inherent anisotropic stiffness of weathered geomaterial and its influence on ground deformations around deep excavations the shear modulus g0 at very small strain 0 001 or less is an important parameter for predicting ground movements of many geotechnical structures recent advances in laboratory testing enable th

molybdenum isotope signatures in continental margin marine sediments abstract we present molybdenum isotope data for four sediment profiles from continental margin settings each profile has a distinctive average isotope composition ranging from 98 95 mo 0 5 to 1 3 relative to j and m laboratory standard this range lies between the modern ocean water value 2 3 and the values typical of mo adsorbed onto mn oxides 0 7 0 1 an important finding of this study is the apparent co variation between the mo isotope composition and the accumulation rate of authigenic mo under reducing conditions this relationship suggests that the chemical processes responsible for mo accumulation under reducing conditions produce an isotope signature in marine sediments in addition to the relationship between mo accumulation and the mo isotope signature there is also a relationship between these parameters and the rate of organic carbon oxidation and burial these relationships suggest that the mo isotope signature of reducing sediments may serve as a tracer for the cycling of organic carbon in continental margin sediments however additional data will be required to refine any such relationships

advanced application of seismic cone penetration test at complex ground conditions abstract seismic piezocone test scptu is a representative geophysical and geotechnical in situ test which can generate multiple types of independent readings and collect relatively continuous data as well as investigate both vertical and lateral spatial variability for geo characterization this study presents special and advanced applications of scptu towards geotechnical site investigations in west central south carolina us which consists of very complex soil formations and unusual geologic settings the special geologic conditions include apparent gap graded soils calcareous soils cementious bonding desiccation ageing and the dissolutioning of old calcareous sediments santee formation at depths of 40 to 50 meter below grade similar to karstic limestone deposits especially diagenetic processes in the santee carbonate mineral sediments have resulted in caves voids and infilled soft soil zones within the soil matrix at these elevations the data obtained from scptu system are successfully utilized for assessing the various special geologic conditions furthermore a unique example is introduced to represent the powerful application of scptu toward special void detection

rhenium and molybdenum enrichments in sediments as indicators of oxic suboxic and sulfidic conditions of deposition abstract the trace elements re and mo both behave conservatively in seawater yet are strongly enriched in reducing sediments their potential for authigenic enrichment above crustal concentrations is greater than for many other elements due to the high ratio of metal sw metal crust we present sedimentary re and mo data from box and multi cores spanning a range of redox conditions from well oxygenated sites to locations with substantial sulfide concentrations at the oxic sites re and mo as expected accumulate at concentrations close to their crustal abundances re shows substantial enrichment in suboxic absence of o 2 and h 2 s sediments of the sea of japan in sediments within the oxygen minimum of the pakistan margin as well as in sediments underlying the sulfide bearing waters of the black sea and saanich inlet re enrichment occurs in these cores just below the depths of fe and u reduction only in the sediments underlying the sulfidic waters of the black sea and saanich inlet is there substantial authigenic mo accumulation absence of re and mo enrichments in sediment trap samples from the sulfide bearing basins suggests that the addition of both metals occurs at or below the sediment water interface the re and mo concentration profiles are modeled to hindcast the removal depth of re and mo in the sediments which along with the re mo ratio determine whether oxic suboxic or sulfidic conditions were present in the water column or in the sediments in the past using this approach historical redox conditions can be inferred even in environments such as continental margins where a substantial lithogenic component can obscure authigenic enrichments of other metals

natural mass dependent variations in the isotopic composition of molybdenum we present the first observations of natural mass dependent fractionation of the isotopic composition of molybdenum mo using multi collector inductively coupled plasma mass spectrometry variations in the isotopic composition of mo are reported as 97 95mo 97mo 95mo sample 97mo 95mo standard 1 1000 external analytical precision of 97 95mo is 1 between sediments deposited under anoxic conditions 97 95mo 1 02 to 1 52 relative to our in house standard and ferromanganese nodules 97 95mo 0 63 to 0 42 97 95mo of pacific ocean seawater 97 95mo 1 48 lies within the range of values for anoxic sediments closest to modern black sea anoxic sediments molybdenites from continental ore deposits have intermediate 97 95mo ranging from 0 26 to 0 09 variations in the abundances of 92mo 95mo 96mo 97mo and 98mo are consistent with mass dependent fractionation a sporadic unidentified interference occurs at mass 94 and 100mo is not measured we hypothesize that the 97 95mo offset between anoxic sediments and ferromanganese nodules results from mo isotope fractionation during inefficient scavenging of mo from seawater by mn oxides under oxic conditions the similarity in 97 95mo of anoxic sediments and seawater is consistent with the very efficient removal of mo from seawater under anoxic conditions in the presence of h2s the data can be interpreted in terms of a steady state mass balance between the mo flux into the oceans from the continents and the mo flux out of the oceans into oxic and anoxic sediments such an interpretation is quantitatively consistent with existing estimates of the removal fluxes of mo to anoxic and oxic sediments these findings suggest that 97 95mo in seawater may co vary with changes in the relative proportions of anoxic and oxic sedimentation in the oceans and that this variation may be recorded in 97 95mo of anoxic sediments hence the mo isotope system may be useful in paleoredox investigations

an expanded shale δ98mo record permits recurrent shallow marine oxygenation during the neoarchean abstract multiple attempts have been made using the ancient shale record to track the molybdenum isotope composition 98mo of seawater during the final two hundred million years of the archean eon 2 7 to 2 5 billion years ago or ga this seawater 98mo value is important because it should have scaled with levels of ocean oxygenation during the runup to the great oxidation event goe unfortunately however it is difficult to tell if the majority of the existing late archean shale 98mo record tracks an ancient seawater value here we further attempt to track pre goe seawater 98mo using an expanded and well characterized shale sample set from western australia jeerinah wittenoom and mt sylvia formations and south africa nauga and klein naute formations most importantly and in contrast to most previous mo isotope studies of similarly aged shales local redox conditions for our shales have been independently constrained using the iron fe speciation proxy and bottom water mo contents at the time of deposition have been qualitatively estimated using mo toc ratios local redox conditions and bottom water mo availability are important parameters because transfer of the seawater 98mo to sediments today is shown to be dependent on these conditions according to our updated sedimentary 98mo record seawater 98mo commonly exceeded 1 0 between 2 69 ga and 2 50 ga in order to drive such a heavy seawater 98mo there must have been a marine sink with a strong preference for lighter mass mo isotopes frequently present over this timeframe the operation of some anaerobic processes in late archean marine settings could theoretically explain the heavier seawater 98mo such processes are known to promote the preferential retention of lighter mass mo isotopes in marine sediments today e g interactions between mo and organic matter or the formation of thio complexes alternatively or in addition adsorption of lighter mass mo isotopes to fe and mn oxide minerals formed in oxygenated marine environments can explain the heavier seawater 98mo a compilation of previous work suggests that oxygenated shallow marine environments were fairly common during the late archean and thus mo adsorption to fe mn oxides formed in these settings probably played an important role in driving heavy seawater 98mo over this timeframe

the saturnian ribbon feature a baroclinically unstable model images of saturn from the two voyager spacecraft showed few discrete atmospheric features in the low contrast latitudinal banding over the planet one unusual feature however was a narrow dark oscillatory structure encircling the planet in the light zone at 45 to 50 north this paper presents a description of this dark structure which we call the ribbon feature a wavelength of 5710 260 km is obtained from moderate resolution images which were used to produce a 360 image of the feature higher resolution image pairs were used to examine the local circulation which shows counterclockwise rotation north of the ribbon and clockwise rotation south of it the zonal circulation measurements show that it is located in a 120 m sec 1 westerly jet but with a small 5 m sec 1 meridional velocity the infrared spectrometer results from voyager showed the greatest thermal wind sheer in this latitude region the regions adjacent to the ribbon are of similar brightness except for the uv 3400 a filter images where the northern part of this zone is lighter than the southern section from this observation we have estimated that the disturbance associated with the ribbon feature extends to at least the 200 mbar level a study of a 120 section of the ribbon feature and the associated latitudinal thermal gradient by l a sromovsky h e revercomb r j krauss and v e suomi 1983 j geophys res 88 8650 8666 led them to suggest that it was produced by some form of baroclinic instability this proposal is considered here with other alternative types of instability we conclude that the ribbon feature could arise from a baroclinic instability we then develop a numerical model of such an instability that is consistent with the observed wavelength the vertical extent of the ribbon and the local latitudinal thermal profile

evaluation of in situ anisotropy from crosshole and downhole shear wave velocity measurements downhole and cross hole shear wave velocity determinations are becoming a routine part of dynamic site evaluation studies the in situ measurements are frequently performed in boreholes using a variety of techniques a seismic cone system has been developed for determining both downhole and crosshole shear wave velocity the system consists of a source and two receivers all embodied in penetrometers at any depth three different polarized sets of shear wave signals can be generated and are recorded by both receivers located at different distances from the source it has been suggested from laboratory tests in large chambers that the measured shear wave velocities can be used to evaluate the in situ stress conditions tests have been performed at research sites in vancouver to evaluate the in situ stress dependence of the measured shear wave velocities the results of this study suggest that variations in structural anisotropy are the predominant factors controlling the directional shear wave velocities

continuous interval shear wave velocity profiling by auto source and seismic piezocone tests a new exploratory procedure for collecting continuous shear wave velocity measurements via cone penetration testing using a special autoseis source is presented whereby wavelets can be generated and recorded every 1 to 10 s the continuous interval seismic piezocone test ciscptu offers a fast productive and reliable means to expedite the collection of downhole shear wave velocity profiles as well as additional readings on cone tip resistance sleeve friction and penetration porewater pressures with depth a site in windsor virginia is utilized for illustrating the collection of data calibration and post processing issues arising from large numbers of wavelets that require filtering windowing and selection in both time and frequency domain analyses at the test site the geology consists of shallow holocene deposits of clays and sands to 8 m that are underlain by much stiffer calcareous sandy marine clay soils of miocene age which extend beyond the termination depths of the soundings at 30 m

tomographic imaging of permafrost using three component seismic cone penetration test we conducted seismic cone penetration tests scpt and tomographic imaging in a permafrost mound in northern quebec canada to study the cryostratigraphy and assess the seismic properties of permafrost at temperatures near 0 c a swept impact source generating both p and s waves and penetrometer mounted three component accelerometers were used to acquire surface to depth first arrival times as input to produce 2d images of p and s wave velocities based on the three component accelerometer records and the propagation modes of body waves the p and s wave first arrivals were detected and discriminated the inversion of the first arrival times was based on the simultaneous iterative reconstruction technique the multioffset surface to depth geometry used in this study limits the lateral resolution of tomographic imaging however the vertical variation in seismic velocities in the permafrost mound shows good reproducibility and can be compared to the cone data the gathering of cone data such as cone r

in situ lateral stress coefficient k0 from shear wave velocity measurements in soils abstractthe at rest lateral stress coefficient k0 is an important soil parameter in geotechnical design problems and yet it is quite elusive in our ability to assess its value either by laboratory or in situ tests in this study an innovative geophysics approach toward the evaluation of the in situ k0 profile with depth is obtained by using small strain stiffness anisotropy ratio g0 hh g0 vh in soils the newly proposed k0 equation is derived from a database compiled from 12 test sites which have direct k0 measurements as procured from field tests either self boring pressuremeters sbp or total stress cells tsc and or laboratory triaxial tests instrumented consolidometers and or suction measurements the data show a strong relationship between the overconsolidation difference ocd p vo and stiffness anisotropy ratio thus enabling a k0 assessment in clays silts and sands

mo total organic carbon covariation in modern anoxic marine environments implications for analysis of paleoredox and paleohydrographic conditions 1 sedimentary molybdenum mo s has been widely used as a proxy for benthic redox potential owing to its generally strong enrichment in organic rich marine facies deposited under oxygen depleted conditions a detailed analysis of mo s total organic carbon toc covariation in modern anoxic marine environments and its relationship to ambient water chemistry suggests that 1 mo s while useful in distinguishing oxic from anoxic facies is not related in a simple manner to dissolved sulfide concentrations within euxinic environments and 2 patterns of mo s toc covariation can provide information about paleohydrographic conditions especially the degree of restriction of the subchemoclinal water mass and temporal changes thereof related to deepwater renewal these inferences are based on data from four anoxic silled basins the black sea framvaren fjord cariaco basin and saanich inlet and one upwelling zone the namibian shelf representing a spectrum of aqueous chemical conditions related to water mass restriction in the silled basin environments increasing restriction is correlated with a systematic decrease in mo s toc ratios from 45 5 for saanich inlet to 4 5 1 for the black sea this variation reflects control of mo s by mo aq which becomes depleted in stagnant basins through removal to the sediment without adequate resupply by deepwater renewal the basin reservoir effect the temporal dynamics of this process are revealed by high resolution chemostratigraphic data from framvaren fjord and cariaco basin sediment cores which exhibit long term trends toward lower mo s toc ratios following development of water column stratification and deepwater anoxia mo burial fluxes peak in weakly sulfidic environments such as saanich inlet owing to a combination of greater mo aq availability and enhanced mo transport to the sediment water interface via fe mn redox cycling and are lower in strongly sulfidic environments such as the black sea and framvaren fjord these observations demonstrate that at timescales associated with deepwater renewal in anoxic silled basins decreased sedimentary mo concentrations and burial fluxes are associated with lower benthic redox potentials i e more sulfidic conditions these conclusions apply only to anoxic marine environments exhibiting some degree of water mass restriction e g silled basins and are not valid for low oxygen facies in open marine settings such as continent margin upwelling systems

century long record of mo isotopic composition in sediments of a seasonally anoxic estuary chesapeake bay abstract a double spike method was used to obtain mo isotope data for sediments and waters of the seasonally anoxic chesapeake bay and its primary tributary the susquehanna river the dissolved mo distribution in the estuary is non conservative reflecting minor mo loss to the sediments although removal of mo to the sediments does not have a large influence on the isotopic composition of the water column the 98mo of dissolved mo in most of the estuary is dominated by seawater six samples with salinity 15 have an average 98mo 2 17 0 12 which agrees well with a 98mo value for the cass 4 seawater standard of 2 23 a single sample of susquehanna river water has a 98mo of 1 02 consistent with recent findings of positive 98mo in rivers worldwide susquehanna river sediments in contrast have 98mo 0 1 the difference between the river water and sediment values implies that isotopic fractionation occurs within the river basin the 98mo values for estuarine sediments are offset from values in the overlying water most samples deposited before 1925 have 98mo less than 0 similar to the susquehanna sediments subsequently there is an increase in the variability of 98mo with values ranging up to 0 8 the transition to increased variability coincides with the onset of authigenic mo deposition which was previously attributed to escalating summertime anoxia authigenic mo concentrations correlate poorly with 98mo in core samples suggesting that independent mechanisms influence the two parameters authigenic mo concentrations may be controlled by shifting pore water h2s levels while 98mo may be primarily affected by annual variations in mn refluxing

a microelectromechanical system digital 3c array seismic cone penetrometer a digital 3c array seismic cone penetrometer has been developed for multidisciplinary geophysical and geotechnical applications seven digital triaxial microelectromechanical system accelerometers are installed at 0 25 m intervals to make a 1 5 m long downhole seismic array the accelerometers have a flat response up to 2 khz the seismic array is attached to a class 1 digital seismic cone which measures cone tip resistance sleeve friction pore pressure and inclination the downhole 3c array can be used together with impulsive seismic sources and or high frequency vibrators that are suitable for high resolution shallow applications results from two field experiments showed that a good data quality including a constant source function within an array and a dense depth sampling allowed robust estimation of seismic velocity profiles in the shallow subsoil using horizontal and vertical seismic sources downhole 9c seismic array data can be easily acquired the quality of the shear wave data is much superior when the surface seismic source is a controlled high frequency vibrator in stead of a traditional sledge hammer a remarkable correlation in depth in a fine scale between low strain seismic shear wave velocity and high strain cone tip resistance could be observed the array measurements of the full elastic wavefield and the broad spectral bandwidth are useful in investigating frequency dependent seismic wave propagation in the porous near surface soil layers which is informative of the in situ fluid flow properties stable estimates of dispersive seismic velocity and attenuation can be obtained

hydrogen sulphide release to surface waters at the precambrian cambrian boundary changes in environmental conditions at the precambrian cambrian transition around 542 million years ago have been suggested as a possible explanation for the apparent rapid increase in abundance of multicellular organisms known as the cambrian explosion the nature of the environmental changes is still a matter of debate however wille et al now report molybdenum isotope signatures of black shales from two stratigraphically correlated sample sets with a depositional age of about 542 million years with the help of a box model of the oceanic molybdenum cycle they find that intense upwelling of hydrogen sulphide rich deep ocean water best explains the observed early cambrian molybdenum isotope signal this suggests that the early cambrian animal radiation may have been triggered by a major change in ocean circulation following a long period during which the ocean was stratified with sulphidic deep water this paper reports molybdenum isotope signatures of black shales from two stratigraphically correlated sample sets with a depositional age of around 542 million years the findings suggest that the early cambrian animal radiation may have been triggered by a major change in ocean circulation terminating a long period during which the proterozoic ocean was stratified with sulphidic deep water animal like multicellular fossils appeared towards the end of the precambrian followed by a rapid increase in the abundance and diversity of fossils during the early cambrian period an event also known as the cambrian explosion 1 2 3 changes in the environmental conditions at the precambrian cambrian transition about 542 myr ago have been suggested as a possible explanation for this event but are still a matter of debate1 2 3 here we report molybdenum isotope signatures of black shales from two stratigraphically correlated sample sets with a depositional age of around 542 myr we find a transient molybdenum isotope signal immediately after the precambrian cambrian transition using a box model of the oceanic molybdenum cycle we find that intense upwelling of hydrogen sulphide rich deep ocean water best explains the observed early cambrian molybdenum isotope signal our findings suggest that the early cambrian animal radiation may have been triggered by a major change in ocean circulation terminating a long period during which the proterozoic ocean was stratified with sulphidic deep water

determination of molybdenum isotope fractionation by double spike multicollector inductively coupled plasma mass spectrometry 1 molybdenum isotopic compositions are precisely determined by mc icp ms measurements using a mo double spike the double spike is added prior to chemical purification so that laboratory and instrumental mass fractionations are separated from natural mass dependent fractionation fractionation is determined on four mo mass ratios providing an internal consistency check the external standard reproducibility is at 0 06 per mil on the 98mo 95mo ratio 2 standard deviation using a normal microconcentric nebuliser with a cyclonic spray chamber the minimum quantity of mo is 1 g for high precision results a hydrothermal molybdenite shows fractionation of 0 3 per mil on the 98mo 95mo ratio relative to our standard johnson matthey 1000 g ml 0 3 icp standard solution lot 602332b fine grained sediments show fractionation of 0 1 and 0 3 per mil on the 98mo 95mo ratio the observed mo isotope fractionation is small but resolvable with the presented high resolution technique

authigenic molybdenum isotope signatures in marine sediments we present new mo isotope data from the mexican continen tal margin that in conjunction with previous data allow us to propose a mechanistic description of the mo isotope system in ma rine sediments we hypothesize that there are unique environmen tally dependent mo isotope signatures recorded in marine sedi ments that reflect the mechanisms responsible for authigenic mo accumulation open ocean anoxic sites defined as having dissolved oxygen and sulfide concentrations near zero in the overlying water exhibit a 98 95 mo isotope signature of 1 6 we believe this val ue reflects mo sulfide formation via diagenetic processes within sediments quantitative formation of mo sulfide within the sulfidic water column of euxinic environments results in sediment isotope values similar to the modern seawater value 2 3 as typified by samples from the highly sulfidic black sea in contrast to these reducing settings manganese oxide rich sediments have measured mo isotope values that are more negative relative to seawater than any other sediment samples analyzed to date similar to fe mn crusts 0 7 most measured mo isotope compositions of marine sediments from open ocean settings appear to reflect a mix ture of lithogenic mo 0 0 and the mo signature of a specific authigenic mo accumulation mechanism we therefore suggest that mo isotopes may record unique signatures that reflect the domi nant chemical mechanism for mo sequestration into sediments

molybdenum isotope evidence for widespread anoxia in mid proterozoic oceans how much dissolved oxygen was present in the mid proterozoic oceans between 1 8 and 1 0 billion years ago is debated vigorously one model argues for oxygenation of the oceans soon after the initial rise of atmospheric oxygen 2 3 billion years ago recent evidence for h 2 s in some mid proterozoic marine basins suggests however that the deep ocean remained anoxic until much later new molybdenum isotope data from modern and ancient sediments indicate expanded anoxia during the mid proterozoic compared to the present day ocean consequently oxygenation of the deep oceans may have lagged that of the atmosphere by over a billion years

sulfidity controls molybdenum isotope fractionation into euxinic sediments evidence from the modern black sea molybdenum mo isotope fractionation has recently been introduced as a new proxy in oceanography and biogeochemistry it is therefore fundamental to understand the processes controlling mo partitioning into modern marine environments this study identifies the availability of dissolved sulfide as the dominant control on overall mo removal from the water column in euxinic systems mo isotopic composition of surface sediments from different localities of the black sea demonstrates complete fixation of mo only below 400 m water depth above a critical concentration of 11 mol l 1 aqueous hydrogen sulfide in the bottom water the mo isotopic composition of these sediments reflects the homogeneous seawater isotopic composition of 2 3 in contrast significant mo isotope fractionation into less euxinic sediments is evident at shallower depths in the black sea as well as in temporarily euxinic deeps of the baltic sea consistent with the observed lower maximum sulfide concentrations in the respective water columns therefore mo isotope signatures in the modern black sea constrain the processes responsible for global mo removal from the ocean by euxinic sediments furthermore models of past ocean anoxia reconstruction have to consider that the seawater mo isotopic composition is not per se archived in euxinic sediments

yield stress history evaluated from paired in situ shear moduli of different modes abstract a special compiled database of shear moduli from different directional and polarization modes hh hv and vh waves at well documented geologic sites shows that stiffness ratio g 0 hh g 0 vh can be used to assess the yield stress ratio ysr in soils in general the reference profiles of ysr for these sites were determined using series of laboratory consolidation tests on undisturbed samples at varied elevations coupled with a good understanding of the engineering geology background of the formations for stress history assessment in soils various empirical correlations were derived from multiple regression analyses using the stiffness ratio and additional variables

pge re os and mo isotope systematics in archean and early proterozoic sedimentary systems as proxies for redox conditions of the early earth abstract re os data and pge concentrations as well as mo concentrations and isotope data are reported for suites of fine clastic sediments and black shales from the barberton greenstone belt south africa fig tree and moodies groups 3 25 3 15 ga the belingwe greenstone belt zimbabwe manjeri formation ca 2 7 ga and shales from the witwatersrand ventersdorp and transvaal supergroups south africa ranging from 2 95 to 2 2 ga moderately oxidizing conditions are required to mobilize re and mo in the environment mo fractionation only occurs in solution and these parameters thus have potential use as paleoredox proxies for the early earth pge re abundance patterns of barberton greenstone belt sediments are uniform and very similar in shape to those of komatiites this indicates 1 that the pge came from a source of predominantly ultramafic composition and 2 that pge were transported and deposited essentially in particulate form sediments from the younger belingwe greenstone belt show more fractionated pge re patterns and have re os ratios 10 to 100 higher than those of barberton sediments their pge abundance patterns and re os ratios are intermediate between those of the mid archean shales and neoproterozoic to recent black shales they reflect scavenging of re from solution in the sedimentary environment 98 95 mo values of black shales of all ages correlate with their concentrations the barberton greenstone belt samples have 1 3 ppm mo similar to a granitoid basaltic source this mo has 98 95 mo between 1 9 and 2 4 relative to present day mean ocean water molybdenum momo and is thus not isotopically fractionated relative to such a source similar to the pge this indicates transport in solid form sediments from the belingwe greenstone belt show in part enhanced mo concentrations up to 6 ppm and mo isotope fractionation 98 95 mo up to 1 4 relative to momo the combined pge re and mo data show mainly reducing conditions in the mid archean and suggest that by 2 7 ga the atmosphere and oceans had become more oxidizing substantially younger samples from the transvaal supergroup to ca 2 2 ga surprisingly have mainly low mo concentrations around 1 ppm and show no significant mo isotope fractionation relative to the continental source among possible explanations for this are a return to reducing atmospheric conditions after 2 7 ga reservoir effects or mo removal by sulfide precipitation following sulfate reduction in early proterozoic oceans

rhenium in the black sea comparison with molybdenum and uranium rhenium concentrations were measured in the black sea to determine the behavior of this redox sensitive element in an anoxic basin under reducing conditions re is removed from solution leading to its depletion from black sea deep waters compared with uranium water column re and mo profiles show evidence of removal from mid depths suggesting that these elements are scavenged either in the water column or slope sediments to a greater degree than u black sea surface waters are enriched in re reflecting re in rivers draining into the northern black sea that are enhanced up to 80 fold over other large world rivers this enrichment is most likely anthropogenic and may be due to coal burning in the region a simple two box model is used to demonstrate that re concentrations in the black sea are not in steady state with respect to current riverine inputs and authigenic fluxes riverine inputs of u and mo are not as significant perhaps reflecting the fractionation of re from the other elements during a high temperature combustion process re2o7 is volatile above 270 c

evidence for episodic oxygenation in a weakly redox buffered deep mid proterozoic ocean abstract over the last two decades popular opinion about prevailing conditions in the mid proterozoic deep ocean has evolved from fully oxygenated to globally euxinic sulfidic to a more heterogeneous stratified water column with localized pockets of euxinia existing in predominantly iron rich ferruginous deep waters the animikie basin in the lake superior region has been essential in shaping our view of marine redox evolution over this time period in this study we present a multi proxy paleoredox investigation of previously unanalyzed strata of the late paleoproterozoic animikie basin using drill cores through the 1 85 ga stambaugh formation paint river group in the iron river crystal falls district of the upper peninsula of michigan usa based on previous tectonic reconstructions and analysis of sedimentary regimes the iron river crystal falls section captures strata from among the deepest water facies of the animikie basin in contrast to previous work on sedimentary rocks in this basin we find evidence from iron speciation trace metal and mo isotope data for episodes of at least local deep water oxygenation within a basin otherwise dominated by ferruginous and euxinic conditions while trace metal enrichments and iron speciation data suggest predominantly anoxic conditions the occurrence of mn rich intervals up to 12 3 wt mno containing abundant mn fe carbonate and a wide range of mo isotope data with extremely negative values 98 95mo 1 0 to 1 1 record the shuttling of mn oxides from surface waters through oxic or suboxic waters to the sediment water interface we propose that such conditions are analogous to those of locally restricted modern and holocene basins in the baltic sea which receive episodic inflow of oxygenated water producing similar geochemical signatures to those observed for the animikie basin we argue that the mid proterozoic was characterized by a lack of a strong redox buffer low sulfide ferrous iron and oxygen contents and thus was vulnerable to dramatic and at least local redox shifts including briefly oxygenated bottom waters a refined view of the mid proterozoic ocean is emerging one that was still predominantly anoxic but marked by regional heterogeneities and short term redox variability that may in part reflect a transitional state between prevailingly anoxic archean and predominantly oxic phanerozoic oceans

large molybdenum isotope variations trace subsurface fluid migration along the dead sea transform large 0 6 to 2 3 97 95mo variations occur in molybdenum enriched iron oxide veins located in anticlines adjacent to the dead sea transform and are thought to reflect the solutions from which the veins formed because of efficient scavenging of mo by iron oxides the wide range of 97 95mo values occurs in a paleohydrologic setting in which dense concentrated evaporitic marine brines in the dead sea rift valley 97 95mo 1 6 penetrated and interacted with sedimentary rocks of the rift flanks which included cretaceous bituminous chalks 97 95mo 0 8 1 2 before intermixing with fe bearing groundwater containing molybdenum of igneous and clastic origin the 97 95mo values higher than seawater 1 6 2 3 are attributed to rayleigh isotopic fractionation along the path of the brine migration molybdenum isotopes thus reveal a powerful potential to trace the sources and processes governing subsurface metalliferous fluid migration

assessing the coefficient of the earth pressure at rest from shear wave velocity and electrical resistivity measurements abstract determination of earth pressure coefficient k 0 in natural soil deposits is a significantly important issue in geotechnical engineering this paper evaluates the feasibility of predicting k 0 values from measurements of vertical and horizontal shear wave velocities v s vh v s hh and v s hv and vertical and horizontal electrical resistivities s v s h a series of seismic piezocone tests scptu improved crosshole ch tests and soil resistivity tests using a modified laboratory apparatus were carried out at two research sites in jiangsu province of china and results were used to develop two existing k 0 shear wave velocity correlations for prediction of k 0 the seismic and electrical resistivity test results showed that both the shear wave velocity ratios v s hh v s hv or v s hv v s vh and the horizontal to vertical electrical resistivity ratio s h s v may provide a good indicator of the inherent soil anisotropy at these sites the existing v s k 0 prediction framework largely requires determining c s hv c s hh ratio and a simple procedure for evaluating this ratio based on the measured horizontal and vertical electrical resistivities the k 0 values predicted by shear wave velocity at both sites are also compared with values determined by jaky s formula and mayne kulhwy s formula in normally consolidated nc soils the k 0 values predicted from these methods showed good agreement however for over consolidated oc soils at shallow depths certain variations between different methods are noted further investigations of the effects of overconsolidation ratio on k 0 predictions will lead to the correction factors for better prediction of k 0 for oc soils this paper has confirmed that reasonable predictions of k 0 for natural soil deposits can be made using the proposed methodology

combining sedimentological trace metal mn mo and molecular evidence for reconstructing past water column redox conditions the example of meromictic lake cadagno swiss alps here we present sedimentological trace metal and molecular evidence for tracking bottom water redox state conditions during the past 12 500 years in nowadays sulfidic and meromictic lake cadagno switzerland a 10 5 m long sediment core from the lake covering the holocene period was investigated for concentration variations of the trace metals mn and mo xrf core scanning and icp ms measurements and for the presence of anoxygenic phototrophic sulfur bacteria carotenoid pigment analysis and 16s rdna real time pcr our trace metal analysis documents an oxic intermediate sulfidic redox transition period beginning shortly after the lake formation similar to 12 5 kyr ago the oxic period is characterized by low sedimentary mn and mo concentrations as well as by the absence of any remnants of anoxygenic phototrophic sulfur bacteria enhanced accumulation preservation of mn up to 5 6 wt in the sediments indicates an intermediate mn enriched oxygenation state with fluctuating redox conditions during a similar to 2300 year long transition interval between similar to 12 1 and 9 8 kyr bp we propose that the high mn concentrations are the result of enhanced mn2 leaching from the sediments during reducing conditions and subsequent rapid precipitation of mn oxyhydr oxide minerals during episodic and short term water column mixing events mainly due to flood induced underflows at 9800 130 cal yr bp a rapid transition to fully sulfidic conditions is indicated by the marked enrichment of mo in the sediments up to 490 ppm accompanied by an abrupt drop in mn concentrations and the increase of molecular biomarkers that indicate the presence of anoxygenic photosynthetic bacteria in the water column persistently high mo concentrations 80 ppm provide evidence that sulfidic conditions prevailed thereafter until modern times without any lasting hypolimnetic ventilation and reoxygenation hence lake cadagno with its persistently stable chemocline offers a framework to study in great temporal detail over similar to 12 kyr the development of phototrophic sulfur bacteria communities and redox processes in a sulfidic environment possibly depicting analogous conditions in an ancient ocean our study underscores the value of combining sedimentological geochemical and microbiological approaches to characterize paleo environmental and redox conditions in lacustrine and marine settings

evaluating the in situ lateral stress coefficient k0 of soils via paired shear wave velocity modes abstractthe utilization of shear wave velocities toward the evaluation of the in situ geostatic horizontal stress state in soils is validated specifically the lateral stress coefficient k0 field shear wave velocities from paired sets of different directional and polarization modes are compiled from 16 well documented test sites involving a variety of geomaterials focus is particularly placed on shear wave velocities measured by downhole tests vsvh crosshole tests vshv and special rotary type crosshole tests vshh at these sites field k0 stress states have been quantified using one or more direct assessment techniques including self boring pressuremeter total stress cells and hydrofracture in field testing as well as suction measurements special consolidometers and or triaxial arrangements on undisturbed samples in the laboratory although the specific delineation of stress induced versus inherent or fabric anisotropy may be difficult it is shown that the ratio of horizontally polarized