spatial variability of watermass conditions within the european epicontinental seaway during the early jurassic pliensbachian toarcian in order to constrain spatial variability in watermass conditions within the european epicontinental seaway prior to during and after the toarcian oceanic anoxic event carbon 13cbel 13ccarb and oxygen 18obel 18ocarb isotope records were obtained from three sections in the grands causses basin southern france these data were then compared with similar records along a north south transect across the european epicontinental seaway as the conclusions reached here strongly depend on the reliability of belemnite calcites as archives of palaeoceanographic changes an attempt was made to improve the understanding of isotope signals recorded in belemnite calcite intra rostral carbon and oxygen isotope data from six belemnite specimens belonging to the genus passaloteuthis were collected intra rostral carbon isotopes are influenced by vital effects whereas oxygen isotopes reflect relative changes in temperature and salinity palaeotemperatures calculated from 18obel isotope records from the grands causses basin confirm relatively low temperatures throughout the late pliensbachian similar cool water conditions have previously been shown in germany england spain and portugal a temperature increase of up to 6 c is observed across the pliensbachian toarcian boundary a pronounced negative shift of at least 3 vienna pee dee belemnite is recorded in bulk carbonate carbon during the lower harpoceras serpentinum zone typical of the toarcian oceanic anoxic event before and after the toarcian oceanic anoxic event a good correlation between 13ccarb and 13cbel exists indicating well ventilated bottom waters and normal marine conditions instead data for the toarcian oceanic anoxic event indicate the development of a strong north south gradient in salinity stratification and surface water productivity for the western tethyan realm this study thus lends further support to a pronounced regional overprint on carbon and oxygen isotope records in epicontinental seaways

angles of friction and dilatancy of sand it is generally realized that the peakfriction angel depends not only on density but alsoon the stress path including differences betweenplane strain and triaxial testing conditions indeed plane strain and triaxial strain angles can differ bymore than 58 for a dense sand for a loose sand atthe critical density it is often suggested that similardifferences occur e g stroud 1971 lade 1984 however some authors have presented data thatsuggest a unique critical state angle e g rowe 1962 1971 bolton 1986 this technical note presents data on a uniquecritical state angle the implication is that thefailure criterion of a very loose sand is accuratelydescribed by the mohr coulomb condition whichgives the known six sided pyramid in principalstress space the test data on dense as well as loose hostunsand are also used to study the rate of dilation this topic was extensively treated by bolton 1986 and it is now generally accepted that thetriaxial rate of dilation coincides with the rate ofdilation found in plane strain tests followingroscoe 1970 bolton used an angle of dilatancyl

3m analytical method evaluation of shaft friction of bored piles in sands abstractthis study presents 3m an analytical method to estimate the skin friction of bored piles in sands it is based on the fundamental mechanic behavior of sands and keeps track of the major mechanisms occurring in the soil close to the pile during loading these include the development of a shear band its potential expansion as induced by soil dilatancy and the ensuing increment of horizontal stresses owing to the restraining effect of surrounding soils the resulting analytical equations are easy to apply and insert in a worksheet the procedure to evaluate the shear band expansion is calibrated against results of direct shear tests at constant normal load whereas the increment of horizontal stresses is evaluated by the closed form solution for the expansion of a cylindrical cavity into a dilatant elastic perfectly plastic medium the effectiveness of the 3m method in predicting shaft friction has been checked against numerical results centrifuge and full scale pile load tests nevertheless pr

carbon isotope records of the early jurassic toarcian oceanic anoxic event from the valdorbia umbria marche apennines and monte mangart julian alps sections palaeoceanographic and stratigraphic implications the toarcian oceanic anoxic event ca 183 ma coincides with a global perturbation marked by enhanced organic carbon burial and a general decrease in calcium carbonate production probably triggered by changes in the composition of marine plankton and elevated carbon dioxide levels in the atmosphere this study is based on high resolution sampling of two stratigraphic successions located in valdorbia umbria marche apennines and monte mangart julian alps italy which represent expressions of the toarcian oceanic anoxic event in deep water pelagic sediments these successions are characterized by the occurrence of black shales showing relatively low total organic carbon concentrations compared with coeval strata in northern europe generally 2 and low hydrogen indices on this basis they are similar to other toarcian black shales described from the tethyan region the positive and negative carbon isotope records from the two localities permit a high resolution correlation such that ammonite biostratigraphy information from valdorbia can be transferred to those parts of the monte mangart section that lack these fossils spectral analyses ofd 13 corg values and of caco3 percentages from the sedimentary records of both the valdorbia and monte mangart sections reveal a strong cyclic pattern best interpreted as an eccentricity signal which hence implies a duration of ca 500 kyr for the negative carbon isotope excursion based on the carbon isotope curves obtained the high resolution correlation between the italian successions and a section in yorkshire northern europe confirms the supposition that the apparent mismatch between the dating of the toarcian oceanic anoxic event in the boreal and tethyan realms is an artefact of biostratigraphy

geochemistry of modern brachiopods applications and implications for oceanography and paleoceanography abstract modern rhynchonellida terebratulida thecideida and a few inarticulated brachiopods were collected live or soon after death at 30 locations from depths of 2 3940 m from the equator to high latitudes covering the atlantic pacific indian caribbean and mediterranean oceans seas well preserved fibers of the secondary layer combined with sr 450 1928 mg kg mn 1 199 mg kg and fe 1 610 mg kg contents confirm with few exceptions the excellent preservation of the modern brachiopod material evaluation of the stable isotope compositions was conducted on 276 specimens and on 374 published samples for a total database of 650 samples from 80 locations it revealed that oxygen isotope incorporation into shell calcite secondary layer of modern articulated brachiopods in most cases occurs in equilibrium with the ambient water and as such reflects surrounding environmental conditions thecideida as a group shallow water and low latitude incorporate oxygen isotopes 3 04 to 0 35 into shell calcite in equilibrium with their ambient water a large majority of genera and species of the terebratulida shallow water and low mid latitude also incorporate oxygen 2 30 to 3 48 into shell calcite in isotopic equilibrium with their surrounding water in contrast equilibrium incorporation of oxygen isotopes into shell calcite by the rhynchonellida is uncertain but a vital effect probably applies to the craniida the question of equilibrium disequilibrium incorporation of carbon isotopes into shell calcite of modern brachiopods remains unresolved at this time isotope compositions range up to 4 5 5 6 and 1 5 for 13 c and up to 5 5 5 9 and 0 3 for 18 o for shallow water low mid and high latitude brachiopods respectively strontium isotopes of modern brachiopods as expected show no significant variation with location latitude water depth temperature salinity and general water conditions once local habitat and ecological influences of fossil brachiopods from similar latitudes are considered their isotopic elemental values should be valuable diagenetic indicators and important oceanographic chemostratigraphic proxies

drilled shaft side friction in gravelly soils to evaluate side friction 28 axial tension uplift load tests were performed on drilled shafts in soil profiles ranging from uniform medium sand through well graded sandy gravel typical load displacement curves for skin friction in gravelly soils were developed measured load capacities were compared with capacities computed using equations proposed by reese and o neill meyerhof and kulhawy reasonable agreement between measured and computed capacities was generally found for sandy profiles however measured capacities were typically two to four times higher than predicted at sites where the gravel fraction was over 50 additional load test data for gravelly soils were collected and combined with the data from utah load tests based on this data set modifications to the design equations were then developed to predict ultimate side friction capacity better while still maintaining a margin of safety

δ18o and δ13c values of modern brachiopod shells abstract researchers have not rigorously tested the hypothesis that calcite from modern brachiopod shells is precipitated in oxygen isotope equilibrium with ambient seawater isotopic variability at the intraspecimen and intertaxon levels has not been examined without such data for modern brachiopods similar data from ancient brachiopods cannot be accurately interpreted in this study a survey is made of 18 o and 13 c values of terebratulid rhynchonellid thecideidine and craniacean brachiopods from antarctica the bay of fundy curacao japan new zealand norway puget sound palau sicily and south africa this suite of samples provides a wide range of taxonomic levels temperatures salinities and depositional environments for evaluating the degree of isotopic equilibrium attained during precipitation of brachiopod calcite new data indicate that modem brachiopod calcite is not always precipitated in oxygen and carbon isotope equilibrium with ambient seawater calcite from the primary layer and specialized shell structures hinge brachidium foramen interarea muscle scars are depleted in both 18 o and 13 c a characteristic of biological fractionation or vital effects often found in other calcerous marine organisms our findings suggest that these portions of the brachiopod shell should be avoided during sampling of ancient brachiopods secondary layer calcite the material most often analyzed in ancient brachiopods has higher 18 o and 13 c values which approach and sometimes correspond with predicted equilibrium values therefore secondary layer calcite is the most suitable portion of the brachiopod shell for use as an ancient seawater proxy although near equilibrium precipitation in secondary layer calcite is encouraging to those studying the isotopic composition of ancient oceans these data come with caveats large intraspecimen variability in the 18 o values of secondary layer calcite 1 in some samples limits the use of brachiopods as precise indicators of the 18 o value or temperature of ancient seawater the 18 o and 13 c values of secondary layer calcite deviate from predicted equilibrium values toward the lower values of the primary layer and specialized shell structures indicating a measurable vital effect in most cases measured 18 o values are lower than the calculated equilibrium values dictated by seasonal variations in the 18 o value and temperature of seawater ontogenetic variations in the 13 c values of secondary layer calcite have also been measured and must be assessed when interpreting ancient data modern brachiopods occur in a wide range of seawater salinities and temperatures therefore the relation between salinity and the 18 o value of seawater must be known to correctly calculate the temperature of calcite precipitation from secondary layer 18 o values errors of up to 15 c are found if ambient seawater is assumed to have a constant 18 o value e g 0 smow and the 18 o values of secondary layer calcite are used to calculate temperature coupled with vital effects and intraspecimen variability these errors can obscure the resolution of secular variations in the rock record

k o ocr relationships in soil the relationships between k o and ocr are investigated for primary loading unloading reloading conditions the study reviews laboratory data from over 170 different soils and presents an approach common to clays silts and sands simple empirical methods for predicting k o for normally consolidated and overconsolidated soils are evaluated the validity of the methods is supported by statistical analyses on the basis of the findings only the effective stress friction angle o and prior stress history ocr and ocrmax are needed to predict approximate values of k o

ca isotope study of ordovician dolomite limestone and anhydrite in the williston basin implications for subsurface dolomitization and local ca cycling abstract a difference of 0 61 is reported between dolomite 1 66 and its precursor limestone 1 05 in the yeoman formation red river equivalent of the williston basin southeastern saskatchewan the significance of the large difference found and the preference for light isotope enrichment in the dolomite is evaluated with assistance from 87 sr 86 sr ratios and dolomitization models previously proposed for the studied rocks in particular i explore the possibility that 44 ca values in dolomite reflect the 44 ca values of the dolomitizing fluids without any correction for mineral fluid fractionation this hypothesis is based on recent studies showing negligible isotopic fractionation between carbonates and ca 2 bearing waters at very low precipitation rates fantle and depaolo 2007 jacobson and holmden 2008 if correct calcium isotopes hold promise as a tool for discriminating among numerous hydrological models of dolomite formation as a case in point the 44 ca value of the yeoman dolomite 1 66 is too low to reflect ca derived from the following sources 1 the original limestone 1 05 2 overlying beds of anhydrite 1 28 or 3 evaporated seawater 0 25 paleozoic carbonates ranging as low as 1 7 appear to be the lightest source of ca in the basin succession suggesting that the mg containing dolomitizing fluid was a connate water with a previous history of water rock interactions with paleozoic carbonates possibly involving earlier episodes of dolomitization and light ca release into migrating basinal fluids the relatively high seawater 44 ca values inferred from measurements of yeoman limestone and lake alma anhydrite suggest that seawater in the williston basin 450 ma was 0 22 0 46 higher in 44 ca than the contemporaneous ocean based on globally distributed brachiopods farkas et al 2007 this finding suggests that 44 ca values preserved in the deposits of epeiric seas may bias the 44 ca reconstruction of the ocean secular record if local ca cycling effects are not taken into account equations describing the isotope balance of ca in an epeiric sea indicate that seawater 44 ca values may be higher lower or equal to the 44 ca value of the ocean depending on the sizes of local scale ca deposition and weathering fluxes in relation to seawater ca exchange fluxes

significant contribution of authigenic carbonate to marine carbon burial carbon is removed from the earth s surface through the formation and burial of carbon bearing rocks and minerals an analysis of pore water profiles collected from marine sediments around the globe suggests that the precipitation of authigenic calcium carbonate accounts for around 10 of the carbonate that accumulates in marine sediments globally carbon is removed from the earth s surface through the formation and burial of carbon bearing rocks and minerals1 2 the formation of calcium carbonate and its burial in marine sediments accounts for around 80 of the total carbon removed from the earth s surface however the fraction of calcium carbonate that precipitates in the oceans versus that which precipitates authigenically in marine sediments is unclear here we compile measurements of the calcium concentration of pore fluids collected at 672 seafloor sites around the globe to calculate the global flux of calcium within marine sediments we use these data combined with alkalinity measurements of pore fluids to quantify authigenic calcium carbonate precipitation we estimate that the net calcium flux into marine sediments that can be ascribed to authigenic carbonate precipitation amounts to around 1 1012 mol yr 1 as such we estimate that authigenic carbonate precipitation accounts for at least 10 of global carbonate accumulation we show that much of the precipitation occurs along the eastern margins of ocean basins where organic matter delivery to the sea floor is likely to be high we suggest that authigenic calcium carbonate precipitation represents a non negligible component of the global carbon cycle

evidence for major environmental perturbation prior to and during the toarcian early jurassic oceanic anoxic event from the lusitanian basin portugal the timing and causal relationships between the pronounced negative c isotope excursion and paleoenvironmental perturbations associated with the toarcian oceanic anoxic event early jurassic remain unclear particularly because biotic crises and carbonate production decrease appear to have been initiated earlier than the main c isotope anomaly here we present a new quantification of late pliensbachian early toarcian calcareous nannofossils abundance and size from the peniche reference section portugal together with o and c isotope records of well preserved brachiopod shells from the same section the brachiopod shell 13c curve parallels that of bulk carbonate and records two pronounced negative isotopic excursions close to the pliensbachian toarcian boundary 2 and during the toarcian oceanic anoxic event 3 5 our results indicate that both c isotope negative excursions were characteristic of benthic and shallow water environments suggesting that these two carbon cycle perturbations affected all epioceanic reservoirs coeval shifts toward lower values of brachiopod oxygen isotope compositions and closely correlated northward migrations of mediterranean ammonite fauna suggest that both events coincided with major rises in seawater temperatures probably as a result of increased co2 levels and enhanced greenhouse conditions co2 induced changes in seawater chemistry likely affected the calcification potential of both neritic and pelagic systems as evidenced by synchronous drops of platform derived carbonate accumulation and drastic reductions in size 3 m of the main pelagic carbonate producer schizosphaerella we suggest that the early toarcian paleoenvironmental crisis occurred in two distinct episodes that were most likely related to two successive phases of intense volcanic degassing in the karoo ferrar province

global and local forcing of early toarcian seawater chemistry a comparative study of different paleoceanographic settings paris and lusitanian basins 1 the early toarcian was characterized by two large perturbations to the carbon cycle a positive trend associated with increased organic matter burial and ocean anoxia and a pronounced negative carbon isotope excursion cie we contrast the geochemical evolution in the carbonate phases of two successions one from the paris basin sancerre core comprising black shales the other from the lusitanian basin peniche section with very minor lithological expression of bottom water anoxia our aim was to identify whether these carbon cycle perturbations were related and differentiate between the common global versus regional expressions of the biogeochemical response and ocean chemistry our results highlight contrasts in timing of different phases of anoxia in both locations through the widely documented negative cie widespread anoxic conditions were not a necessary prerequisite for generating a pronounced cie as required by the recycling so called kuspert model the production of carbonate simultaneously dropped during the 13c negative shift in both locations likely in response to lowered seawater saturation rate induced by substantial absorption of co2 from the atmosphere the recovery interval was accompanied by a rapid reestablishment of seawater alkalinity and primary and carbonate productivity in epicontinental seas as evidenced by high 13c and sr ca in contrast with the more open ocean regime in the lusitanian basin our results confirm that parallels can be draw between the ocean productivity response and feedback during the toarcian cie and the petm both events are characterized by ocean acidification and reduced pelagic calcification followed by a peak in nearshore coccolith productivity which could have helped the recovery from the perturbation

deciphering kinetic metabolic and environmental controls on stable isotope fractionations between seawater and the shell of terebratalia transversa brachiopoda this study presents carbon and oxygen stable isotope data obtained from high resolution sampling 500 m of the brachiopod terebratalia transversa from the san juan islands washington state usa the aim of this study is to unravel the respective effects of physiological and environmental controls on the stable isotopic composition of brachiopod shell calcite based on an sem study of the shell a three dimensional sampling was performed in order to investigate carbon and oxygen isotope variations along isochrons and ontogenetic transects the primary as well as the outer part of the secondary shell layer display large and variable isotopic offsets as high as 7 for 13c and 6 for 18o relative to expected equilibrium values the significant positive correlations between 18o and 13c values indicate that the isotopic compositions of these shell domains are mainly controlled by kinetic isotope fractionation effects the ontogenetic 13c and 18o variations can be used to establish a growth curve of the studied specimen whose age is estimated close to 8 years the extent of apparent o 18 disequilibrium observed in this study is about as large as any yet measured in any organism which makes this brachiopod an interesting and important case the carbon and oxygen isotope compositions increase from the outer towards the inner part of the secondary layer where they reach values of 0 0 8 and 0 8 to 0 2 respectively corresponding calculated temperatures are between 12 and 13 8 c and fall in the range of seawater temperatures recorded off the san juan islands 7 13 c these results suggest that the calcite fibres were secreted more and more slowly during the thickening of the shell throughout the animal s life finally approximating isotopic equilibrium this study illustrates that the stable isotopic composition of the modern brachiopod t transversa is predominantly influenced by kinetic fractionation and to a minor degree by metabolic effects except for the innermost part of the shell the measured isotope ratios do not reflect environmental conditions during shell precipitation it remains to be tested by comparable studies whether other modern brachiopod species or even fossil brachiopods reflect comparable fractionation effects these results point out the need for re examination of paleozoic oceanographic conditions

calcareous nannoplankton changes across the early toarcian oceanic anoxic event in the western tethys 1 calcareous nannoplankton were profoundly affected by environmental perturbations coincident with the early toarcian oceanic anoxic event t oae we quantify the abundance of nannofossils across the t oae at three locations in western europe where the event is marked by a prominent negative carbon isotope excursion cie data were treated by statistical analysis and the shannon diversity index was applied in order to describe nannofossil assemblage changes related to paleoenvironmental evolution in the basal toarcian before the t oae high proportions of taxa with an affinity for low temperature e g p liasicus t patulus bussonius occurred this observation is consistent with interpretations of published oxygen isotope records during the t oae the lowest abundance of nannofossils is observed but there is a peak of a coccolith calyculus from an organism that probably thrived in low saline surface waters depleted of nitrate at the end of the perturbation the lowest diversities of nannofossils occurred and assemblages are dominated by crepidolithus crassus a deep dweller this interval corresponded to progressive reoxygenation of deep water and the reoccupation of the deep photic zone by nannoplankton the highest abundance of nannofossils is recorded above the cie and testifies to the recovery of the entire nannoplankton community the t oae was widespread perhaps global and probably linked to major changes in the atmosphere and hydrosphere however the record of this event varies in the basins surrounding the western tethys suggesting regional imprints on the global signal the regional variability may attest to establishment of effective connections between the arctic and tethys oceans which allowed cool low saline water formed at high latitudes to stream toward the western tethys

calcium isotope evidence for dramatic increase of continental weathering during the toarcian oceanic anoxic event early jurassic abstract the early toarcian was punctuated by pulses of massive carbon injection that are thought to have triggered through increased greenhouse conditions elevated continental discharge and nutrient input marine anoxia seawater acidification and species extinctions nevertheless the mode and tempo of changes in continental weathering across this interval remains highly debated leading to considerable uncertainty about the main causes of these perturbations in this study we present calcium isotope measurements 44 40ca of well preserved brachiopods and bulk rock samples from the hemipelagic strata of pliensbachian toarcian age of peniche in portugal in order to constrain changes in the calcium cycle and hence changes in continental weathering during the early toarcian the data reveal a similar trend as carbon isotope data from the same section and show negative excursions of about 0 5 at the pliensbachian toarcian transition pl to and at the base of the toarcian oceanic anoxic event t oae interval the comparison of 44 40ca ratios recorded in brachiopods and bulk rock corrected for variable dolomite contribution indicates that these excursions reflect changes in the global isotopic composition of seawater rather than changes in the dominant mineralogy of calcifying organisms or in hydrological budget of the considered basin box modeling results suggest that the pl to and t oae 44 40ca excursions can be explained by a transient 90 decrease of carbonate accumulation due to seawater acidification followed by a 500 increase in continental weathering rates the sharp increases in continental weathering inferred from the 44 40ca ratios seem overall consistent with lower toarcian sedimentological and biotic records that document rapid crises in carbonate production followed by episodes of increased calcium carbonate burial nevertheless the maximum of carbonate burial recorded by most nw european basinal successions occurs several hundreds of kyrs after that predicted by box modeling results this mismatch either implies that the european records of carbonate accumulation do not reflect global trends or that the fundamental processes related to the removal of excess alkalinity caused by increased continental weathering are more complex than previously appreciated based on the amount of ca input simulated by box modeling the injection of tens of thousands of gigatons of carbon with an isotopic composition 13c comprised between 6 and 14 appears as the most likely causes of the 13c excursions characterizing these two events these results indicate that environmental and biotic changes of the pl to and t oae were mainly caused a cascade of environmental changes triggered by the massive carbon emissions from the karoo ferrar volcanism

hydrothermal venting of greenhouse gases triggering early jurassic global warming abstract the climate change in the toarcian early jurassic was characterized by a major perturbation of the global carbon cycle the event lasted for approximately 200 000 years and was manifested by a global warming of 6 c anoxic conditions in the oceans and extinction of marine species the triggering mechanisms for the perturbation and environmental change are however strongly debated here we present evidence for a rapid formation and transport of greenhouse gases from the deep sedimentary reservoirs in the karoo basin south africa magmatic sills were emplaced during the initial stages of formation of the early jurassic karoo large igneous province and had a profound influence on the fate of light elements in the organic rich sedimentary host rocks total organic carbon contents and vitrinite reflectivity data from contact aureoles around the sills show that organic carbon was lost from the country rocks during heating we present data from a new type of geological structures termed breccia pipes rooted in the aureoles within the shale of the western karoo basin the breccia pipes are cylindrical structures up to 150 meters in diameter and are mainly comprised of brecciated and baked black shale thousands of breccia pipes were formed due to gas pressure build up during metamorphism of the shales resulting in venting of greenhouse gases to the toarcian atmosphere mass balance calculations constrained by new aureole data show that up to 1800 gt of co2 was formed from organic material in the western karoo basin about 15 times this amount of co2 27 400 gt may have formed in the entire basin during the intrusive event u pb dating of zircons from a sill related to many of the pipes demonstrates that the magma was emplaced 182 5 0 4 million years ago this supports a causal relationship between the intrusive volcanism the gas venting and the toarcian global warming

warming driven mass extinction in the early toarcian early jurassic of northern and central spain correlation with other time equivalent european sections abstract causes of the major mass extinction recorded during the early toarcian early jurassic are controversial many authors have concluded that the mass extinction is caused by the widespread oceanic anoxia derived from a postulated early toarcian oceanic anoxic event etoae supposedly synchronous in all basins and global in extent another group of papers links the mass extinction with a major climate change that occurred synchronously with the mass extinction the results of the study of five sections of the uppermost pliensbachian and lower middle toarcian deposits located in northern and central spain are presented detailed ammonite based biostratigraphy coupled with stable isotope analysis of belemnite calcite and bulk carbonates as well as total organic carbon toc analyses have been performed in all sections records of the vertical distribution of mainly benthic fossils have been compiled in four of the studied sections results obtained in the spanish outcrops have been compared and correlated with other european sections the excellent mutual relation between the patterns of the early toarcian progressive warming and the concomitant progressive losses of species evidences a cause and effect relationship between the increase of temperature and the mass extinction from an uppermost pliensbachian cooling interval warming started at the lower toarcian tenuicostatum zone increase of average seawater palaeotemperature is associated with a progressive and substantial drawdown in the number of species of nektonic planktonic and benthic organisms representing the extinction interval a prominent increase in seawater temperature occurred around the lower toarcian tenuicostatum serpentinum zonal boundary average temperatures at the serpentinum zone increased about 7 c marking the extinction boundary the high temperatures continued during the middle toarcian bifrons chronozone representing the repopulation interval the anoxia linked to the postulated etoae cannot be the responsible for the mass extinction because it has been synchronously recorded in the oxygenated environments of many european and northern african platforms deposition of laminated organic rich black shale facies above 5 wt toc indicating anoxic environments was mostly confined geographically to the western europe euxinic basin and mainly deposited after the extinction event during the interval of faunal recovery

a carbon isotope perturbation at the pliensbachian toarcian boundary evidence from the lias group ne england a perturbation in the carbon isotope record at the time of the pliensbachian toarcian boundary 184 ma in the early jurassic is reported based on new data from yorkshire england two sharp 13 c org negative excursions each with a magnitude of 2 5 and reaching minimum values of 28 5 are recorded in the bulk organic matter record in sediments of latest pliensbachian to earliest toarcian age a similar pattern of negative carbon isotope excursions has been observed at the stage boundary in the sw european section at peniche portugal in 13 c carbonate 13 c wood and 13 c brachiopod records the isotopic excursion is of interest when considering the genesis and development of the later toarcian oceanic anoxic event oae as well as the second order global extinction event that spans the stage boundary furthermore the isotope excursion potentially provides a chemostratigraphic marker for recognition of the stage boundary which is currently achieved on the basis of different ammonite faunas in the nw european and tethyan realms

scale effects on tension capacity for rough piles buried in dense sand this paper examines the effect of pile diameter on the unit shaft friction that can develop on a pile in sand the study is based on a series of tension tests conducted on centrifuge model piles with a range of pile diameters and average initial stress levels the inferred significant increases in lateral effective stresses on the shafts of these piles at peak capacity are shown to be consistent with the normal displacement dilation stiffness relationship measured in appropriate constant normal stiffness cns interface tests the determination of the lateral stress increases and hence shaft capacity also requires measurement or prediction of the non linear cavity expansion stiffness of the sand surrounding the pile shaft predictions obtained for this stiffness using a numerical technique indicate that the operational stiffness surrounding a model pile is well below that assuming the very small strain elastic stiffness and that the degree of normal displacement and hence the lateral stress increa

experimental study of the effect of excavation on existing loaded piles abstractexcavation beneath an existing building to add a new basement is an effective mean to expand underground space that caters to the increased need of space in urban areas because piles serve

astronomical forcing and chronology of the early toarcian early jurassic oceanic anoxic event in yorkshire uk 1 during the early toarcian 183 ma ago a high rate of organic carbon burial globally over a brief interval of time has led to the recognition of a major oceanic anoxic event oae a pronounced negative excursion in the carbon isotope composition of marine organic matter marine carbonate and terrestrial plant material is a key feature of this event but the precise timescale and cause s of this isotopic anomaly are debated associated with the negative carbon isotope excursion is evidence for a coeval rise in seawater palaeotemperature an increase in continental weathering rates and the mass extinction of marine invertebrate species the early toarcian oae provides evidence for the earth s response during rapid climate change and critical to our understanding of the event is a high resolution timescale that allows us to quantify the rates duration and lead lag times of environmental processes in this study we present 2743 new high resolution organic carbon sulphur and carbonate concentration data from samples of well preserved organic rich mudrocks spanning the early toarcian oae in yorkshire uk we have used these data to document the geochemical changes and significantly extend and refine the astronomical timescale across this event our detailed analysis of the relationship between astronomical forcing and carbon isotope changes in both yorkshire and a section from peniche portugal indicates that astronomical forcing paced the timing of major shifts in 13c and hence climate in both sections our analyses also demonstrate that there was a marked increase in the relative strength of astronomical forcing recorded at the onset of the oae and that the recorded nature of astronomical forcing changed during the event both the yorkshire and peniche cyclostratigraphies suggest that one astronomical forcing parameter paced environmental change through the 13c event and that this parameter was obliquity or precession

the significance of an early jurassic toarcian carbon isotope excursion in haida gwaii queen charlotte islands british columbia canada abstract during the early toarcian there was a significant disruption in the short term active carbon reservoir as revealed by carbon isotope records which show a broad positive shift that is interrupted by a large 5 7 negative excursion 13 c org carbon isotope excursion co occurs with the deposition of organic rich shales in many areas this perturbation in carbon isotopes is thought to be indicative of severe climate change and marine anoxia the two leading hypotheses as to the cause of this event invoke either global or regional controls here we present carbon isotope data from haida gwaii british columbia canada showing a significant perturbation within a temporally constrained early toarcian succession that was deposited in the northeastern paleo pacific ocean these data reinforce the concept that the short term active carbon reservoir was affected globally and assist with the correlation of ammonite zonal schemes between western north america and europe the 13 c org data show a broad positive shift that is interrupted by a sharp and pronounced negative excursion of 7 8 5 in 13 c wood in the early toarcian kanense zone this negative excursion also coincides with increasing total organic carbon toc from 0 4 to 1 2 these data suggest that the early toarcian carbon isotope perturbation was indeed global and imprinted itself on all active global reservoirs of the exchangeable carbon cycle deep marine shallow marine atmospheric

settlement of piled foundations a numerical code for the prediction of the settlement of pile groups and piled rafts is presented the code is based on the interaction factors method the non linearity is simulated as suggested by caputo and viggiani that is concentrating it at the pile soil interface in the linear range the accuracy is checked against known benchmark solutions a standard procedure based on the results of load tests on single piles is suggested for the evaluation of soil properties and for the implementation of the analysis in real cases nineteen well documented case histories are then analysed calculating for each of them a linear elastic an equivalent linear elastic and a non linear solution five out of the 19 cases are illustrated in some detail to allow a deeper insight into the procedure in all but one of the analysed cases the predicted values of the average settlement are within 20 of the observed values the maximum differential settlement is predicted with slightly lesser accuracy for foundation

shell structure patterns and trends of oxygen and carbon stable isotopes in modern brachiopod shells this study investigates 13c and 18o variations in the shells of modern brachiopods representing all extant groups of calcite precipitating brachiopods collected live from 8 locations sem examinations determined the ultrastructural characteristics of each species prior to isotope analyses 13c and 18o analyses of shell carbonate were carried out with samples representing disparate morphological features and ultrastructural shell layers of both ventral and dorsal valves generally 18o values from the fibrous secondary or prismatic tertiary shell layers of the articulated terebratulida and rhynchonellida species were in oxygen isotopic equilibrium with ambient seawater isotopic temperatures extrapolated from these values are close to measured annual mean seawater temperatures 18o values were relatively unaffected by shell specialisation the only exception was antarctic species liothyrella uva which did not have a complete tertiary shell layer typical of this genus and had 18o values of the innermost layer strongly correlated with 13c and mostly not in oxygen isotopic equilibrium with ambient seawater with the exception of the rhynchonellid notosaria nigricans the outer primary layer material was depleted in 13c and 18o and highly variable inclusion of this material even as part of a whole shell sample could lead to misinterpretation of seawater temperature therefore only fossil secondary layer material should be used the anomalous articulated thecideidine brachiopod thecidellina barretti is composed of mainly primary shell material and was not in oxygen isotope equilibrium 18o values from the laminar secondary layer material of the inarticulated craniida are highly variable therefore these species are not recommended for use as palaeoenvironmental proxies this study suggests caution when employing fossil brachiopod shells with similar ultrastructures to modern craniid and thecideidine brachiopods the carbon isotope composition is highly variable in all of the brachiopods studied analysis of samples from specialised regions of the secondary shell layer show a pattern of depletion in 13c relative to non specialised secondary material the carbon isotope variability is independent of 18o and is repeated in most of the articulated species regardless of geographical location this is possibly a vital effect produced by metabolic prioritisation

the coefficient of earth pressure at rest laboratory experiments on undisturbed specimens of a large number of soft clay deposits as well as previous measurements on clays and granular soils were used to examine and explain the magnitude and behavior of the coefficient of earth pressure at rest k0 i after sedimentation primary consolidation ii during secondary compression aging iii after active or passive preshearing away from the laterally constrained condition iv during a decrease in effective vertical stress and v during an increase in effective vertical stress in the recompression or compression range in terms of the slope of the effective horizontal versus effective vertical stress path the behavior of k0 is explained using the concept of mobilized angle of friction in laterally constrained deformation condition the jaky equation provides in terms of the angle of internal friction a good estimate of k0 of sedimented normally consolidated young clays and granular soils as well as of of presheared clays and sands

basalts of the northeastern deccan traps india isotopic and elemental geochemistry and relation to southwestern deccan stratigraphy the northeastern deccan traps include flows with strong isotopic and elemental affinities to lavas in the southwest as far as 900 km away however many of the northeastern flows show a negative correlation of 206pb 204pb with end t and positive correlation of 206pb 204pb with 87sr 86sr t distinct from any of the isotopic fields for the southwestern formations this array from end t 5 87sr 86sr t 0 7041 206pb 204pb 17 9 to end t 0 87sr 86sr 0 7068 206pb 204pb 20 5 overlaps the ambenali formation fm field and runs toward that of the common signature peng et al 1994 that appears to have been an important magma type in several of the lower formations of the southwest this array appears to represent mixing between an ambenali type and 1 a common signature end member or 2 an end member with even higher 206pb 204pb and 87sr 86sr and lower end than the common signature such mixing has been postulated but not documented previously for the deccan lavas isotopically and chemically indistinguishable from the ambenali fm form the tops of sections near jabalpur and chikaldara beneath them are flows that chemically resemble the poladpur fm which sits immediately below the ambenali in the southwest and several lavas similar to the khandala fm beneath the poladpur and intervening bushe fm in the southwest given the general stratigraphic correspondence with the southwestern sequence many of these northeastern flows may be petrogenetically related to the respective southwestern formations lavas with broadly poladpurand khandala like elemental compositions are also abundant in a thick section south of mhow several other mhow area flows resemble the distinctive bushe fm however nearly all of the poladpur and khandala like northeastern deccan lavas analyzed have higher 206pb 204pb man any southwestern poladpur or khandala fm basalts if they indeed are related petrogenetically to these formations many of the northeastern magmas interacted less with low 206pb 204pb continental material and thus must have erupted from different feeder systems

basinal restriction black shales re os dating and the early toarcian jurassic oceanic anoxic event 1 profiles of mo total organic carbon toc through the lower toarcian black shales of the cleveland basin yorkshire united kingdom and the posidonia shale of germany and switzerland reveal water mass restriction during the interval from late tenuicostatum zone times to early bifrons zone times times which include that of the putative early toarcian oceanic anoxic event the degree of restriction is revealed by crossplots of mo and toc concentrations for the cleveland basin which define two linear arrays with regression slopes ppm of 0 5 and 17 the slope of 0 5 applies to sediment from the upper semicelatum and exaratum subzones this value which is one tenth of that for modern sediments from the black sea mo toc regression slope 4 5 reveals that water mass restriction during this interval was around 10 times more severe than in the modern black sea the renewal frequency of the water mass was between 4 and 40 ka the mo toc regression slope of 17 applies to the overlying falciferum and commune subzones the value shows that restriction in this interval was less severe and that the renewal frequency of the water mass was between 10 and 130 years the more restricted of the two intervals has been termed the early toarcian oceanic anoxic event but is shown to be an event caused by basin restriction local to nw europe crossplots of re os and mo against toc show similar trends of increasing element concentration with increase in toc but with differing slopes together with modeling of 187 os 188 os and d 98 mo the element toc trends show that drawdown of re os and mo was essentially complete during upper semicelatum and exaratum subzone times mo toc regression slope of 0 5 drawdown sensitized the restricted water mass to isotopic change forced by freshwater mixing so that continental inputs of re os and mo via a low salinity surface layer created isotopic excursions of up to 1 3 in d 98 mo and up to 0 6 for 187 os 188 os restriction thereby compromises attempts to date toarcian black shales and possibly all black shales using re os chronology and introduces a confounding influence in the attempts to use d 98 mo and initial 187 os 188 os for palaeo oceanographic interpretation