middle and late jurassic radiolarian palaeoecology versus carbon isotope stratigraphy abstract jurassic radiolarians are sensitive to palaeoclimatic palaeoceanographic changes recorded by the stable carbon isotope curve carbon isotopic variations have been linked to changes in ocean structure productivity and concentrations of greenhouse gases in the atmosphere in the middle upper jurassic terminilletto section of the umbria marche sabina apennines central italy well preserved radiolarians are present in a sequence of cherty limestones interbedded with platform derived carbonates the 13 c curve in the aalenian kimmeridgian interval indicates three main positive 13 c events in the lower bajocian late bathonian lower callovian and middle oxfordian the positive 13 c shifts are correlated to increases in visible chert in the outcrop and may represent periods of increased biological productivity of surface sea water spumellaria nassellaria ratios and the fluctuations of relative abundance of selected genera tend to correlate with 13 c and chert abundance values and seem to be related to episodes of high nutrient mobilisation from the base of the bajocian the radiolarian associations show a slight tendency towards diversification coincident with increasing 13 c values in the upper part of the middle bajocian last appearances prevail over first appearances associated with the peak of the 13 c event this may indicate maximum eutrophic conditions coincident with the late bathonian early callovian positive 13 c shift the radiolarian associations record a different trend with respect to the bajocian event when the 13 c values are increasing to a maximum radiolarian associations tend to be reduced in species diversity followed by a small diversification trend when the 13 c values are decreasing we speculate that during the callovian a more stressful palaeoenvironment due to high level of eutrophication is indicated by the combination of high productivity of biogenic silica and low carbonate input although varying preservational conditions may have influenced the observed trends in the radiolarian associations the good correlation between changes of sedimentation patterns radiolarian assemblages and 13 c positive anomalies open interesting avenues for further investigations concerning the palaeoecology of mesozoic radiolarians

paleoceanographic modeling of temperature salinity profiles from stable isotopic data temperature salinity t s profiles in ancient seawater can be estimated from oxygen isotopic compositions of well preserved calcitic fossils sampled from known paleodepth gradients the proposed model uses isotopic compositions of fossils to determine possible combinations of temperature and salinity during deposition given estimates of average salinity isotopic composition and net global hydrologic fractionation for ancient oceans increasing density with depth constrains those combinations to narrow ranges this graphic method superposes curves for density and isotopic composition in t s space to reveal possible ancient t s profiles application of this method to oxygen isotope data from ordovician brachiopods deposited on the eastern continental slope of north america demonstrates its usefulness and yields a stable seawater column in which brackish intermediate waters overlie warmer more saline deep waters

stable isotopic studies of nautilus macromphalus sowerby new caledonia and nautilus pompilius l fiji abstract two specimens of nautilus macromphalus sowerby from new caledonia and two specimens of nautilus pompilius l from fiji have been selected for stable isotope analysis of all septa these animals were captured at depths of 80 m and 200 m respectively the early formed septa were also analyzed from three additional specimens of n macromphalus captured in new caledonia at 300 400 m oxygen isotope compositions of septa from both populations are characterized by 1 an abrupt increase in su18o of 1 3 5 from septa 6 to 8 and 2 septum to septum variations in 13 and 18o which are roughly sympathetic and larger for carbon than oxygen septa from the fiji specimens are slightly depleted in 18o relative to those from new caledonia the isotopic step between septa 7 and 8 is interpreted to record the hatching of the embryo after development of the seventh septum marked 18o depletion of septa 1 7 evidently reflect non equilibrium metabolic isotope fractionation during embryonic groth stages or perhaps more likely a difference in the isotopic compositions of nepionic fluid and sea water the oxygen isotope compositions of septa 10 and higher and shell walls appear to closely approach isotopic equilibrium with sea water as demonstrated by a comparison of calculated isotopic and known temperatures for aragonite precipitation by an aquarium grown specimen a slightly warmer average environment of growth is indicated for the fiji samples

comparison of stable carbon and oxygen isotopes in picea glauca tree rings and sphagnum fuscum moss remains from subarctic canada stable isotope ratios from tree rings and peatland mosses have become important proxies of past climate variations we here compare recent stable carbon and oxygen isotope ratios in cellulose of tr

fossil wood carbon isotope stratigraphy of the non marine wealden group lower cretaceous southern england fossil wood carbon isotope data are presented for the wessex formation a non marine unit within the lower cretaceous valanginian barremian wealden group of the isle of wight and dorset southern england the carbon isotope values have a range 13 c c 26 6 to 19 8 that is consistent with that expected for mesozoic c 3 plants consideration of the isle of wight fossil wood carbon isotope data together with data from dorset allows construction of a composite fossil wood carbon isotope curve for almost the entire wealden group the new carbon isotope curve is in smooth continuity with data previously published from the overlying lagoonal vectis formation and marine lower greensand group of aptian age a tentative correlation with a tethyan reference carbon isotope curve allows the provisional application of stage level chronostratigraphy to the wealden group correlations suggest that the wealden group sediments are dominantly of hauterivian and barremian age and that the valanginian is either condensed or partially missing the carbon isotope data presented indicate that even during times of relative carbon cycle quiescence atmosphere co 2 faithfully tracks the carbon isotopic composition of the oceanic reservoir

detailed record of the mid oxfordian late jurassic positive carbon isotope excursion in two hemipelagic sections france and switzerland a plate tectonic trigger the oxfordian late jurassic was a time of widespread change in jurassic marine carbonate sedimentation patterns a marked positive excursion in 13 c is dated as middle oxfordian in age in this study we investigate if changes in carbonate sedimentation coincided with altered carbon cycling and climate we use c isotope records as a proxy for the evolution of the carbon cycle and compare 13 c trends with the evolution of sedimentation in a segment of the opening tethys seaway one of the studied sections is located in the subalpine basin of france trescleoux and oze the other in the swiss jura mountains liesberg carbon isotope stratigraphy of carbonate carbon locates the peak values of the middle oxfordian positive excursion to theantecedens andparandieri subzonesoftheplicatilisandtransversariumammonitezones respectively causesofthe excursionremain enigmatic theexcursion seems not to coincide with a global oceanic anoxic event but regionally enhanced organic carbon accumulation during the early and early middle oxfordian may be the cause of the increase in 13 c the excursion occurs during a time of progressive climate warming anditspeakvaluescoincidewiththefirstcalcareoussedimentsrecurringafteraperiodofreducedcarbonateaccumulationintheearly and early middle oxfordian the excursion is also time equivalent to a major reorganisation of global ocean currents the opening atlantic and tethys oceans combined with rising sea level led to the formation of an efficient circumglobal seaway we conclude that this favoured the widespread recurrence of carbonate producers by providing new habitats as a result ccarb burial increased leading to a lower corg ccarb burial rate and therefore to stabilisation and decrease in 13 c in the middle oxfordian thus the mid oxfordian positive excursion in carbonate c isotopes may reflect changes in the carbon cycle that were triggered by a copious reorganisation of the ocean current system caused by major plate tectonic movements 2007 elsevier b v all rights reserved

the mid oxfordian late jurassic positive carbon isotope excursion recognised from fossil wood in the british isles the carbon isotope ratios of fossil wood have recently been confirmed as a proxy for changes in the isotopic composition of palaeoatmospheres carbon isotope data from fossil wood samples collected from the jurassic oxfordian staffin shale formation on the isle of skye scotland boreal sub boreal ammonite zonation reveal a long term positive carbon isotope excursion of at least 3 this excursion reaches a maximum in the mid oxfordian and closely matches the carbon isotope ratios previously reported from belemnites collected from the same section and carbon isotope data from carbonates in other european sections this confirms that the mid oxfordian positive carbon isotope excursion affected the total exchangeable carbon reservoir fossilised wood samples collected at a higher stratigraphic resolution but over a shorter interval from the corallian group in dorset england antecedens parandieri and cautisnigrae subzones nw european ammonite zonation show considerable scatter in their carbon isotope ratios and no trends are discernable the combined isle of skye and dorset dataset shows that the long term oxfordian positive carbon isotope trend coincides with a long term relative sea level change and that the most positive carbon isotope ratios occur across the plicatilis transversarium biozonal boundary sub mediterranean ammonite zonation this implies that the carbon isotope excursion was not caused by the well documented rise in sea level in the transversarium zone although very low carbon isotope ratios from fossil wood samples are recorded from the nodular rubble member parandieri subzone of dorset there is not a sufficiently coherent signal to ascribe these values to the gas hydrate dissociation event previously hypothesized from the carbon isotope ratios of tethyan marine carbonates a microscopal analysis of the charcoalified debris from the staffin shale formation indicates a prevalence of the wood genus cupressinoxylon derived from a cheirolepidiaceaen conifer

carbon isotope record of the early jurassic toarcian oceanic anoxic event from fossil wood and marine carbonate lusitanian basin portugal thetoarcianoceanicanoxicevent oae intheearlyjurassic 183maago wascharacterizedbywidespreadnear synchronous deposition of organic rich shales in marine settings as well as perturbations to several isotopic systems characteristically two positive carbon isotope excursions in a range of materials are separated by an abrupt negative shift carbon isotope profiles from toarcian fossil wood collected in england and denmark have previously been shown to exhibit this large drop 7 i n 13 c values interpreted as due to an injection of isotopically light co2 into the ocean atmosphere system however the global nature of this excursion has been challengedonthebasisofcarbon isotopedatafromnektonicmarinemolluscs belemnites whichexhibitheavierthanexpectedcarbonisotope values here we present new data principally from fossil wood and bulk carbonate collected at centimetre scale from a hemipelagic section at peniche coastal portugal this section is low in organic carbon average toc 0 5 and the samples should not have suffered significant diagenetic contamination by organic carbon of marine origin the carbon isotope profile based on wood shows two positive excursions separated by a large and abrupt negative excursion which parallels exactly the profile based on bulk carbonate samples from the same section albeit with approximately twice the amplitude 8 in wood versus 3 5 in carbonate these data indicate thatthe negative carbon isotope excursion affected the atmosphereand by implication the global ocean as well the difference in amplitude between terrestrial organic and marine carbonate curves can be explained by greater water availability in the terrestrial environment during the negative excursion for which there is independent evidence from marine osmiumisotope records and plausibly changes in atmospheric co2 content for which independent evidence is also available the peniche succession is also notable for the occurrence of re deposited sediments their lowest occurrence coincides with the base of the negative excursionandtheirhighestoccurrencecoincideswithitstop thus slopeinstabilityandsedimentsupplycouldhavebeenstronglylinked to the global environmental perturbation an association that may misleadingly simulate the effects of sea level fall

calcareous nannofossil changes during the late callovian early oxfordian cooling phase calcareous nannofossil quantitative and biostratigraphic analyses integrated with carbon and oxygen stable isotopes were carried out on the core andra agence nationale pour la gestion des dechets radio actifs france htm 102 across the callovian oxfordian boundary drilled at cirfontaines en ornois department de haute marne eastern france calcareous nannofossil assemblages at the callovian oxfordian transition are dominated by the genus watznaueria an increase in abundance of biscutum spp and a group which consists of axopodorhabdus spp a atavus a rahla and a cylindratus podorhabdus grassei octopodorhabdus decussatus hexapodorhabdus cuvillieri family axopodorhabdaceae and triscutum spp correlates with a significantpositiveexcursionin 18 osuggestingthatthesegroupswereprobablyadaptedtocoolersurfacewaters apositiveincrease in 13 c values is coupled with high abundances of eutrophic taxa such as zeughrabdotus erectus biscutum spp and small sized watznaueria britannica and a decrease in abundance of the big and oligotrophic taxa schizosphaerella punctulata and watznaueria manivitae climate cooling across the callovian oxfordian boundary probably triggered a breakdown in stratification of surface waters leading to more intense nutrient recycling and higher primary productivity that favoured the shift in abundance of small sized eutrophic taxa in the east paris basin

comment on the mid oxfordian late jurassic positive carbon isotope excursion recognised from fossil wood in the british isles by c r pearce s p hesselbo a l coe palaeogeography palaeoclimatology palaeoecology 221 343 357

effects of dissociation on the shear strength and deformation behavior of methane hydrate bearing sediments abstract a series of tests were conducted in order to investigate the shear strength and deformation behavior of methane hydrate bearing sediments during dissociation using the thermal recovery method or depressurization method an innovative temperature controlled high pressure triaxial apparatus which can reproduce the in situ conditions of hydrate reservoirs was used the results indicate that 1 the failure strength of isotropically consolidated methane hydrate bearing sediments which dissociated completely using the thermal recovery method is less than that of pure toyoura sand however the initial stiffness and volumetric strain are higher than that of pure toyoura sand 2 the thermal recovery method will cause the failure of methane hydrate bearing sediments when the axial load is higher than the strength of methane hydrate bearing sediments after dissociation 3 the depressurization method will not cause collapse of methane hydrate bearing sediments during depressurization however water pressure recovery will lead to failure when the axial load is larger than the strength of the methane hydrate bearing sediments after dissociation 4 the depressurization rate shows little effect on the ultimate deformation of methane hydrate bearing sediments while the initial deformation rate increases with increasing depressurization rate 5 the larger the reduction of pore pressure the larger axial strain and volumetric strain

isotopic signals from callovian kimmeridgian middle upper jurassic belemnites and bulk organic carbon staffin bay isle of skye scotland abstract the stable isotope data presented here significantly extend and expand upon previous isotopic investigations of the middle to late jurassic interval the belemnite samples collected from the staffin bay and staffin shale formations from the isle of skye scotland yielded oxygen isotope values consistent with callovian kimmeridgian palaeotemperatures of 6 7 20 6 c the carbon isotope data comprise one of the first moderately high resolution investigations of the relationship between terrestrial 13 c org predominantly fossil wood debris and marine 13 c carb belemnites as derived from a geologically coeval record the staffin bay data reveal a broad early to mid oxfordian positive carbon isotope excursion the excursion maximum occurs in the cordatum zone british boreal ammonite zonation although high values persist into the tenuiserratum zone the correspondence between the marine and terrestrial records indicates a strong coupling of the ocean atmosphere system and suggests that the total exchangeable carbon reservoir would have been affected at this time the mid oxfordian negative carbon isotope excursions identified in published tethyan records and commonly attributed to methane release are not recorded in the staffin bay data which may suggest that the tethyan excursions do not represent fluctuations in the global carbon reservoir and that the fidelity of the methane hypothesis should be re evaluated supplementary material isotopic and geochemical data are available at http www geolsoc org uk sup18339

upper cretaceous stable carbon isotope stratigraphy of terrestrial organic matter from sakhalin russian far east a proxy for the isotopic composition of paleoatmospheric co2 abstract time stratigraphic patterns of stable carbon isotopic ratios recorded in terrestrial organic matter from cenomanian maastrichtian successions for the russian far east can be correlated to those of carbonate carbon from well studied successions for other parts of the world age indicative biostratigraphy based on regional ammonoids and inoceramid bivalves are well established in japan and can be applied to the whole cretaceous succession except for the upper cenomanian lower turonian and the upper part of the maastrichtian zones lacking macrofossils globally correlative carbon isotopic events previously documented with carbonate carbon from europe and with carbonate carbon and marine organic matter from the u s western interior are recognized with similar magnitude through uppermost cenomanian lower campanian in ascending order these events are positive spike across the cenomanian turonian boundary step like leveled segment followed by negative shift lower middle turonian trough like negative excursion middle upper turonian positive rebound coupled with following broad peak coniacian and positive peak basal campanian followed by modest negative excursion the parallel fluctuation of the 13 c value between the terrestrial organic matter and carbonate suggests carbon isotopic equilibrium between surface seawater and atmospheric co 2 and demonstrates that the isotopic curve of terrestrial organic carbon can be used to monitor carbon isotopic fluctuations of co 2 in the ocean atmosphere system in the upper campanian and maastrichtian a negative 13 c excursion within chron 33r and a following rapid rebound can be correlated with the same distinctive carbon isotopic feature of carbonate observed in the deep sea cores from south and north atlantic the indian and the pacific oceans within this interval the 13 c value of terrestrial organic matter also reflects carbon isotopic fluctuation of the global co 2 reservoir with relatively minor regional local noise

carbon and oxygen isotope composition of oxfordian early kimmeridgian belemnite rostra palaeoenvironmental implications for late jurassic seas abstract stable isotope analyses have been undertaken on oxfordian early kimmeridgian belemnite rostra derived from three palaeogeographic provinces of europe 1 the boreal subboreal province isle of skye in scotland 2 the submediterranean province central poland and southern germany and 3 the mediterranean province pieniny klippen belt in the western carpathians the samples have been screened for possible diagenetic alteration by using cathodoluminescence and trace element analyses and have been found to be largely well preserved calculated palaeotemperatures 10 15 c and analyses of belemnite habitats suggest that the boreal subboreal belemnites were living in a relatively shallow sea not deeper than 100 150 m while the other belemnites possibly inhabited deeper neritic environments despite the influence of a vital effect the 13c values of belemnite rostra are interpreted to reflect primary variations in the oceanic carbon isotope signal the fairly uniform submediterranean 13c values indicate a similar isotope composition of dissolved inorganic carbon dic in the area of sedimentation of sponge megafacies in the deep tethyan shelves the slightly lowered 13c values of some mediterranean belemnites might occur due to upwelling providing 12c enriched bottom waters onto the area of the czorsztyn ridge in the oxfordian the discernibly more positive 1 2 5 13c values of boreal subboreal belemnites are related to a high biologic productivity and a high organic matter burial in the partly isolated boreal sea the stated differentiation in carbonate 13c values distinctly exceeds present day differences in isotope composition of seawater dic

terrestrial record of methane hydrate dissociation in the early cretaceous reconstruction of changing c isotopic composition of early cretaceous atmospheric co2 from fossilized c3 vascular land plant tissue revealed a brief and striking negative excursion d 25 in atmospheric d 13 c followed by a rapid positive compensation d 15 during the aptian ca 117 ma mass balance calculations show that dissociation of a small amount of methane gas hydrate is the most tenable cause of the negative excursion this would also result in an increased co2 o2 mixing ratio as o2 is consumed during ch4 oxidation to co2 spurring the exponential phase of angiosperm biogeographic expansion

interpreting carbon isotope excursions carbonates and organic matter abstract variations in the carbon isotopic compositions of marine carbonate and organic carbon provide a record of changes in the fraction of organic carbon buried through time and may provide clues to changes in rates of weathering and sources of organic carbon paired carbonate and organic carbon isotope determinations provide a possibility of interpreting not only changes in the global carbon cycle through time but changes in atmospheric pco2 as well interpretations of these types of data are typically rather qualitative a quantitative basis is required to develop a better understanding of changes in the carbon cycle for this purpose we employ a simple model of the global carbon cycle which is subjected to a number of different perturbations each lasting 500 ky i e much longer than the residence times of carbon and phosphorus in the ocean atmosphere system in addition to standard considerations of carbon mass and isotopic fluxes to the ocean atmosphere system from weathering and volcanism and fluxes of organic carbon and carbonate carbon to sediments the model incorporates sensitivity of the photosynthetic carbon isotope effect to changes in pco2 the inclusion of this parameter leads to unexpected carbon isotope responses to forcing that causes increased rates of organic carbon burial a series of simple to more complex simulations illustrates the significant effects of varying differences between the carbon isotopic composition of sedimented carbonate and organic carbon b with constant b a 50 increase in organic carbon burial produces a parallel increase in carbonate and organic carbon isotopic compositions however the same simulation with b responsive to pco2 changes produces an initial parallel 13 c increase but this is followed by an even greater 13 c enrichment in organic carbon because pco2 falls in response to increased organic carbon burial the counterintuitive overall result of the enhanced organic carbon burial event is that the carbonate carbon isotopic composition actually decreases because of the more substantial increase in 13 c org in addition we illustrate the effects on carbon isotopic compositions of the oceanic inorganic carbon reservoir and buried organic matter of a 50 increase in volcanic co2 outgassing a 50 increase in weathering rate with coupled phosphate and riverine carbon flux responses a 50 decrease in shale associated organic carbon weathering a 50 decrease in silicate weathering rate and the possible effects of the rise in abundance of c4 plants in the late miocene to recent we compare the model simulated carbon isotopic responses for some of these experiments to paired carbonate and organic carbon records to illustrate how these records might be interpreted in light of the model response

preservation of delta 18 o and delta 13 c in belemnite rostra from the jurassic early cretaceous successions stratigraphic collection of 263 belemnite rostra guards from jurassic to lower cretaceous sediments in the moscow area of russia northern germany england new zealand and morocco were analyzed to determine temporal variations in their delta 18 o and delta 13 c as a proxy for isotopic composition of surface seawater internal structures of the rostra were studied using cathodoluminescence and sem techniques their trace element fe mn mg and sr and the stable carbon and oxygen isotope compositions the average stratigraphic resolution is about 1 ma these samples represent a broad range of paleolatitudes and paleoceanographic settings ranging from 42 degrees n to 82 degrees s covering boreal to subtropical brackish to open marine shelf paleoenvironments the rostra originally contained domains enriched in organic matter that were later replaced by luminescent diagenetic calcite thereby generating an impression of seasonal growth rings diagenetic calcite accounts for up to 6 8 percent of the rostrum the trace element content of the rostra range from 227 to 3935 ppm for mg 379 to 1514 ppm for sr and up to 305 and 3662 ppm for mn and fe respectively however selective drilling of only primary calcitic domains resulted in 90 percent of all analyzed samples to fall within the range of trace element values typical for modern low mg calcite shells the chemical and textural data suggest that the primary calcite of the rostra is well preserved as is its isotopic signature the delta 13 c and delta 18 o measurements define oscillating temporal bands of about 3 to 4 per mil width around more or less modern marine values of 2 and 1 per mil respectively oxygen isotopes in the well preserved rostra most likely reflect temperature variations within a approximately 14 or 8 degrees c range the observed 3 to 4 per mil spread of values between contemporaneous specimens which is comparable to the scatter of data reported for modern low mg calcitic brachiopod shells probably reflects the diversity of local ecosystems although some of the spread may be due to real short term temporal variations within single biozones the delta 13 c values of the rostra define a band similar to that of the oxygen isotopes and the temporal oscillations of both isotope curves are commonly in phase the above dataset complemented by the results of jones jenkyns and hesselbo 1994 and jones and others 1994 yields a composite delta 18 o and delta 13 c variations in belemnite guards for the entire jurassic early cretaceous interval for delta 18 o the oscillating band indicates that the most negative values occur at times of independently postulated global and or regional anoxic events such as those in the toarcian and kimmeridgian as well as the aptian these oaes appear to be characterized by up to 10 degrees c higher seawater temperatures than the intervening background times the delta 13 c record shows 13 c depletion for the kimmeridgian event but enrichment for the other two suggesting that the delta 13 c temporal oscillations and oaes are not simply a reflection of surficial productivity due to operation of the biological pump but rather of changing oceanic circulation patterns due to variations in latitudinal surface temperature gradients

carbon isotope composition of lower cretaceous fossil wood ocean atmosphere chemistry and relation to sea level change the carbon isotope composition of fossil wood fragments collected through a biostratigraphically well constructed aptian lower cretaceous shallow marine siliciclastic succession on the isle of wight southern britain shows distinct variations with time the results indicate that the stratigraphic signature of delta sup 13 c sub wood through the aptian was influenced primarily by fluctuations in the isotopic composition of co sub 2 in the global ocean atmosphere system as registered in marine carbonates elsewhere and was not governed by local paleoenvironmental and or paleoecological factors negative and positive excursions in delta sup 13 c sub wood through the lower aptian occur in phase with inferred transgressions and regressions respectively a pattern that contrasts with that observed in many previous studies for different time intervals the relationship between delta sup 13 c variations and relative sea level change is tentatively interpreted as a response to various climatic and eustatic factors relating to rapid sea floor spreading thermal uplift of ocean floor emplacement of plateaus volcanic co sub 2 emissions weathering and sedimentary rate

comment on carbon isotope record of the early jurassic toarcian oceanic anoxic event from fossil wood and marine carbonate lusitanian basin portugal by hesselbo s jenkyns h c duarte l v and oliveira l c v hesselbo et al 2006 hereinafter hjdo06 present stable isotopic profiles through lower toarcian sediments at peniche portugal and interpret them as evidence of a massive injection to the atmosphere of isotopically light co2 derived from methane oxidation the atmospheric inputs supposedly gave rise to negative isotopic excursions in all carbon reservoirs the paper follows others proposing that environmental change in early toarcian time was driven by the release to the atmosphere of methane either from marine clathrates hesselbo et al 2000 kemp et al 2005 or from organic rich shales that were baked by karoo ferrar intrusions mcelwain et al 2005 the methane hypothesis was tested by van de schootbrugge et al 2005 who highlighted the existence of sections that lacked a negative excursion in ac in one or more sample media amongst them is the section on the coast of yorkshire uk used to erect the methane hypothesis by hesselbo et al 2000 which lacks a negative excursion in the c of belemnite calcite mcarthur et al 2000 van de schootbrugge et al 2005 as the excursion is not seen in these sections it cannot represent a global event and so could not have resulted from methane release which would have influenced all reservoirs of carbon new data are now provided by hjdo06 for a section peniche

carbon cycle perturbation in the middle jurassic and accompanying changes in the terrestrial paleoenvironment abstract carbon isotope analyses of fossil wood from the middle jurassic ravenscar group yorkshire ne england reveal a significant excursion toward light isotopic values 13c change of 3 to 4 at about the aalenian bajocian boundary 174 ma a positive carbon isotopic excursion is also shown for the middle bajocian 170 ma but is less clearly defined these isotopic patterns are very similar to the few published marine carbonate records available for this time in particular one based on belemnites from the hebrides basin nw scotland and others from pelagic limestones in italy the similarity of the terrestrial and marine isotope curves is an indication that the observed isotopic signal is a global phenomenon through parts of the ravenscar group the scarborough formation supplementary data from bulk organic carbon and palynofacies analysis confirm that isotopic curves based on bulk analyses may be strongly influenced by the balance of terrestrial versus marine organic matter present in th

high paleolatitude late cretaceous paleotemperatures new data from james ross island antarctica oxygen isotope analysis of well preserved macrofossils from the santonian campanian of james ross island and the maastrichtian of vega island antarctica indicates that cool high paleolatitude temperatures prevailed during the late cretaceous and suggests that cooling occurred between the santonian campanian and the maastrichtian although more than 50 of the material showed diagenetic alteration 52 unaltered aragonite and calcite samples were analyzed mean delta sup 18 o and calculated paleotemperature values were minus 0 23 per thousand and 13 6 c respectively for the santonian campanian and 0 66 per thousand and 11 7 c respectively for the masstrichtian in conjunction with recent late cretaceous paleoclimatic data from high northern paleolatitudes these data indicate the presence of cool polar regions with broad climatic zonation during the late cretaceous this may have partly controlled faunal distributions

stable isotope records from sepia officinalis a key to understanding the ecology of belemnites abstract the stable isotope ratios 1 8 o 1 3 c of the aragonite of cuttlebones of sepia officinalis were measured on a high resolution scale where every septum was measured our studies aim at understanding whether variations of the isotope signature are controlled by ontogenetic and or ecological factors five specimens were reared from eggs under known water temperatures a sixth specimen was caught in the german part of the north sea the data suggest that the oxygen isotope composition is in isotopic equilibrium with the surrounding seawater and reflects ambient temperature migration and seasonal temperature changes are visible in the acquired data set the carbon isotope signature shows signs of biofractionation and no direct correlation to the oxygen signature as far as ontogeny and ecology are concerned

vitrinite reflectance and molecular geochemistry of jurassic sediments the influence of heating by tertiary dykes northwest scotland vitrinite reflectance measurements from sedimentary rocks adjacent to six dykes from sites across the inner hebrides indicate that the lateral extent of thermal alteration is reasonably similar and proportional to dyke thickness d t with alteration starting to take effect at 70 d t detailed sampling of a jurassic siltstone adjacent to a 0 9 m dyke reveals that the zone of maximum extractable organic matter eom wt g rock equivalent to the oil window is relatively narrow ca 25 of the d t the position of this oil window relative o the vitrinite reflectance profile is comparable with that from burial maturation gas chromatograms of the aliphatic hydrocarbon fractions reveal i a shift from branched and cyclic dominated hydrocarbons to an increasing predominance of straight chain components and ii the carbon number distribution of the n alkanes shifts towards the shorter chain homologues with decreasing distance from the dyke contact apart from the methylphenanthrene index mpi1 changes in each of the molecular maturity parameters are initiated by the the thermal effects of the dyke between 80 and 70 d t from the contact the mpi1 parameter was the most sensitive maturity indicator in that it responded to the dyke emplacement even in the distal samples i e distance from dyke contact 140 d t a significant reduction in toc at the dyke contact suggests that the synthesis gas reaction may have occurred i e the reaction of organic matter with steam resulting in the formation of carbon monoxide this reaction may be associated with the vitrinite reflectance reversal this study suggests that these particular dykes have had only a local effect on the maturity of the intruded sediments

late jurassic climate and its impact on carbon cycling abstract the climate of the late jurassic has been characterized by high atmospheric co2 levels and by a monsoonal rainfall pattern in this study we traced the evolution of the global carbon cycle through the late jurassic with the help of carbonate carbon isotope stratigraphy the oxfordian tithonian 13c curve is marked by one major positive carbon isotope excursion with an amplitude 13 c 1 0 middle to late oxfordian and a second minor positive excursion with an amplitude 13 c late kimmeridgian the early kimmeridgian and early tithonian 13c values fluctuate around 13 c 2 0 3 and contrast with the less positive 13c values of early oxfordian and late tithonian age 13 c 1 0 5 a comparison of the late jurassic carbonate carbon isotope curve with the occurrence of organic rich sediments suggests that not only fluctuations in organic carbon burial but also in carbonate carbon burial had an impact on the c isotope record the oxfordian c isotope excursion appears to correspond to a time of overall increased organic carbon burial triggered by increased nutrient transfer from continents to oceans during a time of rising global sea level however episodes of enhanced organic carbon burial during the kimmeridgian and early tithonian are not reflected by prominent spikes in the c isotope record favourable conditions for carbonate platform growth at a time of high global sealevel may have resulted in the stabilisation of the c org c carb burial ratio and hence maintained the 13c record at steady but relatively positive values the middle and late tithonian c isotope values drop below 13 c 1 5 a similar shift to less positive c isotope values was recognized in other c isotope records from the tethys and atlantic oceans and reflects a decrease in the c org c carb burial ratio possibly related to a reorganisation of the global climate system globally widespread marine black shale mature quartzose sandstone assemblages suggest that the relative efficiency of the late jurassic carbon pumps was controlled by weathering erosion and runoff causing widespread marine eutrophication eutrophication favoured the organic carbon pump but it diminished the carbonate platform growth potential the monsoonal rainfall distribution pattern may explain why late jurassic carbonate platforms experienced less severe growth crises than early cretaceous carbonate platforms

new perspective on aptian carbon isotope stratigraphy data from δ13c records of terrestrial organic matter carbon isotope analyses were performed on detrital woody materials in aptian mid cretaceous marine sediments of central hokkaido northern japan a positive 13cwood excursion from 25 4 to 21 8 following a remarkable negative isotope shift is recognized in the early aptian and a small positive anomaly is also found in the latest aptian this 13cwood profile is exactly in phase with the 13ccarbonate curve from a pacific guyot when the age of the guyot carbonates is revised using published sr isotope stratigraphies the highly conformable 13c profiles of pacific and hokkaido sections suggest that 13c compositions of aptian marine and terrestrial carbon reservoirs changed simultaneously by the same amplitude within the ocean atmosphere biosphere system fluctuation patterns of tethyan 13ccarbonate curves are slightly different from those of pacific and hokkaido sections such differences in 13c profiles may be attributed to the local paleoceanographic setting of the aptian mediterranean tethys

strontium isotope stratigraphy and oxygen and carbon isotope variation during the middle jurassic early cretaceous of the falkland plateau south atlantic abstract 87sr 86sr data of belemnites are presented from a middle jurassic early cretaceous succession from the falkland plateau deep sea drilling project sites 511 and 330 that was deposited in a periodically anoxic semi enclosed shallow water basin diagenetically screened strontium isotope values of 0 706789 rise to 0 707044 before increasing sharply to 0 707428 in the uppermost part of the sampled succession comparison with published strontium calibration curves suggests that the oldest samples were callovian to oxfordian in age whilst the remainder of the jurassic part of the succession consisted of kimmeridgian and early tithonian age sediments the nannofossil dinoflagellate and molluscan assemblages provide comparable age determinations the strontium isotope analysis of the youngest belemnites points to a hauterivian barremian age whilst age interpretations based upon the fauna provide a wide age range from the barremian to early albian strontium isotope stratigraphy of this succession hence offers increased age resolution providing data regarding the timing of episodes of bottom water anoxia which have been recorded throughout the south atlantic basin well preserved belemnite specimens display an oxygen isotope range between 0 08 and 2 22 pdb peedee belemnite international standard and a carbon isotope range from 2 35 to 1 33 pdb 13c values become increasingly negative through the late jurassic early cretaceous and in concert with the 87sr 86sr data reveal a trend that could be accounted for by increasing levels of weathering and erosion the oxygen isotope data if interpreted in terms of palaeotemperature are consistent with warm palaeotemperatures in the kimmeridgian and slightly cooler temperatures for the tithonian and early cretaceous parts of the succession the proposed relative kimmeridgian warmth based upon strontium isotope age assignments is thus in good agreement with other published palaeotemperature records

relative sea level change and carbon isotopes data from the upper jurassic oxfordian of central and southern europe studies on cretaceous pelagic limestones have shown a close correspondence between putative sea level curves and the carbon isotope profile suggesting a possible relationship between the two phenomena such a relationship could relate to shelf sea area governing the global burial rate of organic carbon which in turn controls the 13c 12c ratio of dissolved inorganic carbon in the oceanic reservoir in order to see whether or not this relationship might be of more general applicability the major mid oxfordian jurassic transgression is documented to zonal level and appropriate carbon isotope data are presented although the applicability of ammonite zonation to the mid oxfordian is problematic on a regional scale a clear 13c excursion is present in the trunsversariurn zone which is coincident with regional overstep and or evidence of shoreline retreat and or evidence of bathymetric deepening in europe and elsewhere the use of the carbon isotope curve as a proxy for shelf sea area or relative sea level is worthy of further exploration

detailed oxygen and carbon isotope stratigraphy of the oxfordian in central poland a collection of 73 belemnites and brachiopods from detailed stratigraphically documented sections in the polish jura chain of central poland representing almost the whole oxfordian stage was studied for oxygen and carbon isotopes the 18o and 13c v pdb values range from 3 6 to 0 5 and from 1 6 to 2 for belemnite rostra and from 2 5 to 0 4 and from 1 6 to 4 3 for brachiopod shells respectively the 13c temporal trends of belemnite rostra and brachiopod shells show a constant isotopic difference ca 2 5 3 which is interpreted as a vital effect of belemnites or as a result of different life environments 18o values are similar in both groups of fossils the 18o values in the lower and middle oxfordian oscillate around 0 and decrease in the upper oxfordian this decrease results mainly from diagenetic overprint as proved by the cathodoluminescence studies the lower and middle oxfordian 18o derived temperatures were constant in consequence of significant ocean depth for this reason there are no established links with distribution of ammonite faunas the 13c temporal trend displays a gentle slope through the oxfordian and reaches maximum values at the turn of the plicatilis transversarium zones of the middle oxfordian which is commonly considered as a global event it can be related to the sea level highstand and growth crisis of carbonate platforms the decrease in 13c values starting in the upper middle oxfordian is interpreted to be due to the acceleration of carbonate sedimentation rate during this time period

evidence for late jurassic release of methane from gas hydrate four late jurassic carbonate successions deposited in the tethys atlantic ocean record a negative carbon isotope excursion of at least 2 the excursion is present in both organic and carbonate carbon records and is comparable in magnitude and duration to isotopic changes during the late paleocene thermal maximum our results indicate that during the late jurassic long considered a warm greenhouse time additional greenhouse gas was input to the atmosphere by a sudden release of methane from buried gas hydrate a potential triggering mechanism may have been the opening of an oceanic gateway through the early atlantic between the ancient tethys and pacific oceans