geochemistry of proterozoic volcanic and granitic rocks from the gold hill wheeler peak area northern new mexico abstract early proterozoic supracrustal and plutonic rocks from the gold hill wheeler peak area in northern new mexico define three populations amphibolite diorite tonalite hornblendite cumulus amphibolite and felsic volcanics and porphyries also present are mid proterozoic granites amphibolites are similar in ti zr cr ni and ree contents to young calc alkaline and arc basalts and diorites and tonalites are similar in composition to young andesites and to high al2o3 tonalites respectively felsic volcanics resemble young felsic volcanics from mature arc systems in their immobile element contents geochemical model studies suggest that the amphibolites hornblendites diorites and tonalites are related by progressive fractional crystallization of a hydrous parent tholeiite magma produced from partial melting of undepleted lherzolite amphibolites represent parent tholeiites modified by olivine removal hornblendite is an early solid residue comprised chiefly of hornblende clinopyroxene and olivine diorite and cumulus amphibolite represent respectively residual solid clinopyroxene plagioclase hornblende and liquid after 50 crystallization tonalite represents a residual liquid after 80 crystallization felsic volcanic rocks are produced by partial melting of a tonalite or diorite source with granulite facies mineralogy in the lower crust granites have a similar origin to felsic volcanics although requiring an inhomogeneous source with the presence of residual hornblende or garnet the calc alkaline igneous rocks in the gold hill wheeler peak area suggest the presence of an arc system in northern new mexico during the early proterozoic the fact that these rocks interfinger with and are overlain by mature clastic sediments favors a model in which a continental arc system is uplited eroded and buried by cratonic sediments from the north

lithophile elements in huronian low ti continental tholeiites from canada and evolution of the precambrian mantle abstract huronian basalts from central ontario canada dated at about 2450 ma and associated with an early rifting episode are classified as siliceous low ti nb tholeiites they display strong enrichment in large ion lithophile lile and light rare earth lree elements compared to modern oceanic lavas the tectonic setting and geochemistry resemble mesozoic rift related low ti flood basalts including the ferrar group of antarctica and the parana and equivalent etendeka volcanics of south brazil and namibia respectively high lile lree ratios are also similar to subduction related island arc tholeiites and it is suggested that enrichment of the huronian lithospheric mantle source occurred through ancient subduction of crustal material probably during formation and consolidation of the archean continental crust melting models suggest that huronian subcontinental mantle source compositions derived from least contaminated aphyric mafic end members had already undergone a complex evolution including withdrawal of archean basalts and hydrous enrichment in incompatible components despite several subsequent melting episodes and a second probably magmatic enrichment event however many aspects of the huronian source signature were preserved and appeared in later basaltic products of this mantle mass keweenawan volcanics for example dated at about 1100 ma preserve low p zr ti and hree abundances

characterization of hydraulic properties of rocks using probability of fluid induced microearthquakes the use of borehole fluid injections is typical for exploration and development of hydrocarbon or geothermal reservoirs such injections often induce small magnitude earthquakes the nature of processes leading to triggering of such microseismicity is still not completely understood here we consider induced microseismicity using as examples two case studies of geothermal reservoirs in crystalline rocks and one case study of a tight gas sandstone reservoir in all three cases we found that the probability of induced earthquakes occurring is very well described by the relaxation law of pressure perturbation in fluids filling the pore space in rocks this strongly supports the hypothesis of seismicity triggered by pore pressure moreover this opens additional possibilities of using passive seismic monitoring to characterize hydraulic properties of rocks on the reservoir scale with high precision

basinal and shelf sedimentation in relation to the archaean proterozoic boundary abstract in most countries the archaean proterozoic boundary has been designated as an unconformity between the oldest shelf type quartz arenites and a basement consisting of greenstone belts intruded by granitic rocks or high grade gneisses the quartz arenites have been characterized as shallow water shelf deposits and sediments in the greenstone belts as resedimented basinal wackes of volcanogenic origin radiometric ages for rocks of the canadian shield led to initial designation of the archaean proterozoic boundary as thus defined at about 2 5 ga subsequent age determinations have clearly established that a number of quartz arenites originally assigned to the proterozoic are 2 7 2 94 ga old e g witwatersrand and pongola supergroups of south africa to accommodate these old quartz arenites some have suggested that the arch aean proterozoic boundary should be regarded as diachronous embracing a span of time about equivalent to that of the phanerozoic however quartz arenites also are abundant in 3 2 3 5 ga old greenstone belts and high grade metamorphic terranes of south africa western australia and the u s a likewise large regions of basinal volcanogenic sediments occur in post 2 5 ga terranes this greatly expands the diachroneity of geological units that were initially regarded as either uniquely archaean or proterozoic we therefore recommend that chronometric and chronostratigraphic sense be retained for the archaean proterozoic boundary divested of the requirement for all quartz arenites to be proterozoic according to this analysis of the precambrian record shelf sediments have increased in abundance relative to basinal sediments through time but at different rates in different areas this change is attributable to progressive cratonization of shield areas a process that was strongly diachronous on a worldwide scale

an early proterozoic volcanic arc succession in southeastern wyoming the green mountain formation of early proterozoic age in the sierra madre range of southeastern wyoming comprises a bimodal mafic and felsic volcanic assemblage the rocks which are chiefly breccias agglomerates flows and volcaniclastic sediments represent both subaerial and submarine eruptions and in part were redeposited in fluvial and nearshore marine environments volcanic rocks are clearly calc alkaline in character and share a large number of geochemical features in common with continental margin arcs or evolved oceanic arc systems the low mg numbers and ni contents of the basalts require 30 40 olivine fractional crystallization and the high contents of the most incompatible elements high la sm n ratios and low zr nb ratios require an undepleted or enriched mantle source geochemical data are consistent with an origin for the felsic volcanics and associated encampment river granodiorite by shallow fractional crystallization of calc alkaline basalt in a tectonic setting similar to modern ar

early proterozoic oceanic crust in the northern colorado front range implications for crustal growth and initiation of basement faults 1 early proterozoic oceanic crust exposed in a shear zone in the northern colorado front range provides insight into the tectonic evolution of the colorado province tectonically intermingled mylonitic amphibolite locally pillowed metagabbro clinopyroxenite metachert and melange are preserved within the buckhorn creek shear zone west of fort collins whole rock geochemical data support formation of the igneous protoliths in an oceanic environment major and trace element data overlap samples from modern oceanic ridges and are distinct from modern arc trends metagabbros and clinopyroxenites preserve a subhorizontal lineation defined by igneous pyroxenes core and mantle microstructures indicate initial deformation at temperatures 900 c secondary amphiboles define both subhorizontal and subvertical lineations kinematic analysis indicates that the rocks experienced e w strike slip deformation prior to and during amphibolite facies metamorphism followed by n s shortening 40ar 39ar data from secondary hornblende yield age steps as old as 1 9 ga based on the chemical data and kinematic evidence for strike slip deformation we propose that the buckhorn creek rocks originated at an oceanic ridge transform intersection the high t pyroxene fabrics formed during ocean floor deformation prior to 1 7 ga regional deformation of the colorado province the buckhorn creek fragment likely represents original oceanic basement for 1 8 1 7 ga arc magmatism and sedimentation that ultimately formed the colorado province continental crust reactivation of original oceanic fracture zones may be responsible for the network of regularly spaced northeast trending shear zones in colorado once formed subvertical transform faults are likely to survive the transition from oceanic to continental crust and persist as long lived crustal discontinuities

a proterozoic volcano plutonic terrane gunnison and salida areas colorado early proterozoic supracrustal rocks near gunnison and salida colorado include tholeiitic basalt dacite to rhyolite and intercalated sedimentary rocks these were intruded by essentially synchronous gabbroic sheets folded and intruded by major plutons ranging from quartz diorite to granite preservation of primary volcanic and sedimentary features is good to excellent sedimentary rocks in the gunnison area are mostly turbidite wackes whereas near salida they are mostly near source volcaniclastic rocks u pb age measurements on zircons indicate that the earliest bimodal volcanic rocks erupted between 1770 and 1760 m y ago and were intruded by granitic plutons between 1760 and 1750 m y ago renewed bimodal volcanism occurred between 1740 and 1730 m y ago and was followed by a period of deformation producing two fold sets before 1725 m y ago when the first of a series of younger plutons was emplaced the compositions and features of the sedimentary rocks and their association with volcanics are con

early proterozoic bimodal volcanic rocks in central colorado u s a part i petrography stratigraphy and depositional history abstract early proterozoic metamorphic rocks of the salida area include two exceptionally well preserved sections of undeformed volcanogenic rocks a northern section nearly 4000 m thick and a southern section 1700 m thick the stratigraphic and lithologic character of the sections are the same indicating that they were formed contemporaneously in the same subaqueous environment the suite is strongly bimodal consisting of felsic volcaniclastic rocks 50 mafic volcanic and volcaniclastic rocks 22 and gabbro diabase sheets 23 the remaining rocks are mostly pelitic metasediments the felsic rocks which dominate the upper portions of both sections comprise four distinct facies crystal lithic tuff breccia crystal lithic lapilli breccia tuff bedded tuff and massive tuff lithic fragments are typically foreign dominated by pelitic material crystal clasts are feldspar mainly plagioclase and quartz sequences of these facies representing cycles of eruptive activity are uniform in thickness and extend along strike for the entire width of precambrian exposure up to 4 km but individual facies units especially the coarser ones are limited in their lateral extent individual sequences average about 100 m thick but continuous exposures of felsic rocks locally exceed 600 m primary sedimentary structures and vertical and lateral variations indicate deposition typically following remobilization as debris flows and turbidites in a shallow marine environment of low relief mafic volcanic and volcaniclastic rocks form accumulations up to 600 m thick and extend uniformly for several kilometers along strike although individual units are more restricted laterally the principal rock types are basalt flows basaltic lithic breccia pillow lava pillow breccia bedded basaltic lapillistone and laminated basaltic tuff all deposited in a submarine setting accumulations typically including several types are interbedded with felsic rocks but mechanical mixing of mafic and felsic volcaniclastics is rare suggesting separate eruptive centers for the mafic and felsic volcanics the northern section may be more proximal than the southern section as indicated by the greater abundance of flows the thicker sheets of gabbro and the greater abundance of mafic rocks relative to felsic rocks gabbro diabase sheets up to 350 m thick and dominantly concordant intrude throughout both sections they are characterized by lack of internal differentiation simple mineralogy consisting of plagioclase and hornblende pseudomorphous after pyroxene and sub ophitic texture the minor pelitic material indicates that the area was accessible to continental sediment sources although their location is not known the salida bimodal volcanic suite is part of a more extensive accumulation of similar 1700 1800 ma supracrustal rocks that extends west to the gunnison area and perhaps south into northern new mexico

1 700 myr greenstone volcanic successions in southwestern north america and isotopic evolution of proterozoic mantle 1 700 myr greenstone volcanic successions in southwestern north america and isotopic evolution of proterozoic mantle

origin of thick first cycle quartz arenite successions evidence from the 1 7 ga ortega group northern new mexico abstract the 1700 ma old ortega group in northern new mexico represents a 1000 m thick succession of metamorphosed quartz arenites and subordinate pelites published ages of detrital zircon grains from the ortega group indicate that the sediments were derived mainly from 1760 1700 ma old volcano plutonic basement rocks and not from the archean wyoming province to the north evidence for recycling within the ortega group also is lacking consequently the ortega group quartz arenites are considered to be first cycle sediments the compositional and textural maturity of these sandstones is attributed to intense chemical and mechanical weathering abnormally high al contents of pelites within the ortega group imply intense chemical weathering in the provenance similar to present day low relief tropical regions quartz arenites in the ortega group were deposited exclusively within a shallow marine shelf environment influenced by tide storm and wave processes prolonged sediment transport especially on the tide dominated inner shelf in conjunction with inferred gradual subsidence optimized mechanical destruction of labile grains and rounding of quartz grains although the maturity of sediments in the ortega group can be accounted for the mode of origin of 850 m of quartz arenites remains enigmatic thick quartz arenite sequences of global distribution in the phanerozoic coincide with first order eustatic sea level rises world wide occurrences of 1700 ma old thick quartz arenite shelf successions suggest that the ortega group may have accumulated in response to a similar major eustatic sea level rise

paleoproterozoic rocks of central colorado accreted arcs or extended older crust paleoproterozoic 1770 1735 ma bimodal volcanic rocks in central colorado have been considered to represent southward growth of laurentia by arc accretion although the bimodality of these rocks suggests an extensional continental setting rather than continental or oceanic arcs there has been little evidence for pre 1800 ma crust south of the wyoming craton other than the 1840 1 ma elves chasm pluton in the upper granite gorge of the grand canyon arizona we report shrimp u pb ages of inherited zircons from metarhyolites and plutons in central colorado that are latest archean earliest proterozoic 2520 2000 ma and trans hudson penokean 1878 1814 ma associated quartzites contain detrital zircons with mean ages of 1735 ma indicating only local derivation a meta arkose however contains detrital zircons of trans hudson penokean and archean ages we believe it likely that the 1900 1800 ma trans hudson penokean orogens including archean enclaves extended farther south and west than is currently thought and were the source of the bimodal volcanic rocks and associated plutons during the period 1770 1700 ma

petrological evolution of the crust and mantle in its simplest form crust mantle evolution can be thought of as a study of the processes by which material is lost from the mantle and forms new crust the overall goal is achievement of mass balance between the average composition of material known to have been added to the crust and the estimated average composition of the entire crust attainment of this goal for the earth has been elusive primarily because the materials available for study have generally been involved in several stages of evolution including fractionation within both the crust and mantle and recycling of material from crust to mantle thereby complicating the interpretation of available data although the overall composition of the continental crust generally has been modelled as andesitic taylor and mclennan 1981a the present upper continental crust is granodioritic and requires a more mafic lower crust it has been proposed taylor and mclennan 1981a that originally the archean crust had an andesitic composition throughout its volume and that partial melting in the lower crust developed more felsic melts that rose to enrich the upper crust leaving a more mafic residuum of lower crust this concept has been challenged by weaver and tarney 1981a who argue that the granulites of presumed lower crustal origin do not have the correct compositions for this model if one considers more recent additions to the crust from the mantle over the past several hundred million years it appears that these latest additions are basaltic with very little if any granitic additions in fact barker 1981 in his introduction to a special issue of jgr on granites and rhyolites states to date no one has demonstrated that such magmas may form in the mantle indeed much experimental and geochemical work indicates that such siliceous liquids cannot originate there therefore such magmas must be generated in the crust in island arc environments where the average composition of added material normally is thought to be andesitic a anderson 1982 has shown that the parent melt is basaltic not andesitic in addition kay 1980 has shown that the k content of the newly added material is less than the average k content of the previously existing crust in the oceanic crust the additions from the mantle are basaltic and according to o hara 1982 probably are derived from very mafic picritic melts as parents continental flood basalts which have also added material from mantle to crust also are clearly derived from basaltic parental melts basaltic volcanism study project 1981 thus the evidence for the nature of material subtracted from the mantle and added to the crust for the past several hundred million or perhaps a billion years points to very mafic melts this contrasts significantly with the overall andesitic composition of continental crust it implies furthermore that if the overall archean crustal composition was andesitic as estimated by taylor and mclennan 1981a then additions to the crust have become more mafic with time a concept in direct conflict with most models in which secular trends are from mafic to felsic with time veizer and jansen 1979 and mclennan et al 198o a question which is beginning to appear either explicitly or implicitly is whether crustal volcanic rocks or the crust as a whole really represents the parent melt that formed in the mantle a anderson 1982 o hara 1982 and nisbet and walker 1982

the influence of sediment recycling and basement composition on evolution of mudrock chemistry in the southwestern united states this paper reports systematic changes in mudrock composition through time on a single con tinental cmstal block the changes reflect both sediment recycling processes and changes through time in the composition of crystalline material being added to the sedimentary system and are related to tectonic evolution as the block matures from a series of accreted arc terranes to a stable craton the major and trace element distributions reflect different aspects of the provenance of the mudrocks in this study major elements record sediment recycling processes as well as changing proportions of sedi mentary and first cycle source rocks with the exceptions of kzo which tends to increase and sioz and a o3 which show no trend most major oxides tend to decline in relative abundance in younger mud rocks patterns shown by the index of compositional variability fe03 kro naao cao mgo mno tiojialro and by k20 a1203 indicate that the major oxide trends are due to decreasing proportions of nonclay silicate minerals and a concomitant increase in the proportion of clay minerals probably due to decreasing input of first cycle detritus coupled with recycling of sedimentary material excursions from progressive trends marked by increases in mgo k20 and cao reflect episodes of large scale input of nonclay first cycle minerals from crystalline source rocks due to large scale basement uplift the chemistry of low solubility trace elements in contrast is not sensitive to recycling effects and reflects the composition of first cycle input incompatible elements are progressively enriched relative to compatible elements in younger mudrocks and values for chondrite normalised rare earth elements also increase in addition the eu anomaly becomes systematically more negative in younger samples these trends cmnot be explained by diagenetic or weathering processes and therefore indicate that the proportion of fnc tionated granitic first cycle detritus being added to the sedimentary system becomes greater with time these results confirm the importance of tectonic setting in controlling mudrock chemistry and also demonstrate that there is a dynamic relationship between the tectonic evolution of a continental block and the composition of its sedimentary mantle

geology and geochemistry of huronian rhyolites and low ti continental tholeiites from the thessalon region central ontario bimodal volcanism associated with early phases of huronian rifting in central ontario dated about 2450 ma produced low ti tholeiitic basalts and two varieties of crustally derived calc alkaline rhyolite early tholeiites are characteristically highly evolved have mg values from 30 to 50 and display pronounced enrichment in large ion lithophile elements lile and light rare earth element lree in comparison with modern oceanic basalts fractionated heavy rare earth element hree patterns and low ti zr p nb ba and k abundances ti zr ratios rise progressively in early basalts and associated basaltic andesite fractionates from about 35 in early flows to 55 in central units late basalts also carry enriched lile and lree but in contrast to early types have average mg values greater than 50 and lower rare earth element ree abundances with flat hree patterns they also display negative ba nb and p anomalies on chondrite normalized distribution diagrams but lack low k zr and ti contents

the archean proterozoic transition evidence from the geochemistry of metasedimentary rocks of guyana and montana abstract chemical and isotopic compositions of ancient sedimentary rocks have in some cases provided evidence of first order changes yin the composition and extent of continental crust from the archean to the proterozoic we reversed the typical sampling pattern comparing metapelites and carbonates from proterozoic greenstone belts with those from an archean continental margin sequence and found the reverse of the typical age composition relations metapelites and volcaniclastic metagreywackes from the early proterozoic greenstone belts of northern guyana resemble those of many archean greenstone belts in ree trace and major element compositions mean ratios la sm 5 0 la th 5 1 eu eu 0 80 th u 3 4 median k 2 o na 2 o 0 8 schists from an archean continental marginal sequence in montana have compositions like many post archean metapelites derived from continental sources mean ratios la sm 6 8 la th 2 7 eu eu 0 67 th u 5 2 median k 2 o na 2 o 1 7 other archean continental basin sediments also resemble their post archean counterparts implying that upper continental crusts of these eras may not have differed significantly in these respects however temporal change may have occurred in upper crustal contents of ni and cr many archean clastic metasedimentary rocks of both continental and greenstone belt provenance have contents of these compatible elements higher than in their post archean equivalents dolomitic limestone from a greenstone belt of northern guyana has a very low 87 sr 86 sr ratio of 0 7007 such low values may reflect the local influence of mantle derived volcanic rocks during carbonate deposition diagenesis or metamorphism and they may not be reliable indicators of the evolution of sr in seawater archean dolomitic marbles from the continental marginal sequence of montana have 87 sr 86 sr ratios of 0 7065 and higher significantly more radiogenic than many accepted values for carbonates of archean greenstone belts

crustal evolution of southern laurentia during the paleoproterozoic insights from zircon hf isotopic studies of ca 1 75 ga rocks in central colorado lu hf depleted mantle model tdm ages obtained by analysis of zircons previously dated by u pb methods demonstrate that ca 1 75 ga bimodal paleoproterozoic rocks in the gunnison salida region of central colorado and by extension in much of the southwestern u s were formed by partial melting of preexisting crustal rocks the ages of which mostly ages greater than 2 0 ga indicate that range from 1 83 to 1 87 ga some calculated lu hf tdm even older crust was probably involved consistent with the limited presence of ca 2 5 ga xenocrystic zircons in some rocks these results suggest that rocks related to the trans hudson and penokean orogens are cryptically present much farther to the south than previously believed coupled with the bimodality of the volcanic suite in central colorado and indeed in much of the southwestern u s these results indicate that in contrast to current juvenile arc accretion models melting of older crust related to extensional tectonics played an important role in the genesis of many magmatic rocks between 1 6 and 1 8 ga

new models for paleoproterozoic orogenesis in the cheyenne belt region evidence from the geology and u pb geochronology of the big creek gneiss southeastern wyoming the disputed age of the deep crust of the colorado province is central to hypotheses for paleoproterozoic crustal growth in the region we studied the high grade big creek gneiss southeastern wyoming as a potential exposure of pre 1780 ma basement rocks new geologic mapping and u pb geochronological data indicate that the big creek gneiss exposes a deeper but coeval level of the green mountain arc relative to the predominantly supracrustal section to the west the big creek gneiss is composed of supracrustal rocks a ca 1780 ma green mountain arc correlative bimodal intrusive suite a ca 1763 ma extensional bimodal intrusive suite and widespread ca 1630 ma pegmatitic leucogranite the mafic member of the younger bimodal suite is documented here for the first time u pb zircon ages from migmatite leucosomes indicate penetrative deformation of the big creek gneiss at ca 1750 ma we find that the postarc intrusive suite is mantle involved implying a second period of crustal growth shortening postdates arc magmatism by 20 m y implying that termination of arc magmatism and accretion were separate events finally criteria previously used to constrain the polarity of subduction for the green mountain arc are not reliable we propose two competing models 1 southward dipping green mountain arc subduction present coordinates with slab breakoff related magmatism following arc accretion or 2 northward dipping subduction with extensional postarc magmatism in both models high temperature deformation coincides with accretion along the cheyenne belt and extensional magmatism is an important component of crustal growth we prefer the northward dipping subduction model because it can be better integrated with regional tectonic events and published isotopic compositions of the igneous rocks

subaqueous pyroclastic flows and ignimbrites an assessment an assessment of the literature on subaqueous pyroclastic flows and their deposits shows that the term pyroclastic flow is frequently used loosely to describe primary hot gas rich pyroclastic flows mass flows which resulted from the transformation of gassupported flows into water supported ones and secondary mass flows carrying redeposited pyroclastic debris based on subaerial pyroclastic flows the term pyroclastic flow should be restricted to demonstrably hot gas rich mass flows of pyroclastic debris using this definition very few examples of subaqueous pyroclastic deposits with evidence for hot emplacement and of having been wholly submerged have been described in the majority of these cases the evidence for a hot state of emplacement and for the subaqueous nature of the host depositional environment is inadequate the only unequivocal cases of hot pyroclastic flow deposits with adequate supporting evidence are the ordovician nearshore shallow marine ignimbrites of ireland and wales and miocene ignimbrites of southwest japan resulting from the passage of subaerially erupted pyroclastic flows into shallow water other possible examples are near vent dense clast deposits in the donzurobo formation of japan possible submarine intra caldera ponded ignimbrite successions in california and wales and near vent pumiceous deposits of ramsay island wales all other purported cases are either clearly the result of water supported mass flow transportation and deposition debris avalanches debris flows turbidity currents or lack adequate supporting evidence regarding the heat state or the palaeoenvironment only the shallow marine ignimbrites of ireland and wales show adequate evidence of welding but even these could have been nearly wholly exposed above sea level when welding occurred we conclude that when pyroclastic flows enter water they are generally disrupted explosively and or ingest water and transform into water supported mass flows and we suggest the various scenarios in which this occurs there is no evidence to suggest that welding in wholly subaqueous environments is common

geochemistry of the dubois greenstone succession an early proterozoic bimodal volcanic association in west central colorado abstract the dubois greenstone succession an early proterozoic supracrustal succession in west central colorado is composed of fine grained felsic volcaniclastic sediments ash flow tuffs and tholeiitic flows sills and dikes the volcanic rocks comprise a bimodal suite of tholeiite and rhyolite the tholeiites are divided into two groups group i exhibiting nearly flat ree patterns 20 30 chondrites and group ii with light ree enriched patterns 40 70 chondrites these groups can be produced by two stage melting of an undepleted or enriched garnet lherzolite source in which garnet remains in the residue of only the first melting stage which produces group ii magmas the felsic magmas can be produced by partial melting of a high grade gneiss in the lower crust in which zircon is entrained in the magma the dubois greenstone succession appears to have formed by felsic and mafic subaqueous eruptions in which some ash flows upon entering water underwent phreatomagmatic explosions giving rise to detritus which formed the volcaniclastic sediments although tectonic setting cannot be assigned to the succession with a high degree of confidence an immature back arc basin developed on sialic crust in consistent with most data

a comparison of acoustic and rock magnetic properties of equatorial atlantic deep sea sediments paleoceanographic implications compressional wave p wave velocities and magnetic susceptibilities were measured on gravity ggc and piston cores pc and ocean drilling program odp leg 108 advanced piston cores apc from the equatorial atlantic to test our hypothesis that climatically driven changes in terrigenous and biogenic fluxes and in carbonate dissolution control the interrelationships between the two signals in pleistocene sediments deposited above the calcium compensation depth ccd we observed changes in p wave velocity and magnetic susceptibility that are 1 inversely correlated and 2 coherent to changes in glacial interglacial climate glacials show low p wave velocities and relatively high magnetic susceptibilities in contrast interglacials show high p wave velocities and relatively low magnetic susceptibilities these temporal changes in p wave velocity and magnetic susceptibility reflect the climatic history recorded in the sediments and are related to 1 the production of biogenic carbonate mainly planktonic foraminifera and 2 the terrigenous sediment supply that contains magnetic minerals below the ccd this pattern disappears and consistently low p wave velocities and distinctly higher magnetic susceptibilities prevail the distinct decrease of large p wave velocity fluctuations is due to the dissolution of carbonate sediments which cause a distinct decrease in sand grain sizes and a consistently low carbonate content 10 dilution of magnetic material by the carbonate fraction is minor and the high magnetic susceptibility values and the relatively high amplitude variations in magnetic susceptibility are due to changes in the magnetic mineral concentration of the terrigenous non carbonate fraction in early pliocene sediments we also observed covarying velocity and magnetic susceptibility signals that may reflect a predominatly terrigenous control on sedimentation our preliminary results demonstrate that a combined use of non destructive measurements of acoustic and rock magnetic signals provides a potential paleoceanographic tool for characterizing 1 glacial interglacial pelagic sedimentation 2 pelagic sedimentation above the ccd 3 increases in carbonate dissolution and 4 areas below the ccd furthermore rock magnetic fluctuations in sediments below the ccd may provide an important stratigraphic tool for the deep carbonate free basins of the world s oceans

geochemistry and petrogenesis of early proterozoic amphibolites west central colorado u s a abstract early proterozoic supracrustal rocks exposed in west central colorado include amphibolites intimately associated with felsic volcanics and associated volcaniclastic sediments three successions are recognized the dubois succession 1770 1760 ma is comprised chiefly of amphibolites and felsic volcanics the amphibolites exhibit low concentrations of light ree and hfse and are broadly similar in composition to tholeiites from immature island arcs and in some respects to nmorb the cochetopa succession 1745 1730 ma includes large amounts of felsic volcanics and volcaniclastic sediments together with amphibolites that exhibit variable but slight incompatible element enrichment similar to basalts from evolved island arc systems and associated back arc basins the black canyon succession is coeval with the cochetopa succession and is comprised chiefly of volcaniclastic sediments with minor amphibolite these amphibolites exhibit significant incompatible element enrichment similar to basalts from continental margin arc systems geochemical modeling indicates that the amphibolites evolved by closed system fractional crystallization of depleted for the dubois succession to variably enriched parental basalts for the cochetopa and black canyon successions chiefly at shallow depths incompatible element distributions in the amphibolites indicate that mantle sources changed with time from relatively depleted 1770 1760 ma to variable but slightly enriched 1745 1730 ma a provisional model calls upon the dubois succession forming in an island arc system followed by collision with the archean wyoming province at 1750 ma the cochetopa succession was deposited in an intra arc basin developed within a new continental margin arc and the black canyon succession formed in a back arc basin associated with this arc