metallogeny of the handagai skarn fe cu deposit northern great xing an range ne china constraints on fluid inclusions and skarn genesis abstract the newly discovered handagai skarn fe cu deposit is located in the northern great xing an range of ne china and is hosted by the ordovician luohe formation the orebodies that form the deposit are generally concordant with the bedding within these sediments and are spatially related to areas of skarn development the fe cu mineralization in this area records four stages of paragenesis namely prograde skarn retrograde skarn quartz sulfide and quartz carbonate stages the handagai deposit is a calcic skarn that is dominated by an andradite diopside epidote actinolite assemblage the mineralogy and geochemistry of the skarn indicate that it formed from a hydrothermal fluid that altered the carbonate units in this area to a garnet and42 95grs4 53 and pyroxene di71 78hd22 29jo0 2 bearing skarn the epidote within the skarn has an epidote end member composition with the chlorite in the skarn dominantly fe rich indicating that these minerals formed in an fe rich environment the petrographic microthermometric and raman spectroscopic analysis of fluid inclusions within garnet epidote actinolite quartz and calcite precipitated at different stages of formation of the handagai deposit indicate that mineralization related fluid inclusions are either liquid rich two phase h2o nacl type i gas rich two phase h2o nacl type ii three phase liquid vapor solid h2o nacl type iii or co2 h2o nacl inclusions type iv the early stages of mineralization are associated with all four types of inclusion whereas the later stages of mineralization are only associated with type i and ii inclusions inclusion homogenization temperatures vary between the four stages of mineralization 370 c 530 c and 600 c 210 c 290 c 190 c 270 c and 150 c 230 c from early to late respectively with salinities also varying between the earlier and later stages of mineralization 11 18 and 45 7 15 6 9 and 3 7 wt nacl equivalent equiv respectively the majority of the inclusions within the handagai deposit have homogenization temperatures and salinities of 200 c 350 c and 4 14 wt nacl equiv respectively indicating that this is a medium high temperature and medium low salinity type deposit the fluid inclusions were trapped at pressures of 11 to 72 mpa corresponding to depths of 0 4 to 2 9 km the geology mineralogy geochemistry and fluid inclusions microthermometry indicate that the handagai deposit formed as a result of contact infiltration metasomatism with the deposition of ore minerals resulting from a combination of factors that include boiling as a result of reduced pressure cooling and fluid mixing

u pb zircon and geochemical constraints on the age origin and evolution of paleozoic arc magmas in the oyu tolgoi porphyry cu au district southern mongolia abstract uranium pb zircon ages are linked with geochemical data for porphyry intrusions associated with giant porphyry cu au systems at oyu tolgoi to place those rocks within the petrochemical framework of devonian and carboniferous rocks of southern mongolia in this part of the gurvansayhan terrane within the central asian orogenic belt the transition from devonian tholeiitic marine rocks to unconformably overlying carboniferous calc alkaline subaerial to shallow marine volcanic rocks reflects volcanic arc thickening and maturation radiogenic nd and pb isotopic compositions e nd t range from 3 1 to 7 5 and 206 pb 204 pb values for feldspars range from 17 97 to 18 72 as well as low high field strength element hfse contents of most rocks mafic rocks typically have 2 are consistent with magma derivation from depleted mantle in an intra oceanic volcanic arc the late devonian and carboniferous felsic rocks are dominantly medium to high k calc alkaline and characterized by a decrease in sr y ratios through time with the carboniferous rocks being more felsic than those of devonian age porphyry cu au related intrusions were emplaced in the late devonian during the transition from tholeiitic to calc alkaline arc magmatism uranium pb zircon geochronology indicates that the late devonian pre to syn mineral quartz monzodiorite intrusions associated with the porphyry cu au deposits are 372 ma whereas granodiorite intrusions that post date major shortening and are associated with less well developed porphyry cu au mineralization are 366 ma trace element geochemistry of zircons in the late devonian intrusions associated with the porphyry cu au systems contain distinct th u and yb gd ratios as well as hf and y concentrations that reflect mixing of magma of distinct compositions these characteristics are missing in the unmineralized carboniferous intrusions high sr y and evidence for magma mixing in syn to late mineral intrusions distinguish the late devonian rocks associated with giant cu au deposits from younger magmatic suites in the district

phosphorites co rich mn nodules and fe mn crusts from galicia bank ne atlantic reflections of cenozoic tectonics and paleoceanography a wide variety of marine mineral deposits were recovered from 750 to 1400 m water depths on galicia bank iberian margin mineral deposits include 1 carbonate fluorapatite phosphorite slabs and nodules that replaced limestone and preserved original protolith fabric 2 ferromanganese vernadite crusts with high mn and fe mn fe 1 contents and thick stratabound layers consisting mainly of mn up to 27 mno and fe 15 fe2o3 which impregnated and replaced the phosphorite 3 co rich mn nodules are composed of romanechite and todorokite laminae mn rich layers up to 58 mno contain up to 1 8 co 4 goethite nodules with fe up to 67 fe2o3 have low mn and trace metals we interpret this mineralization paragenesis to be related to major changes in oceanographic and tectonic regimes three phosphatization generations formed hardgrounds dated by 87sr 86sr isotopes as late oligocene early miocene and latest early miocene during the latest early miocene the hardground was fractured and breached due to regional intraplate tectonism which was coeval with a widespread regional erosional unconformity the stratabound layers and co rich manganese nodules were derived from low temperature geothermally driven hydrothermal fluids with fluid conduits along reactivated faults during middle and late miocene the introduction of vigorous deep water flow from the arctic generated growth of hydrogenetic ferromanganese crusts finally growth of diagenetic fe rich nodules late pliocene was promoted by the introduction of hypersaline mediterranean outflow water into the atlantic ocean

formation and deformation of hyperextended rift systems insights from rift domain mapping in the bay of biscay pyrenees the bay of biscay and the pyrenees correspond to a lower cretaceous rift system including both oceanic and hyperextended rift domains the transition from preserved oceanic and rift domains in the west to their complete inversion in the east enables us to study the progressive reactivation of a hyperextended rift system we use seismic interpretation gravity inversion and field mapping to identify and map former rift domains and their subsequent reactivation we propose a new map and sections across the system illustrating the progressive integration of the rift domains into the orogen this study aims to provide insights on the formation of hyperextended rift systems and discuss their role during reactivation two spatially and temporally distinct rift systems can be distinguished the bay of biscay parentis and the pyrenean basque cantabrian rifts while the offshore bay of biscay represent a former mature oceanic domain the fossil remnants of hyperextended domains preserved onshore in the pyrenean cantabrian orogen record distributed extensional deformation partitioned between strongly segmented rift basins reactivation initiated in the exhumed mantle domain before it affected the hyperthinned domain both domains accommodated most of the shortening the final architecture of the orogen is acquired once the conjugate necking domains became involved in collisional processes the complex 3 d architecture of the initial rift system may partly explain the heterogeneous reactivation of the overall system these results have important implications for the formation and reactivation of hyperextended rift systems and for the restoration of the bay of biscay and pyrenean domains

the transition from an active to a passive margin sw end of the south shetland trench antarctic peninsula abstract the lateral ending of the south shetland trench is analysed on the basis of swath bathymetry and multichannel seismic profiles in order to establish the tectonic and stratigraphic features of the transition from an northeastward active to a southwestward passive margin style this trench is associated with a lithospheric scale thrust accommodating the internal deformation in the antarctic plate and its lateral end represents the tip line of this thrust the evolutionary model deduced from the structures and the stratigraphic record includes a first stage with a compressional deformation predating the end of the subduction in the southwestern part of the study area that produced reverse faults in the oceanic crust during the tortonian the second stage occurred during the messinian and includes distributed compressional deformation around the tip line of the basal detachment originating a high at the base of the slope and the collapse of the now inactive accretionary prism of the passive margin the initial subduction of the high at the base of the slope induced the deformation of the accretionary prism and the formation of another high in the shelf the shelf transition high the third stage from the early pliocene to the present day includes the active compressional deformation of the shelf and the base of slope around the tip line of the basal detachment while extensional deformations are active in the outer swell of the trench

the origin and evolution of skarn forming fluids from the phu lon deposit northern loei fold belt thailand evidence from fluid inclusion and sulfur isotope studies abstract the phu lon skarn cu au deposit is located in the northern loei fold belt lfb thailand it is hosted by devonian volcano sedimentary sequences intercalated with limestone and marble units intruded by diorite and quartz monzonite porphyries phu lon is a calcic skarn with both endoskarn and exoskarn facies in both skarn facies andradite and diopside comprise the main prograde skarn minerals whereas epidote chlorite tremolite actinolite and calcite are the principal retrograde skarn minerals four types of fluid inclusions in garnet were distinguished 1 liquid rich inclusions 2 daughter mineral bearing inclusions 3 salt saturated inclusions and 4 vapor rich inclusions epidote contains only one type of fluid inclusion liquid rich inclusions fluid inclusions associated with garnet prograde skarn stage display high homogenization temperatures and moderate salinities 421 6 468 5 c 17 4 23 1 wt nacl equiv by contrast fluid inclusions associated with epidote retrograde skarn stage record lower homogenization temperatures and salinities 350 9 399 8 c 0 5 8 wt nacl equiv these data suggest a possible mixing of saline magmatic fluids with external dilute fluid sources e g meteoric fluids as the system cooled some fluid inclusions in garnet contain hematite daughters suggesting an oxidizing magmatic environment sulfur isotope determinations on sulfide minerals from both the prograde and retrograde stages show a uniform and narrow range of 34 s values 2 6 to 1 1 34 s suggesting that the ore forming fluid contained sulfur of orthomagmatic origin overall the phu lon deposit is interpreted as an oxidized cu au skarn based on the mineralogy and fluid inclusion characteristics

re os ages for the erdenet and tsagaan suvarga porphyry cu mo deposits mongolia and tectonic implications the erdenet and tsagaan suvarga deposits are the two largest known porphyry cu mo deposits in mongolia replicate re os analyses of molybdenite from these deposits yield ages of 240 7 0 8 and 240 4 0 8 ma for erdenet and 370 1 1 2 and 370 6 1 2 ma for tsagaan suvarga 2 errors the re os age of erdenet is significantly older and that of tsagaan suvarga is slightly older than published 40ar 39ar ages for sericite associated with mineralization in these deposits 207 4 5 0 and 364 9 7 0 ma respectively these re os results suggest that in the hydrothermal environment 40ar 39ar ages may be partly to significantly reset whereas re os ages record and maintain the age of primary mineralization events these re os ages indicate that porphyry mineralization at erdenet and tsagaan suvarga are related to porphyritic intrusions representing the youngest event during regional magmatism in northern and southern mongolia respectively the re os age of erdenet marks the final stage of arc magmatism in northern mongolia followed by late permian collision between the mongolian north china and siberian blocks the re os age of tsagaan suvarga indicates that devonian arc magmatism in southern mongolia was active at the present latitude of 44 n at least until 370 ma

factors controlling copper solubility and chalcopyrite deposition in the sungun porphyry copper deposit iran the sungun porphyry copper deposit is hosted in a diorite granodioritic to quartz monzonitic stock that intruded eocene volcanosedimentary and cretaceous carbonate rocks copper mineralization is associated mainly with potassic alteration and to a lesser extent with sericitic alteration based on previously published fluid inclusion and isotopic data by hezarkhani and williams jones most of the copper is interpreted to have deposited during the waning stages of orthomagmatic hydrothermal activity at temperatures of 400 to 300 c these data also indicate that the hydrothermal system involved meteoric waters and boiled extensively in this work thermodynamic data are used to delineate the stability fields of alteration and ore assemblages as a function of fs2 fo2 and ph the solubility of chalcopyrite was evaluated in this range of conditions using recently published experimental data during early potassic alteration 450 c copper solubility is calculated to have been 50 000 ppm whereas the copper content of the initial fluid responsible for ore deposition is estimated from fluid inclusion data to have been 1200 3800 ppm this indicates that initially the fluid was highly undersaturated with respect to chalcopyrite which agrees with the observation that veins formed at t 400 c contain molybdenite but rarely chalcopyrite copper solubility drops rapidly with decreasing temperature and at 400 c is approximately 1000 ppm within the range estimated from fluid inclusion data whereas at 350 c it is only 25 ppm these calculations are consistent with observations that the bulk of the chalcopyrite deposited at sungun is hosted by veins formed at temperatures of 360 60 c other factors that in principle may reduce chalcopyrite solubility are increases in ph and decreases in fo2 and acl our analysis shows however that most of the change in ph occurred at high temperature when chalcopyrite was grossly undersaturated in the fluid and that the direction of change in fo2 increased chalcopyrite solubility we propose that the sungun deposit formed mainly in response to the sharp temperature decrease that accompanied boiling and partly as a result of the additional heat loss and decrease in acl which occurred as a result of mixing of acidic cu bearing magmatic waters with cooler meteoric waters of lower salinity

morphostructure of the galicia continental margin and adjacent deep ocean floor from hyperextended rifted to convergent margin styles abstract a joint study and mapping of the morphological features and architecture of the galicia margin based on high resolution multibeam bathymetry data and multichannel seismic profiles provides new insights of the margin morphostructure tectonic processes are the major control of the margin s morphology where the imprint of the north atlantic rifting and opening and later subduction of the bay of biscay and compressional events are still well preserved the west galicia margin which is up to 350 km wide is composed from east to the west of inner transitional and outer sectors the inner sector shows a graded upper slope strongly dissected by a system of submarine canyons and valleys that flow into the 170 km long and 40 60 km wide nw se valle inclan valley the transitional sector which is up to 75 km wide displays a smooth relief dominated by landslides and giant craters finally the outer sector is characterised by several banks n s sub parallel ridges and elongated valleys that project seaward over 200 km i e galicia bank half graben deep galicia margin and peridotite ridge domains the north galicia margin is characterised by a system of terraces up to 30 km wide that form a stepped slope followed by an abrupt lower slope affected by large scale rotational failures the galicia margin constitutes an exceptional area within the atlantic margins for identifying different morphostructure styles that characterised the main stages of the margin s evolution along the wilson cycle the galicia margin hosts the transition between two end members of continental margin styles a western hyperextended rifted margin being the conjugate with the newfoundland margin during the late jurassic and a northern convergent margin now fossilised associated with the partial subduction of the southern sector of the bay of biscay underneath the north iberian margin which occurred in paleocene eocene times thus the morphostructure of the west galicia margin still reflects the detached fault systems and tilted blocks that resulted from the mesozoic north atlantic rifting furthermore the coruna and jean charcot seamounts which are adjacent to the galicia margin correspond to spreading ridges formed by the simultaneous opening of north atlantic ocean and the bay of biscay in the upper cretaceous the rest of the terraced morphology of the north galicia margin is derived from extensional faults caused by an overriding of the iberian plate in relation to the subduction of the bay of biscay oceanic crust during cenozoic times since the late neogene compressional tectonics resulting from the reorganisation of the eurasia iberia and africa plates is also reflected on the present day morphology as the following i an elevation of the biscay abyssal plain up to 150 m over the iberia abyssal plain ii deep seated landslides associated with an uplift of the galicia bank and iii an orientation of submarine canyons along nw se strike slip faults

the ocean continent boundary off the western continental margin of iberia crustal structure west of galicia bank a seismic refraction transect across the galicia bank continental margin shows that the original continental crust thins westward from 17 to 2 km immediately east of a margin parallel peridotite ridge pr immediately west of the pr oceanic crust is only 2 5 3 5 km thick but farther west oceanward it thickens to 7 km the pr caps a similar to 60 km wide lens shaped serpentinized peridotite body underlying both thinned continental and thin oceanic crust when superimposed on a reflection time version of the velocity model the s reflector is clearly intracrustal at its east end westward s cuts down to lower crustal levels eventually coinciding with the top of the serpentinized peridotite lens original crust mantle boundary these observations render almost impossible the seafloor exposure of the pr by s acting as a top to the west detachment fault numerical models of melting and borehole subsidence information constrain our rifting model the easternmost continental crust experienced a total stretching factor of 4 3 most likely in two stages it probably occurred over similar to 25 m y with the highest fate of stretching at the beginning of the main earlier rift phase valanginian 141 135 ma the 3 4 7 km thick continental crust depending on whether serpentinized peridotite is assigned to crust or mantle which may include melt products requires stretching factors 6 more than 11 7 and a rift duration of more than 25 13 m y the thin oceanic crust immediately west of the pr is explained by conductive cooling of the mantle during the long prebreakup stretching phase which temporarily caused reduced melting immediately after breakup

triple junctions of bay of biscay and north atlantic new constraints on the kinematic evolution recently surveyed triple junction trajectories in the bay of biscay and newly available magnetic maps constrain the early oceanic evolution of the north atlantic and bay of biscay from chrons m0 to a33o 118 to 80 ma the opening of the bay of biscay is of the scissors opening type with a pole of rotation located near bordeaux lat 44 6 n long 0 3 w and predicted simultaneous compression in the central and eastern pyrenees structural directions west of iberia do not fit the north america iberia motion therefore a second triple junction of the ridge ridge fault type is postulated just south of the first one which propagated north ward from a more southerly position

constraints imposed by rift inheritance on the compressional reactivation of a hyperextended margin mapping rift domains in the north iberian margin and in the cantabrian mountains the alpine pyrenean cantabrian orogen developed along the plate boundary between iberia and europe involving the inversion of mesozoic hyperextended basins along the southern biscay margin thus this margin represents a natural laboratory to analyze the control of structural rift inheritance on the compressional reactivation of a continental margin with the aim to identify former rift domains and investigate their role during the subsequent compression we performed a structural analysis of the central and western north iberian margin based on the interpretation of seismic reflection profiles and local constraints from drill hole data seismic interpretations and published seismic velocity models enabled the development of crustal thickness maps that helped to constrain further the offshore and onshore segmentation based on all these constraints we present a rift domain map across the central and western north iberian margin as far as the adjacent western cantabrian mountains furthermore we provide a first order description of the margin segmentation resulting from its polyphase tectonic evolution the most striking result is the presence of a hyperthinned domain e g asturian basin along the central continental platform that is bounded to the north by the le danois high interpreted as a rift related continental block separating two distinctive hyperextended domains from the analysis of the rift domain map and the distribution of reactivation structures we conclude that the landward limit of the necking domain and the hyperextended domains respectively guide and localize the compressional overprint the le danois block acted as a local buttress conditioning the inversion of the asturian basin

chloritization of the hydrothermally altered bedrock at the igarape bahia gold deposit carajas brazil the igarape bahia gold deposit has developed from weathering of a near vertical hydrothermal cu au mineralization zone the unweathered bedrock composed of chlorite schists is mainly metamorphosed basalts pyroclastic and clastic sedimentary rocks and iron formation contents and fe fe mg ratios of chlorites increase from distal country rock towards the mineralization zone which can be attributed to different water rock ratios and locations in a hydrothermal system in the hydrothermal system high salinity fluids convected through basin floor rocks stripping metals from the recharge zones with precipitation in discharge zones the chlorite with lower fe fe mg ratios indicates alteration by relatively unreacted mg rich fluids occurring within recharge zones by contrast the chlorite with higher fe fe mg ratios in the mineralization zone formed from solutions rich in fe mn au cu h2s and sio2 within a discharge zone the iron formation could also be formed within the discharge zone or on the basin floor from the fe rich fluids the distal country rock with less chlorite content is a hydrothermal product at low water rock ratios whereas the proximal country rock and the host rock with more chlorite content formed at high water rock ratio conditions the al iv contents of chlorites indicate that the formation temperatures of these rocks range from 204 to 266 c with temperatures slightly increasing from distal country rock towards the mineralization zone

morphological feature analyses of the prestige half graben on the sw galicia bank abstract morphological analysis was carried out on the sw flank of the galicia bank as part of detailed geological studies of the half graben where the prestige oil tanker wreckage is located broad multibeam echosounder simrad em 12s 120 and seismic reflection airgun data were collected on board rv hesperides three groups of morphological features were identified as tectonic erosive and depositional the main tectonic morphological feature is a n s oriented fault scarp in the eastern part of the study area main erosive features are gullies slide scars e w oriented inter lobe channels and a nne ssw oriented main channel dominant depositional morphologies comprise thirteen e w oriented sedimentary wedges seven large e w to ne sw oriented sedimentary lobes and the relatively smooth sedimentary layer covering the eastern and western ridges that comprise the galicia bank s sw flank characterization classification and distribution of these features indicate that the study area constitutes a half graben structure comprising a n s oriented normal fault scarp abruptly connecting steep gradients in the eastern area with the gentle slope of the central area a thick but narrow wedge of sediment has accumulated at the foot of the scarp as a result of mass movement processes that govern the formation of a series of short lived wedges overlapping lobes and also channels this particular kind of slope apron system corresponds to a tectonic controlled drainage pattern from a sharply tilted hanging wall block supplied by sediment from the ridge finally we can conclude that the prestige stern and bow are located at the steep fault scarp close to a channel head and at the axis of inter lobe channels developed by mass movement processes thus morphologic tectonic and sedimentary factors can be considered as potential hazards

zonation patterns of skarn garnets records of hydrothermal system evolution chemically zoned skarn garnets provide a continuous record of hydrothermal processes in lower paleozoic sedimentary rocks within the contact aureole around the drammen granite in the oslo rift southern norway major and trace element zonation profiles the latter obtained using a scanning high resolution proton microprobe reveal early infiltration controlled growth of relatively grossular rich garnets the major and trace elements compositions being buffered by local mineral dissolution subsequent rapid epitaxial growth of andradite rich garnet on grossular rich cores marks the onset of vigorous and focused fluid flow along high permeability zones during this later stage the hydrothermal fluid composition was to a large extent externally controlled and the andradite precipitating from these fluids was characterized by high as and w contents the zonation patterns of the andradite rich garnets record at least five intermittent growth periods with rapid andradite precipitation from fluid batches with high f o 2 and progressively decreasing as and w contents thin layers poor in fe as and w but relatively high in al and mn represent periods of slow growth rates between the major pulses of hydrothermal fluids the marked rimward decrease in the as and w contents of the garnets may reflect influx of meteoric waters or exhaustion of these elements in the hydrothermal fluid reservoir caused by boiling controlled distillation processes at depth

geomorphology of the oceans abstract we present the first digital seafloor geomorphic features map gsfm of the global ocean the gsfm includes 131 192 separate polygons in 29 geomorphic feature categories used here to assess differences between passive and active continental margins as well as between 8 major ocean regions the arctic indian north atlantic north pacific south atlantic south pacific and the southern oceans and the mediterranean and black seas the gsfm provides quantitative assessments of differences between passive and active margins continental shelf width of passive margins 88 km is nearly three times that of active margins 31 km the average width of active slopes 36 km is less than the average width of passive margin slopes 46 km active margin slopes contain an area of 3 4 million km2 where the gradient exceeds 5 compared with 1 3 million km2 on passive margin slopes the continental rise covers 27 million km2 adjacent to passive margins and less than 2 3 million km2 adjacent to active margins examples of specific applications of the gsfm are presented to show that 1 larger rift valley segments are generally associated with slow spreading rates and smaller rift valley segments are associated with fast spreading 2 polar submarine canyons are twice the average size of non polar canyons and abyssal polar regions exhibit lower seafloor roughness than non polar regions expressed as spatially extensive fan rise and abyssal plain sediment deposits all of which are attributed here to the effects of continental glaciations and 3 recognition of seamounts as a separate category of feature from ridges results in a lower estimate of seamount number compared with estimates of previous workers

geochronology and isotopic geochemistry of the a type granites from the huanggang sn fe deposit southern great hinggan range ne china implication for their origin and tectonic setting abstract the huanggang sn fe deposit inner mongolia is located in southern great hinggan range metallogenic belt la icp ms zircon u pb dating show that the k feldspar granite and granite porphyry in the huanggang mine were formed at 136 7 1 1 ma and 136 8 0 57 ma respectively sr nd pb isotope of the rocks and in situ zircon hf isotopic systematics show that 87 sr 86 sr i values range from 0 70211 to 0 70729 close to the 87 sr 86 sr i of oceanic basalts and lower than those of continental crust the e nd t values and nd model ages t dm vary from 0 8 to 0 9 and 855 to 993 ma respectively the pb isotopic compositions are also variable with 206 pb 204 pb 207 pb 204 pb and 208 pb 204 pb values of 18 974 26 107 15 554 15 914 and 38 894 39 890 respectively suggesting that the lead is derived from a mixed source the 176 hf 177 hf values range from 0 282744 to 0 282922 with corresponding e hf t values ranging from 1 9 to 18 3 and two stage hf model ages t dm2 of between 561 and 888 ma the isotope composition shows that huanggang granites were derived from partial melting of juvenile lower crust that originated from depleted mantle perhaps contaminated by small amounts of ancient continental crust younger nd hf isotope model ages imply that an important crustal growth event took place in this area during the neoproterozoic integrating our data with previously published results and the late mesozoic regional tectonic setting we conclude that the huanggang granites were generated in an intraplate tectonic magmatic setting asthenospheric mantle upwelling due to lithospheric delamination and magma underplating caused the partial melting of a mantle wedge metasomatized by the fluids released from subducted oceanic crust or by decompression of depleted mantle this resulted in remelting differentiation and a continued evolution of the mafic juvenile crust producing a large quantity of granitic magma the tectonic setting for these processes may be linked to the nnw subduction of the pacific plate izanagi in the mesozoic which affected most of eastern china

composition and evolution of ore fluids in a magmatic hydrothermal skarn deposit the chemistry of brine vapor and low salinity fluid inclusions measured by proton induced x ray emission from the bismark skarn deposit mexico is consistent with an evolving magmatic hydrothermal system with no evidence for external fluid inputs the results support a model that invokes early phase separation of magmatic fluids into brine and vapor two phase field at high temperature and lithostatic pressure followed by the entrapment of a low salinity magmatic fluid one phase field at lower temperature and hydrostatic pressure the early brine and vapor inclusions contain high pb and zn concentrations and low cu however the vapor contains significantly more cu than the brine and was likely transported as a sulfur complex the fluid phase changes observed and behavior of cu are comparable to those of porphyry cu systems the later low salinity fluid at bismark represents a distinct pulse of magmatic fluid with a high k ca ratio in which base metals including cu were transported by chloride complexes paragenetic relationships and variations in the relative concentrations of cu pb and zn suggest that this fluid was primarily responsible for ore deposition the relative cu pb and zn concentrations in fluid inclusions at bismark are consistent with those measured from base metal ores in high temperature carbonate replacement deposits throughout mexico and suggest that the bulk metal budget of these deposits is primarily controlled by magmatic hydrothermal fluids deficient in cu

seismic image of the cantabrian mountains in the western extension of the pyrenees from integrated escin reflection and refraction data abstract integrated analysis of normal incidence and large aperture seismic reflection data collected in 1992 and 1993 within the spanish escin and complementary projects provide a first complete n s crustal transect across the northern iberian peninsula and continental margin images of the crustal structure of the cantabrian mountains and their transition to the duero basin and to the cantabrian margin are obtained from a a 65 km long vertical reflection profile escin 2 on land b a 200 km long reversed refraction profile and c wide angle recordings of the marine escin 4 profile consistent results between reflectivity pattern and velocity depth distribution reveal important lateral variations in the deep structure the reflective crust imaged in the escin 2 profile changes its attitude from sub horizontal beneath the duero basin to north dipping beyond the mountain front basement thrusts are observed in the upper crust merging into a detachment at 6 s twt and may have triggered the alpine uplift of the range the moho is identified at the bottom of the reflective lower crust and deepens from 12 to 15 s at the northern end of the profile about 35 km inland modelling of the refraction data laterally extends the seismic image and provides evidence for variscan crustal features beneath the duero basin northwards the velocity in the lower crust decreases and the moho constrained by the wide angle data from profile escin 2 deepens to about 60 km ending abruptly at the shoreline the velocity depth model is constrained along the asturian platform up to the continental slope where the crust mantle boundary is located at 24 km depth this margin moho shows a progressive deepening southwards and extends to the coast where it is found at 30 km depth the present seismic data support an important alpine reworking and thickening of the crust under the cantabrian mountains the onshore offshore transition is marked by an imbrication of two crusts of very different thicknesses this signature offers a strong parallelism with the one previously observed further east across the pyrenees in the ecors seismic profile

geochemistry mineralogy and genesis of the ayazmant fe cu skarn deposit in ayvalik balikesir turkey abstract the ayazmant fe cu skarn deposit is located approximately 20 km se of ayvalik or 140 km n of izmir in western turkey the skarn occurs at the contact between metapelites and the metabasites of the early triassic kinik formation and the porphyritic hypabyssal intrusive rocks of the late oligocene kozak intrusive complex the major trace and rare earth element geochemical analysis of the igneous rocks indicate that they are i type subalkaline calc alkaline metaluminous i type products of a high level magma chamber generated in a continental arc setting the 40 ar 39 ar isochron age obtained from biotite of hornfels is 20 3 0 1 ma probably reflecting the age of metamorphic bimetasomatic alteration which commenced shortly after intrusion into impure carbonates three stages of skarn formation and ore development are recognized 1 early skarn stage stage i consisting mainly of garnet with grossular rich gr 75 79 cores and andradite rich gr 36 38 rims diopside di 94 97 scapolite and magnetite 2 sulfide rich skarn stage ii dominated by chalcopyrite with magnetite andraditic garnet ad 84 89 diopside di 65 75 and actinolite and 3 retrograde alteration stage iii dominated by actinolite epidote orthoclase phlogopite and chlorite in which sulfides are the main ore phases 40 ar 39 ar age data indicate that potassic alteration synchronous or postdating magnetite pyroxene amphibole skarn occurred at 20 0 0 1 ma the high pyroxene garnet ratio plus the presence of scapolite in calc silicate and associated ore paragenesis characterized by magnetite hematite chalcopyrite and bornite suggests that the bulk of the ayazmant skarns were formed under oxidized conditions oxygen isotope compositions of pyroxene magnetite and garnet of prograde skarn alteration indicate a magmatic fluid with 18 o values between 5 4 and 9 5 on the basis of oxygen isotope data from mineral pairs the early stage of prograde skarn formation is characterized by pyroxene di 94 97 magnetite assemblage formed at an upper temperature limit of 576 c the lower temperature limit for magnetite precipitation is estimated below 300 c on the basis of magnetite calcite pairs either as fracture fillings or massive ore in recrystallized limestone marble the sulfide assemblage is dominated by chalcopyrite with subordinate molybdenite pyrite cubanite bornite pyrrhotite galena sphalerite and idaite gold copper mineralization formed adjacent to andradite dominated skarn which occurs in close proximity to the intrusion contacts native gold and electrum are most abundant in sulfides as fine grained inclusions grain size with varying from 5 to 20 m sulfur isotope compositions obtained from pyrrhotite pyrite chalcopyrite sphalerite and galena form a narrow range between 4 8 and 1 6 suggesting the sulfur was probably mantle derived or leached from magmatic rocks geochemical data from ayazmant shows that cu is strongly associated with au bi te se cd zn pb ni and co the ayazmant mineralizing system possesses all the ingredients of a skarn system either cogenetic with or formed prior to a porphyry cu au mo system the results of this study indicate that the aegean region of turkey has considerable exploration potential for both porphyry related skarns and porphyry cu and au mineralization

mesozoic metallogeny in east china and corresponding geodynamic settings an introduction to the special issue abstract the giant east china mesozoic metallogenic province hosts some of the world s largest resources of tungsten tin molybdenum antimony and bismuth ores of gold silver mercury lead zinc copper uranium and iron are also of major importance the province and its constituent metallogenic belts or regions south china middle lower yangtze river valley east qinling dabie interior of north china craton yan liao and north east china are the products of several pulses of igneous activity and mineralisation between 240 and 80 ma each successive stage has produced a distinctive suite of deposits that can be readily related to the geodynamic evolution of the region during the mesozoic this geodynamic evolution is linked to a complex series of tectonic events involving far field subduction plate collisions crustal thickening post collision collapse and rifting

oceanic density fronts steering bottom current induced sedimentation deduced from a 50 ka contourite drift record and numerical modeling off nw spain abstract how the various bottom near hydrographic and sedimentary processes control the formation of contourite drifts i e of bottom current related confined deep sea depocenters usually remains widely speculative this study uses a transect of six sediment cores and a sediment echosounder profile across a whole contourite system off nw spain to address the sediment dynamics responsible for the depositional pattern this mounded patch type contourite drift 18 km long 20 km wide with a 150 m deep channel moat has formed around an 800 m high structural obstacle deposition on the contourite drift in the past was characterized by alternating calm and high energy bottom flow conditions calm conditions last glacial period 27 17 cal ka bp late holocene times process based numerical modeling demonstrates that pulse like oceanic density fronts traveling within the transition zone of two water masses labrador sea water mediterranean outflow water provide a powerful mechanism for contouritic deposition rather than the core of a water mass itself these gravity driven density fronts lead to local re suspension of sands stored inside the drift s moat and to subsequent upward transport towards the drift s crest here the oceanic density fronts produce additional km scale eddies these migrating eddies provide an efficient mechanism for further widespread sediment re distribution in comparison with paleoceanographic reconstructions a downward migration or expansion of the mediterranean outflow water by about 300 m led most probably to such temporary contouritic sand deposition we finally propose a conceptual model to explain how seafloor obstacles redirect and perturbate bottom currents this model proposes not only a sharp contact between two water masses but also the transition zone between those as an important high energy regime offering oceanic density fronts a travel medium these fronts are strong enough to distribute fine sands across highly pronounced seabed topography on the respective time scale the moat itself seems to act as the main source for those sands making a remote source and a long distance sediment transport unnecessary

copper mineralization around the ahar batholith north of ahar nw iran evidence for fluid evolution and the origin of the skarn ore deposit abstract this investigation presents and interprets fluid inclusion data from different lithological units of the cu skarn deposits at mazraeh north of ahar azarbaijan nw iran the results provide an assessment of the p t conditions and mineral fluid evolution and suggest new exploration parameters five types of inclusions are recognized from quartz and garnet the temperature of homogenization of type i inclusions with daughter minerals halite and sylvite ranges from 312 to 470 c with total salinity of 52 to 63 wt nacl equiv type ii and iii inclusions with halite have homogenization temperatures of 230 to 520 c and salinity of 31 to 50 wt nacl equiv the salinity of types iv and v biphase liquid vapor inclusions based on their final ice melting temperature varies between 10 2 to 20 8 wt nacl equiv t h vs salinity plots of inclusions show that the salinity of the fluids correlates positively with temperature the inclusions formed at low pressure changes in the temperature and salinity of the fluids can be reconstructed from the inclusions highly saline high temperature fluids were most abundant during the main chalcopyrite ore forming phase in the skarn and mineralized quartz veins low salinity aqueous fluids were abundant in barren veins in which there is no evidence for early hot high salinity brine and might have resulted from late stage dilution and mixing of hydrothermal fluids with meteoric water based on petrographic features and fluid inclusion data early stage magnetite deposition is related to boiling of fluid at temperatures of about 500 c at a later stage boiling at temperatures of around 320 to 400 c favored the deposition of sulfides and fe mobility was decreased at these lower temperatures the following inclusion characteristics may be used as exploration parameters in the mazraeh area i presence of high temperature salt bearing inclusions with t h between 300 and 500 c ii high salinity fluid inclusions and iii inclusions showing evidence of boiling of the fluid in addition the presence of magnetite is an important exploration parameter

initiation of an active margin at the north iberian continent ocean transition 1 the north iberian or cantabrian margin located at the southern flank of the bay of biscay underwent successive tectonic regimes of rifting passive margin and compression from mesozoic to tertiary times a complete crustal cross section of the north iberian margin from the abyssal plain to the shoreline and a reconstruction of its undeformed upper cretaceous structure are presented here it is constrained after the compilation and interpretation of different geophysical data sets recently available in the area the reflective pattern is provided by deep seismic reflection profile escin 4 complemented by commercial profiles and well information from the north iberian platform and the velocity depth control comes from an onshore offshore wide angle seismic profile tested also with gravity modeling the detailed cross section of the meso tertiary basins that fill the platform and abyssal plain shows structures from the three main tectonic events 1 normal faults and asymmetric basins from the permian to lower cretaceous extensional stage 2 upper cretaceous sediments deposited under stable conditions during the passive margin period and 3 inverted faults thrusts and folds related to the tertiary compression the deep structure of the crust beneath the margin is poorly constrained from escin 4 profile that shows reflectivity in the lower crust only at a small area under the platform however the corresponding wide angle experiment provides a conspicuous image of the moho that shows a continued deepening toward the continent on the basis of the geophysical results we propose a new model for this margin where the lower crust is detached and underthrusted to the south as a result of the partial closure of the bay of biscay an interpreted mesozoic crustal scale extensional detachment could be the weakness zone that allowed the lower crust to slide southward under the upper crust resulting in the indentation of the cantabrian margin lower crust into the iberian crust plate convergence stopped at an early stage making this a unique area to study the initial stages of deformation of a passive margin

pyrenean orogeny and plate kinematics 1 the evolution of the pyrenees a mountain range between iberia and eurasia has remained the subject of many debates between geologists and geophysicists for a long time by combining the identification of seafloor spreading anomalies a33o to m0 in the bay of biscay with those in the north atlantic we have derived a position of a mean pole of rotation for the entire opening of the bay of biscay four hundred kilometers of shortening took place between the iberian and eurasian plates in the pyrenean domain during the opening of the bay of biscay from chrons m0 to a33o time 118 to 80 ma the deep seismic etude continentale et oceanique par reflexion et refraction sismique ecors profile shot across the pyrenees and teleseismic data show the presence of two distinct slabs which dip to the north the southern slab is linked to the subduction of the neo tethys ocean which was created from late jurassic to early aptian simultaneously elongated back arc basins formed along the future pyrenean domain this slab was active from at least 118 ma early aptian to 100 ma late albian the northern slab active since 85 ma is linked to the subduction of the lower continental crust located south of the pyrenean domain in the upper crust normal faults as well as the north pyrenean fault became reverse faults and former back arc basins were inverted giving rise to the uplift of the pyrenees as a double asymmetrical wedge

pyroxene composition as an indicator in the classification of skarn deposits the chemical compositions of pyroxenes from 46 skarn deposits in japan were statistically examined after compiling published and newly analyzed compositional data in order to put constraints on skarn metallogeny the mn fe ratio and zn content of pyroxene in each deposit are relatively constant and tend to vary regionally in accordance with metal type most pyroxenes of cu fe deposits are characterized by a low mn fe ratio 0 2 and a high zn content 200 ppm pyroxenes of w deposits have an intermediate mn fe ratio around 0 15 and a very high zn content especially those of w sn f deposits 500 ppm the systematic relation between the pyroxene composition and the metal type extends to the mn fe ratio and cd content of skarn sphalerites these compositional features of pyroxenes and sphalerites seem to indicate that the proportion of fe mn zn and cd contents in hydrothermal fluids did not change significantly from the time of pyroxene formation to the period of the later sulfide deposition on the scale of the deposit the mn fe ratio and zn content of skarn pyroxene can serve as an additional aid in the classification and defining of the environment of skarn formation

the formation of passive margins constraints from the crustal structure and segmentation of the deep galicia margin spain the crustal structure of the mesozoic deep galicia margin and adjacent ocean continent boundary ocb was investigated by seismic reflection including pre stack depth migration and attenuation of seismic waves with time the seismic data were calibrated using numerous geological samples recovered by drilling and or by diving with submersible the n s trending margin and ocb are divided in two distinct segments by ne sw synrift transverse faults locally reactivated and inverted by cenozoic tectonics the transverse faulting and ocb segmentation result from crustal stretching probably in a ne sw direction during the rifting stage of the margin in early cretaceous times the cenozoic tectonics are related to iberia eurasia convergence in palaeogene times pyrenean event in both segments of the deep margin the seismic crust is made of four horizontal layers 1 two sedimentary layers corresponding to post and syn rift sequences where velocity ranges from 1 9 to 3 5 km s 1 and where the q factor is low the two sedimentary layers being separated by a strong reflector marking the break up unconformity 2 a faulted layer where velocity ranges from 4 0 to 5 2 km s 1 and where the q factor is high this layer corresponds to the margin tilted blocks where continental basement and lithified pre rift sediments were sampled 3 the lower seismic crust where the velocity 7 km s 1 and more and the q factor are the highest this layer probably made of partly serpentinized peridotite is roofed by a strong s s seismic reflector and resting on a scattering poorly reflective moho a composite model based both on analogue modelling of lithosphere stretching and on available structural data accounts for the present structure of the margin and ocb stretching and thinning of the lithosphere are accommodated by boudinage of the brittle levels upper crust and uppermost mantle and by simple shear in the ductile levels lower crust and upper lithospheric mantle two main conjugate shear zones may account for the observations and seismic data one sz1 located in the lower ductile continental crust is synthetic to the tilting sense of the margin crustal blocks another sz2 located in the ductile mantle accounts for the deformation of mantle terranes and their final unroofing and exposure at the continental rift axis now the ocb the s s reflector is interpreted as the seismic signature of the tectonic contact between crustal terranes and mantle rocks partly transformed into serpentinite by syn rift hydrothermal activity it is probably related to both shear zones sz1 and sz2 the seismic moho is lower within the lithosphere at the fresh serpentinized peridotite boundary

re os sulfide chalcopyrite pyrite and molybdenite systematics and fluid inclusion study of the duobaoshan porphyry cu mo deposit heilongjiang province china abstract the duobaoshan porphyry deposit located in the northwestern part of the lesser hinggan range is one of the biggest porphyry cu mo deposits in the central asian orogenic belt in china the duobaoshan porphyry deposit occurs in granodiorite and volcanic rocks of the middle ordovician duobaoshan formation six types of veins have been identified in three ore forming stages as follows a quartz potassic feldspar vein in the early ore forming stage an early stage quartz molybdenite vein late stage quartz molybdenite and quartz chalcopyrite pyrite veins in the middle ore forming stage and quartz pyrite and calcite quartz veins in the late ore forming stage the following four types of fluid inclusions are distinguished from various quartz veins two phase aqueous pure gas phase co 2 bearing and daughter mineral bearing inclusions the ore forming fluid for the early ore forming stage belongs to the h 2 o co 2 nacl system which is characterized by high temperatures 550 c intermediate salinities 16 2 18 1 wt nacl eqv and high co 2 content the ore forming fluid from the middle ore forming stage evolved to the h 2 o co 2 nacl system which is characterized by intermediate to high temperatures 230 450 c and high low salinities 0 8 to 65 3 wt nacl eqv and is also rich in co 2 and metals the ore forming fluid finally reached cool temperatures 110 200 c low salinities 3 9 8 4 wt nacl eqv and was co 2 poor intensive fluid immiscibility or boiling occurred when the ore forming fluid with temperatures of 230 450 c and pressures of 10 41 mpa ascended to 4 1 km inducing the escape of co 2 depressing the solubility of fluid and depositing abundant metal sulfides the total re and os concentrations of chalcopyrite and pyrite range from 0 15 to 2 95 g g and 0 74 to 15 01 ng g respectively analyses of seven chalcopyrite and pyrite samples yielded isochron ages of 482 486 ma and the model age of one molybdenite sample is 485 6 3 7 ma the mineralization age of the duobaoshan deposit is between 482 and 486 ma and mantle fluid and materials were involved in the mineralization process the duobaoshan deposit is a classic porphyry cu mo deposit that formed in an early palaeozoic island arc tectonic setting

structure and evolution of the galicia interior basin atlantic western iberian continental margin abstract an industrial multichannel seismic reflection data set is presented on the galicia interior basin g i b a sedimentary basin that has been poorly studied until now seismic stratigraphic units defined in other areas of the western iberian continental margin as well as some deeper reflections can also be identified within this basin although they show some particular characteristics the g i b is bounded to the east by a major fault identified beneath the continental shelf and to the west by an alignment of highs western banks the structural framework of the area consists of nnw sse trending normal faults cross cut by ne sw transfer faults the inception of the g i b probably ocurred during triassic times within the late jurassic early cretaceous rifting phase it probably experienced several extensional episodes the most intense one being during valanginian times evidence for compressional tectonic activity in this basin during cenozoic times has also been found when comparing the g i b with the adjacent deep galicia margin a gap in the timing of the main extensional events as well as some differences in the structural styles have been found in a wider regional context an integration of data about the timing of the processes of continental rifting and oceanic spreading along the whole western iberian margin is consistent with a northward propagating rift for the late jurassic early cretaceous phase

hydrothermal evolution of the sar cheshmeh porphyry cu mo deposit iran evidence from fluid inclusions abstract the sar cheshmeh porphyry cu mo deposit is located in southwestern iran 65 km southwest of kerman city and is associated with a composite miocene stock ranging in composition from diorite through granodiorite to quartz monzonite field observations and petrographic studies demonstrate that the emplacement of the sar cheshmeh stock took place in several pulses each with associated hydrothermal activity molybdenum was concentrated at a very early stage in the evolution of the hydrothermal system and copper was concentrated later four main vein groups have been identified i quartz molybdenite anhydrite k feldspar with minor pyrite chalcopyrite and bornite ii quartz chalcopyrite pyrite molybdenite calcite iii quartz pyrite calcite chalcopyrite anhydrite gypsum molybdenite iv quartz calcite gypsum pyrite dolomite early hydrothermal alteration produced a potassic assemblage orthoclase biotite in the central part of the stock propylitic alteration occurred in the peripheral parts of the stock contemporaneously with potassic alteration and phyllic alteration occurred later overprinting earlier alteration the early hydrothermal fluids are represented by high temperature 350 520 c high salinity up to 61 wt nacl equivalent liquid rich fluid inclusions and high temperature 340 570 c low salinity vapor rich inclusions these fluids are interpreted to represent an orthomagmatic fluid which cooled episodically the brines are interpreted to have caused potassic alteration and deposition of group i and ii quartz veins containing molybdenite and chalcopyrite propylitic alteration is attributed to a liquid rich lower temperature 220 310 c ca rich evolved meteoric fluid influx of meteoric water into the central part of the system and mixing with magmatic fluid produced albitization at depth and shallow phyllic alteration this influx also caused the dissolution of early formed copper sulphides and the remobilization of cu into the sericitic zone the main zone of the copper deposition in sar cheshmeh where it was redeposited in response to a decrease in temperature

mechanisms of extension at nonvolcanic margins evidence from the galicia interior basin west of iberia 1 we have studied a nonvolcanic margin the west iberia margin to understand how the mechanisms of thinning evolve with increasing extension we present a coincident prestack depth migrated seismic section and a wide angle profile across a mesozoic abandoned rift the galicia interior basin gib the data show that the basin is asymmetric with major faults dipping to the east the velocity structure at both basin flanks is different suggesting that the basin formed along a paleozoic terrain boundary the ratios of upper to lower crustal thickness and tectonic structure are used to infer the mechanisms of extension at the rift flanks stretching factor 2 the ratio is fairly constant indicating that stretching of upper and lower crust was uniform toward the center of the basin 3 5 5 5 fault block size decreases as the crust thins and faults reach progressively deeper crustal levels indicating a switch from ductile to brittle behavior of the lower crust at 3 5 faults exhume lower crustal rocks to shallow levels creating an excess of lower crust within their footwalls we infer that initially extension occurred by large scale uniform pure shear but as extension increased it switched to simple shear along deep penetrating faults as most of the crust was brittle the predominant brittle deformation might have driven small scale flow 40 km of the deepest crust to accommodate fault offsets resulting in a smooth moho topography the gib might provide a type example of nonvolcanic rifting of cold and thin crust

recent sedimentary processes in the prestige site area galicia bank nw iberian margin evidenced by high resolution marine geophysical methods an echo character analysis of the oil tanker prestige wreck area was undertaken using high resolution marine geophysical methods topas and airgun seismic reflection profiles multibeam echosounder and tobi sidescan sonar integration and comparison of the results using all these methods is presented given some practical applications for indirect near surface and seafloor interpretations ten different echo types were identified and grouped into four main classes i distinct ii indistinct iii irregular and iv hyperbolic echo character distribution enabled us to determine recent sedimentary processes in the area two major depositional systems can be found through the identification of these sedimentary processes a a slope depositional system sds located in the eastern and central area where mass movement processes are dominant and b a turbiditic main channel depositional system tds located in the western area where channel related processes are dominant both of these interact over the half graben structure of the southwestern sector of the galicia bank where the prestige wreck is located within the sds erosive and depositional mass movement processes characterised a complex depositional system erosive processes occur on the fault scarp channels head inter lobe channels and distal part of the sedimentary lobes moreover depositional processes take place on the top of the fault scarp sedimentary wedges sedimentary lobes and on the west flank of the main channel both depositional systems interact but the sds should be more active during fault scarp reactivation periods through relief rejuvenation and new exposed deposits microearthquake activity would favour the available materials being weathered eroded and transported by mass movements in such a situation the tds acts as the main collector of eroded sediment derived from the fault scarp throughout the sds being responsible for its evacuation into the iberian abyssal plain however outside of fault reactivation periods the sds is less active such as during the present situation

iib trioctahedral chlorite from the barberton greenstone belt crystal structure and rock composition constraints with implications to geothermometry iib trioctahedral chlorite in the barberton greenstone belt bgb metavolcanic rocks was formed during pervasive greenschist metamorphism the chem ical composition of the chlorite is highly variable with the fe fe mg ratio ranging from 0 12 to 0 8 among 53 samples the chemical variation of the chlorite results from the chemical diversity of the host rock especially the mgo content of the rock but major details of the variation pattern of the chlorite are due to the crystal structure of the chlorite all major cation abundances in the chlorite are strongly correlated with each other sil icon increases with mg and decreases with fe while aliv and alvi decrease with mg and increase with fe2 a complex exchange vector explains over 90 of the chlorite compositional variation mg4sife2 3alvi 1 aliv 1 which has 3 parts fe mg substitution coupled with one part tschermakite substitution this ratio is required to maintain the charge and site balances and the dimensional fit between the tetrahedral and octahedral sheets the subtle change in al substitution in chlorite implies that alvi is preferentially ordered in the m 4 site and about 84 of the alvi present is in the m 4 sites when they are nearly filled with alvi based on 47 analyzed chlorite bearing rock samples chlorite chl composition is strongly correlated with the mgo content of the host rock calculated correlation coefficients are 0 91 for sio2chl mgorock 0 87 for al2o3chl mgorock 0 89 for mgochl mgorock and 0 85 for feochl mgorock only weak correlations have been found between chlorite oxides and other oxides of rock between same oxides in chlorite and rock sio2 0 67 al2o3 0 59 feo 0 41 however mgochl is saturated at about 36 wt in rocks that have mgo above 22 wt the mgochl is about 5 wt when the host rock approaches 0 wt of mgo this implies that mg substituting into the chlorite is approximately limited to 1 5 9 2 mg atoms per formula unit and 1 0 3 2 aliv chlorite geothermometers can not be applied to all bgb samples however the empirical chlorite geothermometer based on aliv of chlorite may be applicable to chlorites formed under metamorphic conditions because it can predict the chemical composition of the chlorite from basaltic and dacitic samples in this study an estimated temperature of about 320 c for the greenschist metamorphism of the greenstone belt through this geothermometer is consistent with that obtained by other geothermometers

formation of anhydrous and hydrous skarn in cu au ore deposits by magmatic fluids most skarn ore deposits are characterized by two distinctly different alteration styles an early prograde stage with anhydrous minerals such as garnet and pyroxene forms from relatively high temperature hypersaline liquid a later retrograde stage with hydrous minerals such as epidote amphibole and chlorite plus sulfide ore minerals forms from lower temperature lower salinity fluids these two alteration stages commonly have been thought to reflect a dominance of magmatic and meteoric water respectively with relevance to the source of ore metals we report data from two different skarn systems one being part of the world s largest cu au resource stable isotope compositions of anhydrous and hydrous alteration minerals from both deposits indicate a magmatic source for both the prograde and retrograde stages 18o averages 5 0 per mil for garnet range 3 4 7 2 6 5 per mil for pyroxene 4 3 8 2 and 7 1 per mil for amphibole 4 3 8 7 the d values of late amphibole are more complex with magmatic values 77 to 78 for one deposit and both magmatic and lighter values for another deposit that could be explained either by magmatic degassing or by limited mixing with meteoric water we conclude that the differences in fluid composition prograde versus retrograde stages resulted from a magmatic fluid that intersected its solvus during the early stage creating vapor and hypersaline liquid whereas in the later stage this magmatic fluid did not intersect its solvus because it followed a different cooling path this late low salinity liquid only boiled once its vapor pressure curve was reached causing sulfide ore to precipitate during the retrograde stage

local stress fields and intraplate deformation of iberia variations in spatial and temporal interplay of regional stress sources tertiary to present deformation in the interior of the iberian peninsula reflects spatial and temporal variations of the activity of the plate boundaries local deformation patterns observed in many of the numerous intraplate tertiary basins and their borders such as the madrid basin and the sierra de altomira are at first sight incompatible with the regional stress field under which they were formed we demonstrate however that they can be explained as the effect of several stress fields that acted on the iberian peninsula from earliest tertiary onward data on local deformation can constrain both magnitudes and directions of forces acting on the plate boundaries of iberia enabling us to estimate the relative importance of the different plate driving and deforming mechanisms providing further constraints on the tectonic evolution of iberia

subduction related structures in the north iberian margin the oblique convergence of eurasia and iberia since the early cretaceous caused the formation of the pyrenean intracontinental collisional orogen in the east and progressed to continent ocean collision with subduction of the bay of biscay oceanic crust beneath the north iberian margin in the west two deep multichannel seismic profiles iam 12 and escin 4 integrated with gravity modeling and other geological and geophysical data provide the crustal scale architecture of this margin and its tectonic evolution during the convergence the north iberian margin is modeled with a south or south southeast dipping oceanic crust beneath the outer part of the continental shelf mesozoic basins on the shelf were inverted during the tertiary and compressional activity continued until recent times in the escin 4 section while a shallower probably neogene age basin is subjected to active recent erosion in the iam 12 section in the oceanic areas a marginal trough deepens and widens toward the east as a result of the regional east dip of the oceanic basement the accretionary prism increases in size from west to east 18 56 km and its internal structure and morphology varies along strike the prism is buried by postcorivergence sediments in both sections and in the iam 12 section appears to have been active at least during lutetian to burdigalian times the crustal scale structure of the north iberian margin is that of an arrested subduction zone in which a remnant oceanic basin was being consumed near two continental plates that collided obliquely

geochronology and geochemistry constraints of the early cretaceous taibudai porphyry cu deposit northeast china and its tectonic significance abstract the southern great xing an range sgxr located in the southeastern part of inner mongolia china shows intense mesozoic tectono magmatic activity and hosts economically important polymetallic cu pb zn sn fe ag au mo mineralization here we present new zircon u pb ages whole rock geochemical data nd sr hf isotopic data and re os ages for the taibudai deposit in the sgxr the taibudai granitoids show high sio2 70 62 72 13 wt and alkali na2o k2o 7 04 8 60 wt concentrations low mgo 0 89 1 37 wt and al2o3 14 wt asi ratios

the s reflector west of galicia spain evidence from prestack depth migration for detachment faulting during continental breakup the mechanism of continental extension and breakup and the role of detachment faults in these processes are currently the subject of intense debate one possible detachment fault is the s reflector imaged as an undulating in time locally discontinuous reflection on existing seismic profiles west of iberia here we present new images in depth of the four margin normal profiles across the west galicia rifted margin where the s reflector was originally defined and is best imaged it is shown that faults bounding wedge shaped units of late synrift sediments which hence were active during rifting immediately prior to breakup appear to detach at shallow levels onto the s reflector s itself appears as a continuous locally domal feature and does not generally appear offset the waveform of s is compatible with a reflection from a single interface such as a sharp tectonic boundary the depth sections show that s was active at 1 3 km below the seafloor during final rifting s is interpreted as a brittle detachment fault which controlled the final breakup of the continent west of galicia furthermore the data provide constraints on the sense of shear of s analogy with detachment terranes the present synrift and structural dips of s and the identification of a breakaway to s imply that s accommodated top to the west shear toward the east of the profiles s becomes more complex possibly because of different phases of detachment faulting and the development of both incisement and excisement structures from the geometry of wedge shaped sedimentary units deposited during faulting above s it also appears that s was active at an angle of 20 or less and hence may be considered a genuine low angle normal fault

a multi parameter field monitoring system to investigate the dynamics of large earth slides earth flows in the northern apennines italy abstract large earth slides and rocks lides evolving into earth flows are quite widespread in the northern italian apennines despite being simply referred to as landslides many of them are in fact large complexes of landslides they evolved through multiple and or successive movements undergoing partial and or total reactivations the reactivation of pre existing landslide bodies is the prevalent mechanism for the known landslide events as the historical records and the technical reports indicate landslide reactivation is indeed a relevant topic from the perspective of risk assessment and mitigation a multi parameter monitoring system was installed on a large complex of landslides that underwent partial or total reactivations after heavy rainfall events causing damages to buildings and infrastructures two clusters of automatic piezometers each coupled with an inclinometer and a time lapse resistivity deployment were the core of the monitoring system a weather station collecting data from subsurface thermometers and a water content probe completed the system after the construction of a new geological model of the slope this study aimed at understanding the possible mechanisms leading to the reactivation of the landslide this goal was achieved by gaining insights into the process of rainfall infiltration into the landslide deposits by determining the groundwater flow and evaluating the landslide displacements the monitoring system captured the processes that took place in the landslide bodies and the bedrock in response to a rainfall event in early february 2017 which followed a dry period of eight months the recorded data provided indications on the variation of the hydraulic head in the groundwater within the landslide and the bedrock particularly at the sliding surfaces the electrical conductivity of the groundwater and the resistivity of the terrain varied across the failure surfaces in particular a sudden increase in the electrical conductivity was related to the locations of the main sliding surfaces the joint analysis of time lapse resistivity hydraulic heads and groundwater electrical conductivity helped identify the locations of weaker levels within the landslide masses which were confirmed by data from inclinometers this study improved the knowledge of the hydrogeological behaviour of a complex of landslides in heterogeneous low permeability media moreover the obtained results contributed to the understanding of the role played by different portions of the landslide complex in the evolution of the movement

macflincor and its application to fluids in archean lode gold deposits abstract macflincor was developed to process laboratory data gathered on fluid inclusions and to calculate isochores for geologically important fluids composed of h2o c02 ch4 nacl and n2 within the program interactive diagrams are available to describe those chemical systems which cannot be adequately constrained numerically the user can choose from various published equations of state describing fluid behavior and can easily compare the results obtained by using different equations the program once the basic fluid parameters have been established allows the data to be used to determine the p t trapping conditions to evaluate possible pressure corrections and to compare different depths of formation based on the pressure calculations and given geothermal gradients for illustrative purposes macflincor has been utilized here to constrain different physical chemical parameters of fluid inclusions trapped in ore related quartz veins and breccias of archean lode gold deposits in western australia inferred pressures from individual deposits show a wide range of values which may be due to post entrapment modifications and or observational uncertainties including estimation of liquid vapor ratios

evidence for active subduction beneath gibraltar we report on a marine seismic survey that images an active accretionary wedge west of gibraltar ramp thrusts offset the seafloor and sole out to an east dipping decollement indicating ongoing westward vergent tectonic shortening new traveltime tomographic re sults image a slab of oceanic lithosphere descending from the atlantic domain of the gulf of cadiz passing through intermediate depth 60 120 km seismicity beneath the west ernmost alboran sea and merging with a region of deep focus earthquakes 600 660 km below granada spain together these new data provide compelling evidence for an active east dipping subduction zone

tectonosedimentary evolution of the deep iberia newfoundland margins evidence for a complex breakup history most of the conceptual ideas concerning sedimentary architecture and tectonic evolution of deep rifted margins are based on either intracontinental rift basins or proximal margins both of which underwent only small amounts of crustal thinning in this paper we investigate the tectonosedimentary and morphotectonic evolution related to continental breakup of the highly extended deep iberia newfoundland margins our results show that continental breakup is a complex process distributed in time and space on the basis of mapping of dated seismic units and borehole data we are able to identify two major phases of extension during a first phase dated as tithonian to barremian 145 128 ma deformation is related to exhumation of mantle rocks basins become younger oceanward and fault geometry changes from upward to downward concave resulting in complex sedimentary structures and basin geometries a second phase dated as latest aptian 112 ma overprints previously exhumed mantle and accreted juvenile oceanic crust over more than 200 km leading to the formation of basement highs the observed complex breakup history challenges classical concepts of rifting and leads to new interpretations for the tectonosedimentary evolution of deep rifted margins

structural comparison of archetypal atlantic rifted margins a review of observations and concepts abstract in this study we compare three pairs of conjugate rifted margins that are often referred to as archetypes of rift systems despite numerous differences a remarkable first order structural similarity appears between the magma poor iberia newfoundland the magma rich mid norway east greenland and the sediment rich angola brazil rifted margins typical is the seaward arrangement of distinct domains proximal necking distal and outer that each present specific comparable structural characteristics our study also suggests that magma rich systems may go through a stage of hyper extension indicating that extreme crustal thinning does not preclude a magmatic breakup in this contribution we clarify the definition of a number of terms introduced recently in rifted margin studies we review the major features constitutive of these key referenced systems discuss their similarities and differences and examine how the related deformation modes develop in the life cycle of a rift that goes to seafloor spreading we conclude that the distinct domains observed in the margin architecture represent distinct stages in the evolution of rifted margin independently of their later evolution into magma poor or magma rich environments

are subduction zones invading the atlantic evidence from the southwest iberia margin subduction initiation at passive margins plays a central role in the plate tectonics theory however the process by which a passive margin becomes active is not well understood in this paper we use the southwest iberia margin sim in the atlantic ocean to study the process of passive margin reactivation currently there are two tectonic mechanisms operating in the sim migration of the gibraltar arc and africa eurasia convergence based on a new tectonic map we propose that a new subduction zone is forming at the sim as a result of both propagation of compressive stresses from the gibraltar arc and stresses related to the large scale africa eurasia convergence the gibraltar arc and the sim appear to be connected and have the potential to develop into a new eastern atlantic subduction system our work suggests that the formation of new subduction zones in atlantic type oceans may not require the spontaneous foundering of its passive margins instead subduction can be seen as an invasive process that propagates from ocean to ocean

precambrian crystalline basement in southern mongolia as revealed by shrimp zircon dating single zircon ages determined by ion microprobe shrimp ii for granitoid gneisses from the southern slope of the baga bogd massif gobi altai southern mongolia reveal several episodes of zircon growth ranging from late palaeoproterozoic to late cambrian the oldest events are documented by a zircon crystallization age for a gneiss protolith at 1519 11 ma and by a xenocrystic zircon from a dark grey augen gneiss yielding an age of c 1701 ma discrete igneous events are recorded in granite gneisses with protolith emplacement ages of 983 6 956 3 and 954 8 ma these ages provide the first record of early neoproterozoic magmatic activity in this region a much younger and discrete magmatic event is recorded by several dioritic to granitic orthogneisses which are tectonically interlayered with the older gneisses and have protolith emplacement ages between 502 and 498 ma these late cambrian granitoids of calc alkaline affinity are likely to have been emplaced along an active continental margin and suggest that the baga bogd precambrian crustal fragment was either docked against the southward present day coordinates growing margin of the caob or was a large enough crustal entity to develop an arc along its margin we speculate that the precambrian gneisses of this massif may be part of a crustal fragment rifted off the tarim craton

a type granites in northeastern china age and geochemical constraints on their petrogenesis abstract a type granites are widely distributed in northeastern china ne china they were emplaced during three major episodes the permian late triassic to early jurassic and early cretaceous and evolved in different tectonic regimes according to their mineralogical and geochemical characteristics two subgroups of a type granites aluminous and peralkaline can be recognized the peralkaline subgroup contains alkali mafic minerals such as riebeckite arfvedsonite and sodic pyroxene while the aluminous subgroup contains annite and fe rich calcic or sodic calcic amphibole with respect to the aluminous subgroup the peralkaline granites contain higher rb ga and total rare earth elements ree but lower mgo cao al 2 o 3 ba and sr based on the discrimination criteria of eby geology 20 1992 641 the permian and late triassic to early jurassic a type granites belong to the a 2 post orogenic type whereas the early cretaceous granites are of the a 1 anorogenic type nd isotopic compositions of these a type granites indicate their derivation from a dominantly juvenile crustal source their origin is thought to have involved partial melting of an underplated lower crustal source because the generation of a type granites requires high melting temperature we propose models involving slab break off lithospheric delamination and extension the permian a type granites have the same age range as those in eastern junggar southern mongolia and central inner mongolia they occur along a major suture and form a narrow belt between the north china and siberian cratons we suggest that their formation was associated with post collisional slab break off the late triassic to early jurassic a type granites are likely to be the product of lithospheric delamination after the final collision of the major crustal blocks in the late paleozoic to early triassic the early cretaceous a type granites have an anorogenic affinity and were possibly associated with rifting in eastern china at this time associated with the onset of paleo pacific subduction consequently we conclude that the a type granites in ne china were generated at three different times involving multiple processes operative in different tectonic environments

the betic orogen and the iberian african boundary in the gulf of cadiz geological evolution central north atlantic abstract the study of the gulf of cadiz on the basis of multichannel seismic profiles and wells illustrates the stratigraphy and tectonics the evolution of the southern iberian margins was more complex than in most north atlantic margins since it entailed several phases of rifting convergence and strike slip motions three main tectonic provinces surround the internal zones of the gibraltar arc orogenic belt these include in the iberian margin of the gulf of cadiz the flysch units of the campo de gibraltar complex the betic external zones and the neogene basins of the guadalquivir valley fault bounded blocks of flysch and subbetic units crops out over large areas of the southeastern iberian shelf the basement of the northwestern area in contrast is represented by the paleozoic rocks of the hercynian massif of iberia half graben structures determined the main structural trends of the margin during the mesozoic which were affected by inversion structures during the neogene compressional stages the mesozoic and lower cenozoic units are best observed in wells and seismic profiles from the northern area these units are either obscure below a thick olistostrome deposit or are absent in most of the rest of the gulf of cadiz seven lithoseismic units from triassic to upper oligocene and another seven neogene and quaternary units are identified based on the relationship to the depositional sequence and the emplacement of the olistostrome the first tectonic phase was characterized by a passive margin which was controlled by the development of half graben extensional structures and carbonate platforms this evolution comprises the mesozoic and early cenozoic ocean spreading in the north atlantic induced extensional tectonics which deformed the cretaceous syn tectonic post aptian deposits increased amounts of terrigenous materials were supplied to the margin from aptian to albian times controlling depositional patterns while terrigenous siliciclastic facies replaced the jurassic carbonate platforms from middle eocene to early miocene the margin was influenced by the relative motions of iberia and africa and the development of the alpine orogeny the iberian african boundary in the gulf of cadiz experienced transpression and the mesozoic basins probably underwent subduction the emplacement of an olistostrome took place in the gulf of cadiz towards the central atlantic basin plains during the tortonian the end of the olistostrome emplacement during the late miocene coincides with accelerated tectonic subsidence while thick progradational and aggradational depositional sequences were developed the occurrence of closely juxtaposed regions of compression and extension during the miocene may reflect the westwards progression of the gibraltar arc mountain front over a subducting thinned tethys crust when the motion between iberian and africa was n s to nnw sse oriented the migration of the arcuate mountain front into the eastern gulf of cadiz is attributed to a mechanism of collision induced delamination of the mantle lithosphere in contrast to the betic rif belts however there is no geophysical evidence to postulate that continental collision took place in the gulf of cadiz during the cenozoic

how to concentrate copper porphyry copper deposits which supply nearly 60 of the world9s copper form as upper crustal magmas crystallize and exsolve metal bearing hydrothermal ore fluids however few upper crustal magmas produce economic copper concentrations in her perspective cline discusses work by harris et al that examined silicate melt and fluid inclusions from the bajo de la alumbrera deposit in argentina and revealed processes that may be critical to forming economic rather than barren porphyry systems

skarns related to porphyry style mineralization at caicayen hill neuquen argentina composition and evolution of hydrothermal fluids located in the main cordillera of northwest neuquen argentina the caicayen district shares the following features with cu skarn porphyry copper deposits in other parts of south central and north america as well as asia and the south pacific 1 alteration and mineralization are related to i type magnetite series calc alkaline porphyritic sills of intermediate composition with stockwork veining brittle fracturing and brecciation these are features indicative of a relatively shallow environment of formation 500 bars 2 skarns have an oxidized mineralogy dominated by garnet ad 45 97 clinopyroxene hd 18 60 epidote and hematite magnetite 3 skarns contain up to 15 percent sulfides pyrite pyrrhotite chalcopyrite and locally are associated with distal massive magnetite and hematite lodes 4 massive silica pyrite bodies replace prograde skarn and marble 5 pyroxene skarn and silica pyrite alteration distal to the potassic core are fe and zn enriched respectively 6 mineralized igneous rocks exhibit characteristic early potassic propylitic and late phyllic alteration that in the skarns can be correlated with prograde garnet pyroxene and retrograde silica pyrite respectively and 7 cu au anomalies occur in exposures within the potassic and phyllic halos fluid inclusions from igneous rocks record multiple fluid events 1 a hypersaline inclusion population up to 67 wt nacl equiv for halite sylvite bearing inclusions 2 36 wt kcl equiv and 31 45 wt nacl equiv that homogenized by salt dissolution between 355 and 400 c interpreted to have been trapped at a lithostatic pressure of approximately 500 bars 2 a second hypersaline inclusion population that homogenized by vapor bubble disappearance at 215 to 385 c and may have been trapped at similar temperatures but lower pressures relative to the first population and 3 a population of coexisting nacl saturated inclusions average salinity of 35 wt nacl equiv and vapor rich inclusions in igneous rocks close to skarn homogenized at similar temperatures 326 360 c that may have formed from boiling of a low salinity fluid up to 8 wt nacl at hydrostatic pressures of 120 to 170 bars skarn minerals also record hypersaline fluids with similar homogenization temperatures to those measured in nearby igneous rocks but have slightly lower salinities 23 3 26 wt nacl equiv inclusions from limestone next to skarn have similar homogenization temperatures and salinities 33 wt nacl equiv to skarn and igneous rock inclusions as evidenced by boiling fluids in the phyllic zone and supercritical fluids in silica pyrite hydrostatic regime dominated during retrograde alteration of skarn and porphyry style alteration the vapor phase formed by boiling fluids in igneous rocks nearby skarn produced a vapor plume that may be responsible for retrograde alteration and also of cavernous porosity in carbonate rocks at the skarn front overall caicayen is similar to worldwide copper skarn systems emplaced at shallow levels but it lacks multiple intrusive phases and successive fluid pulses thus resulting in lower copper grades than mined in other copper skarns

the role of deep water sedimentary processes in shaping a continental margin the northwest atlantic abstract the tectonic history of a margin dictates its general shape however its geomorphology is generally transformed by deep sea sedimentary processes the objective of this study is to show the influences of turbidity currents contour currents and sediment mass failures on the geomorphology of the deep water northwestern atlantic margin nwam between blake ridge and hudson trough spanning about 32 of latitude and the shelf edge to the abyssal plain this assessment is based on new multibeam echosounder data global bathymetric models and sub surface geophysical information the deep water nwam is divided into four broad geomorphologic classifications based on their bathymetric shape graded above grade stepped and out of grade these shapes were created as a function of the balance between sediment accumulation and removal that in turn were related to sedimentary processes and slope accommodation this descriptive method of classifying continental margins while being non interpretative is more informative than the conventional continental shelf slope and rise classification and better facilitates interpretation concerning dominant sedimentary processes areas of the margin dominated by turbidity currents and slope by pass developed graded slopes if sediments did not by pass the slope due to accommodation then an above grade or stepped slope resulted geostrophic currents created sedimentary bodies of a variety of forms and positions along the nwam detached drifts form linear above grade slopes along their crests from the shelf edge to the deep basin plastered drifts formed stepped slope profiles sediment mass failure has had a variety of consequences on the margin morphology large mass failures created out of grade profiles whereas smaller mass failures tended to remain on the slope and formed above grade profiles at trough mouth fans or nearly graded profiles such as offshore cape fear

detection and mapping of cold water coral mounds and living lophelia reefs in the galicia bank atlantic nw iberia margin abstract we report for first time the occurrence of cold water coral mounds and large number of living lophelia reefs along the galicia bank atlantic nw iberian margin detection and mapping of living coral reefs and mounds have been carried out by means of multibeam bathymetry backscatter images ultra high resolution and high resolution multichannel seismic reflection data and sampling in addition profiling ctds have been made to characterise environmental conditions as temperature salinity and dissolved oxygen contents of the coral sites based on these dataset two main provinces of cold water coral mounds and reefs have been identified in the galicia bank at water depths between 620 and 1125 m the breogham mound province along the western flank of the galicia bank shows a sequence of well developed mounds composed of 1 stepped semi buried elongated mounds the tallest mounds with heights up 70 m and widths of 450 m lined up in along slope trending ridges and intercalated with upslope migrating sediment drifts at water depths from 1125 to 826 m 2 single and composite seabed mounds show heights of 10 12 m and average widths of 100 m at 825 and 780 m water depths and 3 lophelia reefs forming mini mounds 2 4 m high and 80 100 m width growing on a flat erosional surface at the summit of the bank at 780 750 m water depths otherwise the castelao mound province at the eastern flank of the bank is mainly constituted by cluster of mini mounds hosting living lophelia pertusa and madrepora oculata reefs these living reefs are detected based on ultra high resolutions parametric echosounders as mini mounds with an acoustically transparent interior otherwise semi buried and exposed mounds are mapped with a combination of multibeam and backscatter images identified by their high strength values and seabed expression we conclude that the initiation growth and distribution of cold water coral mounds on the galicia bank have been controlled by the following environmental forcing factors i water masses with a potential density resulted of the turbulent boundary between the mediterranean outflow and the intermediate atlantic water masses which allowed the transport of coral larvae along the ne atlantic margins ii the formation of a hard substrate possibly related to subsurface fluid flow necessary for the initial settle of coral larvae and iii the turbulences created by the mediterranean flow impinging the topography of the bank creating suitable currents that favour intrusion of the nutrient afflux from the atlantic mass waters to deep waters allowing to coral colonies to growth