major types and time space distribution of mesozoic ore deposits in south china and their geodynamic settings the ore deposits of the mesozoic age in south china can be divided into three groups each with different metal associations and spatial distributions and each related to major magmatic events the first event occurred in the late triassic 230 210 ma the second in the mid late jurassic 170 150 ma and the third in the early mid cretaceous 120 80 ma the late triassic magmatic event and associated mineralization is characterized by peraluminous granite related w sn nb ta mineral deposits the triassic ore deposits are considerably disturbed or overprinted by the later jurassic and cretaceous tectono thermal episodes the mid late jurassic magmatic and mineralization events consist of 170 160 ma porphyry skarn cu and pb zn ag vein deposits associated with i type granites and 160 150 ma metaluminous granite related polymetallic w sn deposits the late jurassic metaluminous granite related w sn deposits occur in a ne trending cluster in the interior of south china such as in the nanling area in the early mid cretaceous from about 120 to 80 ma but peaking at 100 90 ma subvolcanic related fe deposits developed and i type calc alkaline granitic intrusions formed porphyry cu mo and porphyry epithermal cu au ag mineral systems whereas s type peraluminous and or metaluminous granitic intrusions formed polymetallic sn deposits these cretaceous mineral deposits cluster in distinct areas and are controlled by pull apart basins along the south china continental margin based on mineral assemblage age and space time distribution of these mineral systems integrated with regional geological data and field observations we suggest that the three magmatic mineralization episodes are the result of distinct geodynamic regimes the triassic peraluminous granites and associated w sn nb ta mineralization formed during post collisional processes involving the south china block the north china craton and the indo china block mostly along the dabie sulu and songma sutures jurassic events were initially related to the shallow oblique subduction of the izanagi plate beneath the eurasian continent at about 175 ma but i type granitoids with porphyry cu and vein type pb zn ag deposits only began to form as a result of the breakup of the subducted plate at 170 160 ma along the nne trending qinzhou hangzhou belt also referred to as qin hang or shi hang belt which is the neoproterozoic suture that amalgamates the yangtze craton and cathaysia block a large subduction slab window is assumed to have formed in the nanling and adjacent areas in the interior of south china triggering the uprise of asthenospheric mantle into the upper crust and leading to the emplacement of metaluminous granitic magma and associated polymetallic w sn mineralization a relatively tectonically quiet period followed between 150 and 135 ma in south china from 135 ma onward the angle of convergence of the izanagi plate changed from oblique to parallel to the coastline resulting in continental extensional tectonics and reactivation of regional scale ne trending faults such as the tan lu fault this widespread extension also promoted the development of ne trending pull apart basins and metamorphic core complexes accompanied by volcanism and the formation of epithermal cu au deposits granite related polymetallic sn w deposits and hydrothermal u deposits between 120 and 80 ma with a peak activity at 100 90 ma

a late cretaceous tin metallogenic event in nanling w sn metallogenic province constraints from u pb ar ar geochronology at the jiepailing sn be f deposit hunan china abstract the jiepailing deposit located in southern hunan province china is a giant sn be f deposit in the nanling w sn province the sn be f mineralization is spatially associated with the jiepailing granite porphyry la mc icp ms zircon u pb dating of the jiepailing granite porphyry yielded a weighted mean 206 pb 238 u age of 90 5 0 9 ma mswd 0 32 which is interpreted as the emplacement age of the granite porphyry hydrothermal muscovite yields a plateau 40 ar 39 ar age of 92 1 0 7 ma mswd 0 9 which is well consistent with the zircon u pb age of the jiepailing granite porphyry responsible for the sn be f mineralization indicating a temporal link between the emplacement of the jiepailing granite porphyry and the sn be f mineralization our new high precise geochronological data suggest that the jiepailing giant sn be f deposit and related granite formed during the early late cretaceous 92 90 ma which provided convincing evidence for a previously unrecognized metallogenic event related to late cretaceous granitic magmatism in nanling region the occurrence of the late cretaceous sn metallogenic event identified in southern hunan province further highlights the importance of systematic metallogenic studies of the nanling w sn province integrated with high precise geochronological data obtained previously it is suggested that the nanling region mainly experienced three tectonomagmatic activities and lithospheric thinning events during mesozoic which are responsible for three sn w metallogenic events to form the world class nanling w sn metallogenic province

oxygen isotopic composition and u pb discordance in zircon we have investigated u pb discordance and oxygen isotopic composition of zircon using high spatial resolution 18o measurement by ion microprobe 18o in both concordant and discordant zircon grains provides an indication of the relationship between fluid interaction and discordance our results suggest that three characteristics of zircon are interrelated 1 u pb systematics and concomitant age discordance 2 18o and the water rock interactions implied therein and 3 zircon texture as revealed by cathodoluminescence and bse imaging a key observation is that u pb disturbed zircons are often also variably depleted in 18o but the relationship between discordance and 18o is not systematic 18o values of discordant zircons are generally lighter but irregular in their distribution textural differences between zircon grains can be correlated with both u pb discordance and 18o discordant grains exhibit either a recrystallized fractured or strongly zoned cl texture and are characteristic of 18o depletion we interpret this to be a result of metamictization leading to destruction of the zircon lattice and an increased susceptibility to lead loss conversely grains that are concordant have less expressed zoning and a smoother cl texture and are enriched in 18o from this it is apparent that various stages of water rock interaction as evidenced by systematic variations in 18o leave their imprint on both the texture and u pb systematics of zircon

u pb geochronology of zircon and polygenetic titanite from the glastonbury complex connecticut usa an integrated sem empa tims and shrimp study abstract u pb ages for zircon and titanite from a granodioritic gneiss in the glastonbury complex connecticut have been determined using both isotope dilution thermal ionization mass spectrometry tims and the sensitive high resolution ion microprobe shrimp zircons occur in three morphologic populations 1 equant to stubby multifaceted colorless 2 prismatic dark brown with numerous cracks and 3 elongate prismatic light tan to colorless cathodoluminescence cl imaging of the three populations shows simple concentric oscillatory zoning the zircon tims age weighted average of 207pb 206pb ages from group 3 grains 450 5 1 6 ma mswd 1 11 and shrimp age composite of 206pb 238 u age data from all three groups 448 2 2 7 ma mswd 1 3 are interpreted to suggest a relatively simple crystallization history titanite from the granodioritic gneiss occurs as both brown and colorless varieties scanning electron microscope backscatter bse images of brown grains show multiple cross cutting oscillatory zones of variable brightness and dark overgrowths colorless grains are unzoned or contain subtle wispy or very faint oscillatory zoning electron microprobe analysis empa clearly distinguishes the two populations brown grains contain relatively high concentrations of fe2o3 ce2o3 up to 1 5 wt nb2o5 and zr cerium concentration is positively correlated with total ree y concentration which together can exceed 3 5 wt oscillatory zoning in brown titanite is correlated with variations in ree concentrations in contrast colorless titanite both as discrete grains and overgrowths on brown titanite contains lower concentrations of y ree fe2o3 and zr but somewhat higher al2o3 and nb2o5 uranium concentrations and th u discriminate between brown grains typically 200 400 ppm u all analyses but one have th u between about 0 8 and 2 and colorless grains 10 60 ppm u th u of 0 0 17 in contrast to the zircon u pb age results shrimp u pb data from titanite indicate multiple growth episodes in brown grains oscillatory zoned cores formed at 443 6 ma whereas white in bse cross cutting zones are 425 9 ma colorless grains and overgrowths on brown grains yield an age of 265 8 ma using the total pb method or 265 5 ma using the weighted average of the 206pb 238u ages however empa chemical data identify zoning that suggests that this colorless titanite may preserve three growth events oscillatory zoned portions of brown titanite grains are igneous in origin white cross cutting zones probably formed during a previously unrecognized event that caused partial dissolution of earlier titanite and reprecipitation of a slightly younger generation of brown titanite colorless titanite replaced and grew over the magmatic titanite during the permian alleghanian orogeny these isotopic data indicate that titanite like zircon can contain multiple age components coupling shrimp microanalysis with empa and sem results on dated zones as presented in this study is an efficient and effective technique to extract additional chronologic data to reveal the complexities of igneous crystallization and metamorphic growth

where was south china in the rodinia supercontinent evidence from u pb geochronology and hf isotopes of detrital zircons abstract u pb geochronology and lu hf isotopic studies on detrital zircons from late neoproterozoic sediments of the cathaysia block south china show abundant grenville age 1 0 ga and neoarchaean populations and minor eoarchaean 3 8 ga paleo to mesoarchaean 3 3 3 0 ga mesoproterozoic 1 7 1 4 ga and pan african 0 70 0 54 ga populations this is the first report of 3 8 ga material in the crust of the cathaysia block the presence of euhedral 1 0 ga zircons indicates that a grenville orogenic belt was within or very close to the southern cathaysia block however the provenance containing the 3 8 ga 3 3 3 0 ga 2 5 ga 1 0 ga and 0 70 0 54 ga zircon populations cannot be found in the south china block the combination of zircon age distributions and the rounded strongly abraded shapes of the archean zircons suggesting long transport is consistent with derivation from other continental terranes previously linked with the southern part of the south china block comparison with the tectono magmatic history and compositions of rocks in western laurentia eastern australia and eastern india east antarctica western australia we suggest that these late neoproterozoic sediments may have originated mainly from eastern india east antarctica this indicates that the south china block was linked with the eastern india east antarctica continents in the late neoproterozoic rather than being located between the western laurentia and eastern australia continental blocks u pb and hf isotope studies on detrital zircons provide an important independent constraint on the palaeogeography of the south china block in the context of the breakup of rodinia and the subsequent assembly of gondwana in late neoproterozoic time and insights into the relationship between the cathaysia and yangtze blocks

partial melting of metagreywackes part ii compositions of minerals and melts a series of experiments on the fluid absent melting of a quartz rich aluminous metagreywacke has been carried out in this paper we report the chemical composition of the phases present in the experimental charges as determined by electron microprobe this analytical work includes biotite plagioclase orthopyroxene garnet cordierite hercynite staurolite gedrite oxide and glass over the range 100 1000 mpa 780 1025 c biotites are na and mg rich with ti contents increasing with temperature the compositions of plagioclase range from an17 to an35 with a significant orthoclase component and are always different from the starting minerals at high temperature plagioclase crystals correspond to ternary feldspars with or contents in the range 11 20 mol garnets are almandine pyrope grossular spessartine solid solutions with a regular and significant increase of the grossular content with pressure all glasses are silicic sio2 67 6 74 4 wt peraluminous and leucocratic feo mgo 0 9 2 9 wt with a bulk composition close to that of peraluminous leucogranites even for degrees of melting as high as 60 vol with increasing pressure sio2 contents decrease while k2o increases at any pressure the melt compositions are more potassic than the water saturated granitic minima the h2o contents estimated by mass balance are in the range 2 5 5 6 wt these values are higher than those predicted by thermodynamic models modal compositions were estimated by mass balance calculations and by image processing of the sem photographs the positions of the 20 to 70 isotects curves of equal proportion of melt have been located in the pressure temperature space between 100 mpa and 1000 mpa with increasing pressure the isotects shift toward lower temperature between 100 and 200 mpa then bend back toward higher temperature the melting interval increases with pressure the difference in temperature between the 20 and the 70 isotects is 40 c at 100 mpa and 150 c at 800 mpa the position of the isotects is interpreted in terms of both the solubility of water in the melt and the nature of the reactions involved in the melting process a comparison with other partial melting experiments suggests that pelites are the most fertile source rocks above 800 mpa the difference in fertility between pelites and greywackes decreases with decreasing pressure a review of the glass compositions obtained in experimental studies demonstrates that partial melting of fertile rock types in the crust greywackes pelites or orthogneisses produces only peraluminous leucogranites more mafic granitic compositions such as the various types of calk alkaline rocks or mafic s type rocks have never been obtained during partial melting experiments thus only peraluminous leucogranites may correspond to liquids directly formed by partial melting of metasediments other types of granites involve other components or processes such as restite unmixing from the source region and or interaction with mafic mantle derived materials

precise sm nd and u pb isotopic dating of the supergiant shizhuyuan polymetallic deposit and its host granite se china the supergiant shizhuyuan w sn bi mo deposit is hosted by the qianlishan granite a small highly fractionated granitic pluton 10 km 2 with multiple phases of intrusions within the early yanshanian granitoid province of se china strong alteration of skarn and greisen that formed in the contact zone between the first and second phases of granite intrusions and devonian limestone is responsible for the polymetallic mineralizations shrimp u pb zircon analysis indicates that the two early phases of the qianlishan granite formed contemporaneously at 152 2 ma metasomatic minerals garnet fluorite and wolframite separated from the skarn and greisen yield a sm nd isochron age of 149 2 ma that is interpreted as the formation age of the shizhuyuan deposit therefore the mineralization of the supergiant shizhuyuan polymetallic deposit formed contemporaneously with or very shortly after the intrusion of the small highly fractionated qianlishan granite

petrogenesis and magmatic hydrothermal evolution time limitation of kelumute no 112 pegmatite in altay northwestern china evidence from zircon upb and hf isotopes abstract granitic pegmatites and associated rare metal deposits unique features in the altay orogen are located in a key tectonic position of the southern central asian orogenic belt caob and document the tectonic evolution of the paleo asian ocean the kelumute no 112 pegmatite which intruded into the jideke two mica granites hosts abundant rare metal e g li be nb ta ore deposits and ranks only second to the koktokay no 3 pegmatite in both size and reserves to explore the evolution time limitation of magmatic magmatic hydrothermal and hydrothermal stages in the pegmatite magma system the tectonic setting and the genetic relationship between pegmatites and granites this study presents zircon u pb and hf isotopic compositions of the kelumute no 112 pegmatite and the wall rocks two mica granite and biotite granite as determined by la icpms and la mc icpms the weighted mean 206 pb 238 u ages of the internal textural zones of the pegmatite including zones i ii iii v and vi are 238 3 2 0 ma 233 5 3 7 ma 188 3 1 7 ma 218 8 1 9 ma and 210 7 1 6 ma respectively wall rocks of two mica granite and biotite granite are dated at 445 6 4 3 ma and 455 6 5 4 ma respectively zircons from the kelumute no 112 pegmatite have lower positive e hf t values 0 03 to 2 35 with t dm model ages of 1112 1225 ma wall rocks show similar zircon e hf t values 1 41 to 4 13 and t dm model ages 1172 to 1515 ma however three xenocrystic zircons from the granites are characterized by larger negative ehf t values 5 85 to 9 83 and older t dm model ages 1839 to 2090 ma thus the following conclusions can be drawn 1 the kelumute no 112 pegmatite and its wall rocks jideke two mica granite and biotite granite have no genetic relationship as indicated by the large gaps between their formation ages however they did originate from a common source composed of ancient crust and mantle derived materials under two different tectonic settings 2 the magmatic magmatic hydrothermal transition and hydrothermal stages of the no 112 pegmatite magma lasted for 5 ma 23 ma and 22 ma respectively and 3 the no 112 pegmatite magma was most likely formed in a post collision tectonic setting indicating that block amalgamation and collisional orogeny of the caob continued into the triassic

in situ la mc icp ms and id tims u pb geochronology of cassiterite in the giant furong tin deposit hunan province south china new constraints on the timing of tin polymetallic mineralization abstract the furong deposit located in southern hunan province china is a newly discovered giant tin deposit spatially associated with the a type qitianling granite the petrogenetic link between the giant furong tin deposit and the qitianling granite batholith remains controversial because of the lack of precise dating for the tin polymetallic mineralization here we report for the first time in situ u pb data on cassiterite obtained by la mc icp ms and the results are compared to id tims data the in situ la mc icp ms analyses of the cassiterites provide a reliable age constraint for tin polymetallic mineralization in the furong deposit yielding an isochron age of 159 9 1 9 ma at 95 confidence level mswd 18 which is indistinguishable from the id tims 206 pb 238 u weighted mean age of 158 2 0 4 ma the in situ u pb ages corroborate the ar ar dates published for the furong tin deposit which indicate that the mineralization is coeval with the emplacement of the qitianling granite batholith these results provide further evidence of a close temporal link between the pluton s emplacement and tin mineralization in the furong area the data obtained clearly demonstrate that in situ la mc icp ms u pb dating of cassiterite is a robust geochronometer for direct dating of tin polymetallic mineralization

magmatic evolution of li f rare metal granites a case study of melt inclusions in the khangilay complex eastern transbaikalia russia abstract we report compositions of homogenized quartz hosted melt inclusions from a layered sequence of li f rich granites in the khangilay complex that document the range of melt evolution from barren biotite granites to ta rich lepidolite amazonite albite granites the melt inclusions are crystalline at room temperature and were homogenized in a rapid quench hydrothermal apparatus at 200 mpa before analysis homogenization runs determined solidus temperatures near 550 c and full homogenization between 650 and 750 c the compositions of inclusions determined by electron microprobe and raman spectroscopy for h 2 o show regular overall trends of increasing differentiation from the least evolved khangilay units to apical units in the orlovka intrusion total volatile contents in the most evolved melts reach over 11 wt h 2 o 8 6 wt f 1 6 wt b 2 o 3 1 5 wt concentrations of rb range from about 1000 to 3600 ppm but other trace elements could not be measured reliably by electron microprobe the resulting trends of melt evolution are similar to those described by the whole rock samples despite petrographic evidence for albite and mica rich segregations previously taken as evidence for post magmatic metasomatism melt variation trends in most samples are consistent with fractional crystallization as the main process of magma evolution and residual melt compositions plot at the granite minimum in the normative qz ab or system however melts trapped in the highly evolved pegmatitic samples from orlovka deviate from the minimum melt composition and show compositional variations in al na and k that requires a different explanation we suggest that unmixing of the late stage residual melt into an aluminosilicate melt and a salt rich dense aqueous fluid hydrosaline melt occurred experimental data show the effectiveness of this process to separate k aluminosilicate melt from na hydrosaline melt and high mobility of the latter due to its low viscosity and relatively low density may explain local zones of albitization in the upper parts of the granite

genesis of the xianghualing sn pb zn deposit south china a multi method zircon study abstract the xianghualing sn pb zn deposit is situated near the center of the world class nanling w sn ore belt associated with the highly evolved laiziling granite of jurassic age previous studies focused mainly on geochemical and geochronological features of the mineralization related granite whereas research on the source evolution and geochronology of the ore forming fluids has been limited we carried out precise u pb dating trace element and hf isotopic analyses on magmatic and hydrothermally altered zircons from the skarn stage and sulfide stage ores in the xianghualing deposit zircon u pb dating results from the two ore forming stages show distinct geochronological populations the skarn stage ores contain mainly magmatic and hydrothermally altered zircons in three age clusters 150 ma 220 ma and 420 ma whereas the sulfide stage ores are characterized by abundant old detrital zircons ranging from 497 to 3409 ma with a peak at 800 1000 ma this pattern may indicate that magmatic hydrothermal events in the silurian and triassic were precursors to the main sn mineralization event in the jurassic when circulation of evolved fluids through older sedimentary rocks led to pb zn mineralization the jurassic zircons exhibit high trace element contents e g hf p y nb ta th u and low ti contents eu anomalies nb ta and th u ratios which imply that the laiziling magma experienced significant plagioclase biotite and muscovite fractional crystallization and that it interacted extensively with post emplacement f rich hydrothermal fluids the positive ce anomalies of these zircons ce ce 1 0 226 indicate that the magmatic hydrothermal fluids that led to the jurassic sn mineralization event were reducing the less negative ehf t values of triassic zircons 18 7 to 2 6 compared to the silurian zircons 14 6 to 2 3 suggest more limited interaction between the mantle and the magma source region the jurassic magmatic zircons in the skarns exhibit even more negative ehf t values 30 7 to 6 7 along with tdmc model ages ranging from 1627 to 3134 ma indicating that the jurassic magma was derived from partial melting of old continental crustal basement based on the combined study of zircons in the skarns and sulfide ores we propose a three stage ore genetic model for the xianghualing sn pb zn deposit

the parkfield prediction fallacy abstract the parkfield earthquake prediction is generally stated as a 95 probability that the next moderate earthquake there should occur before january 1993 that time limit is based on a two sided 95 confidence interval because at the time of the prediction 1985 it was already clear that the earthquake had not occurred prior to 1985 a one sided 95 confidence interval would have been more appropriate that confidence interval ended in october 1991 the parkfield prediction was based on an extrapolation of five of the six events in the 1857 to 1966 earthquake sequence the 1934 event was omitted because it did not fit the regularity exhibited by the other data the fallacy in the prediction is that it did not take account of other less contrived explanations of the parkfield seismicity e g not excluding the 1934 event even if the parkfield earthquake should occur in the near future it would be better explained by less contrived hypotheses

generation of late mesozoic qianlishan a 2 type granite in nanling range south china implications for shizhuyuan w sn mineralization and tectonic evolution abstract the late mesozoic qianlishan granitic complex in the western nanling range south china is associated with the shizhuyuan giant w sn mo bi polymetallic deposit it mainly consists of three phases of intrusions p 1 porphyritic biotite granite p 2 equigranular biotite granite and p 3 granite porphyry all three phases of granite contain quartz plagioclase k feldspar and fe rich biotite they have geochemical affinities of a type granites e g high feot feot mgo ratios 0 84 0 99 total alkali na2o k2o 7 50 9 04 wt high ga al ratios 10 000 ga al 2 6 and high zr nb y ce concentrations 350 ppm high y nb ratios 1 2 suggest that the qianlishan complex belongs to a2 type granite zircon u pb ages indicate a short age interval decreasing from 158 157 ma to 158 155 ma and to 154 ma for the p 1 p 2 and p 3 granites respectively these ages are similar to the mineralization age of the shizhuyuan tungsten polymetallic deposit within error the qianlishan granites were generated at low oxygen fugacity conditions based on the low values of zircon ce4 ce3 ratios 1 53 198 and significantly negative eu anomalies eun eun 0 03 0 13 in apatite new zircon ehf t values for the p 3 granite range from 13 0 to 4 4 similar to those previously obtained for the p 1 and p 2 granites both the granite and apatite grains therein are characterized by high f but low cl concentrations suggesting the influx of a high f cl component the p 2 granites especially contain higher f contents 1840 8690 ppm and w 7 158 ppm and sn 6 51 ppm concentrations and with stronger evolution features positive trends between f and w and sn of qianlishan complex indicate that high f source is crucial for mineralization of w and sn we consider that the lithospheric mantle source may have been metasomatized by subduction fluids in the far end of subduction zones to produce the a2 feature of the qianlishan granite and the fluorine was introduced through breakdown of phengite in the oceanic slab partial melting of the lithospheric mantle was induced by upwelling of the asthenospheric mantle as a consequence of slab rollback tungsten and tin have been enriched in reduced granitic magmas through fractionation enhanced by high f contents forming the giant polymetallic deposits

shrimp zircon u pb geochronological and whole rock geochemical evidence for an early neoproterozoic sibaoan magmatic arc along the southeastern margin of the yangtze block abstract it has been generally accepted that the south china block was formed through amalgamation of the yangtze and cathaysia blocks during the proterozoic sibaoan orogenesis but the timing and kinematics of the sibao orogeny are still not well constrained we report here shrimp u pb zircon geochronological and geochemical data for the taohong and xiqiu tonalite granodiorite stocks from northeastern zhejiang southeastern margin of the yangtze block our data demonstrate that these rocks dated at 913 15 ma and 905 14 ma are typical amphibole rich calc alkaline granitoids formed in an active continental margin combined with previously reported isotopic dates for the 1 0 ga ophiolites and 0 97 ga adakitic rocks from northeastern jiangxi the timing of the sibao orogenesis is thus believed to be between 1 0 and 0 9 ga in its eastern segment it is noted that the sibao orogeny in south china is in general contemporaneous with some other early neoproterozoic 1 0 0 9 ga orogenic belts such as the eastern ghats belt of india and the rayner province in east antarctica indicating that the assembly of rodinia was not finally completed until 0 9 ga

a tale of two plutons petrographic and mineralogic constraints on the petrogenesis of the red lake and eagle peak plutons central sierra nevada california the red lake and eagle peak plutons are similar in age k ar 87 89 m y and range in composition from granodiorite to granite the red lake pluton is equigranular has a locally greisened marginal zone and shows only minor mineralogical and chemical zoning whereas the eagle peak pluton is mineralogically compositionally and texturally zoned with an equigranular margin and a porphyritic core modal and normative trends within each pluton are consistent with separation of plagioclase and mafic minerals leading to a residual liquid enriched in quartz and alkali feldspar the formation of the prominent alkali feldspar megacrysts in the eagle peak core was promoted by plagioclase separation h 2 o undersaturation and a slower cooling rate relative to the red lake magma early loss of volatiles and a resulting increase in magma melt crystals viscosity inhibited crystal segregation within the red lake pluton and prevented the development of zoning late stage aplites associated with both plutons f

petrogenesis of the red mountain pluton laramie anorthosite complex wyoming implications for the origin of a type granite abstract the red mountain pluton the youngest intrusion in the laramie anorthosite complex is one of five monzonitic to granitic a type plutons intruded at 1 43 ga in the laramie mountains of southeastern wyoming the red mountain pluton ranges in composition from fayalite monzonite clinopyroxene quartz monzonite and biotite hornblende quartz syenite to granite the red mountain pluton is petrologically and geochemically distinct from the northern and southern sherman batholith the sybille intrusion and the maloin ranch pluton it has higher feo t feo t mgo and higher k 2 o is more strongly enriched in rees and at any given silica content it has lower abundances of tio 2 feo mgo cao and p 2 o 5 the fayalite monzonite in the red mountain pluton crystallized at temperatures around 1000 c and oxygen fugacities 1 2 log units below that of the fmq buffer similar to the crystallization conditions of the sybille and maloin ranch plutons the biotite hornblende quartz syenite crystallized at oxygen fugacities near or slightly below those of fmq most of the units in the pluton carry mantle like nd sr and pb isotopic compositions similar to the least contaminated anorthositic and ferrodioritic rocks of the lac indicating that the pluton evolved mainly via differentiation substantial crustal assimilation occurred only in the late dikes and the granite we suggest that all of the 1 43 ga a type intrusions in southeastern wyoming are ultimately derived from tholeiites extreme differentiation or partial melting produced monzonitic magmas that have assimilated varying amounts of siliceous crust the differences between the red mountain pluton and other a type granitoids in southeastern wyoming are related to the extent of differentiation prior to crustal assimilation the compositional ranges of a type granitoids in southeastern wyoming suggest that the geochemical spectrum of a type granites worldwide similarly are produced from evolved mantle derived melt that has assimilated varying proportions of crustal material

molybdenite re os and muscovite 40ar 39ar dating of the xihuashan tungsten deposit central nanling district south china abstract the xihuashan tungsten deposit in the central nanling region south china is an important vein type ore deposit hosted in cambrian strata and mesozoic granitic intrusions wolframite and molybdenite are the principal ore minerals the gangue minerals are mainly quartz and muscovite wolframite and molybdenite are products of the first stage hydrothermal activity whereas muscovite formed dominantly at the second stage molybdenite re os and muscovite 40ar 39ar dating have been carried out to investigate the age of mineralization re os isotopic dating for molybdenite associated with wolframite yield a precise well constrained isochron age of 157 8 0 9 ma mswd 1 5 ar ar isotopic analyses of muscovite yield a plateau age of 152 8 1 6 ma in agreement with an inverse isochron age of 152 8 1 6 ma which is 5 mys younger than the re os age the molybdenite re os age is interpreted as the age of tungsten mineralization this age coincides well with the zircon u pb age of the host granitic intrusion reported previously the 5 mys difference between molybdenite re os and muscovite 40ar 39ar ages probably represents the duration of hydrothermal activity the results show that the xihuashan tungsten deposit is one of many important tungsten tin deposits formed during 150 to 160 ma associated with large scale lithospheric extension in south china

distribution and compositions of magmatic inclusions in the mount helen dome lassen volcanic center california insights into magma chamber processes abstract variations in spatial abundances compositions and textures of undercooled magmatic inclusions were determined in a glaciated pleistocene lava dome mt helen 0 6 km3 at the lassen volcanic center lvc southernmost cascades spatial variations were determined by point counting at 86 locations separated by 100 m on the dome major and trace element compositions of host rocks and inclusions at 12 locations along the flow length of the dome were obtained important results include the following 1 inclusion abundances range from 3 19 vol with the highest values generally located along the little eroded northwestern margin and flow front of the dome 2 host rock compositions are markedly uniform across the dome 65 4 0 4 wt sio2 indicating that the degree of inclusion disaggregation was uniform despite large spatial variations in inclusion abundances 3 inclusion sizes range from a maximum of 1 m across to mm sized crystal clots of phenocrysts plus adhering ca rich plagioclase microphenocrysts 4 inclusions have variable macroscopic textures indicating that partial undercooling both prior to and following entrapment in cooler dacitic host magma were important processes 5 inclusions are variably fractionated magmas with large variations in ni 79 11 ppm and cr 87 7 ppm contents that are lower than presumed mantle derived melts furthermore large ranges in incompatible trace elements indicate that inclusion compositions also reflect deep processes involving either melting of variable mantle source rocks or assimilation fractional crystallization 6 inclusions are variably mixed magmas 56 61 wt sio2 that contain up to 50 host dacitic magma 7 correlations between ni and cr contents in hosts and inclusions from individual outcrops indicate that the effect of inclusion disaggregation and magma mingling on host dacitic magma was local e g these features are interpreted to reflect protracted recharge of diverse composition mafic magmas into the base of a shallow magma reservoir containing a lower layer of compositionally evolving hybrid mafic magma and an upper layer of rhyodacitic magma complex interactions among magmas in the upper and lower layers resulted in formation of mafic inclusions by both pre and post entrapment undercooling mechanisms followed by buoyant rise and accumulation near the roof of the reservoir the main stage of inclusion disaggregation probably occurred in the conduit during eruptive ascent and largely ceased upon surface eruption we infer that endogenous growth concentrated inclusions along the margins and top of the dome as more inclusion poor dacite was progressively tapped from deeper regions of the reservoir

generation of metaluminous a type granites by low pressure melting of calc alkaline granitoids melting experiments on two calc alkaline rocks a tonalite and a granodiorite demonstrate that shallow dehydration melting of hornblende and biotite bearing granitoids generates metaluminous a type granitic melts profuse crystallization of calcic plagioclase orthopyroxene during low pressure p 4 kbar incongruent melting explains all of the major and trace element characteristics of a type granites e g their low al ca mg sr and eu contents and high ga al and k na ratios as well as their common association with anorthositic and mangeritic rocks the residual assemblage produced during melting of the same rocks in the deep crust p 8 kbar is dominated by clinopyroxene and as a consequence most of the chemical features diagnostic of a type granites are lost the high temperatures 900 c and low h 2 o contents 4 wt that are characteristic of a type magmas are adequately explained by the h 2 o poor nature of the granitoid source materials and require neither a granulitic nor a f rich source previous attempts to explain the origin of a type granites have focused on the nature of the source material these experiments show that pressure of melting is at least as important as source composition in engendering a type melts

petrogenesis of tourmaline granites and topaz granites the contribution of experimental data abstract fluorine and boron are generally only minor components of granitic rocks but may be found highly concentrated in certain tourmaline granites and topaz granites up to 1 wt b2o3 and 3 2 wt f respectively studies of various examples of these granite types which occur as small bodies emplaced at shallow levels p lithostatic textural and petrographic data indicate that the tourmaline and topaz granite magmas crystallized at low to moderate temperatures below 700 c and that a fluid phase may have been present during the crystallization interval both granites varieties are peraluminous co up to 5 characterized by the presence of white micas lithium micas or muscovite aluminium silicates and other al rich minerals garnet cordierite boron and fluorine are hosted by tourmaline schorl rich member of the schorl dravite series topaz and mica respectively these granites have low ca fe mg and ti contents each the crystallization of tourmaline granite and topaz granite magmas is discussed using experimental data derived from studies of granitic systems with added boron and fluorine both elements act as a flux enabling boron and fluorine enriched melts to persist to temperatures as low as 650 c at 1 kbar in addition the effect of increasing fluorine content displaces the minimum in q ab or at ph2o 1 kbar toward the albite apex plots of fluorine rich topaz granites coincide with this trend suggesting that the role of fluorine in magmatic processes may have affected the rock composition as well as crystallization temperatures boron rich granites plot near the low ph2o minima in qz ab or suggesting that boron has less of an influence on minimum melt compositions the low temperatures of crystallization permits phases such as muscovite or andalusite topaz and two alkali feldspars to crystallize directly from f and b enriched melts at low pressures in addition the limited available experimental data are used to compare the effects of fluorine and boron on major and trace element distribution during melt vapour interaction

nature of parent rocks mineralization styles and ore genesis of regolith hosted ree deposits in south china an integrated genetic model abstract regolith hosted rare earth element ree deposits also called ion adsorption or weathered crust elution deposited ree deposits are distributed over jiangxi guangdong fujian hunan guangxi and yunnan provinces in south china in general these deposits can be categorized into the hree dominated type for example the famous zudong deposit in southern jiangxi province and the lree dominated type such as the heling and dingnan deposits in southern jiangxi province most of these deposits form from weathering of biotite and muscovite granites syenites monzogranites granodiorites granite porphyries and rhyolitic tuffs the parent rocks are generally peraluminous siliceous alkaline and contain a variety of ree bearing minerals mostly ree patterns of regolith are inherited from the parent rocks and therefore characteristics of the parent rocks impose a significant control on the ore formation data compilation shows that autometasomatism during the latest stage of granite crystallization is likely essential in forming the hree enriched granites whereas lree enriched granites could form through magmatic differentiation these deposits are normally two to three fold but could be up to ten fold enrichment in ree compared to the parent granites where the maximum enrichment usually occurs from the lower b to the upper c horizon ce shows different behavior with the other rees strongly positive ce anomalies commonly occur at the upper part of weathering profiles likely due to oxidation of ce 3 to ce 4 and removal of ce from soil solutions through precipitation of cerianite vertical ph and redox gradients in weathering crusts facilitate dissolution of ree bearing minerals at shallow level and fixation of ree at depth through either adsorption on clay minerals or precipitation of secondary minerals at the same time mass removal of major elements plays an important role in concentrating ree in regolith combination of mass removal and eluviation illuviation dynamics is the main mechanism for ree accumulation in weathering crusts favorable exogenetic factors facilitate the accumulation of ree in regolith and preservation of the ore bodies these include quasi equilibrium between denudation and exhumation at regional scales local geomorphology dominated by low lying gentle slopes adequate rainfall and favorable groundwater conditions continuous operation of such a dynamic weathering system is essential in the formation of regolith hosted ree deposits

hf isotopic compositions of the standard zircons and baddeleyites used in u pb geochronology abstract zircon and baddeleyite u pb geochronological dating is widely used in solid earth sciences and the advent of rapid in situ methods of analysis such sims and icp ms has re emphasized the importance of having uniform standards recently it has been shown that hf isotopic data can provide important information on these minerals since they contain high concentrations of hf but have low lu hf ratios which results in negligible age correction however the complex internal structures that result from multiple thermal events such as inherited cores and metamorphic overgrowths require that the hf isotopic data be measured with high spatial resolution however the isobaric interferences of 176 yb and 176 lu on 176 hf hamper the precise determination of the 176 hf 177 hf ratio during in situ laser ablation mc icpms analysis it is shown here that mass biases of yb yb and hf hf change with time during analyses and behave differently for solutions and solid material therefore it is suggested that the mean yb value of the individual spot be used to obtain the precise isotopic composition for in situ zircon and baddeleyite hf isotopic analyses for low yb hf 176 yb 177 hf yb value have little effect on the accuracy of the hf isotopic composition however the appropriate yb isotopic abundance is necessary for high yb hf 176 yb 177 hf 0 001 zircons and baddeleyites since the interference of 176 yb on 176 hf is significant using the mean yb value of the individual spot and newly published yb isotopic abundance data six standard zircons and two standard baddeleyites have been investigated using a neptune mc icpms with 193 nm laser for zircons the obtained 176 hf 177 hf ratios are 0 282307 31 2sd for 91500 0 282680 31 2sd for temora 0 281729 21 2sd for cz3 282177 17 2sd for cn92 1 0 282983 17 2sd for fm0411 and 281234 11 2sd for phalaborwa the baddeleyites from phalaborwa and sk10 2 have 176 hf 177 hf ratios of 0 281238 12 and 0 282738 13 2sd these results agree well with the values obtained by the solution method and indicate that these standards have different hf isotopic compositions in which the extremely low 176 lu 177 hf and 176 yb 177 hf values of cz3 zircon and phalaborwa baddeleyite make them excellent standards for machine calibration during in situ zircon hf isotopic measurement with the other standards being more suitable for the development of the correction method

soil distribution in the mcmurdo dry valleys antarctica abstract the mcmurdo dry valleys mdvs are the largest ice free area ca 6692 km 2 in antarctica here we present a reconnaissance scale 1 2 million soil map of the mdvs the soil map units are subgroups as identified in the u s department of agriculture soil taxonomy the dominant soil subgroups in the mdvs are typic anhyorthels 43 typic haploturbels 36 and typic anhyturbels 14 soils of the mdvs represent an evolutionary sequence that include glacic haploturbels anhyturbels on holocene surfaces typic haploturbels anhyturbels on late quaternary surfaces typic anhyorthels on late to mid quaternary surfaces salic anhyorthels on mid to early quaternary surfaces and petrosalic petrogypsic petronitric anhyorthels on pliocene and older surfaces soils on silt rich tills of pliocene and older age generally are typic or salic anhyorthels they feature less weathering than younger soils because i they are derived from quartzose materials largely devoid of weatherable minerals and ii they have been subject to considerable wind erosion

improvements of precision and accuracy in in situ hf isotope microanalysis of zircon using the laser ablation mc icpms technique abstract we have developed a new analytical technique for precise and accurate in situ hf isotope ratio measurements for zircons by means of laser ablation multiple collector inductively coupled plasma mass spectrometry la mc icpms newly designed sample cell and n 2 mixing technique provided higher elemental sensitivity with smoother signal intensity profiles in order to improve the accuracy of the hf isotope ratio analysis previously reported correction methods for isobaric interferences on 176 hf by 176 yb and 176 lu were rigorously evaluated and we found that the use of independent mass bias factors for hf and yb in the isobaric interference correction resulted in more reliable hf isotopic data in order to test the reliability of the hf isotopic data from 35 m diameter ablation pits that are smaller than the typical size of most zircon grains lu hf isotopes for three zircons harvard 91500 antarctic zircon pma7 and acasta zircon ay199 were measured the present 176 hf 177 hf isotope ratio of 0 282321 46 2 s d and initial 176 hf 177 hf isotope ratio of 0 282315 47 2 s d were obtained for zircon standard 91500 the resulting present 176 hf 177 hf isotope ratio shows an excellent agreement with the previously reported data our in situ isotopic data revealed that the lu hf ratio varied significantly within the 91500 grain 176 lu 177 hf 0 000130 0 000345 suggesting the existence of slight isotopic heterogeneity in present 176 hf 177 hf approximately 15 ppm for antarctic zircon pma7 despite the smaller size of the single grain 50 100 m wide 80 300 m long and the presence of various mineral inclusions resulting analytical precision for the initial 176 hf 177 hf ratio was 128 ppm 0 281208 36 2 s d for acasta zircon ay199 despite the high yb hf 0 05 and lu hf 0 01 isotope ratios with the early archean crystallization age 3 74 ga resulting analytical precision for the initial 176 hf 177 hf ratio was 187 ppm 0 280160 52 2 s d these results demonstrate clearly that in situ hf isotope ratio microanalysis developed here has the potential to become a significant tool for zircon lu hf isotopic study

comparison of characteristic and gutenberg richter models for time dependent m 7 9 earthquake probability in the nankai tokai subduction zone japan summary earthquake forecasts are usually underinformed and can be plagued by uncertainty in terms of the most appropriate model and parameter values used in that model in this paper we explore the application of two different models to the same seismogenic area the first is a renewal model based on the characteristic earthquake hypothesis that uses historical palaeoseismic recurrence times and fixed rupture geometries the hazard rate is modified by the coulomb static stress change caused by nearby earthquakes that occurred since the latest characteristic earthquake the second model is a very simple earthquake simulator based on plate motion or fault slip rates and adoption of a gutenberg richter magnitude frequency distribution this information is commonly available even if historical and palaeoseismic recurrence data are lacking the intention is to develop and assess a simulator that has a very limited parameter set that could be used to calculate earthquake rates in settings that are not as rich with observations of large earthquake recurrence behaviour as the nankai trough we find that the use of convergence rate as a primary constraint allows the simulator to replicate much of the spatial distribution of observed segmented rupture rates along the nankai tonankai and tokai subduction zones although we note rate differences between the two forecast methods in the tokai zone we also see enough similarities between simulations and observations to suggest that very simple earthquake rupture simulations based on empirical data and fundamental earthquake laws could be useful forecast tools in information poor settings

formation and tectonic evolution of southeastern china and taiwan isotopic and geochemical constraints abstract the southern part of china consists of the proterozoic yangtze craton and the phanerozoic south china foldbelts including the himalayan foldbelt of taiwan models for continental growth have been many and controversial isotopic and geochemical data from mesozoic and younger granitoids and sediments are used here to place constraints on the tectonic evolution of southeastern china and to evaluate whether the young phanerozoic foldbelts are representative of old rejuvenated landmass whether they characterize crustal accretion through successive subduction processes hence suggesting a net growth of continental mass or whether they represent some intermediate situation available sm nd isotopic data for phanerozoic granitoids and metasediments from the south china foldbelts and taiwan invariably show proterozoic model ages t dm ranging from 1 to 2 5 ga with a mean of 1 54 0 30 1 ga all rocks have negative nd t values 2 to 15 suggesting variable but important contributions of old continental materials to the sources of the phanerozoic rocks obviously they do not represent wholesale growth of continental mass the granitoids of the south china foldbelts have multiple origins as viewed from their chemical and isotopic characteristics secular geochemical variation has been established for inland granitoids of proterozoic to mesozoic age their high i sr values 0 710 0 737 suggest that most granitoids are essentially anatectic products of ancient continental crust this is compatible with remelting via microcontinental collision or terrane accretion repeated intracrustal reprocessing by partial fusion and differentiation has undoutedly contributed to important mineralization mesozoic granitoids excluding a type alkaline granites in the coastal region and taiwan show relatively low i sr 0 705 0 710 and high nd values implying that greater amounts of mantle components have been added to ancient continental material in the generation of these rocks this means that mesozoic magmatism in the coastal region resulted from subduction of a paleo pacific plate kula beneath the asian continent the overall geochemical evidence seems to be consistent with a model of serial collisions between microcontinental blocks for the bulk of the south china foldbelts the latest arc continent collision began about 4 ma ago in eastern taiwan

mineral chemistry trace elements and sr nd hf isotope geochemistry and petrogenesis of cailing and furong granites and mafic enclaves from the qitianling batholith in the shi hang zone south china abstract the shi hang zone is an important ne trending mesozoic magmatic belt composed of granites with relative high end t values and young tdm model ages in south china however the petrogenesis and the tectonic environment for the shi hang zone magmatic rocks remain controversial we report here mineral chemistry geochemical and sr nd hf isotopic data for the cailing and furong granites and mafic microgranular enclaves mmes from the qitianling granite batholith in southern hunan province south china the qitianling granite batholith is a multi staged composite pluton with three phases cailing furong and huangtangling according to their ages and petrography the cailing 163 160 ma and furong 157 153 ma phases are mainly composed of porphyritic amphibole biotite monzogranite and they share similar geochemical and isotopic characteristics both of them show similar sio2 contents from 66 50 to 70 28 and metaluminous a cnk values of 0 80 to 0 98 the granites are characterized by high contents of large ion lithosphile elements lile such as rb th u pb high field strength elements hfse such as nb ta zr hf and zr nb ce y contents 350 ppm and high 10 000 ga al ratios 2 6 chondrite normalized ree patterns show relative enrichment of light rare earth elements lrees and significant negative eu anomalies mineralogical and geochemical features suggest that the cailing and furong granites are a type which can be further classified as a2 subtype they have relatively lower 87sr 86sr i ratios 0 7091 0 7132 higher end t values 5 5 to 7 6 and younger nd isotopic model ages 1 48 1 56 ga than those common s type granites in south china zircon ehf t values vary from 8 1 to 3 7 the mmes in the cailing phase show similar trace element and sr nd isotopic characteristics with the host granites but zircons from the mmes show different ehf t values 6 4 2 6 with those from the host granites 8 1 to 3 7 this indicates that the mmes and host granites were crystallized from different sources of magmas providing direct evidence for mafic felsic magma mixing processes the isotope data indicate that the cailing and furong granites from the qitianling batholith were derived from a hybrid magma consisting of about 80 felsic magma derived from old crust and about 20 mantle derived mafic magma the strong magma mixing at about 160 155 ma caused by intra arc rifting or back arc extension related to subduction of the paleo pacific plate is favored to explain the petrogenesis of the cailing and furong granites as well as the shi hang zone

lithium isotope behaviour during partial melting of metapelites from the jiangnan orogen south china implications for the origin of ree tetrad effect of f rich granite and associated rare metal mineralization abstract we carried out combined nd and li isotopic studies on the neoproterozoic biotite granites late mesozoic evolved two mica muscovite granites and associated the shuangqiaoshan group metapelites from the jiangnan orogen south china which along with petrological and geochemical data were used to constrain the lithium isotopic behavior during partial melting of metapelites the origin of the ree tetrad effect in evolved granites and implications for related rare metal mineralization the neoproterozoic biotite granites show features typical of s types e g high a cnk ratios and have end 6 9 to 10 and 7li 2 2 4 comparable to the shuangqiaoshan group metapelites with end 6 to 11 and 7li 2 3 7 respectively suggesting that the biotite granites were derived from melting of the metapelites and the li isotopic fractionation during the melting process appears negligible the two late mesozoic shimensi and zengjialong granites occur as small stocks showing high silica peraluminous low cao and sr contents variably enrichment in volatiles f b and are accompanied by w cu and sn mineralization the shimensi granites have end t values of 7 0 8 6 and 7li 2 7 3 9 similar to the shuangqiaoshan group metapelites whereas the zengjialong granites have relatively high end t values 5 1 7 3 and heavy li isotopic features mostly 7li 0 18 1 53 and particularly ree tetrad effect is seen in the latter we argue that the late mesozoic evolved granites formed as a result of re melting of the granulitic residues left in the lower crust after extraction of the neoproterozoic biotite granites from the metapelites such re melting of the residues was triggered by underplating of basaltic magma with more mantle input and f b as well in the source of the zengjialong granites the elevated 7li values of the zengjialong granites were probably caused by intense interaction between melt and external fluids during magma emplacement which in turn resulted in the formation of the ree tetrad effect in the granites isotopic modeling suggests that fluid exsolution from evolved granites is minor and is less likely to have been responsible for the extensive rare metal mineralization as traditionally thought

geochemical factors revealing the differences between the xitian and dengfuxian composite plutons middle qin hang belt implications to the w sn mineralization abstract the xitian and dengfuxian ore fields located in the middle qin hang belt are known for hosting large scale w sn polymetallic deposits the xitian ore field hosts a series of small to large scale sn w deposits including skarn quartz vein and structurally altered rock type whereas the dengfuxian ore field mainly contains a medium scale quartz vein type w deposit these granitic rocks are composed of ore barren triassic and ore related jurassic granites in this study la icp ms zircon u pb dating of three representative samples from dengfuxian triassic granites dtg xitian jurassic granites xjg and dengfuxian jurassic granites djg yields weighted mean 206pb 238u ages of 231 2 2 5 ma 152 5 1 2 ma and 155 9 1 6 ma respectively chemical compositions of the xitian triassic granites xtg and dtg indicate that they belong to relatively lower fractionated granites whereas the xjg and djg are highly fractionated granites the xtg and dtg have similar lu hf isotopic compositions which have peak ehf t values of ca 5 9 and tdmc ages of ca 1 57 ga and peak ehf t values of ca 5 7 and tdmc ages of ca 1 57 ga respectively however the xjg have higher peak ehf t values of ca 5 4 and younger tdmc ages of ca 1 52 ga than those of the djg with peak ehf t values of ca 7 6 and tdmc ages of ca 1 70 ga respectively furthermore the xtg have end t values of 10 5 to 9 40 and nd model ages tdm2 of 1 86 to 1 76 ga which are similar to those of the dtg with end t values of 11 7 to 9 67 and nd model ages tdm2 of 1 95 to 1 79 ga wu et al 2016 cai et al 2015 the xjg have end t values of 11 0 to 9 1 and younger tdm2 ages of 1 69 1 84 ga which are fairly distinct to the reported nd isotopes of the djg cai 2013 it is proposed that the xtg and dtg were originated from the similar magma chamber and formed from partial melting of the proterozoic basement rocks of the south china block scb at low temperatures ca 690 c and oxygen fugacity log fo2 values of ca 17 involved with a certain amount of mantle derived magma magmas of the xjg and djg might be mainly originated from the partial melting of proterozoic basement rocks of the scb in contrast the formation of xjg and djg are involved with a considerable and little mantle derived magma respectively in addition the magma temperatures and log fo2 values of xjg are of ca 856 c and ca 15 respectively which are higher than those of the djg ca 716 c and ca 17 that the xitian and dengfuxian triassic granites did not induce w sn mineralization is likely attributed to their low fractionated signatures the key factors leading to the sn w mineralization in the xitian ore field and w mineralization in the dengfuxian ore field might be magma source and temperature since additional sn could be provided by the mantle and or released by melting of those sn bearing minerals at high temperatures over than 780 c

the combined effects of water and fluorine on the viscosity of silicic magmas abstract the newtonian viscosity of water plus fluorine bearing silicate melt of haplogranitic composition hpg8 has been determined viscosities of hpg8 melt with addition of 3 11 and 4 25 wt of f and up to 3 wt h2o have been obtained using a micropenetration technique in the interval 109 74 to 1011 84 pa s and temperatures varying from 370 to 700 c at ambient pressure determination of the temperature dependence of viscosity from this and previous studies permits the parameterization of the viscosity of melts containing water and fluorine having similar composition within a 0 3 log units standard error the viscosity of water bearing f rich haplogranitic samples is represented by a modified vogel fulcher tammann vft equation which provides a non arrhenian description of the temperature dependence of the viscosity the results of this study indicate that taken individually or together both h2o and f have a strong and similar effect on the viscosity of sio2 rich compositions this similarity between f2o 1 and h2o greatly simplifies the task of predicting viscosity for volatile rich highly silicic magmas the low viscosities of hydrous fluorine bearing granitic melts favour efficient crystallization fractionaction paths for these liquids controlling degassing paths and consequently the eruptive behaviour numerical simulations of eruptive events normally do not take into account the contribution of fluorine this may introduce a significant error in the description of the fluid dynamic properties of magma and therefore in the accurate prediction of eruptive scenarios as well as in hazard assessment studies fluorine unlike water remains dissolved in the melt at high concentrations and low confining pressures the incorporation of fluorine data and the modelling of fluorine bearing viscosity data are therefore of fundamental importance for simulations of magma dynamics and prediction of eruptive scenarios

origin of mafic enclaves from the taihang mesozoic orogen north china craton abstract the origin of mafic enclaves in intermediate and felsic granitoids has long been debated in this paper petrological and geochemical analyses whole rock geochemistry nd sr and zircon in situ hf isotopic compositions are used to address this controversial issue mafic enclaves in the taihang felsic plutons north china craton are fine grained and show typical magmatic textures they occur as rounded to ellipsoidal globules and are sometimes highly elongated without solid state deformation due to stretching within the partially crystallized convective felsic magma such occurrence suggests that the mafic enclaves and host rocks represent two co existing compositionally distinct magmas the mafic enclaves contain abundant hydrous phases hornblende and biotite and show the reaction relationship of clinopyroxene being rimmed by hornblende they also contain plagioclase xenocrysts showing compositional and textural disequilibrium in terms of nd hf isotopes mafic enclaves have end t values of 10 to 15 and host rocks have lower values as a whole 13 to 18 zircons from a single enclave show a large variation in hf isotopic compositions ehf t 5 to 20 a model is proposed whereby an evolved basaltic magma first mixed with a granitic magma of crustal origin at depth and then the mixed magma broke up into discrete globules upon entering the felsic magma chamber forming enclaves by convective motion or forceful injection in the host felsic magma this was followed by a double mechanical transfer of plagioclase crystals at the contact of the two magmas and by the diffusion of mobile elements e g si alkalis p y yb pb from felsic magma to enclave forming magma

fluorite stability in silicic magmas recent experimental evidence is used to assess the conditions under which fluorite forms an early crystallising phase in silicic magmas fluorite solubility primarily depends on the na k al balance in the coexisting silicic melt reaching a minimum in metaluminous melts it can display reaction relationships with topaz and titanite depending on changes in melt composition during crystallisation an empirical model of fluorite stability in ca poor peralkaline rhyolite melts is derived and applied to selected rocks text f text melt left text wt right left left text na text k text al right left 2 1110 3 text t left circ c right 1 5778 right right 2 789

unusually dumbbell shaped guposhan huashan twin granite plutons in nanling range of south china discussion on their incremental emplacement and growth mechanism abstract the guposhan huashan twin plutons crop out as an unusually dumbbell shaped batholith within the middle mesozoic central nanling range granitic belt in south china the batholith was controlled by the east west striking yishan quannan deep crustal fault zone and spatially associated with two regional anticlinoria both plutons show concentric zonation patterns and are composed of two emplacement sequences separated by an approximately 9 m y magmatic lull the 160 163 ma niumiao lisong wanggao sequence and the 148 151 ma xinlu huamei sequence based on field mapping and observations geochronology and geochemistry in a proposed incremental emplacement and growth model the early magmas exploited physical discontinuities such as the contacts between rocks with contrasting competence and densities as well as saddles of regional scale anticlinoria assisted by dominant vertical heat flow and uplifting of the roofs the niumiao lisong wanggao sequence magmas were subsequently emplaced in an over accretion style as distinguishable increments during an approximately 3 m y span gravimetric data observations of field relationships as well as analysis of finite strain and country rock rheology confirm that the plutons became thickened considerably due to largely vertical assembling and growth and most of their space was created by vertical displacement of their country rocks interestingly the coeval twin plutons show contrasting development and growth modes during their assembling and thickening process the guposhan pluton was built on an outward building mode with a reverse zoning pattern while the huashan pluton on an inward building mode with a normal zoning pattern we propose that the contrasting modes largely resulted from their divergent thermal evolution path for example the incremental inward building mode helps retain thermal energy and maintain a high temperature in older units which facilitates injection of subsequent younger increment units of the same sequence within the older host units the independent newer sequence of xinlu huamei magmas however were controlled by shallow brittle faults developed in the older sequence units and emplaced as stocks and dykes by a dyke propagation mechanism

the lanthanide tetrad effect and its correlation with k rb eu eu sr eu y ho and zr hf of evolving peraluminous granite suites lanthanide tetrad effects are often observed in ree patterns of more highly evolved variscan peraluminous granites of mid eastern germany central erzgebirge western erzgebirge fichtelgebirge and northern oberpfalz the degree of the tetrad effect te1 3 is estimated and plotted vs k rb sr eu eu eu y ho and zr hf the diagrams reveal that the tetrad effect develops parallel to granite evolution and significant tetrad effects are strictly confined to highly differentiated samples mineral fractionation as a cause for the tetrad effect is not supported by a calculated rayleigh fractionation which also could not explain the fractionation trends of sr eu and eu eu the strong decrease of eu concentrations in highly evolved rocks suggests that eu fractionates between the residual melt and a coexisting aqueous high temperature fluid mineral fractionation as a reason for the tetrad effect is even more unlikely as ree patterns of accessory minerals display similar tetrad effects as the respective host rocks the accessory minerals inherit the ree signature of the melt and do not contribute to the bulk rock tetrad effect via mineral fractionation these results point in summary to significant changes of element fractionation behavior in highly evolved granitic melts ionic radius and charge which commonly control the element distribution between mineral and melt are no longer the exclusive control the tetrad effect and the highly fractionated trace element ratios of y ho and zr hf indicate a trace element behavior that is similar to that in aqueous systems in which chemical complexation is of significant influence this distinct trace element behavior and the common features of magmatic hydrothermal alteration suggest the increasing importance of an aqueous like fluid system during the final stages of granite crystallization the positive correlation of te1 3 with bulk rock fluorine contents hints at the importance of ree fluorine complexation in generating the tetrad effect as the evolution of a ree pattern with tetrad effect m type implies the removal of a respective mirroring ree pattern w type the tetrad effect identifies open system conditions during granite crystallization

origin of the fluorine rich highly differentiated granites from the qianlishan composite plutons south china and implications for polymetallic mineralization abstract many composite granite plutons occur in south china accompanied by large scale polymetallic mineralization each composite pluton is composed of main phase granite and late stage highly differentiated granite traditionally the highly differentiated granite is thought to be residual melt of the former via fractionation and ore forming materials and fluids are from granite magma itself we propose a different model for the origin of the granites and related mineralization based on petrological and geochemical studies on the qianlishan composite plutons that host the supergiant shizhuyuan w sn bi mo deposit the main phase granite shows features of normal granites while the highly differentiated granite is characterized by f rich water deficient low f o 2 alkalinity ree tetrad effect and modified behavior of some trace elements e g very high k ba and low k rb and zr hf ratios we suggest that the parent magma of the highly differentiated granite was derived from melting of dominantly lower crustal rocks triggered by underplating of a new pulse of basaltic magmas small amounts of basaltic magmas and volatiles such as fluorine were involved in the source of the granite addition of fluorine lowered the solidus temperature and viscosity of granite magma and thus prolonged the process of magma evolution this resulted in extreme fractional crystallization and intense interaction between melt and circulating waters from country rocks forming the unusual geochemical features of the granite the high temperature circulating waters along with metamorphic fluids released from deep crustal rocks subsequently extract ore forming metals from country rocks through forming f bearing complexation forming the polymetallic deposits

age and thermal history of eo and neohimalayan granitoids eastern himalaya abstract four distinct granitoid suites outcrop across a n s transect in the eastern himalaya between the main central thrust mct and the indus tsangpo suture the arunachal and tsona leucogranites outcrop respectively in the mct hanging wall and adjacent the south tibetan detachment both crystallized at about 19 ma and appear to be lateral equivalents of the high himalayan leucogranites in the central tethyan himalaya the dala granitoids form a suite of undeformed plutons emplaced into deformed tethyan himalayan sequence metasediments in the northern tethyan himalaya the yala xiangbo granitoids are part of an igneous complex in the core of the yala xiangbo dome both the dala and yala xiangbo granitoids have eocene magmatic ages 44 1 1 2 ma and 42 5 ma respectively that are notably older than the vast majority of post collisional granitoids along the main himalayan arc pelitic units from the core of the yala xiangbo dome record two episodes of amphibolite grade metamorphism and monazite growth coinciding with well documented episodes of eohimalayan and neohimalayan metamorphism the thermochronological histories of the dala and yala xiangbo units suggest that the eastern tethyan himalaya was tectonically quiescent from ca 40 ma until ca 15 ma miocene exhumation of the dala and yala xiangbo units and all north himalayan domes studied to date appears best explained by a structural control such as concurrent north directed motion on the great counter thrust we hypothesize that an extension of the ninety east ridge may have been responsible for eocene high heat flow beneath the eastern himalaya and explain the localization of magmatism there

episodic growth of the gondwana supercontinent from hafnium and oxygen isotopes in zircon it is thought that continental crust existed as early as 150 million years after planetary accretion but assessing the rates and processes of subsequent crustal growth requires linking the apparently contradictory information from the igneous and sedimentary rock records for example the striking global peaks in juvenile igneous activity 2 7 1 9 and 1 2 gyr ago imply rapid crustal generation in response to the emplacement of mantle super plumes rather than by the continuous process of subduction yet uncertainties persist over whether these age peaks are artefacts of selective preservation and over how to reconcile episodic crust formation with the smooth crustal evolution curves inferred from neodymium isotope variations of sedimentary rocks detrital zircons encapsulate a more representative record of igneous events than the exposed geology and their hafnium isotope ratios reflect the time since the source of the parental magmas separated from the mantle these model ages are only meaningful if the host magma lacked a mixed or sedimentary source component but the latter can be diagnosed by oxygen isotopes which are strongly fractionated by rock hydrosphere interactions here we report the first study that integrates hafnium and oxygen isotopes all measured in situ on the same precisely dated detrital zircon grains the data reveal that crust generation in part of gondwana was limited to major pulses at 1 9 and 3 3 gyr ago and that the zircons crystallized during repeated reworking of crust formed at these times the implication is that the mechanisms of crust formation differed from those of crustal differentiation in ancient orogenic belts

isotopic and paleomagnetic constraints on the mesozoic tectonic evolution of south china in order to better constrain the paleogeographic evolution of south china we measured sm nd and rb sr isotopic compositions for 23 mesozoic granites that crop out throughout the area tightly grouped neodymium depleted mantle model ages 1 4 0 3 ga suggest the region is underlain by relatively homogeneous proterozoic crust and fail to define crustal provinces neither the isotopic nor geologic data suggest that a mesozoic suture exists however granites possessing anomalously high sm 8 ppm and nd 45 ppm concentrations relatively high initial epsilon neodymium 4 to 8 and high but variable initial 87sr 86sr 0 759 to 0 713 form a northeast trending zone that coincides with two prominent mesozoic basins southeast of the zone lie the majority of mesozoic intrusives and upper triassic to lower cretaceous extensional basins found in south china mesozoic paleomagnetic poles are well clustered northwest of the zone pre cretaceous poles southeast of it are discordant with respect to those from the northwest the only recognized tectonostratigraphic terrane in south china lies southeast of the zone the terrane is bordered by a northeast trending sinistral fault that was active in the mesozoic other faults in south china have similar attitudes ages and sense of shear together the observations suggest that the mesozoic tectonic regime in south china consisted of strike slip activity plus concomitant rifting as terranes or fragments of similar crust were transported north along sinistral faults the zone defined by the granites enriched in nd and sm demarcates displaced terranes to the southeast from relatively stable land to the northwest

trace elements u pb ages and hf isotopes of zircons from mesozoic granites in the western nanling range south china implications for petrogenesis and w sn mineralization abstract the e w trending nanling range located in the southern part of the south china block scb is characterized by widespread intra continental mesozoic granitoids and accompanying w sn polymetallic ore deposits detailed studies are presented on trace elements u pb ages and lu hf isotopes in zircons from the mesozoic a2 type like granitoids including the qianlishan qitianling xianghualing huashan guposhan niumiao tong an jinziling and jinjiling plutons from the western nanling range la icp ms u pb analyses of zircon indicate that these granites intruded mainly from ca 160 150 ma two types of zircon magmatic and late magmatic hydrothermal with similar ages can be distinguished based on their zircon trace element compositions the late magmatic hydrothermal zircons have high contents of metallogenic elements e g w and sn and may be closely related with the ore deposits the ehf t values of zircons from the mesozoic granitoids are mildly negative to positive indicating the reworking of both old and young crustal components the significant involvement of mesozoic juvenile mantle derived materials in the source can be excluded because of the rare occurrences of mafic rocks with radiogenic isotopic signatures in the area the average crustal residence age patterns of the mesozoic granites in the western nanling range are similar to those of the neoproterozoic magmatic rocks in the eastern part of the jiangnan orogen which may represent the neoproterozoic collisional belt between the yangtze and cathaysia blocks considering the specific isotopic and metallogenic features of the mesozoic granitoids in the study area we propose that the western nanling range may represent a western extension of neoproterozoic arc continent collisional belt in south china the mesozoic granitoids of this area may have been generated mainly by reworking of deeply buried neoproterozoic arc related volcanic sedimentary materials due to thermal perturbations triggered by the subduction of the paleo pacific plate in mesozoic time

partial melting of two amphibolites contrasting experimental results under fluid absent conditions a large portion of the lower continental crust may be amphibolitic in composition and without a free fluid phase as a consequence h2o undersaturated or fluid absent melting of amphibolites may be responsible for the formation of some granites and migmatites produced during major orogenic events in an attempt to determine the systematics of melting under fluid absent conditions a series of piston cylinder experiments was conducted on two natural amphibolites one a meta alkali basalt aba with a total water content of wt contained in hornblende and the other a meta island arc tholeiite iat which has 1 1 3 wt water contained in hornblende cummingtonite and biotite the experimentally determined melting ranges of the two amphibolites showed that the solidus temperatures and sta temperature interval over which amphibole was stable were controlled by the amphibolites different bulk compositions and their resulting metamorphic assemblages the volume of melt produced by melting of the two amphibolites were compared with estimated amounts based on burnham s 1979 water melt solubility model and the fluid absent melting model presented by clemens and vielzeuf 1987 the observed melt volumes were greater than estimated as the water content of melt largely detemines the volume of melt produced independent measurements of the water content of the glass formed during partial melting in the aba were made by thermogravimetric analyses the water content of the aba glass is 2 wt which is less than the assumed melt water content water content of the melt used in previous modeling of fluidabsent anatexis in mafic lithologies as a consequence more melt can be expected during fluid absent partial melting of mafic lower crust as is observed in the experiments a modification of the clemens and vielzeuf 1987 fluid absent melting model for mafic compositions has been made using the experimental data available on melting in basaltic systems and is presented here for pressures of 5 8 and 10 kbar tectonic scenarios in which the crust is thickened i e by collision then undergoes extension or where a previously thinned crust is later rethickened provide enough heat so that amphibolite melting under fluid absent conditions can become importan and hence responsible for some melts produced during post collisional magmatism the results may also have applications to melting in hydrated oceanic crust in subduction zones and in island arc terains

mesozoic tectonic evolution of the southeast china block new insights from basin analysis abstract in order to better understand the mesozoic tectonic evolution of southeast china block secb in short this paper describes geological features of mesozoic basins that are widely distributed in the secb the analyzed data are derived from a regional geological investigation on various mesozoic basins and a recently compiled 1 1 500 000 geological map of mesozoic cenozoic basins two types of basin are distinguished according to their tectonic settings namely the post orogenic basin type i and the intracontinental extensional basin type ii the latter includes the graben and the half graben or faulted depression basins our studies suggest that the formation of these basins connects with the evolution of geotectonics of the secb the post orogenic basin type i was formed in areas from the piedmont to the intraland during the interval from late triassic to early jurassic and the formation of the intracontinental extensional basin type ii connects with an intracontinental crustal thinning setting in the late mesozoic the graben basin was generated during the middle jurassic and is associated with a bimodal volcanic eruption and the half graben or faulted depression basin filled mainly by the rhyolite tuff and sedimentary rocks during early cretaceous is occupied by the late cretaceous paleogene red colored terrestrial clastic rocks we noticed that the modern outcrops of numerous granites and basins occur in a similar level and the mesozoic granitic bodies contact with the adjacent basins by large normal faults suggesting that the modern landforms between granites and basins were yielded by the late crustal movement the modern basin and range framework was settled down in the cretaceous abundant sedimentary structures are found in the various basins from that the deposited environments and paleo currents are concluded during the late triassic early jurassic time the source areas were situated to the north and northeast sides of the outcrop region in this paper we present the study results on one geological and geographical separating unit and two separating fault zones the wuyi orogenic belt is a late mesozoic paleo geographically separating unit the ganjiang fault zone behaves as the western boundary of early cretaceous volcanic rocks and the zhenghe dapu fault zone separates the se china coastal late mesozoic volcanic sedimentary basins and the wuyi orogenic belt finally we discuss the geodynamic mechanisms forming various basins proposing a three stage model of the mesozoic sedimentary evolution

chemical and isotopic evidence for major mass transfer between mafic enclaves and felsic magma abstract in both the strontian and criffell zoned granitoid plutons certain chemical elements notably k rb ca sr and pb display a correlation between their concentration in microdiorite enclaves and their concentration in the immediately enclosing host granitic rock this appears to represent the effects of post incorporation mixing and exchange between the enclave and its host magma enclave initial 87 sr 86 sr ratios are indistinguishable from those of the host while enclave initial 143 nd 144 nd ratios are systematically more radiogenic establishing that these enclaves are not melt segregations nor restite the isotopic data are in agreement with the chemical data in indicating that sr is almost entirely derived from the host despite clear evidence of major mass transfer of alkali metals alkali earths and transition metals a comparison of the concentrations and ratios of hfse and ree and nd isotopic ratios with those of a number of potential starting protoliths allows the enclave precursors to be positively discriminated in this regard enclave hfse and ree compositions may allow for models of granitoid production by the injection of hot mantle derived magmas into the crust to be tested

a complex magma mixing origin for rocks erupted in 1915 lassen peak california the eruption of lassen peak in may 1915 produced four volcanic introduction rock types within 3 days and in the following order 1 hybrid magma mixing is an important process among interblack dacite lava containing 2 undercooled andesitic inclusions mediate magmas in volcanic arcs e g turner 3 compositionally banded pumice with dark andesite and light campbell 1986 philpotts 1990 and references therein dacite bands and 4 unbanded light dacite all types represent laboratory studies of synthetic analogs of silicate magma stages of a complex mixing process between basaltic andesite systems and mathematical modeling of mixing viscous and dacite that was interrupted by the eruption they contain liquids have suggested a range of possible mixing mechdisequilibrium phenocryst assemblages characterized by the coanisms e g cashman bergantz 1991 however use existence of magnesian olivine and quartz and by reacted and of these results to interpret magmatic systems is limited unreacted phenocrysts derived from the dacite the petrography and by the applicability of synthetic analogs to magmatic crystal chemistry of the phenocrysts and the variation in rock conditions and by the imprecise knowledge of the effective compositions indicate that basaltic andesite intruded dacite magma viscosity of silicate liquid crystal mixtures at magmatic and partially hybridized with it phenocrysts from the dacite magma temperatures and pressures if magmas mix incompletely were reacted cooling crystallization and vesiculation of the hybrid i e mingle features such as compositional banding or andesite magma converted it to a layer of mafic foam the decreased undercooled inclusions are usually apparent but if they density of the andesite magma destabilized and disrupted the foam mix completely mineralogical disequilibrium may be the blobs of foam rose into and were further cooled by the overlying dacite magma forming the andesitic inclusions disaggregation of only direct evidence for a mixing origin andesitic inclusions in the host dacite produced the black dacite and if the thermal and compositional contrasts between light dacite magmas formation of foam was a dynamic process two magmas are great and the ratio of silicic to mafic removal of foam propagated the foam layer downward into the magma is large there is little interaction between them hybrid andesite magma eventually the thermal and compositional and the mafic magma is undercooled e g bacon 1986 contrasts between the hybrid andesite and black dacite magmas were many undercooled inclusions contain reacted phereduced then they mixed directly forming the dark andesite magma nocrysts inherited from their host silicic magma heiken about 40 50 andesitic inclusions were disaggregated into the eichelberger 1980 and bacon 1986 pointed out host dacite to produce the hybrid black dacite thus disaggregation that undercooled inclusions are typically formed from of inclusions into small fragments and individual crystals can be hybrid magmas in general the formation of undercooled an efficient magma mixing process disaggregation of undercooled inclusions retards further mixing sakuyama 1984 inclusions carrying reacted host magma phenocrysts produces cothompson dungan 1985 sparks marshall 1986 existing reacted and unreacted phenocryst populations koyaguchi blake 1991 however fragmentation and or disaggregation of undercooled inclusions plays an important role in hybridization in some magma systems thompson dungan 1985 coulon et al 1986 clynne christiansen 1987 clynne 1989 linneman myers

tracing magma mixing in granite genesis in situ u pb dating and hf isotope analysis of zircons in situ zircon u pb and hf isotopic data have been determined for mafic microgranular enclaves and host granitoids from the early cretaceous gudaoling batholith in the liaodong peninsula ne china in order to constrain the sources and petrogenesis of granites the zircon u pb age of the enclaves 120 1 ma is identical to that of the host monzogranite 120 1 ma establishing that the mafic and felsic magmas were coeval the hf isotopic composition of the enclaves ehf t 4 5 to 6 2 is distinct from the host monzogranite ehf t 15 1 to 25 4 indicating that both depleted mantle and crustal sources contributed to their origin the depleted mantle component was not previously revealed by geochemical and nd and sr isotopic studies showing that zircon hf isotopic data can be a powerful geochemical tracer with the potential to provide unique petrogenetic information some wall rock contamination is indicated by inherited zircons with considerably older u pb ages and low initial hf isotopic compositions hafnium isotopic variations in early cretaceous zircons rule out simple crystal liquid fractionation or restite unmixing as the major genetic link between enclaves and host rocks instead mixing of mantle derived mafic magmas with crustal derived felsic magmas coupled with assimilation of wall rocks is compatible with the data

application of the restite model to the deddick granodiorite and its enclaves a reinterpretation of the observations and data of maas et al 1997 mafic s type granites of the lachlan fold belt always contain a introduction distinctive suite of enclaves dominated by schists and gneisses of high maas et al 1997 have proposed complex models of metamorphic grade generally with lesser numbers of microgranular crustal melting and magma mixing to account for the enclaves maas et al 1997 journal of petrology 38 chemical and isotopic features of several kinds of enclaves 815 841 recently described enclaves from the s type deddick in the s type deddick granodiorite of the lachlan fold granodiorite they concluded that the metasedimentary enclaves belt lfb exposed at mckillops bridge that grancould be either source lithologies or accidental xenoliths and that odiorite is a member of the bullenbalong suite area the most common microgranular enclaves formed as globules of 3100 km white chappell 1988 itself part of the hybrid magma that mingled with the host magma all features of very extensive and slightly more diverse bullenbalong the metasedimentary enclaves are consistent with an origin as lithic supersuite total area 8750 km plus 4000 km of restite fragments from the source and their ubiquity in the mafic svolcanic rocks it occurs near the southern extremity of type granites and their rarity in both felsic varieties and in i type those granites these are the rocks that have been used granites conform with such an origin the argument that these as primary examples of restite and of the restite model enclaves are not in chemical equilibrium with the host granite in s type granites hine et al 1976 white chappell because they do not complement its composition is not valid as they 1977 chappell et al 1987 chappell 1996b and the represent less fertile parts of the source that did not melt to the point enclosed enclaves have been regarded by us as lithic of disaggregation unaltered cores of microgranular enclaves in the restite white chappell 1988 chen et al 1989 s type granites have compositions that do not match those of any chappell white 1991 white et al 1991 wyborn known igneous rock and an origin by metamorphism of a calcareous et al 1991 sediment is probable partial melting during that metamorphism maas et al 1997 mostly reject the presence of restite accounts for the pseudo igneous textures seen in these enclaves enclaves in the deddick granodiorite however the

vapor absent melting at 10 kbar of a biotite and amphibole bearing tonalitic gneiss implications for the generation of a type granites vapor absent melting experiments on a biotite and amphibole bearing archean tonalitic gneiss agc150 at 10 kbar and 875 to 1050 c show that amphibole breaks down from 900 to 950 c producing garnet orthopyroxene and granitic melt biotite dehydration melting produces 10 wt melt up to 950 c via incongruent melting reactions that produce garnet orthopyroxene and titanomagnetite widespread biotite dehydration melting occurs between 950 and 975 c and produces orthopyroxene magnetite titanomagnetite and 20 wt fluorine rich melt up to 0 31 wt f minor f rich 2 7 wt biotite is present even at 1000 c our experiments show that under vapor absent conditions intrusion of hot mantle derived magmas into the lower crust is necessary to initiate widespread biotite dehydration melting in rocks with compositions like agc150 we propose that the high thermal stability of biotite in agc150 suggests that this rock is residual after a previous episode of partial dehydroxylation that left behind somewhat f enriched biotite we show that dehydration melting of such f enriched biotite produces f rich granitic liquids with compositions within the range of a type granite and leaves behind a granulitic residue consisting of orthopyroxene plagioclase quartz titanomagnetite and magnetite

constraints of in situ zircon and cassiterite u pb molybdenite re os and muscovite 40ar 39ar ages on multiple generations of granitic magmatism and related w sn mineralization in the wangxianling area nanling range south china abstract the nanling range in south china hosts numerous w sn rare metal deposits associated with several cycles of polygenetic granitic intrusions in the wangxianling area of the middle nanling range igneous intrusions include the wangxianling and hehuaping granite plutons and more than 20 granite porphyry dykes the wangxianling pluton has a central phase of medium grained tourmaline two mica granite and a marginal phase of medium grained tourmaline muscovite granite the pluton hosts several tungsten deposits including shuiyuanshan and yejiwo mineralization type is dominantly scheelite greisen with subordinate scheelite skarn and wolframite quartz veins the hehuaping pluton composed of coarse grained biotite granite and granite porphyry dykes to the east of the wangxianling pluton have an associated hehuaping tin deposit with tin skarn and subordinate porphyry and greisen mineralization in situ zircon and cassiterite u pb dating molybdenite re os and muscovite 40ar 39ar dating techniques are used to refine the age spectra of granitic rocks and w sn mineralization in the wangxianling area granites of the wangxianling pluton have zircon u pb ages of 224 ma tungsten bearing quartz veins from both the shuiyuanshan and yejiwo tungsten deposits have an average molybdenite re os isochron age of 224 ma and muscovite of scheelite greisen from the shuiyuanshan tungsten deposit yields a 40ar 39ar plateau age of 214 ma the two mineralization ages are consistent with the zircon u pb age of the wangxianling pluton indicating a close association between pluton emplacement and w mineralization in the late triassic both the hehuaping pluton and granite porphyry dykes have zircon u pb ages of 156 ma in situ la icp ms u pb dating of cassiterite in both the tin skarn and tin greisen yields an average age of 156 ma showing that the sn mineralization occurred at a similar time to the late jurassic granitic magmatism thus two mineralization events are identified in the wangxianling area and include an earlier w dominant mineralization event and a later sn dominant mineralization event the earlier event is related both spatially and temporally to intrusion of the late triassic s type wangxianling granite pluton whereas the later mineralization is associated both spatially and temporally with intrusion of the late jurassic hehuaping a2 type granite pluton and a2 type granite porphyry dykes

petrogenesis of the late mesozoic guposhan composite plutons from the nanling range south china implications for w sn mineralization voluminous granite plutons were emplaced in the late mesozoic in the nanling range south china accompanied by large scale polymetallic deposits most plutons are composite composed of major phase granites and highly differentiated late stage granites previous studies have proposed fractionation of both granite types and polymetallic deposits from a common magma we choose to study the ages chemistry and nd hf isotopes of the guposhan complex from the range and propose a different model for the origin of the granite and relationship with associated polymetallic mineralization in the nanling range the major phase granites of the guposhan complex contain medium coarse grained biotite granite and hornblende bearing biotite granite with mafic microenclaves mmes emplaced at 161 1 ma on the contrary the late stage granite is fine grained with apparent zircon ages of 154 3 ma the major phase granites show large variation in chemical compositions and in whole rock nd and zircon hf isotope ratios with end t 6 0 to 1 9 and ehf t 4 5 to 1 5 respectively we suggest that their origin is attributable to a magma mixing process between felsic magma derived from melting of proterozoic basement rocks and mantle derived mafic magma the mafic magma could be represented by the parental magma of the mmes within the plutons which have low sio2 high mgo and high end t values up to 1 8 the late stage granite shows end t and ehf t values similar to the major phase granites but are chemically more evolved sio2 75 80 more reduced and water deficient and in particular are fluorine bearing numerical geochemical modeling and the petrological data indicate that the late stage granite was produced during a new thermal event rather than being produced due to fractional crystallization of the earlier major phase granite the polymetallic deposits are genetically linked with the late stage granite we suggest that a break off of the flat subducted pacific slab beneath the cathaysia block in the late mesozoic resulted in the upwelling of asthenosphere and formation of basaltic magma that underplated and triggered partial melting of the basement rocks forming felsic melts and followed by mixing of the mafic and felsic magmas in an extensional regime

distribution and mobilization of sn in silicate minerals from the mesozoic shizhuyuan w dominated polymetallic deposit south china abstract although mobilization and concentration of elements in super large deposits have become hot topics in recent years studies of the mobilization of metals between minerals using in situ analyses are rare the shizhuyuan w dominated polymetallic deposit in south china is one of the largest non ferrous metal deposits in the world and contains large metal reserves of sn w bi and rare earth elements using laser ablation inductively couple plasma mass spectrometry la icp ms we analyzed trace elements in major silicate minerals and magnetite from granites and skarns of the shizhuyuan deposit tin concentrations of muscovitized biotite range from 196 to 558 ppm muscovite from 57 7 to 332 ppm chloritized biotite from 1 62 to 527 ppm k feldspar from 4 16 to 6 97 ppm kaolinized k feldspar from 1 15 to 9 38 ppm plagioclase from 1 87 to 5 09 ppm sericitic plagioclase from 2 53 to 28 7 ppm kaolinized plagioclase from 0 99 to 17 7 ppm epidote from 1199 to 3382 ppm garnet from 797 to 2860 ppm chloritized garnet from 72 5 to 2548 ppm chlorite from 19 6 to 159 ppm and magnetite from 23 7 to 872 ppm thus sn is mainly hosted in biotite muscovitized biotite garnet and epidote sn occurs as an isomorphous substitution and is predominantly associated with fe3 for fe3 poor minerals sn can isomorphously substitute al in the form of simple cation due to similar radius at the octahedral site such as in k feldspar and kaolinized k feldspar however sn cannot substitute al in the si o tetrahedrons therefore sn and al correlate different in different silicate minerals alteration of biotite to muscovite and chlorite can release a large amount of sn to the magmatic hydrothermal fluids which may be already enriched in sn during the formation of skarn deposits sn f complexes can be converted to cassiterite sno2 to free up f by hydrolysis a significant amount of sn enters the lattices of garnet and epidote therefore release of sn during alteration of garnet to chlorite in a retrograde stage of alteration may have contributed to the mineralization

why is probabilistic seismic hazard analysis psha still used abstract even though it has never been validated by objective testing probabilistic seismic hazard analysis psha has been widely used for almost 50 years by governments and industry in applications with lives and property hanging in the balance such as deciding safety criteria for nuclear power plants making official national hazard maps developing building code requirements and determining earthquake insurance rates psha rests on assumptions now known to conflict with earthquake physics many damaging earthquakes including the 1988 spitak armenia event and the 2011 tohoku japan event have occurred in regions relatively rated low risk by psha hazard maps no extant method including psha produces reliable estimates of seismic hazard earthquake hazard mitigation should be recognized to be inherently political involving a tradeoff between uncertain costs and uncertain risks earthquake scientists engineers and risk managers can make important contributions to the hard problem of allocating limited resources wisely but government officials and stakeholders must take responsibility for the risks of accidents due to natural events that exceed the adopted safety criteria

petrogenesis of mesozoic granitoids in the dabie uhp complex central china trace element and nd sr isotope evidence post collisional magmatism in the dabie orogen is characterized by the near contemporaneous intrusion of voluminous granitoids and minor mafic magmas in the late mesozoic 135 110 ma the granitoids are represented by three major batholiths in northern dabie zhubuyuan baimajian and tiantangzhai the largest zhubuyuan batholith comprises hornblende bearing intermediate rocks penghe suite and hornblende free granitic rocks huangbai suite the huangbai granites show limited variation in chemical composition but are highly variable in textures ranging from medium to coarse grained they have rather homogeneous sr and nd isotopic compositions with 87sr 86sr i 0 708 0 709 and end t 19 to 24 the penghe intermediate suite covers a wide spectrum of rock types including diorite monzodiorite quartz monzonite to monzogranitic rocks and all of them contain hornblende and mafic enclaves the existence of compositional and textural disequilibrium e g calcic and resorbed cores of plagioclase and the nature of chemical variation in these rock types indicate that magma mixing between an evolved mafic and a granitic magma was involved in their genesis fractional crystallization fc could have coupled with the process of magma mixing but with minor contamination by the upper continental crust during magma ascent isotopically the intermediate rocks show a variation in end t values from 13 7 to 18 while their 87sr 86sr i ratios vary from 0 7074 to 0 7088 the genesis and evolution of the dabie post collisional magmatic rocks may be summarized as follows intrusion of mantle derived mafic ultramafic magmas into thickened continental crust induced dehydration melting of the lower crust rocks with intermediate compositions and subsequent production of large amounts of granitic melts huangbai suite extensive interaction between the crustal and mantle derived melts through mixing produced a hybrid parental magma which subsequently underwent a fc process en route to higher crustal levels producing a wide variety of rock types as shown by the penghe intermediate rock suite injection of successive pulses of basic magma into upward mobile magma chambers could have resulted in the formation of the mafic enclaves as well as mafic dykes

u pb zircon geochemical and sr nd hf isotopic constraints on age and origin of jurassic i and a type granites from central guangdong se china a major igneous event in response to foundering of a subducted flat slab abstract the mesozoic geology of se china is characterized by widespread jurassic to cretaceous igneous rocks consisting predominantly of granites and rhyolites and subordinate mafic lithologies however the tectonic regime responsible for the inland jurassic granites remains controversial we report here u pb zircon ages geochemical and sr nd hf isotopic data for the nankunshan alkaline granite and the fogang granitic batholith in central guangdong mineralogical and geochemical features suggest that the fogang and nankunshan rocks are i and aluminous a type granites respectively shrimp u pb zircon analyses yield consistent ages ranging from 159 3 ma to 165 2 ma for four samples from the fogang batholith and an age of 158 5 ma for the nankunshan granite the fogang granites having i sr 0 7098 0 7136 e nd t 4 3 to 12 2 and e hf t 11 5 to 3 1 for the magmatic zircons were derived from paleoproterozoic mafic intermediate igneous protolith with minor addition of mantle derived magmas the nankunshan rocks have relatively lower i sr 0 706 0 708 higher e nd t 0 3 to 2 4 and e hf t 5 7 to 1 1 for the magmatic zircons and some oib like trace element ratios they were likely generated through extensive fractional crystallization of mantle derived alkaline parental magma associated with crustal assimilation these 160 ma i and a type granites in central guangdong were emplaced coeval with the widespread 165 155 ma i and a type granites and syenites following the initiation of intraplate basaltic and or bimodal igneous magmatism at 180 170 ma in the adjacent regions we interpret these jurassic igneous rocks as anorogenic magmatism formed during a major igneous event in response to foundering of an early mesozoic subducted flat slab beneath se china continent

jurassic intraplate magmatism in southern hunan eastern guangxi 40ar 39ar dating geochemistry sr nd isotopes and implications for the tectonic evolution of se china the mesozoic geology of se china is characterized by intensive and widespread magmatism however the tectonic regime that accounted for the mesozoic magmatism has been an issue with little consensus a comprehensive study of ar 40 ar 39 dating geochemistry and sr nd isotopes has been conducted on basalts from southern hunan and syenite intrusions from eastern guangxi three episodes of jurassic magmatism i e alkaline basalts of c 175 ma in age syenitic intrusions of c 160 ma and high mg basalts of c 150 ma are identified the older c 175 ma alkaline basalts are characterized by low sr i sr 0 7035 0 7040 and high nd epsilon nd t 5 to 6 isotopic compositions and oib like trace element patterns e g nb la 1 in contrast the younger c 150 ma high mg basalts have high sr i sr c 0 7054 and low nd epsilon nd t c 2 isotopic compositions and incompatible trace element patterns of arc affinity the c 160 ma syenitic intrusions display a relatively large range of sr and nd isotopic compositions i sr 0 7032 0 7082 epsilon nd t 5 5 to 4 1 with the qinghu syenites having the lowest i sr highest epsilon nd t and oib type incompatible trace element patterns analogous to the c 175 ma alkaline basalts such a secular variation in rock types and geochemical and isotopic characteristics reveals changes in melt segregation depth and mantle sources which are inferred to have resulted from the post indosinian orogenic lithosphere extension and thinning the c 175 ma alkaline basalts are suggested to have formed by small degrees of decompression melting of the astheno sphere or an enriched lithospheric mantle source accreted by asthenosphere derived melts during the initial extension the c 160 ma syenitic and c 150 ma high mg basaltic rocks mainly originated from the enriched lithospheric mantle that melted owing to a raised geotherm caused by lithosphere thinning this interpretation is at odds with the active continental margin related to the subduction of palaeo pacific plate but consistent with continental rifting and extension for the mesozoic of se china

zircon u pb and sm nd geochronology and geochemistry of the sn w deposits in the northern guposhan ore field nanling range southern china abstract the guposhan ore field located in the central part of the nanling range and close to the giant central south peninsula tin ore belt is well known for its large scale sn w mineralization and hosts a series of middle to large scale sn w deposits in this study medium to fine grained biotite granite outcropped in the mining area have zircon u pb ages of 162 8 1 3 ma mswd 0 54 and 162 7 1 2 ma mswd 0 66 respectively these zircon ages are consistent to the sm nd isotopic age of minerals garnet hornblende clinopyroxene and orthopyroxene from the skarn type ores which is 160 4 4 8 ma mswd 1 3 these granites are characterized by high content of sio2 k2o na2o and rees and high ga al ratios indicating that they belong to highly fractionated a type granites with high k calc alkaline and aluminous peraluminous signatures the zircon lu hf isotopes of these granites have ehf t values and tdmc ages of 2 66 to 1 71 and 1 32 1 38 ga respectively combined with the previous studies it was proposed that the magma was formed by the mixing of crust mantle components ca 50 and ca 50 respectively in addition magmas are characterized by low temperatures of ca 710 c and oxygen fugacity log fo2 values of 18 5 to 16 4 formation of these granites were likely related to an intraplate extensional tectonic setting triggered by roll back of the subducted paleo pacific plate beneath the south china block scb these granites are in favor of the sn w mineralization making the guposhan ore district a large scale sn w mineralization ore field in the nanling range

origin of peraluminous a type granites from appropriate sources at moderate to low pressures and high temperatures abstract four triassic plutons from south china exhibit compositional features of s type granites high a cnk values enriched sr nd isotopic compositions and high zircon 18o values but also of a type granites alkali rich and ferroan compositions high zr nb ce y contents and high ga al ratios the s type like features suggest a metasedimentary source however the exact anatectic processes are poorly known here phase equilibrium modelling on the melting of five representative metasedimentary rocks with contrasting compositions at 0 4 1 2 gpa and fmq 1 to fmq 1 indicate that the most likely source should have a composition of mg 1 14 k2o na2o 5 two neoproterozoic volcanic sedimentary rocks adjacent to the pags have compositions that match these requirements and modelled melts at p 0 8 gpa and t 850 c match the main compositional variables of the plutons this study highlights that source composition and anatectic p t conditions are the main factors controlling the generation of peraluminous a type granites

a genetic study of xinlu shuiyanba w sn orefield northeast guangxi situated at the southwestern outer contact zone of the middle yanshanian guposhan granite pluton in pinggui area of guangxi the xinlu shuiyanba w sn deposit is one of the representative w sn polymetallic orefields in the nanling range south china based on the data obtained from previous researches this paper has studied systematically petrochemistry rb sr isotopic age dating and fluid inclusion compositions of the quartz and the results show that the ages of the ore deposits are about 136 ma quite different from the age of the host granite of guposhan which was dated at 161 165 ma it is thus considered that there is no direct relationship between the granite emplacement and the ore formation there occurred an intrusion of a late small granite body at about 151ma in the southern part of guposhan granite pluton which was probably caused by the further rupture of the crust and the upwelling of mantle material the activity of associated mantle derived fluids stimulated the mobilization transportation and enrichment of w sn and other ore forming elements and resulted in the formation of the liuheao and lantoushan ore deposits as representative ones it is suggested that the ore deposits are controlled by late granite as well as favorable strata and structures and the ore materials were mainly derived from late granite researches on oxygen hydrogen and sulfur isotopes show that 18o values are 8 1 13 38 and 10 2 12 35 for liuheao and lantoushan ore deposits respectively and 34s values are 2 09 1 7 and 0 95 3 6 respectively indicating that ore forming elements were dominantly derived from the granite laser raman microprobe analyses show that co2 ch4 and h2o constitute the dominant part of the fluid inclusions in these ore deposits combined with other characteristics it is suggested that ore forming fluids were dominantly derived from the mantle in addition the fluid inclusions in the liuheao ore deposit have rich ch4 while those of the lantoushan ore deposit have abundant co2 probably implying the differences of their fluid source ore forming process and mineralization depth

shrimp u pb zircon geochronology and geochemistry of metavolcanic and metasedimentary rocks in northwestern fujian cathaysia block china tectonic implications and the need to redefine lithostratigraphic units abstract northwestern fujian province is one of the most important pre palaeozoic areas in the cathaysia block of south china metavolcano sedimentary and metasedimentary rocks of different types ages and metamorphic grades granulite to upper greenschist facies are present and previously were divided into several formations and groups tectonic contacts occur between some units whereas deformed unconformities have been reported between others new shrimp u pb zircon ages presented here indicate that the original lithostratigraphy and the old group and formation terminology should be abandoned thus the tianjingping formation was not formed in the archaean or palaeoproterozoic as previously considered but must be younger than its youngest detrital zircons 1790 ma but older than regional metamorphism 460 ma besides magmatic zircon ages of 807 ma obtained from metavolcano sedimentary rocks of the nanshan formation and 751 728 ma for the mamianshan group many inherited and detrital zircons with ages ranging from 1 0 to 0 8 ga were also found in them these ages indicate that the geological evolution of the study area may be related to the assembly and subsequent break up of the rodinia supercontinent the new zircon results poorly constrain the age of the mayuan group as neoproterozoic to early palaeozoic 728 458 ma and not palaeoproterozoic as previously thought many older inherited and detrital zircons with ages of 3 6 2 8 2 7 2 6 2 5 2 0 1 8 and 1 6 ga were found in this study a 3 6 ga detrital grain is the oldest one so far identified in northwestern fujian province as well as throughout the cathaysia block nd isotope tdm values of eight volcano sedimentary and clastic sedimentary rock samples centre on 2 73 1 68 ga being much older than the formation ages of their protoliths and thus showing that the recycling of older crust played an important role in their formation these rocks underwent high grade metamorphism in the early palaeozoic 458 425 ma during an important tectono thermal event in the cathaysia block