end permian catastrophe by a bolide impact evidence of a gigantic release of sulfur from the mantle our studies in southern china have revealed a remarkable sulfur and strontium isotope excursion at the end of the permian along with a coincident concentration of impact metamorphosed grains and kaolinite and a significant decrease in manganese phosphorous calcium and microfossils foraminifera these data suggest that an asteroid or a comet hit the ocean at the end of permian time and caused a rapid and massive release of sulfur from the mantle to the ocean atmosphere system leading to significant oxygen consumption acid rain and the most severe biotic crisis in the history of life on earth

the carbon isotope shift at the permian triassic boundary in the southern alps is gradual carbon isotope ratios in marine carbonate rocks have been shown to shift at some of the time boundaries associated with extinction events for example cretaceous tertiary1 and ordovician silurian2 the permian triassic boundary the greatest extinction event of the phanerozoic3 is also marked by a large 13c depletion4 5 new carbon isotope results from sections in the southern alps show that this depletion did not actually represent a single event but was a complex change that spanned perhaps a million years during the late permian and early triassic these results suggest that the permian triassic p tr extinction may have been in part gradual and in part stepwise 6 7 but was not in any case a single catastrophic event

carbon isotope stratigraphy across the permian triassic boundary a review abstract the palaeozoic mesozoic transition is marked by distinct perturbations in the global carbon cycle resulting in a prominent negative carbon isotope excursion at the permian triassic p t boundary well known from a plethora of marine and continental sediments potential causes for this negative 13 c trend and their links to the latest permian mass extinction have been intensively debated in the literature in order to draw conclusions regarding causation a general 13 c curve was defined after consideration of all available datasets and with due reference to the biostratigraphic background the most important features of the p t carbon isotope trend are the following the 4 7 13 c decline lasting 500 000 years is gradual and began in the changhsingian at the stratigraphic level of the c bachmanni zone the decreasing trend is interrupted by a short term positive event that starts at about the latest permian low latitude marine main extinction event horizon eh indicating that the extinction itself cannot have caused the negative carbon isotope excursion after this short term positive excursion the 13 c decline continues to a first minimum at about the p t boundary a subsequent slight increase is followed by a second occasionally two peaked minimum in the lower and middle i isarcica zone the negative carbon isotope excursion was most likely a consequence of a combination of different causes that may include 1 direct and indirect effects of the siberian trap and contemporaneous volcanism and 2 anoxic deep waters occasionally reaching very shallow sea levels a sudden release of isotopically light methane from oceanic sediment piles or permafrost soils as a source for the negative carbon isotope trend is questionable at least for the time span a little below the eh and somewhat above the p t boundary

secular variation in seawater chemistry during the phanerozoic as indicated by brine inclusions in halite analysis of data on the chemical composition of primary fluid inclusions brine inclusions in primary bedded halite from many evaporite formations of northern pangea shows that during the phanerozoic the chemical composition of marine brines was oscillating significantly between the na k mg ca cl type and the na k mg cl so4 type we regard those changes as corresponding to the chemical evolution of the phanerozoic ocean the changes correlate in time with earlier suggested secular changes in the mineralogies of marine nonskeletal limestones and potash evaporites in addition to those secular changes of seawater chemistry the concentrations of k mg ca and so4 ions in marine brines underwent important changes under the influence of local factors including rock water interaction these secondary changes did not influence the principal chemical type of the brine characteristic for a given time interval in the past concentration of the ca ion did not exceed the present concentration in marine water by a

griesbachian earliest triassic palaeoenvironmental changes in the salt range pakistan and southeast china and their bearing on the permo triassic mass extinction abstract facies and faunal analysis from pakistan and china show that the permo triassic mass extinction of marine invertebrate faunas was associated with a spectacularly rapid griesbachian transgression which lead to the widespread establishment of deep water anoxic and dysoxic conditions the extinction event was thus caused by habitat loss due to the extensive development of inhospitable conditions the initial griesbachian transgression in pakistan produced extensive shallow normal marine conditions in which permian holdover taxa were able to survive until the development of dysaerobic facies in the late griesbachian the exceptionally complete sections of china show a three phased deepening and extinction event beginning in the latest permia by the late griesbachian a variety of dysaerobic and anaerobic facies were developed in all the regions studied several of these contain evidence for minimal sulphate reducing activity suggesting that marine productivity and thus organic matter flux to the sediments was very low in early triassic seas

u pb zircon geochronology and tempo of the end permian mass extinction the mass extinction at the end of the permian was the most profound in the history of life fundamental to understanding its cause is determining the tempo and duration of the extinction uranium lead zircon data from late permian and early triassic rocks from south china place the permian triassic boundary at 251 4 0 3 million years ago biostratigraphic controls from strata intercalated with ash beds below the boundary indicate that the changhsingian pulse of the end permian extinction corresponding to the disappearance of about 85 percent of marine species lasted less than 1 million years at meishan a negative excursion in 13 c at the boundary had a duration of 165 000 years or less suggesting a catastrophic addition of light carbon

major stages of rifting evolution in the earth s history abstract linear extensional rift and rift like structures have been generated many times during various periods of the earth s history since early times these structures have varied with time however in scale morphology formations paragenesis of tectonic features regularity of distribution and evolution i distinguish and consider five major stages of rifting they are katarchean archean early proterozoic late proterozoic paleozoic and mesozoic cenozoic linear structures of the oldest stage combine features of development and structure similar to those typical of the rift and geosynclinal zones in the later periods of the earth s history at the second stage proto rift and proto geosynclinal structures can be distinguished for the first time though differences are not distinct paleo rift zones of the third and fourth stages differ from geosynclinal belts and zones their structural and genetic evolution however is related to the development of the latter in contrast the distribution and evolution of the rift zones and belts during the fifth stage are connected mainly with the destruction of the continents and formation of the secondary oceanic basins they are complementary to the mesozoic cenozoic geosynclinal orogenic belts periods of the greatest development of rift and rift like structures in the archean riphean and mesozoic cenozoic probably correspond to the major phases of the earth s expansion which can be distinguished in its general pulsating evolution

the major ion composition of permian seawater abstract the major ion mg2 ca2 na k so42 and cl composition of permian seawater was determined from chemical analyses of fluid inclusions in marine halites new data from the upper permian san andres formation of texas 274 272 ma and salado formation of new mexico 251 ma analyzed by the environmental scanning electron microscopy esem x ray energy dispersive spectrometry eds method along with published chemical compositions of fluid inclusions in permian marine halites from north america two formations of different ages and the central and eastern european basins eight formations of four different ages show that permian seawater shares chemical characteristics with modern seawater including so42 ca2 at the point of gypsum precipitation evolution into mg2 na k so42 cl brines and mg2 k ratios 5 permian seawater however is slightly depleted in so42 and enriched in ca2 although modeling results do not rule out ca2 concentrations close to those in present day seawater na and mg2 in permian seawater are close to slightly below their concentrations in modern seawater permian and modern seawater are both classified as aragonite seas with mg2 ca2 ratios 2 conditions favorable for precipitation of aragonite and magnesian calcite as ooids and cements the chemistry of permian seawater was modeled using the chemical composition of brine inclusions for three periods lower permian asselian sakmarian 296 283 ma lower permian artinskian kungurian 283 274 ma and upper permian tatarian 258 251 ma parallel changes in the chemistry of brine inclusions from equivalent age evaporites in north america central europe and eastern europe show that seawater underwent secular variations in chemistry over the 50 million years of the permian modeled so42 concentrations are 20 mmol per kg h2o mmolal and 19 mmolal in the asselian sakmarian and artinskian kungurian with higher concentrations in the upper permian tatarian 23 mmolal modeled ca2 is at or above its concentration in modern seawater throughout the permian mg2 is close to slightly below its concentration in modern seawater 55 mmolal in the asselian sakmarian 52 mmolal and tatarian 52 mmolal but slightly higher than modern seawater in the artinskian kungurian 60 mmolal mg2 ca2 ratios are 3 5 total range 2 7 to 5 5 in the lower permian and rose slightly to 3 7 total range 3 1 to 5 8 in the upper permian primarily due to decreases in ca2 these results are consistent with models that predict oscillations in the major ion composition of phanerozoic seawater on the basis of changes in the midocean ridge river water flux ratio driven by changes in the rate of midocean ridge crust production the permian was characterized by low sea levels icehouse conditions and southern hemisphere glaciation such conditions analogous to the present ice age and the similarities between permian seawater and modern seawater all suggest that general phanerozoic supercycles driven by mantle convection and global volcanicity also control the major ion chemistry of seawater

paleophysiology and end permian mass extinction physiological research aimed at understanding current global change provides a basis for evaluating selective survivorship associated with permo triassic mass extinction comparative physiology links paleontological and paleoenvironmental observations supporting the hypothesis that an end permian trigger most likely siberian trap volcanism touched off a set of physically linked perturbations that acted synergistically to disrupt the metabolisms of latest permian organisms global warming anoxia and toxic sulfide probably all contributed to end permian mass mortality but hypercapnia physiological effects of elevated pco2 best accounts for the selective survival of marine invertebrates paleophysiological perspectives further suggest that persistent or recurring hypercapnia global warmth also played a principal role in delayed triassic recovery more generally physiology provides an important way of paleobiological knowing in the age of earth system science 2007 elsevier b v all rights reserved

changes in the global carbon cycle occurred as two episodes during the permian triassic crisis coeval records of ocean atmosphere and terrestrial change are crucial to understanding the pattern and causes of global mass extinction across the permian triassic boundary ptb however relationships among changes in different settings remain largely unclear primarily due to the challenges associated with the correlation among disparate records here we compare marine carbon isotopic records with marine and terrestrial environmental and biotic events recorded in sediments from the meishan ptb section of south china time scaled carbonate carbon isotopes exhibit two gradual major shifts across the ptb at meishan and these are duplicable elsewhere around the tethys ocean the two shifts are associated with two episodes of enhanced terrestrial weathering indicated by an increased abundance of 13 c enriched moretanes relative to hopanes and an elevated abundance of black carbon fragments key marine events previously reported for the ptb including photic zone euxinia faunal mass extinction and cyanobacterial expansion also occur as two episodes coinciding with both of the progressive shifts to negative 13 c values and enhanced weathering the temporal sequence of the duplicable events suggests that the biotic crisis was a consequence of prolonged and episodic changes in the marine and continental systems and argues against an extraterrestrial impact as the main cause

a sulfur isotope event at the end of the permian abstract a hypothesis of light sulfur injection to the ocean atmosphere system at the end of the permian was presented by kaiho et al kaiho k kajiwara y nakano t miura y kawahata h tazaki k ueshima m chen z q shi g r 2001 end permian catastrophe by a bolide impact evidence of a gigantic release of sulfur from the mantle geology 29 815 818 based on a negative shift of 34 s 32 s ratio of carbonate associated sulfate in south china this hypothesis was discussed in some papers with additional data in other areas however the cause and distribution of the negative shift has not been clarified here we show that a significant decrease in the 34 s 32 s ratio of carbonate associated sulfate occurred simultaneously in south china and hungary at the end of the permian coincident with the end permian mass extinction the cause of the abrupt negative shift of 34 s 32 s in these two distant sites is the injection of light sulfur to the surface ocean from the deep ocean rich in h 2 s or deposits rich in sulfide or the mantle this sulfur isotope event was likely caused by either an abrupt warming a bolide impact to the ocean mantle plume induced volcanism or a harmonizing of these possible direct causes are 1 massive release of h 2 s gas from the euxinic surface and intermediate waters due to abrupt warming by volcanic co 2 or impact shock wave in the ocean 2 a huge volcanism penetrated sediments or ore rich in sulfide 3 an extraterrestrial impact to sulfide rich sediments or ore deposit and 4 release of mantle origin sulfur by an impact of 70 km asteroid to the ocean these are four possible causes for a mass extinction there is also a possibility of a local oceanic event only in the tethys

evaluating the relationship between the carbon and sulfur cycles in the later cambrian ocean an example from the port au port group western newfoundland canada abstract we present a high resolution 34 s sulfate and pyrite and 13 c carbonate record from the middle upper cambrian port au port group a mixed carbonate siliciclastic succession exposed in western newfoundland canada the results illustrate systematic 34 s sulfate shifts of 15 over relatively short stratigraphic intervals 10 m likely 34 s sulfate pyrite ca 23 and a generally positive coupling between changes in 13 c carbonate and 34 s sulfate together these results indicate that middle to late cambrian sulfate concentrations were low and that the sulfate reservoir was more sensitive to change than it was in either terminal neoproterozoic or cenozoic oceans however a simple carbon c and sulfur s isotope box model of the late cambrian ocean illustrates that low sulfate concentrations alone fail to account for the 15 34 s sulfate shifts recognized in port au port strata such large shifts can be generated only if fluctuating oceanic redox is invoked marine anoxia forces reduced c s burial and elevated 34 s driving larger 34 s changes per mole of organic carbon buried the conclusion that later cambrian oceans featured both low sulfate levels and widespread subsurface anoxia supports hypotheses that link fluctuating marine redox conditions in the delayed recovery of skeletal animals and metazoan reefs from late early cambrian extinction

evidence for recurrent early triassic massive volcanism from quantitative interpretation of carbon isotope fluctuations abstract carbon cycle disturbance associated with mass extinction at the end of the permian period continued through the early triassic an interval of approximately 5 million years coincidence of carbon cycle stabilization with accelerated middle triassic biotic recovery suggests a link between carbon cycling and biodiversity but the cause of early triassic carbon isotope excursions remains poorly understood previous modeling studies have focused exclusively on the initial negative excursion in 13c across the permian triassic boundary and have not addressed the cycles of positive and negative excursions observed through the early triassic this study uses a simple carbon cycle box model to investigate potential causes underlying the series of early triassic carbon isotope excursions and to assess possible relationships between isotope excursions and coeval patterns of carbonate deposition according to the model introduction of carbon with the isotope composition of volcanic co2 produces small negative carbon isotope excursions followed by larger and more protracted positive excursions positive excursions result because increased pco2 causes warming enhancing marine anoxia and associated regeneration of phosphate and thus allowing greater productivity in addition carbonate weathering is more sensitive than organic carbon weathering to changes in atmospheric pco2 and climate causing an increase in the overall 13c composition of weathered carbon therefore the full early triassic record of negative and positive carbon isotope excursions can only be accounted for within the model by several pulses of carbon release characterized by varying mixtures of organic and mantle isotope compositions thermal metamorphism of coal and carbonate rocks in the crust of the siberian craton during eruption of the siberian traps flood basalts provides the most plausible mechanism for such a carbon release scenario if multiple episodes of co2 release account for early triassic carbon cycle instability regardless of their precise trigger then cessation of co2 release is likely to explain acceleration of biotic recovery early in the middle triassic

the timing and extent of the eruption of the siberian traps large igneous province implications for the end permian environmental crisis we present new high precision 40ar 39ar ages on feldspar and biotite separates to establish the age duration and extent of the larger siberian traps volcanic province samples include basalts and gabbros from noril sk the lower tunguska area on the siberian craton the taimyr peninsula the kuznetsk basin vorkuta in the polar urals and from chelyabinsk in the southern urals most of the ages except for those from chelyabinsk are indistinguishable from those found at noril sk cessation of activity at noril sk is constrained by a 40ar 39ar age of 250 3 1 1 ma for the uppermost kumginsky suite the new 40ar 39ar data confirm that the bulk of siberian volcanism occurred at 250 ma during a period of less than 2 ma extending over an area of up to 5 million km2 the resolution of the data allows us to confidently conclude that the main stage of volcanism either immediately predates or is synchronous with the end permian mass extinction further strengthening an association between volcanism and the end permian crisis a sanidine age of 249 25 0 14 ma from bed 28 tuff at the global section and stratotype at meishan china allows us to bracket the p tr boundary to 0 58 0 21 myr and enables a direct comparison between the 40ar 39ar age of the traps and the permo triassic boundary section younger ages 243 ma obtained for basalts from chelyabinsk indicate that volcanism in at least the southern part of the province continued into the triassic

controls on regional marine redox evolution during permian triassic transition in south china abstract although oceanic anoxia is regarded as a leading cause of the permian triassic boundary ptb mass extinction its timing extent and underlying causes remain unclear here we conducted a high resolution fe s c mo geochemical study of the entire changhsingian and lowermost induan succession in a carbonate ramp setting at ganxi western hubei province south china six stratigraphic units representing discrete redox intervals were identified based on integrated fe s c mo data units i iii are of latest wuchiapingian to early changhsingian age with units i and iii characterized by euxinia and unit ii by uncertain redox conditions unit iv of mid changhsingian age records a gradual transition from euxinic to ferruginous conditions units v and vi spanning the latest permian mass extinction lpme to earliest triassic interval were deposited under dominantly ferruginous conditions punctuated by both euxinic and oxic episodes redox variations at ganxi were controlled by contemporaneous oceanographic changes in the upper oceanic thermocline region i euxinia in units i and iii may record elevated marine productivity as suggested by mean organic carbon accumulation rates or ocar of 6 5 and 5 1 mg cm2 kyr respectively that was possibly related to upwelling ii the euxinic to ferruginous transition from unit iv to units v vi can be attributed to a combination of reduced sulfate availability and rising terrigenous iron inputs mean fe of 1 7 and 3 9 respectively for units v iv and vi compared to 1 0 for units i iii and iii transient intervals of euxinia in units v and vi were facilitated by enhanced sulfate fluxes related to episodic volcanism during this interval an integration of the redox data from ganxi with previously published data from the shangsi and xiakou sections suggests that enhanced weathering fluxes were most likely the key factor controlling the marine redox transition from euxinic to ferruginous conditions during the latest permian across the south china region

an integrated biomarker isotopic and palaeoenvironmental study through the late permian event at lusitaniadalen spitsbergen abstract the largest extinction of the phanerozoic occurred near the permian triassic p tr boundary some 252 ma ago several scenarios and drivers have been proposed for this event here we report for the first time an integrated study comprising sedimentological data biomarker distributions abundances and selected stable carbon and hydrogen isotopes along with bulk isotopes 34spyrite 13ccarb 13corg for a late permian section from lusitaniadalen spitsbergen norway sedimentological and geochemical data support a marine transgression and collapse of the marine ecosystem in the late permian strong evidence for waxing and waning of photic zone euxinia throughout the late permian is provided by chlorobiaceae derived biomarkers including 13c data and 34spyrite implying multiple phases of h2s outgassing and potentially several pulses of extinction a rapid decrease in abundance of various land plant biomarkers prior to the marine collapse event indicates a dramatic decline of land plants during the late permian and or increasing distance from palaeoshoreline as a consequence of sea level rise changes in d of selected biomarkers also suggest a change in source of organic matter om or sea level rise we also found biomarker and isotopic evidence for a phytoplanktonic bloom triggered by eutrophication as a consequence of the marine collapse compound specific isotope analyses csia of algal and land plant derived biomarkers as well as 13c of carbonate and bulk om provide strong evidence for synchronous changes in 13c of marine and atmospheric co2 attributed to a 13c depleted source the source could be associated with isotopically depleted methane released from the melting of gas clathrates and or from respired om due to collapse of the marine ecosystem

close up of the end permian mass extinction horizon recorded in the meishan section south china sedimentary elemental and biotic characterization and a negative shift of sulfate sulfur isotope ratio abstract the permian triassic p tr boundary beds of the meishan section south china have been re studied in detail based on complete samples across the p tr transition under the microscope the end permian mass extinction horizon is calibrated to a 12 mm stratal interval the top being 19 mm below the top of bed 24e of the changhsing formation this abrupt disappearance of skeletal fragments of major benthos characterizes the end permian extinction event suggesting a catastrophic event an abrupt decrease in the 34s 32s ratios of seawater sulfate is confirmed to coincide with the end permian event horizon the sulfur isotope event is thought to have been caused by an overturn of a stratified ocean dominated by h2s implying coincidence of the oceanic mixing and the mass extinction coincident siberian flood volcanism may have triggered a long term 103 years cooling leading an ocean mixing a presumed comet impact to the ocean could have directly caused ocean mixing and the mass extinction

permian triassic boundary interval in the middle east iran and n oman progressive environmental change from detailed carbonate carbon isotope marine curve and sedimentary evolution abstract the end permian negative 13c excursion is well known but its cause and chronology are still in question in an attempt to decipher the timing and reasons for this strong decrease we established high resolution sedimentological biostratigraphical and carbonate carbon isotopic studies in four sections in iran abadeh shareeza zal and djulfa and two in oman wadi sahtan the position of the sections on two different margins of the neotethys has allowed us to distinguish between local and global signals this high resolution chemostratigraphy tested for isochrony on the basis of an updated high resolution conodont and ammonoid biostratigraphy allows the discrimination of nine successive isotopic events ie 0 8 for the permian triassic boundary interval ptbi the negative excursion of the ptbi has been separated into four distinct parts a first drop ie 0 occurs in the late wuchiapingian with an amplitude of around 1 3 a second decrease begins ie 1 2 at the base of the dzhulfites ammonoid beds changhsingian and continues gradually until the extinction event top jolfensis conodont interval without important second order variations its amplitude varies between 1 5 and 2 8 and its duration has been estimated around 2 2 ma revealing a non catastrophic phenomenon the lower meishanensis praeparvus conodont zone records stationary to slightly increasing values ie 3 the interval of the curve after the extinction event between the upper meishanensis praeparvus zone and the base of the i isarcica zone records numerous second order variations ie 4 7 its amplitude is of 1 2 3 1 these second order variations are correlatable in iran but with some uncertainty with oman poor correlation of these small peaks with others published sections might be due to a higher sensitivity to local perturbations and a lower buffer capacity of the whole ocean we assume that the processes leading to the extinction event also caused the isotopic decrease before the extinction level with a maximal amplitude of only 2 8 this allows consideration of some possible mechanisms that were rejected as unrealistic to cause a 4 6 excursion

bryozoan paleoecology indicates mid phanerozoic extinctions were the product of long term environmental stress we compiled the global onshore offshore distribution of marine bryozoans within 396 permian early jurassic bryozoan assemblages and show that bryozoan assemblage generic richness declined significantly in advance of the end permian and end triassic mass extinctions starting as early as the capitanian prior to the end permian and the norian prior to the end triassic we also show that offshore settings were affected first prior to both extinctions suggesting that environmental stress resulted from the gradual encroachment of some deep water phenomenon onto the shelves these patterns support long term oceanographic rather than extraterrestrial extinction mechanisms such as widespread euxinia triggered by massive volcanism and global warming tracking the onshore offshore environmental distribution of these marine invertebrates provides a unique approach to assessing prolonged environmentally induced stress through this 120 m y time interval

association of 34s depleted pyrite layers with negative carbonate δ13c excursions at the permian triassic boundary evidence for upwelling of sulfidic deep ocean water masses 1 a marine permian triassic boundary ptb section at nhi tao vietnam contains a series of at least 9 pyritic horizons characterized by concurrent decreases in pyrite s 34spy and carbonate c isotopic compositions 13ccarb the first and largest of the events that precipitated these pyritic horizons was coincident with the late permian mass extinction while subsequent events were generally smaller and occurred at quasiperiodic intervals of 20 to 30 ka a near complete lack of organic carbon to drive bacterial sulfate reduction in sediment pore waters among other considerations argues against a diagenetic control for these relationships rather the covariant patterns documented herein are most easily explained as the product of recurrent upwelling of anoxic deep ocean waters containing 34s depleted hydrogen sulfide and 13c depleted dissolved inorganic carbon the sulfide 34s record of the study section represents a mixture of a small amount of isotopically heavy authigenic pyrite formed via in situ bacterial sulfate reduction with a generally larger quantity of isotopically light syngenetic pyrite precipitated within the water column during upwelling episodes although upwelling of toxic deepwaters has been invoked in earlier studies as a mechanism for the late permian marine mass extinction this is the first study to 1 document patterns of pyrite 13ccarb covariation that strongly support upwelling as a major process at the ptb and 2 provide evidence of multiple quasiperiodic upwelling events that may reflect reinvigoration of global ocean overturn following a prolonged interval of late permian deep ocean stagnation

high resolution carbon isotope changes in the permian triassic boundary interval chongqing south china implications for control and growth of earliest triassic microbialites abstract high resolution 13 c carb analysis of the permian triassic boundary ptb interval at the laolongdong section beibei near the city of chongqing south china encompasses the latest permian and earliest triassic major facies changes in the south china block scb microbialites form a distinctive unit in the lowermost 190 cm above the top of the changhsing formation latest permian at laolongdong comparable to a range of earliest triassic sites in low latitudes in the tethyan area the data show that declining values of 13 c carb well known globally began at the base of the microbialite high positive values 3 to 4 ppt of 13 c carb in the late permian are interpreted to indicate storage of 12 c in the deep waters of a stratified ocean that was released during ocean overturn in the earliest triassic contributing to the distinctive fall in isotope values this interpretation has been stated by other authors and is followed here the 13 c carb curve shows fluctuations within the microbialite unit which are not reflected in the microbialite structure comparisons between microbialite branches and adjacent micritic sediment show little difference in 13 c carb demonstrating that the microbialite grew in equilibrium with surrounding seawater the early triassic microbialites are interpreted to be a response to upwelling of bicarbonate rich poorly oxygenated water in low latitudes of tethys ocean consistent with current ocean models for the ptb interval however the decline of 13 c carb may be due to a combination of processes including productivity collapse resulting from mass extinction return of deep water to ocean surface oxidation of methane released from methane hydrate destabilisation and atmospheric deterioration nevertheless build up of bicarbonate rich anoxic deep waters may be expected as a result of the partial isolation of tethys due to continental geography release of bicarbonate rich deep water by ocean upwelling in the earliest triassic may have been an inevitable consequence of this combination of circumstances

large perturbations of the carbon cycle during recovery from the end permian extinction high resolution carbon isotope measurements of multiple stratigraphic sections in south china demonstrate that the pronounced carbon isotopic excursion at the permian triassic boundary was not an isolated event but the first in a series of large fluctuations that continued throughout the early triassic before ending abruptly early in the middle triassic the unusual behavior of the carbon cycle coincides with the delayed recovery from end permian extinction recorded by fossils suggesting a direct relationship between earth system function and biological rediversification in the aftermath of earth s most devastating mass extinction

relationships between carbon isotope evolution and variation of microbes during the permian triassic transition at meishan section south china this paper investigates kerogen carbon isotopes the difference between carbonate and kerogen carbon isotopes 13ccarb kero 13ccarb 13ckero and the difference between carbonate and n c19 alkane compound specific carbon isotopes 13ccarb n c19 13ccarb 13cn c19 during the permian triassic transition at meishan south china the results show that kerogen carbon isotopes underwent both gradual and sharp shifts in beds 23 25 and 26 29 respectively the differences between carbonate and organic carbon isotopes both the 13ccarb kero and 13ccarb n c19 which are mainly affected by co2 fixing enzyme and pco2 oscillated frequently during the permian triassic transition both the variations of 13ccarb n c19 and 13ccarb kero coupled with the alternation between cyanobacteria and green sulfur bacteria indicated by biomarkers the episodic low values of 13ccarb n c19 corresponded to episodic blooms of green sulfur bacteria while the episodic high values of 13ccarb n c19 corresponded to episodic blooms of cyanobacteria the relationships between the variation of carbon isotopes and biota show that the microbes which flourished after the extinction of macroorganism affected the carbon isotope fractionation greatly combining the carbon isotope compositions and the pattern of size variation of the conodont neogondolella this paper supposes that anoxia of the photic zone at bed 24 was episodic and it would be caused by the degradation of terrigenous organic matters by sulfate reducing bacteria in the upper water column considered together with results from previous research the high resolution variation of the biogeochemistry presents the sequence of the important geo events during the permian triassic crisis

age and timing of the permian mass extinctions u pb dating of closed system zircons the age and timing of the permian triassic mass extinction have been difficult to determine because zircon populations from the type sections are typically affected by pervasive lead loss and contamination by indistinguishable older xenocrysts zircons from nine ash beds within the shangsi and meishan sections china pretreated by annealing followed by partial attack with hydrofluoric acid result in suites of consistent and concordant uranium lead u pb ages eliminating the effects of lead loss the u pb age of the main pulse of the extinction is 252 6 0 2 million years synchronous with the siberian flood volcanism and it occurred within the quoted uncertainty

carbon sulfur oxygen and strontium isotope records organic geochemistry and biostratigraphy across the permian triassic boundary in abadeh iran pelagic deposits at abadeh represent a complete biostratigraphic record across the permian triassic boundary ptb the presumed water depth during deposition of these sediments was between 60 and 90 m similar to other permian triassic boundary sections the succession at abadeh is characterised by a negative carbon isotope shift of approximately 4 the values start to decrease in the lower c changxingensis c deflecta s l zone reach 0 12 v pdb in the uppermost permian just below the ptb remain low to the early i isarcica zone 0 32 and increase subsequently in the upper i isarcica zone for the time interval of the ptb negative carbon isotope excursion between the c iranica and the i isarcica zones no correlation exists between the 13ccarb and the 18ocarb the above observations argue against the conclusion of heydari et al 2001 that the carbon isotope event at the p t transition is an alteration artefact and not a global signal the decrease in 13ccarb is accompanied by a 5 and potentially up to 10 increase in 34ssss together these features are thought to reflect a complex global event notably the development of widespread anoxic oceans with anoxic bottom layers rising onto the shelves for the carbon isotope drop other factors such as the collapse of ocean primary productivity may also have played a role the 87sr 86sr ratios of dzhulfian seawater show only a minor increase from 0 70705 to 0 70710 reaching 0 70720 in the dorashamian the increase becomes steeper in the early triassic reaching 0 70754 in the n dieneri zone the rise of the strontium isotope values is thought to be related to enhanced continental weathering under humid climatic conditions in the uppermost permian c meishanensis h praeparvus zone and the lack of a dense land vegetation in the early triassic prior to the spathian upper olenekian

ore forming fluid source of the orogenic gold deposit implications from a combined pyrite texture and geochemistry study abstract interpretation of bulk sulfur isotope data of the orogenic gold deposit is frequently hampered by complex zoning in pyrite which calls for in situ determination of sulfur isotope composition of sulfide minerals the qiuling gold deposit located in qinling orogen is representative of orogenic type and selected here to further constrain the source of sulfur and au and test the current popular ore genesis models for deposits of this type detailed backscattered electron imaging bse study is applied to characterize intragrain texture and subsequently in situ sulfur isotope and trace element determination using secondary ion mass spectrometry sims and laser ablation inductively coupled plasma mass spectrometry la icp ms are used to reveal sulfur and metal source and evolution of the ore forming fluid two generations of pyrite i e pre ore stage py1 and ore stage pyrite py2 were investigated in this study in most cases py1 occurs as pyrite framboids while py2 as euhedral grains in which py2a as anhedral core py2b and py2c as euhedral inner and outer rim respectively the 34s values of both py1 and py2 have unusual wide ranges i e a 34s variation from 31 1 to 106 7 for py1 average 0 8 and from 2 7 to 24 1 for py2 average 13 2 the distribution pattern of 34s values in py1 is accommodated with rayleigh fractionation in sulfate restricted pore water modeling results show that neither temperature nor oxygen fugacity change could result the variations in 34s values of py2 and contribution of both preexisting pyrite and a pulse of ore forming fluid with 34s about 14 2 may be responsible for the observed variation in py2 such fluid may have been sourced from metamorphism of old strata such as the neoproterozoic basement furthermore py2a shows an intimate relationship with py1 in its 34s values indicating py1 may have acted as part of sulfur source in the formation of py2a py1 is rich in a suit of element such as bi co mn ni tl and has the lowest as and au py2a is similar with py1 but with elevated as and au py2b contains more abundant as and au compared to py2a py2c is rich in as and especially au but depleted in other elements compared to py2a the distribution pattern coupled with sulfur isotope composition indicates that py2a was likely formed with a contribution of trace elements and sulfur from py1 at the start of hydrothermal process py2b was formed with elevated proportion of contribution from the ore forming hydrothermal fluid while py2c was formed solely by the ore forming fluid without a contribution from previous pyrite consequently the ore forming fluid in the qiuling gold deposit was rich in as au cu and sb while depleted in other metals such as bi co mn ni and tl indicating that the pre ore framboid pyrite may have not contributed any au and as during mineralization this study highlights the importance of detailed texture characterization coupled with relatively large data set of in situ sulfur isotope and trace elements for orogenic gold deposit research and further proves that metamorphic fluids may have significant contribution for au mineralization in orogenic gold deposits

massive volcanism at the permian triassic boundary and its impact on the isotopic composition of the ocean and atmosphere abstract bulk carbonate and conodonts from three permian triassic p t boundary sections at guryul ravine kashmir abadeh central iran and pufels bula bulla italy were investigated for 13 c and 18 o carbon isotope data highlight environmental changes across the p t boundary and show the following features 1 a gradual decrease of 4 to more than 7 starting in the late permian changhsingian c bachmanni zone with two superimposed transient positive excursions in the c meishanensis h praeparvus and the m ultima s mostleri zones 2 two 13 c minima the first at the p t boundary and a higher occasionally double minimum in the lower i isarcica zone it is unlikely that the short lived phenomena such as a breakdown in biological productivity due to catastrophic mass extinction a sudden release of oceanic methane hydrates or meteorite impact s could have been the main control on the latest permian carbon isotope curve because of its prolonged 0 5 ma duration gradual decrease and the existence of a 1 positive shift at the main extinction horizon the p t boundary 13 c trend matches in time and magnitude the eruption of the siberian traps and other contemporaneous volcanism suggesting that volcanogenic effects such as outgassed co 2 from volcanism and even more thermal metamorphism of organic rich sediments as the likely cause of the negative trend

isotopic evidence for an anomalously low oceanic sulfate concentration following end permian mass extinction abstract the cataclysmic end permian mass extinction was immediately followed by a global expansion of microbial ecosystems as demonstrated by widespread microbialite sequences disaster facies in shallow water settings here we present high resolution carbonate carbon 13 c carb and carbonate associated sulfate sulfur isotope 34 s cas records from the microbialite in the cili permian triassic p tr section in south china a stepwise decline in 13 c carb begins in the underlying skeletal limestone predating the main oceanic mass extinction and the first appearance of microbialite and reaches its nadir in the upper part of the microbialite layer the corresponding 34 s cas in the range of 17 4 to 27 4 is relatively stable in the underlying skeletal limestone and increases gradually from 2 m below the microbialite rising to a peak at the base of the microbialite two episodes of positive and negative shifts occurred within the microbialite layer and exhibit a remarkable co variance of sulfur and carbon isotope composition the large amplitude of the variation in 34 s cas as high as 7 per 100 kiloyears suggests a small oceanic sulfate reservoir size at this time furthermore the 13 c carb and 34 s cas records co vary without phase lag throughout the microbialite interval implying a marine driven c cycle in an anoxic ocean with anomalously low oceanic sulfate concentrations on the basis of a non steady state box model we argue that the oceanic sulfate concentration may have fallen to less than 15 perhaps as low as 3 of that in the modern oceans low oceanic sulfate concentration likely was the consequence of evaporite deposition and widespread anoxic sulfidic conditions prior to the main mass extinction by promoting methanogenesis and a build up of atmospheric ch 4 and co 2 low oceanic sulfate may have intensified global warming exacerbating the inimical environmental conditions of the latest permian

chondritic meteorite fragments associated with the permian triassic boundary in antarctica multiple chondritic meteorite fragments have been found in two sedimentary rock samples from an end permian bed at graphite peak in antarctica the ni fe co ni and p fe ratios in metal grains the fe mg and mn fe ratios in olivine and pyroxene and the chemistry of fe ni p and s bearing oxide in the meteorite fragments are typical of cm type chondritic meteorites in one sample the meteoritic fragments are accompanied by more abundant discrete metal grains which are also found in an end permian bed at meishan southern china we discuss the implications of this finding for a suggested global impact event at the permian triassic boundary

pattern of marine mass extinction near the permian triassic boundary in south china the meishan section across the permian triassic boundary in south china is the most thoroughly investigated in the world a statistical analysis of the occurrences of 162 genera and 333 species confirms a sudden extinction event at 251 4 million years ago coincident with a dramatic depletion of 13ccarbonate and an increase in microspherules

abrupt and gradual extinction among late permian land vertebrates in the karoo basin south africa the karoo basin of south africa exposes a succession of upper permian to lower triassic terrestrial strata containing abundant terrestrial vertebrate fossils paleomagnetic magnetostratigraphic and carbon isotope data allow sections to be correlated across the basin with this stratigraphy the vertebrate fossil data show a gradual extinction in the upper permian punctuated by an enhanced extinction pulse at the permian triassic boundary interval particularly among the dicynodont therapsids coinciding with negative carbon isotope anomalies

a unique geochemical record at the permian triassic boundary a 330 metre core drilled through the marine permian triassic boundary in the carnic alps of austria allows closely correlated studies of geochemistry petrography and palaeontology across the boundary the isotope shifts and metal concentrations are extended multiple and complex and do not resemble those seen at the cretaceous tertiary boundary both the carbon isotope shifts and the chemical events including an indium anomaly may have causes related to a major regression of the sea

the tectonics of the western ordos plateau ningxia china slip rates on the luoshan and east helanshan faults analysis of the locus style and rate of faulting is fundamental to understanding the kinematics of continental deformation the ordos plateau lies to the northeast of tibet within the india eurasia collision zone previous studies have suggested that it behaves rigidly and rotates anticlockwise within a large scale zone of ene wsw left lateral shearing for this rotation to be accommodated the eastern and western margins of the ordos plateau should be undergoing right lateral shearing and yet the dominant faulting style appears to be extensional we focus specifically on the kinematics of the faults bounding the western margin of the ordos plateau and make new slip rate estimates for two of the major faults in the region the right lateral strike slip luoshan fault and the normal slip east helanshan fault we use a combination of infrared stimulated luminescence dating of offset landforms with high resolution imagery and topography from the pleiades satellites to determine an average right lateral slip rate of 4 3 0 4 mm a 1 uncertainty on the luoshan fault similarly we use 10be exposure dating to determine a vertical throw rate on the east helanshan fault of 0 6 0 1 mm a corresponding to an extension rate of 0 7 0 1 mm a 1 uncertainty both of these results agree well with slip rates determined from the latest campaign gps data we therefore conclude that right lateral shearing is the dominant motion occurring in the western ordos region supporting a kinematic model of large scale anticlockwise rotation of the whole ordos plateau

the evolution of microbialite forms during the early triassic transgression a case study in chongyang of hubei province south china abstract the widespread development of microbialites in shallow areas of the tethys ocean at the start of the early triassic reflects the deterioration of marine ecosystems in the aftermath of the extinction that marked the demise of the majority of palaeozoic marine faunas here we present a study of the evolving microbialite forms and associated biotic assemblages of this pioneering microbialite interval from exposures at chongyang hubei province china this research provides a perspective on the effects of eustatic transgression on marine ecosystems as water depths increased at the beginning of mesozoic through the study of the changing forms microfacies and distribution of microbialites microbialite forms evolved from stratiform stromatolites to a sequence of tabular thrombolites with an intercalated layer of columnar stromatolites followed by domical thrombolites that were overlain in turn by oolites the stratiform stromatolites contain poorly preserved remains of calcified cyanobacteria but microfossils with chambered structure can also be seen metazoan fossils increased from the base of the overlying tabular thrombolite reflecting increasing biodiversity with deepening of seawater the occurrence of columnar stromatolites within the tabular thrombolite may indicate a temporary sea level shallowing foraminiferans and other metazoans are absent within the columnar stromatolites but spherical cyanobacterial remains are extremely abundant well preserved calcified cyanobacteria may reflect an absence of metazoan predation and or carbonate supersaturation of seawater as water deepened domical thrombolites developed and the more complex seafloor relief created varied niches between and within the domes that harboured more ecologically diverse communities during the process of transgression within the microbialite interval carbon isotopes exhibit a negative relationship with biodiversity implying that upwelling of anoxic deep ocean water if associated with the negative excursion of carbon isotope values did not inhibit the diversification of benthic organisms at least on shallow carbonate platforms in the period immediately after the end permian mass extinction

sulfur isotopic evidence for chemocline upward excursions during the end permian mass extinction the latest permian was a time of major change in ocean chemistry accompanying the greatest mass extinction of the phanerozoic to examine the nature of these changes samples from two well studied marine sections that span the permian triassic boundary have been analyzed the meishan and shangsi sections located in southern china isotopic analysis of the carbonate associated sulfate in these samples provides a detailed record of several isotopic shifts in 34scas approaching and across the ptb ranging from 30 to 15 vcdt with repeated asynchronous fluctuations at the two locations we interpret the patterns of isotopic shifts in conjunction with other data to indicate a shallow unstable chemocline overlying euxinic deep water which periodically upwelled into the photic zone these chemocline upward excursion events introduced sulfide to the photic zone stimulating a bloom of phototrophic sulfur oxidizing bacteria we hypothesize that elemental sulfur globules produced by these organisms and 34s depleted pyrite produced in the euxinic water column were deposited in the sediment later oxidation led to incorporation as cas this created the large changes to the 34scas observed in the latest permian at these locations

decline in oceanic sulfate levels during the early mesoproterozoic abstract multiple sulfur isotope compositions 32 s 33 s 34 s and 36 s were analyzed for paired carbonate associated sulfate cas and disseminated pyrite py from the 1 6 ga gaoyuzhuang formation of the north china craton to reconstruct the history of sulfate levels in proterozoic oceans the 200 m thick study interval yielded relatively constant values for 34 s cas 13 0 1 8 34 s py 8 0 2 3 and 34 s cas py 5 as well as relatively constant 33 s 0 0 05 and 36 s 0 35 0 15 for both cas and pyrite limited variation in 34 s py and slightly lower 33 s of pyrite relative to cas suggest water column precipitation of pyrite limited fractionation of sulfur during microbial sulfate reduction as documented by 34 s cas py implies low seawater sulfate concentrations in the early mesoproterozoic ocean we quantitatively constrained paleo seawater so 4 2 using a novel modeling approach based on measured values of 34 s cas py and 34 s cas t max for the study unit 34 s cas py is 5 4 1 4 n 17 and 34 s cas t max is 6 8 34 myr 1 based on sedimentation rates of 30 150 m myr 1 these data indicate early mesoproterozoic seawater so 4 2 of p o 2 after great oxidation event i

the permian triassic boundary at nhi tao vietnam evidence for recurrent influx of sulfidic watermasses to a shallow marine carbonate platform the permian triassic boundary at nhi tao cao bang province vietnam was sampled in a 7 5 m thick outcrop section at high resolution 5 cm intervals for chemostratigraphic and magnetic susceptibility analysis the section consists entirely of slightly argillaceous limestone representing shallow marine facies of the jinxi platform one of several large carbonate platforms within the nanpanjiang basin located on the southern margin of the south china craton upper permian strata beds 1 7 are mainly dark gray cherty fossiliferous wackestones and packstones containing a diverse open marine fauna whereas uppermost permian and lower triassic strata beds 9 and higher are medium gray calcimicrobial framestones containing rare macrofossils these facies are separated by a 12 cm thick oolitic pisolitic grainstone bed 8 that coincides with the disappearance of most late permian faunal elements as well as with the first appearance of various geochemical anomalies that continue into the lower triassic part of the section this late permian event horizon is characterized by 1 an abrupt decline in total organic carbon to near zero values 2 the onset of a sustained decline in carbonate 13c and 3 the first of eight concentration peaks in pyrite sulfur significantly each sulfide peak is associated with lower pyrite 34s values as well as with the onset of a negative carbonate 13c excursion or the acceleration of an excursion already in progress these chemostratigraphic relationships are consistent with multiple episodes of upwelling of sulfidic 34s and 13c depleted deep ocean waters onto the jinxi platform the first upwelling event was the most intense and caused a drastic reduction in primary productivity and the demise of the late permian fauna subsequent episodes were less intense but may have contributed to a delay in recovery of early triassic marine ecosystems a ten fold increase in magnetic susceptibility in bed 9 may record the influx of fine detrital particles following destruction of terrestrial ecosystems and massive soil erosion the terrestrial signal of the end permian catastrophe thus follows the marine signal with a 12 cm lag which may reflect the time of transit of soil derived particles across the nanpanjiang basin suggesting that the marine and terrestrial crises in the nhi tao region occurred more or less synchronously these observations suggest a model in which renewal of global ocean overturn followed a prolonged interval of deep ocean stagnation during the late permian with upwelling intensity modulated by short term 20 kyr climate cyclicity

geochemistry of early triassic seawater as indicated by study of the rot halite in the netherlands germany and poland abstract study of three halite sections in the rot basin from the eastern netherlands twente rijn 382 borehole central germany mardorf 6 borehole and western poland o no ig2 borehole shows that the 34 s values in rot sulphates of studied samples 27 14 31 98 are characteristic of marine sulphates of late early triassic these values fit in the rot event shift described in the literature the bromine content in halite is 32 158 ppm in the dutch and polish sections relics of sedimentary structures chevron and hopper are recorded in halite grains these structures contain fluid inclusions that were analysed using the ultramicrochemical method of petrichenko petrichenko o i 1973 metody doslidzhennya vkluchen v mineralakh galogennykh porid kiev naukova dumka 92 pp in the german section no sedimentary halite structures occur because the pressure in the inclusions in recrystallized halite is only slightly greater than atmospheric pressure these inclusions are presumed to be early diagenetic in origin the analysis of individual brine inclusions both in sedimentary and diagenetic forms of halite shows that the rot brines correspond to the na k mg cl so 4 so 4 rich chemical type i e the same type that characterises modern seawater however the rot brines differ from the composition characteristic of modern concentrated seawater by a decrease in the content of sulphate ion and an increase in the content of potassium ion on a janecke diagram the points of the brine composition during deposition of rot halite in poland germany and the netherlands only show a small range this suggests a stable composition of basinal brines during the deposition of the halite at the same time the relative content of sulphate ion in the lower triassic rot basin was slightly lower than that in upper permian evaporite basins but higher than that in lower and middle permian and middle and upper triassic evaporite basins the implication is that the content of sulphate ion in seawater was subject to changes in permian and triassic times

stable carbon isotope stratigraphy across the permian triassic boundary in shallow marine carbonate platforms nanpanjiang basin south china a distinct negative 13c excursion is documented in two permian triassic sections heping and taiping in shallow marine carbonate platform deposits in the nanpanjiang basin south china these sections span from the changhsingian to the dienerian and are characterized by a distinct marine boundary facies change from massive skeletal lime packstone in the changhsingian to distinctive calcimicrobial framestone in the griesbachian hindeodus parvus zone the 13corg and 13ccarb excursions occur directly after the onset of the calcimicrobial framestone herein termed the permian triassic boundary event and before the first occurrence of h parvus the isotope shifts are associated with a sharp drop in species abundance and diversity and coincide with a decrease in total organic carbon toc content the shift towards depleted values in 13corg and 13ccarb at the permian triassic boundary event together with low toc contents persists throughout the griesbachian h parvus zone these data document a corresponding negative shift of 13corg and 13ccarb values and low toc contents with the onset of growth of calcified microbial framestones a postextinction disaster facies immediately below the base of the griesbachian h parvus zone based on paleontological evidence the first occurrence of the disaster facies follows the extinction event which implies that the 13c depleted values above this facies postdate the event this suggests that two separate events had to account for the initiation of the extinction and the 13c excursion however the consequences that led to the negative isotopic shift might be linked to the intriguing recovery lag of early triassic ecosystems based on data from ptb sections worldwide of a greater 13c offset in high compared with low latitudes we propose that methane eruptions from thermal destabilization of high latitude clathrate deposits may have led to the negative 13c shift and may have caused long term adverse ecological conditions

photic zone euxinia during the permian triassic superanoxic event carbon and sulfur isotopic data together with biomarker and iron speciation analyses of the hovea 3 core that was drilled in the perth basin western australia indicate that euxinic conditions prevailed in the paleowater column during the permian triassic superanoxic event biomarkers diagnostic for anoxygenic photosynthesis by chlorobiaceae are particularly abundant at the boundary and into the early triassic similar conditions prevailed in the contemporaneous seas off south china our evidence for widespread photiczone euxinic conditions suggests that sulfide toxicity was a driver of the extinction and a factor in the protracted recovery

paleoredox biotic and sulfur isotopic changes associated with the end permian mass extinction in the western tethys abstract detailed cm scale s toc total organic carbon 34ssulfide and pyrite morphological analysis of the permian triassic boundary beds at the bulla section northern italy suggests that marine waters at this site saw the influx of two dysoxic euxinic intervals that mark the end permian extinction event this suggests reduced oxygen conditions and the presence of h2s is the cause of the end permian extinction the bulla section also shows three troughs in 34ssulfate of which the latter two coincide with the dysoxic euxinic intervals this suggests that the latter two 34ssulfate troughs are the result of h2s oxidation in surface waters but the first trough is the result of a different mechanism we propose that h2s was oxidized in another region either to low 34ssulfate water or elemental s which then moved to the bulla area at the balvany section hungary there are two 34ssulfate troughs near the extinction and no evidence of euxinia a similar mechanism to the first bulla 34ssulfate trough is proposed with the suggestion that these waters were also depleted in oxygen in order to effect the extinction at balvany

a global marine sedimentary response to the end permian mass extinction examples from southern turkey and the western united states the end permian mass extinction greatly diminished marine diversity and brought about a whole scale restructuring of marine ecosystems these ecosystem changes also profoundly affected the sedimentary record data presented here attained through facies analyses of strata deposited during the immediate aftermath of the end permian mass extinction southern turkey and at the close of the early triassic southwestern united states in combination with a literature review show that sedimentary systems were profoundly affected by 1 a reduction in biotic diversity and abundance and 2 long term environmental fluctuations that resulted from the end permian crisis lower triassic strata display widespread microbialite and carbonate seafloor fan development and contain indicators of suppressed infaunal bioturbation such as flat pebble conglomerates and wrinkle structures facies considered unusual in post cambrian subtidal deposits our observations suggest that depositional systems too respond to biotic crises and that certain facies may act as barometers of ecologic and environmental change independent of fossil assemblage analyses close investigation of facies changes during other critical times in earth history may serve as an important tool in interpreting the ecology of metazoans and their environment

biogeochemical evidence for euxinic oceans and ecological disturbance presaging the end permian mass extinction event article i nfo the permian triassic boundary event at 252 2 ma marks the largest extinction of marine fauna in the phanerozoic and there is a wide consensus that the extinction coincided with an intense oceanic anoxic event thestratotypeofthechanghsingianstage preciselyconstrainedbytheptbglobalstratotypesectionandpoint gssp and the gssp for the wuchiapingian changhsingian boundary both at meishan in southern china is well documented in respect to geochronology and the pattern of extinction here we report secular trends in bulk isotopic parameters and lipid biomarkers in a core spanning 214 m of stratigraphic section across the ptb and through the entire changhsingian interval our analysis of these data viewed in the context of relative sea level change and strontium isotopes reveals distinct shifts in paleoenvironmental conditions and profound changes in plankton ecology well before and following the biological extinction event specifically patterns of steroids and triterpenoids indicate a marine plankton community that was heavily dominated by bacteria during the late wuchiapingian middle changhsingian and early griesbachian stages secular trends in aromatic hydrocarbons diagnostic for anoxygenic green sulphur bacteria chlorobiaceae identify periods when euxinic conditions extended into the photic zone during the entire changhsingian stage here also the 15

siberian gas venting and the end permian environmental crisis abstract the end of the permian period is marked by global warming and the biggest known mass extinction on earth the crisis is commonly attributed to the formation of the siberian traps large igneous province although the causal mechanisms remain disputed we show that heating of tunguska basin sediments by the ascending magma played a key role in triggering the crisis our conclusions are based on extensive field work in siberia in 2004 and 2006 heating of organic rich shale and petroleum bearing evaporites around sill intrusions led to greenhouse gas and halocarbon generation in sufficient volumes to cause global warming and atmospheric ozone depletion basin scale gas production potential estimates show that metamorphism of organic matter and petroleum could have generated 100 000 gt co2 the gases were released to the end permian atmosphere partly through spectacular pipe structures with kilometre sized craters dating of a sill intrusion by the u pb method shows that the gas release occurred at 252 0 0 4 million years ago overlapping in time with the end permian global warming and mass extinction heating experiments to 275 c on petroleum bearing rock salt from siberia suggests that methyl chloride and methyl bromide were significant components of the erupted gases the results indicate that global warming and ozone depletion were the two main drivers for the end permian environmental crisis we demonstrate that the composition of the heated sedimentary rocks below the flood basalts is the most important factor in controlling whether a large igneous provinces causes an environmental crisis or not we propose that a similar mechanism could have been responsible for the triassic jurassic 200 ma global warming and mass extinction based on the presence of thick sill intrusions in the evaporite deposits of the amazon basin in brazil

environmental and diagenetic variations in carbonate associated sulfate an investigation of cas in the lower triassic of the western usa an integrated stable isotope elemental and petrographic analysis of early triassic spathian carbonates and evaporites along a proximal to deep environmental transect reveals significant variations in 34s composition of carbonate associated sulfate cas the variations in the 34s of cas are strongly correlated with the ca mg composition of carbonates suggesting that the variations are driven by the degree of dolomitization the 34s of dolostones and evaporites are similar to one another and exhibit lower 34s values than limestones from all localities three hypotheses may explain the differences in 34s between proximal dolostones evaporites and inner middle shelf limestones 1 limestones experienced anaerobic sulfate reduction and subsequent incorporation of 34s enriched sulfate into cas during diagenesis while dolostones did not this is unlikely because of the lack of correlation between 34scas and toc as well as other indicators of diagenesis 2 dolomitization controlled the 34scas in proximal paleoenvironments where the source of the 34s depleted fluids was either continentally derived or the result of rayleigh distillation during evaporite formation and 3 a 34s depth gradient existed during the early triassic such that limestones formed in distal waters are more enriched in 34s versus evaporites and dolostones formed in proximal settings we do not favor this hypothesis because the strong correlation between ca mg and 34scas implies that dolomitization controls the 34scas in these samples results from subtidal well preserved non dolomitized limestones suggest that the 34s of spathian seawater sulfate may have been heavier than previously suggested from analyses of evaporite deposits alone