase to pretransitional values occurs when the field temporarily reaches normal directions which suggests that dipolar structure could have been briefly regenerated during the transition in an aborted attempt to reestablish a stationary field changes in the field vector are progressive but jerky with at least two and possibly three large swings at astonishingly high rates each of those transitional geomagnetic impulses occurs when the field intensity is low less than 10 t and is followed by an interval of directional stasis during which the magnitude of the field increases greatly for the best documented geomagnetic impulse the rapid directional change corresponds to a vectorial intensity change of 6700 2700 nt yr 1 which is about 15 50 times larger than the maximum rate of change of the nondipole field observed during the last centuries the occurrence of geomagnetic impulses seems to support reversal models assuming an increase in the level of turbulence within the liquid core during transitions the record closes with an estimated several thousand years of normal polarity with an average intensity of 46 7 20 1 t agreeing with the expected miocene value however the occurrence of rather large and apparently rapid intensity fluctuations accompanied by little change in direction suggests that the newly reestablished dipole was still somewhat unstable

toward an optimal geomagnetic field intensity determination technique 1 paleointensity determinations based on double heating techniques in field zero field cooling zero field in field cooling and two in field steps with opposite laboratory fields are generally considered to be functionally interchangeable producing equally reliable paleointensity estimates to investigate this premise we have developed a simple mathematical model we find that both the zero field first and in field first methods have a strong angular dependence on the laboratory field parallel orthogonal and anti parallel while the two in field steps method is independent of the direction of the laboratory produced field contrary to common practice each method yields quite different outcomes if the condition of reciprocity of blocking and unblocking temperatures is not met even with marginal 10 tails of partial thermoremanence our calculations suggest that the zero field first method with the laboratory produced field anti parallel to the natural remanence nrm is the most robust paleointensity determination technique when the intensity of the lab induced field is smaller than ancient field however the zero field first method with the laboratory field parallel to the nrm is the optimum approach when the intensity of the lab induced field is larger than the ancient field by far the best approach however is to alternatethe infield zerofield iz steps with zerofield infield zi steps

core flow instabilities and geomagnetic storms during reversals the steens mountain impulsive field variations revisited abstract the origin of the large variations in magnetization direction recorded in two different lava flows at steens mountain oregon is discussed the time constant for lava flow cooling and the amplitude of the variations imply extremely large variation rates for the ambient field four orders of magnitude above the present day secular variation two different mechanisms in the liquid outer core namely turbulence and inertial waves that may produce such variations are investigated energetic considerations indicate that the observed impulsive variations are unlikely to be of internal core origin on the other hand it is shown that during reversals when the dipolar field is reduced by a factor ten magnetic storm perturbations at the earth s surface are enhanced by a factor two with respect to their present amplitude it follows that intense magnetic storms can significantly contribute to ambient field changes during reversals the amplitude of the impulsive variations recorded at steens mountain is shown to be consistent with the effect of a strong magnetic storm occurring during cooling of a flow the direction of the variations is also shown to be consistent with this mechanism if the dipolar field contributes significantly to the internal field during the impulsive change

geochemistry of late permian to early triassic pelagic cherts from southwest japan implications for an oceanic redox change major trace and rare earth element abundances were determined for the southwestern japanese pelagic chert sequence from the early late permian to early early triassic to investigate a redox change in deep sea pelagic environments before and at the permo triassic boundary ptb 251 ma the sequence was primarily deposited in the deep sea of the superocean panthalassa and then was accreted to japan in the middle jurassic a remarkable lithostratigraphic change from red chert to siliceous carbonaceous claystone through gray chert is observed in this sequence constituent elements for these sedimentary rocks are essentially derived from two sources 1 an ancient seawater via biogenic mainly radiolarian hydrothermal and authigenic materials and 2 an average shale like terrigenous material the present measurement demonstrates significant stratigraphic changes of the ce cenon ter value estimated ce anomaly value of non terrigenous component recalculated by subtraction of terrigenous rees from bulk rees and the mn te sample mn te paas value excess mn component other than terrigenous one te terrigenous elements including ti al nb hf th paas post archean average australian shale in the permian chert the ce cenon ter values increase from 0 2 to 1 and the mn te sample mn te paas values decrease up section suggesting that the redox condition of deep sea open ocean changed from oxic to suboxic in an interval of approximately 10 myr the fe te sample fe te paas and mn te sample mn te paas values of carbonaceous claystone near or at the ptb are less than unity suggesting that reductive dissolution of iron and manganese occurred under an anoxic condition this supports the idea of the ptb oceanic anoxia in the superocean panthalassa the present data suggest that the anoxic condition prevailed in the deep sea pelagic regions for an extremely long period much more than 10 myr from the middle late permian to early early triassic this long term development of widespread oceanic anoxia may have been linked to the greatest mass extinction of the phanerozoic

major and trace element geochemistry and os isotopic composition of metalliferous umbers from the late cretaceous japanese accretionary complex 1 metalliferous umbers and red shales occur as unique products of the kula pacific ridge forearc collision in the late cretaceous shimanto supergroup an accretionary complex in japan these umbers are closely associated with greenstones of mid ocean ridge basalt morb origin and are regarded as hydrothermal metalliferous precipitates related to mor type volcanism the umbers and red shales were deposited in the trench area where both terrigenous detritus from land and hydrothermal metalliferous particulates from a mor were supplied simultaneously besides a predominance of fe and mn the umbers exhibit remarkable enrichments in p v co ni zn y mo rare earth elements rees and os relative to continental crustal abundances the x fe x mn p v co ni zn y and rees ratios and paas normalized ree patterns of the umbers are very similar to those of modern hydrothermal plume fallout precipitates deposited on flanks of mor this indicates that the umbers preserve primary geochemical signatures of hydrothermal metalliferous sediments that scavenged seawater derived elements and thus can be used as a proxy for late cretaceous seawater the marine 187os 188os ratios reconstructed from the late maastrichtian umbers range from 0 42 to 0 56 and are very consistent with recent data obtained from the pacific and atlantic pelagic carbonates that record an abrupt decline from 0 55 to 0 4 during the period between 67 0 ma and 65 7 ma

on the possibility of recovering paleo diurnal magnetic variations in transitional lava flows i constraints from thermoremanence modelling for an experimental protocol abstract one of the tenets in paleomagnetism is that perturbations of the ground magnetic field due to magnetospheric or ionospheric current systems are too small to leave a detectable paleomagnetic signature in lava flows as suggested by recent work in paleomagnetosphere modelling however external field perturbations may be significantly enhanced during periods of transitional field behavior particularly when the dipole field axis is strongly tilted towards the equator which then leads to an extremely dynamic magnetosphere on the diurnal time scale even for quiet solar wind conditions we here demonstrate that thin rapidly cooled lava flows 50 cm thick with high magnetic blocking temperatures within 50 100 c below the curie temperature indeed have the potential to record such diurnal perturbations further an experimental protocol is suggested to paleomagnetically extract these perturbations our proof of concept is based on numerical modelling of thermoremanence trm acquisition and simulation of thermal demagnetization surfaces for discrete temperature steps in function of vertical position in the flow the trm direction recovered at a given thermal demagnetization step varies with vertical position in the flow and thereby reveals the wave form of the external field variation characteristically the vertical position of a captured signal changes systematically with unblocking temperature which reflects the oblique orientation of cooling isochrons along which the signals are blocked the signals have their largest amplitudes at the maximum unblocking temperatures but decay away at lower temperatures it is by these systmatic trends that external field perturbations if trapped can be paleomagnetically identified and distinguished from a secondary overprint the experimental procedure requires a sample spacing of 1 cm with 1 cm drill cores and small thermal demagnetization steps 15 c at elevated temperatures

transitional geomagnetic impulse hypothesis geomagnetic fact or rock magnetic artifact a striking feature of the steens mountain oregon geomagnetic polarity reversal is the two maybe three extremely rapid field directional changes 6 degrees per day proposed to account for unusual behavior in direction of remanent magnetization in a single lava flow each of these very fast field changes or impulses is associated with a large directional gap some 90 in the record in order to check the spatial reproducibility of the paleomagnetic signal over distances up to several kilometers we have carried out a paleomagnetic investigation of two new sections b and f in the steens summit region which cover the second and the third directional gap the main result is the description of two new directions which are located between the pre second and post second impulse directions these findings weigh against the hypothesis that the geomagnetic field cause the unusual intraflow fluctuations which now appears to be more ad hoc as an explanation of the paleomagnetic data however the alternative baking hypothesis remains also ad hoc since we have to assume variable rock magnetic properties that we have not yet been able to detect within the flows at the original section steens a and d 1 5 km to the north in addition new results for 22 transitional and normal lava flows in section b are presented that correlate well with earlier results from section a

absolute paleointensity and magnetomineralogical changes determinations of absolute paleointensity are often hampered by magnetomineralogical changes produced within samples of lava flows during successive heatings such changes which directly affect the capacity for a sample to acquire a partial thermoremanent magnetization ptrm are reflected by negative ptrm checks a deviation between the original ptrm and a repeated measurement after heating at a higher temperature because the deviations indicated by the ptrm checks can provide a direct estimate of the effects to the ptrms we suggest that they can be used to correct ptrms the correction method we present requires additional measurements in particular ptrm checks performed after each ptrm and specific diagrams to detect acquisition of chemical remanence performing multiple successive ptrm checks can also provide information on the blocking temperatures of the alteration product these experiments conducted on lava flows from different localities show that the magnetomineralogical changes mainly involved grains with blocking temperatures lower than the last heating step the corrections have been tested on recent and historic lava flows from several localities we have also compared results on samples from the same lava flows that were heated in air and in vacuum the mean paleointensity values were found to lie within less than 10 from the expected field intensity at each site the corrections resulted in the recovery of reliable paleointensity determinations for about twice as many specimens heated in vacuum and 65 additional data for specimens heated in air successive heatings at the same temperature in air are often accompanied by a time dependent oxidation of the natural remanent magnetization which is responsible for paleointensity values lower than the expected field a problem that is not related to the corrections we conclude that corrections can be used with fairly high confidence to the ptrms performed in vacuum and in air

updated streamflow reconstructions for the upper colorado river basin 1 updated proxy reconstructions of water year october september streamflow for four key gauges in the upper colorado river basin were generated using an expanded tree ring network and longer calibration records than in previous efforts reconstructed gauges include the green river at green river utah colorado near cisco utah san juan near bluff utah and colorado at lees ferry arizona the reconstructions explain 72 81 of the variance in the gauge records and results are robust across several reconstruction approaches time series plots as well as results of cross spectral analysis indicate strong spatial coherence in runoff variations across the subbasins the lees ferry reconstruction suggests a higher long term mean than previous reconstructions but strongly supports earlier findings that colorado river allocations were based on one of the wettest periods in the past 5 centuries and that droughts more severe than any 20th to 21st century event occurred in the past

how the geomagnetic field vector reverses polarity a highly detailed record of both the direction and intensity of the earth s magnetic field as it reverses has been obtained from a miocene volcanic sequence the transitional field is low in intensity and is typically non axisymmetric geomagnetic impulses corresponding to astonishingly high rates of change of the field sometimes occur suggesting that liquid velocity within the earth s core increases during geomagnetic reversals

absolute paleointensities and paleodirections of miocene and pliocene lavas from fernando de noronha brazil abstract forty four volcanic units were sampled on the equatorial atlantic island of fernando de noronha brazil twenty seven sites are from the 1 8 3 3 myr old quixaba formation and the others are from the approximately 8 12 myr old remedios formation analyses of paleodirections yielded normal and reverse polarities in both formations with virtual geomagnetic poles vgps and vgp dispersion s f of vgp lat 86 9 vgp long 136 3 s f 11 2 for the quixaba formation and vgp lat 86 8 vgp long 196 7 s f 15 5 for the remedios formation successful paleointensity determinations were obtained for 9 of the 27 sampled units in the quixaba formation a modified thellier method was used that includes checks to monitor alterations and repetition of demagnetization steps to detect multidomain tails of partial thermoremanent magnetizations ptrm and magnetization stabilization processes furthermore the additivity of ptrms was monitored during this modified technique of the thellier experiment these additivity checks provide a quality test for correcting the paleointensity determination for magnetomineralogical changes which occur during laboratory treatment such correction methods were used for analyzing approximately 50 of the determinations and lead to a reduction of the within site scatter the mean paleointensity result of 29 3 t corresponding to a virtual axial dipole moment vadm of 7 5 10 22 a m 2 yields approximately the present day field strength mean values of the paleodirections for volcanic units of reversed and normal polarity are closer to a dipolar field configuration than previously observed today s geomagnetic field in the equatorial atlantic shows a significant dipole anomaly our results indicate that this anomaly was far less pronounced in the geological past

rare earth element variations in mid archean banded iron formations implications for the chemistry of ocean and continent and plate tectonics abstract abundances of major and rare earth elements rees are reported for mid archean 3 3 3 2 gyr sedimentary rocks including banded iron formations bifs and ferruginous siliceous mudstone from the cleaverville area in the pilbara craton western australia geological lithological and geochemical lines of evidence indicate that these sedimentary rocks preserve a continuous record of depositional environments ranging from that typical of mid oceanic spreading centers to convergent plate boundary settings a range of environments most likely caused by plate movements except for the mudstone the ree content of these sedimentary rocks changes gradually from the lower to upper stratigraphic horizons europium anomalies decrease up section eu eu values normalized to nasc change from 3 5 to 1 1 as the ree contents and lree hree ratios increase the striking similarity in these ree signatures of bifs and modern hydrothermal sediments leads us to propose that the bifs were in situ hydrothermal precipitates near a mid ocean ridge significant amounts of terrigenous materials contributed to the siliceous and ferruginous mudstone of the uppermost horizon the observation that the source of the sediments shifted from proximal hydrothermal through distal hydrothermal to terrigenous suggests that plate tectonics dominated by horizontal movement was already operating in the mid archean distal hydrothermal sediments without a eu anomaly when normalized to nasc suggest that mid archean seawater had already been strongly influenced by a riverine flux from an upper continental crust and that this component bore no eu anomaly i e it had a negative eu anomaly when normalized to chondrite in addition to an absence of a eu anomaly mid archean seawater did not have a ce anomaly suggesting less oxic conditions in the mid archean than in the modern ocean

deep sea sediment records of the laschamp geomagnetic field excursion 41 000 calendar years before present 1 we have recovered two new high resolution paleomagnetic records of the laschamp excursion 41 000 calendar years b p from deep sea sediments of the western north atlantic ocean the records document that the laschamp excursion was characterized locally by 1 declination changes of 120 2 inclination changes of more than 140 3 1200 year oscillations in both inclination and declination 4 near 90 out of phase relationships between inclinations and declinations that produced two clockwise loops in directions and virtual geomagnetic poles vgps followed by a counterclockwise loop 5 excursional vgps during both intervals of clockwise looping 6 magnetic field intensities less than 10 of normal that persisted for almost 2000 years 7 marked similarity in excursional directions over 5000 km spatial scale length and 8 secular variation rates comparable to historic field behavior but persisting in sign for hundreds of years all of these features with the exception of anomalously large directional amplitude are consistent with normal magnetic field secular variation comparison of our laschamp excursion paleomagnetic records with other late quaternary excursion records suggests that there is a group of excursions which we term class i which have strikingly similar patterns of field behavior and likely share a common cause as part of the overall core dynamo process three general models of secular variation are described that can qualitatively produce class i excursions on the basis of these observations we conclude that class i excursions epitomized by the laschamp excursion are more closely related to normal secular variation and are not necessarily a prelude to magnetic field reversal

detecting multidomain magnetic grains in thellier palaeointensity experiments the thellier technique is the most commonly used method for absolute palaeointensity studies it is based on thellier s laws stating that partial thermoremanent magnetisations ptrms are independent and additive which however only are true for non interacting single domain sd grains for multidomain md grains individual ptrms are not independent and thellier palaeointensity experiments on rocks with a significant proportion of md grains may therefore lead to erroneous palaeofield estimates by introducing a ptrm tail check in the coe version of the thellier technique j geophys res 72 1967 3247 we present a simple method to detect and discard such rocks the usefulness of the ptrm tail check is exemplified by thellier palaeointensity experiments performed on two palaeomagnetic sample collections with different magnetomineralogy miocene baked sediments from french massif central are shown to be ideal for thellier studies with the remanent magnetisation residing in thermally stable sd grains for palaeocene eocene basaltic lavas from faeroe islands 64 of otherwise acceptable palaeointensity estimates are discarded due to the failure of ptrm tail checks indicating the presence of significant concentrations of md grains 2001 elsevier science b v all rights reserved

dependence of the duration of geomagnetic polarity reversals on site latitude an important constraint on the processes governing the geodynamo the flow in the outer core responsible for generating earth s magnetic field is the duration of geomagnetic polarity reversals that is how long it takes for earth s magnetic field to reverse1 it is generally accepted that earth s magnetic field strength drops to low levels during polarity reversals and the field direction progresses through a 180 change while the field is weak1 the time it takes for this process to happen however remains uncertain with estimates ranging from a few thousand up to 28 000 years here i present an analysis of the available sediment records of the four most recent polarity reversals these records yield an average estimate of about 7 000 years for the time it takes for the directional change to occur the variation about this mean duration is not random but instead varies with site latitude with shorter durations observed at low latitude sites and longer durations observed at mid to high latitude sites such variation of duration with site latitude is predicted by simple geometrical reversal models in which non dipole fields are allowed to persist while the axial dipole decays through zero and then builds in the opposite direction and provides a constraint on numerical dynamo models

on the possibility of recovering palaeo diurnal magnetic variations in transitional lava flows 2 an experimental case study abstract geomagnetic field variations of external origin may be enhanced during periods of transitional field behaviour particularly when the dipole moment is low in which case they are likely to leave a paleomagnetic signature in rapidly cooled lava flows to test this proposition we have resampled en bloc and studied in fine detail a thin transitional aa flow from a mid miocene lava sequence on gran canaria which was paleomagnetically investigated previously leonhardt r soffel h c 2002 a reversal of the earth s magnetic field recorded in mid miocene lava flows of gran canaria paleointensities journal of geophysical research 107 2299 doi 10 1029 2001jb000949 the flow is characterised by high unblocking temperatures an equatorial vgp position and a very low absolute palaeointensity of 2 t two slabs were cut out of the flow and sampled at 1 cm intervals along four vertical profiles running parallel to each other thermal demagnetisation was performed on two profiles using heating steps as small as 15 c at elevated temperatures the high temperature part of the unblocking spectrum was found to be remarkably constant across the flow as was the curie temperature of 540 c and the negligible anisotropy of magnetic susceptibility the exsolution lamallae observed under the microscope point to deuteric high temperature oxidation having occurred prior to the acquisition of the primary thermoremanent magnetisation while the absolute palaeointensity values vary only little with vertical position the magnetisation directions recovered by thermal demagnetisation vary considerably on average by some 20 at 500 c these large variations can be attributed to an overprint by secondary minerals formed by fluid diffusion around vesicles and low temperature oxidation since the secondary magnetisation recorded transitional directions as well the overprint must have occurred soon after emplacement the directional variations typically decrease in amplitude with increasing blocking temperature which is contrary to what would be expected if pronounced diurnal external field variations were trapped in the flow

was the 1970 geomagnetic jerk of internal or external origin annual mean data from worldwide magnetic observatories show that there was a jerk1 step change in the second time derivative in the geomagnetic field which took place over an interval of 2 yr around 1970 if such a short lived phenomenon originated in the earth s core and were still detectable after passing through the mantle to the surface this would imply a much lower conductivity for the lower mantle than had been believed previously here we show by an objective test that most of the jerk has an internal origin

deep sea mud in the pacific ocean as a potential resource for rare earth elements world demand for rare earth elements and the metal yttrium is rapidly increasing an analysis of more than 2 000 seafloor sediment samples suggests that deep sea mud constitutes a highly promising giant resource for these elements

rare earth major and trace elements in chert from the franciscan complex and monterey group california assessing ree sources to fine grained marine sediments abstract rare earth element ree major and trace element analyses of 77 samples from the mesozoic franciscan complex and miocene monterey group of california usa indicate that magnitudes of the ce anomaly ce ce and total ree abundances sree in these rocks are controlled dominantly by a the amount of included metalliferous material b the amount of direct terrigenous input and c the overall burial rate the relative importance of these individual processes varies across an ocean basin in such a way that ree relative fractionations and sree correspond with its depositional environment our conclusions are supported by an extensive review of published ree data from various river coastal open ocean and ridge influenced waters as well as terrigenous pelagic and metalliferous sediment the chert sequences record deposition in spreading ridge open ocean basin and continental margin environments the relative importance of metalliferous and terrigenous influences and the role of scavenging from seawater may be estimated from a sample s inferred depositional distance km from the spreading ridge the major element chemistry and the stratigraphie context the ce ce values are low 0 29 in the vicinity of spreading ridges and trend to successively higher 1 values with decreasing metalliferous and increasing terrigenous influences other ree indicators ree lu n la n eu eu also respond to metalliferous and terrigenous influences near the spreading ridge chert ree appears determined by burial rate while shale ree responds to metalliferous abundance in open ocean and continental margin environments ree is controlled by sediment exposure time and therefore is related inversely to burial rate ree data are consistent with the major elements fe2o3 mno and al2o3 in reflecting the respective metalliferous and terrigenous sources p2o5 and cao do not vary with ce ce in any environment but cao shows a weak negative correlation with ree trace element trends e g v cr cu ge si rb sr y th u in general can similarly be accounted for in the context of depositional position relative to metalliferous and terrigenous inputs rees in chert appear less affected by post depositional processes than either major or trace elements indicating that rees are better tools for paleoceanographic or tectonic reconstructions that are based on chert chemistry this work complements recent efforts to elucidate the factors determining large scale ree distributions in marine sediments and has direct bearing on previous attempts to use the ce anomaly in older rocks and sediments as a recorder of secular variations and anoxic events in the overlying water column

revisiting the initial sites of geomagnetic field impulses during the steens mountain polarity reversal summary we present a new palaeomagnetic investigation of the two sites from the steens mountain oregon volcanic record of a miocene polarity reversal which were supposed to record very fast changes of the geomagnetic field or impulses mankinen et al 1985 prevot et al 1985a b approximately 130 cores were first drilled from the two initial sites belonging to sections a and b in order to obtain at least one detailed and complete vertical sampling of each lava flow thermal analyses of natural remanent magnetization complemented by some alternating field treatments low field thermo magnetic curves microscopic observations and electron probe analyses of key magnetic phases lead us to somewhat different conclusions for the first and the second impulses at site b first impulse we find that the dependence of the remanence direction on the sample vertical position in flow b51 does not imply a directional field change during flow cooling but is better explained by a thermochemical overprinting due to the overlying b50 flow however this conclusion does not challenge the existence of the first impulse because this field change seems to be recorded some 25 m away in flow b51 coe prevot 1989 at a place where it is thick enough for this record not to have been erased by the baking due to b50 regarding the second impulse restudied at site a our new findings are more comprehensively explained by a change in the field direction during cooling of flow a41 2 than by some overprinting using a simple model of flow cooling the angular rate of change of the field is estimated to have been of the order of 2 3 or 250 350 nt per day during the impulse this figure is similar to that previously obtained from site d some 250 m away however the directional paths describing the field change are somewhat different at the two sites new investigations are planned to try to understand the origin of this discrepancy

geomagnetic field behavior during the iceland basin and laschamp geomagnetic excursions a simple transitional field geometry we present four new records of the iceland basin excursion ibe and five new records of the laschamp excursion le obtained from rapidly deposited marine sediments in the north atlantic ocean the nordic seas the gulf of mexico the south china sea and the southern indian ocean marked minima in relative paleointensity correspond with the paleomagnetic directional changes associated with all of the excursion records the virtual geomagnetic pole vgp paths of the four ibe records are all similar the vgps move southward over europe and africa reaching the southern hemisphere three reach antarctica and then move to more eastern longitudes before returning northward over australia and east asia describing a large counterclockwise loop the same vgp pattern is observed in other published records the vgp paths observed for the le are similar to those of the ibe however they loop clockwise instead of counterclockwise despite the different sense of looping the marked similarity among the paths for the two excursions suggests that a similar relatively simple geometry dominated the transitional field during both the ibe and the le similar dynamo mechanisms must therefore have been active in the earth s core for both excursions the duration of the excursions is estimated at 2 000 years which supports the suggestion that a difference exists between the mechanisms for excursions and reversals however the coincidence of the longitudinal bands for vgps associated with excursions compared to some reversal paths could also indicate an inherent link between the mechanisms for reversals and excursions

paleointensity variations across the last geomagnetic reversal at la palma canary islands spain a detailed volcanic record of absolute paleointensity has been obtained for the period encompassing the last geomagnetic reversal from a succession of 69 distinct lava flows in two adjacent sections on the island of la palma the correlation between the two sections relies on the positions of the brunhes matuyama boundary and on the flow chronology obtained by a refined potassium argon k ar dating technique several pretransitional flows exhibit very shallow paleomagetic inclinations but they cannot be considered as really transitional paleointensity experiments conducted on 288 specimens provided 168 successful determinations 14 were obtained after correction for 50 lava flows that were considered to represent 45 distinct units the evolution of the paleofield intensity can be constructed by assuming uniform extrusion rates between three dated lava flows the period preceding the transition is characterized by large fluctuations with typical peak to peak amplitudes between 20 and 40 t which decrease down to 7 t prior to the transition the 100 kyr long interval following the reversal is associated with field intensities as high as 60 t and depict a strong and rapid restoration of the dipole field the virtual dipole moments vdms have been compared with sedimentary vdms generated from the record of relative paleointensity from ocean drilling program site 851 to which have been added non dipole components similar to the present geomagnetic field a reasonable fit can be made between the two curves which implies variations in the eruption rates but not incompatible with the uncertainties in the k ar age determinations thus these results can support but do not fully demonstrate the existence of asymmerical saw toothed variations in field intensity

paleomagnetic reconstruction of the global geomagnetic field evolution during the matuyama brunhes transition iterative bayesian inversion and independent verification abstract the earth s magnetic field changed its polarity from the last reversed into today s normal state approximately 780 000 years ago while before and after this so called matuyama brunhes reversal the earth magnetic field was essentially an axial dipole the details of its transitional structure are still largely unknown here a bayesian inversion method is developed to reconstruct the spherical harmonic expansion of this transitional field from paleomagnetic data this is achieved by minimizing the total variational power at the core mantle boundary during the transition under paleomagnetic constraints the validity of the inversion technique is proved in two ways first by inverting synthetic data sets from a modeled reversal here it is possible to reliably reconstruct the gauss coefficients even from noisy records second by iteratively combining four geographically distributed high quality paleomagnetic records of the matuyama brunhes reversal into a single geometric reversal scenario without assuming an a priori common age model the obtained spatio temporal reversal scenario successfully predicts most independent matuyama brunhes transitional records therefore the obtained global reconstruction based on paleomagnetic data invites to compare the inferred transitional field structure with results from numerical geodynamo models regarding the morphology of the transitional field it is found that radial magnetic flux patches form at the equator and move polewards during the transition our model indicates an increase of non dipolar energy prior to the last reversal and a non dipolar dominance during the transition thus the character and information of surface geomagnetic field records is strongly site dependent the reconstruction also offers new answers to the question of existence of preferred longitudinal bands during the transition and to the problem of reversal duration different types of directional variations of the surface geomagnetic field continuous or abrupt are found during the transition two preferred longitudinal bands along the americas and east asia are not predicted for uniformly distributed sampling locations on the globe similar to geodynamo models with cmb heatflux derived from present day lower mantle heterogeneities a preference of transitional vgps for the pacific hemisphere is found the paleomagnetic duration of reversals shows not only a latitudinal but also a longitudinal variation even the paleomagnetically determined age of the reversal varies significantly between different sites on the globe the described bayesian inversion technique can easily be applied to other high quality full vector reversal records also its extension to inversion of secular variation and excursion data is straightforward

new evidence for extraordinarily rapid change of the geomagnetic field during a reversal palaeomagnetic results from lava flows recording a geomagnetic polarity reversal at steens mountain oregon suggest the occurrence of brief episodes of astonishingly rapid field change of six degrees per day the evidence is large systematic variations in the direction of remanent magnetization as a function of the temperature of thermal demagnetization and of vertical position within a single flow which are most simply explained by the hypothesis that the field was changing direction as the flow cooled

geochemistry of mineralization with exchangeable rey in the weathering crusts of granitic rocks in south china abstract mineralization with exchangeable rare earth element ree and yttrium mex rey has been recognized in the weathering profiles in south china since the early 1970 s this type of rey mineralization occurs in weathering profiles of parent rocks ranging in composition from granite to acidic volcanic rocks and lamprophyre the majority of the known resources occurring in the weathering profiles of granitic rocks total resources of this type of rey amount to millions tons of rare earth oxides and therefore represent one of the most important types of rare earth resources in china particularly for heavy rare earth elements hree and yttrium accumulation of rey in the weathering profiles of granitic rocks is strongly controlled by the resistance to weathering of the principal rey bearing accessory minerals in the parent rocks only a limited proportion of total rey 4 and na etc in electrolyte solutions and can be removed by complexing agents such as edta are commonly the major form of ree occurrence in the b horizon cerium is enriched in the top layer a horizon and depleted in the subsurface horizons of the weathering profiles most likely due to the oxidation of ce iii to ce iv followed by cerianite formation or absorption onto clays and or fe and al oxyhydroxides