vanadium in ancient sedimentary rocks of marine origin abstract the distribution of vanadium and vanadyl porphyrins in fractions extractable organic inorganic and kerogen of the serpiano marl and the la luna shaly limestone has been determined by employing a variety of geochemical and spectroscopic techniques including atomic absorption atomic emission electronic absorption and electron spin resonance spectroscopies high levels of vanadium and vanadyl porphyrins were found with the major part of the total vanadium located in the kerogen fractions of both rocks in contrast while the kerogen of the la luna rock also contained the major fraction of total vanadyl porphyrins 70 the corresponding value for the serpiano marl is only 30 no vanadyl species were present in the inorganic fraction of either rock it is suggested that the source of vanadium in these rocks is volcaniclastic materials and that the vanadyl porphyrin entities were incorporated into the kerogen structure through abiotic geochemical modifications of biosynthetic pigment chlorophyll

relationships between sulphur organic carbon and iron in the modern sediments of the black sea abstract the ratio of sedimentary s to organic c has been used as a diagnostic criterion for recognizing anoxic environments in the sedimentary record here we examine the relationship between pyrite s and organic c in the modern unit 1 sediments of the black sea to re evaluate this suggested relationship in box cores from shallow oxic or near oxic water pyrite s contents ranging from 0 1 and 2 5 by weight do not correlate with organic c contents in cores from the deep anoxic basin pyrite s concentrations range between 1 0 and 2 5 and are linearly related to organic c contents with an intercept that is not significantly different from zero the s c ratio is around 0 31 in these sediments which is somewhat lower than the ratio of 0 36 considered to be characteristic of normal marine oxic sediments thus the black sea anoxic sediments appear to be depleted in s relative to organic c the degree of pyritization dop of the sediments may be a better measure of anoxic conditions of sedimentation the dop values measured here show that pyrite formation is fe limited the correlation between organic c and pyrite s probably being induced by a positive correlation between fine grained sediment components the original fe source for pyrite formation in the sediments and organic matter such fe limitation is probably characteristic of anoxic basins where pyrite formation can take place in the water column and fe oxyhydroxides do not accumulate in the surface sediments the results on the sample set examined here are at variance with earlier data and interpretations for the black sea in particular the suggested s enrichment of anoxic black sea sediments was not found because of fe limitation

hydrocarbon potential and depositional environment of the lower cretaceous black mudstones and shales in the coastal guangdong province china abstract the mesozoic especially the cretaceous sequences in the northern south china sea scs are important potential targets of oil and gas exploration however they are currently poorly understood we use organic petrology and geochemistry to evaluate the hydrocarbon potential and study depositional environment of the cretaceous black mudstones and shales from the dayawan section in the guangdong province china these mudstones and shales yield total organic carbon toc contents of 0 63 2 76 and most samples meet the requirement for higher toc source rocks organic matters in the mudstones and shales were sourced mainly from higher plants as well as subordinate benthic macroalgae organic petrology and geochemical data suggested that the organic matters were dominated by type iii and minor type ii and generally have low thermal maturity thus we evaluated the black mudstones and shales have a potential for hydrocarbon generation especially gas prone pr ph trace elements and mixture source of organic matter suggested that these black mudstones and shales formed in a coastal lacustrine environment characterized by weakly oxidizing weakly reducing conditions and low salinity a marine transgression developing in the middle part of the section was recognized generally the northern scs which exhibits the more marine influence likely contains source rocks with higher toc contents and better organic matter types the cretaceous source rocks with higher liquid hydrocarbon generation potential may occur locally in the pearl river mouth basin

spatial and temporal variability of paleocene miocene organofacies of the kura basin eastern azerbaijan and implications for basin evolution and petroleum generation abstract fine grained paleocene miocene strata of eastern azerbaijan record the evolution of the kura basin from an open marine system connecting the south caspian basin to the paratethys of eastern europe to an isolated epicontinental sea tectonic uplift associated with the greater caucasus mountains in azerbaijan resulted in exposure of these strata over much of the northeastern part of the basin allowing detailed observation and sampling over a broad area four hundred paleocene miocene samples collected in eastern azerbaijan demonstrate spatial and temporal geochemical heterogeneity within the predominately mudstone succession indicating a complex evolution of this elongate basin through detailed organic geochemical analysis of samples trends can be seen in the distribution of total organic carbon toc pyrolysis characteristics and biomarker results from a subset of twenty four samples in addition to confirming the well documented regional basin restriction during the oligocene to early miocene deposition of the maikop series heterogeneity of these geochemical indicators across the study area shows spatial variability in oxicity and terrestrial organic input within the basin on a sub regional scale observed geochemical variability suggests a complex evolutionary history of the kura basin during the paleocene miocene and this has important implications for hydrocarbon prospectivity in the region within the 400 collected samples total organic carbon toc values range from 0 3 to 6 3 with oligocene miocene samples showing average values of 1 4 compared to lower toc values found in paleocene eocene strata average 0 3 rock eval pyrolysis shows that the majority of strata are organic lean immature and mixed oil gas to gas prone type ii iii to type iii with a smaller group of latest eocene early miocene samples having better oil prone source potential gas chromatography and biomarker analysis of 24 samples reinforces the immaturity of most samples shows varying levels of terrestrial input in all samples suggests well oxygenated waters prevailed with periodic suboxic to dysoxic anoxic events highlights gross differences between the paleocene eocene and oligocene miocene stratigraphic intervals and shows generally good lateral correlation between samples these interpretations reinforce what is seen through inorganic geochemical evaluation of trace metals bulk composition and stable isotopic ratios and offer more detail as to the evolution of this basin and the implications for oil and gas prospectivity of the region

trace element geochemistry of crude oils and condensates from south african basins abstract crude oil and condensates samples from bredasdorp and orange basins south africa were analyzed for trace elements using inductively coupled plasma optical emission spectrometry the oil and condensate samples were analyzed to classify the oils into family and to determine the origin of the oils and depositional environment of organic matter that yielded the oils using trace elements the concentrations of the elements co cr cu fe mn ni and v determined ranged from 0 10 to 7364 7 ppb iron is the most abundant element in the samples while cobalt is least abundant both concentrations and ratios of nickel and vanadium showed two main families of oils oils of marine origin and oils of terrestrial origin oil samples from the orange basin are mainly of marine source and their organic matter were deposited under anoxic conditions most of the oil samples from the bredasdorp basin are of marine origin with a few samples having terrestrial origin cluster analysis also classified the oil and condensate samples from the two basins into two main families of marine and terrestrial sources

vanadium accumulation in carbonaceous rocks a review of geochemical controls during deposition and diagenesis abstract published data relevant to the geochemistry of vanadium were used to evaluate processes and conditions that control vanadium accumulation in carbonaceous rocks reduction adsorption and complexation of dissolved vanadium favor addition of vanadium to sediments rich in organic carbon dissolved vanadate v v species predominate in oxic seawater and are reduced to vanadyl ion v iv by organic compounds or h 2 s vanadyl ion readily adsorbs to particle surfaces and is added to the sediment as the particles settle the large vanadium concentrations of rocks deposited in marine as compared to lacustrine environments are the result of the relatively large amount of vanadium provided by circulating ocean water compared to terrestrial runoff vanadium rich carbonaceous rocks typically have high contents of organically bound sulfur and are stratigraphically associated with phosphate rich units a correspondence between vanadium content and organically bound sulfur is consistent with high activities of h 2 s during sediment deposition excess h 2 s exited the sediment into bottom waters and favored reduction of dissolved v v to v iv or possibly v iii the stratigraphic association of vanadiferous and phosphatic rocks reflects temporal and spatial shifts in bottom water chemistry from suboxic phosphate concentrated to more reducing euxinic conditions that favor vanadium accumulation during diagenesis some vanadium organic complexes migrate with petroleum out of carbonaceous rocks but significant amounts of vanadium are retained in refractory organic matter or clay minerals as carbon in the rock evolves toward graphite during metamorphism vanadium is incorporated into silicate minerals

depletion of 13c in cretaceous marine organic matter source diagenetic or environmental sigal geochemical studies of cretaceous strata rich in organic carbon oc from deep sea drilling project dsdp sites and several land sections reveal several consistent relationships among amount of oc hydrocarbon generating potential of kerogen measured by pyrolysis as the hydrogen index hi and the isotopic composition of the oc first there is a positive correlation between hi and oc in strata that contain more than about 1 oc second percent oc and hi often are negatively correlated with carbon isotopic composition 13c of kerogen the relationship between hi and oc indicates that as the amount of organic matter increases this organic matter tends to be more lipid rich reflecting the marine source of the organic matter cretaceous samples that contain predominantly marine organic matter tend to be isotopically lighter than those that contain predominantly terrestrial organic matter average 13c values for organic matter from most cretaceous sites are between 26 and 28 and values heavier than about 25 occur at very few sites most of the 13c values of miocene to holocene oc rich strata and modern marine plankton are between 16 to 23 values of 13c of modern terrestrial organic matter are mostly between 23 and 33 the depletion of terrestial oc in 13c relative to marine planktonic oc is the basis for numerous statements in the literature that isotopically light cretaceous organic matter is of terrestrial origin even though other organic geochemical and or optical indicators show that the organic matter is mainly of marine origin a difference of about 5 in 13c between modern and cretaceous oc rich marine strata suggests either that cretaceous marine planktonic organic matter had the same isotopic signature as modern marine plankton and that signature has been changed by diagenesis or that oc derived from cretaceous marine plankton was isotopically lighter by about 5 relative to modern plankton oc diagenesis does not produce a significant shift in 13c in miocene to holocene sediments and therefore probably did not produce the isotopically light cretaceous oc this means that cretaceous marine plankton must have had 13c values that were about 5 lighter than modern marine plankton and at least several per mil lighter than cretaceous terrestrial vegetation the reason for these lighter values however is not obvious it has been proposed that concentrations of co2 were higher during the middle cretaceous and this more available co2 may be responsible for the lighter 13c values of cretaceous marine organic matter

generation and migration of hydrocarbons in the maracaibo basin venezuela an integrated basin study abstract the history of hydrocarbon generation and migration in the maracaibo basin venezuela is closely related to its stratigraphic structural and tectonic evolution during the cretaceous and cenozoic times geochemical evaluation of the possible source rocks within the cretaceous and the tertiary sequences indicates that the argillaceous limestones and calcareous shales of the la luna formation cenomanian coniacian are the most important source rocks in the basin these rocks contain organic carbon ranging from 1 5 to 9 6 c original toc 2 5 10 8 have fluorescent amorphous marine type ii organic matter oil prone and have in the immature stage a h index of 700 mg hc g toc and a h c ratio of 1 5 the beginning of the oil window in these rocks occurs at a relatively low thermal maturity lopatin tti about 10 and the peak of oil generation corresponds to a tti value of 35 geochemistry of oils from the different reservoirs cretaceous paleocene eocene and miocene beds and oil oil and oil source rock correlation studies based on biomarkers have identified three genetic types of oil in the basin a marine type essentially derived from the la luna source a terrestrial type possibly originating either from the cretaceous lisure shales or the paleocene shales and a third type derived from the mixing of the first two types the marine type oil is distributed extensively throughout the basin whereas the terrestrial as well as the mixed marine and terrestrial types are found only in the southwestern part of the basin the marine type oils have been further subdivided based on their alteration and maturity reconstruction of the hydrocarbon generating areas at different geological times using tti maturity diagrams indicates that the generation of oil and gas in the basin took place during two periods the first phase occured during the middle to upper eocene times in the northeastern part of the basin while the second phase occured during the upper miocene to recent times in the central western and southern parts of the basin based on organic geochemical and sedimentological characteristics it is proposed that primary migration of oil from the la luna source rocks took place by expulsion of hydrocarbons through abundant microfractures developed by the pore fluid overpressure during hydrocarbon generation mass balance considerations suggest that the expulsion probably occurred as a hydrocarbon single phase and the expulsion efficiency for oil in la luna source rocks should have been very high 30 50 taking into consideration the development of oil and gas kitchens through time the paleostructures at the time of hydrocarbon generation and the characteristics of oils the migration history of the oil and gas generated from the la luna source has been outlined mixing of oils derived at different times eocene and miocene recent from the la luna source of different areas appeared to have taken place in block iv block 11 lago lamar motatan and bolivar coastal fields

organic geochemical characterisation of depositional palaeoenvironments of source rocks and oils in brazilian marginal basins abstract an investigation of bulk isotopic and molecular features of a wide selection of source rocks and oils from brazilian marginal basins ranging from lower cretaceous to tertiary in age provides a number of organic geochemical criteria that characterise and distinguish their depositional palaeo environments the methods employed include evaluation of organic carbon contents rock eval pyrolysis vitrinite reflectance measurements determination of carbon isotope ratios elemental and visual kerogen analysis assessment of oils and solvent extracts by liquid and gas chromatography and quantitative biological marker investigations using gc ms for aliphatic hydrocarbons and uv vis spectrophotometry for metalloporphyrins selected data were evaluated using principal component analysis the results enable the recognition and differentiation of seven depositional regimes lacustrine freshwater lacustrine saline water marine evaporitic marine carbonate marine deltaic marine highly anoxic with a predominance of calcareous mudstone lithology and marine anoxic with predominance of siliciclastic lithology diagnostic features in the biological markers from these depositional environments include the carbon number distributions of n alkanes pristane phytane ratios absolute concentrations of carotane higher acyclic isoprenoids c 30 hopane and steranes and the abundance of the latter relative to 4 methylsteranes the occurrence and abundance of particular biological markers such as gammacerane tricyclic and tetracyclic terpanes 18 h oleanane 28 30 bisnorhopane and 25 28 30 trisnorhopane and the relative abundances of nickel and vanadyl porphyrins

global and local controls influencing the deposition of the la luna formation cenomanian campanian western venezuela bulk and molecular geochemical micropalaeontological and carbon isotopic data are used to address the different local and global factors influencing the environment of sedimentation of the la luna formation cenomanian campanian approximate palaeolatitude 15 n in a single section in western venezuela based on the constructed chronostratigraphic framework oxygen depleted bottom water conditions and black shale deposition started in western venezuela well before the widespread occurrence of organic rich sediments in higher palaeolatitude regions such as the tethys and the north atlantic near or at the cenomanian turonian boundary in the la luna formation palaeoenvironmental conditions that allowed the preservation of organic matter mainly of marine origin prevailed until santonian times in a distal platform facies with very low siliciclastic input changes in lithology appear to reflect the local response to eustatic sea level variations and the presence of a migrating upwelling belt affecting the bioproductivity of silica and carbonate a marked 13corg isotopic excursion is recognised in the middle part of the section and is apparently unrelated to local palaeoenvironmental changes in bioproductivity and oxygen depletion biological marker data show no variations in association with the isotopic excursion being mainly controlled by local fluctuations in organic matter input and preservation

timing and structure of termination ii in north china constrained by a precisely dated stalagmite record abstract the timing and structure of termination ii t ii is still debatable as the number of high quality records is insufficient this study presents precisely dated stalagmite 18 o data between 133 4 0 3 to 126 6 0 3 ka bp covering most of t ii from north china near the northern limit of the east asian summer monsoon easm an area sensitive to climate change the onset of the last interglacial is constrained at 129 4 0 3 ka bp consistent with south chinese speleothem records further supporting the idea that northern hemisphere summer insolation plays an important role in initiating glacial terminations an extended interval of heavy 18 o is observed immediately prior to this abrupt transition named as the weak monsoon interval wmi in south chinese cave records which was associated with the heinrich stadial 11 h11 in the north atlantic a significant millennial scale interstadial peaking at 132 7 0 3 ka bp is identified preceding the weakest phase of the wmi a synchronous counterpart is also found in some south chinese speleothem and north atlantic alkenone mg ca sst records it is inferred that the main h11 freshwater penetration possibly occurred after 131 5 ka bp leaving some aspects of ocean and atmospheric circulation still in interstadial mode from 134 to 131 5 ka bp following the onset of the last interglacial there was a millennial scale pause in our 18 o record synchronized with a slowdown in the rate of decrease in 18 o in south chinese cave records this is possibly a large regional climate oscillation as it is also identified in some north atlantic records but one which is too weak to be a younger dryas yd type event in summary compared to south chinese cave records significant millennial scale climate oscillations before and after the synchronous onset of the last interglacial is the main feature of our record nevertheless the sequence of these climate events remains very different from termination i t i which is possibly ascribed to the stronger insolation higher atmosphere co2 and the resultant faster and greater meltwater pulse to the north atlantic during t ii than during t i

secular and environmental constraints on the occurrence of dinosterane in sediments abstract the distribution patterns of sedimentary a ring methylated steranes have changed markedly over geological time although dinosterane and its isomer 24 ethyl 4 methylcholestane have been tentatively identified in three proterozoic rock units they are either not detectable or occur in low abundance relative to 3 methyl steranes throughout most of the palaeozoic between permian and middle triassic times 260 220 ma ago 4 methyl sterane abundances in marine sediments increased markedly the presence of dinosterane in some middle triassic marine sediments is contemporaneous with the appearance of fossil cysts of uncontested dinoflagellate affinity 4 methyl steranes including dinosterane or their precursor sterenes and sterols then show a continuous presence often in high abundance in marine sediments from the late triassic through to the present day assemblages of 4 methyl steranes and their precursors but with dinosterane absent or in low relative abundance are often the predominant steroids in lacustrine sediments in the cainozoic dinosterane appears to arise predominantly from marine dinoflagellates and as a consequence is a useful biological marker for mesozoic and cainozoic marine organic matter the isomer 24 ethyl 4 methylcholestane is likely to have multiple origins although its very high abundance in tertiary lacustrine sediments and oils compared to older materials suggests that dinoflagellates could also be the source in these cases

formation of magnetic minerals at hydrocarbon generation conditions in this paper we report the pyrolysis and formation of magnetic minerals in three source rock samples from the wessex basin in dorset southern england the experimental conditions in the laboratory recreated the catagenesis environment of oil source rocks magnetic analysis of both the heated and the unheated samples at room temperature and at very low temperatures 5 k coupled with transmission electron microscopy imaging and x ray analysis revealed the formation of nanometre sized 10 nm magnetic particles that varied across the rock samples analysed but more importantly across the pyrolysis temperature range magnetic measurements demonstrated the formation of these magnetic minerals peaked at 250 c for all rock samples and then decreased at 300 c before rising again at 320 c the newly formed magnetic minerals are suggested to be primarily pyrrhotite though magnetite and greigite are also thought to be present the sizes of the magnetic minerals formed suggest a propensity to migrate together with oil potentially explaining the magnetic anomalies observed above and within oil fields

vertical variations of organic matter content in guayuta group upper cretaceous interior mountain belt eastern venezuela abstract a geochemical study of the vertical variations of organic matter in the guayuta group querecual and san antonio formations has been conducted on a series of samples taken from a sedimentary sequence outcropping in the interior mountain belt the results indicate that despite very high thermal maturity the organic matter content in the samples is still very high and shows geochemical characteristics related to anoxic paleoenvironmental conditions of sedimentation based on micropaleontological data mineralogical data and trace metal v ni ratio of kerogen the analysis of the sequence shows stronger anoxic depositional conditions toward the base of the section and an increase of clastic sediments toward the top the total organic carbon of the sediments increases toward the base of the sequence in addition there are pseudocyclic patterns and heterogeneities of the organic carbon content distribution at the meter scale the results indicate that the lower part of this sedimentary sequence represents a major anoxic event that can be correlated with other sequences of middle and upper cretaceous age

trace metals and organic geochemistry of the machiques member aptian albian and la luna formation cenomanian campanian venezuela abstract two proposed source rock sequences in the lower aptian albian and the upper cenomanian campanian cretaceous sediments of the perija range maracaibo basin were geochemically analyzed in order to find environmentally controlled characteristic fingerprints trace metals and sulfur concentrations were found to be closely related with the physicochemical conditions during deposition of the rocks based on trace metal analyses and sulfur relationships with toc the aptian albian sequence machiques member shows alternate oxic and anoxic episodes close to the bottom water surface where mixed marine and terrestrial organic matter were deposited the cenomanian campanian sequence la luna formation persistently shows anoxic euxinic conditions that allowed the preservation of marine organic matter ratios of trace metals v mo and zn characterize both cretaceous sedimentary columns however some limitations are visualized in using trace metals as correlation tools in further geochemical studies biomarker ratios are related to the organic matter type and lithology some specific ratios and individual compounds allow a clear differentiation between these two sequences and offer in the context of 13 c an excellent tool for further oil source rock correlation studies

trace elements as palaeoenvironmental markers in strongly mature hydrocarbon source rocks the cretaceous la luna formation of venezuela abstract the late cretaceous la luna formation is the main hydrocarbon source rock formation in venezuela in the lake maracaibo area the formation shows a steep maturation gradient affecting sedimentary organic matter om and clay minerals related to local burial history and thrusting events the influence of the gradient is examined through geochemical organic and inorganic and mineralogical investigations carried out on samples from five cored boreholes in the maracaibo basin the analytical procedure comprises rock eval pyrolysis vitrinite reflectance measurement palynofacies observation major and trace element content determination performed on bulk rock samples or after a sequential leach protocol dop calculation and the examination and analysis of clay mineral assemblages the maturation gradient seems to have had no effect upon the distribution of the trace elements referred to as proxy indicators for palaeodepositional conditions of om rich sediments ba p v mo ni co cu cd cr and mn consequently trace elements appear to be reliable palaeoenvironmental markers they indicate that during the la luna fm deposition the water column must have had variable conditions with high primary production near the surface and the correlative development of euxinic conditions at the bottom this provides further arguments for an upwelling system affecting the northern platform of south america during late cretaceous time the relative scarcity of reactive iron in the depositional environment must have taken an active part in a process involving sulphur and acting on the environmental conditions as well as on om vulcanisation this process favours aliphatic om storage and may be relevant for many other om rich facies or hydrocarbon source rocks

late cretaceous upwelling and anoxic sedimentation in northwestern south america abstract black shales and bituminous limestones were widely deposited in northwestern south america during the maximum transgression of late cretaceous seas these cenomanian to santonian campanian anoxic sediments are distributed in two main subprovinces thick chert and phosphorite accumulated in the trough subprovince landward of a possibly partially emergent cordillera central colombia only minor intercalations of chert were deposited in the platform subprovince lying northward in the maracaibo basin northwestern venezuela faunal evidence depauperate benthic fauna planktic foraminiferal assemblages high dominance clupeoid fish assemblages and sedimentological evidence suggest anoxic condition prevailed throughout the region probably the result of dynamic upwelling in the trough subprovince but the reflection of a global anoxic event within the platform subprovince

organically bound metals and biomarkers in the monterey formation of the santa maria basin california abstract systematic variations in metal concentration ratios and biomarker ratios are observed with depth in cores of the monterey formation of the union leroy 51 18 well in the santa maria basin california specific metal ratios v v ni and mo mo cr correlate between kerogen and extractable organic matter further the organic matter in the two predominant lithofacies siliceous shales vs phosphatic shales can be distinguished based upon metal concentration ratios e g v v ni and certain biomarker characteristics e g sterane terpane mono triaromatic steroid hydrocarbon ratios maximum 28 30 bisnorhopane hopane ratios occur over a narrow range of v v ni ratios in kerogen concentrates and extractable organic matter this suggests that metal ratios in kerogen concentrates and eom may be useful for oil source rock correlation studies in the monterey further while kerogen parameters metals are discontinuous at the lithofacies boundary extract parameters biomarkers are gradational at this boundary suggesting about 30 ft 9 m of vertical hydrocarbon migration across the lithofacies contact

source characterization of highly mature pyrobitumens using trace and rare earth element geochemistry sinian paleozoic paleo oil reservoirs in south china abstract understanding the relationships between migrated hydrocarbons and source rocks under highly mature conditions i e pyrobitumen source correlation is a critical and challenging issue in the field of petroleum geology and geochemistry based on a case study of three sinian paleozoic paleo oil reservoirs from yunan and guizhou provinces south china we attempt to provide further understanding of this issue using trace and rare earth element ree geochemistry which can characterize the depositional setting organic input and rock provenance of source rocks results show that the bitumens from the three paleo oil reservoirs can be distinguished from each other using post archean australian shale paas normalized trace element distribution patterns ree distribution patterns hierarchal cluster analysis of element concentrations and redox and provenance sensitive elemental ratios e g v ni ni co ni mo zr cr la sc and la co pyrobitumen in the devonian xiaocaoba paleo oil reservoir is derived primarily from devonian source rocks representing a self sourced petroleum system and one stage hydrocarbon charging similarly pyrobitumen in the sinian jinsha yankong paleo reservoir also received a single fluid charge but the source is different and likely generated by contributions from both lower cambrian and sinian sources in contrast the bitumen in ordovician kaili luomian paleo reservoirs are indicated to have contributions from two different hydrocarbon sources and thus experienced two stages of hydrocarbon charging an early charge from lower cambrian source rocks and a later charge from permian source rocks the new trace and rare earth element method used in this study appears to be effective at providing a better understanding of the hydrocarbon source correlation under highly mature conditions the results improve our understanding of the complex hydrocarbon accumulation alteration evolution in the marine strata of south china which is a potential target for petroleum exploration

petrographic and geochemical characterization of the upper cretaceous coal and mudstones of gombe formation gongola sub basin northern benue trough nigeria implication for organic matter preservation paleodepositional environment and tectonic settings abstract under exploration of the upper cretaceous petroleum systems in the northern benue trough nigeria has been attributed largely to lack of subsurface samples and non integration of organic and inorganic geochemical methods recent access to surface sampling from maiganga coalfield revealed a need for detailed evaluation of the sedimentary facies types for better understanding of the hydrocarbon potential of the area detailed maceral point count py gc chnso as well as major oxides and trace element icp ms analysis were used to characterize the gombe formation coals and the mudstones for determination of the organic matter origin preservation paleodepositional environment tectonic setting and paleoclimatic condition during sedimentation evaluation based on the maceral composition tpi gi values plot of trace elements v versus ni and sedimentary succession suggest deposition of predominantly terrigenous organic matter 45 to 73 huminite maceral in an upper deltaic setting for the maiganga facies the maceral analysis associated with py gc studies indicates that the sedimentary facies of gombe formation have potential to generate liquid hydrocarbon this can be estimated from an average of 21 50 liptinite content and the ternary plot of the py gc pyrolysate m p xylene n octene and phenol suggesting presence of type ii and type ii iii kerogen within the basin assessment of the paleodepositional environment based on the trace elements composition indicates a moderate stratified water column and salinity within a relatively sub oxic to oxic conditions during sedimentation the major oxide composition as well as the binary plots of sio2 versus al2o3 k2o na2o and log sio2 versus k2o na2o for the shales and mudstones revealed a predominance of semi arid to slightly humid warm paleoclimatic conditions and a passive continental margin setting this is in accordance with the cretaceous tectonic events of the west and central africa which affected the petroleum system in the entire benue trough

a users guide to fission track dating calibration abstract misconceptions regarding the fission track dating method prompt the description of five handling procedures and the derivation of commonly used system calibrations problems of registration geometry inhomogeneous uranium distribution accumulated radiation damage and anisotropic etching largely invalidate all but the population and external detector methods and impose strict limitations upon even their routine application complexities of unique absolute thermal neutron dosimetry are illustrated by the calibration and use of the nbs pre irradiated glass srm 962 the 20 disparity in measured f decay constant values cannot be isolated from neutron fluence measurement and calibration frequently a calibration ratio f is evaluated against an age standard and then split into its component parts to illustrate this interdependence of f and zircon fission track ages in agreement with independent k ar ages are obtained by calculating the same track count data with each of the preferred values of f f 7 03 10 17 yr 1 and8 46 10 17 yr 1 together with appropriate selected neutron dosimetry schemes an alternative approach is presented formally relating unknown ages of samples to known ages of standards either by direct comparison of standard and sample track densities or by the repeated calibration of a glass against age standards practical recommendations are given for the reporting and critical assessment of fission track data

vanadium nickel and sulfur in crude oils and source rocks and their relationship with biomarkers implications for the origin of crude oils in venezuelan basins abstract this work presents a study of vanadium nickel and sulfur concentrations and biomarkers in a suite of crude oils and source rocks from three venezuelan basins maracaibo and eastern basins and barinas sub basin crude oils range from unaltered to altered by biodegradation and source rocks are characterized by having different kerogen types type ii iii or iv and maturity levels early mature to post mature vanadium nickel and sulfur concentrations v ni or v v ni and saturate biomarkers were used to classify the oils and source rocks based on inferred paleo redox environment lithology and maturity of the source rock oils are classified into five groups based on v ni ratios they appear to be related to variations in the paleo redox environment from suboxic dysoxic to anoxic suboxic of source rocks with variable lithological composition and organic matter input regardless of their maturity or biodegradation level these five groups are also classified based on biomarkers related to maturity organic matter type paleo redox environment and source rock lithology in source rocks vanadium nickel and sulfur concentrations together with v ni or v v ni ratios provide information about the paleo redox environment and are related to lithology regardless of their maturity these results also indicate variable paleo redox conditions during the sedimentation of venezuelan source rocks all this suggests that while the main source rocks in venezuelan basins are well established there are still uncertainties regarding their lateral and vertical variations in organic and inorganic facies and paleo redox conditions the presence of other source rocks contributing to the accumulation of hydrocarbons in the venezuela basins is also a possibility