uranium series dating of pedogenic silica and carbonate crater flat nevada a 230th 234u 238u dating study on pedogenic silica carbonate clast rinds and matrix laminae from alluvium in crater flat nevada was conducted using small sample thermal ionization mass spectrometry tims analyses on a large suite of samples though the 232th content of these soils is not particularly low mostly 0 1 9 ppm the high u content of the silica component mostly 4 26 ppm makes them particularly suitable for 230th u dating on single 10 to 200 mg totally digested samples using tims we observed that 1 both micro within rind and macro stratigraphic mappable deposit order of the 230th u ages were preserved in all cases 2 back calculated initial 234u 238u fall in a restricted range typically 1 67 0 19 so that 234u 238u ages with errors of about 100 kyr 2 could be reliably determined for the oldest 400 to 1000 ka rinds and 3 though 13 of the samples were 350 ka only three showed evidence for an open system history even though the sensitivity of such old samples to isotopic disruption is very high an attempt to use leach residue techniques to separate pedogenic from detrital u and th failed yielding corrupt 230th u ages we conclude that 230th u ages determined from totally dissolved multiple sub mm size subsamples provide more reliable estimates of soil chronology than methods employing larger samples chemical enhancement of 238u 232th or isochrons

evidence from u th dating against northern hemisphere forcing of the penultimate deglaciation milankovitch proposed that summer insolation at mid latitudes in the northern hemisphere directly causes the ice age climate cycles1 this would imply that times of ice sheet collapse should correspond to peaks in northern hemisphere june insolation but the penultimate deglaciation has proved controversial because june insolation peaks 127 kyr ago whereas several records of past climate suggest that change may have occurred up to 15 kyr earlier2 3 4 5 6 7 8 there is a clear signature of the penultimate deglaciation in marine oxygen isotope records but dating this event which is significantly before the 14c age range has not been possible here we date the penultimate deglaciation in a record from the bahamas using a new u th isochron technique after the necessary corrections for recoil mobility of 234u and 230th and a small age correction for sediment mixing the midpoint age for the penultimate deglaciation is determined to be 135 2 5 kyr ago this age is consistent with some coral based sea level estimates but it is difficult to reconcile with june northern hemisphere insolation as the trigger for the ice age cycles potential alternative driving mechanisms for the ice age cycles that are consistent with such an early date for the penultimate deglaciation are either the variability of the tropical ocean atmosphere system or changes in atmospheric co2 concentration controlled by a process in the southern hemisphere

recognition of non milankovitch sea level highstands at 185 and 343 thousand years ago from u th dating of bahamas sediment abstract thirty one new bulk sediment u th dates are presented together with an improved 18o stratigraphy for odp site 1008a on the slopes of the bahamas banks these ages supplement and extend those from previous studies and provide constraints on the timing of sea level highstands associated with marine isotope stages mis 7 and 9 ages are screened for reliability based on their initial u and th isotope ratios and on the aragonite fraction of the sediment twelve reliable dates for mis 7 suggest that its start is concordant with that predicted if climate is forced by northern hemisphere summer insolation following the theory of milankovitch but u th and 18o data indicate the presence of an additional highstand which post dates the expected end of mis 7 by up to 10 ka this event is also seen in coral reconstructions of sea level it suggests that sea level is not responding in any simple way to northern hemisphere summer insolation and that tuned chronologies which make such an assumption are in error by 10 ka at this time u th dates for mis 9 also suggest a potential mismatch between the actual timing of sea level and that predicted by simple mid latitude northern hemisphere forcing four dates are earlier than that predicted for the start of mis 9 although the most extreme of these dates may not be reliable based on the low aragonite content of the sediment the other three appear robust and suggest that full mis 9 interglacial conditions were established at 343 ka this is 8 ka prior to the date expected if this warm period were driven by northern hemisphere summer insolation

uranium 234 anomalies in corals older than 150 000 years we present new precise u th ages of well preserved coral specimens collected from the island of barbados west indies and the atoll of mururoa french polynesia our new data confirm the ages attributed to oxygen isotope stage 7 in the framework of the milankovitch theory berger 1978 mar tinson et al 1987 by using thermal ionization mass spectrometry tims it is also possible to quantify precisely the 234u238u ratios in corals samples older than 150 kyr b p are shown to be characterized by significant excesses of 234u relative to the uranium isotopic composition expected if the corals grew in present day sea water assuming that the 230th ingrowth ages are accurate these anomalies translate into high initial 234u238u ratios about 1 2 at 200 kyr and up to 1 5 at about 450 kyr b p we propose that the anomalies result from both diagenetic addition and replacement of u and possibly from global changes in the 234u238u composition of sea water through time the 234u anomalies cast doubt on the accuracy of the classical 230th ingrowth dating method in old corals and in particular for the use of measured 234u238u ratios alone to date corals older than 150 kyr

the u series toolbox for paleoceanography the geochemistry of marine sediments is a major source of information about the past environment of the many measurements that provide such information those of the u series nuclides are unusual in that they inform us about the rate and timescales of processes oceanic processes such as sedimentation productivity and circulation typically occur on timescales too short to be assessed using parent daughter isotope systems such as rb sr or sm nd so the only radioactive clocks that we can turn to are those provided by cosmogenic nuclides principally 14c or the u series nuclides this makes the u series nuclides powerful allies in the quest to understand the past ocean climate system and has led to their widespread application over the last decade as in other applications of the u series those in paleoceanography rely on fractionation of the nuclides away from secular equilibrium in the oceanic setting this fractionation is generally due to differences in the solubility of the various nuclides the behavior of the u series nuclides in the ocean environment was widely researched in the middle decades of the twentieth century this work established knowledge of the concentrations of the nuclides in the various compartments of the ocean system and of their fluxes between these compartments such understanding was comprehensively summarized in the ivanovich and harmon u series volume 1992 particularly by cochran 1992 understanding of the behavior of the u series nuclides has not advanced very dramatically in the decade since that summary but a major theme of research has been the use of this geochemical understanding to develop u series tools to assess the past environment table 1 view this table table 1 summary of seawater data for u series nuclides with paleoceanographic applications s soluble i insoluble full descriptions of the paleoceanographic uses and references are provided in the text further details of the half

dissolved redox sensitive elements re u and mo in intense denitrification zone of the arabian sea the concentrations of redox sensitive elements rhenium uranium and molybdenum have been measured in the suboxic water column of the arabian sea to determine their response behavior to intense oxygen minima and denitrifying conditions in the water column north of 12 n within the core of the intense oxygen minimum zone omz of the arabian sea the dissolved oxygen levels drop to values as low as 5 m accompanied by the presence of secondary nitrite maxima snm indicating the occurrence of denitrification in the water column the distributions of re u and mo in the arabian sea show that their dissolved concentrations in the suboxic layer are indistinguishable from those in the overlying and underlying oxic waters suggesting that there is no discernible removal of these elements from the suboxic denitrifying layers in contrast the lateral and vertical distribution of dissolved re u and mo concentrations vary as a function of salinity suggesting their conservative behavior the salinity normalized 35 re u and mo concentrations in the arabian sea are 40 pmol kg 13 8 nmol kg and 114 nmol kg respectively these concentrations are nearly identical to their abundances in the bay of bengal a basin adjacent to the arabian sea characterized by high freshwater influx and fluvial sediments the similarity in concentration suggests that the large variability in the biogenic and detrital particulate fluxes and the suboxic denitrifying conditions between these two oceanic regions do not affect the concentrations of re u and mo and that the prevailing biogeochemical conditions in these regions are inadequate for their removal from the water column

constant bottom water flow into the indian ocean for the past 140 ka indicated by sediment 231pa 230th ratios a down core 231pa 230th record has been measured from the southwestern indian ocean to reconstruct the history of deep water flow into this basin over the last glacial interglacial cycle the 231paxs 230thxs 0 ratio throughout the record is nearly constant at approximately 0 055 significantly lower than the production ratio of 0 093 indicating that the proxy is sensitive to changes in circulation and or sediment flux at this site the consistent value suggests that there has been no change in the inflow of antarctic bottom water to the indian ocean during the last 140 ka in contrast to the changes in deep circulation thought to occur in other ocean basins the stability of the 231paxs 230thxs 0 value in the record contrasts with an existing sortable silt ss record from the same core the observed ss variability is attributed to a local geostrophic effect amplifying small changes in circulation a record of authigenic u from the same core suggests that there was reduced oxygen in bottom waters at the core locality during glacial periods the consistency of the 231paxs 230thxs 0 record implies that this could not have arisen by local changes in productivity thus suggesting a far field control either globally reduced bottom water oxygenation or increased productivity south of the opal belt during glacials

co2 release variations during the last 2000 years at the colli albani volcano roma italy from speleothems studies abstract the colli albani is the quiescent volcano that dominates the southwestern skyline of roma italy the last eruption occurred during the holocene from the eccentric albano maar along its western slope the volcano is presently affected by cyclic seismic swarms ground uplift and diffuse co 2 degassing the degassing has caused several deadly incidents during the last years and constitutes a major civil protection concern as the volcano slopes are densely inhabited nevertheless the volcano does not have a permanent monitoring network and the background level and anomalous co 2 levels the relationship between the gas release and the seismic and ground deformation activity at the colli albani are still to be defined the aim of this work is to define the historical record of co 2 release evidences of deep co 2 periodic release during the last 2000 years in the area of colli albani volcano roma italy are offered from speleothems studies a roman age stone mine now used for mushroom cultivation is decorated with actively growing speleothems characterised by depositional hiatuses different levels of four stalactites separated by depositional unconformities and several samples from a single depositional cycle belonging to a stalagmite have been dated by u th method and analysed for their o and c isotopic composition eight cycles of deposition have been identified from 90 110 a d to 1350 1370 a d some of which are recognised across different speleothems the age gap dividing different growth layers is in the order of one to few hundred years giving a temporal span for periodic interruption of speleothems deposition o and c isotopic analyses performed on the samples collected from a single cycle the oldest have shown that the composition of the mother solutions was initially mainly meteoric and that a progressive increase in the input of a deep component rich in co 2 up to a proportion of 20 30 occurred just before the interruption of the speleothem deposition this could be due to a progressive increase of the acidity of the water solutions that caused the undersaturation of fluids if we extrapolate this mechanism to the other cycles of deposition being characterised by analogue isotopic compositions we can hypothesise periods of deposition interrupted by episodes of co 2 release which in the colli albani volcano are often recorded in coincidence with earthquakes therefore we have correlated the hiatuses with some of the largest historical earthquakes interesting to the city of rome

tims u series dating and stable isotopes of the last interglacial event in papua new guinea the extensive flight of uplifted reef terraces which occurs along the vitiaz strait on the northern flank of the huon peninsula in png papua new guinea contains a particularly good record of sea level changes in the last 250 ky the huon terraces were the target of an international expedition which took place in july august 1988 in particular we searched for suitable samples for u series dating in a reef complex designated as vii which is correlated with the last interglacial episode and high sea level stand this complex is composed of a barrier reef viib a lagoon and a fringing reef viia twelve corals from these terraces and two corals from the older reef complex viii were selected for analysis the petrography oxygen and carbon isotope compositions and magnesium and strontium concentrations were determined along with the concentrations and isotopic compositions of uranium and thorium 230 th 234 u ages of the corals with 99 aragonite having primary textures and which show u sr ratios around 0 4 10 3 and initial 234 u values close to that of present seawater appear to be reliable the most reliable ages from complex vii corals fall in two tight groups centered at 118 ky and 134 ky corals with 234 u t values higher than 160 and u sr ratios substantially lower than seawater are assumed to have undergone diagenetic alteration which appears to be common in this area the simplest model for sea level height for terrace vii is a continuous rise between 134 and 118 ky alternatively there may have been two periods of rapid sea level rise in contrast in the bahamas there is evidence that sea level remained rather constant over the time interval 132 to 120 ky the absence of ages between 132 and 120 ky in png could be the result of changes in the local tectonic uplift rates during that time or erosion that disrupted the continuous record in any event we find no basis for accepting a single brief time for the age of the last interglacial and applying this age as a precise chronometer for worldwide correlation or as a test of climatic models the older ages reported here precede the milankovitch solar insolation peak at 128 ky and the younger ages are 10 ky after this peak if the present high precision data are correct then it will be necessary to reassess the validity of the milankovitch theory of climatic changes the fundamental issue which must now be resolved is a means of identifying coral samples that have not been disturbed by diagenetic processes

pelagic sedimentation on an inactive gullied slope northwest providence channel bahamas abstract the southern flank of little bahama bank is a deep water carbonate slope into which a series of closely spaced canyons 10 200 m deep have been cut it is similar in morphology to many other slopes in the bahamas and these slopes are generally considered to be created by the erosion of downslope sediment gravity flows however little evidence for downslope sediment movement or associated erosion were found in the holocene or latest pleistocene sediments of the slope reported on here the sediments from water depths below 260 m consist of a uniform pelagic drape covering both the gullies and inter gully ridge tops high resolution seismic reflectors are not truncated along individual gully walls and the fine scale stratigraphy of the sediments recorded in glacial interglacial changes in the aragonite calcite ratio of the sediments is preserved in sediments from gullies and ridge tops it appears that for the last two to three glacial cycles there has been only minor downslope transport of sediment despite the gullied morphology erosion is not presently occurring on the slope

234u 238u mass spectrometry of corals how accurate is the uth age of the last interglacial period direct measurement of u and th by mass spectrometry recently provided a spectacular improvement in the precision of coral dating by the uth disequilibrium method 1 mass spectrometric data also provide a much better resolution for the examination of subtle diagenetic effects revealed by small variations of the 234u 238u ratio such perturbations may strongly affect the accuracy of the uth chronometer a compilation of all the corals analyzed to date by mass spectrometry shows that most of the corals from terraces of the last interglacial have initial 234u 238u ratios higher than present day seawater in contrast to modern holocene and last glacial corals some samples that have very high 234u 238u initial ratios up to 1 2 and high u concentrations up to 4 ppm were probably contaminated by continental groundwaters however even apparently pristine samples have 234u 238u initial ratios which are still slightly higher than present day seawater mean value 1 160 compared to 1 140 1 150 2 with little overlap between the two distributions this difference in the u initial ratio raises some uncertainty about the accuracy of the uth age determinations of these corals in spite of the fact that the 234u230th ages cluster in a narrow range between 122 and 133 kyr the data could also be interpreted as resulting from slight contamination of corals that are significantly older than 125 kyr two possible explanations may explain these data 1 all these samples may have been diagenetically altered since they all come from surface outcrops which have been directly exposed to precipitations or soil waters for 125 kyr in this case the true age of these corals remains uncertain depending on the timing of the alteration process i e initial late or continuous 2 the second possibility is that some of the differences in 234u 238u ratios measured in 125 kyr cold corals compared to modern seawater may be due to a higher 234u 238u ratio in seawater 125 kyr ago this could result from temporal variations in the weathering regimes of continental land masses

new 230th u and 14c ages from lake lahontan carbonates nevada usa and a discussion of the origin of initial thorium five sets of coeval lacustrine carbonate samples from pleistocene lake lahontan in western nevada were dated by both the ams 14c and 230th u isochron methods all five groups of samples were analyzed for u th isotopes by alpha spectrometry and one of the groups was additionally measured by thermal and secondary ionization mass spectrometry tims and sims for comparison the 14c ages were corrected to calendar years using the calibration curve recommended by bard et al 1992 without local reservoir correction on the 14c ages mean 230th u isochron ages of some sets are apparently older than their calendar corrected 14c ages by up to 2300 years modern carbon contamination of these carbonate samples through recrystallization or deposition of secondary calcite is likely to be responsible for part of the age discrepancies we explored additional biases associated with the isochron ages maybe produced by the presence of initial th coprecipitated from the lake water it can be shown that if dissolved hydrogenous th is directly incorporated into the pure carbonates then the three component mixing among 1 detrital th 2 hydrogenous th adsorbed on detritus and 3 hydrogenous th incorporated by the carbonate can introduce a positive age bias we have developed an approach to estimate the magnitude of this bias of the lake lahontan carbonates the preliminary estimates suggest a positive age bias of 1000 to 2000 years for two sets of the samples

measurement of adsorbed and total 232th 230th ratios from marine sediments the predictable in situ production of 230th from the decay of uranium in seawater and its subsequent removal by scavenging onto falling particles provides a valuable tool for normalizing fluxes to the seafloor we describe a new application determination of the 232th that dissolves in the water column and is removed to the seafloor 232th is supplied to the ocean in continental minerals dissolution of which leads to a measurable standing stock in the water column sedimentary adsorbed 232th 230th ratios have the potential to provide a proxy for estimating the amount of dissolved material that enters the ocean both today and in the past ten core top samples were treated with up to eight different leaching techniques in order to determine the best method for the separating adsorbed from lattice bound thorium in addition separate components of the sediments were analyzed to test whether clay dissolution was an important contribution to the final measurement there was no systematic correlation between the strength of acid used in the leach and the measured 232th 230th ratios in all cases clean foraminifera produced the same ratio as leaches on bulk sediment in three out of five samples leaches performed on non carbonate detritus in the 63 mu m size fraction were also identical without additional water column data it is not yet clear whether there is a simple one to one correlation between the expected deep water 232th 230th and that produced by leaching especially in carbonate rich sediments however higher ratios and associated high 232th adsorbed fluxes were observed in areas with high expected detrital inputs the adsorbed fraction was 35 50 of the total 232th in seven out of ten samples our 230th normalized 232th fluxes are reasonable by comparison to global estimates of detrital inputs to the ocean in nine cases out of ten the total 230th normalized 232th flux is greater than predicted from the annual dust fall at each specific location but lower than the average global detrital input from all sources

variation in bioturbation with water depth on marine slopes a study on the little bahamas bank abstract reconstructing the paleoceanography of intermediate depth waters is dependent on sedimentary records preserved on marine slopes but knowledge of bioturbation processes in such slope environments is much poorer than for the deep sea in this study 210 pb profiles were measured for the upper 20 cm of sediment from five box cores taken on the slopes of the bahamas in water depths ranging from 400 to 1500 m these were compared with data from the bahamas bank tops and from elsewhere to assess the rate and depth of mixing in the slope environment excess 210 pb inventories are too high to explain by water column decay of 226 ra and are derived largely from atmospheric fallout down core 210 pb xs profiles show an upper zone where 210 pb xs activities decrease exponentially with depth suggesting uniform mixing and a lower zone with patchy 210 pb values reflecting isolated burrows in contrast to bank top sediment which shows 210 pb xs mixing to depths of 40 cm and mixing rates of 1000 cm2 kyr mixing of 210 pb on the slopes penetrates to only 8 cm with mixing rates of 210 pb derived mixing activity in ocean margin sediments diffusive versus nonlocal mixing j mar res 54 1207 1227 a simple model is used to assess the effects of mixing on typical bahamian slope sediments which have deposition rates and compositions which vary dramatically in response to sea level change proxy records such as 18 o are expected to be displaced by up to 0 8 kyr in bulk sediment and individual sediment constituents may be moved by up to 2 kyr relative to one another these mixing effects are reasonably small and may be safely ignored for some studies but for high resolution records or studies where precise age control is important bioturbation of slope sediments should be considered

isotopic approaches for quantifying the rates of marine burial diagenesis 1 diagenetic reactions in marine sediments have the potential to alter geochemical proxy records and affect the global carbon cycle over tens of thousands to millions of years this article describes advances in the use of ca sr and u series isotopes in constraining carbonate recrystallization and silicate dissolution rates in marine systems we specifically focus on recent efforts that interpret isotope variability in marine pore fluids using reactive transport models of varying complexity such studies suggest that calcite recrystallization rates are significant over time scales 1 myr approaching exchange rates of 0 4 1 myr 1 over longer time scales isotopic data point to continued exchange between calcite and coexisting pore fluid though at lower rates than in young sediments extrapolating these recrystallization rates over tens of millions of years we quantify the extent to which geochemical climate proxies such as mg ca in calcite can be altered diagenetically in some cases such diagenetic effects significantly affect the interpretation of long term climatic trends as well as determinations of absolute paleotemperatures silicate dissolution rates in siliclastic marine sediments appear to be similar in magnitude to dissolution rates in terrestrial environments 10 7 10 6 yr 1 such estimates suggest that silicate weathering in marine sediments may play an important role in the carbon cycle at least over time scales approaching 400 500 kyr

234u 238u ratios and230th ages for hateruma atoll corals implications for coral diagenesis and seawater234u 238u ratios published results for corals that are more than ca 50 ka old from for example barbados and vanuata often yield initial 234u 238u activity ratios that are significantly greater than 1 144 0 004 the value for modern seawater this study reports results for corals from hateruma atoll japan and investigates the effects of diagenesis on the initial 234u 238u ratios of the corals hateruma consists of over 95 reef material of less than 500 ka in age because groundwaters associated with recent carbonates tend not to have elevated 234u 238u ratios the scope for increasing the 234u 238u ratios of hateruma corals through groundwater interaction should be minimal the corals examined range from those which show no petrographic or x ray evidence for diagenetic alteration and are pristine to those containing secondary cements of either aragonite or high or low mg calcite these various phases have been mechanically separated and analysed in agreement with previous assertions the analyses of these separates demonstrates that the presence of calcite should be a cause for rejection of coral samples it is also shown that aragonite cement can form later than coral death and may bias estimates of age and initial 234u 238u ratios of the six pristine corals three have anomalous 230th 238u ratios requiring u loss and or230th addition the remaining fifteen of the eighteen total analyses reported here yield ages from 1 6 ka to 260 ka no evidence for an increase in 234u 238u ratios in past seawater from this period has been found the best estimates for 234u 238u ratios are close to the current seawater value

rapid directional changes associated with a 6 5 kyr long blake geomagnetic excursion at the blake bahama outer ridge geomagnetic excursions are recognised as intrinsic features of the earth s magnetic field high resolution records of field behaviour captured in marine sedimentary cores present an opportunity to determine the temporal and geometric character of the field during geomagnetic excursions and provide constraints on the mechanisms producing field variability we present here the highest resolution record yet published of the blake geomagnetic excursion 125 ka measured in three cores from ocean drilling program odp site 1062 on the blake bahama outer ridge the blake excursion has a controversial structure and timing but these cores have a sufficiently high sedimentation rate 10 cm ka to allow detailed reconstruction of the field behaviour at this site during the excursion palaeomagnetic measurements of the cores reveal rapid transitions 230th excess measurements to assess variations in the sedimentation rates through the sections of interest this provides an age and duration for the blake excursion with greater accuracy and with constrained uncertainty we date the directional excursion as falling between 129 and 122 ka with a duration for the deviation of 6 5 1 3 kyr the long duration of this interval and the fully reversed field suggest the existence of a pseudo stable reversed dipole field component during the excursion and challenge the idea that excursions are always of short duration

uranium series dating of fossil coral reefs extending the sea level record beyond the last glacial cycle abstract absolutely dated records of past sea level change are extremely important for understanding the advance and retreat of the large ice sheets when combined with other complementary climate archives and climate models such records offer the potential to gain an improved understanding of earth s natural climate cycles providing a firmer basis for assessing the role of anthropogenic effects such as greenhouse gas emissions in modifying climate the u series dating of fossil coral reefs has been widely utilized to provide absolutely dated records of past sea level change and numerous observations now exist for the past 130 000 years spanning the last glacial cycle despite this controversies still exist regarding the exact timing and character of sea level events within this time interval and extending the sea level history further back in time on the basis of robust and independent age constraints for older fossil reefs remains very elusive this is primarily due to a progressive loss in the resolution of the u series chronometer as one goes further back in time coupled to a lack of well preserved dateable coral in older fossil reefs to overcome these limitations the primary challenges are three fold first new analytical protocols are required to improve the resolution of the u series chronometer enhanced analytical precision must be coupled to accuracy through continued refinement of the u series decay constant determinations and via the implementation of rigorous inter laboratory calibration exercises second efforts should continue to be focussed on gaining an improved understanding of the mechanisms controlling open system exchange of the u series isotopes in fossil reef systems this will allow the number of reliable u series observations to be extended third alternative dateable archives of past sea level change must continue to be emphasized to further complement the coral reef database these limitations are discussed in the context of current developments that further advance the application of u series chronology to older fossil reef systems formed prior to the last glacial cycle

reconstruction of the last deglaciation deconvolved records of δ18o profiles micropaleontological variations and accelerator mass spectrometric14c dating bioturbation acts as a low pass filter in displacing and reducing the amplitudes of stratigraphic signals this often leads to a loss of high frequency events in the stratigraphic record in addition when considering an isotopic signal 18o 14c measured in stratigraphic carriers such as foraminifera bioturbation and carrier abundance changes can create artifacts which may be falsely interpreted as leads or lags in the paleoclimatic record

microbialite development patterns in the last deglacial reefs from tahiti french polynesia iodp expedition 310 implications on reef framework architecture abstract the widespread occurrence of microbialites in the last deglacial reef frameworks 16 6 ka bp implies that the accurate study of their development patterns is of prime importance to unravel the evolution of reef architecture through time and to reconstruct the reef response to sea level variations and environmental changes the present study is based on the sedimentological and chronological analysis 14c ams dating of drill cores obtained during the iodp expedition 310 tahiti sea level on the successive terraces which typify the modern reef slopes from tahiti it provides a comprehensive data base to investigate the microbialite growth patterns i e growth rates and habitats to analyze their roles in reef frameworks and to reconstruct the evolution of the reef framework architecture during sea level rise the last deglacial reefs from tahiti are composed of two distinctive biological communities 1 the coralgal communities including seven assemblages characterized by various growth forms branching robust branching massive tabular and encrusting that form the initial frameworks and 2 the microbial communities developed in the primary cavities of those frameworks a few meters 1 5 to 6 m below the living coral reef surface where they heavily encrusted the coralgal assemblages to form microbialite crusts the dating results demonstrate the occurrence of two distinctive generations of microbialites the reefal microbialites which developed a few hundred years after coralgal communities in shallow water environments whereas the slope microbialites grew a few thousands of years later in significantly deeper water conditions after the demise of coralgal communities the development of microbialites was controlled by the volume and the shape of the primary cavities of the initial reef frameworks determined by the morphology and the packing of coral colonies the most widespread microbialite development occurred in frameworks dominated by branching thin encrusting tabular and robust branching coral colonies which built loose and open frameworks typified by a high porosity 50 in contrast their growth was minimal in compact coral frameworks formed by massive and thick encrusting corals where primary cavities yielded a low porosity 30 and could not host a significant microbialite expansion

mass spectrometric 230th 234u 238u dating of the devils hole calcite vein the devils hole calcite vein contains a long term climatic record but requires accurate chronologic control for its interpretation mass spectrometric u series ages for samples from core dh 11 yielded 230 th ages with precisions ranging from less than 1 000 years 2 for samples younger than 140 ka thousands of years ago to less than 50 000 years for the oldest samples 566 ka the 234 u 238 u ages could be determined to a precision of 20 000 years for all ages calcite accumulated continuously from 566 ka until 60 ka at an average rate of 0 7 millimeter per 10 3 years the precise agreement between replicte analyses and the concordance of the 230 th 238 u 234 u 238 u ages for the oldest samples indicate that the dh 11 samples were closed systems and validate the dating technique in general

modelling the spatial distribution of present day deformation in nepal how cylindrical is the main himalayan thrust in nepal summary the structure of the himalayas in nepal is characterized by underthrusting of the indian lithosphere beneath the chain along the main himalayan thrust mht the mht is affected by major earthquakes of m 8 that have ruptured segments several hundred kilometres in length the study of historical seismicity underlines the existence of a significant seismic gap between the 1905 kangra and the 1934 bihar nepal earthquake areas in western nepal this contribution presents a numerical model of the interseismic deformation using the adeli 2 d finite element code a parametric study has been performed to estimate the influence of the topography the geometry of the flat ramp flat transition of the mht and its rheology the results of these runs are compared along three cross sections of eastern central and western nepal using various recordings of the active deformation of nepal neotectonics microseismicity gps velocities vertical displacement rates deduced from comparative levellings the results of this study suggest 1 a small amount of aseismic slip along the southern part of the mht and 2 an abrupt change in geometry of the mht between central and western nepal the stress build up in eastern and central nepal is produced by coupling of a bend flat ramp transition of the mht and a brittle ductile transition at the foot of the ramp in western nepal on the other hand stress build up is only induced by a brittle ductile transition located along the low angle part of the mht this difference suggests the presence of a lateral ramp on the mht to allow transition between the central and western nepal geometries of the mht this change in mht geometries between central and western nepal is also clearly marked in the himalayan relief an abrupt decrease in altitude and incision between central and western nepal

glacial interglacial differences in circulation and carbon cycling within the upper western north atlantic we investigated glacial interglacial changes in the circulation and carbon cycling in the western north atlantic subtropical gyre using hydrographic data and downcore records of the stable isotopic compositions of individual shells of bahamian benthic foraminifera potential temperature salinity depth relations show that modern thermocline 200 1000 m and deep 1000 2000 m waters in the providence channels bahamas originate in the sargasso sea and are typical of the subtropical gyre gradients in the stable isotopic compositions of late holocene planulina and cibicidoides species from the bank margins 400 to 1500 m depth reflect temperature nutrient and isotopic gradients of modern subtropical gyre waters the difference between the 18o of glacial maximum and late holocene foraminifera is 2 1 for the upper 900 m of the water column and 1 6 for deeper waters indicating that these waters were 4 c and 2 c cooler respectively during glacial time the glacial temperature gradient dt dz was similar to today while the base of the thermocline was 100 m shallower these results differ significantly from our earlier results from multiple shell 18o analyses which implied upper thermocline waters were only 1 c cooler and dt dz was greater during the glacial maximum the difference occurs because bioturbation adversely affects multiple shell analyses of glacial aged samples from shallow water depths at all depths above 1500 m foraminiferal 13c are greater during the glacial maximum than the late holocene by at least 0 1 to 0 2 as much as 0 6 in the lower thermocline indicating that nutrient concentrations throughout the thermocline were reduced and there was no oxygen minimum zone during the glacial maximum this suggests greater more uniform ventilation of the thermocline results of single and multiple shell 13c analyses of glacial age foraminifera compare favorably because samples most affected by mixing correspond to water depths where the glacial interglacial change of 13c was small cooler upper ocean waters during the glacial maximum reflect cooler temperatures at the ocean surface where isopycnal surfaces outcrop including large areas of the subtropical ocean a shallower thermocline base is consistent with southward migration of the northern edge of the subtropical gyre or increased mode water production enhanced thermocline ventilation is consistent with more vigorous winds and all isopycnal surfaces outcropping in the area of ekman downwelling

u and th concentrations and isotope ratios in modern carbonates and waters from the bahamas the short residence times of th and pa in seawater make them very responsive to changes in the ocean environment we use a new multi ion counting technique to make th and pa isotope measurements in seawaters from a near shore environment in which oceanic chemical tracers are not overwhelmed by terrestrial inputs the bahamas an unusual feature of the bahamas setting is the shallow depth of water residing on the bank tops these waters have significantly lower 232th 230th 10 000 than those immediately adjacent to the banks 24 000 31 000 and a 231pa 230th near the production ratio 0 1 the change in 232th 230th and 231pa 230th on the bank tops is explained by almost quantitative removal of th and pa by scavenging and their replacement with a mixture of 230th and 231pa alpha recoiled from the underlying carbonates together with th from dust dissolution analysis of a water profile in the tongue of the ocean which separates the great and little bahama banks allows us to trace the movement of bank top water to depth a distinct minimum in both 232th 230th 13 000 and 231pa 230th 0 5 is observed at 430 m and is interpreted to reflect density cascading of bank top water with entrained carbonate sediment these results suggest that th and pa can be used as water mass tracers in near shore environments uranium concentration measurements on the same waters demonstrate that u is conservative across a range in salinity of 2 psu with a concentration of 3 33 ppb at a salinity of 35 the incorporation of u and th isotopes into marine carbonates has also been assessed by analyzing carbonate samples from the same location as these bahamas waters such incorporation is critical for u th geochronology u isotope analyses demonstrate that seawater 234u averages 146 6 and does not vary by more than 2 5 o and that carbonates capture this value additional high precision measurements 1 o on modern carbonates confirm that all oceans have identical 234u modern marine carbonates are shown to have 232th 230th ratios that reflect the local seawater in which they formed

carbonate veins trace seawater circulation during exhumation and uplift of mantle rock results from odp leg 209 carbonate veins hosted in ultramafic basement drilled at two sites in the mid atlantic ridge 15 n area record two different stages of fluid basement interaction a first generation of carbonate veins consists of calcite and dolomite that formed syn to postkinematically in tremolite chlorite schists and serpentine schists that represent gently dipping large offset faults these veins formed at temperatures between 90 and 170 c oxygen isotope thermometry and from fluids that show intense exchange of sr and li with the basement 87sr 86sr 0 70387 to 0 70641 7lil svec 3 3 to 8 6 carbon isotopic compositions range to high 13cpdb values 8 7 indicating that methanogenesis took place at depth the sr li c isotopic composition suggests temperatures of fluid rock interaction that are much higher t 350 400 c than the temperatures of vein mineral precipitation inferred from oxygen isotopes a possible explanation for this discrepancy is that fluids cooled conductively during upflow within the presumed detachment fault aragonite veins were formed during the last 130 kyrs at low temperatures within the uplifted serpentinized peridotites chemical and isotopic data suggest that the aragonites precipitated from cold seawater which underwent overall little exchange with the basement oxygen isotope compositions indicate an increase in formation temperature of the veins by 8 12 c within the uppermost 80 m of the subseafloor this increase corresponds to a high regional geothermal gradient of 100 150 c km characteristic of young lithosphere undergoing rapid uplift

uranium series dating of marine and lacustrine carbonates of the possible uranium series dating schemes the most important and most widely applied to marine carbonates is 230th dating with 231pa dating playing an increasingly important role for this reason this review will focus on these two methods 230th dating also referred to as u th dating or 238u 234u 230th dating involves calculating ages from radioactive decay and ingrowth relationships among 238u 234u and 230th 232th is also typically measured as a long lived essentially stable index isotope over the time scales relevant to 230th dating at present 230th dating can in principle be used to date materials as young as 3 years and in excess of 600 000 years edwards et al 1987a 1993 edwards 1988 see stirling et al 2001 for an example of dating corals in excess of 600 000 years old 231pa dating also referred to as u pa dating involves calculating ages from the ingrowth of 231pa from its grandparent 235u at present 231pa dating can be used to date materials as young as 10 years and as old 250 000 years edwards et al 1997 230th dating covers all of the 231pa time range and more with somewhat higher precision and is therefore the method of choice if a single method is applied however the combination of 231pa and 230th dating is of great importance in assessing possible diagenetic mobilization of the pertinent nuclides and thereby the accuracy of the ages allegre 1964 ku 1968 even if the primary age exceeds the 250 000 year limit of 231pa dating the combined methods can be used to assess the degree to which the samples have remained closed over the past 250 000 years e g edwards et al 1997 thus

uranium series dating applications in natural environmental science uranium series u series analyses are an essential component of many research projects in earth and environmental science oceanography hydrology and science based archaeology topics range from magma chamber evolution and volcanic hazard prediction global climatic change through dating of authigenic carbonate deposits human evolution through dating of bone to the study of groundwater evolution the u series decay chains contain many elements that can be fractionated in environmental and geological processes half lives of radioactive isotopes of such elements range from seconds to many millennia and application depends on the natural timeframe of the process or the elapsed time this review will be limited to some aspects of the 238u 234u 230th 226ra system with half lives of 245 kyr 76 kyr and 1 6 kyr respectively in environmental systems fractionation of uranium and thorium is a very efficient process because thorium is extremely insoluble while hexavalent uranium in oxidising conditions is relatively soluble many authigenic precipitates of calcite contain virtually no thorium and inorganic precipitates have u ca ratios very similar to the ratio of dissolved uranium and calcium almost no radiogenic 230th in the precipitate means that the radiogenic clock starts effectively at zero however pure authigenic precipitates are rare and many contain some allogenic material mostly silicate with 238u in secular equilibrium with significant 230th some of the characteristics of different types of samples and various methods to accommodate or correct for inherited 230th will be discussed authigenic material should remain a closed system with respect to the relevant isotopes but that requirement is sometimes difficult to maintain because radioactive decay results in damage to the crystal lattice of the host mineral consequences of this recoil effect and correction schemes will be discussed dating archaeological bone based on the systematics of diffusion and adsorption to effectively model open system behaviour is also included

u th ra fractionation during weathering and river transport the potential of radioactive disequilibria as tracers and chronometers of weathering processes has been recognised since the 1960 s e g rosholt et al 1966 hansen and stout 1968 this interest results from the dual property of the nuclides of the u and th radioactive series 1 to be fractionated during water rock interactions and 2 to have radioactive periods of the same order of magnitude as the time constants of many weathering processes and chemical transfers to ground and river waters therefore the study of radioactive disequilibria in surface environments should help to bring information about the nature the intensity but also the time scale of the water rock interactions produced during weathering and related chemical transfers these different properties have justified many of the studies on u th series in weathering profiles and river waters rosholt 1982 scott 1982 and osmond and ivanovich 1992 gave a synthesis of the studies of u series in weathering and surface hydrology up to the 1980 s and the 1990 s respectively here we present the main directions taken in these domains over the last decade they were partly stimulated by the analytical developments made in the measurement of the medium half life nuclides of 238u series i e 234u 230th 226ra in the mid 1980 s namely the use of thermal ionisation mass spectrometry tims e g chen et al 1986 edwards et al 1987 cohen et al 1991 chabaux 1993 chabaux et al 1994 and more recently the use of mc icp ms turner et al 2001 robinson et al 2002 for u and th isotope analysis details of these developments are given in this volume goldstein and stirling 2003 compared to the radioactive counting methods previously used the new techniques permit 1 a reduction by one order of magnitude or more of the size of the sample required for

last glacial emplacement of methane derived authigenic carbonates in the sea of japan constrained by diatom assemblage carbon 14 and carbonate content abstract we studied diatom assemblages and caco 3 contents of methane derived authigenic carbonates from the eastern margin of the sea of japan and assessed the formation time of these samples radioactive 14 c date was determined in selected samples to obtain the maximum age of the time the results of our study suggest mass formation of carbonate nodules in a glacial period within 40 ky consistent with a published u th dating result of carbonate nodules in the study area diatom assemblages and contents in the carbonate nodules abundance of 10 6 g dominance of neritic littoral species warm cold water species ratio lower than 25 differ from the near seafloor sediments in the study area which have characteristics of holocene sediments in the sea of japan and suggest cementation of glacial sediments laminated sediments in some nodule samples are glacial sediments because laminations are records of a low sea level period in the semi enclosed ocean similarity of diatom assemblages and contents in all carbonate samples is another evidence of glacial sediments in nodules glacial sediments with oceanic cold water species as low as holocene sediments restricts the sediment age to before 20 cal ky bp carbonate contents higher than 78 wt suggest the cementation of poorly compacted sediments near the seafloor and the date of carbonate cementation is therefore close to that of the cemented sediments most carbonate nodule samples in this study were formed in a glacial period and detection of 14 c restricts this period to within 40 ky

ba ra th and u in marine mollusc shells and the potential of 226ra ba dating of holocene marine carbonate shells the geochemistry of ba ra th and u and the potential of using 226 ra ba ratios as an alternative dating method are explored in modern and holocene marine mollusc shells five modern shells of the antarctic scallop adamussium colbecki collected from the present day beach and six radiocarbon dated specimens from holocene beach terraces of the ross sea region antarctic between 700 and 6100 calibrated yr bp old have been analysed by mass spectrometry in clean shells 226 ra concentrations and 226 ra ba ratios show a clear decrease with increasing age suggesting the possibility of 226 ra dating limiting factors for such dating are ba and 226 ra present in surface contaminants and ingrowth of 226 ra from u present within the shell surface contamination is difficult to clean off entirely but moderate levels of residual contamination can be corrected using 232 th sub samples from the same shell with different proportions of contamination form a mixing line in a 226 ra ba 232 th ba graph and the 226 ra ba of the pure shell can be derived from the intercept on the 226 ra ba axis contaminant corrected 226 ra ba ratios of late holocene 14 c dated samples fall close to that expected from simple 226 ra excess decay from seawater 226 ra ba values 226 ra ingrowth from u incorporated into the shell during the lifetime of the mollusc can be corrected for however the unknown timing of post mortem u uptake into the shell makes a correction for 226 ra ingrowth from secondary u difficult to achieve in the a colbecki shells 226 ra ingrowth from such secondary u becomes significant only when ages exceed 2500 yr in younger shells 226 ra ba ratios corrected for surface contamination provide chronological information if evidence for a constant oceanic relationship between 226 ra and ba in the ocean can be confirmed for that time scale the 226 ra ba chronometer may enable the reconstruction of variability in sea surface 14 c reservoir ages from mollusc shells and allow its use as a paleoceanographic

high precision u series measurements of more than 500 000 year old fossil corals robust independent age constraints on the absolute timing of climate events based on the u series dating of fossil coral are sparse before the last glacial cycle using multiple collector inductively coupled plasma mass spectrometry with multiple faraday protocols we are able to date 600 ka samples with an uncertainty of better than 15 ka 2 representing a three fold improvement in precision compared with previous techniques using these methods we report u series measurements for a suite of 500 thousand year old ka corals from henderson island an emergent atoll in the south central pacific ocean the fossil corals show extraordinarily little diagenetic alteration for their age and the best preserved sample yields a u series age of 600 15 ka 2 which overlaps with the timing of the warm marine isotope stage mis 15 interglacial the open system model of villemant and feuillet villemant b and feuillet n 2003 dating open systems by the 238u 234u 230th method application to quaternary reef terraces earth and planetary science letters 210 1 2 105 118 and the linear regression or open system isochron is clearly limited for such old samples however the open system model developed by thompson et al thompson w g spiegelman m w goldstein s l and speed r c 2003 an open system model for u series age determinations of fossil corals earth and planetary science letters 210 1 2 365 381 appears to reliably correct for open system effects in roughly half of the corals giving a mis 15 origin for these thus the data provide evidence that the systematic addition of 230th and 234u through recoil is a dominant open system process occurring in the henderson island fossil reef system several coral samples yield significantly older thompson et al open system ages between 650 and 750 ka the uncertainty on these ages typically 30 kyrs is too great for precise assignment but most data overlap with the mis 17 interglacial the reliability of these ages is currently unclear it is shown that separate aliquots of the same coral can yield different thompson model ages therefore there appear to be additional diagenetic mechanisms that create further anomalous excursions in the u series systematics limiting the reliability of the thompson et al open system model

assessing subsidence rates and paleo water depths for tahiti reefs using u th chronology of altered corals we present uranium thorium chronology fora 102 m core through a pleistocene reef at tahiti french polynesia sampled during iodp expedition 310 tahiti sea level we employ total and partial dissolution procedures on the older coral samples to investigate the diagenetic overprint of the uranium thorium system although alteration of the u th system cannot be robustly corrected diagenetic trends in the u th data combined with sea level and subsidence constraints for the growth of the corals enables the age of critical samples to be constrained to marine isotope stage 9 we use the ages of the corals together with o based sea level histories to provide maximum constraints on possible paleo water depths these depth constraints are then compared to independent depth estimates based on algal and foraminiferal assemblages microbioerosion patterns and sedimentary facies confirming the accuracy of these paleo water depth estimates we also use the fact that corals could not have grown above sea level to place a maximum constraint on the subsidence rate of tahiti to be 0 39 m ka with the most likely rate being close to the existing minimum estimate of 0 25 m ka

speleothem evidence for late holocene climate variability and floods in southern greece abstract we present stable isotope data 18o 13c from a detrital rich stalagmite from kapsia cave the peloponnese greece the cave is rich in archeological remains and there are reasons to believe that flooding of the cave has directly affected humans using the cave using a combination of u th and 14c dating to constrain a site specific correction factor for 232th 238u detrital molar ratio a linear age model was constructed the age model shows that the stalagmite grew during the period from ca 950 bc to ca ad 830 the stable oxygen record from kapsia indicates cyclical changes of close to 500 yr in precipitation amount with rapid shifts towards wetter conditions followed by slowly developing aridity superimposed on this signal wetter conditions are inferred around 850 700 500 and 400 100 bc and around ad 160 300 and ad 770 and driest conditions are inferred to have occurred around 450 bc ad 100 150 and ad 650 detrital horizons in the stalagmite indicate that three major floods took place in the cave at 500 bc 70 bc and ad 450 the stable carbon isotope record reflects changes in biological activity being a result of both climate and human activities

protactinium 231 dating of carbonates by thermal ionization mass spectrometry implications for quaternary climate change measurement of protactinium 231 231pa in carbonates by thermal ionization mass spectroscopy yields 231pa ages that are more than 10 times more precise than those determined by decay counting carbonates between 10 and 250 000 years old can now be dated with 231pa methods barbados corals that have identical 231pa and thorium 230 230th ages indicate that the timing of sea level change over parts of the last glacial cycle is consistent with the predictions of the astronomical theory two devils hole calcite subsamples record identical 231pa and 230th ages suggesting that the chronology of this climate record is accurate

lake highstands on the altiplano tropical andes contemporaneous with heinrich 1 and the younger dryas new insights from 14 c u th dating and δ 18 o of carbonates this study provides new geochronological and stable isotope constraints on late pleistocene fluctuations in lake level that occurred in the closed watershed of the central altiplano between 25 and 12 ka u series isochrons and 14 c ages from carbonates are used to confirm and refine the previous chronology published placzek et al 2006b our new data support three successive lake highstands during the late pleistocene i the lake sajsi cycle from 25 to 19 ka that culminated at 3670 m at about 22 ka almost synchronously with the global last glacial maximum ii the lake tauca cycle that lasted from 18 to 14 5 ka and was characterized by the highest water level reached at least 3770 m from 16 5 to 15 ka iii the lake coipasa cycle from 12 5 to 11 9 ka that reached an elevation of 3700 m 42 m above the elevation of the salar de uyuni 3658 m these high amplitude lake level fluctuations are in phase with the cold warm oscillations that occurred in the north atlantic and greenland during the late pleistocene heinrich 1 bolling allerod younger dryas such temporal coincidence supports the hypothesis that wet events recorded in the central altiplano are controlled by the northesouth displacement of the inter tropical convergence zone resulting from changes in the meridional temperature gradient finally the oxygen isotope ratios measured in these lacustrine carbonates allows for calculation of the 18 o value of paleolake waters estimates of water 18 o v smow are 2 8 0 7 for lake tauca and 1 6 0 9 for lake coipasa these data are used to constrain changes in lake hydrology and can be interpreted to indicate that the proportion of precipitation arising from local water recycling was less than 50

a northern lead in the orbital band north south phasing of ice age events abstract re analysis of existing data sets shows that they are fully consistent with northern insolation control of ice age cycles and do not provide strong support for alternate models invoking tropical or southern controls the coldest time of the last 100 ka in central greenland was nearly synchronous with the minimum in summer insolation about 24 ka bp thousand years before 1950 approximately one third of the total termination i warming since then was achieved over the almost 10 ka before the abrupt warming into the bolling which some workers have interpreted as the start of the warming southern warming as recorded in the byrd station antarctica ice isotopic record lagged northern warming co2 rise was roughly synchronous with southern warming methane rise may have been delayed a little as was sea level rise and the change in the isotopic composition of atmospheric oxygen was delayed significantly the data for the extrema just before termination ii are consistent with occurrence of the same phasing as for termination i but with somewhat different progression of the two terminations once initiated perhaps because of differences in the forcing

slope retreat rates estimated from chronology of tufa deposits sheltered by inland notches on mt carmel israel abstract inland notches are elongated half tube indentations that develop on the carbonate rocky cliffs of mountainous zones occasionally tufa accumulates within notches as stalactites drapes and crusts covering the cavity backwall or floors in attempt to determine the age of the latest stage of notch formation and calculate the relative rate of slope retreat u th dating was used on 16 tufa samples from 2 notches providing 28 ages tufa grow during the time interval between the backwall erosion and visor collapse and therefore tufa age is an approximation of the timing of the formation of the surface it developed on i e the age of the notch the oldest known tufa sample is 39 0 10 4 ky 2 and the ages of other tufa samples range from 2 1 to 23 3 ky at the nahal oren notch the present day backwall formed by the end of the last glacial period 14 to18 ky whereas the visor in its present form is from the early holocene 7 to10 ky the oldest sample was found 1 m from the backwall suggesting that backwall retreat rate ranges from 20 to 35 mm ky other samples were deposited 50 to 200 cm from the visor edge suggesting that slope retreat order of magnitude ranges from 101 to 102 mm ky the backwall of the nesher notch formed between 10 and 14 ky our results correspond with the rates of tens of meters per million years similar to the magnitude of denudation found by previous studies in the mediterranean zone of israel dating tufa deposits is a good proxy to estimate the rate of erosion in carbonate slope retreat however a precautionary approach should be taken as rock particles from the eroded bedrock might embed within the tufa affecting the age results questionable samples can be identified using cathodoluminescence cl microscopy

high precision u series dating of last interglacial events by mass spectrometry houtman abrolhos islands western australia the houtman abrolhos islands situated at the western passive margin of the australian continent consist of a series of shelf edge coral reefs the central platforms of the reefs are late pleistocene in age and are generally some 3 5 m above present sea level the uppermost part of the last interglacial reefs normally has an upward shallowing sequence consisting of coral framestone coralline algal bindstone and skeletal grainstone to rudstone this sequence represents deposition in water depths of less than 2 m and provides a good indicator of sea level high precision mass spectrometric dates of corals from the abrolhos reefs including dates obtained from drill cores arological isotopic and stratigraphic criteria are established for the selection of suitable samples for dating and for assessing the reliability of dates using the screened dates and the stratigraphic evidence the timing and character of the sea level variations of the last interglacial in the abrolhos region are examined the data show that sea level of the last interglacial in the abrolhos was 4 m below its present height by ca 134 ka bp and probably reached about 2 m above present height at ca 133 ka bp the exact time at which sea level reached its peak 6 m above present sea level cannot be determined from our data but it is clear that the sea level high stand of the last interglacial lasted until ca 116 ka bp and that for much of the last interglacial sea level at the abrolhos was at a height of about 4 m above its present level

u th dating of marine isotope stage 7 in bahamas slope sediments in order to understand the driving forces for pleistocene climate change more fully we need to compare the timing of climate events with their possible forcing in contrast to the last interglacial marine isotope stage mis 5 the timing of the penultimate interglacial mis 7 is poorly constrained this study constrains its timing and structure by precise u th dating of high resolution n 18 o records from aragonite rich bahamian slope sediments of odp leg 166 sites 1008 and 1009 the major glacial interglacial cycles in n 18 o are distinct within these cores and some mis 7 substages can be identified these sediments are well suited for u th dating because they have uranium concentrations of up to 12 ppm and very low initial 230 th contributions with most samples showing 230 th 232 th activity ratio of s 75 u and th concentrations and isotope ratios were measured by thermal ionisation mass spectrometry and multiple collector inductively coupled plasma mass spectrometry with the latter providing dramatically better precision twenty nine of the 41 samples measured have a n 234 u value close to modern seawater suggesting that they have experienced little diagenesis ages from 27 of the 41 samples were deemed reliable on the basis of both their u and their th isotope ratios ages generally increase with depth although we see a repeated section of stratigraphy in one core extrapolation of constant sedimentation rate through each substage suggests that the peak of mis 7e lasted from v237 to 228 ka and that 7c began at 215 ka this timing is consistent with existing low precision radiometric dates from speleothem deposits the beginning of both these substages appears to be slightly later than in orbitally tuned timescales the end of mis 7 is complex but also appears to be somewhat later than is suggested by orbitally tuned timescales although this event is not particularly well defined in these cores fl 2002 elsevier science b v all rights reserved

duration and structure of the past four interglaciations reanalysis and additional dating of the devils hole 18o paleotemperature record confirm that the last interglaciation in the great basin the continental analog of marine isotopic substage 5e lasted 22 000 yr consistent with the vostok paleotemperature record which suggests a duration of 19 000 yr for this event in antarctica the three preceding interglaciations in the devils hole record analogs of marine isotopic substages 7e 9c and 11c range from 20 000 to 26 000 yr in duration a 20 000 yr duration for the last interglaciation is consistent with tims uranium series dated sea level high stands thus the widely held view that interglaciations were of 11 000 to 13 000 yr duration and constituted only about 10 of mid to late pleistocene climatic cycles needs reexamination the warmest portion of each interglaciation in the devils hole time series is marked by a 18o plateau signifying apparent climatic stability for periods of 10 000 to 15 000 yr duration

the last interglacial ocean the final effort of the climap project was a study of the last interglaciation a time of minimum ice volume some 122 000 yr ago coincident with the substage 5e oxygen isotopic minimum based on detailed oxygen isotope analyses and biotic census counts in 52 cores across the world ocean last interglacial sea surface temperatures sst were compared with those today there are small sst departures in the mid latitude north atlantic warmer and the gulf of mexico cooler the eastern boundary currents of the south atlantic and pacific oceans are marked by large sst anomalies in individual cores but their interpretations are precluded by no analog problems and by discordancies among estimates from different biotic groups in general the last interglacial ocean was not significantly different from the modern ocean the relative sequencing of ice decay versus oceanic warming on the stage 6 5 oxygen isotopic transition and of ice growth versus oceanic cooling on the stage 5e 5d transition was also studied in most of the southern hemisphere the oceanic response marked by the biotic census counts preceded led the global ice volume response marked by the oxygen isotope signal by several thousand years the reverse pattern is evident in the north atlantic ocean and the gulf of mexico where the oceanic response lagged that of global ice volume by several thousand years as a result the very warm temperatures associated with the last interglaciation were regionally diachronous by several thousand years these regional lead lag relationships agree with those observed on other transitions and in long term phase relationships they cannot be explained simply as artifacts of bioturbational translations of the original signals

timing and duration of the last interglacial evidence for a restricted interval of widespread coral reef growth abstract we report new mass spectrometric u series ages for eight last interglacial fossil reefs along the continental margin of western australia corals were selected in growth position from localities that are characterized by apparently low levels of diagenesis and relative tectonic stability so that the fossil reefs provide critical information on last interglacial sea levels without requiring corrections for tectonic movements in addition we have improved the constraint on the timing of onset of reef growth by recovering drill core coral from the base of the reefs uranium and thorium isotopes were measured with high levels of precision leading to improvements in age resolution and allowing samples which have undergone diagenetic exchange of uranium and thorium to be more easily identified and discarded these data supplement our previous results for rottnest island and leander point leading to more than seventy mass spectrometric u series ages from which constraints can be placed on the timing duration and character of the last interglacial sea level highstand reliable ages show that reef growth started contemporaneously at 128 1 ka along the entire western australian coastline while relative sea levels were at least 3 m above the present level because western australia is located far from the former penultimate glacial maximum ice sheets and are not significantly effected by glacial unloading these data constrain the timing of onset of the last interglacial period to 128 1 ka assuming reef growth started soon after sea level approached interglacial levels a unique regressive reef sequence at mangrove bay constrains the timing of termination of the last interglacial period to 116 1 ka the major episode of reef building however both globally and locally along the western australian coast is restricted to a very narrow interval occurring from 128 ka and 121 ka suggesting that global ocean surface temperatures were warm and or sea levels were stable enough to allow prolific reef growth only during the earlier part of the last interglacial

use of uranium thorium dating to determine past 14c reservoir effects in lakes examples from antarctica the chronologies of many lacustrine records suffer from radiocarbon reservoir effects due to the presence of dissolved dead carbon or to slow air water exchange here we use the tims uranium thorium disequilibrium method in conjunction with ams radiocarbon dating to determine the age of lacustrine carbonates and to quantify the past radiocarbon reservoir effect in two antarctic lakes with differing characteristics by correcting a single sample u th age for detrital contamination a 14 c offset of v18 000 yr was obtained for carbonates from the former grounding line of the ross sea ice sheet in glacial lake trowbridge this large reservoir effect is believed to result from the direct input of old co2 from glacial meltwater in the second example an isochron approach on coeval samples formed at the bottom of lake vida now exposed due to lower lake level yielded an age of 9550 340 yr b p and a radiocarbon reservoir age of 3600 yr this offset was probably the result of lack of aeration due to perennial ice cover and or strong density stratification this evidence for long term isolation of the lake bottom indicates another level of hardship for life in the dry valley lacustrine environment an environment studied as an analogue for extreme periods of earth history as well as for exobiological implications the success of the u th technique on these two examples indicates that tims u th dating will be of widespread use in dating the important climate information recorded in the dry valleys both within and beyond the 14 c age range fl 2001 elsevier science b v all rights reserved

the impact of sulfuric acid on element migration and mineralogy of compacted clays ph 1 0 to 3 0 abstract the transport of h2so4 at ph 1 0 1 0 and 3 0 through two mineralogically different compacted clays kc and km was examined using single reservoir diffusion cells with constant source concentrations at the end of the 216 day test period geochemical analyses indicated increased depth of acid diffusion with increased reservoir acidity for both kc and km cells elevated ca al fe and si concentrations were associated with decreased ph values in all cells xrd results showed that these elevated concentrations corresponded to the loss of carbonate and montmorillonite peaks and decreased peak intensities for illite and kaolinite in the kc and km ph 1 0 and 3 0 km cells moreover si x ray absorption near edge structure xanes indicated dissolution of the phyllosilicate phases a relative increase in the amount of quartz and the potential formation of an amorphous silica phase the results of this study showed that despite the extreme ph values considered movement of h2so4 solutions with ph

fluid flow through carbonate platforms constraints from 234u 238u and cl in bahamas pore waters the geometry timing and rate of fluid flow through carbonate margins and platforms is not well constrained in this study we use u concentrations and isotope ratios measured on small volumes of pore water from bahamas slope sediment coupled with existing chlorinity data to place constraints on the fluid flow in this region and by implication other carbonate platforms these data also allow an assessment of the behaviour of u isotopes in an unusually well constrained water rock system we report pore water u concentrations which are controlled by dissolution of high u organic material at shallow depths in the sediment and by reduction of u to its insoluble 4c state at greater depths the dominant process influencing pore water 234 u 238 u is alpha recoil in holocene sediments the increase of pore water 234 u 238 u due to recoil provides an estimate of the horizontal flow rate of 11 cm year but with considerable uncertainty at depths in the sediment where conditions are reducing features in the u concentration and 234 u 238 u profiles are offset from one another which constrains the effective diffusivity for u in these sediments to be1 2 10 8 cm 2 s 1 at depths between the holocene and these reducing sediments pore water 234 u 238 u values are unusually low due to a recent increase in the dissolution rate of grain surfaces this suggests a strengthening of fluid flow probably due to the flooding of the banks at the last deglaciation and the re initiation of thermally driven venting of fluid on the bank top and accompanying recharge on the slopes interpretation of existing chlorinity data in the light of this change in flow rate constrain the recent horizontal flow rate to be 10 6 3 4 cm year estimates of flow rate from 234 u 238 u and cl are therefore in agreement and suggest flow rates close to those predicted by thermally driven models of fluid flow this agreement supports the idea that flow within the bahamas banks is mostly thermally driven and suggests that flow rates on the order of 10 cm year are typical for carbonate platforms where such flow occurs 1999 elsevier science b v all rights reserved

dating open systems by the 238 u 234 u 230 th method application to quaternary reef terraces abstract the sedimentation conditions and diagenetic processes of biogenic and inorganic carbonates are such that the assumptions of a closed system evolution and the absence of initial th invoked in classical 238 u 234 u 230 th dating methods are very often not fulfilled for such material this problem is of interest for all studies requiring accurate dating of corals or aragonite rich sediments as in palaeoclimatology or neotectonics extending the approach of henderson and slowey nature 404 2000 61 66 we propose a consistent model that takes into account possible initial 230 th excess and where continuous selective redistribution gain or loss of 234 u 234 th and 230 th is controlled by recoil processes this model applied to quaternary marine terraces in barbados marie galante lesser antilles arc and pacific islands is able to explain the large scatter in isotopic compositions observed in the series of cogenetic corals or sediments we show that recoil processes generally tend to increase the 234 u 238 u and 230 th 234 u ratios with time leading to an overestimation of the apparent ages calculated using classical methods on the basis of simple assumptions identical marine initial 234 u 238 u 0 and 230 th 232 th 0 ratios we propose a method for calculating a best estimate of the age of cogenetic series our model offers an alternative way to date old reef terraces where corals are almost systematically altered and where classical dating methods do not apply it may also explain the apparent variations of the 234 u 238 u seawater initial ratio estimated from corals formed in the last 300 ka and the apparent uncoupling between sea level highstands and high latitude northern hemisphere summer insolation our set of equations can be applied to all weathering processes where the mobility of u series isotopes is controlled by recoil

direct u th dating of marine sediments from the two most recent interglacial periods a knowledge of the age of marine sediments is necessary to determine the timing of events and rates of processes in the marine realm and the relationships among marine and other climatically sensitive records the establishment of an accurate chronology for pleistocene marine sediments beyond the range of radiocarbon dating approximately the past 45 kyr has therefore been a goal of palaeoceanographers for decades early attempts1 2 based on measurements of the radionuclides 230th and 231pa were beset with problems and subsequent studies focused on tying fluctuations in marine sediment oxygen isotope records to events such as the formation of coral reef terraces and changes in the earth s magnetic polarity3 4 and tuning the resultant chronologies to the earth s orbitally driven insolation variations5 8 but these chronologies especially the age and duration of the last interglacial period have been challenged by several studies9 12 raising questions about the fundamental cause of pleistocene climate fluctuations here we report the direct u th dating of aragonite rich marine sediments from the bahamas and present an accurately dated marine oxygen isotope record for the last two interglacials we obtain dates of 120 127 kyr bp for the last interglacial and 189 190 kyr bp for the late stage 7 interglacial these dates are in accord with the general theory of orbitally forced climate fluctuations and demonstrate the potential of our direct dating approach for developing an absolute chronology for the pleistocene marine oxygen isotope record

rapid fluctuations in sea level recorded at huon peninsula during the penultimate deglaciation about 140 000 years ago the breakup of large continental ice sheets initiated the last interglacial period sea level rose and peaked around 135 000 years ago about 14 meters below present levels a record of last interglacial sea levels between 116 000 years to 136 000 years ago is preserved at reef vii of the uplifted coral terraces of huon peninsula in papua new guinea however corals from a cave situated about 90 meters below the crest of reef vii are 130 000 2000 years old and appear to have grown in conditions that were 6 c cooler than those at present these observations imply a drop in sea level of 60 to 80 meters after 130 000 years sea level began rising again in response to the major insolation maximum at 126 000 to 128 000 years ago the early about 140 000 years ago start of the penultimate deglaciation well before the peak in insolation is consistent with the devils hole chronology

the timing of high sea levels over the past 200 000 years the 230 th ages and 234 u 238 u ratios were determined for barbados corals that grew during periods of high sea level within the last 200 000 years the similarity of the initial 234 u 238 u ratios of some of the corals to the modern marine value suggests that these samples are pristine and that the marine 234 u 238 u ratio 83 000 and 200 000 years ago was within 2 per mil of the modern value the accuracies of the 230 th ages are evaluated on the basis of the 234 u 238 u values and a model of the behavior of uranium and thorium isotopes during diagenesis for the last three interglacial and two intervening interstadial periods sea level peaked at or after peaks in summer insolation in the northern hemisphere this overall pattern supports the idea that glacial interglacial cycles are caused by changes in earth9s orbital geometry the sea level drop at the end of the penultimate interglacial the last interglacial and a subsequent interstadial period lagged behind the decrease in insolation by 5 000 to 10 000 years

sediment transport time measured with u series isotopes results from odp north atlantic drift site 984 abstract high precision uranium isotope measurements of marine clastic sediments are used to measure the transport and storage time of sediment from source to site of deposition the approach is demonstrated on fine grained late pleistocene deep sea sediments from ocean drilling program site 984a on the bjorn drift in the north atlantic the sediments are siliciclastic with up to 30 carbonate and dated by 18o of benthic foraminifera nd and sr isotopes indicate that provenance has oscillated between a proximal source during the last three interglacial periods volcanic rocks from iceland and a distal continental source during glacial periods an unexpected finding is that the 234u 238u ratios of the silicate portion of the sediment isolated by leaching with hydrochloric acid are significantly less than the secular equilibrium value and show large and systematic variations that are correlated with glacial cycles and sediment provenance the 234u depletions are inferred to be due to recoil loss of 234th and are used to calculate comminution ages of the sediment the time elapsed between the generation of the small 50 m sediment grains in the source areas by comminution of bedrock and the time of deposition on the seafloor transport times the difference between comminution ages and depositional ages vary from less than 10 ky to about 300 to 400 ky for the site 984a sediments long transport times may reflect prior storage in soils on continental shelves or elsewhere on the seafloor transport time may also be a measure of bottom current strength during the most recent interglacial periods the detritus from distal continental sources is diluted with sediment from iceland that is rapidly transported to the site of deposition the comminution age approach could be used to date quaternary non marine sediments soils and atmospheric dust and may be enhanced by concomitant measurement of 226ra 230th 230th 234u and cosmogenic nuclides

primary u distribution in scleractinian corals and its implications for u series dating in this study we use microsampling techniques to explore diagenetic processes in carbonates these processes are important as they can affect the accuracy of u series chronometry fission track maps of deep sea scleractinian corals show a threefold difference between the minimum and maximum u in modern corals which is reduced to a factor of 2 in fossil corals we use micromilling and mc icp ms to make detailed analyses of the u and 234uinitial distributions in corals from 218 ka to modern within each fossil coral we observe a large range of 234uinitial values with high 234uinitial values typically associated with low u a simple model shows that this observation is best explained by preferential movement of alpha decay produced 234u atoms alpha recoil diffusion open system addition of 234u may occur when alpha recoil diffusion is coupled with a high u surface layer such as organic material this process can result in large whole coral 234uinitial elevations with little effect on the final age the diagenetic pathways that we model are relevant to both shallow water and deep sea scleractinian corals since both exhibit primary u heterogeneity and may be subject to u addition

temperature control on the incorporation of magnesium strontium fluorine and cadmium into benthic foraminiferal shells from little bahama bank prospects for thermocline paleoceanography surface sediments from little bahama bank lbb intersecting the subtropical thermocline were used to assess the influence of temperature on the incorporation of mg sr f and cd into shells of benthic foraminifera samples were obtained from twelve cores along the southern slope of lbb covering a temperature range of 18 4 5 c between 301 and 1585 m we studied the composition of ten calcitic and one aragonitic species which are often used in paleochemical reconstructions mg ca ratios decrease with increasing water depth in all benthic species both with calcitic and aragonitic mineralogy showing a strong correlation with water temperature similar decrease is seen in sr ca but with no correlation with temperature none of the benthic species studied here exhibits a depth or temperature related change in f ca similar trends are observed when using an ocean wide dataset which includes shallow and deep core tops 300 5000 m we suggest that temperature is the primary control on the mg content of benthic foraminifera based on inorganic precipitation experiments and thermodynamic considerations presented here a 30 40 decrease in the mg distribution coefficient in calcite may be expected as a result of a temperature change from 25 c to 5 c which is about half the observed change in lbb a calibration curve applied to c pachyderma data from core tops along the slope of little bahama bank suggests that water temperature may be inferred from mg ca ratios with an uncertainty of about 0 8 c therefore the mg content of benthic foraminifera may provide a new independent temperature proxy for studying shallow waters paleoceanography the linear decrease in sr ca with increasing depth is not correlated with temperature the trend is constant from the ocean surface down to 5 km suggesting that pressure related effects on the calcification process are a more likely explanation than post depositional dissolution mg ca ratios in aragonitic shells of h elegans covary with temperature in accord with recent observations from corals in contrast the sr and f chemistry of h elegans is very different than that of corals and inorganically precipitated aragonites the disparities between the elemental composition of biogenic and inorganic phases and the large intergeneric and interspecific differences observed both in planktonic and benthic foraminifera implicate temperature related physiological processes in regulating the coprecipitation of elements in foraminiferal shells our work demonstrates that cd ca ratios of shallow calcitic species reflect the vertical distribution of nutrients no significant influence of temperature on the partitioning of cd into the shells was found our data extend the previous deep water calibration boyle 1992 thereby allowing for the reconstruction of the nutrient chemistry of shallow thermocline waters

mid holocene climate in new caledonia southwest pacific coral and pmip models monthly resolved results abstract the mid holocene climate is characterized by an insolation seasonality decrease in the southern hemisphere but measurements of its actual impact on monthly resolved sea surface temperature sst in the southwest pacific region are still insufficient a new caledonian 5 5 ka cal bp coral provides a 20 year long seasonally resolved record of ocean surface conditions as inferred from coral sr ca and ba ca results were compared to monthly series of paleoclimate modeling intercomparison project phase 2 pmip2 model simulations anomalous stable isotope and u ca values are observed in a restricted area of the skeleton related to dissolution features the mid holocene sst seasonal amplitude mean and variability are higher than presently in new caledonia the increased seasonal amplitude in the mid holocene being most probably due to the occurrence of colder winters other southwest pacific mid holocene coral data showed also such an increased seasonal amplitude this could mean that the south pacific convergence zone spcz was weaker or reached locations more northerly than at present which could fit with northward shifts of the inter tropical convergence zone itcz during south hemisphere winter inversely strong rainfalls during the summer deduced from the ba ca signal and reconstructed sea surface salinity sss were interpreted as reflecting pronounced southwestward shifts of the spcz in summer as those occurring today during la nina events none of the six pmip2 models used reproduce the proxy based mid holocene increase of sst seasonal amplitude model maps show a less intense spcz in winter that would be consistent with higher sst seasonal amplitude finally we stress the need for more seasonally resolved data to validate this enhanced mid holocene sst seasonal amplitude in the southwest pacific region and to better understand the underlying mechanisms

u th dating of carbonate platform and slope sediments absolute chronology of marine sediment beyond the 14c age range provides a test for models of climate change and has many other applications u th techniques have been used for such chronology by dating corals but extending these techniques to marine sediment is complicated by the presence of significant initial 230th both in detrital material and scavenged from seawater in this study we investigate four methods of solving the initial 230th problem for a particular type of marine sediment the aragonite rich sediments of carbonate platforms and slopes bulk sediment u th analyses can be corrected for initial th to yield ages with 2 to 3 kyr precision for highstand periods when sediment aragonite contents are particularly high uncertainty on the corrections causes inadequate precision for sediment from other periods however removal of scavenged th before analysis would enable a dramatic increase in this precision but has not proved successful despite a range of chemical leach approaches using heavy liquids to separate the various carbonate minerals found in bahamas sediment enables an isochron approach to correct for initial th but the presence of initial th from two sources requires correction or removal of one source of initial th before the other is deconvolved by the isochron quantitative removal of detrital material before isochron analysis proves a successful approach such isochron data demonstrate that although sediment remains closed to u th on a centimetre scale nuclides are moved from grain to grain by recoil such intergrain exchange is expected to be observed in all sediments containing mineral grains with different u concentrations measured 234u 238u allows the recoil movement to be corrected and results in isochron ages with precision sometimes as low as 3 kyr the accuracy of this approach has been proved by dating samples within the 14c age range sediments spanning the penultimate deglaciation have also been dated after a small correction for bioturbation the age for this event is found to be 135 2 3 5 ka this date is 8 kyr before the peak in northern hemisphere insolation and suggests that deglaciation is initiated by a mechanism in the southern hemisphere or tropics this isochron approach shows considerable promise for dating of sediments older than this event which will provide further information about the timing and mechanisms of global climate change

pleistocene sea levels and tectonic uplift based on dating of corals from sumba island indonesia we collected and dated fossil corals from the uplifted reef tracts of sumba island mass spectrometry tims and ams was used to obtain reliable and precise radiochronological results it is possible to identify outcrops corresponding to major sea level high stands isotope stage 1 starting at 7 1 kyr bp 5a c a 86 kyr bp 5c c a 105 kyr bp 5e between 119 and 132 kyr bp and 9 c a 305 kyr bp the radiochronological data are thus broadly consistent with the timing of sea level fluctuations predicted by the astronomical theory of paleoclimates comparison with similar data from other terrace sequences and from benthic 18o records indicates that the average tectonic uplift rate at cape laundi sumba is on the order of 0 2 0 5m kyr the lowest values 0 3m kyr lead to the build up of polycyclic topographic terraces in which it is possible to find corals grown during different interstadial or even interglacial times

uranium series chronology and environmental applications of speleothems an increasing number of scientists recognize the value of speleothems1 as often extremely well preserved archives of information about past climate vegetation hydrology sea level nuclide migration water rock interaction landscape evolution tectonics and human action well constrained data are required to document past changes reconstruct past patterns and predict future responses of the earth system at a wide range of spatial and temporal scales speleothems are particularly useful in this regard because they can be found in many locations of the globe sampled at high resolution and reliably dated using high precision uranium series techniques speleothems are bodies of mineral material formed in caves as the result of chemical precipitation from groundwater flowing or dripping in a cave most speleothems are composed of calcite formed by slow degassing of co2 from supersaturated groundwater but aragonite and gypsum forms are also common particularly near cave entrances where evaporative effects are important a host of different speleothem types decorate the walls ceilings and floors of caves and their mineralogy and morphology is a function of fluid flow and chemistry of waters feeding a particular location as well as the ambient conditions temperature chemistry light in the air or water filled void subaerial forms include the familiar stalagmites stalactites draperies flowstones subaqueous forms include rimstone pools rafts mammillary calcite wall coatings and dog tooth spar for an extensive review of the types of speleothem that have been observed see hill and forti 1997 speleothems are used in a multitude of ways to explore past environmental conditions perhaps the most fundamental of which is their very presence or absence deposition of speleothems relies on sufficient water supply and soil co2 to enable dissolution and transport of reactants in the vadose zone to underlying caves in arid or glacial times conditions may not have been favorable for speleothem formation

u th dating of lake lisan late pleistocene dead sea aragonite and implications for glacial east mediterranean climate change u series dating can be an effective means to obtain accurate and precise ages on quaternary carbonates however most samples require a correction for u and th in admixed detritus this complication is often addressed through generation of u th isochrons requiring analyses of several coeval samples in addition presence of water derived hydrogenous th in the carbonate can cause inaccuracies in isochron ages this study reports a high resolution u series chronology of sediments deposited by lake lisan the last glacial precursor of the dead sea the strategy employed combines multiple measurements from a few stratigraphic heights and fewer analyses from many heights in a single described and measured section the resulting chronology is based on ages at 22 heights in a 40 m thick section covering the interval of 70 14 calendar ka bp the effects of admixed detritus are evaluated using trace elements nearly pure aragonite samples indicated by very low abundances of insoluble elements such as nb and zr were found to contain hydrogenous th which causes the uncorrected u 230th age of a modern sample to be 2 5 ka nevertheless accurate ages have been obtained by correcting for the detrital and aqueous interferences the resulting ages are in stratigraphic order and their accuracy is evidenced by consistency of lisan formation u series and 14c ages with the coral based calendar radiocarbon age calibration the u th ages provide a context to unravel the limnological history of lake lisan boundaries between the lower middle and upper stratigraphic units correspond to the mis 4 3 and 3 2 transitions respectively during mis 2 and 4 the lake generally showed a stable two layer configuration and a positive fresh water balance reflected by deposition of laminated aragonite detritus dry intervals during mis 2 and 4 are indicated by thick gypsum layers and an inferred depositional hiatus which are temporally associated with heinrich events h1 at 17 ka and h6 at 65 ka respectively during mis 3 the lake level was unstable with intermittent dry periods indicated by abundant clastic layers and a significant hiatus between 43 49 ka clastic layers are associated with dansgaard oeschger events during mis 3 and indicate lake level declines during abrupt northern hemisphere warmings overall the climate of the eastern mediterranean region shows a strong linkage to the northern hemisphere climate with increasing lake size and stability during cold periods and fluctuations and dessication during warmings and heinrich events

strategies for successful u th dating of paleolake carbonates an example from the bolivian altiplano we report over 90 u th dates from carbonates deposited around paleolakes on the bolivian altiplano petrographic and chemical data for tufas and the siliciclastic detritus contained within them allow 1 assessment of possible diagenetic effects 2 a development of a strategy for selection of carbonate samples with low initial th contents and 3 assessment of the uncertainty due to initial th this strategy allows us to produce precise u th dates from lacustrine carbonates the principal consideration in dating such carbonates is the composition and quantity of initial th incorporated into the carbonate and additional uncertainty is introduced because this initial th may have two sources in lacustrine deposits isochron plots measured 230th 232th and x ray diffraction and trace element chemistry of silicic residues all favor regional soil and dust as the sole source of initial th in carbonates from the bolivian altiplano a situation that simplifies single sample dating of altiplano carbonates

age dating and the orbital theory of the ice ages development of a high resolution 0 to 300 000 year chronostratigraphy using the concept of orbital tuning a continuous high resolution deep sea chronostratigraphy has been developed spanning the last 300 000 yr the chronology is developed using a stacked oxygen isotope stratigraphy and four different orbital tuning approaches each of which is based upon a different assumption concerning the response of the orbital signal recorded in the data each approach yields a separate chronology the error measured by the standard deviation about the average of these four results which represents the best chronology has an average magnitude of only 2500 yr this small value indicates that the chronology produced is insensitive to the specific orbital tuning technique used excellent convergence between chronologies developed using each of five different paleoclimatological indicators from a single core is also obtained the resultant chronology is also insensitive to the specific indicator used the error associated with each tuning approach is estimated independently and propagated through to the average result the resulting error estimate is independent of that associated with the degree of convergence and has an average magnitude of 3500 yr in excellent agreement with the 2500 yr estimate transfer of the final chronology to the stacked record leads to an estimated error of 1500 yr thus the final chronology has an average error of 5000 yr