identification of inherited radiogenic pb in monazite and its implications for u pb systematics the simplest interpretation of uranium lead mineral ages in igneous rocks embodies the assumption that melting of pre existing rocks leads to homogenization of the lead isotopes thus resetting the radiometric clock zircons often violate this assumption by only partially dissolving and preserving a component of lead inherited from before the melting episode but until now such behaviour has not been observed in monazite here we report u pb data for zircons and monazites from a tertiary granite from the himalayas in which zircons and monazites contain inherited radio genic lead an analysis of a single entirely igneous zircon crystal plots on concordia at 19 5 0 4 myr eight monazite fractions lie on a line from an upper intercept of 471 10 myr to the youngest fraction which plots slightly above concordia at 21 myr the presence of excess 206pb in the youngest monazite fractions indi cates that the monazite data represent a mixing line between young magmatic monazite and an older inherited component rather than a resetting of 471 myr monazites at 20 myr these data suggest a closure temperature for pb in monazite significantly higher than previously published estimates

u pb dating of monazite and its application to geological problems monazite is an underutilized mineral in u pb geochronological studies of crustal rocks it occurs as an accessory mineral in a wide variety of rocks including granite pegmatite felsic volcanic a

depletion of light rare earth elements in felsic magmas contrary to simple generalizations about their behavior light rare earth elements lree do not act as incompatible elements in very felsic magmas in fact lree concentrations typically decrease often drastically during differentiation of such magmas the simplest explanation for this depletion involves the separation of minute easily overlooked quantities of an extremely lree rich accessory mineral either monazite or allanite our data indicate that felsic liquids with 50 ppm lree may be saturated in either of these accessories and that the concentration required for saturation decreases in increasingly felsic liquids this accounts for incompatible behavior of lree even at high concentrations in mafic magmas in contrast to compatible behavior at low concentrations in felsic magmas partitioning of lree into solid rather than liquid has important implications for trace element and nd isotope modeling of crustal anatexis as well as for magma differentiation

trace element modelling of pelite derived granites the presence or absence of a vapour phase during incongruent melt reactions of muscovite and biotite together with the composition of the protolith determines the trace element characteristics of the resulting melt provided that equilibrium melting occurs for those phases that host the tracc elements of interest for granitic melts rb sr and ba provide critical constraints on the conditions that prevailed during melting whereas ree are primarily controlled by accessory phase behaviour mass balance constraints for eutectic granites that are formed by the incongruent melting of muscovite in pelites indicate that melting in the presence of a vapour phase will result in a large melt fraction and deplete the restite in feldspar hence the melt will be characterized by low rb sr and high sr ba ratios in contrast vapour absent melting will result in a smaller melt fraction and an increase in the restitic feldspar consequently high rb sr and low sr ba ratios are predicted vapour absent melting will also enhance the negative eu anomaly in the melt granites that result from the incongruent melting of biotite in the source will be characterized by higher rb concentrations than those that result from the incongruent melting of muscovite the himalayan leucogranites provide an example of unfractionated crustally derived eutectic melts that are enriched in rb but depleted in sr and ba relative to their metasedimentary protoliths these compositions may be generated by the incongruent melting of muscovite as a low melt fraction f 0 1 from a pelitic source under vapour absent conditions

chemical characteristics of migmatites accessory phase distribution and evidence for fast melt segregation rates equilibration between melt and solid is inhibited by rapid melt extraction and by restricted equilibration armouring slow dissolution when segregation occurs by channelised migration along high porosity pathways melt migration is more rapid than trace element diffusion rates in silicates and faster than accessory phase dissolution rates evidence for channelised flow and deformation enhanced melt segregation into boudin necks fractures and micro shears at low melt fractions is present in the moine kirtomy migmatitie suite kms in sutherland scotland melt migration distances are on a metre to tens of metres scale concordant leucosomes in stromatic migmatities in the kms have low zr contents low lree light rare earth element and h heavy ree contents and positive eu anomalies ree patterns of this type can be produced by removal of leucosome before complete equilibration with source due to the inhibited dissolution of lree and hree bearing accessory phases in water undersaturated melts melting in the kms however occurred at or near the wet granite solidus leaving biotite as a residual phase detailed back scattered electron imaging shows that ree bearing accessory phases remained as residual phases and were concentrated in the melanosome and at the melanosome leucosome boundary irregularly shaped patches of diatexite contain a small proportion of excess zr consistent with entrainment of melanosome schlieren enriched in zircon these data indicate that deformation enhanced melt extraction led to the rapid migration of small melt fractions from the melting site on a time scale less than that required to saturate the melt in zr leucosomes were thus prevented from equilibrating with accessory phases before extraction

polyphase metamorphism and the development of the main central thrust along a cross section through the lesser and higher himalayan units at the kishtwar window area north west india a polyphase barrovian type metamorphism has been delineated in relation to the development of the main central thrust mct in the metapelitic mineral assemblages three metamorphic phases have been distinguished a conditions up to amphibolite grade at moderate to high pressures alm rut ilm kya qtz characterize the m1 phase b pressure release and or temperature increase as a result of movement along the mct and the formation of gneiss domes in the higher himalaya as expressed by oriented n70 100 e fibrolite defines the m2 phase and c finally during uplift of the kishtwar window area a retrogressive m3 phase is characterized by the assemblage quartz muscovite chlorite both optically zoned and single stage garnets have been examined with the electron microprobe to determine their element partitioning normal zoning has been found in samples below the mct in the lesser himalaya indicating prograde growth during the m2 phase whereas tectonically above in the higher himalaya unit the garnets reveal double stage growth with a complex zoning pattern due to reaction partitioning during m1 and m2 and reverse zoning at their rims during the retrogressive m3 phase geothermometry on metapelites along a cross section through the mct zone and the higher himalaya imply distinct readjustments of garnet biotite exchange equilibria and indicate isothermal conditions 500 600 c throughout the section during the m3 retrogression pressure calculations gro an kya qtz and alm rut ilm kya qtz suggest a decrease in pressure towards the top of the section 6 7 5 to 4 5 5 kbar as corroborated by fibrolite replacing kyanite the spatially inverse metamorphism exposed within the lesser himalaya of the kishtwar window is regarded as a product of polyphase metamorphism combined with ongoing thrusting and shearing and is reflected by condensed m2 isograds around the kishtwar window

badrinath gangotri plutons garhwal india petrological and geochemical evidence for fractionation processes in a high himalayan leucogranite the gangotri leucogranite is the western end of the badrinath granite one of the largest bodies of the high himalayan leucogranite belt hhl it is a typical fine grained tourmaline muscovite biotite leucogranite the petrography shows a lack of restitic phases the inferred crystallization sequence is characterized by the early appearance of plagioclase quartz and biotite and by the late crystallization of the k feldspar this suggests that in spite of being of near minimum melt composition the granite probably had long crystallization or melting interval in agreement with previous experimental studies tourmaline and muscovite have a mainly magmatic origin even though the major element composition is homogeneous there are several geochemical trends when cao decreases there is an increase in na2o rb sn u b f and a decrease in k2o fe2o3 tio2 sr ba zr ree th which are best explained by a fractionation process with early crystallizing phases experimental solubility models for zircon and monazite in felsic melt support a magmatic origin for these two accessory phases as well rb sr isotope data show this granite to have like other hhl heterogeneous isotopic values for sr initial 87sr 86sr ratios calculated at 20 ma range between 0 765 and 0 785 therefore no mixing i e no convection occurred between the different batches of magma in contrast 18o data show little variation 13 04 0 25 implying a source with homogeneous 18o values differences in timing between fluid infiltration and the onset of melting related to differences in temperature of the source could explain why source homogenization occurred for the gangotri and not for the manaslu granite the use of experimental results for solubility and the position of the accessory minerals during melting predict a low viscosity for the melt during its extraction this in turn explains the lack of restitic phases major and accessory in the granite as well as some field features lensoid shape pronounced magmatic layering based on the petrographic and isotopic studies it is suggested that the mechanism of ascent was not diapiric but rather that the melt ascended along several fractures and the level of emplacement was partialy controlled by the density contrast between the melt and host rocks

pb isotopic composition colour and microstructure of monazites from a polymetamorphic rock in antarctica a moderate to high grade regionally metamorphosed paragneiss from antarctica contains monazites of several different colours brown yellow and grey each colour type has a distinctive u pb isotopic composition which appears to result from different proportions of radiogenic pb loss isotopic differences are neither related to la nd ce p ca ti and or ba nor to u or th content all colour types have similar structures at the submicron scale as determined by both conventional and high resolution transmission electron microscopy tem these show that the grains are essenttially non metamict but are composed of 100 a crystalline domains misoriented from each other by no more than 2 10 3 radians and separated by narrow confused boundary regions where misorientation is probably accommodated by imperfect atomic arrangements these regions of mismatch form potential zones of high permeability diffusivity which are believed to be fundamental to the isotopic and colour differences between grains colour type is apparently related to the capacity of different minerals to shield included monazite grains from fluids circulating in the rock system

granitic magmas with i type affinities from mainly metasedimentary sources the harcourt batholith of southeastern australia the high k calcalkaline granitic rocks of the 370 ma post orogenic harcourt batholith in southeastern australia have i type affinities but are mildly peraluminous and have remarkably radiogenic isotope characteristics with 87sr 86srt in the range 0 70807 to 0 714121 and endt in the range 5 6 to 4 3 this batholith appears to be a good example of magmas that were derived through partial melting of distinctly heterogeneous source rocks that vary from intermediate meta igneous to mildly aluminous metasedimentary rocks with the balance between the two rock types on the metasedimentary side such transitional s i type magmas formed from mainly metasedimentary source rocks may be more common than is generally realised the harcourt batholith also contains mainly granodioritic igneous microgranular enclaves imes like their host rocks the imes are peraluminous and have rather radiogenic isotope signatures 87sr 86srt of 0 71257 0 71435 and endt of 7 3 to 4 3 though some are hornblende bearing origins of these imes by mixing a putative mantle end member with the host granitic magma can be excluded because of the variability in whole rock isotope ratios and for the same reason the ime magmas cannot represent quench cumulates autoliths from the host magmas less abundant monzonitic to monzosyenitic imes cannot represent accumulations of magmatic biotite and or alkali feldspar because k feldspar is absent and there is no co enrichment of k2o and feo mgo nor can they be mixtures of anything plausible with the host rock magma the granodioritic imes probably originated through high degrees of assimilation of a range of crustal materials partial melts by basaltic magmas in the deep crust and the monzonitic imes as melts of enriched subcontinental mantle such enclave suites provide little or no information on the chemical evolution of their host granitic rocks

melting of continental crust during subduction initiation a case study from the chaidanuo peraluminous granite in the north qilian suture zone the chaidanuo granite batholith is a similar to 500 km 2 homogeneous high level intrusion in the north qilian oceanic suture zone three types of enclaves have been recognized including 1 supracrustal xenoliths 2 biotite gneiss that represents restite of the upper crustal melting and 3 coeval mantle derived mafic magmatic enclave mme the batholith consists dominantly of peraluminous biotite monzogranite with sio2 69 73 wt and a cnk 1 05 1 28 and shows geochemical affinity with the upper continental crust e g enrichment of large ion lithophile elements liles k rb u th pb depletion of high field strength elements hfses nb ta ti p eu and sr and enriched sr sr 87 sr 86 i 0 731 to 0 744 nd epsilon nd t 6 0 to 7 1 isotopes zircon u pb dating indicates that this batholith formed at 516 505 ma coeval with the mmes 510 ma which represent the early stage of seafloor subduction in the north qilian suture zone the hf isotopic composition of the mme epsilon hf t 6 0 to 2 1 is more depleted than that of the host granite epsilon hf t 14 8 to 4 7 suggesting mixing of mantle and crust derived melts the inherited zircon cores in the host granite yield an age peak at similar to 750 ma with a few detritals of 591 1683 ma zircons from a biotite gneiss enclave yield a protolith age of 744 ma and a metamorphic melting event at 503 ma sr nd isotopic modeling reveals that the batholith was generated by melting of neoproterozoic granitic rocks with the addition of 10 18 mantle derived magma therefore peraluminous granite can be produced by melting of crustal materials heated by mantle derived magmas during the early stage of subduction initiation at the site of a prior passive continental margin c 2014 elsevier ltd all rights reserved

bimodal back arc alkaline magmatism after ridge subduction pliocene felsic rocks from central patagonia 47 s abstract volumetrically minor microsyenites alkali microgranite and related trachytic dykes intrude early pliocene oib like alkali basaltic and basanitic flows of the meseta del lago buenos aires in central patagonia 47 s 71 30 w and occur together with scarce trachytic lava flows whole rock k ar ages between 3 98 and 3 08 ma indicate that the emplacement of these felsic rocks occurred more or less synchronously with that of the post plateau basaltic sequence that they intrude during a bimodal mafic felsic magmatic episode devoid of intermediate compositions chemically these rocks have a1 type granitoid affinities and are characterized by high silica and alkali contents 60 68 wt sio2 8 7 10 8 wt na2o k2o major and trace elements patterns evidencing evolution by low pressure fractional crystallization and sr and nd isotopic signatures similar to those of coeval basalts 87sr 86sr o 0 70488 0 70571 143nd 144nd o 0 512603 0 512645 nevertheless some of them have the most radiogenic sr values ever reported for a magmatic rock in the meseta and even in the whole neogene patagonian plateau lavas province 87sr 86sr o 0 70556 0 70571 143nd 144nd o 0 512603 0 512608 in addition very high contents of strongly incompatible elements in the most evolved rocks together with sr isotopic ratios higher than those of coeval basalts suggest the occurrence of open system magmatic processes continuous fractional crystallization from a primitive basaltic source similar to post plateau coeval basalts towards alkali granites combined with small rates of assimilation of host jurassic tuffs afc in a shallow magmatic reservoir best explains the geochemical and petrographic features of the felsic rocks therefore a1 type magmatic rocks can be generated by open system crystallization of deep asthenospheric melts in back arc tectonic settings in central patagonia these 3 4 ma old alkaline intrusions occur aligned along a n160 170 trending lineament the zeballos fault zone stacking the morphotectonic front of one segment of the patagonian cordillera intrusion along this fault zone occurred during the onset of a new transtensional or extensional event in the area related to major regional tectonics occurring in possible relation with the collision of one segment of the chile spreading ridge with the trench

phosphorus and the rare earth elements in felsic magmas an assessment of the role of apatite abstract the solubility of fluorapatite in 17 silica rich melts in the system na 2 o k 2 o al 2 o 3 sio 2 with and without cao or caf 2 was determined at 1 kbar water pressure and 750 900 c apatite saturation occurs at levels of dissolved p 2 o 5 ranging between 0 04 0 02 and 0 28 0 13 wt with only 4 values outside the 0 09 0 20 wt range the results demonstrate not only that apatite is a common liquidus phase in felsic melts but also that under most circumstances it remains in the residue during episodes of partial fusion of the crust given a solubility limit of 0 14 wt dissolved p 2 o 5 the mean of the experimental values a source containing as little as 0 05 p 2 o 5 must be 35 melted before apatite is lost from the residue and no longer buffers the melt p 2 o 5 concentration at the saturation value higher abundances of p 2 o 5 in the source postpone the loss of residual apatite to still higher degrees of melting and if the source p 2 o 5 content exceeds 0 14 wt apatite must be residual for all degrees of melting increasing in abundance as melting proceeds the generally secondary influence of apatite on the rare earth element ree patterns of melt and residue is most apparent when garnet and or amphibole is minor or lacking in the residue fractional crystallization of intermediate e g andesitic magmas toward felsic compositions invariably results in saturation in apatite and some consequent depletion of ree in the melt

neodymium isotope equilibration during crustal metamorphism revealed by in situ microanalysis of ree rich accessory minerals radiogenic isotopes are widely used to investigate crustal evolutionary processes however recent claims of nd and sr isotope disequilibrium during anatexis question the reliability of such information we have conducted an in situ sm nd isotope study of apatite allanite titanite xenotime and monazite in metasedimentary rocks of different metamorphic grade to test nd isotope equilibrium during metamorphism our results show that apatite retains an original probably detrital highly variable nd isotopic signature until at least 500 c before being isotopically homogenised irrespective of textural context within the rock once equilibrated apatite retains its nd isotope signature throughout anatexis in contrast allanite and titanite are equilibrated at temperatures as low as 350 400 c ree rich accessory minerals in high grade rocks 600 c show very similar initial end values at the time of metamorphism we conclude that under these metamorphic conditions nd isotope disequilibrium between crustal melts and metasedimentary sources is unlikely intra grain nd isotope zoning of monazite indicates that partial melting was open system involving the injection of externally derived melt into migmatites this process likely to be common in anatectic terranes but not always obvious at hand specimen scale or from bulk rock geochemical data can produce isotope variation that could potentially be misinterpreted as disequilibrium between the melt and its protolith

combined high precision chronometry and geochemical tracing using accessory minerals applied to the central alpine bergell intrusion central europe abstract the behaviour of nd u th and pb isotopes in granitic rocks is usually controlled by accessory minerals in this study an approach is adopted which uses the initial 143 nd 144 nd as a geochemical tracer together with high precision u th pb geochronology for accessory phases and their respective whole rock this combination of techniques is applied to zircon allanite sphene apatite and thorite from both a tonalite and a granodiorite from the tertiary alpine bergell intrusion inherited isotopic signatures have been identified in bulk zircon fractions by inverse discordance in the u pb system in the case of the granodiorite the initial nd in the zircon is 1 77 units lower than the bulk rock this result indicates that nd isotopes in zircon may serve as a useful tool for tracing crustal precursors in silicic rocks all other accessories yield an initial nd equal to their respective whole rock and u th pb ages equal to or lower than the respective intrusion ages this indicates either the absence of inherited cores or that such cores have exchanged their nd and pb in the case of apatite also sr by diffusion where available experimental mineral melt equilibria and diffusion models are consistent with this behaviour u pb geochronology of carefully selected core free zircons yields a precise intrusion age of 31 88 0 09 ma for the tonalite in contrast granodioritic zircons are partially reset due to radiation damage caused by high u concentrations however an alternative means of dating young intrusions is to use 232th 208pb ages of allanite in the case of allanite the presence of a large excess of 206pb derived from 230th indicates that no total pb loss has occurred since crystallization and the nd isotopes indicate the absence of inheritance using both the allanite age and a 238u 206pb age for sphene an intrusion age of 30 13 0 17 ma is indicated for the granodiorite taken together with an allanite th pb age for the tonalite these results strongly support the high closure temperatures for the allanites studied here 700 800 c at high post magmatic cooling rates all other accessory mineral ages are reset to values similar to hornblende 39ar 40ar ages and reflect the effect of post magmatic cooling superimposed on post metamorphic cooling

age of crustal melting and leucogranite formation from u pb zircon and monazite dating in the western himalaya zanskar india new u pb data from leucogranites in the high himalayan slab in the western himalaya of zanskar reveal that crustal melting occurred at 21 19 5 ma and that anatexis occurred along the himalaya at least from kashmir zanskar to eastern nepal at approx 24 19 5 ma high u monazites from leucogranitic melt pods in migmatites within the 35 km wide sillimanite k feldspar zone at the deepest structural levels exposed umasi la have u pb ages of 20 6 19 5 ma higher level migmatitic melt pods from shafat in the suru valley also contain magmatic monazites with u pb ages of 20 8 0 3 ma zircons from the leucogranites contain an approx 460 ma inherited component as do some umasi la monazites showing that the protoliths were at least ordovician in age

isotopic disequilibrium during melting of granite and implications for crustal contamination of magmas the assumption that the isotopic ratios of anatectic melts generated in response to crust magma interaction are equivalent to the bulk source rock from which they are derived was tested experimentally via dehydration melting of a proterozoic biotite granite heating of the coarse grained granite at 1250 c for durations of 1 to 48 h produced extreme disequilibrium among simultaneously generated mafic and felsic melts quenched to glass and whole rock 87sr 86sr ratios in situ microdrill sr isotopic analyses across gradational contacts between mafic high 87sr 86sr and felsic low 87sr 86sr glass register significant isotopic and chemical heterogeneity on the submillimetre scale our experiments suggest that during the early stages of wall rock melting when the rate of heating may exceed melting rates isotopic equilibrium may not be maintained thus producing contaminant liquids having isotopic compositions different from the bulk source rock if isotopic equilibrium is not attained during partial melting in the crust current geochemical models of open system magmatic processes may require modification

thermal constraints on the emplacement rate of a large intrusive complex the manaslu leucogranite nepal himalaya the emplacement of the manaslu leucogranite body nepal himalaya has been modelled as the accretion of successive sills the leucogranite is characterized by isotopic heterogeneities suggesting limited magma convection and by a thin 100 m upper thermal aureole these characteristics were used to constrain the maximum magma emplacement rate models were tested with sills injected regularly over the whole duration of emplacement and with two emplacement sequences separated by a repose period additionally the hypothesis of a tectonic top contact with unroofing limiting heat transfer during magma emplacement was evaluated in this latter case the upper limit for the emplacement rate was estimated at 3 4 mm year or 1 5 myr for 5 km of granite geological and thermobarometric data however argue against a major role of fault activity in magma cooling during the leucogranite emplacement the best model in agreement with available geochronological data suggests an emplacement rate of 1 mm year for a relatively shallow level of emplacement granite top at 10 km uninterrupted by a long repose period the thermal aureole temperature and thickness and the isotopic heterogeneities within the leucogranite can be explained by the accretion of 20 60 m thick sills intruded every 20 000 60 000 years over a period of 5 myr under such conditions the thermal effects of granite intrusion on the underlying rocks appear limited and cannot be invoked as a cause for the formation of migmatites

the timescale and mechanism of granulite formation at kurunegala sri lanka incipient charnockite formation at kurunegala in sri lanka is characterized by the growth of orthopyroxene at the expense of amphibole and biotite in an originally homogeneous gneiss mineral equilibria in the charnockite assemblage record pressure temperature p t conditions of 738 60 c and 6 9 1 2 kbar at 17 0 1 2 log fo2 and ah2o 0 18 0 16 wholerock trace element and isotopic measurements show that charnockite formation was accompanied by a systematic depletion of sm rb pb u sr nd with a fractionation of rb sr sm nd and th u ratios and crystallization of the charnockite assemblage at 535 5 ma major element fe mg ca and sm nd equilibration between minerals occurred at 524 9 ma whereas pb and rb sr underwent continued exchange to 501 5 ma and 486 1 ma respectively trace element data for both amphibolite and charnockite minerals show that depletion on a whole rock scale can be accounted for either by changes in mineral modes or trace element abundances within the immediate area of dehydration the fractionation of sm nd on a whole rock scale is controlled by the breakdown of amphibole without the growth of a major new host phase for sm in the charnockite rubidium and sr are dependent on the relative behaviour of biotite plagioclase and alkali feldspar modelling of dehydration melting involving the breakdown of amphibole biotite and alkali feldspar reproduces the observed sm nd and rb sr fractionation and indicates the loss of small melt fractions on a cm scale from the charnockite these observations suggest that partial melting is the most plausible means of effecting both the dehydration and depletion that accompanies charnockite formation

mineral leucosome trace element partitioning in a peraluminous migmatite a laser ablation icp ms study abstract low pressure peraluminous migmatites from the pena negra complex central spain stayed partially molten for 5 10 ma until the latest hercynian deformations allowed the segregation of melt as discordant leucosome veins due to long residence within its source the melt had time enough to equilibrate with residual phases other than accessories included within major refractory minerals we estimated crystal melt partition coefficients as the concentration ratios between leucosome samples appearing to be pure melts and mesosome minerals which were analyzed for trace elements with a laser probe coupled to an icp mass spectrometer our data reveal that when biotite is stable li rb cs tl sc v cr ni nb and ta become strongly compatible the role of biotite in fractionating y th u and the ree is insignificant cordierite strongly fractionates li and be and also has some effect on the hree and u garnet produces extreme fractionation of sc y and the hree the ree partition coefficients for ferromagnesian silicates increase with the atomic number this effect being progressively more important through biotite cordierite and garnet k feldspar strongly fractionates ba and pb but plays a secondary role to biotite for rb and cs k feldspar fractionation does not change the lree hree ratio but plagioclase fractionation produces a significant decrease in the lree hree ratio both feldspars greatly fractionate sr and eu monazite fractionation produces a dramatic depletion in ree th and u as well as a decrease in the lree hree and th u ratios apatite also fractionates the ree although in contrast with monazite it increases the lree hree ratio and does not affect the th u ratio zircon fractionation like apatite and garnet produces a strong depletion in the hree and a concomitant increase in the lree hree ratio in contrast with monazite zircon fractionation causes the th u ratio to increase

a model for monazite melt equilibrium and application to the generation of granitic magmas abstract in order to model the behaviour of zr hf ti p u th y and the rare earth elements ree in the continental crust the parameters which control the equilibria between accessory minerals and granitic melts must be determined this paper proposes equations for the equilibrium between monazite and ca poor felsic melts in a first step all the light ree are considered as a single component and an equation describing monazite solubility is deduced from the available experimental data in a second step the fractionation of ree by monazite is investigated on the basis of a natural example of coexisting monazite and obsidian from macusani peru the solubility of monazite can be used as a thermometer based on the total ree content of natural magmatic rocks application of ree thermometry to various peraluminous rock series suggests that it is a reliable tool for determining temperatures of magmatic processes the equation governing ree fractionation by monazite is used to discuss genetic relationships between a melt and a presumed parental rock using the composition of the monazite in the parental rocks and the ree pattern of the daughter rock this method has been applied successfully to high himalayan manaslu and tibetan slab granites it is suggested that detailed petrographical work on monazite including electron microprobe analyses and sem imaging of its internal structures combined with the model presented here can be a useful tool for deciphering the genesis and the differentiation of peraluminous granitic magmas in the continental crust

zanskar shear zone northeast southwest extension within the higher himalayas ladakh india a complete geologic section through the northwestern himalayas is well exposed in ladakh india the collision between the indian shield and the tibetan platform caused large scale intracrustal thrusting and piling up of the himalayan nappes this compressional event was accompanied by prograde regional metamorphism the metamorphism ranges from low grade anchimetamorphism in the indus suture zone in the northeast to upper amphibolite grade in the higher himalaya tectonic unit in the southwest in the zanskar area a well exposed and morphologically prominent shear zone 2 25 to 6 75 km wide can be followed from the northwest to the southeast for at least 80 km in contrast to the main compressional tectonics this shear zone indicates an extensional event within the higher himalaya tectonic unit the zanskar shear zone involves granitic rocks leucogranites of miocene age and various metasediments and in general separates the late precambrian early cambrian sedimentary sequence phe formation from the underlying crystalline basement zanskar crystalline unit a normal sense of shear has been determined by using asymmetric macroscopic and microscopic structures such as pegmatite boudins feldspar augen and crystallographic fabrics the metamorphic isograds are very close within this shear zone as a result of shear deformation a gradual transition from upper amphibolite to lower greenschist facies occurs within 200 m movement in this zone occurred late in the metamorphic history under greenschist or lower metamorphic conditions the minimum horizontal extension and vertical displacement are on the order of 16 and 19 km respectively

isotopic constraints on the age and provenance of the lesser and greater himalayan sequences nepalese himalaya the main central thrust of the central himalaya juxtaposes the lesser himalayan sequence footwall with the greater himalayan sequence hanging wall both of which are regarded as components of the northern passive margin of india considerable uncertainty surrounds their respective ages and sedimentary derivation u pb and sm nd isotopic studies of samples from the langtang area central nepal demonstrate important distinctions between the two rock packages the greater himalayan sequence had a sedimentary provenance that included a major source of 0 8 1 0 ga zircons implying a late proterozoic age the source of the precambrian part of the lesser himalayan sequence contained 1 87 2 60 ga zircons and its depositional age is probably middle proterozoic nd isotopic characteristics of the two sequences are different at 21 ma the greater himalayan rocks had end values between 14 6 and 18 5 while their lesser himalayan counterparts had values between 21 4 and 25 9 giving rise to major differences in their model ages the lesser and greater himalayan sequences at langtang are interpreted as correlative to the lower and upper parts of the vindhyan supergroup currently exposed south of the gangetic plain in northern india on the basis of available age data the exposed hanging wall of the main central thrust in central and eastern nepal contains no archean early proterozoic basement if the fault does root into the basement at depth it must do so farther north than recently published cross sections indicate this implies a total displacement on the fault that is substantially greater than the 140 210 km required by tectonic overlap in the eastern himalayas

accessory mineral behavior during differentiation of a granite suite monazite xenotime and zircon in the sweetwater wash pluton southeastern california u s a abstract compositional and textural characteristics of the accessory minerals monazite xenotime and zircon in the sweetwater wash granites and related aplites indicate that these phases not only controlled much of the trace element geochemistry of the suite but that they also record the melt compositional changes that occurred during magmatic differentiation fractionation of monazite due to decreasing saturation levels of its essential structural constituents with falling temperature was likely responsible for an ongoing trend of light rare earth element ree depletion this was accompanied by increasing heavy ree concentrations until xenotime joined the crystallizing assemblage subsequently combined monazite xenotime fractionation resulted in lowering of the entire ree budget zircon which contains inherited cores that were apparently resorbed and rounded during initial anatexis was saturated throughout the differentiation history of the sweetwater wash suite accessory phases in granite and aplite exhibit strong compositional differences at a variety of scales the differences are best displayed by monazite on average crystals in more differentiated rocks aplites are relatively depleted in light ree s and contain higher concentrations of the substituting elements u and th zircon displays complimentary increases in hf and y while xenotime shows a slight increase in th and in gd ho ratios both phases also exhibit higher u concentrations in aplites than in granites these differences in accessory mineral compositions are observed not only between granites and the more differentiated aplites but also within individual thin sections due to in situ fractionation on an even smaller scale strong compositional variations are present within single crystals possibly due to diffusion controlled melt compositional gradients in the regions a adjacent to growing major phases and b adjacent to the growing accessory crystal itself our observations indicate that compositional variations among accessory minerals are potentially useful for tracking of magmatic processes but that the scale of observed variations must be carefully considered

crystallization of apatite in natural magmas under high pressure hydrous conditions with particular reference to orogenic rock series two separate series of hydrous experiments involving 1 imposing apatite saturation on a series of igneous rock compositions from basanite to rhyolite and 2 crystallizing similar natural rock compositions progressively until apatite appears demonstrate a close dependence between apatite saturation and silica content of the magma and determine p2o5 levels at a given silica value and temperature at which that composition may be expected to crystallize apatite the effect of pressure on apatite solubility is not great and is most significant for silicic compositions

detection of inherited monazite in the manaslu leucogranite by 208pb232th ion microprobe dating crystallization age and tectonic implications abstract although leucogranites are among the least petrologically variable of all igneous rocks ironically they are among the most difficult to reliably date the high himalayan leucogranites have been the subject of numerous geochronological investigations because of their interrelationship with the most significant tectonic features of that mountain belt for a variety of reasons linked to the minimum melt composition of these leucogranites these dating studies have not been entirely successful we report results of a new ion microprobe dating method based on the decay of 232 th to 208 pb in monazite that has directly revealed the presence of inherited pb in monazite from the manalsu granite casting doubt on its previously accepted age monazite ages obtained from this leucogranite yield two distinct populations a large number of ages with a normal distribution and mean age of 22 4 0 5 ma 2 s e that we interpret to be the crystallization age and a smaller inherited fraction with an age of ca 600 ma because formation of the granite is thought to be related to slip on the main central thrust both this date and a second less precise result from a structurally similar pluton near mt everest indicate that the main central thrust was active in the interval 24 22 ma but do not constrain its initiation together with crosscutting relationships these data require that movement on the north himalayan fault occurred prior to 22 ma at both locations

geochemical constraints on the bimodal origin of high himalayan leucogranites major and trace element and rb sr isotope systematics of the manaslu leucogranite central nepal have been examined to constrain the role of mineral fractionation and fluids in peraluminous granite petrogenesis biotite and tourmaline are for the most part mutually exclusive with a predominance of two mica leucogranites over tourmaline leucogranites the 87sr86sr initial isotopic ratios sri indicate that leucogranitic melts were derived from two different sources the two mica leucogranites having a metagreywacke origin with sri 0 752 nd 15 such a bimodal nature of the source zone does not directly influence the magmatic evolution except that probably the higher initial boron content in the metapelitic rocks may increase the na2ok2o ratio in contrast the amount of water present during melting principally controls in part anatectic processes and element behaviour water saturated conditions probably occured during melting of metagreywackeous rocks and favoured crystallization of two mica leucogranites whereas water absent conditions prevailed during melting of metapelitic layers and favoured biotite plagioclase and monazite fractionation in the source zone and tourmaline crystallization in the leucogranite

accessory phase controls on the geochemistry of crustal melts and restites produced during water undersaturated partial melting the profound geochemical conseqences of accessory phase behaviour during partial melting of highgrade metapelites are demonstrated with reference to two geochemically distinct crustal melts produced by biotite dehydration melting reactions under granulite facies kbar 860 cc conditions these two leucogneiss suites from the brattstrand bluffs coastline eastern antarctica have similar field relations transport distances 10 100 s of metres and major element chemistry type 1 leucogneisses have low zr th and lree positive eu anomalies and zr zr and lreet lreet values less than 1 0 i e less than required to saturate the melt mass balance constraints suggest that these melts have been extracted before equilibration with host melanosomes the dry peraluminous nature of vapour undersaturated melts inhibits monazite and zircon solubility and results in concentration of these phases in the residue melts are consequently depleted in lree and hree melanosomes show complementary enrichment in lree while hree patterns are dominated by residual garnet type 2 leucogneisses in contrast have strongly enriched zr th and lree abundances negative eu anomalies and zr zr and lreet lreet 1 resulting from accessory phase entrainment vapour absent partial melting under moderate 6 8 kbar pressure granulite facies conditions of a pelitic source containing monazite is likely to give disequilibrium melts depleted in lree and hree as monazite and garnet are concentrated in the residue if temperatures are high enough 850 870 c to permit relatively large degrees of partial melting then the feldspar component of the source will be removed almost completely giving melts with large positive eu anomalies melts formed under vapour present conditions are unlikely to show such extreme lree and hree depletion or positive eu anomalies even at high degrees of partial melting disequilibrium melting coupled with source entrainment could fortuitously produce ree and trace element signatures similar to those typical of s type granites and usually ascribed to equilibrium melting conditions

a comparative study of diffusion profiles in himalayan and dalradian garnets constraints on diffusion data and the relative duration of the metamorphic events cation diffusion rates at 690 30 c have been calculated by inverse modelling of observed manganese mn zonation profiles in 40 garnets from two kyanite bearing metapelite samples from the high himalayan crystalline series zanskar northwest india knowledge of the initial growth profile of mn in garnet is a pre requisite for this technique following previous workers we model mn partitioning into growing garnet in terms of a rayleigh fractionation process and demonstrate that the mngarnet whole rock partition coefficient is 60 100 three dimensional zonation profiles were obtained by successively grinding and polishing 1 cm slabs of each sample at 0 1 0 2 mm intervals and analysing the garnets at each stage thus ensuring that core sections were measured the diffusion model assumes that garnet has a spherical geometry and behaves as a closed system and simulates diffusive modification of the hypothetical mn rayleigh growth profile for each garnet the derived measure of the time integrated diffusion history for each garnet is then combined with radiometric and field relation constraints for the duration of the himalayan metamorphic event to calculate cation diffusion rates the average cation interdiffusion rate calculated for garnets in the two samples examined is 6 3 2 10 23 m2s 1 this interdiffusion rate pertains to a temperature of 690 30 c which is 0 97 t peak the peak temperature conditions experienced by the samples estimated using standard thermobarometric techniques garnet compositions are py2 17alm65 77gro6 16sp1 17 these new diffusion data are consistent with and more precise than existing high temperature 1000 c experimentally determined diffusion data although some uncertainties remain difficult to constrain qualitative comparison between diffusively modified mn growth profiles in garnets from the scottish dalradian and the himalayan garnets suggests that the duration of metamorphism affecting the dalradian garnets was 10 20 times longer than that endured by the himalayan garnets

the metamorphic signature of contemporaneous extension and shortening in the central himalayan orogen data from the nyalam transect southern tibet abstract geological relationships and geochronological data suggest that in miocene time the metamorphic core of the central himalayan orogen was a wedge shaped body bounded below by the n dipping main central thrust system and above the n dipping south tibetan detachment system we infer that synchronous movement on these fault systems expelled the metamorphic core southward toward the indian foreland thereby moderating the extreme topographic gradient at the southern margin of the tibetan plateau reaction textures thermobarometric data and thermodynamic modelling of pelitic schists and gneisses from the nyalam transect in southern tibet 28 n 86 e imply that gravitational collapse of the orogen produced a complex thermal structure in the metamorphic core amphibolite facies metamorphism and anatexis at temperatures of 950 k and depths of at least 30 km accompanied the early stages of displacement on the main central thrust system our findings suggest that the late metamorphic history of these rocks was characterized by high t decompression associated with roughly 15 km of unroofing by movement on the south tibetan detachment system in the middle of the metamorphic core roughly 7 8 km below the basal detachment of the south tibetan system the decompression was essentially isothermal near the base of the metamorphic core roughly 4 6 km above the main central thrust the decompression was accompanied by about 150 k of cooling we attribute the disparity between the p t paths of these two structural levels to cooling of the lower part of the metamorphic core as a consequence of continued and probably accelerated underthrusting of cooler rocks in the footwall of the main central thrust at the same time as movement on the south tibetan detachment system

apatite dissolution into peraluminous haplogranitic melts an experimental study of solubilities and mechanisms apatite ap dissolution and solubility in the peraluminous haplogranite system were investigated in three sets of experiments at 750 c and 200 mpa ph2o as functions of ap grain size abundance melt ap ratio and melt asi alumina saturation index mol al2o3 na2o k2o cao between an asi of 1 1 1 metaluminous to mildly peraluminous the solubility of ap as measured by p2o5 in the melt is low 0 1 wt p2o5 which agrees with previous work in equilibrium runs with more strongly peraluminous compositions however ap solubility increases linearly with asi to p2o5 0 63 wt in melt at asi 1 3 and can be denned by a simple equation p2o5 3 4 3 1 asi r 0 833 which agrees within error with previous calculations reported in the literature in experiments where ap grains are sparce and widely separated i e simulating ap distribution in an ap bearing peraluminous protolith undergoing anatexis the dissolution of ap involves transient disequilibrium that promotes higher solubility of p2o5 up to nearly six times the equilibrium values adjacent to ap at a given bulk asi of melt and this increases the al si of melt in the ap dissolution aureole the approach to equilibrium between ap and melt is hastened by increasing the ap melt ratio within the local melt pool e g the capsule or by decreasing ap grain size for a similar melt ap ratio diffusivity calculations using inverse error function methods for the normal diffusion of p and ca yield dp 10 11 cm2 s and dca 10 10 cm2 s confirming prior results that diffusion of p away from ap surfaces is the rate limiting factor in ap dissolution these results combined with previous work at higher temperatures but on similar hydrous melts yield an activation energy e for p diffusion of 16 5 kcal mol and a frequency factor d0 of 1 4 10 3 cm2 s phosphorus diffusion through the melt is accompanied by uphill diffusion of al resulting in an increase of up to 2 wt al2o3 in melt near the ap within the ap dissolution aureole melt contains one additional al cation for every p cation i e al p 1 1 which is suggestive of an associated alpo4 complex the exchange reaction in melt is represented by alpsi 1 in which 2 to4 clusters are created in the place of 1 this exchange should be accompanied by discernable changes in melt properties e g density molar volume viscosity the results have applications to equilibrium and local disequilibrium effects during anatexis of apbearing metapelites and to the saturation limits of ap during crystallization of peraluminous magmas the dissolution of flux bearing minerals such as ap e g those containing p b or f may influence the stability and solubility of other trace element bearing minerals during anatexis of metapelites texture e g grain size and distribution and spacial relationship to other minerals plays an important role in reaction kinetics and at least temporarily in mineral solubilities the disequilibrium behavior of accessory minerals has critical consequences for ree modelling of granites

basin analysis of the jurassic lower cretaceous southwest tarim basin northwest china the jurassic through cretaceous southwest tarim basin northwest china contains more than 6 km of fluvial and lacustrine strata deposited in a foreland setting during the successive collisions with eurasia of the changtang block during late triassic early jurassic time and with the mega lhasa block during late jurassic early cretaceous time this tectonism is chronologically linked with the creation of a narrow lower middle jurassic transtensional basin with thick sedimentary infill succeeded by a broader upper jurassic lower cretaceous compressional basin with thinner sedimentary infill the older basin formed between a north northwest striking dextral fault on the eastern side of the southwest tarim basin in the tian shan and a postulated strike slip or normal fault on the western margin of the basin along the kunlun shan the former fault is now the talas ferghana fault the latter may be a predecessor to the main pamir thrust subsidence analysis of the thickest sedimentary section suggests thermal subsidence interpreted as the result of transtension between the two basin bounding faults the younger basin extends farther east and west and does not preserve evidence of activity along the talas ferghana fault the change in basin style between these two episodes of basin development likely reflects either a small counterclockwise rotation of basin bounding structures during the first episode or a small clockwise rotation of the maximum compressive stress between the two episodes

inclusion host relations involving accessory minerals in high grade metamorphic and anatectic rocks in general accessory minerals are expected to participate in partial fusion of their host rocks to a degree determined simply by their solubilities in the melt the possibility must be recognized however that a given accessory grain may be physically isolated from the melt by inclusion within a residual major mineral because of the importance of accessory minerals to crustal rock trace element and isotope geochemistry and because of their common existence as inclusions in major phases we undertook an evaluation of the factors that affect inclusion formation during ultrametamorphism three approaches are taken 1 a review of interfacial energy considerations is used to show that the free energy of the system is lowered by location of accessory minerals at major phase grain perimeters and that the magnitude of this effect is proportional to the square of the accessory grain radius 2 annealing and partial melting experiments 1000 c 10 and 15 kbar on rock analogs are described and the results are shown to confirm the predicted tendency of accessory minerals to occupy grain boundaries and 3 the results of a study of accessory phase rutile and zircon distribution in a migmatite from the tibetan slab are reported again in confirmation of the prediction that accessories tend to be situated at majorphase grain perimeters the latter two aspects of the study reveal that although included accessory grains are common their generally small size results in only a minor contribution to the bulk rock budget of accessory mineral components most of the mass of these components is contained within populations of generally larger accessory grains located at major phase grain boundaries accordingly the assumption that accessory minerals are involved in crustal melting is generally valid

apatite solubility in peraluminous liquids experimental data and an extension of the harrison watson model abstract new experimental data at 750 1000 c 2 5 kbar and for peraluminous melt compositions show a dramatic increase of apatite solubilities and phosphorus melt contents when compared to metaluminous or peralkaline compositions harrison and watson 1984 the formation of alumino phosphate units in peraluminous melts qualitatively explains our data a new apatite solubility model incorporating the data for the peraluminous region is presented application of this model to examples of peraluminous felsic suites is discussed

the effect of accessory minerals on the redistribution of lead isotopes during crustal anatexis a model abstract the initial pb isotopic composition of anatectic granites is modelled as a mixture of pb derived from major minerals that have characteristically low 238 u 204 pb and 232 th 204 pb ratios i e feldspars biopyroboles etc with pb contributed from dissolved accessory minerals with characteristically high 238 u 204 pb and 232 th 204 pb ratios i e zircon monazite etc the initial pb isotopic composition of anatectic granites is a function of a the age type modal distribution and heterogeneity in the initial u and th content of the accessory minerals b variation in melt composition and temperature during anatexis c the fraction of the source melted and d the extent to which the melt was homogenized prior to crystallization the differential behavior of accessory minerals during anatexis can explain the common yet enigmatic decoupling of the pb isotopes from other chemical and isotopic systems in granite rocks granitic plutons derived by anatexis of the same source material are not required to have the same initial pb isotopic composition low temperature peraluminous granites are more likely to exhibit homogeneous initial pb isotopic compositions dominated by the pb contained within the major mineral assemblage of the source material in contrast the initial pb isotopic composition of higher temperature metaluminous or peralkaline anatectic granites is more likely to be heterogeneous unless the melts are homogenized during emplacement and will record a larger fraction of the radiogenic pb component contained in the accessory mineral assemblage of the source material heterogeneity in the initial pb isotopic composition of individual granites or granitic suites can preserve the weighted average age of the radiogenic pb present in the accessory mineral assemblage of the source region even if these minerals are entirely dissolved during anatexis the use of isotopic tracer studies in terrane analysis will be optimized by the isotopic characterization of granitic suites

geochemical and isotopic disequilibrium in crustal melting an insight from the anatectic granitoids from toledo spain in the hercynian anatectic complex of toledo act the anatectic granitoids include leucogranitic leucosomes leucogranitic massifs and restite rich granites they show a broad range of initial sr and nd isotope ratios from 0 711 to 0 720 and 0 51164 to 0 51203 respectively which clearly indicate the absence of isotopic homogenization in the melts broadly the ranges reflect the isotopic variation of the metapelitic protoliths if crustal melting occurs under water undersaturated conditions as is the case of the act the generated melts do not isotopically and chemically equilibrate with the granulitic residuum the preservation of heterogeneities could arise through a number of processes 1 duration of the process in which the presence of melts with disequilibrium features and the high solid content of several of the granites in the act point to a very short lived magmatic system 2 limited diffusion in which poorly segregated and volatile undersaturated granitoids have a very restricted opportunity for isotopic and chemical homogenization and 3 magma dynamics in which the low melting rates the high restite and low water contents and the silica rich composition of these granites together with the small volume and high viscosity values of the melts seriously restrict the physical processes leading to homogenization

the contact between the higher himalaya crystallines and the tibetan sedimentary series miocene large scale dextral shearing space and time evolution of the synmetamorphic structures across the metamorphic pile have been studied in several areas along the himalayan belt east and central nepal garhwal zanskar from one area to the other the evolution is very similar 1 at the base of the pile in the main central thrust mct shear zone the stretching lineation penetrative and regularly oriented n0 e to n30 e indicates the mct transport direction very constant all along the belt from the eohimalayan main metamorphic development up to the late metamorphic movements 2 at the top of the pile at the contact between the crystalline unit and its sedimentary cover gravity driven structures are confirmed north vergent folds ductile normal faulting however there are numerous local indications of late miocene syn to late emplacement of the leucogranitic plutons dextral shearing 3 in between across the medium part of the pile the stretching lineation shows a conspicuous progressive regional clockwise rotation clearly indicated by the strain trajectories mapped in nepal and garhwal points 1 and 2 show that the crystalline sedimentary boundary despite its apparent structural and metamorphic continuity is not only a normal fault but also an important dextral shear zone which has acted since the upper miocene as the main southern limit of the eastward extruding tibetan block

geochemistry of granitic melts produced during the incongruent melting of muscovite implications for the extraction of himalayan leucogranite magmas granites formed from the incongruent melting of muscovite preserve evidence of chemical disequilibrium both between restite and melt and within individual phases during crystallization miocene leucogranites from the himalayas exemplify melt formation from a pelitic source through muscovite breakdown trace elements rb sr and ba reside almost entirely in micas and feldspars in the protolith and therefore are appropriate for quantitative modeling equilibrium between melt and restite was established for sr under fluid phase absent conditions but some disequilibrium is suggested by rb abundances consistent with known diffusion rates for these elements abundances of zr and ce in the granites which provide essential structural constituents of the accessory phases zircon and monazite indicate that the himalayan granite melts were saturated in these elements if formed at temperatures of 670 700 c but slightly undersaturated if formed at somewhat higher temperatures ion microprobe traverses of y and heavy rare earth element abundances across single garnets from himalayan leucogranites provide evidence for disequilibrium between melt and phenocryst during garnet growth thus constraining the evolution of magmatic compositions during melt formation and crystallization in some cases progressive melting of the protolith and crystallization of garnet from the melt appear to have been concomitant indicating that minimum solidus temperatures were maintained throughout the melting event this suggests that thermal buffering rather than melt extraction provided the rate determining step in magma evolution

garnet tourmaline and muscovite bearing leucogranites gneisses and migmatites of the higher himalayas from zanskar kulu lahoul and kashmir

old model nd ages in namibian pan african rocks the nd isotope analytical technique is a powerful tool for studying many geological processes particularly the evolution of the upper mantle as seen through the isotope and trace element geochemistry of mantle derived volcanic rocks1 3 and magmatic processes along destructive plate margins4 5 however previous studies of continental crust6 8 have been largely restricted to archaean examples and concerned primarily with dating their time of derivation from the upper mantle in the present study we investigated the nd and sr isotope characteristics of rocks involved in a relatively young 800 450 myr orogenic event such events represent critical stages in the evolution of most of the earth s continental crust new material is added from the mantle and pre existing crust is remobilized by erosion and sedimentation deformation and magmatic activity nd and sr isotopes were used to outline the range in age and geochemical characteristics of rock sequences and provinces within both the upper mantle and the pre existing crust which were sampled during the orogeny and hence provided the major components of what is now a stable segment of continental crust

ree distribution in some layered migmatites constraints on their petrogenesis abstract the ree distributions in mesosomes neosomes leucosomes and melanosomes of four layered migmatites have been investigated in one example arvika migmatites the ree patterns in adjacent paragneisses the presumed parent rock of the migmatites were also determined ree patterns of neosomes and mesosomes of arvika migmatites are similar to the finegrained layers and coarse grained layers respectively observed in the adjacent paragneiss this is in agreement with the layer by layer paragneiss migmatite transformation model the ree patterns of mesosomes and neosomes indicate that these lithologies may have been closed systems for ree during the formation of the migmatites no indication of metasomatic reactions melt segregation or injection could be detected within the neosomes leucosomes are depleted and melanosomes enriched in ree contents this is interpreted to be due to separation and concentration of accessory minerals monazite epidote allanite zircon sphene apatite garnet into the melanosomes the behaviour of accessory minerals during migmatite formation is closely allied to that of biotite which is also concentrated in the melanosomes

incongruent dissolution of ree and sr rich apatite in peraluminous granitic liquids differential apatite monazite and xenotime solubilities during anatexis the relative solubilities of monazite mnz xenotime xno and apatite ap ree and sr rich and ree and sr poor have been studied in peraluminous granitic liquids in month long experiments at 750 c and 200 mpa ph20 in contrast with the high solubility of the apatite 0 7 wtojop205 in strongly peraluminous liquids monazite and xenotime have much lower solubilities 0 05 wt jop205 in mildly to strongly peraluminous compositions p205 in the liquid is 0 03 0 04 wt joat xenotime saturation and 0 02 0 05 wt jo at monazite saturation in keeping with the low p in the glasses re203 contents are below emp detection thresholds 50 08 wt jo for all conditions of experiments saturation of liquid at equilibrium and local saturation around apatite apatite dissolves incongruently crystallizing ree rich monazite on its surface 1 4 m iong grains resulting in similar low ree contents in liquids monazite precipitation occurs along the margins of dissolving apatite crystals even though the bulk liquid is not monazite saturated the abundance of monazite microcrystals increases with the ree content of the apatite and the degree of apatite dissolution the reaction relationship ap liqi mnz liq2 stemming from differences in relative solubilities greater than an order of magnitude between apatite and monazite results in the dissolution of much smaller amounts of ree into peraluminous liquids than expected by simple evaluation of apatite ree contents the amount of ree contributed from apatite directly to peraluminous granitic liquid is related to the amount of apatite dissolved by simple mass balance only if the total ree content of the apatite is sufficiently low that monazite saturation in liquid 50 100 ppm re203 at 750 c is avoided during dissolution of sr rich apatite the sr partitions into the liquid and at 750 c and 200 mpa ph20 the diffusion coefficient of sr in liquid is 2 x 10 10 cm2js r2 0 659 the reaction relationships described above may have application to some textural features observed in natural igneous rocks for example clusters of monazite microcrystals might be indicators of dissolved apatite monazite morphology can be used to distinguish the source of its ree and the general petrological process rock anatexis or magma crystallization under which the monazite formed in addition monazite microcrystals could serve as nucleation sites for other minerals which might explain their common inclusion in biotite and amphibole within granitoids

ree fractionation and nd isotope disequilibrium during crustal anatexis constraints from himalayan leucogranites abstract the processes controlling rare earth element ree behaviour during crustal anatexis have profound implications not only for ree abundances of crustally derived granites but also for their model nd ages for typical protoliths of anatectic granites such as are exposed in metapelites from the high himalayan crystalline series hhcs a high proportion 90 of bulk rock lree and mree are sited in the accessory phases apatite and monazite and of hree in garnet and apatite mass balance constraints indicate that observed ree abundances of himalayan leucogranites cannot be generated from ree deficient reactant phases in their metasedimentary protoliths muscovite biotite plagioclase and quartz but must result from the dissolution of accessory phases ree and th abundances in anatectic melts are modelled by combining empirical expressions for monazite apatite and zircon solubilities as a function of temperature melt composition and melt water content with analysed accessory phase ree abundances this approach which allows the contribution to the melt from each accessory phase to be identified successfully predicts himalayan leucogranite trace element abundances the lree and th concentrations of a metapelite derived melt are buffered by monazite stability although apatite dissolution contributes up to 10 of lree to the melt together with 50 of the mree and 90 of the hree zircon contributes a negligible proportion of ree to the melt during anatexis dissolution of monazite and apatite in the melt results in 1 increasing ree abundances and lree hree ratios with increasing temperature of melting 2 a negative eu anomaly in the melt 3 high sm nd ratios in the melt relative to its metasedimentary protolith and 4 nd isotope disequilibrium between the melt and its protolith all of these features are observed in the ree geochemistry of himalayan leucogranites the combined effects of sm nd fractionation and nd isotope disequilibrium during anatexis imply that model nd ages calculated for anatectic granites derived from apatite and monazite bearing protoliths should be treated with considerable caution

isotopic study of the manaslu granite himalaya nepal inferences on the age and source of himalayan leucogranites a detailed isotopic study of the manaslu leucogranite was carried out a u pb age of 25 ma and a whole rock rb sr age isochron of 18 ma were obtained suggesting that the magmatic activity lasted at least 7 ma initial sr isotopic ratios are very high 0 740 to 0 760 and initial nd isotopic ratios are low nd in 13 to 16 and they show the existence of large isotopic variations even at the metre scale these are not the result of perturbations by fluids but rather they reflect the initial isotopic heterogeneity of the source material which has not been obliterated by magmatic processes e g fusion mixing by convection these results also support the crustal origin of this leucogranite the tibetan slab paragneisses whose sr and nd isotopic ratios are very similar to those of the granite at an age of 20 ma are the most probable parental material nd model ages for both the leucogranite and the gneisses are in the range 1 5 2 ga a model of formation of the manaslu granite by coalescence of different batches of magma is in agreement with the present data

accessory mineral fractionation of rare earth element ree abundances in granitoid rocks abstract accessory minerals with large distribution coefficients k d s for the ree have the potential to strongly affect the evolution of ree abundances during igneous differentiation e g crystallization melting assimilation a cogenetic suite of lavas basaltic andesites through high silica rhyolites from the batopilas area of mexico which preserve petrographic evidence for apatite and zircon saturation is used to illustrate and confirm an inverse geochemical approach to recognizing early liquidus accessory mineral saturation the transition in behavior of zr from an incompatible trace element in basaltic andesites and dacites to an essential structural constituent esc in high silica rhyolites marks the onset of zircon crystallization a previously published zircon saturation model provides liquidus temperatures that support the interpretation that three high silica rhyolites represent zircon saturated melts while one has excess zircon these results contradict the previous study in which zircon fractionation had been argued against the potential effect of zircon fractionation and accumulation on ree abundances in the samples is evaluated and contributes to an improved petrogenetic interpretation a cogenetic suite of granitoid samples from the saganaga tonalite minnesota ontario north america is characterized by apparently strongly compatible behavior of the ree apatite zircon and sphene are the observed high ree k d accessory minerals forward and inverse modelling approaches provide no evidence that accessory mineral fractionation contributed to the behavior of the ree during differentiation of the samples the data instead suggest that the ree characteristics of the samples were already established by other petrogenetic processes prior to the samples becoming saturated with the observed accessory minerals

isotopic mapping of age provinces in precambrian high grade terrains sri lanka nd model ages of amphibolite and granulite grade rocks in sri lanka form a simple regional pattern that broadly correlates with mappable geological units and is in effect an isotopic map of the island s basement the granulite grade units of the highland group and southwest group have model ages of 2 2 3 0 ga indicating derivation mainly from late archean sources they are bounded to the east and west by late proterozoic gneisses of the vijayan complex with model ages of 1 1 2 0 ga the isotopic data identify three distinct crustal provinces and are not consistent with earlier suggestions that the vijayan gneisses are retrograde equivalents of the highland granulites sri lanka is not a direct continuation of the archean dharwar craton of southern india identification of vijayan type juvenile crustal terrains in other gondwana fragments may play a key role in determining the precise attachment of southern india sri lanka in eastern gondwana

geochemical investigations of the origin of the manaslu leucogranite himalaya nepal the himalayan orogeny is characterized by an intraplate subduction zone the thrusting of the tibetan slab over the foreland is probably responsible for the origin of the manaslu type leucogranites this geochemical study tries to examine the crustal origin of the granite to verify whether the paragneisses of the tibetan slab are the most probable parent material and to determine the subsequent petrogenetic processes the rb sr systematics suggest that 1 1 the scatter of data points in the 87sr86srvs 87rb86sr diagram may be due to the heterogeneity of the initial 87sr86sr ratios 2 2 the initial isotopic ratios are very high 0 730 0 760 and are in agreement with those of the gneisses of the tibetan slab at the time of the melting pb isotopic ratios are homogeneous they are also consistent with a crustal prehistory the ree and th contents are unexpectedly low in comparison with the much higher contents of the parent material monazite left in the residue of melting or more probably extracted in an early stage of the magmatic history may explain the observed ree and th abundances alternatively field observations show that the emplacement of the granite has been accompanied by a very strong hydrothermal activity in consequence the low ree and th contents of the granite could also be due to the loss by solution during prolonged fluid circulation throughout the granitic melt and the sr and pb isotope distribution to the effect of late to post magmatic fluids the isotopic character of which was determined by the underlying tibetan slab

ion microprobe determinations of trace element concentrations in garnets from anatectic assemblages abstract trace element data for garnet cordierite plagioclase alkali feldspar and tourmaline have been obtained by ion microprobe analysis of assemblages from a pelite derived leucogranite a sillimanite grade anatectic gneiss and a kyanite grade sub solidus schist from the high himalaya results confirm that for equilibrium melting residual plagioclase will cause depletion in sr and eu in the melt and residual garnet will result in strong depletion of y and hree consistent with their published partition coefficients all trace elements of interest are strongly incompatible in cordierite implying that for equilibrium fractional melting of pelites at shallow depths hree concentrations in garnets from metasediments are independent of metamorphic grade but the metamorphic garnets are significantly less enriched in hree than is the leucogranite garnet this suggests either that the leucogranite is derived from a source with lower modal abundances of garnet than the analysed metasediments or that garnet from the anatectic gneiss has not reached chemical equilibrium with a granitic melt the latter possibility is consistent with sluggish self diffusion rates in garnets for ree at temperatures of 5 kbar

petrogenesis of the puerto eden igneous and metamorphic complex magallanes chile late jurassic syn deformational anatexis of metapelites and granitoid magma genesis a suite of schists gneisses migmatites and biotite granitoids from the puerto eden igneous and metamorphic complex peimc and biotite hornblende granitoids of the south patagonian batholith southern chile has been studied for that purpose the chemistry of minerals and the bulk rock composition of major and trace elements including rb sr and sm nd isotopes were determined mineralogical observations and geothermobarometric calculations indicate high temperature and low pressure conditions ca 600 700 c and 3 to 4 5 kbar for an event of metamorphism and partial melting of metapelites in late jurassic times previously determined by shrimp u pb zircon ages structures in schists gneisses migmatites and mylonites indicate non coaxial deformation flow during and after peak metamorphic and anatectic conditions andalusite schists and sillimanite gneisses yield initial 87sr 86sr ratios of up to 0 7134 and end150 values as low as 7 6 contemporaneous biotite granitoids and a coarse grained orthogneiss have initial 87sr 86sr ratios between 0 7073 and 0 7089 and end150 values in the range 7 6 to 4 4 this indicates that metamorphic rocks do not represent the natural isotopic variation in the migmatite source thus a heterogeneous source with a least radiogenic component was involved in the production of the biotite granitoids the peimc is considered as a segment of an evolving kilometre sized and deep crustal shear zone in which partial melts were generated and segregated into a large reservoir of magmas forming composite plutons in late jurassic times a biotite hornblende granodiorite and a muscovite garnet leucogranite show initial 87sr 86sr ratios of 0 7048 and 0 7061 and end100 values of 2 6 and 1 8 respectively and are thus probably related to early cretaceous magmas not involved in the anatexis of the metasedimentary rocks

mobility and fractionation of rare earth elements during supergene weathering and gossan formation and chemical modification of massive sulfide gossan primary massive sulfide gossans msg in the bathurst mining camp bmc new brunswick canada are characterized by relative enrichment of au sb and as formation of jarosite group minerals jarosite plumbojarosite and argentojarosite and little or no fractionation in the rare earth elements ree including preservation of large positive eu anomalies average eu eu nasc 4 14 in msg 6 61 in massive sulfide mineralization 0 60 in host rocks the chemical and mineralogical characteristics of msg e g halfmile lake deposit imply low ph 3 and relatively oxidizing conditions during gossan formation oxidation of a volcanogenic massive sulfide body comprising pyrite pyrrhotite sphalerite galena and chalcopyrite with a falling water table the lack of light ree or heavy ree fractionation and preservation of positive eu anomalies characteristic of the original 465 ma hydrothermal fluid is consistent with relatively large water rock ratios during massive sulfide mineralization oxidation and removal of the ree predominantly as sulfate complexes lnso4 ln so4 2 low ph groundwaters recovered from past producing mines in the bmc display ree patterns reflecting those inferred to have occurred during gossan formation gossan at the restigouche deposit in contrast to the halfmile lake deposit displays mineralogical and chemical evidence for having been chemically reworked since primary gossan formation evidence for chemical reworking includes loss of primary massive sulfide mineralization textures replacement of plumbojarosite with anglesite almost complete removal of jarosite minerals loss of au sb and as and apparent preferential removal of eu resulting in loss of positive eu anomalies for most samples average eu eu nasc 1 21 in the gossan with many displaying strong negative anomalies 3 65 in massive sulfide mineralization 0 54 in host rocks based on geochemical modeling conditions inferred for the chemical reworking of the restigouche deposit include near neutral conditions and either relatively oxidizing conditions with eu2 hosted in a preferentially weathered mineral host possibly through substitution for pb in plumbojarosite and beudantite or cycling between reduced and oxidized conditions during gossan reworking

apatite monazite and xenotime in metamorphic rocks this chapter focuses on phosphates that are significant in metamorphic rocks a quick survey of phosphate mineral descriptions at a commercial mineral web site revealed over 500 phosphate mineral names remarkably only three are common in metamorphic rocks apatite monazite and xenotime and this chapter is restricted to discussion of these minerals apatite monazite and to a lesser extent xenotime have enjoyed intensive study during the previous half century following world war ii considerable study was made of minerals that contain fissionable materials and the sometimes large concentrations of u and th in monazite culminated in a number of seminal papers on the occurrence of that mineral e g overstreet 1967 during the 1970s and early 1980s the study of apatite and monazite turned towards their role as a sink for rees and other trace elements in rocks e g watson 1980 watson and capobianco 1981 throughout this period monazite and to some extent xenotime enjoyed attention as a geochronometer e g parrish 1990 and through today this attention has continued to grow accessory minerals such as monazite xenotime and apatite have come to the forefront of research in metamorphic petrology in recent years for two reasons first it has recently been recognized that trace elements in metamorphic rocks and especially trace element zoning in garnet and other major phases contain considerable detailed information about the reaction history a rock has experienced coupled with the fact that diffusion of many trace elements in metamorphic minerals is in general considerably slower than diffusion of major elements in those same minerals the possibility has recently emerged of recovering details of metamorphic petrogenesis that were previously unattainable inasmuch as accessory minerals play a dominant role in the mass budget of many trace elements attention has naturally turned to their paragenesis it has also recently been discovered that

a nd isotope investigation of sediments related to crustal development in the british isles the times of original fractionation of the sm and nd component of clastic sediments from a mantle source crustal residence age have been estimated from sm nd model ages calculated relative to a depleted mantle evolution in this way the provenance and evolution of selected precambrian and phanerozoic sediments and metasediments from the british isles have been examined whereas some archaean and early proterozoic sediments have sm nd model ages that are close to their stratigraphic age the phanerozoic sediments analysed have model ages as much as 2 0 ga in excess of their stratigraphic age a more detailed study of lower palaeozoic sediments deposited on the northern margin of the iapetus ocean provides evidence for a marked change of provenance in the ordovician after the deposition of the dalradian supergroup a component with comparatively high143nd 144nd and sm nd ratio presumably basaltic is present in the sediments throughout the accretionary prism crustal residence age estimates average about 1 5 ga for both these lower palaeozoic sediments and modern pelagic clays and collectively fail to provide any evidence for significant continental growth during the phanerozoic