diatom δ18o evidence for the development of the modern halocline system in the subarctic northwest pacific at the onset of major northern hemisphere glaciation establishing a time frame for the development of the modern halocline and stratified water column in the subarctic north pacific has significant paleoclimatic implications here we present a d18o diatom record consisting of only two species that represents autumn winter conditions in the region across the onset of major northern hemisphere glaciation boundary at circa 2 73 ma a decrease in d18o diatom of 4 6 occurs whereas previously published d18o foram results show a 2 6 increase the d18o diatom and uk37 sea surface reconstructions indicate both a significant freshening of 2 4 practical salinity units and an increase in surface temperatures in the summer to early winter period from circa 2 73 ma onward in contrast the concomitant increase in d18o foram is likely to be reflective of conditions beneath the mesothermal structure and or spring conditions when warmer sea surface temperatures are not present in the region these results are consistent with the development of the modern halocline system at 2 73 ma with year round stratification of the water column and a strengthened seasonal thermocline during the summer to early winter period resulting in one of the largest summer to winter temperature gradients in the open ocean the onset of stratification would also have led to a warm pool of surface water from circa 2 73 ma which may have provided a potential source of extra moisture needed to supply the growing north american ice sheets at this time

the δ15n of nitrate in the southern ocean consumption of nitrate in surface waters we report nitrogen isotope data for nitrate from transects of hydrocast and surface samples collected in the eastern indian and pacific sectors of the southern ocean focusing here on the data from the upper water column to study the effect of nitrate consumption by phytoplankton the 15n of nitrate increases by 1 2 from deep water into the antarctic summertime surface layer due to kinetic isotopic fractionation during nitrate uptake estimation of the nitrate uptake isotope effect from antarctic depth profiles yields values in the range of 5 6 in east indian sector and 4 5 in the east pacific sector surface transect data from the pacific sector also yield values of 4 5 the major uncertainty in the profile based estimation of the isotope effect involves the 15n of nitrate from the temperature minimum layer below the summertime antarctic surface layer which deviates significantly from the predictions of simple models of isotope fractionation for the subantarctic surface it is possible to distinguish between nitrate supplied laterally from the surface antarctic and nitrate supplied vertically from the subantarctic thermocline because of the distinctive relationships between the 15n and concentration of nitrate in these two potential sources our subantarctic samples collected during the summer and fall indicate that nitrate is supplied to the subantarctic surface largely by northward transport of antarctic surface water isotopic data from the pacific sector of the subantarctic suggest an isotope effect of 4 5 indistinguishable from the antarctic estimates in this sector

evidence from diatom bound nitrogen isotopes for subarctic pacific stratification during the last ice age and a link to north pacific denitrification changes higher diatom bound d 15 n 70 wt lower opal content and 1200 ppm lower biogenic barium taken together and with constraints on sediment accumulation rate these results suggest a reduced supply of nitrate to the surface due to stronger stratification of the upper water column of the bering sea during glacial times with more complete nitrate consumption resulting from continued iron supply through atmospheric deposition this finding extends the body of evidence for a pervasive link between cold climates and polar ocean stratification in addition we hypothesize that more complete nutrient consumption in the glacial age subarctic pacific contributed to the previously observed ice age reduction in suboxia and denitrification in the eastern tropical north pacific by lowering the nutrient content of the intermediate depth water formed in the subpolar north pacific in the deglacial interval of the bering sea record two apparent peaks in export productivity are associated with maxima in diatom bound and bulk sediment d 15 n the high d 15 n in these intervals may have resulted from greater surface nutrient consumption during this period however the synchroneity of the deglacial peaks in the bering sea with similar bulk sediment d 15 n changes in the eastern pacific margin and the presence of sediment lamination within the bering sea during the deposition of the productivity peaks raise the possibility that both regional and local denitrification worked to raise the d 15 n of the nitrate feeding bering sea surface waters at these times

diatom bound 15n 14n new support for enhanced nutrient consumption in the ice age subantarctic 1 diatom bound 15n 14n was used to reconstruct the glacial nutrient status of the subantarctic zone in the southern ocean down core records from both the pacific and indian sectors show 15n of 5 to 6 during the last glacial maximum and a decrease coincident with the glacial termination to values as low as 2 the effect of either diatom assemblage or physiological change on the diatom bound 15n 14n is unknown and cannot yet be ruled out as a possible explanation for the observed change however the consistency between indian and pacific sector records and with other paleoceanographic data suggests that the glacial interglacial difference in diatom bound 15n 14n was driven by higher consumption of nitrate in the subantarctic surface during the last ice age such a change in nutrient consumption may have resulted from atmospheric iron fertilization and or decreased glacial mixed layer depths associated with sea ice melting enhanced nutrient consumption in the glacial subantarctic would have worked to lower the concentration of co2 in the ice age atmosphere it also would have reduced the preformed nutrient content of the low latitude thermocline leading to decreases in low latitude productivity suboxia and denitrification

the optimal estimation of earthquake parameters abstract the precision with which various earthquake parameters can be determined using an existing or a proposed network of seismographic stations has recently been of considerable interest analytical solutions for the optimal resolution are presented for the epicenter hypocenter focal mechanism seismic moment and local magnitude estimation problems the algebraic method is to decompose orthogonally the equations of condition for each problem using the singular value theorem the orthonormal equations and the data covariance then yield the uncertainties in the estimations of the unknown earthquake parameters possible biases due to significant linear correlations among the observed data are included in the analysis as an example the ability of data from the berkeley three station network of broadband seismographs to determine the above earthquake parameters is discussed the parameters of the ml 5 9 coyote lake earthquake of august 6 1979 are determined in detail in order to use all of the resolution that a network has for determining earthquake parameters it is necessary to calibrate the network for regional earthquakes which have well determined parameters if the network is not calibrated the use of relatively simple velocity models will lead to significant systematic errors in the estimation of some of the parameters

links between iron supply marine productivity sea surface temperature and co2 over the last 1 1 ma received 3 july 2008 revised 9 october 2008 accepted 27 october 2008 published 14 february 2009 1 paleoclimatic reconstructions have provided a unique data set to test the sensitivity of climate system to changes in atmospheric co2 concentrations however the mechanisms behind glacial interglacial g ig variations in atmospheric co2 concentrations observed in the antarctic ice cores are still not fully understood here we present a new multiproxy data set of sea surface temperatures sst dust and iron supply and marine export productivity from the marine sediment core ps2489 2 odp site 1090 located in the subantarctic atlantic that allow us to evaluate various hypotheses on the role of the southern ocean so in modulating atmospheric co2 concentrations back to 1 1 ma we show that antarctic atmospheric temperatures are closely linked to changes in so surface temperatures over the last 800 ka and use this to synchronize the timescales of our marine and the european project for ice coring in antarctica epica dome c edc records the close correlation observed between iron inputs and marine export production over the entire interval implies that the process of iron fertilization of marine biota has been a recurrent process operating in the subantarctic region over the g ig cycles of the last 1 1 ma however our data suggest that marine productivity can only explain a fraction of atmospheric co2 changes up to around 40 50 ppmv occurring at glacial maxima in each glacial stage in this sense the good correlation of our sst record to the edc temperature reconstruction suggests that the initial glacial co2 decrease as well as the change in the amplitude of the co2 cycles observed around 400 ka was most likely driven by physical processes possibly related to changes in antarctic sea ice extent surface water stratification and westerly winds position

enhanced stratification and seasonality in the subarctic pacific upon northern hemisphere glaciation new evidence from diatom bound nitrogen isotopes alkenones and archaeal tetraethers abstract coincident with the intensification of northern hemisphere glaciation nhg around 2 73 million years ma ago sediment cores from both the open subarctic north pacific and the antarctic indicate a rapid decline in diatom opal accumulation flux to the seabed representing one of the most abrupt and dramatic changes in the marine sediment record associated with the development of pleistocene glacial cycles in the north pacific bulk sediment nitrogen isotope data and alkenone derived sea surface temperature sst estimates suggest that the productivity decline was driven by reduced exchange between surface and deep water due to weaker wind driven upwelling and or a strengthening of the halocline i e stratification in this study of the 2 73 ma transition at ocean drilling program odp site 882 in the western subarctic north pacific diatom bound nitrogen isotopes 15 n db alkenone mass accumulation rate and alkenone and archaeal tetraether based sst reconstructions support the stratification hypothesis indicating perennially lower export production generally higher nitrate consumption and greater inter seasonal variation in sst after the 2 73 ma transition in addition the 15 n db of large and small size fractions of coscinodiscus spp suggest that these diatoms grew mostly during the spring bloom during the late pliocene switching to their current fall to winter growth period at the 2 73 ma transition this view is consistent with their decline in dominance and provides further evidence for increased stratification reduced vertical exchange in the north pacific after 2 73 ma the 15 n db data indicate that over the 100 kyr period after the 2 73 ma transition studied here nitrate consumption did not reach late pleistocene ice age levels and that nitrate consumption in post 2 73 ma warm stages was similar to that before the transition even though productivity was greatly reduced we tentatively attribute this to relatively weak dust borne iron inputs in the early post 2 73 ma period

a novel proxy for terrestrial organic matter in sediments based on branched and isoprenoid tetraether lipids we propose a novel tracer for terrestrial organic carbon in sediments based on the analysis of tetraether lipids using high performance liquid chromatography mass spectrometry hplc ms analysis of terrestrial soil and peats shows that branched tetraether lipids are predominant in terrestrial environments in contrast to crenarchaeol the characteristic membrane lipid of non thermophilic crenarchaeota which is especially abundant in the marine and lacustrine environment based on these findings an index was developed the so called branched and isoprenoid tetraether bit index based on the relative abundance of terrestrially derived tetraether lipids versus crenarchaeol this bit index was applied to surface sediments from the angola basin where it was shown to trace the outflow of the congo river furthermore analyses of particulate organic matter from the north sea showed relatively higher bit indices in water column particulate organic matter near large river inputs a survey of globally distributed marine and lacustrine surface sediments shows that the bit index in these environments correlates with the relative fluvial input of terrestrial organic material making this index generally applicable the new proxy allows the rapid assessment of the fluvial input of terrestrial organic material in immature sediments up to 100 ma old

palaeoceanography polar twins ice ages in the north pacific ocean and the southern ocean were marked by low productivity accumulating evidence indicates that strong stratification restricted the supply of nutrients from the deep ocean to the algae of the sunlit surface in these regions

drastic change in the late pliocene subarctic pacific diatom community associated with the onset of the northern hemisphere glaciation abstract to date there is scarcely clear understanding of the detailed responses of the subarctic pacific phytoplankton communities to the significant climate transition across the initiation of the northern hemisphere glaciation nhg approximately 2 7 million years ago we present more highly resolved evidence of the rapid and drastic change in the phytoplankton biosphere using diatom as a tracer of environmental changes and based on quantitative assemblage analysis of two marine cores from oceanic regions of the north pacific subarctic gyre in the late pliocene subarctic pacific coscinodiscus marginatus and neodenticula kamtschatica were widely dominant but the flora rapidly and drastically shifted to one rich in neodenticula complex n koizumii n seminae at the onset of nhg perhaps due to intense changes in paleoceanographic conditions such as cooling and or a collapse of the previously nutrient regime in the region we also suggest that vertical pumping of biogenic matter by diatoms may have been more efficient in this region earlier than the onset of nhg after the nhg intensification the major primary productivity role in the subarctic pacific shifted from the c marginatus rich flora to the neodenticula complex the drastic decrease of biogenic opaline accumulation reportedly associated with the initiation of nhg would have resulted from not only a decrease of primary production but also from the change in diatom assemblages and consequent effects on their principal role in export flux

effect of global ocean temperature change on deep ocean ventilation 1 a growing number of paleoceanographic observations suggest that the ocean s deep ventilation is stronger in warm climates than in cold climates here we use a general ocean circulation model to test the hypothesis that this relation is due to the reduced sensitivity of seawater density to temperature at low mean temperature that is at lower temperatures the surface cooling is not as effective at densifying fresh polar waters and initiating convection in order to isolate this factor from other climate related feedbacks we change the model ocean temperature only where it is used to calculate the density to which we refer below as dynamic temperature change we find that a dynamically cold ocean is globally less ventilated than a dynamically warm ocean with dynamic cooling convection decreases markedly in regions that have strong haloclines i e the southern ocean and the north pacific while overturning increases in the north atlantic where the positive salinity buoyancy is smallest among the polar regions we propose that this opposite behavior of the north atlantic to the southern ocean and north pacific is the result of an energy constrained overturning

coupled nitrification denitrification in sediment of the eastern bering sea shelf leads to 15n enrichment of fixed n in shelf waters 1 we studied the nitrogen biogeochemistry of the ice covered eastern bering sea shelf using the isotope ratios 15n 14n and 18o 16o of no3 and other n species the 15n 14n of late winter no3 on the shelf decreases inshore and is inversely correlated with bottom water nh4 consistent with an input of low 15n 14n no3 from partial nitrification of nh4 remineralized from the sediments an inshore 15n 14n increase in total dissolved n tdn suggests that 1 the sediment derived nh4 is elevated in 15n due to the same partial nitrification that yields the low 15n 14n no3 and 2 15n deplete no3 from partial nitrification within the sediments is denitrified to n2 the proportion of newly nitrified no3 on the shelf evidenced by an inshore decrease in no3 18o 16o is correlated with the n deficit further implicating nitrification coupled to denitrification however a simple n isotope budget indicates a comparable rate of denitrification supported by diffusion of no3 into the sediments the isotopic impact of benthic n loss is further demonstrated by a correlation between the 15n 14n of shelf surface sediment and the n deficit of the overlying water column both of which increase inshore and northward as well as by arctic no3 isotope data indicating that the fixed n transported through bering strait has a 15n 14n higher than is found in the open bering sea the significant net isotope effect of benthic n loss on the bering shelf 6 8 is at odds with previous assumptions regarding the global ocean s n isotope budget

subpolar link to the emergence of the modern equatorial pacific cold tongue the cold upwelling tongue of the eastern equatorial pacific is a central energetic feature of the ocean dominating both the mean state and temporal variability of climate in the tropics and beyond recent evidence for the development of the modern cold tongue during the pliocene pleistocene transition has been explained as the result of extratropical cooling that drove a shoaling of the thermocline we have found that the sub antarctic and sub arctic regions underwent substantial cooling nearly synchronous to the cold tongue development thereby providing support for this hypothesis in addition we show that sub antarctic climate changed in its response to earth s orbital variations from a subtropical to a subpolar pattern as expected if cooling shrank the warm water sphere of the ocean and thus contracted the subtropical gyres

the continental margin is a key source of iron to the hnlc north pacific ocean here we show that labile particulate iron and manganese concentrations in the upper 500m of the western subarctic pacific an iron limited high nutrient low chlorophyll hnlc region have prominent subsurface maxima between 100 200 m reaching 3 nm and 600 pm respectively the subsurface concentration maxima in particulate fe are characterized by a more reduced oxidation state suggesting a source from primary volcagenic minerals such as from the kuril kamchatka margin the systematics of these profiles suggest a consistently strong lateral advection of labile mn and fe from redox mobilized labile sources at the continental shelf supplemented by a more variable source of fe from the upper continental slope this subsurface supply of iron from the continental margin is shallow enough to be accessible to the surface through winter upwelling and vertical mixing and is likely a key source of bioavailable fe to the hnlc north pacific

subarctic pacific evidence for a glacial deepening of the oceanic respired carbon pool abstract measurements of benthic foraminiferal cadmium calcium cd ca have indicated that the glacial interglacial change in deep north pacific phosphate po4 concentration was minimal which has been taken by some workers as a sign that the biological pump did not store more carbon in the deep glacial ocean here we present sedimentary redox sensitive trace metal records from ocean drilling program odp site 882 nw subarctic pacific water depth 3244 m to make inferences about changes in deep north pacific oxygenation and thus respired carbon storage over the past 150 000 yr these observations are complemented with biogenic barium and opal measurements as indicators for past organic carbon export to separate the influences of deep water oxygen concentration and sedimentary organic carbon respiration on the redox state of the sediment our results suggest that the deep subarctic pacific water mass was depleted in oxygen during glacial maxima though it was not anoxic we reconcile our results with the existing benthic foraminiferal cd ca by invoking a decrease in the fraction of the deep ocean nutrient inventory that was preformed rather than remineralized this change would have corresponded to an increase in the deep pacific storage of respired carbon which would have lowered atmospheric carbon dioxide co2 by sequestering co2 away from the atmosphere and by increasing ocean alkalinity through a transient dissolution event in the deep sea the magnitude of change in preformed nutrients suggested by the north pacific data would have accounted for a majority of the observed decrease in glacial atmospheric pco2

revisiting nutrient utilization in the glacial antarctic evidence from a new method for diatom bound n isotopic analysis holocene in the indian sector is smaller than in previous measurements these data suggest no change in the degree of nitrate utilization in the atlantic sector and at most a 20 increase from 25 to 45 in the indian sector the new measurements suggest that during the last ice age in the atlantic sector of the antarctic the atmospheric source of biologically available iron was not so great as to become significant relative to the iron supply from below given the apparent spatial variability in the degree of nitrate drawdown more work is required to develop an adequate picture of the glacial antarctic nutrient field index terms 4806 oceanography biological and chemical carbon cycling 4845 oceanography biological and chemical nutrients and nutrient cycling 4894 oceanography biological and chemical instruments and techniques 9310 information related to geographic region antarctica

late neogene history of deepwater ventilation in the southern ocean we compiled carbon isotope records from the north atlantic south atlantic and pacific oceans to estimate changes in vertical and interbasinal 13c gradients for the last 9 myr benthic 13c values of deep water in the south atlantic decreased in a series of steps at 7 2 75 and 1 55 ma away from the north atlantic and toward the pacific the benthic 13c of intermediate water in the south atlantic evolved differently from deep waters resulting in an increase in the intermediate to deep 13c gradient 13cid the 13cid increased in steps at 2 75 and 1 55 ma marking the development and intensification of a chemical divide in the atlantic ocean between well ventilated intermediate water and poorly ventilated deep water we suggest these changes in interbasinal and vertical gradients resulted from decreasing northern component water and reduced ventilation of southern component water scw the latter was caused by several interrelated processes in antarctic sources areas including increased sea ice cover enhanced surface water stratification decreased ekman induced upwelling and reduced vertical mixing across the thermocline because antarctic surface water processes and deepwater ventilation rates ultimately influence atmospheric co2 concentration these processes may have acted as a positive feedback that contributed to the major cooling steps in late neogene climate

abrupt transition to strong superrotation driven by equatorial wave resonance in an idealized gcm persistent superrotation is seen in the atmospheres of other terrestrial bodies venus titan but not in that of present earth which is distinguished by equatorial easterlies nevertheless superrotation has appeared in numerical simulations of earth s atmosphere from two layer models to multilevel comprehensive gcms simulations of warm climates that generate enhanced tropical convective variability seem particularly prone to superrotation which has led to hypotheses that the warmer atmospheres of the early pliocene and eocene may have been superrotating and that the phenomenon may be relevant to future climate projections this paper considers a positive feedback leading to superrotation based on an equatorial wave resonance that occurs in a westerly backgroundflow the authors present simulations with an idealized multilevel gcm forced with a zonally varying equatorial heating which show abrupt transitions to strongly superrotating states linearshallowwatertheoryisusedtoshow thatthesetransitions occur asthesuperrotating jetvelocity approaches the phase speed of free equatorial rossby wave modes leading to a resonant amplification of the response to eddy heating and its associated equatorward momentum flux the resonance and transition are most prominent in simulations where the meridional temperature gradient has been reduced and hysteresis behavior is seen when the gradient is eliminated completely no evidence is found in these simulations for the midlatitude wave feedback believed to drive abrupt transitions in two layer models and there is only a minor role for the axisymmetric feedback based on vertical advection by the hadley circulation

universality of the seismic moment frequency relation we analyze the seismic moment frequency relation in various depth ranges and for different seismic regions using flinn engdahl s regionalization of global seismicity three earthquake lists of centroid moment tensor data have been used the harvard catalog the usgs catalog and the huang et al 1997 catalog of deep earthquakes the results confirm the universality of the values and the maximum moment for shallow earthquakes in continental regions as well as at and near continental boundaries moreover we show that although fluctuations in earthquake size distribution increase with depth the values for earthquakes in the depth range of 0 500 km exhibit no statistically significant regional variations the regional variations are significant only for deep events near the 660 km boundary for declustered shallow earthquake catalogs and deeper events we show that the worldwide values have the same value of 0 60 0 02 this finding suggests that the value is a universal constant we investigate the statistical correlations between the numbers of seismic events in different depth ranges and the correlation of the tectonic deformation rate and seismic activity the number of earthquakes above a certain threshold level per year the high level of these correlations suggests that seismic activity indicates tectonic deformation rate in subduction zones combined with the universality of the value this finding implies little if any variation in maximum earthquake seismic moment among various subduction zones if we assume that earthquakes of maximum size are similar in different depth ranges and the seismic efficiency coefficient is close to 100 for shallow seismicity then we can estimate for deeper earthquakes for intermediate earthquakes 5 and 1 for deep events these results may lead to new theoretical understanding of the earthquake process and better estimates of seismic hazard

diatom δ13c δ15n and c n since the last glacial maximum in the southern ocean potential impact of species composition measurements of delta c 13 delta n 15 and c n on diatom bound organic matter were made over the holocene and last glacial maximum lgm from three sediment cores in the southern ocean one each from the atlantic indian and pacific sectors the site in the scotia sea atlantic sector differed considerably from the other two sites by having markedly lower delta c 13 more variable delta n 15 and c n ratios and a sedimentary diatom assemblage that was never dominated by fragilariopsis kerguelensis although environmental parameters certainly have a strong impact on the isotope ratios delta c 13 is also correlated to the proportion of f kerguelensis in the three cores investigated here r 2 0 8 extreme values of delta c 13 delta n 15 and c n at the last glacial maximum were also related to the abundance of winter stages of eucampia antarctica these results suggest that diatom specific isotope records should be interpreted in conjunction with information on the species composition of the samples

design of the optimal seismological network in ukraine it is necessary to have reliable data on the distributions of earthquake hypocenters in the study area to solve many geological and geophysical problems in particular the forecast of strong earthquakes seismic zoning and earthquake proof construction in turn the completeness of the data on the distribution of earthquake hypocenters and the accuracy of their determination largely depends on the effectiveness of the observing system the efficiency of the modern ukrainian network of seismological observations that consists of 28 stations is estimated in this article by the effectiveness of the seismological observation network we mean the ability of the network to record events with minimal magnitudes at certain epicentral distances and allowing us to determine its main parameters time in the focus and coordinates of hypocenters with minimal errors depending on the position of the earthquake hypocenter calculation of the minimum magnitude of earthquakes for the ukrainian seismological network shows if each seismic station increase of susceptibility to 50 000 units then the seismological the network confidently registers earthquakes with a magnitude of 3 or more throughout the ukraine the errors in the determination of the coordinates of epicenters of earthquakes in latitude km and in longitude km do not exceed 1 0 km in the center of the network and 5 0 km on the periphery of the network the values of errors in determining the depths of the earthquake h km centers in the center of the network does not exceed 5 0 km but on the whole territory of ukraine does not exceed 20 km the optimal configuration of the network of ukrainian seismic stations based on the c criterion of optimality introduced earlier to the theory design of optimal experiments by one of the authors of the article is proposed