stacking paleointensity and oxygen isotope data for the last 1 5 myr piso 1500 coupled relative geomagnetic paleointensity rpi and oxygen isotope records are used to construct rpi and oxygen isotope stacks for the last 1 5 myr the coupled correlations are accomplished using the match algorithm lisiecki l e and lisiecki p a 2002 application of dynamic programming to the correlation of paleoclimate records paleoceanography 17 1049 doi 10 1029 2001pa000733 to simultaneously correlate isotope and rpi records the simultaneous match reduces the degree of freedom associated with correlations using rpi or oxygen isotope records alone the overall compatibility of rpi and oxygen isotopes indicates a dominant global but independent component in both signals the local wavelet power spectrum lwps for the rpi stack indicates little significant orbital power although the accompanying oxygen isotope stack has all the lwps characteristics expected of a high resolution oxygen isotope record containing orbital frequencies the piso 1500 stack represents a new stratigraphic template that can be used to correlate among marine sediment records and link them to polar ice cores via variations in cosmogenic nuclide production scaling the stack to values for virtual axial dipole moment vadm indicate maxima at 15 1022 am2 and minima that imply a threshold of 2 5 1022 am2 below which values are associated with either polarity reversals or magnetic excursions

chronostratigraphy of the 600 000 year old continental record of lake van turkey lake van sediment cores from the ahlat ridge and northern basin drill sites of the icdp project paleovan contain a wealth of information about past environmental processes the sedimentary sequence was dated using climatostratigraphic alignment varve chronology tephrostratigraphy argon argon single crystal dating radiocarbon dating magnetostratigraphy and cosmogenic nuclides based on the lithostratigraphic framework the different age constraints are compiled and a robust and precise chronology of the 600 000 year old lake van record is constructed proxy records of total organic carbon content and sediment color together with the calcium potassium ratios and arboreal pollen percentages of the 174 meter long ahlat ridge record mimic the greenland isotope stratotype ngrip therefore the proxy records are systematically aligned to the onsets of interstadials reflected in the ngrip or synthesized greenland ice core stratigraphy the chronology is constructed using 27 age control points derived from visual synchronization with the gicc05 timescale an absolutely dated speleothem record e g hulu sanbao linzhu cave and the epica dome c timescale in addition the uppermost part of the sequence is complemented with four ages from holocene varve chronology and two calibrated radiocarbon ages furthermore nine argon argon ages and a comparison of the relative paleointensity record of the magnetic field with reference curve piso 1500 confirm the accuracy of the age model also the identification of the laschamp event via measurements of 10be in the sediment confirms the presented age model the chronology of the ahlat ridge record is transferred to the 79 meter long event corrected composite record from the northern basin and supplemented by additional radiocarbon dating on organic marco remains the basal age of the northern basin record is estimated at 90 ka the variations of the time series of total organic carbon content the ca k ratio and the arboreal pollen percentages illustrate that the presented chronology and paleoclimate data are suited for reconstructions and modeling of the quaternary and pleistocene climate evolution in the near east at millennial timescales furthermore the chronology of the last 250 kyr can be used to test other dating techniques

eastern turkish high plateau as a small turkic type orogen implications for post collisional crust forming processes in turkic type orogens abstract post collisional magmatism may be generated by extensive crustal melting in tibet type collisional environments or by falling out of slabs from under giant subduction accretion complexes in turkic type collisional orogens giving rise to decompression melting of the asthenospheric mantle replacing the removed oceanic lithosphere in turkic type post collisional magmatism the magmatic products are dominantly alkalic to peralkalic and greatly resemble those of extensional regions giving rise to much confusion especially in interpreting old collisional orogenic belts such magmatic regions are also host to a variety of economically valuable ore deposits including gold one place in the world where today active turkic type post collisional magmatism is present is the eastern anatolian high plateau produced after the terminal arabia eurasia collision in the late miocene the plateau is mostly underlain by the late cretaceous to oligocene east anatolian accretionary complex which formed south of the rhodope pontide magmatic arc this subduction accretion complex has been further shortening since the collision but it has also since been domed and became almost entirely covered by at least 15 000 km3 of volcanic rocks the volcanic rocks are calc alkalic in the north transitional in the middle and alkalic in the south of the plateau where the crust is thinnest today less than 38 km the volcanics are derived almost entirely from an enriched mantle the ages of the volcanics also become younger from north to south from about 11 ma to possibly 17th century ad we interpret the origin of the magmatic rocks as the result of decompression melting of the asthenospheric mantle sucked towards the exposed base of the east anatolian accretionary complex as the oceanic lithosphere beneath it fell out the lower density of the hot asthospheric material was the cause of the doming we believe that similar processes dominated the post collisional tectonics of such vast turkic type orogens as the altaids of central asia the late devonian early carboniferous lachlan belt in southeastern australia and the pan african collage of northeast afro arabia it is likely that archaean collisions were dominated by turkic type post collisional events rather than tibetan ones that only became common in the proterozoic

evidence of lateglacial and holocene climatic change and human impact in eastern anatolia high resolution pollen charcoal isotopic and geochemical records from the laminated sediments of lake van turkey annually laminated sediments from lake van spanning about 13000 varve years were sampled for stable isotopic geochemical pollen and charcoal analyses in order to find evidence of past regional climatic changes and human impact in the semi arid region of eastern anatolia turkey the lateglacial period was cold and dry with steppe vegetation and saline lake water during the younger dryas the lake level dropped dramatically and the vegetation turned to a semi desert geochemical and isotopic records indicate a strong increase in moisture at the onset of the holocene and artemisia chenopod steppes were partly replaced by grass steppe and pistachio scrub a delay of about 3000 years in the expansion of deciduous oak woodlands and high steppe fire frequencies suggest dry spring and summer weather during the early holocene at 8200 yr bp a shift in the regional climate regime facilitated the transport of more moisture into the interior areas of the taurus mountains and caused a change in the seasonal distribution of precipitation the steppe forests dominated by quercus advanced and reached their maximum extention at about 6200 yr bp all the proxy data indicate optimum climatic conditions low water salinity and high lake level between 6200 and 4000 yr bp after 4000 yr bp aridity increased again and the modern climatic situation was established human impact in the catchment of lake van started at 3800 yr bp and was intensified during the last 600 years

a new rock magnetic approach to selecting sediments for geomagnetic paleointensity studies application to paleointensity for the last 4000 years the hypothesis that the ratio of detrital remanent magnetization to anhysteretic remanent magnetization drm arm for sediment samples is a measure of relative geomagnetic paleointensity is critically evaluated by two distinct approaches one approach is a detailed rock magnetic examination of the implicit assumptions of the drm arm method and the construction of a selection process by which to identify sediments that conform to requirements satisfying these assumptions sediments are uniform with respect to drm arm ratio if they contain magnetite in the 1 15 ym particle size range as the predominant magnetic mineral and have variations in magnetite content of less than 20 30 times the minimum concentration the drm arm ratios of these sediments should provide estimates of relative geomagnetic paleointensity relative particle size variations in magnetite are detected with a plot of anhysteretic susceptibility xarm versus low field susceptibility x and the size range 1 15 m is approximately identified by high field hysteresis parameters a rock magnetic evaluation of leboeuf lake sediments with these techniques indicates that these sediments are suitable for a relative plaeointensity study the second approach to evaluating the drm arm ratio as a measure of relative paleointensity is direct comparison with absolute paleointensity data a comparison between the leboeuf lake estimates and thellier thellier results from the western united states supports the conclusion that suitable sediments can record geomagnetic paleointensity fluctuations

geomagnetic dipole strength and reversal rate over the past two million years independent records of relative magnetic palaeointensity from sediment cores in different areas of the world can be stacked together to extract the evolution of the geomagnetic dipole moment1 2 and thus provide information regarding the processes governing the geodynamo so far this procedure has been limited to the past 800 000 years 800 kyr ref 3 which does not include any geomagnetic reversals here we present a composite curve that shows the evolution of the dipole moment during the past two million years this reconstruction is in good agreement with the absolute dipole moments derived from volcanic lavas which were used for calibration we show that at least during this period the time averaged field was higher during periods without reversals but the amplitude of the short term oscillations remained the same as a consequence few intervals of very low intensity and thus fewer instabilities are expected during periods with a strong average dipole moment whereas more excursions and reversals are expected during periods of weak field intensity we also observe that the axial dipole begins to decay 60 80 kyr before reversals but rebuilds itself in the opposite direction in only a few thousand years

magnetic properties of light and dark sediment layers from the japan sea diagenetic and paleoclimatic implications abstract rock magnetic paleoclimatic diagenetic relationships of sediments spanning the last 0 78 ma have been investigated using samples collected from light and dark layers recovered at odp sites 794 yamato basin and 795 japan basin rock magnetic parameters k k fd arm sirm s ratio are shown to reflect diagenetic processes and climate related variations in the concentration mineralogy and grain size of the magnetic minerals contained within the sediments the magnetic mineralogy is dominated by ferrimagnetic magnetite type minerals with a small contribution made by hematite and iron sulphides such as pyrrhotite and or greigite magnetic mineral concentration and grain size vary between light and dark layers with the former characterized by a higher magnetic content and a finer magnetic grain size magnetite dissolution related to sulfate reduction due to bacterial degradation of organic matter is the process responsible for the magnetic characteristics observed in the dark layers testifying to the reducing conditions in the basin variations in the rock magnetic properties of the sediments are strongly correlated with global oxygen isotope fluctuations with glacial stages characterized by a lower magnetic mineral content and a coarser magnetic grain size relative to interglacial stages major downcore changes in the magnetic properties observed at site 794 can be related to changes in the oceanographic conditions of the basin associated with the flow of the warm tsushima current into the japan sea at about 0 35 0 40 ma ago

sedimentary records of relative paleointensity of the geomagnetic field theory and practice sediments have proved irresistible targets for attempts at determining the relative variations in the earth s magnetic field because of the possibility of long and continuous sequences that are well dated and have a reasonable global distribution the assumption underlying paleointensity studies using sedimentary sequences is that sediments retain a record reflecting the strength of the magnetic field when they were deposited early theoretical work suggested that because the time required for an assemblage of magnetic particles in water to come into equilibrium with the ambient magnetic field was quite short no dependence on magnetic field was expected nonetheless a number of experiments showed that sedimentary magnetizations varied in accordance with the field albeit not always in a simple linear fashion experiments in which the sediments were stirred in the presence of a field to simulate bioturbation showed a reasonably linear relationship with the applied field and these results spurred the hope that variations in the earth s magnetic field might indeed be recoverable from appropriate sedimentary sequences examination of existing paleointensity data sets allows a few general conclusions to be drawn it appears that sedimentary sequences can and do provide a great deal of information about the variations in relative paleointensity of the earth s magnetic field the dynamic range of sedimentary data sets is comparable to those acquired from thermal remanences moreover when compared directly with such independent measures of magnetic field variations as beryllium isotopic ratios and thermally blocked remanences there is considerable agreement among the various records when viewed over timescales of hundreds to thousands of years relative paleointensity data sets from more than a few thousand kilometers apart bear little resemblance to one another suggesting that they are dominated by nondipole field behavior when viewed over timescales of a few tens of thousands to hundreds of thousands of years however the records show coherence over large distances at least thousands of kilometers and may reflect changes in the dipole field on the basis of a sequence spanning the brunhes and matuyama chrons the magnetic field has oscillated with a period of about 40 ka for the last few hundred thousand years but these oscillations are not clear in the record prior to about 300 ka thus they are probably not an inherent feature in the geomagnetic field and the correspondence of the period of oscillation to that of obliquity is probably coincidence

an 84 kyr paleomagnetic record from the sediments of lake baikal siberia we have conducted a paleomagnetic study of sediment cores obtained from the selenga prodelta region of lake baikal russia this record which spans approximately the last 84 kyr contributes to a better understanding of the nature of geomagnetic field behavior in siberia and is a useful correlation and dating tool we demonstrate that the lake baikal sediments are recording variations in the geomagnetic field the directional record displays secular variation behavior with a geomagnetic excursion at 20 ka and additional excursions appearing as large amplitude secular variation at 41 61 and 67 ka smoothing of the geomagnetic excursion behavior occurs in lake baikal sediments owing to the intermediate sedimentation rate 13 cm kyr 1 the lake baikal relative paleointensity record correlates to absolute paleointensity data for the last 10 kyr and to relative paleointensity records from the mediterranean sea and indian ocean for the last 84 kyr this correlation suggests a strong global i e dipole component to these records and further supports the reliability of sediments as recorders of relative geomagnetic paleointensity we show that a relative geomagnetic intensity stratigraphy has a potential resolution of 7 kyr by correlating continental and marine records the geomagnetic intensity stratigraphy helps constrain the age of the difficult to date lake baikal sediments

paleomagnetism of lake van sediments chronology and paleoenvironment since 350 ka abstract in the framework of the paleovan project a high resolution paleomagnetic and rock magnetic study was carried out on a 149 m sedimentary sequence recovered from ahlat ridge in the deepest part of the lake van eastern turkey icdp site 5034 2 high sedimentation rates average 30 cm ka allow high resolution measurements of natural remanent magnetization nrm magnetic susceptibility anhysteretic remanence arm and hence of anhysteretic susceptibility arm over the last 350 ka the carrier of the remanence is detrital titanomagnetite largely from volcanic sources based on the similarity of magnetite grain size of tephra layers and the other lacustrine lithologies observed in a plot of the versus arm bulk magnetic parameters often covary with paleoclimatic signals in the lake van sediments a correlation exists between variations of and arm intensity and glacial interglacial marine isotopic stages as well as dust flux and temperatures observed in ice cores from greenland and antarctica the quality of the paleomagnetic record is compromised by weak nrm intensities as well as by the presence of tephra and turbidites throughout the sequence nonetheless a correlation is observed between the relative paleointensity rpi record based on nrm arm and the calibrated piso rpi stack that supports the independently derived age model for the site

a 600 000 year long continental pollen record from lake van eastern anatolia turkey abstract lake van is the fourth largest terminal lake in the world 38 5 n 43 e volume 607 km 3 area 3570 km 2 maximum water depth 460 m extending for 130 km wsw ene on the eastern anatolian high plateau turkey the sedimentary record of lake van partly laminated obtains a long and continuous continental sequence that covers multiple interglacial glacial cycles promoted by the potential of the sedimentary sequence for reconstructing the paleoecological and paleoclimate development of the near east a deep drilling operation was carried out in 2010 supported by the international continental scientific drilling program icdp the 219 m long continental pollen record presented here is based on a well dated composite profile drilled on the so called ahlat ridge in water depth of 360 m encompassing the last 600 000 years it is the longest continuous continental pollen record of the quaternary in the entire near east and central asia obtained to date the glacial interglacial cycles and pronounced interstadials are clearly reflected in the vegetation development based on millennial scale time resolution in general the glacial stadial vegetation is characterized by dwarf shrub steppe and desert steppe whereas the climax vegetation of past interglacials can be described as oak steppe forest similar to the present interglacial in this sensitive semi arid region between the black caspian and mediterranean seas by comparing the lake van pollen record with other western asian and southern european long continental pollen sequences as well as marine and ice core records the regional variability of the climate signals is also discussed

formation of the upper pleistocene terraces of lake van turkey sedimentological and geomorphological studies of terraces around lake van 1647 m provided a preliminary framework for lake level variations the elevations of terraces and past lake level were measured with a differential global positioning system a chronology is developed using 234 u 230 th dating of travertines 39 ar 40 ar dating of pyroclastites and 14 c dating of organic matter facies and stratigraphic correlations identify four transgressions c1 0 c 1 00 c 2 0 and c2 00 each followed by a regression which ended with low lake levels that caused river incision and terrace formation evidence of the oldest transgression c1 0 is found in the uppermost reaches of valleys up to 1755 m an altitude higher than the present lake threshold 1736 m this c1 0 transgression may be related to pyroclastic flows which dammed an outlet located in the western part of the lake basin and which is dated to before 105 ka after 100 ka a second transgression c1 00 reached 1730 1735 m possibly related to a younger ignimbrite flow in association with high water inflow warm and or wetter conditions the two younger transgressions reached 1700 1705 m the first one c2 0 is dated to 26 24 5 cal ka bp and the second one c2 00 to 21 20 cal ka bp available data suggest that the long term lake level changes responded mainly to climate oscillations additional events such as river captures caused by volcanic falls filling valleys tectonism erosion and karstic diversion may have impacted these long term lake level changes copyright 2010 john wiley sons ltd

geochemical and sedimentological control of the magnetic properties of hemipelagic sediments owing to their high sedimentation rates and wide areal extent hemipelagic sediments along continental borderlands are potentially important high resolution recorders of geomagnetic secular variation to assess this possibility we studied suboxic hemipelagic muds from the oregon continental slope and anoxic laminated diatomaceous oozes from the gulf of california these sediments were rapidly deposited with average sedimentation rates of 121 and 135 cm kyr respectively bulk sediment sedimentological and geochemical analyses indicate that the two areas represent contrasting depositional regimes the remanence in both environments resides in fine grained magnetite particles although minor amounts of hematite were observed in the topmost gulf of california sediments despite first order differences the sediments from both areas show similar downcore patterns of systematic increases in solid sulfur mainly as pyrite dramatic decreases in natural nrm anhysteretic and isothermal remanent magnetization intensities and accompanying shifts in the magnetic stabilities these changes are consistent with reduction and dissolution of the ferrimagnetic iron oxides with depth due to early diagenesis of organic matter the magnetic grain size distribution first appears to rapidly coarsen downcore as the smallest and most abundant grains are removed then slowly grows finer as the remaining particles dissolve no evidence was observed for authigenic formation of magnetite provided sufficient concentration and stability of the detrital magnetic particles paleomagnetic directions can survive this dissolution diagenesis however relative paleointensity determinations based on normalization of nrm by concentration in related parameters will give erroneous estimates of paleofield behavior in such diagenetically altered sediments

impact of volcanism on the evolution of lake van ii temporal evolution of explosive volcanism of nemrut volcano eastern anatolia during the past ca 0 4ma thirty two new single crystal ages document 400 000 years of widespread explosive volcanism of historically active nemrut volcano towering over huge alkaline lake van eastern anatolia the dated deposits were selected to monitor the volcanic and compositional evolution of nemrut volcano through time and thus to provide a rigorous temporal framework for the tephra record of the paleovan drilling project tephra samples were taken from large volume deposits or those that occur in medial to distal localities well exposed stratigraphic sections or from the initial phase of an eruptive sequence mainly fallout deposits were chosen because most ignimbrites show more complex and corroded feldspar populations owing to compositional zoning and magma mixing moreover fallout deposits held the promise to be more clearly identifiable with and correlatable to 300 tephra layers in the paleovan drill cores even though commonly in amounts marginal or insufficient in thickness to allow well supported single crystal dating the crystals dated are dominantly anorthoclase the main phenoctyst phase in the trachytic to rhyolitic slightly to strongly peralkaline nemrut magmas ages obtained so far range from ca 400 ka to ca 30 ka for nemrut volcano the causes of significant changes in the frequency volume and composition of tephra layers per unit time are discussed in terms of external erosion climate changes geodynamic factors and internal forcing changes in magma supply and composition and incubation periods preceding large volume rhyolitic eruptions for example the low frequency of tephra layers deposited prior to ca 200 ka may be due to low explosive activity severe erosion between mis 9 and mis 11 or both nevertheless the overall frequency of explosive eruptions appears to have increased during the past ca 200 ka we also recognize a slight peak in explosive eruptions during warm periods e g mis 5 and mis 7 and speculate on lithospheric unloading triggering increased partial melting or magma reservoir unloading following massive glacier melting the ages of 5 dated ignimbrites span ca 250 000 years suggesting that nemrut volcano went through a polycyclic evolution with multiple caldera collapses and major pyroclastic flow eruptions the oldest dated so far as 265 ka the widely held view of the impressive nemrut caldera now dated to have formed at ca 30 ka as the main paroxysmal event during the evolution of the volcano is no longer tenable distinct and coherent compositional characteristics especially in trace element concentrations characterize several groups of trachytic tephras we speculate that the growth of nemrut volcano caused the isolation of the lake van basin on account of their mineralogical anorthoclase hedenbergite fayalite aenigmatite and alkalic chemical compositions and large volume dated nemrut fallout tephras are likely to represent excellent markers in lakes and other sites of paleoclimatological or archeological interest in neighboring countries to the northeast of lake van as far as the caspian sea in what may be called the east anatolian tephra province

the rock magnetic signal of climate change in the maar lake sequence of lac st front france summary rock magnetic properties of the maar lake sediments of lac st front massif central france reflect environmental changes during the last climatic cycle high magnetic concentrations are measured in the sediments deposited under glacial climatic conditions while lower concentrations correspond with more temperate climatic periods low and high temperature measurements indicate that the remanence is carried by titanium poor magnetite however some maghemite and haematite is present in sediments deposited under temperate conditions normalized intensities and coercivities of the anhysteretic remanent magnetization arm are clearly higher for the sediments deposited during the temperate climatic periods of the eemian st germain i ii and mid glacial than for glacial sediments but other magnetic parameters hardly differ between these groups due to slight differences in magnetic composition and possible effects of grain interactions it is not straightforward to relate this different arm behaviour to magnetic grain size variations for the holocene sediments rock magnetic parameters indicate a larger grain size this trend is also suggested by granulometric experiments with an optical laser granulometer dissolution of smaller grains is the most likely explanation for this larger grain size changes in magnetic composition and grain size are extremely limited for the glacial sediments but magnetic concentration varies considerably magnetic concentration maxima in the glacial sediments of lac st front correlate with those of the nearby lac du bouchet thouveny et al 1994 correlating the susceptibility records of these sequences with the 18o record of the grip ice cores thouveny et al 1994 suggests that magnetic concentration maxima may correspond with short cold climatic episodes associated with heinrich events

global changes in intensity of the earth s magnetic field during the past 800kyr recent advances in palaeomagnetic and dating techniques have led to increasingly precise records of the relative intensity of the earth s past magnetic field at numerous field sites the compilation and analysis of these records can provide important constraints on changes in global magnetic field intensity and therefore on the earth s geodynamo itself a previous compilation for the past 200 kyr integrated 17 marine records into a composite curve1 with the geomagnetic origin of the signal supported by an independent analysis of 10be production made on different cores2 the persistence of long term features in the earth s magnetic intensity or the existence of long term periodic changes cannot however be resolved in this relatively short time span here we present the integration of 33 records of relative palaeointensity3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 into a composite curve spanning the past 800 kyr we find that the intensity of the earth s dipole field has experienced large amplitude variations over this time period with pronounced intensity minima coinciding with known excursions in field direction reflecting the emergence of non dipole components no stable periodicity was found in our composite record and therefore our data set does not support the hypothesis that the earth s orbital parameters have a direct and strong influence on the geodynamo

800 000 years of abrupt climate variability we constructed an 800 000 year synthetic record of greenland climate variability based on the thermal bipolar seesaw model our greenland analog reproduces much of the variability seen in the greenland ice cores over the past 100 000 years the synthetic record shows strong similarity with the absolutely dated speleothem record from china allowing us to place ice core records within an absolute timeframe for the past 400 000 years hence it provides both a stratigraphic reference and a conceptual basis for assessing the long term evolution of millennial scale variability and its potential role in climate change at longer time scales indeed we provide evidence for a ubiquitous association between bipolar seesaw oscillations and glacial terminations throughout the middle to late pleistocene

diagenesis in anoxic sediments from the california continental borderland and its influence on iron sulfur and magnetite behavior solid phase and pore water profiles of compounds containing iron and sulfur have been determined by wet chemical magnetic and x ray diffraction techniques in three california continental borderland basins the observed profiles have been fit by simple reaction diffusion models in order to determine reaction rates and constrain budgets for iron and sulfur more than 95 of the solid phase reduced sulfur is pyrite and down core profiles are well fit by a model in which net sulfate reduction rates decrease exponentially with depth net sulfate reduction rates determined from models fit to solid phase reduced sulfur measurements and pore water sulfate profiles yield results that are consistent depth integrated sulfate reduction rates for modern sediments in san pedro santa catalina and san nicolas basins are 11 4 6 3 and 6 3 8 8 mol cm 2yr 1 respectively measurements of solid phase iron species indicate that surficial sediments are enriched in easily reducible ferric oxyhydroxides the enrichment is maintained by a combination of oxidation of fe2 diffusing upward from underlying anoxic sediments as well as input of fresh sediment enriched in ferric oxyhydroxides the three primary sources for iron converted to pyrite and the sequence in which they are utilized are ferric oxyhydroxides magnetite and other crystalline oxides and exchangeable iron in phyllosilicates the majority 50 80 of the iron converted to pyrite is from the silicates and budgetary calculations indicate the amount of iron released from san pedro basin silicates agrees within 35 with the amount of magnesium removed from pore water to solid phases fe2 is enriched in near surface pore waters because rates of dissolved iron production by oxyhydroxide reduction exceed rates of sulfate reduction and pyrite formation at depth pore waters are sulfidic because rates of sulfate reduction exceed rates of iron release from silicates sulfide produced at depth diffuses upward until it reaches sediments with available iron causing a step like increase in solid phase sulfur concentration over 90 of the magnetite present in surficial sediments is dissolved at depth due to reaction with h2s a model is developed to predict the depth at which magnetite dissolution should occur based on sulfate reduction rates and the flux of ferric oxyhydroxides the results of this model predict the onset of dissolution at depths of 5 40 cm in different basins and agree well with the observed depths of magnetite dissolution

climate variations in europe over the past 140 kyr deduced from rock magnetism rapid shifts in climate during the last glacial are now well documented particularly from the oxygen isotope records of the two greenland ice cores grip1 2 and gisp23 in the grip record1 2 these climate events are also seen during the preceding eemian interglacial which may be an analogue for the future climate warmed by the greenhouse effect but these shifts are not found in the eemian section of the gisp2 core3 casting doubt on whether the rapid shifts in the grip oxygen isotope record really do represent a climate signal here we present magnetic susceptibility pollen and organic carbon records from maar lake deposits in the massif central france these data provide an independent record of past climate and we find that they correlate well with the ice core records during the last glacial during the eemian two rapid cooling events seen in our record also correlate with those seen in the grip ice core supporting the idea that rapid climate change did occur in the eemian interglacial and demonstrating that it extended to continental europe

improvements in long core measurement techniques applications in palaeomagnetism and palaeoceanography we report on new developments in the long core measurement techniques using u channels in connection with new small access cryogenic magnetometers with these new instruments u channel samples allow us to measure a wide range of magnetic parameters along entire core length with a spatial resolution and accuracy virtually equivalent to that obtained using discrete cubic samples an additional advantage is that the sediment disturbance when sampling is significantly less when using u channels we present comparisons of results from both continuous and discrete measurements and examine the effectiveness of minimal deconvolution using various techniques examples of continuous measurements of low field susceptibility nrm arm irm hrc from north atlantic deep sea cores show that it is possible to generate logs of combination of parameters related to rock magnetic characteristics of the sediments useful in palaeoceanography in particular the continuous method allows us to rapidly detect core regions with fast changing magnetic parameters useful for correlation between cores and also for understanding changes in palaeo environmental conditions the fast scan also allows us to detect regions of the core where the rock magnetic parameters are suitable or not suitable for palaeomagnetic studies related to changes in the geomagnetic field such as the relative changes in palaeointensity

mineral magnetic proxies of erosion oxidation cycles in tropical maar lake sediments lake tritrivakely madagascar paleoenvironmental implications abstract mineral magnetic measurements were performed on the upper 16 m of five piston cored sedimentary sequences from lake tritrivakely madagascar ams 14 c dating and correlation of the five magnetic susceptibility records allowed establishment of a composite sedimentary record of the last 46 kyr our data suggest that mineral magnetic changes result from changes in concentration of strongly ferrimagnetic terrigenous minerals and from preservation dissolution cycles of detrital iron oxides primarily high coercivity fe iii phases such as hematite in alternately oxic and anoxic depositional environments high coercivity iron oxide phases are restricted to stratigraphic intervals that are interpreted to represent dry periods with oxic conditions comparison with other paleoenvironmental proxies pollen total organic carbon lithology suggests that the sediments record relatively humid conditions before 22 kyr bp and relatively dry conditions during the last glacial maximum lgm and the early holocene such results contrast with the previous observations of relatively dry glacial conditions and humid mid holocene conditions in the summer rainfall area of east and se africa

the annual particle cycle in lake van turkey abstract the varved sediments of lake van provide a high quality continental archive of seasonal to decadal scale climate variability in order to read the natural record modern varve formation was studied on the basis of 1 remotely sensed total suspended matter tsm rs concentrations 2 time series of particle flux and water temperatures and 3 turbidity temperature and oxygen profiles tsm rs validated by contemporaneous water column sampling shows great temporal and lateral variations whitings and turbidity plumes from 2006 to 2009 sequential sediment traps recorded high particle fluxes during spring and fall medium fluxes during summer and almost zero flux during winter the mean total mass flux of 403 mg m 2 day 1 comprised 33 seasonally up to 67 calcium carbonate 7 aquatic organic matter 6 biogenic opal and 54 detrital minerals the caco 3 fluxes are controlled by river discharge precipitation and snowmelt during spring by high productivity during summer and by river discharge precipitation before snowfall starts and mixing during fall in november 2007 an anomalously high caco 3 flux occurred as a result of a warm water surface supersaturated with calcite coinciding with an anomalous runoff event the results demonstrate that the couplets of light and dark laminae in the short sediment cores are true varves representing spring summer fall and winter conditions respectively consequently varve formation can be linked to the seasonal climate pattern providing a calibration that can be used to interpret the partially varved paleo record of lake van and related environmental processes

deconvolution of u channel paleomagnetic data near geomagnetic reversals and short events 1 the deconvolution scheme of oda and shibuya 1996 designed for half core data from the pass through magnetometer aboard the joides resolution has been adapted for treatment of u channel data the program was tested using u channels from ocean drilling program odp site 1090 a significant increase in resolution of the u channel data can be achieved by deconvolution resulting in data comparable with that obtained by continuous discrete sampling large amplitude changes of the magnetization vector revealed by the deconvolution treatment are in good agreement with the results obtained on discrete samples extracted from the same u channels application of this procedure to u channel data from odp sites 983 and 984 over a short time interval around 1 255 ma permitted enhanced definition of the so called bjorn geomagnetic event

magnetite dissolution in siliceous sediments 1 magnetite dissolution and consequent loss of magnetization is widely observed in reducing sedimentary environments where the decrease in eh ph values with depth is driven by bacterially mediated degradation of organic carbon we have observed low magnetizations in sediments with elevated pore water silica concentrations that arise from diagenesis of biogenic silica and or silicic volcanic ash these depletions in magnetization are greater than can be accounted for by dilution with magnetite poor sediments and suggest that postdepositional destruction of magnetite has occurred biosiliceous sediments usually also contain elevated concentrations of organic carbon which makes it difficult to separate organic carbon related magnetite dissolution from other possible mechanisms for magnetite dissolution however the extent of magnetite dissolution in the sedimentary sequences that we have studied is not obviously related to the redox state of the environment this suggests that other mechanisms might have given rise to magnetite dissolution in these siliceous sediments thermodynamic calculations indicate that magnetite is unstable under conditions of elevated dissolved silica concentrations and appropriate eh ph conditions and predict that magnetite will break down to produce iron bearing smectite a survey of magnetic susceptibility and pore water geochemical data from widely distributed ocean drilling program sites supports this observed link between high dissolved silica concentrations and low magnetic susceptibilities this observed link also holds for environments with low biogenic silica productivity and low organic carbon content but with high interstitial silica concentrations due to dissolution of silicic volcanic ashes dissolution of magnetite is therefore predicted to be a common feature of siliceous sedimentary environments

magnetite diagenesis in marine sediments from the oregon continental margin the magnetochemistry of sediments from the oregon continental margin is examined to determine the effects of iron sulfur diagenesis on the paleomagnetic record magnetic mineral dissolution and transformation into iron sulfides are a common feature in these suboxic to anoxic lutites these processes are evidenced in rapid decreases in natural remanent magnetization intensities and stabilities systematic changes in other rock magnetic properties and increases in solid phase sulfur concentrations with depth hysteresis measurements are used to evaluate downcore changes in magnetite concentration and grain size magnetite abundances decrease downcore from initial values of about 0 1 and nominal grain diameters lie within a narrow pseudosingle domain range of 0 08 to 0 6 m a first order surface area reaction model da dt ka is proposed to explain the magnetite dissolution mechanism where a is the total magnetite surface area and k is the rate constant the solution of this equation predicts that the surface area and concentration decrease exponentially and the concentration in addition depends on grain size application of this model in two cores where grain size varies with depth successfully explains the downcore profiles of both concentration and surface area despite extensive magnetite destruction magnetic directions in such sediments appear to reliably record long wavelength trends of the geomagnetic field

interpreting noble gas concentrations as proxies for salinity and temperature in the world s largest soda lake lake van turkey in this work we present noble gas concentration profiles measured in the water column and in the sediment pore water of the earth s largest soda lake lake van eastern anatolia turkey the concentrations of noble gases in particular ar kr and xe in the water body deviate significantly from the expected equilibrium concentrations calculated from the in situ temperature and salinity using existing solubility functions for seawater the specific chemical composition of the water of the soda lake seems to be responsible for the observed deviations our measurements allow the identification and quantification of salinity factors that can be applied to correctly calculate the noble gas equilibrium concentrations for the lake these salinity factors provide a solid and robust empirical basis for the interpretation of noble gas concentration signals measured in the sediment pore water of lake van in terms of palaeosalinity and palaeotemperature

padm2m a penalized maximum likelihood model of the 0 2 ma palaeomagnetic axial dipole moment summary we present a new time varying model for palaeomagnetic axial dipole moment padm for the past 2 myr and compare it with earlier virtual axial dipole moment vadm reconstructions which have been based on stacking and averaging scaled relative palaeointensity records the padm is derived from both absolute and relative palaeointensity data and constructed using a new penalized maximum likelihood pml approach to recover a cubic b spline representation of axial dipole field variations on million year timescales the pml method is explicitly intended to reduce bias in estimating the true axial dipole moment that arises in average vadm reconstructions we apply the pml method to a set of 96 032 published data 1800 palaeointensities from igneous rocks 3300 archaeointensities and 86 relative palaeointensity time series of variable lengths and resolutions two models are discussed padm2mp is a trial model based on a subset of the nine longest available sedimentary records padm2m uses a comprehensive data set 76 records 81 446 data 10 records were eliminated and is our preferred model padm2m has a lower mean than existing vadm reconstructions but shows similarities in long period variability some differences in timing amplitude and resolution of certain features can be attributed to variations in age assignments others result from our more comprehensive data set and a reduction in bias attributable to pml modelling padm2m has an average axial dipole moment over 0 2 ma of 5 3 1022 am2 with a standard deviation of 1 5 1022 am2 the brunhes chron average 6 2 1022 am2 is higher than for earlier epochs of matuyama 4 8 1022 am2 as seen in some previous studies the power spectrum for our model agrees with previous estimates of the global palaeomagnetic power spectrum for frequencies up to about 102 myr 1 we see no distinctive evidence in the power spectrum for orbital forcing of geodynamo behaviour

dynamics of the last four glacial terminations recorded in lake van turkey abstract a well dated suite of lake van climate proxy data covering the last 360 ka documents environmental changes over 4 glacial interglacial cycles in eastern anatolia turkey the picture of cold and dry glacials and warm and wet interglacials emerging from pollen organic carbon authigenic carbonate content elemental profiling by xrf and lithological analyses is inconsistent with classical interpretation of oxygen isotopic composition of carbonates pointing to a more complex pattern in lake van region detailed analysis of glacial terminations allows for the constraining of a depositional model explaining different patterns observed in all the proxies we hypothesize that variations in relative contribution of rainfall snowmelt and glacier meltwater recharging the basin have a very important role for all sedimentary processes in lake van lake level of glacial lake van predominantly fed by snowmelt was low the water column was oxic and carbonates precipitating in the epilimnion recorded the light isotopic signature of inflow during terminations increasing rainfall and significant supply of mountain glaciers meltwater contributed to lake level rise increased rainfall enhanced density gradients in the water column and hindered mixing leading to development of bottom water anoxia carbonates precipitating during terminations show large fluctuations in their isotopic composition full interglacial conditions in lake van are characterized by high or slowly falling lake level rainfall and snowmelt feed the lake but due to re established mixing the isotopic composition of authigenic carbonates is heavier and closer to that of evaporation influenced lake water than that of runoff representing snowmelt and atmospheric precipitation

south atlantic and north atlantic geomagnetic paleointensity stacks 0 80 ka implications for inter hemispheric correlation recent coring of high deposition rate atlantic sediments has led to the development of north atlantic napis and south atlantic sapis geomagnetic paleointensity stacks the sapis stack comprises five records from the sub antarctic south atlantic 41 471s 6 101e four are from piston cores collected during the ocean drilling program odp leg 177 site survey cruise earth planet sci lett 175 2000 145 the other is odp site 1089 leg 177 j geophys res 2001 submitted for publication all but one 4 pc03 of the sapis cores have oxygen isotope records which are used in conjunction with lithologic and geomagnetic variability to derive an optimized correlation to site 1089 the site 1089 age model is derived by mapping the benthic and planktic isotope data to those from nearby core rc11 83 which has 14 calibrated radiocarbon ages in the 11 41 ka interval below this level the chronology is derived by matching the site 1089 benthic oxygen isotope data to the specmap stack the napis stack comprises six records from a wide area of the north atlantic philos trans r soc ser a 358 2000 1009 correlation between cores was based on marine isotopic stage boundaries augmented by millennial scale features heinrich events and fluctuations in concentration dependent magnetic parameters napis was placed on the gisp2 chronology using the marine to ice core oxygen isotope correlation proposed by voelker et al radiocarbon 40 1998 517 for one of the napis cores in the resulting age model the laschampevent recorded in five of six cores falls in a very narrow o1 kyr age range and coincides with the 10 be and 36 cl peak measured in the ice cores comparison of the two stacks placed on their own independent age models indicates that common millennial scale paleointensity features are preserved although more work is needed to define the true global content of the paleointensity record as well as the precise age of many features it is readily apparent that paleointensity can provide a global correlation tool at a resolution unattainable from isotope data alone r 2002 published by elsevier science ltd

high resolution record of northern hemisphere climate extending into the last interglacial period high resolution record of northern hemisphere climate extending into the last interglacial period

u channel track for susceptibility measurements 1 a lightweight transportable and inexpensive magnetic susceptibility track for u channel samples is described the track utilizes a sapphire instruments 3 3 cm square coil having a response function of shape similar to that of the 2g enterprises u channel magnetometer and a half peak width of 3 cm the instrument has been calibrated using a u channel standard made of manganese dioxide the software incorporates automated track control and measurement drift correction susceptibility measurements on this system compare favorably with the 45 mm circular bartington loop used for u channel samples at the laboratoire des sciences du climat et de l environnement gif sur yvette france and with data from the whole core susceptibility track aboard the ocean drilling program research vessel joides resolution

mineral magnetism and geomagnetic secular variation of marine and lacustrine sediments from central italy timing and nature of local and regional holocene environmental change abstract sediment core palaeomagnetic and mineral magnetic records from two crater lakes in central italy and from the western margin of the adriatic sea have been used to evaluate local and regional responses to holocene environmental change in all cores sediment magnetism reflects the interplay between catchment material and the in situ production of bacterial magnetite magnetotactic bacteria in the lakes the earliest holocene sediments record a waning catchment input that we attribute to rising lake levels and increased tree cover in the catchment from 9000 to 5000 yr bp both lakes become anoxic a consequence of water mass stratification driven by high lake levels bottom water anoxia also developed in the adriatic with sapropel s1 produced between 9000 and 7000 yr bp subsequently the lake and adriatic mineral magnetic records show evidence for increased catchment delivery consistent with pollen evidence for bronze age deforestation in the lakes this evidence is first recorded at 4300 yr bp and a number of distinct clearance events are recorded in comparison at adriatic site rf93 30 lithogenic input increases abruptly at 3500 yr bp and is followed by a slowly changing record of waxing and waning sediment delivery inter site comparisons of palaeomagnetic data point to a possible link between the magnitude of the bacterial magnetite component and the recorded magnetic inclination the sites are at near identical latitudes and have similar sediment accumulation rates but the adriatic sites have a core average magnetic inclination that is some 10 steeper than the lake average values we suggest that the large dipole moment of the magnetosome chains which in life produce the passive alignment of the bacterium along the local geomagnetic field line produce a more faithful albeit smoothed record of the geomagnetic field

mid holocene palaeoceanography of the northern south china sea using coupled fossil modern coral and atmosphere ocean gcm model 1 high resolution records of past environments of the south china sea scs could provide important information to better understand the mechanisms of el nino southern oscillation enso and east asian monsoon evolution since scs is located between pacific ocean and eurasian continent scs plays a key role as the moisture source area of monsoon precipitation that affects the terrestrial climate of asia fossil and modern corals were obtained from south china sea scs to study changes in oceanographic conditions when the northern hemisphere experienced perihelion during the early to mid holocene and thermal contrast between scs and the asian continent was larger the fossil coral is 6600 years old and xrd and sem investigations confirmed pristine nature of this sample oxygen isotope measurement of modern coral yielded an average value of ca 6 whereas the fossil coral showed ca 5 5 given that previously reported alkenone sst thermometry and foraminiferal sst reconstruction indicate little changes in sst 0 5 c throughout the holocene in scs we consider the possibility of changes in 18o of seawater to be due to local sea surface salinity sss coral data from the present study 6600 years old coral as well as previously published record 4400 years old showed higher sss during the mid holocene coral data were then compared with the coupled ocean atmosphere gcm miroc3 2 higher sss during the mid holocene time was also seen in aogcm experiments we observed northward shift of inter tropical convergent zone itcz in the experiments that produced increased precipitation on the asian continent the cause of increase in salinity was therefore due to less precipitation in scs and increased continental precipitation inland of asia

structural and geochronological studies on the liba goldfield of the west qinling orogen central china the liba goldfield located to the northeast of the zhongchuan granite in the west qinling orogen wqo of mainland china contains the largest known gold resource of 2 8 moz in the zhongchuan area devonian metasedimentary rocks host the structurally controlled gold mineralization which is associated with silica sericite chlorite carbonate alteration two major styles of mineralization occurred at the goldfield which are disseminated sediment hosted and quartz vein hosted types pyrite arsenopyrite and arsenian pyrite are major gold carriers and gold also occurs as native gold grains and electrum spatially associated with the sulfides numerous felsic intermediate dykes have a similar structural control as the mineralization and their contacts with host rocks are recognized as favorable zones for mineralization detailed fieldwork in conjunction with geochronological studies has helped to define the deformation history and gold metallogenesis of the goldfield three major phases of deformation have been recognized in the zhongchuan area the first deformation d1 event was compressional in broadly a n s orientation the second d2 event was also compressional and orientated in a ne sw direction and the third d3 event was post mineralization and was associated with the emplacement of barren calcite and anhydrite veins compression related to d2 is the key process that controlled the distribution of igneous dykes and gold mineralization in the liba goldfield both igneous and hydrothermal fluids preferentially focused along dilational jogs under local trans extension which took place during the late stage of d2 precise dating with high resolution ion microprobe shrimp u pb on zircon and 40ar 39ar on muscovite biotite hornblende and plagioclase of crosscutting pre mineralization granitic porphyry and diorite dykes have constrained the mineralization age to after ca 227 ma 40ar 39ar analysis of minerals formed in hydrothermal alteration zones associated with gold mineralization indicates that there was a widespread ca 216 ma hydrothermal event that affected almost all lithologies in the area this detailed investigation is the first study to tightly constrain the timing of gold mineralization in the wqo the broadly overlapping timing and similar structural control of the mineralization and igneous dykes show a promising correlation which could be potentially used to map this late triassic gold mineralization event in the wqo

deep sea sediment records of the laschamp geomagnetic field excursion 41 000 calendar years before present 1 we have recovered two new high resolution paleomagnetic records of the laschamp excursion 41 000 calendar years b p from deep sea sediments of the western north atlantic ocean the records document that the laschamp excursion was characterized locally by 1 declination changes of 120 2 inclination changes of more than 140 3 1200 year oscillations in both inclination and declination 4 near 90 out of phase relationships between inclinations and declinations that produced two clockwise loops in directions and virtual geomagnetic poles vgps followed by a counterclockwise loop 5 excursional vgps during both intervals of clockwise looping 6 magnetic field intensities less than 10 of normal that persisted for almost 2000 years 7 marked similarity in excursional directions over 5000 km spatial scale length and 8 secular variation rates comparable to historic field behavior but persisting in sign for hundreds of years all of these features with the exception of anomalously large directional amplitude are consistent with normal magnetic field secular variation comparison of our laschamp excursion paleomagnetic records with other late quaternary excursion records suggests that there is a group of excursions which we term class i which have strikingly similar patterns of field behavior and likely share a common cause as part of the overall core dynamo process three general models of secular variation are described that can qualitatively produce class i excursions on the basis of these observations we conclude that class i excursions epitomized by the laschamp excursion are more closely related to normal secular variation and are not necessarily a prelude to magnetic field reversal

climatically induced lake level changes at lake van turkey during the pleistocene holocene transition sediment core k10 from lake van eastern turkey provides a continuous varve record back to 14 570 calendar years b p before present 1950 the longest unbroken and non floating lake varve sequence yet described the underlying sediment is unvarved and hard changes in the aragonite calcite ratio the presence of protodolomite and magnesite in certain profile sections the annual record of the sedimentation rate the water content of the sediment the concentrations of organic carbon and opal and the texture of the sediments from this core provide a record of the lake level history the new chronology enabled us to redate the old pollen profile van zeist and woldring 1978a b and to establish an accurate timescale for the reconstructed lake level change carbon 14 dates show that the highest lake terrace corresponds to high lake level at around 19 000 years b p during the last glacial 70 m above its present level before 15 000 years b p the lake must have been completely dry marking a reduction of lake level by 500 m in maximum 4000 years beginning at 14 600 years b p and ending at 12 040 years b p the lake level recovered by 250 m to fall again during the next 1400 years by 10 600 years b p the lake began to rise and reached following another regression between 9000 and 8100 years b p the holocene highstand by about 7500 years b p dropping to today s level at about 3000 years b p

odp site 1063 bermuda rise revisited oxygen isotopes excursions and paleointensity in the brunhes chron an age model for the brunhes chron of ocean drilling program odp site 1063 bermuda rise is constructed by tandem correlation of oxygen isotope and relative paleointensity data to calibrated reference templates four intervals in the brunhes chron where paleomagnetic inclinations are negative for both u channel samples and discrete samples are correlated to the following magnetic excursions with site 1063 ages in brackets laschamp 41 ka blake 116 ka iceland basin 190 ka pringle falls 239 ka these ages are consistent with current age estimates for three of these excursions but not for pringle falls which has an apparent age older than a recently published estimate by 28 kyr for each of these excursions termed category 1 excursions virtual geomagnetic poles vgps reach high southerly latitudes implying paired polarity reversals of the earth s main dipole field that apparently occurred in a brief time span 2 kyr in each case several times shorter than the apparent duration of regular polarity transitions in addition several intervals of low paleomagnetic inclination low and negative in one case are observed both in u channel and discrete samples at 318 ka mis 9 412 ka mis 11 and in the 500 600 ka interval mis 14 15 these category 2 excursions may constitute inadequately recorded category 1 excursions or high amplitude secular variation

rock magnetism of late neogene and pleistocene deep sea sediments relationship to sediment source diagenetic processes and sediment lithology we use bivariate scatter plots to illustrate variations in selected rock magnetic properties low field susceptibility anhysteretic and isothermal remanence of late neogene and pleistocene deep sea sediments from 16 sites in the arctic ocean north atlantic equatorial atlantic and north pacific ocean and the arabian sea our intention is to examine the ability of the rock magnetic properties to differentiate the sediments according to factors such as lithology geographical area and the dominant mode of terrigenous sedimentation which at these sites is via ice rafting via bottom currents or via eolian processes overall correlations between sediment magnetic properties and gross lithology is poor and factors such as the source and transport path of terrigenous sediment and detrital magnetic minerals together with the action of reductive diagenetic processes are the major controls on the magnetic properties on the bivariate scatter plots sites with major ice rafted contributions tend to have high sedimentary ferrimagnetic mineral concentrations relatively coarse ferrimagnetic grain sizes and scattered sample point distributions in contrast sites where we infer significant bottom current supply of terrigenous material have tightly grouped sample point distributions carbonate sediments in which the terrigenous component is supplied by eolian processes tend to have a broad range of magnetic mineral concentration caused by glacial interglacial fluctuations in carbonate accumulation and eolian activity sediments containing significant volcanogenic material have high concentrations of relatively coarse grained ferrimagnetic material reductive diagenesis is a significant determinant of sediment magnetic properties in high productivity areas and has the effect of preferentially removing the fine grained ferrimagnetic fraction causing a coarsening of the ferrimagnetic grain size distribution and a rise in the antiferromagnetic ferrimagnetic ratio

sedimentary evolution and environmental history of lake van turkey over the past 600 000 years the lithostratigraphic framework of lake van eastern turkey has been systematically analysed to document the sedimentary evolution and the environmental history of the lake during the past ca 600 000 years the lithostratigraphy and chemostratigraphy of a 219 m long drill core from lake van serve to separate global climate oscillations from local factors caused by tectonic and volcanic activity an age model was established based on the climatostratigraphic alignment of chemical and lithological signatures validated by 40ar 39ar ages the drilled sequence consists of ca 76 lacustrine carbonaceous clayey silt ca 2 fluvial deposits ca 17 volcaniclastic deposits and 5 gaps six lacustrine lithotypes were separated from the fluvial and event deposits such as volcaniclastics ca 300 layers and graded beds ca 375 layers and their depositional environments are documented these lithotypes are i graded beds frequently intercalated with varved clayey silts reflecting rising lake levels during the terminations ii varved clayey silts reflecting strong seasonality and an intralake oxic anoxic boundary for example lake level highstands during interglacials interstadials iii caco3 rich banded sediments which are representative of a lowering of the oxic anoxic boundary for example lake level decreases during glacial inceptions iv caco3 poor banded and mottled clayey silts reflecting an oxic anoxic boundary close to the sediment water interface for example lake level lowstands during glacials stadials v diatomaceous muds were deposited during the early beginning of the lake as a fresh water system and vi fluvial sands and gravels indicating the initial flooding of the lake basin the recurrence of lithologies i to iv follows the past five glacial interglacial cycles a 20 m thick disturbed unit reflects an interval of major tectonic activity in lake van at ca 414 ka bp although local environmental processes such as tectonic and volcanic activity influenced sedimentation the lithostratigraphic pattern and organic matter content clearly reflect past global climate changes making lake van an outstanding terrestrial archive of unprecedented sensitivity for the reconstruction of the regional climate over the last 600 000 years

reactive iron in marine sediments abstract a combined field laboratory study has been undertaken to explore the mineralogy concentrations and reactivity towards sulfide of iron in marine sediments also considered is the importance of bacterial fe liberation in regulating pore water chemistry two contrasting marine environments are included one is the relatively fe poor foam site and the other is the fe rich sediment of the subaqueous mississippi delta results show that oxide minerals are the most important fe phases in early diagenetic pyrite formation however viewed separately lepidocrocite and ferrihydrite are more reactive towards sulfide than goethite and hematite when fe oxides are present in relatively high concentrations dissolved sulfide is nearly absent from sediment pore waters with concomitant high concentrations of dissolved fe even in the presence of active sulfide production by sulfate reduction a combination of experimental results and diagenetic modelling shows that in some sediments pore water fe finds it origin in the bacterial reduction of iron oxides this seems the case even though greater amounts of fe are reduced by reaction of sulfide with iron oxides it appears that distinct microenvironments may exist in marine sediments where in one microenvironment sulfide reacts with fe oxides locally precipitating fe sulfide minerals in another fe reduced and solubilized by microorganisms migrates freely into solution

dissolution and pyritization of magnetite in anoxie marine sediments concentrations of magnetite were determined with depth in sediments of varying h2s content taken from long island sound foam nwc and sachem sites and from a site in the rapidly depositing subaqueous portion of the mississippi delta for the three long island sound sites dissolution of magnetite during burial is clearly demonstrated and for all four sites the rate of magnetite dissolution is proportional to the concentration of dissolved pore water sulfide by combining magnetite depth distributions with sedimentation rate data and measurements of dissolved sulfide we find that magnetite dissolution is well described by the following rate law dcmagdt 1 1 10 5c0 5bcmagamag where cmag is the concentration of magnetite grams per gram of sediment cs is the concentration of dissolved sulfide mm and amag is the specific surface area of magnetite in the sediment cm2 per gram of magnetite this equation means that for a typical range of magnetite surface areas and dissolved sulfide concentrations the half life of magnetite in anoxic marine sediments ranges from about 50 to 1000 years sem observations of magnetite grains from the different sediment sites reveal that magnetite dissolution may be accompanied by extensive replacement by pyrite this only occurs if magnetite is in contact with high concentrations of h2s 1 mm for relatively long periods of time several hundred years with low concentrations of h2s 1 mm magnetite dissolution occurs without identifiable pyrite replacement we suggest that this feature of magnetite diagenesis may prove to be a useful paleosulfide indicator

diagenesis of magnetic minerals in recent haemipelagic sediments rapidly deposited sediments from marine and lake environments are being used increasingly to study decadal to millennial fluctuations in the earth s magnetic field the objectives are to gain more fundamental understanding of the geodynamo and to establish a new dating technique for sediments while lacustrine sections are generally restricted to temperate latitude glacial lakes 20 000 yr old rapidly deposited marine sediments along continental margins potentially offer continuous high resolution yet long term records of geomagnetic secular variation however to interpret the sedimentary magnetic record accurately geochemical processes that affect the reliability of the magnetic signal must be understood we now report downcore magnetic profiles from undisturbed kasten cores taken in rapidly deposited laminated sediments from the gulf of california and in bioturbated haemipelagic muds on the oregon continental slope which give apparently reliable directions but show dramatic decreases in the intensities of natural nrm and artificial arm irm remanences with depth downcore porewater and solid sulphur analyses show concave down decreases in porewater sulphate and systematic increases in pyrite and metastable monosulphides the maximum curvature of the sulphide profile occurs directly below the high magnetization zone combined with other compositional and mineralogical analyses these data suggest that due to oxidative decomposition of organic matter magnetites and other iron oxides become progressively reduced and subsequently sulphidized and pyritized with depth iron reduction seems to occur before sulphide formation changes in magnetic stability parameters are consistent with selective dissolution of the finer sized grains causing downcore coarsening of the magnetic fraction

dynamics of the laschamp geomagnetic excursion from black sea sediments abstract investigated sediment cores from the southeastern black sea provide a high resolution record from mid latitudes of the laschamp geomagnetic polarity excursion age constraints are provided by 16 ams 14c ages identification of the campanian ignimbrite tephra 39 28 0 11 ka and by detailed tuning of sedimentologic parameters of the black sea sediments to the oxygen isotope record from the greenland ngrip ice core according to the derived age model virtual geomagnetic pole vgp positions during the laschamp excursion persisted in antarctica for an estimated 440 yr making the laschamp excursion a short lived event with fully reversed polarity directions the reversed phase centred at 41 0 ka is associated with a significant field intensity recovery to 20 of the preceding strong field maximum at 50 ka recorded field reversals of the laschamp excursion lasting only an estimated 250 yr are characterized by low relative paleointensities 5 relative to 50 ka the central fully reversed phase of the laschamp excursion is bracketed by vgp excursions to the sargasso sea 41 9 ka and to the labrador sea 39 6 ka paleomagnetic results from the black sea are in excellent agreement with vgp data from the french type locality which facilitates the chronological ordering of the non superposed lavas that crop out at laschamp olby in addition vgps between 34 and 35 ka reach low northerly to equatorial latitudes during a clockwise loop inferred to be the mono lake excursion

paleovan international continental scientific drilling program icdp site survey results and perspectives lake van is the fourth largest terminal lake in the world volume 607 km 3 area 3570 km 2 maximum depth 460 m extending for 130 km wsw ene on the eastern anatolian high plateau turkey the sedimentary record of lake van partly laminated has the potential to obtain a long and continuous continental sequence that covers several glacial interglacial cycles ca 500 kyr therefore lake van is a key site within the international continental scientific drilling program icdp for the investigation of the quaternary climate evolution in the near east paleovan as preparation for an icdp drilling campaign a site survey was carried out during the past years we collected 50 seismic profiles with a total length of similar to 850 km to identify continuous undisturbed sedimentary sequences for potential icdp locations based on the seismic results we cored 10 different locations to water depths of up to 420 m multidisciplinary scientific work at positions of a proposed icdp drill site included measurements of magnetic susceptibility physical properties stable isotopes xrf scans and pollen and spores this core extends back to the last glacial maximum lgm a more extended record than all the other lake van cores obtained to date both coring and seismic data do not show any indication that the deepest part of the lake tatvan basin ahlat ridge was dry or almost dry during past times these results show potential for obtaining a continuous undisturbed long continental palaeoclimate record in addition this paper discusses the potential of paleovan to establish new results on the dynamics of lake level fluctuations noble gas concentration in pore water of the lake sediment history of volcanism and volcanic activities based on tephrostratigraphy and paleoseismic and earthquake activities c 2009 elsevier ltd all rights reserved