from greenhouse to icehouse organic walled dinoflagellate cysts as paleoenvironmental indicators in the paleogene abstract dinoflagellates are an important component of the extant eukaryotic plankton their organic walled hypnozygotic cysts dinocysts provide a rich albeit incomplete history of the group in ancient sediments building on pioneering studies of the late 1970s and 1980s recent drilling in the southern ocean has provided a wealth of new dinocyst data spanning the entire paleogene such multidisciplinary studies have been instrumental in refining existing and furnishing new concepts of paleogene paleoenvironmental and paleoclimatic reconstructions by means of dinocysts because dinocysts notably exhibit high abundances in neritic settings dinocyst based environmental and paleoclimatic information is important and complementary to the data derived from typically more offshore groups as planktonic foraminifera coccolithophorids diatoms and radiolaria by presenting case studies from around the globe this contribution provides a concise review of our present understanding of the paleoenvironmental significance of dinocysts in the paleogene 65 25 ma representing earth s greenhouse icehouse transition this episode holds the key to the understanding of extreme transient climatic change we discuss the potential of dinocysts for the reconstruction of paleogene sea surface productivity temperature salinity stratification and paleo oxygenation along with their application in sequence stratigraphy oceanic circulation and general watermass reconstructions

global dinoflagellate event associated with the late paleocene thermal maximum the late paleocene thermal maximum or lptm ca 55 ma represents a geologically brief time interval 220 k y characterized by profound global warming and associated environmental change the lptm is marked by a prominent negative carbon isotope excursion cie interpreted to reflect a massive and abrupt input of 12 c enriched carbon to the ocean atmosphere reservoir possibly as a result of catastrophic gas hydrate release on time scales equivalent to present day rates of anthropogenic carbon input the lptm corresponds to important changes in the global distribution of biota including mass extinction of marine benthic organisms the dinoflagellate cyst record indicates that surface dwelling marine plankton in marginal seas also underwent significant perturbations during the lptm we report on the dramatic response of representatives of the genus apectodinium from two upper paleocene lower eocene sections in the southern new zealand and northern austria hemispheres where the dinoflagellate records are directly correlated with the cie benthic foraminifera extinction event and calcareous nannofossil zonation the results indicate that the inception of apectodinium dominated assemblages appears to be synchronous on a global scale and that the event is precisely coincident with the beginning of the lptm apectodinium markedly declined in abundance near the end of the lptm this apectodinium event may be associated with 1 exceptionally high global sea surface temperatures and or 2 a significant increase in marginal marine surface water productivity such a globally synchronous acme of dinoflagellate cysts is unprecedented within the dinoflagellate cyst fossil record

atmospheric pco2 since 60 ma from records of seawater ph calcium and primary carbonate mineralogy a 60 m y record of atmospheric p co2 has been refined from knowledge of 1 secular changes in the major ion composition of seawater particularly ca and mg and 2 oscillations in the mineralogy of primary oceanic carbonate sediments both factors have had a significant impact on the chemistry of the ocean carbonate buffer system calculated atmospheric p co2 oscillated between values of 100 300 ppm and to maxima of 1200 2500 ppm from 60 to 40 ma and varied between 100 and 300 ppm from 25 ma to the present the refined p co2 values are significantly lower than previous estimates made from seawater ph data where total dissolved inorganic carbon was assumed constant and more in line with modeling and stomatal index estimations of atmospheric p co2 for the tertiary

diagenetic and catagenetic products of isorenieratene molecular indicators for photic zone anoxia a wide range of novel diagenetic and catagenetic products of the diaromatic carotenoid isorenieratene a pigment of the photosynthetic green sulphur bacteria chlorobiaceae has been identified in a number of sedimentary rocks ranging from ordovician to miocene compound identification is based on nmr mass spectrometry the presence of atropisomers and stable carbon isotopes atropisomers contain an axially chiral centre which in combination with other chiral centres results in two or more diastereomers that can be separated on a normal gc column chlorobiaceae use the reverse tca cycle to fix carbon so that their biomass is enriched in 13c high 13c contents of isorenieratene derivatives therefore support their inferred origins isorenieratene derivatives include c 40 c 33 and c 32 diaryl isoprenoids and short chain aryl isoprenoids with additional aromatic and or s containing rings c 33 and c 32 compounds are diagenetic products of c 33 and c 32 carotenoids formed from isorenieratene during early diagenesis through expulsion of toluene and m xylene respectively cyclisation of the polyene acyclic isoprenoid chain can proceed via an intramolecular diels alder reaction followed by aromatisation of the newly formed ring sulphurisation is also an important process during early diagenesis competing with expulsion and cyclisation sulphur bound isorenieratane is released during progressive diagenesis due to cleavage of relatively weak ss and cs bonds cleavage of c c bonds during aromatisation of newly formed rings and during catagenesis yields short chain compounds the inherent presence of a conjugated double bond system in carotenoids implies that similar diagenetic and catagenetic reactions can occur with all carotenoids chlorobiaceae live at or below the oxic anoxic boundary layer and require both light and h 2s the presence of isorenieratene or its diagenetic and catagenetic products in ancient sedimentary rocks and crude oils is therefore an excellent indication for photic zone anoxia in the depositional environment diagenetic and catagenetic products of isorenieratene are expected to find applications in reconstruction of palaeoenvironments and in oil oil and oil source rock correlation studies their presence in several petroleum source rocks suggests that anoxia is an important environmental parameter for the preservation of organic matter

late eocene to early oligocene dinoflagellate cysts from the priabonian type area northeast italy biostratigraphy and paleoenvironmental interpretation abstract marginal marine late eocene through early oligocene dinoflagellate cyst successions have been studied from the type area of the priabonian stage northeast italy the results allow the recognition of dinoflagellate zones previously defined in bio and magnetostratigraphically well calibrated pelagic sequences from central italy thus providing a first order correlation of the priabonian stage to the standard chronostratigraphic scale with unprecedented precision within this detailed biostratigraphic framework successive shifts in the composition of the dinoflagellate cyst assemblages are interpreted in terms of sea level and sea surface temperature sst fluctuations the evaluation of ecologically and sedimentary controlled changes in the composition of dinoflagellate cyst assemblages in combination with sequence stratigraphic analysis allows the reconstruction of third and fourth order sea level fluctuations the third order sea level fluctuations appear to correspond to exxon cycles ta4 1 4 5 the stratigraphically and palaeoenvironmentally important late eocene dinoflagellate cyst species glaphyrocysta priabonensis sp nov is formally described

seismic amplitude tomography for crustal attenuation beneath china summary amplitude tomography reconstructs seismic attenuation directly from recorded wave amplitudes we have applied the tomography to amplitude data reported in the annual bulletin of chinese earthquakes and interpreted the regionally varying crustal attenuation in terms of tectonics the seismic amplitudes were originally recorded for determining the m l and m s magnitudes they generally correspond to the maximum amplitudes of the horizontal components of the short period s waves and intermediate period rayleigh waves both sets of measurements are sensitive to crustal structure the peak amplitudes from m l amplitudes spread spherically with significant dispersion and scattering m s amplitudes show cylindrical spreading with little dispersion average crustal q values for attenuation at 1 hz are 737 and 505 for m l and m s respectively with substantial regional variations frequency dependence in the attenuation is also indicated regions with the lowest attenuation high q values are beneath the south china block sichuan basin ordos platform the daxinganling and the korea craton these tend to be tectonically inactive regions which are generally dominated by intrusive and cratonic rocks in the upper crust regions with the highest attenuation low q values are beneath bohai basin yunnan eastern songpan ganzi terrain margins of the ordos platform and the qilian shan these are predominantly active basins grabens and fold belts the continental margin also highly attenuates both s and surface waves

marked decline in atmospheric carbon dioxide concentrations during the paleogene the relation between the partial pressure of atmospheric carbon dioxide pco2 and paleogene climate is poorly resolved we used stable carbon isotopic values of di unsaturated alkenones extracted from deep sea cores to reconstruct pco2 from the middle eocene to the late oligocene approximately 45 to 25 million years ago our results demonstrate that pco2 ranged between 1000 to 1500 parts per million by volume in the middle to late eocene then decreased in several steps during the oligocene and reached modern levels by the latest oligocene the fall in pco2 likely allowed for a critical expansion of ice sheets on antarctica and promoted conditions that forced the onset of terrestrial c4 photosynthesis

effects of velocity shear in advective mixed layer models abstract a general multidimensional model of the upper mixed layer of oceans and lakes is presented the density profile is approximated as uniform over the depth of the layer such an assumption is not made for the distribution of the horizontal velocity component as there is no observational evidence for it in fact many observations indicate that important velocity shears exist in regions where advection can be expected to play an important role in the dynamics of the mixed layer such as lakes near upwelling and frontal areas and in equatorial oceanic regions it is shown that vertical shear in the horizontal velocity field combined with a horizontal density gradient can result in the production or absorption of mechanical energy production results if the velocity shear tends to destabilize the density profile consumption if the tendency is stabilizing so that work against gravity must be done to mix the stabler density profile to uniformity in the mechanical energy equation this effect of th

similarities between planktonic and larger foraminiferal evolutionary trends through paleogene paleoceanographic changes abstract the paleogene evolutionary records of planktonic foraminifera and larger benthic foraminifera show parallel patterns in development that may in part reflect changes in nutrient flux to surface waters following the terminal cretaceous extinctions faunas were dominated by a few cosmopolitan opportunistic species more specialized k strategists in both groups diversified during the paleocene dominating into the early eocene consistent with he globally mild climatic regime and probable limited rates of nutrient flux to surface waters high latitude cooling intensified in the middle eocene promoting diversification of less specialized taxa characteristic of cooler and deeper waters higher latitudes meridional upwelling zones and boundary currents geographic ranges of warm water taxa diminished and fragmented yet many species survived thus global diversities during the middle eocene were the highest in the cenozoic as cooling and increased rates of nutrient flux further intensified in the late eocene extinction rates of warm water planktonic and larger benthic species exceeded origination rates of cooler water and less specialized forms so diversity dropped to intermediate levels where it remained through the late eocene and oligocene previous observations that planktonic foraminiferal faunas dominated by warm water taxa are often replaced by cool water faunas even though oxygen isotopes only recorded relatively minor cooling can be reconciled by the explanation that the biotic communities responded to changes in trophic resources and euphotic habitats that accompany the temperature reduction as well as to temperature change itself

a novel proxy for terrestrial organic matter in sediments based on branched and isoprenoid tetraether lipids we propose a novel tracer for terrestrial organic carbon in sediments based on the analysis of tetraether lipids using high performance liquid chromatography mass spectrometry hplc ms analysis of terrestrial soil and peats shows that branched tetraether lipids are predominant in terrestrial environments in contrast to crenarchaeol the characteristic membrane lipid of non thermophilic crenarchaeota which is especially abundant in the marine and lacustrine environment based on these findings an index was developed the so called branched and isoprenoid tetraether bit index based on the relative abundance of terrestrially derived tetraether lipids versus crenarchaeol this bit index was applied to surface sediments from the angola basin where it was shown to trace the outflow of the congo river furthermore analyses of particulate organic matter from the north sea showed relatively higher bit indices in water column particulate organic matter near large river inputs a survey of globally distributed marine and lacustrine surface sediments shows that the bit index in these environments correlates with the relative fluvial input of terrestrial organic material making this index generally applicable the new proxy allows the rapid assessment of the fluvial input of terrestrial organic material in immature sediments up to 100 ma old

atmospheric carbon dioxide and early eocene climate a general circulation modeling sensitivity study abstract the early eocene was the warmest time interval of the past 65 million years we have investigated the hypothesis that the warm climate of the early eocene may have been caused by higher than present levels of atmospheric carbon dioxide co2 we have used an atmospheric general circulation model the ncar genesis model coupled to a land surface model and a mixed layer ocean to examine the sensitivity of early eocene climate to varying levels of atmospheric co2 model cases contained a description of the early eocene earth and included either 300 560 or 1680 ppm atmospheric co2 climate responses to increased atmospheric co2 include 1 increased mean annual global temperature by 2 6 c and decreased latitudinal surface temperature gradients 2 maximum warming at high latitudes especially in the winter season 3 increased mean global precipitation 4 increased high latitude clouds in comparison with geological paleoclimate data the climate response to increased co2 does not appear to explain completely the early eocene latitudinal surface temperature gradient for example with the 1680 ppm co2 case high latitude oceans and continents are minimally warm enough to match paleoclimate data while low latitude regions are overly warm when compared to sea surface temperature reconstructions we conclude that co2 was very likely at least double the present level during the early eocene and contributed to the overall character of early eocene climate however consideration of increased poleward oceanic heat transport and or other factors may be required to produce model results that more closely agree with marine and terrestrial paleoclimate data especially at low latitudes

conflicting isotopic and biotic evidence for tropical sea surface temperatures during the tertiary abstract the biotic evidence from a varied group of shallow water organisms including mangroves zooxanthellate corals mainly reefal and larger foraminifera suggests that sea surface temperatures at low latitudes during the tertiary from at least the early eocene to the middle miocene were subtropical to tropical in nature and similar to temperatures prevailing at low latitudes at the present day 20 28 c in a recent paper shackleton 1984 the suggestion is made on the basis of oxygen isotope studies of foraminiferal shells that low latitude sea surface temperatures during the palaeogene and much of the neogene were invariably lower than those in similar regions today with a stable temperature of around 18 c this paper discusses the conflicting evidence for sea surface temperatures obtained from palaeontological and isotopic sources and suggests that palaeotemperatures derived from some isotopic studies are too low to account for the distribution and diversity of many tertiary tropical and subtropical biotas

abrupt deep sea warming palaeoceanographic changes and benthic extinctions at the end of the palaeocene a remarkable oxygen and carbon isotope excursion occurred in antarctic waters near the end of the palaeocene 57 33 myr ago indicating rapid global warming and oceanographic changes that caused one of the largest deep sea benthic extinctions of the past 90 million years in contrast the oceanic plankton were largely unaffected implying a decoupling of the deep and shallow ecosystems the data suggest that for a few thousand years ocean circulation underwent fundamental changes producing a transient state that although brief had long term effects on environmental and biotic evolution

stable warm tropical climate through the eocene epoch earth s climate cooled from a period of extreme warmth in the early eocene epoch ca 50 ma to the early oligocene ca 33 ma when a large ice cap first appeared on antarctica evidence from the planktonic foraminifer oxygen isotope record in deep sea cores has suggested that tropical sea surface temperatures declined by 5 10 degrees over this interval eventually becoming much cooler than modern temperatures here we present paleotemperature estimates from foraminifer isotopes and the membrane lipids of marine crenarcheota from new drill cores in tanzania that indicate a warm and generally stable tropical climate over this period we reinterpret the previously published isotope records in the light of comparative textural analysis of the deep sea foraminifer shells which shows that in contrast to the tanzanian material they have been diagenetically recrystallized we suggest that increasingly severe alteration of the deep sea plankton shells through the eocene produced a diagenetic overprint on their oxygen isotope ratios that imparts the false appearance of a tropical sea surface cooling trend this implies that the long term eocene climatic cooling trend occurred mainly at the poles and had little effect at lower latitudes

reconstruction of sea surface conditions at middle to high latitudes of the northern hemisphere during the last glacial maximum lgm based on dinoflagellate cyst assemblages abstract a new calibration database of census counts of organic walled dinoflagellate cyst dinocyst assemblages has been developed from the analyses of surface sediment samples collected at middle to high latitudes of the northern hemisphere after standardisation of taxonomy and laboratory procedures the database comprises 940 reference data points from the north atlantic arctic and north pacific oceans and their adjacent seas including the mediterranean sea as well as epicontinental environments such as the estuary and gulf of st lawrence the bering sea and the hudson bay the relative abundance of taxa was analysed to describe the distribution of assemblages the best analogue technique was used for the reconstruction of last glacial maximum lgm sea surface temperature and salinity during summer and winter in addition to sea ice cover extent at sites from the north atlantic n 63 mediterranean sea n 1 and eastern north pacific n 1 three of the north atlantic cores from the continental margin of eastern canada revealed a barren lgm interval probably because of quasi permanent sea ice six other cores from the greenland and norwegian seas were excluded from the compilation because of too sparse assemblages and poor analogue situation at the remaining sites n 54 relatively close modern analogues were found for most lgm samples which allowed reconstructions the new lgm results are consistent with previous reconstructions based on dinocyst data which show much cooler conditions than at present along the continental margins of canada and europe but sharp gradients of increasing temperature offshore the results also suggest low salinity and larger than present contrasts in seasonal temperatures with colder winters and more extensive sea ice cover whereas relatively warm conditions may have prevailed offshore in summer from these data we hypothesise low thermal inertia in a shallow and low density surface water layer

eocene circulation of the southern ocean was antarctica kept warm by subtropical waters 1 near the eocene s close 34 million years ago the climate system underwent one of the largest shifts in earth s history antarctic terrestrial ice sheets suddenly grew and ocean productivity patterns changed previous studies conjectured that poleward penetration of warm subtropical currents the east australian current eac in particular caused eocene antarctic warmth late eocene opening of an ocean gateway between australia and antarctica was conjectured to have disrupted the eac cooled antarctica and allowed ice sheets to develop here we reconstruct eocene paleoceanographic circulation in the tasmanian region using 1 biogeographical distributions of phytoplankton including data from recently drilled ocean drilling program leg 189 sites and 2 fully coupled climate model simulations we find that the eac did not penetrate to high latitudes and ocean heat transport in the region was not greater than modern our results do not support changes in thermal isolation as the primary driver of the eocene oligocene climatic transition

the trace metal content of recent organic carbon rich sediments implications for cretaceous black shale formation organic carbon rich sediments are enriched in several redox sensitive and stable sulfide forming trace metals tm and form an important sink in global tm cycles in today s ocean such sediments are deposited in coastal upwelling areas like those in the gulf of california off peru or off the namibian coast and euxinic basins like the black sea in an attempt to distinguish both environments by their specific tm patterns some important conclusions may be drawn 1 the tm enrichment seen in both environments broadly is rather similar 2 upwelling sediments are often enriched in cd and p and depleted in co and mn 3 sapropels have a tendency towards higher enrichments in ba and mo s re as cu ni sb and fe reflecting the strong sulfidation in an anoxic water column 4 upwelling systems cover a broad range of environmental settings where the steepness of the slope the proximity of h2s to the sediment seawater interface and the intensity of bio accumulation and regeneration play an important role for tm accumulation 5 the tm content of anoxic basins is mainly controlled by tm availability in the water column and sedimentation rate 6 enhanced bio productivity is the main switch turning an oxygenated into an anoxic environment cretaceous black shales oae 2 exhibit tm signatures of both coastal upwelling areas and sapropels the strong enrichments in cd mo tl v cu ni bi and sb demonstrate that bio accumulation and presence of h2s in the water column and associated sulfidation processes persisted during this time interval in large parts of the proto atlantic the usefulness of ba as a paleoproductivity proxy is obscured by diagenesis the extreme accumulation in ag and zn requires either an additional tm source for instance hydrothermal input or a different tm seawater composition during the cretaceous the geochemical data suggest that the major driving force for the widespread occurrence of c t black shales seems to be the increase in volcanic activity and associated co2 input throughout the cretaceous the ocean atmosphere system operated in a mode different from today during this time interval after conversion of the nutrient co2 into organic matter the system switched back into the normal operational mode

warm arctic continents during the palaeocene eocene thermal maximum the palaeocene eocene thermal maximum petm 55 5 ma is a geologically relatively brief episode of extreme warmth both deep and surface ocean temperatures increased by up to 5 c in equatorial waters and up to 8 c in mid and high latitude waters from the continents the annual mean air temperature response during the petm is still largely unknown mainly due to a lack of quantitative temperature proxies and sufficient suitable continuous high resolution records recently a new proxy for continental temperature reconstructions has been proposed based on the distribution of membrane lipids of bacteria in present day soils j w h weijers s schouten j c van den donker e c hopmans j s sinninghe damste 2007 environmental controls on bacterial tetraether membrane lipid distribution in soils geochimica et cosmochimica acta 71 703 713 and shown to reconstruct annual mean air temperature in this study we applied this new proxy in an attempt to reconstruct the air temperature in high latitude continental areas during the petm by analysis of a marine sedimentary sequence obtained from the lomonosov ridge in the central arctic ocean integrated ocean drilling program expedition 302 site 004 hole a the results indicate a warming of 8 c above background values of 17 c this warming is coincident with a similar rise in sea surface temperatures documented earlier our results thus further confirm the warm conditions in the arctic and point to a strongly reduced latitudinal temperature gradient during the petm 2007 elsevier b v all rights reserved

on the duration of the paleocene eocene thermal maximum petm 1 the paleocene eocene thermal maximum petm is one of the best known examples of a transient climate perturbation associated with a brief but intense interval of global warming and a massive perturbation of the global carbon cycle from injection of isotopically light carbon into the ocean atmosphere system one key to quantifying the mass of carbon released identifying the source s and understanding the ultimate fate of this carbon is to develop high resolution age models two independent strategies have been employed cycle stratigraphy and analysis of extraterrestrial helium heet both of which were first tested on ocean drilling program odp site 690 these two methods are in agreement for the onset of the petm and initial recovery or the clay layer main body but seem to differ in the final recovery phase of the event above the clay layer where the carbonate contents rise and carbon isotope values return toward background values here we present a state of the art age model for the petm derived from a new orbital chronology developed with cycle stratigraphic records from sites drilled during odp leg 208 walvis ridge southeastern atlantic integrated with published records from site 690 weddell sea southern ocean odp leg 113 during leg 208 five paleocene eocene p e boundary sections sites 1262 to 1267 were recovered in multiple holes over a depth transect of more than 2200 m at the walvis ridge yielding the first stratigraphically complete p e deep sea sequence with moderate to relatively high sedimentation rates 1 to 3 cm ka where a is years a detailed chronology was developed with nondestructive x ray fluorescence xrf core scanning records on the scale of precession cycles with a total duration of the petm now estimated to be 170 ka the revised cycle stratigraphic record confirms original estimates for the duration of the onset and initial recovery but suggests a new duration for the final recovery that is intermediate to the previous estimates by cycle stratigraphy and heet

the ocean circulation in the southern hemisphere and its climatic impacts in the eocene abstract opening of southern ocean gateways may have had a controlling influence on the evolution of global climate the largest step in the history of cenozoic climate from an eocene greenhouse toward the modern glaciated state is correlated with opening of a deep water connection between the southern indian and southern pacific oceans this study synthesizes results from previous work assesses the possibility that ocean heat transport was much greater than modern during the globally warm eocene and explores the sensitivity of polar climate to large changes in ocean heat transport the magnitudes of these sensitivities are compared with those due to greenhouse gas concentration changes we find that ocean heat transport was unlikely to have been sufficiently greater than modern during the eocene to explain the change in the climate specifically in order to have significantly affected antarctic climate ocean heat transport changes would have had to change by an order of magnitude much greater than the largest change produced in our simulations in coupled climate model simulations changes in co2 concentrations from 1120 to 560 ppm supported by proxy records lead to significant antarctic responses in the absence of ocean heat transport changes the results show that antarctic snow accumulation is primarily controlled by changes in summer temperature not precipitation and that snow did not remain on antarctica during summer months in eocene even at low greenhouse gas concentrations greenhouse gas concentration changes and subsequent processes such as ice albedo and weathering feedbacks were more likely to have been the primary cause of antarctic glaciation than ocean heat transport changes

new chronology for the late paleocene thermal maximum and its environmental implications the late paleocene thermal maximum lptm is associated with a brief but intense interval of global warming and a massive perturbation of the global carbon cycle we have developed a new orbital chronology for ocean drilling program odp site 690 weddell sea southern ocean by using spectral analysis of high resolution geochemical records the lptm interval spans 11 precessional cycles yielding a duration of 210 to 220 k y the 13 c anomaly associated with the lptm has a magnitude of about 2 5 to 3 we show that about 2 of the excursion occurs within two steps that each were less than 1000 yr in duration the remainder developed through a series of steps over 52 k y the timing of these steps is consistent with a series of nearly catastrophic releases of methane from gas hydrates punctuated by intervals of relative equilibria between hydrate dissociation and carbon burial further we are able to correlate the records between odp sites 690 and 1051 western north atlantic on the scale of 21 k y cycles which demonstrates that the details of the 13 c excursion are recognizable between distant sites comparison of cycle records at sites 690 and 1051 suggests that sediment representing the interval 30 k y just prior to and at the onset of the lptm are missing in the latter location this unconformity probably resulted from slope failure accompanying methane hydrate dissociation within 10 k y of the start of the lptm

late paleocene arctic coastal climate inferred from molluscan stable and radiogenic isotope ratios abstract characterizing polar climates during past warm intervals is important for understanding greenhouse climate dynamics because high latitude surface temperatures and precipitation patterns are extremely sensitive to global climatic conditions model data comparisons of high latitude climates during past warm intervals cretaceous eocene pliocene are currently at odds specifically simulations of past warm climates produce polar regions characterized by sub freezing temperatures and significant seasonality whereas limited fossil proxy data indicate higher mean annual temperatures and low seasonality i e an equable climate we have constructed a data set to infer northern hemisphere polar marine temperatures during the late paleocene seasonal and mean annual temperature and the oxygen isotopic composition of precipitation are reconstructed for an arctic coastal setting during the thanetian 57 58 ma using fossil shell stable isotope profiles we estimate that coastal water temperatures varied between 10 and 15 c during the seasons of growth presumably spring summer and fall these findings support paleontological evidence implying northern hemisphere polar climates were seasonally warm during the late paleocene in addition estuarine fossil oxygen isotope profiles show periodic excursions to low values as low as 19 vpdb which indicate seasonal pulses of isotopically depleted freshwater

magnetostratigraphic calibration of eocene oligocene dinoflagellate cyst biostratigraphy from the norwegian greenland sea the presence of abundant age diagnostic dinoflagellate cysts in ocean drilling program odp hole 913b leg 151 deep sea drilling project hole 338 leg 38 and odp hole 643a leg 104 has enabled the development of a new biostratigraphy for the eocene oligocene interval in the norwegian greenland sea this development is important because the calcareous microfossils usually used for biostratigraphy in this age interval are generally absent in high latitude sediments as a result of dissolution in parallel with this biostratigraphic analysis we developed a magnetic reversal stratigraphy for these norwegian greenland sea sequences this has allowed independent age determination and has enabled the dinocyst biostratigraphy to be firmly tied into the global geomagnetic polarity timescale gpts the relatively high resolution of this study has enabled identification of dinoflagellate cyst assemblages that have affinities with those from the north sea and the north atlantic which allows regional correlation correlation of each site with the gpts has also allowed comparison of the stratigraphic record preserved in each drill hole hole 913b is the most complete and is the best preserved record of the eocene and oligocene in the northern hemisphere high latitudes and can serve as a reference section for palaeoenvironmental reconstructions of this age interval

correlation between isotope records in marine and continental carbon reservoirs near the palaeocene eocene boundary changes in the isotope content of the large marine carbon reservoir can force shifts in that of the smaller carbon pools in the atmosphere and on land the carbon isotope compositions of marine carbonate sediments from the late palaeocene vary considerably exhibiting a sudden decrease close to the palaeocene eocene boundary which coincides with deep sea benthic extinctions1 and with changes in ocean circulation here we report that these fluctuations in the marine carbon isotope record are closely tracked by the terrestrial records provided by palaeosol carbonates and mammalian tooth enamel in using palaeosol carbonates to reconstruct the co2 content of the ancient atmosphere2 isotope shifts of this sort will have to be taken into account the sharp decrease in 13c 12c ratios in the late palaeocene provides a datum for precise correlation of marine and continental records and suggests that abrupt climate warming at this time may have played an important role in the evolution of land mammals

eocene continental climates and latitudinal temperature gradients global climate during the mesozoic and early cenozoic is thought to have been warmer than at present but there is debate about winter temperatures paleontological data indicate mild temperatures even at high latitudes and in mid latitude continental interiors whereas computer simulations of continental paleoclimates produce winter temperatures closer to modern levels foliar physiognomy and floristic composition of 23 eocene floras from the interior of north america and australia indicate cold month means generally 2 c even where the mean annual temperature mat was

arctic late paleocene early eocene paleoenvironments with special emphasis on the paleocene eocene thermal maximum lomonosov ridge integrated ocean drilling program expedition 302 we reconstruct the latest paleocene and early eocene 57 50 ma environmental trends in the arctic ocean and focus on the paleocene eocene thermal maximum petm 55 ma using strata recovered from the lomonosov ridge by the integrated ocean drilling program expedition 302 the lomonosov ridge was still partially subaerial during the latest paleocene and earliest eocene and gradually subsided during the early eocene organic dinoflagellate cyst dinocyst assemblages point to brackish and productive surface waters throughout the latest paleocene and early eocene dinocyst assemblages are cosmopolitan during this time interval suggesting warm conditions which is corroborated by tex86 reconstructed temperatures of 15 18 c inorganic geochemistry generally reflects reducing conditions within the sediment and euxinic conditions during the upper lower eocene spectral analysis reveals that the cyclicity recorded in x ray fluorescence scanning fe data from close to eocene thermal maximum 2 53 ma presence confirmed by dinocyst stratigraphy is related to precession within the lower part of the petm proxy records indicate enhanced weathering runoff anoxia and productivity along with sea level rise on the basis of total organic carbon content and variations in sediment accumulation rates excess organic carbon burial in the arctic ocean appears to have contributed significantly to the sequestration of injected carbon during the petm

climate model sensitivity to atmospheric co2 levels in the early middle paleogene this study examines the sensitivity of the slab ocean version of the national center for atmospheric research climate system model with revised eocene geography orography and vegetation to changing carbon dioxide co2 levels we compare model results with temperature proxies from the geologic record for the early middle paleogene we ran three modeling experiments with co2 levels at 500 1000 and 2000 ppm and all with atmospheric methane levels of 3 5 ppm surface temperatures in the two higher co2 scenarios are warmer than those of the 500 ppm scenario the largest warming with increasing co2 occurred in the high latitudes particularly in the northern hemisphere during the wintertime compared to the 500 ppm case arctic wintertime temperatures increased by 10 c for the 1000 ppm scenario and 20 c for the 2000 ppm scenario the 1000 and 2000 ppm scenarios produced mean annual and cold month mean temperatures in mid and high latitudes that are much more compatible with the climate interpretations from eocene flora especially for data from the southern hemisphere tropical sea surface temperatures ssts in the 2000 ppm scenario however are still 4 c higher than the warmest temperatures inferred from proxy data the better match between temperatures in the high co2 modeling scenario and high latitude climate interpretations is consistent with the idea that the co2 levels during the eocene were high at least 3 4 times the pre industrial value of 280 ppm but the discrepancies in the tropics suggest that sst estimates from proxies are too low or that the models lack some tropical cooling mechanism that was important at this time

abrupt climate change and transient climates during the paleogene a marine perspective detailed investigations of high latitude sequences recently collected by the ocean drilling program odp indicate that periods of rapid climate change often culminated in brief transient climates with more extreme conditions than subsequent long term climates two examples of such events have been identified in the paleogene the first in latest paleocene time in the middle of a warming trend that began several million years earlier the second in earliest oligocene time near the end of a middle eocene to late oligocene global cooling trend superimposed on the earlier event was a sudden and extreme warming of both high latitude sea surface and deep ocean waters imbedded in the latter transition was an abrupt decline in high latitude temperatures and the brief appearance of a full size continental ice sheet on antarctica in both cases the climate extremes were not stable lasting for less than a few hundred thousand years indicating a temporary or transient climate state geochemical and sedimentolog

a high resolution north sea eocene dinocyst zonation abundant dinoflagellate cysts dinocysts from eocene strata of the north sea exhibit a consistent succession of events based on the analysis of 120 wells from quadrant 3 in the north to quadrants 21 and 22 in the south these events have a constant relationship with stratigraphic sequences and subsequences throughout the area eight eocene dinocyst zones and 23 subzones and the uppermost palaeocene apectodinium augustum biozone are defined by last occurrence or abundance events the north sea dinocyst succession is similar to that in denmark northwest germany belgium the netherlands and southern england permitting correlation with calcareous nannoplankton zones for sections in these areas and hence allowing correlation of north sea stratigraphy with northwest european and worldwide events

the paleocene eocene carbon isotope excursion in higher plant organic matter differential fractionation of angiosperms and conifers in the arctic abstract a study of upper paleocene lower eocene p e sediments deposited on the lomonosov ridge in the central arctic ocean reveals relatively high abundances of terrestrial biomarkers these include dehydroabietane and simonellite derived from conifers gymnosperms and a tetra aromatic triterpenoid derived from angiosperms the relative percentage of the angiosperm biomarker of the summed angiosperm conifer biomarkers was increased at the end of the paleocene eocene thermal maximum petm different when observed with pollen counts which showed a relative decrease in angiosperm pollen stable carbon isotopic analysis of these biomarkers shows that the negative carbon isotope excursion cie during the petm amounts to 3 for both conifer biomarkers dehydroabietane and simonellite comparable to the magnitude of the cie inferred from marine carbonates but significantly lower than the 4 5 of the terrestrial c29 n alkane m pagani n pedentchouk m huber a sluijs s schouten h brinkhuis j s sinninghe damste g r dickens and the iodp expedition 302 expedition scientists 2006 arctic s hydrology during global warming at the paleocene eocene thermal maximum nature 442 671 675 which is a compound sourced by both conifers and angiosperms conspicuously the angiosperm sourced aromatic triterpane shows a much larger cie of 6 and suggests that angiosperms increased in their carbon isotopic fractionation during the petm our results thus indicate that the 4 5 c29 n alkane cie reported previously represents the average cie of conifers and angiosperms at this site and suggest that the large and variable cie observed in terrestrial records may be partly explained by the variable contributions of conifers and angiosperms the differential response in isotopic fractionation of angiosperms and conifers points to different physiological responses of these vegetation types to the rise in temperature humidity and greenhouse gases during the petm

influence of the water content on x ray fluorescence core scanning measurements in soft marine sediments the x ray fluorescence xrf core scanner provides bulk sediment chemistry data measured nondestructively at the split core sediment surface although this method is widely accepted there is little known about the effects of physical properties such as density and water content on xrf core scanner data comparison of xrf scanner measurements from the sediment surface and dry powder samples of sediment core geob7920 indicates strongly reduced element intensities for the lighter elements al and si we relate the lower element intensities of the measurements taken at the sediment surface to the amount of water in the sample volume analyzed by the xrf core scanner the heavier elements k ca ti and fe remain relatively unaffected by the variation of any physical property within sediment core geob7920 additionally we successfully use the elemental intensity of cl as a proxy for the seawater content in the sample volume analyzed by the xrf core scanner this enables the establishment of a correction function for the elements al and si that corrects for the radiation absorption of the water content in sediment core geob7920 off cape blanc nw africa

oxygen isotope and paleobotanical estimates of temperature and δ18o latitude gradients over north america during the early eocene empirical estimates of climate parameters such as mean annual temperature mat are essential to describe both ancient climate and to ground truth climate model simulations of past climates in terrestrial settings no single proxy record is able to provide detailed temporal yet geographically widespread information and it thus becomes essential that paleoclimatic information obtained from different proxies be comparable as an example of how to compare estimates and to illustrate what can be learned by doing so we measured oxygen isotope ratios of phosphate in the tooth enamel of fossil mammals and the body scales of freshwater fish in order to estimate the mean annual temperature mat in which they lived the samples were collected from paleogene rocks of the bighorn green river and powder river basins of wyoming earliest eocene samples provide mat estimates that are similar to mat estimates for the same times and areas obtained from leaf margin analysis furthermore isotopic data from the paleocene eocene thermal maximum petm which has not yet yielded fossil floras indicate a significantly higher mat of 26 c we also used temperature estimates obtained by both methods to investigate paleoelevation and to reconstruct geographic patterns of mat over north america for the early eocene larger laramide basins have higher temperatures and lower inferred elevations compared to associated volcanic highlands where cooler temperatures are consistent with substantial elevations in turn latitudinal gradients in temperature indicate that warming centered on polar regions played an important role during the eocene hothouse lastly we show that the reconstructed eocene relation between oxygen isotope ratios of precipitation and mat is significantly different from the modern relation between these two variables because the relation has changed over time the modern correlation should not be used to estimate paleo mat from measurements of oxygen isotope ratios in fossil material

timing and nature of the deepening of the tasmanian gateway 1 tectonic changes that produced a deep tasmanian gateway between australia and antarctica are widely invoked as the major mechanism for antarctic cryosphere growth and antarctic circumpolar current acc development during the eocene oligocene e o transition 34 33 ma ocean drilling program odp leg 189 recovered near continuous marine sedimentary records across the e o transition interval at four sites around tasmania these records are largely barren of calcareous microfossils but contain a rich record of siliceous and organic walled marine microfossils in this study we integrate micropaleontological sedimentological geochemical and paleomagnetic data from site 1172 east tasman plateau to identify four distinct phases a d in the e o tasmanian gateway deepening that are correlative among odp leg 189 sites phase a prior to 35 5 ma minor initial deepening characterized by a shallow marine prodeltaic setting with initial condensation episodes phase b 35 5 33 5 ma increased deepening marked by the onset of major glauconitic deposition and inception of energetic bottom water currents phase c 33 5 30 2 ma further deepening to bathyal depths with episodic erosion by increasingly energetic bottom water currents phase d 30 2 ma establishment of stable open ocean warm temperate oligotrophic settings characterized by siliceous carbonate ooze deposition our combined evidence indicates that this early oligocene tasmanian gateway deepening initially produced an eastward flow of relatively warm surface waters from the australo antarctic gulf into the southwestern pacific ocean this proto leeuwin current fundamentally differs from previous regional reconstructions of eastward flowing cool water e g a proto acc during the early oligocene and thereby represents an important new constraint for reconstructing regional to global scale dynamics for this major global change event

orbital scale variations and timescales from the arctic ocean we investigate geochemical measurements from the arctic coring expedition to derive sedimentation rates for selected intervals in the early and middle eocene this analysis is performed by quantifying cyclical variations in physical property data and elemental concentrations derived with an x ray fluorescence xrf core scanner our results show that physical properties and xrf derived elemental concentrations are coherent and correlated to each other changes in elemental concentrations occur on depth scales from decimeters to meters and correspond to varying contributions of detrital minerals and biogenic silica we confirm and refine sedimentation rates of the order of 10 to 25 m ma 1 these rates were obtained independently through biostratigraphic and magnetostratigraphic methods we observe a strong imprint of astronomically sourced cycles particularly through climatic precession this observation allows us to test recently proposed theoretical calculations of insolation

maceral total organic carbon and palynological analyses of ross ice shelf project site j9 cores analyses of macerals and total organic carbon indicate that the low organic content of core sediments from ross ice shelf project site j9 has been selectively reduced further probably by postdepositional submarine oxidation palynological analysis revealed a reworked paleogene dinocyst flora of low diversity the transantarctic flora this constitutes the most southerly dinocyst flora reported thus far the antarctic distribution of the transantarctic flora supports the existence of a transantarctic strait during the paleogene the j9 sporomorph assemblage also is reworked and paleogene in age

inorganic geochemistry of albian sediments from the lower saxony basin nw germany palaeoenvironmental constraints and orbital cycles abstract within the international albicore project upper albian sediments from a 245 m core kirchrode i drilled in hannover were studied by inorganic geochemical methods more than 650 samples minimum sample spacing 0 5 m were analysed for major and minor element concentrations this chemical database was used to reconstruct the depositional environment and to investigate the influence of high frequency milankovitch cycles on the chemical composition of the sediments the chemical composition of the sedimentary sequence is primarily controlled by variations in carbonate content corresponding to ca al ratios variations in both ti al and si al ratios are interpreted as fluctuations in detrital composition resulting from increases in smectite and quartz content in the upper section of the core high amounts of reactive iron but low pyrite concentrations the lack of enrichment of redox sensitive trace elements v cr and high mn concentrations indicate oxic bottom water conditions and the absence of an oxygen minimum zone for the upper albian at the kirchrode site the nutrient related trace elements ba p zn suggest a generally oligotrophic setting with slightly elevated productivity only in the uppermost upper albian only one layer was identified as containing volcanogenic material at 87 20 m this layer is characterised by elevated montmorillonite zr and nb mass balance calculations for the entire core suggest that the high mn values cannot be explained by riverine input alone therefore a coastal oxygen minimum zone south of the kirchrode site is postulated as an additional mn source cyclic variations in both carbonate content and al normalised concentrations of predominantly detrital elements like si and ti are seen in a 60 m interval 40 100 m where sedimentological palaeontological and geochemical data suggest stable depositional conditions although carbonate cyclicity cyclicity in detrital input and nutrient related element abundances do not correlate with each other three strong peaks in the results of spectral analysis of these chemical data for this interval appear to correspond to milankovitch frequencies in the eccentricity obliquity and precession bands

structure of the upper water column in the northwest north atlantic modern versus last glacial maximum conditions 1 during the last glacial maximum the northwestern north atlantic constituted a major conduit for labrador and greenland ice sheet meltwaters vertical density gradients in its upper water masses have been reconstructed by combining information from transfer functions based on dinocysts and from oxygen isotope measurements 18o in planktonic foraminifera transfer functions yield temperature and salinity and thus potential density for the warmest august and coldest february months in the photic zone the 18o values in different size fractions of epipelagic globigerina bulloides and mesopelagic neogloboquadrina pachyderma left coiled npl foraminifera allow us to assess gradients through the pycnocline between surface and intermediate waters based on the calibration of a versus 18o relationship from transfer function reconstructions the size and density of npl shells provide further constraints on these gradients the results show the development of a very strong pycnocline during the lgm with a difference of about 3 summer to 1 5 winter units between surface and underlying waters they indicate conditions unfavorable for vertical convection and support the hypothesis of the spreading of a shallow low salinity buoyant layer over the northern north atlantic this layer depicted a strong e w gradient with maximum seasonal contrast and minimum absolute values westward

fe co3 oh in goethite from a mid latitude north american oxisol estimate of atmospheric co2 concentration in the early eocene climatic optimum abstract measured mole fractions x and 13c values of the fe co3 oh component in pedogenic goethite from a mid latitude oxisol of early eocene age 52 ma b p range from 0 0014 to 0 0064 and 20 1 to 15 4 respectively these values of x imply that concentrations of co2 gas in the paleosol were 7400 to 34 000 ppm 13c and 1 x are correlated and define a linear soil co2 diffusive mixing line with a positive slope such positive slopes are characteristic of mixing of two isotopically distinct co2 endmembers atmospheric co2 and co2 from oxidation of soil organic matter from the intercept of the mixing line it is calculated that the 13c value of organic matter in the ancient soil was 28 0 the magnitude of the slope implies an early eocene atmospheric co2 concentration of 2700 ppm a simple model for forest soils suggests that a canopy effect may cause atmospheric co2 concentrations deduced from pedogenic minerals to underestimate the actual concentrations of atmospheric co2 if a significant forest canopy were present at the time of formation of pedogenic goethite in the ione fm the concentration of 2700 ppm calculated for atmospheric co2 could be slightly low but the underestimate is expected to be

heat transport deep waters and thermal gradients coupled simulation of an eocene greenhouse climate for the first time a coupled general circulation model with interactive and dynamical atmospheric oceanic and sea ice components is used to simulate an eocene 50 ma greenhouse climate we introduce efficient ocean spin up methods for coupled paleoclimate modeling sea surface temperatures ssts and salinities evolve unconstrained producing the first proxy data independent estimates for these eocene climate parameters tropical and extratropical model predicted ssts are warmer than modern values by 3 and 5 c respectively salinity driven deep water formation occurs in the north atlantic and tethys the zonal average overturning circulation is weaker than modern eocene ocean heat transport is 0 6 pw less than modern in the northern hemisphere and 0 4 pw greater in the southern hemisphere the model predicted near modern vertical and meridional eocene temperature gradients imply that the dominant theory for maintaining low gradients increased ocean heat transport is incorrect or incomplete and other mechanisms should be explored