circulation mixing and production of antarctic bottom water abstract the antarctic source of bottom water to the abyssal layer of the world ocean is examined as well as its large scale flow pattern and ultimate entrainment rate into the deep water above we make use of the available high quality station data in the southern ocean to construct bottom maps of neutral density and mean property maps including chlorofluorocarbon cfc for the abyssal layer underneath a selected neutral density surface the maximum density at the sill depth of drake passage is used to distinguish between the voluminous deep water mass that is a continuous component of the antarctic circumpolar current from the relatively denser bottom water originated along the antarctic continental margins based on water density antarctic bottom water aabw is defined here generically to include all volumes of non circumpolar water of antarctic origin over the shelf regime multiple localized sources of specific aabw types contribute to the abyssal layer of the adjacent antarctic basins characteristics of these dense bottom waters reflect closely those observed on the parent shelf water mass spreading paths of newly formed deep and bottom waters over the slope regime and their subsequent oceanic circulation patterns are analyzed on the basis of global property maps for the aabw layer interior mixing and interbasin exchanges of aabw are deduced from mean characteristic curves following the southern streamline of the antarctic circumpolar current outflow and mixing of aabw from the weddell sea to the argentine basin is depicted using density and cfc distributions of two zonal hydrographic lines recirculation and mixing of deep and bottom waters within the weddell gyre are also detailed using a meridional section along the greenwich meridian the strength of all localized sources of aabw combined is estimated by two independent approaches an estimate of the total production rate of aabw is calculated based on the oceanic cfc budget for the aabw layer offshore of the 2500 m isobath the sum of all downslope inputs of well ventilated bottom water types underneath the top isopycnal must account for the measured cfc content in the bottom layer the resulting total aabw production rate is about 8 sv which is a conservative figure that neglects the loss of cfc bearing waters across the top isopycnal in recent years whereas about 9 5 sv is calculated assuming a well mixed bottom layer making use of their transient nature cfc distributions at the top of the aabw layer indicate that more direct and rapid entrainment of cfc rich bottom waters below occurs over localized areas with relatively strong upwelling rates and enhanced vertical mixing a second more ad hoc but independent oceanic mass budget of the bottom layer is also constructed a typical basin wide rate of deep upwelling of 3 10 7 m s 1 requires 10 sv 1 sv 106 m3 s 1 of newly formed aabw to sink down the slope around antarctica we have also formulated a spatial distribution of deep upwelling on the isopycnal at the top of the aabw it is expressed as a combination of wind topographic and turbulent components which in turn are functions of the isopycnal depth bottom depth and bottom layer thickness this non uniform upwelling field yields about 12 sv of aabw exported across the top isopycnal fortuitously the overall average of upward speed at the top isopycnal 3 7 10 7 m s 1 compares well with previous estimates of deep upwelling in the northern basins a series of likely sites for strong vertical entrainment of aabw are clearly identified in the modeled distribution of deep upwelling consonant with the observed cfc distributions on the top isopycnal altogether regions with relatively high upwelling rates 5 10 7 m s 1 occupy only a quarter of the total areal extent of the top isopycnal but they account for as much as 45 of the total vertical transport

tracing the nd isotope evolution of north pacific intermediate and deep waters through the last deglaciation from south china sea sediments abstract the intermediate and deep waters of the pacific ocean play a crucial role for regulating global climate changes on the millennium timescale however due to poor preservation of carbonate sediments in the deep pacific little attention has been received to better understand deep ocean circulation and its relationship with abrupt climate events here we present the first authigenic nd isotope e nd record extracted from fe mn oxyhydroxides of the south china sea scs sediments so17940 2 1727 m water depth in order to investigate changes of intermediate and deep water circulations in the pacific ocean since the last glacial maximum lgm in general the seawater e nd record extracted from the scs sediments paralleled the existing nd isotopes of fish teeth debris from the eastern north pacific core during the last deglaciation demonstrating that our authigenic e nd can faithfully record the seawater e nd evolution in the deep pacific ocean at the onset of the deglacial period our data exhibit a clear negative shift in e nd towards a gradually increased component of antarctica intermediate water aaiw and reached a maximal influx during the mid heinrich stadial 1 hs1 16 kyr bp between the hs1 and younger dryas deep water circulation gradually shifted back to the modern condition during the bolling allerod warm interval a pronounced negative e nd excursion had occurred during the pre boreal pb suggesting a rapid reorganization of deep water ventilation in the pacific ocean and was predominated by aaiw this is most likely due to poor ventilation in the western north pacific associated with an intensified summer monsoon during the pb early holocene warm period after the pb period the seawater e nd values were once again dominated by pacific deep water at the study site

the hafnium neodymium isotopic composition of atlantic seawater the first full water column hafnium isotopic compositions of atlantic seawater have been obtained at seven locations from the labrador sea to the drake passage despite subpicomolar concentrations in seawater a precision of the hf isotopic measurements of 03 epsilon hf units was achieved an overall epsilon hf range between 3 1 in the labrador sea and 4 4 in antarctic bottom water was determined the distribution of which broadly reflects continental weathering inputs within particular water column profiles significant differences of up to 4 epsilon hf units occur combined with nd isotope data of the same samples it is evident that the hf isotopic composition of seawater is too radiogenic for a given nd isotopic composition and that the largest difference between expected and measured hf isotopic compositions in seawater occurs near the oldest continental crust in the labrador sea this corroborates the previous proposition which was mainly based on ferromanganese crust data that the hf isotopic composition of seawater is controlled by incongruent weathering of continental crust and possibly to some extent by hydrothermal contributions hafnium concentrations in the ocean do not increase along the deep ocean conveyer indicating an oceanic residence time of only a few hundred years which is significantly shorter than previously assumed the hf isotopic composition of past seawater can therefore serve as a proxy for short distance basin scale mixing processes and the regime and intensity of nearby continental weathering processes c 2009 elsevier b v all rights reserved

metalliferous sediments and the scavenging residence time of nd near hydrothermal vents the isotopic composition of nd is uniform in metalliferous sediments formed at distances varying from 1000 km to within 10 km of the east pacific rise epr palaeoridge these data indicate that hydrothermal vent fluids despite having concentrations more than 500 times greater have no effect on the nd isotopic composition of seawater this implicates efficient scavenging of hydrothermal nd by particulates resulting in extremely short residence times 1 year close to the hydrothermal vents therefore nd isotopic studies of ancient seawater precipitates particularly metalliferous sediments cannot be used to delimit the magnitude of past hydrothermal circulation without independent constraints on local scavenging rates or residence times relative to those of modern oceans

nd and sr isotope compositions of different phases of surface sediments in the south pacific extraction of seawater signatures boundary exchange and detrital dust provenance the radiogenic isotope composition of neodymium nd and strontium sr are useful tools to investigate present and past oceanic circulation or input of terrigenous material we present nd and sr isotope compositions extracted from different sedimentary phases including early diagenetic fe mn coatings unclean foraminiferal shells fossil fish teeth and detritus of marine surface sediments core tops covering the entire midlatitude south pacific comparison of detrital nd isotope compositions to deep water values from the same locations suggests that boundary exchange has little influence on the nd isotope composition of western south pacific seawater concentrations of rare earth elements ree and al ca ratios of unclean planktonic foraminifera suggest that this phase is a reliable recorder of seawater nd isotope composition the signatures obtained from fish teeth and nondecarbonated leachates of bulk sediment fe mn oxyhydroxide coatings also agree with unclean foraminifera direct comparison of nd isotope compositions extracted using these methods with seawater nd isotope compositions is complicated by the low accumulation rates yielding radiocarbon ages of up to 24 kyr thus mixing the signal of different ocean circulation modes this suggests that different past seawater nd isotope compositions have been integrated in authigenic sediments from regions with low sedimentation rates combined detrital nd and sr isotope signatures indicate a dominant role of the westerly winds transporting lithogenic material from south new zealand and southeastern australia to the open south pacific the proportion of this material decreases toward the east where supply from the andes increases and contributions from antarctica cannot be ruled out

reduced north atlantic deep water flux to the glacial southern ocean inferred from neodymium isotope ratios the global circulation of the oceans and the atmosphere transports heat around the earth broecker and denton1 suggested that changes in the global ocean circulation might have triggered or enhanced the glacial interglacial cycles but proxy data for past circulation taken from sediment cores in the south atlantic ocean have yielded conflicting interpretations of ocean circulation in glacial times 13c variations in benthic foraminifera2 3 4 5 6 support the idea of a glacial weakening or shutdown of north atlantic deep water production whereas other proxies such as cd ca ba ca and 231pa 230th ratios show little change from the last glacial maximum to the holocene epoch7 8 9 here we report neodymium isotope ratios from the dispersed fe mn oxide component of two southeast atlantic sediment cores both cores show variations that tend towards north atlantic signatures during the warm marine isotope stages 1 and 3 whereas for the full glacial stages 2 and 4 they are closer to pacific ocean signatures we conclude that the export of north atlantic deep water to the southern ocean has resembled present day conditions during the warm climate intervals but was reduced during the cold stages an increase in biological productivity may explain the various proxy data during the times of reduced north atlantic deep water export

ocean chemistry during glacial time abstract measurements of co2 to air ratios in the gas trapped in bubbles in ice of glacial age suggest that the co2 content of the atmosphere was considerably lower during peak glacial time than during holocene time the purpose of this paper is to show that such a change must in all likelihood be the result of alterations in the nutrient element chemistry of sea water two possible scenarios are presented one involves alternate storage and erosion of phosphorous leaving residues from shelf sediments the other involves changes in the c p ratio in the organic debris falling to the deep sea means of verifying the nutrient cycle hypothesis are also given it is shown that the 13c record as we know it in planktonic and benthic foraminifera the oxygen record as inferred from benthic foraminifera species distributions and the early post glacial caco3 preservation event as recorded by aragonitic pteropods are consistent with both of the hypotheses presented only if an early post glacial spike in the 13c record for planktonic shells could be found would it be possible to eliminate one of these hypotheses i e that involving shelf storage the implications of these nutrient hypotheses to climate theory are as follows if shelf storage is responsible for the glacial to interglacial co2 increase then the co2 change must be considered an amplifier of some primary cause the reason is that sea level changes are needed to drive deposition on and erosion from the shelves on the other hand if changes in the c p ratio for falling debris are responsible then the co2 change could either be an amplifier or a primary cause for the major glacial to interglacial climatic cycle the latter is possible as self sustained oscillations in ocean chemistry might be driven by interactions between ocean ecology and ocean nutrient chemistry

greater supply of patagonian sourced detritus and transport by the acc to the atlantic sector of the southern ocean during the last glacial period reconstructing past detrital flux and provenance in the southernocean provides information about changes in source regions associated with climate variations and transport pathways we present a lastglacial maximum lgm to holocene comparison of 230th normalised fluxes combined with sediment provenance data pb nd and sr isotopes from a latitudinal core transect in the eastern atlanticsector of the southernocean odp leg 177 cores we compare the radiogenic isotopic composition ic of detritus in these cores to that of cores proximal to potential source areas we observe a well defined latitudinal holocene gradient in both detrital flux and provenance of sediment high detrital fluxes in the north are associated with terrigenous material derived from southern africa while low detrital fluxes in the south are associated with supply from southern south america west antarctica and the south sandwich islands the data suggest that this well defined holocene gradient in detrital flux and sediment provenance is controlled by the flow of the antarctic circumpolar current acc and the position of its frontal zones the lgm is characterised by 2 to 6 times higher than modern detrital fluxes at most odp leg 177 sites the lgm detrital fluxes do not show a latitudinal trend and suggest a greatersupply of glaciogenic detritussourced from southern south america glacialpatagonian outwash sediments 5 m fraction were analysed and compared to the bulk compositions of the marine sediments the pb ic of the patagonian sediments is very similar to the glacial ic of sediments in the scotia sea and at 49 s latitude in the eastern atlanticsector we propose that the glacial ic of sediments is controlled by increased delivery of patagoniandetritus initially supplied by glaciers and then transported at depth via the acc

thermodynamic influences on the marine carbon isotope record air sea exchange represents an important controlling factor for the distribution of carbon isotopes in the modern ocean even below the surface mixed layer here we show that this thermodynamic influence varies between water masses with a magnitude which is large relative to the amplitude of typical deep sea sediment 13c records thus changes in air sea exchange processes must be regarded as a significant source of variability for any marine 13c signal

south pacific dissolved nd isotope compositions and rare earth element distributions water mass mixing versus biogeochemical cycling despite its enormous extent and importance for global climate the south pacific has been poorly investigated in comparison to other regions with respect to chemical oceanography here we present the first detailed analysis of dissolved radiogenic nd isotopes end and rare earth elements rees in intermediate and deep waters of the mid latitude 40 s south pacific along a meridional transect between south america and new zealand the goal of our study is to gain better insight into the distribution and mixing of water masses in the south pacific and to evaluate the validity of nd isotopes as a water mass tracer in this remote region of the ocean the results demonstrate that biogeochemical cycling scavenging processes in the eastern equatorial pacific and release of lrees from the sediment clearly influence the distribution of the dissolved ree concentrations at certain locations nevertheless the nd isotope signatures clearly trace water masses including aaiw antarctic intermediate water average end 8 2 0 3 lcdw lower circumpolar deep water average end 8 3 0 3 npdw north pacific deep water average end 5 9 0 3 and the remnants of nadw north atlantic deep water average end 9 7 0 3 filtered water samples taken from the sediment water interface under the deep western boundary current off new zealand suggest that boundary exchange processes are limited at this location and highlight the spatial and temporal variability of this process these data will serve as a basis for the paleoceanographic application of nd isotopes in the south pacific

neodymium associated with foraminiferal carbonate as a recorder of seawater isotopic signatures neodymium isotopic ratios in marine environments have been used as a tracer of water masses and exchange processes between dissolved and particulate phases the interest in this tracer has been growing with improvement of our knowledge on its chemical behaviour in the modern ocean and the identification of sedimentary phases that preserve past seawater epsilon nd values in the last few decades the nd isotopic composition measured on fe mn crusts sediment leachates bulk carbonate fraction corals and fish teeth have been increasingly interpreted in the context of understanding the role of the ocean in paleoclimate changes in particular calcareous foraminiferal tests shells have acquired increasing attention as an archive of seawater nd isotopic signatures because it allows continuous high resolution records to be measured and directly compared to other proxies including stable isotopes and trace metals the main challenge of interpreting the nd isotopic composition of foraminifera is determining the origin of the nd preserved within them in this review we present an overview of methodological progress including that of bulk foraminifera and microanalyses within foraminiferal tests as well as geochemical meaning of extracted nd concentrations and isotopic compositions the growing body of evidence suggests that nd isotopic signatures of sedimentary planktonic foraminifera correspond to bottom water values rather than surface water ones the nd rich phases associated with sedimentary foraminifera are adhesive nano scale particles of mn and fe oxides and hydroxides and mn rich carbonates formed within layers of foraminiferal calcite mechanical cleaning to remove clay minerals is likely to be sufficient in most cases to reconstruct past bottom water circulations unresolved issues include the potential influence of pore water nd on epsilon nd values extracted from sedimentary foraminiferal tests under different sedimentalogical and oceanographic conditions c 2013 elsevier ltd all rights reserved

synchronous deglacial overturning and water mass source changes understanding changes in ocean circulation during the last deglaciation is crucial to unraveling the dynamics of glacial interglacial and millennial climate shifts we used neodymium isotope measurements on postdepositional iron manganese oxide coatings precipitated on planktonic foraminifera to reconstruct changes in the bottom water source of the deep western north atlantic at the bermuda rise comparison of our deep water source record with overturning strength proxies shows that both the deep water mass source and the overturning rate shifted rapidly and synchronously during the last deglacial transition in contrast any freshwater perturbation caused by heinrich event 1 could have only affected shallow overturning these findings show how changes in upper ocean overturning associated with millennial scale events differ from those associated with whole ocean deglacial climate events

the isotopic composition of neodymium in the north pacific abstract we have determined the isotopic composition of neodymium in two water column profiles in the western north pacific and in bottom waters from three other locations in the north pacific the vertical profiles reveal that the water column is stratified with respect to isotopic composition mid depths associated with pacific deep water are uniform having nd 0 3 shallow waters are variable but deep waters are less radiogenic having md 0 4 4 to 5 in the western basin the more negative bottom waters in the western north pacific provide evidence for the advective transport of rare earth elements from antarctic sources to this region bottom waters in the eastern north pacific are more radiogenic nd 0 3 3 to 3 8 indicating very little transport of ree from antarctic sources to this basin overall the isotopic composition of nd in pacific bottom waters appears to be conservative when compared to the silica distribution in spite of evidence for nd removal the findings are generally compatible with other parameters such as temperature salinity and nutrient distributions the presence of nd isotopic signatures associated with antarctic sources in these waters provides evidence for a small component of rare earth elements of north atlantic origin in the bottom waters of the north pacific this is the first tracer evidence to corroborate the suggestion of reid and lynn 1971 that some of the temperature and salinity properties of the deep waters of the north pacific originated in the norwegian and greenland seas

age and isotopic relationships among the angrites lewis cliff 86010 and angra dos reis results of a wide ranging isotopic investigation of the unique antarctican angrite lew 86010 lew are presented together with a reassessment of the type angrite angra dos reis ador the principal objectives of this study are to obtain precise radiometric ages initial sr isotopic compositions and to search for the erstwhile presence of the short lived nuclei 146sm and 26al via their daughter products the isotopic compositions of sm u ca and ti were also measured this allows a detailed appraisal to be made of the relations between and the geneology of these two angrites lew proves to be severely contaminated with modern terrestrial pb which is shown to result from terrestrial weathering nevertheless concordant pb pb model ages of pyroxene separates were obtained 2 4 55784 52 ga for lew and 4 55780 42 ga for ador uranium isotopic compositions are normal within error the inferred initial pb isotopic composition is within error of primordial pb as defined by canon diablo troilite because of the extreme upb ratios of both angrites this places an upper limit of 2 ma on the time between volatile element loss of the angrite parent body or its precursor planetesimals and the final crystallization of the angrites as differentiates initial 87sr86sr ratios were found to be indistinguishable in lew ador and the cumulate eucrite moore county the derived initial 87sr86sr for all three meteorites is 0 698970 15 2 a 147sm 143nd isochron for lew was obtained yielding an age of 4 553 34 ga with an initial 143nd144nd of 0 506682 49 2 146sm142nd isotope systematics were also measured anomalies on 142nd arising from extinct 146sm were clearly resolved resulting in an initial 146sm144sm of 0 0071 17 with nd142 2 57 0 62 at the time of isotopic closure both of these sm nd methods imply derivation of lew from a reservoir with chondritic smnd ratio they are also quite consistent with the previously reported systematics for ador overall the age and isotopic similarities between lew and ador are striking it suggests almost simultaneous production on the same asteroid even though recent experimental studies imply that the two are not comagmatic calcium and titanium do not exhibit enrichments in the n rich isotopes in contrast to cais making it unlikely that the angrite parent body is inherently rich in early condensates from the solar nebula no evidence was found for live 26al in lew when combined with the pb pb age and initial 87sr86sr data this firmly excludes 26al being an important heat source in the early solar system heat supplied for for example 1 the differentiation of the angrite and eucrite parent bodies and 2 metamorphism of the chondrite parent bodies must come from some other source the debate over live vs extinct 26al in the earliest solar system remains unresolved by this new data from lew however both the angrite and eucrite parent bodies have extremely low rbsr and high upb ratios compared to the solar nebula therefore the common initial 87sr86sr of 0 698970 can be firmly associated with the u pb angrite age above and the formation of both bodies this enables an absolute chronology of the early solar system to be established based upon 87sr86sr differences the oldest cais are a minimum of 11 4 ma older than the angrites i e 4 569 5 ga the age and isotopic constraints are discussed with respect to current collapse condensation and accretion timescales calculated for the solar nebula

isotopic composition of neodymium in waters from the drake passage the isotopic composition of neodymium has been determined in seawaters from the drake passage the antarctic circumpolar current which controls interocean mixing flows through this passage the parameter e nd 0 which is a function of the ratio of neodymium 143 to neodymium 144 is found to be uniform with depth at two stations with a value which is intermediate between the values for the atlantic and the pacific and indicates that the antarctic circumpolar current consists of about 70 percent atlantic water cold bottom water from a site in the south central pacific has the neodymium isotopic signature of the waters in the drake passage by using a box model to describe the exchange of water between the southern ocean and the ocean basins to the north together with the isotopic results an upper limit of approximately 33 million cubic meters per second is calculated for the rate of exchange between the pacific and the southern ocean concentrations of samarium and neodymium were also determined and found to increase approximately linearly with depth these results suggest that neodymium may be a valuable tracer in oceanography and may be useful in paleo oceanographic studies

reactivity of neodymium carriers in deep sea sediments implications for boundary exchange and paleoceanography the dissolved neodymium nd isotopic distribution in the deep oceans is determined by continental weathering inputs water mass advection and boundary exchange between particulate and dissolved fractions reconstructions of past nd isotopic variability may therefore provide evidence on temporal changes in continental weathering inputs and or ocean circulation patterns over a range of timescales however such an approach is limited by uncertainty in the mechanisms and importance of the boundary exchange process and the challenge in reliably recovering past seawater nd isotopic composition end from deep sea sediments this study addresses these questions by investigating the processes involved in particulate solution interactions and their impact on nd isotopes a better understanding of boundary exchange also has wider implications for the oceanic cycling and budgets of other particle reactive elements sequential acid reductive leaching experiments at ph 2 5 on deep sea sediments from the western indian ocean enable us to investigate natural boundary exchange processes over a timescale appropriate to laboratory experiments we provide evidence that both the dissolution of solid phases and exchange processes influence the end of leachates which suggests that both processes may contribute to boundary exchange we use major element and rare earth element ree data to investigate the pools of nd that are accessed and demonstrate that sediment leachate end values cannot always be explained by admixture between an authigenic component and the bulk detrital component for example in core wind 24b acid reductive leaching generates end values between 11 and 6 as a function of solution solid ratios and leaching times whereas the authigenic components have end 11 and the bulk detrital component has end 15 we infer that leaching in the mascarene basin accesses authigenic components and a minor radiogenic volcanic component that is more reactive than madagascan derived clays the preferential mobilisation of such a minor component demonstrates that the nd released by boundary exchange could often have a significantly different end composition than the bulk detrital sediment these experiments further demonstrate certain limitations on the use of acid reductive leaching to extract the end composition of the authigenic fraction of bulk deep sea sediments for example the detrital component may contain a reactive fraction which is also acid extractible while the incongruent nature of this dissolution suggests that it is often inappropriate to use the bulk detrital sediment elemental chemistry and or end composition when assessing possible detrital contamination of leachates based on the highly systematic controls observed and evidence from ree patterns on the phases extracted we suggest two approaches that lead to the most reliable extraction of the authigenic end component and good agreement with foraminiferal based approaches either i leaching of sediments without a prior decarbonation step or ii the use of short leaching times and low solution solid ratios throughout

neodymium isotopic variations in northwest pacific waters abstract four vertical profiles of the concentration and isotopic composition of nd in seawater were obtained in the western north pacific two profiles from the kuroshio current regime showed congruently that although the nd concentration increases gradually with depth its isotopic composition varies significantly with depth depending upon the water mass occupying the water column the high salinity kuroshio waters originating from the north pacific tropical water nptw carry the least radiogenic nd nd 7 4 to 8 7 to this region at 250 m from the western margin continental shelves most likely from the east china sea the nd isotopic compositions in the north pacific intermediate water npiw that occurs at 600 to 1000 m in the subtropical region are fairly uniform at nd 3 7 the profile data from the 38 to 40 n kuroshio oyashio mixed water region off sanriku of honshu japan also suggest that the newest npiw with nd 3 2 is formed there by the mixing of various source waters and the radiogenic component of nd is derived mainly from the oyashio waters in the pacific deep water pdw below 1000 m the nd isotopic composition is neither vertically nor horizontally homogeneous suggesting that it serves as a useful tracer for sluggish deep water circulation as well two profiles from the izu ogasawara trench showed a minimum nd value at 2000 m suggesting that there exists a horizontal advective flow in the vicinity of honshu japan there is some evidence from other chemical properties to support this observation the waters below 4000 m including those within the trench in the subtropical region have nd values of around 5 suggesting that the deep waters are fed from the south along the western boundary ultimately from the antarctic bottom water aabw in the south pacific this extends up to 40 n along the japanese islands in the subarctic region 42 n the waters have more radiogenic nd with nd 4 0 throughout the water column presumably due to the supply of nd by weathering in such igneous provinces as the kuril kamchatska aleutian island chain the lateral inhomogeneity of the nd isotopic composition in pdw suggests that there may be different circulation and mixing regimes in the north pacific basin

the distribution of neodymium isotopes and concentrations in the eastern equatorial pacific water mass advection versus particle exchange the radiogenic isotope composition of the rare earth element ree neodymium nd is a powerful water mass proxy for present and past ocean circulation the processes controlling the nd budget of the global ocean are not quantitatively understood and in particular source and sink mechanisms are still under debate in this study we present the first full water column data set of dissolved nd isotope compositions and nd concentrations for the eastern equatorial pacific eep where one of the globally largest oxygen minimum zones omz is located this region is of particular interest for understanding the biogeochemical cycling of rees because anoxic conditions may lead to release of rees from the shelf whereas high particle densities and fluxes potentially remove the rees from the water column data were obtained between 1 40 n and 16 s along a nearshore and an offshore transect near surface zonal current bands such as the equatorial undercurrent euc and the subsurface countercurrent sscc which are supplying oxygen rich water to the omz are characterized by radiogenic nd isotope signatures end 2 surface waters in the northernmost part of the study area are even more radiogenic end 3 most likely due to release of nd from volcanogenic material deep and bottom waters at the southernmost offshore station 14 s are clearly controlled by advection of water masses with less radiogenic signatures end 7 originating from the southern ocean towards the equator however the deep waters show a clear trend towards more radiogenic values of up to end 2 the northernmost station located in the panama basin shows highly radiogenic nd isotope signatures in the entire water column which indicates that particle scavenging downward transport and release processes play an important role this is supported by relatively low nd concentrations in deep waters 3000 6000 m in the eep 20 pmol kg compared to locations in the northern and central pacific 40 60 pmol kg which suggests enhanced removal of nd in the eep

testing the extraction of past seawater nd isotopic composition from north atlantic deep sea sediments and foraminifera neodymium isotopes provide a paleoceanographic proxy for past deep water circulation and local weathering changes and have been measured on various authigenic marine sediment components including fish teeth ferromanganese oxides extracted by acid reductive leaching cleaned foraminifera and foraminifera with fe mn oxide coatings here we compare nd isotopic measurements obtained from ferromanganese oxides leached from bulk sediments and planktonic foraminifera as well as from oxidatively reductively cleaned foraminiferal shells from sediment cores in the north atlantic sedimentary volcanic ash contributes a significant fraction of the nd when the ferro manganese fe mn oxide coatings are leached from bulk sediments reductive leachates of marine sediments from north atlantic core tops near iceland or directly downstream from iceland scotland overflow waters record nd values that are significantly higher than seawater indicating that volcanic material is easily leached by acid reductive methods the nd values from sites more distal to iceland are similar to modern seawater values showing little contamination from iceland derived volcanogenic material in all comparisons core top planktonic foraminifera nd values more closely approximate modern deep seawater than the bulk sediment reductive leached value suggesting that the foraminifera provide a route toward quantifying the nd isotopic signature of deep north atlantic water masses

the sedimentary flux of dissolved rare earth elements to the ocean abstract we determined pore fluid rare earth element ree concentrations in near surface sediments retrieved from the continental margin off oregon and california usa these sites represent shelf to slope settings which lie above within and below the oxygen minimum zone of the northeast pacific the sediments are characterized by varying degrees of net iron reduction with pore fluids from the shelf sites being generally ferruginous and the slope sediments having less pronounced iron reduction zones that originate deeper in the sediment package ree concentrations show maxima in shallow upper 2 10 cm subsurface pore fluids across all sites with concentrations that rise more than two orders of magnitude higher than seawater these pore fluid enrichments highlight the importance of a sedimentary source of rees to the ocean s water column here we use our measurements to estimate the diffusive flux of nd out of ocean sediments resulting in a global flux between 18 and 110 10 6 mol nd yr 1 while we do assume that our pore fluid profiles as well as the very limited data previously published are representative of a wide array of ocean environments this calculated flux can account for the modeled missing nd source flux 76 10 6 mol nd yr 1 in global budgets arsouze et al 2009 pore fluid normalized ree patterns show distinct variation in the middle ree and heavy ree enrichments with sediment depth and amongst sites these patterns show that the heavy ree enrichment of pore fluids at our deep slope site 3000 m water depth is closest to the heavy ree enrichment of seawater this observation supports the view that ree cycling within the upper ten centimeters of deep sea marine sediments as opposed to shallower continental shelf and slope sediments plays a significant role in controlling the integrated global ree flux from the pore fluids and consequently the broad scale ree pattern in seawater

changes in the mode of southern ocean circulation over the last glacial cycle revealed by foraminiferal stable isotopic variability benthic foraminiferal oxygen and carbon isotopic records from southern ocean sediment cores show that during the last glacial period the south atlantic sector of the deep southern ocean filled to roughly 2500 m with water uniformly low in 13c resulting in the appearance of a strong mid depth nutricline similar to those observed in glacial northern oceans concomitantly deep water isotopic gradients developed between the pacific and atlantic sectors of the southern ocean the 13c of benthic foraminifera in pacific sediments remained significantly higher than those in the atlantic during the glacial episode these two observations help to define the extent of what has become known as the southern ocean low 13c problem one explanation for this glacial distribution of 13c calls upon surface productivity overprints or changes in the microhabitat of benthic foraminifera to lower glacial age 13c values we show here however that glacial interglacial 13c shifts are similarly large everywhere in the deep south atlantic regardless of productivity regime or sedimentary environment furthermore the degree of isotopic decoupling between the atlantic and pacific basins is proportional to the magnitude of 13c change in the atlantic on all time scales thus we conclude that the profoundly altered distribution of 13c in the glacial southern ocean is most likely the result of deep ocean circulation changes while the characteristics of the southern ocean 13c records clearly point to reduced north atlantic deep water input during glacial periods the basinal differences suggest that the mode of southern ocean deep water formation must have been altered as well

deglacial whole ocean δ13c change estimated from 480 benthic foraminiferal records terrestrial carbon storage is dramatically decreased during glacial periods due to cold temperatures increased aridity and the presence of large ice sheets on land most of the carbon released by the terrestrial biosphere is stored in the ocean where the light isotopic signature of terrestrial carbon is observed as a 0 32 0 7 depletion in benthic foraminiferal 13c the wide range in estimated 13c change results from the use of different subsets of benthic 13c data and different methods of weighting the mean 13c by volume we present a more precise estimate of glacial interglacial 13c change of marine dissolved inorganic carbon using benthic cibicidoides spp 13c records from 480 core sites more than 3 times as many sites as previous studies we divide the ocean into eight regions to generate linear regressions of regional 13c versus depth for the late holocene 0 6 ka and last glacial maximum 19 23 ka and estimate a mean 13c decrease of 0 38 0 08 2 for 0 5 5 km estimating large uncertainty ranges for 13c change in the top 0 5 km below 5 km and in the southern ocean we calculate a whole ocean change of 0 34 0 19 this implies a terrestrial carbon change that is consistent with recent vegetation model estimates of 330 694 gt c additionally we find that a well constrained surface ocean 13c change is essential for narrowing the uncertainty range of estimated whole ocean 13c change

seismic reflection profiling across the seismogenic fault of the 1995 kobe earthquake southwestern japan abstract the 1995 kobe hyogo ken nanbu earthquake mw 6 9 surface rupture appeared along the nojima fault on the northwest coast of awaji island the aftershock epicentres in northern awaji island are not aligned with the surface faulting suggesting a complicated active fault structure to reveal the structure of the seismogenic fault and its associated active faults a perpendicular 41 6 km long seismic reflection survey was undertaken across northern awaji island the trans awaji seismic reflection profile reveals the fault geometry beneath the area awaji island was uplifted by movement on the kariya fault along its east coast which produced an asymmetry in neogene basin that is shallower in the western part than in the eastern part the faults beneath awaji island show a pop up or a positive flower structure and the basement is bounded by two active faults the nojima along the west coast and the kariya along the east coast both are high angle reverse faults with a right lateral strike slip movement the cluster of aftershocks in the northern part of awaji island has a y shaped hypocentral distribution the nojima and kariya faults thus appear to connect in the middle of the upper crust at about 7 km depth forming a seismogenic master fault three major seismic events have been reported on the active faults in northern awaji island a prehistoric event dated 2000 yr bp the 1596 keicho fushimi earthquake and the 1995 kobe earthquake based on the structural relationship of the active faults that we observed in this study we suggest that these events occurred on the proposed master fault at mid crustal depth

a lead isotopic study of circum antarctic manganese nodules abstract lead isotope ratios in manganese nodules from the circum antarctic ocean display systematic geographical variations eastward in the direction of current movement from south of australia they progressively decrease in the pacific sector and into the western atlantic sector until 30 w from this longitude lead isotope ratios increase in the eastern atlantic sector and reach their highest values in the indian sector near 110 e south of western australia they abruptly decrease these two lead isotope domains correspond closely to the circum antarctic neodymium isotope domains previously recognized by albarede and goldstein 1992 however the intraocean isotopic variations are much clearer for pb than nd reflecting the shorter oceanic residence time of pb 102 y compared with nd 103 y and confirming that pb is a much more sensitive marine tracer throughout the circum antarctic ocean the lead isotopic changes follow the pattern of present day oceanic circulation the pb shows an overall continental signature which is strongest in the indian sector the most probable candidate as the source of the continental signal is north atlantic deep water nadw which enters the circum antarctic in the south atlantic as nadw mixes with circumpolar water lead isotope ratios increase eastward in the indian sector reflecting progressive loss of the pacific derived pb signal the abrupt decrease of lead isotope ratios between the indian and pacific sectors appears to be a consequence of addition of pacific seawater through the pacific lead isotope ratios gradually decrease eastward approaching values of east pacific rise metalliferous sediments ocean ridge basalts and south pacific mn nodules this trend results from an increasing influence of pacific ocean water containing a component derived from pacific volcanism the pacific signature persists into the argentine basin in the southwest atlantic ocean reflecting significant input of water from the drake passage northward into the atlantic the pacific pb component is seen in the atlantic and indian oceans near southern africa as well as in the atlantic and indian sectors of the circum antarctic lead and neodymium isotopes correlate in the atlantic indian sectors but not in the pacific sector reflecting differences in residence times and modes of water mass mixing the renewal of circum antarctic water occurs on a timescale which is short compared to the residence time of nd but long compared to pb as a result dissolved pb is subject to considerable changes over the timescale of circumpolar current movement while nd is less easily affected nadw is added locally in the south atlantic and moves eastward as a water mass as nadw mixes with circumpolar water cpw through the indian sector changes affecting nd pb in nadw and cpw occur in tandem and neodymium and lead isotopes are correlated through the pacific sector gradual addition of pacific seawater occurs over a large region and nd pb relationships are not coupled because simple isotopic mixing systematics are not conserved there neodymium and lead isotopes vary independently the consistency of lead isotope variations with present day ocean bottom water circulation is remarkable considering that the mn nodules as sampled reflect the integrated flux of pb over 105 106 y the oceanic mixing time is 103 y the residence time for pb is 102 y and the circulation time of the circumantarctic ocean is 30 y processes occurring over such different timescales can show such a relationship only if the system is stable over the longest time interval thus on average element sources and ocean circulation through the pleistocene have been similar to the present day despite significant perturbations during glacial periods

glacial age hydrography of the far northwest pacific ocean stable isotope data on benthic foraminifera from more than 30 cores on the northern emperor seamounts and in the okhotsk sea are synthesized in paleohydrographic profiles spanning the depth range 1000 4000 m holocene core top benthic foraminiferal 18o and 13c data are calibrated to modern hydrographic properties through measurements of 13c of co2 and 18o of seawater cibicidoides stable isotope ratios are close to the 13c and equilibrium 18o of seawater whereas uvigerina 18o and 13c are variably offset from cibicidoides glacial maximum 13c of cibicidoides displays a different vertical profile than that of the holocene when results are adjusted by 0 32 to account for the secular change in 13c during the last glacial maximum the data coincide with the modern seawater and foraminiferal curves deeper than 2 km however at shallower depths 13c gradually increases by as much as 1 above the modern value furthermore above 2 km the benthic 18o decreases by 0 5 these results are consistent with a benthic front at 2 km in the north pacific see herguera et al 1992 but they differ from interpretations based on trace metal data which indicate a source of nutrient depleted deep water during glaciation the isotopic data suggest that during glaciation there was a better ventilated watermass at intermediate depths in the far northwestern pacific it was relatively fresher than deep waters there and deep waters were as nutrient rich as today

quaternary climate modulation of pb isotopes in the deep indian ocean linked to the himalayan chemical weathering we use reductive sediment leaching to extract lead pb from the authigenic fraction of marine sediments and reconstruct the pb isotope evolution of the deep central indian ocean over the past 250 thousand years at 3 kyr resolution temporal variations define a binary mixing line that is consistent with data from ferromanganese nodules and which records mixing between two well defined endmembers through time the unradiogenic endmember appears to represent a widely distributed pb source from mid ocean ridges or possibly volcanic aerosols while the radiogenic endmember coincides with the composition of ganges brahmaputra river sediments that are indicative of the himalayan weathering inputs glacial interglacial pb isotope variations are striking and can be explained by an enhancement of himalayan contributions by two to three times during interglacial periods indicating that climate modulates the supply of dissolved elements to the ocean while these changes could accurately record variations in the continental chemical weathering flux in response to warmer and wetter conditions during interglacials the relative proportions of pb derived from the ganges and brahmaputra appear to have been constant through time this observation may point towards particulate dissolved interactions in the estuary or pro delta as a buffer of short timescale variability in the composition and potentially flux of the fluvial inputs in addition the changes are recorded at 3800 m water depth and with the lack of deep water formation in the bay of bengal a mechanism to transfer such a signature into the deep ocean could either be reversible scavenging of dissolved pb inputs and or boundary exchange on the deep sea fan unless the mechanism transferring the pb isotope signature into the deep ocean was itself highly sensitive to global climate cycles and with the absence of a precessional signal in our pb isotope data we suggest that the indian climate and its influence on basin scale chemical weathering were strongly modulated by glacial versus interglacial boundary conditions

glacial water mass geometry and the distribution of δ13c of σco2 in the western atlantic ocean 1 oxygen and carbon isotopic data were produced on the benthic foraminiferal taxa cibicidoides and planulina from 25 new piston cores gravity cores and multicores from the brazil margin the cores span water depths from about 400 to 3000 m and intersect the major water masses in this region these new data fill a critical gap in the south atlantic ocean and provide the motivation for updating the classic glacial western atlantic 13c transect of duplessy et al 1988 the distribution of 13c of co2 requires the presence of three distinct water masses in the glacial atlantic ocean a shallow 1000 m southern source water mass with an end member 13c value of about 0 3 0 5 vpdb a middepth 1500 m northern source water mass with an end member value of about 1 5 and a deep 2000 m southern source water with an end member value of less than 0 2 and perhaps as low as the 0 9 values observed in the south atlantic sector of the southern ocean ninnemann and charles 2002 the origins of the water masses are supported by the meridional gradients in benthic foraminiferal 18o a revised glacial section of deep water 13c documents the positions and gradients among these end member intermediate and deep water masses the large property gradients in the presence of strong vertical mixing can only be maintained by a vigorous overturning circulation

the record of continental dust from australia in tasman sea sediments abstract the flux of aeolian dust from australia to sediments of the tasman sea has increased during glacial stages of the last four glacial cycles low fluxes of dust from australia before 350 ka were followed by an increase in stage 10 and high fluxes in peak glacial periods thereafter the initiation of higher dust fluxes in stage 10 is consisten with previous estimates of the age of onset of aridity in the source area dust flux to the tasman sea is thought to record the intensity of deflation from the source area in interior southeastern australia which was marked by arid conditions and possibly greater windiness during the last glacial a transect of five cores from the central tasman sea revealed consistently low dust fluxes north of 33 s increasing southward to approximately 40 s glacial to interglacial movement of the northern boundary of the dust plume governed by the position of the subtropical ridge was less than 6 latitude probably closer to 3 350 km the position of the dust plume determined in this study and its response to climate change are significantly different from a previous reconstruction based on the measurement of quartz content of the non biogenic sediment fraction

lead concentrations in the northeast pacific evidence for global anthropogenic perturbations lead concentrations were determined by isotope dilution mass spectrometry in 34 surface and deep water samples collected in the northeast pacific between hawaii and california and off the california coast using a deep water sampler protected against fouling by contamination from the ship and hydrowire measured concentrations lie more than one order of magnitude below previously published open ocean values and they show that in most cases 90 or more of the total lead is in a dissolved form lead concentrations are about 10 fold higher in surface and thermocline waters than in deep waters values drop as low as 1 ng kg 5 pmol kg below 3500 m depth lead profiles thus appear different compared to those of most trace metals which show enrichment in deep waters compared to surface concentrations lead concentrations in surface waters increase from 5 to 15 ng kg 25 to 75 pmol kg along a transect starting from a location 200 km off the california coast and continuing towards the center of the north pacific gyre this increase is congruent with that observed for 210 pb concentrations in the same waters sampled at the same time lead is supplied to the open north pacific largely from the atmosphere at a rate of about 60 ng cm 2 yr which exceeds the prehistoric oceanic output flux of authigenic lead recorded in pelagic sediments about tenfold this excess originates from emissions from smelters and combustion of leaded gasoline overwhelming natural lead inputs that entered the ocean during prehistoric time probably largely through rivers vertical lead concentration profiles below the surface mixed layer are probably not in steady state there concentrations must be increasing in response to the increase of anthropogenic inputs because the estimated lead residence times are more than 20 years in the thermocline and about 80 years in deep waters based on an estimated 10 fold input and concentration increase since the mid eighteenth century in the surface mixed layer in the central northeast pacific it is calculated that the 10 ng kg average concentration between 100 and 900 m is 2 to 5 times larger and the 1 8 ng kg average concentration between 900 and 5000 m depth is about 2 times larger than it was in the mid eighteenth century profiles of lead concentrations in the north atlantic are expected to be shifted generally to larger values by a factor of 2 to 3 compared to those in the north pacific because of the effects of greater industrial lead contamination while lead concentration profiles in the south pacific are expected to be shifted generally to lower values compared to the north pacific by about this same factor because of the effects of lesser industrial lead contamination

rare earth element association with foraminifera abstract neodymium isotopes are becoming widely used as a palaeoceanographic tool for reconstructing the source and flow direction of water masses a new method using planktonic foraminifera which have not been chemically cleaned has proven to be a promising means of avoiding contamination of the deep ocean palaeoceanographic signal by detrital material however the exact mechanism by which the nd isotope signal from bottom waters becomes associated with planktonic foraminifera the spatial distribution of rare earth element ree concentrations within the shell and the possible mobility of ree ions during changing redox conditions have not been fully investigated here we present ree concentration and nd isotope data from mixed species of planktonic foraminifera taken from plankton tows sediment traps and a sediment core from the nw atlantic we used multiple geochemical techniques to evaluate how where and when rees become associated with planktonic foraminifera as they settle through the water column reside at the surface and are buried in the sediment analyses of foraminifera shells from plankton tows and sediment traps between 200 and 2938 m water depth indicate that only 20 of their associated nd is biogenically incorporated into the calcite structure the remaining 80 is associated with authigenic metal oxides and organic matter which form in the water column and remain extraneous to the carbonate structure remineralisation of these organic and authigenic phases releases ions back into solution and creates new binding sites allowing the nd isotope ratio to undergo partial equilibration with the ambient seawater as the foraminifera fall through the water column analyses of fossil foraminifera shells from sediment cores show that their ree concentrations increase by up to 10 fold at the sediment water interface and acquire an isotopic signature of bottom water adsorption and complexation of ree3 ions between the inner layers of calcite contributes significantly to elevated ree concentrations in foraminifera the most likely source of ree ions at this stage of enrichment is from bottom waters and from the remineralisation of oxide phases which are in chemical equilibrium with the bottom waters as planktonic foraminifera are buried below the sediment water interface redox sensitive ion concentrations are adjusted within the shells depending on the pore water oxygen concentration the concentration of ions which are passively redox sensitive such as ree3 ions is also controlled to some extent by this process we infer that a the nd isotope signature of bottom water is preserved in planktonic foraminifera and b that it relies on the limited mobility of particle reactive ree3 ions aided in some environments by micron scale precipitation of mnco3 this study indicates that there may be sedimentary environments under which the bottom water nd isotope signature is not preserved by planktonic foraminifera tests to validate other core sites must be carried out before downcore records can be used to interpret palaeoceanographic changes

thermohaline circulation crisis and impacts during the mid pleistocene transition the mid pleistocene transition mpt marked a fundamental change in glacial interglacial periodicity when it increased from 41 thousand year to 100 thousand year cycles and developed higher amplitude climate variability without substantial changes in the milankovitch forcing here we document by using nd isotopes a major disruption of the ocean thermohaline circulation thc system during the mpt between marine isotope stages miss 25 and 21 at 950 to 860 thousand years ago which effectively marks the first 100 thousand year cycle including an exceptional weakening through a critical interglacial mis 23 at 900 thousand years ago its recovery into the post mpt 100 thousand year world is characterized by continued weak glacial thc the mpt ocean circulation crisis facilitated the coeval drawdown of atmospheric co2 and high latitude ice sheet growth generating the conditions that stabilized 100 thousand year cycles

strontium isotope tracing of terrigenous sediment dispersal in the antarctic circumpolar current implications for constraining frontal positions the vigor of the glacial antarctic circumpolar current acc and the locations of frontal boundaries are important parameters for understanding the role of the southern ocean in global climate change toward the goal of understanding the locations of currents we present a survey of sr isotope ratios in terrigenous sediments around the perimeter of antarctica the pattern of the variations within the modern acc is used to suggest that terrigenous sediment from antarctica is injected into the acc via the ross and weddell gyres in the south north of the main acc the sr isotopes reflect continental contributions from africa australia new zealand and south america along a transect northward from the ross sea sr isotope ratios show a decrease from higher values in the south antarctic provenance to lower values in the north provenance from new zealand this otherwise monotonic decrease is interrupted within the acc by a zigzag to lower and then higher values which accompanies minimum terrigenous flux this zigzag requires contributions from two additional sediment sources beyond the main antarctic and new zealand end members the lower sr isotope ratios are attributable to greater contributions from basaltic sources within the current a consistent pattern around the acc the samples with higher sr isotope ratios point to an additional contributor possibly a wind transported component from australia during the lgm there is a systematic geographical variation in the sr isotope ratios similar to that of the holocene a small offset of the zigzag to the north approximately 1 2 may indicate a small northward shift of the southern boundary of the acc more highly resolved data are required to test whether this northward shift is really significant and whether it applies to other acc fronts during the lgm

temporal relationships of carbon cycling and ocean circulation at glacial boundaries evidence from high sedimentation rate south atlantic deep sea cores indicates that global and southern ocean carbon budget shifts preceded thermohaline circulation changes during the last ice age initiation and termination and that these were preceded by ice sheet growth and retreat respectively no consistent lead lag relationships are observed during abrupt millennial warming events during the last ice age allowing for the possibility that ocean circulation triggered some millenial climate changes at the major glacial interglacial transitions the global carbon budget and thermohaline ocean circulation responded sequentially to the climate changes that forced the growth and decline of continental ice sheets

global neodymium hafnium isotope systematics revisited global nd hf isotope systematics can be mainly described with two linear arrays the global silicate earth array the terrestrial array and the global ferromanganese crust and nodule array the seawater array the offset between these two arrays provides evidence for the sources and mechanisms by which these elements are added to ocean water however the reason for this offset is under debate with the two preferred hypotheses being i incongruent release of hf during continental weathering and ii hydrothermal contribution of hf to the seawater budget here we present new nd and hf isotope data on glacio marine core top sediments from around the perimeter of the antarctic continent the results range from ehf 30 0 to ehf 3 9 and end 21 3 to end 0 9 reflecting the large range of basement ages and lithologies around the antarctic continent in nd hf isotope space they confirm the systematic correlations found in rocks from other parts around the world and provide valuable insights into the previously underrepresented group of sediments with very old provenance in this paper we revisit the cause for the offset of the seawater array from the terrestrial array using simple mass balance considerations we use these calculations to test to what degree the seawater array could be a product of preferential weathering of non zircon portions of the upper continental crust implying retention of zircons in the solid residue of weathering lutetium hf and sm nd evolution and mixing calculations show that the global seawater array can be generated with continental sources only on the other hand a predominantly hydrothermal origin of hf in the ocean is not possible because the seawater hf isotopic composition is significantly less radiogenic than hydrothermal sources and requires a minimum fraction of 50 continental hf while hydrothermal sources may contribute some hf to seawater continental contributions are required to balance the budget

nd isotopic composition in the central north pacific three vertical profiles of seawater concentration and isotopic composition of nd were determined for the western to central north pacific ocean in the subarctic oceanic region at depths greater than 500 m one vertical profile of nd isotopic composition was indistinguishable from most previously reported profiles from here the data indicate a rather homogeneous nd isotopic composition in the subarctic oceanic region at middle to deep depths 500 m two stations in the subtropical oceanic region exhibited similar nd isotopic composition profiles to those previously reported the maxima end values at depths of 800 1000 m end 3 4 to 2 7 which correspond to the north pacific intermediate water npiw are found at both subtropical stations this implies a ubiquitous distribution of npiw showing a radiogenic end value in the north pacific the subsurface minimum at a depth of 200 m which indicates the penetration of the north pacific tropical water nptw with an unradiogenic nd isotopic signal was observed at one station in the western pacific this station had much lower end than the central station at depths around 5000 m suggesting the greater prominence of antarctic bottom water aabw in the western subtropical pacific than in the central to eastern subtropical pacific results of a model calculation assuming boundary exchange indicate that the hawaiian islands play an important role in supplying radiogenic nd to the central pacific similar to some continental margins we show that nd isotopic composition is a versatile tracer for ocean circulation and the geochemical cycle of nd in the north pacific further studies on the distribution of nd isotopic composition in the pacific ocean including the southern pacific will better elucidate the circulation and geochemical cycle of nd in the pacific

evolution of ocean temperature and ice volume through the mid pleistocene climate transition earth s climate underwent a fundamental change between 1250 and 700 thousand years ago the mid pleistocene transition mpt when the dominant periodicity of climate cycles changed from 41 thousand to 100 thousand years in the absence of substantial change in orbital forcing over this time an increase occurred in the amplitude of change of deep ocean foraminiferal oxygen isotopic ratios traditionally interpreted as defining the main rhythm of ice ages although containing large effects of changes in deep ocean temperature we have separated the effects of decreasing temperature and increasing global ice volume on oxygen isotope ratios our results suggest that the mpt was initiated by an abrupt increase in antarctic ice volume 900 thousand years ago we see no evidence of a pattern of gradual cooling but near freezing temperatures occur at every glacial maximum

reduced admixture of north atlantic deep water to the deep central south pacific during the last two glacial periods the south pacific is a sensitive location for the variability of the global oceanic thermohaline circulation given that deep waters from the atlantic ocean the southern ocean and the pacific basin are exchanged here we reconstruct the deep water circulation of the central south pacific for the last two glacial cycles from 240 000 years ago to the holocene based on radiogenic neodymium nd and lead pb isotope records complemented by benthic stable carbon data obtained from two sediment cores located on the flanks of the east pacific rise the records show small but consistent glacial interglacial changes in all three isotopic systems with interglacial average values of 5 8 and 18 757 for end and 206pb 204pb respectively whereas glacial averages are 5 3 and 18 744 comparison of this variability of circumpolar deep water cdw to previously published records along the pathway of the global thermohaline circulation is consistent with reduced admixture of north atlantic deep water to cdw during cold stages the absolute values and amplitudes of the benthic 13c variations are essentially indistinguishable from other records of the southern hemisphere and confirm that the low central south pacific sedimentation rates did not result in a significant reduction of the amplitude of any of the measured proxies in addition the combined detrital nd and strontium 87sr 86sr isotope signatures imply that australian and new zealand dust has remained the principal contributor of lithogenic material to the central south pacific

neodymium budget in the modern ocean and paleo oceanographic implications the oceanic nd budget is calculated using a steady state 10 box model and a compilation of field data this is the first attempt to propose consistent estimates of the nd fluxes entering the ocean as well as indicating possible nd sources and the proportion of nd fluxes exchanged between dissolved and particulate fractions with presently available nd data the best estimates give a total nd influx of 9 x 10 9 g yr which leads to an oceanic nd residence time of 500 years from modeling tests we suggest that the authigenic nd scavenged by particulates is 100 remineralized in the deep ocean the total exchanged nd flux may be as high as 2 x 10 10 g yr the epsilon nd 0 values of the influxes are 22 11 1 and 4 for the north atlantic surface atlantic north pacific and surface indo pacific regions respectively atmospheric and riverine nd fluxes are insufficient to explain the magnitude and regional variability of calculated nd influxes and epsilon nd 0 we propose continental margins as an additional source supplying nd to the ocean using the model calibrated for nd we examine the sensitivity of deep water epsilon nd 0 to variations of nd inputs to the ocean deep water nd concentrations and epsilon nd 0 vary with the changes in nd influxes and their epsilon nd 0 as nd sources to the ocean may change during glacial interglacial periods the epsilon nd 0 shifts recorded in ferromanganese nodules and crusts do not necessarily reflect changes in paleoceanic circulation the effects of continental erosion should be considered in reconstructing patterns of ocean circulation using nd isotopes

texture development in experimentally deformed two phase aggregates of calcite and anhydrite abstract fully quantitative textures have been measured from experimentally deformed two phase aggregates of calcite and anhydrite two sets of deformation experiments were performed firstly to investigate the development of microstructure and texture with composition samples with varying volume proportions of calcite and anhydrite were deformed to 20 strain at identical conditions secondly to study the texture development of the two materials with strain and explore the possible use of texture index as a strain gauge in polyphase materials pure calcite and pure anhydrite were deformed at the same conditions as the two phase rocks to strains of 6 12 and 20 the textures in both calcite and anhydrite were found to be similar but not identical to those reported in previous studies for pure samples our experimental investigations and measured textures show that the textures both of the pure materials and of the two phase rocks depend not only on strain but also on stress and grain size through their influence on the deformation mechanisms the dependence of texture index with change in deformation mechanism is particularly pronounced in the anhydrite component where the texture index decreases with grain size which decreases with anhydrite content the texture in the pure calcite and in the calcite component of the two phase rocks was influenced by a preexisting fabric the intensity of the texture in the deformed samples seems to correlate with the stress in the calcite rather than with strain

sr and nd isotopic and trace element compositions of quaternary volcanic centers of the southern andes isotopic compositions of samples from six quaternary volcanoes located in the northern and southern extremities of the southern volcanic zone svz 33 46 s of the andes and from four centers in the austral volcanic zone avz 49 54 s range for 87sr 86sr from 0 70280 to 0 70591 and for 143nd 144nd from 0 51314 to 0 51255 the ranges are significantly greater than previously reported from the southern andes but are different from the isotopic compositions of volcanoes in the central and northern andes basalts and basaltic andesites from three centers just north of the chile rise trench triple junction have 87sr 86sr 143nd 144nd la yb ba la and hf lu that lie within the relatively restricted ranges of the basic magmas erupted from the volcanic centers as far north as 35 s in the svz of the andes the trace element and sr and nd isotopic characteristics of these magmas may be explained by source region contamination of subarc asthenosphere with contaminants derived from subducted pelagic sediments and seawater altered basalts by dehydration of subducted oceanic lithosphere in the northern extremity of the svz between 33 and 34 s basaltic andesites and andesites have higher 87sr 86sr rb cs and hf lu and lower 143nd 144nd than basalts and basaltic andesites erupted farther south in the svz which suggests involvement of components derived from the continental crust in the avz the most primitive sample high mg andesite from the southernmost volcanic center in the andes 54 s has sr and nd isotopic compositions and kr b and ba la similar to morb the high la yb of this sample suggests formation by small degrees of partial melting of subducted morb with garnet as a residue samples from centers farther north in the avz show a regionally regular northward increase in sio2 k2o rb ba ba la and 87sr 86sr and decrease in mgo sr kr b rb cs and 143nd 144nd suggesting increasingly greater degrees of fractional crystallization and associated intra crustal contamination

disparities in glacial advection of southern ocean intermediate water to the south pacific gyre highlights surface mg ca temperatures and salinities show comparable glacial conditions subsurface mg ca temperatures suggest that lgm is 3 to 2 c colder than mis 6 relative to holocene subsurface salinities suggest fresher lgm and saltier mis 6 thermal gradients suggest stratified lgm and well mixed mis 6 water column contrasting glacial scenarios suggest variable formation and advection of soiws abstract the intermediate waters formed in the southern ocean are critical for ventilating the thermocline in the southern hemisphere gyres and transporting climatic signals from high to low latitudes on glacial interglacial time scales despite the importance of the southern ocean intermediate waters soiws information on past changes in soiws formation is fragmentary and its impact on the south pacific gyre spg s thermocline largely unknown here we present a 200 kyr record of paired mg ca ratios and stable oxygen isotope from surface and deep dwelling planktonic foraminifera from the spg on average the globigerina bulloides mg ca derived sea surface temperatures show similar conditions during the lgm and marine isotope stage mis 6 9 4 c versus 9 8 c in contrast the subsurface temperatures derived from the mg ca values of globorotalia inflata and globorotalia truncatulinoides suggest that lgm is 3 to 2 c colder than mis 6 furthermore at subsurface depths the reconstructed 18osw ivc record proxy for relative local salinity changes suggests opposite glacial conditions with slightly saltier than holocene waters during mis 6 and fresher than holocene waters during lgm contrasting glacial scenarios plausibly due to changes in the presence of soiws at the study site suggest variable formation and or advection of soiws to the spg during different glacial stages the variability in soiws is probably driven by the changes in the intensity of the southern westerly winds

late quaternary variability of mediterranean outflow water from radiogenic nd and pb isotopes mediterranean outflow water mow is characterised by higher temperatures and salinities than other ambient water masses mow spreads at water depths between 500 and 1500 m in the eastern north atlantic and has been a source of salinity for the atlantic meridional overturning circulation in the north atlantic we used high resolution nd and pb isotope records of past ambient seawater obtained from authigenic ferromanganese coatings of sediments in three gravity cores at 577 1745 and 1974 m water depth in the gulf of cadiz and along the portuguese margin complemented by a selection of surface sediments to reconstruct the extent and pathways of mowover the past 23 000 years the surface and downcore nd isotope data from all water depths exhibit only a very small variability close to the present day composition of mowbut do not reflect the present day nd isotopic stratification of the water column as determined from a nearby open ocean hydrographic station in contrast the pb isotope records show significant and systematic variations which provide evidence for a significantly different pattern of the mow pathways between 20 000 and 12 000 years ago compared with the subsequent period of time

continental weathering fluxes during the last glacial interglacial cycle insights from the marine sedimentary pb isotope record at orphan knoll nw atlantic abstract regional weathering intensity must have changed dramatically at high latitudes during the quaternary as a consequence of repeated continental glaciation investigation of these glacial interglacial changes at high temporal resolution is possible with the recent development of pb isotopes in femn oxyhydroxide phases as a proxy for region specific weathering intensity where increases in the radiogenic component are thought to correspond to increased continental weathering fluxes here we present a pb isotope record sourced from the femn oxyhydroxide fraction in marine sediments from iodp sites u1302 3 on orphan knoll 3500 mbsl nw atlantic spanning the last 37 ka located at the eastern edge of the laurentide ice sheet lis site u1302 3 is well placed to monitor changes in weathering intensity associated with lis glacial history overall the data show a close correspondence to local surface water 18o with least radiogenic values during times of heavy 18o glacial maximum and most radiogenic values during times of light 18o holocene this supports the prediction that weathering intensity in glaciated regions of the north atlantic correlates with the exposure age of glacial debris superimposed on these background trends are extreme radiogenic excursions e g variation in 206pb 204pb from 19 2 21 0 contemporaneous with heinrich events and the younger dryas these data are substantially more radiogenic than existing records from the nw atlantic and most likely represent episodes of exceptionally high inputs of pre formed femn oxyhydroxides during drainage of the lis due to its extreme isotope composition at least in the nw atlantic region pb would appear to be a good proxy for the fluxes of weathered continental material and perhaps by inference nutrients to the surface ocean

temporal stability of the neodymium isotope signature of the holocene to glacial north atlantic the neodymium isotopic composition of marine precipitates is increasingly recognized as a powerful tool for identifying changes in ocean circulation and mixing on million year to millennial timescales unlike nutrient proxies such as 13 c or cd ca nd isotopes are not thought to be altered in any significant way by biological processes and thus they can serve as a quasi conservative water mass tracer however the application of nd isotopes in understanding the role of thermohaline circulation in rapid climate change is currently hindered by the lack of direct constraints on the signature of the north atlantic end member through time here we present the first results of nd isotopes measured in u th dated deep sea corals from the new england seamounts in the northwest atlantic ocean our data are consistent with the conclusion that the nd isotopic composition of north atlantic deep and intermediate water has remained nearly constant through the last glacial cycle the results address long standing concerns that there may have been significant changes in the nd isotopic composition of the north atlantic end member during this interval and substantiate the applicability of this novel tracer on millennial timescales for paleoceanography research

reconstructing deglacial north and south atlantic deep water sourcing using foraminiferal nd isotopes during the last few decades neodymium isotopes have been increasingly used as a paleoceanographic and paleoclimate proxy on million year through millennial time scales the widespread use of the nd isotope proxy depends on whether the nd isotopic composition of past seawater can be reliably extracted from authigenic sediment phases here we show evidence that planktonic foraminifera with authigenic coatings preserve a deep water nd isotopic signature and thus can be used to reconstruct past deep water nd isotopes applying this method downcore on south atlantic deep cape basin core tno57 21 41 1 s 7 9 e 4981 m the nd isotopic composition of the planktonic foraminiferal fe mn oxide coatings is identical with and confirms that of the reductively leached bulk sediment fraction piotrowski et al 2004 2005 2008 as reflecting changes in bottom water sourcing in the case of northeastern north atlantic core bofs 8k 52 5 n 22 1 w 4045 m the planktonic foraminiferal fe mn oxide coatings have different nd isotopes from reductive sediment leaches clearly acid reductive leaching must be tested in more detail we observe that the nd isotopic composition of the deep northeastern atlantic core shifted during the deglaciation from glacial values similar to the south atlantic cape basin towards holocene values similar to the bermuda rise roberts et al 2010 taken as a whole the nd isotope record from foraminiferal authigenic coatings suggests large scale changes in the proportion of northern and southern deep water sources occurred throughout the atlantic ocean with substantial chemical gradients at times during the last deglaciation

similar glacial and holocene deep water circulation inferred from southeast pacific benthic foraminiferal carbon isotope composition we present holocene and last glacial maximum lgm oxygen and carbon isotope measurements on planulina wuellerstorfi in six southeast pacific cores sedimentation rates are low in this part of the ocean and measurements were made on individual foraminiferal shells in order to identify the holocene and glacial individuals on the basis of their extreme 18o the new 13c data were combined with previous p wuellerstorfi data for interpretation of global thermohaline circulation data from the southern ocean were examined closely for regional coherency and a few anomalous 13c values suspected of having productivity overprint were removed the resulting global 13c distributions and gradients indicate that the deep water circulation was similar during the holocene and lgm this interpretation brings 13c data to a better agreement with cd ca data and marks a sharp contrast with a widely held view based on 13c measurements that the glacial southern ocean was the terminus of the thermohaline circulation the proposed presence of glacial north atlantic deep water does not necessarily contradict the postulated presence of glacial north atlantic intermediate water

neodymium and hafnium boundary contributions to seawater along the west antarctic continental margin highlights nd and hf are released from sediments to the water column in the amundsen sea embayment seawater nd and hf isotope compositions show opposed trends close to the marie byrd seamounts aabw is isotopically distinct in nd between the atlantic and the pacific sectors hf isotope variations occur between the sectors but not with depth in each sector abstract neodymium and hafnium isotopes and elemental concentrations sm nd hf zr have been measured in three water column profiles south of the antarctic circumpolar current in and to the east of the ross sea in conjunction with five bottom water samples from the amundsen sea embayment neodymium and hafnium both appear to be released from sediments in the embayment in the case of nd this is reflected in radiogenic isotope compositions endend up to 5 4 and highly elevated concentrations up to 41 pmol kg hafnium isotopes on the other hand are only very slightly altered relative to the open ocean sites and boundary release is most prominently indicated by elevated concentrations 1 pmol kg versus 0 7 pmol kg there is also a local input of both hf and nd at the marie byrd seamounts which leads to nd isotope compositions as radiogenic as 3 1 and hafnium shifted to less radiogenic compositions in local bottom water a compilation of the new data with literature data reveals a consistent view of the influence of antarctica on the nd isotope composition in lower circumpolar deep water lcdw and antarctic bottom water aabw sector specific nd addition shifts aabw formed in the atlantic sector to less radiogenic isotope compositions average end 9end 9 relative to lcdw average end 8 4end 8 4 whereas aabw in the pacific sector is shifted to more radiogenic values average end 7end 7 the evolution towards more radiogenic endend with depth in lcdw in the pacific sector is likely to reflect admixture of aabw but in addition is also controlled by boundary exchange with the slope as observed at the marie byrd seamounts hafnium isotopes are relatively homogeneous in the data set ranging between ehf 2ehf 2 and 3 8 for most samples excluding less radiogenic compositions in deep waters close to the marie byrd seamounts the hf isotope composition in the pacific sector is however slightly less radiogenic than in the atlantic corresponding to an average of 3 relative to an average of 3 8 this probably reflects unradiogenic hf inputs from antarctica to the pacific sector which are vertically homogenized by reversible scavenging the hf isotope heterogeneity in lcdw between both sectors is likely to indicate a shorter seawater residence time for hf than for nd which is consistent with the dissolved particulate phase partitioning of both elements

strong and deep atlantic meridional overturning circulation during the last glacial cycle extreme abrupt northern hemisphere climate oscillations during the last glacial cycle 140 000 years ago to present were modulated by changes in ocean circulation and atmospheric forcing1 however the variability of the atlantic meridional overturning circulation amoc which has a role in controlling heat transport from low to high latitudes and in ocean co2 storage is still poorly constrained beyond the last glacial maximum2 3 4 here we show that a deep and vigorous overturning circulation mode has persisted for most of the last glacial cycle dominating ocean circulation in the atlantic whereas a shallower glacial mode with southern sourced waters filling the deep western north atlantic prevailed during glacial maxima3 5 our results are based on a reconstruction of both the strength and the direction of the amoc during the last glacial cycle from a highly resolved marine sedimentary record in the deep western north atlantic parallel measurements of two independent chemical water tracers the isotope ratios of 231pa 230th and 143nd 144nd 6 7 8 which are not directly affected by changes in the global cycle reveal consistent responses of the amoc during the last two glacial terminations any significant deviations from this configuration resulting in slowdowns of the amoc were restricted to centennial scale excursions during catastrophic iceberg discharges of the heinrich stadials severe and multicentennial weakening of north atlantic deep water formation occurred only during heinrich stadials close to glacial maxima with increased ice coverage probably as a result of increased fresh water input in contrast the amoc was relatively insensitive to submillennial meltwater pulses during warmer climate states and an active amoc prevailed during dansgaard oeschger interstadials greenland warm periods

retreat of the laurentide ice sheet tracked by the isotopic composition of pb in western north atlantic seawater during termination 1 during the last glacial maximum much of north america was covered by the laurentide ice sheet its melting during termination 1 led to systematic changes in proglacial lake formation continental runoff and possibly north atlantic meridional overturning circulation the accompanying change in chemical weathering rates in the interior of north america throughout the deglaciation resulted in a pronounced change in seawater pb isotope composition in the western north atlantic ocean here we present the first high resolution records of seawater pb isotope variations of north atlantic deep water extracted from authigenic fe mn oxyhydroxides in three sediment cores 51ggc 1790 m depth 31ggc 3410 m depth 12jpc 4250 m depth from the blake ridge off florida these data reveal a striking excursion from relatively unradiogenic 206pb 204pb as low as 18 93 towards highly radiogenic pb isotope compositions that was initiated during the bolling allerod interstadial and was most pronounced in both intermediate and deep waters during and after the younger dryas 206pb 204pb as high as 19 38 at 8 8 ka in 4250 m this pattern is interpreted to be a direct function of increased inflow of continent derived radiogenic pb into the western north atlantic supplied through chemical weathering of north american rocks that had been eroded and freshly exposed during the preceding glacial cycle these sediment derived data are complemented by new laser ablation pb isotope data from a ferromanganese crust from the blake plateau at 850 m water depth which show only small glacial interglacial pb isotope variations of the florida current 206pb 204pb between 19 07 and 19 16 the lack of change in the blake plateau record at the same time as the radiogenic excursion in the deeper sediments supports a northern origin of the pulse of radiogenic pb after the younger dryas the deep western north atlantic has experienced a persistent highly radiogenic pb supply that was most pronounced during the first half of the holocene and still lasts until today

increased dust deposition in the pacific southern ocean during glacial periods dust deposition in the southern ocean constitutes a critical modulator of past global climate variability but how it has varied temporally and geographically is underdetermined here we present data sets of glacial interglacial dust supply cycles from the largest southern ocean sector the polar south pacific indicating three times higher dust deposition during glacial periods than during interglacials for the past million years although the most likely dust source for the south pacific is australia and new zealand the glacial interglacial pattern and timing of lithogenic sediment deposition is similar to dust records from antarctica and the south atlantic dominated by patagonian sources these similarities imply large scale common climate forcings such as latitudinal shifts of the southern westerlies and regionally enhanced glaciogenic dust mobilization in new zealand and patagonia

limits on conservative behavior of nd isotopes in seawater assessed from analysis of fish teeth from pacific core tops abstract neodymium nd isotopes have become an accepted water mass tracer for paleoceanographic reconstructions however high rates of radiogenic nd input from volcanic islands arcs in the western equatorial pacific wep and the subarctic north pacific sanp can significantly alter the isotopic composition of ambient seawaters leading to questions about the conservative nature of nd isotopes in the pacific here we present the first comprehensive study of nd isotopes preserved in core top fossil fish teeth debris from 31 sites in the pacific to define the vertical and horizontal distributions of seawater nd isotopes and to test the reliability of nd isotopes as a water mass tracer in the pacific we found that nd isotopic values of northward flowing lower circumpolar deep water lcdw are significantly modified in the western central equatorial pacific and the sanp as a result of local radiogenic inputs from young circum pacific island arcs consequently modified lcdw with 5 end is created in the central equatorial pacific while recirculated north pacific deep water npdw acquires a radiogenic nd isotope value 2 end in the sanp nd isotopic ratios of fish teeth debris in the central north pacific plotted against salinity or phosphate concentration from the overlying bottom water produce a mixing envelope between modified lcdw and npdw indicating that these nd isotopic values represent the southern and northern sourced end member values for the central north pacific and that mixing of these water masses defines vertical profiles of nd isotopes in this region in the eastern equatorial pacific eep three water masses modified lcdw npdwsanp and npdwwestern pacific combine to produce nd isotopic values that reflect this conservative mixture therefore nd isotopes behave as a conservative water mass tracer in the central north pacific and the eep but high rates of lithogenic inputs from young circum pacific island arcs compromise the conservative behavior of nd isotopes in the wep and sanp

rare earth elements and nd isotopes tracing water mass mixing and particle seawater interactions in the se atlantic abstract distributions of dissolved and particulate rare earth elements rees and seawater neodymium isotopic composition e nd were established in samples from the bonus goodhope bgh ipy geotraces cruise in the se atlantic sector of the southern ocean 36 s 13 e to 57 s 0 feb mar 2008 close to the south african continent in the subtropical domain particulate rees show the highest concentrations and flat paas normalized patterns clearly tracing their lithogenic origin active cerium oxidation onto suspended particles is evidenced by the mirror image relationship of the cerium anomaly between dissolved and particulate phases unradiogenic dissolved neodymium in surface waters e nd 17 1 traces the influence of old sedimentary material brought by the agulhas current and rings to the cape basin area a mass balance calculation suggests that the release of nd from dissolution of lithogenic material corresponds to a remobilization of 154 10 6 t of sediment per year i e 5 of the total sediment delivered to the southeast african coast annually at open ocean stations both dissolved and particulate rees present negative cerium anomalies indicating that particles have acquired a marine signature the increasing ree concentrations with depth and the strong linear correlations of dissolved ree with silica indicate that surface removal and deep re mineralisation of rees are partially related to the biogeochemical cycle of silicate which involves biogenic silica diatoms combined with marine carbonates these authigenic phases could explain the observed ree patterns in suspended particles except for la we suggest that the positive la anomalies in both phases are linked to the oceanic barium cycle and the partial dissolution of barite crystals especially in the polar frontal zone the e nd composition behaves conservatively in intermediate and deep waters while input processes affect the isotopic signal of subtropical surface waters and weddell gyre bottom waters an indian ocean and an atlantic variety of aaiw have been isotopically differentiated e nd 9 3 0 3 and e nd 8 0 0 5 respectively homogeneous signatures characterize circumpolar waters e nd from 8 2 to 8 4 for cdw a binary mixing model has been used to assess the contribution of undiluted nadw reaching southern latitudes

neodymium isotopic characterization of ross sea bottom water and its advection through the southern south pacific since the inception of the international geotraces program studies investigating the distribution of trace elements and their isotopes in the global ocean have significantly increased in spite of this large scale effort the distribution of neodymium isotopes 143nd 144nd end and concentrations nd in the high latitude south pacific is still understudied specifically north of the antarctic polar front apf here we report dissolved nd isotopes and concentrations from 11 vertical water column profiles from the south pacific between south america and new zealand and across the antarctic frontal system results confirm that ross sea bottom water rsbw is represented by an endvalue of 7 and for the first time show that these nd characteristics can be traced into the southeast pacific until progressive mixing with ambient lower circumpolar deep water lcdw dilutes this signal north of the apf that is endbehaves conservatively in rsbw opening a path for studies of past rsbw behavior neodymium concentrations show low surface concentrations and a linear increase with depth north of the apf south of the apf surface nd is high and increases with depth but remains almost constant below 1000m this vertical and spatial nd pattern follows the southward shoaling density surfaces of the southern ocean and hence suggests supply of nd to the upper ocean through upwelling of nd rich deep water low particle abundance due to reduced opal production and seasonal sea ice cover likely contributes to the maintenance of the high upper ocean nd south of the apf this suggests a dominant lateral transport component on nd and a reduced vertical control on nd concentrations in the south pacific south of the apf

southern ocean evidence for reduced export of north atlantic deep water during heinrich event 1 deep sea corals form unique high resolution archives of ocean circulation that can be dated using the decay of uranium to thorium they are abundant in the southern ocean and can provide unprecedented insights into ocean circulation and ocean chemistry on sub millennial time scales in areas where application of traditional paleoceanographic proxies is difficult here we present the first coupled neodymium nd isotope and radiocarbon data from deep sea corals in the drake passage southern ocean adding new constraints on ocean circulation during the last heinrich event h1 16 7 ka the modern day drake passage water column is homogeneous with respect to nd isotopes expressed in epsilon units nd its isotopic value of close to 9 is largely controlled by the mixture of north atlantic deep water and pacific deep water the aragonite of modern drake passage corals reflects this water column value whereas a fossil coral from h1 is significantly higher at 6 4 0 4 we interpret this 2 5 unit shift as a reduction in the influence of north atlantic sourced nd in the southern ocean during h1 this interpretation is supported by a series of radiocarbon analyses on the same sample and is consistent with a twofold or greater reduction in export of north atlantic waters from the atlantic basin combining analyses of radiocarbon and nd isotopes on u series dated deep sea coral skeletons holds great potential for quantification of past ocean ventilation rates

changes in east atlantic deepwater circulation over the last 30 000 years eight time slice reconstructions using 95 epibenthic 13c records eight time slices were reconstructed to trace the distribution of east atlantic deepwater and intermediate water masses over the last 30 000 years our results show that there have been three distinct modes of deepwater circulation near the stage 3 2 boundary the origin of north atlantic deep water nadw was similar to today mode 1 however after late stage 3 the source region of the nadw end member shifted from the norwegian greenland sea to areas south of iceland mode 2 a reduced nadw flow persisted during the last glacial maximum with constant preformed 13c values the nutrient content of nadw increased markedly near the azores fracture zone from north to south probably because of the mixing of upwelled antarctic bottom water aabw from below which then advected with much higher flux rates into the northeast atlantic later the spread of glacial meltwater over the north atlantic led to a marked short term ventilation minimum below 1800 m about 13 500 14c years ago mode 3 the formation of nadw recommenced abruptly north of iceland 12 800 12 500 years ago and reached a volume approaching that of the holocene in the younger dryas 10 800 10 350 years b p another short term shutdown of deepwater formation followed between 10 200 and 9 600 years b p linked to a further major meltwater pulse into the atlantic each renewal of deepwater formation led to a marked release of fossil co2 from the ocean the likely cause of the contemporaneous 14c plateaus over the last 9000 years deepwater circulation varied little from today apart from a slight increase in aabw about 7000 14c years ago it is also shown that the oxygenated mediterranean outflow varied largely independent of the variations in deepwater circulation over the last 30 000 years

preservation of seawater sr and nd isotopes in fossil fish teeth bad news and good news abstract we analyzed 87sr 86sr ratios in foraminifera pore fluids and fish teeth for samples ranging in age from eocene to pleistocene from four ocean drilling program sites distributed around the globe site 1090 in the cape basin of the southern ocean site 757 on the ninetyeast ridge in the indian ocean site 807 on the ontong java plateau in the western equatorial pacific and site 689 on the maud rise in the southern ocean sr isotopic ratios for dated foraminifera consistently plot on the global seawater sr isotope curve for sites 1090 757 and 807 sr isotopic values of the pore fluids are generally less radiogenic than contemporaneous seawater values as are values for fossil fish teeth in contrast pore fluid 87sr 86sr values at site 689 are more radiogenic than contemporaneous seawater and the corresponding fish teeth also record more radiogenic values thus sr isotopic values preserved in fossil fish teeth are consistently altered in the direction of the pore fluid values furthermore there is a correlation between the magnitude of the offset between the pore fluids and the seawater curve and the associated offset between the fish teeth and the seawater curve these data suggest that the hydroxyfluorapatite of the fossil fish teeth continues to recrystallize and exchange sr with its surroundings during burial and diagenesis therefore sr chemostratigraphy can be used to determine rough ages for fossil fish teeth in these cores but cannot be used to fine tune age models in contrast to the sr isotopic system our nd concentration data combined with published isotopic and rare earth element data suggest that fish teeth acquire nd during early diagenesis while they are still in direct contact with seawater the concentrations of nd acquired at this stage are extremely high relative to the concentrations in surrounding pore fluids as a result nd isotopes are not altered during burial and later diagenesis therefore fossil fish teeth from a variety of marine environments preserve a reliable and robust record of deep seawater nd isotopic compositions from the time of deposition

neodymium isotopic composition of intermediate and deep waters in the glacial southwest pacific abstract neodymium nd isotopes tracers of deep water mass source and mixing were measured on sedimentary planktic foraminifera with authigenic coatings from a depth transect of cores 1400 4800 m from chatham rise in the southwest pacific over the past 30 ka we observe deglacial variations in the nd isotopic composition which showed an average glacial composition of e nd 5 0 1 0 3 n 4 for cores sites below 3200 mbsl no significant deglacial variation was observed in the nd isotopic composition of intermediate depth waters 1400 mbsl in contrast with benthic foraminifera c 13 data the deglacial e nd shift of cdw in the southwest pacific is consistent with changes observed in the deep south atlantic and equatorial indian ocean but e nd values are offset by 1 e nd unit to more radiogenic values throughout the deglacial records likely due to admixture of a nd isotope signal which was modified in the southern ocean or pacific perhaps by boundary exchange however this modification did not overprint the deglacial nd isotope change the consistent deglacial evolution of e nd in the south atlantic equatorial indian and southwest pacific cdw is evidence for the connection of cdw during the glacial and propagation of diminished north atlantic deep water export to the glacial southern ocean in contrast spatial heterogeneities in the benthic foraminifera c 13 of cdw have been observed in the atlantic indian and pacific basins of the deep glacial southern ocean the nd isotope data implies a well connected deep southern ocean which transported waters from the atlantic to the indian and pacific oceans during the glacial this suggests that basin scale variability in the glacial c 13 composition of cdw was unrelated to circulation changes

modelling nd isotopes with a coarse resolution ocean circulation model sensitivities to model parameters and source sink distributions the neodymium nd isotopic composition nd of seawater is a quasi conservative tracer of water mass mixing and is assumed to hold great potential for paleoceanographic studies here we present a comprehensive approach for the simulation of the two neodymium isotopes 143nd and 144nd using the bern3d model a low resolution ocean model the high computational efficiency of the bern3d model in conjunction with our comprehensive approach allows us to systematically and extensively explore the sensitivity of nd concentrations and nd to the parametrisation of sources and sinks previous studies have been restricted in doing so either by the chosen approach or by computational costs our study thus presents the most comprehensive survey of the marine nd cycle to date our model simulates both nd concentrations as well as nd in good agreement with observations nd covaries with salinity thus underlining its potential as a water mass proxy results confirm that the continental margins are required as a nd source to simulate nd concentrations and nd consistent with observations we estimate this source to be slightly smaller than reported in previous studies and find that above a certain magnitude its magnitude affects nd only to a small extent on the other hand the parametrisation of the reversible scavenging considerably affects the ability of the model to simulate both nd concentrations and nd furthermore despite their small contribution we find dust and rivers to be important components of the nd cycle in additional experiments we systematically varied the diapycnal diffusivity as well as the atlantic to pacific freshwater flux to explore the sensitivity of nd concentrations and its isotopic signature to the strength and geometry of the overturning circulation these experiments reveal that nd concentrations and nd are comparatively little affected by variations in diapycnal diffusivity and the atlantic to pacific freshwater flux in contrast an adequate representation of nd sources and sinks is crucial to simulate nd concentrations and nd consistent with observations the good agreement of our results with observations paves the way for the evaluation of the paleoceanographic potential of nd in further model studies

rare earth element transport in the western north atlantic inferred from nd isotopic observations the isotopic composition of nd in the water column from several western north atlantic sites and formational areas for north atlantic deep water shows extensive vertical structure at all locations in regions where a thermocline is well developed large isotopic shifts 2 to 3 units are observed across the base of the thermocline regions without a thermocline are characterized by much more gradual shifts in isotopic composition with depth in general the data reveal an excellent correlation between the nd isotopic distribution in the western north atlantic water column and the distribution of water masses identified from temperature and salinity characteristics nadw as identified from t s properties is also characterized by a well defined isotopic composition having nd 0 13 5 0 5 this signature is associated with waters identified as nadw from high latitudes near formational areas in the labrador sea down to the equatorial region the isotopic signature of nadw would appear to be formed by a blend of more negative waters originating in the labrador sea nd 0 18 and more positive waters originating in the overflows from the norwegian and greenland seas nd 0 8 to 10 and is consistent with classical theories on the formation of nadw the isotopic signature of nadw is propagated southward to the equator where it is gradually being thinned out by mixing from above and below with more radiogenic nd associated with northward spreading antarctic intermediate and bottom waters the preservation of the isotopic signature of nadw over these large distances indicate that the ree undergo extensive lateral transport the isotopic composition of nd is largely conservative over the time scales of mixing within the atlantic in spite of the intrinsic nonconservative behavior of neodymium nd concentration gradients generally show surface waters to be depleted in nd relative to deep waters which must require vertical transport processes however isotopic differences in the water column preclude the local downward transport of ree from the surface into underlying deep waters as a simple explanation of the concentration gradient the apparent decoupling of ree in nadw from overlying local surface waters and the increasing concentration with depth provide a conflict with simple vertical transport mechanisms that is not yet resolved

evidence from southern ocean sediments for the effect of north atlantic deep water flux on climate evidence from southern ocean sediments for the effect of north atlantic deep water flux on climate