the effect of clay minerals on diasterane sterane ratios to examine the effect of clay minerals on diasterane sterane ratios the mineral compositions of three sample sets of sedimentary rocks displaying a wide range of diasterane sterane ratios were analysed quantitatively diasterane sterane ratios do not to correlate with clay content but depend on the amount of clay relative to the amount of organic matter clay toc ratios this correlation may explain the high diasterane sterane ratios in crude oils and extracts derived from certain carbonate source rocks based on the concentrations of regular and rearranged steroids in the sample sets it is proposed that diasterenes are partly reduced to diasteranes and partly degraded during diagenesis in a ratio largely determined by the availability of clay minerals it is suggested that the hydrogen atoms required for reduction of the diasterenes originate from the water in the interlayers of clay minerals

the diversity of tectonic modes and thoughts about transitions between them plate tectonics is a particular mode of tectonic activity that characterizes the present day earth it is directly linked to not only tectonic deformation but also magmatic volcanic activity and all aspects of the rock cycle other terrestrial planets in our solar system do not operate in a plate tectonic mode but do have volcanic constructs and signs of tectonic deformation this indicates the existence of tectonic modes different from plate tectonics this article discusses the defining features of plate tectonics and reviews the range of tectonic modes that have been proposed for terrestrial planets to date a categorization of tectonic modes relates to the issue of when plate tectonics initiated on earth as it provides insights into possible pre plate tectonic behaviour the final focus of this contribution relates to transitions between tectonic modes different transition scenarios are discussed one follows classic ideas of regime transitions in which boundaries between tectonic modes are determined by the physical and chemical properties of a planet the other considers the potential that variations in temporal evolution can introduce contingencies that have a significant effect on tectonic transitions the latter scenario allows for the existence of multiple stable tectonic modes under the same physical chemical conditions the different transition potentials imply different interpretations regarding the type of variable that the tectonic mode of a planet represents under the classic regime transition view the tectonic mode of a planet is a state variable akin to temperature under the multiple stable modes view the tectonic mode of a planet is a process variable that is something that flows through the system akin to heat the different implications that follow are discussed as they relate to the questions of when did plate tectonics initiate on earth and why does earth have plate tectonics this article is part of a discussion meeting issue earth dynamics and the development of plate tectonics

a two phase model for compaction and damage 3 applications to shear localization and plate boundary formation a new two phase theory employing a nonequilibrium relation between interfacial surface energy pressure and viscous deformation bercovici et al this issue provides a model for damage void generation and microcracking and thus a continuum description of weakening failure and shear localization here we demonstrate applications of the theory to shear localization with simple shear flow calculations in which one phase the matrix representing for example silicate is much stronger more viscous than the other phase the fluid this calculation is motivated as a simple model of plate boundary formation in a shear zone even without shear the two phases eventually separate due to gradients in surface tension however the influence of shear on phase separation is manifest in several ways as shear velocity increases the separation rate of the phases increases demonstrating a basic feedback mechanism accumulation of the fluid phase causes focused weak zones on which shear concentrates causing more damage and void generation and thus greater accumulation of fluid beyond a critical shear velocity phase separation undergoes intense acceleration and focusing leading to a tear localization in which the porosity becomes nearly singular in space and grows rapidly like a tear or crack at an even higher value of shear velocity phase separation is inhibited such that shear localization gives way to defocusing of weak zones suggestive of uniform microcracking and failure throughout the layer our two phase damage theory thus predicts a wide variety of shear localization and failure behavior with a continuum model applications of the theory to various fields such as granular dynamics metallurgy and tectonic plate boundary formation are numerous

impact of grain size on the convection of terrestrial planets 1 this article presents a set of simulations of mantle convection using a new model of grain size dependent rheology in the present paper it is shown that this rheology behaves in many ways as a visco plastic rheology i use a model of grain size evolution which has been calibrated on experimental data in a previous paper in this physical model the grain size is directly related to the stress state following a temperature dependent piezometric law the rheology used here allows both diffusion and dislocation creep depending on the grain size at low stress the grain size is high and forces the rheology to be dislocation dominated for sufficiently high stresses the equilibrium regime reached by the grains is located in the diffusion creep in this case the viscosity is linked to a stress dependent grain size which actually makes the rheology more non newtonian than it is in dislocation creep this experimentally calibrated model allowed me to perform a set of numerical experiments of convection in which the rheology may be diffusion or dislocation creep dominated depending on the state of the stress tensor then the stress exponent varies from 3 to 5 because of grain size which has a large impact onthe temperature dependence of the viscosity the present paper shows the impact of this new model on the convection regimes of terrestrial planets in particular for a wide range of parameters i observe the episodic regime which is thought to govern the dynamics of venus this process of episodic resurfacing was obtainedin previous simulationsusing visco plastic rheologies is a tight rangeof parameters i obtainit herewithoutusinganad hocplasticitylaw onlyusingaviscousrheologybasedonlaboratorymeasurements in these simulations i show that the cooling rate of the terrestrial planets may be largely modified by the consideration of a grain size dependent rheology

mobile riverbed scour downstream of a piano key weir abstractin parallel to their most frequent application as an auxiliary dam spillway piano key weirs pkws are also installed on low head barrages in combination with run off the river power plants their efficient rating curve advantageous behavior under driftwood blockage and the absence of mechanical elements are optimal for the hydraulic conditions associated with these run off the river projects however in the absence of technical protection measures scouring of the riverbed can occur at the downstream foundation the unhindered scour formation and corresponding ridge generation caused by a pkw are investigated in this paper physical model tests were conducted under various conditions providing a general estimation of the equilibrium scour and ridge dimensions the maximum scour hole depth dominates the shape of the hole and of the ridge it was further shown that the maximum scour slope corresponds to the angle of repose of the sediments on the riverbed finally a comparison of the present

mantle convection with a brittle lithosphere thoughts on the global tectonic styles of the earth and venus summary plates are an integral part of the convection system in the fluid mantle but plate boundaries are the product of brittle faulting and plate motions are strongly influenced by the existence of such faults the conditions for plate tectonics are studied by considering brittle behaviour using byerlee s law to limit the maximum stress in the lithosphere in a mantle convection model with temperature dependent viscosity when the yield stress is high convection is confined below a thick stagnant lithosphere at low yield stress brittle deformation mobilizes the lithosphere which becomes a part of the overall circulation surface deformation occurs in localized regions close to upwellings and downwellings in the system at intermediate levels of the yield stress there is a cycling between these two states thick lithosphere episodically mobilizes and collapses into the interior before reforming the mobile lid regime resembles convection of a fluid with temperature dependent viscosity and the boundary layer scalings are found to be analogous this regime has a well defined nusselt number rayleigh number relationship which is in good agreement with scaling theory the surface velocity is nearly independent of the yield stress indicating that the plate motion is resisted by viscous stresses in the mantle analysis suggests that mobilization of the earth s lithosphere can occur if the friction coeycient in the lithosphere is less than 0 03 0 13 lower than laboratory values but consistent with seismic field studies on venus the friction coeycient may be high as a result of the dry conditions and brittle mobilization of the lithosphere would then be episodic and catastrophic

biomarker evidence for photosynthesis during neoproterozoic glaciation laterally extensive black shales were deposited on the sao francisco craton in southeastern brazil during low latitude neoproterozoic glaciation 740 to 700 million years ago these rocks contain up to 3 0 weight organic carbon which we interpret as representing the preserved record of abundant marine primary productivity from glacial times extractable biomarkers reflect a complex and productive microbial ecosystem including both phototrophic bacteria and eukaryotes living in a stratified ocean with thin or absent sea ice oxic surface waters and euxinic conditions within the photic zone such an environment provides important constraints for parts of the snowball earth hypothesis

formation of ridges in a stable lithosphere in mantle convection models with a viscoplastic rheology numerical simulations of mantle convection with a viscoplastic rheology usually display mobile episodic or stagnant lid regimes in this study we report a new convective regime in which a ridge can form without destabilizing the surrounding lithosphere or forming subduction zones using simulations in 2 d spherical annulus geometry we show that a depth dependent yield stress is sufficient to reach this ridge only regime this regime occurs when the friction coefficient is close to the critical value between mobile lid and stagnant lid regimes maps of convective regime as a function of the parameters friction coefficients and depth dependence of viscosity are provided for both basal heating and mixed heating situations the ridge only regime appears for both pure basal heating and mixed heating mode for basal heating this regime can occur for all vertical viscosity contrasts while for mixed heating a highly viscous deep mantle is required

convection in a variable viscosity fluid newtonian versus power law rheology abstract a number of finite element calculations of convection in a variable viscosity fluid have been carried out to investigate the effects of non newtonian flow when rheology is also subject to a strong temperature and pressure influence a variety of cases has been studied in the range of effective rayleigh numbers between 104 and 106 including different modes of heating and a range of values for activation energy and activation volume power law creep with a stress exponent of 3 turns out to lead to considerably different flow pattern and heat transfer properties than newtonian rheology in general the effect is to reduce viscosity contrasts imposed by p t dependence which can lead in some circumstances to the mobilisation of otherwise stagnant regions within the cell the properties of non newtonian flow can be closely imitated by a newtonian fluid with a reduced value of the activation enthalpy bh with b 0 3 0 5 it appears possible that non newtonian rheology plays a key role in determining the convective style in a planetary mantle

shear heating induced lithospheric scale localization does it result in subduction abstract even though it is a well established fact that the earth is currently in a plate tectonics mode the question on how to break lithospheric plates and initiate subduction remains a matter of debate here we focus on shear heating as a potential mechanism to cause lithospheric shear localization and subsequent subduction initiation in oceanic plates it is shown that shear heating under some conditions i facilitates the formation of a lithospheric scale shear zone and ii is capable of stabilizing a lithospheric scale shear zone thus creating the necessary condition for subduction initiation to occur furthermore we demonstrate that not only the localization process is of importance but also the post localization stage where rapidly growing convective instabilities might prevent an incipient subduction zone from developing we develop scaling laws for both the localization and the post localization stages in the case of lithospheric localization the characteristic length scale equals a quarter of the dominant folding wavelength in the lithosphere thus of the order of the competent layer thickness this shows that oceanic lithosphere develops an intrinsic perturbation length scale that is largely independent of smaller scale heterogeneities we compare the subduction initiation potential of wet olivine and dry olivine rheologies and find that for earth like conditions a dry olivine rheology is more likely to result in subduction initiation a large plate age does not always increase the potential for subduction initiation as it increases the potential for convective instabilities to occur instead an optimal plate age exists for shear heating induced subduction initiation which is around 40 ma for a wet olivine rheology

contrasting microbial community changes during mass extinctions at the middle late permian and permian triassic boundaries abstract microbial communities are known to expand as a result of environmental deterioration during mass extinctions but differences in microbial community changes between extinction events and their underlying causes have received little study to date here we present a systematic investigation of microbial lipid biomarkers spanning 20 myr middle permian to early triassic at shangsi south china to contrast microbial changes associated with the guadalupian lopingian boundary glb and permian triassic boundary ptb mass extinctions high resolution analysis of the ptb crisis interval reveals a distinct succession of microbial communities based on secular variation in moretanes 2 methylhopanes aryl isoprenoids steranes n alkyl cyclohexanes and other biomarkers the first episode of the ptb mass extinction me1 was associated with increases in red algae and nitrogen fixing bacteria along with evidence for enhanced wildfires and elevated soil erosion whereas the second episode was associated with expansions of green sulfur bacteria nitrogen fixing bacteria and acritarchs coinciding with climatic hyperwarming ocean stratification and seawater acidification this pattern of microbial community change suggests that marine environmental deterioration was greater during the second extinction episode me2 the glb shows more limited changes in microbial community composition and more limited environmental deterioration than the ptb consistent with differences in species level extinction rates 71 vs 90 respectively microbial biomarker records have the potential to refine our understanding of the nature of these crises and to provide insights concerning possible outcomes of present day anthropogenic stresses on earth s ecosystems

viscous heating allows thrusting to overcome crustal scale buckling numerical investigation with application to the himalayan syntaxes article i nfo the eastern and western himalayan syntaxes are crustal scale antiforms whose metamorphic evolution is coeval in the india asia collisional history finite element modelling of lithospheric shortening and the resultingcrustal scale folds havepreviously been used todebate the structuralconditions for the development of such structures however numerical models could not account for the metamorphic evolution associated with folding in continuation of previous work we present two dimensional finite element modelling of lithospheric shortening inwhich thermal effects are implemented the new models are consistent with earlier interpretations that crustal folding is the plausible mechanism that shaped the two himalayan syntaxes they further lend support to the concept that lithospheric buckling is a basic response to large scale continental shorteningandan efficientmountainbuilding process introducingviscous shearheating shows however that the buckling mode shifts to a thrusting mode within few shortening depending on the initial thermal rheological structure of the deforming lithosphere the change to the thrusting mode prohibits further fold amplification and lateral fold propagation this mayexplainwhy in continental lithosphere crustal scale folds are isolated whereas regular periodic crustal fold trains are rare focusing deformation on through limbs thrust zones accompanies the establishment of inverted metamorphic gradients these results offer new working hypotheseson howlargethrusts like thehimalayamain centralthrustnucleate results further show that the thermal structure of the lithosphere strongly controls three fundamental deformation and metamorphic modes 1 a cold lithosphere mainly deforms by thermally activated thrusting and exhibits large areas with significant tectonic overpressures twice lithostatic 2 a warm lithosphere is essentially buckled and significant tectonic overpressure builds up in the upper crust and 3 a hot lithosphere tends to thicken homogenously and mainly records lithostatic pressures below the upper crust

chemostratigraphy of the neoproterozoic mirassol d oeste cap dolostones mato grosso brazil an alternative model for marinoan cap dolostone formation abstract we have conducted a detailed study of the neoproterozoic mirassol d oeste cap dolostones that overlay the glacial diamictites of the puga formation 635 ma amazon craton brazil in order to understand the formation of these post glacial dolostones petrographic features indicate that the dolostones are primary to early diagenetic in origin and precipitated in a moderately shallow water platform corresponding to a carbonate ramp during transgressive conditions major and trace element contents as well as c and o isotopic signatures are consistent with an anoxic sediment influenced by sulphate reducing bacteria such an environment is known to provide favourable conditions for the precipitation of dolomite as observed nowadays in modern hypersaline lagoons isotopic compositions of tube like structures suggest local upward fluid seepage from the underlying cap dolostone our data concur with geochemical data from other neoproterozoic cap dolostones to support a microbially mediated model in specific environmental conditions for the formation of these unusual deposits worldwide

simulating the thermochemical magmatic and tectonic evolution of venus s mantle and lithosphere two dimensional models 1 numerical convection models of the thermochemical evolution of venus are compared to present day topography and geoid and recent resurfacing history the models include melting magmatism decaying heat producing elements core cooling realistic temperature dependent viscosity and either stagnant lid or episodic lithospheric overturn in stagnant lid convection the dominant mode of heat loss is magmatic heat pipe which requires massive magmatism and produces very thick crust inconsistent with observations partitioning of heat producing elements into the crust helps but does not help enough episodic lid overturn interspersed by periods of quiescence effectively loses venus s heat while giving lower rates of volcanism and a thinner crust calculations predict 5 8 overturn events over venus s history each lasting 150 myr initiating in one place and then spreading globally during quiescent periods convection keeps the lithosphere thin magmatism keeps the mantle temperature constant over venus s history crustal recycling occurs by entrainment in stagnant lid convection and by lid overturn in episodic mode venus like amplitudes of topography and geoid can be produced in either stagnant or episodic modes with a viscosity profile that is earth like but shifted to higher values the basalt density inversion below the olivine perovskite transition causes compositional stratification around 730 km breakdown of this layering increases episodicity but far less than episodic lid overturn the classical stagnant lid mode with interior temperature rheological temperature scale lower than tcmb is not reached because mantle temperature is controlled by magmatism while the core cools slowly from a superheated start core heat flow decreases with time possibly shutting off the dynamo particularly in episodic cases

the viscosity of earth s lower mantle inferred from sinking speed of subducted lithosphere abstract the viscosity of the mantle is indispensable for predicting earth s mechanical behavior at scales ranging from deep mantle material flow to local stress accumulation in earthquakes zones but mantle viscosity is not well determined for the lower mantle particularly only few constraints result from elaborate high pressure experiments karato 2008 and a variety of viscosity depth profiles result from joint inversion of the geoid and postglacial rebound data forte and mitrovica 1996 kaufmann and lambeck 2000 mitrovica and forte 2004 here we use inferred lower mantle sinking speed of lithosphere subduction remnants as a unique internal constraint on modeling the viscosity profile this entails a series of elaborate dynamic subduction calculations spanning a range of viscosity profiles from which we select profiles that predict the inferred sinking speed of 12 3 mm yr van der meer et al 2010 our modeling shows that sinking speed is very sensitive to lower mantle viscosity good predictions of sinking speed are obtained for nearly constant lower mantle viscosity of about 3 4 1022 pa s viscosity profiles incorporating a viscosity maximum in the deep lower mantle as proposed in numerous studies only lead to a good prediction in combination with a weak postperovskite layer at the bottom of the lower mantle and only for a depth average viscosity of 5 1022 pa s

saturated hydrocarbon biomarkers in oils of late precambrian age from eastern siberia abstract large quantities of petroleum derived from source rocks of late precambrian early cambrian age have been discovered in the lena tunguska region of eastern siberia over the last twenty five years we have examined three oils with presumed late precambrian vendian source rocks from this region for c 15 saturated hydrocarbon biomarkers using gas chromatography gc and gas chromatography mass spectrometry gc ms our results show these oils to have many characteristics in common with other oils of similar age from eastern siberia and oman amongst the compounds detected in the three oils analyzed were 1 n alkanes which show a marine derived distribution 2 centrally branched monomethyl alkanes 3 acyclic isoprenoids pr ph 1 4 tricyclic and tetracyclic terpanes 5 hopanes 6 c 29 unrearranged steranes and 7 c 30 nuclear steranes all of these compounds with the exception of the 4 methylsteranes which on current biochemical knowledge are unexpected in oils of this age can be assigned a prokaryotic source this and other evidence such as the lack of diasteranes suggest microorganism were the major contributors to organic matter deposited as part of a carbonate source rock

hysteresis in mantle convection plate tectonics systems 1 we use simulations of mantle convection with surface yielding to show that multiple tectonic regimes are possible for equivalent system parameter values models with the same lithospheric strength parameters and the same vigor of convection can display different modes of tectonics within the region of multiple solutions the evolutionary pathway of the system is the dominant factor that determines the tectonic mode e g whether mantle convection operates in a plate tectonic like mode the extent of the multiple regimes window is found to increase with the temperature dependent viscosity contrast across the system the implication for models that seek to predict the tectonic regimes of planets is that the temporal evolution of the planet needs to be taken into account a further implication is that modeling studies can lead to different conclusions regarding the tectonic state of a planet extra solar planets in particular despite the final model parameter values remaining equivalent

self consistent generation of tectonic plates in time dependent three dimensional mantle convection simulations 1 presented here are self consistent three dimensional simulations of mantle convection some of which display an approximation of plate tectonic behavior that is continuous in space and time plate behavior arises through a reasonable material description of silicate deformation with a simple yield stress being sufficient to give first order plate like behavior however the required yield strength or fault frictional coefficient is much less than experimentally determined values toroidal poloidal ratios are within geologically observed limits the sensitivity of the system to yield strength and the form of strength envelope is systematically investigated optimum plate character is obtained in a narrow range of yield strength below which diffuse boundaries and above which episodic behavior and eventually a rigid lid are observed models with mobile lids develop very long wavelength horizontal structure the longest wavelength possible in the domain two dimensional models display much greater time dependence than three dimensional models

tracking the onset of phanerozoic style redox sensitive trace metal enrichments new results from basal ediacaran post glacial strata in nw canada abstract a global rise in oxygen levels has been proposed to coincide with the ediacaran to cambrian radiation of animals yet the precise timing and nature of this change remains unresolved one hypothesis is that the ocean atmosphere system became temporarily well oxygenated in the earliest ediacaran directly following the marinoan snowball earth glaciation 635 ma the evidence for oxygenation is based on large enrichments of redox sensitive trace elements in black shale from south china presumably deposited under a euxinic water column these enrichments meet or exceed the bulk concentrations of redox sensitive trace elements found in phanerozoic shale deposited under euxinic water columns here we test the early ediacaran post snowball oxygenation hypothesis with new data from a high resolution multi proxy geochemical and sedimentological study of three stratigraphic sections in the earliest ediacaran sheepbed formation of the mackenzie and wernecke mountains nw canada iron speciation data from all sections suggest that the local water column was dominantly ferruginous with a notable exception of probable euxinic conditions recorded in part of one section redox sensitive elements show no appreciable enrichments in the basal sheepbed formation with maximum concentrations of molybdenum vanadium uranium and chromium only slightly above world average shale values the lack of substantial elemental enrichments within the sheepbed formation is consistent with results from coeval ferruginous strata in svalbard the dominance of local ferruginous conditions in nw canada cannot alone account for the muted redox sensitive element enrichments as v u and cr are thought to be enriched under these conditions and samples deposited under euxinic conditions also lack phanerozoic style enrichments these contrasting results from different localities highlight a need to further investigate the veracity of trace metal enrichments in all localities as representing global redox conditions as the results have important implications for the timing of oxygenation with respect to early animal evolution

scaling of stagnant lid convection with arrhenius rheology and the effects of mantle melting summary on the basis of numerical modelling and scaling analysis a few modifications are proposed for the scaling of stagnant lid convection in order to make it more applicable to the thermal evolution of terrestrial planets the effect of using arrhenius rheology as opposed to more popular linear exponential rheology is first investigated and the stability analysis of top thermal boundary layer is shown to be able to capture systematic differences caused by the different kinds of temperature dependent viscosity the local stability analysis is then extended to handle the effects of mantle melting such as dehydration stiffening and compositional buoyancy a new heat flow scaling law incorporating these effects suggests that mantle melting may reduce the conventional prediction of surface heat flux by up to a factor of 5 10 and its potential impact on our understanding of planetary evolution is briefly discussed

tracing of variabilities within a geological barrier by molecular organic geochemistry case of the callovo oxfordian sedimentary series in the east of the paris basin france abstract the callovo oxfordian claystones located at 500 m depth at bure meuse france are currently being investigated by andra the french national radioactive waste management agency for testing the feasibility of long term and deep geological nuclear waste disposal in order to evaluate its potential as a geological barrier it is very important to study assess and describe its physico chemical variability the molecular biomarker composition of 150 samples of these claystones and their surrounding limestones carry diverse information on the sources of the sedimentary organic matter the chemistry of the depositional environment the preservation and diagenesis conditions it also allows assessing the degree of lateral and vertical variability of the organic matter within these sedimentary series the abundance of unsaturated biomarkers the distribution of steroids and hopanoids and cpi values 2 prove the thermal immaturity of the organic matter the co occurrence of plankton bacteria and land plant biomarkers indicate that the organic matter is a mixture of marine and continental contributions the data also reveal that the organic matter was deposited under oxic and open sea conditions except for a brief event of photic zone anoxia at the beginning of the middle callovian in the claystones the geosynthesis of diasterenes is favored to the detriment of the formation of steranes especially in smectite rich levels and the organic matter is rapidly isolated from oxidizing then reducing conditions after the deposition due to the protective effect of clays on the scale investigated the claystones are characterized by a unique molecular facies and are thus homogenous from their organic content point of view yet detailed investigation of specific molecular families indicates changes related to major claystone limestone transitions the homogeneity of these claystones can be explained by the paleogeographic position of their depositional setting and the plane and sub horizontal paleotopography on which they were deposited this study demonstrates the efficiency of organic geochemistry in the assessment of the variability of geological barriers

a source sink model of the generation of plate tectonics from non newtonian mantle flow a model of mantle convection which generates plate tectonics requires strain rate or stress dependent rheology in order to produce strong platelike flows with weak margins as well as strike slip deformation and plate spin i e toroidal motion here we employ a simple model of source sink driven surface flow to determine the form of such a rheology that is appropriate for earth s present day plate motions in this model lithospheric motion is treated as shallow layer flow driven by sources and sinks which correspond to spreading centers and subduction zones respectively the source sink field is derived from the horizontal divergence of plate velocities and thus directly prescribes poloidal motion the toroidal flow field is solved through the non newtonian stokes equation for shallow layer tangential flow on the surface of a sphere two plate motion models are used to derive the source sink field the first is an idealized square plate which is used to explore the basic aspects of the model the second is an analytically continuous model of earth s present day plates bercovici and wessel 1994 as originally implied in the simpler cartesian version of this model bercovici 1993 the classical power law rheologies do not generate platelike flows as well as the hypothetical whitehead gans stick slip rheology which incorporates a simple self lubrication mechanism for the idealized plate geometry the power law rheologies yield much more diffuse strike slip shear i e radial vorticity than the stick slip rheology for the present day plate geometry the power law rheologies fail to reproduce the original proportion of left and right lateral strike slip shear whereas the stick slip rheology gives almost exactly the right proportion none of the fluid rheologies examined however produce more than approximately 60 of the original maximum shear for either plate model the viscosity fields produced by the power law rheologies are diffuse and the viscosity lows over strike slip shear zones or pseudo margins are not as small as over the prescribed convergent divergent margins in contrast the stick slip rheology generates very platelike viscosity fields with sharp gradients at the plate boundaries and margins with almost uniformly low viscosity quantitative comparisons with the toroidal poloidal kinetic energy partitioning and vorticity fields of the original plate model are also examined and the stick slip rheology is generally found to yield the most favorable comparisons power law rheologies with high viscosity contrasts however lead to almost equally favorable comparisons though these also yield the least platelike viscosity fields this implies that the magnitude of toroidal flow and platelike strength distributions are not necessarily related arid thus may present independent constraints on the determination of a self consistent plate mantle rheology the results of this study however predict that if such a rheology can indeed be uniquely determined it is likely to be in the class of stick slip self lubricating rheologies

the effect of rheological parameters on plate behaviour in a self consistent model of mantle convection abstract in a three dimensional numerical model of mantle convection we have explored the self consistent formation and evolution of plates this was done by investigating the influence of temperature stress and pressure dependence of the viscosity on plate like behaviour further the role of a depth dependent thermal expansivity and of internal heating was examined first order self consistent plate tectonics can be obtained for temperature and stress dependent viscosity we observe virtually undeformed moving plates and the phenomenon of trench migration however plate motion only appears during short intervals which are interrupted by long phases characterised by an immobile lid an improvement is achieved by adding pressure dependence of the viscosity and of the thermal expansivity to the model this leads to extended plates with continuous plate motion and the appearance of a low viscosity zone internal heating accelerates subduction and gives an increase in plate velocity the plates are otherwise left intact we find that the surface velocity is largely determined by subduction rather than by upwellings plate like behaviour is restricted to a narrow parameter window the window is bordered by an episodic or a stagnant lid type of flow on the one side and by a domain in which convection is akin to constant viscosity flow on the other side with these different convective regimes the behaviour of various terrestrial planets can be described self consistently occasionally even a change from the plate regime to the stagnant lid regime occurs such a type of transition has possibly changed the style of tectonics on some terrestrial planets such as mars

the pressure weakening effect in super earths consequences of a decrease in lower mantle viscosity on surface dynamics 1 the quest to identify habitable planets has raised interest in the surface dynamics of terrestrial bodies in this context super earths a new class of exoplanets have become of special interest in the past decade scalings to super earth sizes when compared to the earth suggest changes to convective stresses and mantle temperatures which can cause either an increase in surface mobility or in plate resistance mantle viscosity which depends on temperature stress and pressure plays a critical role in both cases new mineralogical assumptions suggest that the viscosity in super earths acts differently than in the earth and what had been assumed for super earths in planets larger than the earth pressure will become so high that pressure weakening and a decrease of viscosity in the lowermost mantle results we present a numerical convection study featuring this viscosity decrease and find that this leads to a reduction in surface mobility

a mechanism for episodic subduction on venus we propose a mechanism previously developed as a hypothetical cause of the initiation of subduction in the earth s mantle to describe a situation where such subduction may occur transiently at irregular intervals of time it has been suggested that tectonics on venus may be described by such a scenario in our model a subduction event is followed by resumption of high rayleigh number mantle convection below a stagnant lithosphere which thickens due to conductive cooling as it thickens differential buoyancy causes large lithospheric stresses which eventually lead to plastic failure in the upper portions of the lithosphere this plastic zone thickens faster than the lithosphere so that at some critical time it reaches the base of the lithosphere at this point the effective lithosphere viscosity decreases to that of the underlying mantle and subduction can occur we suggest that this is mechanistically consistent with the postulated venusian tectonic style

plate like regime of a numerically modeled thermal convection in a fluid with temperature pressure and stress history dependent viscosity 1 a series of numerical models are presented for two dimensional thermal convection in a fluid with viscosity that nonlinearly depends on degree of damage as well as temperature and pressure increases and viscosity decreases with time when the convection induces strong viscous dissipation the convecting fluid recovers from the damage with a characteristic time that depends on temperature the dependence of viscosity induces a stress viscosity relationship that consists of two branches the intact branch at low stress and the damaged branch at high stress with a hysteresis between the two branches is small large and viscosity is high low on the intact damaged branch the hysteresis lets the viscosity depend on stress history the dependence of viscosity on stress history due to the hysteresis induces a regime where the numerically modeled lithosphere along the surface boundary is fragmented into smaller pieces that are on the intact branch and rigidly move the pieces of lithosphere are separated by narrow mechanically weak zones that are on the damaged branch each piece of lithosphere is further fragmented and mechanically weak zones are newly formed only when the piece is tapped by particularly strong hot uprising plumes this plate like regime is the only regime among the convective regimes searched here where each piece of lithosphere rigidly moves and still is not ruptured by the forces that drive the piece the earth s mantle is suggested to be on the plate like regime

identification of aryl isoprenoids in source rocks and crude oils biological markers for the green sulphur bacteria abstract a series of c13 to c31 aryl isoprenoids 1 alkyl 2 3 6 trimethylbenzenes have been identified in reef hosted oils and their source rocks from the middle and upper silurian of the michigan basin and middle devonian of the alberta basin canada their structure has been confirmed by unambiguous synthesis of the c14 member of the series their structure and isotopic composition indicate that they are derived from isorenieratene from the chlorobiaceae family of sulphur bacteria these results are consistent with geological and geochemical studies that show that the source rocks were deposited under metahaline to hypersaline sulphate and sulphide rich water columns the distribution of other biomarkers in these oils and source rocks indicates that a diverse biota contributed organic matter to the source environment in conjunction with the aryl isoprenoids they show that there is a remarkable similarity in composition between the two sets of oils and source rocks despite their great temporal and geographic separation this reflects the similarity of their environments and emphasizes the importance of sedimentary facies in controlling the composition of organic matter in source rocks and their derived oils

hydrocarbon biomarkers thermal maturity and depositional setting of tasmanite oil shales from tasmania australia this study represents the first geological and organic geochemical investigation of samples of tasmanite oil shale representing different thermal maturities from three separate locations in tasmania australia the most abundant aliphatic hydrocarbon in the immature oil shale from latrobe is a c19 tricyclic alkane whereas in the more mature samples from oonah and douglas river low molecular weight n alkanes dominate the extractable hydrocarbon distribution the aromatic hydrocarbons are predominantly derivatives of tricyclic compounds with 1 2 8 trimethylphenanthrene increasing in relative abundance with increasing maturity geological and geochemical evidence suggests that the sediments were deposited in a marine environment of high latitude with associated cold waters and seasonal seaice it is proposed that the organism contributing the bulk of the kerogen tasmanites occupied an environmental niche similar to that of modern sea ice diatoms and that bloom conditions coupled with physical isolation from atmospheric co2 led to the distinctive isotopically heavy 13c values 13 5 to 11 7 for the kerogen 13c data from modern sea ice diatoms 7 supports this hypothesis isotopic analysis of n alkanes in the bitumen 13 5 to 31 suggest a multiple source from bacteria and algae on the other hand the n alkanes generated from closed system pyrolysis of the kerogen 15 are mainly derived from the preserved tasmanites biopolymer algaenan the tricyclic compounds mean 8 both in the bitumen and pyrolysate have a common precursor they are consistently enriched in 13c compared with the kerogen and probably have a different source from the n alkanes the identification of a location where the maturity of the tasmanite oil shale approaches the oil window raises the possibility that it may be a viable petroleum source rock

the ratios of dibenzothiophene to phenanthrene and pristane to phytane as indicators of depositional environment and lithology of petroleum source rocks abstract the ratio of dibenzothiophene to phenanthrene and the ratio of pristane to phytane when coupled together provide a novel and convenient way to infer crude oil source rock depositional environments and lithologies such knowledge can significantly assist in identifying the source formation s in a basin thereby providing valuable guidance for further exploration the ability to infer this information from analysis of a crude oil is especially valuable as frequently the earliest samples in a new area may be shows and or drill stem test samples from exploratory wells which are characteristically drilled on structural highs stratigraphically remote from the source formation s a cross plot of dibenzothiophene phenanthrene versus the pristane phytane ratios measured on seventy five crude oils from forty one known source rocks ranging in age from ordovician to miocene consistently classified the oils into the following environment lithology groups marine carbonate marine carbonate mixed and lacustrine sulfate rich lacustrine sulfate poor marine and lacustrine shale and fluvial deltaic carbonaceous shale and coal the dibenzothiophene phenanthrene ratio alone is an excellent indicator of source rock lithology with carbonates having ratios 1 and shales having ratios the dibenzothiophene to phenanthrene and the pristane to phytane ratios can also be used to classify source rock paleodepositional environments the classification scheme is based on the premise that these ratios reflect the different eh ph regimes resulting from the significant microbiological and chemical processes occurring during deposition and early diagenesis of sediments the dibenzothiophene phenanthrene ratio assesses the availability of reduced sulfur for incorporation into organic matter and the pristane phytane ratio assesses the redox conditions within the depositional environment interpretation of these ratios has been aided by quantitative biomarker analysis and by carbon isotope data for pristane and phytane obtained by gas chromatography isotope ratio mass spectrometry

a carbon isotope challenge to the snowball earth the snowball earth hypothesis contends that most of the planet was covered with thick ice for millions of years about three quarters of a billion years ago a dramatic warming event thought to have been fuelled by high atmospheric carbon dioxide levels eventually defrosted earth a new isotopic analysis of rocks that were laid down after the initial glaciation challenges the idea of a hard snowball earth the data are consistent with a rather low partial pressure of atmospheric co2 not the orders of magnitude above current levels that would provide the extreme warming necessary for escape from snowball earth this supports the idea that the initial glaciation was much less severe than has been proposed the snowball earth hypothesis postulates that the planet was entirely covered by ice for millions of years in the neoproterozoic era in a self enhanced glaciation caused by the high albedo of the ice covered planet in a hard snowball picture the subsequent rapid unfreezing resulted from an ultra greenhouse event attributed to the buildup of volcanic carbon dioxide co2 during glaciation1 high partial pressures of atmospheric co2 from 20 000 to 90 000 p p m v in the aftermath of the marinoan glaciation 635 myr ago have been inferred from both boron and triple oxygen isotopes2 3 these values are 50 to 225 times higher than present day levels here we re evaluate these estimates using paired carbon isotopic data for carbonate layers that cap neoproterozoic glacial deposits and are considered to record post glacial sea level rise1 the new data reported here for brazilian cap carbonates together with previous ones for time equivalent units4 5 6 7 8 provide estimates lower than 3 200 p p m v and possibly as low as the current value of 400 p p m v our new constraint and our re interpretation of the boron and triple oxygen isotope data provide a completely different picture of the late neoproterozoic environment with low atmospheric concentrations of carbon dioxide and oxygen that are inconsistent with a hard snowball earth

a red algal bloom in the aftermath of the marinoan snowball earth organic matter from the cap dolostones overlying the marinoan age glacigenic diamictites of the araras group amazon craton has been studied to reconstruct the post glacial ecosystem molecular fossils indicate that the post marinoan ecosystem was marked by an apparent decline in marine algal diversity the proliferation of red algae may be explained by environmental changes such as a massive nutrient input accompanying continental weathering after the ice thaw and a dimer light penetrating sea water due to the drowning of the platform in addition the presence of green sulphur bacteria indicates that sea water was stratified with an anoxic possibly euxinic i e sulphidic layer at the water sediment interface sulphur cycling probably occurred at the redox boundary as suggested by the recognition of active sulphate reduction this observation supports a microbially induced model for the formation of the cap dolostones

a conceptual model for the relationship between coronae and large scale mantle dynamics on venus 1 among the most enigmatic features on venus are the more than 500 quasi circular structures collectively referred to as coronae associated volcanism and tectonism suggest that coronae result from small transient mantle plumes although only about 20 have clearly associated positive gravity anomalies indicative of current activity coronae are concentrated within a region defined by the dynamically active highland areas of beta atla and themis regiones bat coronae avoid the lowest or highest topography and geoid subsets of the corona population indicate that the spatial distribution of coronae has evolved from a previously less concentrated global distribution to the current bat concentration recent laboratory experiments on thermal convection at high rayleigh number using fluids with temperature dependent viscosity suggest a straightforward interpretation of these relationships small scale upwellings from a hot lower thermal boundary layer tend to be excluded by longer wavelength downwelling structures from the cold upper boundary layer the relative paucity of coronae in the broad lowland plains regions is consistent with the inference of mantle downwellings beneath the plains coronae are largely excluded from compensated highlands perhaps because the thickened crust is not easily disrupted in these regions laboratory experiments indicate that small transient boundary layer instabilities can coexist with and be focused toward large scale upwellings possibly explaining the spatial concentration of coronae in the bat region thus coronae provide important insights into interacting scales of convective flow in venus s mantle and into the evolution of venus s mantle dynamics direct tests of our model are possible through geological mapping

soft sediment deformation at the base of the neoproterozoic puga cap carbonate southwestern amazon craton brazil confirmation of rapid icehouse to greenhouse transition in snowball earth stratigraphic and isotopic data identify the lower 45 m of the araras group on the southwest margin of the amazon craton as a neoproterozoic platform cap carbonate deposited below wave base upon varanger glacial diamictites of the puga formation the basal beds consist of moderately deep water pinkish dolomudstone with stratiform to wavy fenestral microbialites locally cut by tube like structures and fenestral nonmicrobial planar laminites with tepee like features above the basal carbonates are deep water bituminous lime mudstones with alternating thin calcite crusts and lime mudstone laminae commonly disrupted by calcite crystal fans pseudomorphs after aragonite the basal contact of the puga cap exhibits soft sediment deformational structures principally load casts that are here attributed to rebound induced seismicity acting upon both recently deposited carbonate sediments and underlying unconsolidated diamictite these features constitute the first clearly recognized sedimentological evidence for the rapid change from icehouse to greenhouse conditions as postulated in the snowball earth model of neoproterozoic glaciation

raman spectroscopy and biomarker analysis reveal multiple carbon inputs to a precambrian glacial sediment extractable biomarkers can help elucidate the environment and biota of ancient glaciations although the method must be applied with care as glacial sediments have a potential for incorporation of older detrital carbon in phanerozoic glacial sediments the distinct elemental molecular and isotopic compositions of the terrestrial and marine biomass allow discrimination between primary marine and redeposited terrestrial organic matter however as the proterozoic biosphere was largely microbial and marine biomarker and isotopic analyses are insufficient for distinguishing primary organic matter from secondary reworked organic matter here we report the combined application of raman spectroscopy and biomarker analysis to precambrian glacial sediments which together allows discrimination between mixed pools of organic carbon and provides a promising new approach for rapidly screening precambrian sediments for immature organic matter amenable to biomarker analysis

boron and calcium isotope composition in neoproterozoic carbonate rocks from namibia evidence for extreme environmental change the level and evolution of atmospheric carbon dioxide throughout earth s history are key issues for palaeoclimate reconstructions especially during times of extreme climate change such as those that marked the neoproterozoic the carbon isotope ratios of marine carbonates are crucial in the correlation and identification of neoproterozoic glacial deposits and they are also used as a record for biogeochemical cycling and potential proxy for atmospheric pco2 likewise the boron and calcium isotope compositions of marine carbonates are potential proxies for palaeo seawater ph and the ratio of calcium fluxes into and out of seawater respectively and together they may be used to estimate atmospheric carbon dioxide here we use b and ca isotopes to estimate palaeoenvironmental conditions in the aftermath of a major neoproterozoic glaciation in namibia the validity of the b and ca isotope variation in the ancient marine carbonates is evaluated using the oxygen isotope composition of the carbonates and its correlation to the carbon isotope variation a negative 2 7 to 6 2 11b excursion occurs in the postglacial carbonates and is interpreted to reflect a temporary decrease in seawater ph associated variations in 44ca values ranging between 0 35 and 1 14 are linearly coupled with the carbon isotope ratios and imply enhanced postglacial weathering rates the reconstructed seawater ph and weathering profiles indicates that high atmospheric co2 concentrations were likely during the melt back of neoproterozoic glaciations and precipitation of cap carbonates however the b isotope trend suggests that these concentrations rapidly ameliorated and they do not co vary with 13c thus models attempting to link long lived negative 13c excursions to elevated pco2 need to be reconsidered

photic zone euxinia during the permian triassic superanoxic event carbon and sulfur isotopic data together with biomarker and iron speciation analyses of the hovea 3 core that was drilled in the perth basin western australia indicate that euxinic conditions prevailed in the paleowater column during the permian triassic superanoxic event biomarkers diagnostic for anoxygenic photosynthesis by chlorobiaceae are particularly abundant at the boundary and into the early triassic similar conditions prevailed in the contemporaneous seas off south china our evidence for widespread photiczone euxinic conditions suggests that sulfide toxicity was a driver of the extinction and a factor in the protracted recovery

the occurence of unusual c27 and c29 sterane predominances in two types of oman crude oil abstract two types of oman crude oils reveal unusual sterane distributions type a which is the more common 74 examples is characterised by a predominance of c 29 iso and normal steranes and generally none or only very low relative concentrations of rearranged steranes the triterpanes are characterised by the predominance of the c 29 17 h 21 h norhopane over the c 30 17 h 21 h hopane and non predominant c 20 c 30 tricyclic terpanes the c 29 steranes of this type of crude were not derived from the c 29 sterols of land plant origin frequently proposed as the source of c 29 steranes since there is good geological evidence that these crudes were generated from a pre cambrian source rock a geological period when land plants did not exist the type b crude oil 11 known examples is characterised by a strong predominance of c 27 iso normal and rearranged steranes relatively lower concentrations of 17 h 21 h hopanes and relatively high concentrations of c 20 c 30 tricyclic terpanes the remarkably different biomarker characteristics of these crude oils imply that the organisms active in the depositional environment of the respective source rocks were significantly different

self consistent generation of tectonic plates in time dependent three dimensional mantle convection simulations 2 strain weakening and asthenosphere 1 in a previous paper tackley 2000b it was shown that a combination of temperature dependent viscosity and viscoplastic yielding is sufficient to give rudimentary plate tectonic like behavior in three dimensional models of mantle convection here the calculations are extended to include two complexities that have been suggested as being important in localizing deformation at plate boundaries strain weakening and the presence of a low viscosity asthenosphere introducing an asthenosphere by reducing the viscosity by a factor of 10 where material reaches a solidus 1 dramatically improves plate quality even if the asthenosphere is restricted to regions around spreading centers 2 gives good smoothly evolving platelike behavior over a wide range of yield stress values spanning an order of magnitude and 3 gives bimodal stable solutions over a range of yield stresses either immobile lid or plate behavior may be obtained depending on initial condition by contrast introducing an asthenosphere by using depth dependent viscosity has a much smaller effect on system behavior increasing strain weakening 1 improves localization at spreading centers but leads to an increasingly complex network of spreading centers fragmenting the plates 2 weakens convergent zones and can make downwellings highly episodic and 3 does not lead to pure transform boundaries in these calculations time dependent damage evolution and instantaneous strain rate weakening give very similar results all cases that display platelike behavior have very long wavelength mantle heterogeneity consistent with earth s

effects of strongly temperature dependent viscosity on time dependent three dimensional models of mantle convection numerical simulations of thermal convection in a wide 8 8 1 cartesian box heated from below with temperature dependent viscosity contrasts of 1000 and rayleigh number 105 show that boundary conditions and aspect ratio have an enormous effect on the preferred flow pattern with rigid upper and lower boundaries spoke pattern flow with small diameter 1 5 cells is obtained consistent with laboratory experiments and previous numerical results however with the arguably more realistic stress free boundaries the flow chooses the largest possible wavelength forming a single square cell of aspect ratio 8 with one huge cylindrical downwelling surrounded by upwelling sheets the addition of stress dependence to the rheology weakens the stiff upper boundary layer resulting in smaller cells though still with upwelling sheets and downwelling plumes