a self consistent model of melting magma migration and buoyancy driven circulation beneath mid ocean ridges numerical modeling and analysis are used to investigate the processes leading to the eruption of mantle derived magma at mid ocean ridges our model includes the following effects melting due to decompression magma migration by percolation and circulation of the mantle driven by both the oceanic plates and the distribution of buoyancy beneath the ridge the distribution of buoyancy is due to both the low density of the liquid and the difference in the density of the residual solids relative to unmelted mantle material the calculation of densities is based on a simple petrological model in which garnet spinel lherzolite melts to form a basaltic liquid and a harzburgite residue we find that the system spontaneously evolves to a state in which a rapid upwelling beneath the ridge axis faster than the plate velocity is confined laterally by stably stratified residual material beneath the newly formed plates this effect is exaggerated if a modest decrease in the shear viscosity of the solid upon melting is included our results provide a simple explanation for the narrowness of the zone of crustal formation at mid ocean ridges the model also predicts a transition from steady state to episodic crustal formation as the spreading velocity is reduced perhaps giving rise to along axis variations in the character of seafloor spreading the narrow rapid upwelling gives rise to substantial porosities at depths that are a large fraction of the depth to the solidus this may allow the liquid at depth to segregate into macroscopic channels which would account for the consensus from experimental petrology that the liquids parental to morb are derived from well below the base of the crust

the topography and morphology of low shields and associated landforms of plains volcanism in the tharsis region of mars abstract the morphology and topography of volcanic landforms provide critical information to the investigation of their tectonic setting and the physical characteristics e g rheology of their eruption products their investigation is also an important prerequisite for studies of comparative planetology e g the comparison between surface features of the earth and other planetary bodies numerous small and low shield volcanoes on mars and associated vents and lava flows have previously been compared to terrestrial plains style volcanism which is defined as being an intermediate style between flood basalts and the hawai ian shields this study investigates the topography and morphology of martian landforms associated with plains volcanism using mola moc themis hrsc and hirise data low shields and other landforms of plains volcanism on mars display similarities with terrestrial basaltic volcanic fields and we do not observe any features that do not have morphologic analogues on earth the most typical landforms of martian plains style volcanism are low shields defined as volcanic shields with diameters of typically less than 50 km heights of a few hundred meters only and extremely shallow flank slopes of less than 0 5 other surface features related to plains style volcanism on mars are craters fissure vents cinder and spatter cones lava flows that are commonly associated with lava channels and tubes lava inflation features and volcanic rift zones our results reconfirm the viking orbiter based conclusion that plains volcanism in the eastern snake river plains is perhaps the best terrestrial morphological analogue for these martian surface features icelandic shields distinct structures in hawai i and other basaltic landforms also show similarities to martian plains volcanism sinuous rilles previously not described in association with plains volcanism on mars are interpreted as evidence for high eruption rates the extremely shallow flank slopes of the low shields suggest the eruption of shield building lavas with low viscosity which might be the result of high eruption temperatures high effusion rates a low si and a high mg content along with a possible high fe content or a combination of these factors the spatial distribution of low shield clusters in tharsis does not show any obvious association with large scale tectonic features plains volcanism might represent a relatively recent type of volcanism on mars which is not related to mantle plumes but to a zone of partial melting in an anomalously warm mantle underneath a thickened crust schumacher and breuer geophys res lett 34 l14202 doi 10 1029 2007gl030083 2007

the timing and environment of tepee formation in a marinoan cap carbonate thin carbonate units capping marinoan age glacial diamictites contain atypical tepee like structures that have been interpreted as evidence of seafloor dolomite cementation at parachilna gorge in the adelaide fold thrust belt a marinoan age cap dolomite contains paired tepee and growth fault structures that demonstrate the tepees grew 3 5 7 1 m below the sediment water interface in the early diagenetic zone although generally much larger such tepees and their associated sheet veins have an external morphology and internal structure identical to that of inter tidal tepee structures formed through expansive crystallisation on the other hand cap carbonate hosted tepees lack the size chaotic internal bedding carbonate crust and concretionary morphologies and expected carbon isotope geochemistry to be cold seep structures expansive crystallisation during early diagenesis seems the most likely means of forming tepees in cap carbonates the only cement common to all cap carbonate tepees is microcrystalline dolomite the crystallisation of this mineral phase drove both tepee growth and the fluid overpressure fracturing that formed the sheet veins the same microcrystalline dolomite is the component of cap carbonates routinely selected for isotopic analysis with the resulting 13c values assumed to be representative of coeval marine bicarbonate however the parachilna gorge tepees suggest that the microcrystalline dolomite contains both primary and early diagenetic components their separation is not achieved by current analytical methods

mobility of mo u as and sb within modern turbidites modern turbidites uranium molybdenum arsenic antimony we present and discuss porewaters and sediment data of mn fe mo u as and sb within four recent turbidites from the capbreton canyon sw france the deposition of turbidites on continental margins exerts strong influence on the fate of trace metals causing trace metal migration and or immobilization the down core distribution of the elements here depends entirely of ongoing diagenetic processes rather than the diffusion of o2 the persistence of fe mn oxides under anoxic conditions led to anoxic reoxidation of numerous species as nh4 reduced s compounds and trace metals metal oxides thus control the immobilization of mo and as in the solid phase and the remobilization of u and sb to the porewaters although the low sulphide production prevents anoxic authigenesis of mo and as reducing conditions below each horizon rich in mn fe oxides resulted in u and sb accumulation the exact mechanisms of sb immobilization are not known but it is most certainly different from that of as the profile shapes of mn and u were used to estimate the age of the turbidite deposits which cannot be determined by conventional radionuclide methods our interpretations however depend on calculations of diffusion coefficient particularly for u a simple diffusive model applied to mn suggested that the age of the latest deposit noted t1 was 22 months this date is close to the time elapsed between the core sampling and the last known turbiditic event in the capbreton canyon i e martin storm 18 months using the u data set and depending on diffusion coefficients used the estimated ages of the deeper layers were 4 7 yr for t2 and 7 5 14 yr for t3 the reliability and precision of this new approach to date sediments at short timescales is limited by the ignorance of a precise value for u diffusion coefficient reducing uncertainty on u diffusion coefficient will greatly support application of the proposed approach

early diagenesis in differing depositional environments the response of transition metals in pore water the cycling of fe mn ni co cu cr v and mo during early diagenesis was investigated in sediments from five different depositional environments in the california borderland dissolved o2 no3 no2 and so4 were also measured at each site to establish the position of redox boundaries pertinent to this study sites were chosen to allow the comparison of several parameters of potential importance to the cycling of these metals bottom water o2 concentration sediment redox conditions cycling of metal oxide carrier phases and the relative contribution of biogenic and terrigenous material to the detrital metal flux at 10 m oxygen and above the sequence of terminal electron acceptor utilization was typical of pelagic sediments differing only in scale under these conditions the recycling of mn oxides resulted in an enriched layer near the interface at bottom water 02 concentrations 5 m mn oxides are not recycled under these conditions fe oxides and so42 are important oxidants the depth of the zone of manganese oxidation with respect to the interface affects the efficiency of metal scavenging by manganese oxides trapping and recycling of ni and co with mn oxides results in remobilization from reducing sediments and enrichment in oxic sediments scavenging of these metals is favored by a deep oxic zone in the sediments in contrast cr v and mo appear to be transported to the sediments as reduced species and are released from the sediments by oxidation the source of the reduced species is assumed to be biogenic material the accumulation of these metals is favored by reducing conditions in the sediments cu is enriched in the sediments by transport with detrital biogenic material followed by adsorption onto sediment solids cu is released at the interface and rapidly removed onto the solids at all sites except the one pelagic site at the base of the slope the magnitude of cu released in the slowly accumulating pelagic sediment exceeds the cu binding capacity of the solids resulting in pore water cu concentrations in excess of 100 nm in general metal cycling associated with the early diagenesis of sediments was observed to decouple transport processes from burial processes for the transition metals measured in this study

early plate tectonics versus single plate tectonics on mars evidence from magnetic field history and crust evolution 1 the consequences of an early epoch of plate tectonics on mars followed by single plate tectonics with stagnant lid mantle convection on both crust production and magnetic field generation have been studied with parameterized mantle convection models thermal history models with parameterized mantle convection not being dynamo models can provide necessary but not sufficient conditions for dynamo action it is difficult to find early plate tectonics models that can reasonably explain crust formation as is required by geological and geophysical observations and allow an early magnetic field that is widely accepted as the cause for the observed magnetic anomalies dating of crust provinces and topography and gravity data suggest a crust production rate monotonically declining through the noachian and hesperian and a present day crust thickness of more than 50 km plate tectonics cools the mantle and core efficiently and the core may easily generate an early magnetic field given a sufficiently weak mantle rheology plate tectonics can explain a field even if the core is not initially superheated with respect to the mantle because the crust production rate is proportional to temperature however an early efficient cooling will frustrate later crust production and therefore cannot explain for example the absence of prominent magnetic anomalies in the northern crustal province and the northern volcanic plains in the early hesperian voluminous crust formation following plate tectonics is possible if plate tectonics heat transfer is inefficient but then the crust growth rate has a late peak about 2 ga b p which is not observed these models also require a substantial initial superheating of the core to allow a dynamo if one accepts the initial superheating then as we will show a simple thermal evolution model with monotonic cooling of the planet due to stagnant lid mantle convection underneath a single plate throughout the evolution can better reconcile early crust formation and magnetic field generation

wetland expansion on the continental shelf of the northern south china sea during deglacial sea level rise abstract to identify environmental causes for past changes in vegetation in subtropical east asia we present carbon isotope compositions of plant wax n alkanes and provide estimates of the c4 plant contribution across the past four glacial terminations and interglacials based on cores recovered from the northern south china sea our results show a comparable c4 plant contribution between the last glacial maximum lgm and the holocene an increase of the c4 plant contribution by 15 20 is found for terminations iv ii and i relative to subsequent interglacial peaks coeval with an expansion of cyperaceae and poaceae in contrast termination v reveals a lower c4 plant contribution than marine isotope stage mis 11c the data exhibit a long term trend with a stepwise increase of the c4 plant contribution across interglacials mis 11c 9e 7e and 1 we suggest that no substantial changes in humidity levels over glacial interglacial cycles occurred facilitating a similar c3 c4 plant ratio for the lgm and the holocene instead deglacial sea level rises caused an extensive development of floodplains and wetlands on the exposed continental shelf providing habitats for the spread of c4 sedges and grasses the progressive subsidence of chinese coastal areas and the broadening of the continental shelf over the late quaternary explains the nearly absence of c4 plant occurrence during termination v and a gradual increase of the c4 plant contribution across interglacial peaks taken together changes in coastal environments should be considered when interpreting marine based vegetation reconstructions from subtropical asia

an 800 kyr record of global surface ocean δ18o and implications for ice volume temperature coupling abstract the sequence of feedbacks that characterized 100 kyr glacial cycles of the past million years remains uncertain hampering an understanding of the interconnections between insolation ice sheets greenhouse gas forcing and climate critical to addressing this issue is an accurate interpretation of the marine 18 o record the main template for the ice ages this study uses a global compilation of 49 paired sea surface temperature planktonic 18 o records to extract the mean 18 o of surface ocean seawater over the past 800 kyr which we interpret to dominantly reflect global ice volume the results indicate that global surface temperature inferred deep ocean temperature and atmospheric co2 decrease early during each glacial cycle in close association with one another whereas major ice sheet growth occurs later in glacial cycles these relationships suggest that ice volume may have exhibited a threshold response to global cooling and that global deglaciations do not occur until after the growth of large ice sheets this phase sequence also suggests that the ice sheets had relatively little feedback on global cooling simple modeling shows that the rate of ice volume change through time is largely determined by the combined influence of insolation temperature and ice sheet size with possible implications for the evolution of glacial cycles over the past three million years

phase transitions in the martian mantle and the generation of megaplumes the influences of two exothermic phase transitions the olivine to spinel and the to spinel transition on martian mantle convection have been studied with an axisymmetric spherical shell model there are depth dependences in the thermal expansivity and gravity which taken together decrease by a factor of between 2 to 3 across the mantle we have discovered an unique mechanism for the amplification and superheating of megaplumes in mars which works particularly well because of the optimal heights of the two destabilizing exothermic phase transitions above the martian core mantle boundary cmb the cold descending mantle flow is accelerated by its interactions with the phase transitions and the nearby cmb forces the flow to bend over sharply together these effects result in strong localized viscous heating which will generate and accelerate a rising plume and may even cause melting in its deep interior and produce komatiites

micro scale biogeochemical heterogeneity in sediments a review of available technology and observed evidence the hypothesis that reducing conditions exist in localized zones of high organic matter termed microniches was first suggested over a century ago but only relatively recently have high resolution techniques been available to investigate them in any sediment containing benthic fauna bioturbation affects the distribution of a number of redox sensitive components direct faecal deposition and the death of fauna may be expected to cause particles of labile organic matter microniches to be distributed heterogeneously within the sediment this review discusses the significance and future direction of microniche studies by considering exclusively data obtained on a sub mm scale that provide significant evidence for the existence and properties of microniches microelectrodes and planar optodes have shown the significant effect of burrowing organisms on localized o2 distributions and revealed distinct depletions in o2 due to microniches localized increases in pco2 and decreases in ph measured by optodes were attributed to elevated activity at microniches diffusive gradients in thin films have shown isolated supersaturation of metals and sulphide providing evidence for possible simultaneous oxidation of organic matter by sulphate and iron oxides the stochastic nature of these data and the lack of information for the same precise location hinders interpretation in terms of sediment diagenesis if microniches are known to account for a significant proportion of organic matter degradation re examination of the current understanding of sedimentary diagenesis may be needed further investigation on the distribution and frequency of microniches is required including a wider range of analytes in order to estimate their cumulative effect on element diagenesis immobilisation remobilisation processes and ultimately pollutant fate

depth localization of denitrification in a deep sea sediment from the madeira abyssal plain1 sediments of the madeira abyssal plain are dominated by alternate sequences of pelagic sediment and turbidites composed of relatively organic rich material transported from the continental margin after the deposition of a turbidite and resumption of pelagic sedimentation the zones of o2 and no3 respiration progress slowly into the turbidite from above the oxidation front is characterized by depletion of o2 and no3 at almost identical depths data are presented to show that no3 respiration denitrification within such a turbidite is localized in a very small depth interval at the oxidation front

estimating the hydrogen isotopic composition of past precipitation using leaf waxes from western africa abstract the hydrogen isotopic composition of plant leaf wax n alkanes d wax is a novel proxy for estimating d of past precipitation d p however vegetation life form and relative humidity exert secondary effects on d wax preventing quantitative estimates of past d p here we present an approach for removing the effect of vegetation type and relative humidity from d wax and thus for directly estimating past d p we test this approach on modern day late holocene 0 3 ka sediments from a transect of 9 marine cores spanning 21 n 23 s off the western coast of africa we estimate vegetation type c 3 tree versus c 4 grass using 13 c of leaf wax n alkanes and correct d wax for vegetation type with previously derived apparent fractionation factors for each vegetation type late holocene vegetation corrected d wax d vc displays a good fit with modern day d p suggesting that the effects of vegetation type and relative humidity have both been removed and thus that d vc is a good estimate of d p we find that the magnitude of the effect of c 3 tree c 4 grass changes on d wax is small compared to d p changes we go on to estimate d vc for the mid holocene 6 8 ka the last glacial maximum lgm 19 23 ka and heinrich stadial 1 hs1 16 18 5 ka in terms of past hydrological changes our leaf wax based estimates of d p mostly reflect changes in wet season intensity which is complementary to estimates of wet season length based on leaf wax 13 c

two stage plume melting a possible mechanism for the origin of martian magmatism abstract the origin of martian magmatism is investigated by geochemical modeling based on the isotopic and rare earth element ree compositions of the shergottite nakhlite and chassignite snc meteorites the model proposed in this study consists of three processes early mantle differentiation in the deepest mantle to produce a plume source region composed of hydrated ringwoodite and majorite first stage dehydration melting of the plume to produce nakhlite and chassignite magmas in the deep mantle and finally second stage decompression melting of the residual plume to produce shergottite magmas in the uppermost mantle the production of light ree enriched nakhlite and chassignite magmas can be explained by the persistence of residual garnet through first stage melting and the depleted isotopic composition of the nakhlite and chassignite meteorites can be reasonably attributed to the presence of majorite in the plume source region the strongly depleted ree and isotopic composition of the primitive shergottites can similarly be explained by the existence of majorite in the plume source region coupled with extraction of the nakhlite melt from the depleted source the proposed two stage plume melting model therefore reproduces the chemical and isotopic variations of the martian magmas well suggesting a genetic relationship among the snc magmas

volcanism on mars more than 15 years of planetary exploration of mars have given insight into the geologic processes that have shaped its surface the newly acquired viking data have shown that volcanism is one of the most important geologic processes operating on mars throughout its history in situ chemical analyses of martian soil by the viking lander spacecraft indicate mafic to ultramafic source rocks this is consistent both with available remote sensing data which indicate the presence of mafic minerals such as pyroxene and olivine and with petrologic modeling based on available geophysical data which suggest that martian lavas are probably iron rich and ultramafic these data strongly suggest that basaltic volcanism is widespread on mars and much of the photogeological data may be studied in this context photogeological analysis of the martian surface has shown two main types of volcanic morphologies the first type is central volcanoes which are volcanic landforms developed by continued and prolonged eruption from a point source vent this category includes 1 shields the classic low profile volcanic mountains of which olympus mons is the most spectacular example 2 domes steep sided constructs such as tharsis tholus that may represent lower rates of eruption than the shields or possibly more silicic lava compositions 3 highland patera radially textured low profile volcanoes that occur in the cratered terrain and are interpreted as ash shields 4 alba patera an apparently unique volcanic landform consisting of a vast volcanic center over 1500 km across with flank slopes of less than a tenth of a degree and 5 various small features such as cinder cones the second major category is volcanic plains which are units recognized by several criteria of which the presence of mare ridges and flow lobes are the most useful volcanic plains are subdivided into four main groups 1 simple flows broad smooth to rolling plains that contain numerous mare type ridges but no flow lobes interpreted as being composed of thick single cooling units 2 complex flows displaying multiple overlapping flow lobes interpreted to be indicative of thin multiple cooling units 3 undifierentiated flows plains that typically lack any morphologic identifying feature but are considered to be volcanic partly on the basis of their association with large volcanic centers and 4 questionable plains volcanic units heavily modified by other processes erosion tectonism etc so that their origins are uncertain when these categories of volcanic morphologies are combined with relative age data provided by crater statistics a volcanic history for mars can be derived as follows early heavy bombardment of mars was accompanied and followed by small scale fluvial channeling extensive flood volcanism the plateau plains and ash shield volcanism in the cratered terrain shortly after this time less extensive flood volcanism continued to resurface the planet during formation of the northern southern hemisphere dichotomy central volcanism became more prominent with the development of the alba patera center as well as the older shields and domes of the northern hemisphere early tharsis and elysium regions the development of the tharsis and elysium uplifts may have triggered the release of large scale catastrophic floods producing large channels continued uplift and lithospheric thinning concentrated volcanic activity in the tharsis region producing large shield volcanoes and extensive lava plains both central vent and plains volcanism have been active throughout martian history but the volumes of extrusion have gradually decreased with time this is consistent with a moonlike thermal history involving a lithosphere of increasing thickness with time gradually turning off the volcanism although many questions remain regarding martian volcanism the viking data have provided a remarkable detailed overview of the probable nature of the volcanic history of mars

coherent pan asian climatic and isotopic response to orbital forcing of tropical insolation the oxygen 18 isotope composition of calcite in stalagmites across southern and eastern asia are highly correlated to one another on orbital time scales large negative excursions are coincident with maxima in summer insolation in the subtropics of the northern hemisphere nh these isotopic excursions reflect changes in the precipitation weighted isotopic composition of precipitation 18op we present results from two core experiments using an isotope enabled climate model the high insolation and low insolation experiments in which the model is forced by extrema in nh summer insolation compared to the low insolation experiment the high insolation climate features profound large scale changes in the pattern of monsoon precipitation spanning from africa to southeast asia that are due to changes in the relative contributions of temperature and moisture to the near surface equivalent potential temperature e under high insolation a more rapid increase in land surface temperature in early summer causes the greatest e and hence precipitation to shift from the oceans in low insolation such as today to be over land in high insolation such as the early holocene the model captures the general pattern of isotopic excursions seen in caves spanning from israel to western china including large drops in 18op over eastern tibet 7 the arabian peninsula and northeast africa 4 although there are large changes in precipitation over tibet the change in 18op is due to changes in the 18o of water vapor that is delivered and subsequently precipitated it does not inform on local precipitation amount or intensity

seasonal transitions and the westerly jet in the holocene east asian summer monsoon abstractthe holocene east asian summer monsoon easm was previously characterized as a trend toward weaker monsoon intensity paced by orbital insolation it is demonstrated here that this evolution is more accurately characterized as changes in the transition timing and duration of the easm seasonal stages spring pre mei yu mei yu midsummer and tied to the north south displacement of the westerlies relative to tibet to this end time slice simulations across the holocene are employed using an atmospheric general circulation model self organizing maps are used to objectively identify the transition timing and duration of the easm seasonal stages compared to the late holocene an earlier onset of mei yu and an earlier transition from mei yu to midsummer in the early to mid holocene are found resulting in a shortened mei yu and prolonged midsummer stage these changes are accompanied by an earlier northward positioning of the westerlies relative to tibet invoking changes to seasonal transitions al

porewater redox species and processes in the black sea sediments during the 2003 knorr and the 2005 endeavor cruises to the black sea voltammetric solid state microelectrode data were collected for the vertical distribution of redox species in porewaters from the upper 200 to 300 mm layer of sediments with mm vertical resolution we discuss vertical distributions of dissolved sulfide manganese and iron species in sediments from the oxic suboxic anoxic sulfidic parts of the black sea results of voltammetric profiling demonstrate many processes governing the porewater chemistry of oxic shelf sediments suboxic shelf slope sediments deep anoxic sediments unit i and turbidites in deep anoxic sediments sediments from the oxic shelf areas appear to be spatially similar in their porewater chemistry revealing the same sequence of redox species as elsewhere in the ocean except for the lack of manganese this lack of manganese is explained by its diagenetic remobilization and accumulation in anoxic waters and suboxic sediments sediments from the suboxic part of the shelf slope reveal high concentrations of manganese ii and iron ii in porewaters still the flux of mn ii from these sediments comprises only a part of the mn iv that precipitates from the water column and can be diagenetically recycled in these sediments these sediments appear to be the major net sink of manganese as it is not accumulated in sediments of either the oxic or anoxic parts of the sea the porewater chemistry of deep anoxic cores showed major spatial variations in the magnitude and even direction of the flux of sulfide the sediments from the eastern central black sea show an expected unit 1 source of sulfide to the overlying water and have high sulfide content up to 1600 m in the anoxic western and near coastal cores turbidites cause significant loss of porewater sulfide down to nondetectable sulfide b0 2 m the latter can be explained by the origin and oxidized mn and fe content of turbidites 2007 elsevier b v all rights reserved

precession and glacial cycle controls of monsoon precipitation isotope changes over east asia during the pleistocene abstract precipitation isotope reconstructions derived from speleothems and plant waxes are important archives for understanding hydroclimate dynamics their climatic significance in east asia however remains controversial here we present terrestrial plant wax stable hydrogen isotope dwax records over periods covering the last four interglacials and glacial terminations from sediment cores recovered from the northern south china sea scs as an archive of regionally integrated precipitation isotope changes in southeast china combined with previous precipitation isotope reconstructions from china we find that the scs dwax and southwest central china stalagmite 18 o records show relatively enriched and depleted isotopic values respectively during interglacial peaks but relatively similar isotopic variations during most sub interglacials and glacial periods over the past 430 thousand years during interglacial peaks strong summer insolation should have intensified the convection intensity the isotopic fractionation along moisture trajectories and the seasonality which are all in favor of causing isotopically depleted rainfall over the east asian monsoon regime these effects in combination with a relatively high proportion of indian ocean versus pacific sourced moisture influx should have resulted in strongly depleted precipitation isotopes stalagmite 18 o over most parts of china however southeast china should have been affected by a relatively low ratio of indian ocean versus pacific sourced moisture influx which dominated over effects yielding depleted precipitation isotopes and led to enriched precipitation isotopes dwax it is thus concluded that glacial boundary conditions and insolation forcing are the two most important factors for causing regional differences in precipitation isotope compositions over subtropical east asia on orbital timescales

internal structure and early thermal evolution of mars from mars global surveyor topography and gravity topography and gravity measured by the mars global surveyor have enabled determination of the global crust and upper mantle structure of mars the planet displays two distinct crustal zones that do not correlate globally with the geologic dichotomy a region of crust that thins progressively from south to north and encompasses much of the southern highlands and tharsis province and a region of approximately uniform crustal thickness that includes the northern lowlands and arabia terra the strength of the lithosphere beneath the ancient southern highlands suggests that the northern hemisphere was a locus of high heat flow early in martian history the thickness of the elastic lithosphere increases with time of loading in the northern plains and tharsis the northern lowlands contain structures interpreted as large buried channels that are consistent with northward transport of water and sediment to the lowlands before the end of northern hemisphere resurfacing

early diagenetic processes fluxes and reaction rates in sediments of the south atlantic abstract porewaters recovered from sediment cores gravity corers box corers and multicorers from various subrogions of the south atlantic amazon river mouth equatorial upwelling congo river mouth benguela coastal upwelling area and angola basin were investigated geochemically objectives included determination of eh ph oxygen nitrate sulfate alkalinity phosphate ammonium fluoride sulfide cal mg sr fe mn and si in order to quantify organic matter diagenesis and related mineral precipitation and dissolution processes porewater profiles from the eastern upwelling areas of the south atlantic suggest that sulfate reduction in the deeper parts of the sediment may be attributed mainly to methane oxidation whereas organic matter degradation by sulfate reduction is restricted to the near surface sediments further a prominent concentration gradient change of sulfate and related mineralization products occurred typically in the upwelling sediments at a depth of 4 to 8 m far below the zone of bioturbation or bioirrigation because other sedimentological reasons seem to fail as explanations an early diagenetic sulfide oxidation to sulfate within the anoxic environment is discussed porewater profiles from the sediments of the amazon fan area are mainly influenced by reactions with fe iii phases the remarkable linearity of the concentration gradients of sulfate supports the idea of distinct reaction layers in these sediments in contrast to the upwelling sediments the sulfate gradient develops from the sediment surface to a sulfate reduction zone at a depth of 5 3 m probably because a reoxidation of sulfide is prevented by the reaction with iron oxides and the formation of iron sulfide minerals a comparison of organic matter degradation rates from the different areas of the south atlantic show the expected relationship to primary productivity oxygen is the dominating oxidant whereas organic matter degradation by nitrate mn iv and probably also fe iii reduction is several orders of magnitude lower sulfate reduction is quantitatively of similar importance as oxygen respiration in the organic rich sediments but may also include methane oxidation reoxidation of ammonium and mn2 by oxygen or nitrate do not alter significantly the estimation of organic matter degradation in the oxic zone but may contribute to the nitrate reduction in suboxic layers

the climate of the mis 13 interglacial according to hadcm3 the climate of the marine isotopic stage 13 mis 13 is explored in the fully coupled atmosphere ocean general circulation model the hadley centre coupled model version 3 hadcm3 it is found that the strong insolation forcing at the time imposed a strengthened land ocean thermal contrast resulting in an intensified summer monsoon over asia the addition of land ice over north america and eurasia results in a stationary wave feature across the eurasian continent this leads to a high pressure anomaly over the sea of japan with increased advection of warm moist air onto the chinese landmasses this in turn reinforces the east asian summer monsoon easm highlighting the counterintuitive notion that depending on the background insolation and its size ice can indeed contribute to strengthening the easm the modeling results support the geological record indication of a strong easm 500 000 years ago furthermore arctic oscillation el nino southern oscillation and indian ocean dipole like teleconnection features are discussed in the mis 13 environment it is shown that the change in the tropical pacific sea surface temperature has the potential to impact the north atlantic climate through an atmospheric bridge

interior structure and seasonal mass redistribution of mars from radio tracking of mars pathfinder doppler and range measurements to the mars pathfinder lander made using its radio communications system have been combined with similar measurements from the viking landers to estimate improved values of the precession of mars pole of rotation and the variation in mars rotation rate the observed precession of 7576 35 milliarc seconds of angle per year implies a dense core and constrains possible models of interior composition the estimated annual variation in rotation is in good agreement with a model of seasonal mass exchange of carbon dioxide between the atmosphere and ice caps

phosphorus diagenesis in sediment of the thau lagoon we describe the depth distribution of phosphorus in relation to the distribution of major redox species dissolved o2 n o 3 n h 4 mn and fe and particulate s organic c reactive mn and fe oxides in modern sediments of two stations in the thau lagoon sediments close to the oyster bank zone are enriched in organic carbon and are highly bioturbated while those outside the bank are less bioturbated and organic carbon levels are lower in all sites early diagenesis follows the well accepted depth sequence of redox reactions of organic matter mineralization the upper sediments of the station enriched in organic carbon contain high amounts of reactive particulate organic phosphorus that arrives at the sediment surface through biodeposition only a part of this phosphorus is released to the bottom water after mineralization since more than 50 of total p is buried as an authigenic phosphate mineral in the middle of the lagoon outside the oyster bank zone organic matter seems to be much more refractory but the distribution of the major redox compounds indicates that this organic matter is partially mineralized a portion of the phosphate and ammonium released during mineralization does not escape the sediment since the concentration gradient is close to zero between 1 and 25 cm depth below the sedimentewater interface pore water n and p are likely fixed by biological uptake the characterisation and magnitude of this process require further study 2006 elsevier ltd all rights reserved

ice age terminations 230th dated oxygen isotope records of stalagmites from sanbao cave china characterize asian monsoon am precipitation through the ends of the third and fourthmost recent ice ages as a result am records for the past four glacial terminations can now be precisely correlated with those from ice cores and marine sediments establishing the timing and sequence of major events in all four cases observations are consistent with a classic northern hemisphere summer insolation intensity trigger for an initial retreat of northern ice sheets meltwater and icebergs entering the north atlantic alter oceanic and atmospheric circulation and associated fluxes of heat and carbon causing increases in atmospheric co2 and antarctic temperatures that drive the termination in the southern hemisphere increasing co2 and summer insolation drive recession of northern ice sheets with probable positive feedbacks between sea level and co2

the rocks of mars from far and near award of the meteoritical society 2001 h y mcsween jr the leonard medal address the rocks of mars from far and near

ecologic shift and aridification in the northern tibetan plateau revealed by leaf wax n alkane δ2h and δ13c records abstract two competing factors the global cooling and the uplift of tibetan plateau have been proposed to drive the central asian aridification but their relative role has seldom been discriminated in paleoclimate and paleoenvironment records here we reconstruct a 14 million year long record of paleohydrology and paleoecology in the western qaidam basin by applying the compound specific hydrogen 2h and carbon 13c isotope analyses to terrestrial leaf wax long chain n alkanes the 2h values are low during the interval of 14 6 to 13 0 ma then the 2h increases from 13 0 to 12 2 ma and maintains high values from 12 2 to 3 2 ma with a peak high value of 156 1 at 8 0 ma after 3 2 ma the 2h values are low and vary larger than 30 the 13c values decrease from 14 6 to 13 0 ma and are low from 13 0 to 3 2 ma except a high value at 3 8 ma then they decrease slightly after 3 2 ma low 2h values indicate relatively wet climate between 14 6 and 13 0 ma the decreasing 13c values during the same time period support the ecologic shift with the decline of warm component of conifers after the mid miocene climatic optimum high 2h values since 13 0 ma are synchronous with the uplift of northern tibetan plateau implying tectonics driven aridity large amplitude variation in 2h values since ca 3 2 ma seen in east and west qaidam and lower 13c values reveal the climatic cyclic responses to the northern hemisphere glaciation

source to sink transport processes of fluvial sediments in the south china sea the south china sea offers an excellent case for studying source to sink transport processes of fluvial sediments among the global marginal seas this study synthesizes existing clay mineralogical and geochemical data from similar to 1500 samples from the seafloor and surrounding rivers deepwater mooring observation results and high resolution glacial cyclic clay mineralogy records from six high quality sediment cores source to sink sediment transport from the river mouth to the continental shelf and then to the abyssal basin is investigated at two time scales modern process and late quaternary glacial cycles the results firstly show the high diversity of clay mineralogical and geochemical compositions in riverbed surface sediments surrounding the south china sea e g dominant illite and chlorite in taiwan overwhelming majority of smectite in luzon dominant kaolinite in south china and similar amounts of the four clay mineral species in red and mekong river systems the formation of these fluvial sediments through chemical weathering in surrounding drainage systems is controlled principally by the east asian monsoon climate with warm temperature and high precipitation and subordinately by tectonic activity and specific lithological character the basin wide distribution of clay mineral assemblages combined with neodymium and strontium isotopic compositions reflects strong provenance control and differential settling effects the differential settling of kaolinite in slightly saline and proximal regions relative to smectite in more saline and distal regions is well demonstrated in the south china sea through combining clay mineralogical distributions on the seafloor with observed oceanic current systems the modern transport pathways can be well established e g in the northern south china sea illite and chlorite from taiwan are mainly carried by contour currents with the strong influence of mesoscale eddies high resolution sediment dynamic analysis for the late quaternary reveals different sediment transport patterns in the northern western and southern south china sea when the land sea configuration dramatically changed during glacial conditions in the north the terrigenous dispersal is mainly controlled by provenance supply and oceanic current transport in the west the clay mineral assemblage reflects variations of the prevailing surface current influenced by monsoon winds in the south the clay mineral input indicates intensive chemical weathering during interglacial periods and strengthened physical erosion during glacial periods the transport of terrigenous sediments since the last glaciation is quantitatively reconstructed through studying two deepwater sediment cores located in the northern south china sea the relative contributions from three provenances south china luzon and taiwan highlight their distinct variability over the last 28 ka implying that the southward shift of the inter tropical convergence zone itcz at 16 ka bp caused an increased sediment contribution from south china the intensified influence of the kuroshio current intrusion controls more efficient westward transport of luzon sediments and the stronger deepwater current transports taiwan sourced sediments further westward from the last glaciation to the holocene c 2015 elsevier b v all rights reserved

the asian monsoon over the past 640 000 years and ice age terminations oxygen isotope records from chinese caves characterize changes in both the asian monsoon and global climate here using our new speleothem data we extend the chinese record to cover the full uranium thorium dating range that is the past 640 000 years the record s length and temporal precision allow us to test the idea that insolation changes caused by the earth s precession drove the terminations of each of the last seven ice ages as well as the millennia long intervals of reduced monsoon rainfall associated with each of the terminations on the basis of our record s timing the terminations are separated by four or five precession cycles supporting the idea that the 100 000 year ice age cycle is an average of discrete numbers of precession cycles furthermore the suborbital component of monsoon rainfall variability exhibits power in both the precession and obliquity bands and is nearly in anti phase with summer boreal insolation these observations indicate that insolation in part sets the pace of the occurrence of millennial scale events including those associated with terminations and unfinished terminations records of the asian monsoon have been extended to 640 000 years ago and confirm both that the 100 000 year ice age cycle results from integral numbers of precessional cycles and that insolation influences the pacing of major millennial scale climate events prior records of the asian monsoon have revealed cyclic variations over hundreds of thousands of years probably driven by variations in insolation caused by the precession of earth s orbit hai cheng and colleagues now provide a speleothem record from chinese cave samples that extends earlier records to 640 000 years ago close to the maximum age possible with uranium thorium dating this spectacular record confirms that the characteristic 100 000 year ice age cycle corresponds to an integral number four or five of precession cycles and that insolation influences millennial scale variations in monsoon strength

evidence for recent volcanism on mars from crater counts impact craters help characterize the age of a planetary surface because they accumulate with time they also provide useful constraints on the importance of surface erosion as such processes will preferentially remove the smaller craters earlier studies of martian crater populations revealed that erosion and dust deposition are important processes on mars they disagreed however on the age of the youngest volcanism these earlier studies were limited by image resolution to craters larger than a few hundred metres in diameter here we report an analysis using new images obtained by the mars global surveyor spacecraft of crater populations that extend the size distribution down to about 16 m our results indicate a wide range of surface ages with one region lava flows within the arsia mons caldera that we estimate to be no older than 40 100 million years we suggest that volcanism is a continuing process on mars

orbital controls on the el nino southern oscillation and the tropical climate the global synchroneity of glacial interglacial events is one of the major problems in understanding the link between milankovitch forcing and the climate of the late quaternary in this study we isolate a part of the climate system the tropical pacific and test its sensitivity to changes in solar forcing associated with changes in the earth s orbital parameters we use a simplified coupled ocean atmosphere model that is run for the past 150 000 years and forced with milankovitch changes in the solar insolation this system responds primarily to the precessional cycle in solar forcing and is capable of generating a mean response to the changes in the seasonal distribution of solar radiation even while the annual mean insolation is roughly constant the mean response to the precessional forcing is due to an interaction between an altered seasonal cycle and the el nifio southern oscillation enso changes in the enso behavior result in a mean tropical climate change the hypothesis is advanced that such a change in the tropical climate can generate a globally synchronous climate response to milankovitch forcing

temperature and leaf wax δ2h records demonstrate seasonal and regional controls on asian monsoon proxies orbital scale precipitation isotope records can elucidate climate forcing mechanisms and provide benchmarks for climate model validation the ability to differentiate the influence of temperature seasonality and vapor transport history on precipitation isotope proxies is critical to both objectives we present a 300 k y leaf wax hydrogen isotope record from the south china sea with the effects of local condensation temperature removed 2 h wax t 2 h wax t reflects annually integrated precipitation 2 h in the pearl river catchment of southeast china depleted 2 h wax t lags minimum precession p min by 1 0 0 7 k y reflecting the influence of maximum summer insolation and minimum winter insolation with a minor influence of global ice volume which lags p min by 3 3 0 4 k y in contrast annually integrated cave 18 o minima in central china 1000 km north of our site lag p min by 2 7 0 3 k y in phase with ice volume minima this phase indicates that precipitation 18 o in central china is more strongly influenced by ice volume forcing at the precession band with a lesser influence of northern hemisphere insolation our new 2 h wax t data demonstrate that precipitation isotopes in asia have strong regional variability interpreting water isotope records within the context of regionally varying temperature seasonality and sensitivity to changing glacial boundary conditions is imperative to understanding asian hydroclimatic change

changes in the advection of antarctic intermediate water to the northern chilean coast during the last 970 kyr 1 the antarctic intermediate water aaiw is a key player in global scale oceanic overturning processes and an important conduit for heat fresh water and carbon transport the aaiw past variability is poorly understood mainly due to the lack of sedimentary archives at intermediate water depths we present records of benthic stable isotopes from sediments retrieved with the seafloor drill rig marum mebo at 956 m water depth off northern chile geob15016 27 29 48 s 71 07 58 w that extend back to 970 ka the sediments at this site are presently deposited at the boundary between aaiw and pacific deep water pdw for previous peak interglacials our results reveal similar benthic 13c values at site geob15016 and of a newly generated stack of benthic 13c from various deep pacific cores representing the average pdw this suggests unlike today the absence of aaiw at the site and the presence of nearly pure pdw in contrast more positive 13c values at site geob15016 compared to the stack imply a considerable aaiw contribution during cold phases of interglacials and especially during glacials besides we used three short sediment cores to reconstruct benthic 13c values from the aaiw core during the last glacial and found a 13c signature similar to today s assuming that this was the case also for the past 970 kyr we demonstrate that sea level changes and latitudinal migrations of the aaiw formation site can only account for about 50 of the full range of past 13c increases at site geob15016 during cold periods other processes that could explain the remaining of the positive 13c anomalies are increases in glacial aaiw production and or deeper convection of the aaiw with respect to preceding interglacials

temporal and spatial patterns of sediment deposition in the northern south china sea over the last 50 000 years abstract sediment depositional patterns along the upper continental slope of the northern south china sea scs have been studied using two sediment cores geob16601 6 20 09 07 n 116 14 38 e 1012 m water depth and geob16602 4 18 57 12 n 113 42 64 e 951 m water depth recovered during rv sonne cruise so 221 invers sediment cores were analyzed for bulk sediment element composition by x ray fluorescence xrf core scanning and clay mineral assemblage by x ray diffraction xrd the bulk sediment element and the clay mineral compositions of the two cores suggest similar depositional patterns between 50 kyr bp and 29 kyr bp and 14 kyr bp to present but a clear difference in depositional patterns during the last glacial and deglacial 29 14 kyr bp when sea level was below 90 m between 29 14 kyr bp a higher kaolinite percentage in core geob16602 4 in comparison to core geob16601 6 is interpreted to reflect a higher contribution of clay supplied by the pearl river to core site geob16602 4 in contrast core geob16601 6 received less pearl river supplied clayey material during the same period when the sea level was below 90 m during the last glacial lowstand the detrital fine grained materials supplied by the pearl river were mostly transported by coastal currents to the southwest resulting in a higher contribution of pearl river discharged material at site geob16602 4 than at site geob16601 6 we suggest that sea level induced modifications of the land ocean distribution together with changes in the palaeo physiographic conditions such as the proximity of the palaeo rivers to the individual core sites might be responsible for the different sediment depositional patterns in the study area thus the overriding control of sea level induced changes on the sediment depositional environment might mask climate related changes in sediment depositional pattern in the northern scs

high resolution characterization of the asian monsoon between 146 000 and 99 000 years b p from dongge cave china and global correlation of events surrounding termination ii abstract speleothem samples from hulu eastern china 32 30 n 119 10 e and dongge southern china 25 17 n 108 5 e caves provide a nearly continuous record of the asian monsoon over the last 160 ka wang y j cheng h edwards r l an z s wu j y shen c c dorale j a 2001 a high resolution absolute dated late pleistocene monsoon record from hulu cave china science 294 2345 2348 yuan d cheng h edwards r l dykoski c a kelly m j zhang m qing j lin y wang y wu j dorale j a an z cai y 2004 timing duration and transitions of the last interglacial asian monsoon science 304 575 578 we have obtained higher resolution data in the interval between 99 and 146 ka b p providing a detailed account of 18o variations over most of mis 5 and the latter portion of mis 6 precise 230th dating has replicated the chronology of the samples within error the higher resolution data set confirms the timing of asian monsoon termination ii the midpoint of the negative shift in 18o marking the onset of the last interglacial asian monsoon placing it at 129 0 0 9 ka b p the bulk of this transition 1 7 took place within approximately 70 years with the total range of the transition being 3 the most abrupt portion of the shift in 18o values 1 1 marking the end of the last interglacial asian monsoon occurred in 120 years the midpoint of which is 120 7 1 0 ka b p the dongge cave monsoon 18o record over late mis 6 exhibits a series of sub orbital millennial scale climate shifts that average 1 3 in magnitude and occur on average every 1 8 ky abrupt shifts in 18o of up to 1 also occurred throughout the last interglacial asian monsoon with periods at multi decadal to centennial timescales similar to the amplitude and periodicities of events found by dykoski et al dykoski c a edwards r l cheng h yuan d cai y zhang m lin y an z revenaugh j 2005 a high resolution absolute dated holocene and deglacial asian monsoon record from dongge cave china earth and planetary science letters 233 71 86 during the holocene in the dongge record these shifts cover more than 1 2 of the amplitude of millennial scale and multi centennial scale interstadial events during the last glacial period wang y j cheng h edwards r l an z s wu j y shen c c dorale j a 2001 a high resolution absolute dated late pleistocene monsoon record from hulu cave china science 294 2345 2348 and millennial scale and multi centennial scale interstadial events during the penultimate glacial period in china this study abrupt decadal to millennial scale climate events therefore appear to be a general feature of both glacial and interglacial climate we demonstrate that monsoon intensity correlates well with atmospheric ch4 concentrations over the transition into the bolling allerod the bolling allerod and the younger dryas in addition we correlate an abrupt jump in ch4 concentration with asian monsoon termination ii on the basis of this correlation we conclude that the rise in atmospheric co2 antarctic warming and the gradual portion of the rise in ch4 around termination ii occur within our weak monsoon interval wmi an extended interval of heavy 18o between 135 5 1 0 and 129 0 1 0 ka b p prior to asian monsoon termination ii and northern hemisphere warming antarctic warming over the millennia immediately preceding abrupt northern warming may result from the bipolar seesaw mechanism as such warming albeit to a smaller extent also preceded asian monsoon termination i the bipolar seesaw mechanism may play a critical role in glacial terminations

investigating the long term palaeoclimatic controls on the δd and δ18o of precipitation during the holocene in the indian and east asian monsoonal regions abstract this paper aims to achieve an improved understanding of the long term change trends of precipitation d and 18 o values d p and 18 o p in the asian monsoonal region and their relationship with the corresponding humidity trends during the holocene to do this we first review the observed modern spatial pattern of summer precipitation distribution in the east asian summer monsoon easm region under different easm intensities and the relationship between modern observed 18 o p values and corresponding precipitation amounts on monthly and inter annual timescales in the easm and indian summer monsoon ism regions second we compare holocene lacustrine and marine compound specific hydrogen isotopic records of n alkanes n alkanoic acid d n lacustrine authigenic carbonate and cave stalagmite oxygen isotopic records 18 o c and 18 o s from the asian monsoonal region all of which are closely related to d p and 18 o p variations the results demonstrate that in both the ism and easm regions all of these isotopic records exhibit roughly similar long term characteristics i e they were all more negative during the early holocene and early mid holocene ca 11 6 ka b p b p means before present present 1950 ad and then became more positive towards the late holocene third we compare representative paleo humidity records from the asian monsoonal region the results confirm that in the ism region a humid interval occurred in the early holocene and early mid holocene ca 11 6 ka b p and subsequently the climate became more arid towards the late holocene this indicates an enhanced ism during the early holocene and early mid holocene ca 11 6 ka b p and an ism of decreasing intensity towards the late holocene on a holocene orbital scale both 18 o p and d p appear to be controlled by an amount effect in the ism region consistent with the region s inter annual modern 18 o p data this evidence indicates that both 18 o p and d p paleo records are significantly related to paleo humidity in the ism region in contrast holocene humidity variations in the easm region exhibit clear spatial differences a humid mid holocene interval ca 8 3 ka b p occurred in southern and northern china but an arid interval from ca 7 3 ka b p occurred in central china in the middle reaches of the yangtze river based on precipitation distribution patterns under different easm intensities in the easm region over the past few decades we conclude that easm intensity was enhanced during the mid holocene ca 8 3 ka b p relative to the ism intensity the response of easm intensity to summer insolation was relatively slow in the easm region the relationship between climate and 18 o p and d p is more complex consistent with analyses of regional inter annual modern 18 o p data this evidence demonstrates that both 18 o p and d p paleo records cannot be used directly as paleo humidity i e precipitation amount or easm intensity indicators in the easm region further comparison and analyses demonstrate that the coupled variations in west east equatorial pacific temperature gradients and the west pacific subtropical high wpsh played an important role in determining easm intensity during the holocene

phase transitions in the martian mantle implications for the planet s volcanic history the influences of phase transitions on martian mantle convection and melting in the martian mantle have been studied with an axisymmetric spherical shell model an extended boussinesq model in which viscous and adiabatic heatings are included has been used there are depth dependences in the thermal expansivity and gravity which taken together decrease by a factor of between 2 and 3 across the martian mantle the two destabilizing exothermic phase transitions olivine to spinel and and spinel transitions above the martian core mantle boundary cmb accelerate the mantle flow and result in an amplification and superheating of plumes in mars the additional consideration of the endothermic phase transition spinel to perovskite transition which was only likely present in the early evolution of the planet has little influence on martian mantle convection in this model strong localized viscous heating is generated near the cmb and underneath the lithosphere because here the flow bends over sharply a possible volcanic evolution of mars can be derived from a comparison of the temperature fields with the solidus of anhydrous peridotite if the cooling of the martian mantle is taken into account in the early evolution the mantle was molten to a high degree along the plume axis which possibly resulted in a strong differentiation of the mantle as the planet cooled down the region of melt generation receded to where the maximum of viscous heating occurred at the cmb and immediately underneath the lithosphere upon further cooling the deep mantle melt source region became subsolidus the most recent volcanism on mars was most likely generated at a shallow depth below the lithosphere

venus interpreting the spatial distribution of volcanically modified craters to understand the impact cratering record on venus we investigate two distinct resurfacing styles localized thin flows and large shield volcanoes we statistically analyze the size frequency distribution of volcanically modified craters and using monte carlo simulations their spatial distribution lava flows partially fill most craters darkening their floors in radar images we find that a model featuring localized thin flows occurring throughout geologic time predicts their observed distribution individual flows may be morphologically indistinguishable but combined they cover large provinces recent mantle plumes may drive a small amount of hot spot magmatism that produces the observed clusters of large shield volcanoes and obviously embayed craters ultimately our analysis demonstrates that two styles of volcanism are needed to explain the observed properties of impact craters and that catastrophic resurfacing is not required

a 400 000 year record of vegetational and climatic changes from a volcanic basin leizhou peninsula southern china abstract the tianyang lake in leizhou peninsula is an enclosed crater formed during the early to middle pleistocene over 200 m of diatomaceous mud and clay were deposited in the last 400 000 years providing a continuous middle and late quaternary lacustrine sequence for paleoenvironmental studies the pollen record spans the last four glacial interglacial cycles equivalent to oxygen isotope stages ois 10 to 1 during most of the glacial phases fagaceous monsoon forest was replaced by altitudinal vegetation indicating a regional landscape transformation on the peninsula the montane forest reached down to the lowland by at least 600 m during the ois 6 and 8 in a cool and relatively wet condition with temperature estimated to be more than 4 c lower than present a further lowering of the montane forest belts by about 800 1000 m occurred in the ois 4 2 as implied by the appearance of many temperate elements during the last glacial maximum this mixed forest subsequently gave way to the poaceae grassland a savanna vegetation type favored by drier and cooler climatic conditions this drastic change implies a more significant drop in temperature and precipitation than the previous three glacial periods ois 10 8 and 6 it is thus inferred that the weakening of summer monsoon was more significant towards the end of the late pleistocene particularly during the last glacial maximum lgm

simultaneous measurement of o2 mn fe i and s ii in marine pore waters with a solid state voltammetric microelectrode a solid state au hg voltammetric microelectrode was used to measure simultaneously and with millimeter spatial resolution the vertical distributions of o 2 mn 2 fe 2 hs and i in the pore water of sediments from the canadian continental shelf and slope the electrode was used shipboard to analyze undisturbed sediment cores and in a sediment mesocosm to determine the three dimensional distribution of redox species in the sediment surrounding an actively irrigated worm burrow in cores from emerald basin and cabot strait o 2 disappeared and mn 2 fe 2 and hs appeared in the vertical sequence predicted on the basis of thermodynamics in a core from the scotian slope o 2 disappeared at 14 mm depth but mn 2 was not detected over the 50 mm depth examined with the probe in all three cores i was detected in the pore water below the oxygen penetration depth in none of the cores did the distributions of o 2 and mn 2 overlap the thickness of the layer within which neither o 2 nor mn 24 could be detected ranged from 8 to 40 mm we suggest that nitrate not oxygen is used to oxidize mn 2 the upward directed mn 2 gradients of 3 5 and 10 mol m 4 in the emerald basin and cabot strait sediments respectively drive manganese fluxes that are morc than one order of magnitude lower than the o 2 fluxes which are estimated at 4 5 mmol m 2 d 1 the three dimensional distributions of solutes in the pore water in the sediment surrounding an irrigated worm burrow demonstrate that both the o 2 penetration depth and the depth where mn 2 is first detected are deeper in the vicinity of the worm burrow than away from it this is consistent with the notion that irrigation brings oxygenated water into the worm tube allowing oxygen to diffuse across the burrow wall into the sediment and react with mn 2 and other reduced porewater constituents three dimensional heterogeneity in porewater composition cannot be detected by conventional one dimensional coring and slicing techniques because these latter techniques average the porewater composition in a large volume of sediment they may indicate that the distributions of individual species overlap when in fact they do not

direct correlation of chinese speleothem δ18o and south china sea planktonic δ18o transferring a speleothem chronology to the benthic marine chronology

enso variability reflected in precipitation oxygen isotopes across the asian summer monsoon region abstract oxygen isotope signals 18 o from paleo archives are important proxies for past asian summer monsoon asm climate reconstruction however causes of interannual variation in the 18 o values of modern precipitation across the asm region remain in argument we report interannual 18 o variation in southern tibetan plateau precipitation based on long term observations at lhasa these data together with precipitation 18 o records from five global network of isotopes in precipitation gnip stations and two ice core 18 o records were used to define a regional metric of asm precipitation 18 o asmoi back trajectory analyses for rainy season precipitation events indicate that moisture sources vary little between years with relatively high and low 18 o values a result that is consistent for the south lhasa southeast bangkok and east asm regions hong kong in contrast 18 o values at these three locations are significantly correlated with convection in the estimated source regions and along transport paths these results suggest that upstream convection rather than moisture source change causes interannual variation in asm precipitation 18 o values contrasting values of the asmoi in el nino and la nina years reveal a positive isotope el nino southern oscillation enso response e g high values corresponding to warm phases which we interpret as a response to changes in regional convection we show that the isotope enso response is amplified at high elevation sites and during la nina years these findings should improve interpretations of paleo 18 o data as a proxy for past asm variation and provide new opportunities to use data from this region to study paleo enso activity

deep sea pollen from the south china sea pleistocene indicators of east asian monsoon abstract a high resolution pollen record sampling interval averages 820 years has been obtained from odp site 1144 water depth 2037 m northern south china sea the 504 m sequence in composition length covers the last 1 03 million years according to micropaleontological and isotopic stratigraphy the pollen assemblages are characterized by high proportions of pinus and herb pollen and by their frequent alternations based on these alternations 29 pollen zones have been recognized that are closely correlated to the marine oxygen isotope stages mis 1 29 pinus dominant pollen zones correspond to interglacial periods with lighter 18o values while herb marked ones relate to the heavier 18o stages assigned to glacials judging from the pollen data the exposed northern continental shelf of the south china sea during the glacials was covered by grassland and the extensive northern shelf has formed only since mis 6 ca 150 ka probably as a result of tectonic subsidence tree pollen influx values are indicative of winter monsoon which began to intensify 600 ka ago the summer monsoon variations can be approximated by the fern percentage within the total pollen and spore abundance and the result shows high values in general occurring at interglacials with the maxima at mis 15 5e and 1 the relatively high fern percentage with smaller amplitude in variations before 600 ka might suggest more stable humid conditions before the intensification of winter monsoon

martian plate tectonics the northern lowlands of mars may have been produced by plate tectonics preexisting old thick highland crust was subducted while seafloor spreading produced thin lowland crust during late noachian and early hesperian time in the preferred reconstruction a breakup margin extended north of cimmeria terra between daedalia planum and isidis planitia where the highland lowland transition is relatively simple south dipping subduction occurred beneath arabia terra and east dipping subduction beneath thatsis montes and tempe terra lineations associated with gordii dotsum are attributed to ridge parallel structures while phelegra montes and scandia colles are interpreted as transform parallel structures or ridge fault fault triple junction tracks other than for these few features there is little topographic roughness in the lowlands seafloor spreading if it occurred must have been relatively rapid quantitative estimates of spreading rate are obtained by considering the physics of seafloor spreading in the lower c 0 4 g gravity of mars the absence of vertical scarps from age differences across fracture zones and the smooth axial topography to the first order the height of vertical scarps across fracture zones does not involve gravity crustal thickness at a given potential temperature in the mantle source region scales inversely with gravity thus the velocity of the rough smooth transition for axial topography also scales inversely with gravity plate reorganizations where young crust becomes difficult to subduct are another constraint on spreading age possible plate reorganizations for example the end of spreading through alba patera occur when the ridge axis is far from the trench that is rapid plate motions are inferred to have placed young oceanic crust far from the ridge axis the preferred full spreading rate 900 from the plate pole is 80 mm yr 1 plate tectonics if it occurred dominated the thermal and stress history of the planet a geochemical implication is that the lower gravity of mars allows deeper hydrothermal circulation through cracks and hence more hydration of oceanic crust so that more water is easily subducted than on the earth age and structural relationships from photogeology as well as median wavelength gravity anomalies across the now dead breakup and subduction margins are the data most likely to test and modify hypotheses about mars plate tectonics

east asian monsoon evolution since the late miocene from the south china sea abstract the south china sea scs has become a global focus for paleoclimatic and paleoceanographic studies due to its location which makes it highly sensitive to the east asian monsoon and to pacific ocean changes we present here a refined magnetostratigraphy for the last 6 5 ma for hole u1431d which was recovered during iodp expedition 349 in the central scs magnetic analyses demonstrate that magnetite is the dominant magnetic carrier except for within a greigite bearing layer at 130 5 132 0 meters below sea floor the greigite layer coincides with the timing of intensification of northern hemisphere glaciation and records an oceanographic response to this event environmental magnetic results indicate that the east asian summer and winter monsoon were stable from 6 5 to 5 ma the summer monsoon intensified at 5 ma and then weakened gradually since 3 8 ma in contrast the winter monsoon weakened at 5 ma and has then been enhanced since 3 8 ma and more stable from 0 6 ma spectral analysis indicates that the east asian summer monsoon was driven directly by low latitude insolation changes before 3 2 ma and that it has been affected by both low latitude insolation and high latitude ice volume changes since 3 2 ma

holocene east asian summer monsoon records in northern china and their inconsistency with chinese stalagmite δ18o records abstract monsoon precipitation over china exhibits large spatial differences it has been found that a significantly enhanced east asian summer monsoon easm is characterized by increased rainfall in northern china and by reduced rainfall in southern china and this relationship occurs on different time scales during the holocene this study presents results from a diverse range of proxy paleoclimatic records from northern china where precipitation variability is traditionally considered as an easm proxy our aim is to evaluate the evolution of the easm during the holocene and to compare it with all of the published stalagmite 18 o records from the asian monsoon region in order to explore the potential mechanism s controlling the chinese stalagmite 18 o we found that the intensity of the easm during the holocene recorded by the traditional easm proxy of moisture or precipitation records from northern china is significantly different from the chinese stalagmite 18 o records the easm maximum occurred during the mid holocene challenging the prevailing view of an early holocene easm maximum mainly inferred from stalagmite 18 o records in eastern china in addition all of the well dated holocene stalagmite 18 o records covering a broad geographical region exhibit a remarkably similar trend of variation and are statistically well correlated on different time scales thus indicating a common signal however in contrast with the clear consistency in the 18 o values in all of the cave records both instrumental and paleoclimatic records exhibit significant spatial variations in rainfall on decadal to centennial time scales over eastern china in addition both paleoclimatic records and modeling results suggest that holocene east asian summer monsoon precipitation reached a maximum at different periods in different regions of china thus the stalagmite 18 o records from the easm region should not be regarded as a reliable indicator of the strength of the east asian summer monsoon furthermore modern observations indicate that the moisture for precipitation in the east asian monsoon region is mainly derived from the indian ocean the moisture transport route from the indian ocean to the east asian monsoon region during the holocene is almost identical to that of modern precipitation therefore the strong correlation of 18 o records in the easm and indian summer monsoon ism regions and the similarity of the pattern of latitudinal changes in 18 o values in stalagmites and in modern meteoric precipitation along the water vapor transport route further suggests that the stalagmite 18 o records from the easm region are essentially a signal of the isotopic composition of precipitation which is determined mainly by changes in the 18 o of atmospheric vapor in the upstream source region over the indian ocean and indian monsoon region via the upstream depletion mechanism finally the main trends of the stalagmite 18 o records are strongly correlated with the known evolution of the ism and therefore these records reflect the history of the ism rather than that of the easm our findings support the conclusion that easm variability is mainly controlled by northern hemisphere summer insolation and was strongly modulated by ice volume during the last deglaciation and early holocene which delayed the response of the easm maximum to peak insolation forcing

processes controlling the distribution and cycling of manganese in the oxygen minimum zone of the arabian sea abstract vertical and horizontal distributions of dissolved and particulate manganese were investigated in the arabian sea northwestern indian ocean during the 1995 spring intermonsoon period march april us jgofs process cruise 2 tn045 the region is characterized by an intense basin wide oxygen minimum zone omz that strongly influences the manganese distribution in the omz two distinct dissolved mn d mn maxima were observed at depths of 200 300 m and 600 m respectively the latter peak displayed concentration maxima of approximately 6 nanomolar and was largely confined to stations north of 19 n latitude stations n2 n7 this mid depth maximum was associated with the low oxygen core of the omz o 2 saager et al 1989 geochimica et cosmochimica acta 53 2259 2267 this signal was largely absent at stations along the southern transect likely due to oxidative scavenging of d mn to the suspended particulate phase mid depth particulate mn maxima at some southern stations stations s4 s11 appear to be remnants of this feature the upper d mn maximum 200 300 m depth was more widely distributed than the 600 m peak with d mn concentrations of 3 to as high as 8 nm at most stations east of about 62 e longitude the signal was everywhere correlated with the secondary nitrite maximum at stations within the main denitrification zone delineated by naqvi 1991 nepheloid layers presumably bacterial also were associated with this depth interval particulate mn profiles displayed corresponding concentration minima and low mn al and reactive refractory mn ratios for this same depth interval suggesting reductive dissolution of mn oxyhydroxides these observations imply that in situ microbially mediated processes may be the predominant source of d mn in the upper omz while horizontal advection is more important deeper in the water column

influence of a variable thermal conductivity on the thermochemical evolution of mars 1 the influences of variations in thermal conductivity due to composition temperature and pressure in mantle and crust on the thermochemical evolution of mars have been examined with parameterized convection models we use a temperature and pressure dependent thermal conductivity in the mantle and column averaged values between 1 5 and 4 wm 1k 1 for the crust with 2 wm 1k 1 as the representative value for a basaltic crust the major characteristic of the models is a slower cooling of the upper mantle with a long existing global partial melt zone and a stronger crustal production late in the evolution compared to earlier models which assume a constant thermal conductivity of 4 wm 1k 1 to explain the observed crustal thickness and the early crustal formation on mars the formation of an enriched primordial crust is required recent volcanism can be explained by lateral temperature variations that are caused by thickness variations of the low conducting crust these melt zones which occur underneath thicker than average crust may be the source region for the observed longstanding volcanism in tharsis and elysium instead of plumes rising from the core mantle boundary the evolution of the elastic lithosphere is characterized by a transition at which the elastic strength is first provided by the crust and later also by the upper mantle this finding may explain the estimated elastic lithosphere thickness of less than 16 km in the noachian and more than 100 km in the hesperian and amazonian

the stable hydrogen isotopic composition of sedimentary plant waxes as quantitative proxy for rainfall in the west african sahel various studies have demonstrated that the stable hydrogen isotopic composition d of terrestrial leaf waxes tracks that of precipitation d precip both spatially across climate gradients and over a range of different timescales yet reconstructed estimates of d precip and corresponding rainfall typically remain largely qualitative due mainly to uncertainties in plant ecosystem net fractionation relative humidity and the stability of the amount effect through time here we present d values of the c 31 n alkane d wax from a marine sediment core offshore the northwest nw african sahel covering the past 100 years and overlapping with the instrumental record of rainfall we use this record to investigate whether accurate quantitative estimates of past rainfall can be derived from our d wax time series we infer the composition of vegetation c 3 c 4 within the continental catchment area by analysis of the stable carbon isotopic composition of the same compounds 13 c wax calculated a net ecosystem fractionation factor and corrected the d wax time series accordingly to derive d precip using the present day relationship between d precip and the amount of precipitation in the tropics we derive quantitative estimates of past precipitation amounts our data show that a vegetation composition can be inferred from 13 c wax b the calculated net ecosystem fractionation represents a reasonable estimate and c estimated total amounts of rainfall based on d wax correspond to instrumental records of rainfall our study has important implications for future studies aiming to reconstruct rainfall based on d wax the combined data presented here demonstrate that it is feasible to infer absolute rainfall amounts from sedimentary d wax in tandem with 13 c wax in specific depositional settings

sediment community oxygen consumption in the deep gulf of mexico sediment community oxygen consumption scoc has been measured from the continental shelf out to the sigsbee abyssal plain in the ne gulf of mexico gom scoc rates on the continental shelf were an order of magnitude higher than those on the adjacent continental slope 450 2750 m depth and two orders of magnitude higher than those on the abyssal plain at depths of 3 4 3 65 km oxygen penetration depth into the sediment was inversely correlated with scoc measured within incubation chambers but rates of scoc calculated from either the gradient of the o2 profiles or the total oxygen penetration depth were generally lower than those derived from chamber incubations scoc rates seaward of the continental shelf were lower than at equivalent depths on most continental margins where similar studies have been conducted and this is presumed to be related to the relatively low rates of pelagic production in the gom the scoc however was considerably higher than the input of organic detritus from the surface water plankton estimated from surface water pigment concentrations suggesting that a significant fraction of the organic matter nourishing the deep gom biota is imported laterally down slope from the continental margin

sediment sources and east asian monsoon intensity over the last 450 ky mineralogical and geochemical investigations on south china sea sediments a coupled approach based on clay mineral assemblages and isotopic data sr and nd of sediment from ocean drilling program odp site 1145 has been used to trace the sources of sediment feeding the northern part of the south china sea and to investigate the evolution of east asian monsoon intensity over the last 450 ky clay mineral assemblages are dominated by illite and smectite with lesser abundance of chlorite and kaolinite 87 sr 86 sr and end 0 isotopic data combined with the smectite illite chlorite ratio indicate that the pearl river is the main contributor for detrital material to the northern margin of the scs with variable continental input of volcanic material derived from the erosion of the luzon arc these inputs follow the low latitude solar insolation with a 23 ky periodicity as recorded by a periodic change of the clay mineralogy for the first time this study presents a scs deep sea sediment high resolution record of climatic changes in the last 450 ky showing that smectite illite chlorite variations are mainly related to changes in the east asian summer monsoon intensity because the mineralogical record is independent of other external forcing phenomena such as global glacial interglacial oscillations the smectite illite chlorite ratio has been used here as a proxy to reconstruct past changes of the south east asian summer monsoon intensity d 2005 elsevier b v all rights reserved

manganese uptake during calcite precipitation from seawater conditions leading to the formation of a pseudokutnahorite manganoan magnesian calcite overgrowths were precipitated from artificial seawater at 25 c on pure calcite seeds using a constant disequilibrium technique the composition of the overgrowths and more specifically their mn mg na and sr content was determined as a function of the precipitation rate and mn2 concentration in the parent solution x ray diffraction patterns indicate that the overgrowths produced were one phase multicomponent solid solutions and contained up to 40 mole mnco3 the amount of mn coprecipitated with calcite decreased with increasing precipitation rate thus overgrowths are not in exchange equilibrium with the solutions from which they precipitated a kinetic model is proposed which adequately describes the composition of the overgrowths in terms of the relative precipitation rate of an 8 10 mole magnesian calcite and a pseudokutnahorite from seawater the possible existence of a pseudokutnahorite in marine sediments and its implications are discussed the concentration of mg in the overgrowths decreased with increasing mnco3 content but their mg ca ratio remained nearly constant strontium and na incorporation was strongly dependent on the number of available nonlattices sites

modeling the volcanism on mars the total amount of melt produced in mars during its evolution is estimated by means of a parameterized one dimensional analytic mantle convection model that assumes a stagnant lid and whole mantle convection the fertility of the mantle defined as the potential to create basalt and its variation with time are taken into account the model is composed of core mantle and lithosphere with two boundary layers separating them the contributions to volcanism by pressure release melting prm and by plumes from the core mantle boundary layer are compared and discussed we show that such models tend to produce considerable melting during the early evolution of the planet and that the amount of melting depends strongly on the abundances of radioactive elements although the model s assumptions may not be valid for the early evolution of the planet the model is relevant to the later history which is insensitive to initial conditions we find that prm volcanism should have ceased between 1 and 2 5 byr ago and any recent volcanic activity must have originated in plumes

terrestrial planet evolution in the stagnant lid regime size effects and the formation of self destabilizing crust the ongoing discovery of terrestrial exoplanets accentuates the importance of studying planetary evolution for a wide range of initial conditions we perform thermal evolution simulations for generic terrestrial planets with masses ranging from that of mars to 10m in the stagnant lid regime the most natural mode of convection with strongly temperature dependent viscosity given considerable uncertainty surrounding the dependency of mantle rheology on pressure we choose to focus on the end member case of pressure independent potential viscosity where viscosity does not change with depth along an adiabatic temperature gradient we employ principal component analysis and linear regression to capture the first order systematics of possible evolutionary scenarios from a large number of simulation runs with increased planetary mass crustal thickness and the degree of mantle processing are both predicted to decrease and such size effects can also be derived with simple scaling analyses the likelihood of plate tectonics is quantified using a mantle rheology that takes into account both ductile and brittle deformation mechanisms confirming earlier scaling analyses the effects of lithosphere hydration dominate the effects of planetary mass the possibility of basalt eclogite phase transition in the planetary crust is found to increase with planetary mass and we suggest that massive terrestrial planets may escape the stagnant lid regime through the formation of a self destabilizing dense eclogite layer

water undersaturated mantle plume volcanism on present day mars based on meteorite evidence the present day martian mantle has a combined abundance of up to a few hundred ppm of h2o cl and f which lowers the solidus and enhances the magma production rate adiabatic decompression melting in upwelling mantle plumes is the best explanation for young last 200 myr volcanism on mars we explore water undersaturated mantle plume volcanism using a finite element mantle convection model coupled to a model of hydrous peridotite melting relative to a dry mantle the reduction in solidus temperature due to water increases the magma production rate by a factor of 1 3 1 7 at 50 ppm water and by a factor of 1 9 3 2 at 200 ppm water mantle water also decreases the viscosity and increases the vigor of convection which indirectly increases the magma production rate by thinning the thermal boundary layer and increasing the flow velocity at conditions relevant to mars these indirect effects can cause an order of magnitude increase in the magma production rate using geologic and geophysical observations of the late amazonian magma production rate and geochemical observations of melt fractions in shergottite meteorites present day mars is constrained to have a core mantle boundary temperature of 1750 to 1800 c and a volume averaged thermal rayleigh number of 2 106 to 107 indicating that moderately vigorous mantle convection has persisted to the present day melting occurs at depths of 2 5 6 gpa and is controlled by the rayleigh number at the low pressure end and by the mantle water concentration at high pressure

a high resolution absolute dated holocene and deglacial asian monsoon record from dongge cave china abstract we present a continuous record of the asian monsoon over the last 16 ka from 18o measurements of stalagmite calcite over 900 oxygen isotopic measurements providing information on shifts in monsoon precipitation are combined with a chronology from 45 precise 230th dates 18o and therefore asian monsoon intensity generally follows changes in insolation although changes in 18o are generally accommodated in abrupt shifts in contrast to smoothly varying insolation indicating that threshold effects may be important 18o decreased dramatically 3 at the start of the holocene 11 5 ka and remained low for 6 ka four positive 18o events centered at 11225 97 yr bp 1 05 10880 117 yr bp 1 15 9165 75 yr bp 1 4 and a double event centered at 8260 64 yr bp 1 1 and 8080 74 yr bp 1 0 punctuated this period of high monsoon intensity all four events correlate within error with climate changes in greenland ice cores thus the relationship between the asian monsoon and the north atlantic observed during the glacial period appears to continue into the early holocene in addition three of the four events correlate within error with outburst events from lake agassiz the decline of monsoon intensity in the mid late holocene is characterized by an abrupt positive shift in 18o which occurs at 3550 59 yr bp 1 1 in 100 yr in addition the holocene is punctuated by numerous centennial and multi decadal scale events amplitudes 0 5 to 1 up to half the amplitude of the glacial interstadial events seen in the last glacial period thus holocene centennial and multi decadal scale monsoon variability is significant although not as large as glacial millennial scale variability the monsoon shows a strong connection with northern south american hydrological changes related by changes in itcz position spectral analysis of the 18o record shows significant peaks at solar periodicities of 208 yr and 86 yr suggesting variation is influenced by solar forcing however there are numerous other significant peaks including peaks at el nino frequencies observed for high resolution portions of the record between 8110 and 8250 yr which suggest that changes in oceanic and atmospheric circulation patterns in addition to those forced by solar changes are important in controlling holocene monsoon climate in addition for this high resolution portion we observe a distinctive biennial oscillation of the asian monsoon which has been associated with the tropospheric biennial oscillation tbo

clues to the lithospheric structure of mars from wrinkle ridge sets and localization instability 1 wrinkle ridges are a manifestation of horizontal shortening in planetary lithospheres for which deformation is localized on faults that underlie individual ridges in ridged plains of mars such as solis planum or lunae planum wrinkle ridges are spaced 40 km apart whereas in the martian northern lowlands where ridges are identified only in mars observed laser altimeter mola altimetric data the ridge spacing is at least 80 km we attribute ridge spacing to an instability of the lithosphere under horizontal compression the localization instability which results in periodically spaced faults montesi and zuber 2003a links the difference of ridge spacing in the northern lowlands and in the highland ridged plains to the difference of crustal thickness via the depth of the brittle ductile transition bdt in solis and lunae plana where the crust is 50 to 60 km thick the crust may be ductile at depth limiting faulting to the bdt of crustal rocks in the lowlands the crust is only about 30 km thick and may be brittle throughout thus the depth of faulting may be controlled by the bdt of mantle rocks which is roughly a factor of two deeper than that of crustal rocks the geotherm can be identical in both regions at 12 3 k km 1 although differences of a few k km 1 can be accommodated within this model the heat flux implied by this geotherm is similar to the heat produced by radiogenic decay 3 gyr ago our analysis provides a rheological explanation for the difference in spacing between ridges in the highlands and the lowlands in contrast to the suggestion of head et al 2002 who proposed that alternating lowlands ridges are buried by sediments in addition finite element models that use the lithospheric structure deduced from ridge spacing show that modest gradients of crustal thickness or heat flux across a ridged plains favor the formation of faults dipping toward high elevation areas as may be the case in solis planum golombek et al 2001

the interior structure of mars implications from snc meteorites two end member models of mars present interior structure are presented the first model is optimized to satisfy the geochemical data derived from the snc meteorites in terms of the bulk chondritic ratio fe si 1 71 while the second model is optimized to satisfy the most probable maximum value c 0 366 x m p r p 2 of the polar moment of inertia factor hydrostatic equilibrium and stationary heat transfer are assumed and the basic differential equations for the mechanical and thermal structure are solved numerically together with an isothermal murnaghan birch type equation of state truncated in eulerian strain at forth order we obtain the radial distribution of mass hydrostatic pressure gravity temperature and heat flow density along with the corresponding density stratification viscosity profiles and the global seismic velocity structure of model mars the first model being consistent with the geochemical requirement produces c 0 357 x m p r p 2 whereas the second model commensurate with the geophysical constraint gives fe si 1 35 the calculated central pressure is about 40 gpa in both models and the central temperature is in the 2000 to 2200 k range the model calculations suggest a fe ni fes core a little less than one half of the planetary radius in size surrounded by a silicate mantle subdivided into lower spinel and upper olivine layers and overlain by a 100 to 250 km thick basaltic crust and a surface heatflow density of 25 to 30 mw m 2 in both models the pressure in the mantle is not sufficient for the spinel to perovskite transition to occur the present thermal lithosphere is estimated to be about 500 km thick and to be subdivided into a 300 km thick outermost rheological lithosphere and an underlying thermal boundary layer of mantle convection given the core sulfur content of 14 wt as derived from snc meteorites the martian core is found to be entirely molten implying the nonoperation of a self sustained dynamo due to the absence of sufficiently vigorous convection

holocene changes in biome size and tropical cyclone activity around the northern south china sea abstract the south china sea scs characterized by a large continental shelf is located at the edge of the asian monsoon domain in this study two marine sediment cores from the northern scs nscs continental slope were investigated to construct composite vegetation and precipitation isotopic composition records based on the 13c and d values of plant wax n alkanes throughout the holocene last 11 200 years i e 11 2 ka the composite 13cwax record indicates an overall predominance of c3 vegetation over the last 11 2 ka before 8 ka bp higher 13cwax values are attributed to preferential wax input from grassland and wetland biomes on the exposed continental shelf after the inundation of the shelf by eustatic sea level rise until ca 8 ka bp grassland and wetland biomes suffered a major size reduction and arboreal vegetation became better represented in the 13cwax record the composite temperature corrected dwax t record suggests that moisture source variability drove precipitation isotopic composition changes during the holocene lower dwax t values before 8 3 ka bp are interpreted as a larger moisture contribution by pacific ocean tropical cyclones whereas higher dwax t values after 8 5 ka bp are interpreted as a larger moisture contribution from the indian ocean summer monsoon higher incidence of tropical cyclones in the nscs during the early holocene was related to a temporary westward shift of the western pacific warm pool and enhanced insolation over the northern hemisphere both external and internal forcing mechanisms regulated moisture source changes in east asia during the holocene

tropical ocean temperatures over the past 3 5 million years determining the timing and amplitude of tropical sea surface temperature sst change is an important part of solving the puzzle of the plio pleistocene ice ages alkenone based tropical sst records from the major ocean basins show coherent glacial interglacial temperature changes of 1 to 3 c that align with but slightly lead global changes in ice volume and deep ocean temperature over the past 3 5 million years tropical temperatures became tightly coupled with benthic 18o and orbital forcing after 2 7 million years we interpret the similarity of tropical sst changes in dynamically dissimilar regions to reflect top down forcing through the atmosphere the inception of a strong carbon dioxide greenhouse gas feedback and amplification of orbital forcing at 2 7 million years ago connected the fate of northern hemisphere ice sheets with global ocean temperatures since that time

holocene evolution in weathering and erosion patterns in the pearl river delta sediments in the pearl river delta have the potential to record the weathering response of this river basin to climate change since 9 5 ka most notably weakening of the asian monsoon since the early holocene approximate to 8 ka cores from the pearl river delta show a clear temporal evolution of weathering intensity as measured by k al k rb and clay mineralogy that shows deposition of less weathered sediment at a time of weakening monsoon rainfall in the early mid holocene 6 0 2 5 ka this may reflect an immediate response to a less humid climate or more likely reduced reworking of older deposits from river terraces as the monsoon weakened human settlement of the pearl river basin may have had a major impact on landscape and erosion as a result of the establishment of widespread agriculture after around 2 5 ka weathering intensity sharply increased despite limited change in the monsoon but at a time when anthropogenic pollutants e g cu zn and pb increased and when the flora of the basin changed sr 87 sr 86 covaries with these other proxies but is also partly influenced by the presence of carbonate the sediments in the modern pearl river are even more weathered than the youngest material from the delta cores we infer that the spread of farming into the pearl river basin around 2 7 ka was followed by a widespread reworking of old weathered soils after 2 5 ka and large scale disruption of the river system that was advanced by 2 0 ka

orbital scale timing and mechanisms driving late pleistocene indo asian summer monsoons reinterpreting cave speleothem δ18o 1 southeast china cave 18o often interpreted as a pure east asian summer monsoon proxy lags maximum northern hemisphere summer insolation by 2 9 0 3 kyrs at the precession cycle the arabian sea summer monsoon stack lags by 8 1 kyr consistent with 13 other indian and east asian summer monsoon proxies from marine lake and terrestrial archives this 5 kyr phase difference cannot be attributed to age control inadequacies in the marine chronology it requires reconciliation in the context of proxy interpretation both of these lags are incompatible with a direct response to northern hemisphere summer insolation implicating additional forcing mechanisms analysis of heterodynes in the cave 18o spectrum demonstrates that variance contained in the arabian sea summer monsoon proxies also resides in the cave 18o record this variance is subtracted from the cave 18o record yielding a residual that is highly coherent and in phase with precession minima reflecting the impact of winter temperature change on cave 18o meteorological precipitation under cold conditions thus we argue that the timing of light cave 18o peaks cannot be interpreted as reflecting the timing of strong summer monsoons alone the 2 9 kyr precession band phase lag of cave 18o reflects the combined influence of summer monsoon forcing with a phase lag of 8 kyrs relative to precession minima and winter temperature forcing that is in phase with precession minima this interpretation is consistent with modern seasonality in the amount and isotopic composition of rainfall in southeast china

hydrologic control of carbon cycling and aged carbon discharge in the congo river basin the age of organic material discharged by rivers provides information about its sources and carbon cycling processes within watersheds although elevated ages in fluvially transported organic matter are usually explained by erosion of soils and sedimentary deposits 1 2 it is commonly assumed that mainly young organic material is discharged from flat tropical watersheds due to their extensive plant cover and rapid carbon turnover 3 7 here we present compound specific radiocarbon data of terrigenous organic fractions from a sedimentary archive offshore the congo river in conjunction with molecular markers for methane producing land cover reflecting wetland extent we find that the congo river has been discharging aged organic matter for several thousand years with apparently increasing ages from the mid to the late holocene this suggests that aged organic matter in modern samples is concealed by radiocarbon from atmospheric nuclear weapons testing by comparison to indicators for past rainfall changes we detect a systematic control of organic matter sequestration and release by continental hydrology mediating temporary carbon storage in wetlands as aridification also leads to exposure and rapid remineralization of large amounts of previously stored labile organic matter we infer that this process may cause a profound direct climate feedback that is at present underestimated in carbon cycle assessments

the relationship between martian gravity and topography the relationship between gravity and topography of various regions of mars is used to estimate their effective elastic thicknesses te using direct measurements of line of sight velocity rather than spherical harmonic coefficients estimates of te vary from 70 km for tharsis 29 km for elysium to 14 5 km for the southern hemisphere and show that the thickness of the martian lithosphere increases with age as the radioactive isotopes of k th and u decay a simple parameterised model of the convective thermal history is used to estimate the temperature structure of the lithosphere and shows that the base of the elastic layer has a temperature of 300 50 c or similar to the value for terrestrial continents in both cases the rheology is probably affected by the presence of water the short wavelength behaviour of the gravity field allows the density of the rocks that form the topography to be estimated and gives values of about 3 0 mg m3 for tharsis and elysium this value is substantially greater than that of 2 7 mg m3 obtained for earth and is in agreement with estimates from snc shergottites nahklites chassigny meteorites of 3 3 mg m3 the density of the topography of valles marineris is only 2 35 mg m3 and suggests that ice may be present below the surface in the heavily bombarded southern hemisphere isostatic compensation occurs at wavelengths as short as 700 km which requires the effective compensation depth to be no more than 10 km the gravity field with wavelengths greater than 1500 km may be supported dynamically by a plume rising beneath the tharsis region the difference in temperature between the solidus and the present areotherm is less than 250 c so melt generation can occur in rising plumes

oceanic topography and heatflow indications for a silent discharge of cold rock into the convecting earth the 2 5 km mean relative elevation of mid ocean ridges is arguably consistent with a steady state thickness of 100 km for the oceanic lithosphere here we explore some consequences of this particular value based on seismic models of the uppermost oceanic mantle we infer that no significant heat is added to normal asthenosphere following accretion at spreading centers therefore we adopt the view that kinematic thinning moderates the conductive thickening to yield the steady state thickness of 100 km we devise a method for estimating mean rates of thinning directly from topography age data with no assumptions on the detailed dynamics of delamination we find that delamination delivers a significant fraction 20 of the global downwelling discharge this large non subducting discharge of cold lithospheric material provides an explanation for the most robust features of upper mantle tomography and should be considered in studies of mantle cooling and mixing

timing duration and transitions of the last interglacial asian monsoon thorium 230 ages and oxygen isotope ratios of stalagmites from dongge cave china characterize the asian monsoon and low latitude precipitation over the past 160 000 years numerous abrupt changes in 18o 16o values result from changes in tropical and subtropical precipitation driven by insolation and millennial scale circulation shifts the last interglacial monsoon lasted 9 7 1 1 thousand years beginning with an abrupt less than 200 years drop in 18o 16o values 129 3 0 9 thousand years ago and ending with an abrupt less than 300 years rise in 18o 16o values 119 6 0 6 thousand years ago the start coincides with insolation rise and measures of full interglacial conditions indicating that insolation triggered the final rise to full interglacial conditions

chinese stalagmite δ 18 o controlled by changes in the indian monsoon during a simulated heinrich event carbonate cave deposits in india and china are assumed to record the intensity of monsoon precipitation because the 18 o of the carbonate tracks the isotopic signature of precipitation these records show spatially coherent variability throughout the last ice age and suggest that monsoon strength was altered during the millennial scale climate variations known as dansgaard oeschger events and during the heinrich cooling events here we use a numerical climate model with an embedded oxygen isotope model to assess what caused the shifts in the oxygen isotope signature of precipitation during a climate perturbation designed to mimic a heinrich event our simulations show that a sudden increase in north atlantic sea ice extent during the last glacial period leads to cooling in the northern hemisphere reduced precipitation over the indian basin and weakening of the indian monsoon the precipitation is isotopically heavier over india and the water vapour exported to china is isotopically enriched our model broadly reproduces the enrichment of 18 o over northern india and east asia evident in speleothem records during heinrich events we therefore conclude that changes in the 18 o of cave carbonates associated with heinrich events reflect changes in the intensity of indian rather than east asian monsoon precipitation