coupling mechanisms in double sandbar systems part 1 patterns and physical explanation crescentic sandbars and rip channels along wave dominated sandy beaches are relevant to understand localized beach and dune erosion during storms in recent years a paradigm shift from hydrodynamic template models to self organization mechanisms occurred to explain the formation of these rhythmic features in double sandbar systems both the inner and outer bar rip channels and crescentic planshapes are now believed to be free instabilities of the nearshore system arising through self organization mechanisms alone however the occasional occurrence of one or two inner bar rip channels within one outer bar crescent suggests a forced morphologically coupled origin here we use a nonlinear morphodynamic model to show that alongshore variability in outer bar depth and the relative importance of wave breaking versus wave focussing by refraction across the outer bar is crucial to the inner bar rip channel development the coupling patterns simulated by our model are similar to those observed in the field morphological coupling requires a template in the morphology outer bar geometry which through the positive feedback between flow sediment transport and the evolving morphology that is self organization enforces the development of coupling patterns we therefore introduce a novel mechanism that blurs the distinction between self organization and template mechanisms this mechanism may also be extended to explain the dynamics of other nearshore patterns such as beach cusps the impact of this novel mechanism on the alongshore variability of inner bar rip channels is investigated in the companion paper copyright 2010 john wiley and sons ltd

genesis of fumarolic emissions as inferred by isotope mass balances co2 and water at vulcano island italy we have developed a quantitative model of co2 and h2o isotopic mixing between magmatic and hydrothermal gases for the fumarolic emissions of the la fossa crater vulcano island italy on the basis of isotope balance equations the model takes into account the isotope equilibrium between h2o and co2 and extends the recent model of chemical and energy two end member mixing by nuccio et al 1999 as a result the h2o and co2 content and the d 18o and 13c isotope compositions for both magmatic and hydrothermal end members have been assessed low contributions of meteoric steam added at a shallow depth have been also recognized and quantified in the fumaroles throughout the period from 1988 to 1998 nonequilibrium oxygen isotope exchange also seems to be occurring between ascending gases and wall rocks along some fumarolic conduits the 13cco2 of the magmatic gases varies around 3 to 1 vs peedee belemnite pdb following a perfect synchronism with the variations of the co2 concentration in the magmatic gases this suggests a process of isotope fractionation because of vapor exsolution caused by magma depressurization the hydrogen isotopes in the magmatic gases 1 to vs standard mean ocean water smow as well as the above 13cco2 value are coherent with a convergent tectonic setting of magma generation where the local mantle is widely contaminated by fluids released from the subducted slab magma contamination in the crust probably amplifies this effect the computed isotope composition of carbon and hydrogen in the hydrothermal vapors has been used to calculate the d and 13c of the entire hydrothermal system including mixed h2o co2 vapor liquid water and dissolved carbon we have computed values of about 10 vs smow for water and 2 to 6 5 vs pdb for co2 on these grounds we think that mediterranean marine water dh2o 10 feeds the hydrothermal system it infiltrates at depth throughout the local rocks reaching oxygen isotope equilibrium at high temperatures interaction processes between magmatic gases and the evolving seawater also seem to occur causing the dissolution of isotopically fractionated aqueous co2 and providing the source for hydrothermal carbon these results have important implications concerning fluid circulation beneath vulcano and address the more convenient routine of geochemical surveillance

storm induced response of a nearshore bar system abstract a nearshore bar system was surveyed periodically through a storm and the following recovery period the data showed a very rapid response of morphology to changing wave conditions and allowed various models on bar formation to be tested under low energy conditions prior to the storm a small bar was surveyed 13 m offshore both the high reflectivity of the beach and the cross shore distance to the bar are consistent with a model of sediment convergence at the node or antinode of a standing wave of incident period such a small scale bar may be a common feature on beaches with steep foreshores and more gentle offshore slopes with the increase in wave height during the storm the bar became better developed and migrated offshore at rates up to 2 2 m h 1 the bar maintained its form in that the ratio of trough depth to crest depth h t h c remained roughly constant the bar was in no way related to processes which would cause the convergence of sediment in the breaker zone through most of the storm the bar crest distance offshore was typically only 10 of the surf zone width analysis of the bar distance offshore in terms of a standing wave motion showed that the causative wave period must have been much longer than that of incident waves probably on the order of a minute surf zone wave data showed significant energy in the infragravity band at these periods although no definite link has been made after the height of the storm the bar had a crescentic morphology the development of this morphology occurred very rapidly with parts of the bar migrating onshore at rates up to 1 2 m h 1 in contrast to the storm during the recovery period h t h c varied by nearly a factor of three analysis of the offshore and longshore length scales showed the bar to be similar to one which would be generated by a standing mode 1 edge wave of period on the order of one minute

single crystal 40ar 39ar dating of a late quaternary paroxysm on kos greece concordance of terrestrial and marine ages the late quaternary plinian eruption forming the kos plateau tuff on the island of kos greece was one of the largest in the mediterranean a precise date for this eruption would significantly improve the chronology of the deep sea tephra layer w 3 because reliable correlation of w 3 with the kos plateau tuff has been previously established we have dated sanidine from the eruption at 161 3 1 1 ka using the laser fusion single crystal 40ar 39ar technique this age represents a significant refinement over both conventional and highly precise cassignol method k ar ages and the 40ar 39ar age is shown to be in remarkably good agreement with the age of w 3 inferred from recent astronomically calibrated oxygen isotope chronologies

new gas geothermometers for geothermal exploration calibration and application calibration of five gas geothermometers is presented three of which used co2 h2s and h2 concentrations in fumarole steam respectively the remaining two use co2h2 and h2sh2 ratios the calibration is based on the relation between gas content of drillhole discharges and measured aquifer temperatures after establishing the gas content in the aquifer gas concentrations were calculated in steam formed by adiabatic boiling of this water to atmospheric pressure to obtain the gas geothermometry functions it is shown that the concentrations of co2 h2s and h2 in geothermal reservoir waters are fixed through equilibria with mineral buffers at temperatures above 230 c epidote prehnite calcite quartz are considered to buffer co2 two buffers are involved for h2s and h2 and two functions are therefore presented for the geothermometers involving these gases for waters containing less than about 500 ppm chloride and in the range 230 300 c pyrite pyrrholite epidote prehnite seem to be involved but pyrite epidote prehnite magnetite or chlorite for waters above 300 c and waters in the range 230 300 c if containing over about 500 ppm the gas geothermometers are useful for predicting subsurface temperatures in high temperature geothermal systems they are applicable to systems in basaltic to acidic rocks and in sediments with similar composition but should be used with reservation for systems located in rocks which differ much in composition from the basaltic to acidic ones the geothermometry results may be used to obtain information on steam condensation in upflow zones or phase separation at elevated pressures measured aquifer temperatures in drillholes and gas geothermometry temperatures based on data from nearby fumaroles compare well in the five fields in iceland considered specifically for the present study as well as in several fields in other countries for which data were inspected the results of the gas geothermometers also compare well with the results of solute geothermometers and mixing models in three undrilled icelandic fields

geochemistry of some gases in hydrothermal fluids from the southern juan de fuca ridge five samples of hydrothermal fluids from two vent areas on the southern juan de fuca ridge were analyzed for dissolved gases concentrations in the end member hydrothermal fluid of h2 270 527 mol kg ch4 82 118 mol kg and co2 3920 4460 mol kg are well above values in ambient seawater and are similar to concentrations reported for other ridge crest hydrothermal systems the carbon isotopic ratios of the ch4 13c 17 8 to 20 8 and co2 13c 3 6 to 4 7 suggest that at least some of the ch4 and co2 in the fluids is basalt derived the range of 13c values for the basalt derived co2 is 6 8 to 9 7 calculated by assuming conservation of recharge co2 during hydrothermal circulation apparent temperatures of equilibration between the ch4 and the basalt derived co2 range from 640 c to 750 c small amounts of ethane c2h6 ch4 0 9 10 3 2 2 10 3 propane and butane detected in the samples may also have formed in the basalt one sample of almost pure 95 5 hydrothermal fluid contained a significant fraction up to 63 and 74 respectively of the recharge ar and n2 this suggests that the fluid has not undergone extensive vapor liquid phase separation

intense ch4 plumes generated by serpentinization of ultramafic rocks at the intersection of the 15 20 n fracture zone and the mid atlantic ridge abstract as part of the fara french us program designed to study the mid atlantic ridge mar between 15 n and the azores twenty three dives with the submersible nautile were conducted during the french us faranaut 15n cruise on the eastern and western parts of the 15 20 n fracture zone ridge axis intersection south of the eastern ridge transform fault intersection nine nautile dives were made within the rift valley and along the western rift valley wall ch4 concentrations in the bottom waters reach 53 2 nmol kg along faulted zones on top and on the east flank of the ultramafic inner corner high 15 05 n 44 59 w where serpentinized rocks outcrop no 3he anomaly is associated with methane ruling out any primary mantle component fourteen dives were also made in the rift valley to the north close to the western intersection of the 15 20 n transform high ch4 anomalies up to 22 nmol kg are also present in the bottom waters of the rift valley northern segment on both the western and eastern valley walls and on the inner high adjacent to the eastern wall where ultramafic rocks outcrop seven vertical hydrocasts carried out in the axial valley 4500 m deep show an intense ch4 anomaly with a maximum 35 8 nmol kg at 3200 m depth this ch4 concentration is among the highest found along the mid atlantic ridge charlou and donval 1993 charlou et al 1997 ch4 concentrations of 9 9 14 9 nmol kg are also present on the western wall along the 3200 m isobath the high ch4 concentrations correspond to only weak 3he anomalies this ch4 rich plume is also associated with active fault zones that expose peridotite rocks ch4 output from ultramafic outcrops on the western and eastern intersections of the 15 20 n fracture zone with the mar is believed to reflect ongoing serpentinization these results associated with many other ch4 anomalies measured in the water column above ultramafic outcrops found between 12 n and the azores most likely reflect serpentinization processes extending along the whole slow spreading mid atlantic ridge

geochemical and isotopic evidences of magmatic inputs in the hydrothermal reservoir feeding the fumarolic discharges of tacora volcano northern chile abstract tacora volcano is a nearly unknown and understudied 5980 m high volcano located on the northernmost border between chile and peru tacora is characterized by intense fumarolic activity with extensive white colored hydrothermal areas along the nw and w flanks of the volcanic structure the chemical and isotopic features of gas emissions indicate that the hydrothermal reservoir is significantly affected by contributions from magmatic degassing despite relatively low outlet temperatures 82 93 c water and gas isotopic signatures stem from degassing of andesitic magmas produced from the sediment poor subducting slab isotopic data suggests ch 4 co 2 isotopic equilibration occurs at 400 c likely in the deepest portion of the hydrothermal magmatic fluid reservoir the h 2 h 2 o co co 2 h 2 ar ch 4 co 2 and c 2 c 3 alkenes alkanes pairs tend to approach a chemical equilibrium at temperatures between 200 and 320 c when redox conditions are more oxidizing than those determined by the typical feo feo 1 5 rock buffer system boiling occurs at shallow depth at 85 c within a discontinuous thin aquifer enough as thermal buffer but not able to scrub the uprising magmatic related acidic gases

fluid geochemistry of nisyros island dodecanese greece abstract two distinct hydrothermal aquifers are present beneath the lakki plain a a deep aquifer characterized by temperatures higher than 290 c and chloride rich fluids and b a shallow aquifer with a chloride content close to that of sea water and temperatures in the range 170 255 c the vapor phase boiled from the shallow aquifer feeds the fumarolic vents in the southern half of the lakki plain and its liquid phase flows northeast and southwest contributing to the thermal springs located along the northern and southern coasts of the island this conceptual hydrogeochemical model of nisyros island can be used to reconstruct past hydrothermal eruptions and to estimate the risk of such events happening again in the future

water rock interaction in the magmatic hydrothermal system of nisyros island greece abstract in this work we investigated the water rock interaction processes taking place in the hydrothermal reservoir of nisyros through both 1 a review of the hydrothermal mineralogy encountered in the deep geothermal borehole nisyros 2 and 2 a comparison of the analytically derived redox potentials and acidities of fumarolic related liquids with those controlled by redox buffers and ph buffers involving hydrothermal mineral phases the propylitic zone met in the deep geothermal borehole nisyros 2 from 950 to 1547 m total depth is characterised by abundant well crystallised epidote adularia albite quartz pyrite chlorite and sericite muscovite accompanied by less abundant anhydrite stilpnomelane wairakite garnet tremolite and pyroxene these hydrothermal minerals were produced in a comparatively wide temperature range from 230 to 300 c approximately hydrothermal assemblages are well developed from 950 to 1360 m whereas they are less developed below this depth probably due to low permeability based on the r h values calculated for fumarolic gases and for the deep geothermal fluids of nisyros 1 and nisyros 2 wells redox equilibrium with the feo feo 1 5 rock buffer appears to be closely attained throughout the hydrothermal reservoir of nisyros this conclusion may be easily reconciled with the nearly ubiquitous occurrence of anhydrite and pyrite since r h values controlled by coexistence of anhydrite and pyrite can be achieved by gas separation the ph of the liquids feeding the fumarolic vents of stephanos and polybote micros craters was computed by means of the eq3 code based on the cl d relationship which is constrained by the seawater magmatic water mixing occurring at depth in the hydrothermal magmatic system of nisyros the temperature dependence of analytically derived ph values for the reservoir liquids feeding the fumarolic vents of stephanos and polybote micros craters suggests that some unspecified ph buffer fixes the acidity of these reservoir liquids at values of 4 72 4 85 and 4 88 5 23 respectively many of these ph values are lower than those expected for the full equilibrium condition although they are close to those of the reservoir liquids of nisyros 1 5 16 and nisyros 2 4 87 it is likely that this excess of acidity producing species chiefly co 2 promotes release of fe ii and fe iii to the reservoir liquids through rock dissolution permitting the attainment of redox equilibrium with the feo feo 1 5 rock buffer as already suggested by the late werner giggenbach

excess methane in continental hydrothermal emissions is abiogenic thermogenic hydrocarbons entirely deriving from the thermal degradation of organic matter usually exhibit methane to ethane plus propane ratios smaller than 100 we present hydrocarbon distribution data of continental hydrothermal gases whose methane has been independently identified to derive from the abiogenic reduction of co2 we find that excess amounts of methane with respect to thermogenic hydrocarbon distributions are characteristic for the investigated gases a similar pattern is observed for well discharges whose temperatures are too high to support any microbially mediated methanogenesis these findings strongly suggest that abiogenic methane production in continental hydrothermal systems is a more widespread process than previously assumed the maximum contribution of such emissions to the modern atmospheric ch4 budget is estimated at 1

resonant wave reflection by transverse bedforms and its relation to beaches and offshore bars abstract on an erodible sand bed there may be a coupling between the reflection of incident wave energy and the development of transverse bedforms the nature of this interaction is examined with particular reference to a laboratory experiment in which a veneer of sand was introduced into a pre existing fixed pattern of bars the observed motion of the mobile sand suggested potential development of this existing bar system in the up wave direction but not in the down wave direction it is argued here that this phenomenon may be significant in terms of the growth of shore parallel bars off beaches and for coastal protection in general

chemical and isotopic equilibrium between co2 and ch4 in fumarolic gas discharges generation of ch4 in arc magmatic hydrothermal systems the chemical and isotopic composition of fumarolic gases emitted from nisyros volcano greece and of a single gas sample from vesuvio italy was investigated in order to determine the origin of methane ch4 within two subduction related magmatic hydrothermal environments apparent temperatures derived from carbon isotope partitioning between ch4 and co2 of around 340 c for nisyros and 470 c for vesuvio correlate well with aquifer temperatures as measured directly and or inferred from compositional data using the h2o h2 co2 co ch4 geothermometer thermodynamic modeling reveals chemical equilibrium between ch4 co2 and h2o implying that carbon isotope partitioning between co2 and ch4 in both systems is controlled by aquifer temperature n2 3he and ch4 3he ratios of nisyros fumarolic gases are unusually low for subduction zone gases and correspond to those of midoceanic ridge environments accordingly ch4 may have been primarily generated through the reduction of co2 by h2 in the absence of any organic matter following a fischer tropsch type reaction however primary occurrence of minor amounts of thermogenic ch4 and subsequent re equilibration with co existing co2 cannot be ruled out entirely co2 3he ratios and 13cco2 values imply that the evolved co2 either derives from a metasomatized mantle or is a mixture between two components one outgassing from an unaltered mantle and the other released by thermal breakdown of marine carbonates the latter may contain traces of organic matter possibly decomposing to ch4 during thermometamorphism

magmatic helium in subduction zone natural gases abstract he isotope ratios provide important constraints on the input of magmatic gases into crustal systems natural gas associated with active continental margins from taiwan r o c new zealand the philippines indonesia thailand and alaska u s a contain a magmatic he component based on measured 3 he 4 he ratios r ranging from 0 5 to 3 8 times the atmospheric value ra the methane helium results can be interpreted as the result of a mixture between a low 3 he 4 he 0 01r a high ch 4 3 he crustal end member and a high 3 he 4 he 0 6 3 9r a low ch 4 3 he 6 magmatic component the presence of mantle he does not require significant amounts of mantle methane a better fit to the data is obtained using a zero methane magmatic end member the worldwide association of 3he and magmatic activity suggests that volcanism plays a role in methane generation by supplying the heat needed to convert organic matter to methane thermogenically only gases from the accretionary prism of barbados west indies appear totally devoid of magmatic he 3 he 4 he ratio 0 02ra the he is completely of crustal origin there is no evidence that faults within the accretionary prism of this fore arc act as conduits for the migration of mantle he many of the gases studied contain significant quantities of co2 which appear to result from two processes 3 he 4 he high co 2 3 he gases 0 01ra 1011 possibly result from decarbonation reactions in the crust while the high 3 he 4 he low co 2 3 he gases 2 4ra

bedforms and depositional sedimentary structures of a barred nearshore system eastern long island new york abstract the depositional sedimentary structures and textures of a single barred nearshore system on the atlantic coast of eastern long island new york were studied along seven shore normal transects data along these transects consisted of textural analysis of 160 sediment samples temporal bedform observations and 42 can cores for the analysis of sedimentary structures six sedimentary subenvironments were observed based on distinct combinations of sediment color and texture bedforms physical and biogenic sedimentary structures and benthic infaunal communities the shoreface environment is divided into the upper shoreface the longshore trough and the longshore bar the divisions of the inner shelf environment are the shoreface inner shelf transition the offshore and the coarse grained deposit the first five subenvironments are arranged in bands parallel to the shoreline whereas the coarse grained deposit occurs in patches across the inner shelf the location of fair weather wave base coinciding with a reduction in slope 3 0 0 3 from the shoreface to the inner shelf is characterized by the cessation of debris surge in the troughs of ripples the formation of a rust layer of microorganisms over the bedform surface and a sediment color change caused by an increase in organic detritus the sequence of bedforms and physical sedimentary structures observed in this system fits well with existing wave generated oscillatory flow regime models these models explain the observed sequences as a response to the degree of asymmetric flow created by shoaling waves distribution of biogenic structures and assemblages of infaunal organisms is influenced by the distance landward or seaward of fair weather wave base the overall relationships of this nearshore system can then be summarized as a hypothetical prograding stratigraphic sequence the entire sequence is underlain by organic rich bioturbated offshore deposits overlying the offshore is the planar laminated sediments of the transition grading upward from the transition are the cleaner planar laminated seaward slope deposits of the longshore bar above this is a distinct erosional surface indicating the base of the massive to cross laminated coarse sediments of the longshore trough capping the sequence are the cross to planar laminated clean sands of the upper shoreface and foreshore

methane origin and oxygen fugacity evolution of the baogutu reduced porphyry cu deposit in the west junggar terrain china most porphyry copper deposits worldwide contain magnetite hematite and anhydrite in equilibrium with hypogene copper iron sulfides chalcopyrite bornite and have fluid inclusions with co2 ch4 that are indicative of high fo2 in contrast the baogutu porphyry cu deposit in the west junggar terrain xinjiang china lacks hematite and anhydrite contains abundant pyrrhotite and ilmenite in equilibrium with copper iron sulfides chalcopyrite and has fluid inclusions with ch4 co2 that are indicative of low fo2 the mineralized intrusive phases at baogutu include the main stage diorite stock and minor late stage diorite porphyry dikes the main stage stock underwent fractional crystallization and country rock assimilation contamination and consists of dominant diorite and minor gabbro and tonalite porphyry the country rocks contain organic carbons 0 21 0 79 wt the 13cvpdb values of the whole rocks 23 1 to 25 8 in the wall rocks suggest a sedimentary organic carbon source the 13cvpdb values of ch4 28 2 to 36 0 and co2 6 8 to 20 0 in fluid inclusions require an organic source of external carbon and equilibration of their 13cco2 ch4 values 8 2 25 0 at elevated temperatures 294 830 c suggesting a significant contribution of thermogenic ch4 mineral composition data on the main stage intrusions such as clinopyroxene hornblende biotite magnetite ilmenite sphene apatite and pyrrhotite suggest that the primary magma at baogutu was oxidized and became reduced after emplacement by contamination with country rocks mineral compositions and fluid inclusion gas compositions suggest that the redox state of the system evolved from logfo2 fmq 1 in the magma stage to logfo2 fmq in the hydrothermal stage though oxidized magma was emplaced initially assimilation contamination of carbonaceous country rocks decreased its fo2 such that exsolved fluids contained abundant ch4 and deposited a reduced assemblage of minerals

geographical distribution of 3he 4he ratios in japan implications for arc tectonics and incipient magmatism the 3he 4he and 4he 20ne ratios of 115 natural gas samples including various types of gases from volcanoes hot springs mineral springs water wells petroleum fields and natural gas fields were measured using a mass spectrometer the observed 3he 4he and 4he 20ne ratios range from 7 47 10 8 to 9 65 10 6 and from 0 26 to 1100 respectively the 3he 4he ratios reflect well the geotectonic structure of the japanese islands in northeastern ne japan there is a clear geographical difference in the 3he 4he ratios between the frontal arc forearc and volcanic arc back arc regions lower ratios were found in the trench side region and higher ratios in the back arc side this result suggests that the mantle derived helium in the volcanic arc region is associated with the diapiric uprise of a magma lower 3he 4he ratios in the frontal arc region may be due to radiogenic he produced by radioactive decay of u and th in the crustal and sedimentary rocks in southwestern sw japan there is no clear geographical contrast in the 3he 4he ratios some samples in the frontal arc region show quite high 3he 4he ratios the tendency of the 3he 4he ratios agrees with the distribution of terrestrial heat flow data and reflects geotectonic structures different from ne japan the high 3he 4he ratios observed in the frontal arc region in sw japan may be indicative of renewed or incipient magmatism due to a descending young and warm slab

analysis of observed two and three dimensional nearshore bar behaviour abstract shore parallel sandbar systems often exhibit considerable quasi regular alongshore variations such as crescentic plan shapes therefore morphological change in such systems commonly consists of two and three dimensional variability the former is related to overall on offshore bar migration whereas the latter is induced by the horizontal amplitude growth migration or length scale change of the quasi regular topography in this paper we used a six week data set of bathymetric surveys and video images of breaking induced foam to quantify short term days weeks two and three dimensional variability in the bar crest position of the double barred beach at egmond aan zee netherlands the alongshore uniform response was computed as the mean of each bar crest line whereas the alongshore non uniform behaviour was characterised by the amplitude around each mean a more sophisticated description of the inner bar data set was provided by complex empirical orthogonal function ceof analysis the first complex mode containing about 85 of the variance in the data set corresponded to the amplitude growth and longshore migration of an approximately 600 m long alongshore non uniformity the longshore migration rate varied between 0 and 150 m day and was found to be well related to the longshore component of the offshore wave energy flux the second complex mode explained about 10 of the variance and largely described the alongshore averaged cross shore bar migration the ceof results suggest that short term variability in bar crest position is largely due to changes in the quasi regular topography and not to alongshore uniform on offshore oriented behaviour

dynamics of a nearshore bar system in the northern adriatic a video based morphological classification abstract the aim of this paper is to define a simplified morphodynamic classification suitable for low energy beaches exposed to microtidal conditions the study site is located in the northern adriatic in italy it is an almost 2 km long rectilinear beach bordered at the northern edge by coastal structures and at the southern end by a small river inlet the mechanisms related to the evolution of the submerged part of the beach were derived from video monitoring using argus technology the morphodynamic evolution of the system was studied using an automatic procedure on images for the characterisation of nearshore bars that showed good correspondence with hand based visual interpretation to apply this automatic procedure the bar s plan crest shape was mapped using cross shore pixel luminosity transects traced on time averaged video images a careful sensitivity analysis was undertaken to determine the best spacing between transects for the correct tracing of the shape of the bar crest the error associated to a transect spacing every 25 m resulted in being comparable with the pixel resolution in the area and with the error found comparing the video interpretation with bathymetric surveys from the study of a four and a half year dataset february 2003 may 2007 the submerged beach was found to be characterised by the presence of a single bar in the area next to coastal protection structures however moving southwards of these inner and outer bars were present the morphodynamics of the outer bar and its plan shape modifications were dominated by rhythmic forms occasionally after high energy events the bar became rectilinear but during the following lower energy periods rhythmicity was re established supporting the hypothesis of self organization mechanisms the cross shore position of the bar s crests only showed limited cross shore mobility through time

gases and helium isotopes in high temperature solutions sampled before and after odp leg 158 drilling at tag hydrothermal field 26 n mar hydrothermal fluids were sampled for dissolved gases at tag 26 n mar during two alvin dive series in april may 1993 and march 1995 respectively 17 months before and 4 months after ocean drilling program leg 158 total gas volumes extracted from the 1993 and 1995 samples are of the same order of magnitude even if some increase in h2s c02 and ch4 was noticeable in the 1995 samples no significant difference was observed in helium concentration and helium isotopic ratio 3 he 4 he 8 2 0 1 ra the ch4 3 he ratio found in black smokers sampled in 1993 is around 9 x 10 6 close to ratio found in mar basalts in 1995 this ratio is around 4 times higher due to the ch4 increase the 13 c in c02 measured on two black smokers sampled in 1993 is uniform at 8 4 to 8 8 versus pdb while a 13 c value of 13 is measured at a new site sampled in 1995 located 40 meters east of the main black smokers complex bsc ch4 3 he and 13 c values both point to a mainly magmatic abiogenic origin of the carbon species in the system overall comparison of the 1993 and 1995 data suggests that the hydrothermal circulation is continuing through the basaltic layer carrying helium c02 and ch4 of magmatic origin even if some thermogenic ch4 contribution seems likely in the 1995 samples collected in the new active area we can speculate that the 1994 drilling may have modified the previously steady state hydrothermal circulation in the tag mound and temporarily enhanced the hydrothermal circulation by opening new pathways favouring transient input of ch4 rich fluids before coming back to a new steady state

multiple origins of methane in the earth methane occurrences in the earth s crust are predominantly of biogenic origin i e their ultimate source is biologically formed organic matter methane can also form through inorganic reactions and is consequently termed abiogenic biogenic methanes can either form through bacterial or thermogenic processes bacterial processes follow a co2 reduction and or fermentation pathway the fermentation processes are quantitatively more important in recent fresh sediments and swamps methane formed by co2 reduction however is most common in older sediments and commercial gasfields temperature organic substrate and age may be the major factors controlling the relative importance of the two pathways stable isotope concentrations in thermogenic methanes seem to be controlled by the extent of conversion of organic matter the timing of gas expulsion and trapping the different character of methane in individual sedimentary basins may be a result of the geologic history geothermal methanes are most likely derived from pyrolysis of organic matter abiogenic methane occurs in hydrothermal vents and ophiolite complexes inorganic reactions either surficial or deep seated are the likely source of such methanes a uniform mantle origin of methane is not supported by the observed isotope variations in naturally occurring methanes

waves currents sediment flux and morphological response in a barred nearshore system abstract a shore normal array of seven bi directional electromagnetic flowmeters and nine surface piercing continuous resistance wave staffs were deployed across a multiple barred nearshore at wendake beach georgian bay canada and monitored for a complete storm cycle time integrated estimates of total itvf and net invf sediment volume flux together with bed elevation changes were determined using depth of activity rods the three bars ranging in height from 0 10 to 0 40 m accreted during the storm 0 03 m and the troughs were scoured 0 05 m sediment reactivation depths reached 0 14 m and 12 of the nearshore control volume was mobilized however the invf value for the storm was less than 1 of the control volume revealing a near balance in sediment volume in the bar system landward migration of the inner crescentic and second sinuous bars occurred in association with an alongshore migration of the bar form itself the outermost straight shore parallel bar remained fixed in location the surf zone was highly dissipative throughout the storm 3 8 10 2 192 10 2 and the wave spectrum was dominated by energy at the incident frequency spectral peaks at frequencies of the first harmonic and at one quarter that of the incident wave were associated with secondary wave generation just prior to breaking and a standing edge wave respectively the former spectral peak was within the 95 confidence band for the spectrum while the latter contributed not more than 10 to the total energy in the surface elevation spectrum even near the shoreline during the storm wave height exceeded 2 m h s and periods reached 5 s t p k orbital velocities exceeded 0 5 m s 1 u rm s and were above the threshold of motion for the medium to fine sands throughout the storm shore parallel flows in excess of 0 4 m s 1 were recorded with maxima in the troughs and minima just landward of the bar crest the rate and direction of sediment flux is best explained by the interaction of antecedent bed slopes with spatial gradients in the mean and asymmetry of the shore normal velocity field these hydrodynamic parameters represent steady flows superimposed on the dominantly oscillatory motion and assumed a characteristic spatial pattern from the storm peak through the decay period increases spatially in the magnitudes of both the mean flows and flow asymmetries cause an increasing net transport potential erosion decreases in these values spatially cause a decreasing net transport potential and thus deposition these transport potentials are increased or decreased through the gravity potential induced by the local bed slope shore parallel flow was important in explaining sediment flux and morphological change where orbital velocities mean flows and flow asymmetries were at a minimum

origin of carbon in fumarolic gas from island arcs abstract we have measured 3 he 4 he ratios 13c values and co 2 3 he ratios of fumaroles and hot spring gases in three volcanic areas in japan the 3 he 4 he ratios 13c values and co 2 3 he ratios vary from 02 05 ratm 9 7 to 2 7 and from 7 74 109 to 1 18 1011 respectively based on these data and those in the literature we present the first quantitative estimates of the upper mantle sediment and limestone including slab components in co2 of volcanic and hydrothermal fluids from subduction zones taking compiled c isotopic data of limestone and organic sediment assuming that the co 2 3 he ratio and 13c value of mid ocean ridge basalt morb are representative of the upper mantle component and that later isotopic and elemental fractionations are minimal it is possible to deconvole each fraction of c on the basis of simple mixing equations up to 20 of the carbon in high temperature volcanic gases in subduction zones is derived from a morb type source while the major fraction of the gases is attributable to co2 produced by decarbonation of subducted marine limestone and slab carbonate

coupling mechanisms in double sandbar systems part 2 impact on alongshore variability of inner bar rip channels double sandbar systems are common morphological features along sandy wave dominated micro to meso tidal coastlines in the companion paper we demonstrated how various alongshore inner bar rip channel patterns can develop through morphological coupling to an alongshore variable outer bar the simulated coupling patterns are however scarcely observed in the field instead inner bar rip channels more often possess remarkably smaller and more variable alongshore length scales suggesting that coupling mechanisms do not play a substantial role in the overall double sandbar dynamics here we use a numerical model to show that the relative importance of self organization and morphological coupling changes in favour of the latter with an increase in waterdepth variability along the outer bar crest furthermore we find that the typical alongshore variability in inner bar rip channel scale is indicative of a mixture of self organization and morphological coupling rather than self organization alone morphological coupling may thus be more important to understanding and predicting the evolution of inner bar rip channels than previously envisaged copyright 2010 john wiley and sons ltd

hydrogen isotopic compositions of hydrogen and methane from some volcanic areas in northeastern japan abstract d h ratios of volcanic condensates hydrogen and methane collected from hachimantai zao azuma nasu and kusatsu shirane volcanic areas in northeastern japan were determined together with chemical components on the basis of the isotopic ratios for volcanic condensates it is concluded that most of the water vapor is essentially local surface water which has been heated and slightly enriched in18o by exchange with silicates d values of hydrogen and methane range from 220 to 515 smow and from 180 to 487 smow respectively the d h ratio in volcanic hydrogen indicates that hydrogen may have isotopically equilibrated with water vapor at temperatures between 200 and 400 c the d value of methane also suggests that volcanic methane has been in isotopic disequilibrium with the water vapor and hydrogen and that most of the methanes may be thermogenic methanes produced by pyrolysis of carbonaceous materials

flow characteristics at the rip current neck under low energy conditions abstract this paper presents the flow signature of the rip current neck as determined by fourteen near bottom velocity records with a comparison made to 63 recordings in the surf zone the field experiments including wave monitoring and morphological mapping were conducted under relatively calm dissipative wave conditions tsig 3 6 s hsig 0 3 1 1 m at herzliya beach israel on the mediterranean shore the current data were analysed for shore normal and resultant components the processing of the time series in the form of instantaneous and smoothed velocities provided spectral energy orbital and current velocity specific current discharge and directional distribution data the unique characteristic of the neck environment was found to be its continuous unidirectional seaward flow due to the channeling effect this steady offshore drift constituted the fastest flow in the surf zone with a typically narrow 35 94 directional range through spectral analysis of the unidirectional return flow the morphodynamic process signature at the rip neck was defined by the relative contribution from the incident waves 78 the subharmonic edge waves 14 and the infragravity oscillations 8 the pulsatory jet like rip model with concentration of energy at low frequencies is not corroborated by this study the studied environment of the rip and bar pattern represented an inherited beach morphology at an initial accretional although not yet reflective stage

abiogenic methanogenesis in crystalline rocks isotopically anomalous ch4 rich gas deposits are found in mining sites on both the canadian and fennoscandian shields with 13cch4 values from 22 4 to 48 5 and dch4 values from 133 to 372 these methane deposits cannot be accounted for by conventional processes of bacterial or thermogenic methanogenesis compositionally the gases are similar to other ch4 rich gas occurrences found in canadian and fennoscandian shield rocks sherwood lollar et al 1993 however the isotopically anomalous gases of this study are characterized by unexpectedly high concentrations of h2 gas ranging from several volume percent up to 30 vol the h2 gases are consistently depleted in the heavy isotope with dh2 values of 619 to 659 3h 4he ratios in the range of 0 4 10 8 to 4 4 sx 10 8 indicate that there is no resolvable component of mantle derived he in these deposits based on these results a mantle derived source for the c bearing gases is unlikely several lines of evidence support an alternative abiogenic origin for the gases from sudbury canada and juuka and pori finland the d depleted h2 gas and calculated d ch4 h2 equilibration temperatures of 110 170 c at all three sites are in good agreement with results obtained for abiogenically produced ch4 and h2 in ophiolite sequences in oman and the philippines serpentinization and the hydration of ultramafic rocks are the proposed mechanisms for ch4 and h2 production in these ophiolite sequences the widespread occurrence of serpentinized and altered ultramafic rocks at juuka and at a number of other sites in both canada and finland implies that similar mechanisms may be involved in gas production at at least three sites on the shields the origin of the gases at the remaining shield sites is discussed alternative hypothesis include 1 production of the rest of the shield gases by mixing between abiogenic endmembers and bacterially generated hydrocarbon gas such as identified elsewhere on the canadian and fennoscandian shields sherwood lollar et al 1993 and 2 production of a series of isotopically distinct abiogenic ch4 endmembers at each site due to variability in the isotopic composition of available carbon sources we cannot conclusively distinguish between the alternative scenarios based on existing data however the evidence for an abiogenic ch4 endmember at at least three sites emphasizes the need for substantial revision of current theories of methanogenesis abiogenic processes of ch4 production may be considerably more widespread than previously anticipated

development of a shoreline rhythm outer banks of north carolina abstract a shoreline rhythm was studied at duck north carolina during june of 1980 and 1981 the results of both studies show that the shoreline rhythm developed when small waves approaching the shoreline at an oblique angle rebuilt the beach following an erosional event storm waves on the other hand eroded the rhythm when the shore was being rebuilt small waves and associated longshore currents reshaped the nearshore topography from a shoal to a longshore bar one end of the bar became attached to the beach and in turn caused an increase in the horizontal distance between the tip of the horn and the adjacent bay of the rhythm twice amplitude as more sediments were transported from the nearshore and deposited on the horn twice amplitude continued to increase however as the beach prograded at the horn the beach located at adjacent bays did not rebuild nor was it eroded because rip currents were noted in bay regions of the rhythm it is suggested that these currents prevented nearshore sediments from being transported and deposited on bay beaches thus the increase of the rhythm amplitude was caused more by deposition occurring at the horn than of erosion taking place in the adjacent bays

self organization mechanisms for the formation of nearshore crescentic and transverse sand bars the formation and development of transverse and crescentic sand bars in the coastal marine environment has been investigated by means of a nonlinear numerical model based on the shallow water equations and on a simplified sediment transport parameterization by assuming normally approaching waves and a saturated surf zone rhythmic patterns develop from a planar slope where random perturbations of small amplitude have been superimposed two types of bedforms appear one is a crescentic bar pattern centred around the breakpoint and the other herein modelled for the first time is a transverse bar pattern the feedback mechanism related to the formation and development of the patterns can be explained by coupling the water and sediment conservation equations basically the waves stir up the sediment and keep it in suspension with a certain cross shore distribution of depth averaged concentration then a current flowing with against the gradient of sediment concentration produces erosion deposition it is shown that inside the surf zone these currents may occur due to the wave refraction and to the redistribution of wave breaking produced by the growing bedforms numerical simulations have been performed in order to understand the sensitivity of the pattern formation to the parameterization and to relate the hydro morphodynamic input conditions to which of the patterns develops it is suggested that crescentic bar growth would be favoured by high energy conditions and fine sediment while transverse bars would grow for milder waves and coarser sediment in intermediate conditions mixed patterns may occur

hydrothermal eruptions of nisyros dodecanese greece past events and present hazard abstract the detailed analysis of the craters of hydrothermal eruptions and related products present on nisyros island demonstrates the ephemerality of these morphological forms in other words the mere recognizable existence of the craters and associated deposits implies recency of hydrothermal activity the minimum temperature required to cause the explosive phenomenon and possibly the depth of the reservoir which can be evaluated on the basis of the correlation between the diameter of the crater and the depth of explosion as proposed by fytikas and marinelli 1976 are therefore closely representative of the current hydrothermal circulation both field evidence and historical records indicate that all the deposits of hydrothermal eruption recognized on nisyros island were emplaced as debris flows almost all the ballistic ejecta were entrained in these debris flows and either redeposited far from their landing sites or involved in later crater collapse and erosion this emplacing mechanism implies that the original products were characterized by a water content higher than about 5 by weight steam driven hydrothermal eruptions one of which took place in 1871 originated deposits of limited dispersion as no sign of these erodible products can be found in the field today surface geology and fluid geochemistry together with subsurface information e g primary and hydrothermal lithologies distribution of temperature with depth physical chemical characteristics of deep water bearing zones indicate that two distinct hydrothermal aquifers are present underneath the southeastern part of the caldera floor both aquifers were probably involved in the most important historically documented hydrothermal eruptions which occurred in 1873 at that time violent earthquakes fractured the brittle aquiclude separating the two aquifers and caused a sudden transfer of fluids from the deep to the shallow aquifer thus triggering the hydrothermal eruptions hydrothermal eruptions will probably occur in future and this hazard must be taken into serious consideration the southern half of lakki plain where all past eruptions took place and active fumaroles are concentrated is the zone at highest risk at present gas geochemistry represents an effective tool to detect changes in the p t conditions of the shallow aquifer and particularly the phenomena of pressure build up that may lead to a hydrothermal eruption

helium and methane measurements in hydrothermal fluids from the mid atlantic ridge the snake pit site at 23 n methane and helium isotopes concentrations have been measured in hydrothermal fluids of black smoker vents at the snake pit area mar 23 n as part of the hydrosnake cruise with the submersible nautile the samples contain large quantities of helium and methane with endmember values of 4 6 10 5 cm3 stp g for helium and 1 38 10 3 cm3 stp g for methane the helium isotopic ratio 3he 4he is 8 4 times the atmospheric ratio these values are strikingly similar to those already obtained on the east pacific rise the ch4 3he ratio is also quite similar ch4 3he 2 6 106 suggesting a non biogenic origin of this gas in the fluids assuming that the range of variation of the 3he concentration data obtained so far from various tectonic settings is close to the genuine range of values encountered on mid ocean ridges the global mass flow involved in the hydrothermal circulation at the ridge s axis is estimated between 1000 and 3000 m3 of water sec leading to a residence time of the global ocean with respect to the hydrothermal circulation between 15 and 45 million years this estimate implies that in addition to the individual vents smokers there is an extensive diffuse circulation of hydrothermal fluids along the ridges in agreement with recent observations concerning heat budgets at hydrothermal sites in the eastern pacific

a thermodynamic assessment of the potential synthesis of condensed hydrocarbons during cooling and dilution of volcanic gases the possibility for abiotic synthesis of condensed hydrocarbons in cooling diluting terrestrial volcanic gases has been evaluated on the basis of the consideration of metastable chemical equilibria involving gaseous co co2 h2 and h2o the stabilities of n alkanes and polycyclic aromatic hydrocarbons pahs have been evaluated for several typical volcanic gas compositions under various conditions for cooling diluting of quenched volcanic gas the modeling shows that n alkanes and pahs have a thermodynamic potential to form metastably from h2 and co below 250 c within the stability field of graphite despite the predominance of co2 in volcanic gases synthesis of hydrocarbons from co2 and h2 is less favored energetically than from co and h2 both low temperature and a high h c atomic ratio in volcanic gas generally favor stability of hydrocarbons with higher h c ratios pahs are thermodynamically stable at temperatures 10 50 c higher than large n alkanes however at lower temperatures pahs and n alkanes have similar stabilities and are likely to form metastable mixtures both the energetic drive to form hydrocarbons and possible temperatures of formation increase as the oxidation state o2 of the volcanic gases decreases and as the cooling dilution ratios of volcanic gases increase synthesis of hydrocarbons is energetically more likely in cooling trapped gases than in ashcloud eruptive columns mechanisms for hydrocarbon formation may include fischer tropsch type synthesis catalyzed by magnetite from solid volcanic products on the early earth mars and jupiter s satellite europa several factors would have provided more favorable conditions for hydrocarbon synthesis in volcanic gases than under current terrestrial conditions and might have contributed to the production of organic compounds required for the emergence of life

geochemical and isotopic changes in the fumarolic and submerged gas discharges during the 2011 2012 unrest at santorini caldera greece a geochemical survey of fumarolic and submerged gases from fluid discharges located in the nea kameni and palea kameni islets santorini island greece was carried out before during and after the unrest related to the anomalously high seismic and ground deformation activity that affected this volcanic system since january 2011 our data show that from may 2011 to february 2012 the nea kameni fumaroles showed a significant increase of h2 concentrations after this period an abrupt decrease in the h2 contents accompanied by decreasing seismic events was recorded a similar temporal pattern was shown by the f cl so4 2 and nh4 concentrations in the fumarolic condensates during the sharp increase of h2 concentrations when values up to 158 mmol mol were measured the 13c co2 values which prior to january 2011 were consistent with a dominant co2 thermometamorphic source have shown a significant decrease suggesting an increase of mantle co2 contribution light hydrocarbons including ch4 which are controlled by chemical reactions kinetically slower than h2 production from h2o dissociation displayed a sharp increase in march 2012 under enhanced reducing conditions caused by the high h2 concentrations of may 2011 february 2012 the general increase in light hydrocarbons continued up to july 2012 notwithstanding the contemporaneous h2 decrease the temporal patterns of co2 concentrations and n2 ar ratios increased similarly to that of h2 possibly due to sealing processes in the fumarolic conduits that diminished the contamination related to the entrance of atmospheric gases in the fumarolic conduits the compositional evolution of the nea kameni fumaroles can be explained by a convective heat pulse from depth associated with the seismic activation of the ne sw oriented kameni tectonic lineament possibly triggered by either injection of new magma below nea kameni island as apparently suggested by the evolution of the seismic and ground deformation activity or increased permeability of the volcanic plumbing system resulting from the tectonic movements affecting the area the results of the present study demonstrate that the geophysical and geochemical signals at santorini are interrelated and may be precursory signals of renewed volcanic activity and encourage the development of interdisciplinary monitoring program to mitigate the volcanic risk in the most tourist visited island of the mediterranean sea

the spatial and temporal variability of sand bar morphology the spatial and temporal variability of nearshore sand bar morphology is quantified using a unique data set spanning 2 years the data consist of daily time exposure images of incident wave breaking on an open coast sandy beach which may be used to infer bar morphology lippmann and holman 1989 the morphology in each image is classified into an eight state morphologic scheme in which bars are uniquely defined by four independent criteria the most frequently observed morphologies are the longshore periodic rhythmic bars observed in 68 of the data linear bars occur under highest wave conditions h s 1 78 m and are unstable mean residence time 2 days shore attached rhythmic bars are the most stable mean residence time 11 days and generally form 5 16 days following peak wave events non rhythmic three dimensional bars are very transient mean residence time 3 days eighty seven percent of transitions to lower bar types defined in text occurred one state at a time supporting our selection of the ordering of states and suggesting the suitability of a sequential morphology model transitions to higher states occurred under rising wave energy and were evenly spread among the possible higher states with more substantial changes in morphology resulting from larger wave increases this suggests that up state erosional transitions based on offshore bar migration are better described by an equilibrium model where response is better correlated with incident wave energy than with preceding morphological state time exposure images were also digitized to yield quantitative estimates of bar crest location as a function of longshore distance principal component analysis was used to decompose bar position into two dimensional linear and three dimensional longshore variable components cross shore linear bar position ranges 50 m about the 2 year mean 27 m standard deviation and dominates bar variability 74 6 three dimensional bar structure accounts for 14 of the variance 12 m standard deviation changes in incident wave height precede cross shore bar migration by less than 1 day changes in longshore variability are inversely correlated to changing wave conditions with bar morphology becoming linear rapidly during storms on time scales of less than 1 day evolution to significantly three dimensional structure typically occurs over 5 7 days following peak wave events

reduction of co2 during serpentinization of olivine at 300 c and 500 bar co 2 reduction processes occurring during experimental serpentinization of olivine at 300 c and 500 bar confirm that ultramafic rocks can play an important role in the generation of abiogenic hydrocarbon gas data reveal that conversion of fe ii in olivine to fe iii in magnetite during serpentinization leads to production of h 2 and conversion of dissolved co 2 to reduced c species including methane ethane propane and an amorphous carbonaceous phase hydrocarbon gases generated in the process fit a schulz flory distribution consistent with catalysis by mineral reactants or products magnetite is inferred to be the catalyst for methanization during serpentinization because it has been previously shown to accelerate fischer tropsch synthesis of methane in industrial applications involving mixtures of h 2 and co 2 the carbonaceous phase was predominantly aliphatic but had a significant aromatic component although this phase should ultimately be converted to hydrocarbon gases and graphite if full thermodynamic equilibrium were established its formation in these experiments indicates that the pathway for reduction of co 2 during serpentinization processes is complex and involves a series of metastable intermediates

hydrothermal vent waters at 13 n on the east pacific rise isotopic composition and gas concentration abstract gas concentrations and isotopic compositions of water have been measured in hydrothermal waters from 13 n on the east pacific rise in the most mg depleted samples 5 10 3 moles kg the gas concentrations are 3 4 5 10 5 cm 3 stp kg helium 0 62 1 24 cm 3 stp kg ch 4 10 80 16 71 10 3 moles kg co 2 the samples contain large quantities 95 126 cm 3 kg of h 2 and some carbon monoxide 0 26 0 36 cm 3 kg which result from reaction with the titanium sampling bottles 13 c in methane and co 2 16 6 to 19 5 and 4 1 to 5 5 respectively indicate temperatures between 475 and 550 c whereas 13 c co is compatible with formation by reduction of co 2 on ti at 350 c close to the sampling temperature 3 he 4 he are very homogeneous at 7 5 0 1 r a 3 he 4 he 1 0 10 5 and very similar to already published data as well as ch 4 3 he ratios between 1 4 and 2 1 10 6 18 o and d in water show enrichments from 0 39 to 0 69 and from 0 62 to 1 49 respectively these values correspond to w r ratios of 0 4 7 the distinct 18 o enrichments indicate that the isotopic composition of the oceans is not completely buffered by the hydrothermal circulations the 3 he enthalpy relationship is discussed in terms of both hydrothermal heat flux and 3 he mantle flux

variation in subaerial beach sediment volume on a small sandy beach over a monthly lunar tidal cycle abstract three major patterns of sediment movement along 0 5 m deep horizontal segments of beachface on a small sandy beach at coledale new south wales were determined by empirical orthogonal function eof analysis of a 36 day record of beach change the fundamental beach response is identified by the first eigenfunction mode the mode describes sediment transfers occurring over the beachface between the low tide zone and the berm crest as well as sediment movement along the beach the alongshore translocations occurred about a nodal point located approximately 0 75 of distance along the beach from its southern end transfers across the beach were established by comparing the time series associated with the eigenfunctions describing alongshore transfers of sediment in different segments the slice to slice comparisons showed an increasing phase down the beachface from the berm crest segment to the mid tidal zone the phase difference was approximately 2 5 days per 0 5 m segment the fundamental beach response and secondary sediment transfers typical of the supratidal zone occur with an apparent 28 30 day lunar tide cycle they were unrelated to short term variations in the incident wave amplitude lower down the beachface the time series associated with the eigenfunction describing sediment translocations in the mid tidal zone is aperiodic the irregularities can be linked to particular process events however similar beach changes were not always related to similar process conditions and they were not simply related to wave regime fluctuations the patterns of sediment movement along coledale beach were consistent with similar patterns reported from elsewhere by clarke and eliot 1982 1983a in that they were closely related to variation in the nearshore water circulation system in particular nodal points identified by the eof analysis commonly occurred on the beachface landward of inshore regions where bars most frequently developed the antinodal positions were similarly associated with regions where rip channels are frequently formed

morphodynamics of a bar trough surf zone abstract a field study was made of the distinguishing morphodynamic processes operating in a surf zone which perennially exhibits accentuated bar trough topography the longshore bar trough and rhytmic bar and beach states as described by wright and short 1984 characteristic features of the morphology include a shallow bar with a steep shoreward face a deep trough and a steep beach face this morphology which is favored by moderate breaker heights and small tidal ranges strongly controls the coupled suite of hydrodynamic processes in contrast to fully dissipative surf zones the bar trough surf zone is not at all saturated and oscillations at incident wave frequency remain dominant from the break point to the subaerial beach the degree of incident wave groupiness does not change appreciably across the surf zone infragravity standing waves which in dissipative surf zones dominate the inshore energy remain energetically secondary and occur at higher frequencies in the bar trough surf zone analyses of the field data combined with numerical simulations of leaky mode and edge wave nodal antinodal positions over observed surf zone profiles indicate that the frequencies which prevail are favored by the resonant condition of antinodes over the bar and nodes in the trough standing waves which would have nodes over the bar are suppressed sediment resuspension in the surf zone appears to be largely attributable to the incident waves which are the main source of bed shear stress in addition the extra near bottom eddy viscosity provided by the reformed non breaking waves traversing the trough significantly affects the vertical velocity profile of the longshore current whereas the bar is highly mobile in terms of onshore offshore migration rates the beach face and inner regions of the trough are remarkably stable over time

3 he 4 he ratios in ch 4 rich natural gases suggest magmatic origin natural gas and oil fields commercially exploited since the 1950s are distributed in the zonal area facing the sea of japan in north east japan we report here measurements of the 3he 4he ratios in 27 ch4 rich natural gases obtained from commercial oil and gas wells in the area we observed extraordinarily high 3he 4he ratios up to 8 65 10 6 in gases from wells drilled into deep reservoirs in volcaniclastic rock formations the so called green tuff fig 1 these values are almost identical to those of volcanic fumaroles in the japanese islands in contrast gases in shallower sedimentary rock reservoirs have low 3he 4he ratios with a minimum value of 0 3 10 6 these low values are similar to those of natural gases originating from biological materials this suggests that the formation of natural gas reservoirs in the volcaniclastic rock may be attributed to large scale magmatic activities which occurred in the middle miocene

medium temperature fumarolic gas sampling in order to sample medium temperature fumaroles gases are collected by means of iron or glass tubings and conveyed to the condensation system through glass dewar tubes one type of condenser was designed for condensate measurement and gas sampling for radon activity determination the other with naoh absorbing solution for the s cl ratio measurement and the sampling of rare gases with this method it is possible to obtain precise gas vapour measurements as well as air free gas samples

coupled and noncoupled behavior of three dimensional morphological patterns in a double sandbar system 1 eight weeks of daily low tide time exposure images of the gold coast australia were used to analyze the development of three dimensional morphological patterns in a double sandbar system under continued low energy wave conditions following a morphological reset storm event the patterns in both the inner and outer bar evolved albeit at different spatial and temporal scales through the accretionary sequence commonly observed at single barred beaches continuous wavelet transforms cwt of the inner bar and outer bar breaker lines show that after a storm the patterns developed at a wide range of alongshore wavelengths and that variations in wavelength over space and time were common with the bivariate extension of cwt continuous cross wavelet transforms it is found that the initial inner bar and outer bar three dimensional patterns were spatially noncoupled however over time the inner bar morphology appeared to couple with that of the outer bar with the inner bar patterns developing in response to the increasingly three dimensional onshore propagating outer bar the wavelet analysis suggests that the outer bar geometry and the distance between the inner and outer bars are critical parameters governing the morphological evolution of the composite double sandbar system

equilibrium slopes and cross shore velocity asymmetries in a storm dominated barred nearshore system abstract the near bed 0 10 m elevation horizontal velocities were measured across a two barred lacustrine shoreface during a storm and reveal a spatially coherent but temporally variable pattern in the low order moments of the velocity field large cross shore velocity asymmetries indicated 1 1 spatially extensive and temporally persistent offshore mean flows up to 0 18 m s 1 across the landward slope of the linear outer bar reflecting an undertow driven by a wave induced setup 2 2 an onshore directed skewness opposing the mean flow of wind wave origin and persistent under propagating bores in the inner bar system long after this asymmetry had disappeared from the outer bar extensive sediment reactivation with near zero net sediment flux over the whole of the upper shoreface indicated a sediment prism in a steady state volumetrically over the storm cycle uniform depths of sediment reactivation with zero bed elevation change over the storm cycle revealed local slopes in a steady state in the outer linear bar however time integration of the near bed velocity field at this location indicated an offshore net flux of water while sedimentary structures indicated bedform migration and thus at least bedload almost uniformly onshore when ripples and megaripples were present the sediment transport giving rise to the local equilibrium cannot be explained therefore on the basis of the mean properties of the near bed velocity vector but requires knowledge of the time varying instantaneous sediment transport vector onshore migration of the inner bar correlated well with the large and persistent onshore skewness of the velocity distribution in the inner surf zone associated with translatory surf bores throughout the storm decay period low frequency oscillations were only significant close to the shoreline but may have influenced the development of a sinuous three dimensional inner bar form as it migrated onshore

geochemistry of hydrothermal fluids from an intraplate ocean island everman volcano socorro island mexico abstract socorro island mexico still volcanically active is an alkaline and peralkaline volcanic island in the eastern pacific ocean located on a mid ocean ridge spreading center that was abandoned at 3 5 ma gas and water samples collected on the island in 1999 from the dome fumaroles and hot springs of everman volcano have been analyzed for major components h o c s he and ar isotopic composition and noble gas abundances the boiling point temperature steam vents and low salinity thermal springs discharge cl free meteoric water and are typical surface manifestations of a high temperature hydrothermal system high h 2 and ch 4 contents up to 14 and 3 5 vol in dry gas respectively and an enrichment of ch 4 in 13 c 13 c ch 4 18 may suggest that these reduced gases were at least partially produced by the interaction of ultramafic rocks with water inside volcanic edifice due to serpentinization of olivine the 3 he 4 he ratios 6 0 6 6 r a which are lower than the morb values and the high he ne ratios 4000 and he ar ratios up to 4 indicate a contribution of radiogenic he from the oceanic crust or shallow magma chamber like at a low 3 he hot spot the maximum of the 40 ar 36 ar values 311 is close to the maximum value found in the socorro volcanic rocks noble gas abundances are close to values for the partially degassed air saturated water however with some excess ne concentrations an enrichment in 132 xe or depletion in 84 kr of the least air contaminated gas sample he ne 4000 relative to air saturated water can be related to the contribution of noble gases from a non atmospheric source probably oceanic crustal component assimilated in a shallow magma reservoir

generation accumulation and resource potential of biogenic gas biogenic gas is generated at low temperatures by decomposition of organic matter by anaerobic microorganisms more than 20 of the world s discovered gas reserves are of biogenic origin a higher percentage of gases of predominantly biogenic origin will be discovered in the future biogenic gas is an important target for exploration because it occurs in geologically predictable circumstances and in areally widespread large quantities at shallow depths in rapidly accumulating marine sediments a succession of microbial ecosystems leads to the generation of biogenic gas after oxygen is consumed by aerobic respiration sulfate reduction becomes the dominant form of respiration methane generation and accumulation become dominant only after sulfate in sediment pore water is depleted the most important mechanism of methane generation in marine sediments is the reduction of co2 by hydrogen electrons produced by the anaerobic oxidation of organic matter co2 is the product of either metabolic decarboxylation or chemical decarboxylation at slightly higher temperatures the factors that control the level of methane production after sediment burial are anoxic environment sulfate deficient environment low temperatu e availability of organic matter and sufficient space the timing of these factors is such that most biogenic gas is generated prior to burial depths of 1 000 m in marine sediments most of the biogenic gas formed can be retained in solution in the interstitial pore waters because of higher methane solubility at the higher hydrostatic pressures due to the weight of the overlying water column under certain conditions of high pressures and or low temperatures biogenic methane combines with water to form gas hydrates biogenic gas usually can be distinguished from thermogenic gas by chemical and isotopic analyses the hydrocarbon fraction of biogenic gas consists predominantly of methane the presence of as much as 2 of heavier hydrocarbons can be attributed to admixture of minor thermogenic gas due to low temperature degradation of organic matter the amounts of hydrocarbon components other than methane generally are proportional to temperature age and organic matter content of the sediments biogenic methane is enriched in the light isotope 12c dgr13c1 lighter than 55 ppt owing to kinetic isotope fractionation by methanogens the variations in isotopic composition of biogenic methane are controlled primarily by dgr13c of the original co2 substrate which reflects the net isotopic effect of both addition and removal of co2 the methane isotopic composition also can be affected by mixing of isotopically heavier thermogenic gas the possible complicating factors require that geologic chemical and isotopic evidence be considered in attempts to interpret the origin of gas accumulations accumulations of biogenic gas have been discovered in canada germany italy japan trinidad the united states and ussr in cretaceous and younger rocks at less than 3 350 m of burial and in marine and nonmarine rocks other gas accumulations of biogenic origin have undoubtedly been discovered however data that permit their recognition are not available

sequential stage development of crescentic bars hahoterim beach southeastern mediterranean abstract sequential bar development involving in order multiple bars ridge and runnels transverse oblique bars and meandering or crescentic shore attached or detached bars of both outer and nested inner systems were delineated at hahoterim beach northern israel the concomitant wave data including wave directions energy spectrum significant wave height and length of the calm period showed strong correlation with the bar stages there is a notable lack of correlation between bar stages and incident wave periods which were quite variable even on a daily basis two bar developmental sequences were delineated one shore normal and the other initially oblique but gradually rotating to shore normal in the mature stage threshold conditions for the initial stage development of shore normal crescentic systems were defined as h1 3 1 0 m peak spectral density of 1 m2 hz and swell directions within 7 from the normal the outer crescentic systems formed within 1 to 2 weeks the nested inner crescentic bar system formed under different wave conditions development of inner micro cresentic bars required 3 to 7 weeks of calm waves h1 3 0 3 m except for a short initiating pulse of wave energy from waves of about i m in height the double crescentic pattern indicates the optimal evolutiona y stage of crescentic systems the residence time of bar types was determined by the frequency of crossing of these threshold conditions the outer bars and the mega rip channels composed the most stable inshore elements out of phase relationships between inner and outer bar systems resulted from the lag in response of the outer bars behind changes in wave direction among the inner crescentic bars and shore rhythms phase correlation was the was the rule regional aerial photography and wave data indicate that the bar wave relationships at hahoterim axe representative of the eastern flank of the nile including most of the israeli coast although the bar types described from other coasts are similar to those mapped at hahoterim and the threshold wave conditions for initiation of bar stage development appear to be similar the frequency of occurrence of specific bar types appears to be different at hahoterim

pedogenic slickensides indicators of strain and deformation processes in redbed sequences of the appalachian foreland pedogenic slickensides are convex concave slip surfaces that form during expansion contraction in expansive clay soils such as vertisols in the central appalachians they occur near the tops of fining upward cycles in paleozoic redbeds such as the bloomsburg catskill and mauch chunk formations pedogenic slickensides are found in association with other pedogenic or paleosol features such as clay skinned peds in situ calcareous nodules and root impressions repeated movements along these shear planes during pedogenesis produce strongly aligned clay particles adjacent to pedogenic slickensides as a result they are preserved as discrete fractures throughout diagenesis compaction and superimposed tectonic deformation during whole rock deformation pedogenic slickensides segregate penetratively deformed rocks into independent foliated packets and serve as discontinuities that are followed by later structural features because the original morphology of pedogenic slickensides is known they can be used as crude strain markers

methane anomalies in seawater above the loihi submarine summit area hawaii hydrothermal activity above loihi submarine volcano was characterized by water column distributions of methane ph and helium 3 it was found that the southern loihi summit is almost covered with hydrothermal plumes which have anomalously high concentrations of methane maximum 569 10 6cm3kg 1 accompanied by high concentrations of helium 3 and low ph values minimum 7 18 the plumes consist of two layers a shallow plume about 200 m above the summit and a deep plume about 100 m above the summit probably derived from different hydrothermal vents the shallow and deep plumes showed different ch43he and ch4ph ratios with the same 3heph ratio which implies that methane concentrations differ between the hydrothermal end members for the two plumes the variation of methane between the end members is suggested to result from inter vent inhomogeneity of bacterial activities that consume or produce methane within the vents comparison of the ch43he ratios of the two plumes with the previous data for loihi and other submarine hydrothermal areas confirms that the loihi hotspot has one to two orders of magnitude smaller ch43he value than those of the east pacific rise and the galapagos spreading centers

observations of nearshore crescentic sandbars 1 the temporal and spatial variability of crescentic sandbars is analyzed with hourly long term months video observations collected at four barred sites and are qualitatively compared to the temporal and spatial variability predicted by hypotheses underpinning existing approaches and models for crescentic bar formation edge wave template model linear stability analysis and nonlinear models the observations coming from the single barred beaches at duck north carolina usa and miyazaki kyushu japan and from the double barred beaches at the northern gold coast queensland australia and noordwijk netherlands show that crescentic sandbar wavelength and amplitude variations over space and time are very common for instance at any moment in time the wavelength of the smallest and longest crescentic bar can differ by a factor of 2 temporal changes in wavelength and amplitude result from merging and splitting of individual crescents causing the final configuration of a crescentic sandbar system to be very different from the initial configuration the gold coast data indicate that these intrinsically nonlinear interactions are an attempt of the crescentic bar system to self organize into a more uniform pattern as splitting is usually confined to the longest crescentic bar observed whereas merging usually combines the smallest crescentic bars into a longer bar the observed spatial and temporal crescentic bar behavior contrasts qualitatively with behavior predicted from the edge wave template model and implies that the predictive skill of linear stability models is limited nonlinear models are potentially better suited for a comparison against these field observations several suggestions to improve these models and hence to facilitate a data model comparison are made