single and joint fault plane solutions for microearthquakes in south iceland abstract we obtain fault plane solutions for a swarm of twelve events and two single events ranging in magnitude between 0 3 and 3 1 the events were recorded by a local network in south iceland consisting of eight three component stations with approximately 30 km between the stations for events larger than m l 1 the solutions are well constrained the non uniqueness of the fault plane solutions increases with diminishing magnitude to enhance the uniqueness of the fault plane solutions for the earthquake swarm we search for mechanisms with a common fault plane but possibly varying slip directions in that plane data for all the events are consistent with faulting on a common plane relative location of the events shows that they all occurred less than 11 m from a single plane fault plane solutions for all the analysed events of the swarm as well as the two single events are consistent with strike slip dominated faulting on faults striking roughly north south the results are in agreement with the strikes of mapped surface fractures and focal mechanisms of larger earthquakes in the area this indicates that the microseismicity is related to the same pattern of regional deformation as the major earthquakes in south iceland

radar imagery of mercury s putative polar ice 1999 2005 arecibo results abstract we present an updated survey of mercury s putative polar ice deposits based on high resolution 1 5 km imaging with the upgraded arecibo s band radar during 1999 2005 the north pole has now been imaged over a full range of longitude aspects making it possible to distinguish ice free areas from radar shadowed areas and thus better map the distribution of radar bright ice the new imagery of the south pole though derived from only a single pair of dates in 2005 improves on the pre upgrade arecibo imagery and reveals many additional ice features some medium size craters located within 3 of the north pole show near complete ice coverage over their floors central peaks and southern interior rim walls and little or no ice on their northern rim walls while one large 90 km crater at 85 n shows a sharp ice cutoff line running across its central floor all of this is consistent with the estimated polar extent of permanent shading from direct sunlight some craters show ice in regions that though permanently shaded should be too warm to maintain unprotected surface ice owing to indirect heating by reflected and reradiated sunlight however the ice distribution in these craters is in good agreement with models invoking insulation by a thin dust mantle comparisons with goldstone x band radar imagery indicate a wavelength dependence that could be consistent with such a dust mantle more than a dozen small ice features have been found at latitudes between 67 and 75 all of this low latitude ice is probably sheltered in or under steep pole facing crater rim walls although since most is located in the mariner unimaged hemisphere confirmation must await imaging by the messenger orbiter these low latitude features are concentrated toward the cold longitudes possibly indicating a thermal segregation effect governed by indirect heating the radar imagery places the corrected locations of the north and south poles at 7 w 88 35 n and 90 w 88 7 s respectively on the original mariner based maps

mercury radar imaging evidence for polar ice the first unambiguous full disk radar mapping of mercury at 3 5 centimeter wavelength with the goldstone 70 meter antenna transmitting and 26 antennas of the very large array receiving has provided evidence for the presence of polar ice the radar experiments conducted on 8 and 23 august 1991 were designed to image the half of mercury not photographed by mariner 10 the orbital geometry allowed viewing beyond the north pole of mercury a highly reflective region was clearly visible on the north pole during both experiments this polar region has areas in which the circular polarization ratio pt was 1 0 to 1 4 values 0 1 are typical for terrestrial planets such high values of have hitherto been observed in radar observations only from icy regions of mars and icy outer planet satellites

sabkhas slumping and compaction at mufulira zambia algal structures such as stromatolites have long been recognized as closely associated with the cupriferous dolomitic shales of the katanga supergroup of zaire and zambia discovery of bioherms and biostromes in the predominantly arenaceous deposits of the mufulira copper mine indicates a similar origin with the more common copper deposits in dolomitic shale and their barren gaps due to bioherms renfro 1974 recognized the worldwide association of sabkhas algal mats and stratiform copper deposits his interpretation of sabkha environments in cyclic depositional sequences at mufulira is corroborated by detailed features in the mine recognition of abundant carbonized debris of algal mat from 0 5 m down to microscopic size in the marine sediments of mufulira indicates an accumulation of decomposing vegetable debris that is more than sufficient to promote anoxic conditions in the bottom waters of the lagoons with resulting precipitation of copper and iron sulfides contemporaneously with sedimentation compaction of algal material explains the 80 percent contraction of sun cracked mud flakes also compaction by roughly two thirds of the algal rich graywacke and the c orebody accounts for the rapid sagging of overlying sabkha and terrestrial sediments which was followed by a second marine invasion allowing deposition of the b orebody and central graywacke similar rapid compaction of the latter under its cover of sabkha and red bed sediment caused further sagging marine invasion and deposition of the a orebody and graywacke vertically above the c and b graywackes although renfro s hypothesis of mineralization by ascending groundwaters may account for some initial precipitation of sulfides beneath algal mats the bulk of the preserved mineralization at mufulira exhibits features more compatible with syngenetic deposition of sulfides associated with decaying transported algal material in marine lagoons

mercury full disk radar images and the detection and stability of ice at the north pole the first full disk radar images of mercury were obtained on august 8 and 23 1991 these images were constructed using the very large array vla in socorro new mexico to receive and map radar flux at 3 5 cm x band which was continuously transmitted from the 70 m jet propulsion laboratory deep space network antenna at goldstone california approximately 77 of the surface was imaged at resolutions as good as 150 km about half of the hemisphere photographed by mariner 10 was imaged as well as most of the hemisphere which has not previously been photographed at the time of the observations the north pole was visible and the feature with the highest same sense ss circular reflectivity in the images is near the nominal polar position the peak ss reflectivity of this feature was 7 9 and the circular polarization ratio throughout much of the feature is 1 our best estimate of the size of the feature is that its diameter is 350 km we interpret the feature to be indicative of the presence of ices because of the signal strength and polarization characteristics the ices must be very clean and were thus probably deposited in a relatively short time period the most likely place to find these ices is in any permanently shadowed areas in the polar regions which would be very cold in comparison to absolute reflectivities of other icy bodies and regions in the solar system the reflectivity of the north polar feature is slightly depressed this is probably because the ices do not fill an observational resolution cell i e there is incomplete areal coverage or are covered by a layer of dust or soil which absorbs some of the incoming and outgoing radar energy or both a covering layer would also protect any ices from erosion by energetic sources other prominent features on the unphotographed hemisphere correspond to positions where atmospheric sodium enhancements have been measured from earth this may indicate that these locations are large basins similar to the caloris basin where an atmospheric potassium enhancement has been measured which may be the result of increased degassing in the disrupted surface and near surface direct comparison of the radar echoes from our features with those from the caloris basin are hard to make as caloris was not imaged by us in a favorable geometry features on the photographed hemisphere are smaller and mostly associated with craters and crater complexes most notably the kuiper crater and its environs

push ups fracture patterns and palaeoseismology of the leirubakki fault south iceland abstract field measurements and gps mapping were conducted along the leirubakki fault a 010 trending right lateral strike slip fault located in the holocene lava flows of the south iceland seismic zone because of poor exposures south and north of the holocene lava flow dissected by the fault its length can only be traced for 7 5 km the exposed surface rupture contains fractures that range in size over four orders of a magnitude from the main fault through fault segments 1000 2000 m long fracture arrays 100 250 m long to individual fractures 8 125 m long detailed measurements were made of 63 push ups located at junctions between individual fractures and between fracture arrays and ranging in maximum height from 0 35 to 4 35 m using the push ups the maximum right lateral displacement on the leirubakki fault is estimated at 2 67 m using empirical relationships established globally it is concluded that for a maximum displacement of 2 67 m the true rupture length of the leirubakki fault is around 50 km and that it gave rise to an earthquake of a moment magnitude 7 1

new evidence for surface water ice in small scale cold traps and in three large craters at the north polar region of mercury from the mercury laser altimeter the mercury laser altimeter mla measured surface reflectance rs at 1064 nm on mercury most water ice deposits have anomalously low rs values indicative of an insulating layer beneath which ice is buried previous detections of surface water ice without an insulating layer were limited to seven possible craters here we map rs in three additional permanently shadowed craters that host radar bright deposits each crater has a mean rs value 0 3 suggesting that water ice is exposed at the surface without an overlying insulating layer we also identify small scale cold traps 0 3 and permanent shadows have biannual maximum surface temperatures 100 k we suggest that a substantial amount of mercury s water ice is not confined to large craters but exists within micro cold traps within rough patches and inter crater terrain

orbital eccentricity driven temperature variation at mercury s poles 1 due to mercury s extremely small obliquity variations in orbital eccentricity are likely to have been the dominant cause of changes in polar temperatures on mercury throughout the bulk of its history in the last 10 myr the eccentricity has varied between 0 1 and 0 3 over the past 100 myr eccentricity extremes of nearly zero to greater than 0 4 have likely been reached we calculate the temperature in the near polar region within 10 of the north pole as it varies in response to past eccentricities these calculations show periods with dramatically different temperatures diurnal amplitudes and long period thermal cycles all of which can have a dramatic effect on longitudinal variations in long term subsurface ice stability given forthcoming topographic data thermal models including long term eccentricity can help constrain when past ice might have been delivered to mercury

effects of orbital evolution on lunar ice stability 1 many regions near the lunar poles are currently cold enough that surface water ice would be stable against sublimation losses for billions of years however most of these environments are currently too cold to efficiently drive ice downward by thermal diffusion leaving impact burial as the primary means of protection from surface loss processes in this respect most of the present near surface thermal environments on the moon may actually be quite poor traps for water ice this was not always the case long term orbital changes have dramatically altered the lunar polar thermal environment we develop a simple model of the evolution of the lunar orbit and spin axis to examine the thermal environments available for volatile deposition and retention in the past our calculations show that some early lunar polar environments were in the right temperature regime to have collected subsurface ice if a supply were available however a high obliquity period which occurred when the moon was at about half its present distance from the earth would either have driven this ice out into space or deep into the lunar subsurface since that time as the lunar obliquity has slowly decreased to its present value environments have undergone their own thermal evolution and each of the current cold traps experienced a period when they were most efficient at thermally burying ice we examine the thermal history of a lunar polar crater to provide a framework for examining other processes effecting volatiles in the moon s near surface cold traps

geochemistry of the rare earth elements in hypersaline and dilute acidic natural terrestrial waters complexation behavior and middle rare earth element enrichments rare earth element ree speciation was modelled in acid 2 9 ph 3 5 hypersaline groundwaters from australia and from the palo duro basin in texas usa using a combined specific ion interaction pitzer model and ion pairing model the free metal ion species i e ln3 is the dominant form of dissolved rees in these systems accounting for 40 70 of the dissolved metal in groundwater from lake tyrrell victoria australia 50 90 of the rees in groundwater from lake gilmore western australia and always 90 of each ree in the texas groundwaters lakes tyrrell and gilmore are actually dry lakes that act as groundwater discharge zones the abundance of the free metal ion species increases in these waters with increasing ionic strength and with decreasing ph the free metal ion species is followed in abundance by ree sulfate and ree chloride complexes that account for 20 50 and 10 15 respectively of the dissolved rees in the groundwaters from lake tyrrell 15 30 and 5 20 respectively in the groundwaters from lake gilmore and 3 and 7 respectively in the palo duro basin groundwaters the groundwaters of the lake tyrrell system and the palo duro basin are enriched in the middle rees mrees compared to both the light rees lrees and the heavy rees hrees only nd sm and dy were determined in the lake gilmore groundwaters and consequently it is unclear whether these acid groundwaters are also enriched in the mrees previous investigators suggested that fe rich organic flocs ree phosphate complexation and solid liquid exchange reactions between terrestrial waters and mree enriched surface fe mn coatings suspended particulates or secondary mineral phases within aquifer materials may promote the development of mree enrichments in natural waters we propose that organic colloids and ree phosphate complexes are insignificant in acidic natural waters in regards to mree enrichments instead solid liquid exchange reactions or dissolution of surface coatings suspended particulates and or secondary phases as well as sulfate complexation more likely controls the development of mree enrichments in acidic natural terrestrial waters

the migration of volatiles on the surfaces of mercury and the moon radar observations of mercury have provided the startling discovery of the probable existence of substantial deposits of ices in permanently shaded polar regions butler et al 1993 harmon et al 1994 this has renewed the old argument about the existence of such deposits in the polar regions of the moon it is most likely necessary for volatiles to be able to migrate to the polar regions of these bodies in order to build up such deposits this paper presents the results of the extension of a monte carlo simulation of the migration of molecules on the surface of mercury by butler et al 1993 the results of the simulations show that for typical conditions on mercury 5 15 of all h 2 o which is placed randomly on the surface migrates to stable permanently shaded polar regions for the moon the numbers are 20 50 the numbers for the migration of co 2 are 2 for mercury and 13 for the moon these percentages are similar to those previously calculated and support the idea of ice deposits in the polar regions of both mercury and the moon

craters hosting radar bright deposits in mercury s north polar region areas of persistent shadow determined from messenger images 1 radar bright features near mercury s poles were discovered in earth based radar images and proposed to be water ice present in permanently shadowed areas images from messenger s one year primary orbital mission provide the first nearly complete view of mercury s north polar region as well as multiple images of the surface under a range of illumination conditions we find that radar bright features near mercury s north pole are associated with locations persistently shadowed in messenger images within 10 of the pole almost all craters larger than 10 km in diameter host radar bright deposits there are several craters located near mercury s north pole with sufficiently large diameters to enable long lived water ice to be thermally stable at the surface within regions of permanent shadow craters located farther south also host radar bright deposits and show a preference for cold pole longitudes thermal models suggest that a thin insulating layer is required to cover these deposits if the radar bright material consists predominantly of long lived water ice many small 10 km diameter and low latitude extending southward to 66 n craters host radar bright material and water ice may not be thermally stable in these craters for 1 gy even beneath an insulating layer the correlation of radar bright features with persistently shadowed areas is consistent with the deposits being composed of water ice and future thermal modeling of small and low latitude craters has the potential to further constrain the nature source and timing of emplacement of the radar bright material

the thermal stability of water ice at the poles of mercury recent radar observations of mercury have revealed the presence of anomalous radar reflectivity and polarization features near its north and south poles thermal model calculations show that despite mercury s proximity to the sun the temperatures of flat low reflectivity surfaces at mercury s poles are not expected to exceed 167 kelvin the locations of the anomalous polar radar features appear to be correlated with the locations of large high latitude impact craters maximum surface temperatures in the permanently shadowed regions of these craters are expected to be significantly colder as low as 60 kelvin in the largest craters these results are consistent with the presence of water ice because at temperatures lower than 112 kelvin water ice should be stable to evaporation over time scales of billions of years

areas of permanent shadow in mercury s south polar region ascertained by messenger orbital imaging 1 radar bright features near mercury s poles have been postulated to be deposits of water ice trapped in cold permanently shadowed interiors of impact craters from its orbit about mercury messenger repeatedly imaged the planet s south polar region over one mercury solar day providing a complete view of the terrain near the south pole and enabling the identification of areas of permanent shadow larger in horizontal extent than approximately 4 km in mercury s south polar region all radar bright features correspond to areas of permanent shadow application of previous thermal models suggests that the radar bright deposits in mercury s south polar cold traps are in locations consistent with a composition dominated by water ice provided that some manner of insulation such as a thin layer of regolith covers many of the deposits

hydrogeochemistry and weathering on the yilgarn block western australia ferrolysis and heavy metals in continental brines abstract groundwater samples collected from salt lakes over the archean yilgarn block of western australia show the influence of climate on geochemical weathering patterns major element compositions in salt lake groundwaters show little systematic trend but there are marked differences in ph and fe cu and pb concentrations in the alkaline carbonated systems of the arid northeastern part compared to concentrations of the same elements in groundwater systems of the mediterranean type climatic region of the wheatbelt in the southwestern part of the block in this latter region in addition to higher rainfall input the groundwater systems have steeper hydraulic gradients weathering bedrock is closer to the surface and oxidation and hydrolysis of iron ferrolysis is evident in weathering profiles a combination of vertical diffusion and horizontal groundwater flow is thought to be responsible for the development of ferrolysis and acidity in groundwaters in this region anomalously high concentrations of heavy metals particularly lead are observed in some of the acid saline groundwaters the formation of laterite which is a ubiquitous feature of the yilgam block landscape is a process probably closely linked to ferrolysis

a search for water ice at the lunar poles with clementine images abstract optical and near ir signatures of water ice on the moon s surface were sought in the permanently shadowed regions near its poles significant amounts of multiply scattered radiation partly illuminate primary shadows cast by craters and other features if there is water ice in the permanently shadowed regions of the moon s surface its spectral signature should appear in this multiply scattered light this investigation can be done most effectively with observations obtained by spacecraft because most selenocentric positions occupied by the earth will also be occupied by the sun at some point in time and because the lunar poles are seen only obliquely to a terrestrial observer images obtained by clementine are particularly well suited to this task because the spacecraft s polar orbit allowed images of the poles to be acquired on nearly every orbit resulting in literally thousands of images taken within a few degrees of each pole and because the filters on the ultraviolet visual camera uvvis and the near infrared camera nir occur at major absorption bands or within important continuum features of water ice approximately 5800 images obtained by the uvvis camera and 1800 images obtained by the nir camera were calibrated and combined into coadded mosaics to create multispectral maps of the lunar poles with the highest possible signal to noise unfortunately analysis of our uvvis mosaics indicates that any possible signal from multiply scattered light in primary shadows was overwhelmed by instrumental stray light for the nir camera we were able to determine the normalized reflectance of several regions that were identified by margot et al 1999 science284 1658 1660 as permanent shadows we have identified one permanently shadowed crater with a 1 5 m band spectral signature indicative of between 2 5 and 21 fractional coverage of h2o frost however the same region shows a 2 0 m spectral signature that is inconsistent with the presence of any water

the diagenetic origin of stratiform copper mineralization coates lake redstone copper belt n w t canada extensive stratiform copper mineralization occurs in three upper proterozoic embayments along a 250 km long arcuate belt in the mackenzie mountains supergroup northwest territories canada mineralization is found in transgressive strata between the continental red beds of the redstone river formation and shallow restricted marine carbonates of the overlying coppercap formation a mafic volcanic succession lying stratigraphically beneath the red beds possibly provided copper bearing detritus to the red beds the coates lake deposit the object of this study contains cupriferous sulfides principally chalcocite bornite and chalcopyrite hosted by microbial laminated limestones and dolostones these carbonates are intercalated with red siltstones to form as many as seven red bed carbonate couplets within the 110 m thick transition zone regional and local studies indicate that the host sediments were deposited in a peritidal setting associated with a sabkha environment paragenetic studies reveal a consistent order of precipitation for gangue and ore forming minerals these minerals can be related to the diagenetic evolution of the host sediments their presence at the coates lake deposit may be divided chronologically into four syngenetic to early diagenetic stages syndiagenesis precipitation of gypsum anhydrite after gypsum dolomitization diagenesis 1 deposition of calcite with partial replacement of anhydrite preore pyrite authigenic silica with partial replacement of anhydrite and calcite and authigenic feldspar diagenesis 2 precipitation of copper bearing sulfides in the presence of reduced sulfur sulfate reducing bacteria and organic matter and partial replacement of preore pyrite anhydrite calcite and quartz and diagenesis 3 neomorphism of calcite mineralization identified with the second stage of diagenesis would have preceded the marked reduction in permeability associated with the formation of neomorphic calcite

investigating mercury s south polar deposits arecibo radar observations and high resolution determination of illumination conditions there is strong evidence that mercury s polar deposits are water ice hosted in permanently shadowed regions in this study we present new arecibo radar observations of mercury s south pole which reveal numerous radar bright deposits and substantially increase the radar imaging coverage we also use images from messenger s full mission to determine the illumination conditions of mercury s south polar region at the same spatial resolution as the north polar region enabling comparisons between the two poles the area of radar bright deposits in mercury s south is roughly double that found in the north consistent with the larger permanently shadowed area in the older cratered terrain at the south relative to the younger smooth plains at the north radar bright features are strongly associated with regions of permanent shadow at both poles consistent with water ice being the dominant component of the deposits however both of mercury s polar regions show that roughly 50 of permanently shadowed regions lack radar bright deposits despite some of these locations having thermal environments that are conducive to the presence of water ice the observed uneven distribution of water ice among mercury s polar cold traps may suggest that the source of mercury s water ice was not a steady regular process but rather that the source was an episodic event such as a recent large impact on the innermost planet

geochemistry of acid brines lake tyrrell victoria australia abstract pore water groundwater and sediments were collected from lake tyrrell to study the evolution of brines in an acidic environment lake tyrrell is a 150 km2 inland salt playa acid saline groundwater enters the playa through springs along the lake margin and is evapo concentrated past halite precipitation the brines were found to contain sea salts but some solutes do not follow the seawater evaporation curve processes that occur in neutral alkaline systems e g gypsum formation occur here but precipitation of alunite kal3 so4 2 oh 6 jarosite kfe3 so4 2 oh 6 and fe oxides also affect solute behavior processes that occur in the recharge area and along the groundwater flow path k uptake calcrete and gypcrete formation affect the brine s chemical signature regardless of the chemical variability found among the samples solutes have evolved from a common source sea salt acidification which appears to occur early in the evolution of the groundwater is related to pyrite oxidation and may be enhanced by precipitation of fe oxides alunite and jarosite and evaporation acidity is maintained in the system because of the lack of buffering capacity of aquifer minerals we suggest that this acid brine from australia is another end member in the eugster jones hardie model for the evolution of water by evaporation in closed basins

stratiform copper deposits hosted by low energy sediments ii nature of source rocks and composition of metal transporting water several factors suggest that hematite bearing sediments composed principally of alluvial fan sediments were the source of metal transporting water and of metals in stratiform copper deposits hosted by low energy sediments first such sediments are associated with all examples of larger stratiform copper deposits hosted by low energy sediments second a zonal sequence corresponding to an approximate sulfide solubility product increase is developed laterally into the basin from sandy sediments in contact with the hematite bearing sediments and upward from the contact of the ore hosting sediments with the hematite bearing sediments third the zonal sequence is developed basinward from pinchouts and wedge downs of the hematite bearing sediments and copper mineralization is absent from host horizons where hematite bearing sediments are not developed fourth authigenic mineral assemblages with the exception of hematite sulfides and organic carbon are similar in both the host sediments and in the hematite bearing sediments the authigenic and evaporite mineral assemblages and the nature of associated sediments indicate that most occurrences of the hematite bearing sediments were probably deposited in closed continental basins published sedimentological and paleogeographic analyses show that the rotliegende associated with the kupferschiefer hosted deposits was deposited in a closed continental basin no consistent composition of the hematite bearing sediments is evident although basalt flows or basalt derived clastic components occur in the alluvial fan sediments associated with three of the larger stratiform copper deposits authigenic and evaporite minerals and compositions of modern continental closed basin waters show that the waters originally within the closed basins were na cl so 4 types with variable mg ca and so 4 contents in equilibrium with hematite and with a ph constrained either by carbonate minerals atmospheric carbon dioxide or by quartz microcline muscovite chloride concentrations were likely to have been about six times seawater waters with higher mg and lower ca contents were likely to be associated with alluvial fan sediments containing basalt or dolomite derived clastic components water rock ratios in the alluvial fan sediments were probably 33 percent or less if the 50 cm hypothesis i e that chalcocite in stratiform copper deposits hosted by low energy sediments was precipitated as a result of bacterial sulfate reduction within 50 cm of the surface of the host sediment is true then metal transporting waters were being released from the hematite bearing sediments very early in their burial history if so the metal transporting water was the original closed basin water with a temperature of less than 50 degrees c

the thickness of radar bright deposits in mercury s northern hemisphere from individual mercury laser altimeter tracks the discovery of mercury s radar bright deposits has expanded our understanding of volatiles in the solar system key to deciphering the history and origin of the radar bright deposits is an estimate of the volume of radar bright material that in turn requires a measure of the average thickness of the deposits in this study we investigate changes in topography across radar bright deposits hosted in flat floored complex craters using individual edited mercury laser altimeter mla tracks we compare the difference in heights of radar bright regions and non radar bright regions of the crater floor and the difference of similarly sized and located regions in non radar bright craters and show that the two populations cannot be distinguished the similarity of topography in these two sets of craters allows an upper limit of 15 m to be placed on the thickness of the radar bright deposits

a revised control network for mercury an improved control net for mercury has been completed by utilizing images acquired during the three mariner 10 flybys in 1974 1975 relative positional errors within the net are 1 km on average and absolute locations are estimated to be better than 25 km the analytical triangulation resulted in new values for focal lengths camera a 1493 6 mm camera b 1500 1 mm w0 329 548 and camera orientation angles for 811 images acquired during all three flybys of mercury

surface traces of the minnivellir rettarnes and tjorvafit seismic faults in the south iceland seismic zone segmentation lengths and magnitude of related earthquakes abstract accurate gps mapping and field measurements have been carried out along the surface traces of three n s right lateral historical and prehistorical seismic strike slip faults in the south iceland seismic zone the minnivellir tjorvafit and rettarnes faults we used these data and those previously collected on the selsund and leirubakki faults to characterise the faulting behaviour this study illustrates a characteristic multi scale segmentation including from the longer to the smaller fault elements i fault corresponding to the total length of the seismic fault ii fault segments iii arrays of fractures and iv individual fractures the most distinctive feature of such right lateral fault is its left stepping en echelon arrangement at various scales with push up structures accommodating the motion in the relay zones this study also highlights the role of the nature and thickness of the uppermost layer lava flow thin or thick grassy soil with respect to the type and length of fractures at the surface our mapping reveals complex fault geometry which however is consistent with the general left lateral transform behaviour of the south iceland seismic zone some left lateral conjugate fault branches are present along these major right lateral faults and participate to the deformation the estimation of the strike slip offsets 1 3 2 m based on the analysis of push up structures allow to infer the total rupture lengths 45 70 km for these faults and to estimate the magnitudes 7 0 7 2 of the related earthquakes bringing confirmation that events significantly larger than those of june 2000 ms 6 6 have occurred in the sisz which plays an important role for the seismic hazard assessment

speculations on the geometry of the initiation and termination processes of earthquake rupture and its relation to morphology and geological structure earthquake initiation and termination processes are commonly described in terms of barriers and asperities barriers fall into two classes geometric barriers are associated with places where the orientation of a failure surface changes and relaxation barriers where stress is low because aseismic creep processes outpace tectonic loading geometric barriers fall into conservative and nonconservative subgroups according to whether finite fault motion can proceed without the creation of new structures or whether it demands the creation of new faulting or void space the multiple faulting or fragmentation associated with some nonconservative barriers can disrupt fault planes and form asperities by means of selected examples it is shown that a description in terms of these barriers can help one to visualise the processes of earthquake rupture and its relation to the geological environment

explosive volcanic eruptions on mercury eruption conditions magma volatile content and implications for interior volatile abundances images obtained by the messenger spacecraft have revealed evidence for pyroclastic volcanism on mercury because of the importance of this inference for understanding the interior volatile inventory of mercury we focus on one of the best examples determined to date a shield volcano like feature just inside the southwestern rim of the caloris impact basin characterized by a near central irregularly shaped depression surrounded by a bright deposit interpreted to have a pyroclastic origin this candidate pyroclastic deposit has a mean radius of 24 km greater in size than the third largest lunar pyroclastic deposit when scaled to lunar gravity conditions from the extent of the candidate pyroclastic deposit we characterize the eruption parameters of the event that emplaced it including vent speed and candidate volatile content the minimum vent speed is 300 m s and the volatile content required to emplace the pyroclasts to this distance is hundreds to several thousands of parts per million ppm of the volatiles typically associated with pyroclastic eruptions on other bodies e g co co2 h2o so2 h2s for comparison measurements of the exsolution of volatiles h2o co2 s from basaltic eruptive episodes at kilauea volcano hawaii indicate values of 1300 6500 ppm for the terrestrial mantle source evidence for the presence of significant amounts of volatiles in partial melts derived from the interior of mercury is an unexpected result and provides a new constraint on models for the planet s formation and early evolution

metal partitioning in acid hypersaline sediments lake tyrrell victoria australia abstract oxic metal rich low ph groundwater enters a playa lake system at lake tyrrell partitioning of metals in the playa sediments was studied to determine the fate of the dissolved metals analysis of leachates from sequential extractions of sediment within the top 70 cm of the lake floor indicates that most of the cu pb zn fe and mn are adsorbed onto feoxides cu and to a lesser extent mn are bound to organics or sulfides in discrete thin layers while pb is deposited on exchangeable sites in upper layers possibly as sulfates metal concentrations are not enriched in the sediments which may be due to low ph s and or limited sulfate reduction in the system the lake tyrrell system may represent an ore forming system before extensive precipitation of metal sulfides

radar investigation of mars mercury and titan radar astronomy is the study of the surfaces and near surfaces of solar system objects using active transmission of modulated radio waves and the detection of the reflected energy the scientific goals of such experiments are surprisingly broad and include the study of surface slopes fault lines craters mountain ranges and other morphological structures electrical reflectivities contain information about surface densities and to some extent the chemical composition of the surface layers radar probes the subsurface layers to depths of the order of 10 wavelengths providing geological mapping and determinations of the object s spin state radar also allows one to study an object s atmosphere and ionic layers as well as those of the interplanetary medium precise measurements of the time delay to surface elements provide topographic maps and powerful information on planetary motions and tests of gravitational theories such as general relativity in this paper we limit our discussion to surface and near surface probing of mercury mars and titan and review the work of the past decade which includes fundamentally new techniques for earth based imaging the most primitive experiments involve just the measurement of the total echo power from the object the most sophisticated experiments would produce spatially resolved maps of the reflected power in all four stokes parameters historically the first experiments produced echoes from the moon during the period shortly after world war ii see e g evans 1962 but the subject did not really develop until the early 1960s when the radio equipment was sufficiently sensitive to detect echoes from venus and obtain the first doppler strip maps of that planet the first successful planetary radar systems were the continuous wave cw radar at the goldstone facility of the caltech s jet propulsion laboratory and the pulse radar at the mit lincoln laboratory all of the terrestrial planets were successfully studied during the following decade yielding the spin states of venus and mercury a precise value of the astronomical unit and a host of totally new discoveries concerning the surfaces of the terrestrial planets and the moon this work opened up at least a similar number of new questions although the early work was done at resolution scales on the order of the planetary radii very rapid increases in system sensitivities improved the resolution to the order of 100 km but always with map ambiguities recently unambiguous resolution of 100 m over nearly the entire surface of venus has been achieved from the magellan spacecraft using a side looking synthetic aperture radar reviews of the work up to the magellan era can be found in evans 1962 muhleman et al 1965 evans hagfors 1968 see chapters written by g pettengill t hagfors and j evans and ostro 1993 the radar study of venus from the magellan spacecraft was a tour de force and is well described in special issues of science volume 252 april 12 1991 and in the journal of geophysical research volume 97 august 25 and october 25 1992 venus will not be considered in this paper even though important polarization work on that planet continues at arecibo goldstone and the very large array vla in this paper we review the most recent work in earth based radar astronomy using new techniques of earth rotation super synthesis at the vla in new mexico operated by the national radio astronomy observatory and the recently developed long code techniques at the arecibo observatory in puerto rico operated by cornell university note it was recently brought to our attention that the vla software doubles the flux density of their primary calibrators consequently it is necessary to half the radar power and reflectivity numerical values in all of our published radar results from the vla goldstone radar the symbiotic relationship in these new developments for recent advances in our understanding of mercury and mars is remarkable vla imaging provides for the first time unambiguous images of an entire hemisphere of a planet and the long code technique makes it possible to map mars and mercury using the traditional range gated doppler strip mapping procedure which was apparently developed theoretically at the lincoln laboratory by paul green based on a citation in evans 1962 richard goldstein was the first to obtain range gated planetary maps of venus as reported in carpenter goldstein 1963 such a system was developed earlier for the moon as reported by pettengill 1960 and pettengill henry 1962 we first discuss the synthesis mapping technique

mercurian impact craters implications for polar ground ice abstract recent radar observations of mercury have detected strong depolarized echoes from the north and south polar regions which have been interpreted by some as ice deposits in the floors of permanently shadowed impact craters we have used the experience from mars where subsurface ice lowers the depth to diameter ratio d d of impact craters to test for subsurface ice deposits on mercury this analysis determines the d d ratios for 170 impact craters in the borealis north polar tolstoj equatorial kuiper equatorial and bach south polar quadrangles of the planet possible effects from sun angle and terrain were eliminated to test whether d d differences could be detected at mariner 10 resolutions 1 km pixel we perform a similar analysis using mariner 9 images of mars which have similar resolutions we demonstrate that d d differences due to terrain softening can be detected between craters in the martian polar regions and the equatorial regions at the mariner 9 resolutions although our initial results indicate that the south polar bach quadrangle has a statistically lower d d than the north polar borealis or two equatorial tolstoj and kuiper quadrangles further investigation reveals that this finding is most likely the result of the filtering which was applied to the images of the bach quadrangle by jpl thus no unequivocal evidence exists that the possible ice deposits in craters at mercury s north and south poles are the exposed portions of more extensive subsurface ice caps combined with the temporal constraint imposed by the fact that the proposed ice deposits are found only in usgs class 4 craters this suggests a large rapidly emplaced exogenic source of water to mercury during the mansurian period we suggest that the source was multiple impacts from a fragmented comet or a comet shower

deposition of trace elements and radionuclides in the spring zone lake tyrrell victoria australia acidic saline groundwaters in the region of lake tyrrell carry unusually high concentrations of trace metals but the brines of lake tyrrell do not have the concentrations that would be generated by evaporation of those groundwaters this study investigated the fate of trace metals and radionuclides in the groundwater evaporation lake system six shallow cores collected across the spring zone on the western shore of lake tyrrell northwest victoria where groundwater enters the lake were studied the area chosen has anomalously high surface radioactivity only minor deposition of many major and trace elements is apparently occurring in the sediments most deposition is confined to the upper 15 cm of the sediments and for the trace elements concentrations were quite low x ray diffraction identified a thin band of alunite at 4 8 cm depth which is found to be enriched with cr sc ti la y zr sr ba p and mn by factors up to 10 over surrounding sediments cu and fe are the only metals enriched below 15 cm 226ra the source of the anomalous radioactivity is also enriched within the alunite band in addition auto radiography of an fe oxide with akaganeite jarosite layered sample identified jarosite as another mineral phase that sequesters ra analyses of radionuclides such as 210pb and 228ra with short 25 yr half lives in the sediments suggest that the deposition of radionuclides at lake tyrrell has occurred within a 100 yr time span a 14c measurement of organic mud in the center of the zone with cu enrichment confirmed its recent origin

mars radar mapping strong backscatter from the elysium basin and outflow channel abstract radar reflectivity maps of mars obtained at arecibo in 1990 using a modified delay doppler technique have revealed strong depolarized echoes coming from the elysium flood basin and outflow channel as well as from elysium mons this result is consistent with recent studies which show that much of the basin channel floor is covered with lava flows

new empirical relationships among magnitude rupture length rupture width rupture area and surface displacement source parameters for historical earthquakes worldwide are compiled to develop a series of empirical relationships among moment magnitude m surface rupture length subsurface rupture length downdip rupture width rupture area and maximum and average displacement per event the resulting data base is a significant update of previous compilations and includes the additional source parameters of seismic moment moment magnitude subsurface rupture length downdip rupture width and average surface displacement each source parameter is classified as reliable or unreliable based on our evaluation of the accuracy of individual values only the reliable source parameters are used in the final analyses in comparing source parameters we note the following trends 1 generally the length of rupture at the surface is equal to 75 of the subsurface rupture length however the ratio of surface rupture length to subsurface rupture length increases with magnitude 2 the average surface displacement per event is about one half the maximum surface displacement per event and 3 the average subsurface displacement on the fault plane is less than the maximum surface displacement but more than the average surface displacement thus for most earthquakes in this data base slip on the fault plane at seismogenic depths is manifested by similar displacements at the surface log linear regressions between earthquake magnitude and surface rupture length subsurface rupture length and rupture area are especially well correlated showing standard deviations of 0 25 to 0 35 magnitude units most relationships are not statistically different at a 95 significance level as a function of the style of faulting thus we consider the regressions for all slip types to be appropriate for most applications regressions between magnitude and displacement magnitude and rupture width and between displacement and rupture length are less well correlated and have larger standard deviation than regressions between magnitude and length or area the large number of data points in most of these regressions and their statistical stability suggest that they are unlikely to change significantly in response to additional data separating the data according to extensional and compressional tectonic environments neither provides statistically different results nor improves the statistical significance of the regressions regressions for cases in which earthquake magnitude is either the independent or the dependent parameter can be used to estimate maximum earthquake magnitudes both for surface faults and for subsurface seismic sources such as blind faults and to estimate the expected surface displacement along a fault for a given size earthquake

mercury the enigmatic innermost planet abstract the planet mercury a difficult object for study by astronomical observation and spacecraft exploration alike poses multiple challenges to our general understanding of the inner planets mercury s anomalously high uncompressed density implies a metal fraction of 60 or more by mass an extreme outcome of planetary formational processes common to the inner solar system whether that outcome was the result of chemical gradients in the early solar nebula or removal by impact or vaporization of most of the silicate shell from a differentiated protoplanet can potentially be distinguished on the basis of the chemical composition of the present crust our understanding of the geological evolution of mercury and how it fits within the known histories of the other terrestrial planets is restricted by the limited coverage and resolution of imaging by the only spacecraft to have visited the planet the role of volcanism in mercury s geological history remains uncertain and the dominant tectonic structures are lobate scarps interpreted as recording an extended episode of planetary contraction issues that require global imaging to be fully examined that mercury has retained a global magnetic field when larger terrestrial planets have not stretches the limits of standard hydromagnetic dynamo theory and has led to proposals for a fossil field or for exotic dynamo scenarios hypotheses for field generation can be distinguished on the basis of the geometry of mercury s internal field and the existence and size of a fluid outer core on mercury can be ascertained from measurements of the planet s spin axis orientation and gravity field and the amplitude of mercury s forced librations the nature of mercury s polar deposits suggested to consist of volatile material cold trapped on the permanently shadowed floors of high latitude impact craters can be tested by remote sensing of the composition of mercury s surface and polar atmosphere the extremely dynamic exosphere which includes a number of species derived from mercury s surface offers a novel laboratory for exploring the nature of the complex and changing interactions among the solar wind a small magnetosphere and a solid planet recent ground based astronomical measurements and several new theoretical developments set the stage for the in depth exploration of mercury by two spacecraft missions within the coming decade

radar measurements of mercury s north pole at 70 cm wavelength abstract we present radar imaging of mercury using the arecibo observatory s 70 cm wavelength radar system during the inferior conjunction of july 1999 at that time the sub earth latitude was 11 n and the highly reflective region at mercury s north pole that was first identified in radar images at the shorter wavelengths of 3 6 cm slade m a butler b j muhleman d o 1992 science 258 635 640 and 13 cm harmon j k slade m a 1992 science 258 640 643 was again clearly detected the reflectivity averaged over a 75 000 km2 region including the pole is similar to that measured at the other wavelengths over a comparable area and the 70 cm circular polarization ratio of c 0 87 is possibly slightly lower if this strong backscattering results from volume scattering in low absorption layers the persistence of this effect over more than an order of magnitude change in wavelength scale has implications for the depth and thickness of the deposits responsible the resolution of the radar maps at this wavelength is not sufficient to resolve individual craters nor to discern features at other latitudes but the planet s total reflectivity is consistent with previous work and the scattering function suggests a surface roughness at this wavelength similar to the lunar highlands

complex geometry and segmentation of the surface rupture associated with the 14 november 2001 great kunlun earthquake northern tibet china abstract the 14 november 2001 kunlun china earthquake with a moment magnitude m w 7 8 occurred along the kusai lake kunlun pass fault of the kunlun fault system we document the spatial distribution and geometry of surface rupture zone produced by this earthquake based on high resolution satellite landsat etm aster spot and ikonos images combined with field measurements our results show that the surface rupture zone can be divided into five segments according to the geometry of surface rupture including the sun lake buka daban hongshui river kusai lake hubei peak and kunlun pass segments from west to east these segments each 55 to 130 km long are separated by step overs the sun lake segment extends about 65 km with a strike of n45 75 w between 90 05 e 90 50 e along the previously unrecognized west sun lake fault a gap of about 30 km long exists between the sun lake and buka daban peak where no obvious surface ruptures can be observed either from the satellite images or field observations the buka daban hongshui river kusai lake hubei peak and kunlun pass segments run about 365 km striking n75 85 w along the southern slope of the kunlun mountains between 91 07 e 94 58 e this segmentation of the surface rupture is well correlated with the pattern of slip distribution measured in the field detailed mapping suggest that these five first order segments can be further separated into over 20 second order segments with a length of 10 30 km linked by smaller scale step overs or bends our result also shows that the total coseismic surface rupture length produced by the 2001 kunlun earthquake is about 430 km excluding the 30 km long gap which is the longest coseismic surface rupture for an intracontinental earthquake ever recorded finally we suggest a multiple bilateral rupture propagation model that shows the rupture process of the 2001 m w 7 8 earthquake is complex it consists of westward and eastward rupture propagations and interaction of these bilateral rupture processes

mars mapping with delay doppler radar mars radar imaging results from arecibo 12 6 cm observations are presented the images were derived from delay doppler mapping using a coded long pulse technique to mitigate the effects of echo overspreading images of the depolarized echo are used to identify regions of high decimeter scale roughness some of the strongest echo features are located on the major shield volcanoes or on relatively young off shield flows such as the olympus and pavonis lava aprons the shields themselves have highly irregular radar signatures suggesting complex volcanic histories some mars radar features have twice the depolarized brightness of the roughest terrestrial lava flows apparently due to higher levels of multiple scattering from surfaces of spectacular roughness or from volume scattering low brightness smooth areas are associated with older surfaces such as fractured and highland terra as well as with terrain interpreted to be debris lobes ash flows and aureoles in particular a close connection was found between the 12 6 cm counterpart of the stealth feature and the medusae fossae formation postulated to be deep ignimbrite deposits marte valus is anomalous in being the only outflow channel showing strongly enhanced echoes which supports the idea that this channel and the elysium basin that it drained are filled with lava flows a weak radar feature was found for the south polar residual ice cap comparisons with goldstone 3 5 cm data show that the south polar enhancement is much weaker at 12 6 cm than at 3 5 cm indicating that the southern ice cap becomes optically thin at the longer wavelength a north polar enhancement has also been found which is comparable in strength to the 12 6 cm south polar feature

glaciation on mercury accumulation and flow of ice in permanently shadowed circum polar crater interiors abstract radar bright deposits that coincide with regions in permanent shadow typically found within impact craters at and near the poles of mercury have been interpreted as being composed of water ice we investigate the dynamic properties of these solid water ice deposits glaciers with the goal of constraining their movement flow rates possible deformation and related structures and deposits as an end member we treat the extreme case of maximum ice accumulation where these deposits fill the crater to the shadow line an event we would only expect following maximum accumulation conditions such as a large cometary impact or a comet shower we find that given the extremely cold conditions and the limited thickness of glaciers even under the most favorable accumulation conditions glaciation is cold based ice flow velocities are very low 4 10 8 m yr and with the exception of a sublimation lag deposit glaciation is unlikely to leave any significant impact on the terrain an important accelerator of ice flow is found to be the contribution of lateral heat conduction from the surrounding extremely hot surface terrain 225 k average with up to 450 k maximums which for 55 km craters yields velocities of 10 3 m yr while for smaller 10 km craters velocities may exceed 1 m yr enough to leave a detectable ice deformation imprint such as drop moraines however given that the observed deposits are substantially below their maximum fill capacities these estimates are unlikely to be attained

how thick are mercury s polar water ice deposits an estimate is made of the thickness of the radar bright deposits in craters near to mercury s north pole to construct an objective set of craters for this measurement an automated crater finding algorithm is developed and applied to a digital elevation model based on data from the mercury laser altimeter onboard the messenger spacecraft this produces a catalogue of 663 craters with diameters exceeding 4 km northwards of latitude 55 a subset of 12 larger well sampled and fresh polar craters are selected to search for correlations between topography and radar same sense backscatter cross section it is found that the typical excess height associated with the radar bright regions within these fresh polar craters is 50 35 m this puts an approximate upper limit on the total polar water ice deposits on mercury of 3 1015 kg

trace metal concentrations in modern marine sabkhas abstract trace metal data from a number of hydrologically different types of modern marine sabkhas are presented indicating that these environments do not have elevated trace metal concentrations compared to recent near shore marine sediments and therefore are not active loci of trace metal enrichment today

europa s crust and ocean origin composition and the prospects for life abstract we have considered a wide array of scenarios for europa s chemical evolution in an attempt to explain the presence of ice and hydrated materials on its surface and to understand the physical and chemical nature of any ocean that may lie below we postulate that following formation of the jovian system the europan evolutionary sequence has as its major links a initial carbonaceous chondrite rock b global primordial aqueous differentiation and formation of an impure primordial hydrous crust c brine evolution and intracrustal differentiation d degassing of europa s mantle and gas venting e hydrothermal processes and f chemical surface alteration our models were developed in the context of constraints provided by galileo imaging near infrared reflectance spectroscopy and gravity and magnetometer data low temperature aqueous differentiation from a carbonaceous ci or cm chondrite precursor without further chemical processing would result in a crust ocean enriched in magnesium sulfate and sodium sulfate consistent with galileo spectroscopy within the bounds of this simple model a wide range of possible layered structures may result the final state depends on the details of intracrustal differentiation devolatilization of the rocky mantle and hydrothermal brine reactions could have produced very different ocean crust compositions e g an ocean crust of sodium carbonate or sulfuric acid or a crust containing abundant clathrate hydrates realistic chemical physical evolution scenarios differ greatly in detailed predictions but they generally call for a highly impure and chemically layered crust some of these models could lead also to lateral chemical heterogeneities by diapiric upwellings and or cryovolcanism we describe some plausible geological consequences of the physical chemical structures predicted from these scenarios these predicted consequences and observed aspects of europa s geology may serve as a basis for further analys is and discrimination among several alternative scenarios most chemical pathways could support viable ecosystems based on analogy with the metabolic and physiological versatility of terrestrial microorganisms

high resolution radar imaging of mercury s north pole abstract the recently upgraded arecibo s band 12 6 cm radar was used to make delay doppler images of mercury s north polar region where earlier observations had shown strong echoes from putative ice deposits in craters the image resolution of 1 5 3 km is a substantial improvement over the 15 km resolution of the older arecibo images j k harmon et al 1994 nature 369 213 215 the new observations confirm all the original polar features and reveal many additional features including several at latitudes as low as 72 75 n and several from craters less than 10 km in diameter all of the new features located on the mariner imaged side of the planet can be matched with known craters or other shaded areas we find the north pole to be located 65 km from the original mariner based pole and 15 km from the new mariner based pole of m s robinson et al 1999 j geophys res 104 30 847 30 852 the improved resolution reveals fine structure in the radar features and their respective host craters including radar shadowing highlighting by central peaks and rim walls rim terracing and preferential concentration of radar bright deposits in shaded southern floor areas the radar features high brightness circular polarization inversion c 1 25 and confinement to regions permanently shaded from direct sunlight are all consistent with volume scattering from a cold trapped volatile such as clean water ice the sizes and locations of most of the features show good agreement with the thermal model of a r vasavada d a paige and s e wood 1999 icarus 141 179 193 for insulated buried water ice although the problems of explaining radar features in small craters and the rapid burial required at lower latitudes suggest that other factors may be suppressing ice loss after emplacement

burial rate of mercury s polar volatile deposits 1 delay doppler images of mercury s polar regions showing enhanced radar backscatter have been interpreted as evidence for water ice in the polar craters and are consistent with pure water ice covered by about 20 cm of regolith in this paper we assume that the volatile at the hermean poles is water ice and that it was initially deposited at one time in a clean layer we constrain the time of such an impact by determining the rate of regolith emplacement the rate of burial of ice deposits in polar craters on mercury is estimated to be 0 43 cm myr if the ice deposits in hermean polar craters are both clean and buried by 20 cm of regolith they must be relatively recently emplaced 50 myr ago the predicted h concentration in the uppermost meter of regolith is calculated as a function of both time since emplacement of the ice and initial thickness of the ice layer the combination of neutron data and radar data can provide additional insight into the size and age of ice deposits at mercury

circular polarization radar properties of high altitude ice western kunlun shan and central andes full polarization synthetic aperture radar images of high altitude glaciers and ice fields in the western kunlun shan of tibet and the central andes near santiago chile made with the shuttle imaging radar display regions with circular polarization ratios c in excess of unity the mountainous topography at both locales allows reconstruction of the angular scattering behavior the behavior is very similar to that displayed by greenland s percolation zone glaciologic evidence from the tibetan site confirms ice pipes and lenses embedded in the firn which have been identified as the scatterers producing c 1 in greenland this demonstrates that the cold snow percolation facies radar signature exists outside of greenland the greenland radar behavior had been suggested as an analogue for that of the icy galilean satellites we like previous workers find that the near nadir backscatter is too specular to be considered analogous to that of the jovian moons we also present a crevasse region in tibet that exhibits c 1 and a possible detection of the ice substrate of a rock covered glacier in the andes

the trace metal geochemistry of the lake tyrrell system brines victoria australia abstract we have analyzed the waters of the lake tyrrell system for the trace metals fe mn pb cu and zn in a number of samples both dissolved fe t and fe 2 were also determined great care was exercized to minimize any contamination of the samples not surprisingly the highest metal concentrations occur in the low ph high eh regional groundwaters with much lower values observed in the reflux brines and the neutral wahpool timboram waters it is thought that the source of these metals to the groundwaters is the dissolution of a suite of heavy minerals within the aquifer the pliocene parilla sand as the acid groundwaters flow toward the lake some metals are removed near lake edge at depth the metal concentrations in the spring zone region indicate an extremely dynamic system where at different times of the year due to changes in the hydrologic regime metals can be either removed or solubilized

constraining the thickness of polar ice deposits on mercury using the mercury laser altimeter and small craters in permanently shadowed regions abstract radar bright deposits at the poles of mercury are located in permanently shadowed regions which provide thermally stable environments for hosting and retaining water ice on the surface or in the near subsurface for geologic timescales while the areal distribution of these radar bright deposits is well characterized their thickness and thus their total mass and volume remain poorly constrained here we derive thickness estimates for selected water ice deposits using small simple craters visible within the permanently shadowed radar bright deposits we examine two endmember scenarios in case i these craters predate the emplacement of the ice and in case ii these craters postdate the emplacement of the ice in case i we find the difference between estimated depths of the original unfilled craters and the measured depths of the craters to find the estimated infill of material the average estimated infilled material for 9 craters assumed to be overlain with water ice is 41 14 30 m where 1 standard error of the mean is reported as uncertainty reported uncertainties are for statistical errors only additional systematic uncertainty may stem from georeferencing the images and topographic datasets from the radial accuracy of the altimeter measurements or from assumptions in our models including 1 ice is flat in the bowl shaped crater and 2 there is negligible ice at the crater rims in case ii we derive crater excavation depths to investigate the thickness of the ice layer that may have been penetrated by the impact while the absence of excavated regolith associated with the small craters observed suggests that impacts generally do not penetrate through the ice deposit the spatial resolution and complex illumination geometry of images may limit the observations therefore it is not possible to conclude whether the small craters in this study penetrate through the ice deposit and thus case ii does not provide a constraint on the ice thickness for mercury s polar deposits we argue that case i of the small craters predating the emplacement of the ice deposits is more likely given other geologic evidence that suggests that these ice deposits are relatively young using the ice thickness estimates from case i to calculate the total amount of water ice currently contained in mercury s polar deposits results in a value of 10 14 10 15 kg this is equivalent to 100 1000 km 3 ice in volume this volume of water ice is consistent with delivery via micrometeorite bombardment jupiter family comets or potentially a single impactor

a stable isotope investigation of groundwater surface water interactions at lake tyrrell victoria australia herczeg a l barnes c j macumber p g and olley j m 1992 a stable isotope investigation of groundwater surface water interactions at lake tyrrell victoria australia in w b lyons d t long a l herczeg and m e hines guesteditors the geochemistry of acid groundwater systems chem geol 96 19 32 the stable isotope composition of regional groundwaters around lake tyrrell victoria indicates that the groundwaters are derived entirely from meteoric water that has undergone some degree of evaporation during recharge seepage waters at the western margin of lake tyrrell victoria have a characteristic chemical and isotopic signature of regional groundwater flowing from the northeast and east on a transect of shallow groundwaters across the lake the isotopic composition is increasingly enriched in the heavy isotopes toward the centre of the lake but define a steeper slope on a dd djso plot than that of the regional groundwaters the stable isotopic compositions of the shallow groundwaters within the seepage zone are typical of those due to evaporative enrichment currently occurring with a small component of vertical mixing with the deeper reflux brines reflux brines below the lake are relatively more enriched in tso than the brines forming now at the lake surface the reflux brines appear to have undergone several cycles of evaporation and admixture of regional groundwater as have waters within the mixing zone between regional groundwater and reflux brines

geochemistry and speciation of metals in sediments of the maharlu saline lake shiraz sw iran in this study the total concentration and speciation of trace elements as cr cu cd pb zn and ni in sediments of the maharlu saline lake sw iran are investigated comparison with sediment quality guidelines calculation of the enrichment factors and trace metal profiles in the khoshk river inflow point indicate that maharlu lake is in the threat of contamination especially with respect to ni and cd sequential extraction analysis reveals that elemental speciation in this lake is strongly affected by oxidizing condition of the lake water the studied elements except cr are mainly associated with oxide phases as a result of prevailing oxidizing conditions of the lake and also probably due to the source of elements the ratio of metals in mobile fractions to sum of fractions in lake sediments is very low however metal ratios except for cr in mobile fractions are much higher in surface sediments indicating the impact of anthropogenic loading of trace metals in the recent years

influence of hydrogeology microbiology and landscape history on the geochemistry of acid hypersaline waters n w victoria abstract there is now evidence that naturally occurring acid water is more abundant than previously thought and that it has been important in the geologic past understanding the processes leading to the formation of such systems is required to appreciate the role of acid systems in geologic processes and to develop indicators for recognizing the geologic environmental importance of these systems in the past this paper characterizes the hydrogeology hydrogeochemistry microbial biogeochemistry and landscape attributes of acid groundwater surface water systems in australia with an emphasis on a well studied playa lake system lake tyrrell murray valley a model for the origin of these acid brines is presented and the importance of acid brine producing systems is speculated upon data include porewater and groundwater geochemical measurements collected during a 10 day field campaign and results from geochemical modeling and graphics e g piper diagrams and x y plots of seawater evaporation trajectories key characteristics of the system are 1 aquifer materials have low acid buffering capacities 2 saline groundwater flowing onto playa surfaces is an oxic h2so4 solution 3 authigenic minerals include combinations of jarosite kfe3 so4 2 oh 6 alunite kal3 so4 2 oh 6 and fe oxides that can form as evaporite minerals 4 a source for solutes can be marine aerosols and 5 the formation of ironstones groundwater acidification by various processes including sulfide oxidation and ferrolysis and at many different times are the unique aspects for evolution of these acid brines and they can be considered another end member of the eugster jones hardie model for the evolution of brines in closed basins acid hypersaline groundwater and playa systems such as lake tyrrell may be an example of expected changes in the hydrogeochemistry of terrestrial water during late stage continental denudation under arid conditions historically these systems may have been integral to the formation of opal bauxite some low temperature ore deposits of authigenic k feldspars and continental redbeds natural acid saline systems such as those in australia may also be representative of acid saline systems on mars

new images of mercury s surface from 210 to 290 w longitudes with implications for mercury s global asymmetry abstract ground based images of mercury in the sector 210 to 290 w 70 to 150 e longitude a region not imaged by mariner 10 show many impact craters and at least two large basins a millisecond exposure method was used at the abastumany and skinakas observatories under good atmospheric conditions enough images were obtained that when stacked increased the signal to noise ratio and gave rise to resolution that shows unprecedented detail of surface albedo and physical features we discuss images of a double rimmed basin whose inner portion extends 1000 km across with a total dimension of the outer eroded rim slightly more than 2000 km extending over 245 to 305 w 55 to 115 e longitude and from 40 n to 20 s this basin includes and extends west and north of the dark albedo feature known as solitudo criophori and was unofficially called skinakas after the observatory from which it was first imaged in this manuscript we call the feature basin s the inner basin extends from 263 to 287 w 73 to 97 e and from about 30 n to 5 s some regions within the basin have eroded circular rims that lack rayed structure or evidence of ejecta material these images also show large basins unusual clusters of circular rimmed features and darker albedo material between 210 and 330 w 30 to 150 e longitude implications of the huge basin for the geophysics of mercury are discussed many well defined impact craters have also been imaged an attempt has been made to restore information about relief of the 210 to 290 w 70 to 150 e longitude sector in addition regions on the order of 10 of latitude and 10 of longitude have been examined and reveal rayed craters in comparable detail to the arecibo radar imaging images at the same location where radar backscatter has indicated infilling of craters by volatiles or some other highly coherent backscattering material are also shown

radar images of mars full disk images of mars have been obtained with the use of the very large array vla to map the radar reflected flux density the transmitter system was the 70 m antenna of the deep space network at goldstone california the surface of mars was illuminated with continuous wave radiation at a wavelength of 3 5 cm the reflected energy was mapped in individual 12 minute snapshots with the vla in its largest configuration fringe spacings as small as 67 km were obtained the images reveal near surface features including a region in the tharsis volcano area over 2000 km in east west extent that displayed no echo to the very low level of the radar system noise the feature called stealth is interpreted as a deposit of dust or ash with a density less than about 0 5 gram per cubic centimeter and free of rocks larger than 1 cm across the deposit must be several meters thick and may be much deeper the strongest reflecting geological feature was the south polar ice cap which was reduced in size to the residual south polar ice cap at the season of observation the cap image is interpreted as arising from nearly pure co 2 or h 2o ice with a small amount of martian dust less than 2 percent by volume and a depth greater than 2 to 5 m only one anomalous reflecting feature was identified outside of the tharsis region although the elysium region was poorly sampled in this experiment and the north pole was not visible from earth

circular polarization ratio characteristics of impact craters from mini rf observations and implications for ice detection at the polar regions of the moon 1 in an attempt to reduce the ambiguity on radar detection of water ice at the permanently shadowed regions near the lunar poles radar echo strength and circular polarization ratio cpr of impact craters are analyzed using the miniature radio frequency mini rf radar data from the lunar reconnaissance orbiter mission eight typical craters among over 70 craters are selected and classified into four categories based on their locations and cpr characteristics polar anomalous polar fresh nonpolar anomalous and nonpolar fresh the influences on cpr caused by surface slope rocks and dielectric constant are analyzed quantitatively using high resolution topography data and optical images a two component mixed model for cpr that consists of a normal surface and a rocky surface is developed to study the effect of rocks that are perched on lunar surface and buried in regolith our analyses show that inner wall of a typical bowl shaped crater can give rise to a change of about 30 in local incidence angle of radar wave which can further result in a cpr difference of about 0 2 there is a strong correlation between mini rf cpr and rock abundance that is obtained from high resolution optical images and predictions from the two component mixed model match well with the observed cprs and the estimated rock abundances statistical results show that there is almost no apparent difference in cpr characteristics between the polar and nonpolar anomalous craters or between the polar and nonpolar fresh craters the enhanced cpr in the interior of anomalous craters is most probably caused by rocks that are perched on lunar surface or buried in regolith instead of ice deposits as suggested in previous studies

radar mapping of mercury full disk images and polar anomalies a random code technique has been used at arecibo to obtain delay doppler radar images of the full disk of mercury anomalously bright features were found at the north and south poles the north polar feature is oblong 4 by 8 and offset from the pole the smaller south polar feature is mostly confined to the floor of the crater chao meng fu the polar locations and radar properties of these features indicate that they may be produced by volume scattering in ice the images also reveal a variety of more subdued reflectivity features ranging in size from hundreds to thousands of kilometers some of these appear to have an impact origin

near surface temperatures on mercury and the moon and the stability of polar ice deposits abstract in order to assess the thermal stability of polar ice deposits we present model calculated temperatures of flat surfaces and surfaces within bowl shaped and flat floored polar impact craters on mercury and the moon our model includes appropriate insolation cycles realistic crater shapes multiple scattering of sunlight and infrared radiation and depth and temperature dependent regolith thermophysical properties unshaded water ice deposits on the surface of either body are rapidly lost to thermal sublimation a subsurface water ice deposit is stable within 2 latitude of the moon s poles meter thick water ice deposits require billions of years to sublime if located in the permanently shaded portions of flat floored craters within 10 latitude of the poles of mercury and 13 latitude of the poles of the moon results for craters associated with radar features on mercury are consistent with the presence of stable water ice deposits if a thin regolith layer thermally insulates deposits at lower latitudes and within smaller craters a regolith cover would also reduce losses from diffusion ion sputtering impact vaporization and h ly and is implied independently by the radar observations permanently shaded areas near the moon s poles are generally colder than those near mercury s poles but the moon s obliquity history its orbit through earth s magnetospheric tail and its radar opaque regolith may limit the volume and radar detectability of ice deposits there

backscatter model for the unusual radar properties of the greenland ice sheet a number of planetary objects exhibit large radar reflectivity and polarization ratios and more recently a similar behavior has been observed over a vast portion of the earth s surface the percolation facies of the greenland ice sheet surface based ranging radar data and snow stratigraphy studies demonstrated that the radar properties of that portion of greenland are caused by enhanced scattering from massive large solid ice bodies buried in the top few meters of the dry cold clean snowy surface of the ice sheet and created by seasonal melting and refreezing events from author

topography of the lunar south polar region implications for the size and location of permanently shaded areas we analyze clementine altimetry to constrain the size and location of proposed permanently shadowed regions in the vicinity of the lunar south pole long and short wavelength topography in the vicinity of the pole in combination with measurements of depths of well preserved craters and basins and the lunar topographic power spectrum have direct bearing on the nature of elevations in the south polar region a criterion based on geometric considerations and altimetry demonstrates that the existence of permanent shadowing is not very sensitive to the elevation of the south pole in addition permanent shadowing cannot be a consequence of large structures such as the south pole aitken basin and or a 300 km degraded polar basin perennially dark regions if they exist are most likely associated with craters or other axisymmetric features with diameters of at most 80 km centered at the pole for structures displaced 2 from the pole the maximum allowable diameter decreases to 30 km

no evidence for thick deposits of ice at the lunar south pole the rim of the shackleton crater at the lunar south pole is a candidate crash site for nasa s lcross probe lunar crater observation and sensing satellite due to launch in 2008 the plume of debris kicked up by the crash is to be analysed in the hope that it will reveal the water thought to be there suggestions of lunar ice date from 1996 when data from the clementine spacecraft gave some indications of the presence of ice on crater walls at the south pole now using high resolution radar imagery the radar scattering parameter thought indicative of thick ice deposits has been found also to match radar echoes from the rock strewn walls and ejecta of young impact craters at all lunar latitudes there is no evidence for thick ice though there could be grains of water ice spread more thinly through the lunar soil shackleton crater at the moon s south pole has been suggested as a possible site of concentrated deposits of water ice on the basis of modelling of bi static radar polarization properties and interpretations of earlier earth based radar images1 2 this suggestion and parallel assumptions about other topographic cold traps is a significant element in planning for future lunar landings hydrogen enhancements have been identified in the polar regions3 but these data do not identify the host species or its local distribution the earlier earth based radar data lack the resolution and coverage for detailed studies of the relationship between radar scattering properties cold traps in permanently shadowed areas and local terrain features such as the walls and ejecta of small craters here we present new 20 m resolution 13 cm wavelength radar images that show no evidence for concentrated deposits of water ice in shackleton crater or elsewhere at the south pole the polarization properties normally associated with reflections from icy surfaces in the solar system4 5 6 were found at all the observed latitudes and are strongly correlated with the rock strewn walls and ejecta of young craters including the inner wall of shackleton there is no correlation between the polarization properties and the degree of solar illumination if the hydrogen enhancement observed by the lunar prospector orbiter3 indicates the presence of water ice then our data are consistent with the ice being present only as disseminated grains in the lunar regolith

bistatic radar observations of the moon using mini rf on lro and the arecibo observatory the miniature radio frequency mini rf instrument aboard nasa s lunar reconnaissance orbiter lro is a hybrid dual polarized synthetic aperture radar sar that operated in concert with the arecibo observatory to collect bistatic radar data of the lunar nearside from 2012 to 2015 the purpose of this bistatic campaign was to characterize the radar scattering properties of the surface and near surface as a function of bistatic angle for a variety of lunar terrains and search for a coherent backscatter opposition effect indicative of the presence of water ice a variety of lunar terrain types were sampled over a range of incidence and bistatic angles including mare highland pyroclastic crater ejecta and crater floor materials responses consistent with an opposition effect were observed for the ejecta of several copernican aged craters and the floor of the south polar crater cabeus the responses of ejecta material varied by crater in a manner that suggests a relationship with crater age the response for cabeus was observed within the portion of its floor that is not in permanent shadow the character of the response differs from that of crater ejecta and appears unique with respect to all other lunar terrains observed analysis of data for this region suggests that the unique nature of the response may indicate the presence of near surface deposits of water ice

lunar cold traps effects of double shielding abstract this paper deals with the problem of water permanence on the surface of the moon possible zones where water ice can survive are called cold traps k watson b c murray and h brown 1961 j geophys res 66 3033 3045 these are zones of the moon permanently obscured where the temperatures are low enough to preserve ice for billions of years in this work we developed a model for the topographic temperatures of complex craters whose shape was approximated by a capsized frustum of a circular right cone double shaded areas were simulated by embedding a small hemispherical crater in the shadowed part of the previous one their temperatures were calculated using the r r hodges jr 1980 proc lunar planet sci conf 11th 2463 2477 model first we verified that our results were in agreement with those of previous models our results confirm those obtained by j r salvail and f p fanale 1994 icarus 111 441 445 and in agreement with hodges 1980 we found that the lowest temperatures are reached by tycho like craters that are the larger and shallower among the examined cases when small craters are embedded in the shaded area of larger ones their temperatures are low enough to preserve other volatiles like co 2 hodges 1980 in particular if we consider double shaded areas in biot like craters the temperatures are lower than 103 k in a shell of almost 20 around the poles thus allowing the preservation of ices for geometrical reasons a hemispherical crater embedded in the bottom of a biot like crater cold remain in the shadowed area for latitude values lower than those reached by an analogous crater embedded in sosigene or tycho like craters therefore the latitudinal radius of polar frost caps could be greater than that predicted by previous models that did not consider double shaded areas however double shielding occurs in only a fraction of the secondary craters therefore in this case eventual deposits of ice would be of smaller dimensions compared with the case of primary shielding analysis of the clementine radar data s nozette c l lichtenberg p spudis r bonner w ort e malaret m robinson and e m shoemaker 1996 science 274 5292 5300 and the lunar prospector neutron spectrometer data seems to be consistent with the presence of water ice in very low concentrations across a significant number of craters thus confirming the old hypothesis of watson et al 1961

images of surface volatiles in mercury s polar craters acquired by the messenger spacecraft images acquired by nasa s messenger spacecraft have revealed the morphology of frozen volatiles in mercury s permanently shadowed polar craters and provide insight into the mode of emplacement and evolution of the polar deposits the images show extensive spatially continuous regions with distinctive reflectance properties a site within prokofiev crater identified as containing widespread surface water ice exhibits a cratered texture that resembles the neighboring sunlit surface except for its uniformly higher reflectance indicating that the surficial ice was emplaced after formation of the underlying craters in areas where water ice is inferred to be present but covered by a thin layer of dark organic rich volatile material regions with uniformly lower reflectance extend to the edges of the shadowed areas and terminate with sharp boundaries the sharp boundaries indicate that the volatile deposits at mercury s poles are geologically young relative to the time scale for lateral mixing by impacts and either are restored at the surface through an ongoing process or were delivered to the planet recently

understanding the origin and evolution of water in the moon through lunar sample studies a paradigm shift has recently occurred in our knowledge and understanding of water in the lunar interior this has transpired principally through continued analysis of returned lunar samples using modern analytical instrumentation while these recent studies have undoubtedly measured indigenous water in lunar samples they have also highlighted our current limitations and some future challenges that need to be overcome in order to fully understand the origin distribution and evolution of water in the lunar interior another exciting recent development in the field of lunar science has been the unambiguous detection of water or water ice on the surface of the moon through instruments flown on a number of orbiting spacecraft missions considered together sample based studies and those from orbit strongly suggest that the moon is not an anhydrous planetary body as previously believed new observations and measurements support the possibility of a wet lunar interior and the presence of distinct reservoirs of water on the lunar surface furthermore an approach combining measurements of water abundance in lunar samples and its hydrogen isotopic composition has proved to be of vital importance to fingerprint and elucidate processes and source s involved in giving rise to the lunar water inventory a number of sources are likely to have contributed to the water inventory of the moon ranging from primordial water to meteorite derived water ice through to the water formed during the reaction of solar wind hydrogen with the lunar soil perhaps two of the most striking findings from these recent studies are the revelation that at least some portions of the lunar interior are as water rich as some mid ocean ridge basalt source regions on earth and that the water in the earth and the moon probably share a common origin

radar mapping of mercury s polar anomalies ground based radar observations of mercury have revealed unusually strong highly depolarized echoes from the north1 2 and south2 poles these anomalous echoes have been cited as evidence of polar ice deposits1 5 thermal studies3 5 suggest that the permanently shaded floors of large polar craters are cold enough to preserve water ice in a stable state over aeons in spite of mercury s proximity to the sun here we present high resolution radar maps of mercury s polar regions derived from delay doppler measurements we have resolved the north and south polar anomalies into numerous crater sized features and we have been able to identify the source craters for many of these features after making small corrections to the pole positions on the mariner 10 images the coincidence with crater locations together with other properties of the radar features are consistent with the polar ice hypothesis

polar hydrogen deposits on the moon neutron and gamma ray data measured using the lunar prospector spectrometers were analyzed to define the enhanced hydrogen deposits near both poles of the moon combining the new low altitude neutron data 30 15 km with previous high altitude 100 20 km neutron data and the results of several recent radar investigations sharply constrains the characteristics of each of the polar deposits the deposits at the north appear to be in the form of many small pockets or of generally distributed hydrogen that average to a 100 ppm weight fraction enhancement over that which exists in regolith at more equatorial latitudes those deposits in the permanently shaded craters near the south pole are consistent with a thick ferroan anorthosite regolith containing an enhancement of 1670 890 ppm hydrogen which if in the form of water ice amounts to 1 5 0 8 weight fraction of h sub 2 o neutron data alone cannot discriminate between hydrogen implanted in lunar soil from the solar wind hydrated minerals or h sub 2 o these craters appear to be surrounded by regolith that either contains small pockets of enhanced hydrogen or is soil that is uniformly impregnated with hydrogen enhanced on average by about 100 ppm above that contained in soils at more equatorial latitudes c more 2000 american geophysical union less

stratiform copper deposits hosted by low energy sediments i timing of sulfide precipitation an hypothesis published interpretations on the timing of copper and copper iron sulfide deposition in stratiform copper deposits hosted by low energy sediments range from those postulating deposition during sedimentation to those postulating deposition later in the diagenetic history of the host sediments with most favoring deposition during diagenesis interpretations of sulfide precipitation during diagenesis of the host sediments commonly favor a sulfide replacement of biogenic pyrite and in some instances replacement of anhydrite as well a qualitative reexamination was made of published data on 1 sulfur isotopes sulfide textures and sulfide nonsulfide mineral relationships in stratiform copper deposits hosted by low energy sediments and on 2 timing of bacterial sulfate reduction timing of pyrite formation and timing of authigenic mineral formation in modern analogues of host sediments to ore the reexamination is permissive of the hypothesis that chalcocite but not necessarily copper iron sulfides in stratiform copper deposits was precipitated within 50 cm of the sediment surface and that most precipitated within a few centimeters of the surface as a result of bacterial sulfate reduction the reexamination reveals that evidence for a pyrite replacement origin of chalcocite is based upon equivocal interpretations of sulfide textures textures displayed by most bornite chalcopyrite and digenite can be interpreted to indicate an origin by replacement of preexisting pyrite chalcocite composite grains limited porosity and permeability data on modern analogues of the host sediments and on clays are compatible with the hypothesis the porosity and permeability data and published models of compacting shale and sandstone sequences indicate that flow of copper transporting water was probably along rather than across the host rock bedding

evidence for water ice on the moon results for anomalous polar craters from the lro mini rf imaging radar 1 the mini rf radar instrument on the lunar reconnaissance orbiter spacecraft mapped both lunar poles in two different rf wavelengths complete mapping at 12 6 cm s band and partial mapping at 4 2 cm x band in two look directions removing much of the ambiguity of previous earth and spacecraft based radar mapping of the moon s polar regions the poles are typical highland terrain showing expected values of radar cross section albedo and circular polarization ratio cpr most fresh craters display high values of cpr in and outside the crater rim the pattern of these cpr distributions is consistent with high levels of wavelength scale surface roughness associated with the presence of block fields impact melt flows and fallback breccia a different class of polar crater exhibits high cpr only in their interiors interiors that are both permanently dark and very cold less than 100 k application of scattering models developed previously suggests that these anomalously high cpr deposits exhibit behavior consistent with the presence of water ice if this interpretation is correct then both poles may contain several hundred million tons of water in the form of relatively clean ice all within the upper couple of meters of the lunar surface the existence of significant water ice deposits enables both long term human habitation of the moon and the creation of a permanent cislunar space transportation system based upon the harvest and use of lunar propellant

sedimentary biogeochemistry of an acidic saline groundwater discharge zone in lake tyrrell victoria australia abstract the chemical composition of saline acidic pore waters at a groundwater discharge zone were investigated to delineate the biogeochemical conditions which occur within this zone the discharge area was a surface exposure of a subsurface gradient where regional groundwaters of low ph and salinities similar to seawater were mixing with anoxic sulfidic brines which were refluxing after evaporation within the lake shallow pore water samples collected along transects from the lake edge into the lake revealed large increases in nitrate and iron and small increases in manganese ratios of sulfate to chloride near the shore were similar to those found in seawater while ratios increased further into the lake the mixing of the regional groundwaters with the reflux brines apparently resulted in nitrification sulfur oxidation and iron reduction the sulfide in the brines appeared to have been generated at some remote location probably on the eastern side of the lake where neutral and saline groundwaters discharge and cyanobacterial mats proliferate hence biogeochemical processes occurring in the western discharge zone were fueled primarily by microbial activities in an area situated a few kilometers away

rare earth element distribution in lake tyrrell groundwaters victoria australia abstract the rare earth element ree geochemistry of the saline to hypersaline acidic brines of lake tyrrell victoria australia were analyzed in order to determine the relative importance of concentration and modification processes in the lake system several types of brines were identified on the basis of different ree patterns and concentrations regional groundwater flowing into lake tyrrell yields the highest concentrations of ree while a transitional water group is identified on the basis of lower ree concentrations a third water group the reflux brine is characterized by extremely low ree concentrations the ree patterns suggest that ree are introduced to the lake tyrrell system by the regional groundwater which has concentrated ree from the aquifer material in its acidic waters eventually ree are removed from the evolving water mass as higher levels of ph are reached the data of the study strongly suggest that ree are scavenged from solution by fe oxyhydroxide phases which precipitate as the ph of the system rises water rock interactions probably control ph in the lake system and therefore ultimately control the concentration of ree in solution in this system our results are directly correlated with studies of hydrothermal vents and geothermal solutions which have shown the concentration of ree in solution to be dominantly controlled by ph

genesis of copper mineralisation myall creek prospect south australia the myall creek copper prospect is in unmetamorphosed carbonaceous dolosiltstone and sandstone at the base of the late proterozoic adelaidean tapley hill formation it contains disseminated fine grained chalcopyrite zincian tennanite bornite chalcocite pyrite sphalerite and galena and irregular to straight chalcopyrite rich veinlets some ore minerals rim and or partially replace pyrite or clastic grains there is no evidence of hydrothermal activity the 34scdt values of pyrite and the other sulfides fall in the wide range 3 6 to 44 2 dolomite in both mineralised and unmineralised samples has 13cpdb values concentrated around 3 and 18osmow values around 25 it is concluded that the mineralising fluids were near neutral brines which leached metals from the basement and early adelaidean rocks they entered the tapley hill sediments at moderately low temperatures via permeable strata and faults the metals were precipitated by biogenic h2s and also fixed by reaction with iron sulfides and possibly organic matter continuing ascent of brines into the mineralised strata caused breakdown of detrital feldspars and fe ti oxides and some solution remobilisation of early formed sulfides

radar altimetry of mercury a preliminary analysis measurements of mercurian topography based on arecibo radar observations are presented the data which were obtained from 1978 to 1984 cover much of the equatorial zone of mercury between 12on and 5os latitude over thirty continuous altitude profiles were obtained each spanning from 20 to 90 degrees of longitude at a resolution of 0 15 o longitude by 2 5 o latitude radar depths for large craters support previous indications from imagery that mercurian craters are shallower than lunar craters of the same size one very large 800 km impact basin shows some distinct topographic structure although its relative shallowness suggests postimpact modification by isostatic relaxation or volcanic filling the plains of tir planitia appear topographically smooth to the radar these plains extend well into the hemisphere not imaged by mariner 10 possibly forming part of a large annulus of smooth plains around caloris basin the circum caloris smooth plains are strongly down bowed indicating subsidence under a load this and other similarities to lunar maria suggest a volcanic origin for these plains additional areas of topographically smooth terrain have been found in both the imaged and unimaged hemispheres several ridges scarps and fault zones have been identified in the altimetry three mapped arcuate scarps show heights of about 700 m and cross sectional widths of about 70 km one of these features is clearly a ridge while the other two scarps have a more ridge like appearance than is suggested by images one large scale topographic drop of 3 km correlates well with a mapped system of faults and intracrater scarps the equatorial zone of mercury shows 7 km of maximum relief although the typical elevation difference between highlands and lowlands is closer to 3 km three major highland areas are found the largest two of which are roughly antipodal and aligned within about 10 o of the hot poles of mercury the unimaged hemisphere possessing both large craters and topographically smooth areas does not appear to be markedly different in its topography from the imaged hemisphere no evidence has been found for another caloris type impact structure in the unimaged hemisphere

initial results for the north pole of the moon from mini sar chandrayaan 1 mission 1 we present new polarimetric radar data for the surface of the north pole of the moon acquired with the mini sar experiment onboard india s chandrayaan 1 spacecraft between mid february and mid april 2009 mini sar mapped more than 95 of the areas polewards of 80 latitude at a resolution of 150 meters the north polar region displays backscatter properties typical for the moon with circular polarization ratio cpr values in the range of 0 1 0 3 increasing to over 1 0 for young primary impact craters these higher cpr values likely reflect surface roughness associated with these fresh features in contrast some craters in this region show elevated cpr in their interiors but not exterior to their rims almost all of these features are in permanent sun shadow and correlate with proposed locations of polar ice modeled on the basis of lunar prospector neutron data these relations are consistent with deposits of water ice in these craters

thick ice deposits in shallow simple craters on the moon and mercury permanently shadowed regions near the poles of mercury and the moon may cold trap water ice for geologic time periods in past studies thick ice deposits have been detected on mercury but not on the moon despite their similar thermal environments here we report evidence for thick ice deposits inside permanently shadowed simple craters on both mercury and the moon we measure the depth diameter ratio of approximately 2 000 simple craters near the north pole of mercury using mercury laser altimeter data we find that these craters become distinctly shallower at higher latitudes where ice is known to have accumulated on their floors this shallowing corresponds to a maximum infill of around 50 m consistent with previous estimates a parallel investigation of approximately 12 000 lunar craters using lunar reconnaissance orbiter data reveals a similar morphological trend near the south pole of the moon which we conclude is also due to the presence of thick ice deposits we find that previously detected surface ice deposits in the south polar region of the moon are spatially correlated with shallow craters indicating that the surface ice may be exhumed or linked to the subsurface via diffusion the family of lunar craters that we identify are promising targets for future missions and may also help resolve the apparent discrepancy between the abundance of frozen volatiles on mercury and the moon ice deposits up to around 50 m thick infill some craters near the moon s south pole and mercury s north pole as inferred from the poleward shallowing of simple craters

imaging mercury s polar deposits during messenger s low altitude campaign images obtained during messenger s low altitude campaign in the final year of the mission provide the highest spatial resolution views of mercury s polar deposits images for distinct areas of permanent shadow within 35 north polar craters were successfully captured during the campaign all of these regions of permanent shadow were found to have low reflectance surfaces with well defined boundaries additionally brightness variations across the deposits correlate with variations in the biannual maximum surface temperature across the permanently shadowed regions supporting the conclusion that multiple volatile organic compounds are contained in mercury s polar deposits in addition to water ice a recent large impact event or ongoing bombardment by micrometeoroids could deliver water as well as many volatile organic compounds to mercury either scenario is consistent with the distinctive reflectance properties and well defined boundaries of mercury s polar deposits and the presence of volatiles in all available cold traps

the neutron signature of mercury s volatile polar deposits neutron leakage flux spectra are simulated to explore whether the nature of volatile deposits residing within the permanently shaded craters near the poles of mercury can be identified using state of the art space neutron detection techniques deployed aboard a flyby mission to mercury the most sensitive method for discriminating between h2o ice rich and s rich deposits involves measurement of the flux of epithermal neutrons we conclude that a single flyby over crater chao meng fu at an altitude of 200 km is sufficient to detect a circular deposit rich in elemental sulfur at the 2 6 statistical significance level and that a similar deposit rich in h2o can be identified at the 7 8 level whereas identification of a s rich deposit is not unique but compelling because of auxiliary physical arguments that of an h2o deposit is unique

thermal stability of ice on ceres with rough topography the dwarf planet ceres may have an ice rich crust and subsurface ice exposed by impacts or endogenic activity would be subject to sublimation we model surface and subsurface temperatures on ceres to assess lifetimes of water ice and other volatiles topographic shadowing allows a small but non negligible fraction 0 4 of ceres surface to be perennially below the 110 k criterion for 1 gyr of stability these areas are found above 60 latitude other molecules ch3oh nh3 so2 co2 may be cold trapped in smaller abundances a model for the transport gravitational escape and photoionization of h2o molecules suggests net accumulation in the cold traps buried ice is stable within a meter for 1 gyr at latitudes higher than 50 an illuminated polar cap of water ice would be stable within a few degrees of the poles only if it maintained a high albedo 0 5 at present obliquity if the obliquity exceeded 5 in the geologically recent past then a putative polar cap would have been erased at latitudes 0 30 ice is stable under solar illumination only briefly 10 100 yr unless it has high albedo and thermal inertia in which case lifetimes of 104 yr are possible finally a small hemispheric asymmetry exists due to the timing of ceres perihelion passage which would lead to a detectable enhancement of ice in the northern hemisphere if the orbital elements vary slowly relative to the ice accumulation rate our model results are potentially testable during the dawn science mission

bright and dark polar deposits on mercury evidence for surface volatiles measurements of surface reflectance of permanently shadowed areas near mercury s north pole reveal regions of anomalously dark and bright deposits at 1064 nanometer wavelength these reflectance anomalies are concentrated on poleward facing slopes and are spatially collocated with areas of high radar backscatter postulated to be the result of near surface water ice correlation of observed reflectance with modeled temperatures indicates that the optically bright regions are consistent with surface water ice whereas dark regions are consistent with a surface layer of complex organic material that likely overlies buried ice and provides thermal insulation impacts of comets or volatile rich asteroids could have provided both dark and bright deposits

oil shales evaporites and ore deposits abstract the relationships between oil shales evaporites and sedimentary ore deposits can be classified in terms of stratigraphic and geochemical coherence oil shale and black shale deposition commonly follows continental red beds and is in turn followed by evaporite deposition this transgressive regressive sequence represents an orderly succession of depositional environments in space and time and results in stratigraphic coherence the amount of organic carbon of a sediment depends on productivity and preservation both of which are enhanced by saline environments work on great salt lake utah allows us to estimate that only 5 of toc originally deposited is preserved inorganic carbonate production is similar to toc production but preservation is much higher oil shales and black shales commonly are enriched in heavy metals through scavenging by biogenic particles and complexation by organic matter ore deposits are formed from such rocks through secondary enrichment processes establishing a geochemical coherence between oil shales and ore deposits the permian kupferschiefer of n europe is used as an example to define a kupferschiefer type kst deposit here oxygenated brines in contact with red beds become acidified through mineral precipitation and acquire metals by dissolving oxide coatings oxidation of the black shale leads to further acid production and metal acquisition and eventually to sulfide deposition along a reducing front in order to form ore bodies the stratigraphic coherence of the red bed black shale evaporite succession must be joined by the geochemical coherence of the ore body evaporite black shale association the cretaceous cu zn deposits of angola the zambian copperbelt as well as the creta oklahoma deposits are other kst examples in the zambian copperbelt evaporites are indicated by the carbonate lenticles thought to be pseudomorphs after gypsum anhydrite nodules mvt deposits are also deposited by acid brines but at more elevated temperatures and with carbonates as principal host rocks the pine point deposits are cited for their close association with evaporites alkaline metal rich brines are postulated for the hyc deposit of mcarthur river australia such brines are known from the green river formation and deposits formed from such brines constitute the grt class they can be recognized by the presence of magadi type cherts and zeolite analcime k spar tuffs the cu co ore bodies of outokumpu finland might also belong to this type a new classification of sedimentary ore deposits is proposed based on their geochemical environment kst and mvt are formed from acid ore fluids while grt and ct creede type are derived from basic ore fluids ph of the fluids is best evaluated not from the ores themselves but from their effect on the host rocks

modeling radar scattering from icy lunar regoliths at 13 cm and 4 cm wavelengths 1 two orbital synthetic aperture radars sars the chandrayaan 1 mini sar 13 cm wavelength and the lunar reconnaissance orbiter lro mini rf 13 and 4 2 cm wavelengths have been imaging the lunar surface searching for ice deposits in the polar permanently shadowed areas to understand the radar signatures of lunar polar ices an empirical two component model with parametric variations of the specular and diffuse components was developed and validated this model estimates scattering differences associated with slopes surface roughness thin regolith over ice and patches of ice lunar radar backscatter cross sections for the average surface for the chandrayaan 1 and lro instruments are estimated from the radar cross sections from the moon at 3 8 23 and 68 cm wavelengths measured in the 1960s at the massachusetts institute of technology this modeling predicts that enhanced diffuse scattering from near surface ice can be separated from rocks if the scattering is characterized by both the high reflectivity and circular polarization ratios cprs like those observed on mercury mars and the galilean satellites scattering from near surface ices covered by a thin regolith can be separated from rocks if the enhancement is twice the average or more if however the lunar ice is dispersed throughout the regolith as ice filling pores then scattering differences might be too small to detect preliminary validation using lro radar data for a few polar and midlatitude craters indicate that the observed cprs are consistent with our models for different regolith ice and roughness conditions

characterization of the morphometry of impact craters hosting polar deposits in mercury s north polar region 1 earth based radar images of mercury show radar bright material inside impact craters near the planet s poles a previous study indicated that the polar deposit hosting craters pdcs at mercury s north pole are shallower than craters that lack such deposits we use data acquired by the mercury laser altimeter on the messenger spacecraft during 11 months of orbital observations to revisit the depths of craters at high northern latitudes on mercury we measured the depth and diameter of 537 craters located poleward of 45 n evaluated the slopes of the northern and southern walls of 30 pdcs and assessed the floor roughness of 94 craters including nine pdcs we find that the pdcs appear to have a fresher crater morphology than the non pdcs and that the radar bright material has no detectable influence on crater depths wall slopes or floor roughness the statistical similarity of crater depth diameter relations for the pdc and non pdc populations places an upper limit on the thickness of the radar bright material 170 m for a crater 11 km in diameter that can be refined by future detailed analysis results of the current study are consistent with the view that the radar bright material constitutes a relatively thin layer emplaced preferentially in comparatively young craters

source distribution and economic significance of trace elements in groundwaters from lake tyrrell victoria australia abstract anomalous radioactivity highlighted the lake tyrrell area as a potential mineral exploration target and prompted a 5 year study of its groundwater geochemistry the groundwaters are very acid median ph 4 2 and saline median ionic strength i 1 24 some samples contain unusually high concentrations of cu up to 3 5 mg l 1 pb up to 38 5 mg l 1 and al up to 155 mg l 1 concentrations of most other trace elements exceed seawater values but are not different from those in groundwaters near two other randomly selected australian salt lakes waters with elevated trace element concentrations are spread at isolated sites across the area but some clustering of cu pb enriched waters occurs in the west and southeast r and q mode correspondence analysis identifies factors which relate to both trace elements and samples and are interpreted as reflecting processes whereby trace elements are taken into groundwaters factor 1 involves al cu fe mn and zn whose concentrations relate directly to high acidity factor 2 involves b and sr and probably relates to local sediment enrichments of b and sr factor 3 is strongly weighted by pb and can be explained by contact between groundwaters and locations where clays organic solids and fe mn oxides are particularly enriched by heavy metals factor 4 involves f y and i and probably relates to residual mineral dissolution sample locations grouped according to the influence of each factor on each groundwater composition identify zones where a particular process is dominant laboratory leaching of blanchetown clay and parilla sand confirms that many of the trace elements could have entered the groundwater from local aquifer sediments the potential of these waters as agents of present or future ore formation is also considered by comparing amounts of trace elements carried into the salt lake basin over the last 30 kyr with what persists in present day lake brines results demonstrate that large tonnages of trace elements appear to have been deposited but that sediment dilution mitigates against ore grade concentrations

comparison of areas in shadow from imaging and altimetry in the north polar region of mercury and implications for polar ice deposits earth based radar observations and results from the messenger mission have provided strong evidence that permanently shadowed regions near mercury s poles host deposits of water ice messenger s complete orbital image and topographic datasets enable mercury s surface to be observed and modeled under an extensive range of illumination conditions the shadowed regions of mercury s north polar region from 65 n to 90 n were mapped by analyzing mercury dual imaging system mdis images and by modeling illumination with mercury laser altimeter mla topographic data the two independent methods produced strong agreement in identifying shadowed areas all large radar bright deposits those hosted within impact craters 6 km in diameter collocate with regions of shadow identified by both methods however only 46 of the persistently shadowed areas determined from images and 43 of the permanently shadowed areas derived from altimetry host radar bright materials some sizable regions of shadow that do not host radar bright deposits experience thermal conditions similar to those that do the shadowed craters that lack radar bright materials show a relation with longitude that is not related to the thermal environment suggesting that the earth based radar observations of these locations may have been limited by viewing geometry but it is also possible that water ice in these locations is insulated by anomalously thick lag deposits or that these shadowed regions do not host water ice