latest quaternary oceanographic changes in the okhotsk sea based on diatom records abstract the okhotsk sea is a locus of the north pacific intermediate water formation today the formation of the okhotsk intermediate water is linked with seasonal sea ice cover diatom records from the okhotsk sea show the following 1 during the last glacial maximum between 21 000 yr b p and 18 000 yr b p sea ice covered the western side of the sea throughout the whole year but the eastern part was open this permitted more efficient heat exchange with the atmosphere than waters and hence ventilation of the glacial okhotsk sea waters which in turn caused a greater extent of intermediate water formation through the bussol strait 2 the perennial sea ice cover extended northward and sea ice was present throughout the whole year over a great part of the sea except for the eastern part between 18 000 yr b p and 17 000 yr b p 3 the ice free area extended greatly to the south during the interval between 17 000 yr b p and 11 000 yr b p 4 there was no perennial ice cover over the whole sea and the ice free area that appeared as the seasonal ice area began to extend to the western part between 11 000 yr b p and 8 000 yr b p 5 after 8000 yr b p the ice free waters contracted to the present extent

diatom derived ssts td ratio indicate warm seas off japan during the middle holocene 8 2 3 3 kyr bp abstract regression analysis was performed between the ratio of warm and cold water diatoms td ratio in 123 surface sediment samples in the northwest pacific ocean and the mean annual sea surface temperatures ssts c at the core sites in order to calibrate this proxy for paleo temperatures equations to derive annual sst c from diatom analysis were somewhat different for the tohoku area y 6 5711 0 273 r 0 89946 than for the japan sea y 5 4069 0 26841 r 0 89088 the annual paleo ssts c in the tohoku area were in general higher than in the japan sea despite lower td values because the warm water species fragilariopsis doliolus is abundant only in the tsushima warm current in the japan sea the reliability of the equations is supported by our understanding of the ecology of recent diatoms td derived annual paleo ssts c agree with alkenone derived summer paleo sst c at a site off central japan in the northwestern pacific in a south to north transect of cores around honshu and hokkaido paleo ssts c decreased when the kuroshio and tsushima warm currents weakened the middle holocene 8 2 3 3 cal kyr bp was warmer by 1 2 c than earlier and later parts of the holocene and mean annual paleo ssts c show rhythmic fluctuations with durations of 1000 years and 400 500 years these new data show that annual ssts were warm in the northwestern pacific at times that the northeastern pacific was cold in addition oceanic warm and cold water species defined by kanaya and koizumi kanaya t koizumi i 1966 interpretation of diatom thanatocoenoses from the north pacific applied to a study of core v20 130 studies of a deep sea core v20 130 part iv sci rep tohoku univ 2nd series geol 37 89 130 and koizumi et al koizumi i irino t oba t 2004 paleoceanography during the last 150 kyr off central japan based on diatom floras mar micropaleontol 53 293 365 are illustrated

an isotopic model for basal freeze on associated with subglacial upward flow of pore water 1 subglacial freezing in polar glaciers can have a significant dynamical effect recent studies have shown that freezing of pore water flowing upward through subglacial fine grained sediments at the freezing interface and progression of this freezing front downward are responsible for fast ice flow stoppage in ice streams the upward pore water flow leads to the formation of debris bearing basal ice layers a model for stable isotope composition both in d and 18o is developed for predicting the isotopic composition of the ice segregated by such a mechanism the development of this isotopic model for water films present along the grains of the subglacial sediment predicts the absence of apparent fractionation for the ice formed this prediction is tested against two east antarctic outlet glaciers by studying the d 18o relationships in the basal ice layers of these glaciers

varieties of a single cosmopolitan diatom species associated with surface water masses in the north pacific abstract a time series of 65 sediment trap samples representing 48 month changes in diatom flora and 62 sediment core tops from the western north pacific ocean were analyzed varieties of a single diatom species were found to be characteristic of two surface water masses bounded by the kuroshio current thalassionema nitzschioides var incurvata var inflata and var parva dominate in warm saline waters in the subtropical gyre while t nitzschioides sensu stricto is abundant in less saline waters northwest of this current time series data on percent abundances for the three t nitzschioides varieties in the t nitzschioides complex are compared with path variations of the current south of japan inter annual fluctuations in percent abundance are linked to changes in surface water masses over the sediment traps in association with migration of the kuroshio paths this finding makes the percent abundance a useful tool for deciphering path migrations of the kuroshio current in the geologic past down core analyses of two sediment cores collected beneath the modern kuroshio current were performed a sharp increase in percent abundances from 12 to 9 kyr bp with an abrupt change around 11 kyr bp records the previously reported transition of the kuroshio current from a predominantly offshore path to its modern path path migrations of the kuroshio current may be inferred from percent abundances of these diatoms which comprise a new proxy for delineating the paleoclimate of the northwestern pacific in relation to changes in northward heat transport from the western equatorial pacific ocean by the western boundary current

a 13 000 year climate record from western tibet although the tibetan plateau is important in influencing the atmospheric circulation of the northern hemisphere1 3 there are only a few continuous palaeoclimate records available and these are limited to the plateau s northeastern margin4 6 here we present a 13 000 yr record from sumxi co western tibet constructed from both lake core and shoreline studies which shows that conditions in the early middle holocene were warmer and wetter than at present these results confirm model predictions of an intensified monsoon over the region at 9 000 yr bp owing to an orbitally induced increase in summer insolation7 8 we also find evidence for warm humid pulses at 12 500 and 10 000 yr bp in phase with the steps of the last deglaciation and for a return to cold dry conditions at 11 10 000 yr bp none of which can be explained by orbital variations the existence of the cold episode confirms that the cooling associated with the younger dry as event occurred in continental china6 9 and provides further evidence of the global nature of this event10

persistent solar influence on north atlantic climate during the holocene surface winds and surface ocean hydrography in the subpolar north atlantic appear to have been influenced by variations in solar output through the entire holocene the evidence comes from a close correlation between inferred changes in production rates of the cosmogenic nuclides carbon 14 and beryllium 10 and centennial to millennial time scale changes in proxies of drift ice measured in deep sea sediment cores a solar forcing mechanism therefore may underlie at least the holocene segment of the north atlantic9s 1500 year cycle the surface hydrographic changes may have affected production of north atlantic deep water potentially providing an additional mechanism for amplifying the solar signals and transmitting them globally

paleoceanographic history around the tsugaru strait between the japan sea and the northwest pacific ocean since 30 cal kyr bp abstract the paleoceanographic history around the tsugaru strait since 30 0 cal kyr bp was reconstructed using ecological and biogeographical habitats of diatom species and q mode factor analysis of diatom flora in six piston cores at 30 0 17 5 cal kyr bp a fall in sea level and the intensification of the oyashio current caused erosion of submarine sediments near the shore in the eastern area of the strait and led to deposition of the third and second sequences of thinly laminated layers tl3 and tl2 in the japan sea at 17 5 11 5 cal kyr bp cooling intensified around the strait producing an inflow of oyashio water into the japan sea through the strait at 15 5 14 5 cal kyr bp a cold water mass around the strait developed from subarctic sea ice to arctic waters at 13 0 11 2 cal kyr bp the younger dryas cooling was clearly recorded by the increasing of oceanic cold water diatom species in the eastern area of the tsugaru strait but not in the japan sea at 15 5 13 0 cal kyr bp and 11 25 10 25 cal kyr bp the warming around the younger dryas resulted in the deposition of thinly laminated layers off shimokita in the eastern area of the strait at 9 5 cal kyr bp the oyashio current water intruded into deep depths in the mixed water region off sanriku at 9 5 7 0 cal kyr bp the fluctuation of 1 5 kyr intervals in the strength of the tsushima warm current system in the japan sea was initiated

pliocene pleistocene evolution of the north pacific ocean atmosphere system interpreted from fossil diatoms the relative abundance of diatom taxa in 216 core tops has been quantified and compared using cluster analysis with assemblages in six cores located beneath different water masses of the north pacific ocean all but one sequence span at least 1 5 m y early pleistocene to holocene and one extends to 2 6 ma the quantitative abundance of each taxon and the space time occurrence of each cluster are interpreted as tracers of oceanographic conditions in addition to high frequency glacial interglacial oscillations the records display rapid steplike changes at 2 4 ma 1 6 1 5 ma 1 0 ma 0 8 0 7 ma and 0 35 ma two secondary transitions recorded only in the northwestern cores occur at 2 0 ma and 1 1 ma we conclude that both the high frequency oscillations and the stepwise transitions reflect variations in extent of subarctic water masses under the influence of the siberian high pressure and aleutian low pressure atmospheric cells we further conclude that 1 the subarctic water mass has developed progressively and attained its modern structure only in the late pleistocene 2 some stages of this evolution may have occurred earlier in the eastern subarctic 3 the holocene is an atypical warm extreme so that the present is not a very good key to the past 4 there were several glaciations between 2 4 and 2 0 ma and 5 the subtropical gyre is more conservative than the subarctic gyre and major changes in the region have been due to forcing from the north we propose a conceptual model of oscillating metastable climatic modes maintained by internal feedback and suggest that steplike changes may occur when one set of boundary conditions is temporarily exceeded

strong coherence between solar variability and the monsoon in oman between 9 and 6 kyr ago variations in the amount of solar radiation reaching the earth are thought to influence climate but the extent of this influence on timescales of millennia to decades is unclear a number of climate records show correlations between solar cycles and climate1 but the absolute changes in solar intensity over the range of decades to millennia are small2 and the influence of solar flux on climate is not well established the formation of stalagmites in northern oman has recorded past northward shifts of the intertropical convergence zone3 whose northward migration stops near the southern shoreline of arabia in the present climate4 here we present a high resolution record of oxygen isotope variations for the period from 9 6 to 6 1 kyr before present in a th u dated stalagmite from oman the 18o record from the stalagmite which serves as a proxy for variations in the tropical circulation and monsoon rainfall allows us to make a direct comparison of the 18o record with the 14c record from tree rings5 which largely reflects changes in solar activity6 7 the excellent correlation between the two records suggests that one of the primary controls on centennial to decadal scale changes in tropical rainfall and monsoon intensity during this time are variations in solar radiation

high resolution climatic evolution of coastal northern california during the past 16 000 years holocene and latest pleistocene oceanographic conditions and the coastal climate of northern california have varied greatly based upon high resolution studies ca every 100 years of diatoms alkenones pollen caco 3 and total organic carbon at ocean drilling program odp site 1019 41 682 n 124 930 w 980 m water depth marine climate proxies alkenone sea surface temperatures ssts and caco 3 behaved remarkably like the greenland ice sheet project gisp 2 oxygen isotope record during the balling allerod younger dryas yd and early part of the holocene during the yd alkenone ssts decreased by 3 c below mean bolling allerod and holocene ssts the early holocene ca 11 6 to 8 2 ka was a time of generally warm conditions and moderate caco 3 content generally 4 the middle part of the holocene ca 8 2 to 3 2 ka was marked by alkenone ssts that were consistently 1 2 c cooler than either the earlier or later parts of the holocene by greatly reduced numbers of the gyre diatom pseudoeunotia doliolus 10 and by a permanent drop in caco 3 to 3 starting at ca 5 2 ka coastal redwood and alder began a steady rise arguing for increasing effective moisture and the development of the north coast temperate rain forest at ca 3 2 ka a permanent ca 1 c increase in alkenone sst and a threefold increase in p doliolus signaled a warming of fall and winter ssts intensified higher amplitude and more frequent cycles of pine pollen alternating with increased alder and redwood pollen are evidence that rapid changes in effective moisture and seasonal temperature enhanced el nino southern oscillation enso cycles have characterized the site 1019 record since about 3 5 ka

a decade of west antarctic subglacial lake interactions from combined icesat and cryosat 2 altimetry we use cryosat 2 interferometric satellite radar altimetry over the mercer and whillans ice streams west antarctica to derive surface elevation changes due to subglacial lake activity at monthly resolution for the period 2010 to 2013 we validate cryosat 2 elevation measurements trends and spatial patterns of change using satellite image differencing and in situ vertical movement from global positioning system gps data two subglacial lake discharge events occur in the same subglacial hydrological catchment within a 9 month period using gps measurements that are spanning the gap between the ice cloud and land elevation satellite and cryosat 2 missions we cross calibrate the two missions to establish the efficacy of cryosat 2 altimetry to measure dynamic changes on the ice sheets

biogeochemical weathering under ice size matters 1 the basal regions of continental ice sheets are gaps in our current understanding of the earth s biosphere and biogeochemical cycles we draw on existing and new chemical data sets for subglacial meltwaters to provide the first comprehensive assessment of sub ice sheet biogeochemical weathering we show that size of the ice mass is a critical control on the balance of chemical weathering processes and that microbial activity is ubiquitous in driving dissolution carbonate dissolution fueled by sulfide oxidation and microbial co2 dominate beneath small valley glaciers prolonged meltwater residence times and greater isolation characteristic of ice sheets lead to the development of anoxia and enhanced silicate dissolution due to calcite saturation we show that sub ice sheet environments are highly geochemically reactive and should be considered in regional and global solute budgets for example calculated solute fluxes from antarctica 72 130 t yr 1 are the same order of magnitude as those from some of the world s largest rivers and rates of chemical weathering 10 17 t km 2 yr 1 are high for the annual specific discharge 2 3 4 1 10 3 m our model of chemical weathering dynamics provides important information on subglacial biodiversity and global biogeochemical cycles and may be used to design strategies for the first sampling of antarctic subglacial lakes and other sub ice sheet environments for the next decade

hydrochemistry of ice stream beds evaporitic or microbial effects recently new data have been acquired on the chemical composition of waters within the glacial till beneath the kamb ice stream kis formerly ice stream c and the bindschadler ice stream bis formerly ice stream d two of the arteries of ice loss from the antarctic ice sheet ais we compare this water chemistry with basally stored subglacial waters from arctic and alpine glaciers and the only other measurements of sub ice sheet chemistry to date that emerging from beneath law dome near casey station sw antarctica during a jokulhlaup we find that the chemistries pose significant questions about the hydrology and biogeochemistry of ice sheet beds copyright 2010 john wiley sons ltd

a microbial driver of chemical weathering in glaciated systems glaciological processes under ice sheets provide sustainable ecosystems for microbes forming an aquatic environment through basal melting and providing nutrients and energy from bedrock microbes facilitate solute production in most earth surface environments but the balance of biotic and abiotic weathering in subglacial environment is presently unknown this study demonstrates an up to eightfold increase in dissolved major cations in biotic relative to abiotic weathering experiments using glacial sediments and meltwater this conclusion greatly expands our view of earth s biogeochemically active weathering zone by incorporating the large wet based portions of glaciated continents both at present and during earth s history the profound environmental significance is that microbial processes have the ability to maintain terrestrial chemical weathering rates in cooling climates during glacial advance

pleistocene collapse of the west antarctic ice sheet some glacial sediment samples recovered from beneath the west antarctic ice sheet at ice stream b contain quaternary diatoms and up to 108 atoms of beryllium 10 per gram other samples contain no quaternary diatoms and only background levels of beryllium 10 less than 10 6 atoms per gram the occurrence of young diatoms and high concentrations of beryllium 10 beneath grounded ice indicates that the ross embayment was an open marine environment after a late pleistocene collapse of the marine ice sheet

a microbial ecosystem beneath the west antarctic ice sheet liquid water has been known to occur beneath the antarctic ice sheet for more than 40 years but only recently have these subglacial aqueous environments been recognized as microbial ecosystems that may influence biogeochemical transformations on a global scale here we present the first geomicrobiological description of water and surficial sediments obtained from direct sampling of a subglacial antarctic lake subglacial lake whillans slw lies beneath approximately 800 m of ice on the lower portion of the whillans ice stream wis in west antarctica and is part of an extensive and evolving subglacial drainage network the water column of slw contained metabolically active microorganisms and was derived primarily from glacial ice melt with solute sources from lithogenic weathering and a minor seawater component heterotrophic and autotrophic production data together with small subunit ribosomal rna gene sequencing and biogeochemical data indicate that slw is a chemosynthetically driven ecosystem inhabited by a diverse assemblage of bacteria and archaea our results confirm that aquatic environments beneath the antarctic ice sheet support viable microbial ecosystems corroborating previous reports suggesting that they contain globally relevant pools of carbon and microbes that can mobilize elements from the lithosphere and influence southern ocean geochemical and biological systems

climatic solar oceanic and geomagnetic influences on late glacial and holocene atmospheric 14c 12c change late glacial and holocene 14c12c ratios of atmospheric co2 vary in magnitude from a few per mil for annual decadal pertubations to more than 10 for events lasting millennia a data set illuminating 10 to 104 yr variability refines our understanding of oceanic climatic versus geomagnetic or solar forcing of atmospheric 14c12c ratios most of the variance in the holocene atmospheric 14c12c record can be attributed to the geomagnetic millennia time scale and solar century time scale influence on the flux of primary cosmic rays entering the atmosphere attributing the observed atmospheric 14c12c changes to climate alone leads to ocean circulation and or global wind speed changes incompatible with proxy records climate ocean related 14c redistribution between carbon reservoirs while evidently playing a minor role during the holocene may have perturbed atmospheric 14c12c ratios measurably during the late glacial younger dryas event first order corrections to the radiocarbon time scale 12 000 30 000 14c yr b p are calculated from adjusted lake sediment and tree ring records and from geomagnetically defined model 14c histories paleosunspot numbers 100 9700 cal yr b p are derived from the relationship of model 14c production rates to sunspot observations the spectral interpretation of the 14c12c atmospheric record favors higher than average solar activity levels for the next century minimal evidence was found for a sun weather relationship

an inventory of active subglacial lakes in antarctica detected by icesat 2003 2008 through the detection of surface deformation in response to water movement recent satellite studies have demonstrated the existence of subglacial lakes in antarctica that fill and drain on timescales of months to years these studies however were confined to specific regions of the ice sheet here we present the first comprehensive study of these active lakes for the antarctic ice sheet north of 868 s based on 4 5 years 2003 08 of nasa s ice cloud and land elevation satellite icesat laser altimeter data our analysis has detected 124 lakes that were active during this period and we estimate volume changes for each lake the icesat detected lakes are prevalent in coastal antarctica and are present under most of the largest ice stream catchments lakes sometimes appear to transfer water from one to another but also often exchange water with distributed sources undetectable by icesat suggesting that the lakes may provide water to or withdraw water from the hydrologic systems that lubricate glacier flow thus these reservoirs may contribute pulses of water to produce rapid temporal changes in glacier speeds but also may withdraw water at other times to slow flow

significant groundwater contribution to antarctic ice streams hydrologic budget satellite observations have revealed active hydrologic systems beneath antarctic ice streams but sources and sinks of water within these systems are uncertain here we use numerical simulations of ice streams to estimate the generation flux and budget of water beneath five ice streams on the siple coast we estimate that 47 of the total hydrologic input 0 98 km3 yr 1 to whillans wis mercer mis and kamb kis ice streams comes from the ice sheet interior and that only 8 forms by local basal melting the remaining 45 comes from a groundwater reservoir an overlooked source in which depletion significantly exceeds recharge of the total input to bindschadler bis and macayeal macis ice streams 0 56 km3 yr 1 72 comes from the interior 19 from groundwater and 9 from local melting this contrasting hydrologic setting modulates the ice streams flow and has important implications for the search for life in subglacial lakes

the nature and origin of a jokulhlaup near casey station antarctica description de la nature de l episode d eruption d eau et resultats des etudes menees pour determiner l origine et la source de cette eau

distribution and modification of north pacific intermediate water in the kuroshio oyashio interfrontal zone abstract a multiship ctd survey was conducted in the kuroshio oyash interfrontal zone in the area of 30 41 n 140 e 180 from may to june 1992 to examine the distribution modification process and formation site of north pacific intermediate water npiw low salinity oyashio water and high salinity kuroshio water merge along the kuroshio extension just off the east coast of japan and together flow eastward eastward geostrophic transport and salinity across the kuroshio strong current indicate that the mixture of the kuroshio and oyashia waters along the kuroshio extension can produce new npiw transport estimate suggests that the new npiw bifurcates into the interfrontal zone and into the recirculation of the subtropical gyre a salinity minimum structure can he also created due to the isopycnal mixing along the kuroshio extension between the oyashio and kuroshio waters which have different salinity and vertical velocity structures the low salinity oyashio water seen along the oyashio branches and t

an active subglacial water system in west antarctica mapped from space satellite laser altimeter elevation profiles from 2003 to 2006 collected over the lower parts of whillans and mercer ice streams west antarctica reveal 14 regions of temporally varying elevation which we interpret as the surface expression of subglacial water movement vertical motion and spatial extent of two of the largest regions are confirmed by satellite image differencing a major previously unknown subglacial lake near the grounding line of whillans ice stream is observed to drain 2 0 cubic kilometers of water into the ocean over 3 years while elsewhere a similar volume of water is being stored subglacially these observations reveal a wide spread dynamic subglacial water system that may exert an important control on ice flow and mass balance

diatoms in northeast pacific surface sediments as paleoceanographic proxies abstract fossil diatom total abundances valves g in 54 surface sediment samples from the northeast ne pacific ocean reflect the position of high primary production associated with coastal upwelling and that possible biases associated with dilution or dissolution are small diatom species assemblages defined by q mode factor analysis in 30 samples with abundant diatoms are related to modern oceanographic properties five statistical assemblages given by five specific diatom species and or groups are related to upwelling chaetoceros spores subtropical thalassionema nitzschioides subarctic rhizosolenia hebetata transitional neodenticula seminae and freshwater freshwater diatoms ecological environments these factors are significantly correlated with primary productivity temperature nutrient concentrations and salinity although the strongest relationship is that between diatom assemblages and productivity however it is not possible to distinguish between coastal and open ocean curl driven upwelling based on chaetoceros spores relative percentages by themselves or on the floral factors

ice shelf tidal flexure and subglacial pressure variations abstract we develop a model of an ice shelf ice stream system as a viscoelastic beam partially supported by an elastic foundation when bedrock near the grounding line acts as a fulcrum leverage from the ice shelf dropping at low tide can cause significant 1 cm uplift in the first few kilometers of grounded ice this uplift and the corresponding depression at high tide lead to basal pressure variations of sufficient magnitude to influence subglacial hydrology tidal flexure may thus affect basal lubrication sediment flow and till strength all of which are significant factors in ice stream dynamics and grounding line stability under certain circumstances our results suggest the possibility of seawater being drawn into the subglacial water system the presence of seawater beneath grounded ice would significantly change the radar reflectivity of the grounding zone and complicate the interpretation of grounded versus floating ice based on ice penetrating radar observations

palaeoclimatic changes in the qinghai lake area during the last 18 000 years abstract multi proxy analysis of a sediment core from qinghai lake including pollen carbonate toc tn and 13 c of organic matter was used to document regional climatic changes during the last 18 000 years climate was very cold and dry before 16 9 cal kyr bp the warm and wet period which began at about 14 1 cal kyr bp culminated at 6 5 cal kyr bp and came to its end at about 4 5 cal kyr bp after that the climate gradually became colder and drier during the transitional period from the late glacial to the holocene the climate fluctuated frequently the short term climatic oscillations including the bolling allerod younger dryas and the cooling event at ca 8 2 cal kyr bp appear to be recorded in the qinghai lake sedimentary record the climatic evolution in the qinghai lake area during the past 18 000 years indicates that solar insolation changes on the ten thousand year scale are the likely driving force of the east asia monsoon

solute sources and geochemical processes in subglacial lake whillans west antarctica national science foundation nsf grants opp 0838933 1346250 and 1439774 italian national antarctic program barbante graduate fellowships from the nsf integrative graduate education and research traineeship program 0654336 and nsf center for dark energy biosphere investigations dissertation grant from the american association of university women

珪藻paralia sulcataの増減からみた大陸系混合水の消長 東シナ海北東部の最終氷期 後氷期海洋環境

inputs of glacially derived dissolved and colloidal iron to the coastal ocean and implications for primary productivity 1 glacial meltwaters draining shield bedrock under the greenland ice sheet gis contain 0 4 m total dissolved fe tdfe with an average flow weighted concentration of 53 nm the concentrations of 0 03 and 0 03 0 4 m fe vary over the ablation period with weighted means for each of these fractions being respectively 22 4 nm and 30 8 nm these concentrations are lower estimates as an adjacent larger glacier a more representative source of glacial meltwater had higher dissolved fe concentrations and reactions of meltwaters with proglacial sediments could also enhance dissolved fe concentrations this source of tdfe is additional to the reactive oxyhydr oxide phases identified by raiswell et al 2006 that are also introduced to adjacent polar seas from glaciers the fe concentrations in the shield bedrock underlying the gis are lower than those of other crustal rocks 4 0 cf 6 2 but we argue that these fe concentrations are not limiting on the total dissolved fe concentrations we measure the biogeochemical weathering processes operating on the subglacial debris and suspended sediment in our catchment are likely to be similar to those in other glaciated catchments therefore the meltwater fe concentrations reported here can be used to give a first estimate of global fluxes of meltwater dissolved fe to coastal polar waters a lower estimate of the global flux of tdfe from glacial meltwaters is 75 106 moles fe a this glacial meltwater input of fe to adjacent polar waters will be greatest around greenland where there are highest annual meltwater discharges however the greatest impact of this source of glacial meltwater fe is anticipated to be in antarctic high nutrient low chlorophyll hnlc waters where phytoplankton productivity is typically limited by availability of fe for antarctic waters the estimated meltwater fe tdfe input is about 10 of that suggested to come from sea ice melting but glacial inputs continue throughout the austral summer ablation period after sea ice melt is complete

geochemical weathering at the bed of haut glacier d arolla switzerland a new model waters were sampled from 17 boreholes at haut glacier d arolla during the 1993 and 1994 ablation seasons three types of concentrated subglacial water were identified based on the relative proportions of ca 2c h co 3 and so4 2 to si type a waters are the most solute rich and have the lowest relative proportion of si they are believed to form in hydrologically inefficient areas of a distributed drainage system most solute is obtained from coupled sulphide oxidation and carbonate dissolution so cd it is possible that there is a subglacial source of o2 perhaps from gas bubbles released during regelation because the high so4 2 levels found up to 1200 eq l are greater than could be achieved if sulphides are oxidized by oxygen in saturated water at 0 c c 414 eq l a more likely alternative is that sulphide is oxidized by fe 3c in anoxic environments if this is the case exchange reactions involving fe iii and fe ii from silicates are possible these have the potential to generate relatively high concentrations of hco3 with respect to so4 2 formation of secondary weathering products such as clays may explain the low si concentrations of type a waters type b waters were the most frequently sampled subglacial water they are believed to be representative of waters flowing in more efficient parts of a distributed drainage system residence time and reaction kinetics help determine the solute composition of these waters the initial water rock reactions are carbonate and silicate hydrolysis and there is exchange of divalent cations from solution for monovalent cations held on surface exchange sites hydrolysis is followed by so cd the so4 2 concentrations usually are 414 eq l although some range up to 580 eq l which suggests that elements of the distributed drainage system may become anoxic type c waters were the most dilute yet they were very turbid their chemical composition is characterized by low so4 2 h co3 ratios and high ph type c waters were usually artefacts of the borehole chemical weathering environment true type c waters are believed to flow through sulphide poor basal debris particularly in the channel marginal zone the composition of bulk runoff was most similar to diluted type b waters at high discharge and was similar to a mixture of type b and c waters at lower discharge these observations suggest that some supraglacial meltwaters input to the bed are stored temporarily in the channel marginal zone during rising discharge and are released during declining flow little of the subglacial chemical weathering we infer is associated with the sequestration of atmospheric co2 t he progression of reactions is from carbonate and silicate hydrolysis through sulphide oxidation by first oxygen and then fe iii which drives further carbonate and silicate weathering a crude estimate of the ratio of carbonate to silicate weathering following hydrolysis is 4 1 we speculate that microbial oxidation of organic carbon also may occur both sulphide oxidation and microbial oxidation of organic carbon are likely to drive the bed towards suboxic conditions hence we believe that subglacial chemical weathering does not sequester significant quantities of atmospheric co2 and that one of the key controls on the rate and magnitude of solute acquisition is microbial activity which catalyses the reduction of fe iii and the oxidation of fes2 copyright 2002 john wiley sons ltd

complexity of holocene climate as reconstructed from a greenland ice core glaciochemical time series developed from summit greenland indicate that the chemical composition of the atmosphere was dynamic during the holocene epoch concentrations of sea salt and terrestrial dusts increased in summit snow during the periods 0 to 600 2400 to 3100 5000 to 6100 7800 to 8800 and more than 11 300 years ago the most recent increase and also the most abrupt coincides with the little ice age these changes imply that either the north polar vortex expanded or the meridional air flow intensified during these periods and that temperatures in the mid to high northern latitudes were potentially the coldest since the younger dryas event

influence of bedrock mineral composition on microbial diversity in a subglacial environment microorganisms in subglacial environments drive the chemical weathering of bedrock however the influence of bedrock mineralogy on the composition and activity of microbial assemblages in such environments is poorly understood here using a combination of in situ mineral incubation and dna fingerprinting techniques we demonstrate that pyrite is the dominant mineralogical control on subglacial bacterial community structure and composition in addition we show that the abundance of fe in the incubated minerals influences the development of mineral associated biomass the ubiquitous nature of pyrite in many common bedrock types and high so 4 2 concentrations in most glacial meltwaters suggest that pyrite may be a dominant lithogenic control on microbial communities in many subglacial systems mineral based energy may therefore serve a fundamental role in sustaining subglacial microbial populations and enabling their persistence over glacial interglacial time scales

diatom record of the late holocene in the okhotsk sea abstract the environmental conditions during the past 7000 cal yr bp in the okhotsk sea can be subdivided into three intervals based on diatom assemblages 1 6600 4650 cal yr bp open ocean sea ice free conditions alternated with sea ice cover 2 4650 1300 cal yr bp open ocean conditions and sea ice cover declined fluctuating with short duration and cold open ocean conditions gradually developed and 3 1300 cal yr bp present when cold open ocean conditions predominated with occasional and rapid warming chronological comparisons between climatic fluctuations and cultural history in hokkaido and okhotsk suggest that deteriorating climate could have affected local culture

the geochemistry of redox sensitive trace metals in sediments abstract we analyzed the redox sensitive elements v mo u re and cd in surface sediments from the northwest african margin the u s northwest margin and the arabian sea to determine their response under a range of redox conditions where oxygen penetrates 1 cm or less into the sediments mo and v diffuse to the overlying water as mn is reduced and remobilized authigenic enrichments of u re and cd are evident under these redox conditions with the onset of sulfate reduction all of the metals accumulate authigenically with re being by far the most enriched general trends in authigenic metal accumulation are described by calculating authigenic fluxes for the 3 main redox regimes oxic reducing where oxygen penetrates 1 cm and anoxic conditions using a simple diagenesis model and global estimates of organic carbon rain rate and bottom water oxygen concentrations we calculate the area of sediments below 1000 m water depth in which oxygen penetration is 1 cm to be 4 of the ocean floor we conclude that sediments where oxygen penetrates 1 cm release mn v and mo to seawater at rates of 140 260 60 150 and 5 10 of their respective riverine fluxes using the authigenic metal concentrations and accumulation rates from this work and other literature these sediments are sinks for re cd and u with burial fluxes of 70 140 30 80 and 20 40 respectively of their dissolved riverine inputs we modeled the sensitivity of the response of seawater re cd and v concentrations to changes in the area of reducing sediments where oxygen penetrates 1 cm our analysis suggests a negligible change in seawater re concentration whereas seawater concentrations of cd and v could have decreased and increased respectively by 5 10 over 20 kyr if the area of reducing sediments increased by a factor of 2 and by 10 20 if the area increased by a factor of 3 the concentration variations for a factor of 2 increase in the area of reducing sediments are at about the level of uncertainty of cd ca and v ca ratios observed in foraminifera shells over the last 40 kyr this implies that the area of reducing sediments in the ocean deeper than 1000 m 4 has not been greater than twice the present value in the recent past

the supply of subglacial meltwater to the grounding line of the siple coast west antarctica recent satellite studies have shown that active subglacial lakes exist under the antarctic ice streams and persist almost to their grounding lines when the lowest lying lakes flood the water crosses the grounding line and enters the sub ice shelf cavity modeling results suggest that this additional freshwater influx may significantly enhance melting at the ice shelf base we examine the spatial and temporal variability in subglacial water supply to the grounding lines of the siple coast ice streams by combining estimates for lake volume change derived from ice cloud and land elevation satellite icesat data with a model for subglacial water transport our results suggest that subglacial outflow tends to concentrate towards six embayments in the siple coast grounding line although mean grounding line outflow is 60m3 s 1 for the entire siple coast maximum local grounding line outflow may temporarily exceed 300 m3 s 1 during the synchronized flooding of multiple lakes in a hydrologic basin variability in subglacial outflow due to subglacial lake drainage may account for a substantial portion of the observed variability in freshwater flux out of the ross ice shelf cavity the temporal variability in grounding line outflow results in a net reduction in long term average melt rate but temporary peak melting rates may exceed the long term average by a factor of three

land ocean linkages over orbital and millennial timescales recorded in late quaternary sediments of the japan sea late quaternary sediments of the japan sea are characterized by centimeter to meter scale alternations of dark and light layers which are synchronous basinwide high resolution analyses of the sediments from ocean drilling program site 797 reveal that deposition of the meter scale alternations reflect variations in paleoceanographic conditions which were closely associated with glacio eustatic sea level changes through the modulation of the volume and character of the influx to the sea through the tsushima strait the centimeter to decimeter scale alternations reflect millennial scale variations which are possibly associated with dansgaard oeschger d o cycles with each dark layer appearing to correspond to an interstadial this variability is attributed to the development of a humid climate in central to eastern asia and the consequent increase in discharge from the huanghe and changjiang rivers during interstadials this caused expansion of the east china sea coastal water ecscw which penetrated more strongly into the japan sea the increased influence of the lower salinity nutrient enriched ecscw reduced deep water ventilation and enhanced the surface productivity leading to the development of anoxic bottom waters and deposition of the dark layers thus the centimeter to decimeter scale alternations of the dark and light layers record wet and dry cycles in central to eastern asia possibly associated with d o cycles

chemical weathering in glacial environments do glaciers enhance or inhibit chemical weathering rates relative to other environments the importance of glaciers in the global carbon cycle and climate change hinges on the answer we show that catchments occupied by active alpine glaciers yield cation denudation rates greater than the global mean rate but do not exceed rates in nonglacial catchments with similar water discharge silica denudation rates are distinctly lower in glacier covered catchments than in their nonglacial counterparts because sediment yields are high from glaciers this suggests that water flux rather than physical erosion exerts the primary control on chemical erosion by glaciers potassium and calcium concentrations are high relative to other cations in glacial water probably due to dissolution of soluble trace phases such as carbonates exposed by comminution and cation leaching from biotite preferential weathering of biotite may result in higher 87 sr 86 sr in glacial runoff than expected from whole rock compositions thus although glaciers do not influence total chemical denudation rates at a given runoff they may yield compositionally distinctive chemical fluxes to the oceans disruption of mineral lattices by grinding increases dissolution rates this and high surface area should make glacial sediments exceptionally weatherable weathering of glacial erosion products in environments beyond the glacier margin deserves attention because it may figure prominently in global chemical cycles

successive oceanic and solar forcing indicated by younger dryas and early holocene climatic oscillations in the jura abstract the recent extension of 1 the residual 14 c curve back to 11 400 cal yr b p and 2 the lake level reconstruction in the jura back to ca 13 500 cal yr b p offers the opportunity of testing by proxy data the relationships between climate atmospheric 14 c the sun and the ocean recently suggested from the atmospheric 14 c record the climatic significance of the jura record is supported by correlations with climatic oscillations reconstructed in the alps from glaciers and timberline movements correspondence between the 14 c and paleoclimatic record from the jura suggests a working hypothesis two intervals within the holocene can be distinguished in the middle latitudes of western and central europe an early holocene period shows abrupt climatic oscillations linked to ocean forcing major colder climate phases developed between ca 9000 and 8800 and between ca 8000 and 7000 cal yr b c that coincide with higher 14 c values after 6000 cal yr b c a second period is characterized by smoother multicentury climatic oscillations linked to solar forcing

biolabile ferrous iron bearing nanoparticles in glacial sediments abstract glaciers and ice sheets are a significant source of nanoparticulate fe which is potentially important in sustaining the high productivity observed in the near coastal regions proximal to terrestrial ice cover however the bioavailability of particulate iron is poorly understood despite its importance in the ocean fe inventory we combined high resolution imaging and spectroscopy to investigate the abundance morphology and valence state of particulate iron in glacial sediments our results document the widespread occurrence of amorphous and fe ii rich and fe ii bearing nanoparticles in arctic glacial meltwaters and iceberg debris compared to fe iii rich dominated particulates in an aeolian dust sample fe ii is thought to be highly biolabile in marine environments our work shows that glacially derived fe is more labile than previously assumed and consequently that glaciers and ice sheets are therefore able to export potentially bioavailable fe ii containing nanoparticulate material to downstream ecosystems including those in a marine setting our findings provide further evidence that greenland ice sheet meltwaters may provide biolabile particulate fe that may fuel the large summer phytoplankton bloom in the labrador sea and that fe ii rich particulates from a region of very high productivity downstream of a polar ice sheet may be glacial in origin

paleoceanography during the last 150 kyr off central japan based on diatom floras abstract the paleoceanographic history of the area above the northern boundary of the warm kuroshio current during the last two glacial interglacial cycles was reconstructed based on high resolution records of the diatom flora in core md01 2421 ecological categories of the diatom flora were extracted using q mode factor analysis the four most prominent factors explained 91 4 of the total variance cross spectral analyses were performed on temperature estimates derived from diatom data td the relative abundance of littoral neritic diatom associations and the oxygen isotope record of benthic foraminifera diatom derived temperatures show a 50 23 and 17 kyr periodicity with only the 23 kyr band coherent with that of benthic foraminiferal oxygen isotope values littoral neritic associations show a periodicity at 62 and 17 kyr coherent with td species composition and relative abundance of the diatom flora changed at the marine isotope stage boundaries when cold water and warm water mixed over the core site due to hydrographic disturbances by changes in transport trajectory of the kuroshio current transport and global climatic changes

sedimentary processes at the base of a west antarctic ice stream constraints from textural and compositional properties of subglacial debris samples of sediments from beneath ice stream b at camp upb west antarctica provide the first opportunity to study the relationship between sediment properties and physical conditions in a sub ice stream environment piston coring in holes bored by hot water drilling yielded five 1 3 m long undisturbed subglacial sediment cores we analyzed granulometry composition and particle morphology in these cores the upb cores are composed of a clay rich unsorted diamicton containing rare marine diatoms sedimentary particles in these cores bear no evidence of the recent crushing or abrasion that is common in other subglacial sedimentary environments the presence of reworked diatoms and their state of preservation as well as the relative spatial homogeneity of this diamicton suggest that the upb cores sampled a several meter thick till layer and not in situ glacimarine sediments the till does incorporate material recycled from the subjacent poorly indurated tertiary glacimarine sediments of the ross sea sedimentary basin which extends beneath this part of the west antarctic ice sheet we propose that the lack of significant comminution in the upb till is ultimately due to its setting over these easily erodible clay rich source sediments the resulting fine grained till matrix inhibits glacial comminution because it facilitates buildup of high pore water pressures and hinders interparticle stress concentrations our observations are consistent with the conjecture that subglacial deformation of weak fine grained tills does not produce significant comminution of till debris elson 1988 based on our findings we hypothesize that extensive layers of weak till may develop preferentially where ice overrides preexisting poorly indurated fine grained sediments since such weak till layers create a permissive condition for ice streaming sub glacial geology may have an indirect but strong control over the location extent and basal mechanics of ice streams

chemical weathering signatures from mt achernar moraine central transantarctic mountains i subglacial sediments compared with underlying rock abstract in order to determine chemical weathering rates on the subglacial land surface of antarctica we compare the composition and mineralogy of freshly emerging fine sediments to that of the underlying bedrock as represented by glacially derived cobble sized clasts samples were collected from mt achernar moraine a large blue ice moraine where subglacial material naturally emerges through sublimation of the surrounding ice both rocks and sediments were analyzed for total elemental composition mineral abundance by x ray diffraction and by sequential extractions targeting chemical weathering products the fine sediment fraction is significantly enriched in chemical weathering products and depleted in primary minerals compared with the cobble clasts the alteration pathways consist primarily of the development of smectite kaolinite carbonate minerals and amorphous material extensive fe oxidation is evidenced by a decline in magnetic susceptibility and by increases in extractable fe if we assume the only input into the subglacial system is the water and ice trapped gas supplied by basal melt the net chemical alteration is explained through oxidation of organic matter equal to 0 7 of the bedrock mass and subsequent carbonation weathering the underlying sedimentary rock is sufficiently rich in organic matter for this pathway to be plausible for the o2 that is oxidizing organic matter to be supplied by basal meltwater water fluxes would need to be three orders of magnitude larger than sediment fluxes independent models of basal melt and sediment transport at our field site confirm that such a difference between water and sediment flux is likely at the study site the rate of subglacial carbonation weathering inferred from the mt achernar moraine site may be comparable to that found in high latitude subaerial environments if mt achernar moraine is typical of other antarctic sites the subglacial land surface of antarctica does play a role in global geochemical cycling

u pb geochronology of zircons from fossiliferous sediments of the hajnacka i maar slovakia type locality of the mn 16a biostratigraphic subzone lacustrine sediments of the hajnacka i maar of southern slovakia contain teeth and skeletal remains of a mammal fauna including index early villanyian arvicoline rodents u pb dating of magmatic zircons extracted from the redeposited fossiliferous maar sediments revealed a total of six volcanic events the oldest age of 3 43 ma was interpreted as that corresponding to the initial phreato magmatic eruption that created the maar most zircons grouped around 3 06 0 03 ma the age attributed to the catastrophic eruption that killed the mammal assemblage thriving within and around the maar studied this age coincides with the 3 1 ma boundary between the mn 16a and 16b subzones of the european mammal neogene chronostratigraphic scale estimated from the succession of early villanyian palaeontological localities according to the hypsometry of rodent teeth younger zircon ages overlapped those of the neighbouring basaltic lava flows necks and dykes thus recording superimposed effusions the youngest 1 58 ma old zircon defines the age limit for the final redeposition of the fossiliferous sediments in the maar drainage lake regime