interplay between subduction retreat and lateral extrusion tectonics of the western carpathians 1 analysis of brittle microstructures reveals three tertiary deformation events in the western carpathians 1 late paleogene bedding parallel extension 2 oligocene to middle miocene nne ssw compression and ese wnw extension 3 post mid miocene nw se extension these regional deformations applied to crustal blocks in the intra carpathian region resulted from forces which were induced by the coupled plate tectonic processes of subduction retreat beneath the carpathian arc and lateral extrusion from the eastern alps toward the carpathian region material flow from the alps spread toward east and ne guided by sinistral strike slip zones along the ne trending continental margin subduction retreat was terminated by mid miocene soft collision of the inner western carpathians with the european foreland ongoing subduction retreat beneath the eastern carpathians caused post mid miocene back arc extension forming the pannonian basin extension spread into the western carpathians by reactivating the extrusion related strike slip faults as normal faults

evolution of retreating subduction boundaries formed during continental collision retreating subduction boundaries formed where the rate of subduction exceeds the rate of overall plate convergence appear to be commonly developed features within regions of early or incomplete continent continent collision they are characterized by regional extension within the overriding plate and at their leading edge by thin skinned arcuate thrust belts that are concave towards the overriding plate as is illustrated by examples from the mediterranean region the formation of retreating subduction boundaries is intimately related to the process of continental collision during the early stages of collision retreating subduction boundaries are commonly formed by lateral ejection from zones of crustal shortening along the main collision boundary retreating plate boundaries can also form before the main collision and the associated thrust belts emplaced as precollisional accretionary assemblages because the driving mechanism for retreating subduction boundaries appears to be gravity acting on a dense subducted slab slab pull subduction usually ceases when and only when thick buoyant continental crust enters the subduction zone thus differences in the evolution and duration of retreating subduction systems can be largely attributed to the size and configuration of the deep water regions available to be subducted in some cases retreating subduction boundaries may escape into the open ocean where they form nearly isolated local tectonic systems in these systems the rate of subduction is approximately compensated by the rate of upper plate extension and migration of the system across the oceanic region may be very rapid for example the horseshoe seamounts located about 800 km offshore in the eastern north atlantic may be the active expression of an east dipping westwardly migrating retreating subduction boundary that has evolved from the betic cordillera rif system active in miocene time and may now be progressing across the atlantic at approximately 50 mm yr an analogous situation may be represented by the scotia arc system a westward dipping retreating subduction system located between the south american and antarctic plates which may have escaped into the south atlantic ocean from a zone of crustal shortening in the andes and is now progressing across the atlantic at a rate of about 80 mm yr

ar ar dating of adularia a tool in understanding genetic relations between volcanism and mineralization baia mare area gutii mountains northwestern romania

timing of rotational motion of apuseni mountains romania paleomagnetic data from tertiary magmatic rocks paleomagnetic results are reported from 8 sites in eocene to oligocene magmatic rocks and 27 sites in middle miocene to upper miocene volcanic rocks of the apuseni mountains following af demagnetization 29 sites were selected for tectonic interpretation these results together with previously published data imply a northward displacement of the area studied between the late cretaceous and oligocene followed by a large clockwise rotation prior to the middle miocene after which no significant movement has occurred these results agree with other data from the carpatho pannonian domain showing a period of great mobility during the early miocene

slab breakoff a model for syncollisional magmatism and tectonics in the alps slab breakoff is the buoyancy driven detachment of subducted oceanic lithosphere from the light continental lithosphere that follows it during continental collision in a recent paper davies and von blanckenburg 1994 have assessed the physical conditions leading to breakoff by quantitative thermomechanical modeling and have predicted various consequences in the evolution of mountain belts breakoff will lead to heating of the overriding lithospheric mantle by upwelling asthenosphere melting of its enriched layers and thus to bimodal magmatism breakoff will also lead to thermal weakening of the subducted crustal lithosphere thereby allowing buoyant rise of released crustal slices from mantle depths in this paper we present a test of this model in the tertiary evolution of the european alps in the alps both basaltic and granitoid magmatism occur between 42 and 25 ma following the closure of oceanic basins by subduction and continental collision the granitoids are now well established to result from mixing of basalt with assimilated continental crust to identify the tectonically crucial origin of the partial mantle melts we have compiled all published geochemical and isotopic data of numerous mafic dykes occurring throughout the whole alpine arc their trace element and isotopic composition suggests that they have been formed by low degree melting of the mechanically stable lithospheric mantle we see no evidence for melting of asthenospheric mantle it was thus not decompressed to depths shallower than 50 km once initiated rapid lateral migration of slab breakoff will result in a linear trace of magmatism in locally thermal weakened crust this explains why all alpine magmatic rocks intruded almost synchronously along a strike slip fault the periadriatic lineament a compilation of ages from penninic high pressure rocks subducted to depths of up to 100 km shows that subduction took place at circa 55 40 ma followed by uplift at 40 35 ma from the short time interval between their uplift and the onset of magmatism we infer that both processes have been induced by the breakoff the slab breakoff model fulfills its predictions in the case of the alps and therefore supports the assumptions made in the theoretical model on a geological basis we believe that the characteristic association of magmatic activity with the return of high pressure rocks to the surface allows the identification of this process in the earth s mountain belts

neogene quaternary magmatism and geodynamics in the carpathian pannonian region a synthesis in the carpathian pannonian region in neogene times westward dipping subduction in a land locked basin caused collision of two lithospheric blocks alcapa and tisia with the southeastern border of the european plate calc alkaline and alkaline magmatism was closely related to subduction rollback collision and extension from the spatial distribution of the magmatic activity four segments can be defined western segment magmatism occurring on the alcapa block central segment magmatism occurring on both alcapa and the tisia blocks south eastern segment and interior segment both on the tisia block most calc alkaline magmatism in the region resulted from melting of a heterogeneous asthenospheric mantle source modified by addition of fluids and sediment assimilation and fractionation processes at shallow crustal levels occurred in most of the segments strongly masking the deeper source processes long term subduction rollback and or delamination led to contamination of the asthenosphere beneath the western segment here large volume partial melts of the contaminated mantle caused underplating and crustal anatexis leading to mixing of mantle derived calc alkaline magmas with crustal melts in the central segment calc alkaline magmas were formed by subduction and rollback followed by back arc extension and slab breakoff avariable mantle source is indicated in the back arc setting and larger amount of fluid induced metasomatism source enrichment and assimilation nearer to the trench in the interior segment evolution from typical calc alkaline magmas to adakite like ones was related to extension due to fast rotations and transtensional tectonics here calc alkaline magmas formed by decompression melting of a heterogeneous crust mantle lithosphere while adakite like melts resulted from fliud dominated melting of the lithosphere along the south eastern segment slab breakoff was responsible for the generation of typical calcalkaline magmas but in the extreme south of the segment shallow level tearing of the slab followed breakoff strike slip tectonics allowed the rise of hot asthenosphere and generation of adakite like magmas via slab melting along the torn edge of the east european plate alkalic basaltic volcanism with an oib like asthenosphere source followed the calc alkaline stage

towards a mechanical model for the formation of the pannonian basin abstract new maps showing crustal and lithospheric thickness variations in the pannonian basin and the surrounding east alpine carpathian and dinaric mountains have been prepared on the basis of recent seismic seismologic and electromagnetic data a map presenting miocene faults of regional significance has been also constructed for the same region by using a wealth of recently available national and or more local studies it is suggested that observed crustal and lithospheric structural contrasts have been controlled primarily by neogene kinematic history of the region kinematic history is characterized by the following main patterns 1 1 indentation by adria and large scale backthrusting in the southern alps 2 2 eastward escape and extension of the eastern alps 3 3 extensional collapse in the pannonian basin area 4 4 formation of broad wrench fault systems along strike in the dinarides and southern carpathians and the western carpathians with dextral and sinistral shear respectively 5 5 compression and accretion of the external thrust and fold belt in the eastern carpathians these kinematic patterns are thought to be interrelated and all are manifestations of the late stage evolution of an overthickened orogenic wedge in order to arrive at a better understanding of the mechanism of extension which formed the pannonian basin deep crustal seismic profiles hydrocarbon exploration reflection lines and borehole data have been analyzed in the little hungarian plain this plain represents the transition zone between the alps and the pannonian lowlands and the results are illustrated by eight interpreted cross sections one result of regional importance is the clear recognition that the transdanubian central range at the southeastern flank of the little hungarian plain is composed of alpine pre senonian thrust sheets this finding marks the end of a century of debate the allochthony of the substrata of the pannonian basin can be now considered proven another result of more general interest is that these cross sections document the mode of lithospheric extension preexisting compressional detachment planes reactivate as low angle normal faults and lead to tectonic unroofing of deeply buried metamorphic terranes characterized by ductile flow along subhorizontal lineation

on late oligocene to pliocene depocentre migrations and the evolution of the carpathian pannonian system abstract the late oligocene to pliocene evolution of foredeep basins of the eastern alps carpathians fold and thrust belt is marked by pronounced internal to external and lateral depocentre shifts the latter shifts covering a present along arc distance of 1700 km portray accelerating rates of foredeep depocentre migration particularly so in the late early and in the middle miocene from about 7 to about 45 cm yr lateral depocentre migration came to a close at the beginning of the late miocene the subsequent late miocene to pliocene foredeep infill history was characterized by exponentially increasing accumulation rates in the intersection area of the east european ukrainian and moesian platforms successive steps in the evolution of the foredeep basins had pronounced counterparts in the intra carpathian area the beginning of acceleration of foredeep depocentre migration in latest early miocene times was coeval with the inception of intra carpathian extensional tectonics the extremely rapid middle miocene depocentre shift coupled with a change in direction of foredeep depocentre migration corresponded with maximum extension in the intra carpathian area the ensuing end of foredeep depocentre migration around the middle late miocene transition was coeval with the end of extension of the intra carpathian area which in turn was followed by the inception of overall thermal subsidence at about 11 5 ma the timing of and spatial relationships between discrete coeval events in arc and intra arc evolution put unambiguous geological constraints on geodynamic modelling of the evolution of the carpathian pannonian system it is speculated that the geological observations may best be understood in terms of the surficial effects of lateral migration of slab detachment such effects would mirror the dominant role of a concentrating slab pull taken to result in e g a time progressive acceleration of foredeep depocentre migration

palaeogeography subsidence and thermal history of the neogene styrian basin pannonian basin system austria abstract the neogene styrian basin represents an extensional structure on top of a crustal wedge which was moving eastward during the final stages of the alpine orogeny eastward extrusion was a consequence of continental escape and extensional collapse within the eastern alps in a simple model the evolution of the styrian basin can be subdivided into an early miocene ottnangian to karpatian synrift and a subsequent postrift phase basement subsidence rates during the synrift phase reached 30 cm 100 yr and more than 2000 m of limnic to marine sediments were deposited the coincidence of the synrift phase and the formation of pull apart structures along strike slip zones bordering the eastward moving wedge is evidence for the close genetic relation between extrusion tectonics and basin formation a miocene magmatic phase is related to subduction along the carpathian front magmatic activity started during the synrift stage and continued into the postrift stage heat flow in the vicinity of the miocene volcanoes increased dramatically 300 mw m2 a second volcanic phase producing basalts in plio pleistocene times had only little influence on the heat flow pattern limnic to marine sediments of the synrift stage are separated by a major unconformity from middle to late miocene badenian to pontian marine to limnic fluvial postrift sediments sedimentation during the postrift phase was controlled by marine ingressions during middle miocene early badenian and sarmatian times from the south and a subsequent regression with a decline in salinity subsidence rates during the postrift stage were mostly below 2 5 cm 100 yr in pliocene times subsidence was replaced by uplift which resulted in erosion of a few hundred metres of sediment present day high heat flows are a consequence of thinned crust beneath the styrian basin

thermo mechanical controls on the mode of continental collision in the se carpathians romania abstract the carpathians orogenic system with its along arc variations in topography developed in the aftermath of continental collision is associated with unusual foredeep basins large scale strain and seismicity concentration and high velocity mantle bodies the east carpathians continental collision was non cylindrical leading to large scale variations in thrust nappe kinematics orogenic uplift patterns and foredeep subsidence controlled by the mechanics and geometry of the lower plate thermo mechanical modelling demonstrates that in this low rate convergence regime the subducted lithosphere had enough time to interact with the mantle to advance towards a thermal resettlement this is favored by the low degree of metamorphism mechanical weakness of the lower plate and the lack of active surface processes at the contact with and in the upper plate in contrast low buoyant thick lower crust and active surface processes keep the continuity of the slab intact and promote the development of typical foredeep basins the model explains in a self consistent manner the unusual geometry of the vrancea seismogenic slab in the bend zone of the romanian carpathians the model is also consistent with the presence of two high velocity bodies inferred from seismic tomography studies and explains the depth zonation of seismicity in the vrancea area differences between the northern part of east carpathians and the southeastern bend of the carpathians arc are largely controlled by lateral variations in crustal structure topography emplacement and surface processes along the arc mechanical heterogeneity of the carpathians subduction leads to the development of two end member modes of collision allowing a study of these states and their transition lithospheric configuration and tectonic topography appear to be prime factors controlling variations in slab behavior in the se carpathians at the terminal phase of continental convergence slab delamination roll back and depocenter migration appear to play a more limited role at shallow and lithospheric levels

kinematic evolution of the romanian carpathians abstract the regional pattern of contraction and extension directions and the evolution of the strain field from paleogene to neogene times enabled a reconstruction of the migration path of the carpathian collision front the carpathian nappes were thrust around the moesian plate during paleogene and early neogene times and protruded into a small oceanic embayment between the moesian and european plates the arc structure of the carpathian fold thrust belt was formed in late neogene times as a result of the eastward escaping tisza dacia block due to n directed convergence of the adriatic plate and the retreating subduction of an oceanic slab brittle deformation structures in the romanian carpathians suggest three tectonic events related to major plate motions 1 paleogene to middle miocene ne to ene contraction caused right lateral curved strike slip faults 2 middle miocene to pliocene fan shaped orientations of contraction directions were caused by right lateral oblique convergence in the southern carpathians frontal convergence in the southern eastern carpathians and left lateral convergence in the northern eastern carpathians 3 pleistocene to holocene general e w extension and n s contraction in the carpathian arc and local ese wnw contraction in the vrancea area is related to the late roll back stage and break off of the subducted slab in the bend area

cretaceous to miocene thrusting and wrenching along the central south carpathians due to a corner effect during collision and orocline formation field studies in the romanian south carpathians longitude 22 5 to 24 2 e and latitude 45 2 to 45 6 n demonstrate 1 cretaceous top to ne shearing parallel to the present strike of the thrust system connected with coaxial flattening within the generally northwest dipping foliation 2 paleogene ductile brittle dextral wrenching e w compression 1 87 15 and basin formation petrosani basin along the cerna jiu fault system 3 large scale miocene dextral wrenching along the northern margin of moesia 1 143 16 and 4 probably pliocene early pleistocene n s compression 1 205 25 we discuss the tectonics of the south carpathians stressing the corner effect of the moesian foreland promontory during convergence and formation of the carpathian orocline up to the late early cretaceous subduction of oceanic crust was active between europe moesia on one side and east carpathia rhodopia on the other side collision and intracontinental deformation occurred during the late early and late cretaceous the pinning of the thrust front at the western tip of moesia and the foreland recess north of it caused superposition of thrusting and wrenching during collision and lateral translation tangential stretching during orocline formation and spreading into the recess further convergence during the early tertiary resulted in dislocation of the previously welded east carpathian rhodopian and moesian fragments along the cerna jiu fault system and the further northeast translation of the western segment the intramontane petrosani basin opened as a northeasterly propagating transient pull apart structure along the cerna jiu fault system which acquired a curved northwesterly convex transtensional trace due to the shape of the moesian promontory tightening of the carpathian orocline and or rearrangement of the microplate geometry during the formation of the pannonian basin system led to large scale dextral wrenching along the northern margin of moesia pliocene n s compression reflects final shortening in the carpathian system before ongoing convergence between europe and africa was transferred to the mediterranean rotation of material lines around the moesian corner is corroborated by paleomagnetic studies

tertiary subduction and slab break off model of the carpathian pannonian region abstract this paper illustrates the application of multidisciplinary data analysis to the carpathian pannonian region and presents a new tertiary development model that incorporates all multidisciplinary parameters during the late cretaceous eocene the future carpathian orogen was part of the larger alpine carpathian orogen formed by the southeastward subduction 135 55 ma of the penninic ocean and the ultimate collision 55 40 ma of the european and adriatic continents the subduction in the alpine region ended by the slab break off of the subducting oceanic lithosphere from the continental one and by the related magmatism 43 24 ma while the eocene alps were under continental collision the eocene remnant carpathian flysch basin rcfb was still subducting the carpathians and eastern parts of the alps started to occupy the region of the present carpathians during the early miocene the oceanic plate underlying the rcfb subducted southwestwards later westwards while the northeastward and eastward migration velocity of the accreting plate boundary decreased through time the slower subduction rate caused a steeper dip of the subducting slab the beginning of the eggenburgian 22 19 ma and following duration of extension in the orogenic hinterland accompanied by the asthenosphere upwelling the onset of the crustally derived volcanism above the risen asthenosphere and the younger mantle derived volcanism progressively less contaminated by the crustal material all contemporaneous with a shortening in the carpathian accretionary wedge the subduction of the rcfb finally led at the end of the early miocene to a collision with the continental margin along the westernmost part of the present carpathian arc the subduction roll back of the subducting slab of the rcfb under the advancing inner carpathians the oblique closure of the basin the progressive change of the subduction to collision from the west to the east along the carpathian arc drove a scissors like break off of the subducting oceanic slab along the west carpathians the break off in the east carpathians was driven by the weight of a subducting oceanic slab and buoyancy of the attached continental slab the break off started in the west of the carpathian arc in the early miocene ran along the arc to its present position in the bend area between the east and south carpathians and separated the oceanic slab that subducted passively under its own weight from the european continental margin the lateral propagation rate of the slab tear decreased with time the break off related volcanism was synchronous with the final stages of the collision

1 1 porphyry cu au and epithermal au ag deposits in the southern apuseni mountains romania 1 1 porphyry cu au and epithermal au ag deposits in the southern apuseni mountains romania south apuseni mountains district lat 46 03 n long 22 58 e k kouzmanov p iv scanu g o connor a isotope geology and mineral resources eth sonneggstrasse 5 8092 zurich switzerland b geological institute of romania caransebes str 1 78344 bucharest romania c gabriel resources ltd suite 1501 110 yonge st toronto on m5c 1t4 canada received 19 november 2004 accepted 1 may 2005

from rocks to ore metal enrichment to ore grade is the ultimate outgrowth of large scale and long term fractionation processes of the thermally driven and unique water cooled geological evolution of the earth silicic magmatism along convergent margins is the most important lithospheric fractionation process for the formation of the continental crust and porphyry intrusion related ore deposits reconnaissance microanalysis of melt inclusions from central andean porphyry systems refines a metallogenic model for copper gold and tin porphyry mineralization magmatic mixing and early exsolution of a fluid phase are important ingredients for porphyry cu au systems in association with silicic rocks of moderate levels of fractionation such as diorites and monzonites whereas extended magmatic fractionation with late stage fluid evolution characterize lithophile element enriched tin porphyry systems

the carpatho balkanides and adjacent area a sector of the tethyan eurasian metallogenic belt the tethyan eurasian metallogenic belt temb was formed during mesozoic and post mesozoic times in the area of the former tethyan ocean on the southern margin of eurasia with the afro arabian and indian plates to the south it extends from western mediterranean via the alps and southeastern europe through the lesser caucasus the hindu kush and the tibet plateau to burma and sw indonesia linking with the west pacific metallogenic belt the carpatho balkan region is one of the sectors of the temb characterized by some specific features the emplacement of ore deposits is related to a definite time interval and to specific tectonic settings such as

lateral growth of the continental crust through deep level subduction accretion a re evaluation of central greek rhodope abstract the rhodope massif of northern greece and southern bulgaria has been variably interpreted as a fragment of pre alpine possibly hercynian or precambrian age continental crust that was actively involved in european margin convergent tectonics during the mesozoic and tertiary alternatively we propose that for central greek rhodope the lithological associations and tectonothermal history are consistent with progressive south directed mesozoic crustal growth through deep level subduction accretion a process which involved the near continuous transferral of material of oceanic and continental margin affinity from footwall to hanging wall within a north directed palaeotethyan subduction system central greek rhodope comprises a sequence of schists gneisses and migmatites of wide compositional variation that have undergone intense tectonic intermixing extensive occurrences of marble are associated with amphibolites variably retrogressed eclogites meta gabbros and ultramafic rocks quartzo feldspathic gneisses are abundant throughout the area and are associated with psammitic meta greywacke sequences pelites and quartzites the presence of intercalated marble slivers and thin manganiferous and iron rich siliceous bands is significant the various components exposed in the subduction accretion complex were first underthrust northwards to deep crustal levels subjected to high pressure eclogite facies metamorphism and underplated to the base of the overriding eurasian plate this latter accretion event was characterised by intense southwest directed ductile thrusting and pervasive amphibolite facies metamorphic overprinting it was accompanied by migmatisation and intracrustal melt generation and followed by subduction related magmatism deep level subduction accretion leads to southward growth of the continental margin which in turn leads to subduction retreat allowing the encroachment of the magmatic arc from the north subsequent extensional tectonic exhumation brought the complex up to its present position within the southern margin of eurasia this new interpretation may have implications for other high grade terrains within convergent and collisional systems that have been assumed to represent ancient or pre existing continental crust if so then the importance of deep level subduction accretion as a mechanism of continental crustal growth has hitherto been underestimated

hydrodynamic parameters estimation from self potential data in a controlled full scale site abstract a multi physical approach developed for the hydrodynamic characterization of porous media using hydrogeophysical information is presented several pumping tests were performed in the hydrogeosite laboratory a controlled full scale site designed and constructed at the cnr imaa consiglio nazionale delle ricerche istituto di metodologia per l analisi ambientale in marsico nuovo basilicata region southern italy in order to obtain an intermediate stage between laboratory experiments and field survey the facility consists of a pool used to study water infiltration processes to simulate the space and time dynamics of subsurface contamination phenomena to improve and to find new relationship between geophysical and hydrogeological parameters to test and to calibrate new geophysical techniques and instruments therefore the hydrogeosite laboratory has the advantage of carrying out controlled experiments like in a flow cell or sandbox but at field comparable scale the data collected during the experiments have been used to estimate the saturated hydraulic conductivity k s ms 1 using a coupled inversion model working in transient conditions made up of the modified richards equation describing the water flow in a variably saturated porous medium and the poisson equation providing the self potential v which naturally occurs at points of the soil surface owing to the presence of an electric field produced by the motion of underground electrolytic fluids through porous systems the result obtained by this multi physical numerical approach which removes all the approximations adopted in previous works makes a useful instrument for real heterogeneous aquifer characterization and for predictive analysis of its behavior

magmagenesis in a subduction related post collisional volcanic arc segment the ukrainian carpathians abstract calc alkaline magmatism in the south west ukraine occurred between 13 8 and 9 1 ma and formed an integral part of the neogene subduction related post collisional carpathian volcanic arc eruptions occurred contemporaneously in two parallel arcs here termed outer arc and inner arc in the ukrainian part of the carpathians outer arc rocks mainly andesites are characterized by lile enrichment e g k and pb nb depletion low compatible trace element abundances high 87sr 86sr high 18o and low 143nd 144nd isotopic ratios 0 7085 0 7095 7 01 8 53 0 51230 0 51245 respectively inner arc rocks are mostly dacites and rhyolites with some basaltic and andesitic lavas they also show low compatible element abundances but have lower 87sr 86sr 18o and higher 143nd 144nd ratios 0 7060 0 7085 6 15 6 64 0 5125 0 5126 respectively than outer arc rocks both high nb and low nb lithologies are present in the inner arc based on the lile enrichment especially pb a higher fluid flux is suggested for the outer arc magmas compared with those of the inner arc combined trace element and sr nd o isotopic modelling suggests that the factors which controlled the generation and evolution of magmas were complex compositional differences between the inner and outer arcs were produced by introduction of variable proportions of slab derived sediments and fluids into a heterogeneous mantle wedge and by different extents of upper crustal contamination degrees of magmatic fractionation also differed between the two arcs the most primitive magmas belong to the inner arc isotopic modelling shows that they can be produced by adding 3 8 subducted terrigenous flysch sediments to the local mantle wedge source up to 5 upper crustal contamination has been modelled for fractionated products of the inner arc the geochemical features of outer arc rocks suggest that they were generated from mantle wedge melts similar to the inner arc primitive magmas but were strongly affected by both source enrichment and upper crustal contamination assimilation of 10 20 bulk upper crust is required in the afc modelling assuming an inner arc parental magma we suggest that magmagenesis is closely related to the complex geotectonic evolution of the carpathian area several tectonic and kinematic factors are significant 1 hydration of the asthenosphere during subduction and plate rollback directly related to collisional processes 2 thermal disturbance caused by ascent of hot asthenospheric mantle during the back arc opening of the pannonian basin 3 clockwise translational movements of the intracarpathian terranes which facilitated eruption of the magmas

1 subduction slab detachment and mineralization the neogene in the apuseni mountains and carpathians abstract the inner carpathians comprise several distinct neogene late stage orogenic pb zn cu ag au ore districts the mineral deposits in these districts are closely related to volcanic and subvolcanic rocks and represent mainly porphyry and epithermal vein deposits which formed within short periods of time in each district here we discuss possible geodynamic and structural controls that suggest why some of the neogene volcanic districts within the carpathians comprise abundant mineralization while others are barren the neogene period has been characterized by an overall geodynamic regime of subduction where primary roll back of the subducted slab and secondary phenomena like slab break off and the development of slab windows could have contributed to the evolution location and type of volcanic activity structural features developing in the overlying lithosphere and visible in the carpathian crust such as transtensional wrench corridors block rotation and relay structures due to extrusion tectonics have probably acted in focusing hydrothermal activity as a result of particular events in the geodynamic evolution and the development of specific structural features mineralization formed during fluid channelling within transtensional wrench settings and during periods of extension related to block rotation in the slovakian ore district of the western carpathians neogene volcanism and associated mineralization were localized by sinistral ne trending wrench corridors which formed part of the extruding alcapa block the baia mare ore district in the eastern carpathians reflects a transtensional wrench setting on distributed oversteps close to the termination of the dragos voda fault there mineralization was spatially controlled by the transtensional dragos voda master fault and associated cross fault systems the golden quadrangle cu au ore district of the southern apuseni mountains reflects an unusual rotated transtensional extensional setting close to the termination of a graben system there fluid flow was probably localized by fault propagation at the inner tip of the graben system the spatial and temporal evolution of the magmatism and its changing geochemical signature from n w to s e strongly suggests a link with the contemporaneous northeastward roll back of the subducted slab and a progressive southeastward detachment during accelerating roll back this geodynamic evolution is further supported by the present day overall and detailed mantle lithospheric density images the present day heat flow patterns the crustal architecture and its interpreted evolution and the spatial and temporal evolution of depocentres around the carpathian arc in contrast to all these features the mineral deposits in the west carpathians east carpathians and apuseni mountains are too synchronous with respect to their individual volcanic history and contrast too much with younger volcanics of similar style but barren in southeastern parts of the carpathians to simply link them directly to the slab evolution in all three districts the presence of magmatic fluids released from shallow plutons and their mixing with meteoric water were critical for mineralization requiring transtensional or extensional local regimes at the time of mineralization possibly following initial compressional regimes these three systems show that mineralization was probably controlled by the superposition of favourable mantle lithospheric conditions and partly independent evolving upper crustal deformation conditions in the 13 to 11 ma period the dominant mineralization formed all across the carpathians and was superimposed on structurally favourable crustal areas with at that time volcanic hydrothermal activity the period may reflect the moment when the upper part of the crust failed under lithospheric extension imposed by the slab evolution this crustal failure would have fragmented the overriding plate possibly breaking up the thermal lid to provoke intensive fluid flow in specific areas and allowed subsequent accelerated tectonic development block rotation and extrusion of a family of sub blocks that are arbitrarily regarded as the tisia dacia or alcapa blocks even though they have lost their internal entity

metal fractionation between magmatic brine and vapor determined by microanalysis of fluid inclusions the major and trace element compositions of individual fluid inclusions from a range of magmatic hydrothermal ore deposits were analyzed by laser ablation inductively coupled plasma mass spectrometry to explore the behavior of ore forming components during fluid phase separation boiling in high temperature saline fluid systems data from 13 samples showing unambiguous evidence for coeval trapping of a liquid brine and a coexisting vapor phase identify two groups of elements with drastically different geochemical behavior na k fe mn zn rb cs ag sn pb and tl preferentially partition into the brine probably as cl complexes whereas cu as au probably as hs complexes and b selectively partition into the vapor fluid phase separation is probably a major previously underestimated process in the chemical differentiation that contributes to the extreme range of selective element enrichments in magmatic hydrothermal systems from deep plutons through porphyry style and greisen deposits to epithermal mineralization and volcanic fumaroles

role of the 3 d distributions of load and lithospheric strength in orogenic arcs polystage subsidence in the carpathians foredeep abstract it has been widely documented that the depth of foredeeps does not always reflect the topography of the neighboring orogens in many cases the topographic load is insufficient to explain basin subsidence such is the case of the se carpathians where an anomalously deep almost 13 km foreland basin has evolved since the middle miocene badenian a peculiar feature of this basin is its position relative to the orogen in contrast to typical foredeeps which deepen towards the belt the maximum depth of this basin is 10 20 km out of the orogen the subsidence in the carpathians bend foreland is characterized by two stages the first is middle miocene badenian in age and is related to ne sw extension when fault bounded basins were formed modeling shows that the foreland underwent small pre orogenic uniform thinning the modeling also predicts

tertiary evolution of the intra carpathian area a model abstract the outer carpathian flysch nappes encircle an intra carpathian domain which can be divided into two megatectonic units north pannonian and tisza mostly on the basis of contrasting mesozoic and palaeogene facies development we see two major kinematic problems to be solved 1 1 the present distribution of the mesozoic and palaeogene facies is mosaic like and some belts form exotic bodies within realms of austroalpine affinity 2 2 late eocene palinspastic reconstruction of the outer carpathian flysch nappes suggest that the entire intra carpathian area must have been located several hundreds of kilometres to the south and to the west of its present position neogene extension can account for shortening in the external carpathian nappes but is unable to explain mesozoic facies anomalies and offsets of palaeogene formations we suggest that evolution of the intra carpathian area involved first late palaeogene early miocene juxtaposition of the north pannonian and tisza megatectonic units accompanied by the closure of the external carpathian flysch troughs thereafter extension of this amalgamated unit occurred which was compensated by thrusting of flysch nappes onto the european foreland and formation of molasse foredeeps eastward escape of the north pannonian unit from the alpine collisional belt involved left lateral shear along the pieniny klippen belt and right lateral shear along the mid hungarian zone parts of the late palaeogene basin and an early miocene volcanic edifice were dissected offset and elongated by several 100 kms the driving mechanism of the eastward escape of the intra carpathian area can be related to the collision of apulia and europe and the subduction of the external carpathian crust under the pannonian units the escape ceased gradually in the early miocene when oblique collision between the north pannonian unit and european continent occurred neogene extension of the pannonian region was an areal deformation the extension at locally variable rate resulted in the break up of the heterogenous floor of the neogene basin the driving mechanism of basin extension and contemporaneous compressional deformation of the external carpathians is thought to be related to ongoing subduction involving the marginal part of the attenuated european continental crust tectonic activity in the carpathians and basin subsidence and volcanism shifted in time and in unison from the west toward the east southeast

40ar 39ar muscovite ages from the penninic austroalpine plate boundary eastern alps the radstadt mountains eastern alps expose the tectonic boundary between the base of the austroalpine continental plate hanging wall and the penninic oceanic units foot wall parts of the austroalpine basement were penetratively deformed because of ongoing rifting of the continental crust during the permian 290 250 ma austroalpine permo mesozoic cover rocks were deformed during the cretaceous 80 ma and the paleogene 55 50 ma these ages are interpreted as representing two distinct events of nappe stacking the younger ages represent the collision of austroalpine and penninic tectonic units the penninic nappe complex displays a successive decrease of ages from 37 to 25 ma from high to deep tectonic levels a second age group of 22 ma was found both in low temperature release steps and as plateau ages close to the penninic austroalpine boundary it is attributed to a thermal overprint due to ductile extension of the overthickened orogenic wedge

transpressional collision structures in the upper crust the fold thrust belt of the northern calcareous alps abstract two major structural events characterize the tectonic evolution of the northern calcareous alps nca 1 late early cretaceous to late eocene nw directed dextral transpressional stacking of nappes as an expression of the formation of the austroalpine orogenic wedge and 2 miocene sinistral wrenching due to eastward lateral extrusion of crustal wedges along the central eastern alps three first order detachment horizons are defined by differences of competence within areas of facies transition preexisting normal faults control the thrust architecture transpressional contraction in the nca is indicated by a nw directed thrusting oblique to both the long axis of the nca and the edge of the orogenic foreland b the occurrence of en echelon arrays of thrusts and folds laterally displaced by dextral strike slip faults the thrusts and strike slip faults are kinematically connected to each other and dissect the nca into rhomboidal blocks c ne directed extension parallel to fold and ramp axes and the internal strike of the nca and d clockwise rotation 30 of the entire nca around a vertical axis kinematic and dynamic analysis of mesoscale fault striae data related to transpressional stacking indicates a nw trend of contraction directions and in general a ne trend of the extension directions parallel to fold axes and branch lines of thrusts before rotation the average contraction direction was probably parallel to the generally w directed shear direction recorded in the crystal plastically deformed central part of the eastern alps three balanced cross sections across the nca yield a minimum of 54 65 total shortening

silver lead zinc veins metamorphic core complexes and hydrologic regimes during crustal extension the kokanee range ag pb zn au vein and replacement deposits formed during eocene crustal extension and unroofing of the valhalla metamorphic core complex in the hanging wall of the transcrustal slocan lake fault the 34ssulfide 18oquartz 18osiderite and galena pb isotopic ratios for vein minerals display regional zonations revealing fluid flow paths of a large fossil hydrothermal system sulfur was derived from local country rocks but carbon was derived from a deep seated reservoir possibly the upper mantle lead is a mixture of local upper crustal pb with lower crustal and depleted upper mantle pb regional isotopic zonations were controlled by deep fracture zones such as the slocan lake fault which channeled lower crustal and mantle pb and mantle co2 to higher crustal levels where mixing occurred with highly evolved meteoric waters that had leached local sulfur and upper crustal ph this is the first ag pb zn vein district for which a genetic link between mineralization and metamorphic core complex unroofing is demonstrated

deep crustal structure beneath the central and inner west carpathians abstract the 150 km long deep seismic transect 2t crossing the central part of the slovakian west carpathians has revealed an important whole crustal seismic suture zone dipping to the south this zone is dominated by six large and several minor reflection events because of our good knowledge of the surface geology and a large number of comparative studies of the eastern alps it is clear that the upper reflections are due to overthrust sheets that originated during compression of the apulian passive margin tectonically deeper reflections are interpreted as being due to ligurian oceanic igneous and sedimentary rocks sheared in ductile domain during continental collision with the brianconnais passive margin and continental masses north of the central apulian west carpathians cwc behind a significant strike slip fault are the cenozoic structures of the pieniny klippen belt and the magura rhenodanubian flysch south of the cwc the inner tethyan west carpathians iwc are thrust over the cwc the iwc originated during the late jurassic early cretaceous closure of the tethyan ocean and the seismic image of the iwc is different from the highly reflective cwc suture these three pre neogene nappe systems amalgamated as one overthrust system during the neogene subduction of the moldavian sea as the moldavian accretionary wedge the vepor gemer block of the west carpathians where the cretaceous suture is observed has been untouched by any major cenozoic deformation and has remained relatively rigid this unique structure therefore enables us to observe seismically the cretaceous suture zone which elsewhere in the european alpine belt has been almost completely destroyed more general data about the beginning of subduction and subsequent collision processes are presented significant compression and partial subduction of the apulian upper plate passive margin lasted from the hauterivian to the beginning of the turonian for about 25 30 ma subduction of the ligurian ocean occurred from turonian to campanian times after the early campanian the collision of the apulian and brianconnais plates took place

mesozoic plate tectonic reconstruction of the carpathian region abstract palaeomagnetic palaeobiogeographic and structural comparisons of different parts of the alpine carpathian region suggest that four terranes comprise this area the alcapa tisza dacia and adria terranes these terranes are composed of different mesozoic continental and oceanic fragments that were each assembled during a complex late jurassic cretaceous palaeogene history palaeomagnetic and tectonic data suggest that the carpathians are built up by two major oroclinal bends the alcapa bend has the meliata oceanic unit correlated with the dinaric vardar ophiolite in its core it is composed of the western carpathians eastern alps and southern alcapa units transdanubian range bukk this terrane finds its continuation in the high karst margin of the dinarides further elements of the alcapa terrane are thought to be derived from collided microcontinents czorsztyn in the n and a carbonate unit tisza in the se the tisza dacia bend has the vardar oceanic unit in its core it is composed of the bihor and getic microcontinents this terrane finds its continuation in the serbo macedonian massif of the balkans the bihor getic microcontinent originally laid east of the western carpathians and filled the present carpathian embayment in the late palaeozoic early mesozoic the vardar ocean occupied an intermediate position between the western carpathian austroalpine transdanubian high karst margin and the bihor getic serbo macedonian microcontinent the vardar and pindos oceans were opened in the heart of the mediterranean adriatic microcontinent in the late permian middle triassic vardar subducted by the end of jurassic causing the bihor getic serbo macedonian microcontinent to collide with the internal dinaric western carpathian margin an external penninic vahic ocean tract began opening in the early jurassic separating the austroalpine western carpathian microcontinent and its fauna from the european shelf further east the severin ceahlau magura also began opening in the early jurassic but final separation of the bihor getic ribbon and its fauna from the european shelf did not take place until the late middle jurassic the alcapa and the tisza dacia were bending during the albian maastrichtian the two oroclinal bends were finally opposed and pushed into the gates of the carpathian embayment during the palaeogene and neogene at that time the main n s shortening in distant alpine and hellenic sectors was linked by a broader right lateral shear zone along the former vardar suture

fluid evolution and mineral formation in the beregovo gold base metal deposit transcarpathia ukraine the beregovo vein type gold base metal deposit is hosted by volcanic sedimentary sequences of the pannonian basin in the carpathian neogene volcanic belt four stages of mineralization were distinguished 1 sulfide 2 quartz barite 3 carbonate quartz and 4 carbonate goethite homogenization temperature salinity and chemical and isotopic composition of fluid inclusions in sphalerite galena barite quartz and carbonates combined with the delta 18 o values of quartz carbonates and barite suggest the presence of three major fluid types 1 deep relatively high temperature 250 degrees c and moderate salinity about 8 wt nacl equiv na k cl fluid with relatively high delta 18 o 5ppm delta d 60ppm and delta 13 c 5ppm values 2 high salinity up to 14 wt nacl equiv ca mg na cl formation water with higher delta d values 40ppm and 3 near surface steam heated about 200 degrees c sulfate bicarbonate dominated fluid delta 18 o from 5 to 1ppm and delta d from 110 to 56ppm low delta 13 c values 25ppm for co 2 in type 2 and 3 fluids reflect a significant contribution of carbon from organic rich sedimentary wall rocks the delta 34 s values of sulfide minerals range from 2 to 2 5 for pyrite 1 to 6 for sphalerite and 2 to 8 per mil for galena two sources of sulfur are identified for the beregovo sulfide ores ores with delta 34 s values close to 0 per mil may have been magmatic and those with higher delta 34 s values up to 8ppm perhaps resulted from organic matter 5ppm in the wall rocks two main isotopically and genetically different barite generations were found hypogene barites with delta 34 s values from 13 to 26 per mil and supergene barites with values from 4 0 to 5 5 per mil none of the barites had isotopically equilibrated with the sulfide minerals if equilibrium in the isotopic exchange between sulfate and water were realized the delta 18 o values of the fluid would range from 5 0 to 2 0 and 10 5 to 5 9 per mil for the two generations respectively for comparison oxygen isotope composition for present day precipitation is about 10 per mil

fluid evolution in a subvolcanic granodiorite pluton related to fe and pb zn mineralization banska stiavnica ore district slovakia the central zone of the miocene stiavnica stratovolcano western carpathians hosts an extensive subvolcanic intrusive complex dominated by a granodiorite pluton 14 5 15 5 ma the granodiorite intrusion has a bell jar form and was emplaced mainly into basement rocks although its central part extends to the base of a subvolcanic and volcanic andesitic complex 1 5 to 3 km below the paleosurface in the more uplifted western part of the complex the margin of the granodiorite includes numerous apophyses with associated magnetite skarns whereas in the central apical part it contains an irregular network of fractures hosting base metal stockwork mineralization that extends to a depth of 250 m the granodiorite intrusion especially in the marginal facies is altered high temperature subsolidus deuteric k feldspar secondary biotite and amphibole and endoskarn pyroxene alteration intimately related to magnetite skarns resulted in depletion in fetotal and increase in cao and mgo in the intrusion low temperature hydrothermal alteration epidote chlorite k feldspar sericite closely related to the stockwork mineralization is characterized by enrichment in k2o pb zn cu and mno and depletion in na2o the overlying andesites are affected by acid leaching fluid inclusions and stable isotopes o h were studied in samples of granodiorite related to the skarn and to the stockwork from the top of the pluton down to 1 230 m in depth magmatic quartz contains hypersaline fluid inclusions up to 71 wt nacl equiv vapor rich saline and low salinity inclusions as well as moderate to low salinity liquid rich aqueous inclusions with homogenization temperatures th ranging from 161 to 600 c brine inclusions from magmatic quartz in marginal phases of the granodiorite show signs of nacl saturation during entrapment with the majority probably having been captured under vapor unsaturated conditions most vapor rich inclusions represent early stages of fluid immiscibility whereas the low salinity liquids are products of dilution by meteoric fluid and or late stage portions of magmatic fluids inclusion bearing minerals in the skarn assemblage contain moderate to low salinity fluid inclusions th 215 371 c with evidence of late stage boiling at low hydrostatic pressure hydrothermal minerals from base metal stockwork and massive silica rich rock contains only low salinity inclusions up to 5 wt nacl equiv th 191 367 c the isotopic composition of magmatic biotite and hornblende from granodiorite indicates open magmatic degassing deuterium depletion during granodiorite crystallization influenced by reequilibration to variable degrees fluids in equilibrium with skarn and stockwork related minerals show a clear progressive mixing trend with isotopically relatively heavy possibly 18o shifted meteoric water magnetite skarns and zones of high temperature subsolidus deuteric alteration are related to ponding of magmatic brines in the roof of the intrusion resulting from fluid immiscibility at relatively low pressures the associated escaping vapor was responsible for acid leaching in andesites above the apical part of the pluton stockwork mineralization and associated low temperature potassic alteration are probably related to the large convective hydrothermal system and upflow of late stage deep exsolved supercritical fluids using the increased permeability fracturing of the central apical part of the intrusion

palaeomagnetic evidence for tertiary counterclockwise rotation of adria abstract with the aim of obtaining tertiary palaeomagnetic directions for the adriatic foreland of the dinaric nappe system we carried out a palaeomagnetic study on platform carbonates from stable istria from the northwestern and the central dalmatia segment of imbricated adria despite the weak to very weak natural remanences of these rocks we obtained tectonically useful palaeomagnetic directions for 25 sites from 20 localities all exhibit westerly declinations both before and after tilt correction concerning the age of the magnetizations we conclude that five subhorizontal and magnetite bearing eocene localities from stable istria are likely to carry primary remanence whereas three tilted and hematite bearing ones were remagnetized in the northwestern segment of imbricated adria the cluster of the mean directions improved after tectonic correction indicating pre tilting magnetization in contrast maastrichtian eocene platform carbonates from central dalmatian were remagnetized in connection with the late eocene oligocene deformation or miocene hydrocarbon migration based on the appropriate site locality means we calculate mean palaeomagnetic directions for the above three areas and suggest an alternative interpretation of the data of kissel et al j geophys res 100 1995 14999 for the flysch of central dalmatia the four area mean direction define a regional palaeomagnetic direction of dec 336 inc 52 k 107 95 9 from these data we conclude that stable istria in close coordination with imbricated adria must have rotated by 30 counterclockwise in the tertiary relative to africa and stable europe we suggest that the latest miocene early pliocene counterclockwise rotations observed in northwestern croatia and northeastern slovenia were driven by that of the adriatic foreland i e the rotation of the latter took place between 6 and 4 ma

possible controls of base and precious metal mineralization associated with tertiary detachment faults in the lower colorado river trough arizona and california base and precious metal mineral deposits are located along and adjacent to tertiary detachment faults in western arizona and southeastern california mineralization is characterized by early copper and iron sulfides followed by massive specular hematite in turn followed by fracture filling chrysocolla and malachite mineralization occurred during faulting and was associated with unusually high geothermal gradients that were at least partially due to detachment fault movement that brought hot lower plate rocks up from great depth and juxtaposed them with cool near surface upper plate rocks mixing of ascending reduced metal bearing aqueous solutions with higher level oxidized fluids is proposed as an important process leading to oxide mineralization movement of the redox interface down normal fault ramps at the same rate as displacement of hanging wall rocks resulted in continuous mineralization at some upper plate sites over significant periods of geologic time this produced the largest orebodies aqueous solutions that precipitated iron oxides near the detachment fault carried manganese oxides to higher levels where vein and strata bound sedimentary manganese oxides were deposited

calcium isotope record of phanerozoic oceans implications for chemical evolution of seawater and its causative mechanisms a total of 280 brachiopods of ordovician to cretaceous age complemented by published data from belemnites and planktonic foraminifera are used to reconstruct the evolution of calcium isotope composition of seawater 44 40casw over the phanerozoic the compiled 44 40casw record shows a general increase from 1 3 nist srm 915a at the beginning of the ordovician to 2 at present superimposed on this trend is a major long term positive excursion from the early carboniferous to early permian as well as several short term mostly negative oscillations a numerical model of the global cycles of calcium carbon magnesium and strontium was used to estimate whether the recorded 44 40casw variations can be explained by varying magnitudes of input and output fluxes of calcium to the oceans the model uses the record of marine 87sr 86sr ratios as proxy for seafloor spreading rates a record of oceanic mg ca ratios to estimate rates of dolomite formation and reconstructed atmospheric co2 discharge and erosion rates to estimate continental weathering fluxes the model results indicate that varying magnitudes of the calcium input and output fluxes cannot explain the observed 44 40casw trends suggesting that the isotope signatures of these fluxes must also have changed as a possible mechanism we suggest variable isotope fractionation in the sedimentary output flux controlled by the dominant mineralogy in marine carbonate deposits i e the oscillating calcite aragonite seas the ultimate control of the calcium isotope budget of the phanerozoic oceans appears to have been tectonic processes specifically variable rates of oceanic crust production that modulated the hydrothermal calcium flux and the oceanic mg ca ratio which in turn controlled the dominant mineralogy of marine carbonates hence the 44 40casw as to the causes of the short term oscillations recorded in the secular 44 40casw trend we tentatively propose that these are related to variable rates of dolomite formation and or to changing chemical composition of the riverine flux in particular and ratios induced by variable proportions of silicate vs carbonate weathering rates on the continents

paleomagnetic aspects of plate tectonics in the carpatho pannonian region paleomagnetic data available from the carpatho pannonian region are unevenly distributed at some places observations are sporadic at others the concentration is high in the latter case it is possible to decide whether the movements indicated are related to plate microplate displacements or are of local significance the paleomagnetically best known parts of the carpatho pannonian region belong to the transdanubian central range to the cserhat matra bukk area and to the mecsek villany zone comparison among paleomagnetic data sets characterizing each of them reveals fundamental differences i e points to their independent displacements during the mesozoic and cenozoic most of the isolated observations can be tied to one of the above mentioned paleomagnetic units via coeval mostly late cretaceous cenozoic data thus further subdivision of the carpatho pannonian area at least in the cenozoic does not seem required by available paleomagnetic observations

the mid hungarian line a zone of repeated tectonic inversions abstract the mid hungarian line is a major tectonic feature of the intra carpathian area separating two terranes of different origin and tectonic structure although this tectonic line was known from borehole records it has not been described in seismic sections the study presents interpreted seismic lines crossing the supposed trace of the mid hungarian line these seismic sections show north dipping normal faults and thrust faults as well as cross cutting young strike slip faults a complex tectonic history is deduced including intra oligocene early miocene thrusting middle miocene extension local late miocene inversion and late miocene pliocene normal faulting and left lateral wrenching in the light of our seismic study we think that the best candidate for the mid hungarian line is a north dipping detachment fault beneath large masses of neogene volcanics the auxiliary structures to the north seen on seismic sections suggest that it moved as a south vergent thrust fault during the palaeogene early miocene which later was reactivated as a set of normal faults the northern alcapa unit overrode the southern tisza dacia unit along this fault zone the same relative positions are observed in the northern termination of the line other structures along the supposed trace of the line are north dipping normal or strike slip faults which frequently were reactivated as smaller thrust faults during the late neogene palaeogene early miocene thrusting along the line might be the result of the opposite tertiary rotations of the two major units as suggested by palaeomagnetic measurements and earlier models

giant versus small porphyry copper deposits of cenozoic age in northern chile adakitic versus normal calc alkaline magmatism cenozoic magmatic activity in northern chile led to the formation of two contrasting porphyry copper belts 1 a paleocene early eocene belt comprising small porphyry copper deposits e g lomas bayas of normal calc alkaline affinity and 2 a late eocene early oligocene belt hosting huge porphyry copper deposits e g chuquicamata of adakitic affinity although the first belt comprises both volcanic and plutonic rocks andesitic basaltic and rhyolitic lavas and tuffs and associated sub volcanic porphyries and felsic stocks the latter only includes intrusions mostly granodioritic types including porphyry copper deposits we suggest that the late eocene early oligocene belt formed when fast and oblique convergence between the south america and farallon plates led to flat subduction and direct melting of the subducting plate hence giving rise to plutonic rocks of adakitic affinity the absence of volcanism under prevailing compressional conditions prevented the escape of so2 from the adakitic sulfur rich highly oxidized magmas closed porphyry system which allowed formation of huge mineral deposits on the contrary coeval volcanic activity during formation of the paleocene early eocene calc alkaline porphyries allowed development of open systems hence to outgassing and therefore to small mineral deposits

upper mantle structure beneath the alpine orogen from high resolution teleseismic tomography 1 to understand the evolution of the alpine orogen knowledge of the actual structure of the lithosphere asthenosphere system is important we perform high resolution teleseismic tomography with manually picked p wave arrival times from seismograms recorded in the greater alpine region the resulting data set consists of 4199 relative p wave arrivals and 499 absolute p wave arrivals from 76 teleseismic events corrected for the contribution of the alpine crust to the travel times the three dimensional 3 d crustal model established from controlled source seismology data for that purpose represents the large scale alpine crustal structure absolute p wave arrival times are used to compute an initial reference model for the inversion tests with synthetic data document that the combination of nonlinear inversion high quality teleseismic data and usage of an a priori 3 d crustal model allows a reliable resolution of cells at 50 km 50 km 30 km hence structures as small as two cells can be resolved in the upper mantle our tomographic images illuminate the structure of the uppermost mantle to depth of 400 km along strike of the alps the inversion reveals a high velocity structure that dips toward the se beneath the adriatic microplate in the western and central alps in the eastern alps we observe a northeastward dipping feature subducting beneath the european plate we interpret this feature in the western and central alps as subducted mainly continental european lower lithosphere for the east we propose that parts of the vardar oceanic basin were subducted toward the ne forcing continental adriatic lower lithosphere to subduct northeastward beneath the european plate

far field effects of late miocene subduction in the eastern carpathians e w compression and inversion of structures in the alpine carpathian pannonian region kinematic and paleostress data constrain a late miocene e w compressional event that affected the entire alpine carpathian pannonian system after 9 ma and prior to 5 3 ma the maximum horizontal compression directions obtained from 110 stations show a mean 1 orientation of 083 deformation is mainly strike slip e w directed compression followed early to middle miocene upper plate extension in the pannonian basin which was caused by the retreating subduction boundary in the outer carpathians this compressional event terminated early to middle miocene eastward lateral extrusion of the eastern alps and reverted strike slip faults which bounded earlier extruded wedges such as the salzachtal ennstal fault the periadriatic fault the mur murz vienna basin fault system and strike slip faults in the western carpathians e w compression caused the reorientation of the extension direction of the alpine crustal stack east directed tectonic unroofing of the metamorphic domes in the central eastern alps terminated between 9 and 6 ma and early to middle miocene orogen parallel e w extension switched to late miocene n s extension which parallels modern topographic slopes in the pannonian basin the change from synrift extension to late miocene compression during the postrift phase caused the pronounced postrift subsidence by stress induced downward flexure of the loaded lithosphere we relate late miocene e w compression to coeval late stage west directed subduction of the european plate below the eastern carpathians slab pull of the subducted plate caused subduction roll back and upper plate extension of the pannonian area up to the middle miocene subduction slowed down and ceased when up to 60 km thick buoyant continental crust entered the subduction zone during the short period of continued convergence e w directed compressive stress was transmitted across the subduction boundary into the upper plate compressive stress was transferred through the uppermost brittle crust of the earlier extended pannonian region into the eastern alps up to 1400 km behind the subduction zone e w compression terminated during the pliocene when the pliocene to recent nnw sse compressive stress field was established in central europe

the palaeogene forearc basin of the eastern alps and western carpathians subduction erosion and basin evolution scarce palaeogene sediment remnants in the eastern alps and western carpathians are interpreted as remains of a continuous forearc basin new apatite fission track geochronological data corroborate mild paleocene eocene exhumation and relief formation in the eastern alps palinspastic restoration and nine palaeogeographical maps of the eastern alps and western carpathians ranging from the paleocene to the late oligocene epoch illustrate west to east migration of subsidence in the forearc basin subsidence isochrons indicate that oblique subduction of the european plate below the adriatic plate was responsible for forearc basin migration at a rate of 8 mm a 1 the periadriatic lineament was formed as a result of shearing by oblique subduction the neogene to recent sumatra forearc basin is an analogue for the evolution of the east alpine west carpathian forearc basin

lead isotope signatures of epithermal and porphyry type ore deposits from the romanian carpathian mountains lead isotope analyses have been performed on the two major miocene mining districts of romania baia mare and apuseni mountains these two districts have different non overlapping 206pb 204pb isotopic signatures ranging from 18 752 to 18 876 and 18 497 to 18 740 in the baia mare district epithermal deposits are overall homogeneous in their lead isotopic compositions and have values similar to the average of the calc alkaline volcanic rocks these results suggest a magmatic signature for the pb and possibly other metals in the hydrothermal fluids however magmas in this district show isotopic evidence of crustal assimilation in the southern apuseni mountains the lead isotope compositions of sulfide minerals in porphyry copper deposits are clustered confirming that pb and probably other metals were derived principally from associated porphyry stocks on the other hand lead isotope data on sulfides in epithermal ore deposits are much more scattered indicating a notable contribution of pb from local country rocks in the apuseni mountains fertile volcanics are few and appear to come from a more primitive mantle derived source most of the analysed volcanic rocks seem barren differences in lead isotopic compositions between the baia mare district and the apuseni mountains are due to a different basement and probably to variations in crustal assimilation superimposed on variations in the mantle source composition in the apuseni mountains pb may be partly inherited from the previous mesozoic magmatic hydrothermal stage from a geodynamic point of view it seems that the nature and the source of volcanic rocks and their position related to the collision area of the carpathian arc are not the only factors controlling the fertility of a volcanic district

1 3 epithermal au ag and pb zn cu ag au deposits of the central slovakia neogene volcanic field kremnica and banska stiavnica hodrusa mining districts lat 48 28 n long 19 00 e

interplay of tectonics and neogene post collisional magmatism in the intracarpathian region abstract distribution of the neogene calc alkaline magmatism of the carpathian arc is directly related in space and time to the kinematics of the two major terranes of the intracarpathian area alcapa tisia getia along the south eastern border of the european plate in the west carpathians and adjacent areas the volcanic activity occurred between 20 11 ma with large volumes of both acidic and intermediate rocks generally distributed randomly sometimes transversally to the orogenic belt and as rare small occurrences along the flysch belt in the east carpathians the volcanic rocks are distributed along the northern margin of the zemplin block the north easternmost part of the alcapa and eastward along the front of the getic block at the contact with european plate between tokaj slanske vihorlat up to northern calimani mountains the magmatism occurred between 14 9 ma and along the calimani harghita chain between 9 0 2 ma the calc alkaline magmatic rocks of the apuseni mountains are located in the interior of the tisia block and occurred between 14 9 ma the generation of the calc alkaline magmatism is considered here as the result of complex interplay between plate roll back and lithospheric detachment tectonic processes and the break off of the subducted plate mostly in a post collisional setting 1 the magmatites of the western carpathians and the pannonian basin were generated in direct relation to subduction roll back processes over the downgoing slab during the period of lateral extrusion and back arc extension in this area characterized by maximum crustal shortening we can infer further delamination processes to explain the generation of magmas 2 the magmatic rocks from the northern sector of the east carpathians tokaj slanske vihorlat up to the northern calimani mountains resulted after subduction roll back processes and an almost simultaneous break off of the descending plate all along the arc segment during main clockwise rotation of the intracarpathian terranes 3 in the eastern sector of the east carpathians calimani up to harghita mountains the magmatic rocks were generated through partial melting of the subducted slab followed by gradual break off of the subducted plate along strike north to south 4 the apuseni mts magmatic activity resulted in transtensional tectonic regime by decompressional melting of lithospheric mantle during the translation and rotation of tisia getia block

first deep seismic reflection images of the eastern alps reveal giant crustal wedges and transcrustal ramps 1 the alps are considered as a classical example for an orogen created by continental plate collision in this study we present new images obtained from deep seismic reflection profiling in the eastern alps between munich and venice which give rise to examine and revise existing concepts the seismic sections exhibit a prominent bi verging reflection pattern at crustal scale a major ramp like structure outcropping at the inn valley fault can be traced southward over 80 km into the mountain root where relics of the subducted penninic ocean are expected new models of the evolution of the eastern alps show an upper lower crustal decoupling along transcrustal thrust faults with opposite thrust directions of both the european and the adriatic african continents

kinematics of retreating subduction along the carpathian arc romania kinematic axes and resultant vectors of displacement along the carpathian arc and the apuseni mountains aid in the reconstruction of retreating subduction along the carpathians the recent vertical position of the subducted slab below the vrancea area of the eastern carpathians represents the final rollback stage of a small fragment of oceanic lithosphere formerly situated between the moesian and east european plates the ages and locations of the eruption centers of the andesitic volcanic chain along the carpathian arc in the overriding plate as well as the thrust directions are used as markers to reconstruct the rollback area of the subducted slab between the moesian and east european plates

rosia poieni copper deposit apuseni mountains romania advanced argillic overprint of a porphyry system the rosia poieni deposit is the largest porphyry copper deposit in the apuseni mountains romania hydrothermal alteration and mineralization are related to the middle miocene emplacement of a subvolcanic body the fundoaia microdiorite zonation of the alteration associated with the porphyry copper deposit is recognized from the deep and central part of the porphyritic intrusion towards shallower and outer portions four alteration types have been distinguished potassic phyllic advanced argillic and propylitic potassic alteration affects mainly the fundoaia subvolcanic body the andesitic host rocks are altered only in the immediate contact zone with the fundoaia intrusion mg biotite and k feldspar are the main alteration minerals of the potassic assemblage accompanied by ubiquitous quartz chlorite and anhydrite are also present magnetite pyrite chalcopyrite and minor bornite are associated with this alteration phyllic alteration has overprinted the margin of the potassic zone and formed peripheral to it it is characterized by the replacement of almost all early minerals by abundant quartz phengite illite variable amounts of illite smectite mixed layer minerals minor smectite and kaolinite pyrite is abundant and represents the main sulfide in this alteration zone advanced argillic alteration affects the upper part of the volcanic structure the mineral assemblage comprises alunite kaolinite dickite pyrophyllite diaspore aluminium phosphate sulphate minerals woodhouseite svanbergite series zunyite minamyite pyrite and enargite luzonite alunite forms well developed crystals veins with enargite luzonite and pyrite in a gangue of quartz pyrophyllite and diaspore are present within and around the subvolcanic intrusion this alteration type is partially controlled by fractures a zonal distribution of alteration minerals is observed from the centre of fractures outwards with 1 vuggy quartz 2 quartz alunite 3 quartz kaolinite alunite and in the deeper part of the argillic zone quartz pyrophyllite diaspore 4 illite illite smectite mixed layer minerals kaolinite alunite and e chlorite albite epidote propylitic alteration is present distal to all other alteration types and consists of chlorite epidote albite and carbonates mineral parageneses mineral stability fields and alteration mineral geothermometers indicate that the different alteration assemblages are the result of changes in both fluid composition and temperature of the system the alteration minerals reflect cooling of the hydrothermal system from 400 c biotite to 300 200 c chlorite and illite in veinlets and to lower temperatures of kaolinite illite smectite mixed layers and smectite crystallization hydrothermal alteration started with an extensive potassic zone in the central part of the system that passed laterally to the propylitic zone it was followed by phyllic overprint of the early altered rocks nearly barren advanced argillic alteration subsequently superimposed the upper levels of the porphyry copper alteration zones the close spatial association between porphyry mineralization and advanced argillic alteration suggests that they are genetically part of the same magmatic hydrothermal system that includes a porphyry intrusion at depth and an epithermal environment of the advanced argillic type near the surface

partial melting of slab window margins genesis of adakitic and non adakitic magmas abstract when a mid ocean spreading ridge subducts it typically splits apart at depth to form two tapered slab edges separated by asthenospheric mantle within a slab window we examine the fate of the slab edges using simplified slab window geometries specific thermal parameters and assumptions regarding shear stress and slab hydration six fundamental zones of slab anatexis are identified and classified according to expected melt and restite compositions non adakitic melts of granodioritic to tonalitic composition are generated along the plate edges at depths of 5 65 km whereas adakitic melts form proximal to the edges at depths of 25 90 km as anatexis proceeds the subducted crust is converted to a migmatite of slab melt and eclogitic restite much of the migmatite may shear away from the slab and become incorporated into the mantle the melts will rise and leave behind fragments of restite within mantle peridotite if the peridotite is part of the overriding plate then the restite fragments may become long term residents of the continental lithospheric mantle however if the restite becomes entrained in the asthenosphere it may undergo upwelling and melting or flow away as ductile streaks to become long term mantle heterogeneities slab windows are thereby identified as important sites for slab melting and geochemical replenishment of the mantle

tomographic imaging of deep velocity structure beneath the eastern and southern carpathians romania implications for continental collision the vrancea seismic zone located beneath the elbow of the eastern and southern carpathians is characterized by intermediate depth seismicity associated with subduction and plate collision among many strong earthquakes that have occurred in the region the 1977 vrancea earthquake march 4 1977 ms 7 1 depth of 86 km caused extensive damage and fatalities the vrancea seismic zone is defined by a tabular region of seismicity that extends from the surface to a depth of 200 km the small size about 80 km in length and 40 km in width and geometry of the seismic zone have made it difficult to interpret the kinematics of subduction and continental collision in the romanian carpathians to better understand the collision subduction environment body wave seismic tomography was used to image the deep structure beneath the eastern and southern carpathians in romania a total of 7837 p and 2292 s arrival times from 433 shallow and intermediate depth earthquakes recorded by local and regional seismic stations were inverted for the three dimensional 3 d seismic velocity structure the travel times and ray paths were calculated by an efficient 3 d ray tracing technique by utilizing the lsqr algorithm p and s wave velocity perturbations were determined from the surface down to a depth of 200 km the high resolution p wave tomographic images reveal a pattern of broad heterogeneity in the velocity structure of the region one of the most important features is a high velocity body existing beneath the carpathian arc at depths between 100 and 170 km this high velocity body outlines a slab dipping near vertically where most of the intermediate depth earthquakes occur beneath the transylvanian basin a high velocity zone is dipping toward the se and may represent the base of lithosphere which is in convergence with the subducted slab low velocity bodies are found along the forearc of the carpathian foredeep down to depths of 70 to 80 km these low velocity bodies may be correlated with the shallow sedimentary layer in the foreland and may represent crustal materials wedged and underthrust along with the subducted lithosphere