on the 1470 year pacing of dansgaard oeschger warm events 1 the oxygen isotope record from the greenland ice sheet project 2 gisp2 ice core was reanalyzed in the frequency and time domains the prominent 1470 year spectral peak which has been associated with the occurrence of dansgaard oeschger interstadial events is solely caused by dansgaard oeschger events 5 6 and 7 this result emphasizes the nonstationary character of the oxygen isotope time series nevertheless a fundamental pacing period of 1470 years seems to control the timing of the onset of the dansgaard oeschger events a trapezoidal time series model is introduced which provides a template for the pacing of the dansgaard oeschger events statistical analysis indicates only a 3 probability that the number of matches between observed and template derived onsets of dansgaard oeschger events between 13 and 46 kyr b p resulted by chance during this interval the spacing of the dansgaard oeschger onsets varied by 20 around the fundamental 1470 year period and multiples thereof the pacing seems unaffected by variations in the strength of north atlantic deep water formation suggesting that the thermohaline circulation was not the primary controlling factor of the pacing period

timing of abrupt climate change a precise clock 1 many paleoclimatic data reveal a 1 500 year cyclicity of unknown origin a crucial question is how stable and regular this cycle is an analysis of the gisp2 ice core record from greenland reveals that abrupt climate events appear to be paced by a 1 470 year cycle with a period that is probably stable to within a few percent with 95 confidence the period is maintained to better than 12 over at least 23 cycles this highly precise clock points to an origin outside the earth system oscillatory modes within the earth system can be expected to be far more irregular in period

the 8 2 ka event from greenland ice cores we present a collection of high resolution chemistry and stable isotope records from the plateau of the greenland ice cap during the cold event 8200 yr ago using a composite of four records the cold event is observed as a 160 5 yr period during which decadal mean isotopic values were below average within which there is a central event of 69 yr during which values were consistently more than one standard deviation below the average for the preceding period four cores in north south and central greenland show differences at decadal and shorter timescales it is not yet clear if this represents significant spatial differences in response the results show clear evidence for colder temperatures and a decrease in snow accumulation rate however the changes in chemical concentrations for the ions looked at here are small suggesting only minor changes in atmospheric circulation for this event apart from the decrease in methane concentration greenland ice cores give only weak evidence for effects outside the north atlantic region

mesozoic orogenic gold mineralization in the jiaodong peninsula china a focused event at 120 2 ma during cooling of pregold granite intrusions

reconstruction of millennial changes in dust emission transport and regional sea ice coverage using the deep epica ice cores from the atlantic and indian ocean sector of antarctica continuous sea salt and mineral dust aerosol records have been studied on the two epica european project for ice coring in antarctica deep ice cores the joint use of these records from opposite sides of the east antarctic plateau allows for an estimate of changes in dust transport and emission intensity as well as for the identification of regional differences in the sea salt aerosol source the mineral dust flux records at both sites show a strong coherency over the last 150 kyr related to dust emission changes in the glacial patagonian dust source with three times higher dust fluxes in the atlantic compared to the indian ocean sector of the southern ocean so using a simple conceptual transport model this indicates that transport can explain only 40 of the atmospheric dust concentration changes in antarctica while factor 5 10 changes occurred accordingly the main cause for the strong glacial dust flux changes in antarctica must lie in environmental changes in patagonia dust emissions hence environmental conditions in patagonia were very similar during the last two glacials and interglacials respectively despite 2 4 c warmer temperatures recorded in antarctica during the penultimate interglacial than today 2 3 times higher sea salt fluxes found in both ice cores in the glacial compared to the holocene are difficult to reconcile with a largely unchanged transport intensity and the distant open ocean source the substantial glacial enhancements in sea salt aerosol fluxes can be readily explained assuming sea ice formation as the main sea salt aerosol source with a significantly larger expansion of summer sea ice in the weddell sea than in the indian ocean sector during the penultimate interglacial our sea salt records point to a 50 reduction of winter sea ice coverage compared to the holocene both in the indian and atlantic ocean sector of the so however from 20 to 80 ka before present sea salt fluxes show only very subdued millennial changes despite pronounced temperature fluctuations likely due to the large distance of the sea ice salt source to our drill sites

multi proxy evidence of millennial climate variability from multiple bahamian speleothems abstract northern hemisphere tropical paleoclimate records support significant changes associated with dansgaard oeschger d o events and heinrich stadials 1 to 6 during the last 64 000 years however few absolutely dated terrestrial records from the western atlantic span the last six heinrich stadials here we present geochemical results from three new stalagmites collected from a cave in the bahamas which encompass heinrich stadials 1 to 6 we build on a previous study of the 13 c and 18 o values of the calcite and 18 o value of fluid inclusions from a single stalagmite from the same cave spanning the last three heinrich stadials absolute geochronometry using u th equilibrium series demonstrates that the stalagmites formed between 63 8 and 13 8 kyr bp the 13 c and 18 o values of the calcite show higher values associated with heinrich stadials 1 6 and lower values during the d o interstadial events the sr ca ratios of the calcite are shown to be relatively invariant while in two of the samples the mg ca ratios track the 13 c values increases in the 18 o values across heinrich stadials 1 6 are interpreted as being driven by lower temperatures the two deeper occurring stalagmites demonstrate increased mg ca ratios and 13 c values during heinrich stadials 1 and 2 which are interpreted as a signal of reduced flow rates in the epikarst and increased water rock interactions as a result of increased aridity which potentially occurred across all six heinrich stadials the observed reductions in mean annual temperature and amount of precipitation across heinrich stadials are proposed to be driven by a reduction in sea surface temperatures in the north atlantic and an expanded bermuda high during d o interstadials the bahamas cave records likely indicate warmer and or wetter climate however the isotopic shifts are not as significant as the isotopic excursions associated with heinrich stadials

absolute calibration of the greenland time scale implications for antarctic time scales and for δ14c abstract we propose a new age scale for the two ice cores grip and gisp2 that were drilled at greenland summit based on accelerator mass spectrometry 14c dating of foraminifera in core md95 2042 paleoceanography 15 2000 565 calibrated by means of recently obtained paired 14c and 230th measurements on pristine corals marine radiocarbon calibration curve spanning 10 500 to 50 000 years bp thousand years before present based on paired 230th 234u 238u and 14c dates on pristine corals geological society of america bulletin 2003 submitted for publication the record of core md95 2042 can be correlated very precisely to the greenland ice cores between 30 and 40 ka bp our scale is 1 4 ka older than the grip ss09sea time scale journal of quaternary science 16 2001 299 at the older end of marine isotope stage 3 we use published 230th dates from speleothems to calibrate the record using this scale we show a 14c record that is broadly consistent with the modelled record earth planet sci lett 200 2002 177 and with the data of hughen et al science 303 2004 202 but not consistent with the high values obtained by beck et al science 292 2001 2453 or by voelker et al radiocarbon 40 1998 517 we show how a set of age scales for the antarctic ice cores can be derived that are both fully consistent with the greenland scale and glaciologically reasonable

a revised 10 4 c magnitude of the abrupt change in greenland temperature at the younger dryas termination using published gisp2 gas isotope data and air thermal diffusion constants abstract we revisit the portion of nature 391 1998 141 devoted to the abrupt temperature increase reconstruction at the younger dryas preboreal transition the original estimate of 5 to 10 c abrupt warming is revised to 10 4 c the gas isotope data from the original work were employed combined with recently measured precise air thermal diffusion constants geochim cosmochim acta 67 2003a 345 j phys chem 23a 2003b 4636 the new constants allow a robust interpretation of the gas isotope signal in terms of temperature change this was not possible at the time of the original work when no air constants were available three quasi independent approaches employed in this work all give the same result of a 10 c warming in several decades or less the new result provides a firm target for climate models that attempt to predict future climates

early holocene climate oscillations recorded in three greenland ice cores a new ice core chronology for the greenland dye 3 grip and ngrip ice cores has been constructed making it possible to compare the 18 o and accumulation signals recorded in the three cores on an almost annual scale throughout the holocene we here introduce the new time scale and investigate 18 o and accumulation anoma lies that are common to the three cores in the early holocene 7 9 11 7 ka before present three time periods with significant and synchronous anomalies in the 18 o and accumulation signals stand out the well known 8 2 ka event an event of shorter duration but of almost similar amplitude around 9 3 ka before present and the preboreal oscillation during the first centuries of the holocene for each of these sections we present a 18 o anomaly curve and a common accumulation signal that represents regional changes in the accumulation rate over the greenland ice cap

major features and forcing of high latitude northern hemisphere atmospheric circulation using a 110 000 year long glaciochemical series the greenland ice sheet project 2 glaciochemical series sodium potassium ammonium calcium magnesium sulfate nitrate and chloride provides a unique view of the chemistry of the atmosphere and the history of atmospheric circulation over both the high latitudes and mid low latitudes of the northern hemisphere interpretation of this record reveals a diverse array of environmental signatures that include the documentation of anthropogenically derived pollutants volcanic and biomass burning events storminess over marine surfaces continental aridity and biogenic source strength plus information related to the controls on both high and low frequency climate events of the last 110 000 years climate forcings investigated include changes in insolation of the order of the major orbital cycles that control the long term behavior of atmospheric circulation patterns through changes in ice volume sea level events such as the heinrich events massive discharges of icebergs first identified in the marine record that are found to operate on a 6100 year cycle due largely to the lagged response of ice sheets to changes in insolation and consequent glacier dynamics and rapid climate change events massive reorganizations of atmospheric circulation that are demonstrated to operate on 1450 year cycles changes in insolation and associated positive feedbacks related to ice sheets may assist in explaining favorable time periods and controls on the amplitude of massive rapid climate change events explanation for the exact timing and global synchroneity of these events is however more complicated preliminary evidence points to possible solar variability climate associations for these events and perhaps others that are embedded in our ice core derived atmospheric circulation records

persistent solar influence on north atlantic climate during the holocene surface winds and surface ocean hydrography in the subpolar north atlantic appear to have been influenced by variations in solar output through the entire holocene the evidence comes from a close correlation between inferred changes in production rates of the cosmogenic nuclides carbon 14 and beryllium 10 and centennial to millennial time scale changes in proxies of drift ice measured in deep sea sediment cores a solar forcing mechanism therefore may underlie at least the holocene segment of the north atlantic9s 1500 year cycle the surface hydrographic changes may have affected production of north atlantic deep water potentially providing an additional mechanism for amplifying the solar signals and transmitting them globally

isotope calibrated greenland temperature record over marine isotope stage 3 and its relation to ch4 large temperature variations on millennial time scales in greenland characterised the last ice age abrupt warmings known as dansgaard oeschger do events can be traced in the 18oice record of greenland ice cores however it has been shown that 18oice is not a direct temperature proxy measurements of the isotopic composition of gases trapped in the ice can be used to calibrate the paleothermometer here we present a continuous temperature record based on high resolution 15n measurements and firn model studies it covers a sequence of 9 do events 9 17 during the time period from 38 to 64 kyr bp for which temperature changes of 8 to 15 c were estimated the difference between the modern and the glacial 18oice t relationship can be explained by a combination of source temperature changes and changes in the annual distribution of precipitation a detailed comparison of the temperature evolution with reconstructions of the atmospheric methane ch4 concentration shows that ch4 rises lag temperature increases at the onset of do events by 25 to 70 yr within data resolution the strong correlation between greenland temperature and ch4 on millennial and submillennial time scales suggests that variations on these time scales were probably of hemispheric extent

high resolution ammonium ice core record covering a complete glacial interglacial cycle high resolution ammonium measurements were performed along the greenland ice core program grip deep ice core covering a complete climatic cycle no overall anthropogenic increase is observed over the last 300 years however springtime concentrations have roughly doubled since 1950 biomass burning is estimated to be a major source for ammonia emissions for preindustrial times it contributes between 10 to 40 to the total ammonium deposited on the central greenland ice sheet during the holocene no correlation is found between the ammonium summer concentrations recorded over the last 100 years and the area burned in northern north america which is considered to be the main source area for ammonium deposited on the central greenland ice sheet this suggests that the meteorological factor is predominant for the pattern of ammonium spikes observed in the ice core if unchanged meteorological conditions are assumed for the holocene as indicated by the 18o ice record a decreasing biomass burning activity toward present time can be derived from the ammonium ice record soil and vegetation emissions are responsible for the ammonium background concentrations in the ice the record therefore may be used to trace back the biomass history of the north american continent a pronounced decreasing trend in background ammonium is found during the holocene reflecting decreasing temperature and therefore lower nh3 emissions in the source region variations in the ammonium concentration during the glacial age are discussed in terms of changes in transport and deposition mechanisms and changes in source strength which can be related to the extent of the laurentide ice sheet the data suggest that the laurentide ice sheet was built up immediately after the last interglacial and went through several large fluctuations during the last ice age

on the origin and timing of rapid changes in atmospheric methane during the last glacial period we present high resolution records of atmospheric methane from the gisp2 greenland ice sheet project 2 ice core for four rapid climate transitions that occurred during the past 50 ka the end of the younger dryas at 11 8 ka the beginning of the bolling allerod period at 14 8 ka the beginning of interstadial 8 at 38 2 ka and the beginning of interstadial 12 at 45 5 ka during these events atmospheric methane concentrations increased by 200 300 ppb over time periods of 100 300 years significantly more slowly than associated temperature and snow accumulation changes recorded in the ice core record we suggest that the slower rise in methane concentration may reflect the timescale of terrestrial ecosystem response to rapid climate change we find no evidence for rapid massive methane emissions that might be associated with large scale decomposition of methane hydrates in sediments with additional results from the taylor dome ice core antarctica we also reconstruct changes in the interpolar methane gradient an indicator of the geographical distribution of methane sources associated with some of the rapid changes in atmospheric methane the results indicate that the rise in methane at the beginning of the bolling allerod period and the later rise at the end of the younger dryas were driven by increases in both tropical and boreal methane sources during the younger dryas a 1 3 ka cold period during the last deglaciation the relative contribution from boreal sources was reduced relative to the early and middle holocene periods

impact of precipitation seasonality changes on isotopic signals in polar ice cores a multi model analysis abstract for central greenland water isotope analysis indicates a temperature difference of about 10 c since the last glacial maximum lgm however borehole thermometry and gas diffusion thermometry indicate that lgm surface temperatures were about 20 c colder than today two general circulation model studies have shown that changes in the seasonal precipitation timing in central greenland might have caused a warm bias in the lgm water isotope proxy temperatures and that this bias could explain the difference in the estimated paleotemperatures here we present an analysis of a number of atmospheric general circulation model simulations mostly done within the framework of the paleoclimate modeling intercomparison project the models suggest that the seasonal cycle of precipitation and surface mass balance over central greenland at the lgm might have been very different from today this supports the idea that the accuracy of the water isotope thermometry at the lgm in greenland might be compromised as a result of a modified surface mass balance seasonality however the models disagree on the amplitude and sign of the bias for central east antarctica a strong seasonality effect on the lgm isotopic signal is not simulated by any of the analyzed models for the mid holocene 6 kyr bp the models suggest relatively weak isotope paleothermometry biases linked to changes in the surface mass balance seasonality over both ice sheets

what is what in the ice and the ocean recently released data from the north greenland ice core project ngrip document several rapid abrupt climate changes affecting the northern hemisphere in the last 110 000 years in particular the new core shows high resolution succession of expressed warm and cold episodes which occurred during substages of marine isotope stage mis 5 some of these variations were reported earlier from the gisp2 and grip ice cores in the ngrip core following the intimate group recommendations the oscillations were given labels which are in part the same as in the isotope system of deep sea sediments although to some extent they are not coeval here we recommend honoring the originally published marine designations wherever possible but distinguishing them by a prefix referring to their recognition in the ice

timescales for dust variability in the greenland ice core project grip ice core in the last 100 000 years the calcium representing dust concentration record of the last 100 000 years from the greenland ice core project grip ice core shows a huge dynamic range factor 100 the relationship between dust concentrations and temperature represented by the oxygen isotope ratio is not a simple one as has often been assumed a rapid alternation factor of 5 10 between low concentrations during the dansgaard oeschger interstadial periods and high levels in colder periods is superimposed on a long term trend encompassing a further factor of 5 10 within climate periods there is only a very weak relationship between ca concentration and temperature previous authors biscaye et al 1997 have suggested that the most likely source for the increased dust is eastern asia for the first time we consider each possible cause of both rapid and slow increases from source to deposition we suggest that to account for the size and rapidity of the fast changes significantly higher wind speed in the source area is required although changes in atmospheric residence time could also play a role for the slower long term variability changes in transport speed or possibly route are probably also involved changes in the size of the source area could give some change on longer time periods the probable importance of changes in source area wind speed almost simultaneous with greenland temperature changes confirms that climatic parameters in high and low latitudes were strongly coupled through the atmosphere during glacial climatic changes this adds to evidence that the atmospheric circulation system underwent almost instantaneous large scale changes during the last glacial period

a new greenland deep ice core the polar ice sheets are rich sources of information on past atmospheric conditions including paleoclimates a new deep ice core has been drilled in south greenland comparison of the oxygen isotopic profile with that from camp century and with a deep sea foraminifera record indicates that the new core reaches back to about 90 000 years before present in a continuous sequence the details in the wisconsin part of the ice core records seem to be climatically significant and the general trends reveal all of the relevant emiliani stages recorded in deep sea cores the redated camp century record suggests a dramatic termination of the eem sangamon interglacial

ice core evidence for a very tight link between north atlantic and east asian glacial climate 1 corresponding millennial scale climate changes have been reported from the north atlantic region and from east asia for the last glacial period on independent timescales only to assess their degree of synchrony we suggest interpreting greenland ice core dust parameters as proxies for the east asian monsoon systems this allows comparing north atlantic and east asian climate on the same timescale in high resolution ice core data without relative dating uncertainties we find that during dansgaard oeschger events north atlantic region temperature and east asian storminess were tightly coupled and changed synchronously within 5 10 years with no systematic lead or lag thus providing instantaneous climatic feedback the tight link between north atlantic and east asian glacial climate could have amplified changes in the northern polar cell to larger scales we further find evidence for an early onset of a younger dryas like event in continental asia which gives

grip deuterium excess reveals rapid and orbital scale changes in greenland moisture origin the northern hemisphere hydrological cycle is a key factor coupling ice sheets ocean circulation and polar amplification of climate change here we present a northern hemisphere deuterium excess profile covering one climatic cycle constructed with the use of 18 o and d greenland ice core project grip records past changes in greenland source and site temperatures are quantified with precipitation seasonality taken into account the imprint of obliquity is evidenced in the site to source temperature gradient at orbital scale at the millennial time scale grip source temperature changes reflect southward shifts of the geographical locations of moisture sources during cold events and these rapid shifts are associated with large scale changes in atmospheric circulation

n2o and ch4 variations during the last glacial epoch insight into global processes 1 greenhouse gas measurements along polar ice cores provide important insight into the former composition of the atmosphere its natural variations and the responses to fast climatic changes in the past we present high resolution nitrous oxide n2o and methane ch4 records measured along two ice cores from central greenland covering part of marine isotope stages 3 and 4 in the last glacial epoch the n2o data confirm the hypothesis that n2o shows variations in phase to fast climatic changes observed in the northern hemisphere the so called dansgaard oeschger d o events variations exist not only for events with a long duration 1500 years and more but also for the shorter ones the comparison with ch4 unveils interesting differences between the response of ch4 and n2o to d o events while the average amplitudes of ch4 oscillations associated with d o events are similar to those of the northern hemisphere summer insolation the magnitude of the n2o concentration change instead correlates with the duration of the d o events the records give further insight into the timing of concentration changes at the beginning of d o events they show that for long lasting events the n2o concentration starts to increase before both the sharp increase in the ch4 concentration and the temperature reconstructed for greenland

changes in the atmospheric ch4 gradient between greenland and antarctica during the last glacial and the transition to the holocene significant variations in the interpolar difference of atmospheric ch4 concentration over the holocene period were observed by chappellaz et al 1997 here we extend this study to the last glacial and the transition to the holocene we observe a gradient of 3 4 parts per billion by volume ppbv during the last glacial maximum it increases to 26 10 ppbv during the bolling allerod and remains at 26 9 ppbv during the younger dryas cold period on average we find an interpolar difference of 14 4 ppbv during the cold phases and of 37 10 ppbv during the warm periods of the last glacial with a three box model we derive from the measured gradients the contributions of methane from the tropics and the mid to high latitudes of the northern hemisphere the tropics have been the largest source in all glacial epochs the contribution by the northern latitudes have been very small during the last glacial maximum but surprisingly large during the earlier part of the glacial epoch the model result suggests completely unexpected that the higher atmospheric ch4 concentration during the warm dansgaard oeschger events are caused by a higher source strength of the northern latitudes and not of the tropics

orbital and millennial antarctic climate variability over the past 800 000 years a high resolution deuterium profile is now available along the entire european project for ice coring in antarctica dome c ice core extending this climate record back to marine isotope stage 20 2 800 000 years ago experiments performed with an atmospheric general circulation model including water isotopes support its temperature interpretation we assessed the general correspondence between dansgaard oeschger events and their smoothed antarctic counterparts for this dome c record which reveals the presence of such features with similar amplitudes during previous glacial periods we suggest that the interplay between obliquity and precession accounts for the variable intensity of interglacial periods in ice core records

oxygen isotope and palaeotemperature records from six greenland ice core stations camp century dye 3 grip gisp2 renland and northgrip oxygen isotope variations spanning the last glacial cycle and the holocene derived from ice core records for six sites in greenland camp century dye 3 grip gisp2 renland and northgrip show strong similarities this suggests that the dominant influence on oxygen isotope variations reflected in the ice sheet records was regional climatic change differences in detail between the records probably reflect the effects of basal deformation in the ice as well as geographical gradients in atmospheric isotope ratios palaeotemperature estimates have been obtained from the records using three approaches i inferences based on the measured relationship between mean annual 18o of snow and of mean annual surface temperature over greenland ii modelled inversion of the borehole temperature profile constrained either by the dated isotopic profile or iii by using monte carlo simulation techniques the third of these approaches was adopted to reconstruct holocene temperature variations for the dye 3 and grip temperature profiles which yields remarkably compatible results a new record of holocene isotope variations obtained from the northgrip ice core matches the grip short term isotope record and also shows similar long term trends to the dye 3 and grip inverted temperature data the northgrip isotope record reflects i a generally stronger isotopic signal than is found in the grip record ii several short lived temperature fluctuations during the first 1500 yr of the holocene iii a marked cold event at ca 8 2 ka the 8 2 ka event iv optimum temperatures for the holocene between ca 8 6 and 4 3 ka a signal that is 0 6 stronger than for the grip profile v a clear signal for the little ice age and vi a clear signal of climate warming during the last century these data suggest that the northgrip stable isotope record responded in a sensitive manner to temperature fluctuations during the holocene copyright 2001 john wiley sons ltd

comparison of oxygen isotope records from the gisp2 and grip greenland ice cores recent results1 2 from the greenland ice core project grip summit ice core suggest that the climate in greenland has been remarkably stable during the holocene but was extremely unstable for the time period represented by the rest of the core spanning the last two glaciations and the intervening eemian inter glacial here we present the complete oxygen isotope record for the greenland ice sheet project 2 gisp2 core drilled 28 km west of the grip core we observe large rapid climate fluctuations throughout the last glacial period which closely match those reported for the grip core however in the bottom 10 of the cores spanning the eemian interglacial and the previous glacia tion there are significant differences between the two records it is possible that ice flow may have altered the chronological sequences of the stratigraphy for the bottom part of one or both of the cores considerable further work will be necessary to evaluate the likelihood of this and the extent to which it will still be possible to extract meaningful climate information from the lowest sections of the cores

phase relationships between millennial scale events 64 000 24 000 years ago a core recovered on the iberian margin off southern portugal can be correlated with greenland ice cores using oxygen isotope variability in planktonic foraminifera which closely matches the ice core records of temperature over greenland our age model identifies the base of every interstadial between 64 000 and 24 000 years ago and uses the greenland ice core project grip timescale the oxygen isotope signal in benthic foraminifera on this grip based timescale is quite different from the planktonic record and resembles the temperature record over antarctica when this is synchronized with greenland using the record of methane in the atmospheric air in the polar ice cores we interpret the benthic record as indicating significant fluctuations in ice volume during millennial events and we suggest that antarctic temperature changed as a function of ice volume

possible solar origin of the 1 470 year glacial climate cycle demonstrated in a coupled model dansgaard oeschger events are rapid climate fluctuations that occurred during and at the end of the last ice age with remarkable regularity there were 23 such events between 110 000 and 23 000 years bp with a periodicity of 1 470 years identify the source of this cycle and it should be possible to say what triggered these events the sun had been excluded as a possible cause because of the lack of a 1 470 year spectral contribution in records of solar variability despite this braun et al present a new hypothesis that convincingly explains the 1 470 year period as the net result of two well known solar cycles the devries and gleissberg cycles with periods of 210 years and 87 years many palaeoclimate records from the north atlantic region show a pattern of rapid climate oscillations the so called dansgaard oeschger events with a quasi periodicity of 1 470 years for the late glacial period1 2 3 4 5 6 various hypotheses have been suggested to explain these rapid temperature shifts including internal oscillations in the climate system and external forcing possibly from the sun7 but whereas pronounced solar cycles of 87 and 210 years are well known8 9 10 11 12 a 1 470 year solar cycle has not been detected8 here we show that an intermediate complexity climate model with glacial climate conditions simulates rapid climate shifts similar to the dansgaard oeschger events with a spacing of 1 470 years when forced by periodic freshwater input into the north atlantic ocean in cycles of 87 and 210 years we attribute the robust 1 470 year response time to the superposition of the two shorter cycles together with strongly nonlinear dynamics and the long characteristic timescale of the thermohaline circulation for holocene conditions similar events do not occur we conclude that the glacial 1 470 year climate cycles could have been triggered by solar forcing despite the absence of a 1 470 year solar cycle

visual stratigraphic dating of the gisp2 ice core basis reproducibility and application annual layers are visible in the greenland ice sheet project 2 ice core from central greenland allowing rapid dating of the core changes in bubble and grain structure caused by near surface primarily summertime formation of hoar complexes provide the main visible annual marker in the holocene and changes in cloudiness of the ice correlated with dustiness mark wisconsinan annual cycles both markers are evident and have been intercalibrated in early holocene ice layer counts are reproducible between different workers and for one worker at different times with 1 error over century length times in the holocene reproducibility is typically 5 in wisconsinan ice age ice and decreases with increasing age and depth cumulative ages from visible stratigraphy are not significantly different from independent ages of prominent events for ice older than the historical record and younger than approximately 50 000 years visible observations are not greatly degraded by brittle ice or many other core quality problems allowing construction of long consistently sampled time series high accuracy requires careful study of the core by dedicated observers

anatomy of a dansgaard oeschger warming transition high resolution analysis of the north greenland ice core project ice core large and abrupt temperature oscillations during the last glacial period known as dansgaard oeschger do events are clearly observed in the greenland ice core record here we present a new high resolution chemical 2 mm and stable isotope 20 mm record from the north greenland ice core project ngrip ice core at the onset of one of the most prominent do events of the last glacial do 8 observed 38 000 years ago the unique subannual resolution ngrip record provides a true sequence of change during a do warming with detailed annual layer counting of very high depth resolution geochemical measurements used to determine the exact duration of the transition the continental ions indicative of long range atmospheric loading and dustiness from east asia are the first to change followed by the snow accumulation the moisture source conditions and finally the atmospheric temperature in greenland the sequence of events shows that atmospheric and oceanic source and circulation changes preceded the do warming by several years

kinoshitalite ba mg 3 al2si2 o10 oh f 2 a brittle mica from a manganese deposit in oman paragenesis and crystal chemistry kinoshitalite ideally ba mg 3 al 2 si 2 o 10 oh f 2 was studied in a granulite facies manganese ore associated with calcium bearing magnesian tephroite hausmannite calcite and manganoan clinochlore and in a second assemblage together with hausmannite altered tephroite manganoan diopside and calcite the metamorphic rocks occur enclosed in peridotites of the semail ophiolite sultanate of oman and were metamorphosed during ophiolite obduction single crystal x ray data collected on an inclusion free kinoshitalite of ba 0 99 k 0 06 na 0 01 mg 2 64 mn 0 31 al 2 01 si 2 03 o 10 oh 1 61 f 0 37 cl 0 02 composition yielded a c centered lattice of monoclinic symmetry with a 5 316 1 b 9 230 2 c 10 197 2 a 100 06 1 v 492 6 a 3 and z 1 characteristic of the 1 m polytype the structure was refined in two models assuming complete si al ordering in the space groups c 2 and c 1 allowing for additional twinning the data clearly suggest that in spite of the si al ratio of 1 assumption of complete si al ordering can be rejected two models both in agreement with space group c 2 m causing si al disorder are discussed three dimensional si al disorder would lead to violation of the al avoidance rule and substantial ba displacement the rather well defined ba position capped by two six membered rings of si 3 al 3 o 18 composition suggests one dimensional disorder where completely si al ordered layers exist parallel to 001 the disorder occurs perpendicular to 001 and may be interpreted as random stacking faults

synchronization of the ngrip grip and gisp2 ice cores across mis 2 and palaeoclimatic implications abstract we here present a synchronization of the ngrip grip and gisp2 ice cores based mainly on volcanic events over the period 14 9 32 45 ka b2k before ad 2000 corresponding to marine isotope stage 2 mis 2 and the end of mis 3 the matching provides a basis for applying the recent ngrip based greenland ice core chronology 2005 gicc05 time scale to the grip and gisp2 ice cores thereby making it possible to compare the synchronized palaeoclimate profiles of the cores in detail and to identify relative accumulation differences between the cores based on the matching a period of anomalous high accumulation rates in the gisp2 ice core is detected within the period 16 5 18 3 ka b2k the 18 o and ca 2 profiles of the three cores are presented on the common gicc05 time scale and generally show excellent agreement across the stadial interstadial transitions and across the two characteristic dust events in greenland stadial 3 however large differences between the 18 o and ca 2 profiles of the three cores are seen in the same period as the 7 9 increase in the gisp2 accumulation rate we conclude that changes of the atmospheric circulation are likely to have occurred in this period altering the spatial gradients in greenland and resulting in larger variations between the records

atmospheric co2 and climate from 65 to 30 ka b p 1 using new and existing ice core co2 data from 65 30 ka a new chronology for co2 is established and synchronized with greenland ice core records to study how high latitude climate change and the carbon cycle were linked during the last glacial period atmospheric co2 rose several thousand years before abrupt warming in greenland associated with dansgaard oeschger events 8 12 14 17 four large warm events that follow heinrich events the co2 rise terminated at the onset of greenland warming for each of these events atmospheric co2 is strongly correlated with the antarctic isotopic temperature proxy with an average time lag of 720 370 yr mean 1 during the time interval studied the new data and chronology should provide a better target for models attempting to explain co2 variability and abrupt climate change

timing and climatic impact of greenland interstadials recorded in stalagmites from northern turkey a 50 kyr long exceptionally well dated and highly resolved stalagmite oxygen 18o and carbon 13c isotope record from sofular cave in northwestern turkey helps to further improve the dating of greenland interstadials gi 1 and 3 12 timing of most gi in the sofular record is consistent within 10 to 300 years with the iconic hulu cave record larger divergences 500 years between sofular and hulu are only observed for gi 4 and 7 the sofular record differs from the most recent ngrip chronology by up to several centuries whereas age offsets do not increase systematically with depth the sofular record also reveals a rapid and sensitive climate and ecosystem response in the eastern mediterranean to gi whereas a phase lag of 100 years between climate and full ecosystem response is evident finally results of spectral analyses of the sofular isotope records do not support a 1 470 year pacing of gi

high resolution record of northern hemisphere climate extending into the last interglacial period high resolution record of northern hemisphere climate extending into the last interglacial period

glacial terminations as southern warmings without northern control the timing and mechanisms of the transition from a glacial to an interglacial state are controversial an analysis of antarctic ice core records indicates that glacial terminations may begin as millennial scale warmings in the southern hemisphere that unlike previous events are not reversed by abrupt warming in the northern hemisphere

dust and sea salt variability in central east antarctica dome c over the last 45 kyrs and its implications for southern high latitude climate a detailed record of non sea salt calcium a proxy for dust and sea salt sodium a proxy for sea salt covering the last 45 kyr is presented it shows that in the first part of the transition from the last glacial period to the holocene 18 15 kyr bp the changes in dust flux mainly reflect changes at the dust source namely vegetation cover and local climate the changes in the later part of the transition 12 11 kyr bp are similar in extent to the changes seen in sea salt and most likely reflect a reorganization of the atmospheric circulation during the last glacial period considerable variation of dust but not of sea salt is observed pointing to climatic changes in patagonia the main dust source for dome c a comparison of the glacial records from dome c and taylor dome suggests that similar influences controlled aerosol input at both sites during this period

the grip deuterium excess record abstract ice cores from greenland and antarctica are ideal archives for retrieving long time series of deuterium excess d d 8 18 o a parameter influenced by conditions prevailing in the oceanic regions which provide moisture for polar snow the central greenland grip deuterium excess record has recently been interpreted in terms of oceanic source temperatures both for the holocene and for the last glacial period this approach being less straightforward for the latter period because of changes in the precipitation seasonality between glacial and interglacial periods this article examines why a conventional or sea surface temperature interpretation of the grip excess record seems inconsistent with inferred site and source temperature changes in addition the grip excess record is extended back into the penultimate glacial period and we assess its geographic significance through a comparison with existing dye 3 and north grip data we examine why low d 18o slopes observed during glacial times are associated with low deuterium excess values similarities between the greenland grip and antarctic vostok excess records are discussed in terms of potential links with insolation and insolation gradient changes finally the isotope records in specific do events are examined in light of intruiging differences between the isotope ratios d or 18o and the excess records that may result from a feedback mechanism linked with freshwater oceanic input

a new greenland ice core chronology for the last glacial termination 1 we present a new common stratigraphic timescale for the north greenland ice core project ngrip and grip ice cores the timescale covers the period 7 9 14 8 kyr before present and includes the bolling allerod younger dryas and early holocene periods we use a combination of new and previously published data the most prominent being new high resolution continuous flow analysis cfa impurity records from the ngrip ice core several investigators have identified and counted annual layers using a multiparameter approach and the maximum counting error is estimated to be up to 2 in the holocene part and about 3 for the older parts these counting error estimates reflect the number of annual layers that were hard to interpret but not a possible bias in the set of rules used for annual layer identification as the grip and ngrip ice cores are not optimal for annual layer counting in the middle and late holocene the timescale is tied to a prominent volcanic event inside the 8 2 kyr cold event recently dated in the dye 3 ice core to 8236 years before a d 2000 b2k with a maximum counting error of 47 years the new timescale dates the younger dryas preboreal transition to 11 703 b2k which is 100 150 years older than according to the present grip and ngrip timescales the age of the transition matches the gisp2 timescale within a few years but viewed over the entire 7 9 14 8 kyr section there are significant differences between the new timescale and the gisp2 timescale the transition from the glacial into the bolling interstadial is dated to 14 692 b2k the presented timescale is a part of a new greenland ice core chronology common to the dye 3 grip and ngrip ice cores named the greenland ice core chronology 2005 gicc05 the annual layer thicknesses are observed to be log normally distributed with good approximation and compared to the early holocene the mean accumulation rates in the younger dryas and bolling periods are found to be 47 2 and 88 2 respectively

high resolution greenland ice core data show abrupt climate change happens in few years the last two abrupt warmings at the onset of our present warm interglacial period interrupted by the younger dryas cooling event were investigated at high temporal resolution from the north greenland ice core project ice core the deuterium excess a proxy of greenland precipitation moisture source switched mode within 1 to 3 years over these transitions and initiated a more gradual change over 50 years of the greenland air temperature as recorded by stable water isotopes the onsets of both abrupt greenland warmings were slightly preceded by decreasing greenland dust deposition reflecting the wetting of asian deserts a northern shift of the intertropical convergence zone could be the trigger of these abrupt shifts of northern hemisphere atmospheric circulation resulting in changes of 2 to 4 kelvin in greenland moisture source temperature from one year to the next

the greenland ice core chronology 2005 15 42 ka part 2 comparison to other records a new greenland ice core chronology gicc05 based on multi parameter counting of annual layers has been obtained for the last 42 ka here we compare the glacial part of the new time scale which is based entirely on records from the northgrip ice core to existing time scales and reference horizons covering the same period these include the grip and northgrip modelled time scales the meese sowers gisp2 counted time scale the shackleton fairbanks grip time scale sfcp04 based on 14c calibration of a marine core the hulu cave record three volcanic reference horizons and the laschamp geomagnetic excursion event occurring around greenland interstadial 10 gicc05 is generally in good long term agreement with the existing greenland ice core chronologies and with the hulu cave record but on shorter time scales there are significant discrepancies around the last glacial maximum there is a more than 1 ka age difference between gicc05 and sfcp04 and a more than 0 5 ka discrepancy in the same direction between gicc05 and the age of a recently identified tephra layer in the northgrip ice core both sfcp04 and the tephra age are based on 14c dated marine cores and fixed marine reservoir ages for the laschamp event gicc05 agrees with a recent independent dating within the uncertainties

premetamorphic lateritisation in proterozoic metabasites of rogaland sw norway heterogeneous layers of granulite facies metamorphic basites of the proterozoic supracrustal faurefjell formation in rogaland s w norway display an extreme chemical variation within a single layer the bulk chemical composition gradually changes from approximately basaltic in basic granulites to alumina iron rich in granofelses component ratios and composition volume relations indicate open system chemical reactions mainly involving the extraction of silica apparent enrichment in fe ti p al zr ni co zn y nb hf and ree and variations in resulting metamorphic mineral assemblages are related to premetamorphic progressive lateritisation of a basaltic protolith the weathering generated a continuous chemical suite from sio2 48 wt fe2o3 10 wt and al2o3 19 wt in the basic granulites to 14 wt 40 wt and 25 wt in the fe al granofelses metasomatism during diagenesis and during very high grade metamorphism 1200 900 ma further perturbed the concentrations of relatively mobile elements ca mg k rb sr ba na and li in the laterites without affecting the transition metal ratios in particular the ree did not fractionate differentially during the supracrustal and metasomatic alteration

the greenland ice sheet project 2 depth age scale methods and results the greenland ice sheet project 2 gisp2 depth age scale is presented based on a multiparameter continuous count approach to a depth of 2800 m using a systematic combination of parameters that have never been used to this extent before the ice at 2800 m is dated at 110 000 years b p with an estimated error ranging from 1 to 10 in the top 2500 m of the core and averaging 20 between 2500 and 2800 m parameters used to date the core include visual stratigraphy oxygen isotopic ratios of the ice electrical conductivity measurements laser light scattering from dust volcanic signals and major ion chemistry gisp2 ages for major climatic events agree with independent ages based on varve chronologies calibrated radiocarbon dates and other techniques within the combined uncertainties good agreement also is obtained with greenland ice core project ice core dates and with the specmap marine timescale after correlation through the 18 o of o 2 although the core is deformed below 2800 m and the continuity of the record is unclear we attempted to date this section of the core on the basis of the laser light scattering of dust in the ice

a minimum thermodynamic model for the bipolar seesaw 1 the simplest possible model is proposed to explain a large fraction of the millennial climate variability measured in the isotopic composition of antarctic ice cores the model results from the classic bipolar seesaw by coupling it to a heat reservoir in this thermal bipolar seesaw the heat reservoir convolves northern time signals with a characteristic timescale applying the model to the data of grip and byrd we demonstrate that maximum correlation can be obtained using a timescale of about 1000 1500 years higher correlations are obtained by first filtering out the long term variability which is due to astronomical and greenhouse gas forcing and not part of the thermal bipolar seesaw the model resolves the apparent confusion whether northern and southern climate records are in or out of phase synchronous or time lagged

irregular glacial interstadials recorded in a new greenland ice core the greenland ice sheet offers the most favourable conditions in the northern hemisphere for obtaining high resolution continuous time series of climate related parameters profiles of 18o 16o ratio along three previous deep greenland ice cores1 3 seemed to reveal irregular but well defined episodes of relatively mild climate conditions interstadials during the mid and late parts of the last glaciation but there has been some doubt as to whether the shifts in oxygen isotope ratio were genuine representations of changes in climate rather than artefacts due to disturbed stratification here we present results from a new deep ice core drilled at the summit of the greenland ice sheet where the depositional environ ment and the flow pattern of the ice are close to ideal for core recovery and analysis the results reproduce the previous findings to such a degree that the existence of the interstadial episodes can no longer be in doubt according to a preliminary timescale based on stratigraphic studies the interstadials lasted from 500 to 2 000 years and their irregular occurrence suggests complexity in the behaviour of the north atlantic ocean circulation

using a maximum simplicity paleoclimate model to simulate millennial variability during the last four glacial periods abstract many studies have documented the existence of millennial scale variability in the earth system during the last glacial period an increasing number of studies document the occurrence of similar millennial variability during glacial periods previous to the last one here we use the simplest possible thermal bipolar seesaw model to consider this variability for the last four glacial periods we invert this model and use the high pass filtered vostok stable isotope records to make a first tentative attempt to estimate high latitude n hemisphere temperature variability over the last four glacial periods beyond the reach of greenland ice core records the model result is compared against the vostok methane record which shows rapid variations in parallel to greenland temperature records during the last glacial period a further comparison is carried out against the planktonic oxygen isotope of north atlantic core odp 980 there is agreement between the records on the existence of similar millennial scale variability during the last three glacial periods with very similar characteristics to the variability during the last glacial cycle

16 c rapid temperature variation in central greenland 70 000 years ago variations in the29n2 28n2 ratio of air bubbles trapped in polar ice cores and their relation to variations of the 18o 16o of the ice allow past surface temperature variations and ice age gas age differences to be determined high resolution measurements of29n2 28n2 in dansgaard oeschger event 19 around 70 000 years before the present in ice from central greenland show that at the beginning of the event the ice age gas age difference was 1090 100 years with the use of a combined firn densification temperature and gas diffusion model the 18oice temperature coefficient was determined to be 0 42 0 05 per mil per kelvin this coefficient implies a mean surface temperature change of 16 0 kelvin between 14 3 and 18 1 kelvin which differs substantially from values derived from borehole temperatures and modern spatial 18oice surface temperature correlations

glacial interglacial changes in mineral dust and sea salt records in polar ice cores sources transport and deposition 1 sea salt and mineral dust records as represented by na and ca2 concentrations respectively in greenland and antarctic ice cores show pronounced glacial interglacial variations for the last glacial maximum lgm mineral dust sea salt concentrations in greenland show an increase of a factor of approximately 80 15 compared to the holocene and significant shifts by a factor of 15 5 during dansgaard oeschger events in antarctica the dust sea salt flux is enhanced by a factor of 15 3 during the lgm compared to the holocene and variations by approximately a factor of 8 1 2 exist in parallel to antarctic warm events primary glacial dust sources are the asian deserts for greenland and patagonia for antarctica ice core evidence and model results show that both changes in source strength as well as atmospheric transport and lifetime contributed to the observed changes in greenland ice cores in antarctica changes in ice core fluxes are in large parts related to source variations both for sea salt and dust where the formation of sea salt aerosol from sea ice may play a pivotal role summarizing our latest estimates on changes in sources transport and deposition these processes are roughly able to explain the glacial increase in sea salt in both polar regions while they fall short by at least a factor of 4 7 for mineral dust future improvements in model resolution and in the formulation of source and transport processes together with new ice core records e g on dust size distributions will eventually allow convergence of models and observations

crystal chemical variations in ba rich biotites from gabbroic rocks of lower crust ivrea zone nw italy biotites from mafic rocks occurring at different stratigraphic levels of the ivrea verbano mafic complex are studied the rocks are gabbros and diorites all the biotites are intermediate between phlogopite and annite 0 28 fe mg fe 0 66 biotites from gabbros are enriched in bao and tio2 up to 7 14 and 9 32 wt respectively with respect to those of the diorites up to 1 26 and 6 26 wt respectively systematic compositional variations support the substitution model 2ivsi ivr2 2ival viti r2 fe mg mn in gabbros and ivsi vial ival viti in diorites a predominance of disordered stacking sequences coexisting with 1m 2m1 and 3t polytypes was observed in all biotites it was possible to carry out structural refinements only on three biotites 2m1 from diorites r values between 2 68 and 3 77 and one biotite 1m from gabbros r value 3 09 it was shown that 1 the reduced thickness of the tetrahedral sheet in ba rich biotites supports the coupled substitution ivsi xiik ival xiiba 2 the interlayer site geometry is affected by the whole layer chemistry and does not reflect only local chemical variations 3 in two samples of the 2m1 polytype the m 1 octahedral site is larger and more distorted than the m 2 sites because of the preferential ordering of fe2 in the m 1 site whereas one sample shows complete cation disorder in the octahedral sites biotite 1m shows that fe2 can also be located in the m 2 site some of the differences between the biotites of gabbros and diorites e g ba concentration and exchange vectors may be linked to the host rock composition and to its crystallization process biotite occurs in trace amounts in gabbros and its crystallization is related to the interstitial melt which contributed to the adcumulus growth of the main rock forming phases and became highly enriched in k ba and ti diorites are the result of equilibrium crystallization of a residual melt rich in incompatible elements where biotite is a major constituent

complexity of holocene climate as reconstructed from a greenland ice core glaciochemical time series developed from summit greenland indicate that the chemical composition of the atmosphere was dynamic during the holocene epoch concentrations of sea salt and terrestrial dusts increased in summit snow during the periods 0 to 600 2400 to 3100 5000 to 6100 7800 to 8800 and more than 11 300 years ago the most recent increase and also the most abrupt coincides with the little ice age these changes imply that either the north polar vortex expanded or the meridional air flow intensified during these periods and that temperatures in the mid to high northern latitudes were potentially the coldest since the younger dryas event

oxygen 18 16 variability in greenland snow and ice with 10 3 to 105 year time resolution the 3 km long greenland ice sheet project 2 gisp2 ice core presents a 100 000 year detailed oxygen isotope profile covering almost a full glacial interglacial cycle measuranents of isotopic fluctuations in snow frost and atmospheric water vapor samples collected during summer field seasons up to 20 0 are compatible with the large and abrupt 80 160 changes observed in accumulated tim snow pit 15 80 profiles from the gisp2 summit area however show rapid smoothing of the 180 160 signal near the surface beyond about 2 m depth the smoothedi5180 signal is fairly well preserved and can be interpreted in terms of average local weather conditions and climate the longer climate fluctuations also have regional and often global significance in the older part of the record corresponding to marine isotope stages mis 5a to 5d the effect of orbital climate forcing via the 19 and 23 kyr precession cycles and the 41 kyr obliquity cycle is obvious from the end ofmis 5a at about 75 000 years b p till the end of the glacial at the younger dryas preboreal transition at 11 650 years b p the o180 160 record shows frequent rapid switches between intermediate interstadial and low stadial values fourier spectra of the oscillations that are superimposed on the orbitally induced changes contain a strong periodicity at 1 5 kyr a broad peak at 4 0 kyr and additional shorter periods detailed comparison of the gisp2 180 160 record with the vostok antarctica 15d record pacific ocean foraminiferal 180 160 grande pile france tree pollen and insolation indicates that a counterpart to many of the rapid 180 160 fluctuations of gisp2 can be found in the other records and that the gisp2 isotopic changes clearly are the local expression of climate changes of worldwide extent correlation of events on the independent gisp2 and specmap time scales for the interval 10 000 50 000 years b p shows excellent chronometric agreement except possibly for the event labeled 3 1 the glacial to interglacial transition evidently started simultaneously in the arctic and the antarctic but its development and its expression in greenland isotopes was later suppressed by the influence of meltwater especially from the barents sea ice sheet on deep water formation and ocean circulation meltwaters from different ice sheets bordering the north atlantic also influenced ocean circulation during the bolling allerod interstadial complex and the younger dryas and led to a distinct development of european climate and greenland 180 160 values the holocene interval with long term stable mean isotopic values contains several fluauations with periods from years to millennia dominant is a 6 3 year oscillation with amplitude up to 3 to 4 0 periodicities of 11 and 210 years also found in the solar modulated records of the cosmogenic isotopes 1obe and 14c suggest solar processes as the cause of these cycles depression of180 160 values cooling by volcanic eruptions is observed in stacked gisp215 80 records but the effect is small and not likely to trigger major climate changes

composition of barian mica in multiphase solid inclusions from orogenic garnet peridotites as evidence of mantle metasomatism in a subduction zone setting multiphase solid inclusions in minerals formed at ultra high pressure uhp provide evidence for the presence of fluids during deep subduction this study focuses on barian mica which is a common phase in multiphase solid inclusions enclosed in garnet from mantle derived uhp garnet peridotites in the saxothuringian basement of the northern bohemian massif the documented compositional variability and substitution trends provide constraints on crystallization medium of the barian mica and allow making inferences on its source barian mica in the multiphase solid inclusions belongs to trioctahedral micas and represents a solid solution of phlogopite kmg3 si3al o10 oh 2 kinoshitalite bamg3 al2si2 o10 oh 2 and ferrokinoshitalite bafe3 al2si2 o10 oh 2 in addition to ba 0 24 0 67 apfu mica is significantly enriched in mg xmg 0 85 to 0 95 cr 0 03 0 43 apfu and cl 0 04 0 34 apfu the substitution vector involving ba in the i site which describes the observed chemical variability can be expressed as bafeivalclk 1mg 1si 1 oh 1 a minor amount of cr and vial enters octahedral sites following a substitution vector vi cr al 2 vi mg fe 3 towards chromphyllite and muscovite as demonstrated by variable ba and cl contents positively correlating with fe barian mica composition is partly controlled by its crystal structure textural evidence shows that barian mica together with other minerals in multiphase solid inclusions crystallized from fluids trapped during garnet growth the unusual chemical composition of mica reflects the mixing of two distinct sources 1 an internal source i e the host peridotite and its garnet providing mg fe al cr and 2 an external source represented by crustal derived subduction zone fluids supplying ba k and cl at uhp uht conditions recorded by the associated diamond bearing metasediments c 1100 c and 4 5 gpa located above the second critical point in the pelitic system the produced subduction zone fluids transporting the elements into the overlying mantle wedge had a solute rich composition with properties of a hydrous melt the occurrence of barian mica with a specific chemistry in barium poor mantle rocks demonstrates the importance of its thorough chemical characterization

asian provenance of glacial dust stage 2 in the greenland ice sheet project 2 ice core summit greenland samples of dust from the greenland ice sheet project 2 gisp2 ice core summit greenland dated within marine isotope stage 2 between 23 340 and 26 180 calendar years b p around the time of the coldest local last glacial temperatures have been analyzed to determine their provenance to accomplish this we have compared them with approximately coeval aeolian sediments mostly loesses sampled in possible source areas psas from around the northern hemisphere the 5 m grain size fraction of these samples was analyzed on the basis that it corresponds to the atmospheric dust component of that time and locale which was sufficiently fine grained to be transported over long distances on the basis of comparison of the clay mineralogy and sr nd and pb isotope composition with ice dust and psas and assuming that we have sampled the most important psas we have determined that the probable source area of these gisp2 dusts was in eastern asia the dust was not derived from either the midcontinental united states or the sahara two more proximal areas that have been suggested as potential sources based on atmospheric circulation modeling except for a brief period during an interstadial when dust transport was exceptionally low for glacial times and had a mineralogical composition indicative of a slightly more southern provenance the source area of the dust did not change significantly during times of variably higher fluxes of dust with larger mean grain size or lower fluxes of dust with smaller mean grain size this includes the high dust period that correlates with the heinrich 2 period of major iceberg discharge into the north atlantic variable wind strengths must therefore be invoked to account for these abrupt and significant changes in dust flux and grain size

stochastic resonance in the north atlantic large abrupt changes between warm and cold modes of north atlantic climate exhibit spectral power at 1500 years yet some climatic changes were linked to outburst floods and other events that are unlikely to have been truly periodic we hypothesize that a weak periodic forcing has combined with noise from ice sheet related events to cause the observed mode switches this stochastic resonance hypothesis predicts a recurrence pattern between warmings that is distinct from the predictions of simple periodic and stochastic models and at least some other models the ice isotopic data from central greenland ice cores are consistent with the stochastic resonance hypothesis but not with other models we have tested we thus support arguments for the existence of a periodicity of 1500 years in the north atlantic climate system and for the importance of ice sheet events in forcing north atlantic changes

the holocene younger dryas transition recorded at summit greenland analysis of ice from dye 3 greenland has demonstrated that the transition between the younger dryas and holocene climate periods occurred over a 40 year period a near annually resolved multiparameter record of the transition recorded in the gisp2 core from summit greenland shows that most of the transition occurred in a series of steps with durations of about 5 years some climate proxies associated with mid latitude sources appear to have changed about 15 years before climate proxies associated with more northern regions changes in atmospheric water vapor are likely to have played a large role in the climate transition

contrasting impacts of dansgaard oeschger events over a western european latitudinal transect modulated by orbital parameters abstract terrestrial and marine proxies pollen planktic and benthic foraminiferal oxygen isotopes alkenone and foraminifer derived sea surface temperatures ssts ice rafted debris from images deep sea cores md95 2042 and su81 18 37 n 10 w md99 2331 and md03 2697 42 n 9 w and md04 2845 45 n 5 w show that western european and offshore environments were strongly affected by dansgaard oeschger d o and heinrich h events we concentrate here on latitudinal variability in the forest cover extent and composition of western europe during the succession of d o events showing new pollen records for core md04 2845 and for marine isotopic stages mis 3 and 4 of core md99 2331 in general cold ssts characteristic of greenland stadials were contemporaneous with the expansion of semi desert or steppic vegetation while greenland interstadials were synchronous with the expansion of forest our data reveal that the amplitude of atlantic and mediterranean forest expansions differs for any given d o warming during the glacial period 74 18 ka in the western mediterranean d o 16 17 and d o 8 and 7 corresponding to minima in precession were associated with strong expansion of forest cover contrasting with weak expansion of forest cover during d o 14 and 12 the opposite pattern is revealed at the atlantic sites further north the strongest greenland warmings are recorded for d o 19 11 and 8 this contrasting latitudinal climatic scenario is compared with other northern hemisphere records revealing similarities between the mediterranean climate and the asian monsoon regime which may relate to a summer atmospheric teleconnection between the two regions comparable to the present day situation parallels between mediterranean climate enhancement and peaks in global methane ch 4 during the last glacial period suggest a significant role of monsoon activity in determining ch 4 emission from wetlands

quantification of rapid temperature change during do event 12 and phasing with methane inferred from air isotopic measurements the description of rapid climatic changes during the last glacial period at high northern latitudes has been largely documented through greenland ice cores that are unique climatic and environmental records however greenland ice isotopic records are biased temperature proxies and it is still a matter of debate whether changes in the high latitudes lead or lag rapid changes elsewhere we focus here on the study of the mid glacial dansgaard oeschger event 12 45 ky bp associated to a large d 18 oice change in the grip greenland ice core project ice core we use combined measurements of ch4 d 15 n and d 40 ar in entrapped air associated with a recently developed firn densification and heat diffusion model to infer i the phasing between methane and temperature increases and ii the amplitude of the temperature change our method enables us to overcome the difficulty linked with rapid accumulation change in quantifying the temperature change we obtain a 12f2 5 8c temperature increase at the beginning of do event 12 thus confirming that the conventional use of water isotopes in the greenland ice cores largely underestimates the actual amplitude of rapid temperature change in central greenland in agreement with previous studies methane and temperature increase are in phase at the sampling resolution of that part of our profile 90 years d 2004 elsevier b v all rights reserved

a synchronized dating of three greenland ice cores throughout the holocene as part of the effort to create the new greenland ice core chronology 2005 gicc05 a synchronized stratigraphical timescale for the holocene parts of the dye 3 grip and ngrip ice cores is made by using volcanic reference horizons in electri cal conductivity measurements to match the cores the main annual layer counting is carried out on the most suited records only exploit ing that the three ice cores have been drilled at locations with different climatic con ditions and differences in ice flow however supplemental counting on data from all cores has been performed between each set of reference horizons in order to verify the valid ity of the match after the verification the main dating is transferred to all records us ing the volcanic reference horizons as tie points an assessment of the mean annual layer thickness in each core section confirms that the new synchronized dating is consistent for all three cores the data used for the main annual layer counting of the past 7900 years are the dye 3 grip and ngrip stable isotope records as the high accumulation rate at the dye 3 drill site makes the seasonal cycle in the dye 3 stable isotopes very resistant to firn diffusion an effort has been made to extend the dye 3 holocene record the new syn chronized dating relies heavily on this record of 75 000 stable isotope samples the dat ing of the early holocene consists of an already established part of gicc05 for grip and ngrip which has now been transferred to the dye 3 core gicc05 dates the younger dryas termination as defined from deuterium excess to 11 703 b2k 130 years earlier than the previous grip dating

f phlogopites in the alban hills volcanic district central italy indications regarding the role of volatiles in magmatic crystallisation abstract a systematic analysis of micas contained in effusive pyroclastic and hypabyssal rocks of the alban hills volcanic district ahvd central italy was made in order to characterise minerals of pyroclastic units for tephrostratigraphy and to obtain as much information as possible on the activity of volatiles in this magmatic system the phlogopite shows a large range of f contents between 0 50 and 7 50 wt that make it possible to discriminate different ahvd lithologies in particular micas of lava groundmass are characterised by extremely high f up to 7 50 wt and ba up to 9 70 wt contents seldom or never found in other magmatic ultrapotassic rocks moreover the micas of pyroclastics ultramafic cumulates and holocrystalline inclusions made up of leucite clinopyroxene and phlogopite hereafter italites show mg mg fe values between 0 65 and 0 90 that are not correlated with f contents the variations in f contents observed in the ahvd micas do not appear to be due to a temperature effect or pressure changes but they may be due to variations in the h 2 o and co 2 activities in the magma chamber they make it possible to differentiate three crystallisation environments in the ahvd magmatic system the first one had elevated co 2 activity and formed the italites near the carbonate contact these rocks represent at least those enriched in clinopyroxene without skarn minerals the hypabyssal crystallisation of the ahvd magmas at the periphery of magma chamber the second one characterised by a higher water activity is represented by the micas of the ultramafic cumulates and pyroclastic scorias and is located in the inner part of magma chamber the third environment the groundmass of the lavas it is not related with the previous ones and is characterised by the absence of water and by a high f activity in general our results suggest that the compositional variations observed in the micas al si ti ba reflect different h 2 o activities inversely correlated with f activity in the magma chamber

synchronisation of palaeoenvironmental events in the north atlantic region during the last termination a revised protocol recommended by the intimate group abstract the north atlantic intimate group of the inqua palaeoclimate commission has previously recommended an event stratigraphy approach for the synchronisation of records of the last termination using the greenland grip isotopic record as the regional stratotype and intcal98 for the calibration of radiocarbon dates lowe j j hoek w intimate group 2001 inter regional correlation of palaeoclimatic records for the last glacial interglacial transition a protocol for improved precision recommended by the intimate project group quaternary science reviews 20 1175 1187 here we present a revised protocol for time stratigraphic correlation in the north atlantic region over a more extended time period 30 8 ka this employs the new ngrip isotopic record and associated greenland ice core chronology 2005 gicc05 as the regional stratotype intcal04 for the calibration of radiocarbon dates bayesian based statistical procedures for the construction of age models and tephrochronology to validate correlations between regional site records

a high resolution study of holocene paleoclimatic and paleoceanographic changes in the nordic seas 1 high resolution records from images core md95 2011 in the eastern norwegian sea provide evidence for relatively large and small scale high latitude climate variability throughout the holocene during the early and mid holocene a situation possibly driven by consistent stronger westerlies increased the eastward influence of arctic intermediate and near surface waters for the late holocene a relaxation of the atmospheric forcing resulted in increased influence of atlantic water the main changes in holocene climate show no obvious connection to changing solar irradiance and spectral analysis reveals no consistent signature for any periodic behavior of holocene climate at millennial or centennial timescales there are however indications of consistent multidecadal variability

large arctic temperature change at the wisconsin holocene glacial transition analysis of borehole temperature and greenland ice sheet project ii ice core isotopic composition reveals that the warming from average glacial conditions to the holocene in central greenland was large approximately 15 c this is at least three times the coincident temperature change in the tropics and mid latitudes the coldest periods of the last glacial were probably 21 c colder than at present over the greenland ice sheet

origin of gem corundum in calcite marble the revelstoke occurrence in the canadian cordillera of british columbia abstract the calcite marble hosted gem corundum ruby sapphire occurrence near revelstoke british columbia canada occurs in the monashee complex of the omineca belt of the canadian cordillera corundum occurs in thin folded and stretched layers with green muscovite ba bearing k feldspar anorthite an0 85 1 phlogopite na poor scapolite other silicate layers within the marble are composed of 1 diopside tremolite quartz and 2 garnet alm0 7 0 5grs0 2 0 4 na rich scapolite diopside tremolite na k amphiboles non silicate layers in the marble are either magnetite or graphite bearing predominantly pink locally red or purple opaque to transparent corundum crystals have elevated cr2o3 0 21 wt and variable amounts of tio2 rare blue rims on the corundum crystals contain higher amounts of tio2 0 53 wt and fe2o3 0 07 wt the associated micas have elevated cr v ti and ba contents petrography of the silicate layers show that corundum formed from muscovite at the peak of metamorphism 650 700 c at 8 5 9 kbar because the marble is almost pure calcite dolomite is very rare the corundum was preserved because it did not react with dolomite to spinel calcite during decompression the scapolite bearing assemblages formed during or after decompression of the rock at 650 c and 4 6 kbar gem quality corundum crystals formed especially on borders of the mica feldspar layers in an assemblage with calcite whole rock geochemistry data show that the corundum bearing silicate mica feldspar layers formed by mechanical mixing of carbonate with the host gneiss protolith the bulk composition of the silicate layers was modified by si and fe depletion during prograde metamorphism high element mobility is supported by the homogenization of 18o and 13c values in carbonates and silicates for the marble and silicate layers the silicate layers and the gneiss contain elevated contents of cr and v due to the volcanoclastic component of their protolith

evidence for general instability of past climate from a 250 kyr ice core record recent results1 2 from two ice cores drilled in central greenland have revealed large abrupt climate changes of at least regional extent during the late stages of the last glaciation suggesting that climate in the north atlantic region is able to reorganize itself rapidly perhaps even within a few decades here we present a detailed stable isotope record for the full length of the greenland ice core project summit ice core extending over the past 250 kyr according to a calculated timescale we find that climate instability was not confined to the last glaciation but appears also to have been marked during the last interglacial as explored more fully in a companion paper3 and during the previous saale holstein glacial cycle this is in contrast with the extreme stability of the holocene suggesting that recent climate stability may be the exception rather than the rule the last interglacial seems to have lasted longer than is implied by the deep sea specmap record4 in agreement with other land based observations5 6 we suggest that climate instability in the early part of the last interglacial may have delayed the melting of the saalean ice sheets in america and eurasia perhaps accounting for this discrepancy

magnitude of isotope temperature scaling for interpretation of central antarctic ice cores 1 the conventional interpretation of ice core deuterium and oxygen 18 isotope profiles based on the use of present day observations spatial slope underestimates glacialinterglacial surface temperature changes in central greenland by up to a factor of two this likely results from changes in the seasonality of the precipitation due to the particular location of the greenland ice sheet next to the highly variable northern polar front in this regard the situation is much simpler for central antarctica and this should be reflected in the temperature interpretation of ice core isotopic records with this in mind we closely examine all relevant information focusing on the east antarctic plateau where both model and empirical isotope temperature estimates are available we point to the fact that correctly accounting for the influence of ocean isotopic change is important when interpreting deuterium profiles from ice cores in this region the evidence presently available indicates that unlike for greenland the present day spatial slope can probably be taken as a surrogate of the temporal slope to interpret glacial interglacial isotopic changes at sites such as vostok and epica dome c corresponding temperature changes are within 10 to 30 of those obtained from the conventional interpretation based on the use of the spatial slope index terms 1040 geochemistry isotopic composition chemistry 1827 hydrology glaciology 1863 3344 meteorology and atmospheric dynamics paleoclimatology 9310 information related to geographic region antarctica keywords water isotopes temperature estimate antarctica deuterium oxygen 18

an event stratigraphy for the last termination in the north atlantic region based on the greenland ice core record a proposal by the intimate group it is suggested that the grip greenland ice core should constitute the stratotype for the last termination based on the oxygen isotope signal in that core a new event stratigraphy spanning the time interval from ca 22 0 to 11 5 k grip yr bp ca 19 0 10 0 k 14 c yr bp is proposed for the north atlantic region this covers the period from the last glacial maximum through termination 1 of the deep ocean record to the pleistocene holocene boundary and encompasses the last glacial late glacial of the traditional northwest european stratigraphy the isotopic record for this period is divided into two stadial episodes greenland stadials 1 gs 1 and 2 gs 2 and two interstadial events greenland interstadials 1 gi 1 and 2 gi 2 in addition gi 1 and gs 2 are further subdivided into shorter episodes the event stratigraphy is equally applicable to ice core marine and terrestrial records and is considered to be a more appropriate classificatory scheme than the terrestrially based radiocarbon dated chronostratigraphy that has been used hitherto 1998 john wiley sons ltd

the greenland ice core chronology 2005 15 42 ka part 1 constructing the time scale the greenland ice core chronology 2005 gicc05 is extended back to 42 ka b2k before 2000 ad i e to the end of greenland stadial 11 the chronology is based on independent multi parameter counting of annual layers using comprehensive high resolution measurements available from the north greenland ice core project ngrip these are measurements of visual stratigraphy conductivity of the solid ice electrolytical melt water conductivity and the concentration of na c a 2 s o 4 n o 3 n h 4 a n uncertainty estimate of the time scale is obtained from identification of uncertain annual layers which are counted as 0 570 5 years the sum of the uncertain annual layers the so called maximum counting error of the presented chronology ranges from 4 in the warm interstadial periods to 7 in the cold stadials the annual accumulation rates of the stadials and interstadials are on average one third and half of the present day values respectively and the onset of the greenland interstadials 2 3 and 8 based on 20 year averaged d 18 o

a high resolution absolute dated late pleistocene monsoon record from hulu cave china oxygen isotope records of five stalagmites from hulu cave near nanjing bear a remarkable resemblance to oxygen isotope records from greenland ice cores suggesting that east asian monsoon intensity changed in concert with greenland temperature between 11 000 and 75 000 years before the present yr b p between 11 000 and 30 000 yr b p the timing of changes in the monsoon as established with 230th dates generally agrees with the timing of temperature changes from the greenland ice sheet project two gisp2 core which supports gisp2 s chronology in this interval our record links north atlantic climate with the meridional transport of heat and moisture from the warmest part of the ocean where the summer east asian monsoon originates

a continuous record of temperature evolution over a sequence of dansgaard oeschger events during marine isotopic stage 4 76 to 62 kyr bp 1 our knowledge of the temperature evolution over greenland during dansgaard oeschger events do is currently qualitatively described through the water isotopic profile using two independent paleothermometry methods one based on air isotopic measurements and the other on the combined measurements of water isotopes dd and d 18 o we show a complete and quantitative reconstruction of temperature at the northgrip site over the period 76 to 62 kyr bp do 18 19 and 20 we confirm that the associated warmings are larger than those conventionally depicted by the water isotopes 11 c 16 c and 11 c for do 18 19 and 20 secondly we demonstrate that the relationship between temperature and d 18 o varies rapidly during the last glacial period even over a do finally our temperature reconstruction over do 19 agrees well with that predicted from simple climate models linking the do to iceberg discharges 2004 a continuous record of temperature evolution over a sequence of dansgaard oeschger events during marine isotopic stage 4 76 to 62 kyr bp geophys res lett 31 l22211 doi 10 1029 2004gl021193 2 the last glacial cycle was characterized by millenial scale climate fluctuations that have been documented in the north atlantic region through numerous marine and continental records bond et al 1997 genty et al 2003 the grip and gisp2 summit ice cores dansgaard et al 1993 grootes et al 1993 and the newly northgrip northgrip members 2004 ice core exhibit 25 do during the last glacial period these events are characterized by rapid e g in less than 100 years and large up to 16 c lang et al 1999 warmings over greenland 3 ice cores have already provided a wealth of information on do in greenland through the water isotopes for temperature changes chemical records for atmospheric circulation and analysis of air bubbles for changes in greenhouse gases concentration however temperature reconstruction from water isotopes is subject to large biases mainly due to i the seasonality of the precipitation i e periods without precipitation will not have their temperature recorded fawcett et al 1997 and ii changes in the oceanic source of greenland snow boyle 1997 whereas the latter can be estimated from the combined measurement of dd and d 18 o through the deuterium excess parameter d dd a 8 d 18 o we need additional information to account for the influence of seasonality and possible variation of the vertical atmospheric temperature profile the isotopic composition of the snow depends on the condensation temperature 4 one elegant way to overcome those difficulties is to use the isotopic composition of the air trapped in ice a method based on the thermal diffusion of gases nitrogen and argon which allows estimates of the amplitude of rapid temperature increases severinghaus and brook 1999 lang et al 1999 leuenberger et al 1999 this method gives directly access to the local mean surface temperature and is therefore not affected by seasonality the vertical temperature profile in the atmosphere nor the source temperature of the precipitation it confirms that the conventional temperature to water isotopes relationship based on the spatial slope a s the dd 18 o ice temperature slope calculated from present day surface data underestimates greenland temperature change cuffey et al 1995 the temporal slope a t dd 18 o ice dt at a given site between two different climates is lower than a s by up to a factor of 2 we have recently refined this approach using a sophisticated firnification and heat diffusion model goujon et al 2003 to quantify the temperature increase associated with large do 12 landais et al 2004 5 here we go beyond the simple quantification of the temperature increase a detailed set of d 15 n and d 40 ar measurements over do 18 19 and 20 provides us with strong constraints on the complete temperature scenario between 76 and 62 kyr bp this period roughly corresponds to marine isotope stage 4 with rapid ice sheet growth shackleton 1987 we have also measured a continuous dd profile in the ice that combined with the existing d 18 o record allows us to account for the source temperature effects this complete study makes possible the precise estimation of the temperature change over a sequence of do 6 the d 15 n and d 40 ar profiles figure 1 show a sharp peak corresponding to each warming rapid surface warm geophysical research letters vol 31 l22211

millennial scale variability during the last glacial the ice core record the oxygen isotope records from greenland ice cores show a very strong reproducible pattern of alternation between warm greenland interstadials gi and cold greenland stadials gs at millennial scale during the last glacial period here we summarise what is known about this variability from ice core records the typical cycle has a sawtooth pattern with a very rapid warming event occurring in a few decades a slow cooling trend and then a final fast cooling 25 such events have been numbered in the last glacial the recent gicc05 age scale provides the best available age scale that can be directly applied to this stratigraphy and we summarise the timing of the warming events and the length and strength of each event the greenland stratigraphy can be transferred to other records if we make assumptions about the contemporaneous nature of rapid events in different archives other parameters such as the snow accumulation rate and the concentration of terrestrial dust and sea salt recorded in the greenland cores also show a strong contrasting pattern between gi and gs methane concentrations are generally high during gi and lower during gs with the increase from gs to gi occurring within a century antarctic ice cores show a different pattern each gi has an antarctic counterpart but antarctica appears to warm while greenland is in a gs and cool during gi these changes are consistent with a mechanism involving ocean heat transport but the rapid nature of warmings poses a challenge for modellers while the rapid methane changes pose questions about the pattern of land biosphere emissions during the glacial that are also relevant for understanding glacial interglacial methane variability

40ar 39ar k ar and 230th 238u dating of the laschamp excursion a radioisotopic tie point for ice core and climate chronologies abstract a brief period of enhanced 10 be flux that straddles the interstadial warm period known as dansgaard oeschger event 10 in greenland and its counterpart in antarctica the antarctic isotope maximum 10 is but one consequence of the weakening of earth s magnetic field associated with the laschamp excursion this 10 be peak measured in the grip ice core is dated at 41 250 y b2k before year 2000 ad in the most recent gicc05 age model obtained from the northgrip core via multi parameter counting of annual layers uncertainty in the age of the 10 be peak is however no better than 1630 y at the 95 confidence level reflecting accumulated error in identifying annual layers the age of the laschamp excursion guillou h singer b s laj c kissel c scaillet s jicha b 2004 on the age of the laschamp geomagnetic excursion earth planet sci lett 227 331 343 is revised on the basis of new 40 ar 39 ar unspiked k ar and 238 u 230 th data from three lava flows in the massif central france together with the 40 ar 39 ar age of a transitionally magnetized lava flow at auckland new zealand combined these data yield an age of 40 700 950 y b2k where the uncertainty includes both analytical and systematic 40 k and 230 th decay constant errors taking the radioisotopic age as a calibration tie point suggests that the layer counting chronologies for the northgrip and gisp2 ice cores are more accurate and precise than previously thought at depths corresponding to the laschamp excursion

timing of millennial scale climate change in antarctica and greenland during the last glacial period a precise relative chronology for greenland and west antarctic paleotemperature is extended to 90 000 years ago based on correlation of atmospheric methane records from the greenland ice sheet project 2 and byrd ice cores over this period the onset of seven major millennial scale warmings in antarctica preceded the onset of greenland warmings by 1500 to 3000 years in general antarctic temperatures increased gradually while greenland temperatures were decreasing or constant and the termination of antarctic warming was apparently coincident with the onset of rapid warming in greenland this pattern provides further evidence for the operation of a bipolar see saw in air temperatures and an oceanic teleconnection between the hemispheres on millennial time scales

changes in atmospheric circulation and ocean ice cover over the north atlantic during the last 41 000 years high resolution continuous multivariate chemical records from a central greenland ice core provide a sensitive measure of climate change and chemical composition of the atmosphere over the last 41 000 years these chemical series reveal a record of change in the relative size and intensity of the circulation system that transported air masses to greenland defined here as the polar circulation index pci and in the extent of ocean ice cover massive iceberg discharge events previously defined from the marine record are correlated with notable expansions of ocean ice cover and increases in pci during stadials without discharge events ocean ice cover appears to reach some common maximum level the massive aerosol loadings and dramatic variations in ocean ice cover documented in ice cores should be included in climate modeling

primary aerosol sea salt and soil dust deposited in greenland ice during the last climatic cycle comparison with east antarctic records ion chromatography data of ca mg cl and ca and coulter counter particle measurements are used to study the cycle of marine and continental primary aerosol reaching greenland in relation to climatic changes over the last 150 kyr a detailed comparison between greenland dome summit and antarctic vostok records provides new insight on a potential link between northern and southern patterns ca is a good indicator of continental input and is mainly emitted as caco3 an attempt is made to estimate the contribution of aluminosilicates using the concentration of insoluble particles greater than 0 5 m in diameter the relative abundance of non sea salt mg and ca and of aluminosilicate shows that the calcium content of continental background aerosol over greenland was much higher during the glacial age the neutralization capacity of carbonaceous aerosol is estimated the inverse relationship between 18o and continental input as well as the response of this input to the rapid climatic variations that have occurred during the second part of the glacial age are discussed in terms of source and transport modification in relation to the presence and the extent of the great laurentide ice cap the corresponding vostok profiles strongly suggest that some of the phenomena observed at high northern latitudes are of global concern the marine component of na nam is a good tracer of sea salt aerosol similarly to continental input it shows an inverse but more linear relationship with 18o the sensitivity of greenland and antarctic marine input to climate variations of small and large amplitude is compared and a corresponding estimation is made for the aeolian contribution the respective influence of atmospheric circulation and the water vapor cycle is discussed the chlorine to marine sodium weight ratio increases with temperature from values very close to the bulk seawater ratio during the last glacial maximum 18 20 kyr b p to values significantly higher during the holocene and warm eemian the corresponding excess of chloride hcl is discussed in terms of atmospheric transport taking into account the role of atmospheric acidity on sea salt fractionation processes owing to postdepositional phenomena similar vostok data must be considered cautiously nevertheless aerosol fractionation seems to have been much more important over the vostok site except during glacial extrema

regional variability of ice core dust composition and provenance in greenland 1 mineralogical and isotopic composition sr and nd of six dust samples obtained from six widely spread ice coring sites in greenland were analyzed in order to investigate the regional geographic variability of dust provenance we show that long range transport from eastern asian deserts provides mineral dust with essentially the same composition to all elevated interior sites dye 3 site a grip and northgrip while most material deposited at sites located closer to the edge and at lower altitude hans tausen and renland derives from proximal source regions no contribution from other sources is apparent at any of the interior sites from the mineralogical and isotopic composition of the dust samples each of which represents several decades of dust deposition during the 17th 18th century these results provide additional evidence that african and north american deserts do not play a significant role in the dust deposited over greenland which has implications for ice core record interpretation and atmospheric dust transport model validation

temperature accumulation and ice sheet elevation in central greenland through the last deglacial transition we present a combined heat and ice flow model constrained by measurements of temperature in the greenland ice sheet project 2 gisp2 borehole and by the gisp2 18o record and depth age scale which determines a history of temperature accumulation rate and ice sheet elevation for the past 50 000 years in central greenland important results are that the temperature increase from average glacial to holocene conditions was large approximately 15 c with a 20 c warming from late glacial to holocene that the average accumulation rate during the last glacial maximum between 15 and 30 kyr b p was 5 5 to 7 cm yr 1 approximately 25 of the modern accumulation rate that long term 500 1000 years averaged accumulation rate and temperature have been inversely correlated during the most recent 7 millennia of the holocene and that the greenland ice sheet probably thickened during the deglacial transition the inverse correlation of accumulation rate and temperature in the mid and late holocene suggests that the greenland ice sheet is more prone to volume reduction in a warmed climate than previously thought and demonstrates that accumulation rate is not a reliable proxy for temperature the elevation history of the ice sheet is poorly constrained by the model and independent evidence is needed we also present a simple estimate of the response time for thinning of the interior region of an ice sheet due to retreat of its margins this was approximately 1900 years for central greenland during deglaciation