the occurrence of giant bivalve alatoconchidae from the yabeina zone upper guadalupian permian in european tethys abstract the permian gigantic bivalve family alatoconchidae forms a member of the tropical shallow marine fauna intimately associated with the tethyan warm water adapted verbeekinidae fusulines such as neoschwagerina and yabeina the velebit mountains in central croatia is one of the nine areas in the world that yielded alatoconchidae as first reported early in the 1970 s in addition to the neoschwagerina zone wordian middle guadalupian originally described we newly found alatoconchidae from the yabeina zone capitanian upper guadalupian from the brusane area in the central velebit mountains alatoconchidae occur in three stratigraphic levels of the velebit formation composed of black fusuline algal wackestone packstone with yabeina although fragmented the alatoconchidae shell reach sizes over 40 cm long and possess unique morphology with a lateral flange plus a prominent prismatic external layer in the double layered shell structure our results confirm for the first time in europe and thus in the western tethyan domain that the stratigraphic range of the gigantic bivalve family extends up to the capitanian as well as in the superocean panthalassa as no occurrence has been reported from the overlying lopingian upper permian alatoconchidae likely became extinct globally at the end of the guadalupian i e through the guadalupian lopingian boundary mass extinction

age and duration of the emeishan flood volcanism sw china geochemistry and shrimp zircon u pb dating of silicic ignimbrites post volcanic xuanwei formation and clay tuff at the chaotian section abstract the age and duration of the emeishan basalts sw china remain poorly constrained largely due to the severe thermo tectonic overprinting of the ar ar system and failure to obtain zircon separates from erupted basalts in an attempt to solve this problem geochemical analyses and shrimp zircon u pb dating have been carried out on rare felsic ignimbrite in the uppermost of the emeishan lava succession the xuanwei formation which immediately overlies the emeishan basalts and a clay tuff at the middle late permian boundary at the chaotian section clastic rocks of the lowermost xuanwei formation group 1 in eastern emeishan large igneous province lip have a geochemical affinity to the emeishan felsic volcanic rocks whereas the overlying sediments group 2 are compositionally more akin to mafic components of the emeishan traps this is the reverse of volcanic sequence of the central emeishan lip where the felsic extrusives sit above predominant mafic rocks it is likely that the clastic rocks are water transported sediments resulting from erosion of the volcanic rocks in the center of the emeishan lip this interpretation is further supported by the general agreement between the age of the lowermost xuanwei formation 257 4 ma 260 5 ma and that of the silicic ignimbrite 263 4 ma and the clay tuff at the middle late permian boundary at chaotian 260 5 ma these ages interpreted as the termination age of the emeishan volcanism are indistinguishable within error from the middle late permian boundary age 260 4 0 4 ma and the main stage 259 262 3 ma of the emeishan volcanism inferred from dating of mafic and alkaline intrusions in the emeishan lip all these suggest that the emplacement of the emeishan volcanism took place over a very short interval moreover the temporal link and geochemical analyses suggest that the chaotian clay at the middle late permian boundary was genetically related to the emeishan silicic volcanism this together with the fact at that both the emeishan basalts and the chaotian clay rest on the maokou formation leads us to infer that the emeishan basalt was emplaced at the middle late permian boundary in this sense the emeishan volcanism can be regarded as a boundary event and its age is presumed at 260 ma although more precise dating is required both stratigraphic correlation and chronologic data presented in this paper lend supports to the notion that the emeishan volcanism was one of likely causes of the end guadalupian mass extinction

u pb zircon geochronology and tempo of the end permian mass extinction the mass extinction at the end of the permian was the most profound in the history of life fundamental to understanding its cause is determining the tempo and duration of the extinction uranium lead zircon data from late permian and early triassic rocks from south china place the permian triassic boundary at 251 4 0 3 million years ago biostratigraphic controls from strata intercalated with ash beds below the boundary indicate that the changhsingian pulse of the end permian extinction corresponding to the disappearance of about 85 percent of marine species lasted less than 1 million years at meishan a negative excursion in 13 c at the boundary had a duration of 165 000 years or less suggesting a catastrophic addition of light carbon

the paleozoic minimum of 87sr 86sr ratio in the capitanian permian mid oceanic carbonates a critical turning point in the late paleozoic abstract the secular change in 87sr 86sr ratio of the paleozoic recorded the lowest value below 0 7070 in late middle permian i e the permian minimum suggesting that a major reform in oceanography occurred before the paleozoic mesozoic transition we have detected the correlative lowest 87sr 86sr value 0 706914 0 000012 from the middle upper permian paleo atoll limestone in japan formed primarily on an ancient seamount in mid panthalassa the stratigraphic horizon of the minimum was constrained to the capitanian interval 265 8 260 4 ma middle permian by fusulines as the mid oceanic data represent the global average the present study confirmed the chemostratigraphical utility of the capitanian minimum of 87sr 86sr ratio in global correlation after the long term nearly 280 million years decrease throughout the paleozoic since the cambrian a remarkable turnover of seawater 87sr 86sr values appeared in the capitanian immediately before the guadalupian lopingian middle late permian boundary a major global change likely appeared in the capitanian to change the sr isotope balance in seawater from a mantle flux dominated to a continental flux dominated regime the initial rifting of pangea probably started in the capitanian and the rifting induced new connection of many intra supercontinental drainage systems to the superocean may have caused the overturn in global sr isotopic trend

anisotropic shear wave velocity structure of the earth s mantle a global model 1 we combine a new large data set of surface wave phase anomalies long period waveforms and body wave travel times to construct a three dimensional model of the anisotropic shear wave velocity in the earth s mantle our modeling approach is improved and more comprehensive compared to our earlier studies and involves the development and implementation of a new spherically symmetric reference model simultaneous inversion for velocity and anisotropy as well as discontinuity topographies and implementation of nonlinear crustal corrections for waveforms a comparison of our new three dimensional model s362ani with two other models derived from comparable data sets but using different techniques reveals persistent features 1 strong 200 km thick high velocity anomalies beneath cratons likely representing the continental lithosphere underlain by weaker fast anomalies extending below 250 km which may represent continental roots 2 weak velocity heterogeneity between 250 and 400 km depths 3 fast anomalies extending horizontally up to 2000 3000 km in the mantle transition zone beneath subduction zones 4 lack of strong long wavelength heterogeneity below 650 km suggesting inhibiting character of the upper mantle lower mantle boundary and 5 slow velocity superplumes beneath the pacific and africa the shear wave radial anisotropy is strongest at 120 km depth in particular beneath the central pacific lateral anisotropic variations appreciably improve the fit to data that are predominantly sensitive to the uppermost and lowermost mantle but not to the waveforms that control the transition zone and midmantle depths tradeoffs between lateral variations in velocity and anisotropy are negligible in the uppermost mantle but noticeable at the bottom of the mantle

the carbon isotope excursion on gssp candidate section of lopingian guadalupian boundary an isotopic stratigraphically well documented outcrop in penglaitan guangxi province south china has been proposed as a candidate gssp for the lopingian guadalupian boundary correlatable outcrops from the west wing tieqiao section and east wing penglaitan section of the laibin syncline exhibit synchronous excursions in carbon isotopes the isotopic excursions 13c show the best placement of the boundary may lie at the base of bed 6k which coincides with the clarkina postbitteri conodont zone and with eustatic change 13c increases during the uppermost guadalupian jinogondolella granti conodont zone from the top of 3c to the base of 6i a 13c peak value of 5 is located at the transition between these two conodont zones and is suggested as a proxy for the transition from transgression to regression a gradual depletion of carbon isotopes occurs in the c postbitteri zone from bed 6e to 7b and this gradual 13c excursion also suggests the sequences around the guadalupian lopingian boundary at the candidate section are conformable during the middle later c postbitteri zone a 3 5 dramatic 13c depletion is recorded at the tieqiao section but only a 2 depletion at the deeper facies penglaitan section synchronous with conodont zones that mark eustatic changes

a speculation on the structure of the d layer the growth of anti crust at the core mantle boundary through the subduction history of the earth abstract the growth curve of the continental crust shows that large amounts of continental crust formed in the early part of the earth history are missing in order to test a hypothesis that the former crust was subducted to the deep mantle we performed phase assemblage analysis in the systems of mid oceanic ridge basalt morb anorthosite and tonalite trondhjemite granite ttg down to the core mantle boundary cmb conditions results show that all these materials can be subducted to the cmb leading to the development of a compositional layering in the d layer we speculate that there could be five layers of feo enriched melt from partial melting of morb morb crust anorthosite ttg and slab or mantle peridotite in ascending order although the polymorphic transformation of perovskite to post perovskite in mg fe sio3 may explain the seismic discontinuity at the top of the d layer d discontinuity the effects of solid solution on the sharpness of the transformation suggest that the compositional layering is more plausible for the origin of the d discontinuity the d layer can be an anti crust made up mostly of ttg anorthosite derived from the former continental crust tectonic style of the anti crust at the cmb is similar to that at the surface at both places chemically distinct layers are density stratified and are also characterized by the processes of accretion magmatism and metasomatism

illawarra reversal the fingerprint of a superplume that triggered pangean breakup and the end guadalupian permian mass extinction abstract the permian magnetostratigraphic record demonstrates that a remarkable change in geomagnetism occurred in the late guadalupian middle permian ca 265 ma from the long term stable kiaman reverse superchron throughout the late carboniferous and early middle permian to the permian triassic mixed superchron with frequent polarity changes in the late permian and triassic this unique episode called the illawarra reversal probably reflects a significant change in the geodynamo in the outer core of the planet after a 50 million years of stable geomagnetism the illawarra reversal was likely led by the appearance of a thermal instability at the 2900 km deep core mantle boundary in connection with mantle superplume activity the illawarra reversal and the guadalupian lopingian boundary event record the significant transition processes from the paleozoic to mesozoic modern world one of the major global environmental changes in the phanerozoic occurred almost simultaneously in the latest guadalupian as recorded in 1 mass extinction 2 ocean redox change 3 sharp isotopic excursions c and sr 4 sea level drop and 5 plume related volcanism in addition to the claimed possible links between the above listed environmental changes and mantle superplume activity i propose here an extra explanation that a change in the core s geodynamo may have played an important role in determining the course of the earth s surface climate and biotic extinction evolution when a superplume is launched from the core mantle boundary the resultant thermal instability makes the geodynamo s dipole of the outer core unstable and lowers the geomagnetic intensity being modulated by the geo and heliomagnetism the galactic cosmic ray flux into the earth s atmosphere changes with time the more cosmic rays penetrate through the atmosphere the more clouds develop to increase the albedo thus enhancing cooling of the earth s surface the illawarra reversal the kamura cooling event and other unique geologic phenomena in the late guadalupian are all concordantly explained as consequences of the superplume activity that initially triggered the breakup of pangea the secular change in cosmic radiation may explain not only the extinction related global climatic changes in the end guadalupian but also the long term global warming cooling trend in earth s history in terms of cloud coverage over the planet

bryozoan paleoecology indicates mid phanerozoic extinctions were the product of long term environmental stress we compiled the global onshore offshore distribution of marine bryozoans within 396 permian early jurassic bryozoan assemblages and show that bryozoan assemblage generic richness declined significantly in advance of the end permian and end triassic mass extinctions starting as early as the capitanian prior to the end permian and the norian prior to the end triassic we also show that offshore settings were affected first prior to both extinctions suggesting that environmental stress resulted from the gradual encroachment of some deep water phenomenon onto the shelves these patterns support long term oceanographic rather than extraterrestrial extinction mechanisms such as widespread euxinia triggered by massive volcanism and global warming tracking the onshore offshore environmental distribution of these marine invertebrates provides a unique approach to assessing prolonged environmentally induced stress through this 120 m y time interval

mass extinctions and sea level changes abstract review of sea level changes during the big five mass extinctions and several lesser extinction events reveals that the majority coincide with large eustatic inflexions the degree of certainty with which these eustatic oscillations are known varies considerably thus the late ordovician and end cretaceous extinctions are associated with unequivocal major regressions demonstrated from numerous widespread regions in contrast the multiple high frequency sea level changes reported for the frasnian famennian crisis based on the supposed depth preferences of conodont taxa have little support from sequence stratigraphic analyses which reveals the interval to be one of highstand the end permian mass extinction has long been related to a severe first order lowstand of sea level newell n d 1967 revolutions in the history of life geol soc am spec pap 89 63 91 based primarily on the widespread absence of latest permian ammonoid markers but field evidence reveals that the interval coincides with a major transgression newell s hypothesis that marine extinctions are related to shelf habitat loss during severe regression remains tenable for the end guadalupian and end triassic extinction events but not for other crises rapid high amplitude regressive transgressive couplets are the most frequently observed eustatic changes at times of mass extinction with the majority of extinctions occurring during the transgressive pulse when anoxic bottom waters often became extensive the ultimate cause of the sea level changes is generally unclear a glacioeustatic driving mechanism can only be convincingly demonstrated for the end ordovician and end devonian events at other times it is speculated that they may relate to the widespread regional doming and subsequent collapse caused by the impingement of superplumes and ultimate eruption on the base of the lithosphere

geochemistry of late permian to early triassic pelagic cherts from southwest japan implications for an oceanic redox change major trace and rare earth element abundances were determined for the southwestern japanese pelagic chert sequence from the early late permian to early early triassic to investigate a redox change in deep sea pelagic environments before and at the permo triassic boundary ptb 251 ma the sequence was primarily deposited in the deep sea of the superocean panthalassa and then was accreted to japan in the middle jurassic a remarkable lithostratigraphic change from red chert to siliceous carbonaceous claystone through gray chert is observed in this sequence constituent elements for these sedimentary rocks are essentially derived from two sources 1 an ancient seawater via biogenic mainly radiolarian hydrothermal and authigenic materials and 2 an average shale like terrigenous material the present measurement demonstrates significant stratigraphic changes of the ce cenon ter value estimated ce anomaly value of non terrigenous component recalculated by subtraction of terrigenous rees from bulk rees and the mn te sample mn te paas value excess mn component other than terrigenous one te terrigenous elements including ti al nb hf th paas post archean average australian shale in the permian chert the ce cenon ter values increase from 0 2 to 1 and the mn te sample mn te paas values decrease up section suggesting that the redox condition of deep sea open ocean changed from oxic to suboxic in an interval of approximately 10 myr the fe te sample fe te paas and mn te sample mn te paas values of carbonaceous claystone near or at the ptb are less than unity suggesting that reductive dissolution of iron and manganese occurred under an anoxic condition this supports the idea of the ptb oceanic anoxia in the superocean panthalassa the present data suggest that the anoxic condition prevailed in the deep sea pelagic regions for an extremely long period much more than 10 myr from the middle late permian to early early triassic this long term development of widespread oceanic anoxia may have been linked to the greatest mass extinction of the phanerozoic

δ18o and δ13c of permian brachiopods a record of seawater evolution and continental glaciation abstract two hundred sixty four 18 o and 13 c values of permian articulate brachiopod shells were analyzed and 81 of these values were characterized as well preserved and biostratigraphically well defined these were then utilized for construction of baseline oxygen and carbon isotope curves for the permian interval in addition 21 13 c whole rock values are reported for the wordian and capitanian the early permian asselian to artinskian times are characterized by 2 5 decrease in oxygen isotope values from 0 7 to 3 3 v pdb this is attributed to a 4 7 c increase in temperature in the southern urals concomitant with the retreat of the permo carboniferous ice sheets and return of the 18 o depleted melt water into the oceans the late permian samples from iran jolfa at kuh e ali bashi and china meishan yield 18 o values and presumably temperatures similar to those that followed the termination of the large scale glaciation in the lower permian in between the upper kungurian to capitanian samples from the delaware basin guadalupe mountains are enriched in 18 o at 1 5 to 3 we have no definitive explanation for these data but tentatively suggest that the anomaly can potentially be a result of evaporative enrichment of seawater in 18 o due to intracratonic arid setting of the basin the 18 o enriched nature of the zechstein samples 1 2 to 2 5 on the other hand is in all probability a reflection of the high evaporation rates in the zechstein sea the permian interval is characterized by a relatively constant 13 c at about 4 the exceptions are again the brachiopods from the delaware basin guadalupe mountains which show 1 6 increase in the guadalupian to values of up to 5 9 in the wordian a tentative explanation as in the case of oxygen is based on the proposition that the semi enclosed delaware basin was likely stratified with sequestration of the 13 c depleted carbon to the deeper water layers and a complementary 13 c enrichment in the upper oxygenated layer the coeval open ocean water dic may have been similar to that of the remainder of the permian interval at 4 as indicated by whole rock carbonate samples from oman sicily and iran in the latest permian the trend mimics the well known 13 c drop at the permian triassic boundary

biological overprint of the geological carbon cycle the oxidation of earth s atmosphere is coupled to the net sequestration of organic matter which is related to the relative fractions of organic carbon forg and carbonate fcarb buried in marine sediments these fractions can be inferred from carbon isotope data we present bulk sediment d 13 c records of carbonate d 13 ccarb and organic carbon d 13 corg with a compilation of evolutionary trajectories of major eucaryotic phytoplankton for the past 205 million years our analysis indicates that changes in phytoplankton community structure coupled with the opening of the atlantic ocean basin and global sea level rise increased the efficiency of organic carbon burial beginning in the early jurassic in turn this organic carbon burial increased the oxidation state of earth s surface while drawing down atmospheric co2 levels assuming no substantial negative feedbacks the net oxidation and co2 drawdown appear to be related to the opening phase of the current wilson cycle where the newly formed passive plate margins store organic matter for hundreds of millions of years this process should reverse during the closing phase of the wilson cycle when the continents reassemble and the atlantic ocean basin closes the associated oxidation and storage of organic matter have contributed to the long term depletion of co2 which was a key factor that selected c4 photosynthetic pathways in marine and terrestrial ecosystems in the latter part of the cenozoic these pathways increasingly influenced d 13 corg and ultimately contributed to the reversal of the long term trend in d 13 ccarb

87sr 86sr record of permian seawater abstract a population of 169 permian articulate brachiopod shells was analysed for their 87 sr 86 sr ratios 51 of these characterised as well preserved and stratigraphically well defined are utilized for delineation of the permian seawater strontium isotope trend the 87 sr 86 sr curve shows values of about 0 7080 in the lowermost permian asselian followed by a gradual decline to 0 70685 in the capitanian and a minor rise in the dzhulfian and lower dorashamian to values of 0 70715 just below the permian triassic boundary the early permian decrease in the strontium isotope curve that commences in the early sakmarian is coincident with the advancing deglaciation of the gondwana and with the increased aridity in large parts of the pangaea these factors may have led to a reduced continental weathering of rb rich silicate rocks and thus to the decline in seawater 87 sr 86 sr starting with the artinskian the opening of the neotethys and the associated widespread basaltic volcanism supplied low radiogenic strontium to seawater from an enhanced hydrothermal flux in the capitanian basaltic volcanism in the entire palaeotethys ceased and this may have been the reason for a slightly more radiogenic seawater isotopic composition during the lopingian higher input of riverine sr due to expansion of humid areas may have been a contributory factor

a negative carbon isotope anomaly associated with the earliest lopingian late permian mass extinction abstract palaeozoic life was severely affected in a pair of mass extinction events at the beginning earliest lopingian 260 million years ago and the end 251 million years ago of the late permian however the biological and geochemical record of the earliest lopingian crisis remains poorly constrained we present analyses of strata in south china showing that a negative anomaly of stable carbon isotope ratios accompanied an abrupt extinction of marine faunas at the beginning of the late permian similar to patterns observed at the end permian and the end cretaceous 65 million years ago extinction events

geochemistry and petrogenesis of the permian mafic dykes in the panxi region sw china abstract numerous intrusive bodies of ultramafic mafic to felsic compositions are exposed in association with volcanic rocks in the emeishan large igneous province lip southwestern china in this paper we present new elemental and isotopic data for the permian mafic dykes from the panxi region which is located in the western part of the emeishan lip the characteristics of major and trace elements and sr nd isotopes in combination with isotopic ages suggest that these mafic dykes were originated from a similar mantle source related to an upwelling mantle plume and their formation was involved in a process of variable degrees of fractional crystallisation coupled with assimilation of enriched crustal materials the mafic dyke samples from the panxi region show some systematic variations in geochemical compositions the gabbros in yanyuan contain the lowest ree e g la 5 12 ppm the highest mgo 8 38 21 33 and compatible elements e g cr 104 2610 ppm ni 135 496 ppm and display depleted sr nd isotopic ratios initial 87sr 86sr 0 703752 0 703844 end t 4 87 to 5 13 these gabbros likely represent an undifferentiated composition similar to primary melts derived from a depleted mantle source in contrast the gabbro samples from panzhihua and huili have more enriched lree abundances and incompatible elements and display depleted to slightly enriched sr and nd isotopic signatures initial 87sr 86sr 0 704354 0 705436 end t 0 29 to 4 58 though their trace element spidergram patterns are similar to those of the yanyuan samples these gabbros were formed probably through the removal of a few percent of olivine clinopyroxene plagioclase and apatite from the melts that formed the yanyuan gabbros all the mafic intrusives in the region exhibit elemental and sr nd isotopic features generally comparable with those of the nearby volcanic rocks in addition their emplacement immediately preceded or was synchronous with the main pulse of volcanism that formed lavas over a large area along the western margin of the yangtze craton these lines of evidence suggest that there is a genetic link between the mafic dykes and flood basalts in the emeishan lip and the both share a common mantle source related to the emeishan plume

the oslo rift a review the tectonomagmatic history of the oslo rift may be subdivided into 5 main periods stage 1 300 ma development of a shallow depression stage 2 300 295 ma roughly simultaneous onset of widespread basalt volcanism b1 and vertical movement along nnw sse to n s trending faults stage 3 295 275 ma main rifting period accompanied by volcanism dominated by rhomb porphyry lavas latites stage 4 275 240 ma change of magmatic style from basaltic shield volcanism to central volcanoes of mixed compositions many of which went through caldera collapses intrusion of composite batholiths of intermediate to granitic compositions stage 5 240 ma dike intrusions may have continued into triassic time both the crust and total lithosphere under the rift are thinned relative to the precambrian basement on both sides a 12 km thick high density and high velocity body occupies the lower crust along the rift axis and extends under the eastern and western rift shoulder petrological and geochemical data imply that this massive layer represents dense cumulates and gabbroic rocks formed from mantle derived magmas in deep crustal magma chambers two mantle sources one nearly undepleted age corrected nd of about 1 and sr of 10 to 15 the other mildly depleted nd of about 4 sr of 10 contributed melts to the oslo rift magmatism the two sources are interpreted as different parts of a heterogeneous upper mantle which before the rifting event belonged to the subcontinental lithosphere on their way to the surface the mantle derived magmas were retained in deep crustal magma chambers where they underwent extensive fractional crystallization some also suffered moderate contamination anatectic melts and melts formed by mixing between mantle derived and anatectic melts gave rise to syenitic and granitic intrusions

end guadalupian extinction of the permian gigantic bivalve alatoconchidae end of gigantism in tropical seas by cooling abstract the unique permian bivalve family alatoconchidae has aberrant shell forms and extraordinary size up to 1 m representing the largest bivalve group in the paleozoic their occurrence is reported sporadically from lower middle permian shallow marine carbonates in 9 areas in the world tunisia croatia oman iran afghanistan thailand malaysia the philippines and japan that cover low latitudes of both the tethyan and panthalassan domains alatoconchids almost always occurred in close association with large tested fusulines verbeekinidae and or rugose corals waagenophyllidae of the typical tethyan assemblage suggesting their preferential adaptation to shallow warm water tropical environments this tropical trio alatoconchidae verbeekinidae and waagenophyllidae became extinct either during the late guadalupian or around the guadalupian lopingian boundary g lb their intimate association and occurrence range suggest that these 3 taxonomically distinct clades may have shared not only a common habit but also a common cause of extinction the shell structure of alatoconchids suggests their symbiosis with photosynthetic organisms algae cyanobacteria in order to maintain their large body size that required high energy consuming metabolism in contrast to smaller forms the alatoconchidae attained their largest size in the wordian middle guadalupian probably maximizing the benefits of photosymbiosis the subsequent extinction of the warm water adapted tropical trio both in tethys and panthalassa positively supports the explanation that a critical cooling took place on a global scale including low latitude oceans the end of the gigantism in fusulines and bivalves in the capitanian late guadalupian was likely caused by the collapse of photosymbiotic systems during a temporary temperature drop of seawater kamura cooling event coupled with eutrophication that was detrimental to the tropical fauna adapted particularly to oligotrophic conditions gigantism of bivalves occurred several times in the phanerozoic e g siluro devonian permian triassic early jurassic and jurassic creataceous mostly in warm periods the sea level change in the phanerozoic apparently synchronized with the intermittent rise and decline of bivalve gigantism suggesting that the photosymbiosis related gigantism in low latitudes may serve as a potential monitor of global warming cooling in the past

anoxia as a cause of the permian triassic mass extinction facies evidence from northern italy and the western united states facies faunal and geochemical evidence from the permian triassic boundary sediments of the dolomites and idaho indicates a major anoxic event in the earliest triassic in both regions the basal beds consist of finely laminated micrites with common syngenetic pyrite the only fauna consists of occasional bedding plane assemblages of lingula or clacaria a typical lower dysaerobic assemblage this is a level where previous studies have shown a major negative carbon isotope excursion and a cerium anomaly in the dolomites the pyritic micrite directly overlies strata containing a diverse and typically permian marine fauna of algae foraminifers including fusulinids and articulate brachiopods implying an abrupt extinction in contradiction to many previous views sequence stratigraphic analysis of the dolomite boundary sediments reveals a minor sequence boundary in the late permian followed by extremely rapid transgression leading to the development of the relatively deep water pyritic micrite a maximum flooding surface at the permo triassic boundary a further pulsed deepening in the lower griesbachian recorded in both the dolomites and idaho lead to the widespread establishment of dysaerobic facies it is clear that most of the extinctions occurred at the erathem boundary although the subsequent failure of the marine benthos to fill the empty ecospace in the ensuing griesbachian may have been due to the widespread development of dysaerobic conditions

a chronology of paleozoic sea level changes sea levels have been determined for most of the paleozoic era 542 to 251 million years ago but an integrated history of sea levels has remained unrealized we reconstructed a history of sea level fluctuations for the entire paleozoic by using stratigraphic sections from pericratonic and cratonic basins evaluation of the timing and amplitude of individual sea level events reveals that the magnitude of change is the most problematic to estimate accurately the long term sea level shows a gradual rise through the cambrian reaching a zenith in the late ordovician then a short lived but prominent withdrawal in response to hirnantian glaciation subsequent but decreasingly substantial eustatic highs occurred in the mid silurian near the middle late devonian boundary and in the latest carboniferous eustatic lows are recorded in the early devonian near the mississippian pennsylvanian boundary and in the late permian one hundred and seventy two eustatic events are documented for the paleozoic varying in magnitude from a few tens of meters to 125 meters

late permian to early triassic magnetostratigraphy a late permian to early triassic magnetostratigraphic reference section is presented the lower triassic part is based on results from marine limestone sections in south china published earlier 1 2 reliable new permian data are added here which have been collected in the nammal gorge salt range northwest pakistan where marine sediments have been deposited quasi continuously with occasional minor hiatuses during the late palaeozoic to early mesozoic about 50 of the permian samples from the nammal section contain hidden beneath a strong recent or tertiary overprint a characteristic remanent magnetization chrm which is very likely of permian age this component which was imprinted on the southern hemisphere has normal as well as reversed polarity with a normal mean direction decl 289 3 incl 50 3 95 4 3 n 113 which is in close agreement with the palaeofield direction expected for a site belonging to the indian plate as part of gondwanaland during the permian in the lower upper permian several normal polarity zones are recognized this contradicts the current assumption that rocks of this age belong to the long reversely polarized kiaman hyperzone the kiaman interval must end and the illawarra hyperzone of mixed polarity must begin in or prior to the lowermost upper permian the permian triassic boundary at nammal as well as in the chinese sections is situated very close to a transition from a reversed to a normal polarity zone the upper permian at nammal together with the lower triassic south china sections is estimated to cover about 20 ma nearly 30 polarity changes are observed which result in an average reversal frequency very similar to that observed during the early tertiary the reversal rate after the end of the long lasting reversed kiaman hyperchron apparently increases in a manner similar to that after the end of the cretaceous long normal superchron only a few polarity zones are found in the lower upper permian while progressively more frequent reversals follow in the lower triassic

carbon isotopic evidence for chemocline upward excursions during the end permian event abstract a negative shift in marine inorganic carbon isotope composition 13 c carb during the end permian mass extinction has been used as evidence for several different extinction mechanisms changes to the 13 c of organic matter and the difference between it and 13 c carb 13 c 13 c carb 13 c org have been examined at few locations with conflicting interpretations we examine the changes to both organic and inorganic carbon isotopes across the permian triassic boundary at two marine sections from south china meishan and shangsi and compare these to data from other previously published sections through these analyses we demonstrate that a decrease in 13 c occurred during the extinction event throughout the paleo tethys ocean the extent and intensity of the decrease varies by location averaging a negative shift of 5 several possibilities as to the cause of this shift exist including siberian trap volcanism a change in the terrestrial marine organic carbon input to the system or a change in the dominant marine biota brought about through environmental changes such as widespread ocean anoxia euxinia the decrease in 13 c observed at many of these sections across the event horizon is here interpreted to represent a shift from algae cyanobacteria to less fractionating phototrophic sulfur bacteria in marine shelf environments resulting from upward excursions of the chemocline these chemocline upward excursions would release euxinic water to the photic zone allowing phototrophic sulfur bacteria to thrive the limited available biomarker data are consistent with this interpretation

growth and demise of permian biogenic chert along northwest pangea evidence for end permian collapse of thermohaline circulation abstract the permian chert event pce was a 30 ma long episode of unusual chert accumulation along the northwest margin of pangea and possibly worldwide the onset of the pce occurred at about the sakmarian artinskian boundary in the sverdrup basin canadian arctic where it coincides with a maximum flooding event the ending of high frequency high amplitude shelf cyclicity the onset of massive biogenic chert deposition in deep water distal areas and a long term shift from warm to cool water carbonate sedimentation in shallow water proximal areas a similar and coeval shift is observed from the barents sea to the northwestern usa a landward and southward expansion of silica factories occurred during the middle and late permian at which time warm water carbonate producers disappeared completely from the northwest margin of pangea biotically impoverished and increasingly narrow cold water carbonate factories characterised by non cemented bioclasts of sponges bryozoans echinoderms and brachiopods were then progressively replaced by silica factories by late permian time little carbonate sediments accumulated in the barents sea and in the sverdrup basin where the deep to shallow water sedimentary spectrum was occupied by siliceous sponge spicules by that time biogenic silica sedimentation was common throughout the world silica factories collapsed in the late permian abruptly bringing the pce to an end in northwest pangea the end permian collapse of the pce was associated with a major transgression and with a return to much warmer oceanic and continental climatic conditions chert deposition resumed in the distal oceanic areas during the early middle triassic anisian after a 8 10 ma interruption early triassic chert gap the conditions necessary for the onset expansion and zenith of the pce were provided by the thermohaline circulation of nutrient rich cold waters along the northwestern and western margin of pangea and possibly throughout the world oceans these conditions provided an efficient transportation mechanism that constantly replenished the supply of silica in the area created a nutrient and oxygen rich environment favouring siliceous biogenic productivity established cold sea floor conditions hindering silica dissolution while increasing calcium carbonate solubility and provided conditions adverse to organic and inorganic carbonate production the northwest margin of pangea was for nearly 30 ma bathed by cold waters presumably derived from the seasonal melting of northern sea ice the assumed engine for thermohaline circulation this process started near the sakmarian artinskian boundary intensified throughout middle and late permian time and ceased suddenly in latest permian time it led to oceanic conditions much colder than normally expected from the palaeolatitudes and the influence of cold northerly derived water was felt as far south southern nevada the demise of silica factories was caused by the rapid breakdown of these conditions and the establishment of a much warmer marine environment accompanied by sluggish circulation and perhaps a reduced input of dissolved silica to the ocean complete thawing of northern sea ice would have ended thermohaline circulation and led to warm and sluggish oceanic conditions inimical to the production accumulation and preservation of biogenic silica

a unique geochemical record at the permian triassic boundary a 330 metre core drilled through the marine permian triassic boundary in the carnic alps of austria allows closely correlated studies of geochemistry petrography and palaeontology across the boundary the isotope shifts and metal concentrations are extended multiple and complex and do not resemble those seen at the cretaceous tertiary boundary both the carbon isotope shifts and the chemical events including an indium anomaly may have causes related to a major regression of the sea

some aspects of the permian triassic boundary ptb and of the possible causes for the biotic crisis around this boundary abstract the first appearance datum fad of hindeodus parvus is an excellent datum very close to the base of the otoceras woodwardi zone priority base of the triassic for the first time it allows an exact correlation of the ptb in all marine facies and faunal realms the following features of the extinction and recovery patterns near the ptb are most important for the search for causes of the ptb biotic crisis 1 most strongly affected were the siliceous plankton radiolarians and the warm water benthos and nekton 2 most of the cold water faunas were not significantly affected 3 the recovery of the warm water benthos and siliceous plankton occurred only after an unusually long time during the late olenekian and middle triassic 4 the productivity of the terrestrial plants dropped strongly and the recovery was mainly in the upper olenekian and in the middle triassic 5 several terrestrial extinction events occurred at different levels within the upper permian considerable before the marine ptb at or close to the fad of lystrosaurus no extinction event in the terrestrial faunas can be observed 6 terrestrial faunal elements that survived the dzhulfian dorashamian extinctions were able to survive some months of extreme climatic conditions by hibernation like life stages vertebrates or by dry and freezing resistant eggs conchostracans 7 about 50 of the genera that disappeared at the ptb re appeared in the olenekian middle triassic interval lazarus taxa or in this time interval genera appeared that had undoubtedly evolved from genera that had disappeared at the ptb and 8 the ptb is preceded by mass occurrences of marine and continental fungi and the fungal spike ends abruptly a little before the ptb a scenario for the ptb biotic crisis is elaborated that takes into consideration the real not interpolated diversity patterns of different marine and continental fossil groups the exact correlation of bioevents in different faunal realms and facies the strong biotic crisis in the tethyan warm water faunas in contrast to the much weaker biotic event in cold water faunas the severe dzhulfian dorashamian climate in many parts of the world caused by the continent ocean configuration and by siberian trap volcanism the cooling of the boreal area by the northward drift of pangaea that interrupted the exchange of warm water benthos between the tethys and western north america during the guadalupian the extinction event at the guadalupian lopingian boundary that restricted most of the affected warm water faunas to the tethys the importance of lower scythian anoxia that reached an unusually shallow level and above all the effects of the contemporaneous huge volcanic events about 250 m y ago on the siberian platform and in the eastern tethys that caused a 3 6 months lasting volcanic winter with strong cooling in low latitudes followed by a strong global warming

tracing biogeochemical processes in stream water and groundwater using non linear statistics summary stream water and groundwater solute concentration are subject to a multitude of biogeochemical processes that act at different scales and are often characterized by non linear relationships and feedback loops different multivariate statistical methods were applied to investigate the interplay of different processes the data set from the lehstenbach catchment in south germany comprised 2641 stream water and groundwater samples from 38 different sites in the catchment where 13 different solutes had been determined according to the correlation dimension analysis the number of dominant processes was four the first four components determined via principal component analysis comprised 88 of the total variance whereas the non linear isometric feature mapping explained 92 with the first four components these components were ascribed to prevailing biogeochemical processes and were used to investigate spatial and temporal patterns redox processes and contamination by road salt explained 35 of the variance each another 13 were ascribed to near surface runoff in the acidified topsoil and 9 to the impact of contaminated filter gravel in some of the groundwater wells the redox component exhibited clear seasonal patterns at most stream water and groundwater sampling sites with the most reduced conditions in late summer immediately before the onset of re wetting there was clear evidence that redox processes especially denitrification play an important role even in the oxic aquifer during discharge peaks stream water exhibited higher values of the near surface runoff component however the associated lower values of the redox component pointed to near surface runoff in the riparian wetlands as the predominating runoff generation process rather than to a contribution of upslope soil water a series of major rain storms in fall 1998 altered groundwater and stream water solute concentration for months stream water and groundwater became more oxic and more acidified and showed a higher impact of road salt contamination at some sites overall the spatial and temporal patterns of the predominating components gave a consistent picture and helped considerably to better understand the interplay between biogeochemical and hydrological processes the chosen approach is a promising tool for investigating apparently complex hydrological and biogeochemical systems

emeishan basalts sw china and the end guadalupian crisis magnetobiostratigraphic constraints abstract a magnetostratigraphic investigation of the permian emeishan lip large igneous province was carried out on a composite section in ebian county close to the type area in sichuan sw china the main succession of twelve flows 175 m thick carries a normal polarity whilst the one reliable site from the overlying 30 m thick volcanic waning sequence is marked by a reverse polarity the data enable a correlation to be proposed with an emeishan basalt sequence in western guizhou c 400 km to the se from our knowledge of the geomagnetic field9s reversal behaviour during the permian it suggests that the main lava pile along the eastern half of the emeishan basalt outcrop belt was erupted within a half to one million years using magnetobiostratigraphic data from the adjacent south china platform the normal polarity magnetozone is correlated with the normal polarity chron associated with the upper part of the maokou limestones constrained by conodont data the main emei basalts appear to be at least two biozones older 1 1 5 ma than the mid late permian boundary it is possible however that the emei basalt waning zone sequence which represents an explosive volcanic phase might be coeval with the end guadalupian biotic crisis thus arguments implicating emei basalt volcanism as the causal mechanism behind this major global event have to accommodate the new relative age constraints

fusuline biotic turnover across the guadalupian lopingian middle upper permian boundary in mid oceanic carbonate buildups biostratigraphy of accreted limestone in japan abstract two sections in upper middle to lower upper permian shallow water limestones at kamura and akasaka in southwest japan were analyzed for detailed lithostratigraphy and biostratigraphy both sections represent ancient seamount capping carbonate buildups developed on a basaltic basement in a mid oceanic environment the occurrence of abundant tethyan fusulines allows the recognition of well defined biostratigraphic zonation in both sections and their mutual correlation the upper guadalupian middle permian lepidolina yabeina zone is overlain conformably by the lower lopingian upper permian codonofusiella reichelina zone with a 13 m thick transitional interval barren of index taxa the guadalupian lopingian g l boundary is marked by the first appearance datum fad of the lopingian codonofusiella reichelina assemblage in both sections this study recognizes for the first time the g l boundary horizon in a mid oceanic shallow water environment in addition the shallow water carbonates in the study sections record the extinction of the middle permian large sized fusuline family verbeekinidae at the g l boundary in mid panthalassa as well as in shallow water tethyan shelf areas demonstrating positively that the g l boundary mass extinction occurred on a global scale the abrupt elimination of large shelled fusulines followed by the domination of small shelled fusulines may indicate that environmental stress occurred at the end of guadalupian the dying out of symbiotic algae may have caused the selective extinction of the large shelled fusulines

permian carboniferous and permian triassic magmatism in the rift zone bordering the tethyan margin of southern pangea magma was emplaced in the india australia rift zone along the tethyan margin during permian carboniferous and permian triassic time permian carboniferous alkalic granite and basaltic and rhyolitic lava flows and tuffs formed at the same time as right lateral transtension of pangea as recorded by the magmatic rocks of neocratonic post variscan europe and post kanimblan eastern australia permian triassic tholeiitic basalt in india alkalic magmatic rocks in oman and rhyolite dolerite and undersaturated alkalic volcanic rocks in western australia preceded and accompanied the early opening of the neo tethys ocean coeval magmatism included the voluminous mid plate siberian traps the emeishan basalt of south china and the peak activity of the magmatic arc along the convergent panthalassan margin the background magmatism probably permitted the siberian traps to trigger the environmental catastrophe at the permian triassic boundary

reply to comment by ali j r and wignall p on ota a and isozaki y 2006 fusuline biotic turnover across the guadalupian lopingian middle upper permian boundary in mid oceanic carbonate buildups biostratigraphy of accreted limestone japan journal of asian earth sciences 26 353 368

permo triassic boundary superanoxia and stratified superocean records from lost deep sea pelagic cherts of japan and british columbia canada recorded a long term and worldwide deep sea anoxic oxygen depleted event across the permo triassic or paleozoic and mesozoic boundary 251 2 million years ago the symmetry in lithostratigraphy and redox condition of the boundary sections suggest that the superocean panthalassa became totally stratified for nearly 20 million years across the boundary the timing of onset climax and termination of the oceanic stratification correspond to global biotic events including the end guadalupian decline the end permian extinction and mid triassic recovery

variation in 87 sr 86 sr of permian seawater an overview the strontium isotope ratio 87sr s6sr of seawater has changed significantly through time in response to variations in the input of sr to the oceans from various crust and upper mantle sources with differing 87sr 86sr values an important aspect of this temporal variation is the empirical finding that while the 87sr 86sr of seawater may vary through time at any given time the sr isotope ratio of the oceans is everywhere the same isotopic uniformity is achieved because the marine residence time of sr 4 x 106 yr is long e g veizer 1989 compared to the oceanic circulation time 103 yr the oceans therefore are well mixed with respect to both sr and sr isotope ratio and all coeval marine derived carbonates sulfates and phosphates will possess the same initial 87sr s6sr value consequently the temporal changes in the 87sr s6sr of seawater can be used to correlate and date marine strata and can provide insight into the global processes that have shaped our world

the role of the earth s mantle in controlling the frequency of geomagnetic reversals a series of computer simulations of the earth s dynamo illustrates how the thermal structure of the lowermost mantle might affect convection and magnetic field generation in the fluid core eight different patterns of heat flux from the core to the mantle are imposed over the core mantle boundary spontaneous magnetic dipole reversals and excursions occur in seven of these cases although sometimes the field only reverses in the outer part of the core and then quickly reverses back the results suggest correlations among the frequency of reversals the duration over which the reversals occur the magnetic field intensity and the secular variation the case with uniform heat flux at the core mantle boundary appears most earth like this result suggests that variations in heat flux at the core mantle boundary of the earth are smaller than previously thought possibly because seismic velocity anomalies in the lowermost mantle might have more of a compositional rather than thermal origin or because of enhanced heat flux in the mantle s zones of ultra low seismic velocity