circulation mixing and production of antarctic bottom water abstract the antarctic source of bottom water to the abyssal layer of the world ocean is examined as well as its large scale flow pattern and ultimate entrainment rate into the deep water above we make use of the available high quality station data in the southern ocean to construct bottom maps of neutral density and mean property maps including chlorofluorocarbon cfc for the abyssal layer underneath a selected neutral density surface the maximum density at the sill depth of drake passage is used to distinguish between the voluminous deep water mass that is a continuous component of the antarctic circumpolar current from the relatively denser bottom water originated along the antarctic continental margins based on water density antarctic bottom water aabw is defined here generically to include all volumes of non circumpolar water of antarctic origin over the shelf regime multiple localized sources of specific aabw types contribute to the abyssal layer of the adjacent antarctic basins characteristics of these dense bottom waters reflect closely those observed on the parent shelf water mass spreading paths of newly formed deep and bottom waters over the slope regime and their subsequent oceanic circulation patterns are analyzed on the basis of global property maps for the aabw layer interior mixing and interbasin exchanges of aabw are deduced from mean characteristic curves following the southern streamline of the antarctic circumpolar current outflow and mixing of aabw from the weddell sea to the argentine basin is depicted using density and cfc distributions of two zonal hydrographic lines recirculation and mixing of deep and bottom waters within the weddell gyre are also detailed using a meridional section along the greenwich meridian the strength of all localized sources of aabw combined is estimated by two independent approaches an estimate of the total production rate of aabw is calculated based on the oceanic cfc budget for the aabw layer offshore of the 2500 m isobath the sum of all downslope inputs of well ventilated bottom water types underneath the top isopycnal must account for the measured cfc content in the bottom layer the resulting total aabw production rate is about 8 sv which is a conservative figure that neglects the loss of cfc bearing waters across the top isopycnal in recent years whereas about 9 5 sv is calculated assuming a well mixed bottom layer making use of their transient nature cfc distributions at the top of the aabw layer indicate that more direct and rapid entrainment of cfc rich bottom waters below occurs over localized areas with relatively strong upwelling rates and enhanced vertical mixing a second more ad hoc but independent oceanic mass budget of the bottom layer is also constructed a typical basin wide rate of deep upwelling of 3 10 7 m s 1 requires 10 sv 1 sv 106 m3 s 1 of newly formed aabw to sink down the slope around antarctica we have also formulated a spatial distribution of deep upwelling on the isopycnal at the top of the aabw it is expressed as a combination of wind topographic and turbulent components which in turn are functions of the isopycnal depth bottom depth and bottom layer thickness this non uniform upwelling field yields about 12 sv of aabw exported across the top isopycnal fortuitously the overall average of upward speed at the top isopycnal 3 7 10 7 m s 1 compares well with previous estimates of deep upwelling in the northern basins a series of likely sites for strong vertical entrainment of aabw are clearly identified in the modeled distribution of deep upwelling consonant with the observed cfc distributions on the top isopycnal altogether regions with relatively high upwelling rates 5 10 7 m s 1 occupy only a quarter of the total areal extent of the top isopycnal but they account for as much as 45 of the total vertical transport

sedimentation of 13c rich organic matter from antarctic sea ice algae a potential indicator of past sea ice extent organic matter collected in sediment traps at a nearshore marine site in prydz bay east antarctica displayed a pronounced seasonal variation in carbon isotopes expressed as 13 c om winter values were fairly constant near 20 before increasing to above 15 in response to inputs from sea ice algae in early spring particulate organic matter obtained directly from sea ice cores exhibited very high 13 c om values typically 15 but as much as 8 much above the values of organic matter suspended in the water column below the sea ice the sea ice algae contributed 20 of the annual flux of organic matter and the 13 c om measurements from a sediment core at the site suggest that this value is representative of the recent past all of these carbon isotopic compositions are considerably above the extremely 13 c depleted compositions generally 25 to 30 that have been found in many other antarctic and southern ocean studies the elevated 13 c om values derive from considerable depletion of dissolved carbon dioxide and nutrients within the sea ice and to a lesser extent within stratified surface waters induced by melting sea ice thus elevated 13 c om values in southern ocean sediment cores may indicate the presence of sea ice hosted algae rather than temperature or surface co 2 pressure p co 2 variations

bi polar ocean linkages evidence from late holocene antarctic marine and greenland ice core records a continuous 14c dated palaeoenvironmental 4000 year proxy from the antarctic peninsula glacial marine record demonstrates pronounced cycles of elevated palaeoproductivity warm events that rec

rhenium and molybdenum enrichments in sediments as indicators of oxic suboxic and sulfidic conditions of deposition abstract the trace elements re and mo both behave conservatively in seawater yet are strongly enriched in reducing sediments their potential for authigenic enrichment above crustal concentrations is greater than for many other elements due to the high ratio of metal sw metal crust we present sedimentary re and mo data from box and multi cores spanning a range of redox conditions from well oxygenated sites to locations with substantial sulfide concentrations at the oxic sites re and mo as expected accumulate at concentrations close to their crustal abundances re shows substantial enrichment in suboxic absence of o 2 and h 2 s sediments of the sea of japan in sediments within the oxygen minimum of the pakistan margin as well as in sediments underlying the sulfide bearing waters of the black sea and saanich inlet re enrichment occurs in these cores just below the depths of fe and u reduction only in the sediments underlying the sulfidic waters of the black sea and saanich inlet is there substantial authigenic mo accumulation absence of re and mo enrichments in sediment trap samples from the sulfide bearing basins suggests that the addition of both metals occurs at or below the sediment water interface the re and mo concentration profiles are modeled to hindcast the removal depth of re and mo in the sediments which along with the re mo ratio determine whether oxic suboxic or sulfidic conditions were present in the water column or in the sediments in the past using this approach historical redox conditions can be inferred even in environments such as continental margins where a substantial lithogenic component can obscure authigenic enrichments of other metals

regulation of algal blooms in antarctic shelf waters by the release of iron from melting sea ice during summer 1995 96 we measured iron in the water column and conducted iron enrichment bottle incubation experiments at a station in the central ross sea 76 30 s 170 40 w first in the presence of melting sea ice and 17 days later in ice free conditions we observed a striking temporal change in mixed layer dissolved iron concentrations at this station from 0 72 2 3 nm with sea ice present to 0 16 0 17 nm in ice free conditions these changes were accompanied by a significant drawdown in macronutrients and an approximate doubling of algal diatom biomass our incubation experiments suggest that conditions were iron replete in the presence of sea ice and iron deficient in the absence of sea ice we surmise that bioavailable iron was released into seawater from the melting sea ice stimulating phytoplankton production and the biological removal of dissolved iron from the mixed layer until iron limited conditions developed these observations suggest that the episodic release of bioavailable iron from melting sea ice is an important factor regulating phytoplankton production particularly ice edge blooms in seasonally ice covered antarctic waters

application of tandem accelerator mass spectrometer dating to late pleistocene holocene sediments of the east antarctic continental shelf abstract glacial recession from the antarctic continental shelf is recorded by glacial marine diamictons sands and overlying siliceous oozes in order to clarify the chronology for this sequence use was made of the university of arizona tandem accelerator mass spectrometer tams for 14 c dating small samples of benthic and planktonic foraminifera were selectively removed from diamictons graded sands and surface sediments which were recovered from the wilkes land continental shelf and slope east antarctica organic carbon was also utilized as a source for tams dating of the siliceous oozes and muds uncorrected ages varied from 14 260 140 to 3230 200 yr b p carbon fixed by phytoplankton and foraminifera is strongly influenced by old glacial derived co 2 thus reservoir corrections of up to 5500 yr are needed for the 14 c dates iceberg turbation reworks foraminifera so that dates from resulting deposits diamictons are interpreted as maximum ages the consistency of corrected ages from the shelf along with the sedimentologic interpretation suggests a rather recent recession perhaps mid holocene for this portion of the east antarctic ice sheet further application of the tams method should help clarify other problems concerning the late quaternary glacial history of antarctica

contamination and mobilization of arsenic in the soil and groundwater and its influence on the irrigated crops manipur valley india the arsenic concentration in groundwater used for irrigating the rice crops varies from 10 to 475 ppb the disang shales deposited under marine environment appear to be the main source of arsenic contaminating the groundwater the arsenic content in the rice roots vary from 32 to 52 ppm while the arsenic in the grains is far above the limit prescribed by who sequential extraction process results indicate that a large part of arsenic is present in the residual phases high concentration of arsenic at root depth is present in crystalline fe oxides and is available for the rice plants sequential extraction experiment on soils indicate low arsenic content in organic matter compared to the above phases

old radiocarbon ages in the southwest pacific ocean during the last glacial period and deglaciation marine radiocarbon 14c dates are widely used for dating oceanic events and as tracers of ocean circulation essential components for understanding ocean climate interactions past ocean ventilation rates have been determined by the difference between radiocarbon ages of deep water and surface water reservoirs but the apparent age of surface waters currently approximately 400 years in the tropics and approximately 1 200 years in antarctic waters might not be constant through time as has been assumed in radiocarbon chronologies and palaeoclimate studies here we present independent estimates of surface water and deep water reservoir ages in the new zealand region since the last glacial period using volcanic ejecta tephras deposited in both marine and terrestrial sediments as stratigraphic markers compared to present day values surface reservoir ages from 11 900 14c years ago were twice as large 800 years and during glacial times were five times as large 2 000 years contradicting the assumption of constant surface age furthermore the ages of glacial deep water reservoirs were much older 3 000 5 000 years the increase in surface to deep water age differences in the glacial southern ocean suggests that there was decreased ocean ventilation during this period

factors influencing the distribution of diatoms and other algae in the ross sea quantitative microscopic analyses of sediment trap samples collected in the ross sea between january 1990 and february 1992 reveal striking temporal and spatial differences in algal bloom composition and size trap samples from the southwestern ross sea site a 76 30 s 167 30 e were dominated by the diatom fragilariopsis curia maximum of 92 a species associated with both sea ice and the retreating ice edge in the ross sea this species was probably seeded by melting congelation ice highest flux of diatom valves to both upper and lower traps in the 1991 1992 season occurred as a distinct event in mid february 1991 after which flux decreased by 1 to 3 orders of magnitude as overall flux decreased an increase in relative abundance of chaetoceros resting spores and the open water species thalassiosira antarctica was observed in the lower trap suggesting some localized lateral advection in the south central ross sea site b 76 30 s 175 w algal diversity was much higher with a greater contribution of nondiatom material the prymnesiophyte phaeocystis antarctica dinoflagellates and cysts of unknown affinity were much more common than at site a as were the diatoms fragilariopsis cylindrus fragilariopsis kerguelensis and thalassiosira gracilis highest diatom flux occurred later february 20 to march 6 1991 at this site and was an order of magnitude lower as compared to maximum flux at site a distinct differences in bloom size and composition between sites a and b may be a function of upper water column structure differences in the amount of sea ice melting and the type of sea ice present at the time of ice breakout congelation versus pack ice despite rich surface productivities lower silica flux to the seafloor at site b results from the higher proportion of nonsiliceous algae at site c 72 30 s 172 30 e in the northwestern ross sea diatoms again dominated algal flux however assemblage composition differed from that observed at both sites a and b relative abundance of f curta was lower averaging 60 70 while the remainder of the assemblage was made up of f cylindrus other more robust species of fragilariopsis and chaetoceros resting spores algal flux at site c is intermediate in style between sites a and b significantly spatial differences in diatom assemblages noted above appear to be reflected in seafloor surface sediments suggesting that downcore diatom data provide an interpretable record of paleoproductivity in the ross sea

late pleistocene holocene marine conditions in the ross sea antarctica evidence from the diatom record statistical analyses of diatom assemblages from radiocarbon dated sediment cores were used to reconstruct changing palaeoceanographic conditions in the western and west central ross sea antarctica from c 12 14c kyr bp to the present data from three kasten cores support a north to south time transgressive glacial interglacial transition assemblages at the base of each core suggest that glacial processes affecting frustule preservation were significant during the late pleistocene increasing biogenic silic and decreasing per centages of reworked species suggest that upper water column productivity instead of preservational processes increasingly dominates diatom assemblages during grounding line recession c 12to c 6 14c kyr bp a warm ing during the middle to late holocene c 6to c 3 14c kyr bp may have resulted in a spring sea ice melting prior to the annual inception of the ross sea polynya in the west central ross sea and b increased plateletice delivery due to increased melting beneath t

iron deficiency limits phytoplankton growth in antarctic waters enrichment experiments were performed in the ross sea to test the hypothesis that iron deficiency is responsible for the phytoplankton s failure to use up the luxuriant major nutrient supplies found in these and all other offshore antarctic ocean waters nitrate uptake rates in the controls without added trace elements ranged from 0 58 to 1 22 mol kg 1 d 1 the addition of 1 to 5 nmol of unchelated fe per liter resulted in rates that were 2 to 10 times higher 2 54 to 6 00 mol no3 kg 1 d 1 rates in bottles with 2 nmol mn added were identical to those in the controls 0 57 to 1 04 mol no3 kg 1 d 1 total decreases in no3 were balanced by increases in particulate organic n these results suggest that fe deficiency is the primary reason that the present day southern ocean biological pump is shut off in contrast iron was 50 times more abundant during the last glacial maximum greater fe availability may have stimulated the biological pump and contributed to the ice age drawdown of atmospheric c02 these results also imply that large scale southern ocean fe fertilization is feasible at least in terms of the total amounts of fe required i e 100 000 to 500 000 tons yr 1

controls on the carbon isotopic composition of southern ocean phytoplankton carbon isotopic compositions of suspended organic matter and biomarker compounds were determined for 59 samples filtered from southern ocean surface waters in january 1994 along two north south transects woce sr3 from tasmania to antarctica and across the princess elizabeth trough pet east of prydz bay antarctica along the sr3 line bulk organic matter show generally decreasing 13c contents southward which are well correlated with increasing dissolved molecular carbon dioxide concentrations co2 aq this relationship does not hold along the pet transect using concentrations and isotopic compositions of molecular compounds we evaluate the relative roles of several factors affecting the 13c of southern ocean suspended particulate organic matter along the woce sr3 transect the concentration of co2 aq plays an important role it is well described by a supply versus demand model for the extent of cellular co2 utilization and its associated linear dependence of isotopic fractionation ep on the reciprocal of co2 aq an equally important factor appears to be changes in algal assemblages along the sr3 transect with their contribution to isotopic fractionation also well described by the supply and demand model when formulated to include the cell surface volume control of supply changes in microalgal growth rates appear to have a minor effect on ep along the pet transect algal assemblage changes and possibly changes in microalgal growth rates appear to strongly affect the carbon isotopic variations of suspended organic matter these results can be used to improve the formulation of modern carbon cycle models that include phytoplankton carbon isotopic fractionation

diatom evidence for late holocene climatic events in granite harbor antarctica downcore diatom data from a deep basin in granite harbor antarctica provide new high resolution information concerning changes in oceanographic and depositional processes that have occurred during approximately the last 1250 years the influence of global scale climatic change during the time of the medieval warm period and possibly the little ice age is revealed by long term changes in floral assemblages as recorded by changes in the relative concentration of nitzschia cylindrus the diatom data suggest that granite harbor experienced less annual ice and pack ice cover during both these periods possibly because of higher temperatures during the medieval warm period and stronger offshore winds during the little ice age the sedimentary record reveals several distinct short lived events in which nearly monospecific blooms of corethron criophilum and chaetoceros spp occurred possibly the result of strong stabilization of the upper water column and were most likely a response to regional rather than global conditions although short lived these events may play a significant role in the delivery of organic carbon and biogenic silica to the seafloor

productivity cycles of 200 300 years in the antarctic peninsula region understanding linkages among the sun atmosphere oceans sea ice and biota compared to the rest of the world9s oceans high resolution late holocene paleoclimatic data from the southern ocean are still rare we present a multiproxy record from a sediment core retrieved from a deep basin on the western side of the antarctic peninsula that reveals a dramatic perspective on paleoclimatic changes over the past 3700 yr analyses completed include measurement of magnetic susceptibility and granulometry bed thickness particle size percent organic carbon bulk density and microscopic evaluation of diatom and benthic foraminiferal assemblages and abundances downcore variability of these parameters demonstrates the significance of both short term cycles which recur approximately every 200 yr and longer term events 2500 yr cycles that are most likely related to global climatic fluctuations in the upper 600 cm of the core lower values of magnetic susceptibility ms are correlated with lower bulk density the presence of thinly laminated units specific diatom assemblages and generally higher total organic carbon content below 600 cm magnetic susceptibility is uniformly low though variability in other parameters continues the magnetic susceptibility signal is controlled primarily by dilution of ferromagnetic phases with biosiliceous material this signal may be enhanced further by dissolution of magnetite in the magnetic susceptibility lows high total organic carbon the role of variable primary productivity and its relationship to paleoclimate is assessed through the diatom data in particular magnetic susceptibility lows are characterized by higher than normal abundances of chaetoceros resting spores corethron criophilum and or rhizosolenia spp also are found as is a higher ratio of the most common species of fragilariopsis versus species of thalassiosira these assemblages are indicative of periods of high primary productivity driven by the presence of a meltwater stabilized water column the 200 yr cyclicity noted in other paleoclimatic records around the world suggests a global forcing mechanism possibly solar variability in addition to the cyclic changes in productivity overall elevated productivity is noted below 600 cm or prior to ca 2500 yr b p this increased productivity may represent the tail end of a holocene climatic optimum which is widely recognized in other parts of the world but as yet is poorly documented in antarctica

advance of east antarctic outlet glaciers during the hypsithermal implications for the volume state of the antarctic ice sheet under global warming we present the first circum east antarctic chronology for the holocene based on 17 radiocarbon dates generated by the accelerator method marine sediments from around east antarctica contain a consistent high resolution record of terrigenous ice proximal and biogenic open marine sedimentation during holocene time this record demonstrates that biogenic sedimentation beneath the open marine environment on the continental shelf has been restricted to approximately the past 4 ka whereas a period of terrigenous sedimentation related to grounding line advance of ice tongues and ice shelves took place between 7 and 4 ka an earlier period of open marine biogenic sedimentation conditions following the late pleistocene glacial maximum is recognized from the prydz bay ocean drilling program record between 10 7 and 7 3 ka clearly the response of outlet systems along the periphery of the east antarctic ice sheet during the mid holocene was expansion this may have been a direct consequence of climate warming during an antarctic hypsithermal temperature accumulation relations for the antarctic indicate that warming will cause a significant increase in accumulation rather than in ablation models that predict a positive mass balance growth of the antarctic ice sheet under global warming are supported by the mid holocene data presented herein

holocene sediment records from the continental shelf of mac robertson land east antarctica geochemical records are presented for five sediment cores from basins on the continental shelf of mac robertson land east antarctica the cores contain 2 4 m thick sequences of hemipelagic siliceous mud and ooze smo deposited under seasonally open marine conditions the inner and middle shelf smo sequences are massive dark olive green material whereas the outer shelf smo sequences are dark olive material interspersed with light olive green layers 1 10 cm thick the biogenic material is dominated by marine diatoms including fragilariopsis curta fragilariopsis cylindrus and chaetoceros spp in the dark colored smo and corethron criophilum in the light colored layers radiocarbon dates suggest that the cores provide continuous accumulation records extending from 1 kyr before present b p back as far as 4 15 kyr b p with estimated accumulation rates of 0 07 5 mm yr 1 the three core records from the middle and outer shelf suggest six episodes of increased accumulation of biogenic material at 5 5 kyr b p all three cores 1 2 and 6 2 kyr b p two of the three cores and 3 8 and 10 8 kyr b p one core most of which coincide with corethron layers we interpret these features as the result of enhanced diatom production over the outer shelf possibly related to climatic warm periods the absence of such features in the inner shelf core records is thought to reflect a relatively constant level of seasonal diatom production in adjacent waters maintained by a coastal polynya

the distribution and formative processes of latent heat polynyas in east antarctica a study of polynya characteristics in east antarctica was undertaken using ice concentrations derived from special sensor microwave imager data for the period july 1987 august 1994 the areas of polynyas were defined as having an ice concentration 75 the analysis revealed a total of 28 coastal polynyas within the study region the spatial and temporal variability in areal extent was quantified the timing of mean maximum areal extent varied from june to october the bathymetry and wind regime at each polynya site was examined to gauge the relative importance of these parameters in polynya formation and maintenance in 20 locations shallow banks and shoals form grounding zones for icebergs and anchoring sites for fast ice which form barriers to the predominantly westward drift of the pack ice elsewhere north south coastal protrusions or alignments form similar barriers the subsequent removal of newly formed sea ice from the lee of such barriers by katabatic and synoptic winds maintains areas of reduced ice concentration and open water very few coastal polynyas are attributed solely to katabatic outflow the combined influence of bathymetry topography and winds is responsible for the characteristics of the majority of polynyas many were considered to be marginal characterised by occasional periods when the ice concentration falls below 75 an analysis of annual winter totals of areas with ice concentrations 75 shows no trends in total polynya areal extent over the period 1987 94 known locations of emperor penguin aptenodytes forsteri rookeries were also found to be associated with the locations of coastal polynyas

sedimentary geochemistry of manganese implications for the environment of formation of manganiferous black shales the sedimentary geochemistry of manganese is dominated by the redox control of its speciation higher oxidation states mn super 3 and super 4 occurring as insoluble oxyhydroxides in well oxygenated environments and the lower oxidation state mn super 2 being much more soluble in oxygen deficient settings its geochemical behavior is therefore quite different in oxic and anoxic environments and where oxic and anoxic conditions are juxtaposed mn is recycled between the two environments in modern marine sediments mn is present above its crustal abundance as an oxyhydroxide in all slowly accumulating pelagic sediments of the deep ocean and in surficial deposits of continental margin environments diagenetic recycling of mn in the latter causes surficial deposits to have larger mn enrichments than in many pelagic sediments bottom sediments of permanently anoxic basins show no enrichments and have mn concentrations that are controlled solely by the aluminosilicate fraction manganese carbonates kutnohorite and calcic rhodochrosite are found only in anoxic sediments accumulating beneath surface oxic horizons and therefore under oxygenated bottom waters in many nearshore environments such enrichments are due to delivery of mn by burial of surface oxyhydroxides into the subsurface anoxic environment where they are dissolved pore water mn levels can reach saturation with respect to a mixed mn ca carbonate phase in such sediments the diagenetic origin for these phases is shown by their carbon isotope compositions which typically indicate a carbon source from decomposing organic matter the presence of mn carbonates therefore signifies that the host sediment must have accumulated under oxygenated bottom waters on the basis of this information it is proposed that in contrast to several current explanations for the formation of mn carbonates kutnohorite and rhodochrosite in ancient organic rich shales limestone and marl sequences and in many mn ore deposits the occurrence of these mineral phases indicates that the sediments originally accumulated beneath oxygenated bottom waters by analogy with the present mn carbonates could not have formed in the bottom waters of anoxic basins these diagenetic phases however did form where mn was supplied at a high rate namely by the burial of oxyhydroxide enriched surface sediments to a subsurface anoxic environment this situation could only have occurred under oxygenated bottom waters the presence of mn carbonates in ancient black shales and in some carbonate rich rocks lends strong support to the notion that these rocks did not necessarily form in anoxic basins but owe their carbon richness to a high supply of organic matter to sediments deposited under oxygenated bottom waters probably in continental margin settings

magnitude and geographic variation of the radiocarbon content in antarctic marine life implications for reservoir corrections in radiocarbon dating abstract radiocarbon age estimates on marine derined materials from the antarctic appear old in comparison with the terrestrial radiocarbon timescale as a result of significantly depleted 14 c concentrations in antarctic seas we review measurements of 14 c concentrations in modern antarctic marine life from south georgia the shetland islands and antarctic peninsula and suggest correction factors required to relate radiocarbon measurements on fossil marine materials from these areas to the conventional radiocarbon timescale for dates based on shells seaweeds sealbones and penguin bones the minimum correction factor for south georgia is ca 750 years and for the south shetland islands and antarctic peninsula it may be up to 1250 1300 years for whalebones a minimum correction of 1000 years may apply over a wide geographic area for comparison we also review radiocarbon measurements on marine species and seawater from other sectors of the antarctic in high latitudes correction factors of ca 1400 years are generally applicable to shell seal and penguin samples

archean oil evidence for extensive hydrocarbon generation and migration 2 5 3 5 ga archean sedimentary rocks from the pilbara craton australia contain evidence for petroleum generation and migration in the form of bitumen nodules produced by radiogenic immobilization of fluid hydrocarbons around detrital uraninite thorite and monazite grains the nodules are preserved in sandstones at several stratigraphic levels in the fortescue group 2 75 ga and lalla rookh formation 3 0 ga both nonmarine successions and in deltaic sediments of the mosquito creek formation 3 25 ga the most ancient evidence comes from the warrawoona group 3 46 ga where hydrocarbon droplets were apparently formed in situ from kerogenous sediments by flash maturation during early hydrothermal silicification bituminous relics of petroleum are also commonly preserved in shallow marine sandstones of the black reef formation 2 59 ga and the witwatersrand supergroup 2 85 ga from the kaapvaal craton south africa along with subeconomic methane accumulations in all cases the petroleum was apparently sourced from archean shales generated during the archean and migrated before the late archean or early early proterozoic metamorphism occluded fluid pathways given this widespread and abundant evidence for hydrocarbon generation and migration in archean depositional basins it seems that primordial bacterial biomass producing labile type i kerogen was often buried in sufficient quantities to successfully generate and expel petroleum depositional basins on ancient cratons clearly contained permeable rocks amenable to the migration and probably to the accumulation of petroleum thus the main factors precluding the discovery of economically exploitable hydrocarbon accumulations in archean basins are the subsequent destructive effects of deformation and metamorphism which causes trap breaching imperfect sealing or thermal obliteration however there are ancient stable cratons where such disruption may not have occurred and so petroleum explorers may wish to reassess the possibility of finding valuable hydrocarbon resources in archean rocks

physical forcing of phytoplankton dynamics in the southwestern ross sea coastal zone color scanner czcs imagery of phytoplankton pigments and passive microwave imagery of sea ice distributions in the southwestern ross sea are presented for three different seasons 1978 1989 1979 1980 and 1981 1982 and were analyzed in conjunction with meteorological data obtained from a series of automatic weather stations aws dynamics of the phytoplankton bloom in terra nova bay differed from those in the ross sea owing to spatial differences in katabatic wind fields which determine when the surface waters stratify interannual variation in the timing of formation of the ross sea polynya appears to be controlled by winter temperatures which determine sea ice thickness and integrity rather than variability or intensity in wind stress together czcs aws and passive microwave data suggest that when the ross sea polynya forms early stronger and more frequent katabatic winds result in increased advective losses of phytoplankton in surface waters and a delay in the phytoplankton bloom if polynya formation is delayed until after the winds diminish in frequency the phytoplankton bloom will develop earlier the observation that diatoms dominate both the marginal ice zone and terra nova bay which are hydrographically similar while phaeocystis antarctica is found in unstable waters north of the ross ice shelf suggests that stratification plays an important role in determining species composition in the ross sea

coastal zone color scanner pigment concentrations in the southern ocean and relationships to geophysical surface features the spatial and seasonal distributions of phytoplankton pigment concentration over the entire southern ocean have been studied for the first time using the coastal zone color scanner historical data set from october 1978 through june 1986 enhanced pigment concentrations are observed between 35 s and 55 s throughout the year with such enhanced regions being more confined to the south in the austral summer and extending further north in the winter north and south of the polar front phytoplankton blooms 1 mg m3 are not uniformly distributed around the circumpolar region instead blooms appear to be located in regions of ice retreat or high melt areas such as the scotia sea and the ross sea in relatively shallow areas e g the patagonian and the new zealand shelves in some regions of ekman upwelling like the tasman sea and near areas of high eddy kinetic energy such as the agulhas retroflection among all features examined by regression analysis bathymetry appears to be the one most consistently correlated with pigments correlation coefficient being about 0 3 for the entire region the cause of negative correlation with bathymetry is unknown but is consistent with the observed abundance of iron in shallow areas in the antarctic region it is also consistent with resuspension of phytoplankton cells by wind induced mixing especially in shallow waters on the other hand in the deep ocean especially at latitudes 30 in average pigment concentration over the entire region during different seasons indicates possible influence of time dependent parameters

bottom currents sedimentation and ice sheet retreat facies successions on the mac robertson shelf east antarctica abstract measurements of water turbidity currents seafloor sediment samples and geophysical data document the sedimentary processes and the late quaternary sedimentary history of a continental shelf valley system on the east antarctic continental margin the valley is up to 1200 m in depth and strikes across the shelf it is interpreted as having formed by glacial erosion processes on the outer shelf sill of the valley northwestward offshore currents with speeds of up to 0 47 m s referenced to 100 cm above the seabed were recorded over a 10 month period such currents are competent to initiate bedload transport of medium sand and formation of small ripple sized bedforms which explains the occurrence of ripple cross bedding observed in some x radiographs of cores a nepheloid layer with concentrations of up to 3 5 mg l was noted at two stations and the available evidence suggests that density flows resulting from the sea ice brine rejection mechanism are competent to entrain shelf bottom sediments episodically sediment cores taken from this environment document the succession of facies resulting from retreat of glacial ice from the shelf during the holocene transgression under low sea level glacial conditions the ice sheet is interpreted to have been grounded on the outer shelf where it deposited a grounding line moraine rising sea level and global warming caused the ice shelf to retreat leaving a sub ice shelf glacial marine mud this is overlain by a laminated to massively bedded ice rafted debris rich facies interpreted as being deposited at the glacial calving front above this is a siliceous mud and ooze facies having a basal age of about 10 000 years bp characterising modern open marine conditions two types of iceberg keel marks on the outer part of the shelf valley are recognised from sidescan sonographs one relict arcuate type formed during the retreat of the ice shelf prior to 10 000 years bp and a second modern elongate type that is presently being formed near the shelf break by iceberg grounding processes this facies succession has been described from other antarctic shelf environments and is probably representative of facies deposited during holocene glacial retreat from the antarctic shelf

ripple cross laminated sediments on the east antarctic shelf evidence for episodic bottom water production during the holocene abstract biosiliceous sediments sampled from a submarine valley system on the continental shelf of east antarctica contain intervals of ripple cross lamination interspersed with massively bedded units based on radiocarbon dates from one core collected on the mac robertson shelf the most intensely cross laminated sediments were deposited between 6 and 3 5 kyr bp with isolated cross laminae deposited at other times in the holocene the cross laminated sediments are interpreted here as a signal of episodic density currents flowing across the outer shelf which result from the formation of high salinity shelf water hssw this hssw is formed in winter by brine rejection during sea ice formation and by the exchange and cooling of upwelled saline slope water and it contributes to the bottom water produced along the continental margin of antarctica if this interpretation of the cross laminae is correct then bottom water formation and export from the east antarctic shelf has exhibited temporal and probably also spatial variability throughout the holocene such variability would have implications for oceanographers attempting to quantify antarctic bottom water production rates based only on present day observations

biogenic opal in southern ocean sediments over the last 450 000 years implications for surface water chemistry and circulation we present records of biogenic opal percentage and burial rate in 12 piston cores from the atlantic and indian sectors of the southern ocean these records provide a detailed quantitative description of changing patterns of opal deposition over the last 450 kyr the striking regional coherence of these records suggests that dissolution in the deep sea and sediment pore waters does not obscure the surface productivity signal and therefore these opal time series can be used in combination with other surface water tracers to make inferences about the chemistry and circulation of the southern ocean under different global climate conditions three broad depositional patterns can be distinguished northernmost records 39 42 s latitude are characterized by enhanced opal burial during glacial periods and strong 41 kyr periodicity records from cores just north of the present antarctic polar front 46 49 s show even larger increases in opal burial rate during glacial intervals but have variance concentrated in the 100 and 23 kyr bands southernmost records 51 55 s are completely out of phase with those to the north with greatly reduced opal burial rates during glacial periods taken as a whole the opal records show no evidence for the increased total antarctic productivity predicted by recent geochemical models of atmospheric co2 variability the areal expansion of southern ocean sea ice over the present zone of high siliceous productivity provides one plausible explanation for the glacial interglacial opal patterns the excess silica not taken up in this zone during glacial periods would contribute to greater nutrient availability and thus higher productivity in the subantarctic region however local circulation changes may act to modify this basic signal possibly accounting for the observed differences in the opal variance spectra

recent diatom record of mcmurdo sound antarctica implications for history of sea ice extent analyses of diatom assemblages within surface sediments from mcmurdo sound antarctica document the regional circulation patterns in this large embayment in the southwestern ross sea thalassiosira spp indicative of water column primary productivity is most common in eastern and portions of northwestern mcmurdo sound as a result of its advection into these regions from areas of open water primary productivity surface sediments from southwestern mcmurdo sound are composed mainly of nitzschia curta a small pennate form commonly found both as a member of the sea ice microbial community as well as a dominant component in ice edge blooms in the ross sea the northward advection of oligotrophic water into the western sound from beneath the mcmurdo ice shelf results in the dominance of an autochthonous flora in the southwestern sound sediments deposited during the past 500 years also have been dominated by thalassiosira spp and nitzschia curta thalassiosira spp concentrations reached a maximum between 1600 and 1875 a d corresponding to the time of the little ice age more persistent winds may have been responsible for more prevalent polynyas at that time resulting in greater amounts of open water primary productivity and subsequent higher percentages of thalassiosira spp increased areal extent and or duration of coastal polynyas during the little ice age suggests that within the southwestern ross sea the production of high salinity shelf water and hence antarctic bottom water may have been greater at that time

late pleistocene holocene sedimentary fluxes of organic carbon and biogenic silica in the northwestern ross sea antarctica eight sediment gravity cores collected from thejoides and drygalski basins were analysed in order to understand late pleistocene holocene biogenic dux changes in the ross sea driven by paleoenvironmental changes core lithologies and magnetic susceptibility depth profiles were used for core logging and stratigraphic corre lation nineteen ams radiocarbon dates of bulk organic matter were used to set chrono logical constraints and calculate sediment accumulation rates these rates which vary from 1 4 38 cm ka i were used to obtain the burial f1uxes of biogenic components the highest f uxes occur in the deepest parts o the basins toc 0 05 0 2 g cm 2 ka i biogenic silica 1 5 5 g cm 2 ka i whereas topographic highs show the lowest values toc 0 010 1 g cm 2 ka i biogenic silica 0 1 1 4 g cm 2 ka i dramatic changes in both physical properties and fluxes record the establishment of open marine sedimentation conditions which occurred first in thejoides basin and then with a delay of ca 6000 years in the drygalski basin both toc and biogenic silica ouxes increase through the holocene though slightly difterently the high f1uxes of both lobe and biogenic ba suggest that sedi ment accumulation at basin sites is strongly influenced by lateral transport

pre bomb radiocarbon and the reservoir correction for calcareous marine species in the southern ocean four antarctic marine mollusc shells which were collected alive between 1917 and 1940 were analyzed by accelerator mass spectrometry to provide the first pre bomb radiocarbon measurements of biogenic carbonates from the southern ocean after correcting for the impact of fossil fuel combustion suess effect radiocarbon activities of the pre bomb shells averaged 149 8 10 4 in contrast the 14c values for post bomb molluscs echinoderms brachiopods and foraminifera averaged 96 1 25 2 these biogenic carbonate 14c values are nearly identical to pre bomb estimates 148 to 152 and post bomb measurements 98 4 22 0 of the surface waters in the southern ocean average radiocarbon ages of the biogenic carbonates before and after 1950 1303 84 years and 811 205 years respectively along with those from seals and penguins indicate that the antarctic marine radiocarbon reservoir has decreased in age by nearly 500 years during the second half of the 20th century marine species and seawater measurements firmly place the radiocarbon reservoir correction at 1300 100 years for calcareous marine fossils which are widespread abundant and well preserved organic materials for interpreting ice sheet climate and sea level impacts on the antarctic marine ecosystem during the holocene

on the circulation and water masses over the antarctic continental slope and rise between 80 and 150 e abstract the circulation and water masses in the region between 80 and 150 e and from the antarctic continental shelf to the southern boundary of the antarctic circumpolar current acc 62 s are described from hydrographic and surface drifter data taken as part of the multi disciplinary experiment baseline research oceanography krill and the environment broke two types of bottom water are identified adelie land bottom water formed locally between 140 and 150 e and ross sea bottom water ross sea bottom water is found only at 150 e whereas adelie land bottom water is found throughout the survey region the bottom water mass properties become progressively warmer and saltier to the west suggesting a westward flow all of the eight meridional ctd sections show an antarctic slope front of varying strength and position with respect to the shelf break in the water formation areas between 140 and 150 e and 104 e the antarctic slope front is more v shaped while elsewhere it is one sided the shape of the slope front and the presence or absence of water formation there are consistent with other meridional sections in the weddel sea and simple theories of bottom water formation gill 1973 deep sea research 20 111 140 whitworth et al 1998 in jacobs and weiss eds ocean ice and atmosphere interactions at the antartic continental margin antarctic research series american geophysical union washington pp 1 27 adcp surface velocities and buoy drift tracks show a strong westward flow over the shelf and slope regions in the region 90 100 e there is a strong eastward flow of the waters just south of the southern boundary of the acc suggesting a recirculation of the westward slope current and the presence of a weak cyclonic gyre using the adcp velocities as a reference for the ctd data the average westward transport in this region is 29 4 14 7 sv

sedimentation on the ross sea continental shelf antarctica abstract glacial marine sedimentation has prevailed throughout most of the early glacial history of the ross sea region however since late miocene to early pliocene time the west antarctic ice sheet has advanced onto the continental shelf perhaps several times glacial troughs of the western ross sea may also have formed at this time these glacial troughs border outlet glaciers of the east antarctic ice sheet a widespread lodgement till facies was deposited during this glacial advance holocene retreat of this expanded ice sheet left no conspicuous meltwater record so decoupling of the ice sheet from the seafloor rather than rapid melting is implied modern glacial sediment is far less prevalent than biogenic sediment and reworked glacial sediment except in coastal areas adjacent to small ice shelves and ice tongues little or no debris is being transported beyond the calving line of the ross ice shelf siliceous mud and ooze occurs in the western ross sea where surface circulation is most vigorous and warm deep waters up well this siliceous sediment along with terrigenous silt and clay blankets the seafloor below approximately 300 m water depth most of the ross sea continental shelf is deeper than this surface sediments on shallow banks and coastal platforms have clearly been reworked by marine currents the most vigorous bottom current activity occurs in those areas where geostrophic currents impinge onto the shelf debris flows and turbidity currents are also important in eroding and redistributing glacial sediments on the shelf terrigenous silt and clay are more abundant in surface sediment than basal till the source of this silt and clay is problematic the most plausible sources being onshore transport of suspended sediment by impinging currents and subglacial meltwater input

chronology of the palmer deep site antarctic peninsula a holocene palaeoenvironmental reference for the circum antarctic palmer deep sediment cores are used to produce the first high resolution continuous late pleistocene to holocene time series from the antarctic marine system the sedimentary record is dated using accelerator mass spectrometer radiocarbon methods on acid insoluble organic matter and foraminiferal calcite fifty four radiocarbon analyses are utilized in the dating which provides a calibrated timescale back to 13 ka bp reliability of resultant ages on organic matter is assured because duplicates produce a standard deviation from the surface age of less than laboratory error i e 50 years in addition surface organic matter ages at the site are in excellent agreement with living calcite ages at the accepted reservoir age of 1260 years for the antarctic peninsula spectral analyses of the magnetic susceptibility record against the age model reveal unusually strong periodicity in the 400 200 and 50 70 year frequency bands similar to other high resolution records from the holocene but so far unique f

late pleistocene holocene retreat of the west antarctic ice sheet system in the ross sea part 2 sedimentologic and stratigraphic signature sedimentologic geotechnical geochemical and accelerator mass spectrometer ams radiocarbon data from two marine geologic cruises in the ross sea have allowed us to constrain facies relationships and temporal changes in the west antarctic ice sheet the selection of core sites was facilitated by the use of multibeam bottom imagery and a good quality chirp subbottom reflection system a complex but consistent succession of facies documents a number of environments from subglacial to open marine massive mud rich diamictons have low water contents contain in places a calcareous microfossil assemblage show minimal textural variation and contain low and uniform total organic carbon values this reflects a subglacial setting this unit passes upward into a stratified thin granulated facies consisting of pelletized sandy muddy gravel that is loosely compacted and contains a variable water content and concentrated horizons of pebble sized clasts this facies reflects the lift off zone or thin water film between the basal debris and sea floor overlying this unit are silty clays that contain a well sorted very fine grained sand component there are no coarse grains within this unit this facies is in part laminated and reflects deposition beneath an ice shelf near and away from the grounding line zone the ice shelf facies passes upward into a siliceous mud and ooze unit that represents deposition in an open marine setting a sandy volcaniclastic rich subfacies marks the transition from ice shelf to open marine environments found at the calving line the 86 ams radiocarbon dates on organic matter provide an accurate chronology for 19 cores ice shelf conditions were established in the outer drygalski trough by 11 0 25 ka and perhaps earlier this transition took place in the joides basin by 10 8 ka the calving front of the ross ice shelf passed over the drygalski trough at 74 s by 9 5 0 25 ka the timing of deglaciation in the ross sea calls into question current models for the contribution of antarctic glacial ice to holocene sea level rise and suggests that recession was relatively gradual and more closely aligned with northern hemisphere deglaciation and its associated eustatic pulse

cycling of organic carbon and biogenic silica in the southern ocean estimates of water column and sedimentary fluxes on the ross sea continental shelf we examined the cycling of organic carbon and biogenic silica in the water column and upper sediments of the ross sea seeking to understand the processes leading to the formation of opal rich organic poor sediments over much of the southern ocean between january 1990 and december 1994 we conducted three cruises performing tracer incubation studies 14c 15n 30si 32si to measure rates of primary production nitrate based new production biogenic silica production and biogenic silica dissolution in the upper 50 m over most of the ross sea shelf in spring mid summer and late summer we deployed sediment traps from january 1990 to early march 1992 to measure the mid water 250 m and near bottom gravitational fluxes of particulate organic carbon nitrogen and biogenic silica year round at three sites and obtained sediment cores at 15 sites to assess the accumulation rates of organic carbon and biogenic silica in all known sediment regimes on the shelf at 9 of those sites we also measured nutrient efflux from the sediments enabling us to calculate benthic recycling fluxes of organic matter and opal these data permit estimates of the annual production near surface recycling vertical sinking flux delivery to the seabed benthic regeneration and long term burial of both organic and siliceous material integrated over a 3 3 105 km2 area that covers 75 80 of the ross sea shelf the resulting annual budgets for carbon and silica indicate highly selective preservation of biogenic silica over organic carbon between 50 and 250 m in the water column as well as in the upper seabed selective preservation of silica within the upper 50 m is not indicated and both organic matter and silica are transported from 250 m to the sea floor with virtually 100 efficiency the sio2 c mass ratios for surface layer production 250 m sinking flux delivery to the seabed and long term burial are approximately 0 85 6 1 6 2 and 27 respectively this progressive enrichment in silica results in long term burial of 5 8 of the biogenic silica and 0 17 of the organic carbon produced by phytoplankton in the surface layer a factor of 30 greater preservation efficiency for silica than for carbon nevertheless the ratio of opal burial to opal production in the ross sea is only about twice the apparent global average of 3 and 1 3 of the estimated burial production ratio for the southern ocean as a whole it thus appears that both silica preservation and the decoupling between the cycles of silica and carbon must be even more effective in the waters overlying abyssal southern ocean sediments than they are over the ross sea shelf

microfossil and stable isotope evidence for changes in late holocene palaeoproductivity and palaeoceanographic conditions in the prydz bay region of antarctica microfaunal and microfloral data from two gravity cores and stable isotope results from one of these cores taken on fram bank near prydz bay antarctica indicate changes in sea ice patterns and oceanographic conditions which may have been linked to regional and global climate changes that occurred over the past 8000 yr modern diatom assemblages indicative of ice free conditions 1 2 months of the year and dominated by nitzschia species became prevalent some time around 2000 2700 yr b p the occurrence of chaetoceros spp diatom spore dominated assemblages and increased abundances of benthic and planktonic foraminifera ostracods and diatoms coupled with carbon and oxygen isotope changes around 2700 3400 yr b p strongly suggests that this area of the shelf experienced conditions conducive to increased productivity during this time period based on diatom assemblage associations recognized in modern environments the upper water column of fram bank shelf waters was probably stratified during that time due to the presence of low salinity melt water and a very shallow mixed layer protected from storms with sea ice cover for less than 10 months per year the close correspondence of 13c and 18o values from n pachyderma r2 0 74 throughout one core suggests that whatever oceanographic conditions influenced 18o also influenced 13c changes in prydz bay microfossil abundances and isotopes may result from alterations in circulation patterns upwelling conditions or sea ice patterns which significantly affected benthic and planktonic productivity in the area the environmental conditions indicated by older sediments in the cores are less clear but an ice tongue may have been in place 3200 3800 yr b p and minor fluctuations in productivity are indicated around 6000 and 7000 7500 yr b p the lower 100 cm of both cores may not represent in situ deposition but if the corrected ams dates reflect the actual age of the sediments analyzed microfossil and isotope data indicate that productivity and oceanographic conditions were very variable around 8500 8600 yr b p the chronology adopted herein must be regarded as tentative until further study of the area has been undertaken