effect of maturity on 13c12c ratios of individual compounds in north sea oils abstract carbon isotope variations in individual compounds are reported for north sea oils of variable thermal maturity using the pristane phytane ratio of the oils as an indication of source facies variation and molecular maturity ratios to determine maturity it is possible to differentiate the two effects in these samples maturity accounts for between 50 and 90 of the observed isotopic variation all values becoming heavier with increasing maturity typically by between 2 and 3 however source differences are also apparent with a terrestrially influenced source possibly the heather formation contributing material to the kimmeridge clay sourced oils the heather contribution is isotopically heavier than the kimmeridge oil for most compounds but is isotopically lighter for the isoprenoid hydrocarbons and some other branched compounds it is also more important for lower molecular weight hydrocarbons than for higher homologues

environmental change during the early cretaceous in the purbeck type durlston bay section dorset southern england a biomarker approach abstract the purbeck type section durlston bay dorset uk exhibits littoral lagoonal to lacustrine facies it shows a gradual climatic environmental change from semi arid conditions associated with evaporites at the jurassic cretaceous transition to a more humid climate at the end of the berriasian though generally organic poor total organic carbon toc the distribution of alkanes hopanes and steranes indicates that the origin of the om is mainly algal bacterial and only changed moderately with the climatic evolution the saline and anoxic bottom water conditions indicated for most of the samples point to the recurrence of salinity stratification within the basin a high contribution of odd numbered c 23 c 31 n alkanes from algaenan containing freshwater algae in particular botryococcus is noted for all the samples despite the low abundance of these organisms in the corresponding palynofacies this prominence probably results from the high resistance to degradation and the selective preservation of botryococcus related lipids the subtle balance of aridity and freshwater inputs favoured both an abundance of botryococcus and the development of anoxia leading to the enhanced preservation of om during the intermediate climatic episode while the conditions were less favourable during the semi arid and more humid episodes

offset vsp in a deviated well to support an obc project the marlim field consists of amalgamated oligo miocene sandstones with excellent porosity and permeability characteristics

a tale of shales the relative roles of production decomposition and dilution in the accumulation of organic rich strata middle upper devonian appalachian basin abstract a new consensus on the processes responsible for organic carbon burial in ancient epeiric seas has emerged more firmly grounded in the uniformitarian framework of modern oceanography and biogeochemistry this consensus recognizes the interdependent roles of sedimentation primary production and microbial metabolism in favor of earlier end member models e g production vs preservation in this study one of the classic stratigraphic sequences upon which the preservation end member was based is re interpreted in light of this new consensus the study employs an extensive new sedimentological biogeochemical database from cores drilled in western new york the database spans over 500 m and 15 my of devonian deposition in the appalachian basin and provides a framework for comparative study of organic matter burial the major conclusions are 1 few organic rich units were deposited under pervasive anoxic sulfidic water columns 2 establishment and breakdown of seasonal thermoclines on annual or longer timescales were the predominant mode of stratification and 3 under such conditions remineralization of bio limiting nutrients may have played a key role in organic matter burial by creating a eutrophication pump this pump may have augmented an already rising nutrient inventory such that productivity levels exceeded the threshold required for development of suboxic to anoxic conditions in sediments and episodically in bottom waters a final conclusion asserts that the master variable for organic matter accumulation was relative sea level change which exerted influence on clastic dilution preservation and production processes sea level rise events led to sediment starvation and organic carbon concentration in distal basin sediments as well as to decreased effectiveness of seasonal mixing and thus longer build up intervals for remineralized nutrients episodic mixing of nutrient enriched bottom waters led to enhanced production ultimately increased clastic sediment delivery and water column mixing during relative sea level fall diluted surface sediment organic content such that respiratory demand could be met by increased oxygen supply thus terminating deposition of strata enriched in organic carbon

chemostratigraphy of the posidonia black shale sw germany ii assessment of extent and persistence of photic zone anoxia using aryl isoprenoid distributions aquatic depositional environments where anoxic conditions extend from bottom waters into the photic zone occurred frequently during the geologic past periods of photic zone anoxia pza can be recognized by the presence of specific lipids produced exclusively by the green sulphur bacteria chlorobiaceae that are preserved in the sedimentary record chlorobiaceae perform anoxygenic photosynthesis that requires light penetration into h2s saturated waters sediment samples integrate paleoenvironmental conditions over time intervals ranging from at best a few decades to more commonly several millennia photic zone anoxia recognized in paleoenvironmental analyses is thus defined as episodic with no further interpretation on the duration and persistence of the anoxic events we provide here a high resolution multiproxy chemostratigraphy study for the toarcian posidonia black shale from the dotternhausen section in sw germany in order to assess duration and seasonal fluctuation of photic zone anoxia based on the relative abundance of derivatives of chlorobiaceae lipids we assess the variability in the degree and persistence of photic zone anoxia using an aryl isoprenoid ratio air obtained by calculating the proportion of the short chain c13 17 versus the intermediate chain c18 22 aryl isoprenoids higher relative abundance of the short chain analogues is interpreted as indicating more intensive aerobic degradation of aryl isoprenoids air varies between values of 0 5 indicative of persistent pza phases and 3 0 for short termed episodic pza events absolute concentration of aryl isoprenoids is negatively correlated with the air which is in agreement with a progressive diagenetic breakdown of aryl isoprenoids the air decreases are validated using independent palecological and geochemical redox indicators for the posidonia shale in sw germany d 2004 elsevier b v all rights reserved

variations in the sterane carbon number distributions of marine source rock derived crude oils through geological time abstract the analysis of the sterane data of a large set of crude oils 414 derivedfrom marine carbonate 27 and siliciclastic source rocks 14 where influences of terrestrial or lacustrine derived organic matter can reasonably be excluded shows that there are increases in the relative content of c28 steranes and decreases in the relative content of c29 steranes through geological time there are no consistent variations in the relative content of c27 steranes through time with one major exception a proterozoic oil from oman palaeozolic and older crude oils are thus generally characterised by strong predominances of c29 steranes and low relative concentrations of c28 steranes significantly higher proportions of c28 steranes and lower proportions of c29 steranes occur in oils derived from jurassic and upper cretaceous source rocks these changes through time do not appear to reflect the chemical evolution of the sterols of one particular variety of marine organism the increase in c28 steranes may be related to the increased diversification of phytoplantonic assemblages in the jurassic and cretaceous possible sources of the c28 sterols necessary for the observed changes in crude oil steranes includes diatoms coccolithophores and dinoflagellates although the technique does not give an accurate means of determining the age of the source rock of a crude oil it is possible to distinguish younger crudes derived from the upper cretaceous and tertiary from palaeozoic and older crudes

molecular isotopic characterisation of hydrocarbon biomarkers in palaeocene eocene evaporitic lacustrine source rocks from the jianghan basin china immature organic matter in lacustrine source rocks from the jianghan basin eastern china was studied for distributions and stable carbon isotopic compositions 13 c of hydrocarbon biomarkers all of the bitumens contain isorenieratane 13 c ca 17 indicating the presence of chlorobiaceae and thus periods of euxinic conditions extended into the photic zone aliphatic hydrocarbon fractions are dominated by pristane and phytane and contain relatively low amounts of 4a and 4 methylsteranes c 30 13 c ca 16 believed to originate from 4 methylsterols in dinoflagellates 13 c values of gammacerane ca 24 and c 30 17 21 h hopane ca 23 are consistent with an origin from bacterivorous ciliates that fed on chlorobiaceae the bitumens contain low relative amounts of organo sulphur compounds one rock contains c 37 and c 38 n alkanes 13 c ca 36 derived from alkadienes and alkenones of prymnesiophytes the distributions of hydrocarbon biomarkers suggest that they were initially sulphurised during early diagenesis and later released during early thermal maturation

molecular stable carbon isotope compositions of alkylphenanthrenes in coals and marine shales related to source and maturity abstract phenanthrene phe and methylphenanthrenes mps extracted from coaly shale and coal samples containing terrestrial organic matter are compared with the same compounds from marine shales in terms of yields and 13 c values at marginally to fully mature stages of thermal evolution the shales derived from four boreholes in the hils half graben area northwestern germany were shown to be representative of a greater number of samples from the same sites the 13 c values of extractable phe and mps are less negative in the terrestrial 24 3 to 26 0 than in the marine 28 8 to 30 5 samples since these values are unrelated to mean vitrinite reflectance r r values in the range of 0 5 0 9 it appears that the stable carbon isotope composition of phe and mps is controlled by organic matter type rather than maturity

the effects of thermal maturity on distributions of dimethylnaphthalenes and trimethylnaphthalenes in some ancient sediments and petroleums abstract the distributions of di and trimethylnaphthalenes in two sedimentary sequences from western australia have been examined by capillary gas chromatography and combined gas chromatography mass spectrometry a general decrease was observed in the relative proportions of dimethylnaphthalenes and trimethylnaphthalenes with increasing thermal maturity similar trends were also observed for six crude oils which have very different ratios of ethylcholestane epimers indicating very different thermal histories these results suggest that changes in the relative abundances of certain methyl substituted naphthalenes may be useful indicators of thermal maturity of sedimentary organic matter and the use of a number of isomer ratios is illustrated

geochemistry of an early diagenetic concretion from the birchi bed l lias w dorset u k abstract three concentric growth zones calcitic core dolomitic zone outer rim have been recognised in a carbonate concretion from the birchi bed l lias u k of w dorset each zone has characteristic trace metals carbonate stable isotopes and biological markers the organic matter which fuelled the formation of the concretion was derived from the immature parent shales with beef however bitumen trapped within each zone has been affected by the dominant bacterial processes which led to the precipitation of the carbonates it is suggested that the calcitic core precipitated under sulphate reducing conditions here most biological markers are present in low amounts possibly as a result of bacterial degradation the dolomitic zone is characterised by a high abundance of isotopically light phytane which suggests direct input from methanogens this is consistent with isotopic data for the dolomite which indicates a dominantly methanogenic origin however the presence of hop 17 21 ene n alkenoic acids and of the c 32 hopanoic acid indicate concomitant non methanogenic bacterial activity in the outer rim where calcites have negative carbon isotopic values the high concentrations of n alkenoic acids in the bitumen suggest a non methanogenic bacterial origin for the carbonate the study shows the potential of using organic geochemical techniques to study the in situ formation of diagenetic precipitates biological markers trapped in the concretion may provide a snapshot of sedimentary microbial processes

identification and distribution of chrysene methylchrysenes and their isomers in crude oils and rock extracts abstract chrysene its methylated homologues and their structural isomers are important polyaromatic compounds in crudes oils coals and sediment extracts chrysene benzo a anthracene methylchrysenes and methylbenzo a anthracenes were unequivocally identified in mass chromatograms by comparison with authentic standards and by retention indices reported in the literature the response factors relating those of chrysene and methylchrysenes to internal standards perdeuterated chrysene chrysene d12 and pyrene pyrene d10 were obtained by gc ms analyses of mixture solutions with different concentration ratios the oil families of ordovician reservoirs in the cratonic region of the tarim basin nw china are distinguished by the distribution patterns of chrysene methylchrysenes and their isomers the majority of the oil accumulations and sediment extracts from the middle upper ordovician source rocks are characterized by low concentrations of benzo a anthracene and methylbenzo a anthracenes relative to chrysene and methylchrysenes respectively in contrast some oils with relatively high abundances of benzo a anthracene and methylbenzo a anthracenes were derived from cambrian and lower ordovician source rocks the effect of maturity on the distribution patterns of methylchrysenes in tertiary lacustrine shales from the liaohe basin east china was investigated the 2 1 methylchrysene ratio keeps a nearly constant value with increasing maturity at the low maturity stages and then it abruptly increases corresponding approximately to the onset of intense c 15 hydrocarbon generation this indicates that chrysene and its methylated homologues are useful molecular indicators in petroleum geochemistry

biomarker evidence for two sources for solid bitumens in the subu wells implications for the petroleum prospectivity of the east papuan basin abstract late cretaceous sandstones from the subu 1 and 2 wells aure scarp papua new guinea contain patchily distributed solid bitumens the solid bitumens vary in reflectance and geochemistry indicating that they formed by the biodegradation of two different families of crude oils termed family a and family b biomarker characteristics such as the high abundance of rearranged hopanes and steranes indicate that the family a solid bitumens were derived originally from a clay rich marine source rock low in sulphur which had significant input of terrestrial organic matter these correlate with oils from the iagifu 7x gobe 3x omati 1 and puri 1 wells that are believed to be generated from sources of jurassic age the family b solid bitumens and a fluid inclusion oil from subu 1 have a high abundance of 2 methylhopanes bisnorhopanes and dibenzothiophene and originated from a marine source rock with a calcareous component this source rock had a high proportion of prokaryotic organic matter input a greater sulphur content and a more reducing depositional environment than the jurassic source rocks the lack of correlation with other oils in papua new guinea suggests the presence of a second so far unidentified generative marine source rock in the east papuan basin the fine grained samples in the subu wells are thermally immature vre 0 5 0 6 organically lean and contain type iii organic matter with little hydrocarbon generation potential most of the solid bitumens have peak oil window thermal maturities vre 0 8 1 0 but some have lowered maturities that are interpreted to be due to co extraction of indigenous detrital low maturity organic matter low molecular weight n alkanes alkylcyclohexanes methylalkylcyclohexanes and alkylbenzenes in many of the samples are attributed to overprinting of pre existing variably biodegraded solid bitumens in the sandstones with pristine hydrocarbon charge with a condensate composition this condensate charge has not undergone any major biodegradation or water washing implying that it is a relatively recent event solid bitumen from a vein in a miocene volcanolithic sandstone from the ouha anticline was generated from an early mature palaeogene or late cretaceous source rock that contained predominantly terrestrial organic matter deposited in an oxic environment this sample proves the existence of a different oil generative source rock in the east papuan basin in addition to the two oil source rocks inferred from the subu data

palaeoenvironmental conditions during deposition of the upper cretaceous oil shale sequences in the songliao basin ne china implications from geochemical analysis abstract excellent hydrocarbon source rocks oil shales containing type i organic matter om were deposited in the continental songliao rift basin during the late cretaceous a major contribution of aquatic organisms dinoflagellates green algae botryococcus and minor input from macrophytes and land plants to om accumulation is indicated by n alkane distribution steroid composition and 13 c values of individual biomarkers microbial communities included heterotrophic bacteria cyanobacteria and chemoautotrophic bacteria as well as purple and green sulfur bacteria the presence of methanotrophic bacteria is indicated by 13 c depleted methyl hopane the sediments were deposited in a eutrophic alkaline palaeolake highly reducing saline bottom water conditions and a stratified water column existed during om accumulation of the qingshankou formation and member 1 of the nenjiang formation this is indicated by low pristane phytane gammacerane index and mttc ratios and the presence of carotane and aryl isoprenoids however an abrupt change in environmental conditions during deposition of member 2 of the nenjiang formation is indicated by significant changes in salinity and redox sensitive biomarker ratios a freshwater environment and suboxic conditions in the deep water prevailed during this period higher input of terrigenous om occurred during deposition of the upper nenjiang formation good oil to source rock correlation was obtained using biomarker fingerprints of oil stained sandstone from the quantou formation and oil shales from the qingshankou formation based on the extent of isomerisation of c 31 hopanes the oil was most probably derived from oil shales of the qingshankou formation in deeper parts of the basin

carbon isotopic compositions of prokaryotic lipids as tracers of carbon cycling in diverse settings recent work has highlighted the ubiquity of bacteria and archaea and continues to affirm their significance in diverse biogeochemical processes the 13c values and distributions of diagnostic lipids derived from such microorganisms can provide insights into prokaryotic processes in modern settings and are one of the few means by which past prokaryotic processes in depositional settings can be elucidated here we present a brief review of prokaryotic lipids commonly observed in sediments and the controls on their carbon isotopic compositions we then present two case studies one of mediterranean cold seeps at which anaerobic oxidation of methane occurs and one of a holocene peat deposit in which a variety of aerobic and anaerobic microorganisms govern the degradation of organic matter these two studies illustrate the potential utility of compound specific carbon isotope analyses to deconvolute pathways of carbon flow in microbial communities

source and significance of selected polycyclic aromatic hydrocarbons in sediments hovea 3 well perth basin western australia spanning the permian triassic boundary abstract stable carbon isotopic data for polycyclic aromatic hydrocarbons pahs chrysene and triphenylene benzo e pyrene 9 methylphenanthrene in sediments of comparable thermal maturity from a petroleum drill core hovea 3 well perth basin western australia spanning the largest mass extinction event in the past 500 million years permian triassic boundary are consistent with an algal kerogen source in the basal triassic as opposed to a combustion and or higher plant source in the underlying permian sediments the 13c values of extractable pahs are less negative in the permian inertinitic interval 24 7 to 29 2 than the triassic sapropelic interval 30 to 33 3 a strong correlation is evident between 13c of individual pahs 13c of kerogen and rock eval pyrolysis hydrogen index providing unequivocal evidence that pah 13c is mainly controlled by organic matter type abundant algal derived pahs in basal triassic sediments may be a global feature the lack of coal globally in the basal triassic sediments is also consistent with this observation the early triassic coal gap appears to coincide with the global extinction of peat forming plants at the end of the permian coal did not reappear until the middle triassic and permian levels of plant diversity and thick peat deposits did not recover until the late triassic the pah isotopic data support the contention that a global anoxic event at the end of the permian period contributed to the gradual worldwide asphyxiation and ultimate extinction of many marine and terrigenous organisms

possible algal origin of long chain odd n alkanes in immature sediments as revealed by distributions and carbon isotope ratios a pliocene oil shale pula hungary a c3 plant triticum aestivum and a c4 plant zea mays were compared using isotopic composition of bulk organic matter along with distributions and individual carbon isotope ratios of n alkanes from organic extracts the microalga botryococcus braunii a race was thus shown to be the main source of the predominant 27 29 and 31 n alkanes of pula sediment therefore the dominance of odd carbon numbered n alkanes in the range c25 35 in extracts from immature sediments shall not be systematically assigned to higher plant contribution but algal input is also possible in fact the long chain n alkanes with an odd predominance previously observed in extracts of various immature sediments are likely to be derived at least partially from algae

novel aromatic hydrocarbons of probable bacterial origin in a jurassic lacustrine sequence novel series of aromatic hydrocarbons apparently bacterially derived were detected by gc ms analysis of an oil and three samples of its source rock in addition to high levels of known bacterial marker compounds hopanes benzohopanes and d ring monoaromatic 8 14 secohopanoids all samples exhibited a new series of aromatic secohopanoids which appeared to comprise pairs of c28 c31 demethylated counterparts of the regular d ring monoaromatic 8 14 secohopanoids lacking either the c 27 or more probably the c 28 methyl group further new series appeared to be composed of c28 c30 analogues of the regular and demethylated monoaromatic secohopanoids with an additional c c bond in the e ring alkylnapthalene distributions in the rock samples were dominated by 1 1 5 6 tetramethyl 1 2 3 4 tetrahydronaphthalene 1 2 5 trimethylnapthalene and 1 2 5 6 tetramethylnapthalene deriving from degradation of aromatic 8 14 secohopanoids three prominent phenanthrene analogues of these napthalene derivatives appeared to be present exhibiting similar relative abundance trends in the rock samples which suggests common bacterially derived precursors

biomarkers reveal the role of photic zone euxinia in exceptional fossil preservation an organic geochemical perspective photic zone euxinia pze has proven important for elucidating biogeochemical changes that occur during oceanic anoxic events including mass extinction and conditions associated with unique fossil preservation organic geochemical analyses of a 380 ma invertebrate fossil which included well preserved soft tissues from the gogo formation canning basin western australia showed biomarkers and stable isotopic values characteristic of pze and a consortium of sulfate reducing bacteria which lead to exceptional fossil and biomarker preservation the carbonate concretion contained phytoplankton green sulfur bacteria chlorobi and sulfate reducing bacteria biomarkers with an increasing concentration toward the nucleus where the fossil is preserved the spatial distribution of cholestane unequivocally associated with the fossilized tissue and its high relative abundance to the total steranes suggest that the fossil is a crustacean the presence of an active sulfur cycle in this devonian system including sulfate reduction and the resulting pze played a pivotal role in the preservation of soft tissue from the fossil and its associated low maturity biomarker ratios

higher plant biomarkers reflect palaeovegetation changes during jurassic times abstract the relative abundances of three higher plant derived biomarkers retene cadalene and ip ihmn have been measured in marine sedimentary rocks from the northwest margin of australia it is thought that each biomarker represents input from a different plant type the distributions of these three compounds form a fingerprint representing higher plant input hpf variations in hpf in oxfordian sediments were nearly identical in all three locations with retene becoming very abundant relative to the other two compounds with decreasing age of the sediment this finding strongly suggests that the composition of terrestrial input during deposition largely determines hpf and that the possible effects of diagenesis and catagenesis on the distribution of the three biomarkers are relatively unimportant the marked increase in the abundance of retene relative to that of cadalene during the oxfordian is interpreted to reflect an increase in the contribution of plants that produced precursors for retene i e conifers brought about by a significant change in climate this was exemplified by measuring the distributions of retene and cadalene expressed in the higher plant parameter hpp for a suite of sediments from the carnarvon basin western australia covering the complete jurassic period the hpp profile displays three major cycles each covering a period of at least 10 million years this profile not only compared well with published palaeoclimate data but also showed a remarkable similarity with second order cycles in the global sea level curve thus strongly supporting the proposal that variations in hpf and hpp are indications of changes in palaeoclimate the relation with global sea level further suggests that global factors e g the atmospheric carbon dioxide concentration may play a major role in determining the observed variations in the distributions of these higher plant derived biomarkers

records of seasonal flux in holocene laminated sediments gulf of california holocene laminated sediments from guaymas basin gulf of california mexico have in the past been described as annual couplets of sedimentation couplets comprise an alternation of diatom and terrigenous rich sediment reflecting winter and summer flux to the sediment respectively new data from backscattered electron imagery bsei show that a three component pattern of sedimentation is preserved comprising 1 a lithogenic lamina consisting of clays silt and minor diatomaceous material deposited during the summer and autumn wet season 2 a mixed flora diatomaceous lamina deposited during the early winter collapse of the thermocline and onset of water column mixing and 3 a near monospecific flora lamina of chaetoceros resting spores or more rarely skeletonema costatum representing deposition from or at the end of the spring coastal upwelling bloom recent sediment trap biogenic and terrigenous flux data also show three to four major flux events per year direct comparisons are possible between bsei records and recent sediment trap flux data to facilitate high resolution palaeoceanaographic and palaeoclimatic reconstructions throughout the holocene

lacustrine source rock deposition in response to co evolution of environments and organisms controlled by tectonic subsidence and climate bohai bay basin china three paleogene syn rift intervals from the bohai bay basin the most petroliferous basin in china were analyzed with sedimentological and geochemical techniques to characterize the lateral source rock heterogeneities to reveal the environmental and ecological changes through geologic time and to construct depositional models for lacustrine source rocks under different tectonic and climatic conditions the third es3 and first es1 members of the eocene shahejie formation and the oligocene dongying formation ed display widely variable total organic carbon contents hydrogen indices and visual kerogen compositions suggesting changes in organic facies from deep to marginal sediments carefully selected deep lake facies samples from any interval however display fairly uniform biomarker composition these three intervals have distinctly different biomarker assemblages which indicate weakly alkaline freshwater lakes with a moderately deep thermocline during es3 deposition alkaline saline lakes with shallow chemocline during es1 deposition and acidic freshwater lakes with deep unstable thermocline during the deposition of the dongying formation such environmental changes corresponded to changes in subsidence rate and paleoclimate from rapid subsidence and wet climate during es3 deposition through slow subsidence and arid climate during es1 deposition to rapid subsidence and wet climate during ed deposition and resulted in synchronous changes in terrigenous organic matter input phytoplankton community and primary productivity the co evolution of environments and organisms controlled by tectonic subsidence and climate accounted for the deposition and distribution of high quality lacustrine source rocks with distinctly different geochemical characteristics most rift basins experienced changes in subsidence rates and possibly changes in climates during their syn rift evolutions the models constructed in this paper may have important implications for source rock prediction in other lacustrine rift basins

sulfur rich petroleum derived from lacustrine carbonate source rocks in bohai bay basin east china abstract crude oils produced from the zhanhua depression bohai bay basin are high in sulfur and differ from most lacustrine oils in this basin and elsewhere physical properties biomarker ratios and aromatic hydrocarbon assemblages reveal that they are derived from carbonate source rock horizons representative source rock samples with abundant organic matter toc 1 and s 2 5 mg hc g rock were selected for further correlation and their high bitumen contents indicated their indigenousness to saline or carbonate depositional environments the results of oil source rock correlation suggest that these sulfur rich heavy oils originate from es 3 4 carbonates and marls limited to the bonan sag maturity assessments with burial history showed that they were expelled at the early oil generation window high levels of 20s 5 14 17 and 5 14 17 steranes together with low values for the ts ts tm ratio and two methylated aromatic ratios mdr and mpi 1 were observed in these oils sulfur associated with evaporite and carbonate environments is a significant factor not only in controlling the occurrence of biomarker isomers but also for petroleum formation at abnormally low thermal stress levels

the distribution of molecular fossils derived from dinoflagellates in paleogene lacustrine sediments bohai bay basin china steroids with unconventional side chains in ancient sediments and petroleum have been increasingly used as age diagnostic markers triaromatic dinosteroids and dinosteranes occur widely throughout the eocene oligocene shahejie formation in the southeastern bohai bay basin china consistent with its abundant fossil dinoflagellate assemblages in addition 24 norcholestane biomarkers which commonly appear in marine oils have been found in this lacustrine formation although a firm link has not been established between 24 norcholestane and specific modern taxa both diatoms and dinoflagellates are shown to be likely sources of 24 norcholestanes although the shahejie strata lack intact diatom frustules they do exhibit a good relationship between 24 norcholestane other molecular fossils of dinoflagellates and dinocysts dinoflagellates are important precursor taxa of 24 norcholestanes and the various species identified in eocene oligocene lacustrine shales and mudstones of the shahejie formation are all potential sources of the 24 norcholestanes

the ratios of dibenzothiophene to phenanthrene and pristane to phytane as indicators of depositional environment and lithology of petroleum source rocks abstract the ratio of dibenzothiophene to phenanthrene and the ratio of pristane to phytane when coupled together provide a novel and convenient way to infer crude oil source rock depositional environments and lithologies such knowledge can significantly assist in identifying the source formation s in a basin thereby providing valuable guidance for further exploration the ability to infer this information from analysis of a crude oil is especially valuable as frequently the earliest samples in a new area may be shows and or drill stem test samples from exploratory wells which are characteristically drilled on structural highs stratigraphically remote from the source formation s a cross plot of dibenzothiophene phenanthrene versus the pristane phytane ratios measured on seventy five crude oils from forty one known source rocks ranging in age from ordovician to miocene consistently classified the oils into the following environment lithology groups marine carbonate marine carbonate mixed and lacustrine sulfate rich lacustrine sulfate poor marine and lacustrine shale and fluvial deltaic carbonaceous shale and coal the dibenzothiophene phenanthrene ratio alone is an excellent indicator of source rock lithology with carbonates having ratios 1 and shales having ratios the dibenzothiophene to phenanthrene and the pristane to phytane ratios can also be used to classify source rock paleodepositional environments the classification scheme is based on the premise that these ratios reflect the different eh ph regimes resulting from the significant microbiological and chemical processes occurring during deposition and early diagenesis of sediments the dibenzothiophene phenanthrene ratio assesses the availability of reduced sulfur for incorporation into organic matter and the pristane phytane ratio assesses the redox conditions within the depositional environment interpretation of these ratios has been aided by quantitative biomarker analysis and by carbon isotope data for pristane and phytane obtained by gas chromatography isotope ratio mass spectrometry

molecular proxies as indicators of freshwater incursion driven salinity stratification salinity related stratification in marine environments is one of the main drivers for the development of persistent anoxia and euxinia it therefore plays a vital role in the sedimentary preservation of organic matter and has also been associated with oceanic anoxic events during several mass extinctions in earth s history here we present a novel molecular proxy using relative abundances of methyltrimethyltridecylchromans mttcs as indicators of riverine freshwater incursions into middle to late devonian paleoreefs exposed to conditions of prevailing anoxia photic zone euxinia and water column stratification this paper aims at re instigating a discussion about the origin of these compounds to potentially broaden their utilization as paleoproxies adding freshwater stratification to the general salinity reconstructions the co variation of mttc abundance profiles and 13c values with other biomarker parameters in the sediments studied here indicate a link of mttcs to terrigenous input pointing towards a previously suggested early diagenetic formation of these compounds from phytol with higher plant derived alkylphenols

aliphatic and aromatic biomarkers from gondwanan sediments of late ordovician to early devonian age an early terrestrialization approach abstract twenty one core samples of late ordovician to early devonian age from sections in southern tunisia north african platform gondwana and containing marine and terrestrial organic matter with microbial input were investigated to link the aliphatic and aromatic hydrocarbon distributions with the terrestrial and marine palynomorph content e g acritarchs prasinophytes chitinozoans cryptospores and trilete spores in addition to several biomarkers of algal bacterial origin long chain n alkanes that might be derived from land plants as well as the terrestrial diterpane norabietane were found several land plant derived biomarkers such as retene cadalene simonellite tetrahydroretene and c19 isohexylalkyl naphthalene were observed in the aromatic fractions while these terrestrial biomarkers could be clearly recognized in the middle silurian lower devonian samples their presence in the upper ordovician lower silurian sediments is more doubtful because of much lower relative abundances the land plant biomarkers show a fairly good correlation with the occurrence and abundance of cryptospores and trilete spores derived from bryophytes and tracheophytes which covered the emerged areas around the ghadamis basin during the silurian and devonian the early tracheophytes e g cooksonia lycophytes and zosterophylls are therefore suggested as a new terrestrial source for most of the saturated and aromatic biomarkers found in sediments of middle silurian to early devonian age

biomarker distributions in crude oils and source rocks from different sedimentary environments abstract the saturated and aromatic hydrocarbons from a significant number of oils and source rocks derived from terrestrial and marine organic matter have been analysed by gc and gc ms results show that certain classes of biomarkers including bicyclic sesquiterpanes tricyclic terpanes pregnanes methylsteranes rearranged steranes hopane sulfides benzohopanes long chain alkylbenzenes and pentacyclic triterpanes can be used to distinguish differences in source input and or depositional environments variations in the distributions of the naphthalenes phenanthrenes fluorenes dibenzofurans dibenzothiophenes naphthobenzothiophenes and triaromatic steroid hydrocarbons may also reflect disparities in source input or sedimentary environments

compound specific stable carbon isotope analysis as a tool for correlating coal sourced oils and interbedded shale sourced oils in coal measures an example from turpan basin north western china molecular geochemical methods have shown that it is often diacult to diaerentiate between coal and interbedded shale sourced oils even though coals and interbedded shales may exhibit considerable organic influx variation e g land plant vs algal organic matter due to the changes of depositional setting however compound specific stable carbon isotopic compositions are sensitive to the source input variations typically specific molecules are more depleted in 13 c with increasing content of aqueous biota this hypothesis is examined and exemplified by comparing the stable carbon isotopic ratios of n alkanes from source rock extracts and related oils of the turpan basin northwestern china stable carbon isotopic values of n alkanes extracted from coals and interbedded shales show that d 13 c values of n alkanes with less than 20 carbon atoms vary only slightly however there are dramatic changes in the isotopic compositions of higher molecular weight n alkanes furthermore n alkanes from coal extracts are enriched in 13 c relative to that of interbedded shales with excursions up to 2 3 this comparison enables the diaerentiation of coal and interbedded shale sourced oils and provides information useful in assessing the hydrocarbon system of a basin 2000 elsevier science ltd all rights reserved

variation in stable carbon isotope ratios of individual hydrocarbons as a function of artificial maturity abstract this paper reports isotopic variations in n alkanes isoprenoids and terpenoids from different source rock types as a function of maturity by analysis of these compounds in hydrous pyrolysis products and oil at high pyrolysis temperatures n alkanes isoprenoids and terpenoids in the pyrolysis products become depleted in 12 c the most marked depletion occurs in the terpenoids particularly in the c 29 c 31 hopanes these compounds are isopically very light in the immature unheated samples of the lacustrine green river shale tertiary and a guatemalan carbonate source rock there is a marked depletion in 12 c at 330 c and higher pyrolysis temperatures for these two samples moderately mature samples of the toarcian paris basin shale and a jurassic coal from the hammerfest basin showed less or no 12 c depletion fairly uniform values were recorded for the hopanes in pyrolysates of all samples heated at temperatures of 350 c and above the isotopic composition of n alkanes and isoprenoids are fairly similar to the hopanes in samples pyrolysed at the higher temperatures it appears therefore that with increasing maturity n alkanes isoprenoids and terpenoids become fairly similar in their carbon isotopic composition the isotopic compositions within the different compound groups in the different source rocks are sufficiently different for this technique to be used in source rock oil correlation

molecular indicators of palaeoenvironmental conditions in an immature permian shale kupferschiefer lower rhine basin north west germany from free and s bound lipids a study of the distributions of free and s bound biomarkers and their 13c values in the extract of a bulk sample of the permian kupferschiefer from the lower rhine basin has been carried out to provide a more detailed characterization of the biological inputs the distributions and isotopic compositions of selected components released from nickel boride desulphurization have been compared with those of components in the free fraction the free biomarkers occur in greater abundance than their s bound counterparts the distribution and carbon isotopic composition of both free and bound components in the extract indicate a major cyanobacterial and algal input likewise the free and bound aromatic hydrocarbons contain components which reveal an origin from the carotenoids of chlorobiaceae green sulphur bacteria providing molecular evidence for the occurrence of photic zone anoxia in the water column most of the components in the complex mixture of mono di tri and tetra aromatics in the free aromatic hydrocarbon fraction result from cyclization and aromatization reactions

the role of algal blooms in the formation of lacustrine petroleum source rocks evidence from jiyang depression bohai gulf rift basin eastern china abstract algal blooms are responsible for the laminae in the lacustrine shahejie formation in the jiyang depression one of the sub basins of the bohai gulf rift basin in eastern china about 65 oil fields have been discovered in this depression during the past 40 years and the oil is mainly derived from three types of finely laminated lacustrine rocks of shahejie formation eocene oligocene these lacustrine petroleum source rocks are oil shales calcareous shales and calcareous laminated mudstones optical sem and bsei analyses of these source rocks reveal that there are algal coccoliths and dinoflagellates laminae in the rocks the individual algal lamina is generally composed almost wholly of one species such as reticulofenestra bohaiensis in coccolith laminae and fromea as well as bohaidina in dinoflagellate laminae this distribution suggests that the algal laminae formed from algal blooms in the ancient lake other components of source rocks included organic matter laminae carbonate laminae and clay rich laminae we also discuss the sedimentation of organic matter laminae and carbonate laminae which were related to algal blooms we conclude that the laminated lacustrine petroleum source sediment of jiyang depression formed during episodes of algal blooms alternating with chemical and detrital sedimentation and this represents the primary mechanism responsible for the formation of lacustrine petroleum source rocks

solar modulation of cosmogenic nuclide production over the last millennium comparison between 14c and 10be records for about the last 30 years it has been recognized that the high frequency component of the tree rings 14c 12c record is dominated by the modulation of the cosmic ray flux by the solar wind in particular it has been demonstrated that the three most recent periods of low sunspot occurrence were characterized by high values of atmospheric 14c 12c during the last millennium other periods of high 14c 12c values were observed but their solar origin is still debatable in the present work we compare these fluctuations with an independent record of cosmogenic 10be measured in ice from the south pole to check the solar origin of the observed 14c 12c variations in order to compare quantitatively the results obtained on 10be and 14c it is necessary to take into account the different behaviour of these two cosmogenic isotopes and especially the damping effect of the carbon cycle in the case of 14c as an input to a 12 box numerical model we used the relative fluctuations of the 10be concentrations record measured in south pole ice and converted it into a synthetic 14c record we took into account the fact that 10be modulation is enhanced in polar regions due to the orientation of the geomagnetic field as expected the fluctuations of the modelled 14c record are much smaller a factor of 20 than those observed for the raw 10be record in addition the variations are smoother and shifted in time by a few decades the 10be based 14c variations closely resemble the 14c measurements obtained on tree rings r 0 81 in particular it is easy to identify periods of maximal 14c 12c which correspond to solar activity minima centred at about 1060 1320 wolf 1500 sporer 1690 maunder and 1820 dalton yr a d cross correlation calculations suggest that there is no significant lag between the 10be based 14c and the tree ring 14c records our study strongly suggests the dominance of the solar modulation on the cosmonuclide production variations during the last millennium

geochemical characterization of malm zeta laminated carbonates from the franconian alb sw germany ii abstract during jurassic times especially within the malm stage local depressions formed on the eastern bavarian carbonate platform that were surrounded by wall reefs this created a unique depositional environment where in an open marine setting stagnant and anoxic bottom waters developed in an intra reef depression anoxic conditions were stabilized below wave base by enhanced salinity in the bottom waters and establishment of a density stratification biomarker analysis was applied to characterize palaeosalinity and redox conditions utilizing organic sulfur compound methylated chroman hopanoid and saturated isoprenoid distributions prevention of terrigenous influx by protecting reef walls lead to iron deficiency in intra reefal sediments causing early diagenetic sulfurization of functionalized lipids absence of clay mineral catalysts and early sulfurization favored an unusual steroid distribution lacking rearranged analogues but providing coexistence of saturated steranes with and configuration 13 17 spirosterenes unknown sterenes and steradienes as well as mono di and triaromatic steroids desulfurization of the polar fraction was carried out for two samples to verify that palaeoenvironment reconstruction based on free hydrocarbon and heterocompound distribution was not invalidated by sulfur quenching of selected compounds gammacerane was found to be the only component to occur exclusively in the sulfur bound fraction only minor amounts of hydrocarbons were released upon desulfurization implying that free bitumen analysis was applicable for organofacies characterization organic petrological investigation of organic mats revealed the presence of two different types of such structures comparison of organoclast fluorescence spectra with those of extracted porphyrin fractions indicate an origin of porphyrins exclusively from cyanobacterial mats whereas algal dominated mats yield no porphyrins this aims towards a better localization of specific biomarker origin in geological samples

evidence for photic zone euxinia in the early albian santana formation araripe basin ne brazil organic matter from two black shale units in the santana formation araripe basin ne brazil has been studied to investigate the palaeoenvironmental conditions prevailing during formation of this famous fossil lagerstatte optical and organic geochemical analyses indicate a predominantly autochthonous source with very limited terrestrial input molecular fossils of green sulphur bacteria show that the water column was stratified with euxinic conditions reaching up into the photic zone thus mass mortality events of fish may be explained by intrusion of sulphide containing waters the low quantity of material derived from land plants in this interior marine setting is interpreted to reflect a consequence of enhanced marine productivity resulting in dilution of the continental signal different depositional scenarios are proposed to explain our findings including 1 coastal erosion and nutrient leaching during a transgressive event 2 intrusion of euxinic waters during an early albian oae or 3 an estuarine circulation pattern associated with thermohaline stratification

trimethylnaphthalenes in crude oils and sediments effects of source and maturity abstract three sedimentary sequences and a number of crude oils have been analysed for trimethylnaphthalenes tmns using gas chromatography the sediments were found to contain enhanced relative abundances of 1 2 5 tmn and 1 2 7 tmn in samples of cretaceous age and younger this was especially pronounced in lower maturity sediments containing type iii organic matter older samples containing type iii organic matter were found to contain enhanced relative abundances of 1 2 5 tmn and lower relative abundances of 1 2 7 tmn 1 2 7 tmn appears to be derived directly from the structural degradation of oleanane type triterpenoids present in angiosperms and as such is proposed as a marker for this class of plant and indirectly therefore also for samples deposited since the early cretaceous the crude oils have been classified according to their trimethylnaphthalene compositions this classification enables crudes of higher plant origin to be identified and to be further classified according to whether the organic matter pre dated or post dated the evolution of angiosperms

a comparison of thermal maturity parameters between freely extracted hydrocarbons bitumen i and a second extract bitumen ii from within the kerogen matrix of permian and triassic sedimentary rocks abstract in this study we compared various maturity dependent aromatic steroid and triterpenoid hydrocarbon ratios in bitumens that are freely extractable from sedimentary rocks bitumen i with those in second extracts that comprised hydrocarbons closely associated with the kerogen mineral matrix bitumen ii bitumen ii was released through kerogen isolation and demineralisation using hcl and hf h3bo3 the samples studied although of similar age come from different localities they represent a range of facies and two kerogen types ii and iii and all were deposited under marine conditions the results show that the more stable isomers of methylnaphthalene mn and methylphenanthrene mp are relatively more abundant in bitumen ii the difference between the methylnaphthalene ratio mnr of bitumens i and ii when plotted against the ratio of clay to total organic carbon clay toc gives an excellent correlation r2 0 88 the highest clay toc ratio corresponds with the biggest difference in mnr for the respective bitumens consistent with the more stable isomers being preferentially retained within the clay kerogen matrix since the mp isomers are higher in bitumen ii than in bitumen i it was anticipated that their methylphenanthrene index mpi 1 values a commonly used measure of thermal maturity would also be different for most samples the measured mpi 1 in bitumen i is generally higher than that in bitumen ii except for three samples thus showing a bias towards a lower thermal maturity for the second extract the opposite is true of the mp ratio and mnr this may be attributed to the fact that phenanthrene p which is part of the denominator in mpi 1 is more stable than its methylated counterparts steroid and triterpenoid maturity parameters also showed differences between the two extracts with c27 diasterane sterane and ts ts tm being higher in bitumen i only the former parameter is positively correlated with the clay toc ratio suggesting that clay content probably influences the diagenetic transformation of steroid precursors to diasteranes the observed differences between the maturity parameters of bitumen i and bitumen ii may be especially important in sedimentary rocks that contain high percentages of clay minerals

formation of holocene sedimentary laminae in the black sea and the role of the benthic flocculent layer holocene black sea sediments recovered in 1988 and 1993 from box cores and gravity cores were analyzed geochemically microscopically and with backscattered electron imagery bsei in order to determine the temporal geochemical and sedimentological relationships between the benthic flocculent layer often referred to as the fluff layer and the formation of underlying laminated unit i sediments existence of a permanent benthic fluff layer in the black sea basin is suggested acting as a geochemical transition layer within which all sedimentary particles are hydraulically sorted and particles subject to dissolution or organic remineralization are altered prior to accumulation we propose that particle residence time within the benthic fluff layer is a key factor in determining sedimentary microfabric and geochemical composition of laminated unit i sediments we present a schematic model depicting the above relationships and use it to propose a paleoflux scenario for laminae formation in the unit ii sapropel

organic geochemistry of the early toarcian oceanic anoxic event in hawsker bottoms yorkshire england a comprehensive organic geochemical investigation of the hawsker bottoms outcrop section in yorkshire england has provided new insights about environmental conditions leading into and during the toarcian oceanic anoxic event t oae 183 ma rock eval and molecular analyses demonstrate that the section is uniformly within the early oil window hydrogen index hi organic petrography polycyclic aromatic hydrocarbon pah distributions and tricyclic terpane ratios mark a shift to a lower relative abundance of terrigenous organic matter supplied to the sampling locality during the onset of the t oae and across a lithological transition unlike other ancient intervals of anoxia and extinction biomarker indices of planktonic community structure do not display major changes or anomalous values depositional environment and redox indicators support a shift towards more reducing conditions in the sediment porewaters and the development of a seasonally stratified water column during the t oae in addition to carotenoid biomarkers for green sulfur bacteria gsb we report the first occurrence of okenane a marker of purple sulfur bacteria psb in marine samples younger than 1 64 ga based on modern observations a planktonic source of okenane s precursor okenone would require extremely shallow photic zone euxinia pze and a highly restricted depositional environment however due to coastal vertical mixing the lack of planktonic okenone production in modern marine sulfidic environments and building evidence of okenone production in mat dwelling chromatiaceae we propose a sedimentary source of okenone as an alternative lastly we report the first parallel compound specific c13 record in marine and terrestrial derived biomarkers across the t oae the c13 records of short chain n alkanes acyclic isoprenoids and long chain n alkanes all encode negative carbon isotope excursions cies and together they support an injection of isotopically light carbon that impacted both the atmospheric and marine carbon reservoirs to date molecular c13 records of the t oae display a negative cie that is smaller in magnitude compared to the bulk organic c13 excursion although multiple mechanisms could explain this observation our molecular petrographic and rock eval data suggest that variable mixing of terrigenous and marine organic matter is an important factor affecting the bulk organic c13 records of the t oae

early diagenetic pyrite cementation influences molecular composition of sedimentary organic matter in the dongying depression china abstract micro variations of lipid hydrocarbons and biomarkers in well laminated shales have not been extensively documented especially within different rock textures fabrics and mineralogies comparison of a pyrite cemented zone and its surrounding sediment may offer a new perspective on mineral control on preservation of hydrocarbons and organic carbon a black well laminated shale comprising two adjacent and contrasting calcareous light and pyrite dark laminae at the millimetre scale was selected from the eocene shahejie formation dongying depression bohai bay basin it was horizontally sliced to separate a pyrite cemented concretion from the unaltered laminated shale and investigated using geochemical techniques to assess the heterogeneity of elements minerals microfossils and hydrocarbons within the two slices micro scale changes in source inputs were noted for instance the 4 methylsteranes dinosteranes and the triaromatic dinosteranes show varying distributions between the two slices attributed to slight differences in dinoflagellate contributions similarly variation in the amount of bacterial sulfate reduction is indicated by variations in the aryl isoprenoid ratio relative amount of isorenieratane long chain n alkane carbon isotopic composition and other molecular indicators including the relative amounts of dibenzothiophene dibenzofuran methyldibenzothiophene and methyltrimethyltridecylchromans the primary control on these variations appears to be different euxinic water conditions but diagenesis has also influenced the distributions differential anaerobic bacterial reworking of organic matter and pyrite concretion protection are responsible for organic geochemical variations on a millimetre scale in the shale the pyrite concretion has an altered record of its thermal history but has a more accurate record of the organic geochemistry of microfossils and water column conditions this study shows the potential for future investigations of closely spaced vertical variation in organic geochemical parameters that may shed light on rapid temporal variation in organic matter input and depositional environment

paleosalinity significance of occurrence and distribution of methyltrimethyltridecyl chromans in the upper cretaceous nenjiang formation songliao basin china abstract a group of methyltrimethyltridecyl chromans mttcs was found in core samples of member 1 k 2 n 1 and member 2 k 2 n 2 of the nenjiang formation upper cretaceous from the sk l southern borehole songliao basin china they are assigned for the first time in sediments older than the tertiary in china their composition and distribution are indicative mainly of the redox and salinity conditions in the depositional environment the mttc isomer is in relatively higher abundance in samples from enhanced salinity and reducing conditions but was not detected in samples from aerobic and low salinity environments while mttc appears to be present in samples from environments with a broad range of salinity and redox conditions the mttc mttc ratio has a similar indication as that of the ratio and could be used as a corroborative ratio of paleosalinity a combination of biomarker parameters suggests that the massive lacustrine petroleum prone source rocks associated with the k 2 n 1 interval were likely developed under a stratified water column with enhanced salinity and an anoxic bottom water layer associated with a much less saline fresh to brackish upper water layer

distributions and stable carbon isotopic compositions of biomarkers in torbanites from different palaeogeographical locations abstract the relative distributions and stable carbon isotopic compositions of certain aliphatic and aromatic biomarkers from 11 botryococcus braunii rich torbanites from scotland south africa and australia covering the late carboniferous to late permian were investigated the data was scrutinised for any evidence of molecular features which may be characteristic of palaeogeography the torbanites studied were selected to cover a range of age and palaeoclimatic conditions e g permian and late carboniferous when gondwana was covered by an extensive ice sheet the late permian when the climate warmed from glacial to cool to temperate and the carboniferous when laurasia was located within the equatorial zone all torbanites are composed of abundant n alkanes and novel macrocyclic alkanes which based on similar 13c values are ascribed a common origin all samples are also characterised by a high cyanobacterial input as indicated by abundant hopanoids other biomarker distributions and stable carbon isotopic compositional differences separated the torbanites into three groups which also correlate to three different palaeogeographical palaeoclimatic precincts i group a southern africa and eastern australia temi torbanites which are characterised by a high relative abundance of cyanobacterial and methylotrophic hopanoids abundant branched hydrocarbons and 13c enriched homologous series of monomethylakanes ii group b eastern australia newnes and glen davis torbanites contain relatively high amounts of drimanes and abundant 13c enriched homologous series of monomethylakanes and iii group c scottish torbanites torbane hill and westfield contain high relative amounts of cyanobacterial hopanoids methylotrophic hopanoids and abundant branched aliphatics but no 13c enriched homologous series of monomethylakanes

wave enhanced sediment gravity flows and mud dispersal across continental shelves reappraising sediment transport processes operating in ancient mudstone successions recent studies of marine shelf sediment dispersal show that wave enhanced sediment gravity flows are widespread phenomena and can transport large volumes of fluid mud rapidly across low gradient shelves flow evolution is controlled by sediment supply seabed gradient and spatial distribution of wave energy at the seabed using existing flow models we predict that such flows in mud dominated sediments will develop a three part microstratigraphy produced by changing flow conditions beginning with wave induced turbulent resuspension then development of a wave enhanced sediment gravity flow prior to lutocline collapse and suspension settling petrographic examination of modern flow deposits collected from the eel shelf reveals that resultant beds possess a microstratigraphy consistent with our hypothesis a silt rich basal subunit with curved ripple laminae abruptly overlain by a subunit composed of continuous intercalated silt clay laminae and an upper clay rich drape analyses of beds from ancient mud rich outer shelf and basinal successions cleveland ironstone jurassic uk and mowry shale cretaceous united states show that they too contain beds with this three part organization suggesting that such flows were active in these ancient settings too recognition of these microstructures in these ancient mud dominated successions demonstrates that sediment in these settings was commonly reworked and transported advectively downslope by high energy events contrasting with previous interpretations of these units that deposition was dominated by quiescent suspension settling identification of these recognition criteria now allows the products of this newly recognized sediment dispersal mechanism to be identified in other shale dominated successions

evidence for euphotic zone anoxia during the deposition of aptian source rocks based on aryl isoprenoids in petroleum sergipe alagoas basin northeastern brazil organic geochemistry laboratory chemistry department college of natural sciences federal university of piaui campus minister petronio portella teresina pi 64049 550