behavior of rare earth elements in a paleoweathering profile on granodiorite in the front range colorado usa abstract a paleoweathering profile on the boulder granodiorite in northern colorado provides an opportunity to trace the behavior of rees from parent rock through a weathering profile into unconformably overlying permian sediments with progressive upward weathering of the granodiorite na2o cao sio2 ta hf co th cr sc cr th zr hf la sc zr y and la th decrease al2o3 and fe2o3t increase and tio2 mgo k2o p2o5 rb zr sc cr co hf nb ta y th u ree ti nb and zr nb increase to maximum values and then either level off or decrease lree enrichment is less in the weathering profile than in the parent granodiorite and although the parent does not have an eu anomaly or only a slight positive anomaly all samples from the weathering profile and overlying sediments have significant negative eu anomalies this observation is especially important in that it shows conclusively that a negative eu anomaly can be produced during chemical weathering of granitoids we suggest these eu anomalies are due to relative enrichment of the other rees and partial loss of eu during the breakdown of plagioclase the boulder weathering profile also has a very minor negative ce anomaly that is within error of a ce anomaly in the parent in the unweathered parent 50 of the ree are contained in sphene and in the case of la also in allanite from 10 20 of the ree are contained in apatite and biotite hornblende and from 7 10 of the hrees are in zircon with exception of eu for which feldspars contribute about 8 negligible amounts of rees occur in the feldspars in weathered samples 75 of the rees are contained in clay minerals the crossover between sphene and clay control of rees occurs over a distance of 1 m near the contact with fresh rock except for their small negative eu anomalies the clay minerals have ree patterns very similar to those of the parent rock isocon plots suggest apparent enrichments of many elements in the boulder weathering profile result from losses of na ca and si during plagioclase weathering in addition variable amounts of sr eu ta nb p and ba were lost during weathering although th u zr y th sc zr hf lu hf and ti zr may have been transferred relatively unchanged from granodiorite parent to the bulk weathering profile most other element ratios and ree distributions were significantly changed during weathering this observation implies that caution needs to be exercised when using ree patterns and element ratios to trace sediment provenance the fact that most element ratios and ree distributions also differ between fountain sediments and the bulk weathering profile may be related to one or a combination of four factors listed in order of probable decreasing importance contribution of other sources to the fountain sediments sorting of minerals during sediment deposition remobilization of elements during diagenesis and leaching of elements by water flow through the upper meter of the weathering profile

geochemistry and provenance of the middle ordovician austin glen member normanskill formation and the taconian orogeny in new england the austin glen member of the upper middle ordovician normanskill formation is a sandstone shale ysch succession deposited in the foreland of the taconian orogen petrographic major and trace element and nd pb isotopic data provide substantial constraints on its provenance lack of k feldspar and paucity of plagioclase in addition to the dominance of sedimentary rock fragments indicate that the source was dominated by recycled sedimentary components major and trace element data support this conclusion and indicate that the provenance of both shales and sandstones was the same no evidence of an ophiolitic or volcanic component was observed interpretation of nd isotopic characteristics are complicated by a partial resetting of the nd isotope system at about the time of sedimentation but indicate that the provenance of the austin glen member had a long term history of light rare earth element lree enrichment average tdm 1a8 ga furthermore nd isotopic compositions are extremely homogeneous end 8a1 0a6 1 s d n 23 at 450 ma the approximate depositional age indicating either a single source or very well mixed sources 207pb 204pb ratios are variable but within the range of pb isotopic compositions typically described as grenvillian the range of 207pb 204pb is greater than expected for the range of 206pb 204pb and suggests an additional component of pb possibly introduced during diagenesis the immediate source of the austin glen member may have been the accretionary prism that developed as older sediments of the laurentian margin were scraped off the basin oor incorporated within the accretionary prism and shed into the basin no evidence indicating the arrival of an undifferentiated island arc or continental fragment during the taconian orogeny has been found the data acquired during this study can be explained almost exclusively by grenville province source components but with possible additional contributions from older laurentian terranes and late proterozoic rift volcanics that are not readily quanti ed but likely to have been minor accordingly we conclude that the taconian orogeny in new england involved either 1 a continental arc that involved exclusively laurentia 2 collision of a continental block with identical geochemical characteristics as laurentia or 3 essentially no detritus from any exotic colliding block island arc or continental fragment reached the foreland basin at the time of austin glen deposition

mixing processes in modern estuarine sediments from the gulf of khambhat western india abstract sandy and muddy detritus from two distinctive end member provenance terrains basaltic and granitic are transported to the estuaries of the gulf of khambhat by fluvial discharge and opposing tidal currents making this embayment ideal for investigating the effects of mineralogical and geochemical mixing on sediment composition in estuarine depositional systems rivers flowing predominantly from the north over precambrian metasediments and granites supply a felsic plutoniclastic sand to the gulf whilst a mafic volcaniclastic sand sourced by deccan basalts is transported by rivers draining the western ghats and from the local coastal erosion in the southern part of the gulf sediments from the tapti estuary are rich in basaltic rock fragments 50 and are characterised by a distinctly basaltic source composition la sc 0 25 0 86 th sc 0 12 0 40 cr th 13 121 eu eu 0 93 1 68 and lree hree 2 96 6 57 by contrast the sediments of the sabarmati inner estuary are rich in quartz grains 80 as evident from the major and trace element compositions la sc 1 38 6 63 th sc 0 58 2 98 cr th 0 58 19 39 eu eu 0 46 0 86 and lree hree 2 90 11 40 the detrital compositions of the remaining major estuaries the narmada dhadhar and mahi scatter across a broad range in a qfr diagram and contain varying amounts of quartz feldspar and rock fragments in the narmada estuary the mixed signature characterised by ree values including eu eu 0 42 2 28 and lree hree 4 37 14 80 is caused by the presence of diverse rock types that crop out in the source area in the mahi estuary which largely flows across felsic source terrains the compositional signature is controlled by mixing of felsic detritus from riverine input with mafic sediments from seaward side in the estuary the two end member detrital compositions plutoniclastic and volcaniclastic are mixed in the macro tidal estuaries mixing of sediment takes place where fluvial currents and tidal flows interact and the proportion of mixing varies systematically from outer to central to inner estuary a high degree of mixing of felsic sediments with deccan basalt derived sediments takes place in the outer estuary resulting in felsic mafic ratios of 40 60 sediments in the central estuaries 65 35 and in the fluvial dominated inner estuaries 90 10 are characterised by moderate to minor degrees of mixing the mixing in estuaries is systematic and is reflected in both the mineralogy and geochemistry of the sediments provenances of ancient estuarine successions should therefore be interpreted with great care incorporating awareness of the mixing processes which influence sediment compositions to different degrees in estuaries especially those characterised by strong tidal currents

geochemistry of the mesoproterozoic lakhanda shales in southeastern yakutia russia implications for mineralogical and provenance control and recycling abstract shales of the lakhanda group of late mezoproterozoic age 1050 1000 ma from the southeastern siberian craton in russia have been analyzed for major elements and a number of trace elements including the ree s shales along the maya river formed as platform sediments in a deeper shelf facies whereas shales along the belaya river formed in more active and open environments of an upper shelf carbonate ramp the log of most elemental compositions to al2o3 ratios are the same in the maya and belaya river samples suggesting a similar source rock composition for rocks in the two areas the log of sio2 mgo na2o k2o rb ba and ni to al2o3 ratios are significantly higher and the log of tio2 to al2o3 ratios are significantly lower in shales from the belaya river than the maya river sections the cia chemical index of alteration is thus significantly lower in the belaya shales than the maya shales suggesting less weathering of the in the belaya shales than the maya shales the icvs index of compositional variability fe2o3 k2o na2o cao mgo tio2 al2o3 of the lakhanda shales are less than 1 suggesting that they are compositionally mature and were likely dominated by recycling several samples have icv 1 suggesting some first cycle input the low k2o al2o3 ratios of these shales suggest that minimal first cycle alkali feldspar was present in the initial source most shales of the lakhanda plot parallel and along the a k line in a cn k plots suggestive of intense chemical weathering high cia and do not indicate any clear cut evidence of k metasomatism or direct weathering back to the original source if k metasomatism produced these rocks then they could have formed from tonalites to basalts if weathering produced these rocks then they could have been produced from varied amounts of mostly granodiorite to granite elemental ratios critical of provenance la sc la cr la co th sc th cr th co and eu eu are not significantly different between the maya river and belaya river shales and the ratios are similar to fine fractions derived from the weathering of mostly granitoids and not basic rocks the eu eu th sc and low k2o al2o3 ratios of most shales suggest weathering from mostly a granodiorite source rather than a granite source consistent with a source from old upper continental crust some samples at the bottom of the belaya river section contain very low eu eu 0 35 suggesting significant input of first cycle detritus from highly differentiated granitoids similar to those from the aldan shield

modification of the dichotomy boundary on mars by amazonian mid latitude regional glaciation 1 restoration of the dichotomy boundary to its original position to assess its origin requires a thorough knowledge of processes responsible for its degradation and retreat the unique fretted terrain located along the deuteronilus protonilus mensae northern mid latitude portion of the boundary has been long held to provide clues to dichotomy degradation processes we use new spacecraft data to show that fretted valleys display a multitude of characteristics typical of integrated valley glacial systems on earth multiple theater headed alcove like accumulation areas sharp arete like ridges typical of glacial erosion converging patterns of downslope valley flow valley lineation patterns typical of folding and shear wrap around features indicative of flow around obstacles and broad piedmont like lobes as the valley fill extends out into the northern lowlands the single integrated system containing these features covers about 30 000 km2 and is one of dozens of fretted valleys along the dichotomy boundary in this region these relationships suggest that the boundary area was subjected to very large scale regional glaciation during the amazonian recognition and documentation of this important late stage process provides information critical to reconstructing the original dichotomy boundary

inferring tectonic provenance of siliciclastic rocks from their chemical compositions a dissent abstract chemical compositions of siliciclastic sedimentary rocks are commonly used to infer their tectonic provenance we have tested the universal applicability of the underlying principle in a small but controlled study expecting 100 confirmation of the practice a comparison is made between the chemical composition of the 1480 ma butler hill granite in an uplifted cratonic block of the st francois mountain igneous complex and that of a small 1 m thick regolith body a weathered granite sample and the basal quartz arenites of the 520 ma lamotte formation immediately above the regolith the results show that in plots of k 2 o na 2 o vs sio 2 al 2 o 3 the regolith and sandstone samples correctly plot in the passive margin field although the weathered granite plots in the arc field in plots of th sc zr 10 and la th sc the results plot in the passive and active continental margins and their extensions in other common plots to discriminate tectonic provenance e g sio 2 vs k 2 o na 2 o fe 2 o 3 mgo vs al 2 o 3 sio 2 fe 2 o 3 mgo vs tio 2 sc cr vs la y a few points plot in the passive margin field but scatter into and outside of other fields of tectonic provenances the chondrite normalized ree distributions show variable degrees of negative eu anomalies with flat hree conforming to a felsic source the lree distributions show both positive and negative ce anomalies that can be ascribed to the variability of redox conditions during weathering and diagenesis of the original siliciclastic sediments the variability of the eu anomaly was likely affected by post erosion processes in addition to whatever was inherited from the parent rocks we conclude that chemical compositions can provide good clues but are neither strong indicators nor unique identifiers of their tectonic provenance rather they indicate a dominantly felsic or dominantly mafic or a mixed set of source rocks

geochemistry of shales from the archean 3 0 ga buhwa greenstone belt zimbabwe implications for provenance and source area weathering abstract phyllites from the archean 3 0 ga buhwa greenstone belt zimbabwe were deposited on a stable cratonic platform analyses of the phyllites generally define a single geochemical group based on major and trace element abundances the phyllites are strongly depleted in cao na2o and sr with respect to average archean upper crust by contrast k2o ba and rb are enriched several times relative to average archean upper crust reflecting basin scale k metasomatism transition metals are somewhat depleted whereas high field strength elements are typically enriched relative to average archean upper crust samples generally have fractionated lree patterns average cen smn 2 4 with small negative eu anomalies average eu eu 0 78 and generally flat hrees average gdn ybn 1 3 such geochemical characteristics suggest that the source dominantly consisted of tonalite with less common occurrences mafic volcanic rocks and granite mixing calculations which massbalance the rees and th sc suggest 70 tonalite 15 mafic volcanic rocks and 15 granite as possible proportions for the source of the phyllites a nearby early archean 3 5 ga continental nucleus preserves similar lithologies and is the probable source intense chemical weathering of the source terrane is indicated by premetasomatized chemical index of alteration values of 95 100 nearly complete depletion of cao and na2o and high al2o3 na2o ratios fine grained sediments of comparable age and presumed tectonic setting elsewhere in southern africa show similar geochemical characteristics implying that source area compositions and weathering intensities were similar these mature platformal deposits suggest a tectonically stable environment where intense chemical weathering took place at 3 0 ga across southern africa

provenance diagenesis tectonic setting and geochemistry of tawil sandstone lower devonian in central saudi arabia abstract the tawil sandstone lower devonian in central saudi arabia overlies the sharwara member of the tayyarat formation silurian and succeeded conformly by the shaiba member of the jauf formation petrographical data reveal that the tawil sandstone comprises 96 quartz 3 feldspar and 1 rock fragments and all samples are classified as quartz arenites the presence of well sorted altered to fresh feldspar and discriminate function analysis suggests that the sediments have been subjected to substartial reworking resulting in a high level of maturity modal analysis data q f l suggest a stable cratonic provenance for the sediments and accumulation in a passive margin basin is indicated binary plot of sio2 vs k2o na2o diagenetic features include dissolution of feldspar and rock fragments compaction reduction of the existing pore space through rearrangements and rotation and fragmentation of grains resulting in dissolution of quartz grains and cementation

the terminal ediacaran tubular fossil cloudina in the yangtze gorges area of south china abstract the advent of biomineralizing metazoans in the terminal ediacaran age ca 550 539 ma represents a remarkable biological innovation in the history of life as a poster child of this evolutionary episode cloudina is widely regarded as a weakly biomineralizing tubular fossil with a global distribution therefore cloudina can both inform the evolution of animal biomineralization and facilitate terminal ediacaran stratigraphic correlation however this key taxon has not been fully described from the yangtze gorges area of south china where classical terminal ediacaran strata have been investigated extensively by paleontologists stratigraphers and geochemists here we document an assemblage of three dimensionally silicified tubular fossils from siliceous dolostone of the terminal ediacaran baimatuo member of the dengying formation in the yangtze gorges area western hubei province south china the baimatuo assemblage consists of sinotubulites which has been previously known in the baimatuo member as well as cloudina including c ningqiangensis c hartmannae c cf carinata and c sp indet and other unnamed tubular forms this discovery adds to the diversity of early biomineralizing metazoans in the yangtze gorges area and facilitates the biostratigraphic correlation of the cloudina sinotubulites co occurrence assemblage in terminal ediacaran strata

influence of provenance weathering and sedimentary processes on the elemental ratios of the fine grained fraction of the bedload sediments from the vembanad lake and the adjoining continental shelf southwest coast of india abstract geochemical studies comprising twelve major elements and twenty four trace elements including the rare earth elements ree have been carried out on the concentrations normalized to the average upper continental crust ucc show that the sediments studied are depleted in rb k ba ta hf na and ca and enriched in cs u th rees sc fe co and cr ucc normalized patterns are strikingly similar for all the three sediment types probably because of efficient mixing of sedimentary material during weathering transport and deposition the depletion of na k ca and ba in sediments relative to ucc could be attributed to their mobility during weathering the depletion of ta and hf and enrichment of th ree and sc are probably related to provenance characteristics and enrichment of u is attributed to oxidation reduction processes shale normalized ree values reveal steep hree patterns tbsample tbshale ybsample ybshale lasample lashale smsample smshale and flat lree patterns the shale normalized patterns for all the three types of sediments are remarkably similar with variations in the magnitude of lree enrichment lan ybn varies between 1 72 to 2 57 times that of paas lree enrichment and steep hree patterns are attributed to felsic source rock characteristics other geochemical characteristics such as high la th and low la sc and th sc ratios compared to ucc also support a felsic provenance eu eu values for all the three types are little more than 1 which is also a characteristic feature of archean crust furthermore data plotted on discrimination diagrams of la th vs hf and la th sc cluster closer to granite and away from basalt and komatiite and are consistent with source rock geology geochemical data have also helped in ascertaining the weathering trends the chemical index of alteration cia has been used to quantify the degree of weathering cia values range between 81 and 94 on a scale of 40 100 indicating a high degree of alteration fluvial sediments seem to be more altered on an a cn k diagram the data fall closer to the compositional fields of highly weathered minerals kaolinite gibbsite and chlorite a high degree of weathering is also indicated by other plots such as k2o fe2o3 al2o3 and log k vs log rb the geochemical data are consistent with the studies on clay mineralogy higher kaolinite carried out by other authors on the sediments of the same area secondary processes seem to affect other geochemical discriminants such as co cr ni and u as revealed by plots of 1 la sc vs co th and 2 th hf co and co th cr th ratios and makes them unsuitable for determining provenance and tectonic setting

the provenance of garnet constraints provided by studies of coastal sediments from southern india abstract the provenance of sediment with heavy mineral suites containing garnets with low grossular and high pyrope contents is enigmatic such garnet assemblages characterise sediments in many basins worldwide they are especially common in the sedimentary basins around northern britain but their source cannot be identified in adjacent basement rocks this paper documents garnet populations in beach dune and river sands from southern india which almost exclusively comprise low grossular high pyrope garnets these are derived from the high grade granulite facies metasedimentary and charnockitic rocks that form the basement in this area by analogy similar lithologies are inferred to source sediments with low grossular high pyrope garnet assemblages seen elsewhere in the case of the sandstones of northern britain the most likely location of such material is considered to be greenland

provenance and tectonic setting of the proterozoic turbidites in hunan south china geochemical evidence the geochemical composition of the middle upper proterozoic turbidites in hunan south china is related to provenance and tectonic setting of the sedimentary basin the turbidites are characterized by moderate sio 2 contents al 2 o 3 sio 2 typically 0 1 0 3 and moderate k 2 o na 2 o ratios generally 0 1 0 3 but relatively high fe 2 o 3 mgo contents 5 10 wt and unusually low contents of cao typically 1 wt abundances of ferromagnesian trace elements and incompatible elements are moderate the ree patterns are uniform and similar to the upper continental crust and typical post archean shales with lree enrichment flat hree and significant negative eu anomalies in general the slates show higher contents of fe 2 o 3 mgo and ferromagnesian trace elements and lower ratios of la sc and th sc than the associated graywackes suggesting that more mafic materials were incorporated into the clay size fraction compared to the upper proterozoic banxi group the middle proterozoic lengjiaxi group has higher concentrations for most ferromagnesian trace elements and lower la sc ratios implying more mafic components in the provenance of the latter the relationship among alkali and alkaline earth elements the chemical index of alteration cia and the th u ratios indicate that the source area was affected by a moderate weathering history the main source was old continental crust the yangtze craton dominated by felsic rocks of magmatic origin with a variable admixture of mafic components from continental island arcs e g the fangjingshan dayong and the sibao yiyang island arc chains the flysch deposition took place in a back arc basin rather than a failed intracontinental rift as proposed by some workers we suggest that suturing between the yangtze and cathaysia blocks did not occur until late proterozoic time and that the final assembly of the supercontinent rodinia in south china was probably marked by the jingning orogeny at 0 8 ga

sedimentary rocks and crustal evolution tectonic setting and secular trends a significant change in the composition of turbidites deposited at active tectonic settings is seen at the archean post archean transition in comparison to post archean active margin turbidites archean greenstone turbidites exhibit more uniform th sc ratios but with a similar average greater hree depletion gd n yb n 2 less eu depletion eu eu mostly 0 85 and an absence of low th u ratios th u 3 these data indicate that differing mantle sources and or conditions of mantle melting existed during the archean and that intracrustally differentiated rocks older cratons or young differentiated arcs were relatively unimportant as provenance components for archean turbidites in contrast some sedimentary rocks preserved in archean platformal sequences of high grade terranes display significant negative eu anomalies similar to the majority of post archean shales indicating that the general process of cratonization including intracrustal differentiation has taken place since at least 3

geochemistry of high grade supracrustal rocks from the kerala khondalite belt and adjacent massif charnockites south india abstract the kerala khondalite belt kkb comprises a suite of supracrustal rocks of probable proterozoic age that was metamorphosed to the granulite facies the kkb consists of an interlayered sequence of 1 garnet biotite orthopyroxene graphite gneisses 2 khondalites graphite garnet biotite sillimanite cordierite gneisses and 3 cordierite gneisses garnet biotite cordierite orthopyroxene as well as less abundant mafic granulites calc silicates and quartzites petrologic and geochemical data suggest that these rocks were originally arkosic and argillaceous sediments possibly accompanied by felsic volcanic rocks along with minor intercalations of basalts carbonates and quartz rich sandstones the ree patterns of the metasediments are typically lree enriched with large negative eu anomalies indicating a continental provenance the major and trace element compositions of some of the arkosic rocks of the kkb resemble those of the massif charnockites that bound the kkb to the north which suggests that the massif charnockites may have been the source of some of the kkb sediments modern day analogues of the pelite arkose lithologic association observed in the kkb occur in intracratonic rifts and rifted continental margins this association is clearly distinct from the graywacke mafic volcanic association found in the southern indian greenstone belts and many other lower grade archean sedimentary sequences the kkb supracrustals show both lithologic and chemical similarities to many proterozoic supracrustal successions

mechanism and effect of chemical weathering of sedimentary rocks the mineralogy geochemistry and physical and mechanical properties of rocks from four weathering profiles of miocene to pleistocene mudstones and sandstones in japan showed that chemical weathering of sedimentary rocks is characterized by sequential reaction between percolating groundwater and rock forming minerals pyrite a common mineral contained in sedimentary rocks is especially important in these sequential reactions pyrite is oxidized by oxygen coming from the ground surface and sulfuric acid is generated at the base of the oxidized zone the sulfuric acid in turn dissolves rock forming materials to make a dissolved zone if the fluxes of oxygen and water are in the same direction sulfuric acid generated at the oxidation front migrates farther and forms a dissolved zone if these fluxes are in opposite directions the oxidized and dissolved zones are not differentiated rocks in the dissolved zone are caused to deteriorate by the acid leaching and are acidic if buffering minerals such as calcite and zeolite are absent in the oxidized zone sandstone is strengthened because of cementation by iron oxide or hydroxide while mudstone is weakened because it has greater clay fractions and larger specific surface areas than sandstone

ree geochemistry of recent clastic sediments from the kaveri floodplains southern india implication to source area weathering and sedimentary processes abstract the kaveri river drains through archean gneissic and charnockitic terranes in south india the rare earth element ree chemistry of the floodplain sediments along with their major and trace element composition in different size fractions are discussed we observe a strong coherence between ree and tio2 contents in the sediments which is suggestive of strong control by titanite or its weathered products on the ree chemistry ree concentrations also show a general increase with decreasing size of bulk sediments different size fractions and of light and heavy mineral fractions this suggests the presence of ree in the fe oxy hydroxide surface coatings on clastic grains formed by the weathering of hornblende and titanite in the granodioritic to dioritic protoliths we also interpret the data as showing that ree patterns of clastic sediments notably eu anomaly are affected by the degree of source rock weathering as well as by the fluvial processes of sorting and mineral differentiation therefore for provenance study sediments having all granulometric grades such as the floodplain sediments are preferable because they most closely represent the source particularly when the source region suffered little chemical weathering in the present case the sediments were derived from the high standing hills of archean charnockites because of their recent uplift and physical denudation

geochemical records of qionghai lake sediments in southwestern china linked to late quaternary climate changes abstract knowledge of the chemical weathering history under the subtropical monsoonal climate will help to resolve the discrepancies regarding how climate conditions constrain chemical weathering major element and rare earth element ree compositions of the qionghai lake sediments in sichuan province southwestern china were analyzed aiming to provide information on sediment source discrimination and history of chemical weathering intensities and its responses to variations of indian summer monsoon ism and paleoclimate conditions as revealed by the a cn k diagram and other provenance proxies including tio2 zr ratio th sc vs zr sc and la th vs hf diagrams as well as the ree characteristics the source of qionghai lake sediments was felsic rocks additionally these sediments were subjected to small changes in provenance sedimentary sorting and recycling and weak diagenesis after deposition and or metasomatism indicating original signals were maintained on the intensity of chemical weathering of source area the chemical weathering intensities inferred from cia chemical index of alteration values have significantly fluctuated over the past 28 kyr reflecting three stages of paleoclimate evolution which is consistent with grain size characteristics carbonate contents low frequency magnetic susceptibilities toc and biomarker proxy paq the cia values changed significantly during the typical warm and cold climate events including the last glacial maximum heinrich 1 cold event younger dryas and holocene climatic optimum and generally exhibited an increasing trend in amplitude correspondingly in concert with the climate shifting from cold and dry to warm and humid conditions generally warm and humid climate conditions suggest enhanced chemical weathering intensity whereas weak chemical weathering denotes cold and dry climate in the ism region in addition sequential variations of the cia values during the past 28 kyr may reflect changing chemical weathering processes in responses to the varying intensities of indian summer monsoon and the climate conditions forced by the northern hemisphere solar insolation

geochemistry of the floodplain sediments of the kaveri river southern india abstract the floodplain sediments of the kaveri river southern india derived from archean gneissic and charnockitic source regions show interbedding of silty 4 4 7 and sandy units 1 4 3 7 the geochemistry of silty beds is remarkably uniform at a given location and over a lateral distance of nearly 250 km the sandy beds have more variable chemical compositions yet are comparable to those of silty beds except for the diluting effect of quartz silty sediments retain the geochemical signature of prominently exposed source rocks for almost all elements and provide evidence of tectonic instability in the source region the floodplain sediments contain all size grades sand silt and clay which may have resulted in minimizing the biases imposed on suspended and bedload sediments due to sorting the low chemical index of alteration cia the dominance of unweathered primary minerals and the minor proportion of smectitic clay all suggest that the region has been subjected to little chemical weathering this is possible if the region has undergone recent uplift exposing fresh archean rock to surface denudation the formation of fertile farmland along the kaveri river course and its delta is related to these recent geological processes

geochemistry of fine grained clastic sediments in the archean abitibi greenstone belt canada implications for provenance and tectonic setting abstract archean sandstone and shale samples from turbiditic tf and alluvial facies af in the southern volcanic zone of the abitibi greenstone belt canada have been analyzed for major and trace elements the sandstones from tf are mainly greywackes whereas those from af are lithic arenite sio 2 ranges from 51 to 68 geochemically the clastic sediments cluster into mafic element mep and low mafic element lmep populations the mep sediments which include turbiditic facies sediment samples from the larder lake group in the kirkland lake area are characterized by elevated abundances of mgo 5 ni 200 ppm cr 400 ppm sc 22 ppm and feo 7 5 abundances lower contents of incompatible elements such as th u ta hf zr and total rees n ratios are 4 5 with eu eu 1 the lmep sediments which include samples from the beatty dome and three nations lake formations in timmins the kewagama group noranda area and timiskaming group in the kirkland lake area however show reverse abundance distributions the geochemical gaps shown by the major and trace elements define two populations of sediments suggesting contrasting provenances for them the mep sediments require a dominantly mafic and ultramafic 90 source with 10 felsic contribution whereas the lmep sediments require a mixture of felsic 75 and mafic 25 rocks this compositional distribution of the sediments is closely related to their tectonic environments the mep was formed in basins proximal to or within an active oceanic rift consequently having ultramafic and mafic rocks as the major source for the lmep calc alkaline volcanic sequences formed in an island arc like setting were the major source these two contrasting volcanic plutonic terranes were tectonically juxtaposed during late archean collisional tectonics

dehydration melting phenomena in leptynitic gneisses and the generation of leucogranites a case study from the kerala khondalite belt southern india

another look at rare earth elements in shales linear correlation and mass balance considerations indicate that clays are more important than zircon or other heavy minerals in hosting both light and heavy ree in cratonic shales considering the uniformity of the eu anomaly and ree distributions in cratonic shales it seems likely that detritus is thoroughly mixed during weathering and sediment transport and that the ree patterns in shales reflect the average ree pattern of the sources regardless of the ratio of clays to heavy minerals in the shales shales suspended river loads and near shore marine sediments all have broadly similar ree patterns and reported hree depletions in the latter two groups may reflect incomplete dissolution of heavy minerals during sample preparation ree distributions in shales and suspended river loads determined by inna are similar to those in average upper continent crust and ree distributions in shale averages nasc and paas seem to be reasonably representative of the average composition of post archean upper continental crust

geochemistry of sandstones from the upper miocene kudankulam formation southern india implications for provenance weathering and tectonic setting abstract petrographic major trace and rare earth element compositions of sandstones from the upper miocene kudankulam formation southern india have been investigated to determine their provenance tectonic setting and weathering conditions all sandstone samples are highly enriched in quartz q but poor in feldspar f and lithic fragments l the major element concentrations of these sandstones reveal the relative homogeneity of their source geochemically the kudankulam sandstones are classified as arkose subarkose litharenite and sublitharenite the cia values chemical index of alteration mean value 44 5 for these sandstones and the a cn k diagram suggest their low weathering nature similarly their fe2o3 mgo mean 2 7 al2o3 sio2 0 09 k2o na2o 2 2 ratios and tio2 contents 0 3 are consistent with a passive margin setting the eu eu 0 5 la lu cn 21 la sc 5 9 th sc 1 9 la co 5 7 th co 1 8 and cr th 5 3 ratios support a felsic source for these sandstones chondrite normalized ree patterns with lree enrichment flat hree and negative eu anomaly also are attributed to felsic source rock characteristics for kudankulam sandstones total ree concentrations of these sandstones reflect the variations in their grain size fractions the source rocks are probably identified to be proterozoic gneisses charnockites and granites of the kerala khondalite belt which must have been exposed at least since the late miocene finally the unusual ni enrichment in the kudankulam sandstones unaccompanied by a similar enrichment in cr co and v may be related to either the presence of pyrite in the sandstones or more likely the fractionation of garnet from the source rocks during transportation

the cr th ratio in precambrian pelites from the kaapvaal craton as an index of craton evolution the cr th ratio in precambrian pelites from the kaapvaal craton in southern africa correlates with pelite th sc and co th ratios and appears to monitor changes in source composition it is a more sensitive indicator of provenance than other commonly used ratios including eu eu la yb and th u pelite cr th ratios are controlled most strongly by the effects of local provenance and local tectonics secular decreases in this ratio the most prominent of which occurred at 2 4 2 3 ga in pelites of the kaapvaal craton record rapid uplift exposing granite decreases in the ratio reflect increases in the abundance of komatiite basalt in sediment sources in response to arc collisions rift hotspot volcanism or intracratonic uplift of older greenstones relatively constant cr th ratios appear to require widespread uplift or and efficient sediment mixing during tectonic stability changes in cr th ratio of kaapvaal pelites reflect a complex tectonic history of the craton from about 3 3 ga to 1 8 ga and do not favor single stage cratonization in the late archean

geochemistry of cumulus peridotites and gabbros from the marum ophiolite complex northern papua new guinea the layered cumulus rocks of the marum ophiolite complex in northern papua new guinea range from highly magnesian dunite wehrlite and lherzolite through pyroxenite to norite gabbro with minor anorthosite and ferronorite gabbro near the top of the sequence most of the cumulates particularly the gabbroic rocks are characterised by recrystallised adcumulus textures and all intercumulus melt mesostasis has been expelled trends in the cumulate sequence from mg rich to more fe ca and al rich compositions are consistent with the formation of the layered sequence by magmatic accumulation from mafic tholeiitic magmas with varying degrees of differentiation the cumulates are characterised by extremely low levels of incompatible elements k ba rb p zr nb hf y and ree at all levels of differentiation ree patterns are strongly depleted in lree hree abundances range from 0 3 chondrites in peridotite to 3 x chondrites in the norite gabbros

the influence of sediment recycling and basement composition on evolution of mudrock chemistry in the southwestern united states this paper reports systematic changes in mudrock composition through time on a single con tinental cmstal block the changes reflect both sediment recycling processes and changes through time in the composition of crystalline material being added to the sedimentary system and are related to tectonic evolution as the block matures from a series of accreted arc terranes to a stable craton the major and trace element distributions reflect different aspects of the provenance of the mudrocks in this study major elements record sediment recycling processes as well as changing proportions of sedi mentary and first cycle source rocks with the exceptions of kzo which tends to increase and sioz and a o3 which show no trend most major oxides tend to decline in relative abundance in younger mud rocks patterns shown by the index of compositional variability fe03 kro naao cao mgo mno tiojialro and by k20 a1203 indicate that the major oxide trends are due to decreasing proportions of nonclay silicate minerals and a concomitant increase in the proportion of clay minerals probably due to decreasing input of first cycle detritus coupled with recycling of sedimentary material excursions from progressive trends marked by increases in mgo k20 and cao reflect episodes of large scale input of nonclay first cycle minerals from crystalline source rocks due to large scale basement uplift the chemistry of low solubility trace elements in contrast is not sensitive to recycling effects and reflects the composition of first cycle input incompatible elements are progressively enriched relative to compatible elements in younger mudrocks and values for chondrite normalised rare earth elements also increase in addition the eu anomaly becomes systematically more negative in younger samples these trends cmnot be explained by diagenetic or weathering processes and therefore indicate that the proportion of fnc tionated granitic first cycle detritus being added to the sedimentary system becomes greater with time these results confirm the importance of tectonic setting in controlling mudrock chemistry and also demonstrate that there is a dynamic relationship between the tectonic evolution of a continental block and the composition of its sedimentary mantle

geochemistry of archean shales from the witwatersrand supergroup south africa source area weathering and provenance with a few exceptions shales from the archean witwatersrand supergroup 2800 ma in south africa are depleted in na ca lile ree and hfse compared to phanerozoic shales cr co and ni are enriched in all witwatersrand shales and fe and mg are high in shales from the west rand groups wrg and lower central rand group crg shales from the crg and uppermost wrg are enriched in na al lile ree hfse and transition metals relative to shales from the lower wrg chondrite normalized ree patterns for all witwatersrand shales are enriched in light ree and exhibit small to moderate negative eu anomalies a positive correlation of ree and al2o3 contents in the shales suggests that ree are contained principally in clay minerals relative to shales from the crg shales from the wrg exhibit depletions of na ca and sr a feature probably reflecting intense chemical weathering of their source rocks cia indices in witwatersrand shales are variable chiefly 70 98 even within the same shale unit such variations reflect chiefly variable climatic zones or rates of tectonic uplift in source areas with perhaps some contribution from provenance and element remobilization during metamorphism compared to present day upper continental crust all but the orange grove roodepoort and k8 shales appear to have been derived from continental sources depleted in lile ree and hfse and enriched in transition metals computer mixing models based on six relatively immobile elements th hf yb la sc co and four source rocks indicate that the relative proportions of granite basalt and komatiite increased with time in sediment source areas at the expense of tonalite the contributions of basalt and komatiite appear to reach a maximum during deposition of the booysens shale and granite during deposition of the k8 shales and possibly during deposition of the orange grove shales

ophiolitic source rocks for taconic age flysch trace element evidence flysch generated along the appalachian orogen during the ordovician taconic orogeny ranges in age from late arenig to early caradoc allochthonous flysch and from late llanvirn to ashgill autochthonous flysch sandstones in these units are dominantly lithic arenites with a heavy mineral suite containing common to abundant mg rich chromite north of the canada united states border the only reasonable sources for the chromite were the lower ultramafic units of obducted ophiolites trace element analyses cr ni v cu ti zr y of flysch sandstones indicate a striking increase in cr and ni concentrations from the united states appalachians to the canadian appalachians in the united states units cr is in the range of 10 to 50 ppm canadian flysch units average an order of magnitude more cr these results suggest that ophiolite obduction either did not occur or was of minor importance during the taconic orogeny in the united states appalachians the difference in ophiolite abundance between the canadian and united states appalachians suggests a fundamental difference in tectonic style along the orogen a feature that must be accommodated by plate tectonic models new models will probably need to consider both obliquity of subduction and geological complexity of the ordovician collision zone in order to explain the spatial distribution of obducted ophiolite sheets

elemental distributions and neodymium isotopic compositions of silurian metasediments western maine usa redistribution of the rare earth elements abstract pelitic schists from the lower garnet to lower staurolite zones from the rangeley perry mountain and smalls falls formations of western maine were analyzed for major elements trace elements and neodymium isotopes these formations were derived from highlands created during the taconian orogeny deposited into a trough and metamorphosed during subsequent orogenic events most major and trace element abundances relative to al 2 o 3 were statistically identical between zones of the same formation as well as between formations although the average major element composition of these formations are the same there are systematic variations in some elements notably plots of sio 2 vs al 2 o 3 and k 2 o vs al 2 o 3 suggest that most of the variation could be produced by mixing of a fairly constant ratio of clay minerals and feldspar with varied amounts of quartz due to sorting in the sedimentary system different amounts of these minerals should not influence the shape of the ree patterns of the metapelites but higher amounts of quartz and feldspar may dilute the rees and most elemental abundances of the clay minerals and lead to lower elemental abundances the major difference between the samples within the perry mountain formation are different lree and mree abundances relative to al 2 o 3 which are not correlated to differences in major element or other trace element abundances relative to al 2 o 3 the samples in the perry mountain with higher lree and mree abundances have for example 42 3 8 3 ppm and those with low abundances have 5 6 3 6 ppm the samples with the high ree abundances of the perry mountain formation are similar in abundances and ree patterns to those of the rangeley and smalls falls formations typical of mudstones derived from granitoids another difference between the low and high ree abundance samples are the calculated t dm model ages the high ree abundance samples of the perry mountain formation show t dm similar to the samples of the rangeley formation with ages of about 1 7 1 8 ga the perry mountain samples with low ree abundances however give unrealistically old t dm s between 2 5 and 5 3 ga these unrealistically old t dm s are due to the relatively high sm nd ratios compared to crustal values which are characteristic of samples of the perry mountain formation with lower ree abundances we therefore suggest that these samples may be indicators for open system behavior of the neodymium isotopic system the timing of this disturbance of the neodymium isotope system is difficult to determine and cannot be tied to weathering or a definite postdepositional event the complexities of the data suggest more than one resetting event the most likely event that could have produced much of the movement of the lrees and mrees could have been due to small scale migration between anoxic hemipelagites and turbidite mudstones during diagenesis but some migration may have continued during metamorphism in order to reconcile the neodymium isotopic data

the negative eu anomaly in archean sedimentary rocks implications for decomposition age and importance of their granitic sources abstract a negative correlation between eu anomaly eu eu and chemical index of weathering ciw is found for archean pelites in both greenstone belts and high grade terrains from southern africa western greenland north america western australia and china a similar negative correlation betweeneu eu and chemical index of alteration cia is also found for worldwide young deep sea sediments from various tectonic settings the increase in the indices of weathering and alteration coincide with both shifts in mineral composition and mineral decomposition from plagioclase k feldspar to mica kaolinite and from amphibole to chlorite smectite juvenile crustal materials from local sources are only slightly decomposed due to little or no transport they are characterized by low ciw cia and negligible eu anomalies in contrast crustal materials from large provenance areas have usually suffered long transport and recycling which results in decomposition of high temperature minerals and large ciw cia values that are negatively correlated with significant negative eu anomalies thus the observed trends are interpreted as mainly reflecting increasing contributions of recycled and decomposed materials from large provenances relative to juvenile crustal additions through arc magmatism at local sources in this context there is no obvious distinction between archean greenstone and high grade metasediments and young deep sea sediments the large provenance areas have contained a significant proportion of granitic and rhyolitic materials which in part have not resisted decomposition and erosion due to their occurrence in shallow crustal layers granites received their distinctive negative eu anomaly from equilibration with a feldspar rich residuum the negative eu anomaly of archean metaclastic sediments apparently increased with decreasing age trends of minimum and averageeu eu values of metaclastic sediments evolving with time are calculated for the archean and lead us to infer that the negative eu anormaly eu eu

the controls on the major and trace element variation of shales siltstones and sandstones of pennsylvanian permian age from uplifted continental blocks in colorado to platform sediment in kansas usa shales siltstones and sandstones of pennsylvanian permian age from near the source in colorado to those in the platform in eastern colorado and kansas have been analyzed for major elements and a number of trace elements including the rees the near source sandstones are significantly more enriched student t test at better than the 99 confidence level in sio2 and na2o concentrations and more depleted in al2o3 fe2o3 total tio2 th hf sc cr cs rees y and ni concentrations and laco and lani ratios than the near source shales and siltstones most likely due to more plagioclase and quartz and less clay minerals in the sandstones than in the shales and siltstones there are no significant differences in k2o and sr concentrations and eueu lalu lase thsc thco and crth ratios between the near source sandstones and the near source shales and siltstones samples of the molas hermosa and cutler formations near the source that were formed in different environments in the same area contain no significant difference in eueu lalu lasc thsc thco and crth ratios so a generally silicic source and not the environment of deposition was most important in producing these elemental ratios for example crth ratios of near source shales siltstones and sandstones range from 2 5 to 17 5 and eueu range from 0 48 to 0 78 which are in the range of sources of sediments derived from mainly silicic and not basic sources near source shales and siltstones contain significantly higher student t test and more varied concentrations of most elements al2o3 fe2o3 mno tio2 ba th hf ta co sc rees nb y but significantly lower concentrations of na2o and eueu than platform shales and siltstones in kansas e g la 65 7 40 and eueu 0 55 0 07 in near source shales and siltstones and la 23 7 8 7 and eueu 0 64 0 08 in platform shales and siltstones the sio2 and cao concentrations are not significantly different in platform shales and siltstones compared to the near source shales and siltstones so dilution of other minerals by quartz and calcite is not the main reason for the lower concentration of most elements in the platform relative to the near source shales and siltstones rather the lesser concentrations of most elements in clay minerals of the platform shales and siltstones can account for the lower concentration of most elements compared to corresponding near source shales and siltstones the lower concentrations of many elements in clay minerals in the platform shales and siltstones may be a result of having been derived from recycling of clay minerals from older rocks the greater homogeneity of elemental concentrations of the platform shales and siltstones compared to those in the source is also consistent with homogeneous mixing of such recycled material also there is no significant difference in thsc laco thco lani and crth ratios of the near source sedimentary rocks in colorado to the platform shales and siltstones in kansas and the latter are also consistent with derivation from mostly silicic source rocks

geochemical discrimination of clastic sedimentary rock sources abstract factors controlling the geochemistry of a clastic sedimentary rock can include 1 composition of source terrain 2 chemical weathering 3 hydraulic sorting 4 diagenesis 5 metamorphism and 6 hydrothermal alteration a linear solution inferring source terrain composition from geochemistry of the sediment is impossible in this multivariate system as several unknowns will commonly be present the use of graphical analysis of element pairs circumvents the problem chemically immobile elements will maintain invariant ratios during rock mass change caused by either addition or depletion of mobile elements this results in chemically immobile element scattergrams exhibiting linear trends along radians extending from the origin if the major mineral phases of the immobile elements have behaved in a hydrodynamically similar manner as chemically mobile element plots will produce a scatter of points this relationship can be used to test chemical immobility and similarity in hydrodynamic sorting history the constraint on analysis is that the source area must be compositionally uniform or the sediment well mixed prior to delivery to the basin a second technique using sio2 plots has also been developed to investigate element mobility and hydrodynamic behaviour of the mineral phases containing the elements sio2 immobile element plots result in a linear arrangement of points extending towards either 0 or 100 sio2 the 0 intercept position occurs for elements with major mineral phases concentrated in sand the 100 intercept for those concentrated in clays plotting chemically mobile elements produces different patterns and this can be used to gain information on alteration and sorting history elemental ratios for chemically immobile elements with similar hydrodynamic behaviour will be the same as those for the weighted average composition of the source material this provides a powerful tool for deducing source terrain from sediment geochemistry techniques outlined above were tested on archaean metasandstones from superior province canada immobile element ratio diagrams for nb al ti and zr al ti indicate that a calc alkaline extrusive intrusive suite lying to the north of the study area was the source and not five other volcanic suites in the region this conclusion agrees with previous clast lithology studies and accentuates the applicability of the geochemical techniques

mineralogical and chemical changes of soil and stream sediment formed by intense weathering of the danburg granite georgia u s a abstract a series of soil and stream sediments developed during intense weathering on the metaluminous danburg granite northeastern georgia u s a have been analyzed mineralogically and chemically the concentrations of ba na rb and cs in the silt and coarser fractions are controlled mainly by feldspars and biotite hf is controlled by zircon and the ree rare earth elements and th are largely controlled by sphene variations in feldspar sphene and zircon may produce small variations in eu sm and la lu ratios ferromagnesian minerals control ta fe co sc and cr concentrations the mineralogical and chemical composition of the danburg granite is more closely reflected in the silt than in the sand or gravel fractions of stream sediments in the silt the contents of rb ree th ta fe co and sc and the ratios of la sc th sc la co th co eu sm and la lu are similar to those in the unweathered granite in contrast these element contents or ratios in the sands and gravels are 0 05 3 the concentration in the unweathered granite ta and ba contents are an exception to the above the ta and ba contents of the sands and gravels are similar to those of the granite in the kaolinite halloysite clays the content of na is depleted relative to the source rb cs ba hf and ta are depleted or enriched in the clays relative to the source while the ree th fe co sc and cr are enriched the eu sm eu anomaly size and la lu ratios and the ree patterns of the clays are similar to those of the source thus the mineralogy and element contents of a siltstone developed from metaluminous granitic sources during intense weathering would be expected to be more similar to the source rock than the sandstones and conglomerates claystones should contain similar ree patterns and eu sm ratios as the source rock but such fine grained sediments might represent much larger areas of source rocks than the more locally derived sandstones or conglomerates

geochemical signature of provenance in sand size material in soils and stream sediments near the tobacco root batholith montana u s a abstract trace element geochemistry of sandstones are being used to determine provenance we have conducted preliminary and limited experiments to determine to what extent daughter sands retain the geochemical signature of parent rocks six sets of first order stream sediments soils from adjacent slopes and a variety of parent rocks were collected from southwestern montana u s a sampling in a low relief area ensured that climate and residence time of soils on slopes could be eliminated as variables sand size fractions of stream sediments and soils and the corresponding parent rocks granodiorite quartz monzonite granite gneiss biotite tonalite gneiss and amphibolite were analyzed for most major elements and selected trace elements petrologic modal analysis of the parent rocks and the 0 25 0 50 mm fraction of each sand was done to monitor major mineralogic control if any on chemical compositions of the samples our data show that the abundances of the si and al in sediments do not discriminate provenance abundances of ca mg fe and ti may broadly distinguish between sands derived from metamorphic and igneous source rocks at least in the area studied differences in abundances of the ba and th and the ratio of la lu between granitic tonalitic and amphibolitic parent rocks are preserved in the daughter sediments that we studied however the size of the eu anomaly in the ree patterns of different daughter sediments is not diagnostic of parent rocks abundances of co and sc distinguish between sediments derived from felsic and mafic rocks a better provenance discrimination is obtained if the ratios la sc th sc la co ba sc and ba co are used petrologic modal data show that mineral contents and chemical compositions of parent rocks are compatible with each other the chemical composition of the sands may be roughly correlated to the petrological modal data but the abundances of some minor and trace elements of sediments cannot be inferred from modal mineralogy this is expected because these elements may concentrate in accessory minerals and or may weather out into aqueous or clay mineral fractions it is also compatible with conclusions of previous studies that some of these elements do not reside in sand size fractions of siliciclastic sediments

geochemistry and provenance of sediments from the pongola supergroup south africa evidence for a 3 0 ga old continental craton abstract the 3 0 ga pongola supergroup of south africa is one of the oldest well preserved supracrustal successions the sequence is divided into the nsuze chiefly volcanics quartzites and pelites and the overlying mozaan groups chiefly quartzites and pelites relative to north american shale composite nasc most pongola pelites have similar la yb and eu eu ratios and large ion lithophile elements lile high field strength elements hfse ree v and sc contents ni 30 300 ppm and cr 100 800 ppm contents are greater than those of nasc while cr ni ratios are generally higher than shales and pelites of all ages these trends may reflect residual cr enrichment during intense chemical weathering of komatiitic source rocks local populations of nsuze pelites based on major and trace element data may result from source heterogeneities and or contemporaneous volcanic input into the sedimentary basin pongola quartzite compositions and detrital modes are similar to those of sandstones from phanerozoic passive margin and basement uplift tectonic settings ree lile and hfse contents in pelites suggest that pongola source rocks were remarkably similar in composition to average phanerozoic upper continental crust trace element geographic and isotopic constraints favor 3 2 to 3 0 ga hood granites as a major source for pongola detritus moderate contributions from mafic sources are also required whereas relatively minor contributions from tonalite and komatiite are allowed these results indicate the existence of a chemically evolved felsic craton in southern africa by 3 0 ga this craton appears to have been more evolved than sources for either older moodies 3 3 ga or most of the younger witwatersrand sediments 2 8 2 7 ga pelites from the kaapvaal craton record at least two mafic to felsic source area compositional cycles in pelites deposited from the mid to late archean additional cycles may be masked by a depositional or erosional hiatus between the moodies and pongola sequences these sedimentary patterns suggest that crustal development in southern africa was episodic in nature during the early precambrian

tectonic setting and provenance of the neoproterozoic uinta mountain and big cottonwood groups northern utah constraints from geochemistry nd isotopes and detrital modes abstract the neoproterozoic uinta mountain group was deposited in an east trending intracratonic rift bounded on the north by an active fault system and opening into a shallow sea on the west where the big cottonwood group was deposited in an estuary although this rift may have been associated with the early stages in the breakup of rodinia it was not an aulacogen geochemical nd isotope and detrital mode studies indicate that uinta mountain group sediments were derived from mixed archean and paleoproterozoic sources with the former dominating big cottonwood group sediments appear to have been derived predominantly from paleoproterozoic sources the archean sediment source is the wyoming craton and source rocks comprised dominantly granites enriched in th u y zr hf and ree the relative abundance of enriched granite implied by sedimentary rocks of the uinta mountain group indicates that the wyoming craton is anomalous compared to other archean cratons cia values and a cn k relationships in shales of the uinta mountain and big cottonwood groups indicate high degrees of weathering of sources probably in subtropical to tropical climates supporting a near equatorial location for southwestern laurentia at about 800 ma differences in the nd isotopic composition between the big cottonwood group and neoproterozoic sedimentary rocks in western utah and northeast nevada suggest a northwest striking uplift in northwest utah possibly ancestral to the paleozoic toole uinta arch

quantification of the effects of secondary matrix on the analysis of sandstone composition and a petrographic chemical technique for retrieving original framework grain modes of altered sandstones abstract most studies of sandstone provenance involve modal analysis of framework grains using techniques that exclude the fine grained breakdown products of labile mineral grains and rock fragments usually termed secondary matrix or pseudomatrix however the data presented here demonstrate that when the proportion of pseudomatrix in a sandstone exceeds 10 standard petrographic analysis can lead to incorrect provenance interpretation petrographic schemes for provenance analysis such as qfl and qfr should not therefore be applied to sandstones containing more than 10 secondary matrix pseudomatrix is commonly abundant in sandstones and this is therefore a problem for provenance analysis the difficulty can be alleviated by the use of whole rock chemistry in addition to petrographic analysis combination of chemical and point count data permits the construction of normative compositions that approximate original framework grain compositions provenance analysis is also complicated in many cases by fundamental compositional alteration during weathering and transport many sandstones particularly shallow marine deposits have undergone vigorous reworking which may destroy unstable mineral grains and rock fragments in such cases it may not be possible to retrieve provenance information by either petrographic or chemical means because of this pseudomatrix rich sandstones should be routinely included in chemical petrological provenance analysis because of the many factors both pre and post depositional that operate to increase the compositional maturity of sandstones petrologic studies must include a complete inventory of matrix proportions grain size and sorting parameters and an assessment of depositional setting

provenance evolution of oligocene pliocene foreland deposits in the dezful embayment to constrain central zagros exhumation history this paper presents a detailed provenance analysis of the 6 5 km thick oligocene pliocene foreland succession in the north dezful embayment in zagros iran using petrography geochemistry and palaeoflow analysis we determined three provenance shifts during the exhumation of the zagros orogen above the ahwaz sandstones sourced from the arabian craton a sharp decrease in sio2 al2o3 zr sc th sc th co and th cr within the gachsaran fm and the appearance of first cycle sands derived from metamorphic and volcanic rocks at the base of the aghajari fm characterize the onset of exhumation rising topography and denudation of the zagros orogenic system during the latest oligocene and constitute the first shift the second shift in the middle aghajari fm is marked by a distinct increase in radiolarian cherts and compatible incompatible elements indicating the exhumation of neotethyan radiolarite ophiolite allochthonous slices in the high zagros zone during the tortonian c 9 ma large quantities of carbonate clasts derived from the nearby growing izeh zone anticlines characterize the messinian c 7 ma bakhtyari conglomerates marking the third shift in conclusion a detailed hands on provenance analysis of the clastic sedimentary sequences in the north dezful embayment enabled us to determine catchment areas and shifts hitherto unstudied thus contributing to the exhumation history of the central zagros orogenic system supplementary material details of the petrography and geochemistry results are available at https doi org 10 6084 m9 figshare c 4905558

chromium and nickel in shale of the taconic foreland a case study for the provenance of fine grained sediments with an ultramafic source abstract to test the suitability of using shale geochemistry as a provenance indicator of a source with an ultramafic component we used i c p mass spectrometry to analyze 130 samples from seven localities from newfoundland to new york these samples represent mud from the foreland basin produced during the collision of the taconic are with north america in the ordovician the sandstones in the flysch contain detrital chromite and other detritus that indicate that the source contained ultramafic rocks presumably from ophiolites emplaced during collision this setting is an ideal test case for examining the spatial and temporal variation in cr and ni geochemistry of shale derived from ophiolite bearing highlands shale samples with high concentrations of cr and ni have a cr ni ratio of 1 4 which is approximately the cr ni ratio for ultramafic rocks 1 6 suggesting only minor geochemical partitioning but sandstones have a cr ni ratio of 3 0 suggesting significant sedimentary fractionation analyses of samples taken upsection in a single stratigraphic section suggest that proximity to the source influences cr and ni concentrations a decrease in cr and ni concentrations through time suggests that uplift and erosion of the thrust complex non ophiolitic diluted the ultramafic signal we attribute significant along strike variation in cr and ni concentrations to the relative proportion of ultramafic rocks in the source region this case study shows that cr and ni geoch mistry of shale from basin strata can be used to determine the lateral and temporal variability of ultramafic rocks in an active orogenic setting