87sr86sr in late proterozoic carbonates evidence for a mantle event at 900 ma ago abstract strontium isotopic measurements were made on late proterozoic carbonates from west african craton comparison of samples with acceptable trace element patterns with coeval data from southern africa and with the published australian results suggests that the 87 sr 86 sr ratio of the late proterozoic sea water evolved in the following manner about 0 7075 at 1000 50 ma 0 7056 to 0 7074 at 900 50 ma 0 7068 to 0 7091 0 7106 at 800 50 ma 0 7074 to 0 7077 at 700 50 ma and 0 7076 to 0 7089 0 7096 at 600 50 ma ago the variations are comparable in magnitude and frequency to those described previously for the phanerozoic strontium isotopic values in the radiogenic part of this range suggest that the continental river flux of sr into late proterozoic oceans was of comparable isotopic composition to its present day counterpart 0 711 consequently the non radiogenic 87 sr 86 sr value at 900 50 ma ago signifies a large flux of mantle strontium into the ocean at this time because the present time resolution is only about 75 25ma additional sampling as well as better stratigraphie resolution and more definite selection criteria are required for construction of a more detailed late proterozoic sea water curve

sm nd isotopic dating of proterozoic clay material an example from the francevillian sedimentary series gabon clay fractions of 0 4 m and 0 2 m and acid leachates of these clay fractions were separated from two different kerogen rich black shale samples from the francevillian sedimentary series in gabon they yielded identical sm nd isochron ages of2099 115 ma and2036 79 ma with initial nd values of 6 5 2 0 and 9 3 1 5 respectively these ages define multi episode illitization during early diagenesis as suggested by the differentsm nd ratios of the clay fractions the sm nd isotope data of the kerogen source rock up to 13 organic carbon plot between the two isochrons but close to the clay fractions suggesting that this organic matter reached nd isotopic equilibrium with respect to the clay minerals and the diagenetic fluids analyses of fracture filling bitumen showed that it had very elevated143nd 144nd and147sm 144nd ratios these values are higher than the most elevated values of the leachates but plot on the extension of the two isochrons this indicates that the bitumen reached nd isotopic equilibrium with the kerogen source rock from which it was expelled and the authigenic clay minerals secondary migration and chemical evolution of the bitumen appear to have caused the fractionation between sm and nd with an attendant increase in thesm nd ratio the results suggest that the sm nd isotope method has potential for both dating diagenetically related illitization using leachate residue pairs of small size clay fractions and reconstructing geochemical processes during diagenesis in oil producing sedimentary basins

geochronology of the porgera gold deposit papua new guinea resolving the effects of excess argon on k ar and age estimates for magmatism and mineralization abstract mesothermal epithermal gold mineralization at porgera in the highlands of papua new guinea png occurs in structurally controlled veins and disseminations which overprint and cross cut a suite of shallow level comagmatic mafic alkaline stocks and dykes the porgera intrusive complex pic and their sedimentary host rocks conventional k ar apparent ages of twelve hornblende separates from eight different intrusions scatter between 7 and 14 ma but four biotite separates are concordant at 6 02 0 29 ma 2 40 ar 39 ar step heating experiments on six of the hornblende separates reveal saddleshaped age spectra which indicate the presence of excess 40ar one of these samples yields a well defined plateau with an apparent age of 5 96 0 25 ma 2 this age is identical to that of the biotites and suggests an age of 6 0 0 3 ma 2 for emplacement of the pic older apparent ages obtained from conventional k ar and 40 ar 39 ar analyses are explained by excess 40ar contamination conventional k ar analyses of six separates of hydrothermal illite and roscoelite associated with gold mineralization yield apparent ages of between 5 1 and 6 1 ma and indicate that ore deposition occurred within 1 ma of magmatism at porgera evidence for the evolution of a magmatic volatile phase and the presence of excess 40ar both in the intrusives and in hydrothermal fluids associated with the orebody suggest that magmatic fluids may have had some involvement in metallogenesis but the exact nature of this involvement is not yet clear late miocene magmatism and mineralization at porgera are thought to have occurred shortly prior to or during the initiation of continent arc collision and to pre date associated pliocene uplift and foreland deformation in the highlands

oceanic molybdenum drawdown by epeiric sea expansion in the mesoproterozoic abstract molybdenum is a bioessential micronutrient whose abundance in the global oceans may have played a primary role in evolution of the earth s nitrogen cycle and ultimately in the timing of the ecologic expansion of early eukaryotes because molybdenum mo is delivered to the ocean under conditions of oxic weathering and is removed in suboxic and euxinic environments the concentration of mo in the oceans reflects a complex function of global redox and the hydrologic conditions that influence the areal extent of euxinic sedimentation recent compilations of mo within euxinic shales scott et al 2008 och and shields zhou 2012 sahoo et al 2012 indicate that the oceanic reservoir of mo did not rise substantially above crustal values until the great oxidation event 2 3 ga and a modern mo cycle did not develop until the contraction of ocean euxinia in the latest proterozoic at present a paucity of data from euxinic shales of the late mesoproterozoic 1 3 to 1 0 ga limits our ability to relate marine redox evolution to biological innovation during a critical interval of eukaryotic development here we present data from marine shales of the 1 1 ga atar and el mreiti groups mauritania which were deposited during sea level highstand when shallow epeiric seas covered much of the west african craton epicratonic strata of the el mreiti group were deposited under fluctuating redox conditions near a shallow chemocline as evidenced by iron speciation and record generally low mo concentrations

reliability of k ar dating of clays and silicifications associated with vein mineralizations in western europe k ar ages were determined on fine fractions and one massive silicification associated with vein mineralizations in uranium barium fluorine and related base metals in western europe the reliability of the potassic materials analysed once the mineralogical and geochemical relationships to the low temperature mineralization have been established is demonstrated the isotopic ages are concentrated between nearly 190 and 170 ma this epoch corresponds to that of the rifting of the future atlantic and tethys oceans this type of low temperature mineralization thus seems to be better explained by extensional phenomena

regional magnetic overprinting of witwatersrand supergroup sediments south africa shales from the late archean witwatersrand supergroup of south africa yield stable wellgrouped remanent magnetizations after thermal and alternating field demagnetization virtual geomagnetic poles from 17 sites located throughout the central and western parts of the basin indicate that rocks of the basin were remagnetized after folding a paleomagnetic fold test shows that the fisherian precision parameter k decreases from 22 to 3 after restoring the beds to paleohorizontal illite crystallinity indices show that the remagnetized samples were subjected to at least middle greenschist facies temperatures whereas magnetic blocking temperature estimates indicate upper greenschist facies temperatures a k ar age obtained from clays of 1945 40 ma 2 is assigned to this metamorphic event the new paleomagnetic pole obtained from the witwatersrand basin sites 19 n 46 e k 22 a95 8 is consistent with other 1950 2050 ma poles from southern africa confirming independently the k ar age the distinctive overprint direction seen in shale specimens may be useful as a directional marker for orienting deep bore cores

petrogenesis of the proterozoic athabasca basin northern saskatchewan canada and its relation to diagenesis hydrothermal uranium mineralization and paleohydrogeology abstract in the athabasca basin proterozoic sandstones unconformably overlie archean and aphebian rocks multiple fluid events involving isotopically and chemically distinct fluids which have migrated laterally for considerable distances and along fault zones have produced a paragenetically identifiable assemblage of clay silicate and oxide minerals in the basin and basement rocks altered sandstones and the underlying metasedimentary rocks proximal to fault zones host high grade u ni co unconformity type uranium ore deposits and contain an alteration assemblage of highly crystalline 2m 3t illite 1m kaolinite clinochlore and sudoite hematite dravite and euhedral quartz in the sandstones 18o values of coeval quartz hematite quartz illite quartz dravite illite hematite and kaolinite hematite fluid inclusion temperatures in diagenetic quartz and d values of 1m kaolinite 2m 3t illite dravite and in fluid inclusions in the quartz indicate formation from a basinal fluid that had d values of 60 10 and which underwent salinity temperature and 18o increases from 5 to 34 wt nacl 120 to 240 c and 5 to 3 respectively as a result of increasing burial depth and sustained water rock interactions with the basinal sediments over substantial time periods 18 o 16 o and d h ratios of sudoite and clinochlore in meta sedimentary basement rocks within the alteration haloes indicate formation from a basement derived fluid with 18o and d values of 4 4 and 30 10 respectively that was isotopically distinct from the basinal fluids 18o and d values of late kaolinites in reactivated fault zones indicate formation mainly from low temperature 50 25 c fluids having 18o and d values of 16 and 130 respectively similar to relatively modern meteoric waters in the area some kaolinites have 18o and d values which suggest they formed from meteoric waters at mid latitudes and have experienced varying degrees of oxygen and hydrogen isotope exchange with relatively modern meteoric waters in the re activated faults illite sudoite and dravite have d values that vary by 100 without concurrent changes to their 18o values indicating preferential hydrogen isotope exchange with relatively modern meteoric waters at low temperatures and under conditions of high integrated water rock ratios rb sr isochron and model ages of 1477 57 and 952 ma respectively for the crystalline 2m 3t illites indicate the timing of the high temperature basinal fluid events associated with fluid mixing rb sr and k ar ages on illites with the lowest d values are as young as 300 ma and indicate late stage resetting of their radiogenic isotope systematics as a result of substantial interactions with relatively modern meteoric waters the evolution of sr isotopic compositions of fluids in the basin and basement rocks as reflected by the 87 sr 86 sr ratios of chlorite illite and dravite indicates that mixing of two isotopically distinct fluids in the vicinity of faults was the process by which uranium was precipitated similar to that suggested by oxygen and hydrogen isotope systematics in the clays and silicate minerals nd ratios in the high temperature diagenetic and hydrothermal clay and silicate minerals and the cogenetic uranium ores suggest they all have formed from similar fluids which have interacted substantially with the basin sediments in general the isotopic chemical microthermometric and petrologic data indicate that the athabasca basin has had a protracted fluid history comparable to that documented for more modern sedimentary basins the data clearly show that the major sandstone aquifers have been affected by widespread lateral flow of diagenetic fluids over distances of hundreds of kilometers and also that these fluid migration paths have been modified by cross formational fluid flow near active fault zones

carbon isotope records in a mesoproterozoic epicratonic sea carbon cycling in a low oxygen world abstract carbon isotope profiles of sedimentary strata are widely used as both a tool for stratigraphic correlation and as a mechanism for inferring important changes in earth s biogeochemical cycles chemostratigraphic interpretations however often rely on the assumption that the isotopic composition of dissolved inorganic carbon dic in the surface oceans is broadly homogeneous at times of globally high sea level when epicratonic epeiric environments dominate our sedimentary record carbon isotope records reveal substantial lateral variability here we investigate lateral variability in the marine carbon isotope record from pericratonic to epicratonic environments of the mesoproterozoic 1 1 ga atar el mreiti groups of the taoudeni basin west africa restricted marine epicratonic environments are consistently 2 4 lighter than open marine pericratonic environments suggesting input of an isotopically light carbon source that preferentially affected epicratonic environments in contrast to epicratonic environments in the paleozoic where input of isotopically light carbon is generally attributed to input of terrestrial organic matter we suggest that in situ remineralization of organic carbon via anaerobic microbial cycling drove observed isotopic variability within epicratonic el mreiti group strata the extent of organic matter remineralization and thus degree of 13 c depletion is correlated with water depth and associated with distinct differences in both total organic carbon toc and pyrite concentration suggesting a potential linkage to both the persistence of anoxia and the availability of sulfate within epicratonic environments in such settings the isotopic effects of organic carbon remineralization are potentially enhanced by either methane oxidation following methanogenic decomposition or the intermittent oxidation of an enhanced dissolved organic carbon doc pool

water rock interactions in fault gouge measurements were made of the amounts of d 18o and h2o in fault gouge collected over a depth of 400 m in the san andreas fault of california the amounts and isotopic compositions of the pore fluids also analyzed suggest that formation waters from adjacent franciscan rocks have migrated into the gouge and mixed with local meteoric water thus the gouge is an open system permeable to fluid flow this permeability has important implications concerning heat flow along the fault zone

age and origin of albian glauconites and associated clay minerals inferred from a detailed geochemical analysis abstract glauconitic grains are abundant in sandstones and siltstones from albian and cenomanian transition between lower and upper cretaceous formations of southeastern france morphological and crystal chemical data show that the green grains can be considered as glauconite s s with minute amounts of pyrite dolomite calcite and other clay minerals as grain coatings or crack fillings glauconite grains formed early during sedimentation generally from detrital chlorite biotite or clay particles and were found scattered together with other detrital mineral phases muscovite quartz in the silt in which porosity was considerably reduced afterwards by four stages of carbonate calcite dolomite cementation geochemical data especially the fe u and ce contents of the glauconitic grains strongly suggest increasing oxidizing conditions with time in the sedimentation environment the detailed geochemical analyses also allow the pristine glauconite grains to be distinguished from the other clay minerals occurring in the sequence this enabled k ar and rb sr dating of the glauconitic material which yields identical results of 97 9 0 4 and 97 9 3 5 ma respectively these dates point to a synsedimentary origin for the glauconites during the late albian about 97 98 ma the k ar data also indicate that the albian cenomanian boundary should be placed at 96 0 1 9 ma the similarity between the k ar and rb sr ages precludes any further significant pervasive recrystallization of these minerals during burial of the sequence either by heat flux or fluid flow the k ar study of the clay matrix from the same siltstones suggests synsedimentary precipitation of additional clay minerals probably together with the glauconite grains such as mixed layer illite smectite identified in the clay size fraction of the sedimentary succession

pbpe systematics on diagenetic clays an example from proterozoic black shales of the franceville basin gabon this study presents the first dating attempt of diagenetic clay material by the pb cpb isotope method pb pb isotopic measurements were performed on authigenic 0 4 m clay fractions illite 1m fe mg chlorite extracted from black shales highly enriched in organic matter of the francevillian lower proterozoic sedimentary series in gabon the clay residues and acid leachates 1 n hcl yield a pb pb isochron age of 2328 130 ma mswd 1 24 even if this age is within error limits identical with two sm nd isochron ages previously reported for the same material it is not considered as a true isochron age the pb isotopic data of the residues indicate that the clay minerals are not in isotopic equilibrium however the isotope data of the leachates separately define an isochron age of 2265 150 ma mswd 0 36 which is closer to the sm nd age it is suggested that the leachates are the most appropriate phases for dating diagenetic processes with pb isotopes the u th pb fractionation in the clay fractions is related to the occurrence of organic matter in the sediments the upb and uth ratios of the clays correlate with their organic carbon contents this fractionation is probably due to differential complexation of u th and pb by organic ligands during the dissolution of detrital mineral phases and clay mineral authigenesis

rb sr and k ar dating of precambrian clays and glauconies abstract isotopic dating of sedimentary material requires a different approach from the isotopic dating of plutonic volcanic and high grade metamorphic rocks the present contribution presents mineralogical criteria such as clay composition illite or glauconite crystallinity indices illite or glauconite polymorphic types sedimentological criteria such as mechanisms of genesis as well as chemical criteria such as the sr composition and content of the carbonates associated with the studied clays and glauconies these criteria help in the interpretation of the numerical results and should always be considered in attempts to obtain radiometric ages of sedimentary clays and or glauconies it is emphasized that a difference between measured and expected age seldom means that the chronometer used is inaccurate but it commonly means that a parameter was not recognized or even disregarded a critical review of the uncertainties typically related to sedimentary dating is also proposed they may be grouped into four types 1 genetic uncertainties dependent on the genetic mechanisms of the studied minerals 2 historic uncertainties dependent on the alteration events imprinted in the sediments since deposition weathering diagenesis and or tectono metamorphism 3 stratigraphic uncertainties dependent on the precision of the sample location in the sedimentary sequence and 4 analytic uncertainties dependent on the representativeness and the preparation of the samples as well as the accuracy of the measurements a reliability test of the rb sr and k ar methods as applied to dispersed precambrian clays and glauconies is discussed from an extensively studied sequence from west africa it shows that the k ar system of these minerals is much more sensitive to later modifications than the rb sr system therefore the two techniques may be complementary in geochronological studies of precambrian sediments

the recommended cambrian ordovician global boundary stratotype of the xiaoyangqiao section dayangcha jilin province china this paper provides a brief outline of the current detailed inter disciplinary work on the xiaoyangquiao section trying to expose all the aspects for reference tied to the global single stratigraphic point gssp concept for defining the cambrian ordovician boundary the 45 m critical interval of this section outcrops very well along the steep bank of a stream and is free from folding faulting intrusions and has not been affected by weathering colour alternation of conodonts and acritarchs and crystallinity indices of illite all indicate a maximum thermal grade of 100 c the lithofacies being of great lateral persistence for a hundred kilometres consists mainly of a rhythmical sequence of lime mudstone and shales deposited in a moderately deep outer shelf environment of quiet water well below the normal storm wave base chemical investigation of the rocks demonstrates strong positive correlation between a12o3 content and those of k2o mgo fe2o3 tio2 be cr co ni zn and ba indicating these components are tied to the clay fractions a stable depositional environment is demonstrated by the uniform chemistries through the boundary interval close to the boundary itself p2o5 contents are low indicating continuous sedimentation at fairly substantial rates the major biological events the biostratigraphic framework and the stratigraphic range of conodont graptolite trilobite and acritarch taxa are illustrated briefly with diagrams following the majority views of the calgary plenary session the boundary level is to be chosen at a point marked by the first appearance datum fad of the selected conodont taxon or taxa in the vicinity of the level close to but below the first influx of nematophorous graptolites the following four points marked by the incoming of conodont taxon or taxa are recommended for consideration of the golden spike 1 fad of cordylodus intermedius at 5 28 m below the first influx of nematophorous graptolites 2 fad of hirsutodontus simpler cordylodus drucei albiconus postcostatus at 5 23 m 3 fad of semiacontiodus lavadamensis utahconus utahensis monocostodus sevierensis at 3 85 m 4 fad of cordylodus lindstromi at 2 23 m for the following reasons the fad of h simplex c drucei a postcostatus is favoured 1 the taxa are all distinct and widely dispersed 2 intensive evolutionary change took place in conodonts graptolites trilobites and acritarchs prior to or after this point all the fossil groups occur together providing correlation with many regions throughout the world 3 the point is in a position between the previously widely accepted boundary levels based on graptolites and trilobites 4 the proposed point lies within a thin laterally persistent rhythmical sequence the fad of cordylodus lindstromi is also a favourable point sharing many advantages mentioned above but this point is less satisfactory in being defined by the fad of a single taxon c lindstromi which also has an extremely small population size an isochron age of 500 7 7 4 ma is determined from clay fractions of mudstones 8 5 m below the proposed point by means of the rubidium strontium method the nd signature determined from conodonts trilobites hyolithids and acrotretid brachiopods has a mean value of 6 7 comparable with that of the coeval oceanic water mass occupying southeastern north america and europe and indicating that northeastern china bordered the same ocean the mean tdm model age determined was 1 26 ga at the time of sedimentation compatible with the mean tdm model age of approximately 1 1 ga for the pacific ocean today the relatively low value of the tdm model age indicates a substantial input from young orogenic volcanic island arcs and terranes

k ar dating of episodic mesozoic fluid migrations along the fault system of gernsbach between the moldanubian and saxothuringian northern black forest germany along the sw ne trending fault zone of gernsbach northern black forest over a distance of about 45 km between baden baden and pforzheim basal series of the sedimentary cover are extensively altered by hydrothermal solutions the fluids were conveyed in the fault zone and because of favourable permeabilities they spread out along the unconformity between the basement and sedimentary cover k ar dates on authigenic white micas illites and hydrothermally altered detrital micas point to the occurrence of two major episodes of fluid migration the extensive alteration along the entire fault system occurred about 150 ma ago during the jurassic in relation to these hydrothermal activities the epigenetic strata bound uranium deposit of mullenbach originated in upper carboniferous sediments near the fault and the fluorite quartz vein type mineralization of kafersteige was formed along the fault about 100 ma ago during the cretaceous the results indicate various geological processes of the fault system of gernsbach which is located between the saxothuringian and moldanubian zone the mobilization of the fluids and the formation of the ore deposits were probably caused by and connected with tectonic activities in mid europe

depth varying seismogenesis on an oceanic detachment fault at 13 20 n on the mid atlantic ridge abstract extension at slow and intermediate spreading mid ocean ridges is commonly accommodated through slip on long lived faults called oceanic detachments these curved convex upward faults consist of a steeply dipping section thought to be rooted in the lower crust or upper mantle which rotates to progressively shallower dip angles at shallower depths the commonly observed result is a domed sub horizontal oceanic core complex at the seabed although it is accepted that detachment faults can accumulate kilometre scale offsets over millions of years the mechanism of slip and their capacity to sustain the shear stresses necessary to produce large earthquakes remains subject to debate here we present a comprehensive seismological study of an active oceanic detachment fault system on the mid atlantic ridge near 13 20 n combining the results from a local ocean bottom seismograph deployment with waveform inversion of a series of larger teleseismically observed earthquakes the unique coincidence of these two datasets provides a comprehensive definition of rupture on the fault from the uppermost mantle to the seabed our results demonstrate that although slip on the deep steeply dipping portion of detachment faults is accommodated by failure in numerous microearthquakes the shallow gently dipping section of the fault within the upper few kilometres is relatively strong and is capable of producing large magnitude earthquakes this result brings into question the current paradigm that the shallow sections of oceanic detachment faults are dominated by low friction mineralogies and therefore slip aseismically but is consistent with observations from continental detachment faults slip on the shallow portion of active detachment faults at relatively low angles may therefore account for many more large magnitude earthquakes at mid ocean ridges than previously thought and suggests that the lithospheric strength at slow spreading mid ocean ridges may be concentrated at shallow depths

the control of lava flow during the 1991 1992 eruption of mt etna abstract all the actions carried out in 1992 to protect the village of zafferana etnea from being invaded by lava are described an earthen barrier 234 m long and 21 m high was firstly built in january 1992 by accumulating with mechanical escavators 370 000 m 3 of earth scoriae and stones this embankment contained the lava for about one month and was overflowed by april 9 1992 three additional smaller earthen barriers lenght 90 160 m height 6 12 m were built in april to gain time while the lava front was descending towards zafferana from the overflowed first embankment the major effort of the 1992 operation consisted of several attempts at stopping the lava front advance by diverting the flow out from the natural and extensively tunnelled channel through a skylight near the vent the main intervention point was located in valle del bove at an elevation of 2000 m at 8 km from zafferana in a zone almost unaccessible from land helicopters were hence extensively used during the whole operation initial interventions called for attempts at plugging a tunnel by dumping into it linked concrete blocks hedgehogs and blasted portions of the solid levee each intervention caused the partial obstruction of the tunnelled channel which determined major increases of lava overflow in valle del bove and the consequent halt of the most advanced fronts however benefits were of brief duration at the most two weeks of respite before new lava fronts approached again and again the outskirts of zafferana the final successful intervention was carried out on may 27 29 an artificial channel was dug departing from the natural one the solid separation levee was thinned to 3 m and blasted by 7000 kg of explosives after the explosion 2 3 of the lava flowed spontaneously in the artificial channel and then the total diversion was obtained the tunnel being plugged by dumping into the natural flow 230 m 3 of lava boulders as a consequence of the intervention the active natural lava front that on may 27 was only 850 m from zafferana came to an halt as did the entire flow downhill from the diversion point bringing back the situation as it was five months earlier a few days after the beginning of the eruption with the new front of the diverted flow at 6 7 km from zafferana in june 1992 the effusion rate halved from 30 to 15 m 3 s and with this reduced thrust the lava was no longer capable of covering long distances five months after the conclusive intervention the diverted lava continues to flow over its initial natural field but remaining confined in the upper valle del bove without any new threat to zafferana

the relationship between kar ages and grain size in middle and upper proterozoic shales from the yanshan area north china abstract eight shale samples from the middle and upper proterozoic succession of the yanshan area of north china were dated using the k ar method each sample was divided into four grades of different grain size 2 2 1 1 0 4 and on the basis of the results the eight samples were classified into two models in model 1 the potassium content and the age values show a regular change with different grain sizes the age of the finest grains may represent the age of sedimentation and the age of coarser grains shows the influence of an isotopic system inherited from the terrigenous source in model 2 the ages yielded by materials of any grain size are always younger than that considered reasonable for these strata and show the influence of a re set isotopic system the relationships among the three isotopic systems here called inherited contemporaneous and re set are discussed in an attempt to explain their geological meaning

problems in applying preservation facies and sequence models to sinian neoproterozoic glacial sequences in australia and asia abstract the sinian 800 530 ma is an extraordinary period of earth history characterized by the transition from simple to complex multicellular organisms and by extreme variations in climate eustasy and possibly tectonics understanding sinian stratigraphy may help interpret the co evolution of life and environment during the period though sinian successions are poorly dated and difficult to correlate preservation facies and sequence models based on mesozoic recent successions may be used to interpret them preservation models based on basin subsidence permit estimates of how thick and complete successions can be in different tectonic settings and how long it took for them to be deposited facies models for rift craton shelf slope and basin environments help in identification of these different tectonic settings sequence models facilitate interpretation of the interplay of tectonic subsidence eustasy rates of sedimentation and climate such models applied to the sinian successions of australia and asia indicate the following great shallowing upwards megacycles occur in sinian successions and each ends with regional glaciations deep rift basins formed around 850 800 ma preserve the oldest megacycles but these basins soon were filled with rapidly deposited glaciogenic sediments relatively complete sequences are found only in deep basins subject to repeated rifting cratons and shallow shelves preserve only the youngest megacycles older deposits have been removed by younger glacial advances deep shelves and slopes preserve one to three megacycles depending on the timing of the start of passive margin subsidence megasequences can be correlated based on limited radiometric dating and inferred regional distribution of unique rock types but these sequences are not developed to the same extent in all blocks problems in correlating the four great megacycles recognized elsewhere with those of asia will persist until the requisite facies analysis and u pb dating of interbedded volcanics are done

pb pb dating of young marbles from taiwan direct determination of the depositional age of a sedimentary sequence usually relies on isotopic analyses of authigenic minerals such as glauconite1 and fine grained clay minerals2 4 moorbath et al 5 recently reported the first direct dating of sedimentary carbonates using the whole rock pb pb method the success of this method depends on the chemical fractionation of u from pb and the consequent variation in 206pb 204pb and 207pb 204pb ratios the high values and large variation of u pb ratios in sedimentary carbonates long known to marine geochemists have however not been exploited by geochronologists until recently5 6 here i report a pb pb isochron age for a relatively young carbonate sequence in taiwan and demonstrate that the long lived u pb decay scheme can be used to determine events as young as mesozoic age the new results also lead to the identification of an early jurassic 170 myr bp thermal event which has never before been recognized in the polymetamorphic schist belt the tananao schist of taiwan but is widespread in southeastern continental china and other parts of eastern asia7 10

chemostratigraphy of the late mesoproterozoic atar group taoudeni basin mauritania muted isotopic variability facies correlation and global isotopic trends a b s t r a c t sedimentary strata of the atar el mreiti groups taoudeni basin mauritania are characterized by car bon isotope values that fall largely between 2 5 and 4 0 and contain stratigraphic trends that are strikingly similar to those recorded worldwide in strata with depositional ages from 1 2 ga to 1 1 ga chemostratigraphic results are consistent with recent re os dates of 1 1 ga for atar el mreiti group strata rooney et al 2010 and support an emerging dataset that identifies the late mesoproterozoic as an isotopically distinctive interval in earth history the relatively low amplitude carbon isotope variabil ity limits the use of chemostratigraphy in detailed correlation during this time interval in this study we combine chemostratigraphic data with key chronostratigraphic horizons and detailed analysis of deposi tional facies to construct a rigorous and testable model for the intrabasinal correlation of atar and el mreiti group strata data support a depositional model that results in broadly uniform stratigraphic thicknesses across the west african craton with predominantly stromatolitic facies of the atar group mauritania and the hank and dar cheikh groups algeria representing deposition on shallow water craton margins and clayey carbonate and shale facies of the el mreiti group mauritania representing deposition on a broad shallow water epicratonic platform within this stratigraphic framework regional differences in carbon isotope composition are interpreted to reflect spatial differences in water chemistry likely asso ciated with local carbon cycle dynamics in cratonic environments that have limited exchange with the open ocean similarly distinct differences in trace element composition recorded in multilayered marine cements within deeper water stromatolitic reef facies are interpreted to reflect vertical differences in water chemistry associated with redox gradients in the water column we use this multifaceted approach to test a recent hypothesis that suggests correlation of atar el mreiti group strata with glaciogenic strata of the vazante group sao francisco craton critically preservation of shallow water carbonate and evaporite strata across more than 1200 km of the predominantly epicra tonic taoudeni basin with minimal evidence for high amplitude sea level change is consistent with inferences of late mesoproterozoic highstand conditions in a global greenhouse climate such charac teristics are inconsistent with suggestions of a time equivalency with glaciogenic strata of the vazante group sao francisco craton despite broad similarities in re os geochronology and carbon isotope com position together these results emphasize both the utility and limitations of carbon isotope stratigraphy to inform hypotheses regarding global correlation and biospheric evolution 2012 elsevier b v all rights reserved

subdivision and correlation of late precambrian sequences in australia abstract the diversity of the australian precambrian record is used to empirically assess the application of all available techniques of correlation of late precambrian rocks lithofacies isotopic ages palaeontology and palaeomagnetism within the framework of latest lithostratigraphic geochronologic correlation charts lithostratigraphy is the main tool for intrabasinal correlation and mapping but isotopic ages will continue for some time yet to provide the main criteria for interregional correlation lithostratigraphic correlation is demonstrated over hundreds of kilometres but is generally constrained by tectonic controls to individual major crustal blocks climatic markers such as tillites may be correlated interregionally over thousands of kilometres the most exciting recent development in platform geochronology is the application of u pb zircon dating to fine grained tuffs illite may provide reliable minimum estimates but can be shown to be up to 150 ma too young glauconite and rb sr total rock shale ages have provided useful broad age estimates of sequences for which better methods are unavailable but only when based on cautious assessment and multiple sampling their ages may be either minimum or maximum stromatolites continue to demonstrate their potential for broad correlation when based on rigorous taxonomic study but the framework of time ranges of known taxa must be expanded for stromatolites to achieve their full potential especially for rocks older than 1000 ma acritarchs in black shales provide diverse and complex assemblages with excellent correlation potential but once again the australian taxonomic framework is still inadequate black cherts contain an evolutionarily conservative biota with only limited correlation potential recent palaeomagnetic studies based on both apwp and magnetostratigraphy demonstrate excellent potential for detailed correlations down to at least 1700 ma old however the present chronologically calibrated data base is sparse and must be supplemented by many more detailed studies through thick continuous rock sequences spanning substantial intervals of time the value of multidisciplinary correlation is elegantly demonstrated by very detailed and unambiguous correlation of combined palaeomagnetic isotopic age and stromatolite data across the 1700 ma mcarthur basin previous regional lithostratigraphic correlations have been conclusively and significantly revised with major implications to regional palaeogeography

geochronology of sedimentary and metasedimentary precambrian rocks of the west african craton abstract this contribution summarizes current knowledge of the geochronology of the upper proterozoic sedimentary rocks covering the west african craton this was done by using direct dating methods correlations between the northern edge of the tindouf basin and the northern and southern part of the taoudeni basin as well as the volta basin are proposed an important depositional lack over almost the entire craton is confirmed between 1 7 ga which represents the time of the latest eburnean activities or cooling effects and about 1 0 ga which is the start of the general upper proterozoic sedimentation this lack is remarkable as the other cratons from gondwana continent are covered by middle proterozoic sediments the upper proterozoic sedimentation on the west african craton may be divided into a basal mainly sandstone period ca 1000 900 ma a middle mainly limestone period ca 900 750 ma and an upper mainly siltstone period ca 750 650 ma tectonic volcanic and thermal activities in connection with the pan african orogeny are recorded only around the craton they induced either sedimentation lacks in morocco or sedimentation excesses in hoggar unsolved problems such as the precise stratigraphic position of the uppermost proterozoic tillitic episode and the correlation within the moroccan anti atlas are also raised

late cenozoic tectonics and volcanism along the north anatolian fault new structural and geochemical data abstract different types of volcanic activity have developed along the north anatolian fault zone naf in turkey detailed analysis of satellite images and digital elevation models dems and field observations have been made in order to understand the tectonics and the distribution of volcanic vents in the anatolian block some faults are oblique to the naf and delimit extensional escape wedges vents rooted on open tension fractures show that emplacement of the volcanism is related to tensional fracturing of the anatolian continental block which we attribute to the onset of free borders in the south and west along the naf earliest extension 1 is directed s to ssw and the latest 2 towards w to wsw parallel to the sinistral slip along the naf major and trace element geochemical data indicate that the dominant calc alkaline rocks are associated with various alkaline lavas k ar ages of the volcanics range from 22 to 8 5 ma in galatia massif 900 to 100 ka in niksar and 3 to 12 ka in erzincan isotopic and trace element data are interpreted as reflecting a dominantly lithospheric mantle source slightly mixed with asthenospheric liquids most magmas were fractionated and contaminated by continental crust during their ascent 1 and 2 tectono volcanic events have propagated through time and space from west to east the 1 extension is late oligocene in the galatia massif late miocene in niksar and late pliocene in erzincan the 2 extension and strike slip event along the naf began in the late miocene in the galatia massif early pliocene in niksar and quaternary in erzincan signature from an asthenospheric source in the second event in the three regions suggests that an ancient suture zone galatia massif and or the lithospheric naf transform niksar and erzincan have served to channel small quantities of asthenospheric melts existing at the base of the lithosphere

heterogeneous redox conditions and a shallow chemocline in the mesoproterozoic ocean evidence from carbon sulfur iron relationships abstract oxygenation of earth s oceans in the proterozoic was a protracted process that began prior to the great oxidation event goe and culminated in deep ocean ventilation following neoproterozoic glacial episodes with both of these major thresholds accompanied by profound changes in the evolution of earth s biosphere our understanding of the redox structure of mesoproterozoic oceans however is considerably less certain limited proxy investigations of oceanic redox in the mesoproterozoic have focused largely on early mesoproterozoic shelf to basinal settings with comparatively little attention paid to epeiric sea environments that dominate the late mesoproterozoic sedimentary record here we report multi proxy shale redox data from epicratonic and pericratonic environments of the 1 1 ga atar and el mreiti groups taoudeni basin mauritania these strata were deposited across the west african craton during global sea level highstand and provide insight into the redox structure of mesoproterozoic epeiric seas iron speciation pyrite sulfur isotope and trace metal concentration data suggest a shallow chemocline and highly heterogeneous redox conditions with fundamental heterogeneities in sulfate concentration and the extent and persistence of euxinia between onshore and offshore environments we suggest that a protracted increase in biospheric oxygenation in the late mesoproterozoic was accompanied by unstable and heterogeneous redox conditions in shallow nearshore areas contributing to the fragmentary pattern of early eukaryotic evolution and diversification

earthen barriers to control lava flows in the 2001 eruption of mt etna abstract preceded by four days of intense seismicity and marked ground deformation a new eruption of mt etna started on 17 july and lasted until 9 august 2001 it produced lava emission and strombolian and phreatomagmatic activity from four different main vents located on a complex fracture system extending from the southeast summit cone for about 4 5 km southwards from 3000 to 2100 m elevation a s l the lava emitted from the lowest vent cut up an important road on the volcano and destroyed other rural roads and a few isolated country houses its front descended southwards to about 4 km distance from the villages of nicolosi and belpasso a plan of intervention including diversion and retaining barriers and possibly lava flow interruption was prepared but not activated because the flow front stopped as a consequence of a decrease in the effusion rate extensive interventions were carried out in order to protect some important tourist facilities of the sapienza and mts silvestri zones 1900 m elevation from being destroyed by the lava emitted from vents located at 2700 m and 2550 m elevation thirteen earthen barriers with a maximum length of 370 m height of 10 12 m base width of 15 m and volume of 25 000 m3 were built to divert the lava flow away from the facilities towards a path implying considerably less damage most of the barriers were oriented diagonally 110 135 to the direction of the flow they were made of loose material excavated nearby and worked very nicely resisting the thrust of the lava without any difficulty after the interventions carried out on mt etna in 1983 and in 1991 1992 those of 2001 confirm that earthen barriers can be very effective in controlling lava flows