determining the influences of late quaternary ventilation and productivity variations on santa barbara basin sedimentary oxygenation a multi proxy approach abstract a correlation between warm interstadials implied by 18oice in the gisp greenland ice core and anoxic events recorded by the sediments drilled at odp site 893 in santa barbara basin sbb has been used previously to relate variations in bottom water oxygenation to high frequency changes in the ventilation of the sbb nature 379 1996 243 however an additional control on the oxygen content at depth is the local settling flux of metabolizable organic matter to assess the impact of oxygen consumption related to this source mo cd re and u concentration data are used here in conjunction with corg and 15n to deduce past redox conditions variations in the sedimentary redox boundary depth and the impact of local organic flux on the oxygenation of sbb deep waters comparisons between odp sites 893 1017 and 1019 allow the differentiation of regional signals dominated by ventilation changes from local signals dominated by vertical organic flux it is concluded that prior to the holocene local productivity changes in the santa barbara basin are not solely the cause of sedimentary anoxia episodic injections of low oxygen intermediate water identified on the regional scale strongly influenced the oxygen content of the sbb during this time however over the last 10 000 years the influence of local productivity has increased and the regional similarity among the three sites is complicated by local signals

trace element signatures of chilean upwelling sediments at 36 s abstract with this contribution we continue the discussion on trace element te cycling in chilean upwelling sediments from within and below the oxygen minimum zone omz boning et al 2005 marine geology 220 1 21 low authigenic i e non lithogenic contents of te ag cd mo re and se were interpreted to result from the distinct seasonality in productivity induced organic flux bottom water oxygenation as well as dilution by terrigenous matter while all sediments were reducing enough to become depleted in mn highest enrichments in mo cd and re occur in sediments in contact with the omz here for a meaningful discussion total contents of as bi co cr cu ni pb sb tl v u and zn were corrected for the lithogenic background by determining te al ratios from local river samples the latter showed significantly lower te al ratios than average shale crust or andesite which are classically used for background correction hence the precise assessment of the lithogenic te contribution for the calculation of authigenic te contents allows to examine the source sink relationship of individual authigenic te for chilean sediments four te groups may be distinguished i mo re u and sb likely originate from sea water and accumulate via diffusive supply across the swi ii cd cr cu ni and zn require biologically induced pre concentration within biogenic material iii ag as se tl and v show an intermediate behaviour and iv bi and pb are contributed by anthropogenic activity highest enrichments in ni cu u as and v occur in sediments in contact with the omz the distinct depletion in co along with mn indicates the overall reducing but non sulfidic character of the chilean omz the degree of sedimentary sulfate reduction seems to be the most important control on chilean and peruvian near coastal enrichment of cd mo and u

metal diagenesis in oxic marine sediments the metal nutrient relationships observed for nickel and cadmium in the deep ocean are continued at the interface between seawater and oxidizing pore water this continuum results in pore water concentrations of these metals which are only slightly greater than near bottom seawater levels manganese concentrations in these oxidizing pore waters are also extremely low less than three times bottom water in contrast release in the boundary layer produces a maximum of dissolved copper which is 10 40 times ambient seawater assuming these pore waters are at steady state flux estimates based on these measurements suggest that the manganese in todorokite rich nodules of the central equatorial pacific was not supplied by upward diffusion through pore waters below the interface most nodular nickel is precipitated with manganese while nodular copper is supplied by diffusion

on the atmospheric response experiment to a blue arctic ocean we demonstrated atmospheric responses to a reduction in arctic sea ice via simulations in which arctic sea ice decreased stepwise from the present day range to an ice free range in all cases the tropospheric response exhibited a negative arctic oscillation ao like pattern an intensification of the climatological planetary scale wave due to the present day sea ice reduction on the atlantic side of the arctic ocean induced stratospheric polar vortex weakening and the subsequent negative ao conversely strong arctic warming due to ice free conditions across the entire arctic ocean induced a weakening of the tropospheric westerlies corresponding to a negative ao without troposphere stratosphere coupling for which the planetary scale wave response to a surface heat source extending to the pacific side of the arctic ocean was responsible because the resultant negative ao like response was accompanied by secondary circulation in the meridional plane atmospheric heat transport into the arctic increased accelerating the arctic amplification

exploring links between arctic amplification and mid latitude weather 1 this study examines observed changes 1979 2011 in atmospheric planetary wave amplitude over northern mid latitudes which have been proposed as a possible mechanism linking arctic amplification and mid latitude weather extremes we use two distinct but equally valid definitions of planetary wave amplitude termed meridional amplitude a measure of north south meandering and zonal amplitude a measure of the intensity of atmospheric ridges and troughs at 45 n statistically significant changes in either metric are limited to few seasons wavelengths and longitudinal sectors however in summer we identify significant increases in meridional amplitude over europe but significant decreases in zonal amplitude hemispherically and also individually over europe and asia therefore we argue that possible connections between arctic amplification and planetary waves and implications of these are sensitive to how waves are conceptualized the contrasting meridional and zonal amplitude trends have different and complex possible implications for midlatitude weather and we encourage further work to better understand these

dynamical link between the barents kara sea ice and the arctic oscillation abstractthe recent accelerated arctic sea ice decline has been proposed as a possible forcing factor for midlatitude circulation changes which can be projected onto the arctic oscillation ao and or north atlantic oscillation nao mode however the timing and physical mechanisms linking ao responses to the arctic sea ice forcing are not entirely understood in this study the authors suggest a connection between november sea ice extent in the barents and kara seas and the following winter s atmospheric circulation in terms of the fast sea ice retreat and the subsequent modification of local air sea heat fluxes in particular the dynamical processes that link november sea ice in the barents and kara seas with the development of ao anomalies in february is explored in response to the lower tropospheric warming associated with the initial thermal effect of the sea ice loss the large scale atmospheric circulation goes through a series of dynamical adjustment processes the decelerated zonal mean zonal

influence of thermal and mechanical cracks on permeability and elastic wave velocities in a basalt from mt etna volcano subjected to elevated pressure abstract we report simultaneous laboratory measurements of seismic velocities and fluid permeability on lava flow basalt from etna italy results were obtained for dry and saturated samples deformed under triaxial compression during each test the effective pressure was first increased up to 190 mpa to investigate the effect of pre existing crack closure on seismic properties then the effective pressure was unloaded down to 20 mpa a pressure which mirrors the stress field acting under a lava pile of approximately 1 5 2 km thick and deviatoric stress was increased until failure of the specimens using an effective medium model the measured elastic wave velocities were inverted in terms of two crack densities i the crack density of the pre existing thermal cracks and v the crack density of the stress induced cracks in addition a link was established between elastic properties elastic wave velocities vp and vs and permeability using a statistical permeability model our results show that the velocities increase with increasing hydrostatic pressure up to 190 mpa due to the closure of the pre existing thermal cracks this is interpreted by a decrease of the crack density i from 1 to 0 2 the effect of pre existing cracks closure is also highlighted by the permeability evolution which decreases of more than two orders of magnitude under deviatoric loading the velocities signature is interpreted in the first stage of the loading by the closure of the pre existing thermal cracks however with increasing deviatoric loading newly formed vertical cracks nucleate and propagate this is clearly seen from the velocity signature and its interpretation in term of crack density from the location of the acoustic emission sources and from microstructural observations this competition between pre existing cracks closure and propagation of vertical cracks is also seen from the permeability evolution and our study shows that mechanically induced cracks has lesser influence on permeability change than pre existing thermal cracks

cadmium diagenesis in laurentian trough sediments the depth distributions of cd mn and fe in pore water and sediment were determined on three replicate box cores collected at a 325 m deep station in the laurentian trough the results reveal a surface layer in which the content of solid phase cd first decreases but then increases sharply with depth in contrast mn decreases regularly over the same depth interval in the oxygenated zone of this layer cd probably associated with organic matter is released to the pore water resulting in concentrations that are more than an order of magnitude higher than in the overlying water column some of the dissolved cd is returned to the water column and some migrates downward and is precipitated at depth this part of the cd cycle is virtually complete within the surface layer the base of which corresponds to the base of the zone of mn enrichment in the subsurface layer solid phase cd and mn show little or no concentration change however dissolved cd which reaches often non detectable concentrations 0 05 nm in this layer increases once again deep within the anaerobic zone and attains concentrations even higher than in the surface layer the presence of dissolved cd complexes revealed by 1 5 to 8 fold increases in electrochemically active cd in pore water following uv treatment as well as inconsistent distributions of dissolved and solid phase cd indicate complexities in diagenesis that merit further investigation

past and recent changes in the large scale tropospheric cycles of lead and other heavy metals as documented in antarctic and greenland snow and ice a review abstract the investigation of the occurrence of lead and other heavy metals in antarctic and greenland ancient ice and recent snow is of great interest in reconstructing the past natural tropospheric cycles of these metals and determining to what extent these cycles have now been altered by man because concentrations to be measured are exceedingly low down to the sub pg g level reliable data can however be obtained only if full control of contamination is achieved from field sampling to laboratory analysis the available data show that the past natural concentrations of pb cd zn cu and hg in antarctic ancient ice are highly dependent upon climatic conditions the highest values occurring during the coldest periods of the ice ages especially during the last glacial maximum about 18 000 years ago human activity has led to an increase in lead concentrations during recent centuries both in antarctica tenfold increase and in greenland two hundredfold increase this last increase was followed by a 7 5 fold decrease during the past two decades mainly as a consequence of the rapid fall in the use of lead alkyl additives in the usa as confirmed by recent isotopic data

distinguishing between water column and sedimentary denitrification in the santa barbara basin using the stable isotopes of nitrate 1 below its sill depth the santa barbara basin sbb is commonly suboxic o2 3 m with only brief periods of ventilation associated with development of suboxia the concentration of nitrate decreases with depth into the basin without an associated decrease in phosphate indicating that a substantial fraction of the nitrate supplied to the basin is removed by denitrification coincident with the decrease in nitrate concentration across the redoxcline the interface between oxic and suboxic waters within the sbb there is an increase in the 15n 14n of that nitrate as would be anticipated from the isotopic fractionation associated with denitrification however the increase in 15n 14n of nitrate is much smaller than occurs in the open eastern tropical north pacific etnp for a comparable amount of nitrate loss both the concentrations of n species within the basin and measurements of nitrate 18o 16o suggest that the lower than expected 15n enrichment in the suboxic sbb involves denitrification rather than being due to some unknown source of low 15n 14n n to the deep sbb calculations with a range of models of nitrate supply and consumption indicate that the degree of nitrate consumption in the basin is too small for differences in water circulation to explain the isotopic differences between the santa barbara basin and the open etnp previous studies indicate that the isotope effect of sedimentary denitrification is negligible due to nitrate diffusion in sediment pore waters thus we infer that the small magnitude of the isotopic enrichment of sbb water column nitrate is due to the importance of sedimentary denitrification within the basin assuming that water column and sedimentary denitrification have isotope effects of 25 and 1 5 per mil respectively our results suggest that sedimentary denitrification accounts for more than 75 of the nitrate loss within the suboxic sbb

laboratory simulation of volcano seismicity the physical processes generating seismicity within volcanic edifices are highly complex and not fully understood we report results from a laboratory experiment in which basalt from mount etna volcano italy was deformed and fractured the experiment was monitored with an array of transducers around the sample to permit full waveform capture location and analysis of microseismic events rapid post failure decompression of the water filled pore volume and damage zone triggered many low frequency events analogous to volcanic long period seismicity the low frequencies were associated with pore fluid decompression and were located in the damage zone in the fractured sample these events exhibited a weak component of shear double couple slip consistent with fluid driven events occurring beneath active volcanoes

an oceanographic explanation for the apparent carbon isotope cadmium discordancy in the glacial antarctic the seeming discordance between the glacial to interglacial changes in the carbon isotope ratio and cadmium content of benthic foraminifera from the deep antarctic has cast a shadow on the reliability of these proxies as valid of paleocirculation indicators the problem is that while cadmium content shows little glacial to interglacial change lea and boyle 1990 boyle 1992 the carbon isotope change is larger than at any other place in the ocean curry et al 1988 innu et al 1990 charles and fairbanks 199o even after correction for the 0 35 glacial to interglacial change in the isotope ratio for mean ocean atmosphere carbon a difference of 0 5 to 0 6 remains on the basis of redfield ratios for today s ocean this is equivalent to a 25 increase in cadmium content which is not seen this puzzle has been with us for several years

late magmatic healed fractures in granitoids and their influence on subsequent solid state deformation abstract late magmatic fractures developed during final stages of magma crystallization are recorded in many granitoid plutons by planar trails of magmatic biotite and or leucocratic veins but have not been previously described such biotite rich trails with lengths of a few centimetres to several tens of centimetres widths of a few millimetres and a variable orientation are ubiquitous in meta granitoids of the neves area tauern window eastern alps italy these pre alpine granitoids were metamorphosed to upper amphibolite facies and deformed during the alpine orogeny allowing the effect of planar healed magmatic fractures on the nucleation of subsequent solid state ductile shear zones to be directly assessed numerical models considering power law viscous materials predict that planar arrays of a weaker mineral e g biotite oriented at around 45 to the shortening direction should nucleate and localize viscous deformation however no discernible localization on the natural small scale biotite trails is observed even when they delineate planes that were well oriented for shear reactivation in contrast heterogeneous shear zones nucleated on larger scale 1 10 m long planar compositional or structural boundaries such as joints dykes quartz veins alteration layers surrounding veins and zones of magma mingling outlined by densely packed clusters of basic enclaves irrespective of their orientation relative to the imposed shortening direction clearly some crucial aspect is missing from purely viscous numerical models we propose that this missing aspect is the observed interplay between fracture and flow with new fractures developing and localizing shear at bulk strains too low for discernible localization to occur on the pre existing healed magmatic fractures natural granitoids have a truly elasto plasto viscous rheology even at low differential stress as in the neves example and for high grade metamorphic conditions considered as typical of wet ductile middle crust

thermodynamic influences on the marine carbon isotope record air sea exchange represents an important controlling factor for the distribution of carbon isotopes in the modern ocean even below the surface mixed layer here we show that this thermodynamic influence varies between water masses with a magnitude which is large relative to the amplitude of typical deep sea sediment 13c records thus changes in air sea exchange processes must be regarded as a significant source of variability for any marine 13c signal

isotopic fractionation of cadmium into calcite abstract cadmium mimics the distribution of the macronutrient phosphate in the oceans and has uses as a palaeoproxy of past ocean circulation and nutrient utilization isotopic analyses of dissolved cd in modern seawater show potential as a new tool for disentangling phytoplankton utilization of cd from abiotic processes such as ocean mixing extending this information into the past requires the cd isotope signal to be captured and faithfully preserved in a suitable sedimentary archive however the role that environmental factors such as temperature may play in controlling cd isotope fractionation into such archives has not been assessed to this end we have performed controlled inorganic caco3 precipitation experiments in artificial seawater solutions we grew calcite under different precipitation rates temperatures salinities and ambient mg2 before measuring cd isotopic compositions by double spike mc icpms we find that the isotopic fractionation factor for cd into calcite c a c o 3 c d aq in seawater is always less than one i e light isotopes of cd are preferred in calcite the fractionation factor has a value of 0 99955 0 00012 and shows no response to temperature mg2 or precipitation rate across the range studied the constancy of this fractionation in seawater suggests that marine calcites may provide a record of the local seawater composition without the need to correct for effects due to environmental variables we also performed caco3 growth in freshwater and in contrast to calcite precipitated from artificial seawater solutions no isotopic offset was recorded between the growth solution and calcite c a c o 3 c d aq 1 0000 0 0001 cadmium isotope fractionation during calcite growth can be explained by a kinetic isotope effect during the largely unidirectional incorporation of cd at the mineral surface further the rate of cd uptake and isotopic fractionation can be modulated by increased ion blocking of crystal surface sites at high salinity the fractionation of cd isotopes observed during precipitation of calcite has the same direction and similar magnitude to that implicated for cd removal from the surface ocean by seawater measurements however flux calculations show that caco3 precipitation is unlikely to play a significant role in setting the cd isotope composition in seawater compared to cd utilization in phytoplankton soft tissue marine carbonates therefore record seawater cd isotope chemistry with potential as a palaeoceanographic proxy rather than drive oceanic cd isotope compositions

cadmium chemical tracer of deepwater paleoceanography the oceanic distribution of cadmium resembles that of phosphorus because the cadmium content of foraminiferal shells is governed by the cadmium content of seawater planktonic and benthic fossil shells can be used to infer nutrient distributions within ancient oceans empirical studies demonstrate that cadmium in benthic foraminiferal shells is related to the bottom water composition through a proportionality constant d 2 9 this constant is the same for each of the species studied cibicidoides wuellerstorfi cibicidoides kullenbergi nuttallides umbonifera and uvigerina spp downcore cadmium data from high quality pacific and atlantic sediment cores suggest that the cadmium inventory of the ocean did not change significantly between the most recent glacial maximum and the present hence changes in the cadmium content of fossils at a site directly reflect changes in nutrient distributions due to altered oceanic circulation patterns studies of cadmium in pleistocene sediments show that deep ocean circulation patterns were significantly different during the most recent glacial maximum in the western north atlantic ocean the nutrient content of waters from 2500 to 3500 m was twice as high during glacials as during interglacial periods signifying an increase in the proportion of waters of antarctic origin in this depth interval and a decrease but not a cessation in the flux of north atlantic deep waters through this depth range below 3500 m the nutrient increase was greater indicating a higher proportion of antarctic bottom water above 2500 m the nutrient content was lower during glacial periods than it has been during interglacial times the cd content of high latitude north atlantic and southern ocean surface waters does not show a significant glacial interglacial change which argues against theories for changes atmospheric carbon dioxide that require changes in high latitude nutrient concentrations

a compositional approach to the reconstruction of geochemical processes involved in the evolution of holocene marine flooded coastal karst basins mljet island croatia abstract geochemical patterns in the environment are always the result of certain processes therefore it is essential to decipher a process to properly evaluate the environmental role and potential of chemical elements compounds this allows the distinction between natural and anthropogenic influence on elemental concentrations however if the compositional nature of geochemical data is neglected erroneous or misleading conclusions regarding the processes involved are probable in this study the reconstruction of depositional environments and processes through the holocene in two sediment cores obtained from submerged sinkholes located on the island of mljet croatia was performed by taking into account the compositional nature of geochemical mineralogical and grainsize data problems involving compositional data are always multivariate for example the concentration of a single element does not carry any interpretative information as only the ratios between elements do this has led to the discovery of a large number of geochemical proxies based on elemental ratios which describe certain environmental conditions and processes involved nevertheless some proxies have been found to be restricted to only some specific environments thus preventing them from being used in general therefore some kind of relation between different proxies is necessary to obtain final conclusions however when using simple elemental ratios those correlations cannot be obtained due to the nature of compositional data with a sequential binary partition of a compositional vector orthonormal log ratio olr coordinates proxies can be constructed when based on expert knowledge those proxies fully acknowledge the geochemical properties of the chosen elements with one major difference that the correlation between newly obtained variables is mathematically well grounded as a result the final conclusion is more accurate in this research geochemical proxies obtained as a representation in olr coordinates of the elements that are enriched compared to the local soil were used to perform principal component analyses it helped to unravel the evolution of sedimentary environments mineralogical xrd and heavy mineral data and grain size analyses supported the conclusions obtained based solely on geochemical data furthermore data analysis suggests that the proxies for redox conditions described in the literature should be used with caution as their use is somewhat limited

a link between reduced barents kara sea ice and cold winter extremes over northern continents the recent overall northern hemisphere warming was accompanied by several severe northern continental winters as for example extremely cold winter 2005 2006 in europe and northern asia here we show that anomalous decrease of wintertime sea ice concentration in the barents kara b k seas could bring about extreme cold events like winter 2005 2006 our simulations with the echam5 general circulation model demonstrate that lower troposphere heating over the b k seas in the eastern arctic caused by the sea ice reduction may result in strong anti cyclonic anomaly over the polar ocean and anomalous easterly advection over northern continents this causes a continental scale winter cooling reaching 1 5 c with more than three times increased probability of cold winter extremes over large areas including europe our results imply that several recent severe winters do not conflict the global warming picture but rather supplement it being in qualitative agreement with the simulated large scale atmospheric circulation realignment furthermore our results suggest that high latitude atmospheric circulation response to the b k sea ice decrease is highly nonlinear and characterized by transition from anomalous cyclonic circulation to anticyclonic one and then again back to cyclonic type of circulation as the b k sea ice concentration gradually reduces from 100 to ice free conditions we present a conceptual model which may explain the nonlinear local atmospheric response in the b k seas region by counter play between convection over the surface heat source and baroclinic effect due to modified temperature gradients in the vicinity of the heating area

porewater cadmium geochemistry and the porewater cadmium δ13c relationship results from two continental margin cores collected off pt sur california make possible a direct determination of the relationship between dissolved cadmium and the carbon isotopic composition of dissolved inorganic carbon in the interstitial water of suboxic marine sediments the 13c values of dissolved inorganic carbon decrease nearly 1 in the top 0 5 cm of the sediments and display a more gradual decrease through the top 20 cm of the sediments dissolved cadmium concentrations increase by 0 6 to 1 5 nmol kg in the top 0 5 cm of the sediments and then rapidly decrease to values of approximately 0 12 nmol kg between 5 and 10 cm into the sediments apparently as a result of scavenging onto iron oxide surfaces this pattern contrasts with porewater cadmium profiles previously reported for pelagic sediments which show no evidence of cadmium scavenging by the sediments however porewater cadmium concentrations are poorly correlated with porewater 13c values in both oxic and suboxic sediments these results suggest that the cadmiumcalcium ratios and 13c values of infaunal benthic foraminifera need not be tightly linked and that the relationship between these two aspects of foraminiferal shell chemistry may vary in response to changes in sediment geochemistry

arctic sea ice loss in different regions leads to contrasting northern hemisphere impacts to explore the mechanisms linking arctic sea ice loss to changes in midlatitude surface temperatures we conduct idealized modeling experiments using an intermediate general circulation model and with sea ice loss confined to the atlantic or pacific sectors of the arctic barents kara or chukchi bering seas extending previous findings there are opposite effects on the winter stratospheric polar vortex for both large magnitude late 21st century and moderate magnitude sea ice loss accordingly there are opposite tropospheric arctic oscillation ao responses for moderate magnitude sea ice loss however there are similar strength negative ao responses for large magnitude sea ice loss suggesting that tropospheric mechanisms become relatively more important than stratospheric mechanisms as the sea ice loss magnitude increases the midlatitude surface temperature response for each loss region and magnitude can be understood as the combination of an indirect part induced by the large scale circulation ao response and a residual direct part that is local to the loss region

trace metal solubility in an anoxic fjord abstract intermittent anoxia in the saanich inlet water column provides an easily accessible marine o2 h2s interface to study the response of metals to both a steep redox gradient and the availability of reactive reduced sulfur species our study indicates a strong anoxic zone sink for copper and cadmium and the characteristically enhanced solubility of manganese and iron thiosulfate and sulfite are below detection limits 1 m and 0 1 m respectively and thus not important in metal complexation elemental sulfur concentrations are high at the oxic anoxic interface and throughout the anoxic zone indicating the potential for metal complexation by polysulfides a thermodynamic approach employing metal sulfide formation and class specific sulfidic ligand complexation to generate equilibrium profiles adequately describes the solubility of iron copper and cadmium the extension of this scheme to other transition and class b metals in other marine environments with redox fronts is suggested

paired carbon isotope and cadmium data from benthic foraminifera implications for changes in oceanic phosphorus oceanic circulation and atmospheric carbon dioxide abstract the carbon isotope and cadmium content of foraminiferal shells from oceanic sediments provides information on past chemical distributions in the ocean starting from reasonable assumptions it can be shown that paired data on both tracers provides more information than does either separately the slope of paired isochronous 13c and cd ca data from fossil benthic foraminifera depends on oceanic p cd and gd 13c p ratios the zero cd ca intercept of this line depends on mean oceanic 13c p and the 13c p ratio given data sufficient to define oceanic mean 13c and cd contents it is possible to place quantitative constraints on the product of the c p redfield ratio and mean oceanic phosphorus and to estimate a circulation parameter which is independent of changes in ocean chemical inventories with the limited available data no significant changes in oceanic p cd can be detected between the holocene and most recent glacial maximum if this data is taken to be representative of the whole ocean then the p and cd contents of the ocean were about 17 higher during the last glacial maximum than at present ocean box models indicate that this change in oceanic p and a 2 c deep ocean cooling during glacials would cause a 47 ppmv reduction in atmospheric pco2 during glacial intervals

fluxes of uranium and thorium series isotopes in the santa barbara basin abstract samples from the manop santa barbara basin sediment trap intercomparison were analyzed for the isotopes of uranium thorium radium lead and polonium all of the traps showed approximately the same compositions and isotopic ratios indicating that they trapped similar materials the234th flux via falling particles was very close to the flux predicted from the production and scavenging rates of234th from the water column the210pb content of the trapped particles and the surface sediments were the same however the measured flux of210pb was seven times greater than the predicted flux predicted and measured fluxes of228th and210po were similarly out of balance to explain this apparent inconsistency we suggest as others have done that the santa barbara basin is an area where scavenging from the water column is intensified and where sediments deposited initially on the margins may be physically remobilized on a short time scale these two effects increase the apparent area from which the basin derives the longer lived isotopes but does not increase significantly the supply of the short lived234th

trace metal enrichments in lake tanganyika sediments controls on trace metal burial in lacustrine systems abstract we investigate the distributions of several key diagenetic reactants c s fe and redox sensitive trace metals mo cd re u in sediments from lake tanganyika east africa this study includes modern sediments from a chemocline transect which spans oxygenated shallow waters to sulfidic conditions at depth as well as ancient sediments from a longer core 2 m taken at 900 m water depth modern sediments from depths spanning 70 335 m are generally characterized by increasing enrichments of c s mo cd and u with increasing water depth but static fe distributions it appears that the sedimentary enrichments of these elements are to varying degrees influenced by a combination of organic carbon cycling and sulfur cycling these modern lake characteristics contrast with a period of high total organic carbon corg total sulfur stot and trace metal concentrations observed in the 900 m core a period which follows the most recent deglaciation 18 11 ky this interval is followed abruptly by an interval 11 6 ky that is characterized by lower c s u and mo consistent with other work we suspect that the low concentrations of s mo and u may indicate a period of intense lake mixing during which time the lake may have been less productive and less reducing as compared to the present an alternative but not mutually exclusive hypothesis is that changes in the lake s chemical inventory driven by significant hydrological changes could be influencing the distribution of sedimentary trace elements through time

controls on trace metal authigenic enrichment in reducing sediments insights from modern oxygen deficient settings any effort to reconstruct earth history using variations in authigenic enrichments of redox sensitive and biogeochemically important trace metals must rest on a fundamental understanding of their modern oceanic and sedimentary geochemistry further unravelling the multiple controls on sedimentary enrichments requires a multi element approach of the range of metals studied most is known about the behavior of fe mn and mo in this study we compare the authigenic enrichment patterns of these elements with a group whose behavior is not as well defined cd cu zn and ni in three oxygen poor settings the black sea the cariaco basin venezuela and the peru margin these three settings span a range of biogeochemical environments allowing us to isolate the different controls on sedimentary enrichment our approach relying on the covariation of elemental enrichment factors ef defined for element x as efx x al sample x al lithogenic has previously been applied to mo and u to elucidate paleoenvironmental information on for example benthic redox conditions the particulate shuttle and the evolution of water mass chemistry we find two key controls on trace metal enrichment first the concentration of an element in the lithogenic background sediment used in calculating efx controls the magnitude of potential enrichment maximum enrichment factors of 376 and 800 are calculated for mo 1 ppm in detrital sediments and cd 0 3 ppm respectively compared to values not greater than 17 in any setting for the other five metals 45 ppm to 4 5 wt in detrital sediments second there is a relationship between the aqueous concentration of the element in overlying seawater and its degree of enrichment in the sediment we further identify four important processes for delivery of trace metals to the sediment these are 1 cellular uptake especially important for zn and cd 2 interaction co precipitation with sulfide mo cu and cd 3 passive scavenging via the traditional particulate shuttle mo ni and cu and 4 an association with the benthic fe redox shuttle mn ni finally we summarize the oceanic mass balance of cd and mo and place the first constraints on the contribution of reducing sediments to the oceanic mass balance of cu zn and ni we show that reducing sediments are the ultimate repository for up to half the total output flux of these elements from the oceanic dissolved pool

trace element indicators of increased primary production and decreased water column ventilation during deposition of latest pliocene sapropels at five locations across the mediterranean sea abstract compositions of productivity and redox sensitive trace metals in two upper pliocene sapropel sequences from western mediterranean odp sites 974 and 975 and eastern mediterranean sites 964 969 and 967 provide information about the conditions leading to sapropel deposition except at site 975 closest to the atlantic ocean all sapropels display elevated element al ratios for ba re cd mo u cr cu v and zn high total organic carbon toc concentrations and ba al ratios point to increased primary productivity during sapropel deposition enrichments of redox sensitive trace elements and elevated re mo ratios indicate water column oxygen depletion during sapropel formation anoxia likely was caused by increased fluxes of organic matter to the seafloor that would have enhanced oxygen demand at depth one of the sapropel sequences investigated in this study insolation cycle 178 contains a zone having low toc low ba al ratios and low trace metal contents these features identify this interval as an interruption of the increased productivity associated with sapropels and of the sub oxic anoxic conditions that are fully developed in the upper half of this sapropel layer significant differences in trace metal enrichments between the eastern and western mediterranean indicate that the eastern basin was a focal point for sapropel initiation in contrast site 975 appears to have been heavily influenced by the atlantic ocean during i cycles 178 and 180 and was not strongly influenced by the paleoceanographic changes affecting the rest of the mediterranean

comparative behavior of authigenic re u and mo during reoxidation and subsequent long term burial in marine sediments the trace element re is enriched in mildly reducing suboxic sediments close to or slightly later in the redox sequence than u and before reduction of mo in more reducing sulfidic sediments this work investigates the behavior of authigenic re during oxidation and long term burial in the sediments of several turbidites from the madeira abyssal plain exposure to bottom water o2 clearly remobilizes authigenic re as found in previous work but reimmobilization occurs in reducing sediments below the oxidation front over a depth range of 0 5 3 m the large spread of the re burndown peak must be kinetically controlled perhaps influenced by the corg content once reimmobilized however the authigenic re signal remains immobile for at least 3 4 myr authigenic u in contrast consistently forms peaks 0 5 m broad whereas authigenic mo is lost on oxidation and does not appear to be refixed unless authigenic pyrite is formed these results imply that any paleoenvironmental significance of authigenic re will be compromised in low sedimentation rate environments 10 cm kyr where there is significant exposure of authigenic re to bottom water o2 however authigenic re records from rapidly accumulating continental margin sediments with much less exposure to bottom water o2 still offer considerable potential as high fidelity recorders of past reducing conditions

the flushing of two deep sea basins southern california borderland a time series of water temperature salinity and nutrient measurements has been made in san pedro and san nicolas basins of the southern california borderland between i977 and 1988 these basins exhibit temporally coincident changes in temperature and nutrient content defining a period of basin flushing 1982 1984 and a period of stagnation 1984 1987 during the flushing period cooler oxygenand no rich water replaces warmer oxygenand no depleted bottom water flushing produces a decrease of 0 2 c in the average temperature of san pedro basin bottom water 790 900 m and an increase in the average oxygen content by 12 pm these values are 0 i and 3 for san nicolas basin 1 400 l 800 m the residence time of water in san pedro basin during the flushing period is 12 6 months and j t2 months in san nicolas basin a box model approach constrained by the time series data for the stagnation period was used to determine values of the effective vertical eddy diffusivities for the 790 m horizon in san pedro basin and 1 400 m horizon in san nicolas basin 1 3 0 4 and 9 9k3 4 cm sk respectively

influence of low arctic sea ice minima on anomalously cold eurasian winters 1 influence of low arctic sea ice minima in early autumn on the wintertime climate over eurasia is investigated observational evidence shows that significant cold anomalies over the far east in early winter and zonally elongated cold anomalies from europe to far east in late winter are associated with the decrease of the arctic sea ice cover in the preceding summer to autumn seasons results from numerical experiments using an atmospheric general circulation model support these notions the remote response in early winter is regarded as a stationary rossby wave generated thermally through an anomalous turbulent heat fluxes as a result of anomalous ice cover over the barents kara seas in late autumn which tends to induce an amplification of the siberian high causing colder conditions over the far east the late winter cold anomalies over eurasia are also reproduced in our experiment which is associated with the negative phase of the north atlantic oscillation

does ocean coupling matter for the northern extratropical response to projected arctic sea ice loss the question of whether ocean coupling matters for the extratropical northern hemisphere atmospheric response to projected late 21st century arctic sea ice loss is addressed using a series of experiments with community climate system model version 4 at 1 spatial resolution under different configurations of the ocean model component no interactive ocean thermodynamic slab ocean and full depth dynamic plus thermodynamic ocean ocean atmosphere coupling magnifies the response to arctic sea ice loss but does not change its overall structure however a slab ocean is inadequate for inferring the role of oceanic feedbacks the westerly winds along the poleward flank of the eddy driven jet weaken in response to arctic sea ice loss accompanied by a smaller magnitude strengthening on the equatorward side with largest amplitudes in winter dynamical and thermodynamic oceanic feedbacks amplify this response by approximately 50 air temperature precipitation and sea level pressure responses also show sensitivity to the degree of ocean coupling

on the preservation of laminated sediments along the western margin of north america 1 piston gravity and multicores as well as hydrographic data were collected along the pacific margin of baja california to reconstruct past variations in the intensity of the oxygen minimum zone omz gravity cores collected from within the omz north of 24 n did not contain laminated surface sediments even though bottom water oxygen bwo concentrations were close to 5 mol kg however many of the cores collected south of 24 n did contain millimeter to centimeter scale brown to black laminations in holocene and older sediments but not in sediments deposited during the last glacial maximum in addition to the dark laminations holocene sediments in soledad basin silled at 290 m also contain white coccolith laminae that probably represent individual blooms two open margin cores from 430 and 700 m depth that were selected for detailed radiocarbon dating show distinct transitions from bioturbated glacial sediment to laminated holocene sediment occurring at 12 9 and 11 5 ka respectively the transition is delayed and more gradual 11 3 10 0 ka in another dated core from soledad basin the observations indicate that bottom water oxygen concentrations dropped below a threshold for the preservation of laminations at different times or that a synchronous hydrographic change left an asynchronous sedimentary imprint due to local factors with the caveat that laminated sections should therefore not be correlated without independent age control the pattern of older sequences of laminations along the north american western margin reported by this and previous studies suggests that multiple patterns of regional productivity and ventilation prevailed over the past 60 kyr

particulate cadmium stable isotopes in the subarctic northeast pacific reveal dynamic cd cycling and a new isotopically light cd sink the nutrient type distribution of dissolved cadmium concentrations dcd reflects a biological control in the global ocean with uptake of dissolved cd into biogenic particles in surface waters and regeneration of particulate cd at depth depth profiles of dissolved cd stable isotope composition d 114 110cd while sparse in coverage exist for most of the major ocean basins with spatial coverage improving through the efforts of the geotraces program however a dearth of similarly resolved particulate 114 110cd p 114 110cd distributions limits our ability to use stable cd isotopes to better understand cd cycling in the global ocean here we present two p 114 110cd depth profiles from the subarctic northeast pacific which demonstrate more complex 114 110cd cycling than dissolved profiles would suggest surface p 114 110cd while lighter than surface d 114 110cd is heavy relative to pacific deepwater and crustal p 114 110cd components surface particulate and dissolved 114 110cd distributions are not well explained by closed system rayleigh fractionation following a single fractionation factor in agreement with other recent studies in the atlantic and pacific oceans these variable fractionation trends in surface waters complicate the potential utility of 114 110cd as a paleoproductivity proxy particulate 114 110cd becomes lighter as particulate cd is remineralized in the nutricline reaching a minimum p 114 110cdof around 0 5 among the lightest values reported in natural telluric samples this p 114 110cd trend within the nutricline might be explained by 1 multiple pools of particulate cd with different isotopic compositions and labilities or 2 by fractionation during particulate cd remineralization the observed shallow loss of heavy p 114 110cd above the winter mixed layer rather than the formation of especially light surface p 114 110cd may help to maintain the observed surface to deep d 114 110cd gradient below the mid depth p 114 110cd minimum p 114 110cd increases with depth toward the deepwater d 114 110cd value possibly reflecting an isotopic equilibration between the particulate and dissolved phases dissolved 114 110cd profiles show uniform isotope composition at intermediate depths while calculated remineralized p 114 110cd is isotopically variable and distinct from the bulk dissolved pool this suggests that one dimensional particle export and regeneration is not the primary control on d 114 110cd in the pacific ocean but rather that regenerated 114 110cdis spatially or temporally variable and an advected d 114 110cd signal from subsurface southern ocean waters controls deep north pacific d 114 110cd our results imply that export of isotopically light p 114 110cdto shelf sediments may act as an important oceanic sink helping to balance the known sources and sinks of cd with the global deepwater d 114 110cd

influence of coastal upwelling and el nino southern oscillation on nearshore water along baja california and chile shore based monitoring during 1997 2000 1 in order to determine the sensitivity of coastal upwelling tracers to seasonal wind forcing and el nino southern oscillation enso off baja california and chile nearshore salinity cadmium cd and nutrients phosphate silicate nitrate nitrite were monitored in surf zone waters at six locations along the north and south american coasts during 1997 2000 the clearest responses to upwelling favorable wind forcing were observed at the southern tip of baja california 23 3 n and off central southern chile 36 5 s upwelling tracers at 23 3 n were also the most sensitive to el nino average summer cd and nutrient enrichments were 60 lower following el nino than during the previous non el nino upwelling season at two sites on the northern and central chile coasts conditions associated with el nino resulted in salinity anomalies 1 such large shifts in nearshore water properties suggest it may be possible to reconstruct past enso patterns from geochemical paleonutrient paleosalinity proxy records preserved in nearshore archives such as mollusc or foraminifera shells

radium 228 distribution and mixing in san nicolas and san pedro basins southern california borderland sediment profiles of 228ra and 232th and water column profiles of 228ra are presented for san nicolas and san pedro basins located in the southern california borderland these data are used to estimate fluxes of 228ra from the sediments the vertical eddy diffusivity kz in the water column and the upwelling velocity wz the fluxes of 228ra from sediments estimated by integrating the downcore deficiency of 228ra with respect to its parent nuclide 232th are 335 115 atoms m2s for san nicolas basin and 166 50 atoms m2s for san pedro basin san nicolas basin sediments have an excess of 228ra in the upper 4 cm but irrigation and diffusion create a 228ra deficiency from 4 to 30 cm san pedro basin sediments are anoxic and laminated have a 228ra deficiency above 6 12 cm depth and have no surface excess of 228ra basin waters appear to be well mixed horizontally below sill depth and in steady state with respect to 228ra concentrations of 228ra increase from sill depth to the bottom ranging from approximately 1 0 dpm 100 kg to 2 4 dpm 100 kg in san nicolas basin and from 1 6 dpm 100 kg to 3 1 dpm 100 kg in san pedro basin estimates of kz and wz at several horizons in these basins are made by evaluating two steady state mass balance equations one for 228ra and one for heat this approach is hindered by an inability to accurately define the temperature in waters flowing over the sills and the apparent failure of topography to completely restrict horizontal exchange in the upper part of the water column below sill depth in each basin upper limits for kz are 23 cm2 s at 1700 m in san nicolas and 2 8 cm2 s at 850 m in san pedro basin our best estimates for kz and wz for the deeper part of the basins are kz 5 17 cm2 s and wz 50 150 m y in san nicolas basin and kz 1 3 cm2 s and wz 20 50 m y in san pedro basin the differences in kz between basins reflect differences in the buoyancy gradients upwelling velocities increase from the bottom to the sill of each basin

ventilation changes in the northeast pacific during the last deglaciation under present climate conditions convection at high latitudes of the north pacific is restricted to shallower depths than in the north atlantic to what extent this asymmetry between the two ocean basins was maintained over the past 20 kyr is poorly known because there are few unambiguous proxy records of ventilation from the north pacific we present new data for two sediment cores from the california margin at 800 and 1600 m depth to argue that the depth of ventilation shifted repeatedly in the northeast pacific over the course of deglaciation the evidence includes benthic foraminiferal cd ca 18o 16o and 13c 12c data as well as radiocarbon age differences between benthic and planktonic foraminifera a number of features in the shallower of the two cores including an interval of laminated sediments are consistent with changes in ventilation over the past 20 kyr suggested by alternations between laminated and bioturbated sediments in the santa barbara basin and the gulf of california keigwin and jones 1990 kennett and ingram 1995 behl and kennett 1996 data from the deeper of the two california margin cores suggest that during times of reduced ventilation at 800 m ventilation was enhanced at 1600 m depth and vice versa this pronounced depth dependence of ventilation needs to be taken into account when exploring potential teleconnections between the north pacific and the north atlantic

characteristics of the deep ocean carbon system during the past 150 000 years σco2 distributions deep water flow patterns and abrupt climate change abstract studies of carbon isotopes and cadmium in bottom dwelling foraminifera from ocean sediment cores have advanced our knowledge of ocean chemical distributions during the late pleistocene last glacial maximum data are consistent with a persistent high co2 state for eastern pacific deep water both tracers indicate that the mid depth north and tropical atlantic ocean almost always has lower co2 levels than those in the pacific upper waters of the last glacial maximum atlantic are more co2 depleted and deep waters are co2 enriched compared with the waters of the present in the northern indian ocean 13c and cd data are consistent with upper water co2 depletion relative to the present there is no evident proximate source of this co2 depleted water so i suggest that co2 depleted north atlantic intermediate deep water turns northward around the southern tip of africa and moves toward the equator as a western boundary current at long periods 15 000 years milankovitch cycle variability is evident in paleochemical time series but rapid millennial scale variability can be seen in cores from high accumulation rate series atlantic deep water chemical properties are seen to change in as little as a few hundred years or less an extraordinary new 52 7 m long core from the bermuda rise contains a faithful record of climate variability with century scale resolution sediment composition can be linked in detail with the isotope stage 3 interstadials recorded in greenland ice cores this new record shows at least 12 major climate fluctuations within marine isotope stage 5 about 70 000 130 000 years before the present

geochemical evidence for anoxic deep water in the arabian sea during the last glaciation various paleoceanographic studies have indicated that the deep ocean was probably depleted in dissolved oxygen during the last glacial period approximately 18 kyr b p delta sup 18 o stage 2 compared to present time however direct evidence of low oxygen content in the deep waters has been lacking here the authors report geochemical evidence of near anoxic conditions in the deep arabian sea during the entire last glacial cycle delta sup 18 o stages 2 3 and 4 anoxia is inferred from the concomitant enrichment of organic carbon and authigenic uranium in the glacial sections of a core from the deep eastern arabian sea the anoxic conditions during the last glacial period probably caused by a change in deep water circulation evidently enhanced preservation of organic matter and simultaneous removal of uranium from seawater 57 refs 3 figs 2 tabs

contributions of ice thickness to the atmospheric response from projected arctic sea ice loss author s labe z peings y magnusdottir g abstract 2018 american geophysical union all rights reserved a large ensemble of simulations from a high top atmospheric general circulation model are conducted to compare the atmospheric responses from loss of arctic sea ice thickness and sea ice concentration the response to projected sea ice thickness loss indicates substantial surface warming over the arctic ocean and up to 1 c of cooling in eurasia while the dynamic circulation response from sea ice thickness loss is smaller in magnitude it has a similar spatial anomaly pattern as that due to sea ice concentration loss this pattern resembles the negative phase of the northern annular mode the simulations reveal that sea ice thickness loss enhances the thermodynamic and large scale circulation response from sea ice anomalies these results stress the importance of considering a realistic sea ice thickness distribution in future atmospheric general circulation model sea ice perturbation experiments

abrupt termination of marine isotope stage 16 termination vii at 631 5 ka in santa barbara basin california the marine isotope stage 16 15 boundary termination vii is the first deglacial warming step of the late quaternary following the mid pleistocene transition mpt when 41 kyr climatic cycles shifted to strong 100 kyr cycles the detailed structure of this important climatic event has remained unknown until now core mv0508 19jpc from santa barbara basin california contains a decadal scale climatic and geochemical sediment record of 4000 years duration that includes the early part of this deglacial episode this record reveals that the climatic shift during the early deglacial occurred rapidly 700 years in a progression of three abrupt warming steps the onset of marine isotope stage mis 15 was remarkably abrupt with 4 5 c sea surface warming in 50 years the deglacial sequence contains the well dated lava creek tephra 631 3 4 ka from yellowstone caldera used to date the onset of termination vii at 631 5 ka the late mis 16 and early mis 15 interval exhibits multiple decadal scale negative excursions in 13c of planktic foraminifera likely the result of repeated discharges of methane from methane hydrates associated with both ocean warming and low sea level a warm interstadial that interrupts late mis 16 is marked by elevated concentrations of redox sensitive elements indicating sulfidic oxygen deficient bottom and pore waters and elevated concentrations of total organic carbon and cd reflecting increased surface productivity unlike younger sediments on the california margin these indicators of increased productivity and low dissolved oxygen do not consistently correspond with each other or with preserved laminations possibly reflecting instability of a still evolving ocean atmosphere system following the mpt

wave maintained annular modes of climate variability abstract the leading modes of month to month variability in the northern and southern hemispheres are examined by comparing a 100 yr run of the geophysical fluid dynamics laboratory gcm with the ncep ncar reanalyses of observations the model simulation is a control experiment in which the ssts are fixed to the climatological annual cycle without any interannual variability the leading modes contain a strong zonally symmetric or annular component that describes an expansion and contraction of the polar vortex as the midlatitude jet shifts equatorward and poleward this fluctuation is strongest during the winter months the structure and amplitude of the simulated modes are very similar to those derived from observations indicating that these modes arise from the internal dynamics of the atmosphere dynamical diagnosis of both observations and model simulation indicates that variations in the zonally symmetric flow associated with the annular modes are forced by eddy fluxes in the free troposphere while

acoustic emission and velocities associated with the formation of compaction bands in sandstone received 31 may 2005 revised 2 may 2006 accepted 22 june 2006 published 7 october 2006 1 a series of laboratory experiments has been conducted in which three dimensional 3 d locations of acoustic emissions ae were recorded and used to analyze the development of compaction bands in bleurswiller sandstone which has a porosity of 25 results were obtained for saturated samples deformed under triaxial compression at three different confining pressures 60 80 and 100 mpa a pore pressure of 10 mpa and room temperature we recorded acoustic emissions compressional and shear wave velocities and porosity reduction under hydrostatic condition and under triaxial loading conditions at a constant axial strain rate our results show that seismic velocities and their amplitude increased during hydrostatic pressure build up and during initial axial loading during shear enhanced compaction axial and radial velocities decreased progressively indicating an increase of stress induced damage in the rock in experiments performed at confining pressures of 80 and 100 mpa during triaxial loading acoustic emissions were localized in clusters during progressive loading ae clusters grow horizontally perpendicular to the maximum principal stress direction indicating formation of compaction bands throughout the specimens microstructural analysis of deformed specimens confirmed a spatial correspondence of ae clusters and compaction bands for the experiment performed at a confining pressure of 60 mpa ae locations and microstructural observations show symmetric compaction bands inclined to the cylinder axis of the specimen in agreement with predictions from recent theoretical models

the viscous brittle transition of crystal bearing silicic melt direct observation of magma rupture and healing magmas may fl ow or break depending on their deformation rate the transition between such viscous and brittle behavior controls the style of volcanic eruptions while the brittle failure of silicate melts is reasonably well characterized the effect of crystals on the viscous brittle transition has not yet been constrained here we examine the effect of suspended crystals on the mechanical failure of magmas using torsion experiments performed at temperatures 600 900 c strain rates 10 4 10 1 s 1 and confi ning pressures 200 300 mpa relevant for volcanic systems we present a relationship that predicts the critical stress and associated strain rate at which magmas fail as a function of crystal fraction furthermore the results demonstrate that the viscous to brittle transition occurs at lower stresses and strain rates when crystals are present the fractures formed during brittle failure of crystal bearing magma originate in the melt phase which enables gas to escape and hence to reduce gas overpressure these degassing pathways heal on relatively short time scales owing to the high confi ning pressure at depth highlighting the possibility that coherent lavas may actually be the healed remains of partially degassed magma parcels that have undergone many cycles of fracturing and healing

particulate iron and manganese in the santa barbara basin california abstract particulate fe and mn may be important trace metal scavengers in the water column as well as being probable indicators of biologically mediated redox processes a study has been made of suspended particulate composition in the santa barbara basin a shallow near shore basin off southern california with sub oxic conditions below sill depth observations have revealed several interesting phenomena relating to the geochemistry of fe and mn most striking is a profound enrichment of particulate fe in samples from the bottom two hundred meters these particulates have a constant fe p mole ratio of about three and may originate at the sediment water interface or may be transported to the basin from local marshes for particulate mn enrichments are observed both in the sub sill waters and near the base of the euphotic zone a consideration of particle removal rates suggests that the sub photic zone enrichment has a biogenic origin in the sub sill waters enrichment in mn is apparently due to the precipitation of dissolved mn diffusing from the anoxic basin sediments a simple mass balance suggests that most of the mn lost from the sediments is transported from the santa barbara basin in dissolved form

diagenetic separation of cadmium and manganese in suboxic continental margin sediments abstract the vertical distribution of cd differs from that of mn in sediment cores taken from the continental margins of the arctic and atlantic oceans the oxic surface sediment is depleted in cd and enriched in mn whereas the subsurface sediment is enriched in cd and depleted in mn in some cores the distributions of solid phase and dissolved mn are offset the porewater profiles indicate that mn is being precipitated relatively deep in the sediment whereas the solid phase distributions indicate that mn has been precipitated very close to the sediment surface in the recent past at one deep site located near the base of the continental slope 3000 m the offset may be caused by a relatively recent decrease in ocean productivity a corresponding decrease in the organic carbon flux to the sediment and a subsequent migration of the redox boundary deeper into the sediment however at a site where the upper sediment layers have accumulated during the last few decades this explanation cannot account for the offset distributions we propose that a fluctuating input of organic matter to the sediment on seasonal or decadal timescales causes the position of the redox boundary to fluctuate the fluctuating redox boundary pumps dissolved mn upward and concentrates it as mn oxide in a distinct layer at the upper limit of the redox excursion at the same time it pumps cd downward and concentrates it in a distinct layer at the lower limit of the redox excursion the net result of a fluctuating redox boundary is to increase the spatial separation of cd and mn during the early diagenesis of suboxic sediments

suboxic trace metal geochemistry in the eastern tropical north pacific abstract we analyzed al ti fe mn cu ba cd u mo v and re in water column settling particulate and sediment 0 to 22 cm samples from the intense oxygen minimum zone omz of the eastern tropical north pacific near mazatlan mexico the goal was to determine how the geochemistry of these elements was influenced by suboxic water column conditions and whether the sediments have a unique suboxic geochemical signature the water column was characterized by a mn maximum reaching 8 nmol kg 1 at 400 m concentrations of cu ba cd mo re u and v were unaffected by the low o2 conditions and were comparable to those of the open ocean sinking particles were composed of lithogenic particles of detrital origin and nonlithogenic particles of biogenic origin al ti and fe were mostly at least 79 lithogenic about 75 of the mn was nonlithogenic significant amounts at least 58 of cu ba cd and mo were nonlithogenic sediment geochemistry varied across the continental shelf and slope cadmium u and re have prominent maxima centered at 310 m with 12 3 ppm 10 9 ppm and 68 3 ppb respectively at the core top high values of mo averaging 6 8 ppm and v averaging 90 ppm are seen in omz surface sediment additional down core enrichment occurs for all redox sensitive elements in the top 10 cm for u mo v and re surface sediments are a poor indicator of metal enrichment comparison of the nonlithogenic composition of sediments with sinking particles suggests that direct input of plankton material enriched in metals makes a significant contribution to the total composition especially for cd u and mo we evaluated re mo and cd u ratios as tracers for redox environments rhenium and mo concentrations and re mo ratios do not lead to consistent conclusions concurrent enrichments of re and mo are an indicator of an anoxic depositional environment in contrast high re mo ratios are an indicator of suboxic conditions cadmium is enriched in surface sediments while u has considerable down core enrichment the concentrations of cd and u and the cd u ratio do not follow patterns predicted from thermodynamics though the water column is suboxic these four redox sensitive elements indicate that the sediments are anoxic the implication for paleostudies is that a trace metal sediment signature that indicates anoxic conditions is not necessarily attributable to an anoxic water column

a deliberate tracer experiment in santa monica basin the mixing of heat and chemical constituents across density strata in the ocean plays a major role in ocean circulation and in the response of the climate to thermal and chemical perturbations we are developing a tracer technique which in conjunction with fluid dynamical measurements promises to improve our understanding and our estimates of such diapycnal mixing in a prototype tracer experiment in santa monica basin 50km west of los angeles two tracers sulphur hexafluoride sf6 and per fluorodecalin pfd have been injected on an isopycnal surface near the centre of the basin after 50 days the tracers had mixed along the isopycnal surface to nearly every part of the basin although relatively little had penetrated to the basin walls the diapycnal spreading of the tracer distributions during this first stage of the experiment yielded an apparent eddy diffusivity of 0 33 0 08 cm2s 1 at the ambient density gradient of 4 0 0 5 10 9g cm 4

southern california inner basin sediment trap calibration the deployment of particle interceptor traps pits in the three inner basins of the southern california bight santa barbara santa monica and san pedro where preserved laminated bottom sediments occur provides a natural calibration between the parameters determined with the pits and those derived from the historical sedimentary deposits the accumulation rates and chemical composition of the pit materials compare favorably with these recently deposited bottom sediments the ratio of the measured particle collection rate to the sediment accumulation rate for these three basins averaged0 93 0 20 radionuclide 210pb 228th 232th and trace element fe cu zn cd pb compositions of the pit materials and surface sediments agree within generally 30 in each basin an application of pits as a sampling system in an outer basin san nicolas where the sedimentary record has been obscured by bioturbation is also presented to further demonstrate the utility of pits for spatial and temporal studies of various aspects of particle transport and sediment deposition based on the calibration of the pits in the three inner basins we conclude from the comparison of the radionuclide and trace element compositions between the pit materials and surface sediments from the san nicolas basin that recently deposited sedimentary material has been mixed by bioturbation with older material from the last several hundred years excess210pb and the228th 232th activity ratio in the pit material are 6 and 15 times higher than in the surface sediment total pb and1n hno3 leachable pb are 4 and 8 fold higher in the pit material

cadmium and delta13c paleochemical ocean distributions during the stage 2 glacial maximum changes in heat and salt transport by ocean currents have been implicated in ice age climate cycles weyl 1 968 newell 1 974 broecker et al 1 990b in addition to the direct physical effects of the ocean on climate the ocean carbon system controls atmospheric co2 and the co2 fluctuations documented in ice core bubbles barnola et a1 1 987 neftel et a1 1 988 are thought to be a significant factor in climate oscillations hansen et al 1 984 dramatic changes in oceanic circulation patterns and carbon system chemistry have occurred during the late quaternary glacial interglacial global climate cycles boyle keigwin 1 982 curry lohmann 1 983 shackleton pisias 1 984 boyle keigwin 1 987 duplessy et al 1 988 curry et al 1 988 broecker et al i 990a these changes in the ocean system may be significant driving forces in the progression of ice age co2 cycles toggweiler sarmiento 1 985 ennever mcelroy 1 985 wenk siegenthaler 1 985 boyle 1 988a b broecker peng 1 990 the oceanic distributions of c513c cd and other carbon system linked properties are controlled by the interaction between biological uptake and decomposition with the general circulation of the ocean because records of past oceanic cd and c5 1 3c are preserved in shells of planktonic and benthic foraminifera

the arctic oscillation signature in the wintertime geopotential height and temperature fields the leading empirical orthogonal function of the wintertime sea level pressure field is more strongly coupled to surface air temperature fluctuations over the eurasian continent than the north atlantic oscillation nao it resembles the nao in many respects but its primary center of action covers more of the arctic giving it a more zonally symmetric appearance coupled to strong fluctuations at the 50 hpa level on the intraseasonal interannual and interdecadal time scales this arctic oscillation ao can be interpreted as the surface signature of modulations in the strength of the polar vortex aloft it is proposed that the zonally asymmetric surface air temperature and mid tropospheric circulation anomalies observed in association with the ao may be secondary baroclinic features induced by the land sea contrasts the same modal structure is mirrored in the pronounced trends in winter and springtime surface air temperature sea level pressure and 50 hpa height over the past 30 years parts of eurasia have warmed by as much as several k sea level pressure over parts of the arctic has fallen by 4 hpa and the core of the lower stratospheric polar vortex has cooled by several k these trends can be interpreted as the development of a systematic bias in one of the atmosphere s dominant naturally occurring modes of variability

miocene benthic foraminiferal cd ca records south atlantic and western equatorial pacific cadmium to calcium records in benthic foraminifera interpreted in conjunction with carbon isotope records reflect oceanic circulation patterns and oceanic inventories of cd carbon 13 carbon 12 and indirectly phosphorus cd ca ratios have been determined in benthic foraminifera cibicidoides spp for the late middle and early miocene from a site in the south atlantic deep sea drilling project dsdp site 525 leg 74 2500 m walvis ridge and from a site in the western equatorial pacific dsdp site 289 leg 30 2200 m ontong java plateau both sites have well established carbon isotope records for benthic foraminifera typical of the global record dominated by inventory changes cd ca ratios and carbon isotope values were averaged for the miocene in time intervals substantially longer than estimated oceanic residence times of cd c or p oceanic mean cd ca and carbon isotopes were estimated as weighted means of the values from both sites using weighting factors based on replicating modern oceanic means this may tend to underestimate oceanic inventories earlier than the late miocene because of changing water mass dominance at the south atlantic site from these means the oceanic cd inventory appears relatively stable during the miocene while there are large changes in carbon isotope inventories miocene cd inventory estimates are at least 20 lower than published estimates for quaternary stages 1 and 2 increasing oceanic cd inventories over the past 10 m y are consistent with hypotheses of increased river fluxes in the recent geologic past cd ca differences between sites may be indicative of the extent of basin basin fractionation from bottom water circulation although the validity of this comparison depends on how representative each of these two sites is through time for its respective ocean basin the pacific atlantic cd ca difference based on these two sites was larger in the late miocene compared to the middle and early miocene the relationship between cd ca and carbon isotope inventories and intersite gradients for these sites suggests that either oceanic phosphorus inventories or parameters related to marine organic matter composition must have been different in the miocene than at present large changes in the carbon isotope balance reflected as both positive and negative excursions in the carbon isotope inventories occurred with little effect on cd inventories changes in phosphorus fluxes associated with these carbon isotope flux changes may have been compensated for by changing deposition fluxes to other phosphorus sinks phosphorus inventories may have increased from the middle to late miocene with increasingly negative oceanic carbon isotope inventories however confirmation of these suggestions depend on collecting more cd ca and 13c data throughout the miocene oceans and on developing the application of other constraints for these interpretations

seismicity preceding volcanic eruptions new experimental insights a variety of seismic signals representing different physical mechanisms precedes volcanic eruptions the most meaningful signals are high and low frequency earthquakes and volcanic tremor that have tentatively been related to fracturing and magma transport in the volcanic edifice we provide experimental support for this association by reproducing magma migration while recording seismic signals opening fractures emit high frequency acoustic events while the switch to low frequency and harmonic tremor accompanies the flow of the melt in the fractures discerning between these seismic signals in nature can significantly refine volcanic hazard evaluation

sensitivity of the phosphate cadmium carbon isotope relation in the ocean to cadmium removal by suboxic sediments reconstructions of past deep ocean nutrient concentrations rely largely on the carbon isotopic composition and cadmium content of shells of benthic foraminifera when comparing records of these two paleonutrient tracers a relation similar to the phosphate cadmium carbon isotope relation in the water column today is generally assumed we present new water column sediment and pore water data from the california continental margin which demonstrate that cd accumulation is enhanced in suboxic sediments these results suggest that the oceanic cd inventory is sensitive to changes in the areal extent and redox intensity of suboxic sediments and thus that the phosphate cadmium relation in the ocean could have been different in the past the magnitude of this effect and its evolution through time is presently hard to quantify because the oceanic cd budget is poorly constrained

relative source locations of continuous tremor before and after the subplinian events at shinmoe dake in 2011 volcano monitoring systems are not always ready to resolve signals at the onset of eruptive activity this study makes use of stations installed later to calibrate the performance of the stations that had been operated before the eruption seven stations recorded continuous volcanic tremor before and during the subplinian eruptions of shinmoe dake japan in 2011 we estimated the source locations of the tremor using the amplitude distribution the stability of the analysis was obtained by careful selection of time windows in which signals from a single source are dominated the site effects and the regional attenuation factor were evaluated using tremor recorded after the major eruptions by a dense seismic array and a good number of stations a tremor source changed its depth beneath the crater for one week before the major eruption rising from a depth of a few kilometer to the water layer three times each of which occurred following shallow inflation and minor eruptions it is interpreted as migration of gas probably with magma which further transported heat to the water layer and triggered the subplinian eruptions

the geochemical cycle of rhenium a reconnaissance rhenium re is one of a suite of elements including uranium and molybdenum that display conservative behavior in seawater and are enriched in anoxic sediments the decay of187re to187os provides a geochronometer in ancient sedimentary rocks and gives rise to os isotopic variations in nature in order to better characterize its sources to seawater re was measured in three major rivers amazon orinoco ganges brahmaputra and some of their tributaries re concentrations span four orders of magnitude from 0 02 to 400 pmol kg with the highest concentrations found in rivers draining black shales in the venezuelan andes mainstream re levels in the three rivers are between 1 and 10 pmol kg with a flux weighted average of 2 3 pmol kg the residence time for re in the oceans is estimated to be 750 000 yr with respect to river inputs re profiles from the atlantic and pacific oceans confirm that re behaves conservatively in seawater with no significant uptake onto particles and or recycling within the water column this is also true in the anoxic water column of the black sea re removal into anoxic sediments occurs at or below the sediment water interface as demonstrated in sediment pore waters from chesapeake bay in oxic sediments re is not cycled with manganese oxides and it is not enriched in very slowly accumulating pelagic sediments with a large hydrogenous iron and manganese component or in manganese nodules burial of re in anoxic sediments which accumulate on 0 3 of the ocean floor removes approximately 50 of the riverine re flux to the oceans hence oceanic re concentrations may be very sensitive to changes in the area of anoxic sedimentation

dissolved sulfide distributions in the water column and sediment pore waters of the santa barbara basin dissolved sulfide concentrations in the water column and in sediment pore waters were measured by square wave voltammetry nanomolar detection limit during three cruises to the santa barbara basin in february 1995 november december 1995 and april 1997 in the water column sulfide concentrations measured outside the basin averaged 3 1 nm n 28 in the 0 to 600 m depth range inside the basin dissolved sulfides increased to reach values of up to 15 nm at depths 400 m a suite of box cores and multicores collected at four sites along the northeastern flank of the basin showed considerable range in surficial 400 m at 10 cm decreases in water column nitrate below the sill depth indicate nitrate consumption 55 to 137 mole m 2 h 1 similar to nearby santa monica basin peaks in pore water iron concentrations were generally observed between 2 and 5 cm depth with shallowest peaks at the 590 m site these observations including observations of the benthic microfauna suggest that the extent to which the sulfide flux sustained by elevated pore water concentrations reaches the water column may be modulated by the abundance of sulfide oxidizing bacteria in addition to iron redox and precipitation reactions

evidence for enhanced phosphorus regeneration from marine sediments overlain by oxygen depleted waters phosphorus regeneration and burial fluxes determined from in situ benthic flux chamber and solid phase measurements at sites on the californian continental margin peruvian continental slope north carolina continental slope and from the santa monica basin california are reported comparison of these sites indicates that o2 depleted bottomwaters enhance p regeneration from sediments diminishing overall phosphorus burial efficiency based on these observations a positive feedback linking ocean anoxia enhanced benthic phosphorus regeneration and marine productivity is proposed on shorter timescales these results also suggest that o2 depletion in coastal regions caused by eutrophication may enhance p regeneration from sediments thereby providing additional p necessary for increased biological productivity

planktonic foraminiferal cd ca paleonutrients or paleotemperature records of cd ca in planktonic foraminiferal calcite of globigerinoides bulloides in cores from the subantarctic region of the southern ocean show large glacial interglacial variations with lower cd ca by 0 06 0 10 mol mol 1 at glacial times interpretation of these records in terms of lower dissolved phosphate and inferred higher glacial nutrient utilization has significant implications for glacial atmospheric carbon dioxide pco2 draw down however box core top data for g bulloides in the north atlantic suggest that the incorporation of cd into planktonic foraminifera relative to seawater dcd is temperature sensitive dcd 0 637 exp 0 15t when the subantarctic planktonic cd ca records are corrected for this temperature dependence they show little or no glacial interglacial diferences if as seems likely this observation can be interpreted to indicate a minimal change 0 5 mol kg 1 in surface water phosphate concentrations then the explanation for lowered glacial pco2 must be looked for elsewhere