eastward flow through the mid atlantic ridge at 11 n and its influence on the abyss of the eastern basin abstract the dilute antarctic bottom water of the north atlantic eastern trough is supplied from the western trough through fractures in the mid atlantic ridge in particular the influence on eastern trough property distributions of flow through the romanche and vema fracture zones near the equator and 11 n respectively has been noted previously here new observations are reported that document the abyssal circulation of the northeastern atlantic basins gambia abyssal plain south canary basin and north canary basin in particular the dominance of vema influence the absence of romanche influence and the existence of a system of deep western boundary currents and estimated transport deep isopycnals slope steeply across the vema s eastern end near 39 w corresponding to a geostrophic transport through the vema of 2 1 to 2 3 106 m3s 1 colder than 2 0 c this is half or more of the estimated bottom water that flows north across the equator into the subtropical western north atlantic this transp

deepwater source variations during the last climatic cycle and their impact on the global deepwater circulation the degree of similarity of the 13c records of the planktonic foraminiferal species n pachyderma and of the benthic foraminiferal genus cibicides in the high latitude basins of the world ocean is used as an indicator of the presence of deepwater sources during the last climatic cycle whereas continuous formation of deep water is recognized in the southern ocean the norwegian sea stopped acting as a sink for surface water during isotope stage 4 and the remainder of the last glaciation however deep water formed in the north atlantic south of the norwegian sea during the last climatic cycle as early as isotope substage 5d and this area was also the only active northern source during stages 4 2 a detailed reconstruction of the geographic distribution of 13c in benthic foraminifera in the atlantic ocean during the last glacial maximum shows that the most important deepwater mass originated from the southern ocean whereas the glacial north atlantic deep water cannot be traced south of 40 n at shallower depth an oxygenated 13c rich intermediate water mass extended from 45 n to 15 s in the pacific ocean a ventilation higher than the modern one was also found in open ocean in the depth range 700 2600 m and is best explained by stronger formation of intermediate water in high northern latitudes

enhanced ventilation of the north atlantic subtropical gyre thermocline during the last glaciation the ocean s intermediate1 6 and deep7 8 circulation are both known to have differed during the last glaciation from those of today but little is known about the history of the subtropical gyres variations in gyre processes should be closely linked to variations in global climate as gyre circulation is driven by air sea interactions and reflects the climate at the ocean surface the gyres are also a significant reservoir of carbon and nutrients so that gyre processes affect the distribution of carbon and nutrients in the oceans and thus atmospheric co2 here we use measurements of 13c and 18o in foraminifera from the bahamas to produce a detailed reconstruction of nutrient and temperature profiles in the thermocline during the last glaciation the thermocline of the glacial north atlantic subtropical gyre lacked the oxygen minimum that is characteristic of the modern ocean and was depleted in nutrients indicating greater more uniform thermocline ventilation at that time thus not only intermediate waters1 5 but the entire upper water column within the glacial north atlantic was depleted of nutrients moreover glacial thermocline waters were cooler had a steeper temperature gradient and a shallower base both the ventilation and the thermal structure of the glacial thermocline are consistent with what is known of the glacial climate9 14

benthic foraminiferal δ18o in the ocean s temperature salinity density field constraints on ice age thermohaline circulation benthic 18o data from 95 core sites are used to infer possible temperature salinity t s fields of the atlantic and pacific oceans at the last glacial maximum lgm a constraint of stable density stratification yields logically consistent scenarios for both t and s the solutions are not unique but are useful as a thinking tool using geosecs data we solve for the modem relationship between 18owater w and salinity in the deep sea w smow 1 529 s 53 18 as a starting point we assume that the slope of this equation applies to lgm conditions and predict 18ocalcite c gradients in equilibrium with probable t s fields of lgm deep and bottom waters benthic foraminiferal 18o data from the deep pacific 2 4 km depth and the bottom atlantic 4 km depth are 0 1 0 2 lower than from the deep atlantic 2 4 km depth at the lgm if the modern w s slope applies atlantic deep and bottom waters were more dense than pacific deep waters this assumption would imply bottom waters both fresher s 0 5 and colder t 3 c than overlying deep waters in conflict with other data suggesting ice age deep water much colder than at present it is also possible that the observed c gradients are an artifact of laboratory intercalibration if atlantic deep and bottom water c values were similar to deep pacific values this would be consistent with the hypothesis of a stronger southern ocean versus north atlantic source for deep ocean ventilation at the lgm taking the observed gradients at face value however a solution could be that the lgm w s slope in deep and bottom waters was higher than at present conceivably because of a stronger contribution of salt to the deep ocean via more intense sea ice freezing this would allow pacific deep waters and atlantic bottom waters to have a common source again in the antarctic both would be more dense than atlantic deep waters even though the deep waters were much colder than at present to better constrain these inferences drawn from the spatial distribution of benthic 18o we must reduce scatter in the 18o data with more high quality measurements in high sedimentation rate cores this is especially true at bottom water sites also we must intercalibrate mass spectrometers at different isotope laboratories more accurately to insure our isotope data are compatible

late quaternary paleochemistry of high latitude surface waters recent studies have stressed the role of high latitude nutrient levels and productivity in controlling the carbon isotopic composition of the deep sea and the co2 content of the atmosphere we undertook a study of the chemical composition of the polar planktonic foraminifer neogloboquadrina pachyderma s sinistral coiling from 30 late holocene samples and 49 down core records from the high latitude north and south atlantic oceans to evaluate the history of sea surface chemical change from glacial to interglacial time stable isotopic analysis of coretop samples from the atlantic pacific and southern oceans shows no significant correlation between the 13c of n pachyderma and either 13c or po4 in seawater conversely cd ca ratios in planktonic foraminifera are consistent with the po4 content of surface waters the level of maximum glaciation 18 000 yr b p identified by climap and 18o was chosen for mapping isopleths of 18o on n pachyderma s in the north atlantic reveal a pattern largely influenced by sea surface temperature s s t and generally support the s s t reconstruction of climap differences between the two suggest significantly lower salinity in north atlantic surface waters at high latitudes than in lower latitudes down core 13c records of n pachyderma confirm that low 13c values occurred in the northeast atlantic during the latest glacial maximum labeyrie and duplessy 1985 however a map of 13c for the 18 000 yr b p level for a much larger region in the north atlantic shows that minimum n pachyderma 13c occurred in temperate waters n pachyderma 13c decreased toward the southwest reaching a minimum of 1 at 37 n despite the variability seen in 13c records of n pachyderma none of our cores show significant temporal variability in cd ca from the combined cd ca and 13c data we can see no evidence for an upwelling gyre in the eastern north atlantic during the latest glacial maximum nor evidence that the southern and northern oceans had significantly different levels of preformed nutrients than today

on the late pleistocene ocean geochemistry and circulation a box model of the atmosphere and ocean was developed to investigate how geochemical distributions extant during the late pleistocene may have come about the model simulates the regional distribution of calcium carbonate dissolution as well as the chemical oceanography and atmospheric co2 13c and radiocarbon if the downward biological flux of particulate carbon increases by a factor of 2 to 3 in the antarctic and if this increase is combined with a relative increase of the atlantic sector antarctic bottom water aabw versus north atlantic deep water nadw source ratio from 1 3 to about 2 1 then the model predicts several changes that seem to be recorded in the sedimentary record as follows 1 a global redistribution of nutrients and 12c from the intermediate to deep water takes place with the atlantic intermediate water phosphate decreasing 0 6 mole kg 1 and the 13c increasing 0 3 to 0 5 2 the dissolved oxygen level of the deep sea is reduced from an average of about 180 to 70 mole kg 1 but the intermediate water oxygen declines only a small amount 3 the decrease in intermediate water nutrient concentration results in lower average organic carbon and calcium carbonate production in the warm surface ocean 4 the atmospheric co2 decreases by 90 to 110 ppm 5 initially a global increase in calcium carbonate dissolution occurs which is followed by a relaxation toward better preservation than exists for the present ocean in the model in this paper the reduction of nadw by itself does not produce these effects rather the nutrient decrease that does occur is found mostly in north pacific intermediate water and the model atmospheric co2 decrease is only 10 to 30 ppm it is observed that 92 of the atmospheric co2 change takes place according to a 200 year time constant in the model this corresponds to the response time of the upper ocean and atmosphere to a change in the stationary state atmospheric pco2 thus according to this model the time lag between the nutrient based cause and the atmospheric co2 response is not expected to be particularly large

steady models of arctic shelf basin exchange steady state exchanges between the arctic shelves and the central basins are estimated using an inverse box model estimates based only on mass heat and salt conservation are highly uncertain and cannot determine how the shelf basin exchange is partitioned between dense overflows and surface layer exchange inclusion of 18o conservation greatly reduces the uncertainty with the 18o constraints dense water fluxes from the shelves of 0 2 0 1 sv in the canadian basin and 1 4 0 3 sv in the eurasian basin with a small o 0 1 sv surface layer transport from shelves to basins best satisfy the requirements of steady state up to 3 8 sv of shelfbreak upwelling is consistent within error bars with steady state but none is required water leaving the shelves is replaced primarily from the bering strait the barents sea inflow and runoff and not from the basin surface layer proper representation of these external sources for the shelves is important for capturing the full range of plausible steady solutions the steady state solutions identify the balances which if upset could lead to arctic change

changes in the vertical structure of the north atlantic ocean between glacial and modern times the distribution of planktic foraminiferal 18o over the north atlantic ocean has been interpreted by duplessy et al 1991 1992 in terms of the distribution of surface water salinity during the last glacial maximum lgm and the younger dryas yd we present here the implications of this surface salinity distribution for changes in deep convection during these periods temperature salinity density diagrams of the water column have been constructed using the plancktic and benthic foraminifera 18o values together with sea surface temperature estimates obtained by using micropaleontological transfer functions the precision of these reconstructions is limited by the remaining uncertainties in the two basic assumptions upon which the methods are based the sea surface temperature reconstruction by climap are valid within the statistical uncertainties the water salinity 18o relationship is well constrained for surface and intermediate ocean waters a significant difference between the modern and the reconstructed glacial water structure is observed during the lgm the modern relatively warm and salty norwegian sea surface water and the north atlantic deep water nadw were replaced by low salinity surface water in the northern atlantic ocean and the norwegian sea and cold deep water 0 1 c however surface water salinity in the central north atlantic ocean 52 54 n 25 40 w was sufficiently high to permit deep water convection as a source of north atlantic intermediate and deep waters open ocean convection at the northern limit of the subtropical surface waters around 40 n may have contributed to the ventilation of the intermediate waters the waters deeper than 2000 m were the result of mixing between poorly oxygenated southern waters and well ventilated north atlantic deep waters a similar reconstruction for the cold yd period indicates that the modern type of circulation with warm and ventilated nadw was largely in operation and that the hydrologic pattern was different from that prevailing during the lgm

global variations of surface ocean productivity in low and mid latitudes influence on co2 reservoirs of the deep ocean and atmosphere during the last 21 000 years based on detailed reconstructions of global distribution patterns both paleoproductivity and the benthic 13c record of co2 which is dissolved in the deep ocean strongly differed between the last glacial maximum and the holocene with the onset of termination i about 15 000 years ago the new export production of low and mid latitude upwelling cells started to decline by more than 2 4 gt carbon year this reduction is regarded as a main factor leading to both the simultaneous rise in atmospheric co2 as recorded in ice cores and with a slight delay of more than 1000 years to a large scale gradual co2 depletion of the deep ocean by about 650 gt c this estimate is based on an average increase in benthic 13c by 0 4 0 5 the decrease in new production also matches a clear 13c depletion of organic matter possibly recording an end of extreme nutrient utilization in upwelling cells as shown by sarnthein et al 1987 the productivity reversal appears to be triggered by a rapid reduction in the strength of meridional trades which in turn was linked via a shrinking extent of sea ice to a massive increase in high latitude insolation i e to orbital forcing as primary cause

constraints from paleotracer data on the north atlantic circulation during the last glacial maximum we investigate the extent to which the paleotracers 13c and 18o constrain the north atlantic ocean general circulation during the last glacial maximum lgm the distinction is made in this work between the depiction of water mass distributions and the inference of the oceanic circulation the 13c data indicate that water masses formed in the north atlantic and in the southern ocean were distributed differently during the lgm but the extent of the differences cannot be quantified because of uncertainties in the end member composition reasonable choices of values for the end members produce volumes of lower north atlantic deep water nadw significantly smaller than in the modern atlantic in agreement with previous studies to explore the range of circulations consistent with this water mass distribution a coarse resolution inverse model of the north atlantic is constrained with 13c and 18o paleodata the model shows that the glacial period tracer distribution is fully consistent with the circulation rates estimated for the modern ocean however the paleodata are also consistent with a circulation rate of one half the modern flux of nadw and indeed there are an infinite number of rates of deep water movement that are possible to remove this ambiguity the central need is for a data type capable of setting the overall rates of water movement i e a clock such as that provided by geostrophy or a well sampled radioactive tracer

the information content of pore fluid δ18o and cl abstractpaleoceanographic proxies indicate that the ocean state during the last glacial maximum lgm differed from the modern ocean state depth profiles of ocean sediment pore fluid 18o and cl have been used to reconstruct the 18o and salinity at the lgm here it is investigated whether pore fluid profiles can constrain ocean 18o and salinity at other times and simultaneously their ability to constrain the lgm 18o and salinity an inverse framework is developed that relies on bayesian parameter estimation thus allowing formal separation of prior assumptions from the information in observations synthetic problems are used to explore the information about past ocean tracers that can be recovered from pore fluid profiles it is concluded that prior knowledge of deep ocean mixing time scales is essential to an accurate inverse estimate of lgm ocean salinity and 18o from modern pore fluid profiles the most recent 10 000 years of ocean salinity and 18o and the error in their estimates are bette

a new attenuation relation for peak horizontal acceleration of strong earthquake ground motion in japan abstract a new attenuation relation for peak horizontal acceleration applicable to the near source region in japan is developed the data base consists of 1372 horizontal components of peak ground acceleration from 28 earthquakes in japan and 15 earthquakes in the united states and other countries coefficients describing the decrease in acceleration with increasing distance found by most previous studies of japanese data are significantly smaller than those found by analyzing individual earthquakes this phenomenon is examined and found to result from use of general nonstratified multiple regression analyses the present analysis uses a two step stratified regression procedure and an attenuation model that accounts for geometrical spreading and anelastic attenuation but has magnitude independent shape at very short distances the resulting relation in japan is log 10 a 0 41 m log 10 r 0 032 10 0 41 m 0 0034 r 1 30 where a is the mean of the peak acceleration from two horizontal components at each site cm sec 2 r the shortest distance between site and fault rupture km and m the surface wave magnitude the median estimate of peak horizontal acceleration at the source region is 620 cm sec 2 independent of earthquake magnitude effects of four different ground condition rock hard medium and soft soils on the attenuation relation are also examined average peak horizontal accelerations for the rock and the soft soil sites are 60 and 140 per cent respectively of the value predicted from the equation

deep circulation of the north atlantic over the last 200 000 years geochemical evidence variations in the cadmium calcium ratio of north atlantic deep water are recorded in the fossil shells of benthic foraminifera the oceanic distribution of cadmium is similar to that of the nutrients hence the cadmium calcium ratio in shells records temporal variations in nutrient distributions data from a north atlantic sediment core show that over the past 200 000 years there has been a continuous supply of nutrient depleted waters into the deep north atlantic the intensity of this source relative to nutrient enriched southern waters diminished by about a factor of 2 during severe glaciations this evidence combined with carbon isotope data indicates that the continental carbon inventory may have been less variable than previously suggested

north atlantic thermohaline circulation during the past 20 000 years linked to high latitude surface temperature during a surface cooling event 10 000 to 12 000 years ago higher cd ca and lower 13c 12c ratios are observed in benthic foraminifera shells from rapidly accumulating western north atlantic sediments data from sediment cores show that marked nutrient depletion of intermediate waters occurs in association with reduced glacial north atlantic deep water flux it is proposed that cold high latitude sea surface temperatures enhance intermediate water formation at the expense of deep water formation

changes in the distribution of δ13c of deep water σco2 between the last glaciation and the holocene carbon isotopic measurements on the benthic foraminiferal genus cibicidoides document that mean deep ocean 13c values were 0 46 lower during the last glacial maximum than during the late holocene the geographic distribution of 13c was altered by changes in the production rate of nutrient depleted deep water in the north atlantic during the late holocene north atlantic deep water with high 13c values and low nutrient values can be found throughout the atlantic ocean and its effects can be traced into the southern ocean where it mixes with recirculated pacific deep water during the glaciation decreased production of north atlantic deep water allowed southern ocean deep water to penetrate farther into the north atlantic and across low latitude fracture zones into the eastern atlantic mean southern ocean 13c values during the glaciation are lower than both north atlantic and pacific 13c values suggesting that production of nutrient depleted water occurred in both oceans during the glaciation enriched 13c values in shallow cores within the atlantic ocean indicate the existence of a nutrient depleted water mass above 2000 m in this ocean

cadmium and delta13c paleochemical ocean distributions during the stage 2 glacial maximum changes in heat and salt transport by ocean currents have been implicated in ice age climate cycles weyl 1 968 newell 1 974 broecker et al 1 990b in addition to the direct physical effects of the ocean on climate the ocean carbon system controls atmospheric co2 and the co2 fluctuations documented in ice core bubbles barnola et a1 1 987 neftel et a1 1 988 are thought to be a significant factor in climate oscillations hansen et al 1 984 dramatic changes in oceanic circulation patterns and carbon system chemistry have occurred during the late quaternary glacial interglacial global climate cycles boyle keigwin 1 982 curry lohmann 1 983 shackleton pisias 1 984 boyle keigwin 1 987 duplessy et al 1 988 curry et al 1 988 broecker et al i 990a these changes in the ocean system may be significant driving forces in the progression of ice age co2 cycles toggweiler sarmiento 1 985 ennever mcelroy 1 985 wenk siegenthaler 1 985 boyle 1 988a b broecker peng 1 990 the oceanic distributions of c513c cd and other carbon system linked properties are controlled by the interaction between biological uptake and decomposition with the general circulation of the ocean because records of past oceanic cd and c5 1 3c are preserved in shells of planktonic and benthic foraminifera

the δ13c in benthic foraminiferal tests of fontbotia wuellerstorfi schwager relative to the δ13c of dissolved inorganic carbon in southern ocean deep water implications for glacial ocean circulation models on a transect between 20 and 70 s in the eastern atlantic ocean and weddell sea water samples from 19 hydrographic stations and bottom water from 55 surface sediment samples taken with a multiple corer were investigated for the stable carbon isotopic composition of the total dissolved inorganic carbon 13c co2 these measurements were compared to 13c values determined on live specimens of the benthic foraminifer fontbotia wuellerstorfi and closely related genera from the same stations in addition at 16 stations the stable carbon isotope composition of sedimentary organic carbon was measured general deepwater and bottom water mass circulation patterns as inferred from the 13c co2 are in close agreement with those known from other nonconservative tracers very low 13c values of upper circumpolar deep water 0 3 pee dee belemnite pdb in the polar front region and the eastern limb of the weddell gyre coincide with nutrient maxima however a significant decoupling of the dissolved phosphate signal from the 13c co2 signal is indicated in the abyssal weddell sea we attribute this to temperature dependent fractionation processes during gas exchange of surface waters with the atmosphere at sites of bottom water formation multiple corer water from the sediment water interface is slightly 13c depleted relative to deepwater and bottom water 13 co2 the surface sediment organic carbon 13c is 3 to 4 lower south of the polar front than north of it and the 13corg in freshly accumulated phytodetritus is 3 to 4 lower than surface sediment organic carbon 13c comparison of live f wuellerstorfi 13c and related genera with bottom water 13c co2 exhibits at most stations between the subtropical front 41 s and the southern boundary of the antarctic circumpolar current 55 s a significant lowering of foraminiferal 13c values compilation of a mean last glacial interglacial 13c amplitude 13c from six published southern ocean cores results in a shift of 0 99 0 13 pdb this shift is greater than that in all other regions however all of these cores are from positions close to recent oceanic fronts thus for these peripheral areas of the southern ocean we suggest about half of the glacial interglacial shift can be explained by varying frontal zone positions and widths accompanied by a change in mode and height of export production

changes in east atlantic deepwater circulation over the last 30 000 years eight time slice reconstructions using 95 epibenthic 13c records eight time slices were reconstructed to trace the distribution of east atlantic deepwater and intermediate water masses over the last 30 000 years our results show that there have been three distinct modes of deepwater circulation near the stage 3 2 boundary the origin of north atlantic deep water nadw was similar to today mode 1 however after late stage 3 the source region of the nadw end member shifted from the norwegian greenland sea to areas south of iceland mode 2 a reduced nadw flow persisted during the last glacial maximum with constant preformed 13c values the nutrient content of nadw increased markedly near the azores fracture zone from north to south probably because of the mixing of upwelled antarctic bottom water aabw from below which then advected with much higher flux rates into the northeast atlantic later the spread of glacial meltwater over the north atlantic led to a marked short term ventilation minimum below 1800 m about 13 500 14c years ago mode 3 the formation of nadw recommenced abruptly north of iceland 12 800 12 500 years ago and reached a volume approaching that of the holocene in the younger dryas 10 800 10 350 years b p another short term shutdown of deepwater formation followed between 10 200 and 9 600 years b p linked to a further major meltwater pulse into the atlantic each renewal of deepwater formation led to a marked release of fossil co2 from the ocean the likely cause of the contemporaneous 14c plateaus over the last 9000 years deepwater circulation varied little from today apart from a slight increase in aabw about 7000 14c years ago it is also shown that the oxygenated mediterranean outflow varied largely independent of the variations in deepwater circulation over the last 30 000 years

source of copper in the giant shimensi w cu mo polymetallic deposit south china constraints from chalcopyrite geochemistry and oxygen fugacity of ore related granites abstract porphyry type copper mineralization is generally considered to be related to ore forming fluid exsolution from oxidized magnetite bearing intermediate to felsic magmas however copper deposits associated with ilmenite bearing per aluminous evolved granites also exist and their origin remains obscure the shimensi w cu mo polymetallic deposit located in the northern segment of the jiangnan orogen south china composed mainly of the neoproterozoic shuangqiaoshan group meta sediments volcanic rocks and biotite granite is one of the largest tungsten deposits in the world the w cu mo polymetallic orebodies occur at the contact zone between the mesozoic ilmenite bearing fluorite bearing f rich highly fractionated granite and the neoproterozoic granite the reason for the accompanying cu mineralization within ilmenite bearing granites is unclear in this paper we present a detailed study of chalcopyrite geochemistry including s pb isotopes trace elements and nd isotopes and oxygen fugacity fo2 of ore related granites in the shimensi deposit to constrain the origin of copper sulfur isotope values of the sulfides give a narrow 34s interval of 3 3 to 0 5 mean 1 5 n 32 suggesting the ore forming fluid is of magmatic origin the similarity of pb isotopes of the majority of sulfides and k feldspars from mesozoic granites indicates their genetic relationship however chalcopyrite samples show a wider range of pb isotopic compositions than that of k feldspars suggesting an extra source for the ore forming fluids chalcopyrite from the ore deposit show features of lree enriched patterns variable eu negative anomalies eu eu 0 26 0 75 and la sm n values 0 77 5 93 while the two figures for the mesozoic f rich evolved granites are eu eu 0 18 0 45 and la sm n 2 42 4 09 this along with and the larger range of end values 12 4 to 2 7 of the chalcopyrites than for the mesozoic granites and neoproterozoic granite therein 8 6 to 6 2 suggest that the ore forming fluids cannot be attributed to the mesozoic granites alone the local cu enriched neoproterozoic shuangqiaoshan group rocks should have contributed to the mineralization the low bulk rocks fe3 fe2 ratios 0 02 1 00 average 0 22 fe2 enriched biotite compositions fe2 fe3 5 64 143 average 22 combined with the low ce4 ce3 ratios 3 509 average 142 negative eu anomalies eu eu 0 05 0 56 average 0 25 and low fo2 fmq 3 4 1 9 fmq 1 5 1 7 for the mesozoic magmatic zircons suggest that the granites in the shimensi deposit are relatively reduced the low oxygen fugacity below nno of granites is favorable for significant tungsten mineralization accompanying by minor cu mineralization

evidence from southern ocean sediments for the effect of north atlantic deep water flux on climate evidence from southern ocean sediments for the effect of north atlantic deep water flux on climate