assessing the reliability of magnesium in foraminiferal calcite as a proxy for water mass temperatures though many studies on the mg contents in the calcitic tests of foraminifers exist the processes controlling its uptake are still a matter of debate laboratory cultures offer an excellent opportunity to reveal these mechanisms the mg concentrations within single chambers of the planktic foraminifer globigerinoides sacculifer brady maintained under controlled laboratory conditions were measured 1 at variable temperatures 19 5 29 5 c and constant salinity and 2 at variable salinity 22 45 and constant temperature the experimental results suggest that under natural conditions temperature is the leading mechanism controlling the mg ca ratio temperature and magnesium are related proportionally a temperature increase of ca 10 c gives rise to an increase of the magnesium concentrations of ca 130 drastic unnatural salinity changes dominate the effects of temperature a 110 change in the mg ca ratio was observed when salinity was elevated or reduced by more than ca 10 specimens which underwent gametogenesis reveal significantly higher mg concentrations than specimens that did not release gametes partition coefficients for mg in foraminiferal calcite are orders of magnitude lower than values from inorganically precipitated calcite when comparing observed mg ca ratios of foraminiferal tests with predicted mg ca ratios calculated according to empirical equations it becomes evident that foraminiferal tests are undersaturated with respect to mg for the water temperature they have experienced apparently foraminifers are capable of controlling their mg concentration the physiological processes presumably responsible for such depressed mg ca ratios appear to be temperature controlled as deduced from the close relationship of the observed mg ca ratios and water temperature this study demonstrates that variations in temperature and salinity are definitely reflected in the mg content of foraminiferal tests magnesium may thus serve as a paleo proxy for past surface water temperatures as long as postdepositional changes and salinity variations are of subordinate importance or can be excluded

a study of cleaning procedures used for foraminiferal mg ca paleothermometry the various cleaning steps required for preparation of foraminiferal samples for mg ca and sr ca analysis are evaluated for their relative importance and effects on measured elemental ratios it is shown that the removal of silicate contamination is the most important step for the measurement of mg ca ratios in an example bulk sample mg ca decreases from 10 5 to 2 5 mmol mol 1 during clay removal oxidation of organic material causes a lowering of sample mg ca in the order of 10 or approximately 1 c when converted to temperature use of dilute acid leaching to remove adsorbed contaminants causes partial dissolution of the sample carbonate and a corresponding decrease in mg ca reductive treatment also causes dissolution of the sample and a decrease in the mg ca ratio of up to 10 15 sample preparation for sr ca analysis does not require the same degree of rigor as is necessary for mg ca work the within run reproducibility of the method described here for g ruber in a core top sample from the arabian sea was 1 8 mean sample ratio was 4 72 mmol mol 1 when converted to temperature this becomes 28 0 2 c the equivalent result for sr ca was 0 5 mean ratio 1 44 mmol mol 1

a simple evaluation of cleaning procedures on fossil benthic foraminiferal mg ca 1 recent studies suggest that benthic foraminiferal mg ca may be useful in reconstructing deep water temperature changes during the quaternary and on longer timescales rosenthal et al 1997 lear et al 2000 martin et al 2002 because changes in deep water temperature may be small sample preparation could play an important role in reconstructing accurate temperatures from shell mg ca a simple examination of changes in measured shell chemistry of benthic foraminifera from two intervals subjected to increasingly rigorous cleaning reveals that fossil benthic foraminiferal samples cleaned by oxidation yield lower mg ca values than samples only rinsed and weak acid leached reductive cleaning further lowered the shell mg ca of one of the two benthic species examined lower mg ca values following oxidation and reduction appear to reflect removal of contaminant mg associated with remnant organic matter and adsorbed phases

atlantic meridional overturning circulation and the southern hemisphere supergyre 1 the ocean s role in climate manifests itself through its high heat capacity its own rich internal dynamics and its ability to transport vast quantities of heat and freshwater of particular interest is the global ocean circulation associated with the atlantic meridional overturning amoc because observations are sparse the detailed global structure of the amoc remains poorly understood particularly the pathways along which water returns to the atlantic to compensate the export of north atlantic deep water nadw here we provide the first quantitative 3 dimensional global view of the amoc using a lagrangian reconstruction which integrates hundred of thousands water particle trajectories in an ocean model the resulting pattern elucidates the role of the wind in structuring the pathways of the amoc in particular the lagrangian analysis reveals a strong link with the three subtropical gyres of the southern hemisphere sh which merge into a supergyre spanning the three ocean basins the coupling between the upper ocean wind driven circulation and the overturning in the model suggests that changes in the sh winds can alter the pathways of the amoc and therefore the water properties and the associated heat and freshwater transports

tropical sea surface temperatures during the last glacial period a view based on alkenones in indian ocean sediments abstract the quantification of tropical temperatures during the last glacial cycle 0 150 kyr bp is a controversial issue since different proxies seem to provide conflicting informations to obtain a complementary point of view we use the alkenone method to estimate sea surface temperatures and focus our work on deep sea sediments recovered from the tropical indian ocean we present alkenone data obtained in two cores which cover in detail the last deglaciation and in about twenty cores distributed between 20 s and 20 n that were chosen to evaluate the temperature contrast of the last glacial interglacial transition our results indicate that indian ocean tropical temperatures remained an average within 1 5 2 5 c of their present values during the last glaciation at 10 n the last deglaciation is characterized by two warming steps which is similar to the classical deglacial chronology observed in the north atlantic area at 20 s the deglacial warming occurred at ca 15 cal kyr bp lagging significantly 5 4 kyr behind the antarctic warming but in phase with northern hemisphere time series

a mid holocene thermal maximum at the end of the african humid period the termination of the african humid period ahp about 5 thousand years ago ka was the most dramatic climate shift in northern and equatorial africa since the end of the pleistocene based on tex86 paleotemperature data from lake turkana kenya we show that a temperature shift of 2 4 1c occurred over the two millennia spanning the end of the ahp with the warmest conditions occurring at 5 ka we note a similar shift though of a smaller magnitude in other east african temperature records from lakes malawi and tanganyika as well as mt kilimanjaro additionally we document the temperature history for the last 220 years from lake turkana that indicates the thermal anomaly at 5 ka was warmer than the present day lake turkana temperatures and on par with modern temperatures of lakes tanganyika and malawi we suggest that the thermal response at the end of the ahp may be linked to local insolation during september november when local air temperature rises to an annual maximum over lakes malawi and tanganyika and a secondary maximum over lake turkana and mt kilimanjaro september november insolation peaked at 5 ka and likely caused air and water temperatures in the region to rise to maxima at that time

interhemispheric synchrony of the last deglaciation inferred from alkenone palaeothermometry the relative timings of the last deglacial warming in the southern and northern hemispheres are not well constrained but are a crucial component in understanding the mechanisms of deglaciation1 a clearer picture of the degree of interhemispheric synchrony has been obscured by a dearth of high resolution temperature records that can be tied to the absolute calendar timescale moreover the quantification of tropical temperatures during the last glacial cycle is controversial2 8 here we apply the alkenone method of sea surface temperature reconstruction9 10 to several high resolution sediment cores recovered from the tropical indian ocean between 20 n and 20 s the inferred initial sea surface temperature warming 15 000 calendar years ago at 20 s is in phase with northern hemisphere sea this study and air11 temperature changes but lags antarctic warming12 14 by several millennia this finding along with the results of recent modelling studies15 16 provides strong support for the idea that changes in the ocean s global thermohaline circulation were not the only cause of interhemispheric climate teleconnection during the last deglaciation

oscillations in the southern extent of the indo pacific warm pool during the mid holocene the indo pacific warm pool ipwp is thought to play a key role in the propagation and amplification of climate changes through its influence on the global distribution of heat and water vapour however little is known about past changes in the size and position of the ipwp in this study we use a total of 48 modern and fossil coral records from the mentawai islands sumatra indonesia and muschu koil islands papua new guinea to reconstruct oscillations in the extent of the ipwp since the mid holocene we show that reliable estimates of mean sea surface temperature sst can be obtained from fossil corals by using low resolution sr ca analysis of a suite of corals to overcome the large uncertainties associated with mean sr ca sst estimates from individual coral colonies the coral records indicate that the southeastern and southwestern margins of the ipwp were cooler than at present between similar to 5500 and 4300 years bp similar to 1 2 degrees c 0 3 degrees c and were similarly cool before similar to 6800 years bp this mid holocene cooling was punctuated by an abrupt short lived shift to mean ssts that were warmer than at present between similar to 6600 and 6300 years bp similar to 1 3 degrees c 0 3 degrees c while similarly warm conditions may have also existed after similar to 4300 years bp we suggest that mid holocene cooling at our study sites was related to contractions of the southeastern and southwestern margins of the ipwp associated with the more northerly position of the inter tropical convergence zone itcz that accompanied mid holocene strengthening of the asian summer monsoon conversely intervals of abrupt warming appear to correspond with widespread episodes of monsoon weakening and accompanying southward migrations of the itcz that caused the ipwp to expand beyond our coral sites intervals of a strengthened asian monsoon and cooling in the southwestern ipwp during the mid holocene appear to correspond with a more positive indian ocean dipole iod like mean configuration across the tropical indian ocean suggesting that the asian monsoon iod interaction that exists at interannual time scales also persists over centennial to millennial scales associated mean changes in the pacific enso modes may have also occurred during the mid holocene the dynamic and inter connected behaviour of the ipwp with tropical climate systems during the mid holocene highlights the fundamental importance of the warm pool region for understanding climate change throughout the tropics and beyond c 2009 elsevier ltd all rights reserved

multidecadal and multicentennial variability of the meridional overturning circulation the variability of the meridional overturning circulation moc simulated in a multimillenial control integration of the kiel climate model kcm displays enhanced variability relative to the red background at decadal and centennial timescales the multidecadal variability is the model s version of the atlantic multidecadal variability amv often referred to as atlantic multidecadal oscillation amo while multidecadal variability originates in the north atlantic multicentennial variability is driven in the southern ocean both multidecadal and multicentennial variability are associated with considerable changes in sea ice extent this may be important to understand the different evolution of sea ice cover in the northern and southern hemisphere during the most recent decades with a strong decline observed in the north and almost no trend in the south

isotopic composition of waters from ethiopia and kenya insights into moisture sources for eastern africa 1 oxygen and deuterium isotopic values of meteoric waters from ethiopia are unusually high when compared to waters from other high elevation settings in africa and worldwide these high values are well documented however the climatic processes responsible for the isotopic anomalies in ethiopian waters have not been thoroughly investigated we use isotopic data from waters and remote data products to demonstrate how different moisture sources affect the distribution of stable isotopes in waters from eastern africa oxygen and deuterium stable isotopic data from 349 surface and near surface groundwaters indicate isotopic distinctions between waters in ethiopia and kenya and confirm the anomalous nature of ethiopian waters remote data products from the tropical rainfall measuring mission trmm and national centers for environmental prediction ncep reanalysis project show strong westerly and southwesterly components to low level winds during precipitation events in western and central ethiopia this is in contrast to the easterly and southeasterly winds that bring rainfall to kenya and southeastern ethiopia large regions of high equivalent potential temperatures e at low levels over the sudd and the congo basin demonstrate the potential for these areas as sources of moisture and convective instability the combination of wind direction data from ethiopia and e distribution in africa indicates that transpired moisture from the sudd and the congo basin is likely responsible for the high isotopic values of rainfall in ethiopia

forcing of wet phases in southeast africa over the past 17 000 years a continuous record of hydrologic variability for the past 17 000 years at the mouth of the zambezi river shows that hydrologic conditions in southeast africa were controlled by variations in local insolation and migrations of the intertropical convergence zone rather than by indian ocean temperature records of hydroclimatological variability in southern africa since the last glacial maximum have produced a conflicting picture of the relative influences of events in the remote northern hemisphere and the more local indian ocean this paper presents a continuous record of hydrological variability for the past 17 000 years from marine sediment core drilled off the mouth of the zambezi river the record shows that hydrological conditions in the region were influenced by variations in local insolation and migrations of the intertropical convergence zone which were probably driven by events in the northern hemisphere rather than the indian ocean intense debate persists about the climatic mechanisms governing hydrologic changes in tropical and subtropical southeast africa since the last glacial maximum about 20 000 years ago in particular the relative importance of atmospheric and oceanic processes is not firmly established1 2 3 4 5 southward shifts of the intertropical convergence zone itcz driven by high latitude climate changes have been suggested as a primary forcing2 3 whereas other studies infer a predominant influence of indian ocean sea surface temperatures on regional rainfall changes4 5 to address this question a continuous record representing an integrated signal of regional climate variability is required but has until now been missing here we show that remote atmospheric forcing by cold events in the northern high latitudes appears to have been the main driver of hydro climatology in southeast africa during rapid climate changes over the past 17 000 years our results are based on a reconstruction of precipitation and river discharge changes as recorded in a marine sediment core off the mouth of the zambezi river near the southern boundary of the modern seasonal itcz migration indian ocean sea surface temperatures did not exert a primary control over southeast african hydrologic variability instead phases of high precipitation and terrestrial discharge occurred when the itcz was forced southwards during northern hemisphere cold events such as heinrich stadial 1 around 16 000 years ago and the younger dryas around 12 000 years ago or when local summer insolation was high in the late holocene that is during the past 4 000 years

holocene tropical western indian ocean sea surface temperatures in covariation with climatic changes in the indonesian region the sea surface temperature sst of the tropical indian ocean is a major component of global climate teleconnections while the holocene sst history is documented for regions affected by the indian and arabian monsoons data from the near equatorial western indian ocean are sparse reconstructing past zonal and meridional sst gradients requires additional information on past temperatures from the western boundary current region we present a unique record of holocene sst and thermocline depth variations in the tropical western indian ocean as documented in foraminiferal mg ca ratios and 18o from a sediment core off northern tanzania for mg ca and thermocline 18o most variance is concentrated in the centennial to bicentennial periodicity band on the millennial time scale an early to mid holocene 7 8 5 6 ka warm phase is followed by a temperature drop by up to 2 c leading to a mid holocene cool interval 5 6 4 2 ka the shift is accompanied by an initial reduction in the difference between surface and thermocline foraminiferal 18o consistent with the thickening of the mixed layer and suggestions of a strengthened walker circulation however we cannot confirm the expected enhanced zonal sst gradient as the cooling of similar magnitude had previously been found in ssts from the upwelling region off sumatra and in flores air temperatures the sst pattern probably reflects the tropical indian ocean expression of a large scale climate anomaly rather than a positive indian ocean dipole like mean state

progress in paleosalinity overview and presentation of a new approach this paper concerns the use of stable oxygen isotope ratios 18o and stable hydrogen isotope ratios 2h or d to derive paleosalinity first i evaluate the potential and limitations of existing methods based on 18o and d separately next i propose a new theoretical framework for the combined use of 18o and d to constrain the impact of the hydrological cycle on the surface waters and to thus characterize changes in surface water salinity this new method is accompanied by an error propagation exercise to demonstrate its limitations and areas of potential improvement a feasible strategy is outlined for achieving reconstructions of paleosalinity change with an uncertainty of 1 practical salinity unit or less with the newly proposed method especially in regions with high deuterium excess values

vertical distribution and isotopic fractionation of living planktonic foraminifera from the panama basin a model1 2 which explains the vertical and seasonal distribution of planktonic foraminifera was developed using data from the western north atlantic and is comprised of three tenets 1 the conditions in the photic zone upper 80 100 m exclusively dictate planktonic foraminifera species composition and abundance throughout the water column 2 species are vertically stratified within the photic zone according to their temperature preference depth distribution according to temperature preference has been proposed by several authors3 based on isotope analyses of sediments due to seasonal temperature variations seasonal variations in the 18o composition of seawater and species specific isotope fractionation rigorous proof of this hypothesis cannot be provided from sediment analyses alone 3 the chlorophyll maximum is a major food source zone which is preferentially exploited by foraminifera our data from the panama basin which are presented here are confirmation of this model the panama basin in the eastern equatorial pacific which has a shallow and steep thermocline was sampled for living planktonic foraminifera a multiple opening closing net and environmental sensing system mocness 4 was used to collect 13 sets of eight vertically stratified oblique samples we report here the quantitative distribution and stable isotopic composition of planktonic foraminifera from four mocness tows taken over 5 days during august 1979 rv knorr cruise 73 at 5 20 n 8 50 w each tow consisted of eight samples which integrated 12 5 m intervals from 0 to 100 m for moc 126 25 m intervals from 0 to 200 m for moc 127 100 150 m intervals from 0 to 1 000 m on moc 128 and 250 m intervals from 0 to 2 000 m on moc 131

on the fidelity of shell derived δ18oseawater estimates article i nfo 18 oseawater a robustproxyforsurfacesalinity we assessthe fidelity of shell derived 18 oseawater estimates for the surface dwelling foraminifer globigerinoides ruber white using an atlantic meridional coretop transect spanning basin scale temperature and salinity gradients shell derived and observed 18 oseawater values are well correlated r 2 0 77 but a large systematic bias is observed shell mg ca ratios are significantly elevated above values expected from observed and isotopic calcification temperatures in the saline subtropical gyres of both hemispheres this temperature independent shell mg ca ratio variability termed excess mg ca i s highly correlated with surface salinity r 2 0 77 and the observed salinity dependence 27 4 is much higher than indicated by culture studies 6 2 our coretop data are used to develop new atlantic basin temperature and salinity calibration equations that are accurate 1 1 c and 0 20 respectively precise r 2 0 82 and 0 81 respectively and verifiable using previously published data these results are valid for the relatively high salinities of the subtropical atlantic 35 5 37 3 we discover that inclusion of other published data from lower salinity regions b35 indicates little or no excess mg ca taken together these results point to a strongly non linear positive salinity effect on shell mg ca ratios that significantly affects the accuracy of sst and 18

glacial interglacial variability in atlantic meridional overturning circulation and thermocline adjustments in the tropical north atlantic article i nfo k 37 tex86 atlantic meridional overturning circulation thermocline changes in the strength of atlantic meridional overturning circulation amoc are known to have profound impacts on global climate coupled modelling studies have suggested that on annual to multi decadal time scales a slowdown of amoc causes a deepening of the thermocline in the tropical atlantic however this process has been poorly constrained by sedimentary geochemical records here we reconstruct surface u k 37 index and thermocline tex h 86 water temperatures from the guinea plateau margin eastern tropical atlantic over the last two glacial interglacial cycles 192 kyr these paleotemperature records show that periods of reduced amoc as indicated by the 13 c benthic foraminiferal record from the same core coincide with a reduction in the near surface vertical temperature gradient demonstrating for the first time that amoc induced tropical atlantic thermocline adjustment exists on longer millennial time scales modelling results support the interpretation of the geochemical records and show that thermocline adjustment is particularly pronounced in the eastern tropical atlantic thus variations in amoc strength appear to be an important driver of the thermocline structure in the tropical atlantic from annual to multi millennial time scales

modes of eastern equatorial pacific thermocline variability implications for enso dynamics over the last glacial period 1 changes in el nino southern oscillation enso variability are difficult to extract from paleoceanographic reconstructions because they are superimposed on changes in seasonal variability that modulate the first order climate signal here we address this problem by reconstructing thermocline structure from a marine sediment core retrieved from the eastern equatorial pacific at the core location changes in hydrologic parameters within the thermocline are linked to enso activity with a reduced influence of seasonal variability compared to surface waters we performed repeated isotopic analyses 18o on single specimens of the thermocline dwelling planktonic foraminifera neogloboquadrina dutertrei at several targeted time periods over the last 50 ka to extract the total thermocline variance a parameter supposed to reveal changes in enso no fundamental changes in amplitude and frequency of the events were detected despite differences in climatic background however our data suggest that long term variations in the thermocline variability occurred over the last 50 ka with the highest and lowest enso activities occurring during the last glacial period and the last glacial maximum respectively

high resolution sea surface reconstructions off cape hatteras over the last 10 ka 1 this study presents high resolution foraminiferal based sea surface temperature sea surface salinity and upper water column stratification reconstructions off cape hatteras a region sensitive to atmospheric and thermohaline circulation changes associated with the gulf stream we focus on the last 10 000 years 10 ka to study the surface hydrology changes under our current climate conditions and discuss the centennial to millennial time scale variability we observed opposite evolutions between the conditions off cape hatteras and those south of iceland known today for the north atlantic oscillation pattern we interpret the temperature and salinity changes in both regions as co variation of activities of the subtropical and subpolar gyres around 8 3 ka and 5 2 3 5 ka positive salinity anomalies are reconstructed off cape hatteras we demonstrate for the 5 2 3 5 ka period that the salinity increase was caused by the cessation of the low salinity surface flow coming from the north a northward displacement of the gulf stream blocking the southbound low salinity flow concomitant to a reduced meridional overturning circulation is the most likely scenario finally wavelet transform analysis revealed a 1000 year period pacing the 18o signal over the early holocene this 1000 year frequency band is significantly coherent with the 1000 year frequency band of total solar irradiance tsi between 9 5 ka and 7 ka and both signals are in phase over the rest of the studied period

multispecies approach to reconstructing eastern equatorial pacific thermocline hydrography during the past 360 kyr 1 stable isotope data from eastern equatorial pacific eep core tr163 19 2 15 n 90 57 w 2348 m are presented for the surface dwelling foraminifers globigerinoides ruber and g sacculifer and thermocline dwelling globorotalia menardii and neogloboquadrina dutertrei using species specific normalization factors derived from experimental and plankton tow data we reconstruct a 360 kyr record of water column hydrography across the past three glacial cycles we demonstrate that g ruber maintains a mixed layer habitat throughout the entire record while g sacculifer records a mixture of thermocline and mixed layer conditions and g menardii and n dutertrei record thermocline properties we conclude that g sacculifer is not appropriate for paleoceanographic applications in regions with steep vertical hydrographic gradients results suggest that this region of the eep had a thicker mixed layer and deeper 13cdic boundary between the surface and equatorial undercurrent during the last two glacial periods a shift in n dutertrei and g sacculifer geochemistry prior to 185 kyr suggests water column structure and chemocline gradients changed possibly due to a shift in the position of the undercurrent relative to this site the timing and magnitude of glacial interglacial 13c variations between species indicates that near surface carbon chemistry is controlled by changes in productivity atmospheric circulation and advected intermediate water sources north of the antarctic polar front these results demonstrate that when properly calibrated for species differences multispecies geochemical data sets can be invaluable for reconstructing water column structure and properties in the past

controls on shell mg ca and sr ca in cultured planktonic foraminiferan globigerinoides ruber white mg ca and sr ca ratios were determined on a single species of planktonic foraminiferan globigerinoides ruber white collected from the gulf of eilat and cultured in seawater at five different salinities 32 to 44 five temperatures 18 to 30 c and four ph values 7 9 to 8 4 the mg ca temperature calibration of cultured g ruber with an exponential slope of 8 3 c agrees well with previously published calibrations from core tops and sediment traps however the dependence of mg ca on salinity with an exponential slope of 5 3 psu is also significant and should be included in the calibration equation with this purpose we calculated a calibration equation for g ruber dependent on both temperature and salinity within the 95 confidence limits mg ca mmol mol exp 0 06 0 02 s psu 0 08 0 02 t c 2 8 1 0 r2 0 95 the influence of ph on mg ca ratios is negligible at ambient seawater ph 8 1 to 8 3 however we observe a dominating ph control on shell mg ca when the ph of seawater is lower than 8 0 sr ca in g ruber shows a significant positive correlation with average growth rate presumably part of the variability in shell sr ca in the geological record is linked to changes in growth rates of foraminifera as a response to changing environmental conditions

structure and origin of holocene cold events abstract the present interglacial the holocene spans the period of the last 11 700 years it has sustained the growth and development of modern society the millennial scale decreasing solar insolation in the northern hemisphere summer lead to northern hemisphere cooling a southern shift of the intertropical convergence zone itcz and a weakening of the northern hemisphere summer monsoon systems on the multidecadal to multicentury scale periods of more stable and warmer climate were interrupted by several cold relapses at least in the northern hemisphere extra tropical area based on carefully selected 10 000 year long time series of temperature and humidity precipitation as well as reconstructions of glacier advances the spatiotemporal pattern of six cold relapses during the last 10 000 years was analysed and presented in form of a holocene climate atlas hoclat see http www oeschger unibe ch research projects holocene atlas a clear cyclicity was not found and the spatiotemporal variability of temperature and humidity precipitation during the six specific cold events 8200 6300 4700 2700 1550 and 550 years bp was very high different dynamical processes such as meltwater flux into the north atlantic low solar activity explosive volcanic eruptions and fluctuations of the thermohaline circulation likely played a major role in addition internal dynamics in the north atlantic and pacific area including their complex interaction were likely involved

holocene and eemian sea surface temperature trends as revealed by alkenone and mg ca paleothermometry in this study we review a global set of alkenone and foraminiferal mg ca derived sea surface temperatures sst records from the holocene and compare them with a suite of published eemian sst records based on the same approach for the holocene the alkenone sst records belong to the actualized ghost database kim j h schneider r r 2004 ghost global database for alkenone derived holocene sea surface temperature records available from http www pangaea de projects ghost while the mg ca derived sst database represents a new compilation the actualized ghost database not only confirms the sst changes previously described but also documents the holocene temperature evolution in new oceanic regions such as the northwestern atlantic the eastern equatorial pacific and the southern ocean a comparison of holocene sst records stemming front the two commonly applied paleothermometry methods reveals contrasting sometimes divergent sst evolution particularly at low latitudes where sst records are abundant enough to infer systematic discrepancies at a regional scale opposite sst trends at particular locations could be explained by out of phase trends in seasonal insolation during the holocene this hypothesis assumes that a strong contrast in the ecological responses of coccolithophores and planktonic foraminifera to winter and summer oceanographic conditions is the ultimate reason for seasonal differences in the origin of the temperature signal provided by these organisms as a simple test for this hypothesis eemian sst records are considered because the holocene and eemian time periods experienced comparable changes in orbital configurations but had a higher magnitude in insolation variance during the eemian for several regions sst changes during both interglacials were of a similar sign but with higher magnitudes during the eemian as compared to the holocene this observation suggests that the ecological mechanism shaping sst trends during the holocene was comparable during the penultimate interglacial period although this ecology hypothesis fails to explain all of the available results we argue that any other mechanism would fail to satisfactorily explain the observed sst discrepancies among proxies c 2010 elsevier ltd all rights reserved

coupled sea surface temperature seawater δ18o reconstructions in the arabian sea at the millennial scale for the last 35 ka two sediment cores from the western 905 10 46 9 n 51 56 4 e water depth 1586 m and eastern sk17 15 15 n 72 58 e water depth 840 m arabian sea were used to study past sea surface temperatures sst and seawater 18o 18ow variations for the past 35 ka we used coupled mg ca 18o calcite variability in two planktonic foraminiferal species globigerinoides ruber which thrives throughout the year and globigerina bulloides which occurs mainly when surface waters contain high nutrients during upwelling or convective mixing ssts in both areas based on mg ca in g ruber were 3 to 4 c lower during the last glacial maximum lgm 21 ka than today and the holocene period the sst records based on g bulloides also indicate general cooling down to 18 c in both areas ssts in the western arabian sea based on g bulloides were always lower than those based on g ruber indicating the presence of strong seasonal temperature contrast during the holocene and lgm we interpret the consistent presence of this seasonal temperature contrast to reflect a combination of seasonal summer upwelling sw monsoon and winter convective mixing ne monsoon in the western arabian sea in the eastern arabian sea g bulloides based ssts were slightly lower about 1 c than g ruber based ssts during the holocene indicating the almost absence of a seasonal temperature gradient similar to today however a large seasonal temperature contrast occurred during the lgm which favors the assumption that strong ne monsoon winds forced winter upwelling or convective mixing offshore goa sst and 18ow reconstructions reveal evidence of millennial scale cycles particularly in the eastern arabian sea here the stadial periods northern hemisphere cold periods such as younger dryas and heinrich events are marked by increasing ssts and salty sea surface conditions relative to those during the interstadial periods indeed the 18ow record shows evidence of low saline surface waters during interstadial periods indicating increased freshwater runoff from the western ghats as a consequence of enhanced sw monsoon intensity

analysis of late palaeozoic glacial to postglacial sedimentary successions in south africa by geochemical proxies response to climate evolution and sedimentary environment abstract records of incisive climate changes during the late palaeozoic era are best documented in sedimentary basins of south africa glacial upper carboniferous early permian dwyka group and equivalents and postglacial deposits early to middle permian ecca and beaufort groups are known from the main karoo basin in south africa from the kalahari basin namibia and botswana and other late palaeozoic basins of south gondwana glacial deposits comprise diamictites and tillites followed by postglacial shales with variable organic matter contents and intercalated carbonate horizons this study covers the final glaciation phase upper pennsylvanian asselian sakmarian and the transition into the postglacial stage of the middle to late permian for sedimentary successions from the karoo and eastern kalahari basin element geochemical proxies chemical index of alteration zr ti rb k v cr and organic carbon content supported by mineralogical data record pronounced variation in sedimentary conditions these took place in the course of glacier retreat at the dwyka ecca boundary where climate and weathering processes are known to have changed the proxy signals indicate an increase in sea level and salinity and a shift in redox conditions from oxygenated to temporary anoxic euxinic conditions due to the synchronicity of these events distant sampling localities in the karoo basin can be correlated despite facies differences between the eastern kalahari and karoo basin the geochemical proxies point to a comparable climatic evolution during the postglacial phase for the early permian proxy signals indicate warm humid conditions in the karoo and kalahari basin during the middle permian increased aridity hampered chemical weathering processes as indicated by decreasing cia values results show that i proxies reflect provenance synsedimentary redox regime and late diagenetic alteration ii by combination of different independent geochemical proxies primary conditions of sedimentation and climate can be deduced iii the geochemical proxies applied are independent of local environments and iv the data reveal supra regional or even hemispherical changes in climate and sedimentary conditions thus geochemical proxies can be used as reliable markers for basin wide correlations knowledge about synchronicity on basin scale contributes to an improved understanding of sw gondwana s interaction with and influence on global climatic evolution

low latitude hydrological cycle and rapid climate changes during the last deglaciation sea surface temperature and oxygen isotopic records from two well dated indian ocean cores covering the last deglaciation show the occurrence of two periods of increased salinity along the route of warm surface water transport from the indian to the atlantic ocean one between 18 and 14 5 ka and the other during the younger dryas our results imply that during these periods salt accumulated in the tropical atlantic creating favorable conditions for an abrupt resumption of the thermohaline circulation and abrupt northern hemisphere warming furthermore we suggest that the observed pattern of millennial climate variability during the last glacial and deglaciation resulted from the interaction between the relatively slow rhythm of expansion and decay of the northern hemisphere ice sheets and el nino southern oscillation variability through changes in the position of the intertropical convergence zone this interaction generated an oscillator with millennial time response that operated at times of sufficient northern hemisphere ice sheets extent

reconciling discrepancies between uk37 and mg ca reconstructions of holocene marine temperature variability significant discrepancies exist between the detrended variability of late holocene marine temperatures inferred from mg ca and uk37 proxies with the former showing substantially more centennial scale variation than the latter discrepancies exceed that attributable to differences in location and persist across various calibrations indicating that they are intrinsic to the proxy measurement we demonstrate that these discrepancies can be reconciled using a statistical model that accounts for the effects of bioturbation sampling and measurement noise and aliasing of seasonal variability the smaller number of individual samples incorporated into mg ca measurements relative to uk37 measurements leads to greater aliasing and generally accounts for the differences in the magnitude and distribution of variability an inverse application of the statistical model is also developed and applied in order to estimate the spectrum of marine temperature variability after correcting for proxy distortions the correction method is tested on surrogate data and shown to reliably estimate the spectrum of temperature variance when using high resolution records applying this inverse method to the actual mg ca and uk37 data results in estimates of the spectrum of temperature variance that are consistent this approach provides a basis by which to accurately estimate the distribution of intrinsic marine temperature variability from marine proxy records

temperature δ18o relationships of planktonic foraminifera collected from surface waters abstract most of the isotopic paleotemperature equations used for paleoceanographic reconstructions have been derived from culture experiments or inorganic precipitates of calcium carbonate to test these equations in the modern ocean we measured the oxygen isotope composition of planktonic foraminifera globigerinoides ruber globigerinoides sacculifer globigerina bulloides and neogloboquadrina pachyderma collected from atlantic and southern ocean surface waters and added published plankton tow data from the pacific indian and arctic oceans the resulting species specific regression equations of the temperature 18o relationships for g ruber g sacculifer and g bulloides are statistically indistinguishable the equations derived for g sacculifer and g bulloides agree with relationships obtained from laboratory experiments in which these species were cultured at ph values close to modern surface waters the equation derived from n pachyderma has a significantly lower slope and offset than the other three species but produces a regression equation that is nearly identical to the one for the epifaunal benthic foraminifer cibicides sp our work on plankton tow and pumped samples indicates that culture derived equations appear to be more appropriate for predicting the absolute 18o of the species examined compared to equations derived from inorganic precipitates however over the oceanic temperature range the slopes of the equations we derive for living species agree with the slopes obtained from inorganic precipitates

calibration of mg ca thermometry in planktonic foraminifera from a sediment trap time series 1 paired mg ca and 18o measurements on planktonic foraminiferal species g ruber white g ruber pink g sacculifer g conglobatus g aequilateralis o universa n dutertrei p obliquiloculata g inflata g truncatulinoides g hirsuta and g crassaformis from a 6 year sediment trap time series in the sargasso sea were used to define the sensitivity of foraminiferal mg ca to calcification temperature habitat depths and calcification temperatures were estimated from comparison of 18o of foraminifera with equilibrium calcite based on historical temperature and salinity data when considered together mg ca mmol mol of all species except two show a significant r 0 93 relationship with temperature t c of the form mg ca 0 38 0 02 exp 0 090 0 003 t equivalent to a 9 0 0 3 change in mg ca for a 1 c change in temperature small differences exist in calibrations between species and between different size fractions of the same species o universa and g aequilateralis have higher mg ca than other species and in general data can be best described with the same temperature sensitivity for all species and pre exponential constants in the sequence o universa g aequilateralis g bulloides g ruber g sacculifer other species this approach gives an accuracy of 1 2 c in the estimation of calcification temperature the 9 sensitivity to temperature is similar to published studies from culture and core top calibrations but differences exist from some literature values of pre exponential constants different cleaning methodologies and artefacts of core top dissolution are probably implicated and perhaps environmental factors yet understood planktonic foraminiferal mg ca temperature estimates can be used for reconstructing surface temperatures and mixed and thermocline temperatures using g ruber pink g ruber white g sacculifer n dutertrei p obliquiloculata etc the existence of a single mg thermometry equation is valuable for extinct species although use of species specific equations will where statistically significant provide more accurate evaluation of mg ca paleotemperature

evidence for holocene changes in australian indonesian monsoon rainfall from stalagmite trace element and stable isotope ratios abstract trace element and stable isotope ratios from an active stalagmite lr06 b1 recovered from liang luar cave on the island of flores eastern indonesia are used to reconstruct the position of the austral summer inter tropical convergence zone and australian indonesian summer monsoon variability during the holocene uranium series dating of the stalagmite shows that it commenced growth 12 640 years ago with hiatuses spanning 8 560 to 6 420 and 3 670 to 2 780 years ago stalagmite mg ca and sr ca ratios correlate significantly with one another and with 18 o and 13 c throughout the record this suggests that the mg ca and sr ca ratios are dominated by prior calcite precipitation a process whereby degassing in the vadose zone during periods of low recharge causes deposition of calcite and disproportionate loss of ca 2 ions relative to mg 2 and sr 2 upstream of the stalagmite the degree of initial 234 u 238 u disequilibrium also appears to have been controlled by recharge to the overlying aquifer together with the mg ca sr ca and 18 o values the initial uranium isotope activity ratios 234 u 238 u i imply a generally drier early holocene coincident with a lower sea level and lower southern hemisphere summer insolation comparison of speleothem 18 o time series from flores and borneo shows that they vary in unison for much of the holocene however there is a significant decrease in the borneo 18 o record 6 000 to 4 000 years ago that does not occur in the flores record this anomaly may be related to a change in the australian indonesian summer monsoon circulation in response to a protracted positive phase of the indian ocean dipole under this scenario stronger upwelling off of western indonesia would based on present day effects result in reduced summer convective activity over flores and a subsequent northward shift of the intertropical convergence zone

holocene climate variability although the dramatic climate disruptions of the last glacial period have received considerable attention relatively little has been directed toward climate variability in the holocene 11 500 cal yr b p to the present examination of similar to50 globally distributed paleoclimate records reveals as many as six periods of significant rapid climate change during the time periods 9000 8000 6000 5000 4200 3800 3500 2500 1200 1000 and 600 150 cal yr b p most of the climate change events in these globally distributed records are characterized by polar cooling tropical aridity and major atmospheric circulation changes although in the most recent interval 600 150 cal yr b p polar cooling was accompanied by increased moisture in some parts of the tropics several intervals coincide with major disruptions of civilization illustrating the human significance of holocene climate variability c 2004 university of washington all rights reserved

eclogites of paleozoic or early alpine age in the basement of the penninic siviez mischabel nappe wallis switzerland outcrops of eclogites and retroeclogites occur in the normal limb of the siviez mischabel fold nappe penninic alps wallis switzerland the ecologites are contained in the gneisses of the ergischhorn and barneuza units turtmanntal and val de moiry where they usually associate with banded amphibolites high pressure mineral assemblages in the eclogites pyrope rich almandine and omphacite are overprinted by later amphibolite and greenschist facies metamorphic minerals according to coleman s classification the eclogites belong to the b type with pt values around 650 c for a minimum pressure of 15 kb geochemical investigations suggest a tholeiitic basalt affinity some problems still remain to solve these are 1 the geodynamic contexts and 2 the age of the eclogite facies overprint whether alpine or pre alpine in the absence of radiometric ages the following arguments favour a pre alpine lower paleozoic or older age of the high pressure metamorphism 1 1 the presence of polymetamorphic paragenesis the eclogitic mineral assemblages being the oldest 2 2 the b type of the eclogites which are associated tectonically with polymetamorphic gneisses 3 3 the presence in the same tectonic units of permian gabbros which show no signs of eclogite facies overprint 4 4 the presence of autochthonous sedimentary cover rocks that have been dated triassic to eocene this makes it difficult to assume an eo alpine cretaceous subduction of the underlying basement 5 5 the existence of striking similarity with other pre alpine eclogites related to a lower paleozoic 500 460 ma high pressure event well documented in some alpine and extra alpine basement units it could have associated with a caledonian subduction of oceanic crust

millennial scale trends in west pacific warm pool hydrology since the last glacial maximum models and palaeoclimate data suggest that the tropical pacific climate system plays a key part in the mechanisms underlying orbital scale and abrupt climate change atmospheric convection over the western tropical pacific is a major source of heat and moisture to extratropical regions and may therefore influence the global climate response to a variety of forcing factors the response of tropical pacific convection to changes in global climate boundary conditions abrupt climate changes and radiative forcing remains uncertain however here we present three absolutely dated oxygen isotope records from stalagmites in northern borneo that reflect changes in west pacific warm pool hydrology over the past 27 000 years our results suggest that convection over the western tropical pacific weakened 18 000 20 000 years ago as tropical pacific and antarctic temperatures began to rise during the early stages of deglaciation convective activity as inferred from oxygen isotopes reached a minimum during heinrich event 1 ref 10 when the atlantic meridional overturning circulation was weak pointing to feedbacks between the strength of the overturning circulation and tropical pacific hydrology there is no evidence of the younger dryas event in the stalagmite records however suggesting that different mechanisms operated during these two abrupt deglacial climate events during the holocene epoch convective activity appears to track changes in spring and autumn insolation highlighting the sensitivity of tropical pacific convection to external radiative forcing together these findings demonstrate that the tropical pacific hydrological cycle is sensitive to high latitude climate processes in both hemispheres as well as to external radiative forcing and that it may have a central role in abrupt climate change events

presence of the solar de vries cycle 205 years during the last ice age certain characteristic periodicities in the 14c record from tree rings such as the well known 11 yr schwabe cycle are known to be of solar origin the origin of longer period cycles such as the 205 yr de vries cycle in the 14c record was less certain and it was possible to attribute it either to solar or climatic variability here we demonstrate that the de vries cycle is present in 10be data from the grip ice core during the last ice age 25 to 50 kyr bp analysis of the amplitude of variation of this cycle shows it to be modulated by the geomagnetic field indicating that the de vries cycle is indeed of solar rather than climatic origin

interlaboratory comparison study of mg ca and sr ca measurements in planktonic foraminifera for paleoceanographic research thirteen laboratories from the usa and europe participated in an intercomparison study of mg ca and sr ca measurements in foraminifera the study included five planktonic species from surface sediments from different geographical regions and water depths each of the laboratories followed their own cleaning and analytical procedures and had no specific information about the samples analysis of solutions of known mg ca and sr ca ratios showed that the intralaboratory instrumental precision is better than 0 5 for both mg ca and sr ca measurements regardless whether icp oes or icp ms is used the interlaboratory precision on the analysis of standard solutions was about 1 5 and 0 9 for mg ca and sr ca measurements respectively these are equivalent to mg ca based temperature repeatability and reproducibility on the analysis of solutions of 0 2 c and 0 5 c respectively the analysis of foraminifera suggests an interlaboratory variance of about 8 rsd for mg ca measurements which translates to reproducibility of about 2 3 c the relatively large range in the reproducibility of foraminiferal analysis is primarily due to relatively poor intralaboratory repeatability about 1 2 c and a bias about 1 c due to the application of different cleaning methods by different laboratories improving the consistency of cleaning methods among laboratories will therefore likely lead to better reproducibility even more importantly the results of this study highlight the need for standards calibration among laboratories as a first step toward improving interlaboratory compatibility

younger dryas holocene temperature and rainfall history of southern indonesia from delta o 18 in speleothem calcite and fluid inclusions abstract we have applied a new technique to analyze the oxygen 18o and hydrogen d isotope ratios in speleothem fluid inclusions to reconstruct the temperature and rainfall history of southern indonesia during the younger dryas yd event and the holocene the 12 640 year speleothem record anchored by 33 uranium series dates shows that fluid inclusion 18o values vary in phase with speleothem calcite 18o during the holocene suggesting that the speleothem calcite 18o primarily reflects variations in the 18o of local rainfall significant early to mid holocene decreases in both 18o series are interpreted as an intensification of australian indonesian summer monsoon rainfall in response to deglacial eustatic sea level rise and flooding of the sunda shelf cave drip water temperatures reconstructed from coupled measurements of 18o in speleothem calcite and fluid inclusions remained relatively constant through the holocene this is consistent with reconstructions of indo pacific sea surface temperature sst based on analysis of mg ca ratios in planktonic foraminifera however during the yd event drip water i e cave temperature was 5 c cooler than modern which is substantially cooler than ssts inferred from foraminiferal mg ca but consistent with coral sr ca reconstructions of sst and terrestrial evidence for high elevation snow line depressions lower fluid inclusion 18o values during the yd indicate that the cooling was accompanied by increased monsoon rainfall taken together the results suggest that the southerly penetration of the intertropical convergence zone itcz was largely influenced by the cross equatorial temperature gradient rather than local ssts and air temperatures our results provide new evidence for a rapid cooling of deep tropical air temperatures and repositioning of the itcz during the yd event

antarctic control on tropical indian ocean sea surface temperature and hydrography 1 we reconstructed the surface hydrography of the south equatorial current in the western indian ocean for the last 65 000 years using a marine sediment core record results show that tropical indian ocean temperatures resemble temperatures from antarctic ice cores with warm and cold fluctuations synchronous with the antarctic cold reversal and the antarctic warm events a1 a4 the most likely thermal link involves subantarctic mode water samw which forms north of the subpolar frontal zone and spreads northward into the indian ocean this subsurface water mass is the prime suspect because of a stronger temperature response in the thermocline recorded by the foraminifer n dutertrei than in surface water g ruber

statistical constraints on el nino southern oscillation reconstructions using individual foraminifera a sensitivity analysis recent investigations of submillennial paleoceanographic variability have attempted to resolve high frequency climate signals such as the el nino southern oscillation enso using the population statistics of individual planktic foraminiferal 18o analyses this approach is complicated by the relatively short lifespan of individual foraminifers 2 4 weeks compared to the time represented by a typical marine sediment sample decades to millennia here we investigate the uncertainty associated with individual foraminiferal analyses ifa through simulations on forward modeled 18ocarbonate first focusing on the nino3 4 region of the tropical pacific ocean a bootstrap monte carlo algorithm is developed to constrain the uncertainty on ifa statistics subsequently to test the sensitivity of ifa to changes in seasonal cycle amplitude enso amplitude and enso frequency synthetic time series of 18ocarbonate with differing variability are constructed and tested with our algorithm the probabilities of the ifa technique in detecting changes in enso amplitude and seasonal cycle amplitude or a combination of both for the surface ocean and thermocline at different locations in the tropical pacific are quantified we find that the uncertainty in the standard deviation is smaller than the range that the ifa signal is insensitive to enso frequency and at certain locations the seasonal cycle may dominate enso ifa sensitivity towards enso is highest at the central equatorial pacific surface ocean and the eastern equatorial pacific eep thermocline whereas sensitivity towards the seasonal cycle is highest at the eep surface ocean our results suggest that rigorous uncertainty quantification should become standard practice for accurately interpreting ifa data

increasing australian indonesian monsoon rainfall linked to early holocene sea level rise the australian indonesian summer monsoon affects rainfall variability across the indo pacific region reconstructions of monsoon strength from stalagmites show that precipitation increased from 11 000 to 7 000 years ago as rising global sea level caused the flooding of the indonesian continental shelf the australian indonesian summer monsoon affects rainfall variability and hence terrestrial productivity in the densely populated tropical indo pacific region it has been proposed that the main control of summer monsoon precipitation on millennial timescales is local insolation1 2 3 but unravelling the mechanisms that have influenced monsoon variability and teleconnections has proven difficult owing to the lack of high resolution records of past monsoon behaviour here we present a precisely dated reconstruction of monsoon rainfall over the past 12 000 years based on oxygen isotope measurements from two stalagmites collected in southeast indonesia we show that the summer monsoon precipitation increased during the younger dryas cooling event when atlantic meridional overturning circulation was relatively weak4 monsoon precipitation intensified even more rapidly from 11 000 to 7 000 years ago when the indonesian continental shelf was flooded by global sea level rise5 6 7 we suggest that the intensification during the younger dryas cooling was caused by enhanced winter monsoon outflow from asia and a related southward migration of the intertropical convergence zone8 however the early holocene intensification of monsoon precipitation was driven by sea level rise which increased the supply of moisture to the indonesian archipelago

multidecadal variability and late medieval cooling of near coastal sea surface temperatures in the eastern tropical north atlantic 1 multidecadal variations in atlantic sea surface temperatures sst influence the climate of the northern hemisphere however prior to the instrumental time period information on multidecadal climate variability becomes limited and there is a particular scarcity of sufficiently resolved sst reconstructions here we present an eastern tropical north atlantic reconstruction of ssts based on foraminiferal mg ca ratios that resolves multidecadal variability over the past 1700 years spectral power in the multidecadal band 50 to 70 years period is significant over several time intervals suggesting that the atlantic multidecadal oscillation amo has been influencing local sst since our data exhibit high scatter the absence of multidecadal variability in the remaining record does not exclude the possibility that sst variations on this time scale might have been present without being detected in our data cooling by 0 5 c takes place between about ad 1250 and ad 1500 while this corresponds to the inception of the little ice age lia the end of the lia is not reflected in our record and sst remains relatively low this transition to cooler ssts parallels the previously reconstructed shift in the north atlantic oscillation toward a low pre 20th century mean state and possibly reflects common solar forcing

planktonic foraminifera stable isotopes and water column structure disentangling ecological signals differential carbon and oxygen stable isotope 13c and 18o fractionation between planktonic foraminifera test calcite and sea water related to ecology and life stage confound the potential for reconstructing palaeo water column temperature and carbon gradients multi species analysis and strict selection of test sizes are useful methods for identifying these fractionation processes also known as vital effects in fossil taxa however there are a limited number of species with adequate size controlled data sets needed for ground truthing the approach in the modern here we report 13c and 18o measurements made on twelve species of modern planktonic foraminifera across a range of fourteen tightly constrained size windows from a tropical indian ocean core top sample this data set includes more test size windows per species especially from the smallest identifiable test size classes and a wider range of species than previously attempted we use the size controlled 18o calcite trajectories to infer depth habitats and calculate species specific calcification temperatures the temperatures are then used to constrain species specific calcification depths along the modern vertical temperature profile in the western tropical indian ocean by overlaying the per species 13c calcite trajectories on local water column 13cdic profiles we estimate if and when i e at which test sizes the planktonic foraminifera species investigated approach ambient 13cdic values the profiling shows significant size controlled 13c deviation from seawater values in all species at some life growth stage which we attribute to i metabolic fractionation in tests 300 m of mixed layer photosymbiotic taxa for most species there is a size window where these effects appear to be at a minimum and or in balance exceptions are globigerinita glutinata a small 200 m surface living species globigerina bulloides which is highly opportunistic and deep living globorotalia tumida and globorotaloides hexagonus the latter two species being affected by various unexplained 13c vital effects use of our refined guidelines for test size selection should improve the potential for making realistic reconstructions of water column 13cdic in a modern tropical stratified setting and potentially in the distant geological past when there are no living analogues present