a late glacial high resolution site and source temperature record derived from the epica dome c isotope records east antarctica the timing and synchronisation of greenland and antarctic climate events that occurred during the last glacial period are still under debate as is the magnitude of temperature change associated with these events here we present detailed records of local and moisture source temperature changes spanning the period 27 45 kyr bp from water stable isotope measurements deltad and delta 18 o in the recently drilled epica dome c ice core east antarctic plateau using a simple isotopic model site deltat site and source deltat source temperatures are extracted from the initial 50 yr high resolution isotopic records taking into account the changes in seawater isotopic composition the deuterium isotope variability is very similar to the less precise deltad record from the vostok ice core and the site temperature inversion leads to a temperature profile similar to the classical palaeothermometry method due to compensations between source and ocean water corrections the reconstructed deltat site and deltat source profiles show different trends during the glacial the former shows a decreasing trend from the warm al event 38 kyr bp toward the last glacial maximum while the latter shows increasing values from 41 to 28 kyr bp the low frequency deuterium excess fluctuations are strongly influenced by obliquity fluctuations controlling the low to high latitude temperature gradients and show a remarkable similarity with a high resolution southeast atlantic sea surface temperature record a comparison of the temperature profiles site and source and temperature gradient deltat source deltat site with the non sea salt calcium and sodium records suggests a secondary influence of atmospheric transport changes on aerosol variations

sr nd isotope composition and clay mineral assemblages in eolian dust from the central philippine sea over the last 600 kyr implications for the transport mechanism of asian dust dust transport to the tropical subtropical northwestern pacific over the past 600 kyr was investigated using radiogenic isotopes 87sr 86sr and end together with the clay mineral composition of eolian dust preserved in a sediment core obtained from the philippine sea 12 30 n 134 60 e these data revealed the influence of two prevailing dust sources namely the asian deserts and nearby volcanic arcs e g the luzon arc with average contributions of around 70 and 30 respectively from each the clay mineral composition of the core resembled dust from the central asian deserts cads e g the taklimakan desert as in the north central pacific but published aerosol data collected near the study site during winter spring have the mineralogical signature of dust originating from the east asian deserts eads these data indicate that the relative contribution of ead dust increases with the northeasterly surface winds associated with the east asian winter monsoon eawm during winter spring but the prevailing westerlies and trade winds that carry dust from the cads is the dominant transport agent in the overall dust budget of the study site the results of this study contradict the prevailing view that direct dust transport by the eawm winds in spring dominates the annual flux of eolian dust in the northwest pacific

sedimentary pyrite formation an update sedimentary pyrite formation during early diagenesis is a major process for controlling the oxygen level of the atmosphere and the sulfate concentration in seawater over geologic time the amount of pyrite that may form in a sediment is limited by the rates of supply of decomposable organic matter dissolved sulfate and reactive detrital iron minerals organic matter appears to be the major control on pyrite formation in normal non euxinic terrigenous marine sediments where dissolved sulfate and iron minerals are abundant by contrast pyrite formation in non marine freshwater sediments is severely limited by low concentrations of sulfate and this characteristic can be used to distinguish ancient organic rich fresh water shales from marine shales under marine euxinic conditions sufficient h2s is produced that the dominant control on pyrite formation is the availability of reactive iron minerals calculations based on a sulfur isotope model indicate that over phanerozoic time the worldwide average organic carbon to pyrite sulfur ratio of sedimentary rocks has varied considerably high cs ratios during permo carboniferous time can be explained by a shift of major organic deposition from the oceans to the land which resulted in the formation of vast coal swamps at that time low cs ratios compared to today during the early paleozoic can be explained in terms of a greater abundance of euxinic basins combined with deposition of a more reactive type of organic matter in the remaining oxygenated portions of the ocean the latter could have been due to lower oceanic oxygen levels and or a lack of transportation of refractory terrestrial organic matter to the marine environment due to the absence of vascular land plants at that time

bay of bengal exhibits warming trend during the younger dryas implications of amoc a sharp decline in temperature during the younger dryas yd preceding the current warmer holocene is well documented in climate archives from the northern hemisphere high latitudes although the magnitude of yd cooling varied spatially the response of yd cooling was well documented in the atlantic and pacific oceans but not in the indian ocean here we investigate whether the modern remote forcing of tropical indian ocean sea surface temperature sst by northern hemisphere climate changes holds true for events such as the yd our sst reconstruction from the western bay of bengal exhibits an overall warming of 1 8 c during the yd we further compared our data with other existing mg ca based sst records from the northern indian ocean and found no significant negative sst anomalies in both the arabian sea and the bay of bengal compared to pre and post yd suggesting that no apparent cooling occurred during the yd in the northern indian ocean in contrast most part of the yd exhibits positive sst anomalies in the northern indian ocean that coincide with the slowdown of the atlantic meridional overturning circulation during this period

meso cenozoic long term landscape evolution at the southern moroccan passive continental margin tarfaya basin recorded by low temperature thermochronology abstract this paper presents the first regional study of low temperature thermochronology to be undertaken in the tarfaya basin at the southern moroccan passive continental margin the basin is characterised by vast subsidence since mid triassic times whereby up to 12 km of meso to cenozoic sedimentary rocks accumulated the study focused on the post rift vertical movements along a typical passive margin and besides dealt with the timing and maximum temperature reached by potential source rocks of the basin to unravel the t t development thermochronological analyses were performed on 50 outcrop and well samples from meso cenozoic rocks thermochronological data reveal a continuous subsidence phase in the offshore basin from mid triassic to recent times in contrast apatite u th sm he and apatite fission track data as well as thermal modelling point to an inversion of the northeastern onshore basin starting in the palaeogene at 65 55 ma the rock uplift and exhumation period resulted in the erosion of a 1 0 1 4 km thick cretaceous palaeogene sedimentary pile contemporaneously with peak atlas surface uplift in the cenozoic the exhumation stage could be an explanation for the increasing periodic influx of detrital material into the offshore and southern onshore tarfaya basin since palaeocene detrital apatite fission track ages from 92 16 to 237 35 ma of the upper cretaceous neogene succession indicate no heating above 60 c confirming immature to early mature cenomanian to campanian and eocene source rocks in the onshore tarfaya basin

holocene aridification of india 1 spanning a latitudinal range typical for deserts the indian peninsula is fertile instead and sustains over a billion people through monsoonal rains despite the strong link between climate and society our knowledge of the long term monsoon variability is incomplete over the indian subcontinent here we reconstruct the holocene paleoclimate in the core monsoon zone cmz of the indian peninsula using a sediment core recovered offshore from the mouth of godavari river carbon isotopes of sedimentary leaf waxes provide an integrated and regionally extensive record of the flora in the cmz and document a gradual increase in aridity adapted vegetation from 4 000 until 1 700 years ago followed by the persistence of aridity adapted plants after that the oxygen isotopic composition of planktonic foraminiferglobigerinoides ruberdetects unprecedented high salinity events in the bay of bengal over the last 3 000 years and especially after 1 700 years ago which suggest that the cmz aridification intensified in the late holocene through a series of sub millennial dry episodes cultural changes occurred across the indian subcontinent as the climate became more arid after 4 000 years sedentary agriculture took hold in the drying central and south india while the urban harappan civilization collapsed in the already arid indus basin the establishment of a more variable hydroclimate over the last ca 1 700 years may have led to the rapid proliferation of water conservation technology in south india

comparative study of organic matter preservation in immature sediments along the continental margins of peru and oman part i results of petrographical and bulk geochemical data abstract detailed petrographical and bulk geochemical investigations of organic matter om have been performed on sediments deposited below or close to upwelling areas offshore peru odp leg 112 sites 679 681 688 and oman odp leg 117 sites 720 723 724 in order to obtain a quantitative understanding of its accumulation and degradation microscopical as well as nanoscopical investigations reveal that the om in sediments affected by upwelling mechanisms mainly up to 98 consists of unstructured amorphous organic aggregates without any apparent biological structures in sediments which are not or to a lesser extent affected by upwelling site 720 terrestrial om predominates organic carbon toc contents are highly variable and range between 9 8 in sediments deposited below upwelling cells and 0 2 in sediments outside the upwelling zone the toc sulphur ratios of the sediments scatter widely the samples from the deep water locations sites 688 and 720 show c s ratios of normal marine sediments whereas at the other locations no correlation or even a negative correlation between sulphur and toc concentration exists in most of the upwelling influenced sediments om contains a significant amount of sulphur the incorporation of sulphur into the om followed microbial sulphate reduction and occurred in the upper meters of the sedimentary column below om is still present in vast amounts and relatively hydrogen rich but is nevertheless non metabolizable and becomes the limiting factor for bacterial sulphate reduction according to mass balance calculations 90 99 of the om produced in the photic zone was remineralized and 1 3 was consumed by microbial sulphate reduction the aerobic and anaerobic processes have greatly affected degradation and conservation of om

glacial to holocene swings of the australian indonesian monsoon the australian indonesian monsoon is an important component of the climate system in the tropical indo pacific region 1 however its past variability relation with northern and southern high latitude climate and connection to the other asian monsoon systems are poorly understood here we present high resolution records of monsoon controlled austral winter upwelling during the past 22 000 years based on planktic foraminiferal oxygen isotopes and faunal composition in a sedimentary archive collected offshore southern java we show that glacial interglacial variations in the australian indonesian winter monsoon were in phase with the indian summer monsoon system consistent with their modern linkage through cross equatorial surface winds likewise millennial scale variability of upwelling shares similar sign and timing with upwelling variability in the arabian sea on the basis of element composition and grain size distribution as precipitation sensitive proxies in the same archive we infer that austral summer monsoon rainfall was highest during the bolling allerod period and the past 2 500 years our results indicate drier conditions during heinrich stadial 1 due to a southward shift of summer rainfall and a relatively weak hadley cell south of the equator we suggest that the australian indonesian summer and winter monsoon variability were closely linked to summer insolation and abrupt climate changes in the northern hemisphere the seasonality of the global monsoon is of central importance to the global hydrologic cycle and its environmental influence on human societies palaeoclimate reconstructions generally agree that the strengths of the east asian monsoon and the indian monsoon are tightly coupled to the northern hemisphere climate through zonal migrations of the monsoon convection centres also interpreted as intertropical convergence zone itcz migration 26 the mechanism of the australianindone

a record of long and short term environmental and climatic change during oae3 la luna formation late cretaceous santonian early campanian venezuela abstract the la luna formation was deposited under anoxic dysoxic conditions in a tropical epicontinental sea on the northwest south america margin sedimentological micropaleontological and geochemical evidence provides insights into factors that influenced the sedimentation and controlled the accumulation of organic rich deposits at decimeter and meter scales during the youngest of the cretaceous oceanic anoxic events oae the la luna formation consists of an alternation of black marlstones interbedded with black limestones and black marly limestones the benthic foraminifera assemblages indicate sedimentation in the upper neritic to upper bathyal environment these rocks contain large amounts of organic matter it is interpreted that a combination of warm global and rainy climate and the presence of bathymetric barriers caused poor circulation and low rates of water column ventilation during a high sea level in the early santonian leading to the preservation of carbon rich deposits in this region during the late santonian a cooling trend in global climate increased wind strength and upwelling this change probably reduced runoff causing a weakening of the pycnocline and destabilized the stratification in the water column providing a progressive increase in oxygen in the water column and on the sea floor and a decrease in total organic carbon preservation in a shallower basin these changes and the establishment of full mid and deep water exchange in response to the deepening and widening of the equatorial atlantic gateway could have been important mechanisms for ending the epeiric sea anoxia changes through time in the vanadium nickel fraction planktonic and benthic foraminifera assemblages productivity proxy elements and lithological characteristics support this model superimposed on the general trend variations in calcium carbonate and total organic carbon percentages at the scale of tens of centimeters reveal high frequency cyclic variations which apparently correspond to the main frequencies of orbital forcing this cyclicity is interpreted as a primary depositional signal and is the result of orbital controlled fluctuations in terrigenous dilution and variations in oxygen concentration at the base of the water column variations in the intensity of upwelling can be observed but they did not control the cyclicity

climatic evolution of the central equatorial pacific since the last glacial maximum this paper investigates paleoceanographic changes at a central equatorial pacific site 6 40 n 177 28 w since the last glacial maximum using planktic foraminifera assemblages together with the oxygen isotope 18o and mg ca compositions of three species globigerinoides sacculifer pulleniatina obliquiloculata and globorotalia tumida that dwell in the mixed layer upper thermocline and lower thermocline respectively while the mg ca derived temperatures of the mixed layer and lower thermocline varied within a narrow range from 18 ka onward the upper thermocline temperature increased by as much as 3 c during the last deglaciation 18 12 ka with a simultaneous decrease of 18o these changes are best explained by an enhanced mixing of the upper ocean and a reduced habitat depth separation between p obliquiloculata and g sacculifer during the 18 12 ka interval the planktic foraminifera assemblage during the same period resembles modern composition at subtropical central pacific sites that are strongly influenced by the northeasterly trades and north equatorial current nec we suggest that the study site presently under the control of the intertropical convergence zone itcz north equatorial countercurrent had been influenced by the northeasterly trades and nec during the 18 12 ka interval this interpretation is consistent with previous documentation of a more southerly location of the itcz during two northern hemisphere cooling events the heinrich stadial 1 and the younger dryas and implies that the mean annual position of the itcz was located south of the study site by at least 2 of latitude

rapid precipitation changes in the tropical west pacific linked to north atlantic climate forcing during the last deglaciation abstract the cause of rapid hydrological changes in the tropical west pacific during the last deglaciation remains controversial in order to test whether these changes were triggered by abrupt climate change events in the north atlantic ocean variations in precipitation during the last deglaciation 18 10 ka were extracted from proxy records of chemical weathering and terrigenous input in the western philippine sea wps the evolution of chemical weathering and terrigenous input since 27 ka was reconstructed using the chemical index of alteration cia elemental ratios k al toc tn and ti ca 13corg terrigenous fraction abundance and flux data from international marine global change study program images core md06 3054 collected on the upper continental slope of eastern luzon northern philippines sediment deposited during the last glacial maximum lgm shows weathering equal to or slightly greater than holocene sediment in the wps this unusual state of chemical weathering which is inconsistent with lower air temperatures and decreased precipitation in luzon during the lgm may be due to reworking of poorly consolidated sediments on the eastern luzon continental shelf during the lgm sea level lowstand rapid changes in chemical weathering characterized by higher intensity during the heinrich event 1 h1 and younger dryas yd and lower intensity during the bolling allerod b a were linked to rapid variations in precipitation in the wps during the last deglaciation the higher terrigenous inputs during the lgm relative to those of the holocene were controlled by sea level changes rather than precipitation the terrigenous inputs show a long term decline during the last deglaciation punctuated by brief spikes during the h1 and yd related to sea level rises and rapid precipitation changes in the wps respectively the proxy records of chemical weathering and terrigenous input from eastern luzon suggest high rainfall during the h1 and yd events consistent with inferred rainfall patterns based on fe ca records from offshore mindanao rapid precipitation changes in the wps did not coincide with migrations of the intertropical convergence zone itcz but rather were related to state shifts of the el nino southern oscillation enso during the last deglaciation based on proxy records and modeling results we argue that the atlantic meridional overturning circulation amoc controlled rapid precipitation changes in the tropical west pacific through zonal shifts of enso or meridional migration of the itcz during the last deglaciation our findings highlight the dominant role of the north atlantic ocean in the tropical hydrologic cycle during the last deglaciation

what can we learn from x ray fluorescence core scanning data a paleomonsoon case study x ray fluorescence xrf core scanning of marine and lake sediments has been extensively used to study changes in past environmental and climatic processes over a range of timescales the interpretation of xrf derived element ratios in paleoclimatic and paleoceanographic studies primarily considers differences in the relative abundances of particular elements here we present new xrf core scanning data from two long sediment cores in the andaman sea in the northern indian ocean and show that sea level related processes influence terrigenous inputs based proxies such as ti ca fe ca and elemental concentrations of the transition metals e g mn zr rb ratios are mainly a function of changes in median grain size of lithogenic particles and often covary with changes in ca concentrations that reflect changes in biogenic calcium carbonate production this suggests that a common process i e sea level influences both records the interpretation of lighter element data e g si and al based on low xrf counts is complicated as variations in mean grain size and water content result in systematic artifacts and signal intensities not related to the al or si content of the sediments this highlights the need for calibration of xrf core scanning data based on discrete sample analyses and careful examination of sediment properties such as porosity water content for reliably disentangling environmental signals from other physical properties in the case of the andaman sea reliable extraction of a monsoon signal will require accounting for the sea level influence on the xrf data

the influence of the sunda strait opening on paleoenvironmental changes in the eastern indian ocean abstract with sea level rise in the early holocene the warm and low salinity sea water from the java sea was transported into the eastern indian ocean after the opening of the sunda strait however the impact of this process on sediment provenance and paleoproductivity is rarely known in this study we analyzed the grain size sr nd pb isotopic compositions and biogenic elements of core cj01 185 1538 m water depth in the eastern indian ocean off the sunda strait our new results reveal a large volcanic eruption in the west of java at 2 1 ka and the krakatau eruption at 1883 ce on the basis of the pb isotopic compositions 87 sr 86 sr ratios and e nd values we infer that sediments from core cj01 185 were derived primarily from java island there is a distinct change in sr nd pb isotopic compositions of the sediments from the last glacial period to the holocene indicating less radiogenic nd isotopes from the java sea into the eastern indian ocean after the opening of the sunda strait at 10 ka moreover the sedimentation rate increased significantly from 6 5 cm kyr 1 during the last glacial period to 20 cm kyr 1 in the holocene the input of additional terrigenous nutrients from the java sea induced paleoproductivity with higher toc and tn concentrations after the opening of the sunda strait our results thus suggest that the paleoproductivity was mainly influenced by terrigenous materials input in the holocene other than southeast monsoon or upwelling in the last glacial period

coniacian santonian deep ocean anoxia euxinia inferred from molecular and inorganic markers results from the demerara rise odp leg 207 abstract we investigated coniacian to early santonian sediments from odp site 1261 demerara rise using organic inorganic and molecular methods to reconstruct the development of ocean water anoxia euxinia high lycopane n c 31 values of up to 4 5 suggest oxygen depleted conditions in the water column for most of the time lower values 1 across the early to mid coniacian transition probably mark a period of stronger oxygenation in two higher resolution intervals we observe strong enrichment in zn concurrent with an increase in the lycopane n c 31 ratio marking the onset of euxinic bottom waters whereas decreases in lycopane n c 31 values and decreases in ni enrichment characterize the termination of sulfidic conditions photic zone euxinia appears to be restricted to the early coniacian interval as isorenieratene derivatives were exclusively detected in this part of the section the combination of biomarker and inorganic geochemical proxies suggests a general decoupling of surface and mid water oxygenation from deep water oxygenation from the mid coniacian onwards this process might be related to the successive opening of the equatorial atlantic gateway allowing a migration of surface and intermediate water masses before the establishment of a deep water connection

taupo volcanic zone calc alkaline tephras on the peralkaline mayor island volcano new zealand identification and uses as marker horizons mayor island is a peralkaline rhyolitic caldera volcano characterised by numerous sector confined pyroclastic deposits together with lavas forming at least five composite shields correlation of sequences between sectors is difficult because of the scarcity of island wide marker beds however eight distal calc alkaline fall tephras ca 7 3 14c ka to 64 ka from okataina and taupo volcanic centres in the nearby taupo volcanic zone tvz have been identified on the island these foreign tvz tephras provide marker planes to correlate activity in different sectors of mayor island volcano and refine an eruptive chronology at least seventeen pyroclastic eruptions and fourteen lava producing events including multiple shield forming events have occurred in the past ca 64 ka age controls provided by the calc alkaline tephras confirm the extremely local dispersal characteristics of many of the mayor island eruptives and show that kar ages as young as 25 33 ka on obsidians with 4 2 4 4 k2o are reliable

climate variability and ice sheet dynamics during the last three glaciations a composite north atlantic record from dsdp site 609 and iodp site u1308 spans the past 300 000 years and shows that variability within the penultimate glaciation differed substantially from that of the surrounding two glaciations hematite stained grains exhibit similar repetitive down core variations within the marine isotope stage mis 8 and 4 2 intervals but little cyclic variability within the mis 6 section there is also no petrologic evidence in terms of detrital carbonate rich heinrich layers for surging of the laurentide ice sheet through the hudson strait during mis 6 rather very high background concentration of iceberg rafted debris ird indicates near continuous glacial meltwater input that likely increased thermohaline disruption sensitivity to relatively weak forcing events such as expanded sea ice over deepwater formation sites altered sub tropical precipitation patterns and antarctic warming during high orbital precession and low 65 n summer insolation appear related to high abundance of icelandic glass shards and southward sea ice expansion differing european and north american ice sheet configurations perhaps aided by larger variations in eccentricity leading to cooler summers may have contributed to the relative stability of the laurentide ice sheet in the hudson strait region during mis 6

late cretaceous to early quaternary organic sedimentation in the eastern equatorial atlantic abstract reconstructing the long term evolution of organic sedimentation in the eastern equatorial atlantic odp leg 159 provides information about the history of the climate ocean system sediment accumulation and deposition of hydrocarbon prone rocks the recovery of a continuous 1200 m long sequence at odp site 959 covering sediments from albian to the present day about 120 ma makes this position a key location to study these aspects in a tropical oceanic setting new high resolution carbon and pyrolysis records identify three main periods of enhanced organic carbon accumulation in the eastern tropical atlantic i e the late cretaceous the eocene oligocene and the pliocene pleistocene formation of upper cretaceous black shales off west africa was closely related to the tectono sedimentary evolution of the semi isolated deep ivorian basin north of the cote d ivoire ghana transform margin their deposition was confined to certain intervals of the last two cretaceous anoxic events the early turonian oae2 and the coniacian santonian oae3 organic geochemical characteristics of laminated coniacian santonian shales reveal peak organic carbon concentrations of up to 17 and kerogen type i ii organic matter which qualify them as excellent hydrocarbon source rocks similar to those reported from other marginal and deep sea basins a middle to late eocene high productivity period occurred off equatorial west africa porcellanites deposited during that interval show enhanced total organic carbon toc accumulation and a good hydrocarbon potential associated with oil prone kerogen deposition of these toc rich beds was likely related to a reversal in the deep water circulation in the adjacent sierra leone basin accordingly outflow of old deep waters of southern ocean origin from the sierra leone basin into the northern gulf of guinea favored upwelling of nutrient enriched waters and simultaneously enhanced the preservation potential of sedimentary organic matter along the west african continental margin a pronounced cyclicity in the carbon record of oligocene lower miocene diatomite chalk interbeds indicates orbital forcing of paleoceanographic conditions in the eastern equatorial atlantic since the oligocene miocene transition a similar control may date back to the early oligocene but has to be confirmed by further studies latest miocene early pliocene organic carbon deposition was closely linked to the evolution of the african trade winds continental upwelling in the eastern equatorial atlantic ocean chemistry and eustatic sea level fluctuations reduction in carbonate carbon preservation associated with enhanced carbon dissolution is recorded in the uppermost miocene 5 82 5 2 ma section and suggests that the latest miocene carbon record of site 959 documents the influence of corrosive deep waters which formed in response to the messinian salinity crisis furthermore sea level related displacement of higher productive areas towards the west african shelf edge is indicated at 5 65 5 6 5 55 5 2 4 8 ma in view of humid conditions in tropical africa and a strong west african monsoonal system around the miocene pliocene transition the onset of pronounced toc cycles at about 5 6 ma marks the first establishment of upwelling cycles in the northern gulf of guinea an amplification in organic carbon deposition at 3 3 ma and 2 45 ma links organic sedimentation in the tropical eastern equatorial atlantic to the main steps of northern hemisphere glaciation and testifies to the late pliocene transition from humid to arid conditions in central and western african climate aridification of central africa around 2 8 ma is not clearly recorded at site 959 however decreased and highly fluctuating carbonate carbon concentrations are observed from 2 85 ma on that may relate to enhanced terrigenous eolian dilution from africa

petroleum geology of benue trough and southeastern chad basin nigeria cretaceous cyclic sedimentation in the southern benue trough together with unconformities provide a tripartite subdivision of the sedimentary succession into 1 the albian asu river group 2 the late cenomanian to early santonian cross river group new name comprising the marine nkalagu formation new name and interfingering marginal marine sandstones and 3 the post santonian coal measures sequence most of the albian to eocene marine shales in the benue trough and the turonian shales in the southern chad basin contain well over 0 5 total organic carbon with values of up to 7 4 in turonian anaerobic shales based on the high content of soluble organic matter thermal maturity and the predominantly terrigenous character of the late cretaceous shales mostly natural gas was probably generated in both basins the late santonian folding and uplift would have disrupted petroleum reservoirs also crude oil accumulations which were not dissipated by tectonism would be relocated at relatively shallow depths and hence become accessible to invading meteoric waters

holocene tropical western indian ocean sea surface temperatures in covariation with climatic changes in the indonesian region the sea surface temperature sst of the tropical indian ocean is a major component of global climate teleconnections while the holocene sst history is documented for regions affected by the indian and arabian monsoons data from the near equatorial western indian ocean are sparse reconstructing past zonal and meridional sst gradients requires additional information on past temperatures from the western boundary current region we present a unique record of holocene sst and thermocline depth variations in the tropical western indian ocean as documented in foraminiferal mg ca ratios and 18o from a sediment core off northern tanzania for mg ca and thermocline 18o most variance is concentrated in the centennial to bicentennial periodicity band on the millennial time scale an early to mid holocene 7 8 5 6 ka warm phase is followed by a temperature drop by up to 2 c leading to a mid holocene cool interval 5 6 4 2 ka the shift is accompanied by an initial reduction in the difference between surface and thermocline foraminiferal 18o consistent with the thickening of the mixed layer and suggestions of a strengthened walker circulation however we cannot confirm the expected enhanced zonal sst gradient as the cooling of similar magnitude had previously been found in ssts from the upwelling region off sumatra and in flores air temperatures the sst pattern probably reflects the tropical indian ocean expression of a large scale climate anomaly rather than a positive indian ocean dipole like mean state

petroleum source rocks of the tarfaya basin and adjacent areas morocco abstract this work characterizes the source rock potential of the tarfaya basin and enabled us to reconstruct its geochemical history outcrop samples covering different stratigraphic intervals plus the northwestern part of the zag tindouf basin bas draa area were analyzed for total organic carbon corg and total inorganic carbon contents and total sulfur content rock eval analysis and vitrinite reflectance measurements were performed on 56 samples chosen on the basis corg content a set of 45 samples were extracted and non aromatic hydrocarbons were analyzed by way of gas chromatography flame ionization detection gc fid and gc mass spectrometry gc ms non isothermal open system pyrolysis at different heating rates was applied to obtain kinetic parameters for modelling petroleum generation from four different source rocks high quality petroleum source rocks with high corg content and hydrogen index hi values were found for samples of eocene coniacian turonian and cenomanian age most samples were carbonate rich and organic sulfur values were high to moderate various maturity parameters indicated immature or possibly early mature organic matter based on organic geochemical and petrological data the organic matter is of marine aquatic origin cenomanian or a mixture of aquatic and terrigenous material eocene the early cretaceous interval did not contain high quality source rocks but indications of petroleum impregnation were found

upwelling variability off southern indonesia over the past two millennia modern variability in upwelling off southern indonesia is strongly controlled by the australian indonesian monsoon and the el nino southern oscillation but multidecadal to centennial scale variations are less clear we present high resolution records of upper water column temperature thermal gradient and relative abundances of mixed layer and thermocline dwelling planktonic foraminiferal species off southern indonesia for the past two millennia that we use as proxies for upwelling variability we find that upwelling was generally strong during the little ice age lia and weak during the medieval warm period mwp and the roman warm period rwp upwelling is significantly anticorrelated to east asian summer monsoonal rainfall and the zonal equatorial pacific temperature gradient we suggest that changes in the background state of the tropical pacific may have substantially contributed to the centennial scale upwelling trends observed in our records our results implicate the prevalence of an el nino like mean state during the lia and a la nina like mean state during the mwp and the rwp

geochemical and petrographic characterization of campanian lower maastrichtian calcareous petroleum source rocks of hasbayya south lebanon abstract santonian paleocene marls and fine grained carbonates have been sampled in hasbayya locality south lebanon in order to evaluate their organic matter om content petroleum source rock potential and assess their depositional environment methods included total organic carbon toc total inorganic carbon tic total sulphur ts rock eval pyrolysis organic and inorganic petrography x ray fluorescence xrf gas chromatography mass spectrometry gc ms and curie point pyrolysis gas chromatography mass spectrometry cp py gc ms toc rock eval and vitrinite reflectance vrr results reveal excellent immature petroleum source rocks within the campanian lower maastrichtian interval with toc up to 11 6 wt hydrogen index hi up to 872 mg gtoc tmax up to 433 c and vrr average of 0 36 biomarker ratios and maceral analysis suggest a marine depositional environment with a dominance of algal as well as submicroscopic om original sediment composition and redox sensitive geochemical parameters suggest deposition of the om rich intervals under an oxygen minimum zone omz that was emplaced and controlled by primary productivity and nutrient supply pyrolysate composition shows an important content of organic sulphur compounds thiophenes increasing with toc and thus indicating the presence of type ii and type iis kerogen in the analysed sample set which is consistent with the presence of immature solid bitumen in the hasbayya region the data produced in this study coupled with regional correlations allow us to construct a conceptual depositional model for the upper cretaceous om rich rocks of the eastern mediterranean suggesting deposition under a productivity belt localized along the inner and outer shelf leading to a decrease in source rock quality and a shift in kerogen type toward the deeper parts of the levant basin

stable isotope composition of cave guano from eastern borneo reveals tropical environments over the past 15 000 cal yr bp abstract insular southeast asia is a key driver for global atmospheric and oceanic circulation is a hotspot for biodiversity and conservation and is likely to have played a unique and important role in early human dispersals despite this partially due to its vast size and remote tropical location very few continuous palaeoenvironmental records exist especially in eastern borneo therefore we investigated 13 c and 15 n values and geochemistry of two cave guano deposits to reconstruct palaeoenvironments in eastern borneo firstly a profile was recovered from gomantong caves sabah reflecting a continuous deposit over 15 cal kyr bp secondly a profile was recovered from bau bau cave east kalimantan that ranged from 15 5 cal kyr bp the geochemical signature of each deposit confirmed the material to be ancient guano 13 c values revealed that a continuous dense rainforest persisted over at least the last 15 cal kyr bp around the gomantong site that was relatively insensitive to regional climate change by contrast 13 c values at bau bau indicate that although rainforest remained dominant in the record a significant drying occurred between 7 7 and 6 3 cal kyr bp with up to 25 grasses present although most regional models suggest that sea level rise and increased holocene insolation led to an increase in monsoonal moisture we find some evidence of more regional variability and that a reduction in monsoonal precipitation could have occurred however we cannot discount the implementation of an anthropogenic fire regime that opened the canopy allowing more grasses to occur

evolution patterns of radiolaria and organic matter variations a new approach to identify sea level changes in mid cretaceous pelagic environments the relation between sea level changes plankton productivity and evolution as well as the occurrence of anoxic sediments provides an interesting avenue of paleooceanographic research in this context we examined mid cretaceous radiolarian faunas carbonate isotopic and organic matter type data of deep sea drilling project and ocean drilling program cores from the north atlantic and samples from outcrops of the western tethys from central and northern italy former studies indicate that an expansion of the oxygen minimum zone caused plankton extinctions at the cenomanian turonian boundary an expanded oxygen minimum zone would destroy deeper habitats of planktic foraminifera causing the extinction of deeper dwelling forms although this model is well established for the cenomanian turonian boundary not much is known about the causes of extinctions and radiations during the entire mid cretaceous aptian turonian we demonstrate that the dimension of the oxygen minimum zone which depends on the relative sea level and the corresponding nutrient supply causes the complex pattern of evolution and radiation of planktic protozoa and the sedimentation of black shales in the mid cretaceous this new depositional model allows correlation of micropaleontologic data and different types of black shales in the pelagic realm within a sequence stratigraphic framework

origins and accumulation of organic matter in expanded albian to santonian black shale sequences on the demerara rise south american margin ocean drilling program leg 207 recovered thick sequences of albian to santonian organic carbon rich claystones at five drill sites on the demerara rise in the western equatorial atlantic ocean dark colored finely laminated cenomanian santonian black shale sequences contain between 2 and 15 organic carbon and encompass oceanic anoxic events 2 and 3 high rock eval hydrogen indices signify that the bulk of the organic matter in these sequences is marine in origin however d 13 corg values lie mostly between 30 and 27 and toc tn ratios range from 15 to 42 which both mimic the source signatures of modern c3 land plants the contradictions in organic matter source indicators provide important implications about the depositional conditions leading to the black shale accumulations the low d 13 corg values which are actually common in mid cretaceous marine organic matter are consequences of the greenhouse climate prevailing at that time and an associated accelerated hydrologic cycle the elevated c n ratios which are also typical of black shales indicate depressed organic matter degradation associated with low oxygen conditions in the water column that favored preservation of carbon rich forms of marine organic matter over nitrogen rich components underlying the laminated cenomanian santonian sequences are homogeneous dark colored lower to middle albian siltstones that contain between 0 2 and 9 organic carbon the organic matter in these rocks is mostly marine in origin but it occasionally

significance of coniferous rain forests and related organic matter in generating commercial quantities of oil gippsland basin australia contrary to the conventional belief that humic coal generates primarily gas 3 billion bbl of recoverable oil has been discovered in the humic coaly succession of the fluviodeltaic latrobe group upper cretaceous tertiary that serves as both the reservoir and the source for hydrocarbons in the offshore gippsland basin of southeastern australia evidence for generation of liquid hydrocarbons from the coaly succession includes 1 similarity of n alkane distribution in the oil and in the coal extracts 2 high wax content of oil up to 27 by weight 3 high ratio of pristane phytane in oil 5 6 and 4 dominance of c29 steranes in the oil in the gippsland basin coniferous rain forests dominated by kauri vegetation flourished in a raised bog setting present temperate climate and kauri vegetation of new zealand are considered to be the modern analog to the gippsland basin the coniferous vegetation provided large quantities of hydrogen rich exinite macerals such as cutinite and resinite with potential to generate oil high rainfall raised ground water level low oxygen high acidity and low nutrient conditions of a raised bog setting were suitable for preserving organic matter a comparison of gas chromatograms of oils in the gippsland basin with gas chromatograms of oils generated by hydrous pyrolysis in the laboratory from the immature source rocks suggests that the paraffinic fraction of the oil was derived from coal and the naphthenic fraction was derived chiefly from resin

the origin of monsoons abstract the monsoon is interpreted as an intertropical convergence zone itcz substantially away more than 10 from the equator and the existence of the itcz does not have to rely on land sea contrast land sea contrast can provide a favorable longitudinal location for the itcz but this role can be replaced by sea surface temperature contrast in the longitudinal direction thus the interpretation of the monsoon presented herein differs from the long held fundamental belief that its basic cause is land sea thermal contrast on the continental scale in the sense that the existence of landmass is not considered a necessary condition for monsoons through general circulation model experiments support has been found for this interpretation the asian and australian summer monsoon circulations are largely intact in an experiment in which asia maritime continent and australia are replaced by ocean with sea surface temperature sst taken from that of the surrounding oceans thus in these areas land sea c

guidelines for evaluating petroleum source rock using programmed pyrolysis rock eval pyrolysis is used to rapidly evaluate the petroleum generative potential and thermal maturity of rocks accurate conclusions require programs every 30 60 ft 9 18 m understanding of interpretive pitfalls and supporting data such as visual kerogen vitrinite reflectance and elemental analyses the generative potential of coals is commonly overestimated by pyrolysis and is best determined by elemental analysis and organic petrography most coals show high s2 s3 5 and low hi values 300 mg hc g toc migrated oil and mud additives which alter rock eval data can sometimes be removed by special processing for immature rocks bimodal s2 peaks and pi values over 0 2 indicate contamination pyrolysis downgrades organic poor clay rich rocks which show lower hi and higher tmax values than isolated kerogen because of adsorption of pyrolyzate on the clays tmax values for small s2 peaks 0 2 mg hc g toc are unreliable tmax is affected by maturation organic matter type contamination and the mineral matrix s3 is sensitive to inorganic and adsorbed carbon dioxide and to instrumentation problems acidification of carbonate rich samples and proper maintenance improves s3 measurement constant sample weights 100 mg are recommended below a threshold weight tmax increases by up to 10 c and other parameters decrease organic rich samples which overload the detector can be diluted with carbonate detector linearity is determined by pyrolyzing various weights of an organic rich rock

astronomical timescale and palaeoclimatic implication of stacked 3 6 myr monsoon records from the chinese loess plateau abstract magnetic susceptibility and grain size records from two continuous red clay and loess palaeosol sequences on the chinese loess plateau have been generated to investigate the evolution and variability of the east asian monsoon eam during the late pliocene and pleistocene tuning the grain size records to orbital obliquity and precession yields an improved astronomical timescale for the loess palaeosol sequence 0 2 6 ma and an extended age model for the upper red clay formation 2 6 3 6 ma this timescale indicates older ages for a number of the magnetic polarity boundaries consistent with lock in depth offsets in loess sequences good site to site correlation enables generation of stacked grain size and susceptibility records spanning the last 3 6 myr these records indicate that monsoon evolution since the late pliocene can be subdivided into three phases 0 1 25 1 25 2 72 and 2 72 3 4 ma each phase is characterized by unique amplitude and frequency characteristics for both summer monsoon magnetic susceptibility and winter monsoon grain size spectral analyses of the stacked monsoon proxies indicate that characteristics of both the summer and winter monsoons are dominated mainly by variance in the eccentricity 410 and 100 kyr obliquity 41 kyr and precession 23 and 19 kyr bands over the past 3 4 myr implying a non linear response of the long term eam evolution to orbital and glacial forcing

organic matter preservation and sulfur uptake in sediments from the continental margin off pakistan abstract the bulk and molecular geochemical characteristics of a suite of kerogens isolated from organic matter rich sediments from the pakistan margin has been characterised by elemental analysis rock eval pyrolysis and pyrolysis gas chromatography py gc special attention was given to the geochemistry of alkylthiophenes which are thought to reflect the incorporation of sulfur into organic matter om in the context of early diagenetic sulfate reduction organically bound sulfur comprises up to 60 of total sedimentary sulfur the weight ratios for organic sulfur s org over organic carbon c org varies from 0 01 in some of the recently deposited sediments to 0 11 in older samples the results show that sulfur incorporation into organic matter occurs primarily within the upper few meters of the sediments the amount of sulfur which can be incorporated into the organic matter clearly depends on the quality of om the hydrogen index values hi which characterise the total amount of generated hydrocarbon equivalents of the pyrolysate in mg hc equiv g c org are related to the extent of reworking of organic matter either in the water column or at the sediment water interface or to remineralization processes by sulfate reduction itself which is strongly controlled by the availability of reactive iron high quality organic matter characterised by elevated hi values is capable of sequestering higher amounts of sulfur as expressed by the thiophene content which represent the organically bound sulfur of the pyrolysate in mg g c org as indicated by the ratio of thiophenes versus hi which characterises the proportion of thiophenes in the total pyrolysate sulfurisation of organic matter seems to be terminated at a ratio of 0 01

millennial to centennial scale record of african climate variability and organic carbon accumulation in the coniacian santonian eastern tropical atlantic ocean drilling program site 959 off ivory coast and ghana millennial to centennial scale geochemical records of coniacian to santonian deposits from the deep ivorian basin are used to develop a model for the accumulation of black shales in equatorial regions during the final of the cretaceous oceanic anoxic events oae proxy records from ocean drilling program site 959 document a strong precessional signal in the occurrence of black shales the abundance of quartz and clay mineralogy during oae 3 we hypothesize that this signal reflects changes in atmospheric circulation patterns which in turn caused latitudinal shifts of continental climate belts across western africa furthermore we propose that the periodic deposition of black shales occurred in response to adjustments of oceanic circulation in the deep ivorian basin resulting from climate controlled fluctuations in continental runoff a new high resolution cyclostratigraphic framework allowed us to estimate a rapid change within 1000 yr from dysoxic background to anoxic or euxinic black shale environmental conditions followed by black shale deposition for 10 k y and a gradual return to the initial dysoxic conditions our findings imply a highly dynamic late cretaceous atmosphere ocean system

hydrological and vegetation shifts in the wallacean region of central indonesia since the last glacial maximum abstract precipitation is the most important variable of indonesian climate yet there are substantial uncertainties about past and future hydroclimate dynamics over the region this study explores vegetation and rainfall and associated changes in atmospheric circulation during the past 26 000 years in wallacea a biogeographical area in central indonesia wedged between the sunda and sahul shelves and known for its exceptionally high rainforest biodiversity we use terrestrial plant biomarkers from sediment cores retrieved from mandar bay off west sulawesi to reconstruct changes in wallacean vegetation and climate since the last glacial maximum lgm enriched leaf wax carbon isotope 13cwax values recorded in mandar bay during the lgm together with other regional vegetation records document grassland expansion implying a regionally dry and possibly more seasonal glacial climate depleted leaf wax deuterium isotope dwax values in mandar bay during the lgm and low reconstructed precipitation isotope compositions from nearby sites reveal an intensified austral asian summer monsoon circulation and a southward shift of the mean position of the intertropical convergence zone likely due to strong southern hemisphere summer insolation and the presence of large northern hemisphere ice sheets mandar bay 13cwax was anti correlated with dwax during the lgm and the last deglaciation but was positively correlated during most of the holocene indicating time varying controls on the isotopic composition of rainfall in this region the inundation event of the sunda shelf and in particular the opening of the java sea and karimata strait between 9 4 and 11 1 thousand years ago might have provided new moisture sources for regional convection and or influenced moisture source trajectories providing the trigger for shifts in atmospheric circulation and the controls on precipitation isotope compositions from the lgm to the holocene

mid to late holocene australian indonesian summer monsoon variability abstract the australian indonesian monsoon has a governing influence on the agricultural practices and livelihood in the highly populated islands of indonesia however little is known about the factors that have influenced past monsoon activity in southern indonesia here we present a 6000 years high resolution record of australian indonesian summer monsoon aism rainfall variations based on bulk sediment element analysis in a sediment archive retrieved offshore northwest sumba island indonesia the record suggests lower riverine detrital supply and hence weaker aism rainfall between 6000 yr bp and 3000 yr bp compared to the late holocene we find a distinct shift in terrigenous sediment supply at around 2800 yr bp indicating a reorganization of the aism from a drier mid holocene to a wetter late holocene in southern indonesia the abrupt increase in rainfall at around 2800 yr bp coincides with a grand solar minimum an increase in southern indonesian rainfall in response to a solar minimum is consistent with climate model simulations that provide a possible explanation of the underlying mechanism responsible for the monsoonal shift we conclude that variations in solar activity play a significant role in monsoonal rainfall variability at multi decadal and longer timescales the combined effect of orbital and solar forcing explains important details in the temporal evolution of aism rainfall during the last 6000 years by contrast we find neither evidence for volcanic forcing of aism variability nor for a control by long term variations in the el nino southern oscillation enso

continuous 150 k y monsoon record from lake eyre australia insolation forcing implications and unexpected holocene failure our reconstructed history of lake eyre provides the first continuous continental proxy record of australian monsoon intensity over the past 150 k y this continental record s broad correspondence to the marine isotope record demonstrates that this very large catchment with its hydrology dependent on a planetary scale climate element responds to milankovitch scale climate forcing abrupt transitions from dry phases to wet phases ca 125 and 12 ka coincide with northern hemisphere winter insolation minima rather than southern hemisphere summer insolation maxima indicating that northern hemi sphere insolation exerts a dominant control over the intensity of the australian monsoon stratigraphic and dating uncertainties of other wet phases preclude conclusive correlation to specific insolation signals but within the uncertainties are consistent with northern hemisphere forcing regardless of the hemispheric forcing the low intensity of the early holocene australian monsoon by comparison with the last interglacial and particularly the last high level lacustrine event at 65 60 ka when all forcing elements were modest is an enigma that can be explained by a change in boundary conditions within australia

itcz controls on late cretaceous black shale sedimentation in the tropical atlantic ocean 1 this study presents high resolution organic and inorganic proxy records for coniacian to santonian black shale on the demerara rise odp site 1261 in the western tropical atlantic off south america we integrate these records with approximately time equivalent geochemical data from the eastern tropical atlantic off tropical africa odp site 959 to extract the underlying relationships of intertropical convergence zone itcz dynamics and black shale formation in the tropical cretaceous atlantic at orbital time scales the geochemical records from the demerara rise show repetitive fluctuations in productivity ocean redox conditions and clastic sediment supply consistent with a dynamic paleo upwelling regime off tropical south america upwelling intensity most likely was driven by shifts of the mean annual position of the itcz which connects the large scale precipitation and wind field patterns of the hadley cells upwelling was strongest off south america and burial of oil prone organic matter most pronounced when the itcz was in its southernmost position which maximized the impact of ne trade winds on the inner tropical part of the northern hadley cell geochemical records from the deep ivorian basin equatorial atlantic suggest that source rock formation occurred in phase with regions north of the equator off tropical africa however black shale formation was primarily driven by regional rainfall and nutrient export the results of this study provide a conceptual framework that explains the formation distribution and quality of petroleum source rocks below the tropical component of the hadley cells on orbital time scales

holocene diatom records of wetland development near weipa cape york australia abstract to better understand the response of tropical wetlands to holocene environmental changes two lacustrine diatom records from weipa cape york have been investigated the record from big willum bw01 commenced approx 7 9 calibrated thousand years before present k cal a bp and details stages of initial swamp development a phase of ephemeral conditions between approximately 5 7 and 2 2 k cal a bp and relative wetland stability after 2 2 k cal a bp lithological and to a lesser extent diatom assemblage changes in bw01 appear to be linked to broad scale changes in effective precipitation the record from little willum lw01 commenced around 0 9 k cal a bp and documents initial phases of swamp development until approximately 0 8 k cal a bp with subsequent relative wetland stability the uppermost 10 cm of this record approximately spanning the last 40 years coincide with mining activity in the region only minor changes in the diatom assemblage are recorded for this period implying that the overall character of the swamp probably remained unchanged both sites offer new insights into wetland dynamics in australia s dry tropics and demonstrate that changes in these lacustrine systems were probably driven by shifts in effective precipitation in particular during the late holocene

the late quaternary tectonic biogeochemical and environmental evolution of ferruginous lake towuti indonesia abstract there is a paucity of long and continuous continental records from south east asia suitable to inform on past changes and underlying causes of the region s climate and associated diverse ecosystem evolution during the late quaternary in 2015 the towuti drilling project tdp collected a series of sedimentary drill cores from the tectonic ferruginous and highly biodiverse lake towuti sulawesi one of indonesia s oldest lakes the drill cores contain 1 myr of uninterrupted lacustrine sedimentation to document long term environmental and climatic change in the tropical western pacific the impacts of geological and environmental changes on the biological evolution of aquatic taxa and the geomicrobiology and biogeochemistry of metal rich ultramafic hosted lake sediment here we use lithostratigraphic mineralogical geochemical and geochronological datasets to elucidate lake towuti s tectonic emergence and its biogeochemical responses to climatic and volcanic forcings since lake formation our data document that lake towuti emerged during a phase of accelerated tectonic subsidence from a landscape characterized by active river channels shallow lakes and swamps into a permanent lake at 1 ma the lacustrine sediments feature quasi rhythmic alternations of green organic rich and red sideritic clay beds reflecting changes in lake mixing and biogeochemistry as a response to temperature and hydrological changes driven by orbital scale changes in insolation and continental ice volume through the mid to late pleistocene clay deposition is interrupted by two beds of diatomaceous oozes composed primarily of planktonic diatoms that reflect phases of substantially increased primary productivity the occurrence of these diatomaceous oozes in close association with multiple tephra beds suggests a trophic state change driven by the addition of volcanically sourced p possibly in combination with a lake mixing state that supports recycling of p data on lake age and ontogeny are also in agreement with molecular clock estimates of 0 7 ma 0 18 1 37 ma for the divergence of lake towuti s telmatherinid fishes from a riverine ancestor our data therefore are compatible with an evolutionary model in which lake towuti s endemic fauna is a result of geographic speciation in the malili lakes a set of large lakes in southeast sulawesi driven by physical or chemical dispersal limits imposed by the regional rivers and lakes more detailed chronological constraints and refined climate and environmental proxy datasets are currently in preparation and will help to paint a more detailed history of the region s climate and environmental history in future studies

mid holocene sea level and coral reef demise u th dating of subfossil corals in moreton bay australia it is increasingly apparent that sea level data e g microfossil transfer functions dated coral microatolls and direct observations from satellite and tidal gauges vary temporally and spatially at regional to local scales thus limiting our ability to model future sea level rise for many regions understanding sealevel response at far field locations at regional scales is fundamental for formulating more relevant sea level rise susceptibility models within these regions under future global change projections fossil corals and reefs in particular are valuable tools for reconstructing past sea levels and possible environmental phase shifts beyond the temporal constraints of instrumental records this study used abundant surface geochronological data based on in situ subfossil corals and precise elevation surveys to determine previous sea level in moreton bay eastern australia a far field site a total of 64 u th dates show that relative sea level was at least 1 1 m above modern lowest astronomical tide lat from at least 6600 cal yr bp furthermore a rapid synchronous demise in coral reef growth occurred in moreton bay 5800 cal yr bp coinciding with reported reef hiatus periods in other areas around the indo pacific region evaluating past reef growth patterns and phases allows for a better interpretation of anthropogenic forcing versus natural environmental climatic cycles that effect reef formation and demise at all scales and may allow better prediction of reef response to future global change

compound specific carbon isotope records of vegetation and hydrologic change in central sulawesi indonesia since 53 000 yr bp lake matano 2 29 1 s 121 20 e in central sulawesi the deepest and one of the largest lakes in indonesia provides an excellent opportunity to reconstruct long term hydrological and vegetation changes at the heart of the maritime continent within the tropical western pacific warm pool we measured the carbon isotopic composition of terrestrial leaf waxes 13cwax in new sediment cores from lake matano to understand regional variations in vegetation and their interactions with local and high latitude climate forcings during the past 53 kyr variations in 13cwax record the expansion and contraction of c3 versus c4 vegetation as well as changes in plants carbon and water use efficiency and by inference regional hydroclimate during marine isotope stages 1 and 3 more negative 13cwax values indicate that closed canopy c3 rainforests predominated in sulawesi reflecting a wetter less seasonal climate in contrast more positive 13cwax values record a terrestrial ecosystem with more abundant open canopy vegetation and possible expansion of c4 grasses between 29 and 14 ka bp indicating that during marine isotope stage 2 including the last glacial maximum the climate was more arid likely with increased precipitation seasonality in central sulawesi comparison of our record with other paleovegetation and paleohydrological records from sulawesi and nearby islands suggests coherent long term hydrological changes in central indonesia that appear to be sensitive to high latitude climate across glacial interglacial boundaries however variations in the amplitude of the response of vegetation to these glacial interglacial forcings highlight the importance of regional topographic control on climate and vegetation and suggest an important role for higher elevations in maintaining rainforest refugia during regionally arid time intervals when c4 savannas and grasslands expanded at lower elevations

mesozoic sequence of fuerteventura canary islands witness of early jurassic sea floor spreading in the central atlantic the fuerteventura jurassic sedimentary succession consists of oceanic and clastic deposits the latter derived from the southwestern moroccan continental margin normal mid oceanic ridge basalt n morb flows and breccias are found at the base of the sequence and witness sea floor spreading events in the central atlantic these basalts were extruded in a postrift environment post late pliensbachian we propose a toarcian age for the atlantic oceanic floor in this region on the basis of the presence higher up in the sequence of the bositra buchi filament microfacies aalenian bajocian and of clastic deposits reflecting tectono eustatic events e g late toarcian to mid callovian erosion of the rift shoulder the s 1 sea floor oceanic magnetic anomaly west of fuerteventura is therefore at least toarcian in age the remaining sequence records atlantic tethyan basinal facies e g callovian oxfordian red clays aptian albian black shales alternating with clastic deposits e g kimmeridgian berriasian periplatform calciturbidites and a lower cretaceous deep sea fan system the fuerteventura n morb outcrops represent the only early jurassic oceanic basement described so far in the central atlantic they are covered by a 1600 m nearly continuous sedimentary sequence which extends to upper cretaceous facies

euxinia and primary production in late cretaceous eastern equatorial atlantic surface waters fostered orbitally driven formation of marine black shales 1 oceanic anoxic events oae in the cretaceous represent major perturbations in the global climate and ocean system characterized by widespread deposition of organic carbon in the ocean the causes and effects of these events are poorly constrained mainly because of the lack of high resolution marine records here we report the distribution of molecular markers from a millennial scale record of coniacian santonian black shale oae 3 from ocean drilling program site 959 in the deep ivorian basin in the eastern equatorial atlantic highly branched isoprenoids and alkenone derived organic compounds indicate that diatoms and calcareous nanoplankton were important primary producers changes in redox sensitive trace metal accumulation and biomarkers of green sulfur bacteria provide evidence for extreme variations in redox conditions with intervals of lower photic zone euxinia pze accordingly oxygen in the coniacian santonian tropical atlantic was absent as during the cenomanian turonian boundary oae 2 but over more restricted geographic area and more limited time intervals we hypothesize that pze was a common phenomenon typical in large areas of tropical continental margins these conditions fostered sequestration of atmospheric co2 and thus helped cause the positive excursion in 13c of carbonate documented in higher latitude marine records

abrupt changes in the asian southwest monsoon during the holocene and their links to the north atlantic ocean during the last ice age the indian ocean southwest monsoon exhibited abrupt changes that were closely correlated with millennial scale climate events in the north atlantic region1 2 3 suggesting a mechanistic link in the holocene epoch which had a more stable climate the amplitude of abrupt changes in north atlantic climate was much smaller and it has been unclear whether these changes are related to monsoon variability here we present a continuous record of centennial scale monsoon variability throughout the holocene from rapidly accumulating and minimally bioturbated sediments in the anoxic arabian sea our monsoon proxy record reveals several intervals of weak summer monsoon that coincide with cold periods documented in the north atlantic region4 including the most recent climate changes from the medieval warm period to the little ice age and then to the present we therefore suggest that the link between north atlantic climate and the asian monsoon is a persistent aspect of global climate

dynamics of the australian indonesian monsoon across termination ii implications of molecular biomarker reconstructions from the timor sea abstract molecular biomarker derived proxies in a marine sediment core from the eastern timor sea have been employed to track changes in the australian indonesian monsoon system over the time period from the penultimate glacial to the last interglacial the average chain length of n alkanes originating from terrestrial higher plants reveals an expansion of woody plants during both termination ii and the last interglacial with respect to the penultimate glacial this is consistent with previous reconstructions for the last glacial interglacial cycle indicating that water stress conditions during dry seasons of southern indonesia should have been relieved during interglacials and deglacials relative to glacials however in contrast to an only muted response during heinrich stadial 1 the vegetation composition showed a dramatic and prominent change during heinrich stadial 11 this was probably caused by a much more significant and longer duration iceberg discharge event to the northern north atlantic during heinrich stadial 11 relative to heinrich stadial 1 which exerted a significant influence on the tropical hydrological cycle and monsoon rainfall seasonality in addition marine algae derived biomarkers are used to reconstruct primary productivity variations which are in agreement with previous studies from the same area the precessional cyclicity of paleo productivity variations is possibly induced by changes in the australian indonesian winter monsoon intensity showing a correlation with boreal winter insolation however this phase relationship is in contrast to the inference based on other lines of evidence which suggests strong winter monsoon strength during boreal summer insolation maxima new winter monsoon proxies are therefore required to clarify this discrepancy

distribution of deep sea black shales of cretaceous age in the eastern equatorial atlantic from seismic profiling abstract the presence of thick 200 m carbonaceous shales of cretaceous age in the deep waters of the eastern equatorial atlantic was first revealed by drilling at dsdp sites 367 and 368 near the cape verde islands more recent seismic investigations show that black shales are widely distributed in this region in the gambia basin they are associated with a group of seismic reflectors lying at depths of 400 600 m below the sea floor these can be traced southwards from the drill sites into the sierra leone basin and eastwards beneath the african continental rise to depths at which ambient temperatures fall within the oil generation window in the gambia basin the reflectors continue westwards from the cape verde archipelago before terminating on turonian oceanic basement 92 ma south of the guinea fracture zone near 10 n extension of the same seismic sequence on to younger oceanic crust indicates that deep sea carbonaceous deposits formed close to the present equator as late as the early campanian 80 ma long after a series of oceanic anoxic events in the aptian albian oae1 and over the cenomanian turonian boundary oae2 led to widespread accumulation of black shales this late period of deposition may correspond to the more locally developed oae3 high surface productivity in equatorial upwelling zones during the late cretaceous probably played an important role in delivering large amounts of organic carbon to the sea floor when meridional movement of deep water between the south and north atlantic was restricted by closely spaced east west fracture zones in some areas seismic data show that the black shales level out rather than drape pre existing topography implying significant downslope transport of organic rich material from upwelling cells near the african margin

late cretaceous late turonian coniacian and santonian petroleum source rocks as part of an oae tarfaya basin morocco abstract late turonian coniacian and santonian source rock samples from a recently drilled well tafaya sondage no 2 2010 in the tarfaya basin were analyzed for quantity quality maturity and depositional environment of the organic matter om to our knowledge such a thick sequence of organic matter rich turonian to santonian source rocks was investigated in that great detail for the first time organic geochemical and organic petrological investigations were carried out on a large sample set from the 200 m thick sequence in total 195 core samples were analyzed for total organic carbon corg total inorganic carbon contents and total sulfur ts contents rock eval pyrolysis and vitrinite reflectance measurements were performed on 28 samples chosen on the basis of their corg content non aromatic hydrocarbons were analyzed on selected samples by way of gas chromatography flame ionization detection gc fid and gc mass spectrometry gc ms the organic matter rich carbonates revealed a high source rock potential representing type i kerogen and a good preservation of the organic matter which is mainly of marine phytoplankton origin hi values are high 400 900 mg g corg and in a similar range as those described for more recent upwelling sediments along the continental slope of north africa ts corg ratios as well as pristane over phytane ratios indicate variable oxygen content during sediment deposition all samples are clearly immature with respect to petroleum generation which is supported by maturity parameters such as vitrinite reflectance 0 3 0 4 tmax values 401 423 c production indices s1 s1 s2 0 1 as well as maturity parameters based on ratios of specific steranes and hopanes

north atlantic forcing of millennial scale indo australian monsoon dynamics during the last glacial period recent studies of the last glacial period indo australian summer monsoon iasm have revealed links to both northern and southern hemisphere high latitude climate as well as to regional ocean conditions particular interest has been paid to the monsoon response to heinrich events with variability explained by meridional shifts in positioning of the intertropical convergence zone itcz but this model has not been adequately tested in addition the shorter lived dansgaard oeschger d o events have not been detected beyond d o 1 the bolling allerod in land based records from the indo pacific despite their prominent expression in stalagmites from southern asia raising questions about the sensitivity of the iasm to these events here we present a southern hemisphere stalagmite oxygen isotopic time series from ball gown cave bgc tropical northern australia located on the margins of the modern austral summer itcz that spans 40e31 and 27e8 ka elevated iasm rainfall coincides with heinrich stadials and the younger dryas while decreased rainfall characterizes d o interstadials a response that is antiphased with sites spanning the indo pacific warm pool and with chinese records of the east asian summer monsoon the bgc time series thus reveals a precipitation dipole consistent with a southward northward migration of the itcz during periods of high northern latitude cooling warming as the primary driver of millennial scale iasm variability during the last glacial period our record indicates a strengthening of the iasm after the younger dryas period likely as a result of rising sea level and sea surface temperatures breaking the link with the high latitudes

evolution of middle to late cretaceous oceans a 55 m y record of earth s temperature and carbon cycle a new 55 m y global compilation of benthic foraminifera 13 c and 18 o for the middle to late cretaceous shows that there was widespread formation of bottom waters with temperatures 20 c during the cretaceous greenhouse world these bottom waters filled the silled north atlantic and probably originated as thermocline or intermediate waters in the tropical oceans carbon burial during the cretaceous oceanic anoxic events produced a positive 13 c shift in global carbon reservoirs but this is not particularly large especially by comparison with the remarkable late paleocene carbon maximum the interbasin 13 c gradient was unusually large during the cretaceous hot greenhouse probably because the north atlantic sills prevented the free exchange of waters in the deep basin the hot greenhouse ended when the equatorial atlantic gateway opened sufficiently to flood the deep north atlantic with relatively cool polar waters formed in the southern ocean

monsoon climate of the early holocene climate experiment with the earth s orbital parameters for 9000 years ago values for the precession and obliquity of the earth 9000 years ago indicate that the global average solar radiation for july 9000 years ago was 7 percent greater than at present when the estimated solar radiation values are used in a low resulation climate model the model simulates an intensified continent scale monsoon circulation this result agrees with paleoclimatic evidence from africa arabia and india that monsoon rains were stronger between 10 000 and 5000 years ago than they are today

orbital scale record of the late cenomanian turonian oceanic anoxic event oae 2 in the tarfaya basin morocco high sedimentation rates up to 12 cm kyear of laminated organic carbon rich biogenic limestones in the tarfaya basin provide an unusually high millennial resolution record of the late cenomanian oceanic anoxic event oae 2 the global positive carbon isotope excursion across the cenomanian turonian corresponds to 11 light dark sedimentary cycles we interpret these cycles as a response to orbital obliquity variation and estimate the duration of the complete excursion as 440 kyear or one long eccentricity cycle on this time scale the main increase in delta 13 c values occurred over a short time interval of less than 20 kyear in the late cenomanian and reached a first maximum approximately 15 kyear prior to the bulk mainly coccoliths delta 18 o derived sea surface maximum temperature that occurs coeval to the extinction of rotalipora cushmani organic carbon accumulation rates follow obliquity cycles reaching a maximum approximately 10 kyear after the last occurrence of r cushmani then slowly decreasing during the early turonian thus the maximum temperature and the maximum organic carbon accumulation in the tarfaya basin lagged by at least 15 kyear behind the global carbon isotope shift and a proposed reduction of atmospheric co 2 content the climate change across the cenomanian turonian boundary probably occurred independent of co 2 levels and may have been controlled by different greenhouse gases water vapour and methane and changes in ocean circulation i e opening of the equatorial atlantic gateway

a high resolution record of late quaternary upwelling along the oman margin arabian sea based on planktonic foraminifera planktonic foraminiferal abundances fluxes test sizes and coiling properties are influenced in various ways by the southwest monsoon winds and associated upwelling in the western arabian sea to determine the short term changes in the southwest monsoon we have carried out a high resolution time series analysis of three upwelling indices total flux of planktonic foraminiferal tests and flux and relative abundance of the planktonic foraminiferal species globigerina bulloides from ocean drilling program odp site 723a oman margin western arabian sea spanning the last 19 kyr in addition we have determined the relationships between upwelling intensity and the relative abundance fluxes and shell concentrations of various planktonic foraminiferal species upwelling indices suggest that from 19 to 16 ka 22 to 18 2 cal kyr b p the sw monsoon was relatively strong compared to the period 15 8 to 12 5 ka 17 8 to 13 8 cal kyr b p the intensification of the sw monsoon took place at 12 ka 13 1 cal kyr b p and reached a peak between 10 and 5 ka 10 6 and 4 8 cal kyr b p the high resolution data further demonstrate that the sw monsoon has started weakening from 5 ka 4 8 cal kyr b p and the weakest phase was in place at 3 5 ka 3 cal kyr b p which coincides with evidence of an arid climate in western tibet fluxes and shell concentrations of many of the planktonic foraminiferal species increased between 12 and 5 ka in response to the intensification of the sw monsoon winds after the last glacial period globigerina bulloides shows a fivefold to tenfold increase in flux during this period of intense upwelling the other species whose fluxes are influenced by this upwelling change are in order from strongest to weakest response globigerinita glutinata globigerinoides ruber neogloboquadrina dutertrei globigerinella aequilateralis globigerina falconensis and globigerinoides sacculifer the relative abundances of g bulloides and g ruber increased during intense upwelling whereas the relative abundances of g glutinata n dutertrei g falconensis and g sacculifer did not increase during this period which might be due to differences in the productivity of various species in relation to upwelling change therefore the fluxes and shell concentrations provide better and more reliable information about the changes in the monsoon system in the arabian sea than relative abundance data

oxygen 18 16 variability in greenland snow and ice with 10 3 to 105 year time resolution the 3 km long greenland ice sheet project 2 gisp2 ice core presents a 100 000 year detailed oxygen isotope profile covering almost a full glacial interglacial cycle measuranents of isotopic fluctuations in snow frost and atmospheric water vapor samples collected during summer field seasons up to 20 0 are compatible with the large and abrupt 80 160 changes observed in accumulated tim snow pit 15 80 profiles from the gisp2 summit area however show rapid smoothing of the 180 160 signal near the surface beyond about 2 m depth the smoothedi5180 signal is fairly well preserved and can be interpreted in terms of average local weather conditions and climate the longer climate fluctuations also have regional and often global significance in the older part of the record corresponding to marine isotope stages mis 5a to 5d the effect of orbital climate forcing via the 19 and 23 kyr precession cycles and the 41 kyr obliquity cycle is obvious from the end ofmis 5a at about 75 000 years b p till the end of the glacial at the younger dryas preboreal transition at 11 650 years b p the o180 160 record shows frequent rapid switches between intermediate interstadial and low stadial values fourier spectra of the oscillations that are superimposed on the orbitally induced changes contain a strong periodicity at 1 5 kyr a broad peak at 4 0 kyr and additional shorter periods detailed comparison of the gisp2 180 160 record with the vostok antarctica 15d record pacific ocean foraminiferal 180 160 grande pile france tree pollen and insolation indicates that a counterpart to many of the rapid 180 160 fluctuations of gisp2 can be found in the other records and that the gisp2 isotopic changes clearly are the local expression of climate changes of worldwide extent correlation of events on the independent gisp2 and specmap time scales for the interval 10 000 50 000 years b p shows excellent chronometric agreement except possibly for the event labeled 3 1 the glacial to interglacial transition evidently started simultaneously in the arctic and the antarctic but its development and its expression in greenland isotopes was later suppressed by the influence of meltwater especially from the barents sea ice sheet on deep water formation and ocean circulation meltwaters from different ice sheets bordering the north atlantic also influenced ocean circulation during the bolling allerod interstadial complex and the younger dryas and led to a distinct development of european climate and greenland 180 160 values the holocene interval with long term stable mean isotopic values contains several fluauations with periods from years to millennia dominant is a 6 3 year oscillation with amplitude up to 3 to 4 0 periodicities of 11 and 210 years also found in the solar modulated records of the cosmogenic isotopes 1obe and 14c suggest solar processes as the cause of these cycles depression of180 160 values cooling by volcanic eruptions is observed in stacked gisp215 80 records but the effect is small and not likely to trigger major climate changes

palaeoenvironmental change in tropical australasia over the last 30 000 years a synthesis by the oz intimate group the tropics are the major source of heat and moisture for the australasian region determining the tropics response over time to changes in climate forcing mechanisms such as summer insolation and the effects of relative sea level on exposed continental shelves during the last glacial period is an ongoing process of re evaluation we present a synthesis of climate proxy data from tropical australasia spanning the last 30 000 years that incorporates deep sea core coral speleothem pollen charcoal and terrestrial sedimentary records today seasonal variability is governed largely by the annual migration of the inter tropical convergence zone itcz influencing this region most strongly during the austral summer however the position of the itcz has varied through time towards the end of marine isotope stage mis 3 conditions were far wetter throughout the region becoming drier first in the south universally cooler land and sea surface temperature sst were characteristic of the last glacial maximum with drier conditions than previously although episodic wet periods are noted in the fluvial records of northern australia the deglacial period saw warming first in the coral sea and then the indonesian seas with a pause in this trend around the time of the antarctic cold reversal c 14 5 ka coincident with the flooding of the sunda shelf wetter conditions occurred first in indonesia around 17 ka and northern australia after 14 ka the early holocene saw a peak in marine sst to the northwest and northeast of australia modern vegetation was first established on indonesia then progressively south and eastward to ne australia flores and the atherton tablelands show a dry period around 11 6 ka steadily becoming wetter through the early holocene the mid late holocene was punctuated by millennial scale variability associated with the el nino southern oscillation this is evident in the marine coral speleothem and pollen records of the region

millennial scale trends in west pacific warm pool hydrology since the last glacial maximum models and palaeoclimate data suggest that the tropical pacific climate system plays a key part in the mechanisms underlying orbital scale and abrupt climate change atmospheric convection over the western tropical pacific is a major source of heat and moisture to extratropical regions and may therefore influence the global climate response to a variety of forcing factors the response of tropical pacific convection to changes in global climate boundary conditions abrupt climate changes and radiative forcing remains uncertain however here we present three absolutely dated oxygen isotope records from stalagmites in northern borneo that reflect changes in west pacific warm pool hydrology over the past 27 000 years our results suggest that convection over the western tropical pacific weakened 18 000 20 000 years ago as tropical pacific and antarctic temperatures began to rise during the early stages of deglaciation convective activity as inferred from oxygen isotopes reached a minimum during heinrich event 1 ref 10 when the atlantic meridional overturning circulation was weak pointing to feedbacks between the strength of the overturning circulation and tropical pacific hydrology there is no evidence of the younger dryas event in the stalagmite records however suggesting that different mechanisms operated during these two abrupt deglacial climate events during the holocene epoch convective activity appears to track changes in spring and autumn insolation highlighting the sensitivity of tropical pacific convection to external radiative forcing together these findings demonstrate that the tropical pacific hydrological cycle is sensitive to high latitude climate processes in both hemispheres as well as to external radiative forcing and that it may have a central role in abrupt climate change events

tropical pacific climate at the mid holocene and the last glacial maximum simulated by a coupled ocean atmosphere general circulation model 1 simulations for the mid holocene 6000 years before present 6 ka and the last glacial maximum lgm 21 ka have been performed by a global ocean atmosphere coupled general circulation model gcm after the initial spin up periods both runs were integrated for about 200 years for 6 ka the model shows an enhanced seasonal variation in surface temperature and a northward shift of the african and the indian summer monsoon rain area overall circulation features in the tropics correspond to a strong walker circulation state with negative sea surface temperature sst and precipitation anomalies in the central pacific and positive precipitation anomalies over the indian and australian monsoon regions it is noted that there is about a 0 35 c cooling of the global mean sst in contrast to the 6 ka result the simulated tropical climate anomaly at 21 ka corresponds to a weak walker circulation state the simulated lgm sst decrease is about 2 c over the tropical western pacific it is larger about 5 c over the caribbean sea this sst anomaly is in broad agreement with the observed proxy data interestingly the model simulates a warmer than present sst over the subtropical pacific this may be related to a weaker subtropical anticyclone due to weakened monsoon circulation at the lgm

mid holocene sea surface conditions and riverine influence on the inshore great barrier reef we present measurements of sr ca 18o and spectral luminescence ratios g b from a mid holocene porites sp microatoll recovered from the nearshore great barrier reef gbr these records were used as proxies to reconstruct sea surface temperature sst the 18o of surrounding seawater 18osw and riverine influence respectively and compared with records from a modern porites sp microatoll growing in the same environment strong riverine influence in the mid holocene record is indicated by 1 an increased annual 18osw range in the mid holocene record 2 negative peaks in 18o characteristic of flood events and 3 a higher g b luminescence ratio seasonal cycles in g b suggest that humic acid inputs were elevated for a longer portion of the year during the mid holocene the seasonal cycle of 18osw peaked earlier in the year in the mid holocene record relative to the modern while mean 18osw values from the mid holocene record were similar to modern values these records provide an insight into the oceanographic conditions the nearshore gbr experienced during mid holocene climatic shifts and are consistent with a strong australian indonesian summer monsoon aism system at 4700 cal yr bp

integrated depositional model for the cenomanian turonian organic rich strata in north africa abstract during the late cenomanian early turonian c t oceanic anoxic event oae2 organic rich strata was deposited in rift shelf basins and slopes across north africa and in deep sea basins of the adjacent oceans based on a review of published and unpublished information this paper documents the distribution and organic richness of c t strata across the whole region within a palaeogeographic framework and systematically analyses the conditions and processes which controlled their deposition previously the c t in north africa has been most intensively studied in southern morocco tarfaya and tunisia only little data is availabe for other parts of north africa namely algeria libya and egypt because distribution of c t corg strata there becomes more patchy a general decrease in peak organic richness and black shale thickness occurs from west to east partly as a result of upwelling along the moroccan atlantic coast and the absence of upwelling in the eastern mediterranean area furthermore in the confined central atlantic the oxygen minimum zone omz in many places reached down to the deep sea floor 3 4 km while the lower limit of the omz along the north african tethys was much shallower and underlain by oxic water masses as documented by high resolution biostratigraphic and chemostratigraphic data c t black shale deposition in most areas outside the upwelling zone are restricted to a strong eustatic latest cenomanian transgressive phase triggered by this sea level rise the omz impinged onto the north african continental shelf and the margins of intrashelf basins which mostly formed during the early cretaceous as halfgrabens important units containing c t organic rich strata in the region are the atlantic tarfaya black shales morocco western sahara black shales and phtanites in the moroccan and algerian atlas the bahloul fm in the se constantine basin and in northern and central tunisia the etel fm in the sirte basin the al hilal fm in cyrenaica libya the abu roash fm in the abu gharadig and fayium basins western desert egypt the daliyya fm along the ne sinai palestine isreal coast and the shueib fm in west central jordan

interglacial climates and the atlantic meridional overturning circulation is there an arctic controversy arctic palaeorecords are important to understand the natural range of forcing and feedback mechanisms within the context of past and present climate change in this temperature sensitive region a wide array of methods and archives now provide a robust understanding of the holocene climate evolution by comparison rather little is still known about older interglacials and in particular on the effects of the northward propagation of heat transfer via the atlantic meridional ocean circulation amoc into the arctic terrestrial records from this area often indicate a warmer and moister climate during past interglacials than in the holocene implying a more vigorous amoc activity this is in conflict with marine data although recognized as very prominent interglacials in antarctic ice cores cross latitudinal surface ocean temperature reconstructions show that little of the surface ocean warmth still identified in the northeast atlantic during older interglacial peaks e g mis5e 9 11 was further conveyed into the polar latitudes and that each interglacial developed its own specific palaeoclimate features interactive processes between water mass overturning and the hydrological system of the arctic and how both developed together out of a glacial period with its particular ice sheet configuration and relative sea level history determined the efficiency of an evolving interglacial amoc because of that glacial terminations developed some very specific water mass characteristics which also affected the climate evolution of the ensuing interglacial periods moreover the observed contrasts in the arctic directed meridional ocean heat flux between past interglacials have implications for the palaeoclimatic evaluation of this polar region crucial environmental factors of the arctic climate system such as the highly dynamical interactions between deep water mass flow surface ocean temperature salinity sea ice and atmosphere exert strong feedbacks on interglacial climate regionality that goes well beyond the arctic a sound interpretation of such processes from palaeoarchives requires a good understanding of the applied proxies fossils in particular are often key to the reconstruction of past conditions but the tremendously flexible adaptation strategies of biota sometimes hampers further in depth interpretations especially when considering their palaeoenvironmental meaning in the context of rapid palaeoclimatic changes and long term pleistocene evolution

cenomanian sequence stratigraphy and sea level fluctuations in the tarfaya basin sw morocco we investigated the sequence architecture of two expanded cenomanian successions along a depth transect in the tarfaya basin sw morocco and correlated these successions to published records from northwest europe and india changes in terrigenous material carbonate and organic carbon content carbonate microfacies and foraminiferal biofacies as well as nondepositional and erosional surfaces were used to define depositional sequences and systems tracts we identified two main transgressive cycles in the lower and middle upper cenomanian separated by a major regression at the early middle cenomanian transition sequence boundary ce 3 this regressive interval is characterized by lagoonal low stand deposits indicating an overall sealevel fall of more than 30 m superimposed on the two main transgressive cycles there are 11 third order depositional sequences that correlate to globally recognized sealevel fluctuations and appear to be paced by long eccentricity variations 400 ka period positive carbon isotope excursions in the middle cenomanian 96 0 ma and latest cenomanian 94 0 ma following sealevel lowstands together with planktonic foraminiferal and ammonite datums provide a robust framework for stratigraphic correlation we suggest that the onset of these excursions was triggered by eccentricity minima during periods of low variability in obliquity nodes which probably coincided with glacioeustatic lowstands

the holocene environmental changes in southern indonesia reconstructed from highland caldera lake sediment in bali island diatom pollen geomagnetic and geochemical analyses were carried out on a 3 6 m long sediment core taken from lake buyan a highland caldera lake in central bali island to reconstruct the holocene climate changes in equatorial southern indonesia the core represents 8 thousand years sedimentation of organic diatomaceous lake mud constant inclusion of benthic diatom fossils as main components indicated that suspension and inflow of littoral materials were the main sedimentary process the core contained laminated sediments in two distinct intervals at 6 5 5 0 and 3 6 3 1 cal ky bp and multi proxy records showed generally drier climate in these sections especially at 3 6 3 1 cal ky bp lake bottom waters were more reducing condition in these laminated periods probably due to increased lake productivity by prolonged dry season and wind mixing laminae structures were made up of a layer composed of benthic diatoms and amorphous organic materials and a layer made by only planktonic diatom fossils each of which may represent rainy and dry period deposits although southern indonesia shows clear australian monsoon rainfall seasonality at present counting of layer numbers showed interannual cycles of laminae formation prolonged dry seasons could obscured the rainfall seasonality in these periods but precise depositional patterns were elusive unlaminated sections showed homogeneous sediment mixture of benthic planktonic diatoms and more volume of terrigenous materials indicating wetter climate and seasonality similar to the present time this was supported by the higher share of marsh environment pollens reflecting more stable lake level trends the dry climate from 6 5 cal ky bp was in line with the general perception of stronger enso dynamics from the mid holocene due to weaker than before boreal summer insolation but the sporadic appearances of dry periods imply the influence of regional climate forcings such as temporal migrations of inter tropical convergence zone itcz it was however possible that temporal shifts of large climate mode occurred in equatorial pacific and indian oceans wettest climate was inferred from 3 1 cal ky bp to the present and this might reflect increased importance of austral hemisphere atmospheric convection and subsequent southerly position of itcz in austral summer time

cyclostratigraphy of the upper cretaceous niobrara formation western interior u s a a coniacian santonian orbital timescale abstract the turonian campanian niobrara formation of the western interior basin u s a is characterized by decimeter scale rhythmic alternations of chalk and marl beds and decameter scale oscillations of chalky and marly facies this study applies recent advances in quantitative cyclostratigraphic analysis to high resolution geophysical records in order to test for an orbital signal we studied records of the entire formation 85 m from two wells in colorado 40 17 n 104 38 w 40 14 n 104 41 w the study utilized high resolution time series of borehole resistivity measured from formation microimager tools fmi advanced spectral techniques indicate the presence of eccentricity obliquity and precession periodicities throughout the study interval deviations of bundling ratios in the lower fort hays member from those predicted by simple eccentricity modulation of precession previously reported in the literature are likely due to the influence of obliquity deconvolution and frequency tracking of orbital components were used to reconstruct sedimentation rates for the niobrara formation and thus develop a high resolution orbital timescale which permits calculations of accumulation rates for sedimentary components and the duration of inclusive stages substages and in some cases biozones the niobrara formation in the studied cores appears to be hiatus free and therefore provides a continuous record of rhythmic deposition for astronomical timescale development the relationship between carbonate content and sedimentation rate throughout the niobrara formation indicates that the decameter scale oscillations of chalk and marl are dominantly driven by variations in siliciclastic flux dilution the duration derived from the orbital timescale between the turonian coniacian and coniacian santonian boundaries is 3 40 0 13 myr which is generally consistent with radiometric estimates for the coniacian the orbitally derived duration of the santonian stage is 2 39 0 15 myr which is very similar to estimates based on curve fitting between radiometric dates development of high resolution orbital chronometers provides excellent time resolution in intervals that lack radiometric time control or where control points are widely spaced

evolution of tropical watersheds and continental hydrology during the late cretaceous greenhouse impact on marine carbon burial and possible implications for the future abstract regional climate modelling for the late cretaceous greenhouse and high resolution marine stratigraphic records from both sides of the low latitude atlantic show that tropical south american and african hydrology and watersheds had a strong effect on freshwater transfer into the equatorial atlantic and subsequently the marine carbon record this conclusion is derived from new detailed geochemical records from demerara rise off suriname drilled at ocean drilling program odp site 1261 combined with frequency analyses and climate simulations providing evidence for mainly eccentricity driven changes in carbon burial in the western tropical atlantic shorter orbital frequencies in particular precession clearly dominating black shale cycles off tropical africa odp site 959 are far less dominant at demerara rise despite comparable time resolution of the geochemical records we suggest that these different frequency patterns in carbon burial were related to the regional evolution of cretaceous watersheds and hydrology in tropical south america and africa river discharge deduced from simulations indicates higher and less variable discharge from south america compared to western africa at that time this runoff pattern would have supported more permanent anoxic conditions off south america compared to africa at least indirectly and caused the lack of strong higher frequency geochemical cycles in the western sector of the equatorial atlantic furthermore climate simulations show a general switch of primary runoff from either side of the cretaceous equatorial atlantic every half precession cycle i e every 10 kyr similarities between the developments of cretaceous and holocene hydrology in the tropical atlantic area imply that orbital scale evolution of watersheds is a robust feature through time that is independent from the mean global climate state based upon the comparison of cretaceous and holocene trends in hydrology we infer that future hydrology in the study region may develop in a comparable direction to the one observed in the cretaceous if true this suggests that the modern amazon rain forest could shrink over the next millennium due to a 30 loss of moisture while the congo rain forest in africa is likely to expand in response to a 14 gain in moisture

a high resolution absolute dated late pleistocene monsoon record from hulu cave china oxygen isotope records of five stalagmites from hulu cave near nanjing bear a remarkable resemblance to oxygen isotope records from greenland ice cores suggesting that east asian monsoon intensity changed in concert with greenland temperature between 11 000 and 75 000 years before the present yr b p between 11 000 and 30 000 yr b p the timing of changes in the monsoon as established with 230th dates generally agrees with the timing of temperature changes from the greenland ice sheet project two gisp2 core which supports gisp2 s chronology in this interval our record links north atlantic climate with the meridional transport of heat and moisture from the warmest part of the ocean where the summer east asian monsoon originates

米国 西部内陸 上部白亜系niobrara層のサイクロ層序学 コニアシアン サントニアン軌道時間尺度

sensitivity of the australian monsoon to insolation and vegetation implications for human impact on continental moisture balance general circulation model experiments test the geologically based correlation of high monsoon rainfall over interior australia with northern hemisphere insolation and evaluate the sensitivity of the australian monsoon to ecosystem change our results suggest that northern hemisphere insolation control on the intensity of the siberian high rather than summer insolation over the australian continent determines the strength of the australian monsoon on millennial time scales unlike a classic monsoon regime additional simulations show that the penetration of monsoon moisture into the interior is sensitive to biosphere atmosphere feedbacks linked to vegetation type and soil properties this sensitivity offers a resolution to the observed failure of the australian monsoon to penetrate the interior in the holocene postulated regular burning practiced by early humans may have converted a tree shrub grassland mosaic across the semiarid zone to the modern desert scrub thereby weakening biospheric feedbacks and resulting in long term desertification of the continent

marine carbon burial flux and the carbon isotope record of late cretaceous coniacian santonian oceanic anoxic event iii abstract episodes of widespread distribution of organic rich marine facies within relatively narrow stratigraphic intervals have been interpreted as oceanic anoxic events oaes there are a number of such intervals in the upper cretaceous some of which also exhibit significant positive excursions in carbon isotope records as a result a general model of the relationship between enhanced organic carbon burial and positive c isotope shifts has emerged carbon isotope stratigraphy has therefore developed the dual utility of a chronostratigraphic tool and a means to help identify and define intervals of exceptional organic matter burial and preservation however variations in regional carbon isotope records of globally documented events suggest that the relationship between organic carbon burial flux and magnitude of carbon isotope excursion may not be entirely straightforward for example strata of coniacian santonian age have long been recognized for enhanced organic content in many areas but the designation of oceanic anoxic event iii for this interval has been rather equivocal in the literature mostly due to the weak positive 13 c excursion 0 5 yet in some areas organic carbon accumulation rates for coniacian santonian strata are roughly double that of the older oae ii which is marked by a 2 4 shift in 13 c interestingly the burial flux of carbonate which leads to depletion rather than enrichment of the c isotope signal is also significantly elevated during coniacian santonian time in this study the role of variations in organic carbon and carbonate accumulation rates on carbon isotopic expression are explored through application of data on the composition accumulation rate and areal distribution of end member facies types to the development of a global carbon isotopic mass balance model the results are used to explore the hypothesis that net organic carbon burial during oae iii was not accurately represented in the carbon isotopic record these results have important implications for interpretation of c isotope records related to past perturbations of the global carbon cycle

possible evidence for wet heinrich phases in tropical ne australia the lynch s crater deposit unarguably one of the most significant paleoclimatological discoveries of the last two decades has been that of abrupt climate events dansgaard oeschger cycles and heinrich events most evidence for these events has originated from the high latitude northern hemisphere with few records documenting the response of the low latitude southern hemisphere here we present new data from lynch s crater a unique terrestrial record from ne australia that may show evidence for southward propagations of the intertropical convergence zone itcz during abrupt climate perturbations as a result of alteration of the low latitude air masses proxies for precipitation wetness indicate enhanced rainfall in the region during heinrich events h events 1 3 and the 8 2 ka northern hemisphere cold event a fully coupled atmosphere ocean climate model simulating a 1 sv freshwater influx to the north atlantic ocean produces a scenario which agrees with the climate changes shown by the lynch s crater record the model shows precipitation anomalies that include a southward migration of the itcz and a zonal shift in mid latitude storm tracks over the southern hemisphere equatorial region these data indicate large scale shifts of the austral summer itcz position that is known to control monsoonal precipitation in ne australia this terrestrial record from australia may demonstrate the involvement of the tropical western pacific ocean in itcz migrations during abrupt climate events of the last glacial period defining such past migrations offers insight into the importance and role of the equatorial region in global climate dynamics

organic geochemical characterization of santonian to early campanian organic matter rich marls sondage no 1 cores as related to oae3 from the tarfaya basin morocco abstract in addition to previously analyzed sediments of cenomanian to santonian age in the tarfaya sondage no 2 well this study presents the results of a stratigraphically younger interval of santonian to early campanian age in the adjacent well tarfaya sondage no 1 this interval is part of the oceanic anoxic event 3 oae3 which occurred mainly in the atlantic realm due to known high quality source rocks related to oaes i e cenomanian turonian the investigated sample section was tested for the quality quantity and kind of organic matter om describing also the depositional environment the study was carried out by means of i elemental analysis c org caco 3 ts ii rock eval pyrolysis iii vitrinite reflectance measurements iv gas chromatography flame ionization detection gc fid and v gc mass spectrometry gc ms total content of organic carbon c org values for the hydrogen index hi mainly in the range 500 700 mg g c org and s 2 values 10 40 mg g rock support the assumption of a high petroleum generation potential in these upper cretaceous sediments ts c org ratios as well as pristane phytane ratios indicate variable oxygen contents during sediment deposition representing a typical depositional setting for the late cretaceous and are in good agreement with previously analyzed data in the tarfaya basin phyto and zoo plankton were identified as marine sourced all of the investigated early campanian and santonian samples are immature with some tendencies to early maturation these results are based on vitrinite reflectance 0 3 0 4 vr r t max values 409 425 c production indices pi s 1 s 1 s 2 n alkane ratios i e carbon preference index as the deposition of these sediments is time related to oae3 the depositional environment was characterized by oxygen deficiency or even anoxic bottom water conditions this situation was favored during the cretaceous greenhouse climate by limited oxygen solubility in the then warmer ocean water furthermore local factors related to nutrient supply and primary bioproductivity led to the exceptionally thick upper cretaceous organic matter rich sedimentary sequence of the tarfaya basin

increasing australian indonesian monsoon rainfall linked to early holocene sea level rise the australian indonesian summer monsoon affects rainfall variability across the indo pacific region reconstructions of monsoon strength from stalagmites show that precipitation increased from 11 000 to 7 000 years ago as rising global sea level caused the flooding of the indonesian continental shelf the australian indonesian summer monsoon affects rainfall variability and hence terrestrial productivity in the densely populated tropical indo pacific region it has been proposed that the main control of summer monsoon precipitation on millennial timescales is local insolation1 2 3 but unravelling the mechanisms that have influenced monsoon variability and teleconnections has proven difficult owing to the lack of high resolution records of past monsoon behaviour here we present a precisely dated reconstruction of monsoon rainfall over the past 12 000 years based on oxygen isotope measurements from two stalagmites collected in southeast indonesia we show that the summer monsoon precipitation increased during the younger dryas cooling event when atlantic meridional overturning circulation was relatively weak4 monsoon precipitation intensified even more rapidly from 11 000 to 7 000 years ago when the indonesian continental shelf was flooded by global sea level rise5 6 7 we suggest that the intensification during the younger dryas cooling was caused by enhanced winter monsoon outflow from asia and a related southward migration of the intertropical convergence zone8 however the early holocene intensification of monsoon precipitation was driven by sea level rise which increased the supply of moisture to the indonesian archipelago

orbital scale timing and mechanisms driving late pleistocene indo asian summer monsoons reinterpreting cave speleothem δ18o 1 southeast china cave 18o often interpreted as a pure east asian summer monsoon proxy lags maximum northern hemisphere summer insolation by 2 9 0 3 kyrs at the precession cycle the arabian sea summer monsoon stack lags by 8 1 kyr consistent with 13 other indian and east asian summer monsoon proxies from marine lake and terrestrial archives this 5 kyr phase difference cannot be attributed to age control inadequacies in the marine chronology it requires reconciliation in the context of proxy interpretation both of these lags are incompatible with a direct response to northern hemisphere summer insolation implicating additional forcing mechanisms analysis of heterodynes in the cave 18o spectrum demonstrates that variance contained in the arabian sea summer monsoon proxies also resides in the cave 18o record this variance is subtracted from the cave 18o record yielding a residual that is highly coherent and in phase with precession minima reflecting the impact of winter temperature change on cave 18o meteorological precipitation under cold conditions thus we argue that the timing of light cave 18o peaks cannot be interpreted as reflecting the timing of strong summer monsoons alone the 2 9 kyr precession band phase lag of cave 18o reflects the combined influence of summer monsoon forcing with a phase lag of 8 kyrs relative to precession minima and winter temperature forcing that is in phase with precession minima this interpretation is consistent with modern seasonality in the amount and isotopic composition of rainfall in southeast china

multi proxy evidence for human induced deforestation and cultivation from a late holocene stalagmite from middle java indonesia abstract speleothem multi proxy records have proved highly useful in reconstructing past changes in climatic and environmental conditions as well as karst processes and in distinguishing between the numerous potential driving forces that influence these proxies there is lack of such terrestrial proxies from the tropical indo pacific for the first time we present an annual to decadal scale multi proxy record of 377 samples including stable isotopes 18o 13c and trace elements mg ca sr ca from a holocene calcite stalagmite from bribin cave gunung kidul regency middle java indonesia that has grown over the last 4000 years 11 230th dates 18o values average 7 with high frequency variability of up to 1 and hint at relatively stable overall climatic conditions in the tropical indo pacific region during the late holocene the 13c values of stalagmite jb2 are low 13 at the beginning of the record suggesting a c3 dominated rainforest cover strong positive covariation with mg ca and sr ca ratios is a stringent indication of a dominant natural control by prior calcite precipitation and water rock interaction however 13c values increase dramatically by 4 from 1 1 ka to 0 5 ka clear evidence of an anthropogenic influence through deforestation and cultivation

orbital time scale and new c isotope record for cenomanian turonian boundary stratotype previous time scales for the cenomanian turonian boundary ctb interval containing oceanic anoxic event ii oae ii vary by a factor of three in this paper we present a new orbital time scale for the ctb stratotype established independently of radiometric biostratigraphic or geochemical data sets update revisions of ctb biostratigraphic zonation and provide a new detailed carbon isotopic record for the ctb study interval the orbital time scale allows an independent assessment of basal biozone ages relative to the new ctb date of 93 55 ma gts04 the d 13 corg data document the abrupt onset of oae ii significant variability in d 13 corg values and values enriched to almost 222 these new data underscore the difficulty in defining oae ii termination using the new isotope curve and time scale estimates of oae ii duration can be determined and exported to other sites based on integration of well established chemostratigraphic and biostratigraphic datums the new data will allow more accurate calculations of biogeochemical and paleobiologic rates across the ctb

deglacial δ18o and hydrologic variability in the tropical pacific and indian oceans abstract evidence from geologic archives suggests that there were large changes in the tropical hydrologic cycle associated with the two prominent northern hemisphere deglacial cooling events heinrich stadial 1 hs1 19 to 15 kyr bp kyr bp 1000 yr before present and the younger dryas 12 9 to 11 7 kyr bp these hydrologic shifts have been alternatively attributed to high and low latitude origin here we present a new record of hydrologic variability based on planktic foraminifera derived 18o of seawater 18osw estimates from a sediment core from the tropical eastern indian ocean and using 12 additional 18osw records construct a single record of the dominant mode of tropical eastern equatorial pacific and indo pacific warm pool ipwp hydrologic variability we show that deglacial hydrologic shifts parallel variations in the reconstructed interhemispheric temperature gradient suggesting a strong response to variations in the atlantic meridional overturning circulation and the attendant heat redistribution a transient model simulation of the last deglaciation suggests that hydrologic changes including a southward shift in the intertropical convergence zone itcz which likely occurred during these northern hemisphere cold events coupled with oceanic advection and mixing resulted in increased salinity in the indonesian region of the ipwp and the eastern tropical pacific which is recorded by the 18osw proxy based on our observations and modeling results we suggest the interhemispheric temperature gradient directly controls the tropical hydrologic cycle on these time scales which in turn mediates poleward atmospheric heat transport

the mid cretaceous north atlantic nutrient trap black shales and oaes organic rich sediments are the salient marine sedimentation product in the mid cretaceous of the ocean basins formed in the mesozoic oceanic anoxic events oaes are discrete and particularly organic rich intervals within these mid cretaceous organic rich sequences and are defined by pronounced carbon isotope excursions marine productivity during oaes appears to have been enhanced by the increased availability of biolimiting nutrients in seawater due to hydrothermal alteration of submarine basalts in the pacific and proto indian oceans the exact mechanisms behind the deposition of organic rich sediments in the mid cretaceous are still a matter of discussion but a hypothesis which is often put forward is that their deposition was a consequence of the coupling of a particular paleogeography with changes in ocean circulation and nutrient supply in this study we used a global coupled climate model to investigate oceanic processes that affect the interbasinal exchange of nutrients as well as their spatial distribution and bioavailability we conclude that the mid cretaceous north atlantic was a nutrient trap as a consequence of an estuarine circulation with respect to the pacific organic rich sediments in the north atlantic were deposited below regions of intense upwelling we suggest that enhanced productivity during oaes was a consequence of upwelling of pacific derived nutrient rich seawater associated with submarine igneous events