relation between depositional environment and the elemental composition of early diagenetic siderite early diagenetic siderites from marine and fresh water depositional environments are characterized by distinctive compositional trends siderite from fresh water environments is often relatively pure i e greater than 90 mol feco sub 3 and commonly attains end member composition siderite from marine environments however is always extremely impure and has extensive substitution of mg up to 41 mol and to a lesser extent ca up to 15 mol for fe in the siderite lattice in addition marine siderite generally contains less mn and has a higher mg ca ratio than fresh water siderite this compositional variation appears to result from differences in the chemistry of early marine and meteoric pore waters inasmuch as early marine pore waters generally have a higher mg sup 2 ca sup 2 ratio and contain less mn sup 2 and fe sup 2 and more ca sup 2 and mg sup 2 than meteoric waters

a novel multiproxy approach to reconstruct the paleoecology of extinct cephalopods abstract reconstructing marine paleoenvironments from the skeletal hardparts of nektic organisms is often hampered by their unknown migrational pathways involving different water masses and their corresponding physico chemical parameters despite significant progress over the last years the reconstruction of migration patterns of extinct ammonoids is difficult because both vertical and horizontal ones lead to an intricate combination of reconstructed seawater temperatures paleonvironmental data retrieved from exceptionally well preserved lower albian douvilleiceras mammillatum ammonite zone uppermost cc8a nannofossil zone 110 5 111 0 ma cephalopod shells from madagascar mahajanga basin 40 42 southern latitude are reconstructed based on a novel multi proxy approach here we combine and contrast i nacre tablet paleobathymetry ii westermann morphospace and iii shell isotope geochemistry analysis results obtained allow for a robust reconstruction of habitat depth paleo seawater temperatures and paleoecology of extinct cephalopod taxa the discocone nautiloid cymatoceras is regarded as vertical migrant with a maximum habitat depth of 250 m and a mean habitat water temperature of 20 21 c all three ammonoid taxa cleoniceras desmoceras and eogaudryceras share a platycone to planorbicone shell shape suggesting a demersal life habit at maximal water depths of 450 500 m and temperatures of 19 21 c for cleoniceras and desmoceras and the deepest 525 m and coolest 14 c habitat for eogaudryceras circumstantial evidence from benthic mollusk shells from the same stratigraphic interval as well as sedimentological and paleopathological data provide further support for habitat reconstructions reconstructed paleotemperatures shown here provide well constrained evidence for the thermal structure of past oceanic water masses and have significance for cretaceous paleoceanography in general

broadband recording of strombolian explosions and associated very long period seismic signals on mount erebus volcano ross island antarctica in december 1996 and january 1997 broadband seismometers were deployed on the summit plateau of mount erebus at radial distances of 0 7 1 4 and 1 9 km from the central crater and lava lake strombolian explosions at erebus previously have been observed to produce seismic and acoustic energy between 1 and 6 hz new observations document significant energy with spectral peaks as grave as 20 s nearly identical very long period vlp signals begin 1 5 s prior to explosions have dilatational onsets and persist for up to 150 s similar vlp waveforms were recorded at all three stations indicating that the seismograms are essentially source dominated particle motions suggest an initial depth for the vlp source of up to several hundred meters migrating deeper in the course of 15 s such explosion associated vlp signals may indicate a nondestructive lossy resonance or nonlinear fluid flow excitation within the shallow magmatic system

lichenometric dating science or pseudo science comment to the paper published by osborn mccarthy labrie and burke quaternary research 83 2015 1 12

broadband seismic experiment at merapi volcano java indonesia very long period pulses embedded in multiphase earthquakes abstract multiphase mp and low frequency lf earthquakes with spectral peak amplitudes at 3 4 and 1 hz respectively are two common types of shallow volcanic earthquakes previously recognized at merapi volcano their mechanisms are poorly understood but mps have been temporally associated with lava dome growth we conducted a seismic experiment in january february 1998 using four broadband seismographs to investigate the nature of seismic activity associated with dome growth during our experiment merapi experienced mild dome growth with low level seismic activity we compare our data to that recorded on a local short period sp network with the following preliminary results mp and lf events as recorded and classified on the short period network instruments were recognized on the broadband network frequency spectrograms revealed similar patterns in the near summit region at widely separated broadband stations higher frequency spectra than previously recognized were identified for both mp and lf events and were strongly attenuated as a function of radial distance from the source thus the spectral characteristics of these events as recorded on far field stations are not fully indicative of the source processes in particular many events classified as lf type appear to have much high frequency energy near the source this aspect of these so called lf earthquakes and their association with very long period vlp pulses suggests that many events identified in the far field as lf events are in actuality a variety of the mp event and involve similar source processes broadband records indicated that simple large amplitude vlp pulses were embedded in mp and lf wavetrains from event to event these pulses were similar in their waveforms and had periods of 4 s vlp events embedded in lf and mp earthquakes were located using particle motions the epicenters were clustered in a central region of the dome complex and preliminary source depths were within about 100 m of the dome surface suggesting a source region deep within the dome or the uppermost conduit a similar source location was established by study of mp high frequency onsets our broadband data suggests that we have recorded both elastic seismic waves and a simple embedded pulse that is interpreted to represent a surface tilt at the seismometer site the inferred tilt indicates an inflation and subsequent deflation possibly caused by a gas pressure pulse or episodic shallow magma transport with stick slip movement of the conduit wall

conditions of formation and diagenetic evolution of upper proterozoic phosphate nodules from southern sweden evidence from petrology mineral chemistry and isotopes abstract dark gray to black cryptocrystalline francolite occurs as nodules 2 8 cm in diameter which are embedded in organic matter rich mudstones of the visingso group upper proterozoic southern sweden the 13cpdb values 18 4 to 0 98 of structural co2 complemented by studies of the petrographic character and strontium isotopic composition of francolite indicate precipitation in the suboxic and sulfate reduction zones francolite is intergrown with berthierine that has formed in the suboxic fe reduction zone calcite enriched in mn and to a lesser extent fe occurs as fracture and void fillings and as replacement of francolite mn and mg rich calcian siderites have precipitated as pseudomorphs after bacteria in the zone of microbial methanogenesis the carbon 13 c pdb 0 75 to 7 04 and oxygen 18 o pdb 14 21 to 10 58 isotopes of calcite suggest derivation of carbonate ions from microbial methanogenesis and from thermal decarboxylation of organic matter at temperatures of 60 to 80 c some of the void and fracture filling calcites 13 c 20 8 to 18 63 18 o 5 46 to 5 21 have however precipitated at lower temperatures 25 30 c in the sulfate reduction zone

de glauconiarum origine the glauconitic facies is widespread on present day continental shelves from 50 s to 65 n and at water depths between 50 and 500 m and is in particularly great abundance on the upper slope and outer shelf between 200 and 300 m it is also common in many ancient rocks of post late precambrian age it occurs as sand to pebble sized essentially green particles granular facies but also as a surface coating on particles and hardgrounds and as a diffuse impregnation film and diffuse facies we suggest the replacement of the term glauconite which has been interchangeably used to designate a morphological form and a specific mineral by glaucony facies and glauconitic smectite and glauconitic mica as end members of the glauconitic mineral family the widely accepted model of burst and hower for glauconitization requires a degraded micaceous 2 1 layer lattice structure parent clay mineral however detailed analysis of numerous samples of recent glaucony reveals that such a parent substrate is exceptional the model therefore requires modification generally the parent material is carbonate particles argillaceous kaolinitic faecal pellets infillings of foraminiferal tests various mineral grains and rock fragments that pass gradually into the commonly occurring green grains we show that the process of glauconitization is achieved by de novo authigenic growth of automorphous crystallites in the pores of the substrate accompanied by progressive alteration and replacement of the substrate it is this two fold evolution that causes the verdissement of granular substrates macrofossils and hardgrounds the authigenic mineral is an iron rich and potassium poor glauconitic smectite while new smectites are growing into the remaining pore space the earlier smectites are modified by incorporation of potassium producing decreasingly expandable minerals with a non expandable glauconitic mica as the end member this mineralogical diversity of the glauconitic mineral family explains the highly variable physical and chemical properties of glaucony four categories nascent little evolved evolved and highly evolved glaucony are distinguished glauconitization appears to be controlled by a delicate balance between degree of physical confinement of a particle and the amount of ionic exchange between the micro environment and ambient open marine sea water the optimum conditions for glauconitization are those of semi confinement as a result the interior of a grain is more glauconitized than its less confined periphery similarly for identical substrate types large grains 500 m provide more favourable substrates for glauconitization than lesser confined small grains on a larger scale the formation of glaucony is governed by the availability of iron and potassium and the balance between detrital influx and winnowing low accumulation rates expose grains to the open marine environment for sufficiently long times 105 106 years for highly evolved glaucony

magmatic processes revealed by textural and compositional trends in merapi dome lavas syn eruptive degassing of volcanoes may lead to syn eruptive crystallization of groundmass phases we have investigated this process using textural and compositional analysis of dome material from merapi volcano central java indonesia samples included dome lavas from the 1986 88 1992 93 1994 and 1995 effusive periods as well as pyroclastic material deposited by the november 1994 dome collapse with total crystallinities commonly in excess of 70 phenocrysts 1 microlites the liquids present in merapi andesites are highly evolved rhyolitic at the time of eruption feldspar microlites in dome rocks consist of plagioclase cores ab63an29or8 surrounded by alkali feldspar rims ab53an5or42 compositional pairs which are not in equilibrium a change in the phase relations of the ternary feldspar system caused by degassing best explains the observed transition in feldspar composition a small proportion of highly vesicular airfall tephra grains from the 1994 collapse have less evolved glass compositions than typical dome material and contain rimless plagioclase microlites suggesting that the 1994 collapse event incorporated less degassed partially liquid magma in addition to fully solidified dome rock as decompression drives volatile exsolution rates of degassing and resultant microlite crystallization may be governed by magma ascent rate microlite crystallinity is nearly identical among the 1995 dome samples an indication that similar microlite growth conditions ph2 o and temperature were achieved throughout this extrusive period however microlite number density varied by more than a factor of four in these samples and generally increased with distance from the vent low vent ward microlite number densities and greater microlite concentrations down flow probably reflect progressively decreasing rates of undercooling at the time of crystal nucleation during extrusion of the 1995 dome comparison between dome extrusion episodes indicates a correlation between lava effusion rate and microlite number density suggesting that extrusion slowed during 1995 crystal textures and compositions in the 1992 93 and 1994 domes share the range exhibited by the 1995 dome suggesting that transitions in crystallization conditions i e rates of undercooling determined by effusion rate are cyclic q 2000 elsevier science b v all rights reserved

very long period oscillations of mount erebus volcano as the signal decays vlp scalar moments up to 5 10 11 n m exceed sp moments by an order of magnitude or more suggesting distinct though genetically related sp and vlp source mechanisms we conclude that vlp signals arise from excitation of a quasi linear resonator that is intimately associated with the conduit system and is excited by gravity and inertial forces associated with gas slug ascent eruption and magma recharge vlp signal stability across hundreds of eruptions spanning 5 years the persistence of the lava lake and the rapid posteruptive lava lake recovery indicate a stable near summit magma reservoir and vlp source process index terms 4544 oceanography physical internal and inertial waves 7280 seismology volcano seismology 8419 8414 volcanology eruption mechanisms 8419 volcanology eruption monitoring 7280 keywords strombolian very long period volcano seismology

burial of organic carbon and pyrite sulfur in sediments over phanerozoic time a new theory in present day marine sediments almost all of which are deposited in normal oxygenated seawater rates of burial of organic carbon c and pyrite sulfur s correlate positively and bear a constant ratio to one another c s 3 on a weight basis by contrast calculations based on the isotopic model of garrels and lerman 1981 indicate that at various times during the phanerozoic the worldwide burial ratio must have been considerably different than the present day value this ratio change is caused by the requirement that increases in the worldwide mass of organic carbon must be accompanied by equivalent decreases in the mass of sedimentary pyrite sulfur in order to maintain a roughly constant level of o2 in the atmosphere such apparently contradictory behavior can be explained if the locus of major organic carbon burial has shifted over time from normal marine environments as at present to non marine freshwater or to euxinic environments in the geologic past a shift to predominantly freshwater burial can help explain predicted high c s ratios in permo carboniferous sediments and a shift to euxinic environments can help explain predicted low c s ratios during the early paleozoic it is demonstrated that the three environments today exhibit distinguishably different average c s ratios

carbon isotopic evidence for coupled sulfate reduction methane oxidation in amazon fan sediments abstract carbon isotope ratios of dissolved inorganic carbon were measured on porewaters from amazon fan sediments collected on ocean drilling program leg 155 values as low as 49 6 vs pdb were recorded with the lowest values coinciding with the base of the sulfate reduction zone at each site the values indicate that on the order of 50 85 of sulfate reduction in amazon fan sediments takes place by methane oxidation estimated rates of methane oxidation range from 0 3 1 0x10 5 moles l yr the reasons for the high percentage of sulfate reduction taking place by methane oxidation are thought to be the large decrease in fan sedimentation rates in the early holocene and the terrestrial source of organic matter in fan sediments

early diagenetic reactions in interbedded pelagic and turbiditic sediments in the nares abyssal plain western north atlantic consequences for the composition of sediment and interstitial water abstract measured pore water concentrations of iron in interbedded pelagic and turbiditic sediments from the nares abyssal plain are in excellent agreement with sediment colour and measured redox potential the organic carbon content of these sediments appears to define the redox conditions and consequently the porewater and solid phase concentration of constituents that are involved in early diagenetic reactions in the turbiditic sediments the concentration of no 3 generally goes to zero within a sediment depth of 1 m whereas at 8 m in a pelagic core from the same area the concentration of no 3 is still higher than it is in the bottom water the pore water concentration of mn 2 in the turbiditic sediments increases sharply down to a depth of approximately 3 m and from thereon remains nearly constant due to saturation with respect to mn ca co 3 the pore water of the turbiditic sediments is also saturated with respect to calcite the few diagenetic spikes in the pore water concentration of no 3 and mn 2 and the concentration depth profile of dissolved iron h 4 sio 4 and phosphate all clearly demonstrate the inhomogeneous nature of interbedded pelagic and turbiditic sediments the simultaneous occurrence of peaks of dissolved iron silica and of sediment intervals with a relatively high organic carbon content is attributed to enhanced early diagenetic reactions associated with the decomposition of organic matter in these specific intervals linked with these reactions is the irregular pore water concentration of phosphate which is shown to originate partly from the oxidation of organic matter but mainly from the desorption of phosphate from iron oxide potential concentrations of phosphate are calculated from the stoichiometric early diagenetic reactions and compared with measured concentrations due to the unique combination of low porosity and relatively high sedimentation rates the sediments from the nares abyssal plain are an ideal basis for the study of such interbedded sequences of pelagic and turbiditic deposits

hidden dykes detected on ultra long period seismic signals at piton de la fournaise volcano broadband seismic data enable us to test whether ultra long period ulp signals can be used to investigate magma chamber pressure state and to monitor volcanic eruptions by systematically investigating seismic signals at geoscope station rer we find ulp signals associated with volcanic events during the last 2 decades we tentatively propose to interpret these signals as events highlighting the activity of the upper magma feeding system of the piton de la fournaise volcano and as being related to the deep magma chamber some of these unusual signals were previously detected and usually interpreted in term of tilt battaglia j aki k montagner j j p tilt signals derived from a geoscope vbb station on the piton de la fournaise volcano geophys res lett 27 5 2000 605 608 they are detected using sts1 seismometers sensitive in the bandwidth 10 3 to 10 2 hz this alternative model enables to quantify each event in terms of a pressure drop in the upper magma reservoir of the volcano two kinds of seismic waveforms can be associated with two types of fracturing events the first one is related to the fast rise of a magma batch coming from the deep magma chamber and the second is the result of a slow rise in pressure inside a shallow reservoir in both cases we are able to detect these events on very long period seismic data the interpretation of these signals supports the idea of a single magma source at the sea level thus we propose to classify all the eruptions occurring during the last two decades into two groups corresponding to the two primary pressure states of the magma chamber 2007 elsevier b v all rights reserved

a sequence stratigraphic interpretation of a mudstone dominated succession the lower jurassic cleveland ironstone formation uk microfacies analysis using optical and backscattered electron imagery has been undertaken on 37 samples from the cleveland ironstone formation staithes yorkshire uk four lithofacies were encountered clay rich mudstones silt rich mudstones sand rich mudstones and concretionary carbonates two types berthierine siderite rich ironstones and apatite rich concretionary horizons successive units were found to stack systematically into upward coarsening units on a small 0 1 1 0 m scale upward coarsening and upward fining packages were also found on a larger 1 0 3 0 m scale the small scale upward coarsening units are interpreted to be parasequences while the large scale upward fining and upward coarsening packages are interpreted to be retrogradational and progradational parasequence sets respectively the ironstones occur at the level where the stacking patterns change from being overall progradational to retrogradational while the apatite rich concretionary units occur at the level where the stacking patterns change from being retrogradational to progradational the concretionary carbonates are interpreted to have formed close to at major stratal surfaces the ironstones are interpreted to be either the correlative equivalent of sequence boundaries or part all of the forced regressive system tract while the apatite rich units are interpreted to have precipitated close to at maximum flooding surfaces condensed sections and or major transgressive surfaces

seismicity associated with dome growth and collapse at the soufriere hills volcano montserrat varied seismicity has accompanied growth and collapse of the lava dome of the soufriere hills volcano montserrat earthquakes have been classified as either volcano tectonic long period or hybrid and daily variations in the numbers of events have mapped changes in the style of eruption repetitive hybrid earthquakes were common during the first months of dome growth in july 1996 the style of seismicity changed and regular short lived hybrid earthquake swarms became common this change was probably caused by an increase in the magma flux earthquake swarms have preceded almost all major dome collapses and have accompanied cyclical deformation thought to be due to a build up of pressure in the upper conduit which is later released by magma moving into the dome

broadband seismic observation at the sakurajima volcano japan we installed a portable broadband seismometer streckeisen sts 2 at the sakurajima volcano which has been very active in the recent years the recorded seismograms show a wide variety both in temporal and spectral contents of seismic events from explosions to tremors and exhibit the importance of such broadband seismometry at volcanos we present examples of seismograms to show the potential of broadband seismic observation in monitoring volcanic activities

abstract lower claiborne regional stratigraphic architecture southeast texas to east central louisiana abstract the lower claiborne section and its units discussed and illustrated here of lutetian age middle eocene figure 1 are recognized as a series of marine shelf marginal marine and deltaic strandline deposits regional closely spaced well log cross sections extending for almost 500 miles from south texas to eastern louisiana updip of the claiborne shelf margins clearly show the regional stratigraphic architecture along depositional strike from southeast central texas through east central louisiana ewing 1994 ewing and vincent 1997 the obvious internal forms when viewing the lower claiborne at such great scale are large very low angle sigmoidal clinoform sets delineated by regional flooding surfaces see figure 2 below the flooding surfaces fs are depicted as the flat to sigmoidal lines seen in that cross sectional diagram major fs s shown by heavier lines lesser fs s by thin and or dashed lines these large downlaps are roughly oriented from nw to se across coastal texas and into central louisiana demonstrating the time transgressive nature of the entire lower claiborne the downlaps proceed from oldest to youngest coming from west to east contrast with perkins and hobday 1980 and fisher 1964 basin analysis and subsurface exploration rely on the identification of genetic units or sequences because they are time bounded units which unite all of the co occurring processes and their resulting deposits genetic stratigraphic units are defined and bounded by key flooding surfaces which approximate time lines genetic sequences of galloway 1989a b these units combining progradational and transgressive elements have the advantage of being bounded by surfaces which on the shelf at least are continuous are easy to recognize have associated biozonations and are verifiably correlatable on well logs unconformities which may be detectable in up dip positions in these dynamic basin margin settings are for all practical purposes difficult to impossible to find in the down dip conformable portions of these units and for simplicity s sake are not shown on the accompanying cross section fig 2

whence the gosport sand upper middle eocene alabama the origin of glauconitic shell beds in the paleogene of the u s gulf coastal plain abstract an explanation for the depositional history of the gosport sand has proven to be as puzzling as its diverse mollusk fossils is beguiling we propose that shifting delta lobes produced patchy environments which accumulated to form the gosport sand and likely other glauconite and fossil rich shell beds of the gulf coastal plain of the paleogene we present facies and mineralogical data to suggest glauconite in the gosport sand was deposited during relatively stable environmental conditions increased glauconite maturity and taphonomic alteration in the gosport sand are attributed to eustatic transgression resulting in decreased deposition enhanced winnowing and increased exposure at the sediment water interface increased fossil diversity and abundance likely result from time averaging and accumulation of shells from ancient patchy habitats analogous to modern inner shallow shelf and open sound environments delta progradation and subsidence would have determined the migration of these environments we evoke a similar depositional model for glauconite rich shell beds distributed throughout the paleocene and eocene of the gulf coastal plain based on their transgressive nature and roughly equivalent facies these shifting environmental conditions may have played a partial role in generating the high molluscan diversity of the gulf coastal plain of the paleogene

paleoecology of the eocene wheelock member of the cook mountain formation in western houston county texas abstract eighty five species of foraminifera and forty nine molluscan species were recovered from the wheelock member of the cook mountain formation in the porter springs area of houston county texas and along the little brazos river in brazos county texas the wheelock member is primarily a regressive unit a thin shell lag deposit at the base of the member is all that remains of the transgressive part of the sequence above the shell lag deposit the lower part of the member consists dominantly of bioturbated glauconitic fossiliferous mudstone the percentage of planktic foraminifers and the diversity of benthic foraminifers suggests deposition in an inner or inner middle shelf environment the low diversity and equitability of the molluscan population and the abundance of opportunistic corbulid bivalves suggest that the environment was at least periodically unstable the upper part of the wheelock member consists dominantly of regularly layered or laminated mudstone and siltstone and contains only a low diversity assemblage of agglutinated foraminifera this part of the member was probably deposited in a shallow brackish water environment with a high sedimentation rate planktic foraminifers recovered from the wheelock member support an age correlation with the late middle eocene morozovella lehneri or orbulinoides beckmanni zones according to berggren and others 1985 this corresponds to an absolute age of between 42 and 46 million years b p

deformation and seismic precursors to dome collapse and fountain collapse nuees ardentes at merapi volcano java indonesia 1994 1998 abstract following the eruption of january 1992 episodes of lava dome growth accompanied by generation of dome collapse nuees ardentes occurred in 1994 1998 in addition nuees ardentes were generated by fountain collapse in january 1997 and the 1998 events also suggest an explosive component significant tilt and seismic precursors on varying time scales preceded these events deformation about the summit has been detected by electronic tiltmeters since november 1992 with inflation corresponding generally to lava dome growth and deflation or decreased inflation corresponding to loss of dome mass strong short term days to weeks accelerations in tilt rate and seismicity occurred prior to the major nuees ardentes episodes apart from those of 22 november 1994 which were preceded by steadily increasing tilt for over 200 days but lacked short term precursors because of the combination of populated hazardous areas and the lack of an issued warning about 100 casualties occurred in 1994 in contrast the strong precursors in 1997 and 1998 provided advance warning to observatory scientists enabled the stepped raising of alert levels and aided hazard management as a result of these factors but also the fortunate fact that the large nuees ardentes did not quite descend into populated areas no casualties occurred the nuee ardente episode of 1994 is interpreted as purely due to gravitational collapse whereas those of 1997 and 1998 were influenced by gas pressurization of the lava dome

the origin of harmonic tremor at old faithful geyser volcanic tremor the seismic signal which is often associated with eruptions is among the least understood phenomena in seismology large variations in the physical properties of volcanic rocks and fluids along with the complex geological structure make it difficult to obtain reliable source models old faithful geyser yellowstone national park was chosen as a laboratory for studying fluid flow induced seismicity the geyser s cyclic behavior on an hourly time scale and its accessibility make it suitable for a detailed study of seismic behavior between eruptions simultaneously with underwater pressure measurements inside the geyser we observe that sharp pressure pulses inside the water column attributed to steam bubble collapse are followed by distinct seismic events with a sharp onset and a harmonic horizontal motion whose frequency varies spatially but not temporally a superposition of these events creates the appearance of continuous harmonic tremor since the pressure in the water column exhibits no sign of resonance the harmonic motion must be caused by elastic waves reverberating in the solid medium a near surface soft layer is demonstrated to be a possible elastic model the harmonic tremor observed at old faithful seems analogous to some examples of shallow volcanic tremor

highlights from a seismic broadband array on stromboli volcano an array of nine three component broadband seismometers was deployed in two different configurations on stromboli volcano the analysis of the seismic wavefield related to volcanic explosions revealed some observations which offer a completely new insight into the internal dynamics of a volcano these new observations are restricted to the low frequency range below 1 hz and underline therefore the superiority of broadband recordings over conventional short period observations surprisingly simple wavelets indicate an initially contracting source mechanism gas jets that could not be seen in a short period seismic record at all generate a clear dilatational wavelet in a broadband recording suggesting the same contracting source mechanism the analysis of particle motion and seismic array techniques permits a location of the seismic source we find low frequency signals of 3s and 6s period that are not related to eruptions and do not share a common source with the eruption related events a video recording of visible volcanic activity at the crater region allows one to correlate precisely eruptive features with seismic signals

collection and three dimensional modeling of gps and tilt data at merapi volcano java we study here the deformations associated with the november 1996 to march 1997 eruption period at mount merapi central java one of the most active volcanoes in indonesia this activity period includes a vertical explosion on january 17 and an increase of the lava dome volume by about 3 106 m3 two global positioning system gps campaigns have been carried out on a six benchmark network at the beginning and at the end of the period relative displacements with respect to the reference point show an average subsidence of 6 5 cm a multicomponent tilt station installed on the southeast flank 3 km from the summit recorded a tilt of 11 1 0 7 rad in the tangential direction and 0 9 0 4 rad in the radial direction these data are interpreted using a three dimensional 3 d elastic model based on the mixed boundary element method and a near neighbor monte carlo inversion interpretation of tilt data requires an accurate mesh for discretizing the 3 d topography the final result supports a horizontal elliptic magma source located 8 5 0 4 km below the summit and 2 0 4 km to the east of it in particular the data cannot be consistent with the location of a magma chamber determined from seismic activity analysis i e 2 km below the summit the computed depth depends strongly on the source shape and cannot be constrained properly because of the small amount of data the computed deflation of 11 2 106 m3 is about 3 times larger than the observed increase in the lava dome volume this difference is attributed to rock avalanches and pyroclastic flows on the flanks of the volcano

spatial and temporal variations in early diagenetic organic matter oxidation pathways in lower jurassic mudstones of eastern england abstract the lower liassic succession of the east midlands platform eastern england comprises shallow marine mudstones and oolitic ironstones in these sediments temporal and spatial variations in the relative importance of early diagenetic anaerobic organic matter oxidation pathways are recorded the ironstones are stratigraphically condensed and were deposited upon the market weighton swell mws a topographic high in the basin in shallow water and high energy conditions at times of low relative sea level at times of higher sea level stratigraphically condensed mudstones were deposited upon the mws away from the mws stratigraphically expanded mudstones were deposited throughout the lower liassic the ironstones contain berthierine ooids and pore filling cement and siderite pore filling cement with rare pyrite replacing berthierine and siderite mudstones deposited away from the mws contain pyrite as the sole early diagenetic iron mineral contrastingly mudstones deposited upon the mws contain both early diagenetic pyrite and mn rich siderite the presence of berthierine and siderite in the ironstones indicates that sulphide was absent from early diagenetic pore waters and that fe iii reduction dominated anaerobic organic matter oxidation in contrast in mudstones deposited away from the mws the presence of pyrite indicates that sulphate reduction was a predominant pathway for anaerobic organic matter oxidation in mudstones deposited upon the mws the presence of both pyrite and mn rich siderite suggests that both sulphate reduction and fe iii reduction were important during early diagenesis it is proposed that this spatial and temporal variation in relative importance of early diagenetic anaerobic organic matter oxidation reactions was a result of variation in physical sedimentary parameters sediment accumulation rate and energy of environment at times of low net sediment accumulation rates in shallow water high energy environments suboxic diagenesis fe iii and mn iv reduction dominated giving rise to the characteristic berthierine siderite ironstone assemblage at times of higher sedimentation accumulation rates in deeper lower energy environments sulphate reduction dominated leading to pyrite formation at intermediate conditions fe iii mn iv and sulphate reduction were all important leading to precipitation of both pyrite and mn rich siderite

petrology and palaeoenvironmental significance of authigenic iron rich clays carbonates and apatite in the claiborne group middle eocene ne texas the claiborne group eocene in north east texas consists of clayey sandstones and mudrocks both with variable proportions of dark green to brown clay pellets deposited in a marginal to open marine setting on the gulf coast margin the composition of concretionary carbonate and clay pellets from 5 localities has been investigated using a wide variety of analytical techniques our palaeontological sedimentological c s and stable isotope data support an interpretation of marginal marine facies with limited freshwater input for the claiborne group dark green mature pellets are predominantly associated with transgressive bioturbated marine sediments from the weches formation through to the youngest crockett formation there is a trend from pellets composed mostly of dark green serpentine rich mixed layer clay to those of mostly brown immature nontronite rich mixed layer clay the serpentine is intermediate between odinite and berthierine and may have been originally odinite that has undergone partial transformation to berthierine pellet maturity apparently corresponds with the degree of winnowing and sedimentation rate it does not appear to correspond with global temperature fluctuations though the serpentine rich rather than glauconite rich composition may do siderite cement mostly in the form of concretions post dates the iron rich clay pellets and pre dates calcite cement carbonate and apatite concretions show a wide range of mineral cement textures reflecting variation in sedimentary environment and early diagenetic processes based on water temperatures derived from verneriacardia bivalves a precipitation temperature of 20 c is assumed for the concretionary siderite using this temperature we surmise that the siderite precipitated from marine pore waters with intermittent meteoric water mixing

early diagenesis and its relationship to depositional environment and relative sea level fluctuations upper cretaceous marshybank formation alberta and british columbia early diagenesis of the upper cretaceous late coniacian to early santonian marshybank formation was controlled by depositional environment composition of depositional water fe and organic content of the sediment sedimentation rate proximity to the shoreline and influx of meteoric water related to relative sea level fall five depositional environments each characterized by a distinct early diagenetic mineral assemblage have been recognized offshore shelf sediments that were deposited in a dysaerobic environment are characterized by abundant framboidal pyrite and rare septarian concretions composed of early calcite and siderite intense sulphate reduction promoted by the dysaerobic depositional water was the primary influence on early diagenesis offshore shelf sediments deposited under aerobic conditions are characterized by abundant concretions composed of two generations of siderite s1 and s2 in this environment methanogenesis rather than sulphate reduction was more important early diagenesis of the inner shelf sands was generally limited however in sands deposited proximal to the shoreline mixing of marine and meteoric waters promoted crystallization of fe rich chlorite and siderite the shoreface was characterized by dissolution of detrital minerals in the upper portion and precipitation of kaolinite or illite smectite in the lower portion in the coastal plain environment brackish water and early reducing conditions resulted in formation of abundant euhedral pyrite ankerite rather than siderite is the typical early diagenetic carbonate the 18o values of the earliest cements i e early calcite siderite s1 inner shelf siderite indicate crystallization from a low 18o marine derived porewater assuming crystallization at 25 c a 18o value of about 7 smow can be estimated for the seaway during marshybank formation time similar calculations for the overlying dowling member puskwaskau formation suggest that the 18o value of the seaway increased to about 4 smow consistent with its transgressive nature very low 18o values are exhibited by siderite s2 these results indicate crystallization during intermediate diagenesis 60 c from meteoric water 15 smow that entered the marshybank formation during sea level lowstand

non pelletal glauconite from the campanian qusseir formation egypt implication for glauconitization abstract glauconitization processes proposed in the literatures include the layer lattice theory in which glauconite formed through k uptake by a detrital smectite precursor and the neoformation theory that does not require a smectite like precursor the non pelletal glauconite bed in the uppermost part of the campanian qusseir formation at the abu tartur area and the underlying smectite rich beds provided a potential example for the glauconitization process the glauconite occurs as fine clayey moderately hard and homogeneous bed ranges in thickness from 2 to 3 m under the optical microscope glauconite occurs in a unique morphology as very fine green clayey matrix which differs from the typical pelletal shape of many glauconites under the scanning electron microscope it appears as dense uniform and very fine flakes that are composed of si al fe and k x ray diffraction analysis of both bulk samples and clay fractions indicates that the glauconite bed is composed entirely of glauconite geochemical analysis suggested that the investigated glauconites belong to the 2nd stage of the maturity scale i e moderate maturity or they can be alternatively ranked as evolved chondrite normalized ree patterns exhibit lree enrichment relative to hree la yb n ratios vary from 5 to 8 and slightly negative eu anomalies eu eu from 0 7 to 0 8 clay beds that underlie the glauconite bed are composed of two types of smectites smectite of low k 2 o and fe 2 o 3 contents and smectite of high k 2 o and fe 2 o 3 contents smectite of low k 2 o and fe 2 o 3 contents is considered in this study as the initial precursor of glauconite while smectite of high k 2 o and fe 2 o 3 represents the transitional phase between smectite and glauconite this in turns supports the layer lattice theory in which glauconite formed by k diffusion to a detrital smectite precursor from the sea water due to transgression absence of mixed layer minerals suggests that the diffusion process was active and continuous until reaction completion was reached i e formation of glauconite maturity and ree patterns suggest the possible formation of the studied glauconite probably at shelf environment at approximately 100 m water depth the occurrence of glauconite indicates a marine invasion of the upper part of the qusseir formation which was considered previously as non marine sediments

monitoring a temporal change of seismic velocity in a volcano application to the 1992 eruption of mt merapi indonesia multiplets i e events with similar waveforms are selected from shallow earthquakes recorded on merapi volcano indonesia before the eruption of february 2nd 1992 two multiplet families are found with their sources close to the summit their seismograms are analyzed using the moving window cross spectrum technique which measures the precise time delay between seismic phases in the entire seismogram for both families of multiplets a gradual decrease in the arrival times of coda waves is observed as a function of the date prior to the eruption coda waves are becoming progressively faster up to 1 2 per cent as the time interval to the eruption shortens this observation is interpreted as the consequence of an increase in the seismic velocity inside the volcano the increase in velocity started in may 1991 and was observed until september 1991 4 months before the eruption this velocity increase may be related to an increase in pressure in the magma chamber or in the conduits and to the resulting closure of the surrounding cracks

ground deformation at merapi volcano java indonesia distance changes june 1988 october 1995 abstract edifice deformations are reported here for the period 1988 1995 at merapi volcano one of the most active and dangerous volcanoes in indonesia the study period includes a major resumption in lava effusion in january 1992 and a major dome collapse in november 1994 the data comprise electronic distance measurements edm on a summit trilateration network slope distance changes measured to the upper flanks and other data collected from 1988 to 1995 a major consequence of this study is the documentation of a significant 4 year period of deformation precursory to the 1992 eruption cross crater strain rates accelerated from less than 3 10 6 day between 1988 and 1990 to more than 11 10 6 day just prior to the january 1992 activity representing a general asymmetric extension of the summit during high level conduit pressurization after the vent opened and effusion of lava resumed strain occurred at a much reduced rate of less than 2 10 6 day edm measurements between lower flank benchmarks and the upper edifice indicate displacements as great as 1 m per year over the four years before the 1992 eruption the gendol breach a pronounced depression formed by the juxtaposition of old lava coulees on the southeast flank functioned as a major displacement discontinuity since 1993 movements have generally not exceeded the 95 confidence limits of the summit network exceptions to this include 12 cm outward movement for the northwest crater rim in 1992 1993 probably from loading by newly erupted dome lava and movements as much as 7 cm on the south flank between november 1994 and september 1995 no short term precursors were noted before the november 1994 lava dome collapse but long term adjustments of crater geometry accompanied lava dome growth in 1994 short term 2 cm deflation of the edifice occurred following the november 1994 dome collapse

stability and facies association of early diagenetic mineral assemblages an example from a jurassic ironstone mudstone succession u k abstract sedimentological and petrographic data from two lower liassic ooidal ironstones the frodingham and pecten ironstones and associated mudstones from eastern england have been collected within these ironstones early diagenetic berthierine siderite and minor glauconite have a limited lateral extent associated with an intrabasinal high the market weighton swell this mineral assemblage passes laterally and vertically into mudstones and silty mudstones within which pyrite is the dominant early diagenetic iron mineral the ironstones are stratigraphically condensed having experienced low net sediment accumulation rates and shallow high energy conditions thermodynamic considerations indicate that berthierine and siderite should be stable in anoxic environments where sulfide activity is negligible pyrite is rare within the ironstones suggesting that sulfate reduction was a negligible process during ironstone formation where pyrite is present it postdates berthierine and siderite indicating that sulfate reduction may have been a later process in some beds we propose that berthierine and siderite were precipitated during suboxic diagenesis where sulfate reduction was inhibited and iron reduction was the dominant process of organic matter oxidation suboxic diagenesis resulted from the extended periods of physical and biological sediment reworking during ironstone deposition which favored the oxidation of iron minerals and aerobic egradation and loss of organic matter berthierine formed during early suboxic diagenesis at the expense of detrital clays and iron oxides during later suboxic diagenesis pore water bicarbonate activities increased leading to siderite precipitation early glauconite also formed in places and it seems likely that it formed close to the oxic suboxic interface the predominance of pyrite in the mudstones indicates that sulfate reduction was the major process of organic matter oxidation during early diagenesis

broadband seismic observations at satsuma iwojima volcano japan this paper reports the results of preliminary analysis of broadband seismic observations conducted at satsuma iwojima volcano japan the recorded broadband data show a wide variety of seismic features small m 0 short period volcanic earthquakes characterized by a long 5 s emergent phase and by nearly identical waveforms are located at the very shallow part of the summit crater long period seismic pulses synchronized with a regular amplitude modulation of volcanic tremor have an interval of approximately 46 to 50 min each of the long period pulses has almost identical waveform polarization of the long period events suggests a very shallow source which can be interpreted as a result of a volume expansion mechanism the correlation between the long period seismic pulses and volcanic tremor seems to be associated with magma convection and the degassing process inside the conduit of the volcano

long period seismicity during magma movement at volcan de colima during the period from february to september 2005 volcan de colima produced 30 vulcanian explosions of sufficient magnitude to produce pyroclastic flows of variable size with a total volume of at least 2 5 106 m3 swarms of long period events were associated with each event their duration ranging from about 6 h to 3 days and each swarm containing up to 886 events the characteristics of the swarms have been studied to understand the source mechanism and their relationship with the vulcanian explosions in total 12 548 long period events were analysed using various comparative and statistical methods patterns were not apparent in the data with no correlation between different properties of the swarms duration magnitude or frequency of occurrence of lp events and the magnitude of the associated vulcanian explosion whether recorded by seismicity volume of pyroclastics or altitude of the eruption column this along with other characteristics of the swarms such as the continuation of the swarm after the explosion with an increase in long period event amplitude in some cases suggests that the mechanism is not merely associated with the pressurization under an impermeable cap and resulting pressure differentials between adjacent volumes within the system it is more likely that the production of long period events is dominated by brittle fracturing on the margins of an ascending magma body a model is proposed whereby the unloading above the ascending magma column produced by a vulcanian explosion resulted in an increase in ascent rate reflected in the increasing amplitude of long period events the results reflect the complexity of non linear processes involved during magma ascent degassing crystallization and rupture of the impermeable plug during the vulcanian process at volcan de colima as at many volcanoes long period events represent a useful precursor for eruptive activity for monitoring this paper highlights some useful analyses that can be carried out which could illustrate certain characteristics of an eruptive episode a preliminary model is presented of the conduit processes at work during the cyclic extrusive and explosive activity during 2005

early diagenetic phosphate cements in the albian condensed glauconitic limestone of the tatra mountains western carpathians early diagenetic phosphate cements are described from the albian condensed glauconitic limestone of the tatra mountains western carpathians with regard to their macro and micromorphology distribution classification and genesis the cements occur within stratigraphically condensed semi pelagic foramini feral glauconitic layers and are associated with mature hardgrounds within the tatra albian limestone phosphate cement fabrics consist of crypto to microcrystalline carbonate fluorapatite and they occur as i rim envelopes ii infillings of intraparticle porosity iii rim cement iv multiple rim cement v palisade fabric and vi cluster cement micromorphological variability of the cement fabrics results from varying texture of the cemented sediment the nature of original porosity as well as from presence of associated microbial fabrics the microbial fabrics are interpreted as fossilized coccoid cyanobacteria phosphate cementation developed under peculiar early diagenetic conditions within semi closed microenvironments rich in organic matter in the marine phreatic environment the cementation contributed to the formation of phosphatic fossils and hardgrounds the accretion of the cements was due to concentration of biologically uptaken phosphorus near the sediment water interface enrichment of pore fluids with respect to phosphate and its precipitation within restricted microenvironments phosphate cementation post dated seafloor formation of pelletal glauconite but predated partial decomposition of organic matter as well as dissolution or neomorphism of aragonite and high mg calcite phosphate cementation occurred on a carbonate platform following the submersion of urgonian reefal build ups episodes of phosphate cementation were repeated during the sedimentation of the tatra albian limestone as a response to rapid relative sea level rises and increased influence of nutrient rich tethyan waters

determination of the content and distribution of fixed ammonium in illite smectite by x ray diffraction application to north sea illite smectite a new x ray diffraction method for the determination of the amount and distribution of fixed nht in illite smectite has been developed illite smectite was saturated with k and heated at iso c the 002 and 005 reflections were recorded with steps of 0 01028 and the experimental d values and the values for full width at half height fwhh were determined using a peak profile fitting procedure peak profiles were calculated with the newmod program for illite structures having different amounts of nh and different patterns for the distribution of nh in interlayers for upper jurassic illite smectite from north sea oil source rocks the amount and the distribution of nh in illite interlayers were determined by comparing the experimental values for doo5 and fwhh with the values calculated for the selected illite structures the amounts of nh determined in this manner correlate well with the amounts determined by an isotopic dilution method the results demonstrate that these illite smectite samples have k end member illite and nh4 endmember illite tobelite layers and that the illite layers formed during diagenesis and oil generation actually are tobelite layers

optimized sequential extraction for carbonates quantification and δ13c analysis of calcite dolomite and siderite siderite is present in diverse types of rocks and sediments but its quantification is cumbersome when present in relatively low contents a new analytical method for the sequential separation of different carbonate phases is presented the separation quantification and characterization of the carbonates is based on different kinetic reactions during acid digestion in combination with monitoring the solution composition and the concomitant release of co2 trapping the released gasses permits the isotopic characterization 13c of the different phases based on published rate laws an idealized model was built to identify ph and temperature conditions for optimal separation of the various carbonates by taking the size distribution of carbonate particles into consideration results from the theoretical survey were implemented in an extraction scheme which was optimized and evaluated by tests on pure mineral phases and their mixtures further tests on a diverse array of sediment and rock samples validated the specificity and reproducibility of the method

rhizocarpon calibration curve for the aoraki mount cook area of new zealand development of rhizocarpon growth curve from the aoraki mount cook area of new zealand provides a means to assess little ice age glacier behaviour and suggests approaches that have wider application employing a sampling strategy based on large populations affords the oppor tunity to assess which of various metrics e g single largest average of five largest mean of an entire population best characterise rhizocarpon growth patterns the 98 quantile from each population fitted with a quadric curve forms a reliable representation of the growth pattern since this metric does not depend on the original sample size comparisons are valid where sample strategy must be adapted to local situations or where the original sample size differs for the aoraki mount cook area a surface 100 years old will have a 98 quantile lichen diameter of 34 3 mm whereas a 200 year old surface will have a lichen diameter of 73 7 mm in the southern alps constraints from the age range of calibration points the flattening of the quadric calibration curve and ecological factors limit the useful age range to approximately 250 years copyright 2005 john wiley sons ltd

primary migration by oil generation microfracturing in low permeability source rocks application to the austin chalk texas fracturing of low permeability source rocks is induced by pore pressure changes caused by the conversion of organic matter to less dense fluids oil and gas these fractures increase the permeability and provide pathways for hydrocarbon migration an equation for the pressure change is derived using four major assumptions 1 the permeability of the source rock is negligibly small 0 01 d 10 20 m2 so that the pore pressure buildup by the conversion is much faster than its dissipation by pore fluid flow 2 the stress state is isotropic so that horizontal and vertical stresses are equal the source rock fails when the pore pressure equals the overburden pressure 3 the properties of the rock organic matter and fluids remain constant during oil generation this assumption is valid when the change in depth i e pressure and temperature is small 4 only two reaction rates are required for the conversions a low temperature reaction rate for the kerogen oil conversion e approx 24 kcal mol a approx 1014 m y and a high temperature reaction rate for oil gas conversion e approx 52 kcal mol a approx 5 5 1026 m y the equations for generation rate and pressure change are applied to the austin source rock by adjusting the several variables to fit geochemical data core saturations and observed levels of oil and gas production this application demonstrates that the equations are easily applied in calculating depths of primary migration for low permeability source rocks

accurate surface exposure dating with lichens lichenometry accurately dates exposure times of glacial moraines and landslides when measuring the longest axis of the largest crustose lichen on many blocks as demonstrated by numerous examples in sweden the sizes of rhizocarpon subgenus rhizocarpon describe five pulses of glacial moraine creation in 120 yr six historic california earthquakes between ad 1800 and 1906 caused many landslides that constrain lichen growth as linear with a dating accuracy of 0 5 yr crustose lichen sizes date earthquake created additions to sierra nevada talus with an accuracy of 5 yr the oldest lichen ages are 400 yr for lecanora sierrae 800 yr for lecidea atrobrunnea and 1100 yr for acarospora chlorophana and rhizocarpon subgenus rhizocarpon lichen sizes also record differing spatial attenuation of ground shaking from the magnitude m w 7 9 san andreas earthquake of ad 1857 and the more distant smaller san jacinto ad 1800 earthquake which both caused sierra nevada rockfalls ad 1800 seismic shaking was relatively stronger than that of ad 1857 farther north perhaps expressing stronger love and rayleigh styles of surface waves from the north trending ad 1800 surface rupture that were particularly efficient in causing rockfalls at greater distances

petrology and palaeoenvironmental significance of glaucony in the eocene succession at whitecliff bay hampshire basin uk following the investigations of odin and others into the distribution of green granules glaucony has been widely assumed to be a reliable indicator of a fully marine open shelf environment with a low sedimentation rate we have investigated the value of glaucony as a palaeoenvironmental indicator through an investigation of the pellets and their distribution and reworking in the predominantly brackish to shallow marine tertiary sediments of the hampshire basin together with a re evaluation of the sedimentology glaucony has apparently formed in situ in all lithofacies from shallow marine to estuarine of the three highest glaucony concentrations all dominated by in situ glaucony two occur within highstand system tracts the third is at a sequence boundary several important surfaces do not have more than a few percent glaucony with very variable proportions of mature and in situ pellets the correlation between glaucony concentration and sequence stratigraphy is most obvious in the london clay and wittering formations where least reworking of pellets has occurred in the barton group there are no major concentrations of glaucony at any of the important stratal surfaces we believe this more random glaucony distribution is due to limited glaucony formation and reworking of older glaucony in these sediments ideal conditions for glaucony formation are interpreted to have been fully marine 10 30 m water depth a warm temperature plus low sedimentation rate with periodic winnowing to concentrate the pellets although most of these conditions for glaucony formation occurred in the selsey formation and barton group a factor or factors mitigated against glauconitization we suggest that this was lowering of the water temperature the london clay and wittering formations were deposited relatively rapidly 50 60 m ma 1 and include intervals of estuarine sedimentation both factors that we believe inhibited glaucony formation glaucony maturity reflects the minimum length of time spent in surface sediments close to the oxic sub oxic interface point count data and chemical data for glaucony indicate widespread reworking and an overall increase in reworking with time possibly due to uplift on the isle of wight monocline the apparently wide range of conditions in which glaucony will form and the frequency with which it is reworked suggest that it is a less useful indicator palaeo environmental indicator than is commonly supposed

anatomy and origin of a cretaceous phosphorite greensand giant egypt late cretaceous epicontinental phosphorites porcelanites cherts dark coloured shales glauconitic sandstones and bioclastic and fine grained carbonate rocks in egypt are examined in terms of their overall depositional and diagenetic framework and stable isotopic and organic geochemical characteristics two main depositional realms are interpreted and correlated through sequence stratigraphic analysis 1 a shallow hemipelagic environment accompanying initial stages of marine transgression and conducive to the formation of organic carbon rich shales biosiliceous sediments and thick phosphorites and 2 a relatively high energy depositional regime accompanying sea level fall during which deltas advanced glauconites were reworked seaward and prograding oyster banks became periodically exposed to episodes of fresh water diagenesis thereby promoting solution collapse phenomena in associated cherts lenticular to massive phosphorites are viewed as the result of current winnowing and concentration of authigenic grains initially precipitated in associated reducing shales and biosiliceous sediments in eastern egypt the phosphorites form winnowed lag layers some of which may have been redeposited down slope in structural lows in the west these sands were concentrated into giant phosphorite sand waves built by reworking of penecontemporaneously deposited phosphatic muds during marine transgression carbon isotopic results substantiate interpretations from modern deposits for limitation of phosphate mineral precipitation with depth in sediments as a result of lattice poisoning however direct desorption of phosphorus to pore waters from detrital iron oxyhydroxide phases also may have been important in the cretaceous setting the iron reduced in this process being available for incorporation in glauconites the main locus for authigenic glauconite precipitation appears to be where iron fluxes from regions of lateritic weathering were highest and near the boundary between oxygenated and reduced waters this study suggests a model for the common coexistence of glauconites and phosphorites in the geological record although upwelling is often advocated as the origin of nearly all giant phosphorite deposits we suggest that some of these may have been strongly influenced by fluvially derived phosphorus borne on particulates and desorbed from these compounds upon flocculation and or reduction in bottom waters or pore waters

magma eruption rates of merapi volcano central java indonesia during one century 1890 1992 the magma eruption rates of merapi volcano form 1890 to 1992 are re examined chronologically for this volcano movements of extruded lavas and domes as well as their extrusions are important because they control the modes of the subsequent activities and cause nuees ardentes and lahars the monthly eruption rates varied widely but the cumulative volume of lavas has increased linearly and is expressed as 0 1x106 m3 month the magma production rate of this volcano may have been constant for these 100 years recurrent excessive effusion of lavas is tentatively interpreted by assuming a magma reservoir the averaged eruption rate is small in comparison with other volcanoes such as nyramuragia kilauea and vesuvio however it is remarkable that the activity has been continuous for these 100 years and the total amount of lava discharged during this period reached more than 108 m3 a simple model for the formation of the 1992 lava dome is presented the viscosity of the lavas is probably between 106 and 107 p and the length of the magma conduit is probably less than 10 km

signs of magma ascent in lp and vlp seismic events and link to degassing an example from the 2010 explosive eruption at merapi volcano indonesia the link between seismicity and degassing is investigated during the vei 4 eruptions of merapi volcano indonesia in october and in early november 2010 seismicity comprised a large number and variety of earthquakes including volcano tectonic events a sustained period of long period seismicity lps i e long period events lp very long period events vlp and tremor lps seismicity is ascribed to the excitation of fluid filled cavity resonance and inertial displacement of fluids and magma we investigate here lps that occurred between 17 october and 4 november 2010 to obtain insights into the volcano eruption processes which preceded the paroxysmal phase of the eruption on 4 5 november we proceed to the moment tensor inversion of a well recorded large vlp event during the intrusion phase on 17 october 2010 i e before the first explosion on 26 october by using two simplified models crack and pipe we find a shallow source for this vlp event at about 1 km to the south of the summit and less than 1 km below the surface we analyze more than 90 lp events that occurred during the multi phase eruption 29 october 4 november we show that most of them have a dominant frequency in the range 0 2 4 hz we could locate 48 of those lp events at least 3 clusters of lp events occurred successively we interpret these observations as generated by different fluid filled containers in the summit area that were excited while magma rose we also observe significant variations of the complex frequency during the course of the eruption we discuss these changes in terms of a variable ratio of fluid to solid densities and or by possible conduit geometry change and or permeability of the conduit or the edifice and or by resonance of different fluid containers during the release of more than 0 4 tg of so2 and large but unknown masses of other volcanic gases finally we also discuss how the major explosions of the eruption were possibly triggered by passing waves resulting from regional tectonic earthquakes on 3 and 4 november

textural and mineral chemistry constraints on evolution of merapi volcano indonesia abstract we analyze and compare the textures of merapi lavas basalts and basaltic andesites ranging in age from proto merapi through modern activity with the goal of gaining insights on the temporal evolution of merapi s magmatic system analysis of textural parameters such as phenocryst and microphenocryst crystallinity coupled with crystal size distribution theory provides information about the storage and transport of magmas we combine textural analyses with geochemical investigations for a comprehensive comparison of erupted lavas over time the chemical analyses identify crystal growth processes in magma chambers and underline differences between sample groups our work suggests the occurrence of two distinct histories presumably associated with at least two generally distinct types of rheological behaviors and storage transport systems these behaviors are associated with different plagioclase growth patterns with both groups influenced by late stage shallow decompression degassing induced microlite crystallization both groups contain amphibole crystals that indicate an early period of mid crustal to deep crustal storage of water rich magmas dome lavas from the 20th century eruptive activity indicate quasi steady state nucleation and growth evolution interspersed with episodes of reheating and textural coarsening suggesting residence in magma storage at multiple depths both 10 km and

an overview of the seismicity of merapi volcano java indonesia 1983 1994 abstract from 1982 to 1995 merapi volcano java indonesia experienced two main eruptive cycles from 1984 to 1986 and from 1992 to 1994 each cycle had a duration slightly larger than 2 years four major eruptive events occurred in 1984 1986 1992 and 1994 these eruptions were monitored by a telemetered seismic network we present an overview of the seismicity observed between 1983 and 1995 from seismological observations several types of characteristic events are recognised volcanotectonic earthquakes are standard microearthquakes either shallow an aseismic zone is situated between two seismic zones at a depth between 1 5 and 2 5 km below the summit we postulate that it is a small shallow magma reservoir where magma injected from below can be stored temporarily we try to relate seismic observations during both eruptive cycles to the initial injection of deep magma to the superficial magma system the first eruption in each case seems to involve magma enriched in gas that extrudes the content of the conduit and explodes the old dome a regular outflow of magma follows the initial explosion and gradually a dome is building up then it stops and a period of repose is observed later a second episode of dome growth occurs the height of the dome reaches a maximum corresponding to a state of lithostatic equilibrium the time delay of more than 2 years between the beginning and the end of a cycle may result from crystallisation in a volatile rich magma and from the building up of pressure in the superficial magma pocket some important events like the collapse of the dome on 22 november 1994 are not preceded by any seismic precursor when it reaches a large volume the dome is not stable and is likely to collapse by gravity for instance after the sudden influx of matter or gas or after a heavy rain on merapi tremors are observed but do not always precede a dangerous event

evolution of early cenozoic marine temperatures the equator to high southern latitude sea surface and vertical temperature gradients are reconstructed from oxygen isotope values of planktonic and benthic foraminifers for the following five time intervals late paleocene early eocene early middle eocene late eocene and early oligocene paleotemperatures are calculated using standard oxygen isotope temperature equations with adjustments to account for 1 variations in sea water 18o related to changes in global ice volume over time and 2 latitudinal gradients in surface water 18o these reconstructions indicate that sea surface temperatures sst of the southern oceans in the early eocene were as high as 15 c whereas temperatures during the late paleocene and early middle eocene reached maximum levels of 10 12 c by the late eocene and early oligocene high latitude sst had declined to 6 and 4 c respectively for most of the early paleogene low latitude sub tropical temperatures remained constant and well within the range of holocene temperatures 24 ndash 25 c but by the late eocene and early oligocene declined to values in the range of 18 to 22 c the late paleogene apparent decline in tropical temperatures however might be artificial because of dissolution of near surface foraminifera tests which biased sediment assemblages toward deeper dwelling foraminifera moreover according to recent plate reconstructions it appears that the majority of sites upon which the late eocene and early oligocene tropical temperatures were previously established were located either in or near regions likely to have been influenced by upwelling global deepwater temperature on average paralleled southern ocean sst for most of the paleogene we speculate based on the overall timing and character of marine sea surface temperature variation during the paleogene that some combination of both higher levels of greenhouse gases and increased heat transport was responsible for the exceptional high latitude warmth of the early eocene

depositional trends in siliciclastic deposits of the stone city transgressive systems tract middle eocene texas abstract strata exposed at stone city bluff texas contain shelf sediments deposited during progressive marine deepening from shallow water depths and then capped by a maximum flooding horizon they are part of the early bartonian np16 cook mountain transgressive systems tract exposed in the type section of the stone city member of the crockett formation this locality lies on the inner portion of a shelf transect about 175 km 110 mi shoreward of the late eocene shelf slope margin and probably never farther than 80 km 50 mi from the shoreline sedimentary structures in the sediments change upward reflecting a shift from tidal current dominated to storm dominated deposition in lower intervals tidal control is dominant the transition interval contains isolated storm sands as sheets with lenses 40 cm 15 in thick in mudstones with tidal bedding these storm beds contain teeth bone concentrates and some gravel size clasts at the bases of larger lenses in higher intervals storm deposition is dominant in all units mostly as thin distal layers of very fine sand or silt amalgamated storm deposits form larger units e g the moseley bed local hardground surfaces are developed where storm washing exposed concretionary layers or on condensed winnowed zones glauconite occurrence and siderite concretion formation are most common in the upper intervals storm deposits have dual sediment sources and contain 1 skeletal remains shells fish bone and glauconite pellets concentrated by in place winnowing or 2 fine quartzose sand washed in from shallower water settings alternation of amalgamated storm deposits and mudstone units with thin storm deposits indicate a cyclic record of storm activity

intra annual isotopic variation in venericardia bivalves implications for early eocene temperature seasonality and salinity on the u s gulf coast abstract stable isotope compositions were determined for 166 microsamples of aragonite from the bivalve venericardia hatcheplata collected from the early eocene hatchetigbee formation in southwestern alabama these were milled from two transects one across the left valve hinge plate and one along the growth axis amplitude and spacing of about nine years of seasonal variation is very regular with peaks and troughs occurring at equal intervals and reaching consistent compositions except for some attenuation in both parameters during the last three years of life assuming an ice free world with an ocean 18o value of about 1 0 and using the aragonite water fractionation equation of grossman and ku 1986 isotope derived paleotemperatures are somewhat warmer 31 c than temperatures presently recorded anywhere on the earth s surface and exhibit significantly greater seasonality 12 c than regions with the warmest mean temperatures it is therefore likely that these very negative and extremely seasonal 18o values reflect the influence of seasonal discharge of 18o depleted river water into the eocene gulf of mexico comparison of these data with 1 mean annual temperature versus seasonal temperature variation from modern climates 2 isotopic compositions reported from coeval molluscs and 3 isotopic compositions of global meteoric precipitation and united states rivers suggest that mean annual temperature along this portion of the eocene gulf coast was in fact about 26 c and varied seasonally from a winter low of about 25 c to a summer high of 27 c differences between these temperatures and those derived from direct conversion of oxygen isotope values reflect the influence of seasonal influx of fresh 18o value of 4 7 water during deposition of this portion of the hatchetigbee formation ambient water 18o values varied between winter values of about 1 0 to less than 3 5 during the summer freshwater discharge served to seasonally depress salinity to 10 to 16 ppt along this part of the gulf coast the early eocene was perhaps the warmest time interval of the past 65 million years primarily manifest as lower equator to pole temperature gradients in this context an eocene mean annual temperature of 26 c is not much higher than modern surface water temperatures of about 24 c at 29 30 n immediately off the modern alabama coast seasonal temperature variation of 2 to 3 c about a mean of 26 c however is significantly lower than that off coastal alabama 19 to 30 c and occurs only along modern equatorial coasts at latitudes less than 19 this implies that early eocene tropical conditions extended well beyond modern latitudinal limits

mudrock hosted carbonate concretions a review of growth mechanisms and their influence on chemical and isotopic composition existing interpretations of cement textures and isotopic compositions may significantly under estimate the depth and duration of concretionary growth minus cement porosities can commonly under estimate depths of concretionary growth for some or all of the following reasons i cements might not passively replace host sediment porosity ii non cement carbonate phases such as replaced bioclastic carbonate can be significant iii sediment compaction models over estimate rates of porosity loss at shallow carbon isotope data from modern sediments show that dissolved carbonate in the methanogenic zone has a continuum of values from 30 to 15 and thus overlaps 13 c depleted values normally considered characteristic of sulphate reduction many concretions previously thought to have grown entirely during sulphate reduction may therefore have continued cementation during methanogenesis indicating a deeper and more prolonged cementation history the necessary carbonate supersaturation for concretionary growth could either occur throughout the porewaters the equilibrium model or be generated in situ by organic matter decay the local equilibrium model or created where external fluids are introduced the fluid mixing model

long period and very long period events at mt etna volcano characteristics variability and causality and implications for their sources abstract almost 50 000 long period lp events were recorded at mt etna from november 2003 to may 2006 we analysed these events as well as very long period vlp events which were associated with some of them during some intervals the spectral and wavefield features of lp events remained steady with significant changes occurring between the intervals based on the times of the changes we distinguish five different sub periods in particular during sub period iii june november 2005 the wavefield at the stations nearest to the summit area was composed of p waves locations for 150 lp events occurring in sub period iii determined using radial semblance changed at the same time as the events spectral features changed it was during this sub period that many of the lp events were associated with vlp events based on similarity of the waveforms we distinguished two families of vlp events with gradually evolving waveforms the two families are located in slightly different places but near the sources of the lp events the change between the families occurred at the same time as the spectra of the lp events changed finally the source of the vlp events was investigated by performing complete waveform moment tensor inversion of stacks of the two families synthetic green s functions for the full moment tensor were calculated for a homogeneous half space for both families the source region with the highest variance reduction lies approximately beneath the active craters at 500 m below the altitudes of the stations the solutions for both families are very similar with sources that are between 60 and 70 isotropic attempts to determine deviatoric moment tensors produced consistently poorer fits the remaining energy is poorly constrained and is likely to be noise in conclusion these results highlight changes in the lp and vlp events at mt etna over time and the causal relationship between them

microbial influence on the oxygen isotopic composition of diagenetic siderite abstract numerous early diagenetic siderite concretions previously described have been interpreted as the results of microbially mediated reactions interpretation of oxygen isotope data for such material requires an understanding of the effect of temperature on fractionation processes however whilst equilibrium fractionation of oxygen isotopes between siderite and water has been measured down to 33 c extrapolation to lower temperatures may be invalid furthermore inorganic measurements may not be applicable to microbial systems the specific iron reducing microorganism geobacter metallireducens has been cultured anaerobically in the laboratory using acetate as an organic substrate and amorphous feooh as an electron acceptor the acetate is oxidised to co2 with concurrent iron reduction and extracellular siderite precipitation rhombohedral siderite crystals up to 25 m in size have been precipitated over a range of temperatures 18 40 c stable isotopic analysis of these crystals and the solutions from which they precipitate shows that this microbial precipitation of siderite has an associated isotopic fractionation different from the published equilibrium and which is not simply a function of temperature in all cases 18o values of siderite are lower than predicted by inorganic equilibrium fractionation data this may explain the numerous anomalously low 18o values reported for early diagenetic marine siderites and previously attributed to mechanisms such as mixing with meteoric water sediment water interaction recrystallisation or variable isotopic fractionation despite a lack of supporting evidence

fracture healing in a magma an experimental approach and implications for volcanic seismicity and degassing 1 the healing of magmatic fractures is considered essential to repetitive seismicity and the closure of degassing paths during emplacement of lavas to estimate the healing time of magmatic fractures we performed healing experiments on rhyolitic melts at 850 1000 c and 1 6 3 2 mpa for 0 5 94 h two cylindrical obsidian cores were juxtaposed on surfaces prepared by cutting the cores both with and without polishing these were annealed in an open system cell the contact interface became coherent and finally disappeared the water content across the contact initially decreased toward the interface via diffusive dehydration but later homogenized this change was interpreted to reflect atomic scale closure of the interface probably by chemical bonding we defined this closure interval as microscopic healing time and determined this by fitting the measured profiles with a diffusion model the microscopic healing time was strongly dependent on temperature and roughness of the interface and was for the nonpolished interfaces 67 74 4 0 4 9 and 0 36 0 38 h at 850 900 and 950 c respectively whereas for the polished examples it was 1 3 and 0 5 0 6 h at 850 and 900 c respectively this microscopic healing time is consistent with the period of actual seismicity and is prolonged sufficiently to permit the formation of millimeter thick bubble free obsidian layers along fractures in vesicular lavas through bubble resorption due to diffusive degassing

geochemistry of early siderite cements from the eocene succession of whitecliff bay hampshire basin u k abstract siderite cements in the eocene of whitecliff bay hampshire basin u k occur in a range of depositional facies and morphological associations most siderites are associated with in situ glaucony or occur beneath conspicuous lithological breaks these associations illustrate the importance of slow deposition for early diagenetic carbonate precipitation siderite in the eocene sediments of whitecliff bay is impure and in many cases comprises zoned crystals with an overall decrease in substitution of ca mg and mn for fe from crystal core to rim trends in ca mg and mn from early to later siderite vary between samples with no evident environmental control siderite concretions without calcite cement occur only beneath lithological breaks where meteoric water may have been introduced precipitation temperatures have been calculated from siderite 18o data and are based on the assumption that precipitation occurred from seawater these temperatures are reasonable for typical microbial siderite precipitated in marine sediment but are slightly low for marine siderite where there may have been meteoric overprinting if the precipitation temperature for siderite cements is assumed from 18o data for time equivalent biogenic carbonate rather than the composition of the precipitating fluid the calculated isotopic composition of the precipitating fluid is generally compatible with the inferred marginal marine depositional environments

early diagenesis of organic matter in peru continental margin sediments phosphorite precipitation abstract pore water chemistry total dissolved co 2 nh 4 no 3 no 2 po 4 si oh 4 ca mg fe mn so 4 h 2 s and f and titration alkalinity solid phase chemistry c org p org c tot n tot f si opal and s ii and sediment characteristics porosity dry bulk density and formation factors were determined on a centimeter scale spacing in the upper 20 40 cm of sediments under intense upwelling areas on the peru continental shelf these data demonstrate that carbonate fluorapatite cfa is precipitating from pore waters in the upper few centimeters of a gelatinous mud with high organic carbon content up to 20 c org very high porosity 0 96 ml cm 3 and very low dry bulk density 3 dissolved phosphate concentrations at the sediment water interface range from 20 to 100 m orders of magnitude higher than bottom water concentrations and much higher than predicted from regeneration of organic matter the mechanism of this interfacial phosphate release is unclear but is apparently uncoupled from carbon and nitrogen metabolism and thus may be linked either to dissolution of fish debris or to the presence of a microbial mat in surficial sediments fluoride is incorporated into cfa by diffusion from the overlying seawater and carbonate ions are provided from pore water alkalinity magnesium concentrations in this reaction zone are not significantly different from those of seawater suggesting that magnesium depletion is not a necessary prerequisite for cfa precipitation the environment of precipitation is interface linked rather than driven by organic diagenesis of phosphorus deeper in the sediment most of the cores display a wide range of diagenetic characteristics below the immediate interfacial region but almost all show the precipitation signature near the interface this interface linked early diagenetic porewater environment for the precipitation of cfa explains many of the geochemical characteristics of phosphorites and provides a testable model to compare the modern phosphogenic analog with ancient phosphorite deposits two of the cores display very high solid phase phosphorus and fluoride contents reflecting the presence of apparently modern pelletal apatites