eolian deposition in the northeast pacific ocean cenozoic history of atmospheric circulation the mass accumulation rate and grain size distribution of the total eolian component of north pacific pelagic clays have been used to evaluate changes in eolian sedimentation and in the intensity of atmospheric circulation that have occurred during the past 70 m y eolian deposition was relatively low approximately 12 mg cm2 1 000 yr in the late cretaceous and paleocene reflecting an increasingly humid environment a peak in accumulation rates across the paleocene eocene boundary may be the result of episodic volcanism in mexico a sharp decrease in grain size across the paleocene eocene boundary is not readily interpreted fine eolian grain size and the low accumulation rates averaging 8 mg cm2 1 000 yr in the eocene and early oligocene are in agreement with low early tertiary thermal gradients and less vigorous atmospheric circulation large increases in grain size between 37 and 30 m y ago 20 and 10 m y ago and 5 m y ago to the present suggest that atmospheric circulation intensified by a factor of 1 5 1 8 and 1 4 respectively at these times eolian accumulation rates increased from 8 mg cm2 1 000 yr at the eocene oligocene boundary to approximately 25 mg cm2 1 000 yr at the end of the miocene with significant changes at 25 and 13 m y ago increased rates about 25 m y ago probably reflect movement of the core site into the influence of the westerlies and the increase 13 m y ago appears to be a response to steepening thermal gradients and intensifying atmospheric circulation resulting from major expansion of antarctic ice in the mid miocene along with a general increase in global aridity in the late cenozoic an order of magnitude increase in eolian accumulation rates 25 to 226 mg cm2 1 000 yr in pliocene pleistocene time coincides with the onset of northern hemisphere glaciation and consequent climatic deterioration the large increase in accumulation rates in pliocene pleistocene time coincides with a relatively smal increase in the intensity of atmospheric circulation compared to that in oligocene and miocene time suggesting that the increased deposition rates were the result of an increase in global aridity in glacial times rather than a further increase in the vigor of the global wind systems

late oligocene early miocene birth of the taklimakan desert as the world s second largest sand sea and one of the most important dust sources to the global aerosol system the formation of the taklimakan desert marks a major environmental event in central asia during the cenozoic determining when and how the desert formed holds the key to better understanding the tectonic climatic linkage in this critical region however the age of the taklimakan remains controversial with the dominant view being from 3 4 ma to 7 ma based on magnetostratigraphy of sedimentary sequences within and along the margins of the desert in this study we applied radioisotopic methods to precisely date a volcanic tuff preserved in the stratigraphy we constrained the initial desertification to be late oligocene to early miocene between 26 7 ma and 22 6 ma we suggest that the taklimakan desert was formed as a response to a combination of widespread regional aridification and increased erosion in the surrounding mountain fronts both of which are closely linked to the tectonic uplift of the tibetan pamir plateau and tian shan which had reached a climatically sensitive threshold at this time

the sedimentary expression of oceanic anoxic event 1b in the north atlantic abstract the aptian albian oceanic anoxic event 1b contains the record of severalperturbations in the global carbon cycle and multiple black shale levels particularly in the western tethys the local lithological expression of anoceanic anoxic event depends on palaeogeographical and depositional settingas well as on regional palaeoclimate marine sediments at a particular locationmay therefore be more or less organic rich or not at all and they may consistof different lithologies in most studies however much of the lithologicalvariability associated with oceanic anoxic events is left unaccounted for and thus the exact processes leading to the enrichment of organic matter in thesemarine sediments and their subsequent preservation in the geological recordare unknown this study focuses on the local sedimentary processes behindthe deposition of organic rich sediments at deep sea drilling project site 545and ocean drilling program sites 1049 and 1276 in the north atlantic duringoceanic anoxic event 1b although speci cally dealing with the sedimentsdeposited during this particular event at these localities it is expected that thesame processes were responsible for determining the exact sedimentaryproducts at localities in similar settings as well as during other similar eventsin the mesozoic here it is shown that the deposition of organic richsediments during oceanic anoxic event 1b was a consequence of theenhanced productivity favoured by upwelling and by riverine nutrientinput or aeolian fertilization of the euphotic zone depending ongeographical location slope instability processes resulted in the transfer ofpart of these organic rich sediments from the shelf to deep sea depocentres asmud laden organic rich turbidites especially in the northern north atlantic the so called black shales are much more varied than their name implies the end product of sedimentation during an oceanic anoxic event at aparticular location is commonly the result of several equi nal processes actingon a local scale rather than the direct result of basinal or even globalmechanisms keywords aptian albian kilian event north atlantic oae 1b oceandrilling program oceanic anoxic event paquier event

the paleoclimatic record provided by eolian deposition in the deep sea the geologic history of wind the mineral component of pelagic sediment is brought to the deep sea by transport in the wind extraction and analysis of this dust allows estimation of the past aridity of the eolian source region via flux determinations and of the intensity of the transporting winds from grain size data these two parameters the grain size and mass flux of dust vary independently there are three significant sources of modern dust eastern and central asia northwest africa and arabia all in the northern hemisphere as the rainfall associated with the intertropical convergence zone is an effective barrier to southerly transport of dust the northern hemisphere is an order of magnitude more dusty than is the southern an asymmetry that has characterized most of the cenozoic eolian flux data show that most of the northern hemisphere was more arid during glacial maxima with 3 to 5 times as much dust transported during glacial stages than during interglacials only northwestern south america varied in the opposite sense the periodicity of quaternary variation in both eolian flux and eolian grain size data is strongly influenced by the milankovitch cycles of orbital variability wind intensities vary on a shorter time scale than the general 100 kyr cycles of glaciation and general aridity eolian grain sizes display forcing at precessional 19 and 23 kyr tilt 41 kyr and at approximately 30 kyr periodicities as a result the generalization that winds are uniformly stronger during glacial times is not valid whole cenozoic records show that the largest change in dust flux an order of magnitude increase occurred in the northern hemisphere and reflects continental drying associated with the late pliocene onset of northern hemisphere glaciation southern hemisphere eolian records show no sign of paleoclimatic changes in the late pliocene the most important change in cenozoic atmospheric circulation was a severalfold reduction in wind intensity that occurred at the time of the paleocene eocene boundary before then latest cretaceous and paleocene winds were essentially as strong as those of the late cenozoic this shift appears to be one of several climatic responses to a change in the nature and amount of global heat transport at about 55 ma

abyssal circulation and benthic foraminiferal changes near the paleocene eocene boundary a major change in cenozoic deep sea benthic foraminifera occurred in the atlantic indian and pacific oceans near the paleocene eocene boundary benthic foraminiferal abundance changes began at about 61 5 ma at pacific deep sea drilling project dsdp site 577 a major extinction event followed at 58 57 ma between zones p6a and p6b and a series of first appearances continued until circa 55 5 ma zone p6c these faunal changes occurred during a 6 c warming of pacific bottom water and may indicate that the primary cause was changing temperature other potential causes of the faunal turnover include global changes in surface ocean productivity and changing bottom water source regions comparison of benthic and planktonic 13c records requires no change in the ratio of oceanic phosphorous to carbon during the late paleocene to early eocene which weakens the case for but does not disprove a change in surface ocean productivity at this time interbasinal comparisons of benthic foraminiferal 13c records document that water with high 13c values filled the cape basin during the late paleocene and possibly the early eocene circa 61 57 ma but apparently did not extend into the western basins of the atlantic this pattern suggests a supply of antarctic source water for the cape basin and possible tectonic isolation of the western atlantic basins during at least part of the late paleocene carbon isotope comparisons show that bottom water supply to the cape basin was reduced in the early eocene eolian grain size data suggest that a decrease in zonal wind intensity occurred at the end of the paleocene these late paleocene climatic changes bottom water warming and decreased wind intensity correspond with evidence for an important global tectonic reorganization and extensive subaerial volcanism which may have contributed to climatic warming through increased supply of co2

origin and development of artemisia asteraceae in asia and its implications for the uplift history of the tibetan plateau a review abstract the spatial and temporal evolution of artemisia and its relationship with the tibetan plateau tp uplift are examined by summarizing pollen data from 122 sites across china the pollen morphological data reveal that artemisia may have originated from the arid semiarid middle latitudes of asia in the late eocene and spread west and east in the oligocene as the result of early uplift of the tibetan plateau and the global cooling during the miocene artemisia reached the southeastern part of the tp and became common in the western tp due to the high elevation in these regions at the same time the asian monsoon prevented the spread of artemisia to the southern part of the tp since the pliocene especially in the pleistocene artemisia distribution was very similar to its current distribution which indicates that the topography of the tp and the paleoenvironmental conditions in the east asia became more like today thus the cenozoic origin and evolution of artemisia in the asia was strongly influenced by the uplift of the tp global cooling as well as monsoon development

differing controls over the cenozoic pb and nd isotope evolution of deepwater in the central north pacific ocean dissolved pb and nd isotope ratios of seawater as recorded by chemical marine precipitates such as hydrogenetic ferromanganese crusts have been used as paleoenvironmental proxy tracers for the north pacific however all ferromanganese crusts studied so far have either been subject to phosphatization or hydrothermal influence in their old part or only the young parts have been analyzed thus the pb and nd isotope compositions of north pacific deep waters prior to 20 ma are not well constrained we present new results for three ferromanganese crusts one of which cj01 shows no phosphatization and is located far away from the epr its age is inferred to be 75 ma and thus provides for the first time an opportunity to trace the nd and pb isotope evolution of central north pacific seawater back to the latest cretaceous the three crusts no matter whether phosphatized or not display very similar pb and nd isotope trends with age suggesting no modification of the pb and nd isotope distribution by post depositional phosphatization our data suggest that dissolved pb in deep waters of the central north pacific over the cenozoic and latest cretaceous has mainly been derived from eolian dust and only to a minor extent from weathering of island arcs for pb these trends broadly resemble the pb isotope evolution of the eolian silicate dust fraction of core ll44 gpc3 in the central north pacific we suggest that the isotope evolution of dissolved pb in central north pacific seawater has been mainly controlled by pb released from eolian dust from north america prior to 50 ma and after 40 ma from asia in contrast the nd isotope time series of the crusts are by no means similar to the nd isotope evolution of the silicate dust fraction in core gpc3 suggesting a decoupling from the pb and negligible contributions from dust to the dissolved nd in the central north pacific deep water the rise of nd isotope ratios of pacific seawater during the cenozoic has most likely been caused by the increasing volcanic activity and erosion of the volcanic arcs around the pacific

cenozoic evolution of asian climate and sources of pacific seawater pb and nd derived from eolian dust of sediment core ll44 gpc3 1 the large diameter piston core ll44 gpc3 from the central north pacific ocean records continuous sedimentation of eolian dust since the late cretaceous two intervals resolved by nd and pb isotopic data relate to dust coming from america prior to 40 ma and dust coming from asia since 40 ma the intertropical convergence zone itcz separates these depositional regimes today and may have been at a paleolatitude of 23 n prior to 40 ma such a northerly location of the itcz is consistent with sluggish atmospheric circulation and warm climate for the northern hemisphere of the early to middle eocene since 40 ma correlations between nd 7 55 end t 10 81 and pb 18 625 206 4pb 18 879 15 624 207 4pb 15 666 38 611 208 4pb 38 960 0 8294 207 6pb 0 8389 2 0539 208 6pb 2 0743 isotopes reflect the progressive drying of central asia triggered by the westward retreat of the paleo tethys comparisons between the changes with time in the isotopically well defined dust flux and nd and pb isotopic compositions of pacific deep water allow one to draw two major conclusions 1 dust bound nd became a resolvable contribution to pacific seawater only after the one order of magnitude increase in dust flux starting at 3 5 ma therefore eolian nd was unimportant for pacific seawater nd prior to 3 5 ma 2 the lack of a response of pacific deep water pb to this huge flux increase suggests that dust bound pb has never been important instead mobile pb associated with island arc volcanic exhalatives probably consists of a significant contribution to pacific deep water pb and possibly to seawater elsewhere far away from landmasses

tracing dust sources and transport patterns using sr nd and pb isotopes continental dust transported through the atmosphere can be a tracer of atmospheric circulation and transport as well as being a source of information about climate in the dust s source area this information about the provenance of dust transported from desert areas and deposited elsewhere on the oceans and continents can be evaluated using several observational techniques satellite imagery has been used to this end in recent decades and air mass back trajectories have been calculated to trace dust deposits back to their source area another method consists of analysis of the concentration and composition of certain tracers in the dust itself and comparing them to soils and sediments from possible source areas this method has the advantage of being useable for paleo atmospheric circulation and paleo dust transport studies whereas satellite imagery and air mass back trajectories are restricted to relatively recent times we review here different kinds of isotopic tracers that have been used to trace dust provenance but special attention is focused on the use of sr nd and pb isotopes we evaluate their use in studies of both spatially as well as temporally varying continental dust source and transport

evidence for northeastern tibetan plateau uplift between 25 and 20 ma in the sedimentary archive of the xining basin northwestern china the growth history of the tibetan plateau provides a valuable natural laboratory to understand tectonic processes of the india asia collision and their impact on and interactions with asian and global climate change however both tibetan plateau growth and asian paleoenvironments are generally poorly documented in pre pliocene times and reflect limited temporal coverage for different parts of the plateau here we present magnetostratigraphic results from the xining basin at the ne margin of the tibetan plateau precisely dating the record between the earliest oligocene 33 ma to the middle miocene 16 ma the pattern of observed paleomagnetic polarity zones is unequivocally correlated to the geomagnetic polarity time scale gpts indicating relatively constant and low sediment accumulation rates 32 m myr except for a peculiar period of unstable accumulation between 25 3 and 19 7ma at the beginning of this interval a marked permanent increase in magnetite content of the sediments is observed and likely relates to a change in provenance we directly relate this unstable period of sediment accumulation and provenance change to the coeval exhumation recently reported by low temperature thermochronology from the laji shan range which subsequently formed the southernmargin of the xining basin evidence for ne tibet tectonismat 25 20 ma can be associated with widespread deformation over the entire himalayan tibetan orogen at this time which may be linked to the coeval appearance of monsoon climate in eastern asia and the onset of central asian desertification

a 420 000 year record of cyclicity in oceanic and atmospheric processes from the eastern equatorial pacific samples from the upper portion of a cyclic pelagic carbonate sediment sequence in deep sea drilling project dsdp hole 503b 4 0 n 95 6 w are the first group to be analyzed for paleoceanographic and paleoclimatic proxy indicators of ice volume deep ocean and surface water circulation and atmospheric circulation in order to resolve the complex origin of the cyclicity temporal resolution is taken from the 18o time scale most other parameters are calculated in terms of their mass flux to the seafloor caco3 percent in the sediments fluctuates in the well known pacific pattern and is higher during glacial times the fluxes of opal and organic carbon have patterns similar to each other and show a variability of a factor of 2 5 to 4 the longer organic carbon record shows flux maxima during both glacial and interglacial times the accumulation patterns of both opal and organic carbon suggest that the variability in surface water productivity and or seafloor preservation of those materials is not simply correlated to glacial or interglacial periods eolian dust fluxes are greater during interglacial periods by factors of 2 to 5 indicating that eolian source regions in central and northern south america were more arid during interglacial periods the record of eolian grain size provides a semiquantitative estimation of the intensity of the transporting winds the eolian data suggest more intense atmospheric circulation during interglacial periods opposite to the anticipated results we interpret this observation as recording the southerly shift of the intertropical convergence zone to the latitude of hole 503b during glaciations

quantitative resolution of eolian continental crustal material and volcanic detritus in north pacific surface sediment proxy records of continental climate and atmospheric circulation provided by analyses of eolian continental material extracted from marine sediment have resulted in significant new information concerning the behavior of these climate systems on various timescales these studies however currently are limited to certain geographic areas because no chemical or physical extraction procedure provides an unambiguous separation of eolian continental crustal material from other contaminants like volcanic detritus we employ a combined analytical and statistical procedure in an effort to extract a more refined eolian signal from areas that may be affected by volcanic detritus bulk surface sediment samples from 33 locations in the north pacific were treated using a conventional sequential extraction procedure to remove the carbonate silica and oxyhydroxide components and the residue was analyzed by instrumental neutron activation analysis inaa for la ce sm eu yb lu hf sc and th q mode factor analysis of these data shows that 99 of the variance is explained by two end members which we interpret to be continental crustal material and volcanic detritus five least squares normative analysis models were evaluated to estimate the relative amount of these end members in each sample the continental crustal component was approximated using a fine grained fraction of china loess and bulk loess the volcanic component was approximated using the compositions of average kurile kamchatka volcanic material a median ocean drilling program odp leg 145 ash and a median kurile basalt the model based on average kurile kamchatka volcanic material and the fine loess fraction gives the most accurate results central and east pacific samples typically contain up to 100 of the eolian continental crustal component while samples near japan kamchatka and the aleutians contain a majority of volcanic detritus however the highly variable composition of volcanic material can result in systematic errors up to 25 in samples dominated by volcanic detritus the geographic distribution of the compositional end members is consistent with a continental dust source originating in asia and being diluted by ash from the volcanic arcs of the pacific rim this improved identification and resolution of the eolian continental component realized in this approach should permit paleoclimatic reconstructions to be developed from sediments in significant portions of the world that were previously precluded from analysis because of limitations with chemical or physical extraction procedures

miocene climate change on the chinese loess plateau possible links to the growth of the northern tibetan plateau and global cooling the evolution of the asian monsoon arid environmental system during the cenozoic was closely related to the growth of the himalayan tibetan plateau and global climate change however due to inconsistencies in paleoclimatic reconstructions and to various constraints on the timing of the growth of the tibetan plateau the relative impacts of regional uplift and global cooling on asian climate change remain controversial here we investigate the mineralogical composition of a miocene red clay deposit on the western chinese loess plateau in order to infer changes in chemical weathering and monsoon intensity variations of four mineralogical ratios chlorite quartz illite quartz calcite quartz and protodolomite quartz reveal that the summer monsoon intensity was relatively strong during the early miocene 23 5 18 5 ma weakened gradually until 9 5 ma and strengthened again in the late miocene we synthesized previously published thermochronological data from the northeastern tibetan plateau and surrounding mountains and the results suggest that two phases of the rapid growth of northern tibet occurred around 24 17 and 13 7 ma comparison of paleoclimatic proxies and thermochronological data suggests that the gradual weakening of the summer monsoon intensity from 18 5 to 9 5 ma paralleled global cooling whereas two intervals of strengthened monsoon in the early and late miocene were possibly related to the rapid growth of northern tibet our combination of paleoenvironmental proxies and thermochronological data reveals possible links between miocene asian monsoon evolution phased growth of the tibetan plateau and global climate change and confirms the interconnection of geodynamic and atmospheric processes in the geological past

the assessment of ree patterns and 143nd 144nd ratios in fish remains abstract the ree content and isotopic composition of sr and nd have been determined in fish teeth ranging in age from the trias to the present and from various localities mostly around the atlantic these measurements have been carried out on selachian and teleost remains from the same locality in togo and show no appreciable difference which suggests with the help of a mass balance calculation of the ce anomaly that diagenetic effects are not responsible for the ree enrichment of biogenic phosphates one group of fossil teeth has about 3 times the ree abundances of shale and a shale normalized pattern with a minimum at sm it is thought to reflect deposition in the open sea environment a second group has ree concentration about 10 times higher than the first group with either a regular light ree enrichment or more frequently a maximum in the middle ree both being probably indicative of deposition in estuarine or near shore conditions the shape of the ree spectra and the size of the ce anomaly can be used semi quantitatively to determine the depth of deposition the results presented here on late cretaceous eocene fish teeth samples from morocco reflect an increasing influx of deep waters with a lowla yb ratio and strong negative ce anomaly which agrees well with the evolution of sediment chemistry and microfauna associations in contrast nd is typical of the water mass in which the fish debris decayed examples of nearly isolated basins identified with nd isotopes include the south atlantic prior to the lutetian nd 13 5 the miocene persian gulf nd 3 1 and bolivia during the late cretaceous nd 12 8 togo and guinea bissau results suggest that in the south atlantic the meridional oceanic circulation had not started before 45 ma ago combination of ree and nd data suggests that the assignment of jurassic cretaceous samples measured so far to open sea water masses is still ambiguous

late pleistocene continental climate and oceanic variability recorded in northwest pacific sediments core v21 146 provides a continuous record of northwest pacific pelagic sedimentation spanning the past 530 000 years downcore variations of 18o from benthic foraminiferal calcite were correlated to the specmap record to provide an age model for late pleistocene paleoclimatic and paleoceanographic variation fluxes of caco3 and eolian material have been determined by combining information about linear sedimentation rates bulk densities and component percentages the mass accumulation rate mar of caco3 varies from 58 to 1435 mg cm kyr 1 and exhibits the pacific ocean pattern of higher accumulation associated with glacial periods for the younger portion of the record however the pattern of caco3 accumulation appears to shift during the mid brunhes so that prior to 350 000 years ago it exhibits an opposite pattern of greater accumulation during interglacial periods the flux of eolian dust is a proxy measure of the source area aridity and correlates well to the loess soil stratigraphy in china dust fluxes range from 43 to 718 mg cm kyr 1 and are greater by a factor of about 4 during glacial times cross spectral analysis of the eolian flux and oxygen isotope records shows an inphase and coherent relationship at each of the major orbital periodicities of 100 41 and 19 kyr eolian grain sizes generally used as a proxy record of wind intensity range from 8 4 2 9 m to 6 2 13 6 m a change in grain size variability occurs near about 300 ka such that the older portion is characterized by lower frequency and higher amplitude fluctuations than the younger portion power spectra for the eolian grain size record show dominant peaks at 100 and 50 kyr and a broad 25 35 kyr peak but coherency to the oxygen isotope curve at only the 100 and 33 kyr periodicities the phase relationship for eccentricity between the eolian grain size and 18o records suggests that at the 100 kyr frequency the smallest grain sizes are associated with glacial conditions

causes and implications of the middle rare earth element depletion in the eolian component of north pacific sediment abstract previous studies clearly demonstrate that the detrital fraction of central north pacific sediment is derived almost exclusively from wind born particles from the arid and semi arid regions in asia these conclusions are based in part on trajectories observed for westerly wind systems and on a grainsize distribution for central north pacific sediment which can only be explained by eolian transport these observations have been verified by comparing the mineralogy neodymium isotopic composition and trace element geochemistry of the sediment with its asian source region however recent geochemical investigations consistently highlight compositional differences exemplified by a mree middle rare earth element depletion and a lower th sc ratio in eolian material extracted from north pacific sediment when compared to bulk china loess the continental analog of the eolian material these geochemical differences persist even when the bulk loess is subjected to the same extraction procedure here we present experiments demonstrating that these compositional differences are caused by a combination of grainsize fractionation during transport and partial dissolution of ree and th bearing phosphatic phases during the extraction procedure two bulk loess samples from china were separated into several different grain size fractions and a split of each fraction was subjected to the extraction procedure commonly used to isolate terrigenous material from marine sediment all extracted and unextracted sample pairs were analyzed for p th sc fe la ce sm eu yb and lu the amount of p removed by the extraction procedure correlates well with both the observed mree depletion and the decrease in th sc and is most pronounced in the finest grained samples these correlations strongly suggest that the extraction procedure dissolves inorganic phosphate phases which are rich in mrees and th a comparison of the compositions of the 2 3 mm loess size fractions with central north pacific sediment shows that both of these materials are identical

deglacial dust provenance changes in the eastern equatorial pacific and implications for itcz movement abstract the provenance of eolian dust supplied to deep sea sediments has the potential to offer insights into changes in past atmospheric circulation specifically measuring temporal changes in dust provenance can shed light on changes in the mean position of the intertropical convergence zone itcz a region acting as a barrier separating wind blown material derived from northern versus southern hemisphere sources here we have analyzed nd sr and pb isotope ratios in the operationally defined detrital component extracted from deep sea sediments in the eastern equatorial pacific eep along a meridional transect at 110 w from 3 s to 7 n odp leg 138 sites 848 853 sr isotope results show that barite sr has a significant influence on 87sr 86sr isotope ratios of samples in the upwelling zone of the eep however sites located 3 or more away from the equator sites 852 and 853 are believed to not be affected by barite sr and provide useful detrital sr signals 208pb 206pb and 207pb 206pb ratios in all cores fall into the pb isotope space of five potential dust sources asia north and central south america sahara and australia with no distinct isotopic fingerprinting of the dominant source s end values were most valuable for discerning detrital source provenance and their values at all sites ranging from 5 46 to 3 25 were more unradiogenic for sediments deposited during the last glacial than for those deposited during the holocene there are distinct latitudinal trends in the end values with more radiogenic values further south and less radiogenic values further north excluding site 848 this distinction holds true for both holocene and last glacial periods for the most southerly site 848 we invoke for the first time a distinct southern hemisphere australian source as being responsible for the unradiogenic nd isotope ratios both average last glacial and holocene end values show similar sharp gradients along the transect between 5 29 n and 2 77 n suggesting little movement of the glacial itcz in the eep however during the deglacial this gradient is stronger and shifted further north between 5 29 n and 7 21 n suggesting a more northerly possibly stronger deglacial itcz

the behavior of rare earth elements in seawater precise determination of variations in the north pacific water column abstract we present new highly precise and accurate data for ten rare earth elements rees in two water column profiles and in bottom waters from three additional localities in the north pacific our results presented here and in an earlier publication indicate that the water column in the western north pacific is stratified with respect to the isotopic composition of nd as well as nd la sm nd and er la both the nd isotopic and the ree data show that ree transport is strongly influenced by horizontal advection even in the sluggish circulation of the pacific in general rees increase in concentration with depth at mid latitude they reach a maximum concentration at about 3000 m and then decrease to the bottom at high latitude heavy rees reach a maximum concentration near 3000 m whereas light rees continue to increase in concentration with depth the deep water maximum and bottom water depletion is interpreted as an advective feature resulting from the flow of a lower concentration of rees in antarctic bottom water under a higher concentration of rees in the north pacific concentrations of rees do not show a linear relationship with those of si indicating that the ree cycle is not directly coupled to that of the si cycle ree element ratios i e nd la correlate with hydrographie properties which suggests that major features of the ree patterns may be conserved during lateral transport comparison of our ree data to those in previously published reports on pacific seawater shows that the identification of ree distributions affected by advection is only made possible by the high precision analysis we developed for this study the ce concentration we observe is relatively constant over 200 4500 m depth at both sites where we have complete profiles this unique constancy of ce is in contrast to the contiguous rees la and nd which show substantial concentration variations with depth

rare earth major and trace element composition of monterey and dsdp chert and associated host sediment assessing the influence of chemical fractionation during diagenesis abstract chert and associated host sediments from monterey formation and deep sea drilling project dsdp sequences were analyzed in order to assess chemical behavior during diagenesis of biogenic sediments the primary compositional contrast between chert and host sediment is a greater absolute sio2 concentration in chert often with final sio2 98 wt this contrast in sio2 and si al potentially reflects precursor sediment heterogeneity diagenetic chemical fractionation or both sio2 concentrations and si al ratios in chert are far greater than in modern siliceous oozes however and often exceed values in acid cleaned diatom tests compositional contrasts between chert and host sediment are also orders of magnitude greater than between multiple samples of the host sediment calculations based on the initial composition of adjacent host observed porosity reductions from host to chert and a postulated influx of pure sio2 construct a chert composition which is essentially identical to observed sio2 values in chert thus precursor heterogeneity does not seem to be the dominant factor influencing the current chert composition for the key elements of interest in order to assess the extent of chemical fractionation during diagenesis we approximate the precursor composition by analyzing host sediments adjacent to the chert the sio2 concentration contrast seems caused by biogenic sio2 dissolution and transport from the local adjacent host sediment and subsequent sio2 reprecipitation in the chert along with sio2 other elements are often added with respect to al to monterey and dsdp chert during silicification although absolute concentrations decrease the two monterey quartz chert nodules investigated in contrast to the opal ct and quartz chert lenses formed primarily by extreme removal of carbonate and phosphate thereby increasing relative sio2 concentrations dsdp chert formed by both carbonate phosphate dissolution and sio2 addition from the host manganese is fractionated during chert formation resulting in mno al 2 o 3 ratios that no longer record the depositional signal of the precursor sediment ree data indicate only subtle diagenetic fractionation across the rare earth series ce ce values do not change significantly during diagenesis of either monterey or dsdp chert eu eu decreases slightly during formation of dsdp chert la n yb n is affected only minimally as well during formation of one monterey opal ct chert lens ree al ratios show subtle distribution changes at gd and to a lesser extent near nd and ho ree compositional contrasts between diagenetic states of siliceous sediment and chert are of a vastly smaller scale than has been noted between different depositional environments of marine sediment indicating that the paleoenvironmental ree signature is not obscured by diagenetic overprinting

aspects of atmospheric circulation the late pleistocene 0 950 000 yr record of eolian deposition in the pacific ocean rea d k 1990 aspects of atmospheric circulation the late pleistocene 0 950 000 yr record of eolian deposition in the pacific ocean palaeogeogr palaeoclimatol palaeoecok 78 217 227 the eolian component of pelagic sediments provides a proxy record of atmospheric circulation intensity and of dust transport examination of those records indicates that the atmosphere responds to orbital forcing but that during the past 875 000 years the variability in atmospheric circulation is at much shorter periods than the 100 000 year variation in ice volume the mid brunhes climatic event is well characterized in the eolian grain size records and in records of sea surface phenomena it is not seen in proxy indicators of either deep water or ice volume variability the increase in the amplitude of paleoclimatic variability that denotes the early late pleistocene transition occurs suddenly about 875 000 years ago in the eolian grain size record which is about 20 000 to 25 000 years earlier than the transition in the deep sea caco3 dissolution record or in the 8180 proxy record of ice volume

geochemistry of paleoproterozoic black shales from the intracontinental cuddapah basin india implications for provenance tectonic setting and weathering intensity abstract the cuddapah supergroup is one of the series of thick proterozoic sedimentary sequences developed on archean cratonic peninsular india the stratigraphically higher cumbum formation includes well preserved and unweathered black shales that include marine facies recording lower greenschist facies metamorphism in multielement normalized diagrams conservative elements ti al ree sc co plot parallel and close to post archean upper continental crust pa ucc small variations in absolute concentrations of conservative elements covary with fe2o3 content which ranges from 1 6 11 wt accordingly those concentrations are controlled by hydrothermal leaching or additions of fe consistent with reduced fluids reflected in variable eu anomalies in th sc vs sc co ordinates these shales trend to slightly lower sc but greater th sc than either pa ucc or average proterozoic shale cratonic lithologies such as tonalite clasts or detrital gold are not represented in basal conglomerates and ree systematics and low al2o3 yb th yb and zr sm ratios rule out a significant tonalite component in the source consequently both sedimentary and geochemical evidences endorse an extra cratonic provenance the best compositional fit is to average paleoproterozoic andean type continental margin granite with 10 of closepet type granite contributing to the excess zr and ree an active continental margin provenance is also consistent with the th sc zr discriminant diagram of siliciclastic sedimentary rocks the chemical index of alteration cia corrected for diagenetic addition of k is 85 100 indicative of intense weathering of the catchment compared to a range of mean values of 70 88 at 1 8 ga shales are variably enriched in v cr ni relative to pa ucc consistent with the established kerogen transition metal association the cuddapah supergroup may have evolved as a foreland basin to the 2 1 1 8 ga central indian tectonic zone with its associated granites evolving into an intracontinental basin connected to the ocean given the marine kerogen v ni association this scenario is similar to the paleoproterozoic mcarther river australia and athabasca canada basins which evolved from foreland basins respectively to the barrumundi and trans hudson orogens collectively as part of assembly of the proposed paleoproterozoic supercontinent columbia

nd sr isotope and rey geochemistry of metalliferous sediments in a low temperature off axis hydrothermal environment costa rica margin abstract metalliferous deposits are ubiquitous in marine sediments and play a major role in the elemental cycles of iron manganese and other trace elements the metalliferous sediments studied here were sampled near a basaltic seamount named dorado on the eastern flank of the east pacific rise west of nicoya peninsula costa rica based on heat flow data and porewater profiles this site is an area of active low temperature hydrothermal discharge most samples are from gravity core gc50 which is characterized by the presence of abundant authigenic minerals mainly fe mn oxyhydroxides and apatites our data suggest that these minerals have initially precipitated during the miocene from a high temperature hydrothermal plume when the dorado site was located near the east pacific rise with increasing distance from the ridge axis the plume precipitates were buried under hemipelagic sediments after the onset of the present day low temperature hydrothermal activity these precipitates were dissolved and re precipitated higher up in the sediment pile to form the observed assemblage of authigenic minerals the study thus shows that the metalliferous deposits of the dorado seamount have a very complex origin which could be unraveled by a combined approach based on nd sr isotopes rey data rare earth elements and yttrium and mineralogical observations

crystallinity and diagenesis of sedimentary apatites the crystallinity of sedimentary apatites was determined by fourier transform infrared spectroscopy ft ir using the splitting of a triply degenerate antisymmetric bending vibration of orthophosphate the crystallinity indices of recent marine apatites are low 3 0 3 6 while those of onland ancient apatites are high 4 5 7 8 indicating post depositional recrystallization the infrared spectra reveal that recrystallization is associated with a decrease in carbonate content substituting for po43 and an increase in fluoride order within the apatite structure the relationship between the crystallinity index and po43 18o suggests alteration of the primary isotopic composition by exchange reactions between po43 oxygens and surrounding waters the monterey samples have a large range of crystallinity index that reflects a set of complex and highly variable diagenetic conditions this demonstrates the use of ft ir criteria for differentiating between pristine and altered apatites and as a consequence for relating geochemical markers to formation or diagenetic environments it is suggested that only those samples that have low crystallinity indices c i 3 8 should be considered as pristine apatite spectra of fish remains indicate that differences in rare earth element ree patterns correspond to variations in crystallinity carbonate content and f order in the apatite lattice the fact that crystallinity is not correlated with geologic age suggests that environmental factors such as accumulation rate and pore water chemistry govern the recrystallization process in general sr content decreases and 18op exhibits high variability with increasing crystallinity

extracting the silicate mineral fraction from ancient carbonate assessing the geologic record of dust abstract the climatic influence of eolian dust particles 63 m is well recognized in the cenozoic earth system but less so for the pre cenozoic in ancient carbonate rocks that formed isolated from fluvio deltaic influx the silicate mineral fraction can in some cases represent atmospheric dust here we present a methodology for sequential extraction of carbonate organic matter pyrite and iron oxide from pre cenozoic carbonate strata to isolate the eolian fraction and illustrate the application to stratigraphic sequences from a late paleozoic carbonate buildup and ramp setting

dust production and deposition in asia and the north pacific ocean over the past 12 myr the silicate fractions of recent pelagic sediments in the central north pacific ocean are dominated by eolian dust derived from central asia an 11 myr sedimentary record at odp sites 885 886 at 44 7 n 168 3 w allows the evaluation of how such dust and its sources have changed in response to late cenozoic climate and tectonics the extracted eolian fraction contains variable amounts 70 of clay minerals with subordinate quartz and plagioclase uniform nd isotopic compositions nd 8 6 to 10 5 and sm nd ratios 0 170 0 192 for most of the 11 myr record demonstrate a well mixed provenance in the basins north of the tibetan plateau and the gobi desert that was a source of dust long before the oldest preserved asian loess formed nd values of up to 6 5 for samples 2 9 ma indicate 35 wt admixture of a young kamchatka like volcanic arc component the coherence of pb and nd in the erosional cycle allows us to constrain the pb isotopic composition of asian loess devoid of anthropogenic contamination to 206pb 204pb 18 97 0 06 207pb 204pb 15 67 0 02 208pb 204pb 39 19 0 11 87sr 86sr 0 711 0 721 and rb sr ratios 0 39 1 1 vary with dust mineralogy and provide an age indication of 250 ma 40ar 39ar ages of six dust samples are uniform around 200 ma and match the k ar ages of modern dust deposited on hawaii these data reflect the weighted age average of illite formation changes from illite smectite with significant kaolinite to illite and chlorite rich kaolinite free assemblages since the late pliocene document changes in the intensity of chemical weathering in the source region such weathering evidently did not disturb the k ar systematics and only induced scatter in the rb sr data we propose that when smectite forms at the expense of illite k and ar are quantitatively lost from what becomes smectite but are quantitatively retained in adjacent illite layers 40ar 39ar age data therefore are insensitive to smectite formation during chemical weathering but date the diagenetic growth of illite the major k bearing phase in the dust over the past 12 myr the dust flux to the north pacific increased by more than an order of magnitude documenting a substantial drying of central asia this climatic change however did not alter the ultimate source of the dust and neoformational products of chemical weathering always remained subordinate to assemblages reworked by mechanical erosion in dust deposited in eastern asia and the pacific ocean

geochemical implications of rare earth element patterns in hydrothermal fluids from mid ocean ridges abstract rare earth element data are reported for vent fluids collected from eight deep sea hydrothermal areas including samples from sediment hosted and bare rock hydrothermal systems the morb normalized ree patterns from these diverse settings are remarkably similar to each other but distinctly different than seawater or basalt being lree enriched and possessing a strikingly positive eu anomaly the ree concentrations making up these patterns vary widely however both on a spatial and temporal basis when plotted against ionic radii these fluid trends are remarkably linear and show the same fractionation patterns exhibited by plagioclase during magma segregation this analysis suggests that the partitioning of the ree between fluid and rock during high temperature hydrothermal alteration of morb is dominated by crystochemical exchange during dissolution and recrystallization reactions at the exposed surfaces of plagioclase phenocrysts a comparison of ree ionic radii in eight coordination indicate that the partitioning of 3ree and 2eu are dominated by chemical substitution for ca 2 and sr 2 respectively these considerations predict that the total 3ree content of vent fluid varies in a systematic way during the transition from an rich morb plagioclase to ab rich hydrothermal plagioclase and that these parameters can be used as indicators of the average extent of alteration inside active hydrothermal systems

multiple ash layers in late quaternary sediments from the central indian basin abstract we have investigated three sediment cores collected from water depths 5000 m along the transect 76 30 e in close proximity to a fracture zone in the central indian basin cib the cores yielded five volcanic horizons of which four have visual and dispersed shards rhyolitic glass shards of bubble wall platy angular and blocky types were retrieved from various stratigraphic horizons in the cores the abundance of glass shards composition of bulk sediments and 230thexcess ages of the host sediments were used to distinguish the volcanic horizons of the four volcanic horizons three are now newly reported and correspond to ages of 85 107 109 and 142 146 ka while the fourth horizon is of 70 75 ka by using trace element ratios and cr and nb based normative calculations cryptotephra has been identified for the first time from the cib sediment the cryptotephra forms the fifth ash horizon and is of 34 ka a comparison with the published data on volcanic tephra in and around the indian ocean indicate the shard rich horizon srh of 70 75 ka to resemble the younger toba tuffs ytt while the other volcanic horizons that were deposited during different time periods do not correlate with any known marine or terrestrial records these tephra layers have produced a tephrostratigraphic framework across the tectonically and volcanically complex regions of the cib due to the lack of terrestrial equivalents of these tephra it is hypothesized that the newly found volcanic horizons may have been derived from submarine volcanic eruptions multiple layers of submarine volcaniclastic deposits found at water depths as great as 5300 m reaffirm the growing belief that submarine phreatomagmatic eruptions are much more common in the intraplate region of the indian ocean than previously reported

mineralogical variation of sr nd isotopic and elemental compositions in loess and desert sand from the central loess plateau in china as a provenance tracer of wet and dry deposition in the northwestern pacific we determined sr and nd isotopic compositions and major trace and rare earth element ree compositions of evaporite and detrital minerals in loess and desert sand from the central loess plateau clp where 80 of the loess deposits in china are found the loess exhibited a narrow range of variation in 87sr 86sr 0 715 0 001 a sequential extraction experiment on the loess however showed that water and acetic acid hoac soluble minerals mainly halite and calcite hydrochloric acid hcl soluble minerals chlorite and phosphate and hcl insoluble minerals illite kaolinite smectite vermiculite feldspar and quartz have distinct 87sr 86sr ratios approximately 0 7111 0 0004 0 7141 0 0004 and 0 7195 0 0010 respectively the water and hoac soluble ratios were regionally uniform and were close to the 87sr 86sr value of river water from the huanghe yellow river and the maximum 87sr 86sr value of spring rainwater in japan suggesting selective solution of eolian halite and calcite into the chinese river water and into the japanese rainwater the mineralogical elemental and sr nd isotopic compositions of hcl soluble and insoluble minerals in the clp loess were different from those of the northern desert sand but were indistinguishable from those of its fine grained fraction supporting the view that the loess is composed of the fine grained fraction of desert sand that was transported to the southeast in the atmosphere the 87sr 86sr end and gd yb values of hcl insoluble minerals in the clp loess were almost identical to those of airborne dust soil minerals and deep sea sediments in the northwestern pacific considered to be of eolian origin suggesting dissolution of the loess evaporite minerals during atmospheric transportation these relationships demonstrate the usefulness of sr isotopes of water and hoac soluble minerals and sr and nd isotope ratios and ree compositions of acid insoluble minerals in loess as provenance markers for wet and dry deposition respectively

dynamics diffusion and geomorphological significance of tidal residual eddies many shallow tidal areas show the occurrence of ebb and flood surplusses organized in cell like structures or tidal residual eddies they seem to arise from a nonlinear transfer of vorticity from the oscillating tidal field to the mean field the irregular structure of the bottom topography or the coastline acting as a catalyst to produce the necessary vorticity gradients the dynamical characteristics of the eddies assist our understanding of the geomorphology of the sea bed

asian dust from land to sea processes history and effect from modern observation to geological records production transport and deposition of aeolian dust from land to sea closely interact with regional environment and global climate this special issue addresses transport of aeolian dust from the asian inland to the loess plateau and north pacific ocean and their possible links to oceanic ecosystem global climate and even human activity over various timescales the papers in this volume are multidisciplinary in nature and include sedimentology mineralogy geochemistry environmental magnetism and climate modelling on multi timescales from interannual glacial interglacial to tectonic timescales based on modern observation geological records and modelling this special issue offers new insights especially into aeolian provenance dynamics controls on dust production a novel marine aeolian proxy as well as long term aeolian input to the marginal basins of ne asia and its influence on oceanic productivity this issue provides a good example for future comprehensive studies of source to sink processes of asian dust from land to sea

quaternary fluctuations in the northern hemisphere trade winds and westerlies the mass accumulation rate and grain size of the total colian component isolated from pelagic sediment in two north pacific cores piston core kk75 02 under the prevailing westerlies and deep sea drilling project site 503 beneath the trade winds have been used to evaluate changes in the intensity of atmospheric circulation and source area aridity over the past 700 000 yr the eolian grain size a direct indicator of wind intensity fluctuates at periodicities similar to those calculated for the earth s orbital parameters of precession obliquity and eccentricity both sites display greater variability in wind intensity prior to 250 000 yr ago eolian accumulation rates an indicator of source area aridity fluctuate at periodicities similar to those of the glacial interglacial cycles lower eolian accumulation rates during colder glacial times most likely reflect increased glacial age humidity at central asian and central american source areas

local and regional geochemical signatures of surface sediments from the cariaco basin and orinoco delta venezuela we have analyzed the chemical compositions of 87 samples from the cariaco basin and 20 samples from the orinoco delta venezuela in order to better characterize the fluvial sources of material to the cariaco basin we observe distinctive regional patterns in composition shelf sediments found near the tuy river manzanares river the araya margarita region and in the northern portion of the unare platform record reproducible compositional differences however linear mixing models using only the composition from these rivers do not satisfy the variability observed in modern sediment trap samples collected from the basin average trap values are best approximated by mixing upper crust 30 50 with local river sources 50 70 of either the tuy unare or neveri rivers and eolian dust

provenance of the north pacific sediments and process of source material transport as derived from rb sr isotopic systematics abstract rb sr isotopic systematics of 111 samples of sediments in nine cores from the north pacific of quaternary and pliocene ages have been investigated they provide information on the provenance the process of particle transport and temporal variation in the flux of source material the rb sr isotopic systematics of the core sediments show well correlated pseudo isochrons the pseudo isochrons reflect the mixing of two types of material i e the asian continental material with high 87 rb 86 sr ratios 4 5 6 5 and high 87 sr 86 sr ratios 0 723 0 727 and the volcanic material with low 87 rb 86 sr ratios and low 87 sr 86 sr ratios from island arc volcanics such as the izu ogasawara mariana and the japanese islands and oceanic islands such as the hawaiian islands 0 0 2 0 0 703 0 708 the clearness of the pseudo isochrons implies that the rb sr isotopic composition of the weathering products derived from the asian continental crust is extremely homogenized the fine fraction a few m with a high 87 rb 86 sr ratio 5 0 6 5 is widely transported into the north pacific by the middle latitude westerlies and contributes largely to pelagic sediments the coarser fraction with a lower 87 rb 86 sr ratio

flushing of the deep pacific ocean and the deglacial rise of atmospheric co 2 concentrations during the last deglaciation 19 000 9 000 years ago atmospheric co2 increased by about 80 ppm understanding the mechanisms responsible for this change is a central theme of palaeoclimatology relevant for predicting future co2 transfers in a warming world deglacial co2 rise hypothetically tapped an accumulated deep pacific carbon reservoir but the processes remain elusive as they are underconstrained by existing tracers here we report high resolution authigenic neodymium isotope data in north pacific sediment cores and infer abyssal pacific overturning weaker than today during the last glacial maximum but intermittently stronger during steps of deglacial co2 rise radiocarbon evidence suggestive of relatively old deglacial deep pacific water is reinterpreted here as an increase in preformed 14c age of subsurface waters sourced near antarctica consistent with movement of aged carbon out of the deep ocean and release of co2 to the atmosphere during the abyssal flushing events the timing of neodymium isotope changes suggests that deglacial acceleration of pacific abyssal circulation tracked southern hemisphere warming sea ice retreat and increase of mean ocean temperature the inferred magnitude of circulation changes is consistent with deep pacific flushing as a significant and perhaps dominant control of the deglacial rise of atmospheric co2

lead nd and sr isotope records of pelagic dust source indication versus the effects of dust extraction procedures and authigenic mineral growth abstract eolian silicate dust of the 328 cm long piston core kodos 02 01 02 from the northeast equatorial pacific was analyzed for chemical compositions and nd sr and pb isotopic ratios to evaluate their use as hemispheric dust source discriminator and to examine the potential influence of authigenic smectite on these source signals neodymium and sr isotope ratios of the core determine a change from southern to northern hemisphere dust deposition at about 7 6 ma samples deposited between 15 5 and 7 6 ma resemble southeast equatorial pacific surface and down core dust values while younger samples correspond to signatures typical for dust derived from central asia the 15 5 to 7 6 ma lower interval of the core is smecite rich however previously proposed chemical fingerprints for authigenic smectite such as positive eu anomalies or high fe al ratios are not observed in the kodos samples the up to 40 smectite in the kodos core dust are thus interpreted to represent largely detrital smectite and no evidence is found for authigenic modification of nd sr isotopic or element ratio source signals of the dust records lead isotope results of the core lack prominent down core variation with changing source regimes as reported above a compilation of pacific pb isotope dust records reveals that pb isotope ratios vary as a function of silicate dust extraction procedures the step of removing biogenic silica thereby appears critical use of naoh appears most effective while minimally attacking eolian silicate material it is concluded that of the pb isotopic dust records published so far only a few are useful for dust source identification however once the silicate dust extraction procedure is further optimized for retrieving the pristine silicate dust pb isotopic composition specific source signatures should become well resolvable

the origin of clay minerals in active and relict hydrothermal deposits samples of fe oxide rich hydrothermal sediments were collected from active and inactive portions of the transatlantic geotraverse tag hydrothermal field on the mid atlantic ridge clays separated from tag metalliferous sediments in this study all consist of al poor nontronite oxygen isotope thermometry of the clays yields formation temperatures of 54 67 c for samples from the inactive alvin mound compared with 81 96 c for samples from the active tag site the latter are the highest recorded temperatures for authigenic hydrothermal clays sr isotope analysis of the clays from the active mound suggests that they precipitated from seawater dominated fluids containing less than 15 hydrothermal end member fluid in contrast nontronite from the inactive alvin mound has 87sr 86sr values that closely resemble that of detrital north atlantic clays suggesting a dominantly continental source for the sr rare earth element data are consistent with a significant detrital input to the inactive site but also demonstrate the extent of hydrothermal input to the low temperature fluid crystallographic fractionation of the trivalent ree is apparent in the heavy ree enrichments for all nontronite samples the inferred formation mechanism for nontronite rich fe oxyhydroxide deposits at the surface of the active mound is by direct precipitation from low temperature fluids at the inactive alvin site in contrast the deposits form during alteration of pelagic sediments by diffuse fluids and replacement of biogenic carbonate with nontronite and fe oxyhydroxide these two modes of formation are both important in seafloor hydrothermal settings where clay minerals are a significant component of the hydrothermal deposit

a direct link between the china loess and marine δ 18 o records aeolian flux to the north pacific most studies of quaternary climates conducted during the past 150 years have focused on glacial sequences and for the past 25 years marine sediments have provided significant further understanding of glacial and interglacial palaeoclimates an important goal of palaeoclimatology however to link the well known detailed continental records to marine records of similar resolution has yet to be realized the classic loess sequences of china provide an apparently continuous record of continental climate over the past 2 4 million years1 2 the oxygen isotope 18o timescale developed from the marine record3 gives us a global chrono stratigraphy of late pleistocene climates previously it has been suggested in studies of the aeolian component in pelagic sediments that it may be possible to link these two records directly by finding a suitable core from the north west pacific downwind from china4 5 here we report the results of such an effort for core v21 146 fig 1 and tie the last 500 000 years of the chinese loess soil sequence directly to the 18o timescale and in so doing refine the dating of regional loess and soil horizons

modern climate forcing of terrigenous deposition in the tropics cariaco basin venezuela one approach to deciphering tropical quaternary paleoclimate records has been to study the composition of terrigenous material in order to infer past changes in hydrologic and atmospheric conditions here we present the inorganic geochemistry major and trace elements of modern sediment traps and shelf sediments in the tropical cariaco basin venezuela in order to characterize seasonal variation in deposition of the terrigenous component and to document linkages within the ocean atmosphere climate system we show that variation in the chemistry of terrigenous input to the basin is a sensitive monitor of the annual meridional migration of the intertropical convergence zone itcz additionally seasonal terrigenous relative abundances are decoupled from terrigenous absolute fluxes showing that abundances are not directly related to terrigenous delivery changes in mixing between local fluvial sediments fluvial and or eolian mafic material and saharan dust explains the observed seasonality the modern seasonal variations are significantly smaller than those observed in the glacial interglacial paleorecord indicating that climate sensitivity at the two time scales is very different a striking contrast in the behavior of ti al between the longer glacial interglacial time scale and the modern seasonality also suggests that long term terrigenous deposition is not linked simply to 100kyr shifting of the itcz the modern data can be reconciled with the glacial interglacial record by invoking generally drier conditions during glacial periods over tropical latitudes combined with intermittent wet conditions caused by precessional forcing 2007 elsevier b v all rights reserved

late cenozoic changes in atmospheric circulation deduced from north pacific eolian sediments abstract isolation and analysis of the eolian component of late cenozoic pelagic sediments from the north pacific provides direct information concerning changes in atmospheric circulation a 50 increase in intensity of both the prevailing westerlies and the tradewinds coincides with increasing pole to equator temperature gradients resulting from the onset of northern hemisphere glaciation at the same time the mass flux of dust from continents to the north pacific increased by a factor of 4 5 apparently reflecting significantly increased continental aridity associated with the late cenozoic glacial ages

effects of the ground surface on polarimetric features of broadband radar scattering from subsurface metallic objects throughout the world the problem of buried unexploded ordnance uxo poses an enormous persistent and expensive problem while uxo generally consists of sizable bodies of ferrous metal and can therefore be detected with current technology it is extremely difficult to distinguish them reliably from typically widespread pieces of clutter thus the problem is one of subsurface discrimination the authors previous modeling work on scattering of ground penetrating radar gpr from metallic objects surrounded by an infinite soil like medium has suggested the utility of a number of key discriminants in broadband fully polarimetric sensing in particular resonance structure induced field rotation and ellipticity and bistatic observation of scattered signals were shown to offer key information about target shape and size the authors investigate the effects on signature features of the proximity of a ground surface to the target for the common case of shallow burial 1 m overall their analyses suggest that the key discriminants seen in scattering in an infinite medium survive the complex interactions with the ground surface in some instances these revealing signatures appear to be strengthened by the presence of a nearby surface multiposition backscatter also allows fundamental inferences about target elongation and symmetry when those cannot be obtained from single position viewing

the effect of diagenesis and fluid migration on rare earth element distribution in pore fluids of the northern cascadia accretionary margin analytical challenges in obtaining high quality measurements of rare earth elements rees from small pore fluid volumes have limited the application of rees as deep fluid geochemical tracers using a recently developed analytical technique we analyzed rees from pore fluids collected from sites u1325 and u1329 drilled on the northern cascadia margin during the integrated ocean drilling program iodp expedition 311 to investigate the ree behavior during diagenesis and their utility as tracers of deep fluid migration these sites were selected because they represent contrasting settings on an accretionary margin a ponded basin at the toe of the margin and the landward tofino basin near the shelf s edge ree concentrations of pore fluid in the methanogenic zone at sites u1325 and u1329 correlate positively with concentrations of dissolved organic carbon doc and alkalinity fractionations across the ree series are driven by preferential complexation of the heavy rees simultaneous enrichment of diagenetic indicators doc and alkalinity and of rees in particular the heavy elements ho to lu suggests that the heavy rees are released during particulate organic carbon poc degradation and are subsequently chelated by doc ree concentrations are greater at site u1325 a site where shorter residence times of poc in sulfate bearing redox zones may enhance ree burial efficiency within sulfidic and methanogenic sediment zones where ree release ensues cross plots of la concentrations versus cl li and sr delineate a distinct field for the deep fluids z 75 mbsf at site u1329 and indicate the presence of a fluid not observed at the other sites drilled on the cascadia margin changes in ree patterns the presence of a positive eu anomaly and other available geochemical data for this site suggest a complex hydrology and possible interaction with the igneous crescent terrane located east of the drilled transect

magnetostratigraphy of an early middle miocene loess soil sequence in the western loess plateau of china 1 stratigraphy and magnetic susceptibility of the quaternary eolian deposits at different sites in china can be closely correlated confirming their spatial coherence and temporal continuity the extent to which these conclusions are true for the miocene loess soil sequences remains to be addressed here a 231 9 m eolian section qa iii is geomagnetically dated yielding an age span of 21 4 11 4 ma with the portion older than 19 6 ma being partially water reworked the magnetozones litholigic structure and magnetic susceptibility of the sequence are highly correlative with the qa i and qa ii sections 30 km west of qa iii these sequences demonstrate that the miocene loess deposits are also spatially correlative in stratigraphy present a near continuous sequence of paleoenvironment changes and that magnetic susceptibility is a useful tool for stratigraphic correlation the basal age of qa iii confirms again the onset of asian inland deserts and monsoon dominate climates by the early miocene

geochemistry of eolian dust in pacific pelagic sediments implications for paleoclimatic interpretations geochemical data rees th sc were determined for the operationally defined eolian dust oded fraction 63 m of late quaternary sediment samples n 57 from the north and equatorial pacific ocean paleoclimate studies commonly have assumed that this sediment fraction represents eolian materials from continental source regions this study shows on the basis of geochemical data published mineralogical data and mixing models that the oded fraction actually is a mixture of materials from two endmember sources the continental crust eolian transported weathering products and the oceanic crust primarily volcanogenic material mixing model results show that the average ash content is significant in the oded fraction equatorial pacific 43 north pacific 24 we have used this information to reconsider and refine the results of previous paleoclimate studies in the northwest pacific the flux of the eolian fraction is greater during glacial stages and shows a latitudinal maximum between 35 n and 42 n eolian fluxes are greatest during interglacial periods in the equatorial pacific these results are consistent with previous interpretations in contrast to previous assumptions eolian mass accumulation rates may not be a valid indicator of paleo aridity because they are correlated with grain size furthermore the relative abundance of the two endmembers is correlated with the average grain size of the dust fraction the continental crust component is associated with larger grains this compositional effect should be considered in future studies which commonly utilize grain size as a proxy indicator of paleo wind intensity

cretaceous oceanic red beds corbs different time scales and models of origin abstract the cretaceous oceanic red bed corb is a newly opened window on global oceanic and climate changes during the cretaceous greenhouse world as a result of the international geoscience programmes 463 494 and 555 2002 2010 corbs have been documented in many places by numerous publications the principle goal of this paper is to summarize scientific advances on corbs including chronostratigraphy sedimentology mineralogy elemental and isotopic geochemistry and their relationship to oceanic anoxic events oaes palaeoclimate and palaeoceanography we propose a new geochemical classification of the corbs using cao al 2 o 3 and sio 2 values which lithologically refer to marly clayey and cherty corbs respectively detailed mineralogical studies indicate that hematite goethite and mn 2 bearing calcite are the minerals imparting the red color of corbs hematite clusters of several to tens of nanometers in the calcite structure are the main cause of the red coloring of limestones and the mn 2 bearing calcite gives additional red color goethite was thought to form originally with hematite and was subsequently transformed to hematite during late diagenesis chronostratigraphic data allow the distinction of two groups of corbs by their durations short term corbs are generally less than 1 myr in duration and seem to be on the scale of milankovitch cycles during the deposition of cretaceous reddish intervals from odp cores 1049 and 1050 low primary productivity and relatively high surface temperature resulted in low organic carbon flux into the sediments which reduced oxygen demand and produced oxidizing early diagenetic conditions in such an oxic environment iron oxides formed imparting the reddish color the long term corbs depositional events lasted longer than 4 myr and may be a possible consequence of the oaes enhanced amounts of organic carbon and pyrite burial during and after the oaes would have resulted in a large and abrupt fall in atmospheric co 2 concentration which probably induced significant global climatic cooling during and after the oaes global cooling would have enhanced formation of cold deep water increasing its oxidizing capacity due to the greater content of dissolved oxygen and would promote formation of oceanic red beds sedimentological mineralogical and geochemical data indicate that corbs were deposited under highly oxic oligotrophic conditions probably at a low sedimentation rate the cretaceous red and white limestones from italy have similar compositions of terrestrial input sensitive elements al ti k mg rb zr higher contents of fe 2 o 3 and depleted redox sensitive elements v cr ni and u and micronutrient elements cu zn indicating similar provenance sources but red limestones were deposited under more oxic conditions at the sediment water interface than white limestones the cretaceous red shales such as those from the north atlantic and tibet have similar mineralogy and geochemistry as the late cenozoic red clays in the pacific ocean and the environment where both are formed was well oxidizing at a very low sedimentation rate we compiled seventeen published stratigraphic examples of phanerozoic oceanic red beds including the late cenozoic red clays in the pacific different hypotheses explain the origin of red pigmentation of limestones and shales including 1 detrital origin of iron derived from continental weathering 2 iron bacterial mediation at the time of sedimentation and 3 iron oxidation in oligotrophic highly oxic environment additional research on phanerozoic oceanic red beds is needed in order to better document their origin and palaeoceanographic and palaeoclimatic significance

quantitative paleoenvironmental and paleoclimatic reconstruction using paleosols abstract paleosols fossil soils are preserved throughout the geologic record in depositional settings ranging from alluvial systems to between basalt flows until recently paleosols were studied using primarily qualitative methods in recent years paleopedology has shifted from a largely qualitative field based on comparisons with modern analogues to an increasingly quantitative endeavor some of this change has been a result of applying existing techniques to new materials but many of the innovations have been the result of applying new techniques to new materials including thermodynamic modeling of soil formation isotope geochemistry and applications of empirical relationships derived from modern soils a variety of semi quantitative and quantitative tools has been developed to examine past weathering and pedogenesis and to reconstruct both paleoenvironmental and paleoclimatic conditions at the time that the paleosols formed though it is often not possible to achieve the same temporal resolution as with marine records for paleoclimatic reconstructions proxies based on paleosols are potentially a much more direct means of making paleoclimatic reconstructions because soils form at the earth s surface in direct contact with the atmospheric and climatic conditions at the time of their formation paleoclimatic and environmental properties that may be reconstructed using the new proxies include provenance weathering intensity mean annual precipitation and temperature during pedogenesis nutrient fluxes into and out of the paleosols the atmospheric composition of important gases including co2 and o2 the moisture balance during pedogenesis the soil gas composition reconstructed vegetative covering and paleo altitude

piston core record of late paleogene 31 ma to recent seafloor hydrothermal activity in the southwest pacific basin a large diameter piston core containing 8 35 m of metalliferous sediment has been recovered from a small abyssal valley in the remote southwest pacific basin 31 42 194 s 143 30 331 w 5082 m water depth providing unique insight into hydrothermal activity and eolian sedimentation there since the early oligocene a combination of fish teeth sr isotope stratigraphy and inaa geochemical data reveals an exponentially decreasing hydrothermal flux 31 ma to the present although hydrothermal sedimentation related to seafloor spreading explains this trend a complex history of late eocene early oligocene ridge jumps propagating rifts and plate tectonic reorganization of south pacific seafloor could have also played a role a possible hiatus in deposition as recorded by changes in core composition just below 2 m depth is beyond the resolution of the fish teeth sr isotope dating method employed here however the timing of this interval may be coincident with extinction of the pacific farallon ridge at 20 ma a low flux eolian component accumulating at this site shows an increase relative to the hydrothermal component above 2 m depth consistent with dust generating continental sources far to the west australia new zealand this is the first long term paleoceanographic record obtained from within the south pacific bare zone rea et al 2006 an anomalous region where pacific seafloor has largely escaped sediment accumulation since the late cretaceous

late cenozoic eolian deposition in the north pacific asian drying tibetan uplift and cooling of the northern hemisphere a newly constructed record of eolian dust accumulation from the central north pacific shows that dust deposition increased by an order of magnitude quite rapidly at 3 6 ma we associate this sudden drying with the uplift of at least the northern portion of the tibetan plateau shutting off the indian ocean moisture source to central and western china this ten fold increase in atmospheric dust loading appears to be associated with the 1 m y long shift toward heavy 18o values that occurred at 3 6 2 6 ma the dust grain size record of wind intensity begins its late cenozoic coarsening a million years before the drying event at 4 5 ma the northern hemisphere cooling that results in intensification of the subpolar westerly winds may have as its ultimate cause the drawdown of atmospheric co2 in the latest miocene and the early pliocene closing of the panamanian seaway

mineralogy of aeolian dust reaching the north pacific ocean 2 relationship of mineral assemblages to atmospheric transport patterns atmospheric dust particles actually comprise a small number of mineral assemblages we determined the composition of these assemblages and their geographic distribution by statistical analysis of mineralogy data air mass trajectory analysis was used to identify transport paths and possible source regions for these samples three types of trajectories are most common and each displays different proportions of four mineral assemblages the first indicates outflow of air from central asia and is associated with an illite rich mineralogy the second type comprises trajectories which include low altitude transport over the japanese islands for mixed mineralogies which contained a small amount of the illite rich end member the third type is made up of trajectories crossing the north american continent and is present exclusively in the eastern north pacific area there is a mixed mineralogy associated with these trajectories our results suggest that both source area mineralogy and transport pathway contribute to the compositional variability of the mineral aerosol at a given location the results presented here show that event specific meteorological data can be useful in understanding spatial patterns of eolian transport

the application of neodymium isotope as a chronostratigraphic tool in north pacific sediments it has been suggested that dust generation was closely linked to the development of global ice sheets and or cooling this feature has allowed asian dust to be a potential chronostratigraphic tool in north pacific ocean npo sediments the orbital scale age control in npo sediments is usually established by adjusting the benthic foraminiferal 18o to the global 18o stack lr04 however it would become difficult if the sediments did not contain enough foraminifera this study investigates sr and nd isotopes trace elements mineralogy and grain size of the operationally defined aeolian dust oded extracted from the sediments recovered at ocean drilling program odp site 1209b on the shatsky rise in the npo covering the past five glacial interglacial cycles the geochemical results show that the oded at site 1209b is actually a mixture of asian dust and volcanic ash the variation of nd isotope mimics the cycles of glacial interglacial ice sheets as revealed by the global benthic foraminifera s oxygen isotope stack lr04 over the past 500 ka the low high nd values corresponded with the cool warm periods we propose that nd variation reflects the evolving aeolian dust in site 1209 sediments the excellent agreement between nd values at site 1209b and lr04 stack over the past 500 ka allows establishing the orbital timescale age control by tuning nd to the lr04 curve we thus propose that nd isotope provides a chronostratigraphic technique in npo sediments especially for sediments with a limited amount of foraminifera

the use of foraminifera as a record of the past neodymium isotope composition of seawater 1 we present new isotopic data for sedimentary planktonic foraminifera as well as for potential water column and sedimentary sources of neodymium nd which confirm that the isotopic composition of the foraminifera is the same as surface seawater and very different from deep water and sedimentary nd the faithfulness with which sedimentary foraminifera record the isotopic signature of surface seawater nd is difficult to explain given their variable and high nd ca ratios ratios that are often sedimentary foraminifera ratios that are often much higher than is plausible for direct incorporation within the calcite structure we present further data that demonstrate a similarly large range in nd ca ratios in plankton tow foraminifera a range that may be controlled by redox conditions in the water column cleaning experiments reveal in common with earlier work that large amounts of nd are released by cleaning with both hydrazine and diethylene triamine penta acetic acid but that the nd released at each step is of surface origin while further detailed studies are required to verify the exact location of the surface isotopic signature and the key controls on foraminiferal nd isotope systematics these new data place the use of planktonic foraminifera as recorders of surface water nd isotope ratios and thus of variations in the past supply of nd to the oceans from the continents via weathering and erosion on a reasonably sure footing

provenance of dust in the pacific ocean eolian dust preserved in deep sea sediment cores provides a valuable indicator of past atmospheric circulation and continental paleoclimate in order to identify the provenance of eolian dust nd and sr isotopic compositions and rb sr and rare earth element ree concentrations have been determined for the silicate fractions of deep sea sediments from the north and central pacific ocean different regions of the pacific ocean are characterized by distinct air borne inputs producing a large range in end 10 to 1 stsr 86sr 0 705 0 721 la yb 5 15 eun eu 0 6 1 0 and sr nd 4 33 the average nd isotopic composition of pacific deep sea sediments eno 6 is more radiogenic than the average from the atlantic ena 8 in contrast the average 1475m 14and ratio for pacific sediments 0 114 is identical to that of atlantic sediments and to that of global average riverine suspended material the values of ena and 147sm 144nd are positively correlated for the pacific samples but negatively correlated for atlantic samples reflecting a fundamental difference between the dominant components in the end members with radiogenic nd island arc components in the pacific and lree enriched intraplate ocean island components in the atlantic samples from the north central pacific have distinctive unradiogenic end values of 10 87sr 86sr 0 715 high la yb 12 and low eun eu 0 6 and sr nd 3 6 these data are virtually identical to the values for loess from asia and endorse the use of these sediments as indicators of asian paleoclimate and paleowind directions island arc contributions appear to dominate in the northwest pacific resulting in higher end 1 to 1 and lower 87sr 86sr 0 705 and la yb 5 sediments from the eastern pacific tend to have intermediate sr and nd isotopic compositions but regionally variable sr nd and ree patterns they appear to be derived from the west margin of the north and south american continents rather than from asia our results confirm that dust provenance can be constrained by isotopic and geochemical analyses which will facilitate reconstructions of past atmospheric circulation and continental paleoclimate

distribution of biogenic silica and quartz in recent deep sea sediments all available quartz and biogenic silica concentrations from deep sea surface sediments were intercalibrated plotted and contoured on a calcium carbonate free basis the maps show highest concentrations of biogenic silica opal along the west african coast along equatorial divergences in all oceans and at the polar front in the southern indian ocean these are all areas where upwelling is strong and there is high biological productivity quartz in pelagic sediments deposited far from land is generally eolian in origin its distribution reflects dominant wind systems in the pacific but in much of the atlantic and indian oceans the distribution pattern is strongly modified by turbidite deposition and bottom current processes

sedimentary indicators of atmospheric activity in the northern hemisphere during the cenozoic abstract the concentrations and accumulation rates of eolian phases and the mineralogy of sediments from a north pacific core ll44 gpc3 have been used to evaluate changes in eolian sedimentation and atmospheric activity during the cenozoic the quartz content and clay mineralogy of the sediments reflect changing source areas for eolian material whereas the accumulation rates of eolian phases reflect climatic variation and wind intensity eolian sedimentation decreased from 70 to 50 m y ago at the site as it moved north out of the equatorial pacific where it was supplied with eolian debris from north america and africa low rates of eolian sediment accumulation 50 to 25 m y ago reflect the temperate humid environment of the early tertiary and the lack of vigorous atmospheric circulation at that time from 25 to 7 m y ago eolian accumulation increased as the site moved into the influence of the westerlies from 7 to 3 m y ago there was a more rapid increase in accumulation of eolian material at the site which was not accompanied by changes in mineralogy or quartz content and was therefore related to climatic change and more vigorous atmospheric circulation about 2 5 m y ago a dramatic increase in eolian sedimentation accompanied the onset of dry northern hemisphere glaciation

neodymium isotopic variations in north pacific modern silicate sediment and the insignificance of detrital ree contributions to seawater the neodymium isotopic composition of the silicate fraction of holocene pelagic sediments from the north pacific define two provinces a central north pacific province characterized by unradiogenic and remarkably homogeneous end 10 2 0 5 and a narrow circum pacific marginal province characterized by more radiogenic and variable end 4 2 3 8 the silicate fraction in the central north pacific is exclusively eolian based on prevailing wind patterns meteorological data and neodymium isotopic data the only significant sediment source is chinese loess leaching experiments on chinese loess confirm that leachable nd is isotopically indistinguishable from bulk and residual silicate nd silicates in the circum north pacific marginal province comprise eolian loess volcanic ash and hemipelagic sediments derived from volcanic arcs a compilation of pacific seawater and mn nodule end data shows no clear spatial variation except for a general decrease from surface to deep waters from 3 to 4 and slightly lower end in bottom waters along the western north pacific due to the incursion of antarctic bottom water the relative homogeneity of bottom water end which contrasts sharply with the distinctive variation in sediment end plus the large difference between the average end of bottom waters and the central north pacific eolian silicates 4 vs 10 suggests that any contribution of ree to seawater from eolian materials is insignificant furthermore leaching of ree from eolian particles as they sink though the water column must be insignificant because nd in shallow waters is more radiogenic than nd in deeper waters that there is no contrast in the nd isotopic composition of bottom waters that overlie the central and marginal sediment provinces suggests that the ash and hemipelagic sediments derived from pacific rim volcanic arcs also contribute minimal ree to seawater the elimination of eolian ash and hemipelagic sediments leaves only near shore riverine particulates as a possibly significant particulate source of ree to seawater

mineralogical and geochemical compositions of the eolian dust from the northeast equatorial pacific and their implications on paleolocation of the intertropical convergence zone 1 eolian components of a 328 cm long piston core collected from the northeast equatorial pacific at 16 12 n and 125 59 w were investigated for mineral and geochemical compositions in order to constrain the sources of dust and determine the latitudinal position of the intertropical convergence zone itcz recorded in the core the eolian components below 250 cm are characterized by smectite and phillipsite rich mineral composition depleted rare earth elements rees and high eu sm ratios indicative of volcanic rich composition these characteristics are found in equatorial and south pacific surface sediments of which eolian particles are supplied from central and south america in contrast eolian components above 250 cm are characterized by quartz and illite rich mineralogy and more shale like ree and trace element compositions which are common in surface sediments of the central pacific north of the itcz where eolian particles are sourced from the asia and north america the observed changes are attributed to the shifting of its eolian sources from the central and south america to the china and north america across the hemispheric dust barrier of the itcz this result suggests that smectite illite transition a phenomenon that smectite amount increases over illite at a depth can be used as a tracking tool for the paleolocation of the itcz in the northeast and central pacific backtrack path construction of pacific plate indicates paleolocation of the itcz north of 12 n 2 prior to late miocene

rare earth elements in old biogenic apatites abstract the ree distributions in individual upper devonian conodonts have been measured by ion probe the patterns of all analyzed conodonts are enriched in middle ree eu gd and have a weak or no ce anomaly concentrations and la yb or la sm ratios vary very little within or among individuals from the same zone which suggests that uptake of labile ree from sediments was essentially quantitative therefore the ree signature of the primary carriers probably organic and oxyhydroxides particulates from marine suspensions was efficiently transferred to biogenic apatites and survived late diagenetic processes ree patterns of conodonts do not resemble those of present day seawater and post cretaceous biogenic phosphates which are typically depleted in nd and sm with a negative ce anomaly since ree distributions in the modern water column mimic those of nutrients we assume that in pre cretaceous seawater they were not controlled by surface biological activity we assume instead that ree in pre cretaceous seawater can be explained by mechanism of desorption adsorption on particle surfaces progressive extraction of lree from river water by oxyhydroxides leads to precipitates enriched in middle ree a simple quantitative model was calculated in order to illustrate the proposed mechanism

elemental mobility in phosphatic shales during concretion growth and implications for provenance analysis shale normalized rare earth element ree patterns record variable redox conditions in coprolitic phosphorite concretions and their host shales from the pennsylvanian age cyclothems in the u s midwestern states of oklahoma kansas nebraska iowa and ohio as well as the mississippian age fayetteville shale of arkansas shale normalized enrichments in middle ree mree developed as the phosphatic concretions lithified under reducing conditions in pore waters of organic rich muds depletions in mree sm ho in host shales correspond to the mree enrichments in some nearby concretions rare and weak negative cerium depletions in both reworked and unreworked phosphorite concretions suggest exposure to oxygenated waters positive europium anomalies in thick phosphorite coatings on coprolitic phosphorite concretion cores suggest extreme reduction during lithification of the phosphorite coating flat ree patterns in both host shales and phosphorite concretions probably reflect detrital influence phosphate diagenesis can affect the trace element chemistry of black shale enough to alter provenance signals overall enrichment in ree in phosphorite relative to host shale suggests movement of ree as does the mree enriched phosphorite near the mree depleted host shale diagenetically mobile ree can affect la th sc relationships used in provenance analysis the extent of the diagenetic modification of la th sc distribution is related to the amount of p2o5 present typical la th sc distribution in host shale results when p2o5 values are below 0 5 high la abundance substantially skews la th sc distribution when p2o5 is above 5 0 but when p2o5 is between 0 5 and 5 0 the extent of the effect is unclear oxides of aluminum and other major elements may be useful in recording detrital influence and proximity to the shoreline in phosphorite concretions most of the concretions nearest to shoreline sources of detrital input have both flat ree patterns and elevated values of al2o3 al2o3 fe2o3

cenozoic mass accumulation rates in the equatorial pacific based on high resolution mineralogy of ocean drilling program leg 199 1 we use continuous mineralogy logs derived from multisensor track physical properties data and reflectance spectroscopy to calculate high resolution carbonate opal and terrigenous mass accumulation rates mar for the eight sites cored during ocean drilling program leg 199 in the equatorial pacific the largest change in equatorial pacific sedimentation patterns of the last 55 myr occurs at the greenhouse icehouse transition shortly after the eocene oligocene boundary calcite compensation depth deepened dramatically the equatorial zone of opal accumulation narrowed and the intertropical convergence zone shifted to the equator during the paleogene the opal equatorial accumulation bulge extended to about 12 n whereas the neogene bulge extended only to about 7 n very low eocene carbonate mar was followed by much higher oligocene and early miocene mar with the carbonate equatorial bulge extending to 4 n terrigenous mars indicate the paleoposition of the intertropical convergence zone and a pliocene pleistocene increase in asian dust flux

mineralogy of aeolian dust reaching the north pacific ocean 1 sampling and analysis the mineral composition of the 2 m clay and 2 to 20 m silt size fractions of aerosol particles collected near the margins of the north pacific ocean was determined by x ray diffraction analysis although the same mineral phases are present in the two size fractions there are significant differences in the quartz plagioclase and kaolinite concentrations north pacific aerosols are primarily composed of illite in both size fractions in addition to kaolinite in the 2 m size class and quartz and plagioclase in the 2 to 20 m size class quartz and plagioclase are present in significantly higher amounts in the 2 to 20 m size fraction while kaolinite is greater in the 2 size class western north pacific aerosol particles contain significantly higher 2 m quartz than samples collected in the east and eastern north pacific aerosols have significantly higher concentrations of 2 m smectite than those from the west

ichthyolith strontium isotope stratigraphy of a neogene red clay sequence calibrating eolian dust accumulation rates in the central north pacific abstract cenozoic pelagic red clays of predominantly eolian and hydrogenous origin blanket much of the central north pacific ocean basin the eolian component is a key indicator of past paleoclimatic conditions thus cenozoic atmospheric circulation can potentially be reconstructed through provenance studies of pacific red clays provided there are precise age controls methods commonly employed in the past to date red clay cores have included cobalt accumulation rates ichthyolith biostratigraphy magnetostratigraphy and ichthyolith strontium isotope stratigraphy the first two dating methods yield ages with large uncertainties while magnetostratigraphy is only relevant to cores with accumulation rates in excess of 1 mm kyr ichthyolith strontium isotope stratigraphy has shown promise as a chronological tool in marine studies but has been only sparingly employed in the dating of marine red clay sequences in this study we present a complete age depth profile for a large diameter piston core from the central north pacific ocean ew9709 pc 01 32 5 n 141 2 w consisting of 11 m of primarily wind deposited dust to generate this age depth profile strontium isotopic compositions were determined on fish teeth ichthyoliths previously cleaned of contaminants using a newly modified reductive cleaning procedure ages were determined by reference to the recently refined sr isotope curve for neogene seawater comparison with nearby giant piston core ll44 gpc3 reinforces the accuracy of our methods the data for ew9709 pc 01 indicate a fairly constant sediment accumulation rate of 0 45 mm kyr over most of the 24 myr time period represented by this core

geochemistry of the xining xifeng and jixian sections loess plateau of china eolian dust provenance and paleosol evolution during the last 140 ka abstract loess and paleosol samples from three distant sections xining xifeng jixian of the chinese loess plateau were analyzed for chemical and nd sr isotopic compositions in order to obtain information about the paleoclimatic variation during the last 140 ka these three sections represent three different climatic conditions from arid in the west xining to more humid in the east jixian across the loess plateau isotopic analyses show that all the three sections display a restricted range of 143 nd 144 nd ratios or e nd 10 0 5 indicating the dominance of relatively young and uniform upper crustal sources for the eolian dust the loess and paleosol samples have typical upper crustal 87 sr 86 sr ratios 0 714 0 718 and their variation can partly be attributed to different carbonate silicate ratios in the samples ree data from the three sections are indistinguishable from each other they show typical upper crust patterns characterized by la yb n 10 and eu eu 0 65 the high degree of chemical and isotopic homogeneity suggests that the dust source region must have undergone multiple recycling and thorough sedimentary mixing processes various chemical indicators have been used to monitor the pedogenetic intensity in these sections although results for the jixian section agree reasonably well with the known climatic conditions on the loess plateau the other two sections yield results not in agreement with some well accepted proxies like magnetic susceptibility or grain size distribution some chemical proxy indicators established in our previous work on the luochuan section such as the systematic u depletion and negative ce anomalies in ree patterns in soils are not clearly recorded in the present case the discrepancy between different climatic proxies could be related to the effective soil water budget temperature as well as the rate of development of each proxy

eolian inputs of lead to the north pacific we evaluate the importance of natural eolian pb to the dissolved oceanic pb budget by measuring the isotopic composition of pb in 35 holocene and late quaternary sediment samples from the north pacific and in 10 samples of chinese loess when the pacific is divided into sediments provinces based on published end and sedimentological data pb from the central north pacific tends to be the most radiogenic and homogeneous due to the dominance of eolian chinese loess lead from the marginal north pacific and the sparsely sampled regions south of 5 n are less radiogenic and more variable owing to hemipelagic inputs from various volcanic arcs and older continental crust located around the pacific rim 208pb 204pb ratios provide the most distinctive provenance information due to the relatively high ratios in chinese loess the chinese loess samples come from 3 localities and span up to 2 myr of time acetic acid leachate bulk loess and loess silicate fractions were analyzed separately leachate pb is considerably less radiogenic than silicate pb the isotopic composition of the silicate component closely matches the sediment data from the central north pacific confirming the dominance of eolian loess in this region we divided up a suite of published hydrogenous pb isotope data from the pacific ocean according to their locations within the three independently defined sediment provinces these data define three distinct fields differentiated primarily by their 206pb 204pb ratios which increase going from the central to southern to marginal provinces this relationship with sediment province strongly suggests that natural eolian and probably hemipelagic inputs significantly impact the seawater pb budget direct support for the dominance of eolian chinese loess in the central north pacific dissolved pb budget comes from the close match between loess leachate pb and the central province hydrogenous pb data eolian inputs are likely to dominate local seawater pb budgets only where eolian pb fluxes are high relative to hemipelagic pb fluxes and where the flux of pb carried by deep water advection is low

asian aridity and the zonal westerlies late pleistocene and holocene record of eolian deposition in the northwest pacific ocean rea d k and leinen m 1988 asian aridity and the zonal westerlies late pleistocene and holocene record of eolian deposition in the northwest pacific ocean palaeogeogr palaeoclimatol palaeoecol 66 1 8 a 30 000 year record of eolian deposition in the northwestern pacific ocean provides a history of the aridity of the asian source region and information on the changing latitude and intensity of the zonal westerlies the position of the maximum in eolian flux to the deep sea remained unchanged at 38 to 40 n during this entire time period but the dust flux record of aridity is greatest 6000 years ago at the holocene climatic optimum eolian grainsize data indicate that the northern margin of the westerly jet stream retreated northward during the holocene to a poleward extreme at about 6000 years ago and then moved back toward the equator the change in wind intensity across this margin was continually reduced throughout the holocene these sorts of data enhance our understanding of the behavior of the atmosphere during times of climate change and can be used to test computer generated models of past climatic conditions

metalliferous sediments from the h m s challenger voyage 1872 1876 abstract the legendary cruise of h m s challenger 1872 1876 around the globe must always occupy an eminent place in the annals of oceanography as being the first systematic attempt made on a global scale to explore the ocean this expedition made fundamental discoveries in biology and geology which have not been surpassed by any later scientific cruise sediment with high content of metals later called metalliferous was among the enigmatic findings taken onboard although the nature of metalliferous sediments is well known today the very first sampled sediments of this type have not been studied to date motivated by the historical value of challenger s metalliferous sediment collection we undertook an investigation addressing two questions 1 the composition of sediments from seafloor for which we have very limited data 2 sr nd pb fe zn isotope signature of these sediments collected before the substantial human impact on the ocean during the 20th century the se pacific metalliferous sediments sampled by the challenger s explorers are of 2 types 1 metalliferous oozes blanketing ridge crests and flanks down to the calcite compensation depth ccd and 2 stripped of caco 3 metalliferous sediments located beneath the ccd in the deeps near the mid ocean ridges the abiogenic part of these sediments is composed mainly of poorly crystalline to x ray amorphous fe mn oxyhydroxides and an amorphous silicate phase these sediments have geochemical features similar to those of all the other metalliferous sediments very high fe and mn content on abiogenic basis very low al al fe mn and high content on abiogenic basis of as ba be bi cd co cu mo ni pb sb th tl u v w y zn and zr their ree distribution patterns are similar to that of deep seawater and show weak signs of hydrothermal imprint weak positive or no eu anomaly seawater and or terrigenous input from south america control the sr nd pb isotope signature of the challenger metalliferous sediments and have almost completely obliterated any original morb derived hydrothermal signal zn isotopes are mainly contributed from seawater although other zn sources hydrothermal fluid and detrital aluminosilicates barite and volcanic glass are necessary to fully explain zn isotope ratios fe isotopes indicate relatively slow fe 2 to fe 3 oxidation in the non buoyant plume thus producing relatively lighter fe isotope signature of the feooh particles that formed the studied metalliferous sediments

onset of asian desertification by 22 myr ago inferred from loess deposits in china the initial desertification in the asian interior is thought to be one of the most prominent climate changes in the northern hemisphere during the cenozoic era1 2 3 4 but the dating of this transition is uncertain partly because desert sediments are usually scattered discontinuous and difficult to date here we report nearly continuous aeolian deposits covering the interval from 22 to 6 2 million years ago on the basis of palaeomagnetic measurements and fossil evidence a total of 231 visually definable aeolian layers occur as brownish loesses interbedded with reddish soils this new evidence indicates that large source areas of aeolian dust and energetic winter monsoon winds to transport the material must have existed in the interior of asia by the early miocene epoch at least 14 million years earlier than previously thought3 5 regional tectonic changes and ongoing global cooling are probable causes of these changes in aridity and circulation in asia

geochemical evidence for african dust and volcanic ash inputs to terra rossa soils on carbonate reef terraces northern jamaica west indies abstract the origin of red or reddish brown clay rich terra rossa soils on limestone has been debated for decades a traditional qualitative explanation for their formation has been the accumulation of insoluble residues as the limestone is progressively dissolved over time however this mode of formation often requires unrealistic or impossible amounts of carbonate dissolution therefore where this mechanism is not viable and where local fluvial or colluvial inputs can be ruled out an external source or sources must be involved in soil formation on the north coast of the caribbean island of jamaica we studied a sequence of terra rossa soils developed on emergent limestones thought to be of quaternary age the soils become progressively thicker redder more fe and al rich and si poor with elevation furthermore although kaolinite is found in all the soils the highest and oldest soils also contain boehmite major and trace element geochemistry shows that the host limestones and local igneous rocks are not likely source materials for the soils other trace elements including the rare earth elements ree show that tephra from central american volcanoes is not a likely source either however trace element geochemistry shows that airborne dust from africa plus tephra from the lesser antilles island arc are possible source materials for the clay rich soils a third as yet unidentified source may also contribute to the soils we hypothesize that older more chemically mature jamaican bauxites may have had a similar origin the results add to the growing body of evidence of the importance of multiple parent materials including far traveled dust to soil genesis

radiogenic hf isotopic compositions of continental eolian dust from asia its variability and its implications for seawater hf the inorganic silicate fraction extracted from bulk pelagic sediments from the north pacific ocean is eolian dust it monitors the composition of continental crust exposed to erosion in asia 176lu 177hf ratios of modern dust are sub chondritic between 0 011 and 0 016 but slightly elevated with respect to immature sediments modern dust samples display a large range in hf isotopic composition ic 4 70 hf 16 45 which encompasses that observed for the time series of dsdp cores 885 886 and piston core ll44 gpc3 extending back to the late cretaceous hafnium and neodymium isotopic results are consistent with a dominantly binary mixture of dust contributed from island arc volcanic material and dust from central asia the hf nd isotopic correlation for all modern dust samples hf 0 78 nd 5 66 n 22 r2 0 79 is flatter than those reported so far for terrestrial reservoirs moreover the variability in hf of asian dust exceeds that predicted on the basis of corresponding nd values 4 7 hf 2 5 10 9 nd 10 1 this is attributed to 1 the fixing of an important unradiogenic fraction of hf in zircons balanced by radiogenic hf that is mobile in the erosional cycle 2 the elevated lu hf ratio in chemical sediments which given time results in a hf signature that is radiogenic compared with hf expected from its corresponding nd isotopic components and 3 the possibility that diagenetic resetting of marine sediments may incorporate a significant radiogenic hf component into diagenetically grown minerals such as illite together these processes may explain the variability and more radiogenic character of hf isotopes when compared to the nd isotopic signatures of asian dust the hf nd isotope time series of eolian dust are consistent with the results of modern dust except two samples that have extremely radiogenic hf for their nd hf 8 6 and 10 3 nd 9 5 and 9 8 these data may point to a source contribution of dust unresolved by nd and pb isotopes the hf ic of eolian dust input to the oceans may be more variable and more radiogenic than previously anticipated the hf signature of pacific seawater however has varied little over the past 20 myr especially across the drastic increase of eolian dust flux from asia around 3 5 ma therefore continental contributions to seawater hf appear to be riverine rather than eolian current predictions regarding the relative proportions of source components to seawater hf must account for the presence of a variable and radiogenic continental component data on the ic and flux of river dissolved hf to the oceans are urgently required to better estimate contributions to seawater hf this then would permit the use of hf isotopes as a monitor of past changes in erosion

resolving eolian volcanogenic and authigenic components in pelagic sediment from the pacific ocean abstract we measured major and trace element concentrations in the operationally defined chemically extracted residual aluminosilicate component of sediment from ocean drilling program sites 1215 and 1256 in the central and eastern equatorial pacific ocean and found that this residual component contains volcanogenic and authigenic aluminosilicates in addition to inferred eolian material while the residual component younger than 20 ma from the central pacific odp site 1215 is similar compositionally to upper continental crust and suggests an increase in the delivery of asian dust material since 20 ma the residual in sediment older than 20 ma indicates significant amounts of volcanogenic and authigenic materials volcanogenic debris comprises as much as 40 of the residual between 23 40 ma which coincides with the mid tertiary ignimbrite flare up that occurred in much of western north america the residual component extracted from the 50 ma biogenic sediment reflects authigenic signatures seawater like negative cerium anomalies and elevated fe si ratios the previously interpreted increase in an andesitic detrital source in north pacific locations may instead be authigenic material presenting significant challenges for many paleoclimate proxies additionally in the eastern pacific odp site 1256 the residual component contains 70 of volcanogenic material most likely originating from central america and also includes refractory barite the ability to separately identify eolian volcanogenic and authigenic materials in the aluminosilicate component of pelagic sediment allows resolution respectively of the climatic geologic and chemical processes contributing to the paleoceanographic archive in this critical oceanic region

sources of fe to the equatorial pacific ocean from the holocene to miocene abstract biological productivity in the modern equatorial pacific ocean a region with high nutrients and low chlorophyll is currently limited by the micronutrient fe in order to test whether fe was limiting in the past and to identify potential pathways of fe delivery that could drive fe fertilization i e dust delivery from eolian inputs vs fe supplied by the equatorial undercurrent we chemically isolated the terrigenous material from sediment along a cross equatorial transect in the central equatorial pacific at 140 w and at ocean drilling program site 850 in the eastern equatorial pacific we quantified the contribution from each potential fe bearing terrigenous source using a suite of chemical and isotopic discrimination strategies as well as multivariate statistical techniques we find that the distribution of the terrigenous sources i e asian loess south american ash papua new guinea and ocean island basalt varies through time latitude and climate regardless of which method is used to determine accumulation rate there also is no relationship between flux of any particular fe source and climate moreover there is no connection between a particular fe source or pathway eolian vs undercurrent to total productivity during the last glacial maximum pleistocene glacial episodes and the miocene biogenic bloom this would suggest an alternative process such as an interoceanic reorganization of nutrient inventories may be responsible for past changes in total export in the open ocean rather than simply fe supply from dust and or equatorial undercurrent processes additionally perhaps a change in fe source or flux is related to a change in a particular component of the total productivity e g the production of organic matter calcium carbonate or biogenic opal

grain size distribution and depositional processes of the mineral component of abyssal sediments lessons from the north pacific grain size analyses of the mineral component of abyssal pacific surface sediments show two distinctly different size distributions that can be associated with sediments that are dominantly eolian and dominantly hemipelagic respectively in the range of 1 to 30 m eolian grains show a distinct size mode at about 2 m 9 and little material coarser than about 16 m 6 hemipelagic grains are characterized by a much flatter size distribution that has a broad size mode near 2 m 9 and important amounts of material coarser than 16 m 6 this ability to distinguish between hemipelagic and eolian grains will obviate some long standing concerns in the interpretation of deep sea sediments examples of the utility of this technique are given for the north pacific and south atlantic

late pleistocene paleoclimatology of the central equatorial pacific a quantitative record of eolian and carbonate deposition detailed records of vso 6i3c percentage and mass accumulation rate of caco and eolian percentage mass accumulation rate and grainsize generated for core rcl l 210 from the equatorial pacific reveal the timing of paleoclimatic events over the past 950 000 yr the caco percentage record shows the standard pacific correlation of high caco content with glacial periods but displays a marked change of character about 490 000 yr ago with older stages showing much less variability the carbonate mass flux record however does not show such a noticeable change sedimentation rates vary from about 0 5 to 3 0 cm l000 yr and during the past 490 000 yr sections with enhanced sedimentation rates correspond to periods of high caco percentage eolian mass accumulation rates an indication of the aridity of the source region are usually higher during glacial times eolian grainsize an indication of the intensity of atmospheric circulation generally fluctuates at a higher frequency than the loo ooo yr glacial cycle the mid brunhes climatic event centered at 300 000 yr ago appears as a 50 000 yr interval of low intensity and reduced variability of atmospheric circulation furthermore the nature of this entire record changes then with the younger portion indicating less variation in wind intensity than the older part of the record the late matuyama increase in amplitude of paleoclimatic signals begins 875 000 yr ago in the eolian record 25 000 yr before the 6i80 and caco percentage amplitude increases about

the maastrichtian record from shatsky rise northwest pacific a tropical perspective on global ecological and oceanographic changes we present new isotopic and micropaleontological data from a depth transect on shatsky rise that record the response of the tropical pacific to global biotic and oceanographic shifts during the mid maastrichtian results reveal a coupling between the upper ocean characterized by a weak thermocline and low to intermediate productivity and intermediate waters during the earliest maastrichtian oxygen and neodymium isotope data suggest a significant contribution of relatively warm intermediate water from the north pacific isotopic shifts through the early maastrichtian suggest that this warmer water mass was gradually replaced by cooler waters originating in the southern ocean although the cooler water mass remained dominant through the remainder of the maastrichtian it was displaced intermittently at shallow intermediate depths by north pacific intermediate water the globally recognized mid maastrichtian event similar to 69 ma manifested by the brief appearance of abundant inoceramid bivalves over shallow portions of shatsky rise is characterized by an abrupt increase similar to 2degrees 3degrees c in sea surface temperatures a greater flux of organic matter out of the surface ocean and warmer similar to 4degrees c intermediate waters results implicate simultaneous changes in surface waters and the sources distribution patterns of intermediate water masses as an underlying cause for widespread biotic and oceanographic changes during mid maastrichtian time

glacial to interglacial fluctuations in productivity in the equatorial pacific as indicated by marine barite an empirical correlation between marine barite baso4 accumulation rate in core top sediment samples from two equatorial pacific transects at 140 w and 110 w and the estimated primary productivity of the overlying water column were used to evaluate glacial to interglacial changes in productivity fluctuations in barite accumulation rates down core indicate that during glacial periods of the past 450 000 years the productivity in the central and eastern equatorial pacific was about two times that during intervening interglacial periods this result is consistent with other evidence that productivity was high in the eastern and central equatorial pacific during the last glacial

thorium derived dust fluxes to the tropical pacific ocean 58 ma abstract eolian dust in pelagic deep sea sediments can be used to reconstruct ancient wind patterns and paleoenvironmental response to climate change traditional methods to determine dust accumulation involve isolating the non dissolvable aluminosilicate minerals from deep sea sediments through a series of chemical leaches but cannot differentiate between minerals from eolian authigenic and volcanogenic sources other geochemical proxies such as sedimentary 232th and crustal 4he content have been used to construct high resolution records of atmospheric dust fluxes to the deep sea during the quaternary here we use sedimentary th content as a proxy for terrigenous material eolian dust in 58 myr old sediments from the shatsky rise odp site 1209 and compare our results with previous dust estimates generated using the traditional chemical extraction method and sedimentary 4hecrustal concentrations we find excellent agreement between th based dust estimates and those generated using the traditional method in addition our results show a correlation between sedimentary th and 4hecrustal content which suggests a source older than present day asian loess supplied dust to the central subtropical pacific ocean during the early paleogene