reply to discussion of the paper high to ultrahigh pressure uhp ductile shear zones in the sulu uhp metamorphic belt china implications for continental subduction and exhumation by zhao et al

high pressure eclogites in northern jiangsu southern shandong province eastern china abstract eclogites are distributed for more than 500 km along a major tectonic boundary between the sino korean and yangtze cratons in central and eastern china these eclogites usually have high p assemblages including omphacite kyanite and or coesite or its pseudomorph and form a high p eclogite terrane they occur as isolated lenses or blocks 10 cm to 300 m long in gneisses type i serpentinized garnet peridotites type ii and marbles type iii type i eclogites were formed by prograde metamorphism and their primary metamorphic mineral assemblage consists mainly of garnet pyrope prp 15 40 mol omphacite jadeite jd 34 64 mol pargasitic amphibole kyanite phengitic muscovite zoisite an sio2 phase apatite rutile and zircon type ii eclogites characteristically contain no sio2 phase and are divided into prograde eclogites and mantle derived eclogites the prograde eclogites of type ii are petrographically similar to type i eclogites the mantle derived eclogites have high mgo feo fe2o3 and cr2o3 compositions in bulk rock and minerals and consist mainly of pyrope rich garnet prp 48 60 mol sodic augite jd 10 27 mol and rutile type iii eclogites have an unusual mineral assemblage of grossular rich grs 57 mol garnet omphacite jd 30 34 mol pargasite rutile pargasitic and taramitic amphiboles calcic plagioclase an68 epidote zoisite k feldspar and paragonite occur as inclusions in garnet and omphacite in the prograde eclogites this suggests that the prograde eclogites were formed by recrystallization of epidote amphibolite and or amphibolite facies rocks with near isothermal compression reflecting crustal thickening during continent continent collision of late proterozoic age equilibrium conditions of the prograde eclogites range from p 26 kbar and t 500 750 c in the western part to p 28 kbar and t 810 880 c in the eastern part of the high p eclogite terrane the prograde eclogites in the eastern part are considered to have been derived from a deeper position than those in the western part subsequent reactions manifested by 1 narrow rims of sodic plagioclase or paragonite on kyanite and 2 symplectites between omphacite and quartz are interpreted as an effect of near isothermal decompression during the retrograde stage the conditions at which symplectites re equilibrated tend to increase from west p 9 kbar and t 680 c equilibrium temperatures of type ii mantle derived eclogites and type iii eclogite are 730 750 c and 680 c respectively

fluid rock interactions during uhp metamorphism a review of the dabie sulu orogen east central china comprehensive review on the characteristics of petrology oxygen isotope fluid inclusion and nominally anhydrous minerals nams for many dabie sulu ultrahigh pressure uhp metamorphic rocks including drill hole core samples reveals that fluid has played important and multiple roles during complicated fluid rock interactions attending the subduction and exhumation of supracrustal rocks we have identified several distinct stages of fluid rock interactions as follows 1 the neoproterozoic supercrustal protoliths of uhp rocks experienced variable degrees of hydration through interactions with cold meteoric water with extremely low oxygen isotope compositions during neoproterozoic snow ball earth time 2 a series of dehydration reactions took place during triassic subduction of the yangtze plate beneath the sino korean plate the released fluid entered mainly into volatile bearing high pressure hp and uhp minerals such as phengite zoisite epidote talc lawsonite and magnesite as well as into uhp nams such as garnet omphacite and rutile 3 silicate rich supercritical fluid hydrous melt existed during the uhp metamorphism at mantle depths 100 km which mobilized many normally fluid immobile elements and caused unusual element fractionation 4 the fluid exsolved from the nams during the early exhumation of the dabie sulu terrane was the main source for hp hydrate retrogression and generation of hp veins 5 local amphibolite facies retrogression at crustal depths took place by infiltration of aqueous fluid of various salinities possibly derived from an external source 6 the greenschist facies overprinting and low pressure lp quartz veins were generated by fluid flow along ductile shear zones and brittle faults during late stage uplift of the uhp terrane

uhp metamorphism and exhumation of the dabie orogen china evidence from shrimp dating of zircon and monazite from a uhp granitic gneiss cobble from the hefei basin a shrimp u pb study of zircons separated from an ultrahigh pressure uhp granitic gneiss cobble sample ds12 from the upper jurassic fenghuangtai formation of the hefei basin north of the dabie orogen has identified three different domains 1 cores some of which show straight boundaries and strong oscillatory zoning with th u ratios of 0 12 0 70 and an imprecise upper intercept age of 777 220 ma mswd 2 4 2 mantles variable in shape and cathodoluminescence cl intensity and containing many uhp mineral inclusions including coesite and omphacite and with th u ratios of 0 02 0 26 and a weighted mean 206pb 238u age of 244 5 ma mswd 4 7 and 3 rims which are more homogeneous and luminescent in cl than the mantles and contain fewer uhp mineral inclusions with th u ratios of 0 01 0 05 and a weighted mean 206pb 238u age of 226 2 ma mswd 0 65 monazites from the same sample do not contain coesite and omphacite inclusions but they do show sector zones and are composed of two contrasting domains the light domains in backscattered electron bse images have a th u ratio of 7 3 18 9 and a weighted mean 206pb 238u age of 221 2 ma mswd 0 94 the dark domains in bse have a th u ratio of 2 8 7 2 and have a weighted mean 206pb 238u age of 218 2 ma mswd 0 96 based on these data and a review of the literature it can be concluded that 1 the protolith of gneiss sample ds12 is a granitoid of neoproterozoic age 2 the ages of 244 and 226 ma for the mantle and rim domains of the zircons are time records of two discrete stages in the uhp evolution of dabieshan 3 the ages of 221 and 218 ma for the light and dark gray domains respectively of the monazites record the times of two stages of retrogressive metamorphism during exhumation of the uhp granitic gneiss to a higher crustal level 4 the exhumation rate of the gneiss is estimated to be 6 km ma and 5 the uhp metamorphic blocks of the dabie orogen provided significant detritus to the hefei basin in the jurassic

alpine and pacific styles of phanerozoic mountain building subduction zone petrogenesis of continental crust a broad continuum exists between two distinct end member types of mountain building alpine type orogenic belts develop during subduction of an ocean basin between two continental blocks resulting in collision they are characterized by an imbricate sequence of oceanward verging nappes some alpine belts exhibit superimposed late stage backthrusting sediments are chiefly platform carbonates and siliciclastics in some cases associated with minor amounts of bimodal volcanics pre existing granitic gneisses and related continental rocks constitute an autochthonous parautochthonous basement metamorphism of deeply subducted portions of the orogen ranges from relatively high pressure hp to ultrahigh pressure uhp calcalkaline volcanic plutonic rocks are rare and have peraluminous s type bulk compositions in contrast pacific type orogens develop within and landward from long sustained oceanic subduction zones they consist of an outboard oceanic trench accretionary prism and an inboard continental margin island arc the oceanic assemblage consists of first cycle in part melanged volcaniclastics and minor but widespread cherts deep water carbonates intimately mixed with disaggregated ophiolites the section recrystallized under hp conditions recumbent fold vergence is oceanward a massive slightly older to coeval calcalkaline arc is sited landward from the trench complex on the stable non subducted plate it consists of abundant dominantly intermediate metaluminous i type volcanics resting on old crust both assemblages are thrown into open folds intruded by comagmatic i type granitoids and metamorphosed locally to regionally under high t low p conditions in the subduction channel of collisional and outboard circumpacific terranes combined extension above and subduction below allows buoyancy driven ascent of ductile thin aspect ratio slices of hp uhp complexes to midcrustal levels where most closely approached neutral buoyancy exposure of rising sheets caused by erosion and gravitational collapse results in moderate amounts of sedimentary debris because exhumed sialic slivers are of modest volume at massive sialic buildups associated with convergent plate cusps syntaxes tectonic aneurysms may help transport hp uhp complexes from mid to upper crustal levels the closure of relatively small ocean basins that typify many intracratonic suture zones provides only limited production of intermediate and silicic melts so volcanic plutonic belts are poorly developed in alpine orogens compared with circumpacific convergent plate junctions generation of a calcalkaline arc mainly depends on volatile evolution at the depth of magma generation phase equilibrium studies show that under typical subduction zone p t trajectories clinoamphibole ca al hydrous silicates constitute the major hydroxyl bearing phases in deep seated metamorphic rocks of morb composition other hydrous minerals are of minor abundance ca and na clinoamphiboles dehydrate at pressures of above approximately 2 gpa but low temperature devolatilization may be delayed by pressure overstepping thus metabasaltic blueschists and amphibolites expel h2o at melt generation depths and commonly achieve stable eclogitic assemblages partly serpentinized mantle beneath the oceanic crust dehydrates at roughly comparable conditions for reasonable subduction zone geothermal gradients however white micas biotites remain stable to pressures 3 gpa accordingly attending descent to depths of 100 km mica rich quartzofeldspathic lithologies that constitute much of the continental crust fail to evolve substantial amounts of h2o and transform incompletely to stable eclogite facies assemblages underflow of amphibolitized oceanic lithosphere thus generates most of the deep seated volatile flux and the consequent partial melting to produce the calcalkaline suite along and above a subduction zone where large volumes of micaceous intermediate and felsic crustal materials are carried down to great depths volatile flux severely diminishes thus continental collision in general does not produce a volcanic plutonic arc whereas in contrast the long continued contemporaneous underflow of oceanic lithosphere does

two billion years of evolution enclosed in hydrothermal rutile recycling of the sao francisco craton crust and constraints on gold remobilisation processes abstract the quadrilatero ferrifero in the sao francisco craton brazil is known for its world class gold deposits hosted by the rio das velhas greenstone belt rdv as in other greenstone belts gold is also concentrated in late archean early paleoproterozoic supracrustal units in this case within the moeda formation this unit has been compared to the witwatersrand basin where there has been a long term debate over the nature of the gold and whether it is detrital placer hydrothermal or hybrid modified placer presently links between gold in the moeda formation and rdv are tenuous to enlighten this area of ambiguity a new approach using chemical isotopic and mineral inclusion data from detrital rutile found in the gold bearing horizons of the moeda formation is presented grain textures and mineral inclusions have contributed to establishing a primary hydrothermal origin for the rutile related to as fe cu sb pb w rich mineralising fluids fe nb and v indicate that the likely source of the gold related rutiles is the archean banded iron formations within the rdv where most of the lode gold occurs average nb ta values of these rutiles are lower than average continental crust ratios which suggests fractionation driven by fluid precipitation and or competing mineral phases u pb data yield primary crystallization ages older than deposition ages 2 58 ga supporting the detrital nature of these rutiles rutiles record either resetting or new growth at 2 1 ga and at ca 500 ma during which gold was remobilised hence this study supports a modified placer model for the gold bearing horizons of the moeda formation these fluid assisted gold remobilisation events can be found in other correlated paleoproterozoic gold bearing horizon units that represent intracratonic basins related to the rifting of the kenorland supercontinent this study reinforces the suitability of rutile and mineral inclusions as a powerful tool to elucidate processes and provenance

mineral inclusions in zircons of para and orthogneiss from pre pilot drillhole ccsd pp1 chinese continental scientific drilling project the pre pilot drillhole ccsd pp1 chinese continental scientific drilling project ccsd with depth of 432 m is located in the donghai area in the southwestern sulu terrane the core samples are mainly comprised of paragneiss orthogneiss and ultramafic rock with minor intercalated layers of eclogite and phengite bearing kyanite quartzite all analyzed paragneiss and orthogneiss samples were overprinted on amphibolite facies retrograde metamorphism coesite and coesite bearing ultrahigh pressure uhp mineral assemblages were identified by raman spectroscopy and electron microprobe analysis as inclusions in zircons separated from paragneiss eclogite and phengite bearing kyanite quartzite samples in the paragneiss samples uhp mineral inclusion assemblages mainly consist of coe omp grt phe coe jd phe ap preserved in the mantles m and rims r of zircons these uhp mineral inclusion assemblages yield temperatures of 814 852 c and pressures of 28 kbar presenting the p t condition of uhp peak metamorphism of these country rocks according to the mineral inclusions and cathodoluminescence images of zircons the orthogneisses can be divided into two types uhp og1 and non uhp og2 in og1 orthogneisses low pressure mineral inclusion assemblage mainly consisting of qtz phe ab ksp ap were identified in zircon cores c while coesite or coesite bearing uhp mineral inclusions were identified in the mantles m and rims r of the same zircons these features suggest that the og1 orthogneisses together with the paragneisses phengite bearing kyanite quartzite and eclogite experienced widespread uhp metamorphism in the sulu terrane however in the zircons of og2 orthogneiss samples no uhp mineral inclusions were found inclusions mainly comprised qtz phe ap and were identified in cores c mantles m and rims r of og2 zircons the cathdoluminescence images of all analyzed zircons showed clear zonings from cores to rims these features indicate that the og2 orthogneisses in pre pilot drillhole ccsd pp1 did not experience uhp metamorphism therefore we should not rule out the possibility that some orthogneisses in sulu terrane might represent relatively low pressure granitic intrusives emplaced after the uhp event

ultrahigh pressure metamorphic rocks from the chinese continental scientific drilling project i petrology and geochemistry of the main hole 0 2 050 m the main hole mh of the chinese continental scientific drilling project ccsd in southern sulu has penetrated into an ultrahigh pressure uhp metamorphic rock slice which consists of orthogneiss paragneiss eclogite ultramafic rock and minor schist recovered eclogites have a uhp metamorphic mineral assemblage of garnet omphacite rutile phengite kyanite coesite epidote ultramafic rocks contain garnet olivine clinopyroxene orthopyroxene ti clinohumite phlogopite gneisses and schists contain an amphibolite facies paragenesis but their zircons have coesite garnet omphacite or jadeite and phengite inclusions indicating that eclogites and gneisses have been subjected to in situ uhp metamorphism using available geothermobarometers p t estimates of 3 1 4 4 gpa and 678 816 c for eclogites were obtained if surface outcrops and neighboring shallow drill holes are considered together we suggest that a huge supracrustal rock slab 50 km long 100 km wide 5 km deep was subducted to a depth 100 km and then exhumed to the surface the depth interval 0 2 050 m of the ccsd mh can be divided into six lithological units unit 1 consists of alternating layers of quartz rich and rutile rich eclogites with thin interlayers of gneiss and schist eclogites of unit 1 are characterized by nb ta sr and ti depletions low mg number and general lree enrichment unit 2 comprises rutile and ilmenite rich eclogite and minor normal eclogite and is characterized by high tio2 total fe v co and sr and very low sio2 alkali zr ba nb ta and total ree contents and lree depleted ree patterns with slightly positive eu anomalies unit 3 contains ultramafic rock and minor mgo rich eclogite protoliths of uhp rocks from units 1 2 and 3 represent a layered mafic to ultramafic intrusion at crustal depth units 4 and 6 consist of interlayered eclogite and paragneiss the eclogites are characterized by th u nb ta and ti depletion and k enrichment and lree enriched ree patterns paragneisses show nb ta sr and ti depletions and lree enriched ree patterns occasionally with slightly negative eu anomalies indicating that their protoliths represent metamorphic supracrustal series unit 5 consists mainly of orthogneisses showing distinct nb ta sr and ti depletions and lree enriched ree patterns with pronounced negative eu anomalies suggesting granitic protoliths in conclusion it is proposed that the southern sulu uhp belt consists of a series of meta supracrustal rocks a layered mafic ultramafic complex and granites

zircon u pb ages ree concentrations and hf isotope compositions of granitic leucosome and pegmatite from the north sulu uhp terrane in china constraints on the timing and nature of partial melting granitic leucosome and pegmatite are widely distributed within biotite bearing orthogneiss in the northern part of the sulu ultrahigh pressure uhp metamorphic terrane eastern china a combined study of mineral inclusions cathodoluminescence cl images u pb shrimp dates and in situ trace element and lu hf isotope analyses of zircons provided insight into the nature and timing of partial melting in these rocks zircon grains separated from biotite bearing orthogneiss typically have three distinct domains 1 pre metamorphic magmatic cores with qtz kfs pl ap inclusions which record a neoproterozoic protolith age of 790 ma 2 mantles with coe phe ap inclusions that record triassic uhp age at 227 3 ma and 3 narrow rims with quartz inclusions that record hp granulite facies retrograde metamorphism at 210 3 ma in contrast zircons separated from granitic leucosome have only two distinct domains 1 the central uhp areas with coe phe ap inclusions record triassic uhp age of 227 3 ma and 2 outer magmatic areas with qtz kfs ab ap inclusions that record partial melting time of 212 2 ma zircons separated from pegmatite contain mineral inclusions of qtz kfs ap and show regular magmatic zoning from centre to edge the centres record partial melting time of 212 2 ma in line with the outer domains of granitic leucosome whereas the edges give a younger age of 201 2 ma related to pb loss and partial recrystallization during late triassic regional amphibolite facies retrogression these data indicate that partial melting in the north sulu uhp gneissic rocks took place during post uhp retrograde hp granulite facies metamorphism pre metamorphic magmatic zircon cores from biotite bearing orthogneiss give uniform 176hf 177hf of 0 28187 0 00003 2 sd standard deviation corresponding to ehf 790 and hf model ages tdm2 of about 16 3 and 2 41 ga respectively this is consistent with the generation of its protolith by reworking of paleoproterozoic to late archean crust in contrast uhp zircon domains from biotite bearing orthogneiss and granitic leucosome are characterized by distinct trace element composition with low lu hf 0 006 low th u 0 1 and considerably higher 176hf 177hf 0 28233 0 00002 2 sd than the pre metamorphic cores the uniform but significantly different hf isotope composition between the uhp ehf 227 14 6 0 8 2 sd and pre metamorphic ehf 227 27 7 domains indicates equilibration of the lu hf isotope system only within the uhp metamorphic mineral assemblage the disequilibrium between whole rock and uhp zircon suggests that about two thirds of the whole rock hf retained in the pre metamorphic zircon domains zircon domains crystallized during partial melting at 212 ma in granitic leucosome and pegmatites have a hf isotope composition indistinguishable from that of the uhp zircon domains this suggests that only hf and zr equilibrated during uhp metamorphism was remobilized during partial melting while pre metamorphic zircon remained stable or was not accessible in contrast the magmatic zircon edges from pegmatite have somewhat lower 176hf 177hf 0 28216 and ehf t 17 6 1 2 2 sd indicating some release of less radiogenic hf for instance by dissolution of pre metamorphic zircon during late regional amphibolite facies retrogression

diamond from the dabie shan metamorphic rocks and its implication for tectonic setting diamond occurs in ultrahigh pressure metamorphic rocks from dabie shan anhui province eastern china diamond bearing rocks include eclogite gamet pyroxenite and jadeitite diamond occurs in a mineral assemblage with coesite and jadeite the diamonds and diamondiferous rocks of dabie shan are interpreted to be the products of ultrahigh pressure metamorphism in the underthrust basement of the yangtze continental plate during the early mesozoic at greater than 4 0 gigapascals and 900 c this interpretation is based on the distribution of rock units the stability field of diamond and isotopic data indicating a crustal origin for the rocks most diamonds occur as euhedral inclusions in garnets and are 10 to 60 micrometers across although some are up to 700 micrometers across

a potential method to confirm the previous existence of lawsonite in eclogite the mass imbalance of sr and lrees in multistage epidote ganghe dabie uhp terrane lawsonite is an important hydrous mineral that is stable at low temperature lt and high to ultrahigh pressure hp uhp conditions in subducted slabs the occurrence absence of lawsonite in eclogite is a significant constraint for the construction of the metamorphic tectonic and fluid melt evolution histories of an hp uhp terrane however lawsonite is very rarely preserved in natural eclogites and accurate judgment of its former existence is a significant challenge for petrologists at present whether lawsonite has ever existed in lawsonite absent eclogite is mainly judged by i pseudomorphs after lawsonite and ii phase equilibria modelling in this study major element and trace element distributions in multistage minerals were examined in the ganghe lawsonite absent uhp eclogite in the dabie uhp terrane eastern china this work demonstrates that the whole rock sr and light rare earth elements lrees are mainly dominated by epidote other minerals garnet omphacite quartz kyanite barroisite phengite and accessory minerals play a very limited role in the sr and lrees budgets two stages of epidote which have noticeably different sr and lrees contents were recognized in the eclogite i epidote porphyroblasts ep p core which are suspected to be the pseudomorphic mineral after lawsonite contain significantly high sr 7200 10 300 ppm and lrees 160 1300 ppm for la ii an earlier stage epidote ep in core occurs as inclusions in matrix omphacite or in omphacite inclusions in the suspected pseudomorphic minerals after lawsonite spmal this early epidote has significantly lower sr 990 1890 ppm average 1495 ppm n 17 and lrees contents 60 110 ppm for la average 91 ppm n 17 all of the existing early stage minerals predating the spmal have very low contents of sr and lrees and the total amounts of these elements in the early stage minerals do not balance those in the spmal this indicates that a missing ca al sr and lree rich mineral which was previously in equilibrium with the early stage minerals likely existed in the ganghe eclogite on the basis of the mineral geochemistry and phase equilibria modelling we confirm that the missing mineral cannot be anything but lawsonite this study indicates that examining the mass im balance of sr and lrees between multistage hp uhp epidote can be used as a potential method to confirm the previous existence of lawsonite in lawsonite absent eclogite

timing of collision of the sino korean and yangtse cratons u pb zircon dating of coesite bearing eclogites the suture zone between the sino korean and yangtse cratons in central china is marked by a series of fault bounded belts composed of crustal protoliths in the dabie mountains some of these blocks contain coesite and diamond indicating subduction to minimum depths of 120 km as a result of continental collision the blocks range from the structurally lowest ultrahigh pressure metamorphic belt and decrease in metamorphic grade upsection to the structurally highest low greenschist facies belt furthermore the faults mark large contrasts in metamorphic grade these features form a structure that is similar to metamorphic core complexes indicating extension as part of the exhumation process timing of the continental collision has previously been inferred as late triassic from regional geologic relations or caledonian from 40 ar 39 ar dating of the adjacent and possibly related qinling metamorphic belt u pb dating of zircon from ultra high pressure eclogites yields a metamorphic age of 209 2 ma this age coincides with later stages of collision and is therefore a minimum estimate of the time of collision

first finding of microdiamond coesite and other uhp phases in felsic granulites in the moldanubian zone implications for deep subduction and a revised geodynamic model for variscan orogeny in the bohemian massif abstract heavy mineral fractions and polished thin sections from felsic granulites from the moldanubian zone of the bohemian massif were thoroughly studied by means of raman microspectroscopy combined with optical microscopy and scanning electron microscopy the following phases were identified among others as inclusions in robust minerals such as garnet and zircon diamond characterized by an intense narrow peak at 1332 cm 1 was found in two inclusions in zircon they have a size of 5 m coesite identified by its very characteristic peak at 520 cm 1 was found in an inclusion in garnet together with quartz coesite has been almost completely transformed into quartz only minor coesite nano domains remain kumdykolite the orthorhombic polymorph of naalsi 3 o 8 characterized by strong peaks at 220 456 and 492 cm 1 occurs either as single crystals or as a part of multiphase inclusions in garnet and in zircon along with other mineral phases such as k feldspar phengite rutile moissanite sic exhibiting the characteristic raman bands at 767 788 and 969 cm 1 occurs as inclusions in garnet diamond and coesite are considered to have formed at the peak ultrahigh pressure metamorphic uhpm conditions kumdykolite has been proposed to be a metastable phase formed during rapid cooling from high temperature moissanite points to extremely reduced conditions during subduction to great depths the finding of uhp phases in felsic granulites in the moldanubian zone is clear evidence for subduction of crustal materials to mantle depths the garnet hosting the uhp phase inclusions usually preserves prograde compositional zoning this in combination with the uhpm mineral inclusions suggests that the felsic material should have passed uhp metamorphism at a low temperature gradient isothermal decompression the commonly accepted model at temperatures of 850 950 c would have substantially modified and homogenized the garnet composition eliminating any compositional zoning therefore the uhpm felsic rocks could have experienced only a short term granulite facies metamorphism after they were exhumed to crustal levels

mineral and fluid inclusions in zircon of uhp metamorphic rocks from the ccsd main drill hole a record of metamorphism and fluid activity abstract the chinese continental scientific drilling ccsd main drill hole 0 3000 m in donghai southern sulu orogen consists of eclogite paragneiss orthogneiss schist and garnet peridotite detailed investigations of raman cathodoluminescence and microprobe analyses show that zircons from most eclogites gneisses and schists have oscillatory zoned magmatic cores with low pressure mineral inclusions of qtz pl kf and ap and a metamorphic rim with relatively uniform luminescence and eclogite facies mineral inclusions of grt omp phn coe and rt the chemical compositions of the uhp metamorphic mineral inclusions in zircon are similar to those from the matrix of the host rocks similar uhp metamorphic p t conditions of about 770 c and 32 kbar were estimated from coexisting minerals in zircon and in the matrix these observations suggest that all investigated lithologies experienced a joint in situ uhp metamorphism during continental deep subduction in rare cases magmatic cores of zircon contain coesite and omphacite inclusions and show patchy and irregular luminescence implying that the cores have been largely altered possibly by fluid mineral interaction during uhp metamorphism abundant h 2 o co 2 h 2 o or co 2 dominated fluid inclusions with low to medium salinities occur isolated or clustered in the magmatic cores of some zircons coexisting with low p mineral inclusions these fluid inclusions should have been trapped during magmatic crystallization and thus as primary only few h 2 o and or co 2 dominated fluid inclusions were found to occur together with uhp mineral inclusions in zircons of metamorphic origin indicating that uhp metamorphism occurred under relatively dry conditions the diversity in fluid inclusion populations in uhp rocks from different depths suggests a closed fluid system without large scale fluid migration during subduction and exhumation

reply to comment by p j o brien on the onset of india asia continental collision early steep subduction required by the timing of uhp metamorphism in the western himalaya by mary l leech s singh a k jain simon l klemperer and r m manickavasagam earth planetary science letters 234 2005 83 97

the onset of india asia continental collision early steep subduction required by the timing of uhp metamorphism in the western himalaya ultrahigh pressure uhp rocks in the nw himalaya are some of the youngest on earth and allow testing of critical questions of uhp formation and exhumation and the timing of the india asia collision initial collision of india with asia is widely cited as being at 55f1 ma based on a paleomagnetically determined slowdown of india s plate velocity and as being at ca 51 ma based on the termination of marine carbonate deposition even relatively small changes in this collision age force large changes in tectonic reconstructions because of the rapid india asia convergence rate of 134 mm a at the time of collision new u pb shrimp dating of zircon shows that indian rocks of the tso morari complex reached uhp depths at 53 3f0 7 ma given the high rate of indian subduction this dating implies that indian continental crust arrived at the asian trench no later than 57f1 ma providing a metamorphic age for comparison with previous paleomagnetic and stratigraphic estimates india s collision with asia may be compared to modern processes in the timor region in which initiation of collision precedes both the slowing of the convergence rate and the termination of marine carbonate deposition the indian uhp rocks must have traveled rapidly along a short hence steep path into the mantle early continental subduction was at a steep angle probably vertical comparable to modern continental subduction in the hindu kush despite evidence for modern day low angle subduction of india beneath tibet oceanic slab break off likely coincided with exhumation of uhp terranes in the western himalaya and led to the initiation of low angle subduction and leucogranite generation d 2005 elsevier b v all rights reserved

regional ultrahigh pressure coesite bearing eclogitic terrane in central china evidence from country rocks gneiss marble and metapelite the dabie mountains represent a fault bounded coesite bearing eclogite gneissic terrane within the collisional belt between the sino korean and yangtze cratons the following geologic evidence indicates that this terrane has been subjected to regional ultrahigh pressure metamorphism 1 the country rocks have a metamorphic pressure temperature evolution compatible with that of the eclogites on the basis of the occurrence of quartz pseudomorphs after coesite calcite pseudomorphs after aragonite relict high pressure assemblages in different rock types of the country rocks and consistent comparable compositional zonations of garnets in both country rocks and eclogites 2 peak metamorphic pressure temperature conditions consistently decrease both from east to west in the collisional belt and from north to south in the dabie mountains and clockwise pressure temperature paths are common for eclogites over the region 3 layered eclogites interbedded with gneisses and amphibolites contain omphacite kyanite and garnet indicating a minimum pressure of 20 kbar at 600 c for formation of these rocks

large areal extent of ultrahigh pressure metamorphism in the sulu ultrahigh pressure terrane of east china new implications from coesite and omphacite inclusions in zircon of granitic gneiss abstract coesite and omphacite inclusions have been identified for the first time as minute inclusions in zircon from amphibolite facies granitic orthogneiss in the sulu ultrahigh pressure uhp metamorphic terrane of eastern china by raman spectroscopy and microprobe analyses the occurrences of these minerals in the voluminous granitic gneiss of sulu support a regional and pervasive uhp metamorphic event that predated regional amphibolitic retrogression taking into account the widespread discoveries of coesite in other lithologies we thus conclude that a substantial crustal component in the sulu uhp metamorphic terrane appears to have shared a common history of triassic subduction to mantle depths and later exhumation

coesite bearing eclogite from the dabie mountains in central china coesite and coesite pseudomorphs are recognized in eclogite from the dabie mountains a collision zone between the sino korean and yangtze cratons in central china this third known occurrence of coesite in deep crustal rocks is within an archean gneiss terrane and is the first locality where coesite has been identified as an inclusion in both omphacite and garnet crystals at the same location coesite bearing eclogite is estimated to form at pressures of 28 kbar and temperatures from 600 to 710 c the dabie mountains eclogite underwent retrograde metamorphism to amphibolite facies after its formation the preservation of coesite in eclogite is found to be strongly controlled by the pressure temperature time path that coesite bearing eclogite followed during its uplift and retrograde metamorphism

shrimp u pb dating trace elements and the lu hf isotope system of coesite bearing zircon from amphibolite in the sw sulu uhp terrane eastern china abstract in this study we link mineral inclusion data trace element analyses u pb age and hf isotope composition obtained from distinct zircon domains of complex zircon to unravel the origin and multi stage metamorphic evolution of amphibolites from the sulu ultrahigh pressure uhp terrane eastern china zircon grains separated from amphibolites from the ccsd mh drill hole g12 and niushan outcrop g13 were subdivided into two main types based on cathodoluminescence cl and laser raman spectroscopy big dusty zircons with inherited cores and uhp metamorphic rims and small clear zircons weakly zoned grey white luminescent inherited cores preserve mineral inclusions of cpx pl ap qtz indicative of a mafic igneous protolith dark grey luminescent overgrowth rims contain the coesite eclogite facies mineral inclusion assemblage coe grt omp phe ap and formed at t 732 839 c and p 3 0 4 0 gpa in contrast white luminescent small clear zircons preserve mineral inclusions formed during retrograde hp quartz eclogite to lp amphibolite facies metamorphism t 612 698 c and p 0 70 1 05 gpa inherited zircons from both samples yield shrimp 206 pb 238 u ages of 695 520 ma with an upper intercept age of 800 31 ma the uhp rims yield consistent triassic ages around 236 225 and 239 225 ma for g12 and g13 with weighted means of 229 3 and 231 3 ma respectively small clear zircons from both samples give 206 pb 238 u ages around 219 210 ma with a weighted mean of 214 3 ma interpreted as the age of retrograde quartz eclogite facies metamorphism matrix amphibole from both samples indicate ar ar ages of 209 0 7 and 207 0 7 ma respectively probably dating late amphibolite facies retrogression the data suggest subduction of neoproterozoic mafic igneous rocks to uhp conditions in middle triassic 230 ma times and subsequent exhumation to an early hp 214 ma and a late lp stage 208 ma over a period of 16 and 6 myr respectively thus early exhumation from a mantle depth of 120 100 km to about 60 km occurred at an average rate of 0 3 cm y while subsequent exhumation to a middle crustal level took place at approximately 0 54 cm y these exhumation rates are considerably slower than those obtained for uhp rocks in the dora maira and kokchetav massifs 2 3 cm y based on similar p t estimates and trace element and hf isotope compositions sulu amphibolites can be identified as retrograde uhp eclogites the ehf 800 of 8 implies a significant input from the depleted mantle to the sulu dabie terrane during the middle neoproterozoic overgrown rims are characterized by a distinct trace element composition with low lu hf and th u and significantly higher 176 hf 177 hf ratios than inherited cores consistent with formation during after garnet re crystallization and fractionation of the lu hf system during uhp metamorphism the combined dataset suggests homogenization of the 176 hf 177 hf ratio within the metamorphic mineral assemblage and during protolith formation observed variations are explained by mixing of material from both domains during laser ablation e g due to partial recrystallization of inherited cores

secondary production of ampelisca mississippiana soliman and wicksten 2007 amphipoda crustacea in the head of the mississippi canyon northern gulf of mexico abstract annual production was calculated for the dominant ampeliscid amphipod ampelisca mississippiana soliman y wicksten m 2007 ampelisca mississippiana a new species amphipoda gammaredea dominated the head of the mississippi canyon northern gulf of mexico zootaxa submitted at the head of the mississippi canyon in the northern gulf of mexico average densities were 12 094 2499 ind m 2 with secondary production of 6 93 g dry wt m 2 yr 1 based on the size frequency method hynes hamilton h b n coleman m 1968 a simple method for assessing the annual production of stream benthos limnology and oceanography 13 569 573 menzies c a 1980 a note on the hynes hamilton method of estimating secondary production limnology and oceanography 25 4 770 773 with a production biomass p b ratio of 3 11 growth rates of this magnitude are comparable to available data for freshwater and shallow marine ampeliscids but are unexpectedly high for deep ocean habitats growth efficiency appeared to be approximately 35 growth assimilation 100

fluids in deeply subducted continental crust petrology mineral chemistry and fluid inclusion of uhp metamorphic veins from the sulu orogen eastern china abstract the complex vein associations hosted in southern sulu ultrahigh pressure uhp eclogites contain quartz omphacite or jadeite kyanite allanite zoisite rutile garnet these minerals have chemical compositions similar to those of host eclogites inclusions of polycrystalline quartz pseudomorphs after coesite were identified in vein allanite and garnet and coesite inclusions were found in vein zircon these facts suggest that the veins together with host eclogites have been subjected to synchronous uhp metamorphism the vein minerals contain relatively high concentrations of rare earth elements ree high field strength elements hfse and transition metal elements tme a kyanite quartz vein has a whole rock composition similar to adjacent uhp metamorphic granitic gneisses abundant primary multi solid fluid inclusions trapped within uhp vein minerals contain complex daughter minerals of muscovite calcite anhydrite magnetite pyrite apatite celestite and liquid and gas phase of h 2 o with solids up to 30 70 of the inclusion volume the presence of daughter minerals anhydrite and magnetite indicates the subduction fluids were oxidizing and provides a possible interpretation for the high oxygen fugacity of subduction zone magmas these characteristics imply that the uhp vein minerals were crystallized from supercritical silicate rich aqueous fluids that were in equilibrium with peak uhp minerals and that the fluids in deeply subducted continental crust may contain very high concentrations of silicate as well as hree hfse and tme such fluids might have resulted in major fractionation between nb and ta i e the uhp fluids have subchondritic nb ta values whereas the host eclogites after extraction of the fluids have suprachondritic nb ta values therefore voluminous residual eclogites with high nb ta ratios may be the complementary suprachondritic reservoir capable of balancing the subchondritic depleted mantle and continental crust reservoirs

zircon the metamorphic mineral a mineral that forms under conditions as variable as diagenesis to deep subduction melt crystallization to low temperature alteration and that retains information on time temperature trace element and isotopic signatures is bound to be a useful petrogenetic tool the variety of conditions under which zircon forms and reacts during metamorphism is a great asset but also a challenge as interpretation of any geochemical data obtained from zircon must be placed in pressure temperature deformation fluid context under which condition and by which process zircon forms in metamorphic rocks remains a crucial question to answer for the correct interpretation of its precious geochemical information in the last 20 years there has been a dramatic evolution in the use of zircon in metamorphic petrology with the advent of in situ dating techniques zircon became relevant as a mineral for age determinations in high grade metamorphic rocks since then there has been incredible progress in our understanding of metamorphic zircon with the documentation of growth and alteration textures its capacity to protect mineral inclusions zircon thermometry trace element patterns and their relation to main mineral assemblages solubility of zircon in melt and fluids and isotopic systematics in single domains that go beyond u pb age determinations metamorphic zircon is no longer an impediment to precise geochronology of protolith rocks but has become a truly indispensable mineral in reconstructing pressure temperature time fluid paths over a wide range of settings an obvious consequence of its wide use is the rapid increase of literature on metamorphic zircon and any attempt to summarize it can only be partial in this chapter reference to published works are intended as examples and not as a compilation this chapter approaches zircon as a metamorphic mineral reporting on its petrography and texture deformation structure and mineral chemistry including trace element and isotopic systematics linking this information together highlights the potential of zircon as a key mineral in petrochronology

north kona slump submarine flank failure during the early tholeiitic shield stage of hualalai volcano abstract the north kona slump is an elliptical region about 20 by 60 km 1000 km 2 area of multiple geometrically intricate benches and scarps mostly at water depths of 2000 4500 m on the west flank of hualalai volcano two dives up steep scarps in the slump area were made in september 2001 using the rov kaiko of the japan marine science and technology center jamstec as part of a collaborative japan usa project to improve understanding of the submarine flanks of hawaiian volcanoes both dives at water depths of 2700 4000 m encountered pillow lavas draping the scarp and bench slopes intact to only slightly broken pillow lobes and cylinders that are downward elongate dominate on the steepest mid sections of scarps while more equant and spherical pillow shapes are common near the tops and bases of scarps and locally protrude through cover of muddy sediment on bench flats notably absent are subaerially erupted hualalai lava flows interbedded hyaloclastite pillow breccia and or coastal sandy sediment that might have accumulated downslope from an active coastline the general structure of the north kona flank is interpreted as an intricate assemblage of downdropped lenticular blocks bounded by steeply dipping normal faults the undisturbed pillow lava drape indicates that slumping occurred during shield stage tholeiitic volcanism all analyzed samples of the pillow lava drape are tholeiite similar to published analyses from the submarine northwest rift zone of hual lai relatively low sulfur 330 600 ppm and water 0 18 0 47 wt contents of glass rinds suggest that the eruptive sources were in shallow water perhaps 500 1000 m depth in contrast saturation pressures calculated from carbon dioxide concentrations 100 190 ppm indicate deeper equilibration at or near sample sites at water depths of 3900 to 2800 m either vents close to the sample sites erupted mixtures of undegassed and degassed magmas or volatiles were resorbed from vesicles during flowage downslope after eruption in shallow water the glass volatile compositions suggest that the tholeiitic lavas that drape the slump blocks were erupted either 1 early during shield stage tholeiitic volcanism prior to emergence of a large subaerial edifice or alternatively 2 from submarine radial vents during subaerial shield building because no radial vents have been documented on land or underwater for the unbuttressed flanks of any hawaii volcano alternative 1 is favored in comparison to other well documented hawaiian slumps and landslides north kona structures suggest a more incipient slump event with smaller down slope motions and lateral displacements

structural geometry of an exhumed uhp terrane in the eastern sulu orogen china implications for continental collisional processes high precision 1 200 1 1000 mapping of yangkou bay eastern sulu orogen defines the structural geometry and history of one of the world s most significant uhp ultrahigh pressure belts at least four stages of folds are recognized in uhp eclogites and associated quartzo feldspathic gneiss uhp eclogite facies rootless f1 and isoclinal f2 folds are preserved locally in coesite eclogite mylonitic to ultramylonitic quartzo feldspathic and coesite eclogite shear zones separate small scale 5 10 m thick nappes of ultramafic mafic uhp rocks from banded quartzo feldspathic gneiss these shear zones are folded and progressively overprinted by amphibolite greenschist facies shear zones the prograde to retrograde d1 d5 deformation sequence is explained by deep subduction of offscraped thrust slices of lower continental or oceanic crust from the down going plate caught between the colliding north and south china cratons in the mesozoic after these slices were structurally isolated along the plate interface they were rolled in the subduction channel during exhumation and structural juxtaposition with quartzo feldspathic gneisses forming several generations of folds sequentially lower grade foliations and lineations and intruded by in situ and exotically derived melts shear zones formed during different deformation generations are wider with lower grades suggesting that deep crustal upper mantle deformation operates more efficiently perhaps with more active crystallographic slip systems than deformation at mid upper crustal levels

ultra high pressure uhp marble and eclogite in the su lu uhp terrane eastern china a large mass of dolomitic marble including many eclogite blocks occurs in orthogneisses of the rongcheng area of the su lu province eastern china the marble consists mainly of dolomite calcite formerly aragonite graphite forsterite diopside talc tremolite and phlogopite aggregates of talc and calcite occur at the boundary between dolomite and diopside tremolite is a reaction product between talc and calcite eclogite blocks are rimmed by dark green amphibolite the primary mineral assemblage in the core of eclogite is na bearing garnet up to 0 2 wt na2o omphacitic pyroxene clintonite and rutile secondary minerals are pargasitic edenitic amphibole plagioclase sodic diopside chlorite zoisite and titanite the peak metamorphic conditions based on stability of the dolomite forsterite aragonite now calcite graphite assemblage under conditions where tremolite is unstable are estimated at t 610 660 c and p 2 5 3 5 gpa for xco 0 001 a reaction between dolomite and diopside to form talc under tremolite unstable conditions indicates a temperature decrease under ultra high pressure conditions p 2 4 gpa xco 0 0013 the formation of secondary tremolite is consistent with a nearly adiabatic pressure decrease post dating the ultra high pressure metamorphism the temperature decrease under ultra high pressure conditions preceding decompression may reflect the underplating of a cold slab and the rapid decompression probably corresponds to the upwelling stage promoted by the delamination of a downwelling lithospheric root the p t conditions of the amphibolitization stage are estimated at 0 9 gpa and 460 c and are similar to conditions recorded by the surrounding orthogneisses

fluid generation and evolution during exhumation of deeply subducted uhp continental crust petrogenesis of composite granite quartz veins in the sulu belt china

metamorphic evolution mineral chemistry and thermobarometry of schists and orthogneisses hosting ultra high pressure eclogites in the dabieshan of central china as is typical of ultra high pressure uhp terrains the regional extent of the uhp terrain in the dabieshan of central china is highly speculative since the volume of eclogites and paragneisses preserving unequivocal evidence of coesite and or diamond stability is very small by contrast the common garnet xmn 0 18 0 45 phengite si 3 2 3 35 zoned epidote ps38 97 biotite titanite two feldspars quartz assemblages in the more extensive orthogneisses have been previously thought to have formed under low p t conditions of ca 400 50 c at 4 kbar however certain orthogneiss samples preserve garnets with xca up to 0 50 rutile inclusions within titanite or epidote and relict phengite inclusions within epidote with si contents p f u of up to 3 49 overlapping with the highest values 3 49 3 62 recorded for phengites in samples of undoubted uhp schists these and other mineral composition features such as a site deficiencies in the highest si phengites na in garnets linked to y yb substitution and al f ti 1 o 1 substitution in titanites are taken to be pointers towards the orthogneisses having experienced a similar metamorphic evolution to the associated uhp schists and eclogites re evaluated garnet phengite and garnet biotite fe mg exchange thermometry and calculated 5 rutile 3 grossular 2sio2 h2o 5 titanite 2 zoisite equilibria indicate that the orthogneisses may indeed have followed a common subduction related clockwise p t path with the uhp paragneisses and eclogites through conditions of pmax at ca 690 c 715 c and 36 kbar to tmax at ca 710 c 755 c and 18 kbar prior to extensive re crystallisation and re equilibration of these ductile orthogneisses at ca 400 c 450 c and 6 kbar the consequential conclusion that it is no longer necessary to resort to models of tectonic juxtapositioning to explain the spatial association of these dabieshan orthogneisses with undoubted uhp lithologies has far reaching implications for the interpretation of controversial gneiss eclogite relationships in other uhp metamorphic terrains

clinopyroxenite from the sulu ultrahigh pressure terrane eastern china origin and evolution of garnet exsolution in clinopyroxene the rizhao garnet clinopyroxenite occurs as small mantle slices faulted into subducted continental crust in the sulu ultrahigh pressure uhp terrane china two representative garnet clinopyroxenites with exsolution microstructures were studied 1 a massive ilmenite rich specimen composed of coarse grained clinopyroxene containing abundant exsolution rods of grossular rich garnet 20 vol ilmenite 3 4 vol in a fine grained matrix of clinopyroxene garnet ilmenite and 2 megacrystic garnet bearing sample characterized by garnet containing inclusions of clinopyroxene and ilmenite the clinopyroxene inclusions show exsolution rods and blebs with variable amounts of garnet 1 15 vol and minor ilmenite both exsolved and matrix garnets have similar grossular rich compositions the aggregate composition of clinopyroxene garnet ilmenite intergrowth is similar to the whole rock composition we propose that the parental phase of exsolved garnet ilmenite lamellae and clinopyroxene host was either a homogeneous clinopyroxene hypothesis a or a majoritic garnet hypothesis b that experienced three discrete evolution stages if the parental phase was clinopyroxene abo3 with an si deficiency in the b site the rizhao garnet clinopyroxenite could have an initial assemblage clinopyroxene grt ilm formed at near solidus conditions 1400 c at 5 gpa in the upper mantle the second stage is defined by garnet exsolution from the primary clinopyroxene involving decreasing temperature and or increasing pressure related to continental subduction coexisting clinopyroxene host and garnet exsolution grtexs recrystallized at temperatures of 900 c at an assumed minimum p of 5 gpa the third stage is represented by recrystallization of exsolution phases to form the fine grained matrix of cpx grt ilm at 700 c and 3 gpa during the early exhumation of the uhp terrane the speculative hypothesis b implies that the proposed majoritic garnet was from the mantle transition zone 450 km depth this suggestion remains to be tested

syn exhumation partial melting and melt segregation in the sulu uhp terrane evidences from leucosome and pegmatitic vein of migmatite abstract in order to investigate partial melting and melt evolution during exhumation of deeply subducted continental crust we carried out a combined study on layered leucosomes and pegmatitic veins from the weihai rongcheng migmatites in the sulu ultra high pressure uhp metamorphic terrane eastern china the leucosomes are millimetric to centimetric in thickness and mainly consists of k feldspar quartz plagioclase the pegmatitic veins emplace along the compositional layers or crosscut them and are mainly composed of k feldspar quartz cl images show that most zircon grains of the leucosomes have a core rim zoning structure whereas zircons of the pegmatitic veins are mostly new growth grains with rarely preserved relict domains the inherited zircon domains ca 750 ma are of a magmatic origin with zircon ehf t values between 5 7 and 5 3 mean 0 8 1 5 suggesting that the protolith rock is a mid neoproterozoic juvenile crust the zircon overgrowth rims 223 3 ma of the leucosomes and the new zircon grains 217 2 ma of the pegmatitic veins formed in equilibrium with melt and are similar to magmatic zircons in terms of their cl images and trace element compositions e g heavy enriched ree patterns i e very low gd lu n ratios with positive ce and variably negative eu anomalies high y contents and low hf y ratios compared with the inherited protolith zircon domains the triassic zircon domains of the leucosomes and the pegmatitic veins have obviously high u but low th contents resulting in very low th u ratios

neoproterozoic granitoid did not record ultrahigh pressure metamorphism from the southern dabieshan of china abstract it has been often debated whether all granitic gneisses associated with coesite bearing eclogites in southern dabieshan china have also been subjected to ultrahigh pressure uhp metamorphism we show here that a metagranitoid adjacent to the bixiling eclogite ultramafic complex has preserved primary granitic textures and an igneous mineral assemblage of documentclass aastex usepackage amsbsy usepackage amsfonts usepackage amssymb usepackage bm usepackage mathrsfs usepackage pifont usepackage stmaryrd usepackage textcomp usepackage portland xspace usepackage amsmath amsxtra usepackage ot2 ot1 fontenc newcommand cyr renewcommand rmdefault wncyr renewcommand sfdefault wncyss renewcommand encodingdefault ot2 normalfont selectfont declaretextfontcommand textcyr cyr pagestyle empty declaremathsizes 10 9 7 6 begin document landscape mathrm biotite mathrm plagioclase mathrm microcline mathrm quartz mathrm allanite pm mathrm amphi

u pb zircon ages constrain the architecture of the ultrahigh pressure qinling dabie orogen china new shrimp and tims zircon ages 40ar 39ar ages and eclogite locations contribute significantly to our understanding of the ultrahigh pressure dabie shan 1 the geographic extent of the yangtze craton that was subducted to ultrahigh pressure extends to the northern edge of the dabie shan 2 the northern half of the dabie shan is a magmatic complex intruded over a 10 myr interval between 137 and 126 ma that accommodated 100 n s stretching of the pre existing collisional architecture 3 granitic orthogneisses and enclosing ultrahigh pressure paragneisses have indistinguishable zircon populations the population of triassic zircon ages ranges from 219 to 245 ma leading us to question the prevailing assumption that 219 ma zircons formed at ultrahigh pressure and to propose instead that they reflect late retrogression at crustal pressures following the bulk of exhumation

deep subduction of felsic rocks hosting uhp lenses in the central saxonian erzgebirge implications for uhp terrane exhumation abstract contrasting metamorphic conditions determined by chemical geothermobarometric investigations of ultrahigh pressure uhp lenses surrounded by high pressure hp and medium pressure mp felsic country rocks are an enigmatic feature of uhp terranes one of the major questions arising is whether the uhp lenses and the country rocks are a product of different peak metamorphic conditions corresponding to different maximum depth or whether country rocks also experienced uhp conditions but equilibrated and or re equilibrated at a different metamorphic stage here we address this question to the central saxonian erzgebirge in the northwestern bohemian massif germany in order to screen the variety of garnet from lithologies occurring in the study area we analyzed the detrital garnet record from seven modern stream sands in addition to 700 inclusion bearing garnet grains previously studied from the 125 250 m grain size fraction we analyzed the 63 125 and 250 500 m fractions and extended the dataset to overall 2100 inclusion bearing grains the new findings of coesite and diamond inclusions in several garnet grains which are in compositional contrast to garnet of the known uhp lenses but match with those of the felsic country rocks show that considerable parts of the country rocks underwent uhp metamorphism melt inclusions containing cristobalite kokchetavite and kumdykolite in garnet derived from the country rocks point to partial melting and re equilibration during exhumation at hp ht conditions although an amalgamation of rocks which reached different maximum depth may be responsible for some of the contrasting peak metamorphic conditions the mineralogical evidence for uhp conditions in the felsic country rocks surrounding the uhp lenses proves a largely coherent slab subducted to uhp conditions furthermore the presence of coesite in the subducting voluminous felsic crust and its transformation to quartz during exhumation have great implications for buoyancy development during the metamorphic cycle which may explain the high exhumation rates of uhp terranes

petrology geochemistry and isotope data on a ultrahigh pressure jadeite quartzite from shuanghe dabie mountains east central china abstract in the dabie ultrahigh pressure terrane of east central china coesite bearing jadeite quartzites occur locally as intercalated layers with marble and mafic eclogite this rock assemblage is in turn enclosed within quartzofeldspathic gneisses metamorphic parageneses and kelyphitic textures reveal a multistage metamorphic evolution and complex exhumation history the primary peak metamorphic assemblage consists of jadeite garnet coesite rutile apatite minor coesite and coesite pseudomorphs occur as inclusions in jadeite and garnet three stages of retrograde assemblages are observed in the jadeite quartzites stage a is represented by the polymorphic transformation of coesite to quartz aggregates stage b is characterized by formation of coronas around jadeite porphyroblasts consisting of an inner layer of oligoclase amphibole and an outer layer of albite aegirine augite the last stage stage c involved total replacement of jadeite and most garnets by taramitic amphibole albite aegirine augite peak metamorphic p t conditions were 26 kbar at 660 c and are consistent with the estimates from the adjacent coesite bearing eclogites the jadeite quartzites display clockwise p t path that matches those of the adjacent eclogites major and trace element data suggest that the protolith of the jadeite quartzite could have been an albitized siltstone enriched in na and depleted in k and ca the highly negative present day end value 24 7 indicates a very old age for the protolith its late archean model age tdm of 2 58 ga is among the oldest so far identified for rocks from the dabie uhpm terrane concordant field relations and petrogenetic considerations suggest that all mafic politic carbonate and gneissic rocks have experienced in situ uhp metamorphism during triassic continental collision between the sino korean and yangtze cratons

discovery of early paleozoic eclogite from the east kunlun western china and its tectonic significance abstract eclogites discovered in the eastern part of the east kunlun mountains western china are primarily composed of garnet omphacite quartz rutile the garnets show end member components of 48 55 almandine 1 2 spessartine 19 29 grossularite and 16 29 pyrope and the omphacite has a jadeite content of 21 63 the peak metamorphic assemblage of eclogites records a p t condition of 1 6 gpa and 590 c 650 c zircon u pb dating of the inherited magmatic zircons from fine grained eclogite reveals a neoproterozoic age of 934 ma representing the protolith age of the eclogite zircons from the coarse grained eclogite contain inclusions of garnet omphacite and rutile and yield a weighted mean age of 428 ma indicating the metamorphic age of eclogite the eclogites together with the late cambrian 508 ma high pressure granulite to the west constitute an early paleozoic high pressure metamorphic belt in the east kunlun

behavior of calcium isotopes during continental subduction recorded in meta basaltic rocks abstract in order to investigate the behavior of ca isotopes during subduction we report high precision ca isotopic data of a suit of well characterized meta basaltic rocks from the dabie sulu orogen including six greenschists six amphibolites and seven eclogites except two samples that may have been affected by carbonation alteration greenschists amphibolites and eclogites yield comparable 44 42ca values ranging from 0 36 to 0 41 0 32 to 0 39 and 0 32 to 0 42 respectively overall dabie sulu meta basaltic rocks have an average 44 42ca of 0 37 0 06 2sd n 17 19 comparable to terrestrial basalts previously reported 0 36 0 05 2sd n 34 combined with no correlation of 44 42ca with h2o and rb tio2 this study suggests that prograde metamorphism dehydration cannot significantly fractionate ca isotopic compositions of meta basaltic rocks given the comparable cao contents in meta basaltic rocks with increasing metamorphism grade isotope fractionation may be limited by insignificant ca loss during dehydration two heavy greenschists with 44 42ca of 0 46 and 0 49 also have high co2 concentrations indicating carbonation alteration that is evidenced by 0 04m hcl leaching experiments the limited 44 42ca variation observed in the other metamorphic samples is most likely inherited from their igneous protoliths considering that terrestrial basalts have 44 42ca systematically lower than the upper mantle subduction of mafic lithologies e g oceanic slabs thus could reflux light ca isotopes back into the mantle and may create mantle heterogeneity

flake tectonics in the sulu orogen in eastern china as revealed by seismic tomography 1 seismic tomographic image reveals a crocodile like p waves velocity structure beneath the sulu orogenic belt which marks the subduction collision zone between the sino korean block sk and yangtze block yz in eastern china it may imply that the upper crust of the yz was detached from its lower crust and thrust over the sk for a maximum of 400 km in the sulu region whereas the remnant of the subducted yangtze lithosphere was lay beneath the sk this crustal detached structure flake tectonics might have occurred after the triassic subduction collision

a mechanism for na incorporation in garnet an example from garnet in orthogneiss from the su lu terrane eastern china sodian and yttrian na y garnet occurs in orthogneisses of the su lu terrane of eastern china with major quartz microcline and albite and subordinate biotite titanite hematite and zircon acmite rich pyroxene muscovite epidote allanite and hastingsitic amphibole occur in a few of the samples the na y garnet can be divided into almandine spessartinegrossular ai 1 6 per formula unit pfu for 0 12 hereafter denoted as ai garnet and andradite spessartine feh 1 3 pfu hereafter denoted as feh garnet groups average composition of the ai garnet in each sample ranges from alm3ssps13prp grs49adr2 to aim2lsps67prpogrssadr7 the feh garnet contains a calderite component cdr and its composition is alm4 7spslo 2 prp 2adrs9 8 cdr3 12 na y and yb contents of the ai rich garnet reach 0 37 1 46 and 0 42 oxide wt respectively and na y yb 0 99 t 0 16 the feh garnet contains up to 0 11 2 1 and 0 48 wt of na20 y203 and yb203 respectively and its na y yb value 0 17 t 0 1 is lower than that of the ai garnet we conclude that na y and yb are incorporated in the ai rich garnet by the 8jna 8j y yb ca mn 2substitution whereas in the feh garnet y and yb are dominantly incorporated by the 8j y yb l4j ai feh ca mn sl substitution with up to 3 mol y yb for ca mn comparison ofna y yb of garnets in the orthogneisses and in some pegmatites implies that increasing pressure favors incorporation of na with y and yb and that under the albite epidote amphibolite facies or higher pressure conditions y and yb probably substitute into the garnet structure by 8jna 8j y yb ca mn 2 instead of the 8j y yb 4j al feh ca mn sl type substitution effective under lower pressure conditions

plastic flow of coesite eclogite in a deep continent subduction regime microstructures deformation mechanisms and rheologic implications abstract ultrahigh pressure uhp metamorphic rocks are continental crust that once has been subducted to mantle depth and subsequently exhumed to the surface in collisional orogenic belts despite the long distance transport of the uhp rocks in a deep subduction channel and the fast strain rate required for rapid exhumation little evidence for uhp deformation is found in the exhumed uhp terrains so far identified some uhp rocks have even preserved primary igneous and volcanic structures these observations have led to the postulation that the stress level is low a few mpa in the deep subduction zones deformation microstructures of some eclogite mylonites from a ductile shear complex in the sulu uhp metamorphic belt eastern china provide for the first time convincing evidence that dislocation creep is the predominant deformation mechanism for the major constituent minerals of the uhp rocks in a highly strain localized shear zone at the uhp conditions omphacite phengite and kyanite are the main strain accommodating phases and are dynamically recrystallized through progressive subgrain rotation and grain boundary migration coesite is either fractured with irregular extinction in the moderately deformed eclogite or pseudomorphed by polycrystalline quartz aggregates that have a foam structure garnet does not show optically discernable plastic deformation p t conditions for the deformation are estimated to be p 3 3 gpa and t 624 c using garnet omphacite kyanite phengite coesite quartz thermobarometry suggesting that deeply subducted continental crust remains cold at the upper mantle depths large part of the deeply subducted crust remains relatively undeformed strain is strongly localized into narrow shear zones stress level in the deep subduction channel is extrapolated on the order of tens of mpa much higher than it was previously thought

early palaeozoic north qaidam uhp metamorphic belt on the north eastern tibetan plateau and a paired subduction model an early palaeozoic uhp metamorphic belt was recently discovered in the north qaidam mountains in the north eastern part of the tibet plateau the belt contains abundant eclogite with lesser amounts of garnet peridotite and gneiss the paragneiss contains abundant zircon with coesite inclusions whereas the eclogite has garnet with coesite pseudomorphs and omphacite with exsolved quartz the calculated peak metamorphic conditions for the eclogite are t 730 c and p 2 8 gpa the garnet peridotites are magnesium rich with mg s 100 mg mg fe up to 92 olivine in the peridotites is highly magnesian fo 91 5 and tio2 poor and is typical of low t garnet peridotites calculated peak metamorphic conditions for the peridotites are t 837 c and p 2 5 gpa u pb and sm nd isotope dating indicate that continental subduction started during the early ordovician 495 ma the north qaidam uhp together with the north qilian hp belt about 300 km to the north constitute a pair of genetically related early palaeozoic subduction zones along the northern margin of the tibet plateau

a coherent lithostratigraphic unit in the coesite eclogite complex of dabie shan china geologic and petrologic evidence abstract as a contribution to the discussion about the in situ vs exotic origin of the ultrahigh pressure metamorphic uhpm rocks and to the real size of the exhumed tectonic units the wuhe pailou unit wpu in eastern dabie shan was studied the wpu typically consists of two micas epidote gneiss marble with minor eclogite and jadeite bearing granofels with rare garnetite and eclogite nodules these lithologies are enclosed within leucocratic granitic gneiss jadeite bearing granofels is the most peculiar lithology of the wpu being the only felsic rock in dabie shan still preserving extensive relics of the uhpm mineral assemblage the uhp peak assemblage is coesite jadeite garnet epidote phengite kyanite with accessory rutile apatite and zircon all eclogites consist of garnet omphacite quartz coesite rutile or high al titanite phengite clinozoisite kyanite two micas epidote gneiss associated with the jadeite bearing granofels typically consists of epidote muscovite biotite plagioclase k feldspar rare garnet and accessory rutile titanite apatite and zircon locally the wpu paragneiss contains garnet with inclusions of phengite kyanite rutile and amphibole na plagioclase symplectite after omphacite a clockwise p t path was inferred for the wpu which consists of an early prograde part up to coesite eclogite facies conditions p 3 3 gpa and t 720 c an early decompression stage and a late part characterised by a near adiabatic decompression down to medium pressure p 1 1 gpa t 670 c and to low pressure amphibolite facies conditions followed by a final cooling to greenschist facies conditions both field and laboratory data consistently suggest that the wpu characterised by the close association of paragneiss marble eclogite and granofels is a supracrustal metasedimentary sequence which underwent subduction uhpm and exhumation as a coherent tectonic unit therefore within collisional orogens large coherent slices of continental crust may be subducted at depths greater than 100 km

ages of ultrahigh pressure metamorphism and protolith orthogneisses from the eastern dabie shan u pb zircon geochronology the dabie shan contains two rare geologic features one the occurrence of ultra high pressure metamorphic rocks peak p 2 7 gpa uhp in the east central part of this belt and two some of these uhp rocks are characterized by anomalously 18o depleted oxygen isotopic compositions geochronological data are presented that constrain the age of the uhp metamorphism the ages of protoliths and potentially the age of hydrothermal alteration believed to be responsible for the anomalous oxygen isotopic compositions the age of uhp metamorphism in the eastern dabie shan is dated at 218 5 1 7 ma using u pb in zircon separated from host gneisses this age is identical within uncertainty with a less precise age using u pb in zircon separated from uhp eclogite 225 5 3 6 ma and with previously published ages from uhp eclogites of the dabie shan map relationships strongly support an in situ as opposed to exotic orgin of the uhp eclogites in this region the identical ages of uhp metamorphism in the gneisses and eclogites provides additional support for this interpretation the age of the protolith gneisses is dated as 772 5 9 5 ma based on the upper intercept of the zircons which accords well with other dates of granitic gneisses in the qinling belt the association of mafic and felsic magmatism is interpreted to reflect rifting along the northern margin of the yangtze block at this time these upper intercept ages may date the hydrothermal circulation of 18o depleted meteoric water which gave rise to the anomalously 18o depleted uhp protoliths of the dabie shan and sulu region the coincidence of these protolith ages with the early sinian glaciation of south china is consonant with the suggestion that the highly anomalous oxygen isotopic compositions in this region date from this time the upper intercept age of the eclogite is imprecisely determined at 447 82 79 ma but is younger than the host gneisses and is not characterized by anomalous oxygen isotopic compositions

the relationship between systematic metamorphic patterns and collisional processes along the qinling sulu odesan collisional belt between the north and south china cratons

petrology of ultrahigh pressure rocks from the southern su lu region eastern china abstract in the su lu ultrahigh p terrane eastern china many coesite bearing eclogite pods and layers within biotite gneiss occur together with interlayered metasediments now represented by garnet quartz jadeite rock and kyanite quartzite in addition to garnet omphacite rutile coesite other peak stage minerals in some eclogites include kyanite phengite epidote zoisite talc nyboite and high al titanite the garnet quartz jadeite rock and kyanite quartzite contain jadeite quartz garnet rutile zoisite apatite and quartz kyanite garnet epidote phengite rutile omphacite assemblages respectively coesite and quartz pseudomorphs after coesite occur as inclusions in garnet omphacite jadeite kyanite and epidote from both eclogites and metasediments study of major elements indicates that the protolith of the garnet quartz jadeite rock and the kyanite quartzite was supracrustal sediments most eclogites have basaltic composition some have experienced variable crustal contamination or metasomatism and others may have had a basaltic tuff or pyroclastic rock protolith the su lu ultrahigh p rocks have been subjected to multi stage recrystallization and exhibit a clockwise p t path inclusion assemblages within garnet record a pre eclogite epidote amphibolite facies metamorphic event ultrahigh p peak metamorphism took place at 700 890 c and p 28 kbar at c 210 230 ma the symplectitic assemblage plagioclase hornblende epidote biotite titanite implies amphibolite facies retrogressive metamorphism during exhumation at c 180 200 ma metasedimentary and metamafic lithologies have similar p t paths several lines of evidence indicate that the supracrustal rocks were subducted to mantle depths and experienced in situ ultrahigh p metamorphism during the triassic collision between the sino korean and yangtze cratons

hydroxyl rich topaz in high pressure and ultrahigh pressure kyanite quartzites with retrograde woodhouseite from the sulu terrane eastern china hydroxyl rich topaz was recognized in thick kyanite quartzites from both high pressure hp and ultrahigh pressure uhp belts of the sulu terrane china these quartzites contain variable proportions of quartz kyanite and topaz with minor phengite pyrite and rutile some topaz grains from the uhp belt contain abundant inclusions of oriented kyanite whereas those from the hp belt are partially replaced by woodhouseite caal 3 po 4 so 4 oh 6 most topaz crystals contain 9 5 to 13 5 wt f 0 92 1 30 atoms per formula unit apfu indicating 35 55 substitution of f by oh such naturally occurring hydroxyl rich topaz has not been previously reported some topaz grains from the hp belt show distinct zoning 1 decreasing f content from narrow cores 13 3 16 5 wt to thick rims 9 5 wt or 2 oscillatory zoning 9 44 12 77 wt unit cell parameters of topaz show a positive linear correlation between the oh content and a and b as well as volume based on our petrologic data the experimentally determined curve of ky h 2 o topaz oh at very high pressures and calculated oh oh f isopleths of topaz at low pressures the topaz with x oh 0 35 from the uhp belt may have formed at p t conditions within the coesite stability field the p t condition of hp topaz is less well constrained its high x oh 0 40 0 55 may have been caused by lower metamorphic temperatures and higher initial x oh in comparison with uhp topaz hydroxyl rich topaz together with other hydrous minerals in uhp rocks may be important carriers of h 2 o to mantle depths of 100 200 km during continental subduction