the stabilization of self organised leucogranite networks implications for melt segregation and far field melt transfer in the continental crust abstract net structured leucocratic vein systems are ubiquitous in high grade and migmatite terrains and are interpreted to represent interconnected former magma bearing structures that accommodated the migration of granitic magmas out of their anatectic source regions net structured leucogranite vein systems in high grade gneisses from the damara belt in namibia describe a size based hierarchy and spatial distribution that indicates self organisation of the magma transfer system the internal geometry and connectivity of the net structured leucogranites are controlled by variations in melt pressure whereas regional strains control the orientation of the leucogranites foliation parallel stromatic and shear band hosted granite veins accommodate transport at relatively low melt volumes and account for the metre scale segregation of melt close to the anatectic source during times of higher melt supply the formation of extensional fractures that cross cut stromatic and shear band hosted melt sheets at high angles is promoted extensional fracturing and associated dilatancy create gradients in magmastatic head that cause melt to be drained from pervasive stromatic and shear band hosted vein networks into spaced dilatant fractures this has the potential to initiate buoyancy driven far field melt transfer along suitably orientated extensional fractures as vertical dykes or self propagating hydrofractures our results suggest that melt transfer systems are able to adjust to variations in melt supply by forming conduits that accommodate varying melt volumes and will tend to develop towards a state of self organisation

experimental melting of biotite plagioclase quartz muscovite assemblages and implications for crustal melting abstract in order to understand the role of mica rich rocks as a source of granite magmas a series of melting experiments was performed on two different starting materials the first composition is a model biotite gneiss consisting of 30 wt biotite 30 wt plagioclase and 40 wt quartz the second composition is a model two mica pelites consisting of 15 wt biotite 15 wt muscovite 30 wt plagioclase and 40 wt quartz experiments were performed under vapor absent conditions at 1 0 gpa and between 750 o and 950oc with only biotite in the starting material the volume of melt is always less than 15 vol below 900oc and reaches 25 vol at 950oc in experiments that involve both biotite and muscovite in the starting material the melt proportion increases up to 28 vol at 825oc and reaches 60 vol at 950oc for the biotite plagioclase quartz bpq assemblage the solidus is located at 800oc at 1 0 gpa the melting reaction produces a metaluminous granitic liquid and leaves a residuum consisting of garnet biotite orthopyroxene plagioclase quartz in addition the experiments show that at 1 0 gpa biotite can be stable above 950oc with both micas in the starting material bpqm the solidus at 1 0 gpa is located at 750oc the melting reactions produce a peraluminous granitic liquid and leave a residuum of garnet sillimanite biotite quartz plagioclase kfeldspar in experiments below 900oc at 950oc the residuum consists of garnet orthopyroxene biotite plagioclase the melt fraction is determined by the proportions of the hydrous phases and of the amount of feldspar relative to quartz mineral modes of the source rocks particularly the amount of quartz are at least as important as the amount of available h20 in controlling the melt fraction generated during crustal anatexis

mapping the distribution of melt during anatexis at the source area of crustal granites by synchrotron μ xrf proyecto fapa universidad de los andes bogota colombia centro nacional de pesquisa em energia e materiais brazilian synchrotron light laboratory lnls proposal n xafs1 17105 cariparo cassa di risparmio di padova e rovigo project makearth european union s horizon 2020 research and innovation programme under the marie sklodowska curie grant agreement no 654606

depletion of light rare earth elements in felsic magmas contrary to simple generalizations about their behavior light rare earth elements lree do not act as incompatible elements in very felsic magmas in fact lree concentrations typically decrease often drastically during differentiation of such magmas the simplest explanation for this depletion involves the separation of minute easily overlooked quantities of an extremely lree rich accessory mineral either monazite or allanite our data indicate that felsic liquids with 50 ppm lree may be saturated in either of these accessories and that the concentration required for saturation decreases in increasingly felsic liquids this accounts for incompatible behavior of lree even at high concentrations in mafic magmas in contrast to compatible behavior at low concentrations in felsic magmas partitioning of lree into solid rather than liquid has important implications for trace element and nd isotope modeling of crustal anatexis as well as for magma differentiation

partial melting of metagreywackes part ii compositions of minerals and melts a series of experiments on the fluid absent melting of a quartz rich aluminous metagreywacke has been carried out in this paper we report the chemical composition of the phases present in the experimental charges as determined by electron microprobe this analytical work includes biotite plagioclase orthopyroxene garnet cordierite hercynite staurolite gedrite oxide and glass over the range 100 1000 mpa 780 1025 c biotites are na and mg rich with ti contents increasing with temperature the compositions of plagioclase range from an17 to an35 with a significant orthoclase component and are always different from the starting minerals at high temperature plagioclase crystals correspond to ternary feldspars with or contents in the range 11 20 mol garnets are almandine pyrope grossular spessartine solid solutions with a regular and significant increase of the grossular content with pressure all glasses are silicic sio2 67 6 74 4 wt peraluminous and leucocratic feo mgo 0 9 2 9 wt with a bulk composition close to that of peraluminous leucogranites even for degrees of melting as high as 60 vol with increasing pressure sio2 contents decrease while k2o increases at any pressure the melt compositions are more potassic than the water saturated granitic minima the h2o contents estimated by mass balance are in the range 2 5 5 6 wt these values are higher than those predicted by thermodynamic models modal compositions were estimated by mass balance calculations and by image processing of the sem photographs the positions of the 20 to 70 isotects curves of equal proportion of melt have been located in the pressure temperature space between 100 mpa and 1000 mpa with increasing pressure the isotects shift toward lower temperature between 100 and 200 mpa then bend back toward higher temperature the melting interval increases with pressure the difference in temperature between the 20 and the 70 isotects is 40 c at 100 mpa and 150 c at 800 mpa the position of the isotects is interpreted in terms of both the solubility of water in the melt and the nature of the reactions involved in the melting process a comparison with other partial melting experiments suggests that pelites are the most fertile source rocks above 800 mpa the difference in fertility between pelites and greywackes decreases with decreasing pressure a review of the glass compositions obtained in experimental studies demonstrates that partial melting of fertile rock types in the crust greywackes pelites or orthogneisses produces only peraluminous leucogranites more mafic granitic compositions such as the various types of calk alkaline rocks or mafic s type rocks have never been obtained during partial melting experiments thus only peraluminous leucogranites may correspond to liquids directly formed by partial melting of metasediments other types of granites involve other components or processes such as restite unmixing from the source region and or interaction with mafic mantle derived materials

trace element modelling of pelite derived granites the presence or absence of a vapour phase during incongruent melt reactions of muscovite and biotite together with the composition of the protolith determines the trace element characteristics of the resulting melt provided that equilibrium melting occurs for those phases that host the tracc elements of interest for granitic melts rb sr and ba provide critical constraints on the conditions that prevailed during melting whereas ree are primarily controlled by accessory phase behaviour mass balance constraints for eutectic granites that are formed by the incongruent melting of muscovite in pelites indicate that melting in the presence of a vapour phase will result in a large melt fraction and deplete the restite in feldspar hence the melt will be characterized by low rb sr and high sr ba ratios in contrast vapour absent melting will result in a smaller melt fraction and an increase in the restitic feldspar consequently high rb sr and low sr ba ratios are predicted vapour absent melting will also enhance the negative eu anomaly in the melt granites that result from the incongruent melting of biotite in the source will be characterized by higher rb concentrations than those that result from the incongruent melting of muscovite the himalayan leucogranites provide an example of unfractionated crustally derived eutectic melts that are enriched in rb but depleted in sr and ba relative to their metasedimentary protoliths these compositions may be generated by the incongruent melting of muscovite as a low melt fraction f 0 1 from a pelitic source under vapour absent conditions

the mechanism of ascent and emplacement of granite magma during transpression a syntectonic granite paradigm we propose a model for syntectonic ascent and emplacement of granite magma based on structural relations in part of the northern appalachians in the study area in western maine strain was distributed heterogeneously during devonian acadian transpression metasedimentary rocks migmatites at high grades record two contrasting types of finite strain in zones that alternate across strike rocks in both types of zones have a penetrative moderately to steeply ne plunging mineral elongation lineation defined by bladed muscovite fibrolite sillimanite at high grades in straight belts of enhanced deformation rocks have s l fabrics that record apparent flattening to plane strain apparent flattening zones afzs but rocks between these belts have l s fabrics that record apparent constriction apparent constriction zones aczs at metamorphic grades above the contemporary solidus rocks in afzs developed stromatic structure in migmatite which suggests that percolative flow of melt occurred along the evolving flattening fabric stromatic migmatites are intruded by concordant to weakly discordant m scale composite sheet like bodies of granite to suggest magma transport in planar conduits through the afz rocks inhomogeneous migmatite is found in the intervening aczs which suggests migration of partially molten material through these zones en masse probably by melt assisted granular flow inhomogeneous migmatites are intruded by irregular m scale bodies of granite that vary from elongate to sub circular in plan view and seem cylindrical in three dimensions these bodies apparently plunge to the northeast parallel to the regional mineral elongation lineation to suggest magma transport in pipe like conduits through the acz rocks we postulate that the form of magma ascent conduits was deformation controlled and was governed by the contemporaneous strain partitioning magma ascent in planar and pipe like conduits through migmatites is possible because oblique translation during contraction displaces isotherms upward in the orogenic crust to form a thermal antiform within this hot corridor it is the difference in temperature between melt producing reactions in the anatectic zone and the wet solidus for granite melt that enables magma to migrate pervasively up through the orogenic crust without congealing heat advected with the migrating melt promotes amplification of the thermal antiform in a feedback relation that extends the zone of plastic deformation and pervasive melt migration to shallower levels in the crust at the wet solidus we suggest melt flows obliquely toward axial culminations in the thermal antiform which are sites of melt accumulation and perturbations from which magma may escape to form plutons batches of melt that escape from these perturbations may be trapped by tectonic structures higher in the crust or ascent may become inhibited with decreasing depth by thermal arrest and solidification if the rate of arrival of subsequent melt batches exceeds the rate of crystallization at the site of pluton construction melt pressure ultimately may lead to sub horizontal magma fracture or viscous flow of wall rocks may allow lateral spreading the resultant plutons have sub horizontal tabular geometries with floors that slope down to the ascent conduit as the thermal antiform decays the height of sub solidus crust that separates the deepest part of the pluton from the anatectic zone increases consequently pluton inflation declines and solidification leads to infilling of the magma feeder channel to form a root zone that passes downward into migmatite which may explain the difficulty of determining precisely the floor to these deeper segments of large plutons using gravimetry

a regional perspective of the quetico metasedimentary belt superior province canada alternating greenstone granite and metasedimentary gneiss belts are a first order tectonic feature of the southern superior province the tectonic development of the quetico metasedimentary belt is reviewed with regard to depositional structural and metamorphic plutonic history over its 1200 km length the belt consists of marginal metasedimentary schists of turbiditic origin and interior metasedimentary migmatite and peraluminous leucogranite polyphase deformation has resulted in a steep easterly striking foliation and regional gently east plunging stretching lineation metamorphic grade varies in a low p facies series from greenschist at the belt margins to upper amphibolite and local granulite in the central migmatite intrusive granite zone mineral assemblages in the central zone yield estimates of metamorphic pressure that increase systematically eastward over 800 km from about 250 mpa 2 5 kbar near the canada united states border to 600 mpa 6 kbar in granulites adjacent to the kapuskasi

electrical conductivity in a partially molten crust from measurements on metasedimentary enclaves abstract the complex electrical impedance of a garnet biotite sillimanite residual enclave in the neogene dacite of el hoyazo se spain has been determined up to 978 c at 200 300 mpa this well studied material represents a direct sampling of the alboran domain thinned lower crust undergoing partial melting the paragenesis is garnet biotite sillimanite plagioclase graphite cordierite coexisting with widespread 10 wt rhyolitic melt occurring as inclusions and interstitial glass and developed during regional anatexis at 850 50 c and 500 700 mpa the samples were used in cyclic measurements consisting in heating cooling ramps at progressively higher maximum temperature to observe the effect of reactions on conductivity in the first cycle up to 850 c at 2 3 kbar re melting of the interstitial glass is achieved with no additional reactions and logarithmic conductivity s m is up to 1 5 at t 950 c new melt with orthopyroxene ilmenite is produced from biotite partial breakdown and the logarithmic conductivity s m is up to 0 7 application of mixing models as hashin shtrikman bounds or archie s law shows that once interconnected melt controls the electrical conductivity of the enclave the electrical conductivity of the rock can be simulated with the electrical conductivity data obtained on the starting matrix glass of the enclave and with the new melt our experimental results obtained on a graphitic metasedimentary material evidence show that graphite does not contribute to the conductivity enhancement and that the electrical anomaly observed below the betics can be explained as effect of partial melting of a residual crust comparison with previous works on mafic granulites shows that similar conductivity values can be achieved both by melting of a residual felsic crust or by melting of mafic materials and suggests that pelitic rocks can be more common at deep levels than expected

dehydration melting and the granulite transition in metapelites from southern namaqualand s africa in a prograde amphibolite granulite transition zone in the namaqualand metamorphic complex metapelites show an interbanding of the amphibolite facies association biotite sillimanite quartz with the granulite facies association garnet cordierite k feldspar relict graded bedding shows that compositional banding is of sedimentary origin the garnet cordierite k feldspar gneisses contain quartzofeldspathic segregations surrounding garnets and have more fe rich bulk compositions than the biotite sillimanite schists

characterization and p t evolution of melt bearing ultrahigh temperature granulites an example from the anapolis itaucu complex of the brasilia fold belt brazil between garnet orthopyroxene and sillimanite and coronae or sapphirine quartz ultrahigh temperature metamorphism symplectites involving corundum sapphirine spinel cordierite plagioclase sillimanite orthopyroxene biotite and ilmenite the retrograde segment of the p t path was further constrained by biotite producing reactions a composite p t path was constructed

high p high t anatexis of archaean tonalitic grey gneisses the eseka migmatites cameroon abstract the eseka migmatites provide a good example of high p high t anatexis of archaean quartz plagioclase biotite grey gneisses partial melting resulted in the development of neosomes comprising a quartzo feldspathic fraction of granodioritic to trondhjemitic composition and ferromagnesian minerals represented by hornblende mainly 15 45 vol garnet in lesser amounts 4 8 vol and scarce clinopyroxene thermobarometry suggests that anatexis occurred close to the amphibolite granulite facies transition under conditions estimated at around 9 kbar and 750 c a late retrogression is documented by the growth of epidote and chlorite and by plagioclase albitization textural relations mineralogical data and recalculation of the primary mineral assemblages suggest that the biotite dehydration melting conditions were reached leading to the generation of granodioritic melts in equilibrium with k feldspar hornblende and garnet clinopyroxene in some cases this was followed during melt crystallization by a retrograde reaction involving the granodioritic melt and hornblende to produce biotite epidote assemblages and trondhjemitic neosomes compared to similar migmatites the eseka neosomes are characterized by higher al and ti contents of hornblende the presence of garnet and the lack of sphene which can be related to higher p t conditions geochemical data point to the segregation and removal of some melt in the eseka migmatites resulting in limited concentration of hornblende and garnet at the site of melting this together with previous field observations and experimental data could suggest that some hornblende rich gneisses or amphibolites found in the lower middle crust may represent a residue left after extraction of anatectic melts geochronological and petrological data further suggest that large portions of the archaean ttg rocks from the congo craton have been reworked under high grade conditions during the paleoproterozoic

aluminous granulites from the pulur complex ne turkey a case of partial melting efficient melt extraction and crystallisation abstract in the pulur complex ne turkey a heterogeneous rock sequence ranging from quartz rich mesocratic gneisses to silica and alkali deficient fe mg and al rich melanocratic rocks is characterized by granulite facies assemblages involving garnet cordierite sillimanite ilmenite spinel plagioclase quartz biotite corundum rutile and monazite textural evidence for partial melting in the aluminous granulites particularly leucosomes is largely absent or strongly obliterated by a late stage hydrothermal overprint however inclusion relations high peak p t conditions the refractory modes bulk and biotite compositions of the melanocratic rocks strongly support a model of partial melting the melt was almost completely removed from the melanocratic rocks and crystallised within the adjacent mesocratic gneisses which are silica rich bear evidence of former feldspar and show a large range in major element concentrations as well as a negative correlation of most elements with sio2 peak conditions are estimated to be 800 c and 0 7 0 8 gpa subsequent near isothermal decompression to 0 4 0 5 gpa at 800 730 c is suggested by the formation of cordierite coronas and cordierite spinel symplectites around garnet and in the matrix sm nd rb sr and 40ar 39ar isotope data indicate peak conditions at 330 ma and cooling below 300 c at 310 ma

archean continental assembly in the southeastern superior province of canada between 1988 and 1993 seismic reflection and refraction surveys were acquired across the medium to high grade opatica plutonic gneiss belt the low grade abitibi greenstone belt and the pontiac metasedimentary belt all of which form part of the late archean superior province shallowly north dipping reflections define a structural style consistent with the northward underthrusting and accretion over about 30 ma of various exotic terranes against a backstop provided by the opatica belt this rapid southward growth of the archean protocraton was driven by at least one north dipping subduction zone as revealed by north dipping reflections that extend to 65 km depth in the upper mantle below the opatica belt in contrast to the mainly orthogneissic opatica and pontiac belts the midcrust of the abitibi belt comprises metasedimentary and igneous rocks plus imbricated units of unknown affinity relict midcrustal accretionary complexes of substantial size whieh are indicative of primary suture zones are interpreted near the northern and southern limits of the abitibi belt an interpreted basal decollement and significantly older ages in the north suggest that the upper crustal greenstone rocks are allochthonous evidence of large scale extension appears to be confined to the southern volcanic zone of the abitibi which developed into a half graben as the original suture zone was reactivated in extension unusually high seismic p wave velocities 7 5 8 2 kms 1 are present in the lower 8 km of the abitibi crust and they correlate well with a downward reduction in seismic reflectivity attributable to late modification of the deepest part of the crust crustal xenolith studies suggest that this process may be linked to early proterozoic magmatism

melt segregation and magma interactions during crustal melting breaking out of the matrix abstract differentiation of the continental crust begins with its partial melting the products of crustal melting are silicic hydrous h2o undersaturated granitic liquids that are generated within matrices of residual crystals crustal differentiation requires that felsic magmas form and escape from these solid residua an important question is whether granitic magmas collect into large batches within or near their sources which then give rise to ascent or alternatively bleed out of the sources in smaller streams or pulses we demonstrate that the physical reality is closer to the second alternative and thus question the validity of the concepts of magma segregation and source fertility as they are sometimes visualised granitic plutons contain chemically distinct sub populations formed by source level entrainment of the peritectic assemblages into the melts rapid evacuation at source levels and high ascent rates protect the magmas from wall rock interactions during their tenure at source depths and during their ascent through cool upper crust the existence of different types of granites and hence of clearly defined chemically different magmas within plutons dictates that felsic magmas must separate efficiently from their anatectic sources and must ascend to the sites of their emplacement with minimal chemical interaction with crust through which the magma must move exposed deep crustal sections are typically lithologically diverse with the more fertile rocks commonly forming discrete layers surrounded by rocks with contrasting compositions if the melts were required to segregate and accumulate into large volumes within their hot sources especially by slow gravity driven melt percolation it is very likely that they would be substantially modified by reaction with diverse source rocks thus the processes mooted to occur in melting assimilation storage and homogenisation mash or deep crustal hot dch zones would act to erase original compositional heterogeneities and produce larger batches of more homogeneous magma perhaps carrying evidence of extensive magma mixing from various lines of evidence we conclude that mash and dch zones may not exist and even if they do they cannot form the sources of most granitic magmas the intrinsic heterogeneity in crustal source rocks the likely occurrence of peritectic assemblage entrainment and the inefficiency of magma mixing decree that granitic rocks will retain source inherited chemical and isotopic heterogeneities rapid semi continuous and disequilibrium withdrawal of small magma batches from source rocks means that elements of whole rock trace element chemistry and accessory mineral chemistry will be decoupled from major element variations this also means that a large source with low nominal fertility due to low hydrous mineral content for example could still produce a substantial granitic pluton by additions of individually small increments of magma

grain scale melt distribution in two contact aureole rocks implications for controls on melt localization and deformation the grain scale spatial arrangement of melt in layer parallel leucosomes in two anatectic rocks from two different contact aureoles located in central maine usa is documented and used to constrain the controls on grain scale melt localization the spatial distribution of grain scale melt is inferred from microstructural criteria for recognition of mineral pseudomorphs after melt and mineral grains of the solid matrix that hosted the melt in both rocks feldspar mimics the grain scale distribution of melt and quartz is the major constituent of the solid matrix the feldspar pockets consist of individual feldspar grains or aggregates of feldspar grains that show cuspate outlines they have low average width length ratios 0 54 and 0 55 respectively and are interstitial between more rounded and equant width length ratios 0 65 for both samples quartz grains in two dimensions the feldspar pockets extend over distances equivalent to multiple quartz grain diameters possibly forming a connected three dimensional intergranular network both samples show similar mesoscopic structural elements and in both samples the feldspar pockets have a shape preferred orientation in one sample feldspar inferred to replace melt is aligned subparallel to the shape preferred orientation of quartz indicating that pre or syn anatectic strain controlled the grain scale distribution of melt in the other sample the preferred orientation of feldspar inferred to replace melt is different from the orientations of all other mesoscopic or microscopic structures in the rock indicating that differential stress controlled grain scale melt localization this is probably facilitated by conditions of higher differential stress which may have promoted microfracturing grain scale melt distribution and inferred melt localization controls give insight into possible grain scale deformation mechanisms in melt bearing rocks application of these results to the interpretation of deep crustal anatectic rocks suggests that grain scale melt distribution should be controlled primarily by pre or syn anatectic deformation feedback relations between melt localization and deformation are to be expected with important implications for deformation and tectonic evolution of melt bearing rocks

petrogenesis and tectonic implications of the charnockites in the yishui terrane north china craton abstract a combined study of zircon u pb ages lu hf isotopes and whole rock geochemistry was carried out for representative charnockites from the yishui terrane in the western shandong province ncc the results demonstrate that the charnockites in the yishui terrane are of igneous origin rather than derivation from remelting or metamorphism of supracrustal rocks zircon u pb dating for the charnockites in the yishui terrane indicates protolith emplacement around 2 52 2 56 ga and synchronous metamorphism around 2 50 2 53 ga zircon lu hf isotopes analyses show that the charnockites have positive e hf t values with an average 4 03 and depleted mantle two stage zircon hf model ages t dm2 mainly cluster around 2 7 3 0 ga indicative of a source of juvenile crust formed around 2 7 3 0 ga furthermore the charnockites with 2 tend to be magnesian calcic to calc alkalic and metaluminous only a small population of the charnockites with 70 wt sio 2 are ferroan alkali calcic and weakly peraluminous which are consistent with geochemical features of cordilleran type granitoids suggesting a deeply eroded magmatic arc derived from remelting of juvenile crust mainly formed around 2 7 3 0 ga taken the comprehensives of available whole rock geochemical and zircon lu hf isotopic data of the charnockites synchronous emplacement and metamorphism high temperature setting of charnockites granulite facies metamorphism of anticlockwise p t path in the yishui terrane as well as the whole ncc we conclude that the combined geodynamics of mantle plume and oceanic crust subduction might contribute to the formation of the charnockites in the yishui terrane as well as similar late archean charnockites in other areas of the ncc further implying extensive occurrences of modern style plate tectonic accretions in late archean in the ncc

an experimental study of element partitioning among biotite muscovite and coexisting peraluminous silicic melt at 200 mpa h2o

quaternary ostracode and foraminiferal biostratigraphy and paleoceanography in the western arctic ocean abstract the stratigraphic distributions of ostracodes and selected calcareous benthic and planktic foraminiferal species were studied in sediment cores from 700 to 2700 m water depth on the northwind mendeleev and lomonosov ridges in the western arctic ocean microfaunal records in most cores cover mid to late quaternary sediments deposited in the last 600 ka with one record covering the last 1 5 ma results show a progressive faunal turnover during the mid pleistocene transition mpt 1 2 to 0 7 ma and around the mid brunhes event mbe 0 4 ma reflecting major changes in arctic ocean temperature circulation and sea ice cover the observed mpt shift is characterized by the extinction of species that today inhabit the sea ice free subpolar north atlantic and or seasonally sea ice free nordic seas echinocythereis sp rockallia cf enigmatica krithe cf aquilonia pterygocythereis vannieuwenhuisei after a very warm interglacial during marine isotope stage mis 11 dominated by the temperate planktic foraminifer turborotalita egelida the mbe experienced a shift to polar assemblages characteristic of predominantly perennial arctic sea ice cover during the interglacial and interstadial periods of the last 300 ka these include the planktic foraminifera neogloboquadrina pachyderma the sea ice dwelling ostracode acetabulastoma arcticum and associated benthic taxa pseudocythere caudata pedicythere neofluitans and polycope spp several species can be used as biostratigraphic markers of specific intervals such as ostracodes rabilimis mirabilis mis 5 and p vannieuwenhuisei extinction after mis 11 and foraminiferal abundance zones bulimina aculeata late mis 5 and bolivina arctica mis 5 11

melt segregation in the continental crust before melt will segregate from its restite and source there must be both a driving force and space into which the melt can move the continental crust is anisotropic and in most cases is subject to deviatoric stresses during melting under these conditions melt segregation begins when an interconnected network of melt forms and the source becomes permeable melt is driven by pressure gradients from its restite toward dilatant sites set up in the heterogeneously deforming source the source is continually drained of melt and so need never contain more melt than that required to maintain permeability 26 where the solid matrix breaks down and diapirism can occur

granulite facies regional and contact metamorphism of the tasiuyak paragneiss northern labrador textural evolution and interpretation the tasiuyak paragneiss at the western margin of the nain plutonic suite has been subjected to two granulite facies metamorphic events i regional metamorphism during the paleoproterozoic torngat orogeny and ii contact metamorphism due to emplacement of the mesoproterozoic nain plutonic suite regional metamorphism led to partial melting of pelitic rocks and the development of a locally well preserved sequence of prograde and retrograde textures these textures are partly controlled by bulk composition and formed in the pressure temperature p t field of the continuous reaction biotite sillimanite plagioclase quartz garnet k feldspar melt along a hairpin p t path with peak conditions of 8 10 kbar 0 8 1 0 gpa and up to 870 c in the nakfmash na2o k2o feo mgo al2o3 sio2 h2o system these textures controlled the development of the contact metamorphic assemblages contact metamorphism of the pelitic rocks between the tessiarsuyungoakh intrusion and the makhavinekh lake pluton led to

the composition and petrogenesis of the lower crust a xenolith study granulite facies lower crustal xenoliths from a single basaltic vent hill 32 in the mcbride volcanic province north queensland australia illustrate the extreme lithologic diversity of the deep crust these xenoliths are dominantly mafic but intermediate and felsic granulites represent a significant proportion 20 of the xenolith population all xenoliths have high grade mineralogies and generally well equilibrated textures as well as decompression features which are indicative of derivation from deep crustal levels 0 7 1 0 gpa major and trace element chemistry for 12 xenoliths chosen to span the observed lithologic range are used to constrain the petrogenesis of these rocks in the smaller layered samples metamorphic differentiation may lead to nonrepresentative sampling however in most instances such secondary processes can be identified and the original chemical characteristics delineated the mafic xenoliths formed through a variety of processes including crystallization of mafic magma crystal accumulation from mafic and felsic magmas and partial melting of intermediate compositions to yield a mafic residuum the two analyzed intermediate xenoliths are metasediments based upon high alumina to alkali ratios and rare earth element patterns whereas the two felsic xenoliths have compositions similar to igneous rocks comparisons of noncumulate and or restite xenoliths with unmetamorphosed rock types show that k and rb are variably depleted whereas th and u are strongly depleted in all rock types the large ion lithophile element depletion patterns for xenoliths are similar to those of rocks from granulite facies terrains suggesting similar processes were operative suggestions of an anomalously ba and sr rich lower crust are not supported by the data by using the observed lithologic proportions of xenoliths at hill 32 and the chemical analyses presented here a weighted mean composition of the lower crust can be obtained and compared with recently proposed lower crustal compositions the weighted mean composition is mafic and formed through a combination of basaltic underplating crystal accumulation tectonic underplating and partial melting no simple model of lower crust formation through basaltic or andesitic underplating nor intracrustal melting is sufficient to explain lower crust formation in phanerozoic continental margin settings

insights into the complexity of crustal differentiation k2o poor leucosomes within metasedimentary migmatites from the southern marginal zone of the limpopo belt south africa differentiation of the continental crust is the result of complex interactions between a large number of processes which govern partial melting of the deep crust magma formation and segregation and magma ascent to significantly higher crustal levels the anatectic metasedimentary rocks exposed in the southern marginal zone of the limpopo belt represent an unusually well exposed natural laboratory where the portion of these processes that operate in the deep crust can be directly investigated in the field the formation of these migmatites occurred via absent incongruent melting reactions involving biotite which produced cm to m scale k2o poor garnet bearing stromatic leucosomes with high ca na ratios relative to their source rocks field investigation combined with geochemical analyses and phase equilibrium modelling designed to investigate some aspects of disequilibrium partial melting show that the outcrop features and compositions of the leucosomes suggest several steps in their evolution 1 melting of a portion of the source with restricted plagioclase availability due to kinetic controls to produce a magma melt entrained peritectic minerals in variable proportions relative to melt 2 segregation of the magma at near peak metamorphic conditions into melt accumulation sites mas a k a future leucosome 3a reequilibration of the magma with a portion of the bounding mafic residuum via chemical diffusion h2o k2o which triggers the co precipitation of quartz and plagioclase in the mas 3b extraction of melt dominated magma to higher crustal levels leaving peritectic minerals entrained from the site of the melting reaction and the minerals precipitated in the mass to form the leucosome in the source the key mechanism controlling this behaviour is the kinetically induced restriction of the amount of plagioclase available to the melting reaction this results in elevated melt h2o and k2o and chemical potential gradient for these components across the leucosome mafic residuum contact the combination of all of these processes accurately explains the composition of the k2o poor leucosomes these findings have important implications for our understanding of melt segregation in the lower crust and minimum melt residency time which according to the chemical modelling is 5 years we demonstrate that in some migmatitic granulites the leucosomes constitute a type of felsic refractory residuum rather than evidence of failed magma extraction this provides a new insight into the ways that source heterogeneity may control anatexis this article is protected by copyright all rights reserved

experimental partitioning of rb cs sr and ba between alkali feldspar and peraluminous melt hydrous partial melting experiments performed between 650 and 750 c at 200 mpa h20 on synthetic metapelite compositions quartz albite muscovite biotite mineral mixtures doped with ba sr rb and cs yielded alkali feldspar crystals with a wide range of compositions in equilibrium at their rims with peraluminous melt measured partition coefficients for normally trace lithophile elements between feldspar and melt d m fsp gl m ba sr rb cs do not depend on either temperature or bulk composition of melt for the compositions studied values of d sr fsp gl are between 10 and 14 and appear to be independent of the albite and orthoclase contents of the feldspar crystals in contrast values of d ba fsp gl and d rb fsp glare strongly dependent on the orthoclase content of feldspar relationships that can be expressed by the following linear equations d ba fsp gl 0 07 0 25 orthoclase and d rb fsp gl 0 03 0 0 1 orthoclase where orthoclase is in mole percent these equations reproduce the range of previously reported values for d ba and d rb determined on natural and synthetic samples a single partition coefficient for cs was also determined at d cs fsp gl 0 13 these data can be used in conjunction with recently published partition coefficients for muscovite biotite and plagioclase feldspars blundy and wood 1991 icenhower and london 1995 to model quantitatively the trace element signatures of peraluminous magmas during anatexis and crystallization depending on bulk composition and pressuretemperature trajectories during episodes of partial melting ba and sr and to a lesser extent rb are retained at the source while cs and li are enriched in the first melts these results explain why peraluminous granitic magmas with s type sedimentary sources carry a distinctive enrichment in li and cs

geochemical modeling of low melt fraction anatexis in a peraluminous system the pena negra complex central spain abstract a study was made of the chemical fractionation associated with four cases of anatectic segregation of low melt fraction cordieritic granites from migmatized meta greywackes the aims of the study were to 1 reveal the fractionation patterns of major and trace elements 2 compare the major element chemistry of leucogranites and the quantitative behavior of source minerals during anatexis inferred by mass balance adjustment with available experimental data for peraluminous systems and 3 discuss the behavior of trace elements in crustal melting by comparing the chemically determined composition of leucogranites with the results of three fractionation models two of these assume a perfect diffusive behavior of trace elements within residual solids but they use a different set of distribution coefficients the third assumes a perfect nondiffusive behavior in relation to their source rocks the leucogranites are strongly depleted in li transition elements and light rare earth elements but enriched in k2o sio2 and ba the k rb ratio in leucogranites is higher than in sources and reaches values typical of high grade metamorphism mass balance analysis using the anatexis mixing model shows that the chemistry of cordierite leucogranites is compatible with its having originated by closed system water undersaturated anatexis on previously migmatized meta greywackes leaving a residue enriched in cordierite plus biotite and exhausted in k feldspar biotite melts congruently unless important amounts of sillimanite were also present in the source compared with experimental melts obtained from sources with the same chemical composition but with a different femic mineralogy biotite sillimanite instead of cordierite biotite the pena negra leucogranites are richer in k2o and mgo with a lower fe fe mg ratio the differences in magnesium are believed to result from the changes in the mineral assemblage of the source rocks however the differences in potassium contents are still not well understood the behavior of trace elements during anatexis cannot be modeled by trace element fractionation equations because of the sluggish diffusion kinetics of trace elements at the temperature of anatexis making the melting rate of minerals greater than the diffusion rate of trace elements within minerals the behavior of trace elements essentially consists in following that of the minerals containing them

formation of diatexite migmatite and granite magma during anatexis of semi pelitic metasedimentary rocks an example from st malo france petrological and geochemical variations are used to investigate the introduction formation of granite magma from diatexite migmatites derived from partial melting experiments show that protoliths of pelite metasedimentary rocks of pelitic to greywacke composition at st and greywacke composition yield up to 40 vol malo france anatexis occurred at relatively low temperatures granite melt over the temperature range 650 900 c and pressures 800 c 4 7 kbar principally through muscovite typical of anatexis of the continental crust conrad et dehydration melting biotite remained stable and serves as a tracer al 1988 vielzeuf holloway 1988 patino douce for the solid fraction during melt segregation the degree of partial johnston 1991 vielzeuf montel 1994 patino douce melting calculated from modal mineralogy and reaction stoichiometry harris 1998 therefore to make a granite magma was 40 vol there is a continuous variation in texture the melt fraction must be segregated from a solid fraction mineralogy and chemical composition in the diatexite migmatites of much greater volume and then collected together mesocratic diatexite formed when metasedimentary rocks melted the type of melt residuum separation process depends sufficiently to undergo bulk flow or magma flow but did not on the melt fraction present experience significant melt residuum separation mesocratic diatexite melt residuum separation at low degrees of partial that underwent melt segregation during flow generated 1 memelting f and consequently low melt fraction mf lanocratic diatexites at the places where the melt fraction was has been documented from metatexite migmatites in removed leaving behind a biotite and plagioclase residuum enriched these rocks melt segregation produced centimetre scale in tio2 feot mgo cao sc ni cr v zr hf th u and leucosomes distributed in a host composed of layers that ree and 2 a complementary leucocratic diatexite enriched in have melted and others that have not e g henkes sio2 k2o and rb where the melt fraction accumulated leucocratic johannes 1981 gupta johannes 1982 dougan 1983 diatexite still contained 5 15 vol residual biotite mg number sawyer 1987 tait harley 1988 barbey et al 1990 40 44 and 10 20 vol residual plagioclase an22 anatectic brown 1994 leucosomes represent small volumes of granite magma developed from the leucodiatexite first by further felsic magma formed when melt was squeezed out of the melt residuum separation then through fractional crystallization deforming matrix mclellan 1988 sawyer 1991 1994 most biotite in the anatectic granite is magmatic mg number brown 1994 brown et al 1995 and collected in low18 22 pressure sinks such as shear bands and inter boudin

microstructures of melt bearing regional metamorphic rocks the most reliable microstructural criterion for the former presence of felsic melt in regional migmatites is a three mineral quartz k feldspar and sodic plagioclase aggregate in veinlets several other criteria are potentially reliable namely 1 euhedral crystals of feldspar precipitated from liquid or peritectic minerals e g garnet cordierite orthopyroxene k feldspar lining felsic protoleucosomes 2 inclusionfree euhedral overgrowths of feldspar precipitated from liquid or peritectic minerals e g garnet cordierite orthopyroxene k feldspar on residual grains of the same minerals with abundant inclusions in the mesosome 3 aligned euhedral feldspar crystals 4 simple twinning in k feldspar 5 dihedral angles of 60 subtended where a grain of feldspar and or quartz inferred to have pseudomorphed former melt meets two grains of other minerals 6 cuspate volumes of quartz k feldspar or sodic plagioclase especially where surrounded by grains inferred to have been residual during melting 7 veinlets of inferred former melt now mineral pseudomorphs consisting of one of quartz k feldspar or sodic plagioclase preferably though less commonly involving two or three of these minerals along grain boundaries or along inferred former intragranular fractures 8 biotite pseudomorphed by feldspar 9 veinlets of plagioclase that is more sodic than plagioclase grains in the adjacent rock 10 plagioclase with oscillatory zoning 11 microgranophyric intergrowths of quartz and alkali feldspar in patches or veinlets between primary grains 12 symplectic replacement aggregates that can be explained by reactions between peritectic grains and cooling melt and 13 melanosome patches and layers from which leucosome has been extracted however all these criteria must be interpreted with care some other proposed criteria are questionable for example 1 random mineral distributions 2 grain size increase 3 interstitial grains 4 corroded relics of inferred reactant mineral grains surrounded by areas of quartz k feldspar or sodic plagioclase 5 projections into a mineral grain 6 lobes of myrmekite and 7 plagioclase rims with a constant sodic composition occurring on plagioclase cores that are more calcic and or of variable composition

partial melting of metapelites in the gagnon terrane below the high pressure belt in the manicouagan area grenville province pressure temperature p t and u pb age constraints and implications metapelites of the parautochthonous gagnon terrane at the footwall of the high pressure high p belt in the manicouagan area central grenville province preserve an impressive textural record of partial melting reactions mainly in polymineralic inclusions within garnet the dominant textures were developed within the pressure temperature p t field of the continuous dehydration melting reaction biotite kyanite or sillimanite plagioclase quartz garnet k feldspar melt with sillimanite instead of kyanite in the southern part of the footwall inferred p t paths have a hair pin form in the range of 750 850 c and 1000 1500 mpa for the kyanite bearing rocks monazite crystallization ages are consistently late grenvillian either 995 or 985 ma and one sample contains monazite of both ages two of these samples also contain inherited monazite with ages of 1738 5 and 1719 30 ma indicative of an earlier metamorphic event tonalite and diorite from the same area yield archean zircon crystall

giant granulite terranes of northeastern superior province the ashuanipi complex and minto block the ashuanipi complex and minto block of the superior province are large regions that have been classified as high grade gneiss terranes on the basis of the presence of orthopyroxene bearing units like the granite greenstone and metasedimentary subprovinces of the southern superior province the two terranes consist predominantly of intrusive rocks but are distinguished by their primary magmatic orthopyroxene both high grade and gneiss are misnomers because granulite facies gneisses are only sparingly present and the regions consist dominantly of massive unmetamorphosed plutonic rock the ashuanipi complex consists of a deformed metamorphosed package of metasedimentary rocks and primitive early tonalite cut by widespread orthopyroxene garnet granodiorite diatexite as well as plutons of tonalite granite and syenite based on its lithological and chronological similarity and on strike position the complex appears to be the continuation of metasedimentary subprovinces such as the quetico its evolution involved deposition of immature greywacke in an accretionary prism early arc tonalitic magmatism and deformation followed by widespread intracrustal magmatism in the period 2700 2670 ma both metamorphic and igneous rocks record equilibration under granulite facies conditions 700 835 c 0 35 0 65 gpa a 0 3 and indicate exposure levels of 20 km the minto block at the latitude of leaf river consists of several north northwest trending domains of similar scale and diversity to the east trending subprovinces of the southern superior province the central goudalie domain is dominantly amphibolite facies tonalitic rocks including some with ages 3 ga with small belts of volcanic and sedimentary origin lake minto domain contains poorly preserved supracrustal remnants in a plutonic complex comprising hornblende granodiorite clinopyroxene orthopyroxene granodiorite orthopyroxene biotite diatexite and granite the hornblende granodiorite suite constitutes most of the utsalik and tikkerutuk domains and is thought to represent continental arc magmatism on the basis of their distinct aeromagnetic and lithological character two additional domains are evident north of the leaf river area the inukjuak domain in the west and the douglas harbour domain in the east the northerly grain of the minto block appears to have been established in situ with respect to the easterly belts of the southern superior province i e no large scale block rotation during the same interval of time 3 0 2 7 ga modification of the tectonic framework for the superior province is required to explain minto arc magmatism in the interval 2730 2690 ma ago a continental magmatic arc built the berens river and bienville subprovinces and minto block on the southern and eastern edges respectively of a northern protocratonic foundation in the same period primitive volcanic arcs and accretionary prisms developed outboard on oceanic crust and were accreted to form a southern tectonic regime

zoned monazite and zircon as monitors for the thermal history of granulite terranes an example from the central indian tectonic zone the growth and dissolution behaviour of detrital metamorphic and magmatic monazite and zircon during granulite facies anatexis in pelitic and psammo pelitic granulites and in garnetiferous granite from the southern margin of the central indian tectonic zone citz have been investigated using reconstructed metamorphic reaction history monazite electron microprobe dating and sensitive high resolution ion microprobe shrimp u pb zircon geochronology whereas the pelitic granulites record medium pressure granulite facies metamorphism bm1 stage the psammo pelitic granulite reached ultrahigh temperatures tmax 880 c at 8 7 kbar the meta psammite additionally records two stages of granulite facies recrystallization bm2 and bm3 irrespective of variations in the bulk rock compositions and peak metamorphic conditions monazite is highly reactive during the bm1 event producing complex chemically zoned crystals textural compositional and chemical ages of these grains indicate the stability of six compositional domains cd1 to cd6 in the paragenetic sequence of which cd1 represents pre metamorphic detrital cores of paleoproterozoic age cd2 and cd3 combined mean age of 1612 14 ma mark two stages of recrystallization of detrital monazite cores during prograde events rims of cd4 monazite ages between 1615 14 and 1586 14 ma on partially to completely equilibrated cores indicate melt crystallization at or immediately following peak bm1p metamorphism cd5 monazite age of 1574 7 ma is restricted to the psammo pelitic granulites and marks final melt crystallization at the solidus during post peak cooling bm1r stage where r represents retrograde metamorphism the metamorphic rim of cd6 monazite age of 1539 24 ma around partially resorbed cd5 domains is linked to the decomposition of bm1 garnet during the terminal hydration event as part of a granulite facies recrystallization event compositionally homogeneous monazite and rims of chemically zoned monazite grains in granite together record a magmatic crystallization age of 1604 9 ma shrimp u pb zircon dating of the psammo pelitic granulite and garnetiferous granite indicates detrital or inherited cores of paleo to neoarchean age 3584 3 to 2530 3 ma which have been variously recrystallized and overgrown by new zircon 1 at 1658 12 ma 2 between 1595 5 and 1590 6 ma 3 at 1574 9 ma these zircon dates are correlated with the timing of the following 1 the protoliths of precursor sediments of the metasedimentary granulites deposited between 2530 and 1658 ma 2 a short lived high grade event 65 70 myr before the culmination of the bm1 granulite facies event 3 a high t anatectic event corresponding to the peak bm1p metamorphism at tmax 900 c 4 final crystallization of anatectic melt at the solidus cf bm1r metamorphic stage these chronological constraints from monazite and zircon when integrated with the metamorphic reaction history and published geochronological data allow recognition of three episodes of granulite facies metamorphism in the citz at 1658 ma pre bm1 event between 1612 and 1574 ma bm1 event and between 1572 and 1539 ma combined bm2 and bm3 events as part of a latest paleoproterozoic to early mesoproterozoic orogenic event this orogeny is linked to the growth of the proto greater indian landmass

mineral leucosome trace element partitioning in a peraluminous migmatite a laser ablation icp ms study abstract low pressure peraluminous migmatites from the pena negra complex central spain stayed partially molten for 5 10 ma until the latest hercynian deformations allowed the segregation of melt as discordant leucosome veins due to long residence within its source the melt had time enough to equilibrate with residual phases other than accessories included within major refractory minerals we estimated crystal melt partition coefficients as the concentration ratios between leucosome samples appearing to be pure melts and mesosome minerals which were analyzed for trace elements with a laser probe coupled to an icp mass spectrometer our data reveal that when biotite is stable li rb cs tl sc v cr ni nb and ta become strongly compatible the role of biotite in fractionating y th u and the ree is insignificant cordierite strongly fractionates li and be and also has some effect on the hree and u garnet produces extreme fractionation of sc y and the hree the ree partition coefficients for ferromagnesian silicates increase with the atomic number this effect being progressively more important through biotite cordierite and garnet k feldspar strongly fractionates ba and pb but plays a secondary role to biotite for rb and cs k feldspar fractionation does not change the lree hree ratio but plagioclase fractionation produces a significant decrease in the lree hree ratio both feldspars greatly fractionate sr and eu monazite fractionation produces a dramatic depletion in ree th and u as well as a decrease in the lree hree and th u ratios apatite also fractionates the ree although in contrast with monazite it increases the lree hree ratio and does not affect the th u ratio zircon fractionation like apatite and garnet produces a strong depletion in the hree and a concomitant increase in the lree hree ratio in contrast with monazite zircon fractionation causes the th u ratio to increase

the influence of source rock type chemical weathering and sorting on the geochemistry of clastic sediments from the quetico metasedimentary belt superior province canada abstract the geochemistry of clastic sediments is controlled by at least four factors source rock composition weathering of the source rocks sorting of the weathered detritus and post depositional alteration during diagenesis and metamorphism in order to evaluate the relative importance of these factors major trace and rare earth element contents were determined for distal and proximal clastic turbidites from the archaean quetico metasedimentary belt the degree of metamorphism of the samples ranges from middle greenschist to upper amphibolite facies simple mixing of archaean mafic and acidic rocks of similar composition to those found in the adjacent granite greenstone terrains will account for the tio2 feot mgo cr sc y and hree contents of the clastic turbidites the metasediments are enriched in lree relative to the mafic acidic rock mixing line indicating that the acidic source was enriched in the lree compared to archaean terrains from other parts of the world some quetico turbidites have an additional fe rich source component possibly a chemical sediment incorporated at the time of turbidite slumping cao na2o k2o rb and sr form trends on bivariant plots that are oblique to the mafic acidic rock mixing line and hence cannot be accounted for by simple mixing of the source rocks chemical weathering of feldspars prior to deposition can account for cao na2o k2o rb and sr trends since cao na2o and sr are lost to the weathering solutions and k2o and rb are retained on the product clays the higher na 2 o cao k 2 o na 2 o rb k 2 o and sr cao ratios but lower cao content of the distal samples suggest that they were derived from a bulk sediment that had experienced a greater degree of chemical weathering than the proximal sediments sorting is the factor that most strongly influences the composition of individual samples within the proximal sample group the coarse grained metagraywackes with their higher quartz feldspar and heavy mineral contents are enriched in sio2 cao na2o sr lree zr and hf relative to the fine grained clay rich metapelites metapelites are enriched in tio2 al2o3 feot mgo k2o cr zn sc y hree cs and rb as a result of their higher clay contents thus the use of clastic sediment compositions in determining average crustal compositions e g for the ree can only give satisfactory results when all grain size fractions are sampled in their correct relative proportions the chemical differences observed between the high and low grade samples can be accounted for by source rock type chemical weathering of the source rocks or sorting post depositional element mobility does not appear to be an important factor in determining the composition of the quetico metasediments

the fluid regime of high temperature metamorphism during granitoid magma genesis the strong negative correlation between the temperatures and melt h2o contents of granitoid magmas implies that the crustal melting reactions that produced the magmas were strongly buffered with t and ah2o co varying within a narrow band this observation can only be explained if the partial melting reactions that created the magmas were either fluid absent from the outset or evolved toward this condition as melting progressed since these melting reactions occur during upper amphibolite to granulite facies metamorphism it is reasonable to conclude that metamorphic events responsible for the generation of granitoid magmas generally occur in the absence of excess pervasive fluid

on the pseudomorphing of melt filled pores during the crystallization of migmatites pseudomorphs of melt filled pores recognized by their generally cuspate shape are used as diagnostic for the former presence of partial melt they are commonly observed in migmatites from the mid to deep crust although they occur in the smaller pores in migmatites from shallower levels 1 2 kbar the pseudomorphing of meltfilled pores is controlled by the kinetics of nucleation and is a consequence of the greater supersaturation required for nucleation in a small pore compared with a larger one we examine three migmatites in detail a contact metamorphosed cherty band from an iron formation an archaean regional granulite from an accretionary prism and an amphibolite facies sample from the roots of an archaean mountain chain the greater undercooling required for nucleation in progressively smaller pores is recorded by the composition of plagioclase pseudomorphs a study of dihedral angles at the corners of pseudomorphed pores demonstrates that melt solid textural equilibrium was probably attained only in the contact aureole the regional granulite preserves an almost unmodified reaction controlled melt distribution with little evidence for either melt solid textural equilibration or solid solid re equilibration whereas the reactioncontrolled melt distribution in the regional amphibolite facies example has been modified by a partial approach to solid solid textural equilibrium it is not clear whether the differences in dihedral angle population are due to differences in uplift and exhumation rates or due to the presence of h2o on grain boundaries

large scale melt depletion in granulite terranes an example from the archean ashuanipi subprovince of quebec this study uses field petrographic and geochemical methods to estimate how much granitic melt was formed and extracted from a granulite facies terrane and to determine what the grain and outcrop scale melt flow paths were during the melt segregation process the ashuanipi subprovince located in the north eastern superior province of quebec is a large 90 000 km2 metasedimentary terrane in which 85 of the metasediments are of metagreywacke composition that was metamorphosed at mid crustal conditions 820 900 c and 6 7 kbar in a late archean dextral transpressive orogen decrease in modal biotite and quartz as orthopyroxene and plagioclase contents increase together with preserved former melt textures indicate that anatexis was by the biotite dehydration reaction biotite quartz plagioclase melt orthopyroxene oxides using melt orthopyroxene ratios for this reaction derived from experimental studies the modal orthopyroxene contents indicate that the metagreywacke rocks underwent an average of 31 vol partial melting the metagreywackes are enriched in mgo cao and feot and depleted in sio2 k2o rb cs and u have lower rb sr higher rb cs and th u ratios and positive eu anomalies compared to their likely protolith these compositions are modelled by the extraction of between 20 and 40 wt granitic melt from typical archean low grade metagreywackes a simple mass balance indicates that about 640 000 km3 of granitic melt was extracted from the depleted granulites the distribution of relict melt at thin section and outcrop scales indicates that in layers without leucosomes melt extraction occurred by a pervasive grain boundary porous flow from the site of melting across the layers and into bedding planes between adjacent layers in other rocks pervasive grain boundary flow of melt occurred along the layers for a few to tens of centimetres followed by channelled flow of melt in a network of short interconnected and structurally controlled conduits visible as the net like array of leucosomes in some outcrops the leucosomes contain very little residual material 5 biotite orthopyroxene indicating that the melt fraction was well separated from the residuum left in situ as melt depleted granulite only 1 3 vol percentage melt remained in the melt depleted granulites hence the extraction of melt generated by biotite dehydration melting in these granulites was virtually complete under conditions of natural melting and strain rates in a contractional orogen

melt segregation in the continental crust distribution and movement of melt in anatectic rocks the grain and outcrop scale distribution of melt has been mapped in anatectic rocks from regional and contact metamorphic environments and used to infer melt movement paths at the grain scale anatectic melt is pervasively distributed in the grain boundaries and in small pools consequently most melt is located parallel to the principal fabric in the rock typically a foliation short branched arrays of linked melt bearing grain boundaries connect melt depleted parts of the matrix to diffuse zones of melt accumulation protoleucosomes where magmatic flow and alignment of euhedral crystals grown from the melt developed the distribution of melt leucosome and residual rocks normally melanocratic in outcrop provides different but complementary information the residual rocks show where the melt came from and the leucosomes preserve some of the channels through which the melt moved or sites where it pooled different stages of the melt segregation process are recorded in the leucosome melanosome arrays regions where melting and segregation had just begun when crystallization occurred are characterized by short arrays of thin branching leucosomes with little melanosome a more advanced stage of melting and segregation is marked by the development of residual rocks around extensive branched leucosome arrays generally oriented along the foliation or melting layer places where melting had stopped or slowed down before crystallization began are marked by a high ratio of melanosome to leucosome because most of the melt has drained away very few leucosomes remain to mark the melt escape path this is common in melt depleted granulite terranes many migmatites contain abundant leucosomes oriented parallel to the foliation mostly these represent places where foliation planes dilated and melt drained from the matrix via the branched grain boundary and larger branched melt channel leucosome arrays collected melt collected in the foliation planes was partially or fully expelled later when discordant leucosomes formed leucosomes or veins oriented at high angles to the foliation layering formed last and commonly lack melanocratic borders hence they were not involved in draining the matrix of the melting layer discordant leucosomes represent the channels through which melt flowed out of the melting layer

k rb sr ba u and th geochemistry of the lapland granulites fennoscandia lile fractionation controlling factors the lile geochemical patterns of the three main lithological units graywacke shale metasedimentary sequence tholeiitic metaigneous rocks and migmatitic rocks of the lapland granulite belt are described k ba sr and th concentrations in metasediments are nearly similar to average continental crust whereas rb and u are unevenly impoverished in particular graphitic metashales and calcsilicate rocks are not significantly depleted in uranium tholeiitic metaigneous rocks comprises metavolcanics which present k rb ratios similar to metasediments and metaplutonics with lile abundances close to those of the low k tholeiites migmatites show wide range in lile content metatexites and diatexites have higher k rb th and u concentrations and similar k rb ratios with respect to equivalent unmobilized rocks potassic pegmatoids are strongly enriched k rb ba and th but moderately in sr and u plagioclasic pegmatoids and ferromagnesian restites are rich in sr and poor in other lil elements

on the origin and fluid content of some rare crustal xenoliths and their bearing on the structure and evolution of the crust beneath the bakony balaton highland volcanic field w hungary rarely occurring clinopyroxene plagioclase bearing felsic granulite and skarn xenoliths were studied from the mantle and crustal xenolith bearing alkaline basaltic and pyroclastic localities of the bakony balaton highland volcanic field w hungary geobarometry and geothermometry of the xenoliths made it possible to categorise them in three groups according to their depth of formation the first group formed in the lower crust together with mafic and metasedimentary granulites the second group represents magmatic intrusions of the middle crust and the third one comprises contact metamorphic rocks of relatively shallow origin the calculated pressure difference from the core and rim compositions of plagioclase and clinopyroxene as well as garnet breakdown reactions in some xenoliths show evidence for pressure decrease due to crustal thinning both in lower crustal and middle crustal xenoliths during formation of the pannonian basin fluid inclusion studies reveal the dominance of the co2 rich fluids in the whole crustal section in contrast with fluids found in mafic garnet bearing xenoliths crustal stratigraphy was constructed for the periods prior to the extension and after the extension on the basis of geobarometry and geophysical data on the basis of mineral stabilities and geothermo barometry we estimated that the pre extensional thickness of the lower and upper crust may have been 27 34 and 26 28 km respectively comparison of pre extensional and present day thickness of the lower and upper crust indicate that thinning affected both the lower and the upper portion of the crust but on a different scale the calculated thinning factors are between 2 25 and 3 4 for the lower crust and 1 3 1 56 for the upper crust

petrology and u pb geochronology of the telohat migmatites aleksod central hoggar algeria the aleksod region is composed of metasedimentary rocks and large areas of biotite and hornblende bearing migmatites anatexis associated with the main deformation stages occurred under high pressure and temperature conditions estimated at 13 2 kbar and 750 50 c the bulk mineralogical composition of the telohat migmatites shows that their protolith was granodioritic internal structures of zircons and u pb data suggest a polyphased evolution with a 2131 12 ma age for the protolith and a 609 17 ma age for the pan african tectono metamorphic evolution thus precluding any kibaran event in the aleksod area leucosomes are richer in sr and display lower rb zr nb y th u and ree contents than melanosomes wherein accessory phases are stored eu contents are also lower in the leucosomes but in lesser proportion than the other rare earth s leading to a significant positive anomaly petrogenetic modelling accounting for accessory mineral phases clearly shows that the trace element contents of leucosomes and melanosomes follow a distribution law consistent neither with equilibrium nor fractional melting their trace element patterns are best explained by the model of disequilibrium melting with mixing of a few residual phases the present results and previous sr isotopic data as well raise the question of disequilibrium melting in anatexis of crustal material

migmatites formed by water fluxed partial melting of a leucogranodiorite protolith microstructures in the residual rocks and source of the fluid abstract the opatica subprovince in the canadian shield is a late archaean 2761 2702 ma plutonic arc formed above a north dipping subduction zone anatexis 2690 2677 ma of leucogranodiorite and leucotonalite orthogneisses in the opatica generated migmatites in an area of north vergent back thrusts visible at the surface and in l ithoprobe seismic profile 48 schollen diatexite migmatites occur in the thrusts and metatexite migmatites between them the modal mineralogy microstructure and whole rock major trace and oxygen isotope compositions of the protolith and migmatites were investigated to 1 determine the melting reaction 2 find microstructural criteria for identifying residual rocks in leucocratic systems where there is no melanosome and 3 to determine the source of the fluid involved in anatexis partial melting of the protolith did not change the mineral assemblage but the abundance of quartz and microcline both declined and plagioclase and biotite increased in the residual rocks quartz plagioclase and microcline show evidence for dissolution and biotite does not thus water fluxed melting of quartz plagioclase microcline occurred a mass balance indicates 25 30 partial melting the melting reaction consumed the microcline and created essentially monomineralic domains of plagioclase extraction of 80 90 of the melt left a thin film of melt on the grain boundaries and crystallization of these in the plagioclase domains created diagnostic microstructures microcline fills the last remaining pore space and forms high aspect ratio crystals between plagioclases or triangular crystals at grain junctions quartz shows a range of morphologies from high aspect ratio films through the string of beads to isolated rounded grains as the microstructure progressively equilibrated after crystallisation most accessory phases including zircon remained in the residuum however almost all the schollen migmatites have high contents of th u nb ta and ree relative to the protolith due to contamination by accessory phases derived from mafic rocks disaggregation of the mafic rocks may have been facilitated by the high strain in the back thrusts where the schollen diatexites formed average whole rock 18 o for the protolith and migmatites are similar ca 8 2 and the small difference between melt rich 8 6 and residuum rich rocks 8 0 is consistent with fractionation thus the fluid that caused melting was probably of metamorphic origin with 18 o similar to the protolith the seismic profile shows several reflectors extending to a present depth of 20 km ca 40 km in the late archaean under the migmatites these are the paths along which the metamorphic fluid migrated and generated the migmatites now at the surface a new type of neosome reported in this study may have formed along fractures that the fluids migrated along however these are peripheral pathways in the metatexites adjacent to the back thrusts and schollen diatexites

u pb geochronology of the opatica tonalite gneiss belt and its relationship to the abitibi greenstone belt superior province quebec u pb ages for zircon monazite and titanite from samples collected from two transects across the opatica tonalite gneiss belt in the superior province of quebec indicate that the belt contains rocks that are significantly older than those in the adjacent low grade northern abitibi belt tonalite and tonalite gneiss which make up most of the belt formed over an interval of 100 ma from pre 2800 to 2702 ma five samples have ages of ca 2807 13 2773 23 and 2702 3 ma zircon growth at 2718 2721 ma in the two oldest samples may record an early period of high grade metamorphism in the belt hornblende diorite monzodiorite and tonalite plutons were intruded at 2693 2696 ma particularly along the southern boundary with the abitibi belt these include the canet pluton at ma the lac ouescapis pluton at 2693 2 ma and the barlow pluton at 2696 3 ma pink granite plutons and dykes are the youngest intrusive rocks in the belt three samples have yielded zircon ages of 2690 2 and 2686 4 ma

topology of syntectonic melt flow networks in the deep crust inferences from three dimensional images of leucosome geometry in migmatites we have determined the three dimensional form of leucosome in two migmatites produced by syntectonic anatexis of different protoliths 1 stromatic migmatite derived from pelite which comprises sheets of leucosome quartzofeldspathic layers with grt with walls of melanosome bt rich selvages in mesosome schistose layers of bt pl qtz or grt or crd and 2 a migmatitic garnet amphibolite derived from basalt which is composed of spindle shaped leucosomes qtz pl spatially associated with peritectic grt in melanosome hbl qtz or cpx three dimensional images were generated from two dimensional representations of spatial data obtained by two methods 1 serial grinding and 2 high resolution x ray computed tomography hr x ray ct projections of three dimensional images of stromatic migmatite derived using data from either method show the planar nature of leucosome throughout the sample melt transport through this rock when it was partially molten could be modeled as flow in parallel conduits in the image derived from hr x ray ct data garnet in leucosome is only rarely in contact with melanosome which suggests these garnet grains were suspended in melt during flow projections of three dimensional images of the migmatitic garnet amphibolite do not reveal the full extent of leucosome connectivity due to the irregular geometry of leucosome connectivity in this sample can be shown however by virtual slicing of the three dimensional images perpendicular to the plane of the two dimensional representations approximately parallel to the lineation defined by the leucosome and by using three dimensional projections of a single leucosome connectivity tree constructed by projecting leucosome patches from slice to slice and noting the overlap based on leucosome geometry and volume we estimate effective porosity for flow in this rock to have been 20 vol at stagnation leucosome in the migmatitic garnet amphibolite occurs in strain shadows around garnet which are inferred to have been obstacles to flow along linear paths blocking of inferred flow channels by garnet contributes to the high degree of path length tortuosity in this sample tau 2 6 which is expressed visually by the complex form of the leucosome in three dimensions cross sectional areas for individual inferred melt flow paths are highly variable over 2 3 orders of magnitude and minimum channel radius is changeable by approximately 1 order of magnitude meaning there was large variability along the channels and implying strong local flow divergences based on these data unusually straight and uniform channels would have dominated the mesoscopic melt flux through this rock when it was partially molten

thermo tectonic evolution of an archean accretionary complex u pb geochronological constraints on granulites from the quetico subprovince ontario canada abstract u pb geochronological data have been obtained for a granulite zone in the quetico subprovince an archean accretionary complex of the superior province north of manitouwadge ontario canada this granulite zone represents the culmination of a low pressure high temperature regional metamorphism in the quetico subprovince and an apparent continuation of a northward increase in metamorphic grade in the wawa subprovince and across the quetico wawa boundary a u pb zircon age of 2666 1 ma from a concordant magnetite bearing granitic pegmatite in the quetico granulite zone is consistent with the inferred timing of regional metamorphism in amphibolite facies zones 2671 2665 ma and indicates that the low pressure high temperature metamorphism in the quetico subprovince commenced during the main compressional deformation titanite in a calc silicate rock from low leucosome fraction layered migmatites that might represent incipient melting gave a 207pb 206pb age of 2658 1 ma the timing of the granulite facies metamorphism is constrained by u pb zircon ages of 2650 2 and 2651 3 ma from mafic granulite and garnet bearing tonalitic leucosome respectively that are similar to reported u pb ages for mafic granulites in the upper levels of the kapuskasing structural zone the present u pb data suggest a diachronous development of peak metamorphic conditions of the regional metamorphism in the quetico and wawa subprovinces this diachronous development and the zonal distribution of the regional metamorphism are probably related to oblique collision at a convergent plate margin and differential rates of erosional uplift away from the quetico wawa boundary

formation and evolution of granite magmas during crustal reworking the significance of diatexites taylor mclennan 1985 the physical processes ina continuous section through reworked archaean crust records the volved particularly how granite magma is formed remain generation of granitic magma and its subsequent development in the controversial miller et al 1988 white chappell opatica subprovince in the canadian shield there the transition 1990 a partially melted source can form a granitic from palaeosome to granite was a closed system process through magma only if large volumes of melt are separated from intermediate stages of patch migmatite and diatexite the average most of their residuum understanding this process is degree of partial melting was less than 30 but the melt crucial to determining how crustal recycling and differfraction was redistributed within individual diatexite layers during entiation occurs for example melt residuum separation deformation regions that lost melt became residual diatexites could be a nearly perfect single stage process at the enriched in tio2 feot mgo cao sc cr co sr rare earth site of partial melting as described for leucosomes in elements ree and high field strength elements hsfe melt metatexite migmatites wickham 1987a sawyer 1991 accumulated to create diatexite magmas enriched in large ion 1994 brown et al 1995 alternatively the separation lithophile elements lile but contaminated with residuum macould be an imperfect multi stage process that yields a terial such diatexite magmas are parental to granites found at magma with a large residual component as is observed higher crustal levels in the terrane flow of the diatexite magma in in diatexite migmatites bea 1991 greenfield et al response to deformation separated some of its residuum into schlieren 1996 sawyer 1996 the metatexite model necessarily parautochthonous plutons were created where ascending granitic produces leucocratic residuum free granites such as magma locally ponded below impermeable layers and structures those described by le fort 1981 and montel et al magma left the anatectic region in dykes and lost its remaining residuum as it crystallized consequently the allochthonous granite 1991 and maximizes the geochemical signature of magmas that rose through 20 km of crust to feed the highest level crustal differentiation in contrast the diatexite model plutons in this region are highly fractionated and essentially free of can produce residuum rich granites and so reduce the residuum geochemical effect of crustal differentiation as chappell 1996 noted how anatectic magmas formed in the deeper crust evolve to the granitic magmas emplaced in the upper crust is also poorly known because few crustal sections

constraints on melting and magma production in the crust major intrusions of granitic rocks are found in several tectonic settings and in all cases crustal melts may contribute to the volumes of granitic magma high grade metamorphism and partial melting of the crust take place predominantly under fluid absent conditions we present a model for calculating the amounts of melt that may be formed by fluid absent breakdown of micas and amphiboles in common crustal rock types pelitic quartzofeldspathic intermediate and mafic melt proportions depend mainly on the kind of source rock the pressure at which melting takes place the temperature and the hydrous mineral h2o content of the source as a consequence of the pressure dependence of water solubility in silicate melts any given source rock will produce more melt by a given fluid absent reaction at lower pressure at a given pressure higher temperature reactions can produce more melt from a given source rock based on a survey of the compositions of common rock types we show that the amounts of melt can vary from 50vol thus crustal rocks vary widely in their fertility as magma sources depending on the types and amounts of hydrous phases they contain in general muscovite breakdown in pelites will yield only small quantities of melt and lead to migmatite formation biotite breakdown in pelites occurs at higher temperature and because most high grade pelites below granulite grade are biotite rich can yield up to about 50 vol of granitoid melt rocks of intermediate composition and hornblende rich mafic rocks are potentially highly fertile magma sources also provided that the high temperatures necessary for biotite and hornblende breakdown are realized pyroxene rich mafic rocks and quartzofeldspathic rocks are much less potentially fertile data suggest that mechanisms exist for the efficient segregation of melt and restite in systems with 30and probably 20vol melt the pressure temperature history of a region can greatly influence crustal source fertility through its control over the occurrence of subsolidus dehydration and melting equilibria

granite migmatite genetic link the example of the manaslu granite and tibetan slab migmatites in central nepal in central nepal the tibetan slab is made up of biotite gneisses metapelites and metagreywackes orthogneisses metagranites and migmatites melanosomes are generally biotite muscovite bearing but locally they may be tourmaline rich when associated with boron rich granitic material leucosomes occur as lenses conformable with the foliation veins patches or as fillings in shear zones and extensional structures field relationships and mineralogical and chemical data show that three processes may have contributed to the formation of the tibetan slab leucosomes metamorphic differentiation or disequilibrium partial melting low zr tonalitic leucosomes in situ equilibrium partial melting high zr leucosomes and some granitic leucosomes and injection of externally derived melts most granitic and some tonalitic leucosomes the manaslu pluton belongs to the high himalayan leucogranite belt and was emplaced at the top of the tibetan slab it corresponds to a muscovite biotite leucogranite that has been assumed to derive from melting of the tibetan slab gneisses formation i phase relationships a more magnesian chemistry of the ferromagnesian minerals from the tibetan slab migmatites as compared to the manaslu leucogranite the microtextures of accessory phases and trace element compositions lower u li f and higher sr eu y yb contents in the migmatite leucosomes show that the in situ himalayan migmatites at the crustal level presently exposed have not been produced under the same p t xh2o conditions as the manaslu leucogranite magma while the formation i was the probable source for the manaslu granite migmatites within the formation are not the remanants of a melting process from which the manaslu granite was derived both the tibetan slab migmatites and the manaslu leucogranite may be considered as evidence of dehydration and melting at deeper crustal levels and of percolation of melts and hydrothermal fluids through the crust

geological evolution of the manitouwadge greenstone belt and wawa quetico subprovince boundary superior province ontario constrained by u pb zircon dates of supracrustal and plutonic rocks fifty million years of archean evolution is recorded in the manitouwadge greenstone belt and the wawa quetico boundary region from ca 2720 ma volcanism and subvolcanic plutonism associated with m

empirical calibration of the silica ca tschermak s anorthite scan geobarometer the pressure sensitive equilibrium among anorthite quartz and the ca tschermak component in clinopyroxene caal2sio6 cats caal2siocpx6 sioqtz2 caal2si2opl8 scan can be used as a geobarometer in granulites with the proper assemblage and has been calibrated using mineral composition data from partial melting experiments of natural assemblages and from phase equilibrium experiments on the end member cmas system the experimental data cover the p t range 4 32 kbar and 900 1400 c linear least squares regression analysis of the experimental data resulted in the following empirical expressions for pressure in terms of composition and temperature p 5 066 0 760 1300 800 t lnk276 16 t 2 5 kbar orp 6 330 0 116 lnk301 9 t 1 0 kbar where k aplan acpxcats the first equation incorporates an enthalpy term but is less accurate than the second equation in which the enthalpy of reaction is ignored application of these expressions to natural and experimental equilibrium mineral assemblages demonstrates that the empirical barometers are applicable over a wide range of pressures 4 kbar temperatures 700 c and bulk compositions mg 32 5

the structural history of a part of the archaean quetico metasedimentary belt superior province canada abstract the first generation structures of the quetico metasedimentary belt are large scale recumbent folds which in the kashabowie area are northwestward vergent and facing that is they face towards the centre of the metasedimentary belt during this folding basaltic pillows were elongated normal to fold hinges and a schistosity was developed subsequent deformation has largely destroyed the schistosity but the pillow elongation remains although reoriented second generation tight to isoclinal upright folds are characteristic of the belt and have an associated prominent but not perfectly axial planar schistosity s 2 refolding of earlier folds causes second generation folds to be either upward or downward facing depending upon whether the present exposure level is either above or below the earlier fold axial surface third generation close to tight asymmetric folds which become markedly disharmonic or convoluted at the highest metamorphic grades crenulate and fold the subvertical s 2 schistosity towards the centre of the belt folding and generation of s planes pre dates the metamorphic peak in the central part of the belt and post dates metamorphism at the belt margin but deformation continued as the belt cooled post folding brittle and brittle ductile structures such as extension gashes shear fractures tension gashes and boudinage of post folding quartz veins all indicate layer parallel extension throughout the belt anisotropy within the metagrey wackes and metapelites controls the location of many of these minor structures the orientation and geometry of the structures indicate that an early period of gravitational instability in the adjacent shebandowan volcanic belt granite greenstone terrain produced recumbent folds directed towards the metasedimentary belt subsequently the quetico metasedimentary belt experienced subhorizontal shortening normal to and subhorizontal extension parallel to its axis for most of its history including both the heating and cooling stages

in situ migmatite and hybrid diatexite at mt stafford central australia metasedimentary gneisses show a rapid change in grade within a 10 km wide low p high t regional aureole at mt stafford arunta block central australia migmatites occur in all but the lowermost of five metamorphic zones which are characterized by 1 muscovite quartz schist 2 andalusite cordierite k feldspar granofels with small melt segregations 3 spinel sillimanite cordierite k feldspar migmatite 4 garnet orthopyroxene cordierite migmatite and minor diatexite and 5 biotite cordierite plagioclase diatexite that shows a transition to granite a subsolidus unit comprising interbedded sandstone and siltstone is equivalent to bedded migmatite the main rock type in zones 2 4 mesoscopic textures and migmatite classification of this unit vary with grade in zone 2 metatexite is developed in siltstone layers that are separated by quartz rich unmelted metapsammite layers melt segregation was less efficient in zones 3 and 4 where the dominant migmatite layering is a modified bedding high proportions of melt were present in zone 4 in which schlieren migmatite is transitional between bedded migmatite and metapelite sourced diatexite the preservation of sedimentary structures and coexistence of melt reactants and products in zone 4 metapelite imply that melting proceeded insitu without substantial migration of melt zone 5 biotite cordierite plagioclase diatexite carries rafts of bedded migmatite with strongly resorbed edges as well as large k feldspar and quartz augen this unit of comparatively ca rich migmatites is inferred to have been formed by the mixing of locally derived and injected granitic melt

fluid absent melting and the roles of fluids in the lithosphere a slanted summary abstract the presence or absence nature and compositions of lithospheric fluids are crucial factors in the evolution of igneous and metamorphic rocks despite this confusion still surrounds perceptions of the degrees of fluid involvement in many geological settings however experimental and field investigations constrain these roles and we are able to make some valid generalizations studies of prograde metamorphism have highlighted the spatial heterogeneity of fluid concentrations in many crustal environments this commonly indicates internal lithological control of volatile activities under fluid present conditions crustal fluids do not appear to mix readily fluid flow is generally structurally or lithologically controlled the transition from amphibolite to granulite facies is characterized by a decrease in ah2o as well as a temperature increase in many terranes these phenomena correlate with the appearance of migmatites some granulites are not migmatitic but have chemical and mineralogical characteristics of melt depleted restites this indicates efficient extraction of melts incongruent melting reactions involving the breakdown of crystalline hydrates in crustal rocks produce granitoid melts plus denser restites that are nearly or actually anhydrous experimental and theoretical treatments of fluid absent melting show that micas and amphiboles decompose at 700 to 900 c for mid to lower crustal pressures the melts resemble the compositions of s and i type granitoids pervasive aqueous fluids could not generally have been present during this melting since exposed granulite terranes are not characterized by high melt proportions and the magmas themselves are water undersaturated likewise the general presence of very h2o poor pervasive fluids is unlikely since this would allow only subsolidus dehydration at normally attainable crustal temperatures in this case the amphibolite granulite transition is possible at relatively low temperatures and the resultant rocks would not contain evidence of in situ melting the granulite granite connexion and effective crustal differentiation seem viable only during high temperature fluid absent metamorphism data on continental geotherms show that the lower crust is not entirely granulitic granulites are produced in regions of anomalously high heat flow the mantle connexion thus inferences on the nature of the lower crust should not be entirely based on studies of exposed granulite terranes mineral assemblages in eclogites also indicate widespread internal buffering of volatile activities and probable fluid absent conditions mantle derived basaltic magmas too are volatile bearing and it is plausible that volatile fixing phases also occur in the mantle volatiles may largely be introduced into the mantle through subduction processes and only released during the melting attending the breakdown of hydrous minerals as in the crust

internal differentiation of the archean continental crust fluid controlled partial melting of granulites and ttg amphibolite associations in central finland fault bound blocks of granulite and enderbite occur within upper amphibolite facies migmatitic tonalitic trondhjemitic granodioritic ttg gneisses of the iisalmi block of central finland these units record reworking and partial melting of different levels of the archean crust during a major tectonothermal event at 2 6 2 7 ga anhydrous mineral assemblages and tonalitic melts in the granulites formed as a result of hydrous phase breakdown melting reactions involving amphibole at peak metamorphic conditions of 8 11 kbar and 750 900 c a nominally fluid absent melting regime in the granulites is supported by the presence of carbonic fluid inclusions the geochemical signature of light rare earth element lree depleted mafic granulites can be modelled by 10 30 wt partial melting of an amphibolite source rock leaving a garnet bearing residue the degree of melting in intermediate granulites is inferred to be less than 10 wt and was restricted by the availability of quartz pressure temperature estimates for the ttg gneisses are significantly lower than for the granulites at 660 770 c and 5 6 kbar based on the p t conditions melting of the ttg gneisses is inferred to have occurred at the wet solidus in the presence of an h 2 o rich fluid a hydrous mineralogy abundant aqueous fluid inclusions and the absence of carbonic inclusions in the gneisses are in accordance with a water fluxed melting regime low ree contents and strong positive eu anomalies in most leucosomes irrespective of the host rock composition suggest that the leucosomes are not melt compositions but represent plagioclase quartz assemblages that crystallized early from felsic melts furthermore similar plagioclase compositions in leucosomes and adjacent mesosomes are not a migmatite paradox as both record equilibration with the same melt phase percolating along grain boundaries

petrogenesis of migmatites in maine usa possible source of peraluminous leucogranite in plutons high t low p facies series conditions during deformation within a devonian crustal scale shear zone system defined by kilometer scale straight belts of apparent flattening strain that anastomose around lozenges of apparent constrictional strain at upper amphibolite facies grade metapelites are partially melted the onset of which is introduction

the exhumation of the indo burman ranges myanmar abstract the indo burman ranges ibr are a mountain range comprised of mesozoic cenozoic rocks which run the length of western myanmar extending into india and bangladesh to the west lies the indian ocean and to the east lies the central myanmar basin cmb along which the irrawaddy river flows the ibr are considered to be an accretionary prism developed at the juncture of the indian and sunda plates and a number of hypotheses have been proposed for their evolution however in order for these hypotheses to be evaluated the timing of ibr evolution needs to be determined we undertook a two pronged approach to determining the timing of uplift of the ibr 1 we present the first low temperature thermochronological age elevation profiles of the ibr using zft aft and zhe techniques our data show a major period of exhumation occurred around the time of the oligo miocene boundary we tentatively suggest subject to further verification an additional period of exhumation at or before the late eocene 2 we carried out a detailed multi technique provenance study of the sedimentary rocks of the ibr and arakan coastal region to their west and compared data to coeval rocks of the cmb we determined that during eocene times rocks of the cmb and ibr were derived from similar local provenance that of the myanmar arc to the east therefore at this time there was an open connection from arc to ocean by contrast by miocene times provenance diverged rocks of the cmb were deposited by a through flowing irrawaddy river with detritus derived from its upland source region of the mogok metamorphic belt and cretaceous paleogene granites to the north such a provenance is not recorded in coeval rocks of the ibr indicating that the ibr had uplifted by this time providing a barrier to transport of material to the west to the previously published list of viable proposals to explain the exhumation of the range we add a new suggestion the period of exhumation around the time of the oligo miocene boundary could have been governed by a change to wedge dynamics instigated by a major increase in the thickness of the incoming bengal fan sediment pile

the age and provenance of metasedimentary rocks in the quetico subprovince ontario from single zircon analyses implications for archean sedimentation and tectonics in the superior province abstract u pb isotopic analyses have been performed on single detrital zircon grains from greywacke samples collected along the northern boundary of the quetico subprovince in northwest ontario secondary lead loss was virtually eliminated by choosing crack free grains and removing the outer surface using air abrasion thus the 207 pb 206 pb age can be considered a good approximation to the age of crystallization of each grain zircons in the quetico metasediments show a range of ages from 2698 3 ma to 3009 4 ma deposition and metamorphism of the metasediments is bracketed within a 10 5 ma time span between crystallization of the youngest detrital zircon grain and a late tectonic intrusion the blalock pluton which cuts the sediments and has a zircon age of 2688 4 ma the most easterly metasediment sample contains zircons with ages which cluster around 3007 6 ma which is within error of the age of a batholith dated in the adjacent marmion lake area of the wabigoon subprovince this along with the fact that most detrital zircons were only slightly abraded by sedimentary transport suggests that the source of many zircons may have been proximal from the north there is also a significant cluster of young zircon ages in the range 2698 2709 ma surprisingly only a few ages correspond to the time of most intense arc type felsic volcanism 2710 2745 ma in the main greenstone belt of the western wabigoon subprovince sedimentary deposition occurred at a time of extensive deformation in the adjacent wabigoon subprovince the pattern of detrital grain ages indicates that this involved uplift of a complex older sialic landmass petrographic evidence for the presence of substantial felsic volcanic detritus as well as the fact that many of the zircons only slightly pre date deposition indicates that much of the sediment was probably derived from erosion of active felsic volcanic centers these data combined with regional geochronological and field studies favour deposition in a basin formed by late orogenic collisional events

melt production during granulite facies anatexis experimental data from primitive metasedimentary protoliths we conducted fluid absent partial melting experiments at 0 5 and 1 0 gpa in the temperature range 750 to 1000 c to investigate the influence of bulk rock mg 100mg mg fe and the effects of additional tio2 on the granulite grade anatectic evolution of relatively magnesian metapelites and metagreywackes in these experiments melting began between 780 and 830 c by the incongruent breakdown of biotite to produce quartz saturated granulite facies residual mineral assemblages in equilibrium with h2o undersaturated granitic melt the glass quenched melt compositions produced in this study vary little generally the glasses have compositions similar to those of many natural strongly peraluminous leucogranites the solidus temperatures in both rock types increase with increasing mg but are unaffected by the presence or absence of a tio2 component at 0 5 gpa the metapelites melted at temperatures up to 50 c lower than the equivalent metagreywackes but at 1 gpa there was no discernible difference this study suggests that the fluid absent solidus has a steep positive dp dt slope in metapelites and steep negative dp dt slope in metagreywackes the pattern of melt production with increasing temperature is strongly controlled by the upper limit of biotite stability in tio2 free compositions this was found to increase by 15 to 20 c in the metapelites and by 30 to 40 c in the metagreywackes as a function of increasing mg from 49 to 81 the presence of a tio2 component increases the upper limit of biotite stability by 50 c in the metapelites and by 80 c in the metagreywackes over that observed in the equivalent tio2 free compositions in consequence in the tio2 free samples large pulses of melt up to 35 wt are produced over narrow temperature ranges as little as 15 c in these experiments between 830 and 875 c in the tio2 bearing samples the major pulse of melt production occurs more gradually between 830 and 900 c

fluid absent melting behavior of a two mica metapelite experimental constraints on the origin of black hills granite we have studied experimentally the vapor absent melting behavior introduction of a proterozoic metapelite hp 60 1 from the black hills south peraluminous leucogranites such as the miocene granites dakota to assess whether the high do tourmaline bearing granites of the himalaya and tourmaline granites of the harney of the harney peak suite resulted from muscovite dominated depeak suite in south dakota are widely considered to be hydration melting at 10 kbar samples were sealed with no added the product of muscovite dehydration melting yet few h2o in gold capsules then run in a 0 5 inch 1 27 cm pistonexperimental studies of muscovite dehydration melting cylinder apparatus over the temperature interval 812 975 c reactions have been performed because the low temexperiments were conducted at 10 kbar to allow comparison with peratures of the reactions hinder the approach to equiother metapelite melting studies mass balance calculations imply librium in addition melt fractions generated are typically the melting reaction muscovite biotite plagioclase quartz low resulting in small melt pockets which are very difficult melt alkali feldspar aluminosilicate garnet until to analyze with the electron microprobe in this study muscovite is exhausted 812 c then the reaction biotite we assess the possible genetic relationship between the plagioclase quartz alkali feldspar aluminosilicate tourmaline bearing granites of the harney peak suite melt garnet the inferred muscovite reaction is completed below and the aluminous metasediments these granites intrude 812 c and produces 1 2 wt melt melt production of the although the attempt to investigate the muscovite decontinuous biotite reaction increases steadily with rising temperature hydration melting reaction was hindered by the surto 32 wt in our highest temperature run the low melt prisingly low melt productivity we were able to infer a productivity of the muscovite reaction at 10 kbar suggests that balanced reaction illuminating the dominantly peritectic melting at lower pressures may be necessary to generate mobile melt nature of fluid absent muscovite breakdown under the fractions by muscovite dominated reactions in our starting material conditions investigated in addition melts of hp 60 1 are considerably more mafic than isotopic and trace element studies indicate a genetic the tourmaline bearing granites with average combined tio2 relationship between s type granites and aluminous metamgo feo contents of 1 85 wt and 0 84 wt respectively sediments in the black hills of south dakota where the in particular melts of hp 60 1 are enriched in ti and would harney peak granite hpg intruded proterozoic and probably stabilize biotite rather than tourmaline upon cooling archean schists and metagreywackes undergoing regional arguing against hp 60 1 as a potential source rock for the metamorphism the timing and mode of emplacement of tourmaline granites the hpg and the deformation and regional metamorphic

partial melting and the formation of granulite facies assemblages in namaqualand south africa abstract dehydration melting reactions in which water from a hydrous phase enters the melt leaving an anhydrous solid assemblage are the dominant mechanism of partial melting of high grade rocks in the absence of externally derived vapour equilibria involving melt and solid phases are effective buffers of ah2 o the element partitioning observed in natural rocks suggests that dehydration melting occurs over a temperature interval during which for most cases ah2o is driven to lower values the mass balance of dehydration melting in typical biotite gneiss and metapelite shows that the proportion of melt in the product assemblage at t 850 c is relatively small 10 20 and probably insufficient to mobilize a partially melted rock body granulite facies metapelite biotite gneiss and metabasic gneiss in namaqualand contain coarse grained discordant unfoliated anhydrous segregations surrounded by a finer grained foliated matrix that commonly includes hydrous minerals the segregations have modes consistent with the hypothesis that they are the solid and liquid products of the dehydration melting reactions bt sil qtz pi grt crd kfs l metapelite bt qtz pl opx kfs l biotite gneiss and hbl qtz opx cpx pl l metabasic gneiss the size shape distribution and modes of segregations suggest only limited migration and extraction of melt growth of anhydrous poikiloblasts in matrix regions development of anhydrous haloes around segregations and formation of dehydrated margins on metabasic layers enclosed in migmatitic metapelites all imply local gradients in water activity also they suggest that individual segregations and bodies of partially melted rock acted as sinks for soluble volatiles the preservation of anhydrous assemblages and the restricted distribution of late hydrous minerals suggest that retrograde reaction between hydrous melt and solids did not occur and that h2o in the melt was released as vapour on crystallization this model combined with the natural observations suggests that it is possible to form granulite facies assemblages without participation of external fluid and without major extraction of silicate melt

tectonic pumping of pervasive granitic melts finite element 2d models are used to study how tectonic stresses pump pervasive granitic melts within migmatites we start by assuming elliptical melt filled veins of different orientations interconnected by the assumption that they share the same pressure the melt is then redistributed in the vein array by the application of lateral compression or extension the effective permeability of vein networks is thought to be up to 13 orders of magnitude higher than the matrix permeability of 10 19 m2 this allows us to approximate pressure equilibration and neglect irreversible compaction in the matrix this simple configuration allows solution of constitutive equations for the equation of state in the viscoelastic matrix the melt in the vein array and the mechanical equilibrium along with force balance on the walls of the deforming veins a rectangular box is pressurized by a constant load applied to one side and continuously deformed by shift of another side with constant velocity new veins cannot initiate and pre existing veins cannot migrate bodily down pressure gradients however potential flaws are cut in line with the tip of every pre defined vein this means that veins not only close open and shear as they rotate but can also undergo limited propagation at rates dictated by the bulk deformation of the matrix we use constant viscosities s in the range 1017 1018 pa s deformation rates e vary between 10 10 and 10 9 s 1 and a total strain up to 4 5 isolated veins parallel and normal to 1 have melt pressures between p0 and p0 4 se the mean vein pressure differs from these extremes and is equilibrated by driving melt from shrinking veins into veins parallel to 1 which widen and lengthen the above assumptions result in an asymptotic pattern of stress distribution and the amount of melt redistributed at given strain approaching the kinematic limit with time this occurs whatever the viscosity of the matrix and the strain rate multilayered systems are modeled by pre defining a single vertical vein crossing the planar horizontal boundary between two uniform media compression parallel to the layering expels melt from the part of the vein in the more viscous layer to open and extend that part of the same vein in the less viscous layer melt moves in the opposite direction during lateral extension if sheet like bodies become sufficiently tall to become buoyant horizontal sheets resulting from lateral compression are likely to rise to higher crustal levels as diapirs while vertical sheets resulting from lateral extension are more likely to ascend as dikes

structure of the high grade opatica belt and adjacent low grade abitibi subprovince canada an archaean mountain front plutonic gneisses in the archaean opatica belt in canada record crustal scale wsw vergent i e longitudinal high temperature d1 ductile shearing similar structures occur in adjacent greenstone belts but only in narrow amphibolite facies zones near the base metavolcanics in the greenschist facies portions do not record penetrative d1 structures the greenstone belts are interpreted as allochthonous on the gneisses they form the uppermost d1 thrust sheets sse vergent i e approximately transverse d2 thrusting imbricated the opatica belt and formed a large antiform either a culmination or an antiformal stack in the southern opatica the imbricated opatica belt wedged under the northern part of the abitibi subprovince and created a tight syncline with nnw vergent d2 thrusts interpreted as backthrusts on its northern limb the opatica belt abitibi subprovince contact therefore resembles some phanerozic mountain fronts further southwards propagating imbrication of the crust beneath the abitibi subprovince created a s vergent foreland fold and thrust belt in the overlying greenstones high grade opatica gneisses and adjacent low grade abitibi greenstones contain complementary structural patterns and may therefore represent the internal and foreland parts of an archaean mountain belt similar in many respects to phanerozoic examples

migmatization and secondary granitic magmas effects of emplacement and crystallization of primary granitoids in southern bohemia austria the sauwald and muhl zones of the prebatholithic moldanubian middle crust in northern austria contain metapelites and metaluminous to weakly peraluminous metagreywackes respectively both zones were affected by low pressure high temperature metamorphism and anatexis the metapelites of the sauwald zone became in situ diatexites probably by fluid absent reactions involving the breakdown of muscovite and the partial breakdown of biotite the biotite plagioclase quartz gneisses of the muhl zone experienced only slight melting following this event and while the mid crust was still hot additional heat was locally advected into the muhl zone by the intrusion of the weinsberg granite this brought about fluid present partial melting of the biotite plagioclasequartz gneisses producing relatively large volumes of metaluminous to weakly peraluminous i type schlieren granite this cool wet restite rich magma remained close to its site of generation thus infracrustal i type granitoids may be formed anywhere in the crust and not always at high t under special circumstances the heat and fluids from granitic magmas can spawn secondary granites also relatively low initial 87sr 86sr values of around 0 707 in i type rocks do not necessarily indicate either lower crustal magma sources or mixing with mantle derived magma the weinsberg granite magma came from the lower crust p probably 700 mpa where widespread fluid absent breakdown of biotite plagioclase quartz assemblages occurred the necessary high heat flow was probably provided by newly underplated mafic magmas however these seem not to have mixed or mingled with the crustally derived weinsberg magmas deep equivalents of the muhl zone metagreywackes may have formed the weinsberg protolith fluid absent experiments show that the melting temperature probably exceeded 850 c and that a garnet bearing orthopyroxene rich residue should be present in the lower crust fluid present experiments demonstrate that the availability of free h2o can radically alter the characteristics of the partial melts from apparent s type mineralogy with fluid absent melting to i type mineralogy with wet melting

orthopyroxene poikilitic tonalites of the desliens igneous suite ashuanipi granulite complex labrador quebec canada the ashuanipi complex of the archean superior province consists of an older sequence of sedimentary rocks cut by sills and goblet shaped intrusions of the desliens igneous suite dis the complex was regionally metamorphosed to granulite facies and subsequently intruded by peraluminous granodiorite batholiths tonalites of the dis contain characteristic 2 cm inclusion filled orthopyroxene crystals of probable igneous origin variably recrystallized and overgrown by garnet biotite and blocky orthopyroxene that suggest metamorphic p t conditions of 0 5 0 62 gpa and 750 850 c andesine in tonalite contains abundant drop like quartz inclusions inclusion filled pyroxene and plagioclase are both inferred to have nucleated on partly resorbed quartz and plagioclase grains within a melt similar poikilitic textures characterize subordinate leucotonalite diorite gabbro and pyroxenite which together with tonalite make up the dis some of the petrological characteristics of the suite are unusual but known

melt producing versus melt consuming reactions in pelitic xenoliths and migmatites abstract melt producing reactions have operated both in pelitic xenoliths and in pelitic migmatites but melt consuming reactions related to in situ melt crystallization are largely restricted to migmatites hence xenolith reaction textures may provide clues on the relative roles of both reaction types in migmatites a comparison of xenoliths and migmatites results in a catalogue of textural and chemical features some of which are argued to be diagnostic the results have implications for the identification of restite in igneous rocks and for the relative importance of prograde and retrograde processes in different domains of layered migmatites