the posidonia shale lower toarcian of sw germany an oxygen depleted ecosystem controlled by sea level and palaeoclimate abstract the lower toarcian posidonia shale is famous for its excellently preserved fossils and its high amount of organic matter up to 16 both quality of preservation and accumulation of organic matter have been explained by permanent anoxic bottom water conditions high resolution geochemical sedimentological and palaeoecological investigations of various sections of the posidonia shale in sw germany however indicate that oxygen availability was variable and ranged from short oxygenated periods to longer term anoxia the benthic macrofauna consists of nine fossil communities and was used in combination with geochemical data to reconstruct a time averaged oxygen curve anoxic conditions prevailed during the deposition of the toarcian black shales they were however punctuated by various short periods weeks to years with oxygenated bottom water conditions sedimentological e g distinctiveness of microlamination siliciclastic content and geochemical parameters e g organic matter content isotopic signatures 18o and 13c molecular redox parameters pristane phytane ratio arylisoprenoids exhibit a remarkable covariation and seem to be controlled by sea level fluctuations maximum oxygen depletion and an extreme negative shift of 13corg values 34 occurred during the early falciferum zone this is explained by the recycling of 12c enriched carbon derived from remineralization of organic matter on and within the substrate during low sea level stand and a highly elevated redox boundary including photic zone anoxia the subsequent transgression permitted enhanced water exchange with the tethyan ocean and caused improvement of living conditions at the end of the falciferum zone other important factors controlling the depositional environment are the overall palaeogeographic situation and climate the early jurassic is the latest period before break up of pangaea and probably was ruled by a strong meridional atmospheric circulation system with pronounced seasonal changes of prevailing trade and monsoon wind systems an estuarine circulation with a positive water balance and surface water with slightly reduced salinity in the summer alternated with an anti estuarine circulation and a negative water balance in the winter during the summer months a stratified water column with anoxic conditions below the halocline developed 18o data indicate low salinity in the surface water during the monsoon influenced summer high productivity was then located in the photic zone and the corresponding isotopically light 18o signal was fixed in the calcareous nannoplankton during the winter months a saline circulation system brought oxygen to the benthic environment favouring temporary benthic colonization especially during times of relative sea level high stand

estimates of the amount and rate of sea level change across the rhaetian hettangian and pliensbachian toarcian boundaries latest triassic to early jurassic an attempt is made to determine the amount and rate of sea level change for two major events in the latest triassic to early jurassic both of which are associated with mass extinctions using the best available facies evidence and time scale the amount of marine deepening across the pliensbachian toarcian boundary based on analysis of the excellent yorkshire coast section is likely to have been a few tens of metres at a rate of between 1cm 1 2 ka 1 and 1cm 0 4 ka 1 the change across the rhaetian hettangian triassic jurassic boundary was different in that the sea level rise was immediately preceded by a sea level fall effectively a 9regression transgression9 couplet the earliest jurassic sea level rise is likely to have been much more rapid than that across the pliensbachian toarcian boundary at a rate of at least 1 cm 0 2 ka 1 whereas the speed of pliensbachian toarcian change is consistent with the growth of oceanic ridges the appreciably more rapid triassic jurassic change is suggestive of a different tectonoeustatic mechanism involving stress induced changes in plate density

jokulhlaups a reassessment of floodwater flow through glaciers 1 in glaciated catchments glacier generated floods jokulhlaups put human activity at risk with large sporadic jokulhlaups accounting for most flood related fatalities and damage to infrastructure in studies of jokulhlaup hydrodynamics the view predominates that floodwater travels within a distinct conduit eroded into the underside of a glacier however some jokulhlaups produce subglacial responses wholly inconsistent with the conventional theory of drainage by focusing on icelandic jokulhlaups this article reassesses how floodwater flows through glaciers it is argued that two physically separable classes of jokulhlaup exist and that not all jokulhlaups are an upward extrapolation of processes inherent in events of lesser magnitude and smaller scale the hydraulic coupling of multiple nonlinear components to the flood circuit of a glacier can induce extreme responses including pressure impulses in subglacial drainage representing such complexity in mathematical form should be the basis for upcoming research as future modeling results may help to determine the glaciological processes behind heinrich events moreover such an approach would lead to more accurate predictive models of jokulhlaup timing and intensity

structure and geochemistry of tethyan ophiolites and their petrogenesis in subduction rollback systems suprasubduction zone ssz ophiolites in orogenic belts represent oceanic crust generation in subduction rollback cycles during the closing stages of basins prior to terminal continental collisions mantle flow and slab rollback result in one or more episodes of arc splitting and basin opening producing a collage of protoarc and forearc oceanic lithosphere in suprasubduction zone settings the jurassic cretaceous ssz tethyan ophiolites in the eastern mediterranean region i e mirdita pindos troodos kizildag oman generally have penrose type oceanic crust and contain well developed sheeted dike complexes indicative of magmatic extension beneath narrow rift zones during their seafloor spreading evolution igneous accretion of these ssz tethyan ophiolites involved upper plate extension and advanced melting of previously depleted asthenosphere in host basins showing a progressive evolution from morb like to iat island arc tholeiite to boninitic extremely refractory protoarc assemblages however there are some distinct differences in the geochemical evolution of these tethyan ophiolites that appear to have resulted from variations in their subduction zone geodynamics whereas a major part of the kizildag and troodos lavas shows island arc affinity similar to their counterparts in the pindos and mirdita ophiolites a significant component of the oman lavas indicates morb affinity and the majority of the kizildag and oman data plot within the mantle array between n morb and e morb on the nb yb th yb discriminant diagram furthermore the troodos and oman lavas do not show any particular th enrichment in their multi element patterns suggesting that fluid melt input from subducted sediments was not that significant in generation of their magmas although all ophiolites exhibit geochemical features indicating increased subduction influence during the melt evolution of their younger extrusive sequences and dike intrusions as evidenced by their negative nd values their overall characteristic trace element patterns seem to have been strongly affected by the maturity of the subduction systems in which they developed

latest eocene early oligocene climate change and southern ocean fertility inferences from sediment accumulation and stable isotope data abstract the earliest oligocene 33 5 ma is marked by a major step in the long term transition from an ice free to glaciated world the transition characterized by both cooling and ice sheet growth triggered a transient but extreme glacial period designated oi 1 high resolution isotope records suggest that oi 1 lasted for roughly 400 000 yr the duration of magnetochron 13n before partially abating and that it was accompanied by an ocean wide carbon isotope anomaly of 0 75 one hypothesis relates the carbon isotope anomaly to enhanced export production brought about by climate induced intensification of wind stress and upwelling particularly in the southern ocean to understand how this climatic event affected export production in the southern ocean biogenic silica opal and carbonate accumulation rates were computed for the sub polar indian ocean using deep sea cores from odp site 744 kerguelen plateau our findings suggest that net productivity in this region increased by several fold in response to the oi 1 glaciation in addition calcareous primary producers dominant in the late eocene were partially replaced by opaline organisms suggesting a trend toward seasonally greater surface divergence and upwelling in this sector of the southern ocean we attribute these changes to intensification of atmospheric oceanic circulation brought about by high latitude cooling and the appearance of a full scale continental ice sheet on east antarctica higher terrigenous sediment accumulation rates support the idea that wind induced changes in regional productivity were augmented by an increased supply of glacial dust and debris that provided limiting micro nutrients e g iron rich dust particles we speculate that the rapid changes in biogenic sediment accumulation in the southern ocean and other upwelling dominated regions contributed to the ocean wide positive carbon isotope anomaly by temporarily increasing the burial rate of organic carbon relative to carbonate carbon the changes in burial rates in turn may have produced a positive feedback on climate by briefly drawing down atmospheric pco2

chemostratigraphy of the jurassic system applications limitations and implications for palaeoceanography current chemostratigraphical studies of the jurassic system primarily involve the use of one sedimentary component marine organic carbon one divalent transition metal substituted in carbonate manganese and two isotopic tracers strontium isotope ratios 87 sr 86 sr and carbon isotope ratios 13 c carb and 13 c org in carbonate and in organic matter other parameters such as mg ca and sr ca ratios in calcite oxygen isotope ratios 18 o in carbonate sulphur isotope ratios 34 s in carbonate hosted sulphate nitrogen isotope ratios 15 n org in organic matter osmium isotope ratios 187 os 188 os in black shales and neodymium isotope ratios 143 nd 144 nd in various mineral phases are also useful but at present give poor resolution because the database is incomplete or compromised by various factors stratigraphical patterns in total organic carbon toc can be of either local or regional significance depending on the lateral extent of the former nutrient rich and productive water mass divalent manganese follows a similar pattern being concentrated most probably as a very early diagenetic phase only in oxygen depleted waters that typically underlie zones of elevated organic productivity shifts in mg ca and sr ca ratios on the time scale of ammonite subzones seem largely to reflect temperature changes strontium isotope ratios from pristine skeletal calcite provide a global signal 13 c values from carbonates with minimal diagenetic overprint potentially do the same although small spatial differences in palaeo water mass composition may have been locally significant oxygen isotope determinations on carbonate rocks and fossils generally yield values that are too scattered to be stratigraphically useful because they reflect palaeotemperature the evaporation precipitation balance in sea water and the impact of any diagenesis involving an aqueous phase nitrogen isotope ratios in organic matter reflect the chemistry of ancient water masses as affected by nitrate utilization and denitrification and the stratigraphical pattern of this parameter is more likely to correlate only on a regional basis neodymium isotope ratios in sea water are also water mass dependent and greatly affected by regional sources and oceanic current systems preliminary data on sulphur isotope ratios in carbonates and osmium isotope ratios in organic rich shales both potentially offering global correlation indicate that these tracers may be valuable although the records at present are not sufficiently well established to allow high resolution regional correlation in all cases biostratigraphically well dated reference sections against which the relevant geochemical data have been calibrated are required in the first instance to date studies on the stratigraphical distribution of organic carbon have been principally carried out in both northern boreal and southern tethyan europe carbon isotope stratigraphy has been undertaken primarily but not exclusively on bulk pelagic sediments from the alpine mediterranean or tethyan domain and strontium isotope stratigraphy has been undertaken largely on calcitic skeletal material belemnites and oysters from northern and southern europe in many sections including those containing ammonites multi parameter chemostratigraphy can give resolution that exceeds that attainable by classic biostratigraphical means strontium isotope ratios in skeletal calcite are a particularly powerful tool for illustrating changes in sedimentary rate and revealing gaps in the stratigraphical record

biogeochemical constraints on the triassic jurassic boundary carbon cycle event 1 the end triassic mass extinctions represent one of the five most severe biotic crises in earth history yet remain one of the most enigmatic ongoing debate concerns the environmental effects of the central atlantic magmatic province camp eruptions and their linkage with the mass extinction event across the triassic jurassic boundary there is conflicting paleo evidence for changes in atmospheric pco2 during the extrusion of the camp basalts studies on sediments from european and pacific localities have however identified a substantial negative isotopic anomaly up to 3 5 across the tr j boundary providing an important indicator of changes in the operation of the ancient global carbon cycle we sought to explain the paleo evidence by utilizing a carbon cycle model for the hothouse world of the end triassic that emphasizes the chemical weathering of silicate and carbonate rocks and the ocean carbonate chemistry we find that volcanic co2 outgassing fails to fully account for either a sufficient rise in atmospheric pco2 indicated by the stomata of fossil leaves or the sedimentary isotopic fingerprint instead the scenario that best fits all of the geologic evidence is a positive feedback loop in which warming due to a buildup of volcanically derived co2 triggers destabilization of seafloor methane hydrates and the catastrophic release of ch4 palfy et al 2001 we calculate that this carbon cycle perturbation was huge involving the release of 8000 9000 gt c as co2 during the camp basaltic eruptions and 5000 gt c as ch4 in the model the initial isotopic excursion is assumed to take place over 70 kyr while complete reequilibration of the ocean atmosphere system with respect to co2 is accomplished over 700 1000 kyr our results thus provide a preliminary theoretical explanation for the bioevents estimated pco2 changes and isotopic excursions observed in marine and continental sediments at this time

the oligocene miocene stratigraphic evolution of the majella carbonate platform central apennines italy abstract the stratigraphic architecture of the bolognano formation documents the evolution of the majella carbonate platform in response to global and local changes that affected the mediterranean area during the oligocene miocene interval the bolognano formation consists of a homoclinal ramp that developed in a warm subtropical environment five different lithofacies associations have been identified lepidocyclina calcarenites cherty marly limestones bryozon calcarenites hemipelagic marls and marly limestones and lithothamnion limestones each association corresponds to a single lithostratigraphic unit except for the lepidocyclina calcarenites that form two distinct lithostratigraphic units lepidocyclina calcarenites 1 and 2 these six units reflect alternation of shallow water carbonate production and drowning specifically two of the three stages of shallow water carbonate production regard the development of wide dune fields within the middle ramp one stage dominated by red algae and a sea grass carbonate factory whereas the two drowning phases are represented by marly cherty limestones and calcareous marls a new biostratigraphic framework for bolognano formation is presented based on high resolution analysis of calcareous nannofossil assemblages which proved to be very useful for biostratigraphic constraints also in shallow water settings using this approach we have linked the first drowning phase late chattian aquitanian p p in age to western mediterranean volcanism and the mi 1 event and the second drowning phase late burdigalian serravallian in age to the closure of the indo pacific passage and the occurrence of the global monterey event these results permit a new deciphering in terms of sequence stratigraphy of the bolognano formation that is interpreted as a 2nd order super sequence that can be subdivided into 3 transgressive regressive sequences

mesozoic tertiary tectonic evolution of albania in its regional eastern mediterranean context abstract research carried out since the opening of albania to the western geological community in the 1990s allows the geology and tectonics of this small balkan country to be integrated into an overall interpretation of neotethys in the eastern mediterranean region specifically greece and the former yugoslavia region albanian geology is most famous for the occurrence of contrasting ophiolites of jurassic age the country is sub divided into three main geotectonic units those in the west i e sazani ionian kruja krasta cukali and the albanian alps relate to the western margin of apulia effectively part of north africa from early mesozoic time onwards in the east is the korabi zone interpreted as a microcontinent located further northeast within neotethys between the two is the mirdita zone dominated by two contrasting jurassic ophiolites the western type ophiolite and the eastern type ophiolite taking account of evidence from greece and former yugoslavia the following tectonic evolution is proposed from early mesozoic time onwards neotethys in albania existed as a northward continuation of the pindos oceanic basin in greece pindos mirdita ocean a korabi microcontinent was rifted off apulia in the early mid triassic followed by passive margin subsidence until late middle jurassic time a rifted slow spreading mor type ophiolite formed within the western pindos mirdita oceanic basin in late triassic early late jurassic time using present co ordinates the shkoder peje scutari pec lineament in the north of albania is interpreted as an important transform fault zone that influenced the regional tectonic evolution during the entire mesozoic early tertiary rift drift emplacement history of the pindos mirdita ocean taking account of evidence from the greek and former yugoslavia ophiolites the easterly albanian ophiolites formed within the pindos mirdita ocean above a westward dipping intra oceanic subduction zone in the early late jurassic metamorphic soles were formed during initial intra oceanic displacement ca 162 174 m y and underlying melanges originated as subduction accretion complexes the mor western type ophiolite evolved into the iat boninitic eastern type ophiolite after subduction began during tithonian berriasian time trench margin collision emplaced the ophiolites eastwards over the korabi margin coupled with redeposition of ophiolitic and continental margin material as exotic blocks debris flow deposits and turbidites these were emplaced onto the upper surface of the ophiolitic thrust sheet during the latest stages of emplacement onto the korabi microcontinent following collision in the east oceanic crust remained within a small remnant pindos mirdita oceanic basin passive conditions were restored in the mid late cretaceous with shallow water carbonate deposition on microcontinental units and both pelagic and redeposited carbonates in basinal settings from the maastrichtian onwards africa eurasia convergence resulted in large scale westward thrusting deforming the apulian foreland in oligo miocene time the suture zone was re activated in oligo miocene time as the albanie thassalie piggy back type basin in central and southern albania albania as a whole was rotated 45 clockwise as part of the western aegean arc in post eocene time coastal and offshore albania experienced strong subsidence after early miocene time forming the periadriatic basin including the tirana depression interpreted as a foredeep related to continuing regional convergence southern albania experienced extensional tectonics in plio quaternary time related to southward roll back of the aegean active margin

fresh arguments against the shaw megaflood hypothesis a reply to comments by david sharpe on paleohydraulics of the last outburst flood from glacial lake agassiz and the 8200 bp cold event

regional reconstruction of subglacial hydrology and glaciodynamic behaviour along the southern margin of the cordilleran ice sheet in british columbia canada and northern washington state usa abstract subglacial landsystems in and around okanagan valley british columbia canada are investigated in order to evaluate landscape development subglacial hydrology and cordilleran ice sheet dynamics along its southern margin major landscape elements include drumlin swarms and tunnel valleys drumlins are composed of bedrock diamicton and glaciofluvial sediments their form truncates the substrate tunnel valleys of various scales km to 100s km length incised into bedrock and sediment exhibit convex longitudinal profiles and truncate drumlin swarms okanagan valley is the largest tunnel valley in the area and is eroded 300 m below sea level over 600 m of late wisconsin age sediments consisting of a fining up sequence of cobble gravel sand and silt fill okanagan valley landform substrate relationships landform associations and sedimentary sequences are incompatible with prevailing explanations of landsystem development centred mainly on deforming beds they are best explained by meltwater erosion and deposition during ice sheet underbursts during the late wisconsin glaciation okanagan valley functioned as part of a subglacial lake spanning multiple connected valleys few 100s km of southern british columbia subglacial lake development started either as glaciers advanced over a pre existing sub aerial lake catch lake or by incremental production and storage of basal meltwater high geothermal heat flux geothermal springs and or subglacial volcanic eruptions contributed to ice melt and may have triggered along with priming from supraglacial lakes subglacial lake drainage during the underburst s sheetflows eroded drumlins in corridors and channelized flows eroded tunnel valleys progressive flow channelization focused flows toward major bedrock valleys in okanagan valley most of the pre glacial and early glacial sediment fill was removed a fining up sequence of boulder gravel and sand was deposited during waning stages of the underburst s and bedrock drumlins in okanagan valley were enhanced or wholly formed by this underburst s subglacial lake development and drainage had an impact on ice sheet geometry and ice volumes the prevailing conceptual model for growth and decay of the cis suggests significantly thicker ice in valleys compared to plateaus subglacial lake development created a reversal of this ice sheet geometry where grounded ice on plateaus thickened while floating valley ice remained thinner due to melting and enhanced sliding with significant transfer of ice toward the ice sheet margin subglacial lake drainage may have hastened deglaciation by melting ice lowering ice surface elevations and causing lid fracture this paper highlights the importance of ice sheet hydrology its control on ice flow dynamics distribution and volume in continental ice masses

the early origins of terrestrial c4 photosynthesis abstractthe c4 photosynthetic pathway is a series of structural and biochemical modifications around the more primitive c3 pathway that improve the photosynthetic efficiency under specific climatic conditions hence the origin and subsequent geographical expansion of the c4 plants likely reflects a record of climate change multiple paleoatmospheric pco2 proxies indicate a critical co2 threshold was breached 30 ma that potentially selected for co2 concentrating mechanisms to overcome photorespiratory stresses imposed on the basic c3 pathway details of the c4 pathway s earliest origins remain enigmatic given the paucity of the geologic record nonetheless 13c proxy records from paleosol carbonates ungulate teeth and plant derived compounds indicate c4 plants likely represented an important component of plant biomass by the early miocene low co2 levels appear to be a precondition for the development of the c4 photosynthetic pathway however comparisons of 13c proxy records indicate that the timin

slow spreading accretion and mantle denudation in the mirdita ophiolite albania the mirdita ophiolite in albania occupies a n s corridor which escaped most alpine and cenozoic deformation possibly due to a thick ophiolitic basement the sheeted dike complex strikes ns and dips steeply indicating that the ridge was oriented parallel to the ns corridor and that the ophiolite has not been significantly tilted although differential motion between individual massifs cannot be excluded classically the western massifs have been considered lherzolitic and the eastern massifs harzburgitic detailed structural mapping reveals that the deep mantle section was harzburgitic and that the major differences between the two are restricted to the uppermost mantle and lower crustal section these are typically ophiolitic in the eastern massifs being composed of a thick dunitic transition zone rich in basaltic impregnations and chromite deposits overlain by a lower crust of layered gabbros in contrast in the western massifs the uppermost mantle is composed of highly strained to mylonitic lherzolites which originate from more depleted harzburgites by impregnation and tectonic dispersion of melt during deformation occurring at 1000 800 c layered gabbros are locally absent and the crust can be reduced to diabase dikes or sills and extrusives the diabase intrusions are locally sheared together with peridotites and metamorphosed to amphibolites the contrast between the eastern and western massifs is ascribed to successive episodes of magmatic and amagmatic spreading in a slow spreading environment the low t high strain deformation of the western massifs is localized in the dome shaped envelopes of these massifs this structure and even the present day topography of the western massifs evoke the turtleback domes described along the mid atlantic ridge mar and explained by mantle denudation tucholke et al 1998

arido eustasy a new example of non glacial eustatic sea level change abstract sea level fluctuation is common in the stratigraphical record and is partly explained by periodic polar glaciation such fluctuation in the absence of polar glaciation during the warm periods of earth s history is poorly understood and currently under discussion here i reconsider the palaeo environmental information extracted from the variation in the carbon isotope record and explain the phenomenon by coupling the levels of marine and fresh water reservoirs through long term wet and arid climate modes the arido eustasy model produces a standard anti covariation pattern of marine organic and carbonate carbon isotope records which may appear throughout the geochemical record of the last 200 myr under the model orbitally forced periods of extremely wet climate result in environmental crisis sea level falls and carbon cycle perturbations during which negative excursions in the marine organic carbon isotope record of sediments containing matter from terrestrial vegetation should be understood as a proxy reporting periods of high precipitation rather than changes in the global carbon reservoir i propose that the early toarcian oceanic anoxic event is an example of arido eustasy

contrasting watermass conditions during deposition of the whitby mudstone lower jurassic and kimmeridge clay upper jurassic formations uk abstract the whitby mudstone formation wmf and kimmeridge clay formation kcf are both jurassic organic rich black shale units containing well preserved marine organic matter despite such gross similarities they exhibit opposite trends in 13 c toc versus wt decarbonated total organic carbon toc r 0 76 for wmf and 0 71 for kcf the 13 c toc versus toc trend also varies geographically within both units only the kcf data exhibit a positive correlation between 13 c toc and 15 n org r 0 76 and the presence of aryl isoprenoids probable indicators of photic zone anoxia maturity differences are insufficient to explain such contrasts bulk and compound specific isotopic variations in the kcf are interpreted largely as a reflection of primary productivity during deposition rather than a dominantly diagenetic signal due to incorporation of sulphurised carbohydrate the contrasts between the formations and the geographic variation in coeval shelf sediments are explained by a model stressing the relative positions and stabilities of the chemocline pycnocline nutricline and euphotic zone and the effect these have on productivity co 2 recycling and bacterial floras

sequence stratigraphy and tectonosedimentary history of the upper jurassic of the eastern paris basin lower and middle oxfordian northeastern france in the present study the difficulty which lies in the identification of sea level fall discontinuities in deep depositional environments led the authors to use the transgressive surfaces i e the most noticeable surfaces in the present case to determine depositional cycles four 3rd order lower and middle oxfordian cycles were identified s1 s2 s3 and s4 in the eastern paris basin these four cycles can be organised into two lower frequency cycles so i and so ii which comprise the s1 s2 and the s3 s4 cycles respectively during the time intervals of the s1 s2 and s3 cycles sedimentation occurred along a southward dipping carbonate siliciclastic ramp prograding from the northern ardennes area the s4 cycle shows the development of a reefal distally steepened ramp which subsequently evolved into a flat topped platform as a result of the compensation infill of the available accommodation space by the carbonate production during a climatic warming in this case reef growth isopach and facies maps suggest synsedimentary activities of hercynian faults coevals with the floodings of the so i and so ii cycles one of these events generated a diachronism of the maximum flooding plicatilis zone during the so ii cycle between the northwestern and southeastern parts of the studied area the depositional patterns found in the eastern paris basin and the swiss jura show great similarities for the early middle oxfordian both regions were probably connected and recorded the same tectonosedimentary evolution in contrast a tectonic control certainly generated differences between the sequence stratigraphic framework of the eastern paris basin and the eustatic chart

detailed record of the mid oxfordian late jurassic positive carbon isotope excursion in two hemipelagic sections france and switzerland a plate tectonic trigger the oxfordian late jurassic was a time of widespread change in jurassic marine carbonate sedimentation patterns a marked positive excursion in 13 c is dated as middle oxfordian in age in this study we investigate if changes in carbonate sedimentation coincided with altered carbon cycling and climate we use c isotope records as a proxy for the evolution of the carbon cycle and compare 13 c trends with the evolution of sedimentation in a segment of the opening tethys seaway one of the studied sections is located in the subalpine basin of france trescleoux and oze the other in the swiss jura mountains liesberg carbon isotope stratigraphy of carbonate carbon locates the peak values of the middle oxfordian positive excursion to theantecedens andparandieri subzonesoftheplicatilisandtransversariumammonitezones respectively causesofthe excursionremain enigmatic theexcursion seems not to coincide with a global oceanic anoxic event but regionally enhanced organic carbon accumulation during the early and early middle oxfordian may be the cause of the increase in 13 c the excursion occurs during a time of progressive climate warming anditspeakvaluescoincidewiththefirstcalcareoussedimentsrecurringafteraperiodofreducedcarbonateaccumulationintheearly and early middle oxfordian the excursion is also time equivalent to a major reorganisation of global ocean currents the opening atlantic and tethys oceans combined with rising sea level led to the formation of an efficient circumglobal seaway we conclude that this favoured the widespread recurrence of carbonate producers by providing new habitats as a result ccarb burial increased leading to a lower corg ccarb burial rate and therefore to stabilisation and decrease in 13 c in the middle oxfordian thus the mid oxfordian positive excursion in carbonate c isotopes may reflect changes in the carbon cycle that were triggered by a copious reorganisation of the ocean current system caused by major plate tectonic movements 2007 elsevier b v all rights reserved

rogen moraine an example of glacial reshaping of pre existing landforms abstract rogen moraine is widely distributed in the core areas of the former scandinavian and laurentide ice sheets it is generally agreed upon that these gently arched ice flow transverse ridges can be used in reconstructions of paleo ice flow patterns and that they indicate a melted bed or poly thermal basal ice regime however the processes of ridge generation have been contentious this study proposes a two stage formation of rogen moraine based on detailed sedimentological and structural investigations in excavated trenches in a rogen moraine landscape in the province of dalarna central sweden field data suggest that rogen moraine ridges are the reshaped remains of pre existing transverse moraine ridges originally deposited from ice cored moraines in an ice marginal zone due to back and down wasting of ice cores inter ridge troughs were filled with debris flow and fluvial deposits which after landscape inversion were transformed to areas of transverse and hummocky moraines it is proposed that this primary landscape formation occurred during an early weichselian deglaciation this relict landscape was later preserved beneath cold based mid to late weichselian ice sheet s which turned wet based during the preboreal deglaciation phase and re moulded the precursor landforms into rogen moraine

on the origin of cenozoic and mesozoic third order eustatic sequences abstract the origin of third order eustatic sequences is reviewed by comparing recent sequence stratigraphic data to the latest best constrained astronomical model middle eocene to holocene icehouse sequences correspond to 1 2 myr obliquity cycles constraints from oxygen isotope records highlight the link between icehouse sea level lowerings sequence boundaries and 1 2 myr obliquity nodes mesozoic greenhouse sequences show some relation with the 2 4 myr eccentricity cycles suggesting that orbital forcing contribute to sea level change we suggest that during the icehouse large ice sheets associated with significant glacioeustatic changes 25 m up to 120 m changes were mainly governed by obliquity forcing during icehouse worlds obliquity forcing was the stongest control on global sea level and depositional sequences additionally during the middle eocene third order sequences were glacioeustatically driven in tune with 1 2 myr obliquity cycle suggesting that the presence of significant ice sheets is earlier than previously supposed i e early eocene in contrast during greenhouse worlds e g ephemeral small to medium sized or no ice sheets 0 25 m glacioeustatic changes the expression of obliquity in the sedimentary record is weak and intermittent instead the eccentricity signature which is the modulator of climatic precession is documented moreover we presume that greenhouse sequences on the myr scale are global and hence cannot be caused by regional tectonism e g intraplate stress or mantle hot blobs instead the eccentricity link implies a weaker glacioeustatic control because thermoeustasy is too small to explain the sea level changes stratigraphically well documented fourth order sequences may be linked to the astronomically stable strongest amplitude 405 kyr eccentricity cycle and possibly to 160 200 kyr obliquity modulation cycles fifth order sequences to the short 100 kyr eccentricity cycles and finally sixth order sequences to the fundamental obliquity 40 kyr and climatic precession 20 kyr cycles these astronomical cycles could be preserved in the sedimentary record and have been demonstrated to control sea level changes accordingly by placing depositional sequence orders into a high resolution temporal framework i e orbital periodicities standardization of eustatic sequence hierarchy may be possible

link between cyclic eustatic sea level change and continental weathering evidence for aquifer eustasy in the cretaceous abstract cyclic fluctuations in global sea level during epochs of warm greenhouse climate have remained enigmatic because absence or subordinate presence of polar ice during these periods precludes an explanation by glacio eustatic forcing an alternative concept suggests that the water bearing potential of groundwater aquifers is equal to that of ice caps and that changes in the dynamic balance of aquifer charge versus discharge as a function of the temperature related intensity of the hydrological cycle may have driven eustasy during warm climates however this idea has long been neglected for two reasons 1 the large storage potential of subsurface aquifers was confused with the much smaller capacity of rivers and lakes and 2 empirical data were missing that document past variations in the hydrological cycle in relation to eustasy in the present study we present the first empirical evidence for changes in precipitation continental weathering intensity and evaporation that correlate with astronomically long obliquity forced sea level cycles during the warmest period of the cretaceous cenomanian turonian we compare sequence stratigraphic data with changes in the terrigenous mineral assemblage in a low latitude marine sedimentary sequence from the equatorial humid belt at the south tethyan margin levant carbonate platform jordan thereby avoiding uncertainties from land ocean correlations our data indicate covariance between cycles in weathering and sea level predominantly chemical weathering under wet climate conditions is reflected by dominance of weathering products clays in deposits that represent sea level fall aquifer charge discharge conversely preservation of weathering sensitive minerals feldspars epidote and pyroxenes in transgressive sediments reflects decreased continental weathering due to dryer climate aquifer discharge charge based on our results we suggest that aquifer eustasy represents a viable alternative to glacio eustasy as a driver of cyclic 3rd order sea level fluctuations during the middle cretaceous greenhouse climate and it may have been a pervasive process throughout earth history

carbon isotope record of the early jurassic toarcian oceanic anoxic event from fossil wood and marine carbonate lusitanian basin portugal thetoarcianoceanicanoxicevent oae intheearlyjurassic 183maago wascharacterizedbywidespreadnear synchronous deposition of organic rich shales in marine settings as well as perturbations to several isotopic systems characteristically two positive carbon isotope excursions in a range of materials are separated by an abrupt negative shift carbon isotope profiles from toarcian fossil wood collected in england and denmark have previously been shown to exhibit this large drop 7 i n 13 c values interpreted as due to an injection of isotopically light co2 into the ocean atmosphere system however the global nature of this excursion has been challengedonthebasisofcarbon isotopedatafromnektonicmarinemolluscs belemnites whichexhibitheavierthanexpectedcarbonisotope values here we present new data principally from fossil wood and bulk carbonate collected at centimetre scale from a hemipelagic section at peniche coastal portugal this section is low in organic carbon average toc 0 5 and the samples should not have suffered significant diagenetic contamination by organic carbon of marine origin the carbon isotope profile based on wood shows two positive excursions separated by a large and abrupt negative excursion which parallels exactly the profile based on bulk carbonate samples from the same section albeit with approximately twice the amplitude 8 in wood versus 3 5 in carbonate these data indicate thatthe negative carbon isotope excursion affected the atmosphereand by implication the global ocean as well the difference in amplitude between terrestrial organic and marine carbonate curves can be explained by greater water availability in the terrestrial environment during the negative excursion for which there is independent evidence from marine osmiumisotope records and plausibly changes in atmospheric co2 content for which independent evidence is also available the peniche succession is also notable for the occurrence of re deposited sediments their lowest occurrence coincides with the base of the negative excursionandtheirhighestoccurrencecoincideswithitstop thus slopeinstabilityandsedimentsupplycouldhavebeenstronglylinked to the global environmental perturbation an association that may misleadingly simulate the effects of sea level fall

erratum to the posidonia shale lower toarcian of sw germany an oxygen depleted ecosystem controlled by sea level and palaeoclimate palaeogeogr palaeoclimatol palaeocol 165 2001 27 52 abstract the lower toarcian posidonia shale is famous for its excellently preserved fossils and its high amount of organic matter up to 16 both quality of preservation and accumulation of organic matter have been explained by permanent anoxic bottom water conditions high resolution geochemical sedimentological and palaeoecological investigations of various sections of the posidonia shale in sw germany however indicate that oxygen availability was variable and ranged from short oxygenated periods to longer term anoxia the benthic macrofauna consists of nine fossil communities and was used in combination with geochemical data to reconstruct a time averaged oxygen curve anoxic conditions prevailed during the deposition of the toarcian black shales they were however punctuated by various short periods weeks to years with oxygenated bottom water conditions sedimentological e g distinctiveness of microlamination siliciclastic content and geochemical parameters e g organic matter content isotopic signatures 18 o and 13 c molecular redox parameters pristane phytane ratio arylisoprenoids exhibit a remarkable covariation and seem to be controlled by sea level fluctuation maximum oxygen depletion and an extreme negative shift of 13 c org values 34 occurred during the early falciferum zone this is explained by the recycling of 12 c enriched carbon derived from remineralization of organic matter on and within the substrate during low sea level stand and a highly elevated redox boundary including photic zone anoxia the subsequent transgression permitted enhanced water exchange with the tethyan ocean and caused improvement of living conditions at the end of the falciferum zone other important factors controlling the depositional environment are the overall palaeogeographic situation and climate the early jurassic is the latest period before break up of pangaea and probably was ruled by a strong meridional atmospheric circulation system with pronounced seasonal changes of prevailing trade and monsoon wind systems an estuarine circulation with a positive water balance and surface water with slightly reduced salinity in the summer alternated with an anti estuarine circulation and a negative water balance in the winter during the summer months a stratified water column with anoxic conditions below the halocline developed 18 o data indicate low salinity in the surface water during the monsoon influenced summer high productivity was then located in the photic zone and the corresponding isotopically light 18 o signal was fixed in the calcareous nannoplankton during the winter months a saline circulation system brought oxygen to the benthic environment favouring temporary benthic colonization especially during times of relative sea level high stand

biological overprint of the geological carbon cycle the oxidation of earth s atmosphere is coupled to the net sequestration of organic matter which is related to the relative fractions of organic carbon forg and carbonate fcarb buried in marine sediments these fractions can be inferred from carbon isotope data we present bulk sediment d 13 c records of carbonate d 13 ccarb and organic carbon d 13 corg with a compilation of evolutionary trajectories of major eucaryotic phytoplankton for the past 205 million years our analysis indicates that changes in phytoplankton community structure coupled with the opening of the atlantic ocean basin and global sea level rise increased the efficiency of organic carbon burial beginning in the early jurassic in turn this organic carbon burial increased the oxidation state of earth s surface while drawing down atmospheric co2 levels assuming no substantial negative feedbacks the net oxidation and co2 drawdown appear to be related to the opening phase of the current wilson cycle where the newly formed passive plate margins store organic matter for hundreds of millions of years this process should reverse during the closing phase of the wilson cycle when the continents reassemble and the atlantic ocean basin closes the associated oxidation and storage of organic matter have contributed to the long term depletion of co2 which was a key factor that selected c4 photosynthetic pathways in marine and terrestrial ecosystems in the latter part of the cenozoic these pathways increasingly influenced d 13 corg and ultimately contributed to the reversal of the long term trend in d 13 ccarb

marginal formation of de geer moraines and their implications to the dynamics of grounding line recession de geer moraine ridges occur in abundance in the coastal zone of northern sweden preferentially in areas with proglacial water depths in excess of 150 m at deglaciation from detailed sedimentological and structural investigations in machine dug trenches across de geer ridges it is concluded that the moraines formed due to subglacial sediment advection to the ice margin during temporary halts in grounding line retreat forming gradually thickening sediment wedges the proximal part of the moraines were built up in submarginal position as stacked sequences of deforming bed diamictons intercalated with glaciofluvial canal infill sediments whereas the distal parts were built up from the grounding line by prograding sediment gravity flow deposits distally interfingering with glaciolacustrine sediments the rapid grounding line retreat ca 400 m yr 1 was driven by rapid calving in turn enhanced by fast iceflow and marginal thinning of ice due to deforming bed conditions the spatial distribution of the moraine ridges indicates stepwise retreat of the grounding line it is suggested that this is due to slab and flake calving of the ice cliff above the waterline forming a gradually widening subaqueous ice ledge which eventually breaks off to a new grounding line followed by regained sediment delivery and ridge build up less

the peridotites of the kukes ophiolite albania structure and kinematics abstract structural study of the kukes ultramafic massif which belongs to the albanian mirdita zone is of great interest for reconstruction of alpine tectonic environments from bottom to top the following lithological succession is observed in the ultramafic mafic section harzburgites harzburgites with dunitic lenses dunites an intermediate zone and gabbros the ultramafic rocks are apparently weakly deformed the textures indicate a high temperature deformation and slight locally superimposed low temperature deformation this is confirmed by olivine lattice preferred orientation which indicates that 010 100 was the activated glide system in olivine i e at high temperature the kinematics of deformation have been determined from the lattice preferred orientation of olivine an inversion of the shear sense occurs at the base of the dunite zone and is interpreted as being due to asthenospheric flow a simple geometric reconstruction indicates that the kukes ultramafic massif could correspond to the eastern flank of a nnw sse orientated paleo ridge

the interpretation and classification of subglacially deformed materials abstract a general classification of subglacially deformed materials is proposed based on sediment properties and their relationship to styles of subglacial strain deformation till is defined as homogenized usually diamictic material formed by glacially induced shear of subsole materials three types are recognized type a formed by pervasive ductile deformation type b formed by brittle shear and comminution till produced by the reduction of void space by in situ crushing and abrasion the term glacitectonite is adopted for materials that have undergone subglacial shear but retain some of the structural characteristics of the parent material original structures may be truncated by glacitectonic fabric elements type a or distorted but not truncated type b the principles of strain and material response particle orientation mechanisms fabric development and drainage conditions are reviewed examples of deformation tills and glacitectonites from breidamerkurjokull iceland slettmarkbreen norway loch lomond scotland and east yorkshire england are used to illustrate the nature of subglacially deformed materials and their relationship to former subglacial strain and drainage conditions the geologic evidence suggests a continuum of bed strengths can be recognized in deforming substrata ranging from high strength low strain type b deformation till and comminution till to low strength high strain type a deformation till

preservation of elemental and isotopic source identification of sedimentary organic matter the amount and type of organic matter in the sediments of lakes and oceans contribute to their paleoenvironmental and paleoclimatological records only a small fraction of the initial aquatic organic matter survives destruction and alteration during sinking and sedimentation selective degradation modifies the character of the surviving small fraction of organic matter which becomes incorporated in bottom sediments organic matter alterations can continue to sub bottom depths of hundreds of meters corresponding to millions of years source and paleoenvironmental information nonetheless remains preserved in the molecular elemental and isotopic compositions of organic matter c n and 13c values of total organic matter in particular appear to retain paleoenvironmental information for multi myr time periods

osmium isotope evidence for the regulation of atmospheric co2 by continental weathering the long term stability of earth9s climate throughout the phanerozoic stands in marked contrast to the dramatic fluctuations that have taken place on time scales as short as a few years reflecting the high efficiency of longer term climate regulation through negative feedbacks a fundamental mechanism is thought to involve control of co 2 in the ocean atmosphere system through continental weathering although unambiguous high resolution data supporting this hypothesis have hitherto not been available organic rich mud rocks from yorkshire england which were deposited during the toarcian oceanic anoxic event ca 181 ma early jurassic contain evidence of an exceptionally large excursion in the 187 os 188 os ratio of contemporaneous seawater from 0 4 to 1 0 the most likely explanation for this excursion is that it resulted from a transient increase in global continental weathering rates of 400 800 the os isotope excursion coincided with a well documented global 13 c excursion of 6 that affected all the major biospheric reservoirs of the time higher mean global temperatures caused global chemical weathering rates to increase substantially while in turn chemical weathering was very effective in reducing the elevated levels of atmospheric co 2 and the high temperatures to preexcursion levels

massive dissociation of gas hydrate during a jurassic oceanic anoxic event in the jurassic period the early toarcian oceanic anoxic event about 183 million years ago is associated with exceptionally high rates of organic carbon burial high palaeotemperatures and significant mass extinction heavy carbon isotope compositions in rocks and fossils of this age have been linked to the global burial of organic carbon which is isotopically light in contrast examples of light carbon isotope values from marine organic matter of early toarcian age have been explained principally in terms of localized upwelling of bottom water enriched in 12c versus 13c refs 1 2 5 6 here however we report carbon isotope analyses of fossil wood which demonstrate that isotopically light carbon dominated all the upper oceanic biospheric and atmospheric carbon reservoirs and that this occurred despite the enhanced burial of organic carbon we propose that as has been suggested for the late palaeocene thermal maximum some 55 million years ago the observed patterns were produced by voluminous and extremely rapid release of methane from gas hydrate contained in marine continental margin sediments

a case for a comet impact trigger for the paleocene eocene thermal maximum and carbon isotope excursion abstract we hypothesize that the rapid onset of the carbon isotope excursion cie at the paleocene eocene boundary 55 ma may have resulted from the accretion of a significant amount of 12c enriched carbon from the impact of a 10 km comet an event that would also trigger greenhouse warming leading to the paleocene eocene thermal maximum and possibly thermal dissociation of seafloor methane hydrate indirect evidence of an impact is the unusual abundance of magnetic nanoparticles in kaolinite rich shelf sediments that closely coincide with the onset and nadir of the cie at three drill sites on the atlantic coastal plain after considering various alternative mechanisms that could have produced the magnetic nanoparticle assemblage and by analogy with the reported detection of iron rich nanophase material at the cretaceous tertiary boundary we suggest that the cie occurrence was derived from an impact plume condensate the sudden increase in kaolinite is thus thought to represent the redeposition on the marine shelf of a rapidly weathered impact ejecta dust blanket published reports of a small but significant iridium anomaly at or close to the paleocene eocene boundary provide supportive evidence for an impact

isotopic signals from callovian kimmeridgian middle upper jurassic belemnites and bulk organic carbon staffin bay isle of skye scotland abstract the stable isotope data presented here significantly extend and expand upon previous isotopic investigations of the middle to late jurassic interval the belemnite samples collected from the staffin bay and staffin shale formations from the isle of skye scotland yielded oxygen isotope values consistent with callovian kimmeridgian palaeotemperatures of 6 7 20 6 c the carbon isotope data comprise one of the first moderately high resolution investigations of the relationship between terrestrial 13 c org predominantly fossil wood debris and marine 13 c carb belemnites as derived from a geologically coeval record the staffin bay data reveal a broad early to mid oxfordian positive carbon isotope excursion the excursion maximum occurs in the cordatum zone british boreal ammonite zonation although high values persist into the tenuiserratum zone the correspondence between the marine and terrestrial records indicates a strong coupling of the ocean atmosphere system and suggests that the total exchangeable carbon reservoir would have been affected at this time the mid oxfordian negative carbon isotope excursions identified in published tethyan records and commonly attributed to methane release are not recorded in the staffin bay data which may suggest that the tethyan excursions do not represent fluctuations in the global carbon reservoir and that the fidelity of the methane hypothesis should be re evaluated supplementary material isotopic and geochemical data are available at http www geolsoc org uk sup18339

geodynamic evolution of ophiolites from albania and greece dinaric hellenic belt one two or more oceanic basins all the geological constraints for an exhaustive reconstruction of the triassic to tertiary tectonic history of the southern dinaric hellenic belt can be found in albania and greece this article aims to schematically reconstruct this long tectonic evolution primarily based on a detailed analysis of the tectonic setting the stratigraphy the geochemistry and the age of the ophiolites in contrast to what was previously reported in the literature we propose a new subdivision on a regional scale of the ophiolite complexes cropping out in albania and greece this new subdivision includes six types of ophiolite occurrences each corresponding to different tectonic units derived from a single obducted sheet these units are represented by 1 sub ophiolite melange 2 triassic ocean floor ophiolites 3 metamorphic soles 4 jurassic fore arc ophiolites 5 jurassic intra oceanic arc ophiolites and 6 jurassic back arc basin ophiolites the overall features of these ophiolites are coherent with the existence of a single though composite oceanic basin located east of the adria pelagonian continental margin this oceanic basin was originated during the middle triassic and was subsequently early jurassic affected by an east dipping intra oceanic subduction this subduction was responsible for the birth of intra oceanic arc and back arc oceanic basins separated by a continental volcanic arc during the early to middle jurassic from the uppermost middle jurassic to the early cretaceous an obduction developed during which the ophiolites were thrust westwards firstly onto the neighboring oceanic lithosphere and then onto the adria margin

icelandic jokulhlaup impacts implications for ice sheet hydrology sediment transfer and geomorphology abstract glaciers and ice sheets erode entrain and deposit massive quantities of debris fluxes of subglacial meltwater exert a fundamental control on ice dynamics and sediment transport budgets within many glacial systems outburst floods jokulhlaups constitute high magnitude high frequency fluxes of meltwater relative to normal ablation controlled discharge this paper presents a synthesis of research on recent icelandic jokulhlaups and their geomorphological and sedimentary impact we identify jokulhlaup impacts within subglacial englacial and proglacial settings and discuss their wider significance for ice sheet hydrology sediment transfer and geomorphology because jokulhlaups erode deposit and re work sediment simultaneously they usually cause significant glaciological and sedimentological impacts jokulhlaups that propagate as subglacial flood waves often produce widespread hydromechanical disruption at the glacier base recent icelandic jokulhlaups have been recognised as highly efficient agents of reworking subglacial sediment and glacial sediment entrainment models of jokulhlaup impact therefore need to encompass the sub and englacial environment in addition to the proglacial zone where research has traditionally been focussed most jokulhlaups transport sediment to proglacial sandar and often directly to oceans where preservation potential of the impact is greater proglacial jokulhlaup deposits form distinctive sedimentary assemblages coupled with suites of high energy erosional landforms this study of modern jokulhlaup processes and sedimentary products may be useful for the interpretation of meltwater processes associated with quaternary ice sheets

what drove sea level fluctuations during the mid cretaceous greenhouse climate the major states in which earth s climate operates i e icehouse greenhouse and hothouse are epochs of tens of millions of years these states set long term boundary conditions that need to be considered for climate and sea level interpretations this paper summarizes the conceptual models for hydrological cycling derived from the characteristics of these three climate states while glacio eustatic forcing of sea level changes under icehouse climate conditions is fairly well understood the drivers of eustatic sea level fluctuations under greenhouse conditions remain enigmatic this lack of understanding may be related to incoherencies in the current ideas about the impact of accelerated hydrological cycling on sea level under greenhouse climate conditions as an example for a greenhouse climate we review evidences that link proxies for climate and sea level for the intensely studied but controversially discussed mid cretaceous sea level history based on sequence stratigraphy and a recently published high precision timescale we demonstrate that the late middle turonian pewsey 13c isotope maximum represents a major transgression not a regression as previously stated which conflicts with the interpretation of a co occurring 18o maximum to reflect a short glacial episode this contradiction can be solved by the concept presented here that dominance of aquifer eustasy characterized sea level forcing during the turonian greenhouse climate despite a possible though contentious sporadic presence of minor ice sheets the effects of temperature and ice volume both lead to a pronounced 18ocarb maximum during glacio eustatic regressions in contrast the opposing effects of temperature and groundwater volume on oxygen isotope fractionation lead to a 18ocarb maximum during aquifer eustatic transgressions we suggest that throughout earth history both aquifer eustatic and glacio eustatic forcing formed a combined sea level response with dominance of aquifer eustasy being typical for the greenhouse climate mode during the icehouse mode aquifer eustasy apparently remains active as a background process but is outpaced by the glacio eustatic effect

the timing of paleoenvironmental change and cause and effect relationships during the early jurassic mass extinction in europe the early jurassic marine mass extinction is one of several crises thought to coincide with anoxia transgression and warming caused by catastrophic release of gas hydrates however high resolution study of expanded sections in yorkshire england reveal that only the first of these factors is truly coincidental with extinction the well known transgression and large negative carbon isotope perturbation attributed to massive release of methane from gas hydrates occur after these events the anoxic event is developed diachronously in the european area with anoxia developing and fading away earlier in the mediterranean region compared with the nw european record however for a brief interval in the mid semicelatum subzone anoxia was simultaneously developed throughout the european region and it is this time that is marked by extinction of both benthic and pelagic marine fossils the sea level curve is also more complex than hitherto assumed with a minor regression occurring late in the semicelatum subzone shortly after the extinction the toarcian crisis occurred during a phase of global warming but the postulated release of methane from gas hydrates is too late to be implicated in the extinction mechanism as indeed is a recently reported cooling event from within the warming trend

nitrogen isotope evidence for water mass denitrification during the early toarcian jurassic oceanic anoxic event bulk sedimentary nitrogen isotope 15ntot data have been generated from lower jurassic black carbon rich shales in the british isles and northern italy deposited during the early toarcian oceanic anoxic event a pronounced positive 15ntot excursion through the exaratum subzone of the falciferum zone defined by characteristic ammonites in the british isles broadly correlates with a relative maximum in weight percent total organic carbon and in some sections with a negative 13corg excursion upwelling of a deoxygenated water mass that had undergone partial denitrification is the likely explanation for relative enrichment of 15ntot and parallels may be drawn with quaternary sediments of the arabian sea gulf of california and northwest mexican margin the development of early toarcian suboxic water masses and consequent partial denitrification is attributed to increases in organic productivity approximately coincident phenomena include the following a relative climatic optimum realignment of major oceanic current systems and a possible release of methane gas hydrates from continental margin sediments early in the history of the oceanic anoxic event

sedimentary and stratigraphic evidence for subglacial flooding south central michigan usa abstract the glacial landscape in south central michigan is a dissected surface with streamlined residual and upland blocks surrounded by lowland valleys dominated by outwash the upland surface has ridges hills and hummocks composed of boulder gravel which are transitional to drumlins in a down ice direction and is dissected by tunnel channels with eskers within them sedimentary descriptions from 14 gravel pits indicate a consistent stratigraphy across a width of 15 km the upland consists of bedrock covered by a lower till with subglacial melt out or lodgment characteristics above the lower till is a sand and gravel facies that passes upward into a boulder gravel facies nestled within depressions on the boulder gravel surface is a discontinuous facies of laminated sand and silt above the gravel is an upper till with supraglacial melt out and flow till characteristics analyses of the till and gravel indicate an upward change in clast lithology from locally derived carbonates to clastics and finally to crystallines from the lower till through the gravel facies into the upper till the transition mimics the bedrock lithology up ice of the study area and is explained by meltwater erosion of bedrock previously deposited subglacial sediment and overlying debris rich basal ice the systematic change in clast lithology and the stratigraphic position of the gravel facies between a subglacial and supraglacial till strongly suggests that the gravel facies sediment was deposited subglacially and that the entire till gravel till sequence resulted from the same glacial advance

release of methane from a volcanic basin as a mechanism for initial eocene global warming a 200 000 yr interval of extreme global warming marked the start of the eocene epoch about 55 million years ago negative carbon and oxygen isotope excursions in marine and terrestrial sediments show that this event was linked to a massive and rapid approximately 10 000 yr input of isotopically depleted carbon it has been suggested previously that extensive melting of gas hydrates buried in marine sediments may represent the carbon source and has caused the global climate change large scale hydrate melting however requires a hitherto unknown triggering mechanism here we present evidence for the presence of thousands of hydrothermal vent complexes identified on seismic reflection profiles from the voring and more basins in the norwegian sea we propose that intrusion of voluminous mantle derived melts in carbon rich sedimentary strata in the northeast atlantic may have caused an explosive release of methane transported to the ocean or atmosphere through the vent complexes close to the palaeocene eocene boundary similar volcanic and metamorphic processes may explain climate events associated with other large igneous provinces such as the siberian traps approximately 250 million years ago and the karoo igneous province approximately 183 million years ago

melt out till and ribbed moraine formation a case study from south sweden abstract hummocky moraine with dispersed agglomerations of ribbed moraine here named asnen type ribbed moraine forms a 20 40 km wide zone over smaland south sweden terminated to the north by a sharp boundary to streamlined terrain the hummocky ribbed moraine zone can be geomorphologically linked to the subaqueous goteborg moraine formed at an oscillation stand still phase during the deglaciation of the swedish west coast based on detailed sedimentological and structural investigations of ribbed moraine ridges it is concluded that diamict sequences and associated sorted sediment were deposited due to passive melt out from stagnant debris rich ice with synsedimentary deposition of sorted sediments preferentially at a melting ice bed interface to accommodate for the geomorphological expression such an interpretation further implies that debris rich ice formed in an intermediate adfreezing zone between ice at the pressure melting point and a frontal frozen zone at deglaciation basal debris rich ice was stacked into transversally arranged zones controlled moraine forming ribbed moraine embryos the active phase of ridge formation the stacked sequences of debris rich ice eventually melted out beneath a stable and melt retarding supraglacial ablation complex to form the final moraine ridges the passive phase of ridge formation in areas with no stable supraglacial ablation complex the resulting landform after final de icing was a hummocky moraine landscape internal composition of moraine hummocks suggests that most of them are composed of sediment gravity flow sediments intercalated with stream deposited sediments all resting on a platform of subglacial melt out till de icing of the zone now occupied by hummocky and ribbed moraine took a considerable time deglacial 14 c age differences from lake basins on either side of the geomorphic boundary to the streamlined terrain indicate a separation between active and stagnant ice along that boundary and that it took another 200 300 yr for the stagnant ice zone to melt during the final formation of present day landforms

climate induced fluctuations in sea level during non glacial times during periods of time when the earth supports ice caps sea level fluctuates periodically at intervals of 104 105 yr with amplitudes of tens to more than 100 metres these fluctuations result from expansions and contractions of continental ice sheets that occur in phase with the milankovitch periodicities of the earth s orbit1 2 smaller amplitude sea level fluctuations associated with milankovitch periodicities are also evident during warm periods such as the late triassic3 5 which lack strong evidence for continental glaciation6 we argue here that in times of limited ice volume periodic climate induced changes in lake and groundwater storage have the potential to produce small fluctuations in sea level this mechanism could contribute a small component of the sea level change observed in the quaternary period and may dominate the milankovitch eustatic sea level signal during earlier periods with limited ice volume6 we present evidence of contemporaneous milankovitch periodicities in late triassic lake sediments7 and sea level fluctuation3 5 which support the causal link between lake water storage and eustasy

review short term sea level changes in a greenhouse world a view from the cretaceous abstract this review provides a synopsis of ongoing research and our understanding of the fundamentals of sea level change today and in the geologic record especially as illustrated by conditions and processes during the cretaceous greenhouse climate episode we give an overview of the state of the art of our understanding on eustatic global versus relative regional sea level as well as long term versus short term fluctuations and their drivers in the context of the focus of unesco iugs igcp project 609 on cretaceous eustatic short term sea level and climate changes we evaluate the possible evidence for glacio eustasy versus alternative or additional mechanisms for continental water storage and release for the cretaceous greenhouse and hothouse phases during which the presence of larger continental ice shields is considered unlikely increasing evidence in the literature suggests a correlation between long period orbital cycles and depositional cycles that reflect sea level fluctuations implying a globally synchronized forcing of eustatic sea level fourth order depositional sequences seem to be related to a 405 ka periodicity which most likely represents long period orbital eccentricity control on sea level and depositional cycles third order cyclicity expressed as time synchronous sea level falls of 20 to 110 m on 0 5 to 3 0 ma timescales in the cretaceous are increasingly recognized as connected to climate cycles triggered by long term astronomical cycles that have periodicity ranging from 1 0 to 2 4 ma future perspectives of research on greenhouse sea level changes comprise a high precision time scale for sequence stratigraphy and eustatic sea level changes and high resolution marine to non marine stratigraphic correlation

paleogene plants fractionated carbon isotopes similar to modern plants the carbon isotope composition 13c 13c of terrestrial plant biomarkers such as leaf waxes and terpenoids provides insights into past carbon cycling the 13c 13c values of modern plant biomarkers are known to be sensitive to climate and vegetation type both of which influence fractionation during lipid biosynthesis by altering plant carbon supply and its biochemical allocation it is not known if fractionation observed in living plants can be used to interpret fossil lipids because plant biochemical characteristics may have evolved during the cenozoic in response to changes in global climate and atmospheric co2 the goal of this study was to determine if fractionation during photosynthesis leaf leaf in the paleogene was consistent with expectations based on living plants to study plant fractionation during the paleogene we collected samples from eight stratigraphic beds in the bighorn basin wyoming usa that ranged in age from 63 to 53 ma for each sample we measured the 13c 13c of angiosperm biomarkers triterpenoids and n alkanes and abundance permitting conifer biomarkers diterpenoids leaf 13c 13c values estimated from different angiosperms biomarkers were consistently 2 lower than leaf 13c 13c values for conifers calculated from diterpenoids this difference is consistent with observations of living conifers and angiosperms and the consistency among different biomarkers suggests ancient elipidelipid values were similar to those in living plants from these biomarker based 13cleaf 13cleaf values and independent records of atmospheric 13c 13c values we calculated leaf leaf these calculated leaf leaf values were then compared to leaf leaf values modeled by applying the effects that precipitation and major taxonomic group in living plants have on leaf leaf values calculated and modeled leaf leaf values were offset by less than a permil this similarity suggests that carbon fractionation in paleogene plants changed with water availability and major taxonomic group to about the same degree it does today further paleoproxy data suggest at least two of the stratigraphic beds were deposited at times when pco2pco2 levels were higher than today biomarker data from these beds are not consistent with elevated leaf leaf values possibly because plants adapted carbon uptake and assimilation characteristics to pco2pco2 changes over long timescales

drumlinization and drumlin forming instabilities viscous till mechanisms glacially induced flow naturally tends to thin and extended till cover through shock formation even in the absence of longitudinal gradients in the applied stress thicker till cover has an increased effective pressure at its surface and base a lower sliding velocity or deformation rate and above a critical thickness a decrease in wave velocity with thickness leading to reverse facing shocks moving downstream for sliding and for some theologies of internal deformation a decrease in sediment flux with thickness occurs implying backward moving kinematic waves and reverse facing reverse moving shock downstream facing shocks are also formed which move upstream if the till is sliding and downstream if the till is deforming internally eventually shocks coalesce leaving an upstream lacing shock for sliding and a downstream facing shock for internal deformation it is observed that some drumlins have downstream blunt ends only fairly realistic three dimensional drumlin shapes can be produced from symmetric sediment bodies and barchan shapes can be produced from linear forms perpendicular to the ice sheet flow the fact that viscous theories produce drumlinoid forms suggests that on this scale till behaves viscously and the the lower length scale for drumlins represents the plastic viscous transition scale

petrology and texture of the ultramafic rocks of the xigaze ophiolite tibet constraints for mantle structure beneath slow spreading ridges abstract the xigaze ophiolite southern tibet exhibits an unusual ophiolite sequence characterized by 1 1 the limited thickness less than 3 km of its crustal unit which is mostly composed of dolerite intrusives the gabbros being very scarce 2 2 the scarcity of harzburgites and dunites the ultramafic rocks consisting mostly of cr diopside bearing harzburgites and iherzolites although there are some textural and chemical variations from the basal iherzolites to the upper harzburgite and dunites no sharp discontinuity exists between the peridotite series of the xigaze ophiolite which all belong to the same peridotite suite the peridotites have been equilibrated at relatively low temperatures and pressures 1155 c 0 5 0 6 gpa for the cr diopside bearing harzburgites and 1255 c 1 0 1 1 gpa for the stratigraphically 2 km deeper iherzolites indicative of a low thermal gradient at the xigaze paleo ridge accordingly the peridotites have locally been deformed under low stress 0 2 gpa conditions and at decreasing temperatures from up to 1000 c to 900 800 c as evidenced by the activation of the 010 100 ok1 100 and 001 100 olivine glide systems the equilibrium temperatures and pressures estimated for the peridotites the inferred shape of the melting zone beneath the xigaze paleo ridge the low temperature low stress conditions inferred for the deformation of the peridotites and the pattern of the mantle structure determined on the basis of structural and microstructural data are in good agreement with a slow spreading ridge origin for the xigaze ophiolite

astronomical forcing and chronology of the early toarcian early jurassic oceanic anoxic event in yorkshire uk 1 during the early toarcian 183 ma ago a high rate of organic carbon burial globally over a brief interval of time has led to the recognition of a major oceanic anoxic event oae a pronounced negative excursion in the carbon isotope composition of marine organic matter marine carbonate and terrestrial plant material is a key feature of this event but the precise timescale and cause s of this isotopic anomaly are debated associated with the negative carbon isotope excursion is evidence for a coeval rise in seawater palaeotemperature an increase in continental weathering rates and the mass extinction of marine invertebrate species the early toarcian oae provides evidence for the earth s response during rapid climate change and critical to our understanding of the event is a high resolution timescale that allows us to quantify the rates duration and lead lag times of environmental processes in this study we present 2743 new high resolution organic carbon sulphur and carbonate concentration data from samples of well preserved organic rich mudrocks spanning the early toarcian oae in yorkshire uk we have used these data to document the geochemical changes and significantly extend and refine the astronomical timescale across this event our detailed analysis of the relationship between astronomical forcing and carbon isotope changes in both yorkshire and a section from peniche portugal indicates that astronomical forcing paced the timing of major shifts in 13c and hence climate in both sections our analyses also demonstrate that there was a marked increase in the relative strength of astronomical forcing recorded at the onset of the oae and that the recorded nature of astronomical forcing changed during the event both the yorkshire and peniche cyclostratigraphies suggest that one astronomical forcing parameter paced environmental change through the 13c event and that this parameter was obliquity or precession

glacioeustatic fluctuations the mechanism linking stable isotope events and sequence stratigraphy from the early oligocene to middle miocene one of the most difficult challenges of sequence stratigraphy is the establishment of synchronism between events observed in widely separated basins problems arise because the resolution of the best stratigraphic methods is not good enough to establish the synchronism of similar aged events on a global scale unless a common mechanism affecting global eustasy is assumed such as variations in the ice volume there is no a priori reason to expect that sequences of similar age in widely separated basins are indeed synchronous the stable oxygen isotope composition of marine carbonates is a proxy for sea level which has been underutilized in sequence stratigraphy identification of isotope events is based on d sup 18 o data from dsdp and odp sites 522 529 563 608 and 747 drilled in the atlantic and indian oceans these records were used to define oligocene and miocene oxygen isotope zones in addition we present isotope data from petrobras well a drilled in the campos basin brazil ages of isotope events correspond well with the ages of sequence boundaries and maximum flooding surfaces because of the good correlation between the isotope and sequence stratigraphic records we reconfirm that ice volume change is the common mechanism driving sea level fluctuations from the oligocenemore to present less

the structures of two ophiolite massifs bay of islands newfoundland a model for the oceanic crust and upper mantle abstract for a detailed analysis of their main structures accumulation planes foliation planes and lineations the peridotite gabbro units of table mountain and blow me down mountain bay of islands newfoundland have been divided into several structural units each one being characterized by specific microstructures of deformation or accumulation a fishbone pattern with the accumulation plane in the mafic cumulates dipping toward the ridge and the foliation plane in the ultramafic tectonites dipping away from it is postulated for the structure of the lithosphere formed at a spreading center the tectonic structures in the peridotites are related to asthenospheric flow in the uppermost mantle and the direction of the ridge is inferred from the lineation trend in the peridotites the structures in the cumulates are related to subsidence of the magma chamber floor during spreading at the base of the massifs the tectonic structures in the mafic metamorphic rocks are parallel to those observed the latter have been deformed at moderate temperatures under high stresses and display mylonitic textures at their contact with the mafic tectonites from these superimposed textures we infer a kinematic model for the oceanic thrusting of the lithosphere the direction of thrusting is given by the lineation trend and its sense by the analysis of shear all these data are combined into a paleogeographic scheme for the newfoundland caledonides

secular variation in late cretaceous carbon isotopes a new δ13c carbonate reference curve for the cenomanian campanian 99 6 70 6 ma carbon stable isotope variation through the cenomanian santonian stages is characterized using data for 1769 bulk pelagic carbonate samples collected from seven chalk successions in england the sections show consistent stratigraphic trends and 13c values that provide a basis for highresolution correlation positive and negative 13cexcursions and inflection points on the isotope profiles are used to define 72 isotope events key markers are provided by positive 13c excursions of up to 2 the albian cenomanianboundary event mid cenomanian event i thecenomanian turonian boundary event the bridgewick hitch wood and navigation events of late turonian age and the santonian campanian boundary event isotope events are isochronous within a framework provided by macrofossil datum levels and bentonite horizons an age calibrated composite 13c reference curve and an isotope event stratigraphy are constructed using data from the english chalk the isotope stratigraphy is applied to successions in germany france spain and italy correlation with pelagic sections at gubbio central italy demonstrates general agreement between biostratigraphic and chemostratigraphic criteria in the cenomanian turonian stages confirming established relationships between tethyan planktonic foraminiferal and boreal macrofossil biozonations correlation of the coniacian santonian stages is less clear cut magnetostratigraphic evidence for placing the base of chron 33r near the base of the upper santonian is in good agreement with the carbon isotope correlation but generates significant anomalies regarding the placement of the santonian and campanian stage boundaries with respect to tethyan planktonic foraminiferal and nannofossil zones isotope stratigraphy offers a more reliable criterion for detailed correlation of cenomanian santonian strata than biostratigraphy with the addition of campanian 13c data from one of the english sections a composite cenomanian campanian age calibrated reference curve is presented that can be utilized in future chemostratigraphic studies the cenomanian campanian carbon isotope curve is remarkably similar in shape to supposedly eustatic sea level curves increasing 13c values accompanying sea level rise associated with transgression and falling 13c values characterizing sea level fall and regression the correlation between carbon isotopes and sea level is explained by variations in epicontinental sea area affecting organic matter burial fluxes increasing shallow sea floor area and increased accommodation space accompanying sea level rise allowedmore efficient burial ofmarine organic matter with the preferential removal of 12c from the marine carbon reservoir during sea level fall reduced seafloor area marine erosion of previously deposited sediments and exposure of basin margins led to reduced organiccarbon burial fluxes and oxidation of previously deposited organic matter causing falling 13c values additionally drowning of carbonate platforms during periods of rapid sea level rise may have reduced the global inorganic relative to the organic carbon flux further enhancing 13c values while renewed platform growth during late transgressions and highstands prompted increased carbonate deposition variations in nutrient supply changing rates of oceanic turnover and the sequestration or liberation of methane from gas hydrates may also have played a role in controlling carbon isotope ratios

subglacial water sheet floods drumlins and ice sheet lobes the effect of subglacial lakes upon ice sheet topography and the velocity patterns of subglacial water sheet floods is investigated a subglacial lake in the combined michigan green bay basin great lakes north america leads to 1 an ice sheet lobe in the lee of lake michigan 2 a change in orientations offlood velocities across the site of a supraglacial trough aligned closely with green bay in agreement with drumlin orientations 3 low water velocities in the lee of lake michigan where drumlins are absent and 4 drumlinization occurring in regions of predicted high water velocities the extraordinary divergence of drumlin orientations near lake ontario is explained by the presence of subglacial lakes in the ontario and erie basins along with ice sheet displacements of up to 30 km in eastern lake ontario the megagrooves on the islands in western lake erie are likely to be the product of the late stage of a water sheet flood when outflow from eastern lake ontario was dammed by displaced ice and instead flowed westward along the erie basin the finger lakes of northern new york state northeastern u s a occur in a region of likely ice sheet grounding where water sheets became channelized green bay and grand traverse bay are probably the products of erosion along paths of strongly convergent water sheet flow

grain size distribution and rheology of the upper mantle abstract the physical processes that govern the grain size of rocks in the upper mantle are examined the analysis is based on the experimental data on creep recrystallization and grain growth in dunites and on a theoretical model for the thermomechanical structure of the cooling moving lithosphere the grain size of rocks is shown to be determined by the in situ stress only at the deeper part where the temperature is high enough to allow significant strain rate above this depth the microstructures record the thermomechanical history of rocks rather than the in situ stress in the case of the oceanic lithosphere where the thermomechanical history is best known the following features of grain size distribution are found at the uppermost mantle where the amount of grain growth is limited the grain size is determined by the initial value and the growth rate and where the effect of grain growth dominates it increases with depth when the amount of grain growth becomes large and the grain size reaches the steady state size corresponding to the ambient stress while the rock is hot enough to deform the grain size is then determined by the applied stress this grain size is however frozen when the rock gets cool and the strain rate becomes too small to induce any further dynamic recrystallization thus at the intermediate depth region the grain size records the fossil frozen stress at which the microstructures of rock have been frozen since the frozen stress increases with age the grain size in this depth interval decreases with depth finally the grain size below this level reflects the in situ stress and increases with depth its extent being dependent on the nature of return flow in the deep mantle thus the grain size versus depth relation may show a sigmoid curve the qualitative features of this curve may be similar also in the case of the continental lithosphere if a similar thermal event i e the intrusion of hot material and subsequent cooling occurs the results are quite consistent with the observed depth variation of olivine grain size in peridotite nodules ave lallemant et al 1980 the present model suggests that the depth of minimum grain size 65 and 150 km at the continental rift zone and the shield region respectively corresponds to that where the mechanical properties of the upper mantle change from elastic to ductile at tectonic stress levels 1 mpa and in the geological time scale this result leads to a new definition of the thickness of lithosphere in terms of its rheological properties this thickness is about twice as large as that inferred from the flexure of lithosphere but approximately equal to seismic thickness the model suggests the importance of grain growth as well as dynamic recrystallization and plastic flow in determining the texture of upper mantle rocks and therefore seismic anisotropy

basinal restriction black shales re os dating and the early toarcian jurassic oceanic anoxic event 1 profiles of mo total organic carbon toc through the lower toarcian black shales of the cleveland basin yorkshire united kingdom and the posidonia shale of germany and switzerland reveal water mass restriction during the interval from late tenuicostatum zone times to early bifrons zone times times which include that of the putative early toarcian oceanic anoxic event the degree of restriction is revealed by crossplots of mo and toc concentrations for the cleveland basin which define two linear arrays with regression slopes ppm of 0 5 and 17 the slope of 0 5 applies to sediment from the upper semicelatum and exaratum subzones this value which is one tenth of that for modern sediments from the black sea mo toc regression slope 4 5 reveals that water mass restriction during this interval was around 10 times more severe than in the modern black sea the renewal frequency of the water mass was between 4 and 40 ka the mo toc regression slope of 17 applies to the overlying falciferum and commune subzones the value shows that restriction in this interval was less severe and that the renewal frequency of the water mass was between 10 and 130 years the more restricted of the two intervals has been termed the early toarcian oceanic anoxic event but is shown to be an event caused by basin restriction local to nw europe crossplots of re os and mo against toc show similar trends of increasing element concentration with increase in toc but with differing slopes together with modeling of 187 os 188 os and d 98 mo the element toc trends show that drawdown of re os and mo was essentially complete during upper semicelatum and exaratum subzone times mo toc regression slope of 0 5 drawdown sensitized the restricted water mass to isotopic change forced by freshwater mixing so that continental inputs of re os and mo via a low salinity surface layer created isotopic excursions of up to 1 3 in d 98 mo and up to 0 6 for 187 os 188 os restriction thereby compromises attempts to date toarcian black shales and possibly all black shales using re os chronology and introduces a confounding influence in the attempts to use d 98 mo and initial 187 os 188 os for palaeo oceanographic interpretation

the meltwater hypothesis for subglacial bedforms this paper presents an historical and in places informal account of the meltwater hypothesis which invokes enormous outburst floods for the formation of subglacial bedforms it begins with a brief discussion of the difficulties of determining processes of formation for landforms which are not seen in formation analogy provides a solution to these difficulties analogy between erosional marks at the bases of turbidites and drumlins which were the starting point for this hypothesis rests on the idea that inverted erosional marks at the ice bed are subsequently infilled to form drumlins field tests on the sedimentology architecture and landform associations of drumlins in the livingstone lake drumlin field are outlined before more extensive work on bedrock erosional forms and flood routes is introduced bedrock erosional forms played a central part in establishing the hypothesis since their form and ornamentation are confidently interpreted as fluvial their form and genesis are discussed mainly with reference to sites at french river and wilton creek ontario though some remarkable bedrock erosional forms in antarctica support their regional extent initially in the meltwater hypothesis drumlins were thought to be cavity fills and erosional drumlins were recognized later this development is shown to be central to the realization that drumlin composition may be inferred from drumlin form the scale of drumlin fields measured at about 10 3 km 2 and the magnitude of the inferred floods require that the flood events were regional regional scale flood tracts in ontario quebec alberta and the northwest territories extending over 1000 km in length and several hundred kilometers in width support this suggestion floods had they occurred would have caused rapid rates of sea level rise and may have changed climate through their effects on ocean stratification and sea surface temperatures the meltwater hypothesis covers a range of bedforms besides drumlins and bedrock erosional marksffluting rogen moraine hummocky terrain and transverse ridges recent work shows how these forms are best explained by the meltwater hypothesis the roles of water storage and release which underpin the theory of the meltwater hypothesis remain poorly understood r 2002 published by elsevier science ltd

tempo and scale of late paleocene and early eocene carbon isotope cycles implications for the origin of hyperthermals abstract the upper paleocene and lower eocene are marked by several prominent 1 carbon isotope 13c excursions cie that coincide with transient global warmings or thermal maxima including the paleocene eocene thermal maximum petm the cie which are recorded mainly in marine sedimentary sequences have also been identified in continental sequences occurred episodically and yet appear to be paced or triggered by orbital forcing to constrain the timing and scale of the cie relative to long term baseline variability we have constructed a 4 52 million year myr long high resolution 3 kyr bulk sediment carbon isotope record spanning the lower eocene to upper paleocene c25r c24n from a pelagic sediment section recovered at odp site 1262 in the southeast atlantic this section which was orbitally tuned utilizing high resolution core log physical property and geochemical records is the most stratigraphically complete upper paleocene to lower eocene sequence recovered to date time series analysis of the carbon isotope record along with a high resolution fe intensity record obtained by xrf core scanner reveal cyclicity with variance concentrated primarily in the precession 21 kyr and eccentricity bands 100 and 400 kyr throughout the upper paleocene lower eocene in general minima in 13c correspond with peaks in fe i e carbonate dissolution both of which appear to be in phase with maxima in eccentricity this covariance is consistent with excess oceanic uptake of isotopically depleted carbon resulting in lower carbonate saturation during periods of high eccentricity this relationship includes all late paleocene and early eocene cie confirming pacing by orbital forcing the lone exception is the petm which appears to be out of phase with the 400 kyr cycle though possibly in phase with the 100 kyr cycle reinforcing the notion that a mechanism other than orbital forcing and or an additional source of carbon is required to account for the occurrence and unusual scale of this event

effects of an oceanic anoxic event on the stable carbon isotopic composition of early toarcian carbon the early toarcian transgression is marked by the occurrence of organic carbon rich shales in large parts of western europe and in other parts of the world as well based on the positive carbon isotope excursion of pelagic limestones in the middle to upper part of the falciferum zone in several of the tethyan sections the widespread occurrence of the early toarcian shales was explained by an oceanic anoxic event oae jenkyns 1988 jenkyns and clayton 1997 the rapid burial of large amounts of organic carbon which is rich in 12 c would have led to a relative enrichment in 13 c of the global carbon reservoir and hence to an increase in delta 13 c of the limestones in southwest germany and a number of other locations both organic and inorganic carbon display a negative isotope excursion in the upper part of the tenuicostatum zone and the lower part of the falciferum zone synchronous to black shale deposition and predating the positive isotopic excursion kuspert 1982 1983 it is presently unclear what the exact cause for this widespread negative isotopic excursion is jenkyns and clayton 1997 the objective of our study was to examine if the negative carbon isotope excursion of organic matter om in the southwest german toarcian shales can be attributed to compositional changes of the om or if the excursion is related to variations in delta 13 c sub co2 aq in the photic zone to this end we analyzed the molecular and stable carbon isotope composition of om in ten samples spanning the early toarcian toc 2 5 10 5 percent hi 350 700 biomarker distributions and kerogen pyrolysates differ only slightly among the samples and delta 13 c values of primary production markers follow closely those of associated carbonate and kerogen delta 13 c sub carb toc this strongly suggests that differences in delta 13 c toc are related to differences in delta 13 c of co 2 aq in the photic zone supporting kuspert9s model of advection of isotopically light organic matter derived co 2 from anoxic bottom waters evidence for euxinic conditions extending into the photic zone was found by the presence of derivatives of carotenoids such as isorenieratane from anoxygenic phototrophic sulfur bacteria their concentrations are extremely low in black shales from the tenuicostatum zone but are significant in the falciferum and bifrons zone with a maximum in the exaratum subzone suggesting that photic zone euxinia pze was a common feature of the early toarcian sea in southwest germany our data therefore support the kuspert model of advection of isotopically light organic matter derived co 2 from anoxic bottom waters to the upper part of the photic zone resulting in a negative isotope spike the enrichment in 13 c in the middle of the falciferum zone which followed the negative spike may be attributed to the burial of isotopically light organic matter through worldwide black shale deposition