rapid stepwise onset of antarctic glaciation and deeper calcite compensation in the pacific ocean the ocean depth at which the rate of calcium carbonate input from surface waters equals the rate of dissolution is termed the calcite compensation depth at present this depth is 4 500 m with some variation between and within ocean basins the calcite compensation depth is linked to ocean acidity which is in turn linked to atmospheric carbon dioxide concentrations and hence global climate1 geological records of changes in the calcite compensation depth show a prominent deepening of more than 1 km near the eocene oligocene boundary 34 million years ago 2 when significant permanent ice sheets first appeared on antarctica3 4 5 6 but the relationship between these two events is poorly understood here we present ocean sediment records of calcium carbonate content as well as carbon and oxygen isotopic compositions from the tropical pacific ocean that cover the eocene oligocene boundary we find that the deepening of the calcite compensation depth was more rapid than previously documented and occurred in two jumps of about 40 000 years each synchronous with the stepwise onset of antarctic ice sheet growth the glaciation was initiated after climatic preconditioning7 by an interval when the earth s orbit of the sun favoured cool summers the changes in oxygen isotope composition across the eocene oligocene boundary are too large to be explained by antarctic ice sheet growth alone and must therefore also indicate contemporaneous global cooling and or northern hemisphere glaciation

organic rich layers in the metochia section gavdos greece evidence for a single mechanism of sapropel formation during the past 10 my abstract three well developed 10 ma old sapropels from the island of gavdos greece were selected for a detailed geochemical micropaleontological and sedimentological study the sapropels are characterized by a high organic carbon and a low carbonate content productivity was higher during sapropel formation as indicated by increased ba contents and higher percentages of the planktonic foraminiferal species neogloboquadrina acostaensis enrichment of mo and v in the sapropels indicates less oxygenated bottom water conditions which is supported by the flourishing of low oxygen tolerant benthic foraminifera variation in grainsize and the ti al ratio point to an alternating dominance of fluvial sapropels and eolian derived homogeneous intervals terrigenous clastics evidence for a local origin of the enhanced fluvial input comes from the gradual replacement of the sapropels by cyclic turbidite sequences which were fed by bed load type rivers the increased fluvial input during sapropel formation increased the sedimentation rate and caused the observed carbonate depletion the results obtained for the gavdos sapropels are consistent with those of previous studies of younger sapropels and related caco 3 cycles in the mediterranean the consistency in most of the geochemical and micropaleontological characteristics indicates that all sapropels and related layers are the result of a single mechanism for at least the past 10 my namely precession induced dry wet oscillations in the mediterranean climate still the effect of this mechanism on the intensity of surface water productivity dilution and diagenetic signals may differ from site to site depending on location depositional environment and intensity of the astronomical forcing

magnetosusceptibility event and cyclostratigraphy method applied to marine rocks detrital input versus carbonate productivity magnetic susceptibility data from marine rocks can be used for global correlation due to synchronous variations in global erosion we show here that the magnetic susceptibility signature found in two forms resides mainly in paramagnetic and other detrital constituents in most marine rocks the first form is a short term low magnitude high frequency cyclic climate signature that is often useful for regional correlation the second form is a longer term higher magnitude low frequency signature resulting from transgressive and regressive events that can be used for global correlation fluctuations in detrital input due to eustatic based erosion are the primary cause of events these fluctuations are driven by large scale processes such as global orogenic cycles however variations in carbonate productivity cannot be ruled out when explaining the low magnitude climate driven cyclicity also observed in magnetic susceptibility data sets

putative greigite magnetofossils from the pliocene epoch greigite crystals of bacterial origin are widespread in modern sedimentary environments but their occurrence in the fossil record remains controversial grains from romanian pliocene aged sediments have now been identified as bacterial in origin tentatively placing them among the oldest known greigite magnetofossils

mixed carbonate siliciclastic record on the north african margin malta coupling of weathering processes and mid miocene climate we investigated rock outcrops spanning the middle miocene global climate cooling step on the maltese islands in order to reconstruct continental weathering rates and terrigenous fluxes as well as to explore the coupling between these later regional climate and carbonate accumulations sedimentation at this location was dominated during the oligocene and early miocene by a transitional platform to slope carbonates but progressively switched to a clay rich carbonate slope system in the middle miocene around 13 ma an abrupt change toward clay dominated marls occurred and marl deposition persisted until the tortonian ca 12 ma when a shallow water carbonate ramp was reestablished clay mineralogy and bulk rock oxygen isotope analyses suggest that the deposition of the blue clay formation was mainly caused by global climate change and related change in the rate of continental weathering a significant negative correlation r 2 0 65 exists between the carbonate content and the 1 8 o record this combined with the variation of mass accumulation rate of terrigenous material suggests that shorter term periods of globally cooler climate mi events were associated with higher rates of accumulation in continental derived material since during the miocene malta was attached to the north african margin we propose that the observed trends were due to a regional increase in rainfall during cooler periods which consequently increased continental weathering and runoff we further suggest that this pattern was linked to the perturbation of atmospheric fronts due to an increased thermal gradient during the miocene thus regional increase in rainfall might have been linked to the northward migration of the intertropical convergence zone itcz

extended orbitally forced palaeoclimatic records from the equatorial atlantic ceara rise abstract we extend existing high resolution oligocene miocene proxy records from ocean drilling program odp leg 154 the extended record spans the time interval from 17 86 to 26 5 ma the data are age calibrated against a new astronomical solution that affords a re evaluation of the intricate interaction between orbital milankovitch forcing of the climate and ocean system and the fidelity with which this forcing is recorded in oxygen and carbon stable isotope measurements from benthic foraminifera and associated lithological proxy records of magnetic susceptibility colour reflectance and the measured sand fraction our records show a very strong continual imprint of the earth s obliquity cycle modulate in amplitude every 41 ka a very strong eccentricity signal in the carbon isotope records and a strong but probably local imprint of climatic precession on the coarse fraction and magnetic susceptibility records our data allowed us to evaluate how the interaction of long multi million year beats in the earth s eccentricity and obliquity are implicated in the waxing and waning of ice sheets presumably on antarctica our refined age model confirms the revised age of the oligocene miocene boundary previously established by analysis of the lithological data and allows a strong correlation with the geomagnetic time scale by comparison with data from odp site 1090 southern ocean

extending the astronomical polarity time scale into the miocene an astronomical time scale is presented for the late miocene based on the correlation of characteristic sedimentary cycle patterns in marine sections in the mediterranean to the 65 n summer insolation curve of la90 1 2 with present day values for the dynamical ellipticity of the earth and tidd dissipation by the moon this correlation yields ages for all sedimentary cycles and hence also for the recorded polarity reversals and planktonic foraminiferal and dinoflagellate events the tortonian messinian t m boundary placed at the first regular occurrence of the globorofuliu conomiozea group in the mediterranean is dated at 7 24 ma the duration of the messinian is estimated at 1 91 myr because the miocene pliocene boundary has been dated previously at 5 33 ma 3 the new time scale is confirmed by oar 3gar ages of volcanic beds and by the number of sedimentary cycles in the younger part of the mediterranean messinian

detrital sediment fluxes from continents to oceans abstract detrital sediment is carried from land to the sea by three agents rivers glaciers and winds the shoreline is an arbitrary boundary within the detrital sediment transport system which extends from a site of origin across areas of temporary storage to a site of long term deposition the most important of the agents moving sediment across the land is river transport estimated to be in the order of 20 10 12 kg of sediment annually at present analysis of drainage basins indicates that relief and runoff are the most important factors in determining the sediment load of rivers the competence of rivers to transport sediment is governed by the volume flow gradient and the sediment load itself today most large rivers are fed by snowmelt in highland areas runoff from rainfall in the drainage basin and groundwater inflow along the river course water is lost to evaporation and groundwater infiltration river courses can often be divided into two segments a degradational section in which the gradient is relatively steep and little temporary storage of sediment takes place and an aggradational section where the gradient is sharply reduced through meandering and where large scale temporary sediment storage forms a flood plain lakes trap sediment inland and prevent its transport to the sea today many high and mid latitude rivers are interrupted by lakes of glacial origin there are also some large areas of internal drainage that deliver no sediment to the sea the load carried by rivers has been markedly altered by human activity and may have doubled over the past few thousand years only to be reduced in the past century by the widespread construction of dams the ancient use of fire in hunting and its subsequent use in clearing land has increased erosion extensive deforestation and cultivation processes have also increased the sediment supply dam construction is a relatively new factor and affects the sediment transport system by trapping sediment before it can reach the sea the resulting lower sediment supply from rivers is at least in part compensated by increased coastal erosion glacial erosion is difficult to estimate there is an ongoing controversy whether ice sheets are effective erosive agents or not estimates of the present global flux of glacial detritus range from 0 8 50 10 12 kg annually with the lower value most probable the dust flux is in the order of 0 5 to 0 9 10 12 kg annually but may vary greatly with time

chemical cycles in pliocene sapropel bearing and sapropel barren eastern mediterranean sediments abstract high resolution 3 4 cm investigations of major and minor elements were carried out on sediment cores from odp leg 160 sites 964 ionian basin 969 mediterranean ridge 967 and 966 northern slope and top of eratosthenes seamount south of cyprus at site 967 element al ratios display pronounced cyclic records that are related to astronomically forced climatic variations sediments from the top of eratosthenes seamount site 966 show a similar pattern to those from site 967 but they are more disturbed by bioturbation and also strongly influenced by long term variations in sediment dispersal sediments from site 969 display similar trends to those from site 964 i e they are characterized by higher mg al slightly higher k al and lower ti al ratios during sapropel formation higher ti al ratios at site 969 compared with sediments from site 964 may be explained by a westward transport of material from a source in the east where ti al ratios are highest sites 966 and 967 elevated mg al ratios at site 969 during sapropel intervals are due to river derived material transported through the kithira strait between peloponnesus and crete from the northwestern aegean sea which originates from ultramafic rocks a change in intermediate water currents current reversal during sapropel formation may explain the enhanced supply of mg rich and the relatively diminished supply of ti rich material we propose that during deposition of the reddish intervals at site 969 a change in circulation did not occur because a drastic decrease in ti al ratios is not evident in these sediments ba peaks indicative of former sapropels are not present ba enrichments in the same sapropel barren intervals at site 967 northern slope of eratosthenes seamount suggest that during such intervals the burn down process was more effective than during the sapropel bearing intervals mn contents in all investigated pliocene sediments correlate with the carbonate contents higher mn contents of the sapropel barren sediments suggest that during time intervals of sapropel formation either mn accumulation at the margins of the permanently oxic upper water column or mn export into the western mediterranean might have occured the latter could only be explained by sub or anoxic conditions in large parts of the water column

a review of calcareous nannofossil astrobiochronology encompassing the past 25 million years this paper presents a review of astrobiochronological calibration of recent to late oligocene calcareous nannofossil datum events biohorizons included in the paper are those of the widely used standard nannofossil zonations of martini e 1971 standard tertiary and quaternary calcareous nannoplankton zonation in farinacci a ed proceedings of the second international conference on planktonic microfossils roma rome ed tecnosci vol 2 pp 739 785 and okada h and bukry d 1980 supplementary modification and introduction of code numbers to the low latitude coccolith biostratigraphy zonation bukry 1973 1975 marine micropaleontology 51 321 325 as well as supplementary biohorizons proposed in the literature the biohorizons have been selected on the basis of the unambiguous taxonomy of the index taxa and their biostratigraphic usefulness we emphasise the application of rigorous methodology in nannofossil studies which permits an evaluation of biohorizons in terms of reliability and calibrates their potential correlatability astrochronological age estimates rely on the geologic timescale developed by the ics in 2004 with some new calibrations included we provide an overview of the relative position of biohorizons versus the astronomically calibrated ages of magnetic reversals and reference isotope stratigraphies surprisingly there are still few high resolution quantitative biostratigraphic studies of astrochronologically tuned sections in spite of the central role of such studies in addressing fundamental problems such as the tempo and mode of plankton evolution

magnetic properties of sedimentary greigite fe3s4 new data are presented here that document the previously poorly known magnetic characteristics of sedimentary greigite fe3s4 several diagnostic magnetic properties can be used in conjunction to rapidly screen sediments to detect the presence of greigite such discriminants are necessary because greigite displays a similar or higher range of coercivities compared to most ferrimagnetic minerals and the commonly used method of alternating field demagnetization cannot be used to distinguish between palaeomagnetic remanence components due to greigite and other ferrimagnetic minerals sedimentary greigite has high ratios of the saturation isothermal remanent magnetization to magnetic susceptibility mrs which are accompanied by hysteresis ratios of mrsms 0 5 and bcr bc 1 5 ms is the saturation magnetization bc is the coercive force and bcr is the coercivity of remanence greigite has no low temperature phase transition whereas the ferrimagnetic iron sulphide pyrrhotite undergoes a major phase transition at about 34 k and unoxidized magnetite displays the verwey transition at 118 k low temperature measurements may therefore prove valuable in distinguishing between magnetite pyrrhotite and greigite although the absence of a low temperature transition cannot be taken as definitive evidence for the presence of greigite greigite also displays characteristic high temperature behaviour with a major drop in magnetization between 270 and 350 c determination of the mrs ratio is an excellent means of rapidly screening sediments to identify stratigraphic intervals that may contain greigite subsequent low and high temperature analyses can then provide unambiguous identification of greigite and enable the evaluation of the presence of other magnetic minerals

completing the neogene geological time scale between 8 5 and 12 5 ma a much improved high resolution magnetostratigraphy is presented for the interval between 8 5 and 12 5 ma in the deep marine astronomically tuned monte dei corvi beach section in northern italy this section contains the formally designated boundary between the middle and upper miocene defined by the tortonian gssp the natural remanent magnetization is carried by an unusual low temperature component of primary origin according to interpretations of isothermal remanent magnetization irm acquisition curves the palaeomagnetic signal is most probably carried by iron sulphides such as greigite or pyrrhotite the resultant magnetostratigraphy is reliable and can be straightforwardly calibrated to the astronomically tuned neogene time scale atnts2004 showing that the section ranges from chron c5an 2n up to c4 2r 1 the inferred correlation of the tortonian gssp to the older part of chron c5r 2n is confirmed thereby guaranteeing global correlation potential in addition the monte dei corvi beach section has been re tuned to the new numerical solution la2004 for the interval between 8 5 and 12 9 ma this exercise shows that the characteristic cycle patterns are not consistent with a single solution with fixed values for dynamical ellipticity and tidal dissipation for the younger part of the section sedimentary cycles show an excellent fit with intricate details of precession obliquity interference in the nominal la2004 1 1 solution however this solution produces serious mismatches between the sedimentary cycles and the precession obliquity interference in the interval older than 10 2 ma for this interval changes in tidal dissipation value while keeping dynamical ellipticity constant at its present day value are necessary to maintain a perfect fit a detailed visual comparison reveals a very good to excellent fit with la2004 1 1 2 and to lesser extent with la2004 1 0 5 however la2004 1 1 2 is the preferred tuning target for the moment in the interval older than 10 2 ma the astronomical re tuning on precessional scale to la2004 1 1 yielded slightly different astronomical ages for each basic cycle and hence also for the calcareous plankton events and magnetic reversal boundaries with uncertainties ranging within a few thousand years the age of the tortonian gssp turns into 11 625 ma instead of the previously published 11 608 ma our ages should replace existing ages in the astronomically tuned neogene time scale atnts2004

middle miocene pliocene stable isotope stratigraphy and paleoceanography of the mediterranean abstract stable isotope analyses of the planktonic foraminifers globigerinoides obliquus and globigerinoides trilobus from a number of sections from sicily italy yielded a rather detailed middle miocene to upper pliocene record a comparison between this record and previously published stable isotope records from the pacific and atlantic oceans suggests that at least during the time span considered the mediterranean had a paleoclimatic and paleoceanographic history that bears a close resemblance to that of the world s oceans four different local mediterranean overprints on the general isotope signal are distinguished 1 the disruption of the tethys sea way and the subsequent installation of a strong salinity stratification 2 short term eustatic sea level changes during the miocene resulting in salinity stratification and sapropel deposition 3 periodic increase of run off and subsequent salinity stratification during the pliocene also resulting in sapropel deposition 4 pliocene trends in the carbon isotope pattern deviating from the oceanic one the reason for which remained obscure

on the origin of upper miocene sapropelites a case study from the faneromeni section crete greece for the first time results of an integrated geochemical and micropalaeontological study of upper miocene sapropelites in a land based section in the mediterranean are presented three sapropelites and adjacent homogeneous intervals in the cretan faneromeni section have been investigated in detail the chemical and foraminiferal characteristics were found to be markedly similar to those of plio pleistocene sapropelites as the physiography and climate of the late miocene mediterranean were not fundamentally different from those of today our preferred model for late miocene sapropelite formation is similar to the one recently developed for plio pleistocene sapropelites increased seasonality and freshwater input during northern hemisphere summer insolation maxima triggered high export production and oxygen consumption rates which in combination with a concomitant decrease in deep water formation rate resulted in the observed high organic matter content of the sapropelites

mid miocene isotope stratigraphy in the deep sea high resolution correlations paleoclimatic cycles and sediment preservation mid miocene pelagic sedimentary sections can be correlated using intermediate and high resolution oxygen and carbon isotopic records of benthic foraminifera precision of a few tens of thousands of years is readily achievable at sites with high sedimentation rates for example deep sea drilling project sites 289 and 574 the mid miocene carbon isotope records are characterized by an interval of high 13c values between 17 and 13 5 ma the monterey excursion of vincent and berger 1985 upon which are superimposed a series of periodic or quasi periodic fluctuations in 13c values these fluctuations have a period of approximately 440 kyr suggestive of the 413 kyr cycle predicted by milankovitch theory vincent and berger proposed that the monterey excursion was the result of increased organic carbon burial in continental margins sediments the increased 13c values called 13c maxima superimposed on the generally high mid miocene signal coincide with increases in 18o values suggesting that periods of cooling and or ice buildup were associated with exceptionally rapid burial of organic carbon and lowered atmospheric co2 levels it is likely that during the monterey excursion the ocean atmosphere system became progressively more sensitive to small changes in insolation ultimately leading to major cooling of deep water and expansion of continental ice we have assigned an absolute chronology based on biostratigraphic and magneto biostratigraphic datum levels to the isotope stratigraphy and have used that chronology to correlate unconformities seismic reflectors carbonate minima and dissolution intervals intervals of sediment containing 13c maxima are usually better preserved than the overlying and underlying sediments indicating that the 13c values of tco2 in deep water and the corrosiveness of seawater are inversely correlated this again suggests that the 13c maxima were associated with rapid burial of organic carbon and reduced levels of atmospheric co2 the absolute chronology we have assigned to the isotopic record indicates that the major mid miocene deepwater cooling ice volume expansion took 2 m y and was not abrupt as had been reported previously the cooling appears abrupt at many sites because the interval is characterized by a number of dissolution intervals the cooling was not monotonic and the 2 m y interval included an episode of especially rapid cooling as well as a brief return to warmer conditions before the final phase of the cooling period the increase in 18o values of benthic foraminifera between 14 9 and 12 9 ma was greatest at deeper water sites and at sites closest to antarctica the data suggest that the 18o value of seawater increased by no more than about 1 1 per mil during this interval and that the remainder of the change in benthic 18o values resulted from cooling in antarctic regions of deepwater formation equatorial planktonic foraminifera from sites 237 and 289 exhibit a series of 0 4 per mil steplike increases in 13c values only one of these increases in planktonic 13c is correlated with any of the features in the mid miocene benthic carbon isotope record

cenozoic global sea level sequences and the new jersey transect results from coastal plain and continental slope drilling the new jersey sea level transect was designed to evaluate the relationships among global sea level eustatic change unconformity bounded sequences and variations in subsidence sediment supply and climate on a passive continental margin by sampling and dating cenozoic strata from coastal plain and continental slope locations we show that sequence boundaries correlate within 0 5 myr regionally onshore offshore and interregionally new jersey alabama bahamas implicating a global cause sequence boundaries correlate with 18o increases for at least the past 42 myr consistent with an ice volume glacioeustatic control although a causal relationship is not required because of uncertainties in ages and correlations evidence for a causal connection is provided by preliminary miocene data from slope site 904 that directly link 18o increases with sequence boundaries we conclude that variation in the size of ice sheets has been a primary control on the formation of sequence boundaries since 42 ma we speculate that prior to this the growth and decay of small ice sheets caused small amplitude sea level changes 20 m in this supposedly ice free world because eocene sequence boundaries also appear to correlate with minor 18o increases subsidence estimates backstripping indicate amplitudes of short term million year scale lowerings that are consistent with estimates derived from 18o studies 25 50 m in the oligocene middle miocene and 10 20 m in the eocene and a long term lowering of 150 200 m over the past 65 myr consistent with estimates derived from volume changes on mid ocean ridges although our results are consistent with the general number and timing of paleocene to middle miocene sequences published by workers at exxon production research company our estimates of sea level amplitudes are substantially lower than theirs lithofacies patterns within sequences follow repetitive predictable patterns 1 coastal plain sequences consist of basal transgressive sands overlain by regressive highstand silts and quartz sands and 2 although slope lithofacies variations are subdued reworked sediments constitute lowstand deposits causing the strongest most extensive seismic reflections despite a primary eustatic control on sequence boundaries new jersey sequences were also influenced by changes in tectonics sediment supply and climate during the early to middle eocene low siliciclastic and high pelagic input associated with warm climates resulted in widespread carbonate deposition and thin sequences late middle eocene and earliest oligocene cooling events curtailed carbonate deposition in the coastal plain and slope respectively resulting in a switch to siliciclastic sedimentation in onshore areas oligocene sequences are thin owing to low siliciclastic and pelagic input and their distribution is patchy reflecting migration or progradation of depocenters in contrast miocene onshore sequences are thicker reflecting increased sediment supply and they are more complete downdip owing to simple tectonics we conclude that the new jersey margin provides a natural laboratory for unraveling complex interactions of eustasy tectonics changes in sediment supply and climate change

punctuated evolution of global climate cooling during the late middle to early late miocene high resolution planktonic foraminiferal and oxygen isotope records from the mediterranean high resolution planktonic foraminiferal and oxygen isotope records are presented from a mediterranean deep marine succession dated astronomically between 12 12 and 9 78 ma planktonic and benthic oxygen isotope records are punctuated by two episodes of 18o increase which have astronomical ages of 11 4 and 10 4 ma and correspond to the mi5 and mi6 events of miller et al 1991a these ice growth events coincide with low amplitude variations in the 1 2 myr obliquity cycle and are accompanied by significant faunal changes in the mediterranean such as the arrival of neogloboquadrinids the increase in abundance of the g apertura g obliquus group and the areal differentiation between n atlantica and n acostaensis short term variations in the planktonic foraminiferal and oxygen isotope records correspond to dominantly precession controlled sedimentary cycles features of the sapropel grey marl layers indicate that the short term astronomically controlled circum mediterranean climate changes remained basically the same over the last 12 myr

the low temperature geochemical cycle of iron from continental fluxes to marine sediment deposition suspended sediments from 34 major rivers geographically wide spread and 36 glacial meltwater streams have been examined for their variations in different operationally defined iron fractions fehr iron oxides soluble in dithionite fepr iron soluble in boiling hcl but not in dithionite and feu total iron less that soluble in boiling hcl river particulates show a close association between fehr and total iron fet reflecting the effects of chemical weathering which derive oxide iron from and retain it in close association with total iron consistent with this continental scale average fehr fet ratios vary with runoff ratios average river runoff per unit area average precipitation per unit area by contrast the diminished effects of chemical weathering produce no recognizable association of fehr with fet in glacial particulates and instead both fepr and feu are closely correlated with fet reflecting essentially pristine mineralogy a comparison of the globally averaged compositions of riverine particulates and marine sediments reveals that the latter are depleted in fehr fepr and fet but enriched in feu the river and glacial particulate data are combined with estimates of authigenic hydrothermal atmospheric and coastal erosive iron fluxes from the literature to produce a global budget for fehr f e pr f e u and fet this budget suggests that the differences between riverine particulates and marine sediments can be explained by i preferentially removing fehr from the riverine particulate flux by deposition into inner shore reservoirs such as floodplains salt marshes and estuaries and ii mixing the resulting riverine particulates with fehr depleted glacial particulates preliminary measurements of inner shore sediments are consistent with i above phanerozoic and modern normal marine sediments have similar iron speciation characteristics which implies the existence of a long term steady state for the iron cycle this steady state could be maintained by a glacioeustatic feedback where fehr enriched riverine particulates are either more effectively trapped when sealevel is high small ice masses diminished glacial erosion or are mixed with greater masses of fehr depleted glacial particulates when sealevel is low large ice masses enhanced glacial erosion further important controls on the steady state for fehr operate through the formation of euxinic sediments and ironstones which also provide sealevel dependent sinks for fehr enriched sediment

microbial mounds prior to the frasnian famennian mass extinctions hantang guilin south china late frasnian mounds of the yunghsien formation guilin south china developed as part of the guilin platform mostly in reef flat and platform margin settings microbial mounds in platform margin settings at hantang about 10 km west of guilin contain frasnian biota such as stachyodes and kuangxiastraea and thus occur below the frasnian famennian mass extinction boundary platform margin facies were dominated by microbes algae and receptaculitids massive corals and stromatoporoids are not common and rarely show reef building functions as they did in givetian time the margin mounds are composed of brachiopod receptaculitid cementstone and a variety of boundstones that contain rothpletzella renalcis thrombolite and stromatolite other microbial communities include girvanella izhella ortonella and wetheredella solenoporoid algae are abundant locally zebra structures and neptunian dykes are well developed at some intervals pervasive early cementation played an important role in lithification of the microbial boundstones and rudstones frasnian reefs of many regions of the world were constructed by stromatoporoids and corals although a shift to calcimicrobe dominated frameworks occurred before the famennian however the exact ages of many frasnian margin outcrops are poorly constrained owing to difficulties dating shallow carbonate facies the hantang mounds represent a microbe dominated reef building community with rare skeletal reef builders consistent with major late devonian changes in reef composition diversity and guild structure occurring before the end of the frasnian a similar transition occurred in the canning basin of western australia but coeval successions in north america western europe and the northern urals are either less well known or represent different bathymetric settings the transition in reef building style below the frasnian famennian boundary is documented here in the two best exposed successions on two continents which may have been global set in the larger context of late devonian and mississippian microbial reef building the hantang mounds help to demonstrate that controls on microbial reef communities differed from those on larger skeletal reef biota calcimicrobes replaced stromatoporoids as major reef builders before the frasnian famennian extinction event and increasing stromatoporoid diversity towards the end of the famennian did not result in a resurgence of skeletal reef frameworks calcimicrobes dominated margin facies through the famennian but declined near the devonian carboniferous boundary stromatolite and thrombolite facies which occurred behind the mound margin at hantang rose to dominate mississippian shallow water reef frameworks with only a minor resurgence of the important frasnian calcimicrobe renalcis in the visean when well skeletonized organisms corals also became volumetrically significant frame builders again

middle miocene oxygen minimum zone expansion offshore west africa evidence for global cooling precursor events three dissolution events ca 16 ma 15 5 ma and 14 3 ma ago have been identified in sediments from the congo fan multiproxy benthic foraminiferal and sedimentary records suggest an expanded oxygen minimum zone consistent with enhanced upwelling at these times marine carbonate records from adjacent north africa indicate coincident episodes of increased continental weathering suggesting that an intermittently stronger polar front strengthened west african offshore winds increasing surface water productivity and enhanced north african weathering during these events we propose that columbia river flood basalt volcanism estimated to have released 106 tg co2 and 106 tg so2 between 16 and 15 6 ma ago may have influenced these climatic changes

the tortonian reference section at monte dei corvi italy evidence for early remanence acquisition in greigite bearing sediments summary the reliability of primary natural remanent magnetization nrm signals in greigite bearing sediments has been frequently questioned here we show that the stable nrm in the deep marine middle to late miocene sediments at monte dei corvi northern italy is mainly carried by greigite combined rock magnetic experiments and scanning electron microscopy successfully enabled discrimination between two greigite populations one fine grained and relatively well dispersed greigite population grain size between 60 and 200 nm is most likely of magnetotactic origin the second greigite population with larger grain sizes typically 700 nm to 1 m is most likely of authigenic bacterially mediated origin and is related to post depositional sulphidization processes greigite is the main magnetic remanence carrier in the older part of the section 12 8 to 8 7 ma whereas greigite and fine grained presumably magnetotactic magnetite are present in the younger part of the section 8 7 to 6 9 ma similar remanent magnetization directions of the magnetite and greigite components and the likelihood of a magnetotactic origin suggests that the nrm is of syn depositional age we suggest that moderate methane seepage from the underlying sediments may have occurred that resulted in the preservation of pristine greigite this corroborates the reliability of the previously established magnetostratigraphy at monte dei corvi

miocene deepwater oceanography a global synthesis of miocene benthic foraminiferal carbon and oxygen isotopic and faunal abundance data indicates that miocene thermohaline circulation evolved through three regimes corresponding approximately to early middle and late miocene times there is evidence for major qualitative differences between the circulation of the modern ocean and the miocene ocean prior to 11 ma the 13c 12c ratios of the benthic foraminifera cibicidoides are interpreted in terms of water mass aging i e the progressive depletion of dissolved o2 and lowering of 13c values as the result of oxidation of organic matter as water flows further from its sources at the surface of the oceans both isotopic and faunal data indicate that the early miocene regime from 22 to 15 ma was the most different from today s during that interval intermediate and deep waters of both the atlantic and the pacific oceans aged in a northward direction and the intermediate waters of the indian the south atlantic and the south pacific oceans were consistently the youngest in the global ocean we speculate that early miocene global thermohaline circulation may have been strongly influenced by the influx of warm saline water tethyan indian saline water from the tethys into the northern indian ocean the isotopic and faunal data suggest that flow from the tethyan region into the indian ocean diminished or terminated at about 14 ma isotopic and faunal data give no evidence for north atlantic deep water nadw formation prior to about 14 5 ma with the exception of a brief episode in the early miocene from 14 5 to 11 ma nadw formation was weak and circumpolar and antarctic water flooded the deep south atlantic and south pacific as the antarctic ice cap grew from about 10 ma to the end of the miocene thermohaline circulation resembled the modern circulation in many ways in latest miocene time 6 to 5 ma circulation patterns were very similar to today s except that nadw formation was greatly diminished the distribution pattern of siliceous oozes in miocene sediments is consistent with our proposed reconstruction of thermohaline circulation major changes which occurred in circulation during the middle miocene were probably related to the closing of the tethys and may have contributed to rapid middle miocene growth of the antarctic ice cap appendices 1 4 6 and 7 are available withentire article on microfiche order fromamerican geophysical union 2000 floridaavenue n w washington dc 20009 document 88p 002 5 00 payment mustaccompany order

climate response to orbital forcing across the oligocene miocene boundary spectral analyses of an uninterrupted 5 5 million year my long chronology of late oligocene early miocene climate and ocean carbon chemistry from two deep sea cores recovered in the western equatorial atlantic reveal variance concentrated at all milankovitch frequencies exceptional spectral power in climate is recorded at the 406 thousand year ky period eccentricity band over a 3 4 million year period 20 to 23 4 my ago ma as well as in the 125 and 95 ky bands over a 1 3 million year period 21 7 to 23 0 ma of suspected low greenhouse gas levels moreover a major transient glaciation at the epoch boundary approximately 23 ma mi 1 corresponds with a rare orbital congruence involving obliquity and eccentricity the anomaly which consists of low amplitude variance in obliquity a node and a minimum in eccentricity results in an extended period approximately 200 ky of low seasonality orbits favorable to ice sheet expansion on antarctica

geological constraints on tidal dissipation and dynamical ellipticity of the earth over the past three million years the evolution of the solar system has been shown to be chaotic which limits our ability to retrace the orbital and precessional motion of the earth over more than 35 50 myr ref 2 moreover the precession obliquity and insolation parameters can also be influenced by secular variations in the tidal dissipation and dynamical ellipticity of the earth induced by glacial cyclicity and mantle convection here we determine the average values of these dissipative effects over the past three million years we have computed the optimal fit between an exceptional palaeoclimate record from the eastern mediterranean sea and a model of the astronomical and insolation history by testing a number of values for the tidal dissipation and dynamical ellipticity parameters we find that the combined effects of dynamical ellipticity and tidal dissipation were on average significantly lower over the past three million years compared to their present day values determined from artificial satellite data and lunar ranging this secular variation associated with the plio pleistocene ice load history has caused an average acceleration in the earth s rotation over the past 3 myr which needs to be considered in the construction of astronomical timescales and in research into the stationarity of phase relations in the ocean climate system through time

astronomical tuning of the la vedova high cliff section ancona italy implications of the middle miocene climate transition for mediterranean sapropel formation article i nfo continuous marine successions covering the middle miocene climate transition mmct 15 13 7 ma are scarce and the lack of a high resolution magnetobiostratigraphic framework hampers the construction of astronomically tuned age models for this time interval the la vedova high cliff section exposed along the coast of the conero riviera near ancona italy is one of the few mediterranean sections covering the critical time interval of the mmct starting from an initial magnetobiostratigraphic age model a robust astronomical tuning was constructed for the interval between 14 2 and 13 5 ma using geochemical element data and time series analysis a shift in 18 o of bulk sediment towards heavier values occurs between 13 92 and 13 78 ma and could be related to the mi3b oxygen isotope event which reflects the rapid expansion of the east antarctic ice sheet in the middle miocene the onset of the cm6 carbon excursion is reflected in the bulk record by a rapid increase in 13 c at 13 86 ma our results confirm the proposition that these events coincide with a 405 kyr minimum in eccentricity and a node in obliquity related to the 1 2 myr cycle from 13 8 ma onwards distinct quadruplet cycles containing sapropelitic sediments were deposited this may suggest a causal connection between the main middle miocene cooling step and the onset of sapropel formation in the

cyclic variations in the chemical composition of eastern mediterranean pliocene sediments a key for understanding sapropel formation abstract two pliocene mediterranean sediment cores from ocean drilling program odp leg 160 sites 964 pisano plateau ionian basin and 967 lower northern slope of eratosthenes seamount south of cyprus have been analyzed for major and minor elements si ti al fe mg ca k ba cr ni v zn zr by x ray fluorescence analysis at a depth resolution of 3 to 4 cm a total of 430 samples core 964c 9h comprises five sapropels with up to 9 7 total organic carbon toc one 2 5 m thick turbidite and a 50 cm segment of a second turbidite whereas core 967b 9h contains eight sapropels with toc contents of up to 6 7 cyclic variations in carbonate content and detrital matter composition are evident at both sites at site 964 pisano plateau terrigenous detrital matter chemistry reflects periods of stronger saharan dust input higher si al and zr al ratios alternating with fluvial input from the northern borderlands higher mg al ratios cyclicity is not well expressed at this location because turbidites and winnowing occur site 967 eratosthenes seamount sediments are strongly influenced by discharge from the nile river during humid periods low k al and mg al ratios at site 967 sapropels occur only during periods of enhanced nile discharge with correspondingly lower si al ti al mg al k al and zr al ratios accumulation rates of carbonate and terrigenous detrital matter were 30 lower during such episodes because of the reduction in eolian input and carbonate production and or carbonate dissolution periodical ba enrichments which are not only seen in the sapropels but in every k al minimum document the association of enhanced bioproductivity and sapropel formation as calculated from excess ba concentrations productivity increased by up to a factor of five during intervals of intensified nile runoff fluviatile discharge seems to be responsible for an enhanced input of nutrients and suspended matter containing low mg al and k al ratios based on organic carbon concentrations episodes of sapropel formation lasted at least from 1000 to 4000 years at site 964 and from 2000 to 6000 years at site 967 periods of enhanced bio productivity as defined by ba enrichments lasted from 8000 to 12 000 years at site 967 episodes of high river discharge and corresponding nutrient input as well as conditions of sapropel formation seem to have lasted longer in the eastern part of the basin site 967 than at the pisano plateau site 964

the origin of miocene evaporites in the tuz golu basin central anatolia turkey implications from strontium sulfur and oxygen isotopic compositions of the ca sulfate minerals abstract sulfur oxygen and strontium isotope compositions of the sulfate minerals gypsum and anhydride of the miocene evaporites in the tuz golu basin which is the largest closed and inner basin of turkey located in the central anatolia were investigated to evaluate the origin of the sulfates and interpret the precipitation paleoenvironment the isotopic mineralogical and chemical properties and composition of the samples collected from drillings were investigated the 34scdt and 18osmow values of the sulfate minerals range from 18 78 to 35 90 and 7 55 22 57 respectively most of the 34s values are similar to marine messinian water in addition the 87sr 86sr ratios of the minerals vary from 0 707803 to 0 708209 most of the 34s and 18o values and 87sr 86sr ratios of the investigated samples in the tuz golu basin are similar to those of the isotopic values of the messinian marine sulfates indicating that the minerals were precipitated mostly from marine water the 34s and 18o values of some samples are higher than those of the evaporites precipitated from the miocene seawater and indicate that the evolution of the sufates in the basin was also controlled by the recycling dissolution of the predeposited marine sulfates oligocene eocene arid conditions and bacterial sulfate reduction bsr processes additionally the low 18o values and 87sr 86sr ratios with high sr content of some samples other than those of the miocene marine sulfates may have been caused by the influence of volcanic emanations hydrothermal fluid re oxidation of sulfur and partially the contribution of the external or internal nonmarine water to the basin e g meteoric water or groundwater surface water the ca sulfate minerals with high sr contents and low 87sr 86sr ratios may have precipitated under the seawater dominated hydrothermal fluid mixing conditions

unlocking the ice house oligocene miocene oxygen isotopes eustasy and margin erosion oxygen isotope records and glaciomarine sediments indicate at least an intermittent presence of large continental ice sheets on antarctica since the earliest oligocene circa 35 ma the growth and decay of ice sheets during the oligocene to modern ice house world caused glacioeustatic sea level changes the early eocene was an ice free greenhouse world but it is not clear if ice sheets existed during the middle to late eocene doubt house world benthic foraminiferal 18o records place limits on the history of glaciation suggesting the presence of ice sheets at least intermittently since the earliest oligocene the best indicator of ice growth is a coeval increase in global benthic and western equatorial planktonic 18o records although planktonic isotope records from the western equatorial regions are limited subtropical planktonic foraminifera may also record such ice volume changes it is difficult to apply these established principles to the cenozoic 18o record because of the lack of adequate data and problems in stratigraphic correlations that obscure isotope events we improved oligocene to miocene correlations of 18o records and erected eight oxygen isotope zones oi1 oi2 mi1 mi6 benthic foraminiferal 18o increases which are associated with the bases of zones oil circa 35 8 ma oi2 circa 32 5 ma and mil circa 23 5 ma can be linked with 18o increases in subtropical planktonic foraminifera and with intervals of glacial sedimentation on or near antarctica our new correlations of middle miocene benthic and western equatorial planktonic 18o records show remarkable agreement in timing and amplitude we interpret benthic planktonic covariance to reflect substantial ice volume increases near the bases of zones mi2 circa 16 1 ma mi3 circa 13 6 ma and possibly mi5 circa 11 3 ma possible glacioeustatic lowerings are associated with the 18o increases which culminated with the bases of zone mi4 circa 12 6 ma and mi6 circa 9 6 ma although low latitude planktonic 18o records are required to test this these inferred glacioeustatic lowerings can be linked to seismic and rock disconformities for example we link 12 oligocene early late miocene inferred glacioeustatic lowerings with 12 of the sequence boundaries inferred eustatic lowerings of haq et al 1987

integrated stratigraphy and astronomical tuning of the serravallian and lower tortonian at monte dei corvi middle upper miocene northern italy an integrated stratigraphy calcareous plankton biostratigraphy magnetostratigraphy and cyclostratigraphy is presented for the serravallian and lower tortonian part middle upper miocene of the monte dei corvi section located in northern italy the detailed biostratigraphic analysis showed that both the discoaster kugleri acme and the first influx of neogloboquadrina acostaensis are recorded at monte dei corvi these events which passed unobserved in previous studies play an important role in delineating the serravallian tortonian boundary thermal and alternating field demagnetization revealed a characteristic low temperature component marked by dual polarities the resultant magnetostratigraphy for the upper part of the section can be unambiguously calibrated to the gpts ranging from c5n 2n up to c4r 2r unfortunately the lower part of the section including the serravallian tortonian boundary interval did not produce a reliable magnetostratigraphy despite the fact that some short reversed intervals and a single normal interval are recorded using sedimentary cycle patterns in combination with the calcareous plankton biostratigraphy the section can be correlated cyclostratigraphically in detail to the partially overlapping and previously tuned section of monte gibliscemi on sicily the monte dei corvi section is dated astronomically by calibrating the basic small scale sedimentary cycles to the precession and 65 n lat summer insolation time series of the la93 solution following an initial tuning of larger scale cycles to eccentricity an almost perfect fit is found between the cycle patterns and intricate details especially precession obliquity interference in the insolation target between 8 5 and 10 ma the tuning to precession remains robust for most intervals back to the base of the section dated at 13 4 ma and shows that the section is continuous apart from a possible short hiatus in the tortonian it provides accurate astronomical ages for all sedimentary cycles calcareous plankton events polarity reversals and ash layers and marks a significant improvement of the recently proposed astronomical calibrations of the monte dei corvi section and of parallel sections in the mediterranean astronomical ages for the ancona and respighi ashbeds are significantly older than previously reported 40 ar 39 ar biotite ages even if the revised older age for the fct san dating standard of 28 02 ma is applied the astronomical dating of the magnetic reversals in the monte dei corvi section results in the completion of the astronomical polarity time scale for the last 13 myr the monte dei corvi section has recently been proposed as the stratotype section for the serravallian tortonian boundary despite the moderate to

long period orbital control on middle miocene global cooling integrated stratigraphy and astronomical tuning of the blue clay formation on malta 1 application of an astronomical age model to a bulk carbonate oxygen isotope record in the ras il pellegrin section on malta indicates that the major step in the middle miocene global cooling 13 82 ma 0 03 coincides with minimum eccentricity values associated with the 400 kyr cycle and minimum obliquity amplitudes associated with the 1 2 myr cycle this orbital configuration is very similar to that found for comparable oxygen isotope enrichment events in the late paleogene and neogene the stepwise character of the middle miocene cooling event appears to be controlled by the combined influence of the 100 kyr eccentricity cycle and the 172 kyr cycle in obliquity amplitude the integrated stratigraphy further allows extension of the astronomical polarity timescale to the top of chron c5acn the boundary between the globigerina limestone and the blue clay formation coincides with the major step in middle miocene global cooling and provides a level suitable for placing the physical reference point for the langhian serravallian boundary

orbitally paced climate evolution during the middle miocene monterey carbon isotope excursion one of the most enigmatic features of cenozoic long term climate evolution is the long lasting positive carbon isotope excursion or monterey excursion which started during a period of global warmth after 16 9 ma and ended at similar to 13 5 ma approximately 400 kyr after major expansion of the antarctic ice sheet we present high resolution 1 9 kyr astronomically tuned climate proxy records in two complete sedimentary successions from the northwestern and southeastern pacific odp sites 1146 and 1237 which shed new light on the middle miocene carbon isotope excursion and associated climatic transition over the interval 17 1 12 7 ma we recog nize three distinct climate phases with different imprints of orbital variations into the climatic signals 1146 and 123 7 delta 18 o delta 13 c 1237 xrt fe fraction 63 pm 1 climate optimum prior to 14 7 ma characterized by minimum ice volume and prominent 100 and 400 kyr variability 2 long term cooling from 14 7 to 13 9 ma principally driven by obliquity and culminating with rapid cryosphere expansion and global cooling at the onset of the last and most pronounced delta 13 c increase 3 icehouse mode after 13 9 ma with distinct 100 kyr variability and improved ventilation of the deep pacific the monterey carbon isotope excursion 16 9 13 5 ma consists overall of nine 400 kyr cycles which show high coherence with the long eccentricity period superposed on these low frequency oscillations are high frequency variations 100 kyr which closely track the amplitude modulation of the short eccentricity period in contrast to delta 13 c the delta 18 o signal additionally shows significant power in the 41 kyr band and the 1 2 myr amplitude modulation of the obliquity cycle is clearly imprinted in the 1146 delta 18 o signal our results suggest that eccentricity was a prime pacemaker of middle miocene climate evolution through the modulation of long term carbon budgets and that obliquity paced changes in high latitude seasonality favored the transition into the icehouse climate c 2007 elsevier b v all rights reserved

impacts of orbital forcing and atmospheric carbon dioxide on miocene ice sheet expansion the processes causing the middle miocene global cooling which marked the earth s final transition into an icehouse climate about 13 9 million years ago myr ago 1 4 remain enigmatic tectonically driven circulation changes 5 6 and variations in atmospheric carbon dioxide levels 7 8 have been suggested as driving mechanisms but the lack of adequately preserved sedimentary successions has made rigorous testing of these hypotheses difficult here we present high resolution climate proxy records covering the period from 14 7 to 12 7 million years ago from two complete sediment cores from the northwest and southeast subtropical pacific ocean using new chronologies through the correlation to the latest orbital model 9 we find relatively constant low summer insolation over antarctica coincident with declining atmospheric carbon dioxide levels at the time of antarctic ice sheet expansion and global cooling suggesting a causal link we surmise that the thermal isolation of antarctica played a role in providing sustained long term climatic boundary conditions propitious for ice sheet formation our data document that antarctic glaciation was rapid taking place within two obliquity cycles and coincided with a striking transition from obliquity to eccentricity as the drivers of climatic change

astronomic calibration of the late oligocene through early miocene geomagnetic polarity time scale at ocean drilling program odp site 1090 subantarctic south atlantic benthic foraminiferal stable isotope data from cibicidoides and oridorsalis span the late oligocene through early miocene f24 16 ma at a temporal resolution of f5 ky over the same interval a magnetic polarity stratigraphy can be unequivocally correlated to the geomagnetic polarity time scale gpts thereby providing direct correlation of the isotope record to the gpts in an initial age model we use the newly derived age of the oligocene miocene o m boundary of 23 0 ma of shackleton et al geology 28 2000 447 revised to the new astronomical calculation la2003 of laskar et al icarus in press to recalculate the spline ages of cande and kent j geophys res 100 1995 6093 we then tune the site 1090 y 18 o record to obliquity using la2003 in this manner we are able to refine the ages of polarity chrons c7n through c5cn 1n the new age model is consistent within one obliquity cycle with previously tuned ages for polarity chrons c7n through c6bn from shackleton et al geology 28 447 450 2000 when rescaled to la2003 the results from site 1090 provide independent evidence for the revised age of the oligocene miocene boundary of 23 0 ma for early miocene polarity chrons c6aar through c5cn our obliquity scale age model is the first to allow a direct calibration to the gpts the new ages are generally within one obliquity cycle of those obtained by rescaling the cande and kent j geophys res 100 1995 6093 interpolation using the new age of the o m boundary 23 0 ma and the