structural mineralogical and petrophysical effects on deep crustal rocks of fluid limited polymetamorphism western gneiss region norway the proterozoic banded granulite facies complex of bardsholmen western gneiss region norway t 815 845 c was locally transformed to eclogite t 455 510 c p 12 kbar and amphibolite facies rocks t 460 c during the caledonian continental collision the granulite complex consists of mafic two pyroxene granulite and leucocratic orthopyroxene garnet bearing layers alternating on a scale from 1 cm to 10 m the granulite facies rocks change to eclogite facies rocks over centimetre scale distances along well defined fluid infiltration fronts the mafic granulite was transformed to omphacite garnet rich eclogites and the leucocratic rocks were converted to quartz phengite rich assemblages with minor garnet and local omphacite melange like lithologies consisting of mafic lenses of eclogite surrounded by felsic material represent an advanced stage in the process of converting deep crust to eclogite facies during amphibolitization this melange like lithology evolves to a rock where amphibolite lenses and layers are surrounded by granitoid gneiss a lithology typical of the western gneiss region the bardsholmen locality illustrates the profound control exerted by fluids on the timing of metamorphism the structural make up and petrophysical properties such as density and rheology of crustal root zones fluid induced metamorphism will therefore exert control on the attributes of orogenic belts such as topography and moho depth and influence the dynamics of collision zones by controlling the time of orogenic collapse and the buoyancy of the subducted crust we suggest that orogens may develop differently depending on the fluid budget

active circulation of saline ground waters in carbonate platforms evidence from the great bahama bank measurements of salinity temperature and ground water discharges within the great bahama bank provide evidence of active circulation of near normal ocean water beneath north andros island elevated salinity waters 38 42 derived by density refulx from the great bahama bank flow eastward beneath the island and mix with normal salinity cold ground waters 19 20 c from deeper than 250 m in the adjacent oceans east to west flow of water from the straits of florida may be driven by head differences generated by the florida current which impinges on the western margins of the platform alternatively density differences between the reflux and tongue of the ocean sea waters may cause more local circulation on the eastern flanks these flows have important diagenetic implications particularly in the explanation of pervasive secondary dolomitization widely reported at shallow depths in the bahamas

effluent from diffuse hydrothermal venting 2 measurement of plumes from diffuse hydrothermal vents at the southern juan de fuca ridge an array of temperature and velocity sensors was deployed for two weeks in the bottom boundary layer at the southern juan de fuca ridge during the national oceanic and atmospheric administration vents 90 field experiment the instruments were placed close to the seafloor to detect effluent from diffuse hydrothermal sources located 1 2 km distant over the duration of the field deployment we detected effluent from two vent sources the plume from the larger of the two sources was sensed at all of the instrument locations permitting estimates of dilution based on the field measurements our data also permitted estimation of energy flux from diffuse vents approximately 125 75 mw from a source to the north of the instrument array and 12 8 mw from a small source to the east the largest source of error in the data was estimation of the plume width we have described a sensor array that would reduce this error in future work such an array would be suitable for a long term vent activity monitor

large heat and fluid fluxes driven through mid plate outcrops on ocean crust geophysical data for the cocos plate sea floor suggest that basement outcrops along mid ocean ridge flanks can discharge very large quantities of heat and fluid this is indicative of high crustal permeability at the regional scale

transposed high pressure granulite fabrics cabo ortegal nw spain implications on the scales of deformation localization abstract high pressure granulite facies rocks of the bacariza formation cabo ortegal nw spain were syn metamorphically deformed at the contacts with the bounding units peridotite and eclogite massifs this enabled the formation of meter thick spectacular shear zones with reworked and transposed foliations and lineations the texturally stable mineral assemblage of the new fabrics records an intense ductile deformation of the mineral aggregate at temperatures of 700 800 c associated with amalgamation of eclogite high pressure granulitic rocks and ultramafic sheets in deep portions of a subduction channel the lattice preferred orientation of the main constituent minerals garnet augite amphibole plagioclase quartz and biotite discloses the active deformation mechanisms at the scale of the mineral grains and the relationships with the deformation at larger scales overprinting relationships of the metamorphic assemblages demonstrates that partitioning and deformation localization occurred at different scales under similar high grade conditions complete macroscopic transposition in the shear zones was complementary to meso and microscopic partitioning of deformation intensity and mechanisms between different lithological layers and mineral species

pre caledonian granulite and gabbro enclaves in the western gneiss region norway indications of incomplete transition at high pressure the western gneiss region of norway is a continental terrane that experienced caledonian high pressure and ultrahigh pressure metamorphism most rocks in this terrane show either peak caledonian eclogite facies assemblages or are highly strained and equilibrated under late caledonian amphibolite facies conditions however three kilometre size rock bodies flatraket ulvesund and krakenes in outer nordfjord preserve pre caledonian igneous and granulite facies assemblages and structures where these assemblages are preserved the rocks are consistently unaffected by caledonian deformation the three bodies experienced high pressure conditions 20 23 kbar but show only very localized about 5 eclogitization in felsic and mafic rocks commonly related to shear zones the preservation of pre caledonian felsic and mafic igneous and granulite facies assemblages in these bodies therefore indicates widespread 95 metastability at pressures higher than other metastable domains in norway late caledonian amphibolite facies retrogression was limited the degree of reaction is related to the protolith composition and the interaction of fluid and deformation during the orogenic cycle whereby metastability is associated with a lack of deformation and lack of fluids either as a catalyst or as a component in hydration reactions the three bodies appear to have been far less reactive than the external gneisses in this region even though they followed a similar pressure temperature evolution the extent of metastable behaviour has implications for the protolith of the western gneiss region for the density evolution of high pressure terranes and hence for the geodynamic evolution of mountain belts

uplift of deep crust during orogenic extensional collapse a model based on field studies in the sogn sunnfjord region of western norway the western gneiss region wgr in norway experienced high pressure metamorphism during silurian devonian continent continent collision the eclogite bearing lower crust is separated from the middle and upper crust by major detachment zones formed during extensional collapse of the orogen formation of the devonian basins is related to the extension the footwall of the detachment zones comprises three structural and metamorphic zones the upper zone zone 1 is characterized by penetrative homogeneous down to the west simple shear developed under retrograde greenschist facies metamorphism zone 2 suffered inhomogeneous simple shear of the same polarity petrography and mineral chemistry data from the lower zone zone 3 show a record of initial eclogite facies metamorphism at 600 c and 16 kbar which was decompressed almost isothermally to amphibolite facies conditions at 550 c and 10 12 kbar both the eclogite and amphibolite facies metamorphism developed in a regime of pure shear with vertical shortening the rapid decompression records an approach of approximately 20 km to the surface related to uplift that was probably the result of the removal of a thickened thermal boundary layer in the mantle lithosphere the pure shear regime which developed initially in the lower crust was truncated by zones of simple shear as the lower crust was uplifted to middle and upper crustal levels extension by simple shear in the upper crust was rooted in the lower crust where extension occurred by pure shear the shear zones in zones 1 and 2 did not penetrate the pure shear regime of the lower crust a considerable amount of tectonic stripping of the orogenic welt predates deposition of the devonian sedimentary basins

a gabbro to eclogite transition on flemsoy sunnmore western norway the migmatitic gneisses on the nordoyane islands western norway enclose abundant inclusions of coronitic gabbros and different types of country rock eclogites gabbros on flemsoy show a prograde step wise transition to eclogite via a transitional stage in which garnet and orthopyroxene form coronas between igneous olivine and sodic plagioclase relics after igneous plagioclase cumulates eclogitization proceeds by a complex set of continuous and discontinuous reactions opx and spinel form as transient phases but are consumed in various omphacite forming reactions during eclogite recrystallization relict igneous clinopyroxene shows a continuous increase in jd content while garnet becomes less calcic and more homogeneous from the corona stage to recrystallized eclogite the reactions are strongly diffusion controlled and have been enhanced locally by oxidation and the presence of a fluid phase and deformation while low strain areas of the gabbros remained coronitic whole rock chemistry mineral parageneses and calculated p t conditions are similar for the gabbroeclogites and two types of country rock eclogites some of the layered country rock eclogites appear to have been derived from the coronite bodies p estimates are in the order 15 20 kbar while kgarcpxd values suggest maximum t values of 750 60 c for the eclogite metamorphism in the area

temporal and spatial variability of hydrothermal manganese and iron at cleft segment juan de fuca ridge a unique data set for hydrothermal mn and fe was collected at cleft segment on the juan de fuca ridge between 1983 and 1991 the data set includes observations of focused and diffuse venting fluids and neutrally buoyant plumes formed by chronic and episodic venting manganese heat and iron heat ratios for plumes from the north end of the cleft segment were combined with independently determined estimates of plume heat flux to yield annually averaged chronic venting fluxes for mn of 0 36 0 17 mol s 1 and for fe of 0 61 0 34 mol s 1 over 6 years of plume measurements at north cleft segment observed episodic hydrothermal discharge accounted for 15 of the total vented mn and 35 of vented fe the chronic fluxes for mn and fe at a second venting center located at the south end of the cleft segment were estimated to be approximately equal to the fluxes at north cleft segment chronic plumes at north cleft segment are mixtures of focused and diffuse discharge that contribute heat mn and fe in variable proportions similar examination of south cleft segment data strongly suggests the presence of an as yet unobserved venting source relatively depleted in mn and fe but contributing substantially to the overall heat temporal and spatial variations in the concentrations of mn and fe and in mn heat and fe heat ratios for focused seafloor vents were difficult to resolve within complex chronic plumes manganese heat and iron heat ratios of megaplumes suggest they may have derived from reservoirs of diffuse fluids while smaller event plumes may have formed by different processes and have properties similar to chronic plumes the accurate assessment of segment scale hydrothermal fluxes of mn and fe requires coordinated measurements of representative seafloor sources and the neutrally buoyant plume that integrates all seafloor discharge

bending anisotropy a mechanical constraint on the orientation of fold axes in an anisotropic medium abstract bending anisotropy is the property of a layer of material whereby it bends more easily in some directions than it does in others in macroscopically homogeneous layers bending anisotropy results from the material itself being rheologically anisotropic in the plane of the layering in this paper we investigate bending anisotropy in materials with orthorhombic symmetry and linear elastic or viscous behaviour although such models are rheologically simple we believe they may provide a first approximation to the behaviour of some tectonites with linear and planar fabrics thus we predict that in rocks with strong linear fabrics folds will form with axes nearly parallel to the linear fabrics for a variety of different stress fields this has important geological consequences

helium radon and manganese at the tag and snakepit hydrothermal vent fields 26 and 23 n mid atlantic ridge abstract 3 he 4 he and 222 rn have been measured in samples of vent fluids from the tag and snakepit hydrothermal vent fields and in samples from the neutrally buoyant plume at tag the hydrothermal end member 3 he 4 he at tag normalised to the ratio in air is r r a 7 5 0 9 222 rn 187 dpm kg 1 and 226 ra 13 5 0 4 dpm kg 1 at snakepit r r a 7 86 1 85 222 rn 82 dpm kg 1 and 226 ra 10 3 0 2 dpm kg 1 helium isotope tracer systematics have been described which allow hydrothermal end member properties to be estimated from plume data or non conservative behaviour in the buoyant plume to be identified comparison of plume mn concentrations and he isotope data shows that mn behaves conservatively in the plume system over the time scale considered in contrast 222 rn is highly non conservative and there is a large 222 rn excess in the neutrally buoyant plume the hydrothermal end member accounts for less than 2 5 of the excess 222 rn enrichment at the top of the buoyant plume attributed to entrainment of 222 rn enriched fluids during buoyant plume rise 222 rn 3 he ages of the tag plume give values of around 1 2 days close to the vent field and up to 10 days in adjacent waters 222 rn mn ages are similar except for a region of anomalous water at the level of neutral buoyancy which is enriched in 222 rn and si but not 3 he and mn and which may be derived from the walls of the axial valley at the depth of the neutrally buoyant plume

cenozoic dolomites of carbonate islands their attributes and origin abstract dolomites found on and below carbonate islands atolls and oceanic platforms provide useful insights into the origin of dolomite insights that may not be attainable from the study of more ancient cratonic dolomites for this reason they have been the subject of study for decades a critical mass of case studies now exist and some significant conclusions can be drawn from the cumulative data in most cases the association with an island is causal and not genetic nevertheless these dolomite occurrences are referred to herein as island dolomites one type of dolomite on carbonate islands is penecontemporaneous dolomite a phase that forms while the host sediment is in its original depositional setting island examples are holocene in age occur in holocene sediments and originate as a direct precipitate from either normal or evaporated seawater these are microcrystalline poorly ordered ca rich 18o enriched and geochemically unstable phases that are susceptible to recrystallization in the setting in which they formed post depositional dolomite is the other type of dolomite associated with carbonate islands this type of dolomite replaces older precursors and forms as cement distinctive characteristics include a dominance of fabric preserving texture pore lining cement rims that may exhibit micron scale banding with low mg calcite and formation in association with precursor dissolution sr isotopic dating indicates that all examples are neogene or quaternary in age those formed during the middle miocene through pliocene are massive laterally continuous and often multigenerational in contrast younger examples tend to be localized partial replacements of a single generation sr isotope ages also suggest global synchroneity in many dolomitization events which suggests a connection between dolomitization global eustacy and or global climatic factors geochemical attributes of post depositional island dolomites are ca enrichment positive 18o and 13c low sr contents 150 300 ppm and low fe global similarity in petrography and geochemistry of replacive island dolomites argues for a similar origin inferred origins however depend primarily on how 18o and sr data are interpreted values for 18o and dsr must be assumed due to uncertainties in oxygen isotope fractionation and sr partitioning there is no consensus or uniformity in those assumptions thus interpretations can vary and be biased to a desired result covariant trends in 13c and 18o some negative 13c values and high sr all favor a mixing zone origin but examples with these attributes are few lack of covariance in the isotopes mean 18o of 2 0 to 3 5 and low sr future studies should standardize the type of data collected and the analytical techniques employed multiple geochemical attributes should be measured on microsampled components and quantitative modeling should be employed in order to constraint interpretations as much as possible also needed are a better understanding of the kinetic processes that form these dolomites more careful assessment of their recrystallization status and an improved understanding of dsr and 18o at low temperature

early carboniferous unroofing in western norway a tale of alkali feldspar thermochronology abstract 40ar 39ar thermochronologic data from an extensional detachment zone in western norway document punctuated late paleozoic through mesozoic tectonothermal activity diffusion and thermal modeling of alkali feldspars sampled in a profile through the detachment replicate laboratory argon release patterns when feldspars comprise three or four diffusion domains with differing activation energies that represent high intermediate and low closure temperatures these domains correspond to distinct changes in late paleozoic cooling rates 1 slow cooling at 0 4 2 2 c m yr from ca 380 360 ma 2 rapid cooling at 15 c m yr in late devonian early carboniferous time 360 340 ma 3 slow cooling at 0 4 1 7 c m yr after ca 340 ma with partial argon loss in permian and late jurassic early cretaceous times the early carboniferous rapid cooling event recorded by the feldspars links the western norway margin to contemporaneous unconformities regional extension basin inversion and igneous activit

introduction to special section on measurements and monitoring at the tag hydrothermal field mid atlantic ridge 26 n 45 w the international oceanographic community carried out a coordinated series of cooperative cruises and dives with japanese russian and u s submersibles between 1993 and 1995 to perform baseline measurements and to establish a seafloor observatory to monitor the active sulfide mound in the tag hydrothermal field before during and after drilling by ocean drilling program leg 158 in october november 1994 the results of that effort and related work are reported herein as group of 23 papers comprising a special section in this issue of geophysical research letters

active and relict sea floor hydrothermal mineralization at the tag hydrothermal field mid atlantic ridge the tag hydrothermal field is a site of major active and inactive volcanic hosted hydrothermal mineralization in the rift valley of the slow spreading mid atlantic ridge at 26 degree n the axial high is the principal locus of present magmatic intrusions the tag field contains three main areas of present and past hydrothermal activity 1 an actively venting high temperature sulfide mound 2 two former high temperature vent areas 3 a zone of low temperature venting and precipitation of fe and mn oxide deposits the volcanic centers occur at the intersections between ridge axis parallel normal faults and projected axis transverse transfer faults the intersections of these active fault systems may act as conduits both for magmatic intrusions from sources beneath the axial high that build the volcanic centers and for hydrothermal upwelling that taps the heat sources radiometric dating of sulfide samples and manganese crusts in the hydrothermal zones and dating of sediments intercalated with pillow lava flows in the volcanic center adjacent to the active sulfide mound indicate multiple episodes of hydrothermal activity throughout the field driven by heat supplied by episodic intrusions over a period of at least 140 times 10 sup 3 yr the sulfide deposits are built by juxtaposition and superposition during relatively long residence times near episodic axial heat sources counterbalanced by mass wasting in the tectonically active rift valley of the slow spreading oceanic ridge hydrothermal reworking of a relict hydrothermal zone by high temperature hydrothermal episodes has recrystallized sulfides and concentrated the first visible primary gold reported in a deposit at an oceanic ridge

subduction and eduction of continental crust major mechanisms during continent continent collision and orogenic extensional collapse a model based on the south norwegian caledonides during continental collision in the middle silurian the thickness of the lithosphere under the caledonides of s norway was doubled by subduction of the western margin of baltica including the western gneiss region under laurentia crustal rocks of the baltic plate reached sub moho depths of near 100 km or more as inferred from the presence of coesite in eclogites isostatic calculations indicate an average elevation of the mountain chain of about 3 km at this stage the subducted lithosphere experienced vertical constrictional strains as a result of slab pull by its heavy and cold root eduction of the deeply buried crustal material was initiated by decoupling of the thermal boundary layer in the subducted lithosphere isostatic rebound resulted in very rapid uplift 1 2 mm yr 1 and the deep crust was exhumed mainly by tectonic extensional stripping over a period of 30 40 myr the eduction was probably related to a rolling hinge footwall uplift mechanism and the early high pressure coaxial fabrics were overprinted by extensional simple shear as the deep crust reached middle and upper crustal levels the model explains the present day normal crustal thickness under the exhumed deep rocks without necessarily invoking large scale lateral flow of material in the lower crust or igneous underplating

monazite geochronology of uhp and hp metamorphism deformation and exhumation nordoyane western gneiss region norway u th pb monazite geochronology is combined with previous structural analysis and quantitative estimates of metamorphic conditions to date the thermotectonic evolution of uhp and hp plates 820 c 39 kbar 780 c 18 kbar metamorphosed during the late silurian early devonian collision between baltica and laurentia the upper plate contains a microdiamond bearing kyanite garnet graphite gneiss and associated kyanite eclogites independently indicating probable diamond forming conditions in situ dating of monazite in the microdiamond sample using the shrimp ii at the geological survey of canada yielded ages of 415 6 8 ma for those included in garnet and 398 6 ma for those in the matrix these ages compare to 408 0 5 6 and 397 5 4 4 ma determined using the electron microprobe at the university of massachusetts both methods also identified complexly zoned detrital cores up to 150 micrometers in diameter with ages of 1100 950 ma and scattered grains with ages of 900 500 ma but no ages of 1680 1650 ma equivalent to the local baltica basement were found agreement between the two techniques allowed evaluation of monazite age domains 198 analyses from the microdiamond rock and a kyanite garnet sillimanite mylonite produced from it using a combination of high resolution element imaging and trace element analysis of u th pb and y this comparison yielded three mean ages of 407 0 2 1 ma 394 8 2 3 ma and 374 6 2 7 ma combining this geochronology with previous p t estimates we propose that the uhp unit reached its maximum depth of 125 km at a maximum age of 407 ma when monazite was included in garnet and experienced 65 km of exhumation at an average rate of 10 9 mm year during top southeast thrusting that brought it into contact with the hp unit following these events both units were exhumed together at an average rate of 3 8 mm year until reaching a depth of 37 km at 395 ma where these rocks experienced extensive re equilibration and top west and left lateral shearing after 395 ma these units continued to be exhumed at an average rate of 0 8 to 1 4 mm year until 375 ma the time of last equilibration of asymmetric monazite porphyroclasts in the mylonite the exhumation histories of these units record a change in mechanism from syncollisional exhumation through late to post orogenic collapse that was a consequence of plate reorganization

a method for quantitatively estimating diffuse and discrete hydrothermal discharge submarine hydrothermal fluids discharge as undiluted high temperature jets and as diffuse highly diluted low temperature percolation estimates of the relative contribution of each discharge type which are important for the accurate determination of local and global hydrothermal budgets are difficult to obtain directly in this paper we describe a new method of using measurements of hydrothermal tracers such as fe mn fe heat and mn heat in high temperature fluids low temperature fluids and the neutrally buoyant plume to deduce the relative contribution of each discharge type we sampled vent fluids from the north cleft vent field on the juan de fuca ridge in 1988 1989 and 1991 and plume samples every year from 1986 to 1991 the tracers were on average 3 to 90 times greater in high temperature than in low temperature fluids with plume values intermediate a mixing model calculates that high temperature fluids contribute only 3 of the fluid mass flux but 90 of the hydrothermal fe and 60 of the hydrothermal mn to the overlying plume three years of extensive camera ctd sled tows through the vent field show that diffuse venting is restricted to a narrow fissure zone extending for 18 km along the axial strike linear plume theory applied to the temperature plumes detected when the sled crossed this zone yields a maximum likelihood estimate for the diffuse heat flux of8 9 104 w m for a total flux of 534 mw considering that diffuse venting is active along only one third of the fissure system for mean low and high temperature discharge of 25 c and 319 c respectively the discrete heat flux must be 266 mw to satisfy the mass flux partitioning if the north cleft vent field is globally representative the assumption that high temperature discharge dominates the mass flux in axial vent fields leads to an overestimation of the flux of many non conservative hydrothermal species by about an order of magnitude

marine and meteoric diagenesis of pleistocene carbonates from a nearshore submarine terrace oahu hawaii abstract the nearshore slope of oahu consists of a shallowly dipping shelf extending from the shoreline out to the 20 m contour where there is a sharp break in slope down to 30 m limestones recovered in a series of short cores taken from this nearshore terrace are typical of shallow marine reef environments and comprise either a branching coral or massive coral facies the composition as well as shoreward zonation of facies suggests that the terrace represents an in situ fossil reef complex th u ages of in situ corals are all pleistocene and suggest that the bulk of the feature formed during marine oxygen isotope stage 7 later accretion along the seaward front of the terrace occurred during marine oxygen isotope substages 5a and or 5c deposition during these interglacial highstands has not previously been documented in the sea level record on oahu although the diagenetic record in the cored samples is incomplete three periods of diagenesis are identified early shallow marine meteoric and post meteoric shallow marine early shallow marine diagenesis includes cementation by aragonite and mg calcite in an active marine phreatic zone and predominantly micritization in a stagnant marine phreatic zone meteoric processes occurred in the vadose zone and include precipitation of calcite needle fibers meniscus cements micritic networks neomorphism and dissolution all limestones are now in an active marine phreatic zone evidence of post meteoric shallow marine diagenesis is found in last generation mg calcite cements and internal sediments occurring directly on limestone substrates that have otherwise been stabilized to calcite the present seafloor is undergoing extensive biological and physical erosion no holocene limestones were recovered petrographic and geochemical signatures of subaerial exposure and meteoric diagenesis are recognized within the upper several centimeters of all cores thus the present seafloor in the study area is a flooded pleistocene subaerial exposure surface

new evidence for coesite in eclogite and gneisses defining an ultrahigh pressure province in the western gneiss region of norway widespread evidence of ultrahigh pressure metamorphism is reported from the nordfjord and stadtlandet area of the western gneiss region in norway outlining a distinct ultrahigh pressure province coesite has been found as inclusions in garnet omphacite or kyanite in eclogite from 5 new localities and quartz pseudomorphs after coesite occur in eclogite minerals at an additional 12 localities quartz pseudomorphs after coesite within garnet and clinozoisite are reported for the first time from associated gneisses which is evidence for in situ ultrahigh pressure metamorphism at least at a local scale the boundary to an ultrahigh pressure province is defined by a metamorphic break from lower pressure 2 8 gpa within a 10 km wide mixed zone in the nordfjord area this zone may mark the disrupted tectonic boundary to a small ultrahigh pressure unit and casts doubt on the assumption that the western gneiss region behaved as a coherent terrane during burial and exhumation

evolution of caledonian deformation fabrics under eclogite and amphibolite facies at vardalsneset western gneiss region norway the vardalsneset eclogite situated in the western gneiss region sw norway is a well preserved tectonite giving information about the deformation regimes active in the lower crust during crustal thickening and subsequent exhumation the eclogite constitutes layers and lenses variably retrograded to amphibolite and is composed of garnet and omphacite with varying amounts of barroisite actinolite clinozoisite kyanite quartz paragonite phengite and rutile the rocks record a five stage evolution connected to caledonian burial and subsequent exhumation 1 a prograde evolution through amphibolite facies t 490 63 c is inferred from garnet cores with amphibole inclusions and bell shaped mn profile 2 formation of l s tectonite eclogite t 680 20 c p 16 2 kbar related to the subduction of conti nental crust during the caledonian orogeny lack of asymmetrical fabrics and orientation of eclogite facies extensional veins indicate that the deformation regime during formation of the l s fabric was coaxial 3 formation of sub horizontal eclogite facies foliation in which the finite stretching direction had changed by approximately 90 disruption of eclogite lenses and layers between symmetric shear zones characterizes the dominantly coaxial deformation regime of stage 3 locally occurring mylonitic eclogites t 690 20 c p 15 1 5 kbar with top w kinematics may indicate however that non coaxial deformation was also active at eclogite facies conditions 4 development of a widespread regional amphibolite facies foliation t 564 44 c p 10 3 8 1 kbar quartz veins and development of conju gate shear zones indicate that coaxial vertical shortening and sub horizontal stretching were active during exhumation from eclogite to amphibolite facies conditions 5 amphibolite facies mylonites mainly formed under non coaxial top w movement are related to large scale movement on the extensional detachments active during the late orogenic extension of the caledonides the structural and metamorphic evolution of the vardalsneset eclogite and related areas support the exhumation model including an extensional detachment in the upper crust and overall coaxial deformation in the lower crust

chemistry of ore forming fluids and mineral formation rates in an active hydrothermal sulfide deposit on the mid atlantic ridge the chemical composition of diffuse effluent from the tag hydrothermal mound 26 n mid atlantic ridge directly demonstrates that mixing of entrained seawater and high temperature black smoker fluids leads to the precipitation of sulfides silica and anhydrite and to the zone refining of metals including cu zn u and the rare earth elements in an actively forming sulfide ore body rates of mineral formation deduced from these data are extremely rapid and are up to an order of magnitude greater for anhydrite 5 15 107 kg yr than for sulfides 106 107 kg yr comparison with mineral inventories for tag suggests that virtually all of the anhydrite in the tag mound is contemporary and confirms that the sulfide precipitated episodically during the history of mound growth and that much of it has been lost by oxidation and reworking

petrologic and geochemical constraints on the origin of subsurface dolomite enewetak atoll an example of dolomitization by normal seawater dolomite is present 1 250 1 400 m below sea level in eocene strata of enewetak atoll petrographically the deep enewetak dolomite postdates brittle compaction of rigid grains in the host eocene strata the 87 sr 86 sr ratio of these dolomites 0 70865 0 70901 indicates that they formed at one or more times between the middle miocene and the present since the top of the lower miocene is more than 900 m above the deep dolomitic interval the dolomite must have formed at a minimum burial depth of 900 m stable oxygen isotope determinations suggest dolomite precipitation from cold marine water lower miocene and eocene carbonate strata on the atoll are apparently in open communication with cold modern ocean water suggesting that those same strata were in open communication with ocean water during dolomitization at a depth of about 1 000 m modern pacific ocean water becomes undersaturated with respect to calcite but is still supersaturated with respect to dolomite therefore it is proposed that the deep enewetak dolomite precipitated from cold deep ocean water undersaturated with respect to calcite at a burial depth of more than 900 m

spatial variability of turbulent mixing in the abyssal ocean ocean microstructure data show that turbulent mixing in the deep brazil basin of the south atlantic ocean is weak at all depths above smooth abyssal plains and the south american continental rise the diapycnal diffusivity there was estimated to be less than or approximately equal to 0 1 x 10 4 meters squared per second in contrast mixing rates are large throughout the water column above the rough mid atlantic ridge and the diffusivity deduced for the bottom most 150 meters exceeds 5 x 10 4 meters squared per second such patterns in vertical mixing imply that abyssal circulations have complex spatial structures that are linked to the underlying bathymetry

buoyancy driven plumes in rotating stratified cross flows plume dependence on rotation turbulent mixing and cross flow strength a three dimensional time dependent convection model is used to describe circulation and property fields in rotating stratified and moving fluids near a point source of heat the study context and consequently model scales are those of chronically discharging hydrothermal vent fields found at submarine ridge crests hydrothermal plumes having distinctive thermal and chemical anomalies have been observed to rise several hundreds of meters above the deep sea floor before being advected away by background cross flows typically of magnitude 1 4 cm s 1 the model is used to study effects of rotation and indicate differences in plumes with respect to variation of subgrid scale turbulence intensity and cross flow strength counterrotating vorticity couplets in all three coordinate directions develop in the lower plume stem at startup and follow the plume to the level of neutral buoyancy for a nonrotational case 0 patterns resemble those previously found for jets injected into homogenous cross flow ambient fluid entrainment into the convecting column is primarily from the upstream side but deflection of background flow around both sides of the rising column is the root of the relative vorticity z couplet in the lower plume turbulence intensity within the buoyant region of the plume and or globally controls smoothness and temporal variability of distal nonbuoyant plume distributions allowing or preventing oscillations of potential temperature for example at background buoyancy frequency n over the range of turbulent mixing studied rise height of plumes did not change appreciably but breadth of plumes counterintuitively increased for decreasing turbulent mixing strength increasing cross flow strength u0 bends model plumes such that rise height u0 0 4 for the two largest values of cross flow for which r the ratio of maximum vertical velocity to u0 took values of 2 8 and 1 0 plumes showed evidence of bifurcation

an atlantic hydrothermal plume trans atlantic geotraverse tag area mid atlantic ridge crest near 26 n the physical characteristics of an atlantic hydrothermal plume and its seafloor sources are described from the first data set of water column properties associated with a high temperature source area at a slow spreading oceanic ridge the observations comprise five near bottom tows of a camera color video and still temperature sensor array through the buoyant portion and 23 conductivity temperature depth ctd profiles through the neutrally buoyant portion of the plume made at the trans atlantic geotraverse hydrothermal field in the rift valley of the mid atlantic ridge at 26 08 n 44 49 w in july 1985 the source area is a mound up to 250 m wide and 50 m high constructed primarily of massive sulfides between depths of 3620 and 3670 m at the base of the east wall flow and discharge regimes systematically changed from the center to the edge of the mound high temperature black smokers vented at fast rates 1 m s from discrete sulfide chimneys and at slow rates from fractures and clear solutions vented at slow rates from diffuse sources in the inner zone of the mound intermediate temperature blue white and white smokers vented at slow rates from discrete sulfide sulfate chimneys and clear solutions vented from diffuse sources in the middle zone patchy diffuse discharge of clear solutions through sulfide talus occurred in the outer zone the diffuse discharge of clear solutions and the discrete discharge from the white smokers were observed to turbulently rise up to several meters above the seafloor where the discharge was laterally advected in prevailing laminar flow at several centimeters per second a convective heat flux of 8 8 106 w for only the black smokers that vented from fractures was estimated by applying a buoyant plume model to temperature anomalies measured with the towed array this value is intermediate between values estimated for entire vent fields at the fast spreading east pacific rise discharge from the black smokers rose to form the neutrally buoyant portion of the plume that was cold and fresh relative to surrounding seawater where it attained density equilibrium between 190 and 350 m above the mound in contrast hydrothermal plumes observed in the pacific were warm and salty relative to surrounding seawater the difference is attributed to the effect on plume density of entrainment during rise through opposite salinity profiles that decrease downward in the atlantic and increase downward in the pacific resulting in different temperature salinity compensations at neutral buoyancy the temperature difference between the neutrally buoyant portion of the plume and surrounding seawater negative for the atlantic positive for the pacific is not a unique function of convective heat flux from a source area as a consequence of both the effect of the entrainment of salinity on plume density and the separation of diffuse and discrete components of discharge the hydrothermal plume and the hydrothermal mound are inferred to have grown in size and complexity in response to the development of hydrothermal flow and discharge regimes for at least the past 104 years

diffuse venting and background contributions to chemical anomalies in a neutrally buoyant ocean hydrothermal plume plumes originating in high temperature hydrothermal discharges entrain background water and often entrain diffuse source fluids during convective ascent the mixing of fluid from those three different sources determines the chemical composition of the ensuing neutrally buoyant plumes here convection models and aluminum data from the trans atlantic geotraverse tag site are used to examine relative contributions of focused diffuse and background sources to anomalies in the plume our analysis shows that anomalously high al values observed just above the seafloor at tag which we assume stem from diffuse flows can contribute as much as 50 to the al anomaly in the neutrally buoyant plume found 350 m above bottom background water contributes nearly an equal fraction of al to the anomaly more generally entrained contributions depend on gradients in profiles external to the rising plume entrainment also depends on effective source area distributed high temperature vents entrain more fluid than a single composite high temperature vent larger effective source area is particularly significant for entrainment of diffuse source or other tracers trapped within a few tens of meters of the seafloor downstream cross stream and temporal variabilities exhibited in the three dimensional model plume also underscore problems of sampling and interpreting actual plume data

modern marine dolomite cement in a north jamaican fringing reef minor quantities of ordered dolomite delta sup 18 o 2 0 per thousand pdb composition ca sub 1 22 mg sub 0 78 co sub 3 sub 2 have formed from near normal seawater in a subtidal hardground as part of a modern fringing coral reef crystals 5 mu m in diameter precipitated within the past 1 8 ka in the form of syntaxial fringes on mg calcite marine cements and skeletal allochems the crystals have a fine modulated microstructure and c reflections both apparently formed during crystal growth

a model of an atlantic and pacific hydrothermal plume a turbulent entrainment model of a hydrothermal plume was modified to include the effects of vertical structure in the background temperature and salinity fields owing to the stably stratified salinity field in the pacific relatively warm salty water spreads at an equilibrium level where the plume density equals the ambient density in contrast the unstable salinity profile in the atlantic gives the plume added buoyancy and it continues to rise to an equilibrium level where it is relatively cool and fresh these attributes result from the mixing between the plume and the surrounding seawater at each level below the spreading layer the equilibrium temperature anomaly is not directly proportional to the source strength but depends on the mixing and background salinity gradient the net entrainment of surrounding seawater is greater in the atlantic plume model than in the pacific plume model for the same buoyancy flux recent data from the tag hydrothermal field at 26 n on the mid atlantic ridge and data from a vent field on the endeavor segment of the juan de fuca ridge are compared to model results the model predicts the penetration height and s characteristics of the atlantic plume and it explains some of the differences between the observed atlantic and pacific hydrothermal plumes

a layered aquifer model of atoll island hydrology validation of a computer simulation abstract the finite element model femwater was used to simulate groundwater movement in the two dimensional vertical plane of an atoll island section the model island had dimensions consistent with enjebi island enewetak atoll a surficial holocene aquifer to a depth of 15m with hydraulic conductivity 6 9 10 4 ms 1 overlying a plio pleistocene aquifer with k 6 9 10 2 ms 1 a tidally varying water level was applied to the ocean and lagoon boundaries and the model was run until pseudo steady state conditions were achieved in the groundwater variations hydraulic head contours in the vertical section demonstrate that water motion under the supratidal portion of the island is almost exclusively vertical calculated water table tidal lags and efficiencies are in excellent agreement with measured values from shallow wells on enjebi island confirming the validity of the layered aquifer model and the approximate magnitudes of the hydraulic conductivities model results near island margins can be interpreted to explain other features of hydrologic field data from atoll islands the results emphasize the potential importance of tidal effects and vertical water flow on reef island groundwater systems and cast doubt on the utility of traditional models using the dupuit assumptions of essentially horizontal flow

dynamic hydrology and diagenesis of a submerged pleistocene fringing reef discovery bay jamaica abstract in the discovery bay area of north jamaica a pleistocene fringing reef grew and was subsequently planed off as sea level rose to and fell from a highstand approximately 5 to 10 m below modern sea level between 132 000 and 147 000 yrs bp dynamic movement of seawater through the reef today evidenced by flow of water in and out of open core holes has caused precipitation of cements which overprint previous diagenetic fabrics in certain zones in the reef flat and distal fore reef facies where porosity is diffuse modern water movement is slow and has had little effect on pre existing diagenetic fabrics which are dominantly vadose in texture in facies with conduit porosity as in the reef crest and proximal portions of the shallow fore reef seawater is channelized and high flow rates have resulted in the precipitation of substantial amounts of holocene sparry high magnesian calcite cements 15 18 mol mgco 3 up to 250 m thick resulting in incorporation of significant amounts of 14 c in the pleistocene rocks smaller mg calcite crystals having lower magnesium content are characteristic of zones with diffuse porosity the dynamic marine system apparently also favors the precipitation of dolomite in zones of diffuse porosity water motion within the reef results in the slow movement out of the man made conduits in zones of conduit porosity such as in facies having highly localized permeability water is sucked into open core holes in accordance with bernoulli s principle it is not known to what depths such channelized flow occurs data from a recording current meter demonstrate that the driving force responsible for the dynamic hydrology has a strong tidal component the tidal component is augmented by wind driven waves and is probably superimposed on another unidentified current which contributes to the flow of water in the reef at all tidal stages

production and cycling of calcium carbonate in a shelf edge reef system st croix u s virgin islands applications to the nature of reef systems in the fossil record abstract geologic reefs are the end products of not only constructive processes that produce calcium carbonate but also of destructive processes e g bioerosion and wave action that reduce solid substrate to sediment and of physical processes that rework the reef fabric and transport sediment a study was conducted at cane bay on the island of st croix u s virgin islands to quantify the suite of processes that have influenced holocene reef development data on carbonate production reef accretion bioerosion and sediment transport were used to construct a detailed carbonate budget and to apply the findings of this study to the character of reefs observed in the fossil record total carbonate production on the reef ranged from 0 to 5 78 kg m2 per year with a reef wide average of 1 21 kg m2 per year 1 13 by corals 0 02 by coralline algae 0 06 by primarily molluscs forams and echinoderms based on 7 cores only 0 91 kg m2 per year of this have been retained within the reef interior the remaining 0 24 kg m2 per year of sediment along with the 0 06 kg m2 per year contributed directly by molluscs etc are deposited within reef channels and are probably flushed from the reef by major storms of the material recovered in the cores 58 was either loose sediment and rubble or open void space much of the recognizable coral material was demonstrably reworked and out of place accretion rates across the shelf generally increased with water depth as a result of active slumping along the steepening reef face over the past 2 000 3 000 years the importance of detrital material in the reef fabric and the major role played by secondary processes that constantly rework the substrate have resulted in a reef whose interior is more of a garbage pile than an in place assemblage of corals cemented together into a rigid framework the physical similarities between the detrital fabric of the reef at cane bay and those found in many ancient deposits imply that the general processes operating along the cane bay shelf have persisted during much of the evolution of ancient reefs it is proposed that our modern models overemphasize the importance of in place framework as a criterion for an ecologic reef

kinematic linkage between internal zone extension and shortening in more external units in the nw alps in the alps a major extensional shear zone unroofed eclogites in its footwall from 30 kbar to c 10 kbar implying of the order of 60 km of relative vertical movement in the period 45 36 ma the horizontal component of divergence was of the order of 100 km we use the foreland basin sedimentary record to prove that the extension was contemporaneous with thrusting in units structurally beneath the eclogites the brianconnais and or external zones this thrust related convergence during that time period was of the order of 44 56 km and therefore of the same order of magnitude as internal zone divergence extension may have been driven by internal density contrasts buoyant continental crust underneath the mafic eclogites or dense subducted slab offset from the orogen can induce extension any dynamic model must account for the comparable magnitudes of extension and shortening in adjacent parts of the orogen relative plate motions in the period 45 36 ma played a subsidiary role

high temperature deformation in the basal shear zone of an eclogite bearing fold nappe sveconorwegian orogen sweden ductile shear zones associated with emplacement of high pressure nappes are key features to resolve exhumation mechanisms the eastern segment of the sveconorwegian orogen hosts an eclogite bearing fold nappe whose basal shear zone shows structures associated with emplacement of the eclogite bearing nappe and decompression under high to intermediate pressure granulite and upper amphibolite fades conditions based on detailed structural mapping of a 4 km well exposed section of the basal shear zone we describe two major phases of deformation an early deformation stage d1 formed a penetrative gneissic foliation and tectonic layering including isoclinal folds f1 the sequence was subsequently affected by up to km scale tight south vergent folds f2 with sheared out limbs at the outcrop scale asymmetric f2 folds are commonly s vergent but symmetric folds with different degrees of tightness are also present melt was present at all stages of deformation and the structural relations demonstrate mutual feedback between melt localization and fold formation f2 folds have shallowly e plunging fold axis parallel to a stretching lineation defined by high grade mineral aggregates both constitute prominent structures of the basal shear zone f2 folds are associated with an axial planar fabric s2 defined by upper amphibolite and locally granulite facies mineral assemblages d2 shear structures are associated with top to the east kinematic indicators throughout the section the d1 episode was responsible for emplacement of the eclogite nappe into its present structural position the subsequently developed lineation parallel folds are interpreted to form by general shear where the structures reflect the regional e directed flow of the entire eclogite nappe c 2015 elsevier b v all rights reserved less

omphacite fabric variation in the cabo ortegal eclogite nw spain relationships with strain symmetry during high pressure deformation petrostructural study of cabo ortegal eclogite tectonites provides an insight into the relationships between omphacite lattice preferred orientation and the fundamental deformation parameters in particular strain symmetry microstructural evidence is consistent with a tectonic origin of eclogite fabrics by coeval pyroxene plastic deformation and recrystallization under eclogite facies metamorphic conditions omphacite shape fabrics and garnet spatial distributions are anisotropic and representative of the fields of either apparent flattening or constriction omphacite lattice preferred orientations are dominated by 010 axis maxima normal to the foliation s type or flattening fabrics by 001 axis maxima parallel to the lineation l type or constriction or correspond to other fabric patterns described in the literature omphacite crystallographic fabrics are consistently asymmetric with respect to the structural framework defined by foliation and lineation this suggests that non coaxial deformation components either simple or general shear accompanied eclogite fabric development in addition to any flattening or constriction strain paths and permit shear sense determination these petrostructural features were acquired in the course of eo hercynian ductile deformation probably during deep subduction under 1 5 1 7 gpa confining pressure temperatures above 600 700 c low differential stress 15 20 mpa and slow strain rate 10 12 10 15s 1

growth of large sulfide structures on the endeavour segment of the juan de fuca ridge abstract mapping and sampling with dsrv alvin has established that sulfide blocks 0 5 m across dredged from the axial valley of the endeavour segment at 47 57 n are samples of unusually large sulfide structures the steep sided structures up to 30 m in length 20 m in height and 10 15 m across are localized by venting along normal faults at the base of the western axial valley wall and are distributed for about 200 m along strike paralleling the 020 trend of the ridge crest high temperature fluids 350 to more than 400 c pass through the massive sulfide structures and enter seawater through small concentric nozzle like features projecting from the top or the sides of the larger vent structures diffuse low temperature flow is pervasive in the vicinity of the active sulfide structures exiting from basalt and sulfide surfaces alike evidence of recent volcanic activity is sparse the two largest samples taken with the dredge would not have been recoverable using the submersible these samples represent massive complex portions of the sulfide structures which were not closely associated with rapid high temperature fluid flow at the time of sampling they contain textural evidence of sealed hydrothermal fluid exit channels mineralogy is dominated by fe sulfides nnd amorphous silica pyrite marcasite wurtzite chalcopyrite and iss are the most common sulfide phases pyrrhotite galena and sphalerite are present in trace amounts barite amorphous silica and chalcedony are the only non sulfide phases anhydrite is not observed in any of the dredge samples although it is common in the chimney like samples recovered by alvin specific mineralogical textural zones within the dredge samples are anaoogous to individual layers in east pacific rise at 21 n and southern juan de fuca ridge samples with two exceptions a coarse grained highly porous fe sulfide rich interior containing sulfidized tubeworm casts and a 2 5 cm thick zone near the outer margin of the samples dominated by late stage amorphous silica the porous interior may have formed by dendritic crystal growth from a slowly circulating fluid within a large enclosed chamber the amorphous silica deposited from a seawater hydrothermal fluid mixture percolating slowly through the walls of the enclosed chamber conductive cooling of the fluid as it traversed the walls allowed amorphous silica to precipitate these silica rich zones are the densest most durable portions of the structures and may be responsible for the lasting stability of the large sulfide features observations in these samples are consistent with two distinct phases of development phase 1 is analogous to chimney growth and construction at 21 n and ends when flow channels become sealed to rapid flow of through going fluid the flow is evidently redirected within the structure phase 2 includes dissolution of anhydrite and precipitation of amorphous silica during conductive cooling of sluggishly circulating hydrothermal fluid or seawater hydrothermal fluid mixtures evolution of vent structures through phase 2 allows lateral and vertical growth of unusually large structures

a turbulent convection model with an observational context for a deep sea hydrothermal plume in a time variable cross flow 1 a turbulent convection model for a hydrothermal fluid discharging into a tidally modulated stratified cross flow is used to investigate time variable conditions in plumes such as the one rising from dante a sulfide mound at 2175 m depth on the endeavour segment of the juan de fuca ridge that plume is the consequence of the coalescence of 10 or more small individual plumes from chimneys discharging hot salt diminished fluid into the near bottom ocean at dante the discharge encounters ambient horizontal currents with speeds oscillating from near zero to a maximum of 7 cm s 1 speeds which can bend a plume more than 45 from the vertical model results are compatible with field measurements of the plume footprint size and vertical velocity both 20 m above the source when earlier estimates for dante s heat flux of 50 mw drive the convection the small scale short period variability of velocities and properties distributions observed in the field is mimicked in model results plumes pool above a source during periods of weak cross flows but stream away from the source with more diluted concentrations and lower rise heights at other times plume distributions at identical cross flow speeds differ whether the flow is accelerating or decelerating small changes in background hydrographic profiles create differences in rise heights comparable to those caused by large changes in source buoyancy flux if put into an entrainment context results suggest an entrainment coefficient eff that varies from 0 11 to 0 025 with increasing height 2 76 m above the source

implications to garnet clinopyroxene geothermometry of non ideal solid solution in jadeitic pyroxenes garnet clinopyroxene geothermometry has been applied to numerous rock types from the blueschist and eclogite terrain of the sesia zone in the western alps discrepancies in apparent temperatures of up to 600 c have been found suggesting substantial deviation from ideal behaviour of the garnet clinopyroxene equilibria in certain assemblages assemblages containing jadeitic pyroxenes rather than omphacitic or diopsidic pyroxenes yield very low kd 2 0 values and correspondingly high apparent temperatures 1 000 c the garnets coexisting with high na pyroxenes have compositions similar to those coexisting with omphacitic pyroxenes departure from ideal behaviour of these garnets is likely to be minor and is accomodated in the formulation of the geothermometer numerous examples of coexisting garnet clinopyroxene pairs indicate that there is no obvious relationship of kd with jadeite content in pyroxenes with jadeite content less than 70 but at higher values kd varies inversely with the jadeite content the dependence of kd upon the jadeite content in the high na pyroxenes is believed to be due to the preference of m2 sites for fe2 in the enstatite jadeite substitution fe2 mgna 1al 1 this substitution is usually very limited and has no demonstrable effect upon x fe cpx when the m1 fe2 mg content of the pyroxenes is high as in omphacitic and diopsidic pyroxenes however when the m1 fe2 mg content is low as in jadeitic pyroxenes the non ideality of the enstatite type exchange has a marked effect on x fe cpx and consequently on garnet clinopyroxene calculations

complex strain patterns developed at the frontal and lateral tips to shear zones and thrust zones abstract many of the complex strain patterns seen in shear zones and thrust zones such as variable fabric orientations refolded folds and fabrics together with folds with hinges almost parallel to the main transport direction can be explained in terms of differential movement within the shear zones these strains are developed at the frontal and lateral tips of the zones as they propagate examples are taken from the moine thrust zone of scotland which show variations in strains particularly at the lateral tips the form of differential movement described here may lead to complex strain paths and non plane strain ellipsoids and the spatial variations in finite strain may be used to delineate zones of extensional and compressional flow and differential movement in the shear zones or thrusts

temporal variability of the hydrothermal plume above the kairei vent field 25 s central indian ridge 1 continuous profiling of the nonbuoyant plume above a hydrothermal vent site can be used to determine the interaction between the plume formed by venting high temperature fluids and changing background temperature salinity and current fields over a tidal cycle we have conducted a 12 hour monitoring of the nonbuoyant plume above the kairei vent field 25 s central indian ridge the depth of the plume particle maximum varies significantly in the water column from 2150 m to 2350 m but remains strongly associated with the 2 36 987 potential density isopycnal we have used the interaction between two unrelated physical oceanographic phenomena to isolate the section of the time series record most suitable for determining the heat flux of the kairei source on the basis of the rise height of the plume to neutral buoyancy at the start of the time series internal waves are observed with a period similar to the calculated buoyancy period n 1 about 3 hours no consistent relationship is observed between the rise height of the plume and the calculated heat flux for the last 6 hours of the time series isopycnal surfaces are compressed above a strongly developed nonbuoyant plume such that the calculated buoyancy period is less than that of the internal waves a more constant heat flux can be calculated on the basis of the plume rise height from this part of the record

interaction between fluid flow fracturing and mineral growth during eclogitization an example from the sunnfjord area western gneiss region norway in sunnfjord western gneiss region of south norway a proterozoic layered gabbro complex displays various degrees of transformation to eclogite in the unreacted parts layering in the gabbro is defined by modal variations of plagioclase olivine pyroxenes and minor fe ti oxide and spinel coronitic and foliated eclogite formed from the gabbro by hydration reactions at t 510 620 c causing a volume decrease of c 13 in the coronitic eclogite the mafic magmatic phases are replaced by aggregates of omphacite barroisite tremolite talc and rutile whereas the plagioclase domains are pseudomorphed by omphacite barroisite clinozoisite kyanite paragonite and garnet the felsic and mafic domains are separated by a garnet rim up to 5 mm thick garnet was also formed along dilational veins connecting and radiating out of coronas including the same eclogite facies minerals in addition microfractures filled by amphibole and omphacite cut through the corona and vein garnet oriented perpendicular to the garnet layering the transformation of dry gabbro to eclogite with hydrous minerals requires supply of water the timing of metamorphic reactions is therefore dependent on the timing of fluid introduction the inclusion pattern of garnet in the holt tyssedalsvatnet metagabbro complex indicates that transformation started under eclogite facies conditions brittle deformation in form of fractures allowing infiltration of fluids and mobilisation of elements is shown to be the most important process initiating transformation brittle deformation is thereby active in deep crustal levels corresponding to eclogite facies conditions fracturing is interpreted as having been caused by a combination of high fluid pressure volume changes during mineral transformations and external stresses ductile deformation started after the initial metamorphic transformation garnet chemistry and zoning pattern are controlled by the chemistry of the growth place the fluid influx and element supply abrupt chemical variations across corona garnet may have been formed by an interaction between rapid growth and transport along microfractures between plagioclase and mafic domain the metamorphic transition proceeded rapidly the transformation of the deep crust to eclogite can be viewed as a dynamic process where the volume changes result in fracturing and these fractures funnelling fluid and element enhancing mineral reaction the densification causes further fracturing indicating that the process is self driven provided that fluid is available

a tem study of disequilibrium plagioclase breakdown at high pressure the role of infiltrating fluid high pressure metamorphism 600 c 20 kbar of the allalin gabbro western alps resulted in the breakdown of plagioclase an63 to fine grained zoisite jadeite kyanite and quartz in rare cases this reaction failed to reach completion the resulting textures of partial reaction have been studied by transmission and analytical electron microscopy in localised regions of a plagioclase crystal where the extent of reaction is 10 only zoisite developed and the orientation relationship left 100 right text zo left 101 right text p1 1 and left 012 right text zo left 010 right text p1 1 is frequently present in regions where 10 50 of plagioclase has transformed the reaction plagioclase h2o zoisite kyanite quartz nasica 1al 1 pl has occurred the systematic orientation relationship between plagioclase and zoisite is absent at 50 transformation complete breakdown of plagioclase occurred in localized micron scale domains by the reaction plagioclase h2o zoisite jadeite kyanite quartz and the reaction products are variably orientated with respect to each other incomplete reaction together with the concentration of reaction products around cracks in original plagioclase grains suggests that extent of reaction was controlled primarily by the availability of h2o the textural observations are interpreted in terms of two possible disequilibrium reaction models 1 plagioclase persists metastably with its original igneous composition to a pressure 17 kbar at 600 c reaction to the equilibrium assemblage then develops adjacent to cracks in response to the presence of aqueous fluid at intracrystalline sites only partial reaction occurs because jadeite and sometimes kyanite and quartz fail to nucleate for kinetic reasons 2 localized regions of a plagioclase crystal partially equilibrate at several stages during the increase of pressure 9 17 kbar at 600 c possibly due to discrete episodes of fluid infiltration in both these models the extent of reaction may be limited by nasi caal interdiffusion in plagioclase

aluminum reactivity in hydrothermal plumes at the mid atlantic ridge direct measurements of buoyant plume waters collected by submersible show that the behavior of al is highly nonconservative during the early mixing of submarine hydrothermal fluids and seawaters at the tag and mark sites on the mid atlantic ridge al is removed from the hydrothermal end members and is also stripped from the entrained seawater to produce levels of al in the plume solutions about one fifth of normal seawater concentrations the behavior of al appears to be similar to that inferred for other anionic species v as cr p which exhibit constant element iron ratios in hydrothermal plume particles and suggests that such elements are removed from seawater during the early stage of formation of hydrothermal plumes

rheology of the plate interface dissolution precipitation creep in high pressure metamorphic rocks abstract subduction zone models invoke deformation to be concentrated along the plate interface in a region of particularly low temperature geophysical observations do not provide constraints on temperature stress and deformation patterns with desired resolution in contrast the record of high pressure metamorphic rocks exhumed from subduction zones provides details on p t history deformation mechanisms and stress state albeit not readily correlated with the former dynamic situation on larger scale here we review available information on dissolution precipitation creep dpc in high pressure metamorphic rocks which if representative for subduction zones in general can pose constraints on conditions rheology and flow patterns along the plate interface the key observations and conclusions are that 1 deformation is typically highly inhomogeneous and localized into shear zones 2 stresses are generally too low to drive crystal plastic deformation 3 microfabrics suggest dissolution precipitation creep to be the predominant deformation mechanism 4 an aqueous fluid at quasi lithostatic pressure is available throughout allowing for tensile fracturing and crack healing or sealing 5 low stress combined with high strain rates required for localized deformation at typical subduction rates implies low viscosity and 6 contribution of shear heating to the thermal budget of subduction zones should be moderate the dominant deformation mechanism dpc is reviewed in some detail including experimental and theoretical approaches various examples of dpc in high pressure metamorphic rocks are illustrated emphasizing the role of interphase boundaries as sites of dissolution rheology governed by dpc is proposed to control interplate coupling and development of a subduction channel with return flow being a likely candidate for rapid exhumation of high pressure metamorphic rocks

acoustic mapping of diffuse flow at a seafloor hydrothermal site monolith vent juan de fuca ridge diffuse flow of hydrothermal solutions commonly occurs in patchy areas up to tens of meters in diameter in seafloor hydrothermal fields it is recognized as a quantitatively significant component of thermal and chemical fluxes yet is elusive to map we report a new acoustic method to detect and map areas of diffuse flow using phase coherent correlation techniques the sonar system was modified to record phase information and mounted on dsv sea cliff the submersible occupied a stationary position on the seafloor and the transducer scanned the seafloor surrounding monolith vent a sulfide edifice venting black smokers at a nominal range of 17 m at a depth of 2249 m on the juan de fuca ridge patchy areas of uncorrelated returns clearly stood out from a background of returns that exhibited ping to ping correlation the areas of uncorrelated returns coincided with areas of diffuse flow as mapped by a video survey with the navy s advanced tethered vehicle atv correlated returns were backscattered from invariant seafloor uncorrelated returns were distorted by index of refraction inhomogeneities as they passed through diffuse flow between the seafloor and the transducer the acoustic method presented can synoptically map areas of diffuse flow when combined with standard in situ measurement and sampling methods the acoustic mapping will facilitate accurate determination of diffuse thermal and chemical fluxes in seafloor hydrothermal fields

geothermometry and geobarometry a discussion geothermometric and geobarometric methods are considered under two groupings directly calibrated methods and internally consistent data set methods emphasis is placed on the importance of error propagation calculations they allow the calculation of model uncertainties on temperatures and pressures due to the quantifiable uncertainties involved in the calibration and application of methods the possibility of systematic errors due to the unquantifiable effects of the assumptions and approximations involved must be evaluated using the criterion of geological reasonableness the advantages of the internally consistent data set approach are expounded and an appropriate error propagation procedure developed

distribution and composition of hydrothermal plume particles from the ashes vent field at axial volcano juan de fuca ridge in 1986 and 1987 buoyant and neutrally buoyant hydrothermal plume particles from the ashes vent field within axial volcano were sampled to study their variations in composition with height above the seafloor individual mineral phases were identified using standard x ray diffraction procedures elemental composition and particle morphologies were determined by x ray fluorescence spectrometry and scanning electron microscopy x ray energy spectrometry techniques the vent particles were primarily composed of sphalerite anhydrite pyrite pyrrhotite chalcopyrite barite hydrous iron oxides and amorphous silica grain size analyses of buoyant plume particles showed rapid particle growth in the first few centimeters above the vent orifice followed by differential sedimentation of the larger sulfide and sulfate minerals out of the buoyant plume the neutrally buoyant plume consisted of a lower plume which was highly enriched in fe s zn and cu and an upper plume which was highly enriched in fe and mn the upper plume was enriched in fe and mn oxyhydroxide particles and the lower plume was enriched in suspended sulfide particles in addition to the fe and mn oxyhydroxide particles the chemical data for the water column particles indicate that chemical scavenging and differential sedimentation processes are major factors controlling the composition of the dispersing hydrothermal particles short term sediment trap experiments indicate that the fallout from the ashes vent field is not as large as some of the other vent fields on the juan de fuca ridge

metastability of granulites and processes of eclogitisation in the uhp region of western norway the flatraket complex a granulite facies low strain enclave within the western gneiss region provides an excellent example of metastability of plagioclase bearing assemblages under eclogite facies conditions coesite eclogites are found 28 kbar unprecedented metastability of plagioclase and quartz is implied alternatively a tectonic break exists between the flatraket complex and uhp eclogites supporting the concept of a tectonic boundary to the uhp zone of the western gneiss region the distribution of eclogite and amphibolite facies metamorphic overprints demonstrates that the reactivity of the crust during deep burial and exhumation is strongly controlled by fluid availability and is a function of the protolith

40ar 39ar mineral dates related to devonian extension in the southwestern scandinavian caledonides abstract middle devonian sedimentary basins exposed in west central norway formed during post caledonian extension they developed along west dipping low angle normal faults which effected ductile shearing of pre caledonian basement units of the western gneiss region wgr kinematic indicators suggest that the west vergent ductile deformation overprinted older east vergent caledonian fabric elements ductile extensional deformation led to development of a 2 km thick shear zone beneath the devonian basins five amphibole and nine muscovite concentrates from rocks within the shear zone and from unaffected gneisses of the western gneiss region have been analyzed with 40ar 39ar incremental release dating techniques in an attempt to calibrate the timing of extensional events well defined plateau ages are recorded by muscovite concentrates within the shear zone amphiboles display disturbed plateau ages clearly related to extraneous argon outside the shear zone muscovite records caledonian ages results suggest that a late tectonometamorphic event affected the rocks within the shear zone this event which not exceed ca 500 c completely rejuvenated muscovite argon systems and perturbed argon distribution within amphiboles this metamorphism is correlated with the extensional deformation which effected exhumation of the caledonian high pressure rocks and controlled formation of devonian basins

consequences of progressive eclogitization on crustal exhumation a mechanical study summary the very low water content of the granulitic unit of holsnoy in the bergen arcs norway caused its partial metastable preservation throughout caledonian burial end exhumation leading to the observed mixture of completely eclogitized and uneclogitized rocks the eclogitization of the granulite facies protolith led to a density increase 10 but also to a large rheological weakening that resulted in the localization of all deep ductile deformation in the eclogite fraction we address the consequences on subduction dynamics of the concomitant evolution of large scale density and rheology during progressive eclogitization of crust by comparing the behaviour of buried crust with various properties in the channel flow model large scale buoyancy and density are integrated in a single adimensional parameter the exhumation number which describes the capacity of the crust to exhume for a crust whose eclogitization causes a very large viscosity decrease burial resistant end member goes through a maximum in the partially eclogitized zone that is there is a given proportion of eclogite for which the crust is strongly weakened but still significantly lighter than surrounding mantle for this partially eclogitized crust with max the maximum possible downward flow is very low this zone acts as a bottleneck and all incoming crust in excess is forced backwards and starts exhuming this return flow zone is bounded downwards in the partially eclogitized zone by max while its upper limit propagates upwards at a constant rate the curve eclogite fraction controls the maximum proportion of eclogite of the crust that can be exhumed we also demonstrate that large exhumation rates reached by certain uhp units are incompatible with any stationary flow regime whatever the nature of subducted crust the additional presence of a weak layer on top of the channel favours burial for narrow channels and exhumation for large ones but does not qualitatively change the dynamics of the subduction channel this study shows that deep crustal circulation in subduction zones and exhumation from large depths are controlled by the evolution of large scale crustal properties with progressive eclogitization

vergence and facing patterns in large scale sheath folds the careful geometric analysis of minor structural detail elucidates the relationships and evolution of associated large scale curvilinear hinge geometries developed during wnw directed caledonian thrusting exposed in neoproterozoic moine psammites of the moine nappe reversals in the polarity of structural facing associated with minor folding mark the position of major sheath folds which parallel transport upwardly convex sheaths closing in the direction of thrust transport cored by older gneissose basement inliers are termed culminations whilst those opening in the transport direction and cored by moine psammites are termed depressions sheath folds are bisected by transport parallel and foliation normal culmination depression surfaces which separate not only the reversals in facing but also delineate zones of minor fold hinge obliquity into clockwise and anticlockwise domains relative to the transport direction the sense of obliquity of minor z and s folds is thus dependent on position with respect to the surfaces of culmination and depression and not the fold axial surfaces surfaces of culmination and depression may be superimposed on original overturned antiformal and synformal folds to produce a variety of dome culmination on antiform saddle depression on antiform inverted saddle culmination on synform and basin depression on synform configurations the curvilinear hinges of minor folds may also be asymmetrical about the transport direction and within the plane of the regional foliation to define patterns of fold hinge line vergence classical concepts of fold limb vergence may thus relate to larger antiformal and synformal hinges whilst the fold hinge line vergence defines major curvilinear hinges associated with culminations and depressions major sheath folds may therefore be interpreted in terms of both minor fold hinge line and limb vergence coupled with fold axis obliquity and reversals in the polarity of structural facing the ability to recognise consistent and reliable structural relationships between facing and hinge obliquity at small scales indicates that the regional deformation process forms a linked and coherent system through several orders of magnitude 1999 elsevier science ltd all rights reserved

creep of garnet in eclogite mechanisms and implications abstract the rheological properties of subducting rocks represent a fundamental parameter in the dynamics of subduction zones making robust predictions about these properties and the general strength evolution of subducting plates is hampered by a relatively restricted understanding of the mechanisms by which rocks deform at high and ultrahigh pressure this uncertainty is relates to the discrepancy between experimental and field based observations of eclogite deformation and in particular the role of garnet to further investigate this important aspect we performed a textural and micro structural investigation applying optical microscopy element mapping and electron backscatter diffraction on deformed garnet polycrystals from an eclogite mylonite the results were compared to those from a study of undeformed polycrystals that formed from a supercooled frictional melt at hp conditions the mylonites polycrystals are flattened parallel to the main high pressure foliation in the rock and individual grains were shortened by an average 15 although dislocation creep is commonly presumed to dominate garnet straining in eclogites no record of this mechanism was found instead the garnet grains have dissolution surfaces indicative of deformation by intergranular pressure solution the observations provide compelling evidence for the role of fluids and syn tectonic porosity in the weakening of garnet a supposedly rigid eclogite component such weakening represents a crucial step in the fundamental feedback loop between fluid ingress metamorphism and near instantaneous competence loss in rocks undergoing deep subduction

the geometry and timing of orogenic extension an example from the western italian alps contacts between rocks recording large differences in metamorphic grade are indicative of major tectonic displacements low p upon high p contacts are commonly interpreted as extensional i e material points on either side of the contact moved apart relative to the palaeo horizontal but dating of deformation and metamorphism is essential in testing such models in the western alps the piemonte ophiolite consists of eclogites t 550 600 c and p 18 20 kbar structurally beneath greenschist facies rocks t 400 c and p 9 kbar mapping shows that the latter form a kilometre wide shear zone the gressoney shear zone gsz dominated by top se movement related to crustal extension rb sr data from micas within different gsz fabrics which dynamically recrystallized below their blocking temperature are interpreted as deformation ages ages from different samples within the same fabric are reproducible and are consistent with the relative chronology derived from mapping they show that the gsz had an extensional deformation history over a period of c 9 myr between c 45 36 ma this overlaps in time with the eclogite facies metamorphism the gsz operated over the entire period during which the footwall evolved from eclogite to greenschist facies and was therefore responsible for eclogite exhumation the discrete contact zone between eclogite and greenschist facies rocks is the last active part of the gsz and truncates greenschist facies folds in the footwall these final movements were therefore not a major component of eclogite exhumation pressure estimates associated with old and young fabrics within the gsz are comparable indicating that during extensional deformation there was no significant unroofing of the hangingwall since there are no known extensional structures younger than 36 ma at higher levels in this part of the alps exhumation since the final juxtaposition of the two units at 36 ma seems to have been dominated by erosion key words deformation age eclogite exhumation rb sr dating tectonic

discrete and diffuse heat transfer atashes vent field axial volcano juan de fuca ridge abstract heat fluxes of discrete and diffuse components of hydrothermal discharge are estimated from submersible measurement in the ashes vent field located in the caldera of axial volcano on the central juan de fuca ridge the discrete component comprises discharge from individual vents and the diffuse component comprises seepage from large areas of the seafloor the investigation centered on the high temperature portion of the field a 100 100 m area of fractured lobate and sheet lava flows encompassing discrete discharge 326 c from seven individual vents and diffuse flow from intervening areas a total of 4 4 2 10 6 w was estimated for the discrete heat flux based on measurements of effluent temperature flow rate and orifice diameter at all the known individual vents by d s v alvin in september 1987 a total of 15 75 10 6 w was calculated with a standard plume model for the diffuse flux based on a grid of temperature measurements at altitudes of 1 m and 20 m above the study area using a 1 m long vertical array of temperature sensors mounted at the front of alvin s instrument platform the study indicates that 1 the diffuse component rises separately from the discrete component of hydrothermal discharge and is laterally advected by a prevailing current below the discrete component and that 2 the diffuse component of convective heat flux is approximately an order of magnitude greater than the discrete component in the high temperature portion of the ashes vent field

chemical reaction rates and entrainment within the endeavour ridge hydrothermal plume the aging of the hydrothermal plume over the endeavour segment of the juan de fuca ridge was estimated by measuring the222rn3he ratio in the plume as it dispersed despite uncertainties in the source function of hydrothermal input it wa determined that the relative sequence of removal from the plume ish2 c 222rn ch4 mn where c is a measure of particle concentration and the mean life of222rn is 5 5 days h2 is removed from the plume within hours of input while mn is not removed within the two week timescale of the radon helium clock entrainment of bottom water within the buoyant plume may introduce additional chemical signatures into the spreading effluent layer over that which would be introduced by hydrothermal discharge alone this is particularly significant for those chemical species which are not greatly enriched in the vent fluids relative to bottom water concentration and which display a nutrient like profile in the deep ocean thus we found that significant fractions of the si and226ra anomalies in the plume were not of hydrothermal origin but were derived from entrained bottom water which has a higher concentration of these elements than ambient water at plume height

temporal variations in diffuse hydrothermal flow at tag we have obtained direct measurements of diffuse hydrothermal effluent temperature velocity and chemistry from the tag hydrothermal mound 26 08 n 44 49 w mid atlantic ridge we report on the time series physical measurements obtained from a location on the eastern flank of the main summit complex several features were observed including strong tidal variability in flow a conspicuous elevation of effluent temperatures during the period 11 october 17 october 1994 and a long term increase in temperature superimposed upon all other trends the six day long temperature excursion is coincident with increases in sediment and effluent temperatures observed by instruments left in place on the tag mound by other workers we have established through time lapse seafloor video observations and through drilling records that the mid october effluent temperature excursion is correlated closely with local drilling activity by the ocean drilling program

folds with axes parallel to the extension direction an experimental study abstract experimental studies of single and multilayer folding have generally considered shortening of layers oriented perpendicular to the maximum extension direction x i e layers parallel to yz or in a more limited number of cases oblique layers still containing the intermediate y axis few experimental studies have considered the case where the extension direction x lies within the layer itself although in nature folds with axes parallel to x are quite commonly seen these folds have often been ascribed to passive rotation of fold axes during continued shear but it has been shown both theoretically and experimentally that active buckle folds can also develop with axes parallel to x single and multilayer analogue model experiments were performed on planar layers oriented initially perpendicular to the intermediate y axis and with the extension direction x lying within the layer itself all experiments were conducted in plane strain either in pure shear or simple shear paraffin waxes of different melting ranges were used as analogues for rocks with a power law rheology stress exponent around 2 3 with a viscosity ratio of ca 30 1 no measurable fold amplification was discernible for shortening of 36 or shear strain of 3 6 neither domed initial perturbations with circular sections parallel to the layer nor cylindrical perturbations elongate parallel to the initial stretching direction were significantly amplified only at much higher viscosity ratios ca 600 1 did active buckle folding develop this folding at high viscosity ratio was associated with flow of the matrix in the x direction around the layer developing a strong linear fabric parallel to x in the matrix immediately adjacent to the layer the development of this flow discontinuity between matrix and layer may be characteristic of active buckling of layers parallel to xz with fold axes parallel to x

near field variability of the tag non buoyant plume 26 n mid atlantic ridge we report the initial results of a nine hour monitoring of the non buoyant plume above the tag hydrothermal vent field at 26 n on the mid atlantic ridge a ctd conductivity temperature and pressure and nephelometer particle sensor were continuously raised and lowered through the non buoyant plume for nine hours at a site situated 100 m south of the hydrothermal mound this method permits a detailed record of the variability of the non buoyant plume close to the vent field to be made our results show that the particulate maximum of the non buoyant plume appears 150 m lower in the water column at the start and end of the record compared with profiles recorded towards the middle of the record a corresponding structure also appears in the temperature and salinity records with the result that the plume particle maximum resides on the 27 8035 isopycnal throughout modelling of the rise height of an axisymmetric plume can only account for 95 m of the variability in the final level of neutral buoyancy plume bending due to currents is a likely explanation for the recorded temporal variability

holocene dolomitization of supratidal sediments by active tidal pumping sugarloaf key florida abstract sugarloaf key is an area where holocene dolomitization is occurring calcium rich dolomite is found in a 0 25 to 10 cm thick surface crust which transgresses a thin layer of carbonate mud overlying the karsted pleistocene miami oolite radiocarbon ages of the crust range from 160 years b p to 1420 years b p with a corresponding increase in dolomite content from 0 to 80 the relatively high permeability of the underlying pleistocene oolite and low permeability of the holocene carbonate mud results in a tidal lag between surface water and the partly confined aquifer consequently seawater is pumped upward and downward through the holocene sediment during spring tides the highest concentration of dolomite is found in areas where the sediment layer is thinnest and tidal pumping is most effective limited analyses of surface and subsurface water taken at intervals throughout the pumping cycle suggest that the dolomitizing fluid is essentially florida bay water the earliest diagenesis is caused by precipitation of dolomite cement which occurs as 0 1 to 0 3 micron subrounded crystallites that show no distinct crystal form during further cementation and somewhat later during replacement of preexisting crystallites poorly ordered dolomite forms as 1 to 5 micron euhedral rhombs x ray diffraction data indicate that the crystallized dolomite is better ordered and less calcium rich than the dolomite composed of crystallites

the tectonic implications of solundian upper devonian magnetization of the devonian rocks of kvamshesten western norway the allochthonous old red sandstone of kvamshesten western norway records polyphase orogenic deformation and palaeomagnetic results from both the devonian sediments and mylonites associated with the basal thrust define a syn to post tectonic magnetization withd 218 i 3 and 95 9 7 the corresponding pole position lat 21 s long 324 e suggests a late devonian early carboniferous magnetization age solundian and probably dates the time of thrust movements

exhumation of deep crustal metamorphic rocks and crustal extension in arc and back arc regions we adress the problem of exhumation of metamorphic rocks in arc and back arc positions based on observations of the aegean and tyrrhenian back arc regions in both regions back arc extension has been active for 25 ma at least while convergence and crustal thickening was going on at the thrust front compressional structures are reworked in the back arc domain as extensional flat lying detachments which allow unroofing of the metamorphic pile metamorphic rocks suffer first a dynamic burial during nappe stacking and then fast exhumation when they reach the extensional region we describe a continuous process of burial and exhumation that is contemporaneous with the migration of the thrust front toward external zones the front of extension follows behind at approximately one hundred kilometers at the convergence front continuous subduction of a cold oceanic slab or continuous accretion of continental units keeps a cool p t gradient and hp lt metamorphic rocks are formed at depth the overall cool environment leads to a deep brittle ductile transition and thus to a resistant crust which can sustain its large thickness while the thrust front propagates forward parts of the accretionary wedge which were formed earlier enter the back arc domain which can be already under extension and which is warmer because of a greater distance to the cold slab and the presence of the volcanic arc the brittle ductile transition rises in the thick crust which then becomes unstable and subsequently collapses the exhumation history of metamorphic rocks below detachments is two fold 1 a constantely thickening crust is unroofed by flat lying detachments which rework early thrusts this first period is characterized by a good preservation of hp lt parageneses 2 the second period is when rocks are in the zone of crustal scale extension of the back arc region deep crustal metamorphics are exhumed below flat lying detachements which affect the whole crust

estimation of heat and chemical fluxes from a seafloor hydrothermal vent field using radon measurements the circulation of seawater through newly formed ocean crust at mid ocean ridge spreading centres is important in the oceanic heat and chemical budgets the heat transfer in submarine hydrothermal systems accounts for 25 of the total global heat loss1 the transfer of mass resulting from basaltic alteration affects the geochemistry of seawater2 and is responsible for the formation of ore deposits on and beneath the seafloor3 various geophysical techniques have been employed in efforts to determine the heat output from hydrothermal vent fields4 9 however the magnitudes of the heat and chemical fluxes through these systems remain uncertain here we introduce a geochemical approach for estimating the flux from a vent field based on radon 222rn measurements in the overlying effluent plume this method was applied successfully in september 1986 during a 23 day expedition to an active vent field on the 170 km endeavour segment of the juan de fuca ridge fig la we estimate the heat flux from this site to be l 5 l09 w

eclogite facies polyphase deformation of the drosdal eclogite western gneiss complex norway and implications for exhumation abstract exhumation of the deep crust during orogenic extension is accepted as a geological phenomenon but structures formed during burial and the earliest stages of exhumation are often overprinted by deformation events occurring at shallower crustal levels the western gneiss complex wgc of norway comprises variably retrogressed high pressure hp and ultrahigh pressure uhp eclogite bodies enclosed in predominantly felsic amphibolite facies rocks the drosdal body located in the sunnfjord area is one of the largest and best preserved eclogites in the wgc and comprises over ca 3 km2 of exposed eclogite facies rocks it is an excellent example of an eclogite tectonite and displays a wealth of structures formed during deformation at a minimum depth of 50 km and peak temperatures of ca 800 c large volumes of mylonites with the eclogite facies assemblage garnet clinopyroxene quartz amphibole clinozoisite phengite kyanite rutile are preserved structures associated with the eclogite facies metamorphism include e w trending isoclinal folds boudinage hinge parallel lineations and meter scale kyanite dominated veins the drosdal body was tightly folded on the kilometer scale under eclogite facies conditions subsequently the shapes of the drosdal body and other mafic bodies in the sunnfjord area were modified during eclogite to amphibolite facies e w directed stretching to give boudin like lenses the timing of formation of a pervasive eclogite facies lineation eclogite facies folds and kyanite bearing veins overlapped substantially and this portion of the deformation history was dominated by a constrictional strain field partitioning of deformation occurred after a substantial amount of eclogite facies deformation had already taken place and resulted in the relative rotation of linear features in specific zones on the scale of 400 m the eclogite facies lineations and fold hinges within the drosdal body are subparallel to amphibolite and greenschist facies structures throughout the wgc although circumstantial this suggests that structures belonging to each of these three metamorphic facies formed during one progressive deformation event corresponding to extensional exhumation our observations are consistent with models involving inhomogeneous deformation of the lower crust during early orogenic extension we envisage that transtensional noncoaxial deformation dominated the extensional deformation of the wgc but that coaxial deformation must have occurred locally

excess 222rn above the cleft segment of the juan de fuca ridge the distributions of excess 222rn above the north cleft segment of the juan de fuca ridge were determined from 1988 to 1991 in order to obtain a better understanding of the temporal variability of heat flux from this ridge segment based on the inventories of excess 222rn the hydrothermal heat flux was estimated to be 2 7 1 3 gw in 1990 the large uncertainty results from errors in calculating the standing crop of 222rn the difficulty in determining the 222rn to heat ratio and the problem of entrainment of low temperature waters into the rising plume the high resolution sampling program carried out in 1990 permitted the mapping of apparent plume ages for different sections of the neutrally buoyant plume about 3 km to the east of the ridge axis there is a sharp gradient in the apparent age of the plume while to the west the plume appears to be younger this plume age distribution could indicate a current flow to the northwest during the time this transect was sampled the mean 222rn heat ratios for the high and low temperature vent fluids were 0 0017 disintegrations per minute dpm g 1 c 1 and 0 0044 dpm g 1 c 1 respectively the extrapolated end member concentrations of excess 222rn in low temperature vent fluids are a factor of 6 greater than the high temperature fluids based on the regressions of excess 222rn activity and mg concentration in north cleft segment vent fluid samples

geothermal springs of the west florida continental shelf evidence for dolomitization and radionuclide enrichment abstract on the sea bed of the west florida continental shelf about 45 km ssw of ft myers florida an 85 km 2 area has been discovered in which six thermal springs discharge warm chemically altered seawater from vents and seepage zones the spring water apparently originates in the subsurface ocean around the florida platform and penetrates the highly porous strata of the platform about 500 1000 meters below sea level it percolates toward the interior of the platform and is geothermally heated to about 40 c en route then it rises along more vertical flow channels and is discharged in warm submarine springs beneath the platform several chemical processes alter the percolating seawater one process seems to be a secondary dolomitization of the limestone of the platform because in the discharging seawater magnesium is lower by 2 7 mmole kg and calcium higher by 3 6 mmole kg than in normal seawater with the same chlorinity other reactions within the sediments of the platform enrich the spring effluents 1000 fold in 226 ra 10 000 fold in 222 rn and 90 fold in 228 ra compared to the seawater surrounding the platform thus the springs may be important sources of radionuclides for the gulf of mexico the percolating seawater also loses all of its oxygen and nitrate to reduction processes loses most of its phosphate and 40 of its 238 u and roughly quadruples its silica content coastal carbonate platforms are fairly common geological features thus processes like those beneath the west florida shelf may function on a world wide basis to play an important role in the diagenesis of carbonate sediments

tapping into the sub seafloor examining diffuse flow and temperature from an active seamount on the juan de fuca ridge abstract a unique sampling strategy involving the cementing of a permanent fluid sampler directly to the seafloor on axial seamount juan de fuca ridge has recently allowed the first long term direct coupling to a low temperature hydrothermal vent on a mid ocean ridge using the hydrologically sealed sampler direct measurement of fluid volume and heat flux from a diffuse hydrothermal vent on the seafloor was obtained over a period of 206 days enhanced variance at both tidal and lower frequencies was recorded with a high coherence between the temperature and flow data we estimate a volume flux of 48 m 3 yr and a heat flux of 260 w m 2 for the square meter of seafloor sampled by the instrument measurement of the darcy flow velocities of the effluent fluid are approximately 1 5 10 6 m s and indicate fluid velocities within cracks in the substrate of 1 4 m day with an effective upper crustal permeability of 10 11 10 12 m 2 while the measured variability in fluid flow is driven primarily by changes in the thermal buoyancy of upwelling fluid there is also a significant above hydrostatic pressure gradient contribution to the measured flux this overpressure produces roughly four times the driving force compared to that attributed to thermal buoyancy alone small variations in the volume flux and the effluent fluid temperature 1 5 10 8 m s and 0 5 c respectively also occurred on approximately tidal time scales and appear to be related to poroelastic control of the velocity of hydrothermal fluid through the seafloor boundary i e tidal pumping

recent tectonic magmatic and hydrothermal activity on the east pacific rise between 17 s and 19 s submersible observations the objective of the naudur cruise december 1993 of the submersible nautile was to study the interaction among magmatic tectonic and hydrothermal processes at a very fast spreading mid ocean ridge axis twenty three dives were completed both along and across the axis in four areas located between 17 10 and 18 45 s on the east pacific rise rock sulfides water and biological samples have been collected along each of the segments two main types of segments have been distinguished characterized either by the predominance of present day volcanic activity or by predominant tectonic activity linked to both types of activity 69 hydrothermal sites have been discovered and sampled they comprise four types interpreted as successive evolutionary stages the first are shimmering water sites which occur immediately after the formation of lava lakes and are characterized by large surface area and poorly developed associated fauna the second in areas dominated by recent volcanic activity have waters venting directly from lava fissures and more focused discharge areas through black smoker chimneys the third stage is represented by more mature hydrothermal vents and deposits along the faults bounding the eastern side of the axial graben in tectonic dominated areas the associated fauna is well developed the fourth stage corresponds to the reactivation of volcanic activity with lava flows young black smokers and diffuse venting associated with the faults bounding the axial graben fluids collected range from 200 to 340 c and show a wide variability in chemical and gas composition within each of the explored areas evidence of recent volcanic activity has been observed

the tectonic significance of pre scandian 40ar 39ar phengite cooling ages in the caledonides of western norway pre silurian continental margin deposits in western norway non conformably overlying allochthonous continental orthogneisses retain ordovician 40 ar 39 ar cooling ages for phengites implying either rapid cooling immediately after a late ordovician orogenic event or less likely a slow cooling following an early ordovician or older orogeny the dalsfjord suite hoyvik group basement cover pair are probably a lateral equivalent to late proterozoic sandstones sparagmites covering the jotun nappe gneisses of the middle allochthon in central south norway the hoyvik group underwent polyphase deformation greenschist facies metamorphism t max 40 ar loss probably occurred during subsequent scandian deformation and late to post orogenic extension the hoyvik group rocks were unroofed before the wenlock time 423 428 ma and cooled through the temperature for argon retention in phengite at c 447 4 ma indicating a maximum cooling rate between 14 and 22c ma 1 through ashgill and llandovery times before being subjected to low grade metamorphism during the scandian orogeny rapid pre scandian cooling combined with peak metamorphic conditions of 450c or less may indicate that the dalsfjord hoyvik basement cover pair were avected by an orogenic event during the late ordovician caradoc time the data also suggest that the caledonian margin of baltica may have experienced a more protracted tectonism during the caledonian cycle than previously models focusing on early caledonian and tremadoc or older ophiolite obduction and the scandian continental collision between baltica and laurentia

the middle devonian basins of western norway sedimentary response to large scale transtensional tectonics abstract the devonian basins of western norway were formed during late to post orogenic extension of overthickened caledonian crust the basins are situated in the hanging wall of the extensional nordfjord sogn detachment zone nsdz and display extensional half graben geometries in sections parallel to the local direction of principal extension based on overall facies configurations paleocurrent patterns and intrabasinal structures we infer an anticlockwise rotation of the syndepositional extension direction from nw se in the south solund basin to wsw ene in the north hornelen basin the axes of folds that are roughly parallel to the local extension direction are rotated correspondingly the kvamshesten basin is located between the solund and hornelen basins sedimentological and structural data show evidence of an early southeastwards tilt direction followed by a more eastwards tilt and associated e w flowing paleodrainage correspondingly nw se trending folds and reverse faults are superposed by e w trending ones at low to intermediate stratigraphic levels the variations in apparent tilt direction for the basins together with variations in intrabasinal structure is interpreted to reflect an anticlockwise rotation of the regional syndepositional strain field the above observations and inferences indicate that the devonian basins in western norway formed in a strain field dominated by regional transtension accommodated by extension along the nsdz and sinistral strike slip along orogen parallel shear zones and faults to the north of the basins alternatively nw directed extension preceded the introduction of a sinistral strike slip component the models are in accordance with recent work carried out in the footwall of the nsdz and illustrates the tectono sedimentary response to a complex interplay between extension and strike slip that appears to have been fundamental in the late stage disintegration of the caledonian orogen

theory applied to the mid atlantic ridge hydrothermal plumes the finite difference approach a system of differential equations describing the entrainment of ambient seawater during the rise of a buoyant hydrothermal plume has been solved by an explicit finite difference method chosen for its ease of application an equation for tracer concentration has been added so that concentrations in the neutrally buoyant plume can be calculated for those elements whose background profiles vary over the depth range of the buoyant plume the height of plume rise can be related directly to the thermal and hydrothermal vent flux for the tag vent field 26 n mar five plume layers have been identified the calculated heat flux is 500 940 mw and the fluid flux is 0 210 0 392 m3 s 1 the fluid flux to the neutrally buoyant plume is 1460 2740 m3 s 1 calculated plume concentrations of mn compared with measurements made at tag in 1988 indicate that there is either 50 removal of manganese in the buoyant plume or that low temperature vent fluids contribute about 50 of the total thermal output of the tag vent field