calcareous nannofossil zonation of the jurassic cretaceous boundary interval and correlation with the geomagnetic polarity timescale abstract calcareous nannofossil stratigraphy has been investigated in six european land sections and at two deep sea drilling project sites 391c and 534a ranging from the upper kimmeridgian to the lower valanginian most of the sections contain a continuous record of the jurassic cretaceous boundary interval a time of rapid increase in nannofossil abundance and diversity and allow development of a revised nannofossil zonation scheme for this period numerous nannofossil lineages have been studied in detail and the results help to increase potential stratigraphic resolution in this interval the proposed scheme consists of six zones which are units recognizable in all sections regardless of nannofossil preservation and eleven subzones determinable in all but the most poorly preserved material thirty eight additional biohorizons are proposed based on the stratigraphy of the two dsdp sites these can be accurately established only in moderately well preserved material but spotty occurrences of these taxa in other sections may be stratigraphically useful most of the sections studied have been investigated magnetostratigraphically and the results of this study allow correlation between nannofossil zonation and the geomagnetic polarity time scale magnetostratigraphy indicates that many nannofossil events can be quite precisely determined and are not significantly time transgressive finally the magnetostratigraphic definitions of two stage boundaries are refined the kimmeridgian tithonian and berriasian valanginian boundaries are placed within chrons cm22n and cm15n respectively two new genera faviconus and umbria and seven new species are described umbria granulosa rhagodiscus nebulosus cretarhabdus octofenestratus faviconus multicolumnatus nannoconus infans nannoconus compressus and nannoconus wintereri eight subspecies and three taxonomic emendations are also described

the posidonia shale lower toarcian of sw germany an oxygen depleted ecosystem controlled by sea level and palaeoclimate abstract the lower toarcian posidonia shale is famous for its excellently preserved fossils and its high amount of organic matter up to 16 both quality of preservation and accumulation of organic matter have been explained by permanent anoxic bottom water conditions high resolution geochemical sedimentological and palaeoecological investigations of various sections of the posidonia shale in sw germany however indicate that oxygen availability was variable and ranged from short oxygenated periods to longer term anoxia the benthic macrofauna consists of nine fossil communities and was used in combination with geochemical data to reconstruct a time averaged oxygen curve anoxic conditions prevailed during the deposition of the toarcian black shales they were however punctuated by various short periods weeks to years with oxygenated bottom water conditions sedimentological e g distinctiveness of microlamination siliciclastic content and geochemical parameters e g organic matter content isotopic signatures 18o and 13c molecular redox parameters pristane phytane ratio arylisoprenoids exhibit a remarkable covariation and seem to be controlled by sea level fluctuations maximum oxygen depletion and an extreme negative shift of 13corg values 34 occurred during the early falciferum zone this is explained by the recycling of 12c enriched carbon derived from remineralization of organic matter on and within the substrate during low sea level stand and a highly elevated redox boundary including photic zone anoxia the subsequent transgression permitted enhanced water exchange with the tethyan ocean and caused improvement of living conditions at the end of the falciferum zone other important factors controlling the depositional environment are the overall palaeogeographic situation and climate the early jurassic is the latest period before break up of pangaea and probably was ruled by a strong meridional atmospheric circulation system with pronounced seasonal changes of prevailing trade and monsoon wind systems an estuarine circulation with a positive water balance and surface water with slightly reduced salinity in the summer alternated with an anti estuarine circulation and a negative water balance in the winter during the summer months a stratified water column with anoxic conditions below the halocline developed 18o data indicate low salinity in the surface water during the monsoon influenced summer high productivity was then located in the photic zone and the corresponding isotopically light 18o signal was fixed in the calcareous nannoplankton during the winter months a saline circulation system brought oxygen to the benthic environment favouring temporary benthic colonization especially during times of relative sea level high stand

middle and late jurassic radiolarian palaeoecology versus carbon isotope stratigraphy abstract jurassic radiolarians are sensitive to palaeoclimatic palaeoceanographic changes recorded by the stable carbon isotope curve carbon isotopic variations have been linked to changes in ocean structure productivity and concentrations of greenhouse gases in the atmosphere in the middle upper jurassic terminilletto section of the umbria marche sabina apennines central italy well preserved radiolarians are present in a sequence of cherty limestones interbedded with platform derived carbonates the 13 c curve in the aalenian kimmeridgian interval indicates three main positive 13 c events in the lower bajocian late bathonian lower callovian and middle oxfordian the positive 13 c shifts are correlated to increases in visible chert in the outcrop and may represent periods of increased biological productivity of surface sea water spumellaria nassellaria ratios and the fluctuations of relative abundance of selected genera tend to correlate with 13 c and chert abundance values and seem to be related to episodes of high nutrient mobilisation from the base of the bajocian the radiolarian associations show a slight tendency towards diversification coincident with increasing 13 c values in the upper part of the middle bajocian last appearances prevail over first appearances associated with the peak of the 13 c event this may indicate maximum eutrophic conditions coincident with the late bathonian early callovian positive 13 c shift the radiolarian associations record a different trend with respect to the bajocian event when the 13 c values are increasing to a maximum radiolarian associations tend to be reduced in species diversity followed by a small diversification trend when the 13 c values are decreasing we speculate that during the callovian a more stressful palaeoenvironment due to high level of eutrophication is indicated by the combination of high productivity of biogenic silica and low carbonate input although varying preservational conditions may have influenced the observed trends in the radiolarian associations the good correlation between changes of sedimentation patterns radiolarian assemblages and 13 c positive anomalies open interesting avenues for further investigations concerning the palaeoecology of mesozoic radiolarians

early jurassic carbon and oxygen isotope records and seawater temperature variations insights from marine carbonate and belemnite rostra pieniny klippen belt carpathians abstract new carbon and oxygen isotope records and discussion of the main variations in seawater temperature through the sinemurian aalenian of the pieniny klippen basin northern tethys ocean are presented herein comparison of the recorded changes in stable isotope compositions of bulk carbonate and belemnite rostra from an open marine environment with previously documented predominantly restricted epicontinental data enables determination of major climatic events that were most likely of worldwide extent a slight positive 13c shift is recorded in the lowermost upper pliensbachian a significant positive excursion in carbonate carbon isotope values is documented in the lower toarcian serpentinum zone furthermore the 13c values display a falling trend in the lower upper toarcian and relatively constant values in the aalenian temperatures inferred from the 18o values of well preserved belemnite rostra suggest rather cool seawater conditions 10 13 c in the pieniny klippen basin during the late sinemurian warming by 4 c in the early pliensbachian and then cooling by 8 c in the late pliensbachian the seawater temperature rose once more in the early toarcian and began to fall again during the middle toarcian in the middle late aalenian seawater temperatures oscillated between 10 and 13 c

dissociation of oceanic methane hydrate as a cause of the carbon isotope excursion at the end of the paleocene isotopic records across the latest paleocene thermal maximum lptm indicate that bottom water temperature increased by more than 4 c during a brief time interval 104 years of the latest paleocene 55 6 ma there also was a coeval 2 to 3 excursion in the 13c of the ocean atmosphere inorganic carbon reservoir given the large mass of this reservoir a rapid 13c shift of this magnitude is difficult to explain within the context of conventional hypotheses for changing the mean carbon isotope composition of the ocean and atmosphere however a direct consequence of warming bottom water temperature from 11 to 15 c over 104 years would be a significant change in sediment thermal gradients and dissociation of oceanic ch4 hydrate at locations with intermediate water depths in terms of the present day oceanic ch4 hydrate reservoir thermal dissociation of oceanic ch4 hydrate during the lptm could have released greater than 1 1 to 2 1 1018 g of carbon with a 13c of approximately 60 the release and subsequent oxidation of this amount of carbon is sufficient to explain a 2 to 3 excursion in 13c across the lptm fate of ch4 in oceanic hydrates must be considered in developing models of the climatic and paleoceanographic regimes that operated during the lptm

correlation of early cretaceous carbon isotope stratigraphy and platform drowning events a possible link the early cretaceous carbonate carbon isotope record is marked by three positive high amplitude 1 5 excursions each covering time spans of more than 106 years they are of late valanginian hauterivian and early and late aptian age in a case study along a transect across the western tethys ocean we identified a coincidence between 13c excursions black shale formation and widespread carbonate platform drowning events we conclude that the 13c excursions reflect a change in partitioning of carbon between the organic and carbonate carbon sinks which was triggered by climate induced ecological changes in cretaceous pelagic and neritic environments episodes of intensified greenhouse climate conditions led to an increase in weathering erosion and runoff rates and to elevated nutrient transfer rates from continents into oceans the resulting increase in oceanic nutrient levels favoured marine phytoplankton production and black shale deposition while conditions for carbonate producing biotas became unfavourable partial choking of carbonate production along river influenced coasts resulted in widespread carbonate platform drowning during times of sea level rise in the valanginian and aptian widespread contemporaneous black shale deposits and drowned carbonate platforms therefore reflect the contrasting response of the marine organic and carbonate carbon pumps to nutrient enhanced phytoplankton productivity the change in marine carbon partitioning is mirrored in a shift of the 13c record towards more positive values the transition to the 13c peak values lasted up to several hundred thousand years the peaks of the excursions also covering a time span of up to several hundred thousand years reflect a new stabilisation of the carbon partitioning between carbonate and organic carbon sinks a renewed intensification of carbonate sedimentation under mesotrophic conditions was facilitated by stabilisation of the sea level rise at a high level decreasing 13c values record increasing carbonate carbon burial rates at constant or decreasing organic carbon accumulation rates these changes contributed to the stabilisation of the marine carbon budget and the global carbon cycle up to millions of years after its initial perturbation

collisions with ice volatile objects geological implications a qualitative treatment abstract an aperiodic collision of the earth with extra terrestrial ice volatile bodies is proposed as a mechanism to produce rapid changes in the geologic record due to the volatile nature of these bodies evidence for their impacts particularly in the ocean might be subtle and best seen as spikes in the geochemical or fossil record against normal background differing effects would result depending on the site of the major break up of the object in the atmosphere on land or in the ocean this paper focuses on the effects of adding material to the seas oceans and atmosphere the treatment is largely qualitative however mass balance calculations were used to estimate the relative mass needed to affect changes in a variety of reservoirs although actual impactors probably have a variable composition the effects of water c n and s containing objects are discussed in the atmosphere effects could include increased rain acidity increased levels of nutrients and enhanced greenhouse warming cooling oceanic effects might include increased oceanic productivity nitrogen containing objects as a result of increased chemical weathering and or greenhouse effects increased temperatures coupled with enhanced productivity could result in wider spread oceanic anoxia or altered calcite aragonite stability possible examples of such impacts from the geologic record and potential biotic effects are given

variations in the sterane carbon number distributions of marine source rock derived crude oils through geological time abstract the analysis of the sterane data of a large set of crude oils 414 derivedfrom marine carbonate 27 and siliciclastic source rocks 14 where influences of terrestrial or lacustrine derived organic matter can reasonably be excluded shows that there are increases in the relative content of c28 steranes and decreases in the relative content of c29 steranes through geological time there are no consistent variations in the relative content of c27 steranes through time with one major exception a proterozoic oil from oman palaeozolic and older crude oils are thus generally characterised by strong predominances of c29 steranes and low relative concentrations of c28 steranes significantly higher proportions of c28 steranes and lower proportions of c29 steranes occur in oils derived from jurassic and upper cretaceous source rocks these changes through time do not appear to reflect the chemical evolution of the sterols of one particular variety of marine organism the increase in c28 steranes may be related to the increased diversification of phytoplantonic assemblages in the jurassic and cretaceous possible sources of the c28 sterols necessary for the observed changes in crude oil steranes includes diatoms coccolithophores and dinoflagellates although the technique does not give an accurate means of determining the age of the source rock of a crude oil it is possible to distinguish younger crudes derived from the upper cretaceous and tertiary from palaeozoic and older crudes

sea water circulation on an oolite dominated carbonate system in an epeiric sea middle jurassic switzerland the middle jurassic burgundy carbonate platform occupied a central part of the central european epeiric sea during the middle jurassic the facies architecture of the oolitic calcarenite bodies was affected by tidal currents on the platform and relative sea level changes the 13c values of inorganic carbonates sampled in biostratigraphic defined intervals do not match very well between closely spaced sections and hence are of restricted use for stratigraphic purposes it appears that the platform interior might have been decoupled from the global carbon pool although deposited in a rapidly accumulating setting the recorded isotope signatures might be affected by some local stratigraphic gaps nonetheless the carbon isotope data imply lateral changes of the platform waters these appear to be related to the position on the platform and to the sediment dispersal pattern as evidenced by clay minerals adjacent to the eastern margin of the platform detrital chlorite and illite occur in considerable proportions both ascribed to a boreal source to the east and the north east in contrast smectite rich mixed layer clay mineral content increases significantly towards the platform interior pointing to a delivery from the north west all these data are suggestive of an overall clockwise current pattern in the central european epeiric sea during the middle jurassic

magnetostratigraphic calibration of the late valanginian carbon isotope event in pelagic limestones from northern italy and switzerland abstract magnetostratigraphic biostratigraphic and carbon isotope data are presented from five lower cretaceous pelagic limestone sections in the southern alps a positive carbon isotope event is recorded in bulk carbonate from the upper valanginian of all five sections and the magnetostratigraphy and biostratigraphy provide the age model the record of the isotope event in absolute time is closely replicated in all five sections as the sections are located in two paleogeographic basins and are separated by up to 300 km the synchronous isotope event cannot be interpreted as an artifact of diagenesis a reduction in magnetization intensity coincident with the 13 c peak may be due to diagenetic magnetite dissolution enhanced by increased organic carbon burial according to the age model which uses gts89 timescale 1 background 13 c values of 1 5 are recorded from 145 to 137 ma between 137 and 136 ma 13 c increases to a maximum value of about 3 values begin to decrease from 136 ma and reach background values at about 132 ma the rate of change of 13 c for the onset of the event about 1 5 m y is greater than for the decay about 0 5 m y suggesting an abrupt perturbation of the carbon system from equilibrium followed by a more gradual return to background values

lower jurassic epicontinental carbonates and mudstones from england and wales chemostratigraphic signals and the early toarcian anoxic event sections through lower jurassic epicontinental carbonates from southern britain junction bed and equivalent show a positive carbon isotope excursion 13ccarbonate detectable in bulk rock in the falciferum zone of the lower toarcian isotopic data from organic matter in more clay rich sections from wales and north east england together with determinations on belemnite calcite indicate that highest 13c values are localized in the upper exaratum subzone of the falciferum zone levels of particular enrichment in organic carbon were developed in the early to mid exaratum subzone and hence pre date this 13c maximum these phenomena reflect the impact of the early toarcian oceanic anoxic event in the british area similar isotopic trends have been recorded in other toarcian sections from tethyan europe and are interpreted as reflecting the chemistry of sea water on the assumption of isotopic correlation between the english and tethyan sections the 13c maximum would be everywhere dated as latest exaratum subzone in terms of the north european ammonite scheme absolute oxygen isotope values in carbonates probably reflect both early diagenetic cementation and later temperature related burial diagenesis although a palaeotemperature maximum is tentatively identified as characterizing the early falciferum zone subsequent climatic deterioration may have been triggered by drawdown of co2 related to regional excess carbon burial during the oceanic anoxic event using the positive 13c excursion as a correlative level in sections from different faunal provinces britain italy and spain implies that lower toarcian zonal stratigraphy is diachronous between northern and southern europe there is evidence for partitioning of water masses between the north european shelf and the tethyan continental margin during the early jurassic

a modeling case for high atmospheric oxygen concentrations during the mesozoic and cenozoic changes in atmospheric oxygen concentration over earth history are commonly related to the evolution of animals and plants but there is no direct geochemical proxy for o2 levels meaning that estimations rely heavily on modeling approaches the results of such studies differ greatly to the extent that today s atmospheric mixing ratio of 21 might be either the highest or lowest level during the past 200 m y long term oxygen sources such as the burial in sediments of reduced carbon and sulfur species are calculated in models by representation of nutrient cycling and estimation of productivity or by isotope mass balance imb a technique in which burial rates are inferred in order to match known isotope records studies utilizing these different techniques produce conflicting estimates for paleoatmospheric o2 with nutrient weathering models estimating concentrations close to or above that of the present day and imb models estimating low o2 especially during the mesozoic here we re assess the imb technique using the copse biogeochemical model imb modelling is confirmed to be highly sensitive to assumed carbonate 13c and when this input is defined following recent compilations predicted o2 is significantly higher and in reasonable agreement with that of non imb techniques we conclude that there is no model based support for low atmospheric oxygen concentrations during the past 200 m y high mesozoic o2 is consistent with wildfire records and the development of plant fire adaptions but links between o2 and mammal evolution appear more tenuous

orbital pacing and secular evolution of the early jurassic carbon cycle global perturbations to the early jurassic environment 201 to 174 ma notably during the triassic jurassic transition and toarcian oceanic anoxic event are well studied and largely associated with volcanogenic greenhouse gas emissions released by large igneous provinces the long term secular evolution timing and pacing of changes in the early jurassic carbon cycle that provide context for these events are thus far poorly understood due to a lack of continuous high resolution 13c data here we present a 13ctoc record for the uppermost rhaetian triassic to pliensbachian lower jurassic derived from a calcareous mudstone succession of the exceptionally expanded llanbedr mochras farm borehole cardigan bay basin wales united kingdom combined with existing 13ctoc data from the toarcian the compilation covers the entire lower jurassic the dataset reproduces large amplitude 13ctoc excursions 3 recognized elsewhere at the sinemurian pliensbachian transition and in the lower toarcian serpentinum zone as well as several previously identified medium amplitude 0 5 to 2 shifts in the hettangian to pliensbachian interval in addition multiple hitherto undiscovered isotope shifts of comparable amplitude and stratigraphic extent are recorded demonstrating that those similar features described earlier from stratigraphically more limited sections are nonunique in a long term context these shifts are identified as long eccentricity 405 ky orbital cycles orbital tuning of the 13ctoc record provides the basis for an astrochronological duration estimate for the pliensbachian and sinemurian giving implications for the duration of the hettangian stage overall the chemostratigraphy illustrates particular sensitivity of the marine carbon cycle to long eccentricity orbital forcing

magnetostratigraphic biostratigraphic and stable isotope stratigraphy of an upper miocene drill core from the sale briqueterie northwestern morocco a high resolution chronology for the messinian stage we report a high resolution stable isotope carbonate magnetostratigraphic and biostratigraphic record from a 175 m drill core from the sale briqueterie which is part of the bou regreg section in northwestern morocco the sale drill core spans the interval from paleomagnetic chron c4n partim to c3r earliest gilbert which represents the time leading up to and including the isolation and desiccation of the mediterranean i e the messinian salinity crisis during chrons c3an and c3ar 6 935 to 5 894 ma the isotope and carbonate signals display quasi periodic variations with estimated periods of 40 and 100 kyr respectively we interpret the 40 kyr 18o variations as reflecting changes in global ice volume caused by obliquity induced changes 41 kyr in solar insolation in polar regions the 100 kyr carbonate variations probably represent long term modulation of the amplitude of the precessional cycle 21 kyr which is not resolved by our sampling frequency the cyclic nature of the oxygen isotope signal permits us to extend the isotope nomenclature of shackleton et al 1994a from stage tg24 in chron c3r earliest gilbert to stage c3ar 18o 18 at the base of chron c3ar 6 935 ma a major change in paleoceanographic conditions is recorded across the tortonian messinian boundary which we correlate to chron c3bn at 7 04 ma benthic foraminiferal 18o values increased by an average of 0 4 in two steps at 7 17 ma and 6 8 ma and 13c values decreased by 0 7 0 8 between 7 1 and 6 8 ma representing the late miocene carbon shift the first step in 18o values coincides with an inferred reversal in deep water circulation through the rifian corridor and the second correlates with the base of the tripoli formation and onset of crisis conditions in the mediterranean we suggest that the increase in 18o values represents at least in part an increase in global ice volume that lowered sea level and contributed to the establishment of a negative water budget in the mediterranean average 18o values remained high throughout most of chrons c3ar and c3an reaching maximum 18o values during isotope stages tg20 and 22 in chron c3r earliest gilbert the glacio eustatic falls associated with these events may have resulted in the complete isolation of the mediterranean from the world ocean shackleton et al 1994a following stage tg12 in the sale record there exists a trend toward progressively lower 18o values that may represent a series of marine transgressions that eventually reflooded the mediterranean and ended the salinity crisis

tertiary oxygen isotope synthesis sea level history and continental margin erosion tertiary benthic and planktonic foraminiferal oxygen isotope records are correlated to a standard geomagnetic polarity time scale making use of improved chronostratigraphic control and additional oligocene isotope data synchronous changes in both benthic and planktonic 18o values which occurred in the oligocene to miocene 36 5 2 ma are interpreted in part to represent ice growth and decay the inferred ice growth events correlate with erosion on passive continental margins as interpreted from seismic and chronostratigraphic records this association is consistent with a link between oligocene to miocene erosional events and rapid 15 m m y glacioeustatic lowerings of about 50 m high benthic foraminiferal 18o values suggest the presence of continental ice sheets during much of the oligocene to recent 36 0 ma substantially ice free conditions probably existed throughout the paleocene and eocene 66 36 ma the mechanisms and rates of sea level change apparently were different between the early and late tertiary with glacioeustatic changes restricted to the past 36 m y pre oligocene erosion on passive continental margins was caused by eustatic lowerings resulting from global spreading rate changes we apply a model which suggests that large areas of the continental shelves were subaerially exposed during such tectonoeustatic lowstands stimulating slope failure and submarine erosion the different mechanisms and rates of eustatic change may have caused contrasting erosional patterns between the early and late tertiary on passive continental margins this speculation needs to be confirmed by examination of data from several passive margins

variations of the187os 186os ratio of seawater over the past 28 million years as inferred from metalliferous carbonates abstract the os concentration and isotopic composition of metalliferous carbonates deposited on the east pacific rise over the past 28 ma are reported with complimentary sr isotope data variations in the os isotopic composition of these samples are interpreted as a record of past changes in the os isotopic composition of seawater these results are consistent with isotopic analyses of leachable os in pelagic clays which have also been interpreted as a record of the187os 186os ratio of seawater through time 1 the metalliferous carbonate record clearly shows that seawater os and sr isotope systems are partially decoupled from one another over the past 28 ma accelerated weathering of ancient organic rich sediments is suggested as a possible mechanism to account for this decoupling and the rapid increase in the187os 186os ratio of seawater over the past 15 ma this rapid increase suggests that the seawater os record can potentially be used as a stratigraphic tool in some neogene marine deposits

phosphogenesis carbon isotope stratigraphy and carbonate platform evolution along the lower cretaceous northern tethyan margin we distinguish three different stages in the evolution of the tithonian late jurassic to aptian early cretaceous northern tethyan carbonate platform 1 carbonate production in the coral oolite mode late tithonian to early valanginian early barremian to early aptian 2 carbonate production in the crinoid bryozoan mode early valanginian haute rivian late aptian and 3 platform retrogradation and destruction condensation and phosphogenesis that is platform drowning early valanginian to early hauterivian middle hauterivian late hauterivian to early barremian early to early late aptian and latest aptian to earliest albian transitions from the coral oolite mode to the crinoid bryozoan mode and consequently to platform drowning may have been driven by increases in nutrient levels on the shelf phases of relative sea level rise in times of carbonate production in the coral oolite mode are named constructive because of the observed platform regeneration following phases of widespread emersion during late sea level highstands in contrast phases of relative sea level rise in times of platform drowning are termed destructive the 13 c stratigraphies obtained from valanginian hauterivian and aptian albian hemipelagic successions beyond the platform correlate well with the early cretaceous pelagic 13 c record positive excursions in the pelagic 13 c record correspond in time to episodes of platform drowning this suggests the existence of a coupling mechanism between changes in the global carbon cycle and platform drowning in our view the early cretaceous crises in carbonate platform growth were the consequence of reinforced greenhouse conditions which may have been triggered by episodes of extensive flood basalt volcanism strong greenhouse conditions may have induced the following chain of feedback mechanisms enabling the biosphere to return to normal conditions climate warming sea level rise accelerated water cycle intensified weathering nutrient mobilization platform destruction increased productivity increased phosphogenesis and carbon burial weakened greenhouse conditions

carbon cycle history through the jurassic cretaceous boundary a new global δ13c stack we present new carbon and oxygen isotope curves from sections in the bakony mts hungary constrained by biostratigraphy and magnetostratigraphy in order to evaluate whether carbon isotopes can provide a tool to help establish and correlate the last system boundary remaining undefined in the phanerozoic as well provide data to better understand the carbon cycle history and environmental drivers during the jurassic cretaceous interval we observe a gentle decrease in carbon isotope values through the late jurassic a pronounced shift to more positive carbon isotope values does not occur until the valanginian corresponding to the weissert event in order to place the newly obtained stable isotope data into a global context we compiled 31 published and stratigraphically constrained carbon isotope records from the pacific tethyan atlantic and boreal realms to produce a new global 13c stack for the late oxfordian through early hauterivian interval our new data from hungary is consistent with the global 13c stack the stack reveals a steady but slow decrease in carbon isotope values until the early valanginian in comparison the late jurassic early cretaceous 13c curve in gts 2012 shows no slope and little variation aside from the well defined valanginian positive excursion chemostratigraphic correlation durschning the jurassic cretaceous boundary interval is difficult due to relatively stable 13c values compounded by a slope which is too slight there is no clear isotopic marker event for the system boundary the long term gradual change towards more negative carbon isotope values through the jurassic cretaceous transition has previously been explained by increasingly oligotrophic condition and lessened primary production however this contradicts the reported increase in 87sr 86sr ratios suggesting intensification of weathering and a decreasing contribution of non radiogenic hydrothermal sr and presumably a concomitant rise in nutrient input into the oceans the concomitant rise of modern phytoplankton groups dinoflagellates and coccolithophores would have also led to increased primary productivity making the negative carbon isotope trend even more notable we suggest that gradual oceanographic changes more effective connections and mixing between the tethys atlantic and pacific oceans would have promoted a shift towards enhanced burial of isotopically heavy carbonate carbon and effective recycling of isotopically light organic matter these processes account for the observed long term trend interrupted only by the weissert event in the valanginian

onshore offshore correlations of cretaceous fluvial deltaic sequences southern baltimore canyon trough we evaluate cretaceous depositional sequences on approximately 4400 km 2700 mi of newly released multichannel seismic profiles and five wells on the continental shelf in the southern baltimore canyon trough and tie the data to three wells drilled onshore in the maryland coastal plain seismic geometries coupled with facies and biostratigraphy from the wells are used to delineate mid cretaceous aptian turonian depositional sequences and paleogeography beneath these sequences 400 1000 m 1300 3300 ft of lower cretaceous sedimentary rocks underlie the modern shelf they thicken along strike to the southwest implying a southern sediment source aptian to cenomanian sediments were deposited in shelf to nearshore settings a landward movement of the depocenter and a shift toward facies indicative of deeper paleodepths marks a 107 yr mid cretaceous transgression within which we identify five sequences a composite maximum flooding surface mfs within the uppermost of these retrogradational units is associated with the cenomanian turonian boundary and ocean anoxic event 2 shingled lower turonian seismic reflections prograde across the outer shelf downlapping onto the composite mfs and are truncated by a mid turonian sequence boundary the upper cretaceous section thickens seaward and along strike to the northeast implying a northern source and little late cretaceous accommodation beneath the modern shelf mid cretaceous strata offshore maryland are likely sand prone considering their proximity to the correlative fluvial facies of the onshore potomac group these potential reservoir sands are capped by regional confining units generated by 107 yr global mean sea level flooding events and are excellent targets for supercritical carbon storage

high resolution stable isotope records from the upper cretaceous rocks of italy and spain glacial episodes in a greenhouse planet high resolution 13c and 18o records from upper albian to lower santonian pelagic carbonates of the contessa quarry section in italy exhibit large positive oxygen isotopic excursions of 1 in the lower cenomanian and upper turonian coniacian strata within the uncertainties of biostratigraphic correlation these positive excursions appear to correspond to times of large sea level regressions in global sequence stratigraphic sea level curves several lines of evidence suggest that the major 18o excursions in contessa reflect episodes of global cooling and not differential diagenesis numerical models of oxygen isotope exchange during diagenesis show that a high contrast in the degree of alteration would be required to produce these signals as artifacts of diagenesis and lithological data provide no evidence for such large contrasts in the degree of alteration furthermore although precise correlation with a section in the south of spain is hampered by stratigraphic complexities the general sequence of major positive 18o excursions is reproduced it is unlikely that differential diagenesis would produce similar artifacts in multiple sites one explanation for the link between episodes of global cooling and sea level falls is that global cooling events led to polar ice sheet accumulation lowering sea level although ice free conditions have been inferred from evidence for a much warmer climate in late cretaceous time our results suggest that the relationship between continental high latitude ice sheets and overall climatic warmth warrants further examination

illawarra reversal the fingerprint of a superplume that triggered pangean breakup and the end guadalupian permian mass extinction abstract the permian magnetostratigraphic record demonstrates that a remarkable change in geomagnetism occurred in the late guadalupian middle permian ca 265 ma from the long term stable kiaman reverse superchron throughout the late carboniferous and early middle permian to the permian triassic mixed superchron with frequent polarity changes in the late permian and triassic this unique episode called the illawarra reversal probably reflects a significant change in the geodynamo in the outer core of the planet after a 50 million years of stable geomagnetism the illawarra reversal was likely led by the appearance of a thermal instability at the 2900 km deep core mantle boundary in connection with mantle superplume activity the illawarra reversal and the guadalupian lopingian boundary event record the significant transition processes from the paleozoic to mesozoic modern world one of the major global environmental changes in the phanerozoic occurred almost simultaneously in the latest guadalupian as recorded in 1 mass extinction 2 ocean redox change 3 sharp isotopic excursions c and sr 4 sea level drop and 5 plume related volcanism in addition to the claimed possible links between the above listed environmental changes and mantle superplume activity i propose here an extra explanation that a change in the core s geodynamo may have played an important role in determining the course of the earth s surface climate and biotic extinction evolution when a superplume is launched from the core mantle boundary the resultant thermal instability makes the geodynamo s dipole of the outer core unstable and lowers the geomagnetic intensity being modulated by the geo and heliomagnetism the galactic cosmic ray flux into the earth s atmosphere changes with time the more cosmic rays penetrate through the atmosphere the more clouds develop to increase the albedo thus enhancing cooling of the earth s surface the illawarra reversal the kamura cooling event and other unique geologic phenomena in the late guadalupian are all concordantly explained as consequences of the superplume activity that initially triggered the breakup of pangea the secular change in cosmic radiation may explain not only the extinction related global climatic changes in the end guadalupian but also the long term global warming cooling trend in earth s history in terms of cloud coverage over the planet

long eccentricity cycle in pliocene oceanic carbon reservoir a comparison between the mediterranean and the south china sea abstract as quantitative paleoclimate time series extend deeper into the geological past growing evidence indicates the extensive occurrence of the 400 kyr long eccentricity cycle in geological records the long cycles are best manifested in the marine carbon isotope as a series of 13 cmax which correspond to the long eccentricity s minima however it remains unclear how eccentricity affects the oceanic carbon reservoir to determine what processes are involved in generating the 400 kyr cycles one long eccentricity cycle in the late pliocene from 3 2 myr to 2 8 myr was examined in two sections respectively from the mediterranean and the south china sea the results indicate that the mediterranean section displays distinct precession cycles in all of the studied proxy time series and their amplitudes are modulated by eccentricity whereas the precession cycles and the eccentricity modulation are much weaker in the proxy sequences from the south china sea the difference is attributed to the fact that african monsoon was overwhelmingly dominated by precessional forcing and the mediterranean basin was isolated from glacial induced reorganizations of the global ocean whereas totally different conditions existed in the south china sea it may be inferred from the comparison that the 13 cmax originated largely from the global ocean and was unlikely caused by local basin factors at the long eccentricity maximum summer insolation reached a maximum at low latitudes and the intensified global monsoon changed the ocean carbon reservoir and the 13 c value because of the long residence time of carbon in the ocean 13 c changes in the global oceanic reservoir primarily occur on a 10 5 yr time scale with a smoothing effect in the lower frequencies the 400 kyr long eccentricity was pervasive at least in the cenozoic ocean but its expression was subject to spatio temporal variations particularly under the influence of the ice sheet development

detailed record of the mid oxfordian late jurassic positive carbon isotope excursion in two hemipelagic sections france and switzerland a plate tectonic trigger the oxfordian late jurassic was a time of widespread change in jurassic marine carbonate sedimentation patterns a marked positive excursion in 13 c is dated as middle oxfordian in age in this study we investigate if changes in carbonate sedimentation coincided with altered carbon cycling and climate we use c isotope records as a proxy for the evolution of the carbon cycle and compare 13 c trends with the evolution of sedimentation in a segment of the opening tethys seaway one of the studied sections is located in the subalpine basin of france trescleoux and oze the other in the swiss jura mountains liesberg carbon isotope stratigraphy of carbonate carbon locates the peak values of the middle oxfordian positive excursion to theantecedens andparandieri subzonesoftheplicatilisandtransversariumammonitezones respectively causesofthe excursionremain enigmatic theexcursion seems not to coincide with a global oceanic anoxic event but regionally enhanced organic carbon accumulation during the early and early middle oxfordian may be the cause of the increase in 13 c the excursion occurs during a time of progressive climate warming anditspeakvaluescoincidewiththefirstcalcareoussedimentsrecurringafteraperiodofreducedcarbonateaccumulationintheearly and early middle oxfordian the excursion is also time equivalent to a major reorganisation of global ocean currents the opening atlantic and tethys oceans combined with rising sea level led to the formation of an efficient circumglobal seaway we conclude that this favoured the widespread recurrence of carbonate producers by providing new habitats as a result ccarb burial increased leading to a lower corg ccarb burial rate and therefore to stabilisation and decrease in 13 c in the middle oxfordian thus the mid oxfordian positive excursion in carbonate c isotopes may reflect changes in the carbon cycle that were triggered by a copious reorganisation of the ocean current system caused by major plate tectonic movements 2007 elsevier b v all rights reserved

high resolution organic carbon isotope stratigraphy of the middle jurassic lower cretaceous agardhfjellet formation of central spitsbergen svalbard we present the first complete organic carbon isotope curve from the agardhfjellet formation central spitsbergen svalbard samples from two drill cores dh2 and dh5r were analysed for 13corg total organic carbon toc and rock eval rock eval litho and biostratigraphy demonstrate a similar development in the two cores allowing construction of a composite 13corg curve covering the bathonian to lowermost cretaceous there are only weak correlations between rock eval parameters and 13corg suggesting the isotopic signal is not mainly controlled by type of kerogen maturation but rather reflects regional or global environmental changes the carbon isotope curves from the cores can be correlated with previously published curves from outcrops of the slottsmoya member and with more distant localities in the barents sea siberia great britain and the atlantic features in common with other published curves include a callovian oxfordian positive excursion a kimmeridgian middle volgian negative trend and a middle volgian negative excursion these correlations allow refinement chronostratigraphy of the jurassic of svalbard

neogene himalayan weathering history and river87sr86sr impact on the marine sr record abstract clastic sediments in the bengal fan contain a neogene history of erosion and weathering of the himalaya we present data on clay mineralogy major element stable and radiogenic isotope abundances from lower miocene pleistocene sediments from odp leg 116 nd and sr isotope data show that the himalayan provenance for the eroded material has varied little since 17 ma however from 7 to 1 ma smectite replaces illite as the dominant clay while sediment accumulation decreased implying an interval of high chemical weathering intensity but lower physical erosion rates in the ganges brahmaputra gb basin o and h isotopes in clays are correlated with mineralogy and chemistry and indicate that weathering took place in the paleo gangetic flood plain the87sr86sr ratios of pedogenic clays vermiculite smectite record the isotopic composition of sr in the weathering environment and can be used as a proxy for87sr86sr in the paleo gb basin the sr data from pedogenic clays shows that river87sr86sr values were near 0 72 prior to 7 ma rose rapidly to 0 74 in the pliocene and returned to 0 72 in the middle pleistocene these are the first direct constraints available on the temporal variability of87sr86sr in a major river system the high87sr86sr values resulted from intensified chemical weathering of radiogenic silicates and a shift in the carbonate silicate weathering ratio modeling of the seawater sr isotopic budget shows that the high river87sr86sr values require a ca 50 decrease in the sr flux from the gb system in the pliocene the relationship between weathering intensity 87sr86sr and sr flux is similar to that observed in modern rivers and implies that fluxes of other elements such as ca na and si were also reduced increased weathering intensity but reduced sr flux appears to require a late miocene pliocene decrease in himalayan erosion rates followed by a return to physically dominated and rapid erosion in the pleistocene in contrast to the view that increasing seawater87sr86sr results from increased erosion mio pliocene to mid pleistocene changes in the seawater sr budget were the result of reduced erosion rates and sr fluxes from the himalaya

obscuring of long eccentricity cyclicity in pleistocene oceanic carbon isotope records abstract long eccentricity 400 kyr cycles in carbon isotope records from the pacific and atlantic oceans and the mediterranean sea of the past 5 0 ma are compared all records show maximum 13c values 13cmax at eccentricity minima during the pliocene but this relationship obscured in the pleistocene after 1 6 ma in particular for the open ocean deep water 13c records since a clear anti phase relationship was set up between oceanic 18o and 13c in the 100 kyr band from this time we attribute the obscured 400 kyr signal to a major change in the oceanic carbon reservoir probably associated with restructure of the southern ocean a similar change occurred in the miocene at 13 9 ma when the 400 kyr cyclicity in 13c records flattened out together with a drastic cooling and antarctic ice sheet expansion a remarkable exception is the mediterranean surface water 13c record which remained paced by the long term eccentricity cycle throughout the pliocene and pleistocene suggesting a low latitude climatic origin of the 400 kyr signal that is independent of glacial interglacial forcing since the earth is currently passing through an eccentricity minimum it is crucial to understand the nature of the 13cmax events

erratum to the posidonia shale lower toarcian of sw germany an oxygen depleted ecosystem controlled by sea level and palaeoclimate palaeogeogr palaeoclimatol palaeocol 165 2001 27 52 abstract the lower toarcian posidonia shale is famous for its excellently preserved fossils and its high amount of organic matter up to 16 both quality of preservation and accumulation of organic matter have been explained by permanent anoxic bottom water conditions high resolution geochemical sedimentological and palaeoecological investigations of various sections of the posidonia shale in sw germany however indicate that oxygen availability was variable and ranged from short oxygenated periods to longer term anoxia the benthic macrofauna consists of nine fossil communities and was used in combination with geochemical data to reconstruct a time averaged oxygen curve anoxic conditions prevailed during the deposition of the toarcian black shales they were however punctuated by various short periods weeks to years with oxygenated bottom water conditions sedimentological e g distinctiveness of microlamination siliciclastic content and geochemical parameters e g organic matter content isotopic signatures 18 o and 13 c molecular redox parameters pristane phytane ratio arylisoprenoids exhibit a remarkable covariation and seem to be controlled by sea level fluctuation maximum oxygen depletion and an extreme negative shift of 13 c org values 34 occurred during the early falciferum zone this is explained by the recycling of 12 c enriched carbon derived from remineralization of organic matter on and within the substrate during low sea level stand and a highly elevated redox boundary including photic zone anoxia the subsequent transgression permitted enhanced water exchange with the tethyan ocean and caused improvement of living conditions at the end of the falciferum zone other important factors controlling the depositional environment are the overall palaeogeographic situation and climate the early jurassic is the latest period before break up of pangaea and probably was ruled by a strong meridional atmospheric circulation system with pronounced seasonal changes of prevailing trade and monsoon wind systems an estuarine circulation with a positive water balance and surface water with slightly reduced salinity in the summer alternated with an anti estuarine circulation and a negative water balance in the winter during the summer months a stratified water column with anoxic conditions below the halocline developed 18 o data indicate low salinity in the surface water during the monsoon influenced summer high productivity was then located in the photic zone and the corresponding isotopically light 18 o signal was fixed in the calcareous nannoplankton during the winter months a saline circulation system brought oxygen to the benthic environment favouring temporary benthic colonization especially during times of relative sea level high stand

biological overprint of the geological carbon cycle the oxidation of earth s atmosphere is coupled to the net sequestration of organic matter which is related to the relative fractions of organic carbon forg and carbonate fcarb buried in marine sediments these fractions can be inferred from carbon isotope data we present bulk sediment d 13 c records of carbonate d 13 ccarb and organic carbon d 13 corg with a compilation of evolutionary trajectories of major eucaryotic phytoplankton for the past 205 million years our analysis indicates that changes in phytoplankton community structure coupled with the opening of the atlantic ocean basin and global sea level rise increased the efficiency of organic carbon burial beginning in the early jurassic in turn this organic carbon burial increased the oxidation state of earth s surface while drawing down atmospheric co2 levels assuming no substantial negative feedbacks the net oxidation and co2 drawdown appear to be related to the opening phase of the current wilson cycle where the newly formed passive plate margins store organic matter for hundreds of millions of years this process should reverse during the closing phase of the wilson cycle when the continents reassemble and the atlantic ocean basin closes the associated oxidation and storage of organic matter have contributed to the long term depletion of co2 which was a key factor that selected c4 photosynthetic pathways in marine and terrestrial ecosystems in the latter part of the cenozoic these pathways increasingly influenced d 13 corg and ultimately contributed to the reversal of the long term trend in d 13 ccarb

arctic reappraisal of global carbon cycle dynamics across the jurassic cretaceous boundary and valanginian weissert event abstract late jurassic early cretaceous global carbon cycle dynamics have mainly been inferred from tethyan atlantic and pacific carbon isotope 13c records these records indicate a steady deceleration of the carbon cycle in late jurassic and jurassic cretaceous j k boundary times followed by a major mid valanginian carbon cycle perturbation demarcated by the well documented positive excursion named the weissert event however this model remains to be confirmed in boreal records which are rare and typically difficult to correlate with the global 13c signal in this study the first continuous and biostratigraphically calibrated organic carbon isotope 13corg stratigraphy is established for the bathonian lower barremian representing 30 myr of the boreal realm based on high resolution sampling of bulk rock marine shale from four time equivalent sections in arctic svalbard supplemented by existing 13corg data the 13corg stratigraphy displays several distinctive trends notably i a kimmeridgian positive excursion followed by a large negative excursion 6 4 in the upper kimmeridgian middle volgian consistent with existing boreal 13c records ii an upper volgian ryazanian overall positive recovery across the j k boundary and iii a prominent positive excursion 5 5 in the valanginian interpreted to represent the weissert event followed by steady high values into the lower barremian with no apparent excursion decay time calibrated correlation of the observed trends with existing 13c records representative of the entire exchangeable carbon reservoir reflects major global carbon cycle adjustments including i boreal decoupling from the global carbon reservoir during late jurassic and j k boundary times due to basinal isolation and ii global carbon cycle recoupling at the onset of the weissert event coinciding with incipient oceanographic connectivity boreal carbon cycling was inherently controlled by the basin configuration the new 13corg stratigraphy provides a well calibrated tool for boreal and boreal tethyan correlations and confirms that the weissert event represents an important perturbation of the global carbon cycle

carbon isotope ratio of cenozoic co2 a comparative evaluation of available geochemical proxies 1 the carbon isotope ratio 13c of plant material is commonly used to reconstruct the relative distribution of c3 and c4 plants in ancient ecosystems however such estimates depend on the 13c of atmospheric co2 13cco2 at the time which likely varied throughout earth history for this study we use benthic and planktonic 13c and 18o records to reconstruct a long term record of cenozoic 13cco2 confidence intervals for 13cco2 values are assigned after careful consideration of equilibrium and non equilibrium isotope effects and processes as well as resolution of the data we find that benthic foraminifera better constrain 13cco2 compared to planktonic foraminiferal records which are influenced by photosymbiotes depth of production seasonal variability and preservation furthermore sensitivity analyses designed to quantify the effects of temperature uncertainty and diagenesis on benthic foraminifera 13c and 18o values indicate that these factors act to offset one another our reconstruction suggests that cenozoic 13cco2 averaged 6 1 0 6 1 while only 11 2 million of the last 65 5 million years correspond to the pre industrial value of 6 5 with 90 confidence here 13cco2 also displays significant variations throughout the record at times departing from the pre industrial value by more than 2 thus the observed variability in 13cco2 should be considered in isotopic reconstructions of ancient terrestrial plant ecosystems especially during the late and middle miocene times of presumed c4 grassland expansion

influence of oceanic anoxic events on the evolution of mid cretaceous radiolaria in the north atlantic and western tethys abstract mid cretaceous aptian turonian extinction radiation events of radiolaria from the north atlantic and western tethys are summarized in relation to oceanic anoxic events oae from investigations of radiolarian faunas black shales and stable carbon isotopes extinction and radiation events of radiolaria can be observed from the late early aptian the earliest albian the latest albian and the cenomanian turonian boundary these events correlate well with organic carbon rich sediments that contain type ii kerogen and show positive 13c excursions they correspond to the oceanic anoxic events oae in the early aptian oae 1a selli level early albian oae 1b late albian oae 1d and latest cenomanian oae 2 bonarelli level detailed investigations of the two most significant events the selli and the bonarelli level in the umbria marche basin of central italy show that extinctions coincide with the first occurrence of marine black shales type ii kerogen and the most prominent rise of 13corg values stepwise extinctions and continuous radiations precede and follow the events similar patterns are evident for the oae 1b and 1d black shales dominated by terrestrial organic matter type iii kerogen e g oae 1c are not characterized by isotopic excursions or by radiolarian extinction radiation events contemporaneous drowning events documented from carbonate platforms around the investigated basins provide a link to a model where flooding of lowlands and leaching of nutrients during a relative rise of sea level lead to an increased productivity and an expansion of the oxygen minimum zone omz because of the loss of deep habitats deeper dwelling forms become extinct shallower dwelling radiolarians survive a narrowing of the omz during highstands and relative sea level falls together with a coupled decrease of the nutrient supply leads to the development of new niches and therefore to radiation

post 125 ma carbon storage associated with continent continent collision tectonic fragments subjected to high pressure metamorphism in the alps contain up to 1 vol each of dolomite and graphite indicating that significant amounts of carbon bearing sediment were transported to depths greater than 50 km during the alpine orogeny the absence of a cretaceous tertiary volcanic arc on the overriding plate suggests that much of the subducted carbon remains at depth today averaged over the length of the alpine chain and the estimated amount of subduction that occurred in the past 125 m y 10 16 kg of carbon was buried because of collision in the alpine region additional consideration of the himalayan chain suggests that more than 10 17 kg of carbon has been buried since 125 ma by continent continent collision transfer of this amount of carbon from atmospheric and sedimentary reservoirs into a deep seated metamorphic reservoir may help explain the significant decrease in global surface temperature that occurred from 125 ma to the present

a case for a comet impact trigger for the paleocene eocene thermal maximum and carbon isotope excursion abstract we hypothesize that the rapid onset of the carbon isotope excursion cie at the paleocene eocene boundary 55 ma may have resulted from the accretion of a significant amount of 12c enriched carbon from the impact of a 10 km comet an event that would also trigger greenhouse warming leading to the paleocene eocene thermal maximum and possibly thermal dissociation of seafloor methane hydrate indirect evidence of an impact is the unusual abundance of magnetic nanoparticles in kaolinite rich shelf sediments that closely coincide with the onset and nadir of the cie at three drill sites on the atlantic coastal plain after considering various alternative mechanisms that could have produced the magnetic nanoparticle assemblage and by analogy with the reported detection of iron rich nanophase material at the cretaceous tertiary boundary we suggest that the cie occurrence was derived from an impact plume condensate the sudden increase in kaolinite is thus thought to represent the redeposition on the marine shelf of a rapidly weathered impact ejecta dust blanket published reports of a small but significant iridium anomaly at or close to the paleocene eocene boundary provide supportive evidence for an impact

cenozoic carbon cycle imbalances and a variable weathering feedback abstract the long term stability of earth s climate and the recovery of the ocean atmosphere system after carbon cycle perturbations are often attributed to a stabilizing negative feedback between silicate weathering and climate however evidence for the operation of this feedback over million year timescales and in response to tectonic and long term climatic change remains scarce for example the past 50 million years of the cenozoic era are characterized by long term cooling and declining atmospheric co2 p co 2 during this interval constant or decreasing carbon fluxes from the solid earth to the atmosphere suggest that stable or decreasing weathering fluxes are needed to balance the carbon cycle in contrast marine isotopic proxies of weathering i e 87sr 86sr 7 li and 187os 188os are interpreted to reflect increasing weathering fluxes here we evaluate the existence of a negative feedback by reconstructing the imbalance in the carbon cycle during the cenozoic using the surface inventories of carbon and alkalinity only a sustained 0 25 0 5 increase in silicate weathering is necessary to explain the long term decline in p co 2 over the cenozoic we propose that the long term decrease in p co 2 is due to an increase in the strength of the silicate weathering feedback i e the constant of proportionality between the silicate weathering flux and climate rather than an increase in the weathering flux this increase in the feedback strength which mirrors the marine isotope proxies occurs as transient 1 million year timescales remains invariant to match the long term inputs of carbon over the cenozoic this results in stable long term weathering fluxes even as p co 2 decreases we attribute increasing feedback strength to a change in the type and reactivity of rock in the weathering zone which collectively has increased the reactivity of the surface of the earth increasing feedback strength through the cenozoic reconciles mass balance in the carbon cycle with the marine isotopic proxies of weathering and may explain why there are periods when the earth system is more sensitive to carbon cycle perturbations

a tale of two extinctions converging end permian and end triassic scenarios the end permian c 252 ma and end triassic c 201 ma mass extinction events are commonly linked to the emplacement of the large igneous provinces of the siberia traps and central atlantic magmatic province respectively accordingly scenarios for both extinctions are increasingly convergent and cross fertilization of ideas has become important here we present a synthesis of extinction scenarios based on a critical assessment of the available palaeontological sedimentological geochemical and geophysical evidence how similar were the extinction events what gaps exist in our understanding and how can a comparison of the events enhance our understanding of each event individually our focus is on the most important proximate kill mechanisms including climate change and atmospheric pollution increased soil erosion weathering and runoff forest dieback and the spread of pathogens and ocean temperature changes anoxia and acidification there is substantial evidence to suggest that very similar kill mechanisms acted upon late permian as well as late triassic ecosystems strengthening the hypothesis that the ultimate causes of the mass extinction events were similar

cenozoic record of δ 34 s in foraminiferal calcite implies an early eocene shift to deep ocean sulfide burial understanding the changes in and drivers of isotopic variability of sulfur in seawater sulfate 34sso4 sw over geological time remains a long standing goal particularly because of the coupling between the biogeochemical sulfur and carbon cycles the early cenozoic has remained enigmatic in this regard as the existing seawater sulfate isotopic records appear to be decoupled from the well defined carbon isotope composition of the ocean here we present a new cenozoic record of sulfur isotopes using carbonate associated sulfate hosted in the calcite lattice of single species foraminifera the vastly improved stratigraphy afforded by this record demonstrates that carbon and sulfur cycles as recorded by their isotopes are not fully decoupled in the early cenozoic with a model driven by partial coupling of the carbon and sulfur cycles we demonstrate that a change in sulfur isotopic fractionation of the pyrite burial flux best explains the large increase in 34sso4 sw 53 million years ago ma and the subsequent long steady state we suggest that the locus of pyrite burial changed from shallow epicontinental seas and shelf environments to more open ocean sediments around 53 ma loss of extensive shelf environments corresponds to cretaceous palaeogene sea level changes and tectonic reorganization occurring as the himalayan arc first collided with asia a cenozoic reconstruction of the 34s of marine sulfate suggests a shift in the locus of pyrite burial from shallow seas to the open ocean during the early eocene

relative paleointensity rpi and oxygen isotope stratigraphy at iodp site u1308 north atlantic rpi stack for 1 2 2 2 ma narpi 2200 and age of the olduvai subchron 2015 elsevier ltd integrated ocean drilling program iodp site u1308 49 53 n 24 14 w water depth 3871 m provides a record of relative paleointensity rpi and benthic stable isotope stratigraphy back to 3 2 ma the record since 1 5 ma was published previously and here we present the interval from 1 5 ma to 3 2 ma early pleistocene late pliocene the benthic oxygen isotope record in this interval is correlated to marine isotope stage mis 51 to km2 with an apparent hiatus that removed part of the interval spanning mis 104 g2 2 6 2 65 ma at the gauss matuyama boundary the mean sedimentation rate for the 1 5 3 2 ma period is 8 5 cm kyr the age model was built by correlation of the benthic oxygen isotope record to a global stack lr04 apart from the expected polarity reversals three magnetic excursions are recorded punaruu in mis 31 32 at 1092 ka gilsa in mis 54 55 at 1584 ka and a newly recognized excursion labeled porcupine after the nearby porcupine abyssal plain in mis g6 g7 at 2737 ka the ages of polarity reversals at site u1308 on the lr04 time scale are consistent with the current geomagnetic polarity timescale gpts with the exception of the base of the olduvai subchron that occurred in mis 73 corresponding to 1925 ka on the lr04 time scale 25 kyr younger than in the current gpts the rpi record at site u1308 is calibrated using the oxygen isotope age model and combined with four other north atlantic records to obtain a north atlantic rpi stack for 1 2 2 2 ma narpi 2200 that is compared with published rpi stacks epapis sint 2000 and padm2m for 2 2 3 2 ma the site u1308 rpi record is compared with a rpi record from north atlantic iodp site u1314 and with the pacific epapis stack the mean sedimentation rates of the north atlantic sites in narpi 2200 are greater by about an order of magnitude than most of the records incorporated in other stacks the comparison of epapis and narpi 2200 yields an apparent lag for narpi 2200 relative to epapis attributed the epapis age model constructed by correlation of magnetic concentration parameters a proxy for carbonate percentage to a calibrated oxygen isotope record the long rpi record from site u1308 yields a very similar mean value for the brunhes and matuyama virtual axial dipole moments 7 05 1022 am2 implying no polarity bias in the strength of the main geomagnetic dipole in contrast to interpretations from sint 2000 and padm2m the results strengthen the case that rpi can be used to improve global stratigraphic correlation for sites with mean sedimentation rates up to several decimeters kyr

a model for atmospheric co 2 over phanerozoic time a new model has been constructed for calculating the level of atmospheric co sub 2 over phanerozoic time which is much simpler mathematically than the blag model but more complex geologically and biologically results suggest that there has been a notable pattern of varying atmospheric co sub 2 level over the past 570 my with high levels during the mesozoic and early paleozoic and low levels during the permo carboniferous and late cenozoic sensitivity analysis shows that within reasonable limits of the principal governing parameters this qualitative trend of varying co sub 2 is relatively insensitive to the actual values chosen for these parameters causes of the co sub 2 variation are multiple and no single geological or biological process can be called upon to explain all co sub 2 variation for all time the calculated trend of co sub 2 over time agrees well with independent estimations of paleoclimates thus the greenhouse theory of paleoclimate on a long geological time scale is supported by the results of the present study

tectonic cycles and the history of the earth s biogeochemical and paleoceanographic record an integrated approach to earth history for the last 2 5 b y reveals the strong interdependence of all geologic variables three earth history components are identified and interrelated secular trends as the earth ages recurring events of a previously proposed supercontinent megacycle worsley et al 1984 1985 and nonrecurring environmental shifts declining secular trends are endogenic heat production atmospheric carbon dioxide levels and surface temperatures continental differentiation enzyme efficiency atmospheric oxygen levels and solar luminosity are increasing secular trends four phases of a supercontinent cycle supercontinent fragmentation maximum continent dispersal continental assembly and supercontinental stasis recur with a 0 5 b y period and are correlated with tectonism cratonic sediment preservation atmospheric and hydrospheric evolution and the distribution of marine platform stable isotopes these correlations reflect coupling among the various oceanic and continental constituents during consecutive supercontinent assemblies and fragmentations nonrecurring shifts are unique and irreversible events in earth history e g development of photosynthesis occurrence of banded iron formations and deposition of detrital uraninite that represent periods of rapid geochemical adjustment to biospheric evolution earth s tectonobiogeochemical history is then synthesized by integrating secular trends and nonrecurring events with the supercontinent cycle emphasizing the preferentially preserved periods of fragmentation and continental dispersal paleoceanographic consequences of the megacycle are considered to reflect the stepwise coupling of secular trends and nonrecurring events to a biotically controlled phosphorus organic carbon climate linkage required to maintain earth s post archean surface temperature

carbon isotope stratigraphy and carbonate production during the early middle jurassic examples from the umbria marche sabina apennines central italy abstract the carbon isotopic signature of carbonates depends on secular variations of organic carbon and carbonate carbon production burial rates a decrease in carbonate productivity makes the organic carbonate carbon ratio unstable up to the point that even minor variations in the organic carbon reservoirs can provoke carbon isotopic shifts the 13c positive shifts of the middle carixian early pliensbachian and the early bajocian recorded in the umbria marche sabina domain represent a good example of this mechanism both sedimentology and lithostratigraphy of pelagic platform basin carbonate systems in this area show that important changes in the source of carbonates correspond to the observed isotopic shifts the middle carixian event is in fact well correlatable to the drastic reduction of benthic carbonate production on rift related intrabasinal highs which then became pelagic carbonate platforms the early bajocian event is concomitant with the beginning of a long hiatus on the pelagic carbonate platforms and with a drop of the biodiversity of calcareous organisms followed by the onset of biosiliceous sedimentation in basins

carbon and oxygen isotope stratigraphy of the english chalk and italian scaglia and its palaeoclimatic significance a detailed carbon and oxygen isotope stratigraphy has been generated from upper cretaceous coastal chalk sections in southern england east kent culver cliff isle of wight eastbourne and seaford head sussex norfolk coast and the british geological survey bgs trunch borehole norfolk data are also presented from a section through the scaglia facies exposed near gubbio italian apennines wherever possible the sampling interval has been one metre or less both the chalk and scaglia carbon isotopic curves show minor positive excursions in the mid cenomanian mid and high turonian basal coniacian and highest santonian lowest campanian there is a negative excursion high in the campanian in chalk sections that span that interval the well documented cenomanian turonian boundary spike is also well displayed as is a broad positive excursion centred on the upper coniacian a number of these positive excursions correlate with records of organic carbon rich deposition in the atlantic ocean and elsewhere the remarkable similarity in the carbon isotope curves from england and italy enables cross referencing of macrofossil and microfossil zones and pinpoints considerable discrepancy in the relative positions of the turonian coniacian and santonian stages the oxygen isotope values of the various chalk sections although showing different absolute values that are presumably diagenesis dependent show nonetheless a consistent trend the east kent section which is very poorly lithified indicates a warming up to the cenomanian turonian boundary interval then cooling thereafter regional organic carbon burial documented for this period is credited with causing drawdown of co 2 and initiating climatic deterioration inverse greenhouse effect data from other parts of the world are consistent with the hypothesis that the cenomanian turonian temperature optimum was a global phenomenon and that this interval represents a major turning point in the climatic history of the earth

foraminiferal assemblages extinctions and appearances associated with the early toarcian oceanic anoxic event in the llanbedr mochras farm borehole cardigan bay basin united kingdom abstract the uppermost pliensbachian lower toarcian sediments recovered from llanbedr mochras farm borehole north wales uk were deposited in the cardigan bay basin and mainly consist of alternating marls and marly limestones the current study analyses the foraminiferal assemblages from the cored interval 143 m that has been assigned to the spinatum zone upper pliensbachian to the lower part of the bifrons zone middle toarcian the foraminiferal assemblages are dominated by the suborders lagenina and robertinina four main ecostratigraphic intervals have been identified based on changes in the foraminiferal assemblages that occurred before during and after the toarcian oceanic anoxic event t oae ecostratigraphic interval i upper part of the spinatum zone is characterized by a diverse assemblage with specialist opportunist and intermediate forms this assemblage is interpreted to represent a phase that pre dates the biotic crisis the ecostratigraphic interval ii tenuicostatum zone shows an abrupt increase in opportunist forms such as the genus reinholdella and a facultative opportunist such as paralingulina tenera which was tolerant to oxygen depleted conditions this second interval represents the initial biotic crisis phase in response to decreasing oxygenation the ecostratigraphic interval iii is considered the peak of the biotic crisis coincident with the negative carbon isotopic excursion at the base of the serpentinum zone and characterized by the dominance of the opportunist reinholdella 87 97 of the assemblage and low diversity the ecostratigraphic interval iv upper part of serpentinum zone and lower part of bifrons zone is characterized by an increase of diversity and an abrupt decrease in reinholdella this assemblage is interpreted to reflect the increased availability of oxygen from deep infaunal to epifaunal microhabitats and the return to normal conditions at the sea bottom ecostratigraphic fluctuations in the mochras foraminiferal assemblages across the t oae event are comparable with those from other parts of the uk the lusitanian basin portugal the umbria marche basin italy and the atlassic basin north africa in addition a foraminiferal turnover is evident across the pliensbachian toarcian boundary and the t oae and reflects the effects of the early jurassic biotic crisis on benthic foraminifera controlling factors of the biotic crisis are discussed regarding that anoxic conditions do not necessarily have a lethal effect on all foraminiferal species and other oceanographic and environmental factors need consideration fragmentation of epicontinental platforms sea level changes crisis of carbonate productivity and temperature changes

δ13c of organic carbon in the bengal fan source evolution and transport of c3 and c4 plant carbon to marine sediments carbon isotopic measurements on organic carbon oc in sediment cores from the bengal fan odp leg 116 show a dramatic 10 increase beginning ca 7 ma ago and a rapid decrease after 0 9 ma these shifts reflect changes in the mixing ratio of terrigenous carbon derived from c3 and c4 plants the rapid increase in 13c of bengal fan oc at 7 ma shows that late miocene expansion of c4 plants already documented in the siwaliks was widespread over all the himalayan foreland after 7 ma relations of 13c with sedimentological parameters show that c4 plants dominate in the foreland whereas c3 plants remain abundant in the mountain range variations in the source of the sediments and of the oc appear to be sensitive to climate hydrologic conditions in the basin major changes in the isotopic composition of the carbon flux in one of the worlds largest river systems modify the isotopic budgets of both marine dissolved carbon and the sedimentary carbon mass

tectonic controls of phanerozoic sedimentary rock cycling the cyclic nature of the phanerozoic sedimentary rock distribution carbon sulphur coupling and material transfer among sedimentary reservoirs appears to be controlled by tectonic factors the distribution of preserved sedimentary mass in terms of rock mass remaining u geologic age shows a minimum c 300 350 ma ago which separates two subcycles of erosion and deposition of sedimentary rocks the older subcycle was interrupted because of the major continental collisions of the devonian and late carboniferous these collisions resulted in a reduction of outcrop areas of rocks of the older cycle relative to their masses leading to a decline in the probability of destruction and an increase in half life of these older sediments a strong correlation exists between the long term cyclicity in the phanerozoic global sea level curve and the distribution of carbon and sulphur among their major exogenic reservoirs this correlation is related to two principal tectonic modes of the phanerozoic oscillatory and submergent it is postulated that the submergent mode of active plate convergence obduction and subduction of sediments large ridge volume and high sea level gave rise to low erosion and sedimentation rates less restricted environments of carbonate deposition and relatively high atmospheric co 2 levels high temperatures resulting from an increased rate of production of co 2 from diagenetic and metamorphic reactions at subduction zones as sea level rose carbon was transferred from the sedimentary reservoir of reduced organic carbon to that of oxidized inorganic carbon in limestones whereas sulphur moved from the oxidized sulphate reservoir to the reduced sulphide reservoir as sea level fell reservoir transfers were opposite to those above culminating in the oscillatory mode of generally elevated continental interiors these reservoir transfers are consistent with secular changes observed in the distribution of 13 c and 34 s in sedimentary materials during the phanerozoic petrographic examination of phanerozoic oolite formations shows that ooids with preserved calcitic relict textures are characteristic of pre carboniferous carbonate rocks whereas ooids with relict textures indicative of initial aragonite mineralogy are dominant in rocks of younger age these changes in ooid mineralogy may be interpreted as reflecting changes in co 2 levels of the ocean atmosphere system consistent with the above tectonic considerations atmospheric co 2 levels were higher prior to carboniferous time favouring formation of calcitic ooids and skeletal parts after the carboniferous co 2 levels fell and aragonite and mg calcites of greater than 8 mol mg increased in abundance as precipitates

mid late miocene vegetation and environments in southeast china insights from a marine palynological record in northwestern taiwan abstract taiwan island represents the exposed accretionary prism developed by eastward subduction of south china sea scs oceanic lithosphere beneath the philippine sea plate since the middle miocene there are many well documented data about the biostratigraphic correlation except for palynological studies here we present a new palynological record of mid late miocene deposits from the chuhuangkeng section miaoli northwestern taiwan which reveals a vegetation and paleoelevation reconstruction in southeast china during the middle to late miocene corresponding to the time interval of about 14 5 5 5 ma most samples yielded well preserved palynomorphs and the palynological results suggest that the dominant vegetation was the mixed coniferous broadleaved forests in the coastal mountains of southeast china cmsc during the mid late miocene moreover based on large amounts of tsuga and picea pollen we hypothesized that a subalpine conifer forest then flourished in the cmsc and the estimated maximum paleoelevation might be up to 3000 m above sea level a s l during the mid late miocene being 1000 1500 m higher than today these findings offer a new perspective to comprehend the paleotopographic evolution of china and the source area of taiwan s spruce forests additionally the high abundance of pinus tsuga picea pollen and fern spores also suggests an enhancement of the easm during the mid late miocene

geocarbsulf a combined model for phanerozoic atmospheric o2 and co2 abstract a model for the combined long term cycles of carbon and sulfur has been constructed which combines all the factors modifying weathering and degassing of the geocarb iii model berner r a kothavala z 2001 geocarb iii a revised model of atmospheric co2 over phanerozoic time am j sci 301 182 204 for co2 with rapid recycling and oxygen dependent carbon and sulfur isotope fractionation of an isotope mass balance model for o2 berner r a 2001 modeling atmospheric o2 over phanerozoic time geochim cosmochim acta 65 685 694 new isotopic data for both carbon and sulfur are used and new feedbacks are created by combining the models sensitivity analysis is done by determining 1 the effect on weathering rates of using rapid recycling rapid recycling treats carbon and sulfur weathering in terms of young rapidly weathering rocks and older more slowly weathering rocks 2 the effect on o2 of using different initial starting conditions 3 the effect on o2 of using different data for carbon isotope fractionation during photosynthesis and alternative values of oceanic 13c for the past 200 million years 4 the effect on sulfur isotope fractionation and on o2 of varying the size of o2 feedback during sedimentary pyrite formation 5 the effect on o2 of varying the dependence of organic matter and pyrite weathering on tectonic uplift plus erosion and the degree of exposure of coastal lands by sea level change 6 the effect on co2 of adding the variability of volcanic rock weathering over time berner r a 2006 inclusion of the weathering of volcanic rocks in the geocarbsulf model am j sci 306 in press results show a similar trend of atmospheric co2 over the phanerozoic to the results of geocarb iii but with some differences during the early paleozoic and for variable volcanic rock weathering lower co2 values during the mesozoic atmospheric oxygen shows a major broad late paleozoic peak with a maximum value of about 30 o2 in the permian a secondary less broad peak centered near the silurian devonian boundary variation between 15 and 20 o2 during the cambrian and ordovician a very sharp drop from 30 to 15 o2 at the permo triassic boundary and a more or less continuous rise in o2 from the late triassic to the present

paleoceanographic changes during the early cretaceous valanginian hauterivian evidence from oxygen and carbon stable isotopes we investigated valanginian hauterivian bulk rock and belemnite samples from vocontian basin sections in southeastern france for their stable carbon and oxygen isotope signature firstly because these sections permit calibration with high resolution biostratigraphy based on ammonites and secondly because detailed isotope studies for the hauterivian are lacking the results show that 13c values for bulk rock decrease during the late valanginian early hauterivian with 1 and increase again during the late hauterivian with 1 the 18o signal for bulk rock samples is mostly disturbed by diagenesis the belemnites show carbon and oxygen isotope values that are lower and higher than bulk rock samples respectively we explain this as the result of the belemnites recording a deeper water signal with lighter 13c values and heavier 18o values implicating colder water at greater depth the overall preservation of the belemnites is very good and permits the construction of a paleo temperature trend this trend shows warm deeper water temperatures during the late early valanginian 15 c and progressively cooler temperatures during the late valanginian and early hauterivian 11 c during the late hauterivian temperatures increase again 13 c we relate this cooling trend for deeper water to a second order sea level rise which allowed for the exchange of cold boreal and warm tethyan water masses the influx of cold nutrient rich water had a profound effect on carbonate producing biota along the northern margin of the tethys during the hauterivian leading to prolonged phases of condensation and platform destruction during the early hauterivian the carbonate system along the northern tethyan margin shifted into a green water mode of carbonate production high rates of carbonate production under mesotrophic conditions also observed in other parts of the world meant that the global carbon cycle became buffered shown by the stable trends in carbon isotopes

feedbacks between oceanic redox states and marine productivity a model perspective focused on benthic phosphorus cycling a new model for the marine cycles of particulate organic carbon poc oxygen nitrate and phosphorus has been developed and applied to explore the controls and constraints on marine productivity and nutrient inventories the coupled benthic pelagic model uses a new approach for the simulation of the reactive phosphorus turnover preac corresponding to the sum of organic p authigenic p and adsorbed phosphate in marine sediments the simulated poc preac burial ratio in shelf slope and rise and deep sea sediments increases under strongly reducing conditions in agreement with field observation the model runs revealed that the spread of anoxia in bottom waters may enhance the productivity of the global ocean by one order of magnitude if sufficient nitrate is provided by n2 fixation thus anoxic bottom waters promote eutrophic conditions and vice versa additional model runs showed that the productivity and nutrient inventory of the glacial ocean were probably enhanced due to the falling sea level marine regression induced a narrowing of the depositional areas on the continental shelves and thereby an increase in the fraction of poc exported to the deep ocean the accelerated poc delivery in turn decreased the oxygen contents of the deep water and thus favored the release of phosphate from deep sea and rise sediments enhanced recycling of phosphate at the seafloor promoted further poc export in a positive feedback loop

models for the deposition of mesozoic cenozoic fine grained organic carbon rich sediment in the deep sea the widespread occurrence of organic carbon rich strata black shales in certain portions of jurassic cretaceous and cenozoic sequences has been well documented from deep sea drilling project sites in the atlantic and pacific oceans and from sequences now exposed on land originally deposited in the tethyan ocean these ancient black shales usually have been explained by analogy with examples of modern deep sea sediments in which organic matter locally is preserved by 1 increasing the supply of organic matter 2 increasing the rate of sedimentation and or 3 decreasing the oxygen content of the bottom water however detailed examination of many black shales reveals characteristics that cannot be explained by simple local models including their approximate coincidence in time globally their occurrence in a variety of different environments including open oxygenated oceans restricted basins deep and shallow water their interbedding with organic carbonpoor strata which often dominate a so called black shale sequence their deposition by pelagic hemipelagic turbiditic and other processes and the variations in type and amount of organic matter that occur even within the same sequence a more complex model for the origin of black shales therefore appears most appropriate in which the cyclic preservation of organic matter depends on the interplay of the three main variables namely supply of organic matter sedimentation rate and deep water oxygenation each of which varies independently to some extent the variation and relative importance of these parameters in individual basins and widespread black shale deposition in general are linked globally and temporally by changes in global sea level climate and related changes in oceanic circulation an important and often overlooked factor for the supply of organic matter to deep basin sediments is the frequency and magnitude of redepositional processes the interplay of these variables is discussed in relation to the middle cretaceous and cenozoic organic carbon rich strata in particular which show marked differences in the relative importance of the different variables

marine biodiversification in response to evolving phytoplankton stoichiometry abstract diversification of the marine biosphere is intimately linked to the evolution of the biogeochemical cycles of carbon nutrients and primary productivity a meta analysis of the ratio of carbon to phosphorus buried in sedimentary rocks during the past 3 billion years indicates that both food quantity and critically food quality increased through time as a result of the evolving stoichiometry nutrient content of eukaryotic phytoplankton evolving food quantity and quality was primarily a function of broad tectonic cycles that influenced not just carbon burial but also nutrient availability and primary productivity increasing nutrient availability during the middle to late proterozoic culminated in the production of food phytoplankton biomass and fresh dead organic matter with c p redfield ratios sufficient to finally promote geologically rapid biodiversification during the proterozoic phanerozoic transition this resulted in further massive nutrient sequestration into biomass that triggered positive feedback via nutrient recycling bioturbation mesozooplankton grazing on phytoplankton productivity increasing rates and depths of bioturbation through the phanerozoic suggest that nutrient recycling continued to increase increasing bioturbation and nutrient cycling appear to have been necessary to sustain the primary productivity and energetics biomass metabolic rates and physical activity such as predation of the marine biosphere because of the geologically slow input of macronutrients like phosphorus from land and the continued sequestration of nutrients into marine and terrestrial biomass

plate tectonic trigger of changes in pco2 and climate in the oxfordian late jurassic carbon isotope and modeling evidence abstract the transition from the middle to the late jurassic was characterized by significant changes in oceanography and climate and by changes in global carbon cycle as shown in the c isotope record a prominent mid oxfordian positive excursion in bulk carbonate carbon isotope values 13 c carb with an amplitude of more than 1 has been documented from many sections in the northern tethys realm in this study we present new bulk organic matter c isotope data 13 c org from northwestern tethys that do not record the mid oxfordian positive excursion in carbonate carbon on the contrary 13 c org decreases during the interval of the most rapid increase in 13 c carb we demonstrate that this decrease is not due to a changing marine terrestrial organic carbon partitioning but that the contrasting isotope trends record peculiar environmental and climate changes which occurred near the beginning of the late jurassic using a simple carbon cycle model we show that an increase in atmospheric p co 2 starting at modern levels could be the cause of contrasting trends in 13 c carb and 13 c org we suggest that a reorganisation of ocean currents related to the opening and or widening of the tethys atlantic pacific seaway and a massive spread of shallow sea carbonate production led to higher p co 2 model simulations indicate that this increase in p co 2 may have triggered changes in the biological carbon pump and in organic carbon burial that can explain the middle oxfordian c isotope record

simulated impact of altered southern hemisphere winds on the atlantic meridional overturning circulation 1 previous work has suggested that the strength and latitudinal position of the southern hemisphere sh mid latitude westerly winds has an important impact on climate and the atlantic meridional overturning circulation amoc we probe this hypothesis by conducting ensembles of experiments using the gfdl cm2 1 coupled ocean atmosphere model with altered sh wind stress we find consistent with previous work that enhanced reduced and poleward equatorward displaced sh westerly winds lead to an amoc intensification weakening while the amoc takes more than a century to respond fully to the altered sh winds initial effects in the north atlantic can occur within a few decades the amoc changes generate sst and surface air temperature responses in the north atlantic and adjacent continental regions in the southern hemisphere the atmosphere responds to the altered ocean circulation with a further strengthening and poleward movement of the sh winds thereby constituting a modest positive feedback

carbon isotope composition of upper cambrian to lower ordovician carbonate in korea and its bearing on the cambrian ordovician boundary and lower ordovician paleoceanography abstract this study presents an example of locating cambrian ordovician boundary in the lower paleozoic carbonate succession in korea using carbon isotope stratigraphy the yeongweol unit of the lower paleozoic joseon supergroup comprises the upper cambrian wagok formation and the lower ordovician mungok formation in the cambrian ordovician transition interval conventionally the boundary was placed at the lithostratigraphic boundary between the two formations this study reveals that the boundary is positioned in the basal part of the mungok formation based on the carbon isotope stratigraphy coupled with biostratigraphic information of conodont and trilobite faunas the 13c curve of the lower ordovician mungok formation shows a similar trend to that of the coeval stratigraphic interval of argentine precordillera buggisch et al 2003 suggesting that the 13c curve of the mungok formation reflects the early ordovician global carbon cycle

interpreting carbon isotope excursions carbonates and organic matter abstract variations in the carbon isotopic compositions of marine carbonate and organic carbon provide a record of changes in the fraction of organic carbon buried through time and may provide clues to changes in rates of weathering and sources of organic carbon paired carbonate and organic carbon isotope determinations provide a possibility of interpreting not only changes in the global carbon cycle through time but changes in atmospheric pco2 as well interpretations of these types of data are typically rather qualitative a quantitative basis is required to develop a better understanding of changes in the carbon cycle for this purpose we employ a simple model of the global carbon cycle which is subjected to a number of different perturbations each lasting 500 ky i e much longer than the residence times of carbon and phosphorus in the ocean atmosphere system in addition to standard considerations of carbon mass and isotopic fluxes to the ocean atmosphere system from weathering and volcanism and fluxes of organic carbon and carbonate carbon to sediments the model incorporates sensitivity of the photosynthetic carbon isotope effect to changes in pco2 the inclusion of this parameter leads to unexpected carbon isotope responses to forcing that causes increased rates of organic carbon burial a series of simple to more complex simulations illustrates the significant effects of varying differences between the carbon isotopic composition of sedimented carbonate and organic carbon b with constant b a 50 increase in organic carbon burial produces a parallel increase in carbonate and organic carbon isotopic compositions however the same simulation with b responsive to pco2 changes produces an initial parallel 13 c increase but this is followed by an even greater 13 c enrichment in organic carbon because pco2 falls in response to increased organic carbon burial the counterintuitive overall result of the enhanced organic carbon burial event is that the carbonate carbon isotopic composition actually decreases because of the more substantial increase in 13 c org in addition we illustrate the effects on carbon isotopic compositions of the oceanic inorganic carbon reservoir and buried organic matter of a 50 increase in volcanic co2 outgassing a 50 increase in weathering rate with coupled phosphate and riverine carbon flux responses a 50 decrease in shale associated organic carbon weathering a 50 decrease in silicate weathering rate and the possible effects of the rise in abundance of c4 plants in the late miocene to recent we compare the model simulated carbon isotopic responses for some of these experiments to paired carbonate and organic carbon records to illustrate how these records might be interpreted in light of the model response

orbitally paced climate evolution during the middle miocene monterey carbon isotope excursion one of the most enigmatic features of cenozoic long term climate evolution is the long lasting positive carbon isotope excursion or monterey excursion which started during a period of global warmth after 16 9 ma and ended at similar to 13 5 ma approximately 400 kyr after major expansion of the antarctic ice sheet we present high resolution 1 9 kyr astronomically tuned climate proxy records in two complete sedimentary successions from the northwestern and southeastern pacific odp sites 1146 and 1237 which shed new light on the middle miocene carbon isotope excursion and associated climatic transition over the interval 17 1 12 7 ma we recog nize three distinct climate phases with different imprints of orbital variations into the climatic signals 1146 and 123 7 delta 18 o delta 13 c 1237 xrt fe fraction 63 pm 1 climate optimum prior to 14 7 ma characterized by minimum ice volume and prominent 100 and 400 kyr variability 2 long term cooling from 14 7 to 13 9 ma principally driven by obliquity and culminating with rapid cryosphere expansion and global cooling at the onset of the last and most pronounced delta 13 c increase 3 icehouse mode after 13 9 ma with distinct 100 kyr variability and improved ventilation of the deep pacific the monterey carbon isotope excursion 16 9 13 5 ma consists overall of nine 400 kyr cycles which show high coherence with the long eccentricity period superposed on these low frequency oscillations are high frequency variations 100 kyr which closely track the amplitude modulation of the short eccentricity period in contrast to delta 13 c the delta 18 o signal additionally shows significant power in the 41 kyr band and the 1 2 myr amplitude modulation of the obliquity cycle is clearly imprinted in the 1146 delta 18 o signal our results suggest that eccentricity was a prime pacemaker of middle miocene climate evolution through the modulation of long term carbon budgets and that obliquity paced changes in high latitude seasonality favored the transition into the icehouse climate c 2007 elsevier b v all rights reserved

evidence for late jurassic release of methane from gas hydrate four late jurassic carbonate successions deposited in the tethys atlantic ocean record a negative carbon isotope excursion of at least 2 the excursion is present in both organic and carbonate carbon records and is comparable in magnitude and duration to isotopic changes during the late paleocene thermal maximum our results indicate that during the late jurassic long considered a warm greenhouse time additional greenhouse gas was input to the atmosphere by a sudden release of methane from buried gas hydrate a potential triggering mechanism may have been the opening of an oceanic gateway through the early atlantic between the ancient tethys and pacific oceans

magnetostratigraphy of the toarcian stage lower jurassic of the llanbedr mochras farm borehole wales basis for a global standard and implications for volcanic forcing of palaeoenvironmental change the lower jurassic toarcian stage c 183 174 ma is marked by one of the largest global exogenic carbon cycle perturbations of the phanerozoic which is associated with the early toarcian oceanic anoxic event t oae c 183 ma climatic and environmental change at the t oae is reasonably well constrained in the marine realm with marine anoxic or euxinic conditions developing locally across both hemispheres at the same time as the t oae negative carbon isotope excursion however high resolution stratigraphic comparison between different palaeo ocean basins and with the continental realm can be complicated palaeomagnetic reversals can provide a precise and accurate stratigraphic correlation tool between marine and continental sedimentary archives and even between sedimentary and igneous successions here we present a high resolution magnetostratigraphic record for the toarcian stage in the biostratigraphically complete and expanded llanbedr mochras farm borehole cardigan bay basin wales this study provides the first geomagnetic polarity reversal scale that is integrated with high resolution biostratigraphy and carbon isotope stratigraphy for the entire toarcian stage this stratigraphic framework also provides a new precise correlation with the basalt lava sequence of the karoo ferrar large igneous province linking the pliensbachian toarcian boundary and t oae climatic and environmental perturbations directly to this episode of major volcanic activity supplementary material details of the palaeomagnetic data and dip direction are available at https doi org 10 6084 m9 figshare c 4052720