a global view of martian surface compositions from mgs tes thermal emission spectrometer tes data from the mars global surveyor mgs are used to determine compositions and distributions of martian low albedo regions two surface spectral signatures are identified from low albedo regions comparisons with spectra of terrestrial rock samples and deconvolution results indicate that the two compositions are a basaltic composition dominated by plagioclase feldspar and clinopyroxene and an andesitic composition dominated by plagioclase feldspar and volcanic glass the distribution of the two compositions is split roughly along the planetary dichotomy the basaltic composition is confined to older surfaces and the more silicic composition is concentrated in the younger northern plains

chemistry and mineralogy of outcrops at meridiani planum analyses of outcrops created by the impact craters endurance fram and eagle reveal the broad lateral continuity of chemical sediments at the meridiani planum exploration site on mars approximately ten mineralogical components are implied in these salt rich silicic sediments from measurements by instruments on the opportunity rover compositional trends in an apparently intact vertical stratigraphic sequence at the karatepe west ingress point at endurance crater are consistent with non uniform deposition or with subsequent migration of mobile salt components dominated by sulfates of magnesium striking variations in cl and enrichments of br combined with diversity in sulfate species provide further evidence of episodes during which temperatures ph and water to rock ratios underwent significant change to first order the sedimentary sequence examined to date is consistent with a uniform reference composition modified by movement of major sulfates upward and of minor chlorides downward this reference composition has similarities to martian soils supplemented by sulfate anion and the alteration products of mafic igneous minerals lesser cementation in lower stratigraphic units is reflected in decreased energies for grinding with the rock abrasion tool survival of soluble salts in exposed outcrop is most easily explained by absence of episodes of liquid h2o in this region since the time of crater formation

the chlorine isotopic composition of martian meteorites 1 chlorine isotope composition of martian mantle and crustal reservoirs and their interactions the martian meteorites record a wide diversity of environments processes and ages much work has been done to decipher potential mantle sources for martian magmas and their interactions with crustal and surface environments chlorine isotopes provide a unique opportunity to assess interactions between martian mantle derived magmas and the crust we have measured the cl isotopic composition of 17 samples that span the range of known ages martian environments and mantle reservoirs the 37cl of the martian mantle as represented by the olivine phyric shergottites nwa 2737 chassignite and shergotty basaltic shergottite has a low value of approximately 3 8 this value is lower than that of all other planetary bodies measured thus far the martian crust as represented by regolith breccia nwa 7034 is variably enriched in the heavy isotope of cl this enrichment is reflective of preferential loss of 35cl to space most basaltic shergottites less shergotty nakhlites chassigny and allan hills 84001 lie on a continuum between the martian mantle and crust this intermediate range is explained by mechanical mixing through impact fluid interaction and assimilation fractional crystallization

halogen and cl isotopic systematics in martian phosphates implications for the cl cycle and surface halogen reservoirs on mars abstract the cl isotopic compositions and halogen cl f br and i abundances in phosphates from eight martian meteorites spanning most rock types and ages currently available have been measured in situ by secondary ion mass spectrometry sims likewise the distribution of halogens has been documented by x ray mapping halogen concentrations range over several orders of magnitude up to some of the largest concentrations yet measured in martian samples or on the martian surface and the inter element ratios are highly variable similarly cl isotope compositions exhibit a larger range than all pristine terrestrial igneous rocks phosphates in ancient 4 ga meteorites orthopyroxenite alh 84001 and breccia nwa 7533 have positive 37 cl anomalies 1 1 to 2 5 these samples also exhibit explicit whole rock and grain scale evidence for hydrothermal or aqueous activity in contrast the phosphates in the younger basaltic shergottite meteorites 37 cl anomalies 0 2 to 5 6 phosphates with the largest negative 37 cl anomalies display zonation in which the rims of the grains are enriched in all halogens and have significantly more negative 37 cl anomalies suggestive of interaction with the surface of mars during the latest stages of basalt crystallization the phosphates with no textural major element or halogen enrichment evidence for mixing with this surface reservoir have an average 37 cl of 0 6 supporting a similar initial cl isotope composition for mars the earth and the moon oxidation and reduction of chlorine are the only processes known to strongly fractionate cl isotopes both positively and negatively and perchlorate has been detected in weight percent concentrations on the martian surface the age range and obvious mixing history of the phosphates studied here suggest perchlorate formation and halogen cycling via brines which have been documented on the martian surface has been active throughout martian history

coastal geomorphology of the martian northern plains the paper considers the question of the formation of the outflow channels and valley networks discovered on the martian northern plains during the mariner 9 mission parker and saunders 1987 and parker et al 1987 1989 data are used to describe key features common both in the lower reaches of the outflow channels and within and along the margins of the entire northern plains it is suggested that of the geological processes capable of producing similar morphologies on earth lacustrine or marine deposition and subsequent periglacial modification offer the simplest and most consistent explanation for the suit of features found on mars

refined data of alpha proton x ray spectrometer analyses of soils and rocks at the mars pathfinder site implications for surface chemistry 1 an extensive recalibration of the alpha proton x ray spectrometer apxs was performed to improve the data evaluation of the mars pathfinder mpf rock and soil in situ measurements many samples and geostandards were measured with an mpf identical spare apxs under simulated martian atmospheric pressure and low night temperature conditions precise calibration curves for major and minor elements were obtained using an improved spectral evaluation method for the original mpf spectra refined and new elemental compositions of the mpf rocks and soils were derived however all initial conclusions about soils and rocks remained valid the mpf soil composition revealed the mafic nature of the surface as inferred from the results of viking 1 and 2 data however the mpf rocks reflect a felsic composition for all samples linear correlations of sulphur with all other elements were noticed reflecting the fact that the rocks were covered with varying degrees of soil which compared to the rocks is rich in sulphur extrapolating to low sulphur abundance 0 3 the composition of a soil free rock was calculated the mpf rock composition is high in si and k and low in mg and fe compared to the soil using elemental data from mpf and martian meteorites a global estimation of the martian crust composition was derived the crust is of basaltic nature with a high abundance of incompatible elements k rb nd u th and volatile elements s cl while carbonates are lower or absent

ignimbrites of amazonis planitia region of mars a series of postulated ignimbrite units is mapped in the amazonis memnonia and aeolis quadrangles of mars the units cover about 2 2 106 km2 within a broad but discontinuous and irregular belt trending east west along the highland lowland boundary the ignimbrites overlie parts of the western and southern aureole materials of olympus mons but are embayed in places by the lava plains of the lowlands stratigraphic relations between the basalt flows from the tharsis montes region and the ignimbrites are not clearly defined crater counts suggest that the younger ignimbrites postdate the lava flows crater counts per square kilometer for the ignimbrites range from 7 29 1 95 10 4 to 6 36 2 01 10 5 for craters larger than 1 km in diameter the ignimbrite materials form thick 100 m extensive relatively flat sheets that are smooth to grooved or gently undulating grooved surfaces appear to be yardangs and in most places are not alined with prevailing wind directions the seven mapped ignimbrite units are characterized by morphologic expression stratigraphic position and crater counts similarities to ignimbrites in the pancake range of central nevada include 1 rounded patches of smooth high albedo nonwelded material superposed on jointed low albedo welded material 2 local complementary joint sets in welded materials and 3 thick flow sheets of great areal extent that follow but subdue underlying topography four major eruptive centers occur in areas where units are thickest and where a dominant nnw sse structural trend is expressed locally by unit margins elongate collapse features and normal faulting a minimum volume of 3 85 106 km3 for the deposits has been calculated from thickness estimates based on shadow measurements and crater rim height relations

mixed hydrothermal fluids and the origin of the martian soil the martian soil consists mainly of weathered basaltic rock and a salt component enriched in volatile and mobile elements primarily sulfur chlorine sodium and potassium since the discovery of this mobile element component by the viking x ray fluorescence spectrometer volcanic aerosols have been considered a likely source for these enrichments alternative sources of the mobile element component are fluids supplied to the surface by hydrothermal processes related to impact craters and volcanism we show that a mixed hydrothermal fluid model can successfully explain the composition of the mobile element component of the soil this model is constructed using terrestrial analogs constrained by the viking and pathfinder measurements of the martian soil chemistry the potential hydrothermal fluid contributions to the soil are tightly constrained because the relative abundances of the mobile elements in hydrothermal fluids are nearly constant the two end member types of hydrothermal fluids considered in the model are the neutral chloride and the acid sulfate type the neutral chloride fluids have high cl and na contents and a significant amount of k but their s abundance relative to cl s cl ratio is too low to match the martian soil however acid sulfate hydrothermal systems characterized by substantial vapor transport and high s cl ratios are likely on mars due to the low abundance of water indeed as the availability of water declines in a hydrothermal system the neutral chloride system can evolve to a vapor dominated acid sulfate system a combination of the two types of fluids can quantitatively explain the s and cl abundance in the soil and provide reasonable abundances of other mobile elements including na k and br without predicting an excess of any element measured in the soil however the hydrothermal fluids are unlikely to be involved in the formation of the magnetic minerals in the soil because the fe contents of the fluids are too low although the acid sulfate fluids have fe concentrations a factor of 100 larger than the neutral chloride fluids the acid sulfate fluids would contribute less than 1 of the total fe in the soil the volcanic aerosol models are poorly constrained in contrast to the hydrothermal fluid models because in volcanic aerosols the relative abundances of the mobile elements are highly variable therefore while volcanic aerosols can explain the mobile element component of the soil significant contributions from other sources cannot be excluded determining the relative contributions of hydrothermal components compared to volcanic aerosols will require measurements in the martian soil of trace elements that provide signatures of the hydrothermal fluids such as high lithium contents that are associated with neutral chloride fluids

latent outflow activity for western tharsis mars significant flood record exposed observations permitted by the newly acquired mars observer laser altimeter data have revealed a system of gigantic valleys northwest of the huge martian shield volcano arsia mons in the western hemisphere of mars northwestern slope valleys nsvs these features which generally correspond spatially to gravity lows are obscured by veneers of materials including volcanic lava flows air fall deposits and eolian materials geologic investigations of the tharsis region suggest that the system of gigantic valleys predates the construction of arsia mons and its extensive associated lava flows of mainly late hesperian and amazonian age and coincides stratigraphically with the early development of the outflow channels that debouch into chryse planitia similar to the previously identified outflow channels which issued tremendous volumes of water into topographic lows such as chryse planitia the nsvs potentially represent flooding of immense magnitude and as such a source of water for a northern plains ocean

global mineral distributions on mars 1 determining the mineralogy of mars is an essential part of revealing the conditions of the surface and subsurface a deconvolution method was used to remove atmospheric components and determine surface mineralogy from thermal emission spectrometer data at 1 pixel per degree ppd minerals are grouped into categories on the basis of compositional and spectral similarity and global concentration maps are produced all binned pixels are fit well with rms errors of 0 005 in emissivity higher rms errors are attributed to short wavelength particle size effects on dust covered surfaces significant concentrations 0 10 of plagioclase high ca pyroxene sheet silicates high si glass and hematite are detected and display distributions consistent with previous studies elevated concentrations of plagioclase and high ca pyroxene are consistent with basaltic surfaces and are located in low albedo highlands regions north of 45 s significant concentrations of plagioclase and sheet silicates high si glass and low concentrations of high ca pyroxenes are consistent with andesitic surfaces and are concentrated in both southern and northern high latitude low albedo regions andesitic surfaces in the southern hemisphere have a lower spectral contrast than northern surfaces an isolated surface located in solis planum is spectrally distinct but compositionally similar to other surfaces interpreted to be andesitic in composition concentrations of olivine below the detection limit correctly identify its presence in two of three locations potassium feldspar low ca pyroxene basaltic glass olivine sulfate carbonate quartz and amphibole are not detected with confidence at 1 ppd the results presented here indicate a predominance of volcanic compositions within martian dust free surfaces

alpha particle x ray spectrometer apxs results from gusev crater and calibration report 1 the chemical composition of rocks and soils on mars analyzed during the mars exploration rover spirit mission was determined by x ray analyses with the alpha particle x ray spectrometer apxs details of the data analysis method and the instrument calibration are presented measurements performed on mars to address geometry effects and background contributions are shown cross calibration measurements among several instrument sensors and sources are discussed an unintentional swap of the two flight instruments is evaluated new concentration data acquired during the first 470 sols of rover spirit in gusev crater are presented there are two geological regions the gusev plains and the columbia hills the plains contain soils that are very similar to previous landing sites on mars a meteoritic component in the soil is identified rocks in the plains revealed thin weathering rinds the underlying abraded rock was classified as primitive basalt one of these rocks contained significant br that is probably associated with vein filling material of different composition one of the trenches showed large subsurface enrichments of mg s and br disturbed soils and rocks in the columbia hills revealed different elemental compositions these rocks are significantly weathered and enriched in mobile elements such as p s cl or br even abraded rock surfaces have high br concentrations thus in contrast to the rocks and soils in the gusev plains the columbia hills material shows more significant evidence of ancient aqueous alteration

clues to martian brines based on halogens in salts from nakhlites and mer samples 1 chlorine and br abundances in fracture filling secondary salts in nakhla veins determined in this study by synchrotron x ray microprobe br and electron microprobe cl techniques compare well to the halogens determined recently by apxs instruments in soils and rock rinds at the gusev and meridiani sites the salts in these mars rocks arise from martian brines that have undergone evaporative or freezing concentration the halogen abundances in these salts are corrected for dilution effect because of mixing with halogen poor phases to obtain their true abundances which seem to be close to the halogen abundances in terrestrial sea brines consistent with the petrographic evidence for evaporative salt deposition sequence of carbonate sulfate halite in nakhlite meteorites nakhla veins yield high br 250 ppm and low cl br ratios 10 50 suggesting possible salt deposition from concentrated brines whereas lafayette iddingsite with low br 11 ppm and high cl br ratios 250 300 indicates salt deposition from dilute brines on mars the low cl br ratios 20 to 80 in salts from gusev and meridiani rock rinds indicate that they presumably originate from concentrated subsurface martian brines the high cl br ratio 270 in salts deposited by dilute solutions in lafayette and adirondack is similar to the chondritic cl br ratio which seems to characterize the dilute brines on mars prior to halite precipitation including early mars waters noachian or earlier our results seem to be consistent with the burt knauth model involving density stratification during evaporation freezing of brine solutions in martian regolith

organic molecules in the sheepbed mudstone gale crater mars the sample analysis at mars sam instrument on board the mars science laboratory curiosity rover is designed to conduct inorganic and organic chemical analyses of the atmosphere and the surface regolith and rocks to help evaluate the past and present habitability potential of mars at gale crater central to this task is the development of an inventory of any organic molecules present to elucidate processes associated with their origin diagenesis concentration and long term preservation this will guide the future search for biosignatures here we report the definitive identification of chlorobenzene 150 300 parts per billion by weight ppbw and c2 to c4 dichloroalkanes up to 70 ppbw with the sam gas chromatograph mass spectrometer gcms and detection of chlorobenzene in the direct evolved gas analysis ega mode in multiple portions of the fines from the cumberland drill hole in the sheepbed mudstone at yellowknife bay when combined with gcms and ega data from multiple scooped and drilled samples blank runs and supporting laboratory analog studies the elevated levels of chlorobenzene and the dichloroalkanes cannot be solely explained by instrument background sources known to be present in sam we conclude that these chlorinated hydrocarbons are the reaction products of martian chlorine and organic carbon derived from martian sources e g igneous hydrothermal atmospheric or biological or exogenous sources such as meteorites comets or interplanetary dust particles

geologic context of the mars radar stealth region in southwestern tharsis stealth is a region on mars that has no distinguishable radar return stealth was discovered in 1988 by muhleman et al 1991 in 3 5 cm earth based radar images and it was found to extend 2000 km along the martian equator west of arsia and pavonis montes stealth was proposed to be a deposit of unconsolidated granular material with a minimum thickness of several meters with the most likely explanation being that stealth is a volcanic tephra deposit muhleman et al 1991 1995 stealth overlies some of the youngest geologic units on mars including lava flows and a giant curvilinear ridged lobate unit on the west flank of arsia mons stealth also overlies part of a region of smooth and wind scoured materials called the medusae fossae formation examination of high resolution viking orbiter images suggests that stealth is the youngest of several discontinuous wind worked mantles of fine grained 1 cm sediment older deposits of fine sediment appear to be interbedded with lava flows and show evidence of aeolian deposition dunes and deposits in the lee of topographic obstacles and erosion yardangs and pedestal craters the geologic context supports a volcanic ash origin for stealth if stealth is composed of tephra then its extent and the nature of landforms in the region indicate that it resulted from multiple eruptions that occurred relatively late in martian history possible source vents include linear depressions flanked by constructive volcanic landforms that are located on the lower western slopes of arsia and pavonis montes

prodigious ash deposits near the summit of arsia mons volcano mars 1 mars orbiter camera images are used to identify widespread material interpreted to have formed via explosive volcanism on arsia mons volcano mars this material crops out in cliff sections associated with pit craters in layers 45 50 m thick the large range of elevations where the material is found 6 2 17 5 km suggests locally derived materials although extensive reworking has produced a wide variety of dune forms two possible styles of volcanism appear possible for generating this material 1 explosive volcanism associated with pit crater formation due to the release of magmatic gases or 2 the interaction between dikes and volatile rich substrates although the best examples occur on arsia mons pit craters on ascraeus mons also suggest explosive activity the absence of comparable features on olympus mons indicates that the eruptive histories of the larger tharsis shields were more diverse than has been inferred from viking orbiter images

late weichselian vegetation climate and floral migration at liastemmen north rogaland south western norway palynological results from liastemmen indicate a tripartite division of the late weichselian in the pleniglacial period from deglaciation ca 14000 bp to ca 13000 bp artemisia dominated pioneer vegetation on disturbed mineral soil was strongly influenced by cold winters and katabatic winds the late weichselian interstadial ca 13000 bp ca 11000 bp comprises a salix shrub consolidation phase and from ca 12700 bp a tree birch phase in the last 500 years of this period july and january means are estimated to about 16 c and between 2 c and 6 c respectively in the younger dryas stadial ca 11000 bp ca 10200 bp artemisia dominated vegetation returns three brief climatic deteriorations ca 12 250 bp 11 700 bp and 11 300 bp unfavourable to woody vegetation on humus soils are demonstrated within the interstadial critical climatic factors include cool winters and strong winds exposing vegetation and soil to frost drought and erosion the oldest and strongest oscillation probably involving local deforestation is correlated with the older dryas deterioration boreal circumpolar eurasiatic and arctic alpine plants dominated the late glacial flora for the majority of the late glacial taxa a northward migration is demonstrated this may also apply for papaver radicatum pinguicula alpina and primula scandinavica all with bicentric distributions in norway today

high resolution thermal inertia mapping from the mars global surveyor thermal emission spectrometer abstract high resolution thermal inertia mapping results are presented derived from mars global surveyor mgs thermal emission spectrometer tes observations of the surface temperature of mars obtained during the early portion of the mgs mapping mission thermal inertia is the key property controlling the diurnal surface temperature variations and is dependent on the physical character of the top few centimeters of the surface it represents a complex combination of particle size rock abundance exposures of bedrock and degree of induration in this work we describe the derivation of thermal inertia from tes data present global scale analysis and place these results into context with earlier work a global map of nighttime thermal bolometer based thermal inertia is presented at 1 4 per pixel resolution with approximately 63 coverage between 50 s and 70 n latitude global analysis shows a similar pattern of high and low thermal inertia as seen in previous viking low resolution mapping significantly more detail is present in the high resolution tes thermal inertia this detail represents horizontal small scale variability in the nature of the surface correlation with albedo indicates the presence of a previously undiscovered surface unit of moderate to high thermal inertia and intermediate albedo this new unit has a modal peak thermal inertia of 180 250 j m 2 k 1 s 1 2 and a narrow range of albedo near 0 24 the unit covering a significant fraction of the surface typically surrounds the low thermal inertia regions and may comprise a deposit of indurated fine material local 3 km resolution maps are also presented as examples of eolian fluvial and volcanic geology some impact crater rims and intracrater dunes show higher thermal inertias than the surrounding terrain thermal inertia of aeolian deposits such as intracrater dunes may be related to average particle size outflow channels and valleys consistently show higher thermal inertias than the surrounding terrain generally correlations between spatial variations in thermal inertia and geologic features suggest a relationship between the hundred meter scale morphology and the centimeter scale surface layer

explosive volcanism in the tharsis region global evidence in the martian geologic record 1 a global equatorial set of layered deposits on mars has been reexamined with mars global surveyor data the stratigraphy morphology and erosional characteristics of units separated by thousands of kilometers are remarkably similar to each other and consistent with a widespread episodic subaerial source of fine grained material this study is the first to propose a genetic link between many units that have traditionally been considered on a local or regional level including the medusae fossae formation valles marineris interior deposits chaotic terrain terra meridiani and arabia materials mapping relationships suggest that all of these units are post noachian in age and formation may have continued until the recent past thinning of deposits with increasing distance from the tharsis rise suggests that much of these materials may be volcanic ash flows and air fall from explosive eruptions in the tharsis region analogous to those produced by terrestrial plinian eruptions contemporary martian winds would preferentially transport ash from an eruption plume near tharsis east or west along the equator depending on the season erosion has removed much of the original volcanic ash and only isolated layered stacks remain sometimes in topographic depressions that inhibit erosion modeling indicates that widespread dispersion of ash after an eruption is easily attainable in present or past atmospheric conditions consistent with the hypothesis that the far reaching deposits may be composed of ash from past explosive eruptions in the vicinity of tharsis

regional dust deposits on mars physical properties age and history major dust storms on mars play an important role in the deposition and removal of fine dust material thermal radar and visual remote sensing observations provide important constraints on the martian regolith which have been used to determine the location and physical properties of regional dust deposits these deposits are located in three northern equatorial regions tharsis 20 s to 50 n 60 to 190 w arabia 5 s to 30 n 300 to 360 w and elysium 10 to 30 n 210 to 225 w they are covered by fine 2 40 m bright albedo 0 27 particles with fewer exposed rocks and coarse deposits than found elsewhere dust is currently deposited uniformly throughout the equatorial region at a rate of 40 m global storm over geologic time the rate of accumulation may vary from 0 to 250 m yr due to changes in atmospheric conditions produced by orbital variations dust deposited during global storms is subsequently removed only from dark regions resulting in a net accumulation in the low inertia bright regions the thickness of these current dust deposits is 0 1 2 m the thermal inertia places a lower limit of 0 1 m on the thickness of these deposits while the sparse but ubiquitous presence of exposed rocks and the degree of visible mantling indicate that the thickness is less than 5 m dual polarization radar observations of a very rough texture in tharsis are consistent with this model with a 2 m thick dust layer burying most of the surface rocks but permitting radar sampling of the rough subsurface based on their thickness and rate of accumulation the age of these deposits is 105 106 years suggesting a cyclic process of deposition and removal one possible cause may be cyclic variations in the magnitude and location of maximum wind velocities related to variations in mars orbit at present perihelion and maximum wind velocities occur in the south whereas regional dust deposits occur in the north suggesting net transport from south to north orbital parameters oscillate with periods ranging from 5 104 to 106 years the agreement between these periods and the dust deposit age suggests a possible link at different stages in orbit evolution maximum wind velocities will occur in the north with subsequent erosion and redistribution of the accumulated fines based on this model much of the uppermost martian surface is very young and is being continually reworked

theoretical modeling of eruption plumes on mars under current and past climates we have used a combined conduit transport eruption column model to explore the evolution of volcanic eruption plumes on mars under different atmospheric conditions in the calculations we consider a volatile phase composed of h2o co2 and so2 and take into account that the magmatic water erupted at the vent may condense as the eruption column rises into the martian atmosphere as two end member models we explore the eruption of rhyolitic and basaltic melt compositions containing different amounts of volatiles as well as having different eruption temperatures under current martian atmospheric conditions eruption plumes are found to rise as high as 100 km for a mass eruption rate of 5 107 kg s 1 which is consistent with model calculations by wilson and head 1994 in contrast under a dense atmosphere 105 pa on the martian surface which may have existed earlier in martian history the same eruption plume reaches only about 25 km height all magmatic water released during the eruption is found to freeze as it rises in the eruption column which means that fallout from the plume will contain water ice which can be subsequently deposited in near surface layers this ice may then suddenly melt due to higher surface heat flow or shallow intrusions leading to rapid release of water on the flanks of volcanoes only if the atmosphere were hotter in the past could the water in the eruption plume condense and produce rain rather than ice furthermore the calculations show that smaller micron size particles would be distributed globally from eruption plumes under current martian conditions but would not have been as widely dispersed from plumes erupted into an earlier dense atmosphere

aeolian dunes as evidence for explosive volcanism in the tharsis region of mars two transverse dune fields occur among late amazonian volcanic and aeolian landforms in southwestern tharsis mars the first is located 70 km northwest of biblis patera around 5 n 125 w the second is located about 500 km northwest of arsia mons at 2 s 130 w the latter is the largest dune field thus far documented to occur in the equatorial latitudes of mars unlike other dunes on the planet both dune fields in tharsis have low thermal inertias 2 7 10 3cal cm 2sec 0 5k 1 and high albedos 0 26 that are indistinct from their surrounding terrain both dune fields have superposed features such as impact craters lava flows smooth surfaced units and bright wind streaks the dune fields therefore appear to be inactive and mantled by fine grained material i e particles 60 m to form aeolian dunes require a supply of sand on earth most dune sands are supplied by fluvial and littoral processes but this is not the case in tharsis on mars because they are superposed on a late amazonian surface the climate is assumed to have been hyper arid throughout the time that the dunes have existed under these conditions the only plausible source for quantities of sediment sufficient to form transverse dune fields is explosive volcanism therefore the two dune fields in tharsis are evidence that explosive volcanism has occurred in this region in the late amazonian epoch

acidic volatiles and the mars soil large portions of mars surface are covered with deposits of fine homogeneous weathered dusty soil material nanophase iron oxides silicate mineraloids and salts prevail in the soil the mode of formation of this somewhat peculiar type of soil is still far from being clear one scenario suggests that weathering took place during early epochs when mars may have been warm and wet the properties of the soil are not easily reconciled with this scenario we propose another possible scenario that attributes in part the peculiar nature of the martian dust and soil to a relatively young weathering product formed during the last few hundreds of millions of years in a process that involves acidic volatiles we tested this hypothesis in an experimental study of the first step of acidolytic weathering of a partly palagonitized volcanic tephra of hawaiitic lava origin using sulfuric hydrochloric and nitric acids and their mixtures the tephra effectively neutralize the added acidity the protonic acidity added to the tephra attacks the primary minerals releasing fe al and mg which control the ph acting as lewis acid species of varying acid strengths the full amount of acidity added to the tephra is stored in it but only a very small fraction is preserved as the original protonic acidity the majority of the added sulfate and chloride were present as salts and easily solubilized minerals well crystallized sulfate salt minerals of aluminum and calcium were detected by powder x ray diffractometry whereas secondary magnesium and iron minerals were not detected due probably to lack of crystallinity the presence of gypsum caso4 2 h2o and alunogen al2 so4 3 17 h2o is probably responsible for the observed increased hygroscopicity of the acidified tephra and their tendency to form hardened crusts we suggest that if this mechanism is of importance on mars then the chemically weathered component of the martian soil consists of a salt rich mineral mixture containing the salts of the anionicligands so4 and cl resulting from volatiles emitted from volcanoes during more recent eruptions up to 109 years b p the lack of liquid water on mars surface during that time slowed or halted mineralogical evolution into highly crystallized minerals having large mineral grains the chemically weathered components are mixed with the products of physical weathering the recently formed soil may cover and coat more evolved hydrothermally modified mineral deposits formed in earlier epochs of mars

acid sulfate weathering of synthetic martian basalt the acid fog model revisited the acid fog model has received considerable attention as a model of soil formation on mars previous evaluations of this model have focused on experimental weathering of terrestrial basalt samples however these samples differ significantly from what now is thought to be typical of martian basalt the acid fog model is tested here using synthetic basaltic analogs derived from mars pathfinder soil and rock compositions reaction of synthetic basalt with various acidic solutions and subsequent evaporation has led to the formation of several putative secondary mineral phases many of these phases were not produced in prior experimental studies aimed at aqueous interactions on mars of these alteration phases mg fe ca and al sulfates were identified in addition secondary ferric oxide phases formed via rapid fe oxidation under relatively high ph levels buffered by basalt dissolution amorphous silica is a ubiquitous product in these experiments and has formed by precipitation from solution and by the dissolution of minerals and glasses leaving behind leached surface layers composed of residual silica the secondary products formed in these experiments demonstrate the importance of primary mineralogy when testing models of aqueous interactions on mars new constraints are placed on both the reactivity of primary basalt and the secondary mineralogy present at the martian surface copyright 2004 by the american geophysical union

possible precipitation of ice at low latitudes of mars during periods of high obliquity most of the old cratered highlands of mars are dissected by branching river valleys that appear to have been cut by running water1 2 yet liquid water is unstable everywhere on the martian surface in the equatorial region where most of the valleys are observed even ice is unstable3 4 it has been suggested therefore that mars had an early denser atmosphere with sufficient greenhouse warming to allow the existence of liquid water5 here we suggest instead that during periods of very high obliquities ice could accumulate at low latitudes as a result of sustained sublimation of ice from the poles and transport of the water vapour equatorwards at low latitudes the water vapour would saturate the atmosphere and condense onto the surface where it would accumulate until lower obliquities prevailed the mechanism is efficient only at the very high obliquities that occurred before formation of tharsis very early in the planet s history but limited equatorial ice accumulation could also have occurred at the highest obliquities during the rest of the planet s history partial melting of the ice could have provided runoff to form the channels or replenish the groundwater system

the spatial distribution of rocks on mars abstract the spatial distribution of rocks exposed at the surface of mars has been mapped using viking infrared thermal mapper irtm observations overall there are no regions on the surface of mars at a scale of 1 1 in latitude and longitude that are rock free the modal value of rock abundance is 6 areal coverage with no areas having more than 30 35 rock cover the model developed to determine rock abundance relates the thermal emission in each of the four surface sensing irtm bands to temperature contrasts within the field of view non unit thermal emissivity due to absorption bands in the surface materials and the absorption and scattering of the outgoing energy by atmospheric dust and water ice each of these effects produce characteristic spectral and diurnal signatures allowing them to be separated the temperature contrasts provide a means to determine both the abundance of exposed rocks and the fine component thermal intertia rock abundance alone does not produce the observed variation in bulk thermal inertia of the surface low inertia fine bright surfaces have fewer rocks exposed than do high inertia coarse dark surfaces rock abundance does not correlate well with the rms slope nor reflectivity determined from delay doppler radar measurements there is however a possible correlation between rms slope determined from continuous wave radar observations dual polarization radar measurements which provide the best radar measure of small scale roughness indicate that the tharsis volcanic region is very rough whereas thermal measurements indicate very few rocks and a covering of dust together these observations suggest an approximately 1 m thick mantle of fines covering a very rough subsurface this fine material may be an aeolian deposit of dust storm fallout valles marineris together with several major channels and chaotic terrains have high rock abundances as does the acidalia planitia basin this observed distribution may reflect the initial deposition of coarse material associated with channel formation syrtis major is unique in having a high inertia but a very low rock abundance together with low radar roughness these observations are consistent with mantling of rocks by sand the observed distribution of rocks and fines indicates that aeolian processes both erosional and depositional play a dominant role in shaping the present martian surface

chemical composition of martian fines of the 21 samples acquired for the viking x ray fluorescence spectrometer 17 were analyzed to high precision compared to typical terrestrial continental soils and lunar mare fines the martian fines are lower in al higher in fe and much higher in s and cl concentrations protected fines at the two lander sites are almost indistinguishable but concentration of the element s is somewhat higher at utopia duricrust fragments successfully acquired only at the chryse site invariably contained about 50 higher s than fines no elements correlate positively with s except cl and possibly mg a sympathetic variation is found among the triad si al ca positive correlation occurs between ti and fe sample variabilities are as great within a few meters as between lander locations 4500 km apart implying the existence of a universal martian regolith component of constant average composition the nature of the source materials for the regolith fines must be mafic to ultramafic

episodic flood inundations of the northern plains of mars throughout the recorded history of mars liquid water has distinctly shaped its landscape including the prominent circum chryse and the northwestern slope valleys outflow channel systems and the extremely flat northern plains topography at the distal reaches of these outflow channel systems paleotopographic reconstructions of the tharsis magmatic complex reveal the existence of an europe sized noachian drainage basin and subsequent aquifer system in eastern tharsis this basin is proposed to have sourced outburst floodwaters that sculpted the outflow channels and ponded to form various hypothesized oceans seas and lakes episodically through time these floodwaters decreased in volume with time due to inadequate groundwater recharge of the tharsis aquifer system martian topography as observed from the mars orbiter laser altimeter corresponds well to these ancient flood inundations including the approximated shorelines that have been proposed for the northern plains stratigraphy geomorphology and topography record at least one great noachian early hesperian northern plains ocean a late hesperian sea inset within the margin of the high water marks of the previous ocean and a number of widely distributed minor lakes that may represent a reduced late hesperian sea or ponded waters in the deepest reaches of the northern plains related to minor tharsis and elysium induced amazonian flooding

sounding the subsurface of athabasca valles using marsis radar data exploring the volcanic and fluvial hypotheses for the origin of the rafted plate terrain 1 to test the volcanic and fluvial hypotheses for the origin of the rafted plate terrain observed in the vicinity of athabasca valles 5 n 150 e central elysium planitia we investigated the subsurface radar echo from the mars advanced radar for subsurface and ionosphere sounding marsis 5 mhz band data over this area the backscattered signal losses were compared to finite difference time domain fdtd simulations of those arising from three hypothetical geoelectrical subsurface models which differed in their assumed composition percentage basalt versus ice and assumed mode of origin fluvial discharge frozen sea mudflow and low viscosity lavas the dielectric values used in these models are derived from laboratory measurements of mars analog materials under mars like conditions fdtd simulations suggest that if the near surface environment is ice rich it will result in an average loss rate of 0 053 db m for massive ice having less than 1 of suspended particulates and 0 065 db m for a mudflow consisting of a 50 50 mixture of ice and basaltic dust whereas the losses associated with a lava flow model increase to 0 19 db m in comparison the actual signal losses experienced by marsis within this region were on the order of 0 18 db m within the first 160 m beneath the surface this suggests that propagation characteristics of athabasca s near subsurface are more consistent with a volcanic rather than a fluvial or mudflow origin of the rafted plate terrain although limitations on radar sounding depth in this region cannot rule out the possibility of more deeply buried massive ice deposits

primary centers and secondary concentrations of tectonic activity through time in the western hemisphere of mars five main stages of radial and concentric structures formed around tharsis from the noachian through the amazonian as determined by geologic mapping of 24 452 structures within the stratigraphic framework of mars and by testing their radial and concentric orientations tectonic activity peaked in the noachian stage 1 around the largest center claritas an elongate center extending more than 20 in latitude and defined by about half of the total grabens which are concentrated in the syria planum thaumasia and tempe terra regions during the late noachian and early hesperian stage 2 extensional structures formed along the length of present day valles marineris and in thaumasia with a secondary concentration near warrego vallis radial to a region just to the south of the central margin of valles marineris early hesperian stage 3 radial grabens in pavonis syria ulysses and tempe terra and somewhat concentric wrinkle ridges in lunae and solis plana and in thaumasia sirenum memnonia and amazonis are centered northwest of syria with secondary centers at thaumasia tempe terra ulysses fossae and western valles marineris late hesperian early amazonian stage 4 structures around alba patera the northeast trending alignment of tharsis montes and olympus mons appears centered on alba patera stage 5 structures middle late amazonian represent the last pulse of tharsis related activity and are found around the large shield volcanoes and are centered near pavonis mons tectonic activity around tharsis began in the noachian and generally decreased through geologic time to the amazonian statistically significant radial distributions of structures formed during each stage centered at different locations within the higher elevations of tharsis secondary centers of radial structures during many of the stages appear related to previously identified local magmatic centers that formed at different times and locations throughout tharsis

formation of glaciers on mars by atmospheric precipitation at high obliquity surface conditions on mars are currently cold and dry with water ice unstable on the surface except near the poles however geologically recent glacierlike landforms have been identified in the tropics and the midlatitudes of mars the ice has been proposed to originate from either a subsurface reservoir or the atmosphere we present high resolution climate simulations performed with a model designed to simulate the present day mars water cycle but assuming a 45 obliquity as experienced by mars a few million years ago the model predicts ice accumulation in regions where glacier landforms are observed on the western flanks of the great volcanoes and in the eastern hellas region this agreement points to an atmospheric origin for the ice and reveals how precipitation could have formed glaciers on mars

localization and physical property experiments conducted by opportunity at meridiani planum the location of the opportunity landing site was determined to better than 10 m absolute accuracy from analyses of radio tracking data we determined rover locations during traverses with an error as small as several centimeters using engineering telemetry and overlapping images topographic profiles generated from rover data show that the plains are very smooth from meter to centimeter length scales consistent with analyses of orbital observations solar cell output decreased because of the deposition of airborne dust on the panels the lack of dust covered surfaces on meridiani planum indicates that high velocity winds must remove this material on a continuing basis the low mechanical strength of the evaporitic rocks as determined from grinding experiments and the abundance of coarse grained surface particles argue for differential erosion of meridiani planum

equatorial and midlatitude distribution of chlorine measured by mars odyssey grs 1 the 2001 mars odyssey gamma ray spectrometer grs has made the first measurement of the equatorial and midlatitude distribution of cl at the near surface of mars a mean concentration value of 0 49 wt cl has been determined from a grand sum of grs spectra collected over the planet excluding high latitude regions cl is significantly enriched within the upper few tens of centimeters of the surface relative to the martian meteorites and estimates for the bulk composition of the planet however cl is not homogeneously distributed and varies by a factor of 4 even after smoothing of data with a 10 arc radius filter several contiguous geographically large 20 regions of high and low cl concentrations are present in particular a region centered over the medusae fossae formation west of tharsis shows significantly elevated cl a large region north of syrtis major extending into utopia planitia in the northern hemisphere shows the lowest cl concentrations on the basis of hierarchical multivariate correlations cl is positively associated with h while negatively associated with si and thermal inertia we discuss four possible geologic mechanisms aeolian volcanic aqueous and hydrothermal that may have affected the cl distribution seen by grs while some of the distribution may be due to cl rich dust deposits transported by aeolian processes this mechanism does not appear to account for all of the observed variability we propose that reactions with volcanic exhalations may have been important for enriching cl in medusae fossae formation material

final chemical results from the mars pathfinder alpha proton x ray spectrometer 1 the calibrated pathfinder alpha proton x ray spectrometer apxs instrument is capable of measuring concentrations of all major and minor rock forming elements ranging from carbon through zirconium in atomic number therefore it is capable of constraining the petrology of the measured samples in particular the pathfinder data are the first in situ measurements of martian rocks and may be compared with previous remote sensing measurements as well as with the compositions of snc meteorites pathfinder soil and rock sample abundances from the alpha proton and x ray modes have been quantified the abundances suggest that 1 the rocks are covered with various amounts of soil 2 the soil free rocks on a volatile free basis have some element ratios similar to mars meteorites yet have different bulk chemistry indicative of more evolved rocks with higher silica abundances 3 the carbon and nitrogen contents are below detection limits and 4 the alpha mode oxygen reveals excess amounts of oxygen in some samples which is indicative of sample bound water contained within minerals or glasses in samples

mineralogy composition and alteration of mars pathfinder rocks and soils evidence from multispectral elemental and magnetic data on terrestrial analogue snc meteorite and pathfinder samples major element multispectral and magnetic properties data were obtained at ares vallis during the mars pathfinder mission to understand the compositional mineralogical and process implications of these data we obtained major element mineralogical and magnetic data for well crystalline and nanophase ferric minerals terrestrial analogue samples with known geologic context and snc meteorites analogue samples include unaltered palagonitic and sulfatetic tephra from mauna kea volcano hydrolytic and acid sulfate alteration steam vent material from kilauea volcano hydrolytic alteration and impactites from meteor crater relithification salient results for mars pathfinder include 1 band depths bd530b and bd600 and the reflectivity ratio r800 r750 are consistent with the dominant ferric mineral being nanophase ferric oxide associated with an unknown amount of h2o and occurring in composite particles along with subordinate amounts of other ferric minerals hematite and hematite plus nanophase goethite are most consistent with the data but maghemite akaganeite schwertmannite and nanophase lepidocrocite are also possible interpretations ferric oxides that are consistently not favored by the data as sole alteration products are jarosites and well crystalline goethite and lepidocrocite 2 the strength of the ferric adsorption edge r750 r445 implies the fe3 fe2 values for pathfinder rock and soil are within the ranges 0 7 3 and 3 20 respectively 3 ferrous silicates are indicated for subsets of pathfinder rocks and soils one subset has a band minimum near 930 nm that can attributed to low ca pyroxene alternatively the band could be a second manifestation of certain ferric oxides including nanophase goethite maghemite akaganeite and schwertmannite another subset has a negative spectral slope from 800 to 1005 nm which could result from the high energy wing of a high ca pyroxene and or olivine band a mixture of bright and dark materials and for rocks thin coatings of bright dust on dark rocks 4 chemical data on pathfinder rocks and soils are consistent with two component mixtures between an andesitic rock with low mgo and so3 concentrations soil free rock and a global basaltic soil with high mgo and so3 concentrations rock free soil pathfinder rock free soil can be modeled as a chemical mixture of snc meteorites and the pathfinder soil free rock 5 pathfinder soil cannot be obtained by chemical alteration of pathfinder rocks by any of the hydrolytic and acid sulfate alteration processes we studied presumably global mixing has obscured and possibly erased the elemental signatures of chemical alteration 6 the strongly magnetic phase in palagonitic and sulfatetic tephra is titanomagnetite and possibly its oxidation product titanomaghemite fe ti spinels the saturation magnetization of the tephra samples 0 5 2 0 am2 kg is at or below the low end of the range inferred for martian dust 4 2 am2 kg implying that lithogenic fe ti spinels are a possible candidate for the martian strongly magnetic phase 7 the predominantly palagonitic spectral signature and magnetic nature of martian soil and dust are consistent with glassy precursors with imbedded fe ti spinel particles comparison with lunar glass production rates suggests that production of sufficient quantities of glassy materials on mars by volcanic and impact processes is sufficient to account for these observations

iron sulfur mineralogy of mars magmatic evolution and chemical weathering products models for the evolution of sulfide minerals on mars and reaction pathways to their oxidative weathering products in martian regolith have been proposed based on petrogenetic associations between komatiitic rock types viking geochemical data snc meteorites and terrestrial fe ni sulfide deposits to test the weathering model komatiitic pyrrhotites and olivines were exposed to sulfuric acid solutions with and without dissolved ferric iron added to simulate deep weathering processes and the reaction products were identified by mossbauer spectroscopy secondary fes sub 2 pyrite or marcasite feooh goethite and possibly jarosite were formed from pyrrhotite while olivine was oxidized to nanophase goethite these results suggest that on mars acidic groundwater induced pyrrhotite yields fes sub 2 yields feooh jarosite oxidative weathering reactions particularly in the presence of dissolved fe sup 3 such gossaniferous materials occurring in martian regolith were derived mainly from fe ni sulfides associated with komatiitic basalts and not from sulfides occurring in calc alkaline porphyry copper deposits granitic hydrothermal veins sediment hosted pbs zns ores etc which presumably did not evolve on mars due to the virtual lack of plate tectonic activity there

mineralogic and compositional properties of martian soil and dust results from mars pathfinder mars pathfinder obtained multispectral elemental magnetic and physical measurements of soil and dust at the sagan memorial station during the course of its 83 sol mission we describe initial results from these measurements concentrating on multispectral and elemental data and use these data along with previous viking snc meteorite and telescopic results to help constrain the origin and evolution of martian soil and dust we find that soils and dust can be divided into at least eight distinct spectral units based on parameterization of imager for mars pathfinder imp 400 to 1000 nm multispectral images the most distinctive spectral parameters for soils and dust are the reflectivity in the red the red blue reflectivity ratio the near ir spectral slope and the strength of the 800 to 1000 nm absorption feature most of the pathfinder spectra are consistent with the presence of poorly crystalline or nanophase ferric oxide s sometimes mixed with small but varying degrees of well crystalline ferric and ferrous phases darker soil units appear to be coarser grained compacted and or mixed with a larger amount of dark ferrous materials relative to bright soils nanophase goethite akaganeite schwertmannite and maghemite are leading candidates for the origin of the absorption centered near 900 nm in imp spectra the ferrous component in the soil cannot be well constrained based on imp data alpha proton x ray spectrometer apxs measurements of six soil units show little variability within the landing site and show remarkable overall similarity to the average viking derived soil elemental composition differences exist between viking and pathfinder soils however including significantly higher s and cl abundances and lower si abundances in viking soils and the lack of a correlation between ti and fe in pathfinder soils no significant linear correlations were observed between imp spectral properties and apxs elemental chemistry attempts at constraining the mineralogy of soils and dust using normative calculations involving mixtures of smectites and silicate and oxide minerals did not yield physically acceptable solutions we attempted to use the pathfinder results to constrain a number of putative soil and dust formation scenarios including palagonitization and acid fog weathering while the pathfinder soils cannot be chemically linked to the pathfinder rocks by palagonitization this study and mcsween et al 1999 suggest that palagonitic alteration of a martian basaltic rock plus mixture with a minor component of locally derived andesitic rock fragments could be consistent with the observed soil apxs and imp properties

phytoliths and microcharcoal at jinluojia archeological site in middle reaches of yangtze river indicative of paleoclimate and human activity during the last 3000 years a variety of phytoliths together with prolific microcharcoal particles sponge spicules and diatoms were extracted and identified in four cultural layers from an archeological site at jinluojia macheng hubei province central china the warmth iw and aridity iph indices calculated from grass phytoliths reveal warm and wet periods during the west zhou early east zhou tang and song dynasties whilst cool and dry periods occurred during the late east zhou ming and qing dynasties the paleoclimate conditions reconstructed on the basis of grass phytoliths extracted from archeological sediments are in agreement with those from natural sediments in the middle yangtze region in contrast the woody phytoliths show a positive correlation with microcharcoal particles suggesting an anthropogenic contribution to the woody phytoliths from the use of woody plants for fuel during cooking and heating two episodes of the enhanced abundance of woody phytoliths and microcharcoal particles were found to occur at east zhou dynasty and from ming and qing dynasties to the present proposed to be a consequence of the population expansion and or the frequent wars