the meteoritical bulletin no 81 1997 jul meteoritical bulletin no 81 lists 181 new meteorites noteworthy among these are a new lunar meteorite dar al gani 262 four observed falls dong ujimqin qi galkiv mount tazerzait and piplia kalan four irons albion great sand sea 003 hot springs and mont dieu two mesosiderites dong ujimqin qi and lamont an acapulcoite fro 95029 a eucrite piplia kalan two probably paired ureilites dar al gani 164 and 165 an r chondrite hammadah al hamra 119 an ungrouped type 3 chondrite hammadah al hamra 180 a highly unequilibrated ordinary chondrite wells ll3 3 and a variety of carbonaceous and unequilibrated ordinary chondrites from libya and antarctica all italicized abbreviations refer to addresses listed in the appendix

diffusion of ar in k feldspar present and absent the mechanisms of ar release from k feldspar samples in laboratory experiments and during their geological history are assessed here modern petrology clearly established that the chemical and isotopic record of minerals is normally dominated by aqueous recrystallization the laboratory critique is trickier which explains why so many conflicting approaches have been able to survive long past their expiration date current models are evaluated for self consistency especially arrhenian non linearity leads to paradoxes the models testable geological predictions suggest that temperature based downslope extrapolations often overestimate observed geological ar mobility substantially an updated interpretation is based on the unrelatedness of geological behaviour to laboratory experiments the isotopic record of k feldspar in geological samples is not a unique function of temperature as recrystallisation promoted by aqueous fluids is the predominant mechanism controlling isotope transport k feldspar should therefore be viewed as a hygrochronometer laboratory degassing proceeds from structural rearrangements and phase transitions such as are observed in situ at high temperature in na and pb feldspars these effects violate the mathematics of an inert fick s law matrix and preclude downslope extrapolation the similar upward concave non linear shapes of arrhenius trajectories of many silicates hydrous and anhydrous are likely common manifestations of structural rearrangements in silicate structures

geological geophysical and thermal characteristics of the salton sea geothermal field california abstract the salton sea geothermal field is the largest water dominated geothermal field in the salton trough in southern california within the trough local zones of extension among active right stepping right lateral strike slip faults allow mantle derived magmas to intrude the sedimentary sequence the intrusions serve as heat sources to drive hydrothermal systems we can characterize the field in detail because we have an extensive geological and geophysical data base the sediments are relatively undeformed and can be divided into three categories as a function of depth 1 low permeability cap rock 2 upper reservoir rocks consisting of sandstones siltstones and shales that were subject to minor alterations and 3 lower reservoir rocks that were extensively altered because of the alteration inter granular porosity and permeability are reduced with depth field permeability is enhanced by renewable fractures i e fractures that can be reactivated by faulting or natural hydraulic fracturing subsequent to being sealed by mineral deposition in the central portion of the field temperature gradients are high near the surface and lower below 700 m surface gradients in this elliptically shaped region are fairly constant and define a thermal cap which does not necessarily correspond to the lithologic cap at the margin of the field a narrow transition region with a low near surface gradient and an increasing gradient at greater depths separates the high temperature resource from areas of normal regional gradient geophysical and geochemical evidence suggest that vertical convective motion in the reservoir beneath the thermal cap is confined to small units and small scale convection is superimposed on large scale lateral flow of pore fluid interpretation of magnetic resistivity and gravity anomalies help to establish the relationship between the inferred heat source the hydrothermal system and the observed alteration patterns a simple hydrothermal model is supported by interpreting the combined geological geophysical and thermal data in the model heat is transferred from an area of intrusion by lateral spreading of hot water in a reservoir beneath an impermeable cap rock

a brine interface in the salton sea geothermal system california fluid geochemical and isotopic characteristics data from 71 geothermal production intervals in 48 wells from the salton sea geothermal system ssgs indicate that fluids in that system cluster into two distinct populations in terms of their salinity and their stable isotopic compositions the distinctive hot hypersaline brine typically 20 wt total dissolved solids for which the ssgs is known is overlain by a cooler 260 c fluid with distinctly lower salinity typically 10 wt total dissolved solids hypersaline brines have high and rather consistent 18o shifts produced by water rock interaction and have a very narrow range in d values low tds fluids on the other hand show a wide range in both d and 18o production of both types of fluid from closely spaced geothermal wells in many regions of the ssgs indicates that a relatively sharp salinity interface exists over much of the field the fluid interface typically cross cuts sedimentary bedding but is consistently found where reservoir temperatures are approximately 260 c at these temperatures hypersaline brines have densities of approximately 1 0 gm cm3 while the low tds fluids have densities as low as 0 85 gm cm3 this stable density stratified interface acts as a barrier to convective heat and mass transfer in the ssgs isolating the hypersaline reservoir from overlying dilute fluids a lithologic cap implied by previous ssgs models is unnecessary in such a stratified system since heat and mass transfer across the interface must occur by slow conductive diffusional and interface mixing processes regardless of local permeability

age inheritance and uplift history of the old woman piute batholith california and implications for k feldspar age spectra ion probe u pb zircon analyses yield a crystallization age of 74 pm 3 ma for both peraluminous and metaluminous plutons within the old woman piute batholith these analyses reveal that about 50 of the zircons from the peraluminous sweetwater wash granite are restitic inherited zircons from this batholith yield ages ranging from older than 1800 ma to 1100 ma and most are similar in age to proterozoic igneous rocks in the eastern mojave desert 40 ar 39 ar hornblende ages from the metaluminous granodiorite are 73 pm 2 ma and mica ages from both plutonic series are 70 pm 2 ma k feldspar age spectra yield age gradients with initial steps between 60 and 67 ma and rise to plateau ages of 70 pm 2 ma several k feldspars from the granodiorite yield elevated plateau ages after 50 39 ar released that result from excess argon uplift rates as high as 4 mm yr between 74 and 70 ma are required by the narrow age range for all minerals

the heating duration and provenance age of rocks in the salton sea geothermal field southern california abstract 40ar 39ar step heating of single k feldspar crystals 500 g in a furnace with a low argon blank and accurate temperature control provide constraints on the thermal history of the salton sea geothermal field southern california estimates of 40ar loss from detrital k feldspars coupled with kinetic information gleaned from laboratory degassing of 39ar allow possible thermal histories to be evaluated samples from core and cuttings of sandstones from the state 2 14 landers 1 dearborn farms 1 magmamax 2 elmore 3 and sinclair 3 wells have been analyzed for this purpose no recent 40ar loss is recognized in any of the 17 crystals measured even for samples currently at temperatures greater than 275 c this observation suggests that the present temperature distributions in these wells have not been maintained for greater than 1000 years however aggregates 100 mg of two k feldspar samples do reveal recent 40ar loss from the state 2 14 well suggesting a time scale of 1000 to 5000 years for near peak thermal conditions these estimates of heating duration are broadly consistent with earlier results from thermal modelling but do not support interpretations that paleotemperatures were once hotter than present provenance ages span the tertiary through middle proterozoic but cluster at ages of 25 70 and 1250 ma these age peaks are very common k feldspar k ar ages in detachment terranes of southeastern california and southwestern arizona both drained by the colorado river this coincidence supports earlier suggestions that the sands of the salton trough were derived mainly from the colorado river unrealistically low apparent activation energies

lunar highland meteorites and the composition of the lunar crust abstract major minor and trace element data obtained by neutron activation techniques and by spark source mass spectrometry ssms on two lunar meteorites mac88104 and mac88105 are reported both mac samples were also analysed for their contents and isotopic compositions of rare gases additional ssms data were obtained on four lunar highland meteorites previously found in antarctica alha81005 y791197 y82192 and y86032 mac88104 and mac88105 are very similar in chemistry suggesting that they are pieces of a single fall event the bulk chemical composition of mac88104 5 is not very different from the other lunar highland meteorites highly aluminous with relatively low contents of ree and siderophile element concentrations slightly above 1 of a ci chondritic level however mafic element concentrations mg cr mn etc are slightly lower in mac88104 5 than in the other lunar highland meteorites the contents of solar rare gases in the two mac samples are low indicating only a small regolith contribution in agreement with rare petrographically identifiable regolith components the mac samples and also y82192 and y86032 are classified as fragmental breccias with negligible regolith components in contrast to alha81005 and y791197 which are regolith breccias with high solar wind derived rare gas contents there is no correlation among lunar meteorites between peak shock pressures and solar gas contents indicating that peak shock pressures of up to 25 gpa do not lead to gas loss a low 26al activity vogt et al 1990 and high contents of cosmogenic rare gases in mac88104 5 suggest a long exposure 400 000 years in the lunar sub surface k ar ages are in excess of 3 9 by lunar highland meteorites and compositionally similar granulitic rocks from the apollo 16 and 17 landing sites contain about 1 of a ci chondritic component according to siderophile and volatile element contents but independent of the amount of regolith components apparently the major fraction of meteoritic elements in these rocks was not provided by micrometeorites impacting the regolith the abundances of siderophile e g ir and volatile elements may therefore reflect the last spike of accretion of the moon after the formation of the anorthositic crust lunar meteorites of highland origin are chemically different from the bulk of the apollo 16 highland samples in having higher fe mg ratios and lower contents and less fractionated patterns of incompatible and siderophile elements since lunar highland meteorites are associated with at least three but probably four different fall events and since they are not derived from chemically exotic front side terranes they may represent a better sampling of the average chemical composition of the lunar crust than previous estimates based on returned lunar samples and remote sensing data a comparison between an average highland composition derived by taylor 1982 and an estimate based on lunar highland meteorites shows that the taylor composition contains higher concentrations and more fractionated incompatible elements mainly because of a substantial amount of kreep a trace element rich highly fractionated component from the front side of the moon not present at the sites from which the lunar meteorites come

thermal regime of the state 2 14 well salton sea scientific drilling project temperature logs were made repeatedly during breaks in drilling and both during and after flow tests in the salton sea scientific drilling project well state 2 14 the purpose of these logs was to assist in identifying zones of fluid loss or grain and to characterize reservoir temperatures at the conclusion of the active phase of the project a series of logs was begun in an attempt to establish the equilibrium temperature profile initially we were able to log to depths below 3 km but beginning in late may of 1986 it was impossible to log below about 1 8 km owing to casing failure our best estimates of formation temperature below 1 8 km are 305 5 c at 1890 m and 355 10 c at 3170 m for the upper 1 8 km the latest temperature log october 24 1986 using a digital slickline heat shielded downhole recording device was within a few degrees celsius of equilibrium as confirmed by a more recent log july 31 1987 to a depth of 1 km as in most other wells in the salton sea geothermal field there is an impermeable thermally conductive cap on the hydrothermal system this cap extends to a depth of more than 900 m at the state 2 14 well thermal conductivities of 19 samples of drill cuttings from this interval were measured at room temperature the conductivity values were corrected for in situ porosity as determined from geophysical logs and for the effects of elevated temperature thermal gradients decrease from about 250 mk m 1 same as degrees celsius per kilometer in the upper few hundred meters to just below 200 mk m 1 near the base of the conductive cap using one interpretation thermal conductivities increase with depth mainly because of decreasing porosity resulting in component heat flows that agree reasonably well with the mean of about 450 m w m 2 this value agrees well with heat flow data from shallow wells within the salton sea geothermal field a second interpretation in which measured temperature coefficients of quartz and carbonate rich rocks are used to correct thermal conductivity results in lower mean conductivities that are roughly constant with depth and consequently systematically decreasing heat flux averaging about 350 mw m 2 below 300 m this interpretation is consistent with the inference from fluid inclusion studies that the rocks in this part of the field were once several tens of degrees celsius hotter than they are now the age of this possible disturbance is estimated at a few thousand years

regional patterns of magnetite authigenesis in the appalachian basin implications for the mechanism of late paleozoic remagnetization we report paleomagnetic and rock magnetic data from sedimentary carbonates of the appalachian basin that have implications for the mechanism of widespread late paleozoic remagnetization in this rock type sampling was accomplished mostly along two across basin transects one in devonian carbonates of new york state and the other in ordovician and mississippian carbonates of tennessee and alabama paleomagnetic investigations of the new york devonian carbonates along a transect from albany to buffalo indicate that these rocks were completely remagnetized in alleghenian time rock magnetic studies show that magnetite concentration varies in a regular fashion along the transect with a local maximum near syracuse and decreasing gradually to the east and west this pattern shows a striking correlation with the degree of diagenetic alteration of clay minerals in a devonian bentonite horizon which took place during alleghenian time we conclude that most of the magnetite present in these carbonates is of authigenic origin and that clay mineral alteration and magnetite authigenesis were coeval late paleozoic events that were controlled by the same diagenetic factors thermoviscous remagnetization processes cannot be ruled out in this setting in light of the observed degree of thermal maturity however our results suggest that chemical factors played a critical role in remagnetization since they allow us to infer that magnetite authigenesis and remagnetization are about the same age we propose a geochemical model for magnetite authigenesis wherein the iron is derived from detrital smectites during diagenetic illitization which is triggered by the introduction of potassium rich brines results from the tennessee transect from nashville to chattanooga show a very different pattern paleomagnetic studies indicate that late paleozoic remagnetization has affected ordovician carbonates of the nashville dome paleozoic carbonates in the overthrust belt near chattanooga also carry the late paleozoic remagnetization however mississippian carbonates between the dome and the overthrust belt are very weakly magnetized and show no evidence for late paleozoic remagnetization samples show only a present field magnetization or at one locality in northwestern alabama a dual polarity magnetization of probable mississippian age rock magnetic studies indicate that higher concentrations of magnetite are present in the remagnetized rocks of the nashville dome and the overthrust belt than in the nonremagnetized mississippian carbonates we therefore conclude that magnetite authigenesis and remagnetization are related events in this setting and that the remagnetization must be due to chemical processes the presence of a remagnetization shadow in the younger rocks now exposed between the fold thrust belt and the flexural arch is attributed to westward flow of magnetite forming aqueous fluids through deep sub carboniferous aquifers during alleghenian time upward migration of the fluids through the mississippian carbonates may have been prevented by the devono mississippian chattanooga shale an impermeable stratum that is present throughout the region

lunar meteorites from oman abstract sixty named lunar meteorite stones representing about 24 falls have been found in oman in an area of 10 7 103 km2 in southern oman lunar meteorite areal densities average 1 g km 2 all lunar meteorites from oman are breccias although two are dominated by large igneous clasts a mare basalt and a crystalline impact melt breccia among the meteorites the range of compositions is large 9 32 al2o3 2 5 21 1 feo 0 3 38 g g 1 sm and 1 to 22 5 ng g 1 ir the proportion of nonmare lunar meteorites is higher among those from oman than those from antarctica or africa omani lunar meteorites extend the compositional range of lunar rocks as known from the apollo collection and from lunar meteorites from other continents some of the feldspathic meteorites are highly magnesian high mgo mgo feo compared with most similarly feldspathic apollo rocks two have greater concentrations of incompatible trace elements than all but a few apollo samples a few have moderately high abundances of siderophile elements from impacts of iron meteorites on the moon all lunar meteorites from oman are contaminated to various degrees with terrestrial na k p zn as se br sr sb ba u carbonates or sulfates the contamination is not so great however that it seriously compromises the scientific usefulness of the meteorites as samples from randomly distributed locations on the moon

feldspathic lunar meteorites pecora escarpment 02007 and dhofar 489 contamination of the surface of the lunar highlands by post basin impacts abstract pca pecora escarpment 02007 and dhofar 489 are both meteorites from the feldspathic highlands of the moon pca 02007 is a feldspathic breccia consisting of lithified regolith from the lunar surface it has concentrations of both incompatible and siderophile elements that are at the high end of the ranges for feldspathic lunar meteorites dhofar 489 is a feldspathic breccia composed mainly of impact melted material from an unknown depth beneath the regolith concentrations of incompatible and siderophile elements are the lowest among brecciated lunar meteorites among 19 known feldspathic lunar meteorites all of which presumably originate from random locations in the highlands concentrations of incompatible elements like sm and th tend to increase with those of siderophile elements like ir feldspathic meteorites with high concentrations of both suites of elements are usually regolith breccias iridium derives mainly from micrometeorites that accumulate in the regolith with duration of surface exposure micrometeorites have low concentrations of incompatible elements however so the correlation must reflect a three component system we postulate that the correlation between sm and ir occurs because the surface of the feldspathic highlands terrane has become increasingly contaminated with time in sm rich material from the procellarum kreep terrane that has been redistributed across the lunar surface by impacts of moderate sized post basin impacts the most sm rich regolith breccias among feldspathic lunar meteorites are about 3 enriched compared to the most sm poor breccias but this level of enrichment requires only a few percent sm rich material typical of the procellarum kreep terrane the meteorite data suggest that nowhere in the feldspathic highlands are the concentrations of k rare earths and th measured by the lunar prospector mission at the surface representative of the underlying bedrock all surfaces covered by old regolith as opposed to fresh ejecta are at least slightly contaminated dhofar 489 is one of 15 paired lunar meteorite stones from oman total mass of meteorite 1037 g on the basis of its unusually high mg fe ratio the meteorite is likely to have originated from northern feldspathic highlands

siderophile and other geochemical constraints on mixing relationships among hed meteoritic breccias we have used neutron activation and electron probe fused bead techniques to analyze the bulk major and trace element compositions of 104 named hed meteorites about 100 102 distinct meteorites depending upon pairings including 32 polymict eucrites 30 howardites and six diogenites most were not previously analyzed for siderophile trace elements many not even for major elements our typical sample was 350 mg and in some cases two separate chips were analyzed as a test of meteorite heterogeneity meteorites with extraordinary compositions include bluewing 001 an unequilibrated eucrite that is rich in ti sm and other incompatible elements y 791192 a cumulate dominated polymict eucrite and lew 87002 an oddly sm rich howardite dominated by a ferroan variety of diogenite the eucrite diogenite mixing ratio is the single most important factor determining the compositions of polymict heds but wide ranges in eucrite incompatible element contents in diogenite cr and v contents and in sc contents of both eucrites and diogenites make for diversity among the polymict heds as our new siderophile data help to show the common practice of describing the entire class of howardites as regolith breccias is erroneous most howardites are fragmental breccias showing no sign of origin from true in the lunar sense i e soil like near surface regolith howardites are highly diverse in ni content often remarkably ni poor compared to lunar regolith breccias however the few 8 howardites with between 300 and 1200 lg g ni consistently show some combination of other traits suggestive of regolith origin most importantly all four cases or five if we include malvern which appears to have been altered by annealing of howardites known to have enrichments in solar wind noble gases belong to the 300 lg g ni group in many cases an abundance of glasses particularly in spheroidal or turbid brown form provides additional evidence for regolith origin we propose that the important subset of howardites that are regolith breccias be formally distinguished by the designation regolithic howardite apart from high siderophile levels the regolithic howardites are compositionally distinctive in having al2o3 consistently near 8 9 wt corresponding to a eucrite diogenite mixing ratio of precisely 2 1 assuming the heds are reasonably representative of the ancient i e pre vestoid launch surface of vesta this clustering of regolith composition is difficult to explain unless most of the ancient diogenite component was brought to the surface in a single early episode i e probably a single great impact after which smaller scale cratering with no further major excavations of diogenite until the vestoid forming event efficiently homogenized the surface such a single excavation model may also help to explain why diogenites in marked contrast with eucrites are seldom polymict and why al2o3 poor diogenite dominated howardites consistently lack major siderophile enrichments the low siderophile contents of polymict eucrites are most enigmatic possibly in the hedasteroidal context low collision velocities etc only materials blended by multiple impacts consistently acquire major enrichments in siderophile elements 2009 elsevier ltd all rights reserved

the meteoritical bulletin no 82 1998 july abstract meteoritical bulletin no 82 lists information for 974 new meteorites including 521 finds from antarctica 401 finds from the sahara 21 finds from the nullarbor region of australia and 7 falls ban rong du burnwell fermo jalanash juancheng monahans 1998 and silao many rare types of meteorites are reported counting pairing groups as one these include one cr chondrite two ck chondrites two co chondrites four cv chondrites one ch chondrite or bencubbin like six c2 unclassified chondrites two eh chondrites two el chondrites three r chondrites thirty unequilibrated ordinary chondrites one un grouped chondrite three eucrites six howardites one diogenite eleven ureilites nine iron meteorites one mesosiderite two brachinites one lodranite one winonaite and two lunar meteorites dar al gani 400 and eet 96008 all italicized abbreviations refer to addresses tabulated at the end of this document

shallow drilling in the salton sea region the thermal anomaly during two shallow thermal drilling programs thermal measurements were obtained in 56 shallow 76 2 m and one intermediate 457 3 m depth holes located both onshore and offshore along the southern margin of the salton sea in the imperial valley california these data complete the surficial coverage of the thermal anomaly revealing the shape and lateral extent of the hydrothermal system the thermal data show the region of high thermal gradients to extend only a short distance offshore to the north of the quaternary volcanic domes which are exposed along the southern shore of the salton sea the central thermal anomaly has an arcuate shape about 4 km wide and 12 km long across the center of the anomaly the transition zone between locations exhibiting high thermal gradients and those exhibiting regional thermal gradients is quite narrow thermal gradients rise from near regional 0 09 c m to extreme 0 83 c m in only 2 4 km the heat flow in the central part of the anomaly is greater than 600 mw m2 and in the two local anomalies exceeds 1200 mw m2 the shape of the thermal anomaly is asymmetric with respect to the line of volcanoes previously thought to represent the center of the field with its center line offset south of the volcanic buttes there is no broad thermal anomaly associated with the magnetic high that extends offshore to the northeast from the volcanic domes the salton sea thermal anomaly can be described as three nested thermal features superimposed on the regional salton trough heat flux a broad region of elevated conductive heat flow with constant temperature gradients of about 0 1 c m a central anomaly of high 0 4 c m near surface gradients observed through a conductive thermal cap underlain by a nearly isothermal zone of hydrothermal circulation and two local anomalies with shallow temperature gradients as high as 0 8 c m superimposed on the central geothermal system these observations of the thermal anomaly provide important constraints for models of the circulation of the hydrothermal system thermal budgets based on a simple model for this hydrothermal system indicate that the heat influx rate for local hot spots in the region may be large enough to account for the rate of heat flux from the entire salton trough

history of the paired lunar meteorites mac88104 and mac88105 derived from noble gas isotopes radionuclides and some chemical abundances abstract noble gas isotopes radionuclides and chemical abundances were studied in the lunar meteorites mac88104 and mac88105 collected in the macalpine hills area of antarctica the concentrations of the noble gas isotopes and the radionuclide activities in the two meteorites are essentially identical proving that the two meteorites are paired from 40k 40ar dating we obtain a gas retention age of 3550 400 ma typical for lunar surface material probably before breccia compaction the mac88104 5 material resided for 630 200 ma at an average shielding depth of 85 g cm 2 that is about 50 cm below the lunar surface in the lunar regolith as judged from the concentration of cosmic ray produced kr and xe isotopes although this duration of lunar regolith residence is relatively long mac88104 5 represent immature regolith material the concentration of solar wind implanted noble gases are two orders of magnitude lower than those in mature lunar soil the reason for that might be the relatively high average shielding the 40 ar 36ar ratio of the trapped component is 5 7 1 0 indicating an intermediate antiquity of the material we estimate that the solar wind and lunar atmospheric particles were implanted about 2000 ma ago the radionuclide activities allow us to derive the exposure history of the mac88104 5 material the duration of the moon earth transfer was 0 24 ma production of the radionuclides on the lunar surface immediately before ejection is possible but duration and shielding depth for such an exposure cannot be determined from our data we obtain a terrestrial age of 0 1 tterr 0 6 ma and an ejection time of mac88104 5 from the moon of 0 1 tejection 0 8 ma the exposure histories of the lunar meteorites discussed in this work indicate that at least two impact events are required for their ejection from the moon our first noble gas results for lunar meteorite yamato 793274 show that it represents mature lunar regolith material with relatively high concentrations of solar wind implanted noble gases and a duration of several hundred million years of exposure to cosmic rays

new lunar meteorites impact melt and regolith breccias and large scale heterogeneities of the upper lunar crust we have analyzed nine highland lunar meteorites lunaites using mainly inaa several of these rocks are difficult to classify dhofar 081 is basically a fragmental breccia but much of its groundmass features a glassy fluidized texture that is indicative of localized shock melting also much of the matrix glass is swirly brown suggesting a possible regolith derivation we interpret dar al gani dag 400 as an extremely immature regolith breccia consisting mainly of impact melt breccia clasts we interpret dhofar 026 as an unusually complex anorthositic impact melt breccia with scattered ovoid globules that formed as clasts of mafic subophitic impact melt the presence of mafic crystalline globules in a lunar material even one so clearly impact heated suggests that it may have originated as a regolith our new data and a synthesis of literature data suggest a contrast in al2o3 incompatible element systematics between impact melts from the central nearside highlands where apollo sampling occurred and those from the general highland surface of the moon impact melts from the general highland surface tend to have systematically lower incompatible element concentration at any given al2o3 concentration than those from apollo 16 in the case of dhofar 026 both the bulk rock and a comparatively al poor composition 14 wt al2o3 7 g g sm extrapolated for the globules manifest incompatible element contents well below the apollo 16 trend impact melts from luna 20 57e distribute more along the general highland trend than along the apollo 16 trend siderophile elements also show a distinctive composition for apollo 16 impact melts ni ir averaging 1 8x chondritic in contrast lunaite impact melt breccias have consistently chondritic ni ir impact melts from luna 20 and other apollo sites show average ni ir almost as high as those from apollo 16 the prevalence of this distinctive ni ir ratio at such widely separated nearside sites suggests that debris from one extraordinarily large impact may dominate the megaregolith siderophile component of a nearside region 2300 km or more across highland polymict breccia lunaites and other kreep poor highland regolith samples manifest a strong anticorrelation between al2o3 and mg the magnesian component probably represents the chemical signature of the mg suite of pristine nonmare rocks in its most pure form unaltered by the major kreep assimilation that is so common among apollo mg suite samples the average composition of the ferroan anorthositic component is now well constrained at al2o3 29 30 wt implying about 17 19 wt modal mafic silicates in good agreement with the composition predicted for flotation crust over a ferroan magma ocean warren 1990

trapped noble gases indicate lunar origin for antarctic meteorite the isotopic abundances of the noble gases he ne ar kr xe are reported for antarctic meteorite alha81005 it contains solar wind implanted gases whose absolute and relative concentrations are quite similar to lunar regolith samples but not to other meteorites alha81005 also contains a large excess 40ar component which is identical to the component in lunar fines implanted from the lunar atmosphere large concentrations of cosmogenic 21ne 82kr and 126xe in alha81005 indicate a total cosmic ray exposure age of 2 108 years the noble gas data alone are strong evidence for a lunar origin of this meteorite

lithostratigraphy of the state 2 14 borehole salton sea scientific drilling project sedimentary rocks from the california state 2 14 research borehole of the salton sea scientific drilling project located in the imperial valley of southern california were deposited in the continental basin of the salton trough lacustrine shale and siltstone are the dominant lithologies sandstones were deposited in lake margin meander channel fill and lacustrine delta environments framework modal clast compositions of the sandstones indicate a dominant colorado river provenance rare pebbly mudstones were deposited as storm induced debris flows primary depositional structures in the sediments are commonly disrupted by seismic disturbances nonmarine gastropods and ostrocods are relatively uncommon and occurrences of stratabound sulfides suggest periods of brackish water conditions bedded anhydrite and centimeter scale mudcracks record intervals of dessication the state 2 14 sedimentary rocks are interpreted as the basinward facies of the borrego and brawley formations which range from pliocene to pleistocene in age

the thermal significance of potassium feldspar k ar ages inferred from age spectrum results 40ar39ar age spectrum analyses of three microcline separates from the separation point batholith northwest nelson new zealand which cooled slowly 5 c ma 1 through the temperature zone of partial radiogenic 40ar accumulation are characterized by a linear age increase over the first 65 percent of gas release with the lowest ages 80 ma corresponding to the time that the samples cooled below about 100 c the last 35 percent of 39ar released from the microclines yields plateau ages 103 99 and 93 ma which reflect the different bulk mineral ages and correspond to cooling temperatures between about 130 to 160 c theoretical calculations confirm the likelihood of diffusion gradients in feldspars cooling at rates 5 c ma 1 diffusion parameters calculated from the 39ar release yield an activation energy e 28 8 1 9 kcal mol 1 and a frequency factor grain size parameter d0l2 5 6 3 9 14sec 1 this arrhenius relationship corresponds to a closure temperature of 132 13 c which is very similar to the independently estimated temperature from the observed diffusion compensation correlation this d0l2 implies an average diffusion half width of about 3 m similar to the half width of the perthite lamellae in the feldspars the range in microcline k ar ages from the separation point batholith is the result of relatively small temperature differences within the pluton during cooling comparison of the diffusion laws determined for microcline with those for anorthoclases and other homogeneous k feldspars e 40 to 52 kcal mol 1 reveals that ar diffusion is more highly temperature dependent in the disordered structural state than in the ordered structural state previously published u shaped age spectra are probably the result of the superimposition of excess 40ar upon diffusion profiles of the kind described here

40ar 39ar age spectrum analysis of detrital microclines from the southern san joaquin basin california an approach to determining the thermal evolution of sedimentary basins abstract detrital microcline grains from sedimentary strata preserve a record of thermal evolution in the temperature range 100 to 200 c which can be revealed by40ar 39ar age spectrum analysis microcline separates from deep drill hole intersections with eocene to miocene sediments in the basin and tejon blocks of the southern san joaquin valley california analysed by the age spectrum approach show radiogenic40ar 40ar gradients that record both the slow cooling of the uplifting sediment source 65 ma ago and a recent thermal event this information in conjunction with the observation of fission track annealing in the coexisting apatites allows estimation of the temperature time conditions of this thermal event at about 140 c for 200 ka present and paleotemperature data is in accord with heating related to several kilometers of pleistocene sediment deposition heat flow calculations suggest that this recent subsidence has depressed the thermal gradient from about 30 c km 1 to the present apparent gradient of 24 c km 1 40ar 39ar analysis of detrital microcline crystals yields thermochronological information in the temperature time range of petroleum maturation and provides this technique with potential as both a useful exploration tool and as a means of probing the fundamental geodynamic processes of basin evolution

active ore formation at a brine interface in metamorphosed deltaic lacustrine sediments the salton sea geothermal system california the salton sea geothermal system is an area of active hydrothermal metamorphism of pliocene to pleistocene deltaic lacustrine and evaporitic sediments deposited in a modern continental rift zone temperatures up to 365 degrees c hypersaline metalliferous brines with up to 26 wt percent total dissolved solids and active base metal ore formation accompany low pressure greenschist and amphibolite facies metamorphism at depths less than 3 2 km drill cores recovered by the salton sea scientific drilling project shed new light on the nature and origin of ore formation in the eastern portion of the salton sea geothermal system base metal ore mineralization occurs in vertical fractures that comprise the major form of fluid permeability at 1 to 3 km in the modern geothermal system type 1 veins are dominated by carbonate contain pyrrhotite and other sulfides are completely sealed and occur in wall rock showing minimal alteration fluid inclusion data indicate that they were deposited under a thermal gradient much higher than that now found in the eastern part of the system type 2 veins are dominated by silicates and hematite are permeable and occur in wall rocks showing pervasive chloritization and epidotization fluid inclusion data indicate that they are forming now from the geothermal brines under the modern thermal gradient fluid inclusions record an apparent steep progressive salinity increase in the vein systems in the upper 2 km of the system however fluid production data from salton sea geothermal wells indicate that reduced metalliferous hypersaline brine averaging 23 wt percent total dissolved solids is overlain by more oxidized metal poor fluid averaging 5 wt percent total dissolved solids a sharp interface exists between the fluids at 1 to 2 km paralleling the 250 degrees c isothermal surface a model is developed for type 2 vein ore formation involving mixing at the interface between the two fluids magmatic intrusion induces fracturing heating and the expulsion of reduced connate fluids to cause early type 1 vein mineralization following the rising thermal front deep hypersaline brine rises diapirically and mixes with overlying fluids in vertical fractures transecting the ascending interface forming type 2 veins the hypersaline brine rises to a level of density temperature stabilization causing pervasive greenschist metamorphism of the host sediments the diapir then begins to cool and descend shallow oxidized brine is drawn in as the hypersaline brine descends promoting late stage hematite in type 2 veins the eastern salton sea geothermal system presently appears to be in this latter mode of cooling and retrograde brine descent ore formation in the system is caused by the coincidence of transaxial entry of a major river into an active rift zone deposition of metal bearing deltaic sediments to form a closed basin sedimentary environment episodic lacustrine evaporite formation and injection of heat and elements by rift related magmatic intrusions at depth the presence of an upwelling brine diapir in the system may be analogous to conditions immediately prior to the exhalation of metalliferous fluids that formed stratiform fe zn pb cu sulfide and oxide deposits in paleorift zone environments

composition and evolution of the lunar crust in the descartes highlands apollo 16 samples from the north ray crater ejecta blanket apollo 16 were investigated by petrographic microscope electron microprobe instrumental neutron activation and xray fluorescence analyses and 40ar 39ar and rb sr dating techniques nine major groups of monomict and polymict breccias were defined on the basis of microscopic texture and these were further subdivided into chemical subgroups on the basis of characteristic elements such as al mg fe cr ree ni and co the polymict breccias fragmental breccias granulitic breccias and impact melt breccias are the result of multiple impact induced mechanical mixing and melting and of thermal and impact metamorphism of rock and mineral clasts derived from primordial igneous crustal rocks for calculations of mixing models it was found that end members consisting of the pristine igneous rock components present as discrete samples at the apollo 16 site and supplemented by kreep dunite and a meteoritic component yield the best fits for the composition of polymict breccias the end member rocks a re ferroan anorthosite various magnesian gabbronorites including sodic ferrogabbro and feldspathic lherzolite and spinei troctolite the following model is proposed for the composition and stratigraphy of the target for north ray crater the lower section of the stratigraphy is composed of a megabreccia with clasts of highly feldspathic polymict breccias kreep free old eastern highland rock suite interpreted as nectaris ejecta descartes formation the top section contains kreep bearing polymict breccias kreep bearing young western highland rock suite and appears to be similar to the lithologies found in the cayley plains this material interpreted as cayley formation may be a distant facies of imbrium basin ejecta deposits of the imbrium basin the petrographic differences between these two major selenographic units the descartes and the cayley formations in the apollo 16 area are more distinct than the chemical differences the petrographic and chemical composition of the primordial igneous upper crust in the regions of the nectaris and imbrium basins has been calculated by subtraction of the kreep and meteoritic components from the bulk composition of the descartes and cayley materials the nectaris crust which is better constrained consists of 86 87 a northosite 4 sodic ferrogabbro 0 5 1 3 feldspathic lherzolite 6 8 regular magnesian gabbronorite 1 8 2 8 dunite and 0 1 spinel troctolite a model for the evolution of the upper lunar crust in the descartes highlands is proposed on the basis of isotope ages and clast matrix relationships of polymict breccias essential features of this model in sequenial order are 1 development of multiple layers of kreep free early feldspathic fragmental megabreccias and impact melt sheets on the primordial crust in the time period from 4 4 aeons to the time of the nectaris impact which could have occurred as late as 3 85 aeons ago 2 excavation of these megabreccias by the nectaris event and deposition of a nectarian feldspathic fragmental megabreccia in the descartes area 3 introduction of kreep basaltic material into the upper crust mainly west and northwest of the descartes site and formation of kreepy impact melt sheets most probably from 4 05 to 3 80 aeons ago 4 imbrium impact at 3 8 aeons ago and deposition of kreep bearing imbrian feldspathic fragmental breccias at the descartes site which form the cayley formation and 5 redeposition mixing and melting of all preexisting breccias yielding kreep bearing and kreep poor post cayley fragmental breccias and melt ejecta glass bombs as the result of small impacts craters 1 5 km in diameter in the cayley plains and the descartes mountains respectively

geochemistry petrology and ages of the lunar meteorites kalahari 008 and 009 new constraints on early lunar evolution abstract kalahari 008 and 009 are two lunar meteorites that were found close to each other in botswana kalahari 008 is a typical lunar anorthositic breccia kalahari 009 a monomict breccia with basaltic composition and mineralogy based on minor and trace elements kalahari 009 is classified as vlt very low ti mare basalt with extremely low contents of incompatible elements including the ree the lu hf data define an age of 4286 95 ma indicating that kalahari 009 is one of the oldest known basalt samples from the moon it provides evidence for lunar basalt volcanism prior to 4 1 ga pre nectarian and may represent the first sample from a cryptomare the very radiogenic initial 176hf 177hf ehf 12 9 4 6 the low ree th and ti concentrations indicate that kalahari 009 formed from re melting of mantle material that had undergone strong incompatible trace element depletion early in lunar history this unusually depleted composition points toward a hitherto unsampled basalt source region for the lunar interior that may represent a new depleted endmember source for low ti mare basalt volcanism apparently the moon became chemically very heterogeneous at an early stage in its history and different cumulate sources are responsible for the diverse mare basalt types evidence that kalahari 008 and 009 may be paired includes the similar fayalite content of their olivine the identical initial hf isotope composition the exceptionally low exposure ages of both rocks and the fact that they were found close to each other since cryptomaria are covered by highland ejecta it is possible that these rocks are from the boundary area where basalt deposits are covered by highland ejecta the concentrations of cosmogenic radionuclides and trapped noble gases are unusually low in both rocks although kalahari 008 contains slightly higher concentrations a likely reason for this difference is that kalahari 008 is a polymict breccia containing a briefly exposed regolith while kalahari 009 is a monomict brecciated rock that may never have been at the surface of the moon altogether the compositions of kalahari 008 and 009 permit new insight into early lunar evolution as both meteorites sample lunar reservoirs hitherto unsampled by spacecraft missions the very low th and ree content of kalahari 009 as well as the depletion in sm and the lack of a kreep like signature in kalahari 008 point to a possible source far from the influence of the procellarum kreep terrane possibly the lunar farside

exsolution in hornblende and its consequences for 40ar39ar age spectra and closure temperature abstract step heating studies of hornblende and biotite which coexist in an amphibolite near north walpole vermont reveal dramatically different 40 ar 39 ar age spectra the biotite mg 59 is characterized by a plateau over 98 percent 39ar release at 343 5 ma in strong contrast to the amphibole which exhibits both a complex age spectrum and a k ar age significantly younger than the biotite the amphibole release pattern contains three complete age cycles which range between extremes of 199 ma and 408 ma interestingly the k ca ratio calculated from reactor produced isotopes also varies with ar release but follows a trend which is antipathetic to the 40 ar 39 ar age pattern detailed microstructural examination including transmission electron microscopy tem reveals a complex exsolution structure that is consistent with both the complexity of the release pattern as well as the low degree of radiogenic 40ar 40ar retentivity in the amphibole this result underscores the variability of closure temperature tc for 40ar in metamorphic amphiboles and should warn against accepting a single universal value of tc

from nanometer to megameter isotopes atomic scale processes and continent scale tectonic models abstract earth sciences deal with physical entities spanning 15 orders of magnitude from nanometer crystal lattice unit cells to megameter faults and orogens the understanding of megameter scale processes is greatly improved by the study of the nanometer scale processes the growth of crystals their deformation under shear and the transport of isotopes used for dating from a physical point of view the transport of atoms across a crystal with high potential barriers and no interatomic voids is not accurately described by fick s equations which were developed for dilute solutions with unhindered particle mobility a variety of more general descriptions have been recently proposed all of which share features such as complex temperature dependence as opposed to linear arrhenian behaviour from a petrological point of view the ubiquitous recognition of microstructures in chemical and isotopic disequilibrium underscores the fact that diffusive reequilibration is a much slower process than creating the structures themselves diffusion in an inert matrix fickian diffusion is observed to be negligible with respect to the growth of discrete mineral generations as the latter frequently involves aqueous fluids isotope geoscientists should follow petrologists and stress the geohygrometric properties of minerals dissolution reprecipitation the fact that mineral reactions and microstructure development do not solely depend on temperature may explain why some thermochronological models from the literature have made predictions whose field tests have failed the demise of one class of models might initially seem unfortunate actually it is a great benefit because it shifts our attention to the reality of petrogenesis and to the sequence of events that any mineral assemblage records

thermal history of the eastern gulf of suez ii reconstruction from apatite fission track and k feldspar measurements abstract apatite fission track aft measurements from miocene graben fill sediments of the eastern gulf of suez in three deep boreholes belayim 113 m 2 6 ras garra m 1 and alma 2 yield a wide range of ages from 125 to 320 ma and mean track lengths 10 1 12 7 m this range is similar to that recorded from precambrian crystalline basement flanking the graben which is the major source for the rift fill since the aft ages exceed the age of the host strata which are presently at their highest post depositional temperatures the rift related thermal regime is one of only moderate heating downhole aft data in the belayim 113 m 2 6 borehole attest to a higher rift temperature than in the ras garra m 1 borehole some 85 km to the south where little or no thermal overprinting is evident these findings are consistent with previously reported bottom hole temperatures and vitrinite reflectance data in the study area despite the higher syn rift thermal regime indicated for belayim 113 m 2 6 apatite provenance ages in ras garra m 1 are considerably younger thus the aft data in the ras garra m 1 area do not record significant rift related thermal effects but rather they mainly retain a pre rift provenance signature which reflects the order and depth of erosion at the uplifted flanks the younger aft ages in ras garra m 1 despite the weaker rift related thermal effect suggest a deeper level proportional to an additional 5 10 c of exhumation of the uplifted crystalline basement southwards along the eastern rift flank by mid miocene time this result is consistent with earlier findings which indicate both increased extension and heat flow southwards in the gulf of suez and earlier exhumation of the rift flank immediately preceding extension and opening of the gulf of suez the most deeply exhumed basement rocks presently exposed on the rift flanks were heated to temperatures 110 c total annealing of apatite but 40 ar 39 ar data and non resetting of zircon ft clocks in sinai 40 ar 39 ar data from granite penetrated in graben drilling at 3 89 km further corroborates pre rift palaeotemperatures

the meteoritical bulletin no 84 2000 august meteoritical bulletin no 84 lists information for 1341 newly classified meteorites comprising 842 from antarctica 341 from africa 66 from australia 48 from asia including 42 from the arabian peninsula 38 from north america 4 from europe and 2 from south america information is provided for 11 recent falls bilanga devri khera djoumine guangmingshan kitchener kobe leighlinbridge sabrum songyuan tagish lake and vissannapeta 4 martian meteorites dar al gani 670 735 dhofar 019 los angeles and sayh al uhaymir 005 008 3 lunar meteorites northwest africa 032 dhofar 025 and 026 an ungrouped enstatite rich meteorite zaklodzie 11 iron meteorites and a wide variety of other interesting stony meteorites including ck cm co cr cv r enstatite and unequilibrated ordinary chondrites primitive achondrites hed achondrites ureilites and aubrites

constraints on the age of heating at the fenton hill site valles caldera new mexico subsurface samples and temperature data from the fenton hill drilling site adjacent to the valles caldera new mexico allow an investigation of the thermal history of this site through analyses of the behavior of isotopic dating systems in changing thermal regimes and through thermal modeling estimates of the age of the heating event at fenton hill responsible for the current elevated temperatures vary from about 1 to 4 ma however new 40ar 39ar analyses and thermal modeling indicate that the age of heating may be much younger than previously believed the 40ar 39ar analyses of microcline separates from five samples ranging in drill hole depth from 1 13 to 4 56 km and in situ temperatures from 110 c to 313 c indicate thermal events at the site at around 1030 and 870 ma and a very recent thermal event related to the thermal development of the caldera the maximum estimates of peak heating duration during this recent thermal event are between 3 and 60 ka two distinct thermal perturbations are recognized in the subsurface temperature data a shallow disturbance probably related to heating from a lateral flow of hot water just above the precambrian surface at a depth of about 730 m and a deep thermal disturbance the source of which is unknown model studies indicate the age of the shallow thermal disturbance to be about 10 ka with reasonable constraints on the source of the deep thermal disturbance it must lie within a few kilometers of the site and its maximum age is estimated to be less than about 40 ka thus heating at the fenton hill site appears to be much younger than the main caldera event at about 1 ma and is probably related to a magmatic and or hydrothermal event very close to fenton hill during the last few tens of thousands of years

activation of the nyainqentanghla shear zone implications for uplift of the southern tibetan plateau neogene extension of the tibetan plateau is manifested as a series of north south trending graben the most prominent of which is the yadong gulu rift the nyainqen tanghla shan a ne sw trending mountain range 100 km nw of lhasa bounds the western margin of the yangbajian graben the central segment of the yadong gulu rift the eastern edge of the nyainqentanghla massif is marked by a low angle 25 o detachment fault shear zone of amphibolite grade mylonites the noar 3 ar thermal history results from samples collected along two deeply incised valleys within the massif reveal that a rapid cooling event propagated from 8 ma in the core of the range to 4 ma within the high strain zone at the eastern boundary assuming that faulting initiated at high angle 60o thermal histories were fit to a numerical simulation of slip on a normal fault to yield estimates of both the age of fault initiation and the slip rate history the form of the isotopically derived thermal histories are similar to general form predicted by the thermal model and suggests that significant movement began at 8 1 ma in the southern valley goring la and proceeded at an average slip rate of 3 mm yr between 8 and 3 ma a more complex history is required to fit the data from the northern valley balum chun but the timing of initiation and average slip rate are similar to the goring la result numerical simulations in which the fault angle is varied indicate that the isotopically derived temperature histories are inconsistent with slip occurring at low angle 40o because the extension direction of the yangbajian graben is representative of most rifts on the southern tibetan plateau our data suggest that crustal thickness and elevation reached close to their present values by 8 1 ma a carbon isotopic shift in pedogenic carbonates from the siwalik formation at about 7 5 ma appears to reflect intensification of the asian monsoon and by inference that the plateau had attained an important threshold elevation by that time formation of a diffuse plate boundary in the indian oceanic lithosphere beginning at 7 5 8 0 ma is also consistent with this history we suggest that the plateau had attained a threshold area and elevation by 8 1 ma sufficient to trigger these three independent manifestations

dhofar 081 a new lunar highland meteorite the lunar meteorite dhofar 081 found as a single fragment of 174 g in the dhofar region of oman is a shocked feldspathic fragmental highland breccia dominated by anorthosite rich lithic and mineral clasts embedded into a fine grained mostly shock melted clastic matrix major mineral phases in the bulk rock are ca rich plagioclase an96 5 99 5 pyroxene fs21 9 46 2wo3 0 41 4 and olivine fa29 3 47 8 accessory phases include fe ni metal ilmenite and ti cr rich spinel dhofar 081 contains subordinate crystalline fragments of large anorthosites intersertal impact melt rocks microporphyritic impact melt breccias dark fine grained impact melt breccias large cataclastic feldspars and irregularly shaped brown glass clasts mafic components are rare and no genuine regolith components were found in the sections studied minerals in dhofar 081 show homogeneously distributed shock features intergranular recrystallization strong fracturing and mosaicism in feldspar as well as a high density of mostly irregular fractures in pyroxene and olivine localized impact melting caused by one or several impacts led to a strong lithification based on these effects an equilibration shock pressure of about 15 20 gpa is estimated for the strongest shock event in dhofar 081 devitrification of the glassy material in the rock indicates thermal annealing after shock melting suggesting that the 15 20 gpa shock event predated the ejection event according to the concentrations of implanted solar noble gases dhofar 081 represents a polymict clastic breccia deposit with possibly a minor regolith component a similar noble gas record of dhofar 081 and macalpine hills 88104 05 suggests the possibility of a source crater pairing of both meteorites as indicated by noble gas measurements pairing of dhofar 081 with the other lunar meteorites found in oman dhofar 025 and dhofar 026 is unlikely

the salton sea scientific drilling project in march 1986 a research borehole called the state 2 14 reached a depth of 3 22 km in the salton sea geothermal system of southern california this was part of the salton sea scientific drilling project sssdp the first major i e multimillion dollar research drilling project in the u s continental scientific drilling program the principal goals of the project were to investigate the physical and chemical processes of a high temperature high salinity magmatically driven hydrothermal system the borehole encountered temperatures of up to 355 c and produced metal rich alkali chloride brines containing 25 wt of total dissolved solids the rocks penetrated exhibit metamorphism and ore genesis in action they show a progressive transition from unconsolidated lacustrine and deltaic sediments to hornfelses with lower amphibolite facies mineralogy accompanied by pervasive veins containing iron copper lead and zinc ore minerals the sssdp included an intensive program of rock and fluid sampling flow testing and downhole logging and scientific measurement the purpose of this paper is to introduce this special section of the journal of geophysical research on the sssdp to describe briefly the background of the project and the drilling and testing of the borehole to summarize the initial scientific results and to discuss how the lessons learned are applicable to future scientific drilling projects

a noble gas data collection of lunar meteorites we collected the published noble gas data of altogether 35 lunar meteorites this compilation includes the stable isotopes of he ne ar kr and xe we also give a summary of cosmogenic trapped and radiogenic noble gas components of lunar meteorites for which data are available in the literature

multipath ar transport in k feldspar deduced from isothermal heating experiments abstract the hypothesis underlying k feldspar thermochronometry that a single energy fickian diffusion is operating at all temperatures has been investigated three isothermal heating experiments on a granitic microcline show that a discrete distribution of domain sizes is unable to explain experimental data a continuous distribution of domain sizes also fails as its temperature dependence is incorrect the most likely explanation is that fast pathway diffusion is superimposed on the variety of diffusion mechanisms predicted by kinetic theory this prevents extrapolation of laboratory experiments to geological conditions geological models based on k feldspar thermochronometry must be seriously re examined and limited to non isotopic constraints

rapid early miocene acceleration of uplift in the gangdese belt xizang southern tibet and its bearing on accommodation mechanisms of the india asia collision abstract five samples from a biotite hornblende granodiorite phase of the 42 5 ma quxu pluton gangdese batholith southern tibet have been collected at 250 m vertical intervals biotite from these rocks yields monotonically decreasing40ar 39ar isochron ages with decreasing elevation of 26 8 0 2 23 3 0 5 19 7 0 3 18 4 0 4 and17 8 0 1ma tc 335 c coexisting k feldspars have virtually identical minimum apparent40ar 39ar ages of 17 0 0 4ma tc 285 c these data indicate parts of southern tibet experienced a pulse of uplift in the early miocene with the rate of uplift rising from 0 07 to 4 4 mm year in the interval 20 to 17 ma an apatite fission track age of 9 9 0 9ma from this locality constrains the average uplift rate at this site to about 0 81 mm year between 17 and 9 9 ma and 0 30 mm year from 9 9 ma to present k feldspar from the dagze granite 30 km to the east near lhasa yields a minimum apparent40ar 39ar age of 35 9 0 9ma tc 227 c which indicates an average uplift rate there of 0 21 mm year since then the marked pulse of uplift of the quxu granodiorite and the difference in uplift history between the dagze and quxu plutons suggests southern tibet has experienced discrete pulses of uplift variable in both space and time these data are not consistent with models which require a large proportion of uplift of the tibetan plateau to have occurred in the last 2 ma the data support the suggestion that convergence between india and asia was largely accommodated by tectonic escape during the opening of the south china sea 32 to 17 ma ago and permit distributed shortening as a mechanism for crustal thickening and uplift of this part of the tibetan plateau subsequent to 20 ma

petrology chemistry and isotopic compositions of the lunar highland regolith breccia dar al gani 262 lunar meteorite dar al gani 262 dg 262 found in the libyan part of the sahara is a mature anorthositic regolith breccia with highland affinities the origin from the moon is undoubtedly indicated by its bulk chemical composition radionuclide concentrations noble gas n and o isotopic compositions and petrographic features dar al gani 262 is a typical anorthositic highland breccia similar in mineralogy and chemical composition to queen alexandra range que 93069 about 52 vol of the studied thin sections of dar al gani 262 consist of fine grained 100 m constituents and 48 vol is mineral and lithic clasts and impact melt veins the most abundant clast types are feldspathic fine grained to microporphyritic crystalline melt breccias 50 2 vol includes recrystallized melt breccias whereas mafic crystalline melt breccias are extremely rare 1 4 vol granulitic lithologies are 12 8 vol intragranularly recrystallized anorthosites and cataclastic anorthosites are 8 8 and 8 2 vol respectively and devitrified glasses are 2 7 vol impact melt veins 5 5 vol of the whole thin sections cutting across the entire thin section were probably formed subsequent to the lithification process of the bulk rock at pressures below 20 gpa because the bulk rock never experienced a higher peak shock pressure mafic crystalline melt breccias are very rare in dar al gani 262 and are similar in abundance to those in que 93069 the extremely low abundance of mafic components and the bulk composition may constrain possible areas of the moon from which the breccia was derived the source area of dar al gani 262 must be a highland terrain lacking significant mafic impact melts or mare components on the basis of radionuclide activities an irradiation position of dg 262 on the moon at a depth of 55 85 g cm3and a maximum transit time to earth 0 15 ma is suggested dar al gani 262 contains high concentrations of solar wind implanted noble gases the isotopic abundance ratio 40ar 36ar 3 is characteristic of lunar soils the terrestrial weathering of dg 262 is reflected by the occurrence of fractures filled with calcite and by high concentrations of ca ba cs br and as there is also a large amount of terrestrial c and some n in the sample which was released at low temperatures during stepped heating high concentrations of ni co and ir indicate a significant meteoritic component in the lunar surface regolith from which dg 262 was derived

compositional order disorder and stable isotope characteristics of al fe epidote state 2 14 drill hole salton sea geothermal system epidote ca2fe3si3o12 oh ca2al3si3o12 oh is a common hydrothermal mineral in metasediments and veins at depths 900 m in the state 2 14 drill hole of the salton sea geothermal system the mole fraction of ca2fe3si3o12 oh in epidotes xps from this drill hole ranges from 0 11 to 0 42 and complex compositional zoning of octahedral fe3 and al is typical within single grains with increasing depth there is an overall but irregular decrease in the fe3 content of epidotes in metasandstones in most samples vein epidotes are more fe3 rich and exhibit a wider compositional range than metasandstone epidotes from the same depth octahedral fe3 in the m 1 sites in four epidotes evaluated by 57fe mossbauer spectroscopy ranges from 7 5 1 7 to 11 4 1 5 of the total iron the most ordered epidote formed in veins at 2618 m in the biotite zone this epidote has an ordering parameter 1 2xfe3 m 1 of 0 85 0 03 which corresponds to a calculated state of equilibrium order disorder at 390 60 c in close agreement with the probable downhole temperature of 340 c two epidote samples from the chlorite calcite zone 1420 m 265 c 1867 m 300 c are more disordered corresponding to calculated states of equilibrium order disorder of 450 c these data suggest that the analyzed epidotes from the chlorite calcite zone are in a metastable state of substitutional order disorder the measured value of depidote from 1420 m is 96 which is 5 6 lighter than epidotes from 1867 m depidote 90 2227 m depidote 91 and 2618 m depidote 90 when compared to the reservoir fluid from the december 1985 flow test the derived fractionation of hydrogen isotopes between epidote and the geothermal brine is 19 at 1867 m and 340 c this value is in accord with published experimental hydrogen isotope fractionations between iron rich epidote and aqueous electrolyte solutions therefore considering the complexity of the salton sea brine the isotopic temperature is similar to the inferred downhole temperature

feldspathic lunar meteorites and their implications for compositional remote sensing of the lunar surface and the composition of the lunar crust we present new compositional data for six feldspathic lunar meteorites two from cold deserts yamato 791197 and 82192 and four from hot deserts dhofar 025 northwest africa 482 and dar al gani 262 and 400 the concentrations of feo or al2o3 and th or any other incompatible element together provide first order compositional information about lunar polymict samples breccias and regoliths and regions of the lunar surface observed from orbit concentrations of both elements on the lunar surface have been determined from data acquired by orbiting spacecraft although the derived concentrations have large uncertainties and some systematic errors compared to sample data within the uncertainties and errors in the concentrations derived from orbital data the distribution of feo and th concentrations among lunar meteorites which represent 18 source regions on the lunar surface is consistent with that of 18 random samples from the surface approximately 11 of the lunar meteorites are low feo and low th breccias consistent with large regions of the lunar surface particularly the northern farside highlands almost all regoliths from apollo sites on the other hand have larger concentrations of both elements because they contain fe rich volcanic lithologies from the nearside maria and th rich lithologies from the high th anomaly in the northwestern nearside the feldspathic lunar meteorites thus offer our best estimate of the composition of the surface of the feldspathic highlands and we provide such an estimate based on the eight most well characterized feldspathic lunar meteorites the variable but high on average mg fe ratio of the feldspathic lunar meteorites compared to ferroan anorthosites confirms a hypothesis that much of the plagioclase at the surface of the feldspathic highlands is associated with high mg fe feldspathic rocks such as magnesian granulitic breccia not ferroan anorthosite geochemically the high mg fe breccias appear to be unrelated to the mafic magnesian suite rocks of the apollo collection models for the formation of the upper lunar crust as a simple flotation cumulate composed mainly of ferroan anorthosite do not account for the complexity of the crust as inferred from the feldspathic lunar meteorites

porosities of lunar meteorites strength porosity and petrologic screening during the meteorite delivery process porosity has been directly measured for eight lunar meteorite breccias and calculated for two more on the basis of literature density measurements lunar meteorite regolith breccias display systematically low porosity in comparison to otherwise analogous apollo regolith breccias among seven meteoritic regolith breccias porosity ranges from 1 to 11 and averages 7 5 1 3 2 whereas for 44 analogous apollo samples porosities mostly calculated from literature density data the average is 25 1 7 the origin of this disparity is enigmatic but the trend probably reflects mainly a bias in favor of strong compact breccias among fragments that manage to survive the violent process of launch to lunar escape velocity 2 38 km s in addition compaction during launch may play an important role the population of lunar meteorites is clearly not a random unmodified sample of lithic materials near the surface of the parent body