alternating field characteristics of pseudo single domain 2 14 μm and multidomain magnetite abstract we report normalized af demagnetization curves of anhysteretic remanences arm s produced by 1 10 and 40 oe steady fields and of saturation isothermal remanence irm s in a suite of dispersed unannealed magnetite powders with median sizes of 2 4 6 10 and 14 m pseudo single domain or psd size range and 100 m multidomain or md size interpreted in the light of the domain structure test first proposed by lowrie and fuller 12 the relative stability trend of curves for the 2 m sample is of single domain sd type the 1 oe arm being most resistant to demagnetization followed by the 10 oe and 40 oe arm s and irm s for the 100 m sample the trend is exactly reversed and is of md type in the 4 14 m samples hitherto undescribed transitional trends between sd type and md type occur at 6 m 1 oe 10 oe and 40 oe arm s preserve an sd type trend but for all af s 75 oe irm s is more resistant than any of these remanences at 10 m this trend is unmistakable and only at 14 m do the 1 oe 10 oe and 40 oe arm curves merge we conclude 1 that the lowrie fuller test distinguishes between small md grains enhanced by psd remanence and large md grains lacking psd remanence rather than between sd and md structures per se and 2 that in the psd transition region from 6 to 14 m in magnetite irm s changes over to md type relative stability around 6 m whereas 10 oe and 40 oe arm s achieve an md type trend around 14 m in accord with the predicted field dependence of the psd threshold size our theoretical interpretation assumes that the intrinsic internal field coercive force spectra of weak field and strong field remanences are identical but that the observed external field spectrum is shifted to lower fields as a result of the internal demagnetizing field nj r of the remanence j r the effect is slight for weak field j r s but substantial for irm s since all coercivities high as well as low are shifted the result of the lowrie fuller test is determined simply by the shape of the intrinsic coercivity spectrum or the corresponding af demagnetization curve depending on the model of self demagnetization used either subexponential or sublinear af decay curves of weak field remanence will automatically lead to an md type trend whereas by either model the decay curves that characterize sd and psd remanences decaying slowly initially and then more rapidly will always produce and sd type trend

diagenetic fate of biogenic soft and hard magnetite in chemically stratified sedimentary environments of mamangua ria brazil d r and l j acknowledge funding from fapesp grants 2012 212123 and 2011 22018 3 respectively f a acknowledges funding from faperj cnpq and capes a p r acknowledges funding from the australian research council grants dp140104544 and dp160100805

a high resolution paleointensity stack of the past 14 to 68 ka from black sea sediments abstract detailed paleo and mineral magnetic analyses of a sediment composite record from the southeastern black sea yielded a high resolution well dated paleointensity record though hampered by some larger hiatuses in some cores and contaminated by diagenetically formed greigite the paleomagnetic composite record obtained from the preserved primary detrital magnetite phase reflects a highly dynamic geomagnetic field during the last glacial period relative variations of paleointensity inferred from the sediments magnetisations were converted into a record of the virtual axial dipole moment vadm lowest vadm values are linked with the laschamp 0 50 10 22 a m 2 at 41 0 ka the norwegian greenland sea 1 5 10 22 a m 2 at 64 5 ka and the mono lake 3 0 10 22 a m 2 at 34 5 ka geomagnetic excursions the fully reversed field during the laschamp excursion exhibits a vadm of 2 0 10 22 a m 2 which is more than 25 of the present day axial dipole moment 7 628 10 22 a m 2 rates of change calculated from the black sea vadm record also give some information on how to assess the global decay of the present day geomagnetic field which is significantly enhanced in the area of the south atlantic anomaly comparison with provided c 14 and 10 be records confirm partly in the very detail the non linear anti correlation of geomagnetic field intensity and the production of cosmogenic radionuclides in the earth s upper atmosphere however discrepancies in the timing of lows and highs in the compiled records points out that the combination of different data sets from different archives remains a challenge

increased productivity in the eastern equatorial pacific during the last glacial maximum 19 000 to 14 000 yr b p a widespread pronounced enrichment in the organic carbon content occurs at shallow depths in eastern equatorial pacific sediments the c org peak is shown by radiocarbon dating to be temporally coincident with the last stage 2 or wisconsin glacial maximum in contrast caco 3 profiles show less overall variation which appears to be partly a function of the location of the sediments relative to the lysocline consideration of the iodine c org ratio in the sediments rules out enhanced preservation as a cause of the stage 2 organic carbon enrichment the peak instead must have resulted from a significant increase in productivity during the glacial maximum

the upper and lower nunivak sedimentary geomagnetic transitional records from southern sicily van hoof a a m van os b j h and langereis c g 1993 the upper and lower nunivak sedimentary geomagnetic transitional records from southern sicily phys earth planet inter 77 297 313 the detailed paleomagnetic records of the upper and lower nunivak polarity transitions have been determined from pliocene marine marls in southern sicily magnetites are the most important carrier of the remanence in both records the transitions are recorded in two components a low temperature and a high temperature component the two components do not represent the geomagnetic field because the changes in these components take place at lithological boundaries in addition the directional changes do not completely match directional changes of the same transitions recorded in calabria some 250 km away the character of the virtual geomagnetic poles paths is probably caused by smoothing of the stable directions before and after the transitions the directional changes as well as the smoothing mechanism can be explained by the diagenetic magnetite formation model van hoof et al 1992 in which shortly after burial the remanence carried by newly formed secondary magnetites is superposed on the initial remanence carried by primary magnetite

sedimentation at manop site h eastern equatorial pacific over the past 400 000 years climatically induced redox variations and their effects on transition metal cycling gravity cores recovered from manganese nodule project site h 6 33 n 92 49 w show marked downcore variations in the abundance of calcium carbonate organic carbon opal manganese and other components deposited over the past 400 000 years variations in the downcore abundance of organic carbon which ranges from 0 2 to 1 0 can be used to hindcast redox conditions in the surface sediments over this time the results indicate that the depth to the manganese redox boundary varied from about 5 to 25 cm below the seafloor during four major cycles downcore variations in solid phase mn ni and cu can be produced by such changes in redox conditions a model which predicts that solid phase mn can be trapped and buried when the mn redox boundary migrates rapidly upward is consistent with the observed organic carbon and mn records and supports the reconstructed redox variations the history of redox variations at site h can be explained by changes with time in surface water productivity major productivity variations at the site occur over 100 kyr cycles with relatively higher productivity occurring during glacial stages thus quaternary climate changes influence surface water productivity redox conditions in sediments and the cycling of transition metals

quantitative extraction and analysis of carriers of magnetization in sediments we have applied an integrated procedure for quantitative magnetic mineral extraction based on the separation method of petersen von dobeneck vali 1986 to a range of sediment types to examine the efficiency and representative nature of the extraction process carriers of magnetization have been identified by rock magnetic measurements microscopy and x ray diffraction quantification of the extraction efficiencies is achieved by before and after extraction rock magnetic measurements susceptibility anhysteretic and isothermal remanences these magnetic measurements show that our modified extraction method extracts large proportions of the magnetization carriers in a range of sediment types e g over 75 per cent for magnetite dominated sediments the extraction efficiency is dependent on the sample magnetic mineralogy and whether the magnetic grains occur as discrete grains or as inclusions within host grains susceptibility extraction efficiencies are strongly dependent on whether the susceptibility is of paramagnetic or ferrimagnetic origin the amount of material recovered in the extract shows some inverse correlation with the density of the sediment suspension used during extraction in terms of the mineralogies extracted we identify a diverse and complex range of mineral assemblages all sizes of discrete grains of magnetite are extracted including single domain and superparamagnetic grains and chains of bacterial magnetite other commonly extracted iron and titanium oxides are haematite and ilmenite ferrimagnetic chromites and sulphides were also obtained from some samples considerable amounts of quartz and feldspar are extracted due to the presence of magnetic inclusions within these diamagnetic host grains in the deep sea sediments we examined feldspars constitute a large proportion of the extracts but are significantly less abundant in other sediments where quartz is dominant a wide variety of paramagnetic minerals was identified in the extracts including pyroxenes amphiboles chlorites micas mg cr spinels garnets ti oxides apatites tourmaline and zircon many of which contain ferrimagnetic inclusions possibly less than 0 1 m in grain size dissolution of ultrafine grains of magnetite during pre extraction carbonate dissolution as suggested by sun jackson 1994 does not occur in our samples

geochemical and sedimentological control of the magnetic properties of hemipelagic sediments owing to their high sedimentation rates and wide areal extent hemipelagic sediments along continental borderlands are potentially important high resolution recorders of geomagnetic secular variation to assess this possibility we studied suboxic hemipelagic muds from the oregon continental slope and anoxic laminated diatomaceous oozes from the gulf of california these sediments were rapidly deposited with average sedimentation rates of 121 and 135 cm kyr respectively bulk sediment sedimentological and geochemical analyses indicate that the two areas represent contrasting depositional regimes the remanence in both environments resides in fine grained magnetite particles although minor amounts of hematite were observed in the topmost gulf of california sediments despite first order differences the sediments from both areas show similar downcore patterns of systematic increases in solid sulfur mainly as pyrite dramatic decreases in natural nrm anhysteretic and isothermal remanent magnetization intensities and accompanying shifts in the magnetic stabilities these changes are consistent with reduction and dissolution of the ferrimagnetic iron oxides with depth due to early diagenesis of organic matter the magnetic grain size distribution first appears to rapidly coarsen downcore as the smallest and most abundant grains are removed then slowly grows finer as the remaining particles dissolve no evidence was observed for authigenic formation of magnetite provided sufficient concentration and stability of the detrital magnetic particles paleomagnetic directions can survive this dissolution diagenesis however relative paleointensity determinations based on normalization of nrm by concentration in related parameters will give erroneous estimates of paleofield behavior in such diagenetically altered sediments

mineral magnetic properties of holocene sediments in the subaqueous yangtze delta and the implications for human activity and early diagenesis abstract this study examines the temporal and spatial distribution of magnetic properties in holocene sediment cores taken from the subaqueous yangtze delta china to evaluate depositional environmental changes including the sediment with an anthropogenic provenance and changes in the bottom water chemistry our approach is to compare the magnetic properties in holocene cores with those from a suite of surficial sediment samples taken at various locations from the yangtze delta and the adjacent continental shelf the results indicate that the magnetic properties in sediment cores change generally with sedimentary facies mainly due to their in phase changes with sediment grain size and redox conditions but that they have also been significantly altered by effects of human activity and early diagenesis magnetic parameters that exhibit soil erosion associations show remarkable increases over the past 800 years reflecting an increase in the terrestrial supply of fine grained magnetic minerals induced by the intensification of human activity in the yangtze river catchment early diagenesis was strong in core hzk8 located at the depocenter of the subaqueous yangtze delta including dissolution of fine grained ferrimagnetic minerals and the precipitation of authigenic greigite and pyrite as evidenced by both room temperature and thermo magnetic analyses the dissolution of ferrimagnetic minerals coincides with changes in sedimentation rate at different sites and time periods suggesting that this factor is important for controlling the rate of early diagenesis authigenic iron sulfides suggest the function of sulfate reducing bacteria which implies a hypoxic environment at this site from 6000 cal yr bp

magnetofossils in the sediment of lake baikal siberia abstract a multidisciplinary approach involving rock magnetics transmission electron microscopy and x ray diffraction was used to identify a biogenic magnetite component in the lake baikal siberia sedimentary magnetic record the distinctive biogenic component to the magnetic record occurs as chains of single domain elongate hexagonal and tear drop cone shaped magnetite particles these magnetofossils are inferred to be magnetosomes produced by magnetotactic bacteria living in the surficial sediment throughout lake baikal postdepositional reduction diagenesis results in the loss of the fine grained magnetofossils at depth in addition this study shows that the fine grained magnetofossils are removed by the process of storage diagenesis during long periods 21 months of core storage which results in a change to a coarser grained slightly higher coercivity bulk magnetic mineral assemblage although the lake baikal sedimentary magnetic record has several distinct and complex components by determining their origin this study has shown that the sediments are well suited for environmental magnetic study

magnetotactic bacteria and their magnetofossils in sediments abstract living magnetotactic bacteria from freshwater environments show under natural and laboratory conditions a great variety of morphological appearances their magnetosomes vary in number shape and size one species of bacteria yields up to 1000 magnetosomes per cell individual particles reach a size of up to 200 nm as a rule they form elongated chains in bacteria which are held under laboratory conditions loop shaped arrangements and nearly unordered clusters are also found during the laboratory experiments different species of bacteria periodically dominated freshwater samples always exhibited a great variety of different magnetosomes on the other hand samples from marine environment clearly showed the preponderance of one type of particle these observations may reflect specific properties of the physico chemical milieu in which the bacteria grew at the end of our experiments north and south seeking bacteria co existed in roughly equal quantities quaternary unconsolidated sediments from the ammersee bavaria and the antarctic quaternary to tertiary deep sea sediments from the atlantic and pacific and jurassic limestones from the sonnwendgebirge tyrol austria were analyzed for fossil magnetosomes we found that fossil magnetosomes were morphologically similar to those from living bacteria but seemed to be corroded in some cases the observed differences in quantity size and shape of magnetosomes from various sediments may be influenced by variations in bacterial viability and particle stability at different sites but are not determined by geographical latitude

fossil bacterial magnetite in deep sea sediments from the south atlantic ocean the magnetostratigraphy of deep sea sediment cores has proven to be a powerful and high resolution method of dating and comparing sedimentary records in contrast to this widespread application relatively few attempts have been made to analyse and identify the mineralogy grain size and origin of the carrier of the remanent magnetization1 2 it is widely assumed that dominant ferrimagnetic minerals in deep sea sediments are of lithogenic origin that is that they derive from oceanic or continental detritus volcanic ashfalls micrometeorites hydrothermal precipitation or chemical mineralization processes a very different view was taken by kirschvink and lowenstam3 who suggested that fossil remnants of magnetite mineralizing organisms in particular magnetotactic bacteria might play an important part in the magnetization of sediments deposited in certain detritus poor aquatic systems we have used rock magnetic diagnostic methods to characterize the magnetic phases in deep sea sediments from the south atlantic these phases were then extracted and studied with the electron microscope our results indicate that fossil bacterial magnetite is the main carrier of the natural remanent magnetization in sediments ranging in age from quarternary to eocene different types of bacterial magnetosomes were detected most of them occurring in chains of identical particles and nearly all of them falling into the theoretically determined4 size range of single domain magnetitite

the upper kaena sedimentary geomagnetic reversal record from southern sicily a detailed paleomagnetic and rock magnetic record of the upper kaena polarity reversal was determined from late pliocene marine marls in southern sicily two separate characteristic magnetization components were distinguished a low temperature lt component between 200 and 50 c and a high temperature ht component between 500 and 580 610 c the two components record the reversal in a slightly different way but both were acquired in an early stage following deposition most probably by authigenic biogenic formation of magnetic minerals the actual r n reversal via e and horizontal inclinations seems to take 3 3 kyr and is followed by a stable normal interval 3 3 kyr and subsequently by a significant excursion 50 60 in declination 3 6 kyr relative intensities were lower during a time span of 5 6 kyr and show a minimum of 10 of the nontransitional values but during the excursion no intensity changes are apparent the vgps of the ht component are confined to a longitude between india and australia those of the lt component oscillate between this same longitude and one passing over north and south america we conclude that most if riot all observed features are largely determined by the remanence acquisition process which is complicated by authigenic formation of magnetic minerals and cyclically fluctuating paleoredox conditions this has not only resulted in considerable smoothing but also in delayed nrm acquisition in specific sedimentary intervals we believe that the observed excursion is a sedimentary artifact and not related to geomagnetic field behavior during transitions we emphasize that many reported geomagnetic features may in fact be due to the sedimentary remanence acquisition process

a 600 years warm season temperature record from varved sediments of lago plomo northern patagonia chile 47 s abstract high resolution records of calibrated proxy data for the past millennium are fundamental to place current changes into the context of pre industrial natural forced and unforced variability although the need for regional spatially explicit comprehensive reconstructions is widely recognized the proxy data sources are still scarce particularly for the southern hemisphere and especially for south america we present a 600 year long warm season temperature record from varved sediments of lago plomo a proglacial lake of the northern patagonian ice field in southern chile 46 59 s 72 52 w 203 m a s l the thickness of the bright summer sediment layer relative to the dark winter layer measured as total brightness reflectance 400 730 nm is calibrated against warm season sondjf temperature 1900 2009 r 0 58 p aut 0 056 re 0 52 ce 0 15 rmsep 0 28 c five year triangular filtered data in lago plomo warm summer temperatures lead to enhanced glacier melt and suspended sediment transport which results in thicker light summer layers and to brighter sediments although patagonia shows pronounced regional differences in decadal temperature trends and variability the 600 years temperature reconstruction from lago plomo compares favourably with other regional continental temperature records but also emphasizes significant regional differences for which no data and information existed so far these regional differences seem to be real as they are also reflected in modern climate data sets 1900 2010 the reconstruction shows pronounced subdecadal multidecadal variability with cold phases during parts of the little ice age 16th and 18th centuries and in the beginning of the 20th century the most prominent warm phase is the 19th century which is as warm as the second half of the 20th century the exceptional summer warmth ad 1780 1810 is also found in other archives of northern patagonia and central chile our record shows the delayed 20th century warming in the southern hemisphere the comparison between winter precipitation and summer temperature inter seasonal coupling from lago plomo reveals alternating phases with parallel and contrasting decadal trends of winter precipitation and summer temperature positive and negative running correlations r winter pp summer tt this observation from the sediment proxy data is also confirmed by two sets of reanalysis data for the 20th century reanalysis data show that phases with negative correlations between winter precipitation and summer temperature e g dry winters and warm summers at lago plomo are characteristic for periods when circumpolar westerly flow is displaced southward and enhanced around 60 s

relative paleointensity of the geomagnetic field during the brunhes chron abstract we conducted a paleomagnetic study of four sediment cores taken from different regions in the low latitudes of the pacific ocean in order to recover relative paleointensity variations during the brunhes chron three cores have good age control from oxygen isotope stratigraphy we extensively examined rock magnetic uniformity by the iso thermal remanent magnetization irm acquisition and the alternating field demagnetization of the anhysteretic remanent magnetization arm and the irm only rock magnetically homogeneous sediments were used biogenic magnetites were found in all but one core and their dissolution in early diagenesis was not significant the four cores showed coherent variations of the remanent intensity normalized by the arm implying that these variations represent the behavior of the geomagnetic field long term paleointensity variations during the brunhes chron are characterized by an asymmetric pattern rapid increases in the intensity occurred just after the brunhes matuyama transition in the mid brunhes from about 500 to 400 ka and during the last 100 ka and gradual decreases between them the first one supports the idea of rapid regeneration of the geomagnetic field after polarity reversals 1 the other two may have been triggered by very short polarity reversals

magnetite diagenesis in marine sediments from the oregon continental margin the magnetochemistry of sediments from the oregon continental margin is examined to determine the effects of iron sulfur diagenesis on the paleomagnetic record magnetic mineral dissolution and transformation into iron sulfides are a common feature in these suboxic to anoxic lutites these processes are evidenced in rapid decreases in natural remanent magnetization intensities and stabilities systematic changes in other rock magnetic properties and increases in solid phase sulfur concentrations with depth hysteresis measurements are used to evaluate downcore changes in magnetite concentration and grain size magnetite abundances decrease downcore from initial values of about 0 1 and nominal grain diameters lie within a narrow pseudosingle domain range of 0 08 to 0 6 m a first order surface area reaction model da dt ka is proposed to explain the magnetite dissolution mechanism where a is the total magnetite surface area and k is the rate constant the solution of this equation predicts that the surface area and concentration decrease exponentially and the concentration in addition depends on grain size application of this model in two cores where grain size varies with depth successfully explains the downcore profiles of both concentration and surface area despite extensive magnetite destruction magnetic directions in such sediments appear to reliably record long wavelength trends of the geomagnetic field

effects of diagenesis on magnetic mineralogy in a jurassic claystone limestone succession from the paris basin we performed detailed rock magnetic and geochemical analyses on a previously published early jurassic magnetostratigraphic section the results improve our understanding of acquisition and preservation processes of magnetization in a series of alternating claystones and limestones the main carrier of magnetization is magnetite anhysteretic remanent magnetization arm varies by a factor of 40 and the arm variations are linked to magnetite grain size comparison of magnetic and geochemical data shows that when carbonate content is high 30 and 13 c0 magnetite is characterized by small grain sizes whereas when carbonate content is low 20 magnetite is coarse grained it appears that the oxidation of organic matter by sulfate reduction controls both 13 c and magnetite grain size h 2 s produced during sulfate reduction causes partial dissolution of magnetite grains with the finest magnetite grains those that best record the magnetic signal being dissolved first despite this partial dissolution both the direction and polarity of the original remanent magnetization are preserved

environmental magnetism principles and applications 1 in environmental magnetism rock and mineral magnetic techniques are used to investigate the formation transportation deposition and postdepositional alterations of magnetic minerals under the influences of a wide range of environmental processes all materials respond in some way to an applied magnetic field and iron bearing minerals are sensitive to a range of environmental processes which makes magnetic measurements extremely useful for detecting signals associated with environmental processes environmental magnetism has grown considerably since the mid 1970s and now contributes to research in the geosciences and in branches of physics chemistry and biology and environmental science including research on climate change pollution iron biomineralization and depositional and diagenetic processes in sediments to name a few applications magnetic parameters are used to routinely scan sediments but interpretation is often difficult and requires understanding of the underlying physics and chemistry thorough examination of magnetic properties and of the environmental processes that give rise to the measured magnetic signal is needed to avoid ambiguities complexities and limitations to interpretations in this review we evaluate environmental magnetic parameters based on theory and empirical results we describe how ambiguities can be resolved by use of combined techniques and demonstrate the power of environmental magnetism in enabling quantitative environmental interpretations we also review recent developments that demonstrate the mutual benefit of environmental magnetism from close collaborations with biology chemistry and physics finally we discuss directions in which environmental magnetism is likely to develop in the future

paleomagnetic evidence for fossil biogenic magnetite in western crete abstract previous paleomagnetic research has shown that the concentration of fine grained magnetite preserved in miocene marine clays of western crete drops during two successive geomagnetic transitions although the mechanism responsible for this effect was not known magnetite precipitation by magnetotactic bacteria offers a straightforward explanation for this decrease reduced field strengths during a reversal will strain the competitive advantage of having intracellular magnetite and will force bacteria to precipitate correspondingly more magnetite if they are to maintain the same alignment in the geomagnetic field their ability to do this is limited by several magnetophysical constraints which should act to reduce the numbers of magnetite precipitating cells particularly in fields of less than about 12 of the present level this would lead to a decrease in the supply of bacterial magnitude to the sediments recovery of intact magnetotactic bacterial fossils may lead to a new method for estimating paleointensities from sedimentary rocks

magnetotactic bacteria and single domain magnetite in hemipelagic sediments remanent magnetism in marine sediments has been used extensively over the past twenty years to calibrate the geological time scale study geomagnetic reversals and secular variation and measure the rates of seafloor spreading although these sediments may contain different magnetic minerals magnetite is the most commonly observed and magnetically stable phase and its size shape and post depositional fate affect the magnetic remanence of the sediments biogenic magnetites are single domain with a high natural magnetic remanence nrm and have been suggested as a significant source of magnetic remanence in marine sediments we have studied surface sediments from the santa barbara basin and report the occurrence of living magnetotactic bacteria and the deposition of biogenic ultra fine grained single domain magnetite using a novel extraction technique transmission electron microscopy and squid magnetometry we show that these bacteria and the magnetite they produce are the major source of stable remanent magnetism in these sediments

authigenic magnetite formation in suboxic marine sediments the resolution and reliability of magnetostratigraphy and reconstructed time series of geomagnetic field behaviour depend critically on where remanence is acquired and fixed in the sediment column and whether the magnetization is altered chemically after deposition if authigenic magnetic minerals are formed at depth or if the magnetic carriers are changed after deposition then the nature and timing of magnetic events can be affected by depth offsets in remanence acquisition and mixing of detrital and authigenic signals using palaeo and rock magnetic and sediment geochemical analyses we have studied how early diagenesis affects the magnetic properties of suboxic hemipelagic sediments here we report evidence of the formation of fine grained authigenic magnetites near the commonly observed brown tan green colour boundary which marks the transition from fe oxidizing to fe reducing conditions we propose that biogenic magnetite produced by magnetotactic bacteria forms as part of the microbially mediated sequence of reactions involved in the oxidation of organic matter the magnetite is created as a metabolic by product of the microorganisms use of iron redox transitions as a source of energy active magnetite formation appears to be restricted to a zone between the levels of nitrate and iron reduction

environmental magnetism past present and future environmental magnetism involves the application of rock and mineral magnetic techniques to situations in which the transport deposition or transformation of magnetic grains is influenced by environmental processes in the atmosphere hydrosphere and lithosphere the first explicit description of environmental magnetism as a distinct field was in 1980 since that time environmental magnetism has become a broad field that is finding application in an ever increasing array of scientific disciplines in this review of the present state of environmental magnetic studies we divide the field into three broad but arbitrary categories the first involves the use of mineral magnetic assemblages in the geological record to study physical processes in depositional environments this category includes the correlation of sediment cores using magnetic susceptibility measurements studies of geomagnetic field behavior the analysis of depositional and postdepositional mechanical processes that affect sediments and the examination of magnetic parameters that might represent proxies for paleoclimatic variation the second category encompasses studies of the processes responsible for variations in the magnetic minerals brought into a sedimentary environment these provenance investigations include studies of changes in catchment derived sediment in lakes fluctuations in contributions from terrigenous aeolian and glaciogenic components in deep sea sediments and the origin of atmospheric particulates the final category addresses in situ changes and transformations of magnetic minerals in sedimentary environments including pedogenesis authigenetic diagenetic formation of ferrimagnetic phases dissolution of magnetic minerals due to reductive diagenesis and contributions of biomagnetism to sedimentary magnetism because environmental magnetism can address problems in so many disciplines and because many of these problems may be inaccessible to other techniques it is likely that the scope of environmental magnetism will continue to expand rapidly environmental magnetism is capable of providing important data for studies of global environmental change climatic processes and the impact of humans on the environment all of which are major research initiatives in the international scientific community these factors suggest that environmental magnetism has a bright and diverse future

elongated prismatic magnetite crystals in alh84001 carbonate globules potential martian magnetofossils using transmission electron microscopy tem we have analyzed magnetite fe 3o 4 crystals acid extracted from carbonate globules in martian meteorite alh84001 we studied 594 magnetites from alh84001 and grouped them into three populations on the basis of morphology 389 were irregularly shaped 164 were elongated prisms and 41 were whisker like as a possible terrestrial analog for the alh84001 elongated prisms we compared these magnetites with those produced by the terrestrial magnetotactic bacteria strain mv 1 by tem again we examined 206 magnetites recovered from strain mv 1 cells natural darwinian selection in terrestrial magnetotactic bacteria appears to have resulted in the formation of intracellular magnetite crystals having the physical and chemical properties that optimize their magnetic moment in this study we describe six properties of magnetite produced by biologically controlled mechanisms e g magnetotactic bacteria properties that collectively are not observed in any known population of inorganic magnetites these criteria can be used to distinguish one of the modes of origin for magnetites from samples with complex or unknown histories of the alh84001 magnetites that we have examined the elongated prismatic magnetite particles 27 of the total are indistinguishable from the mv 1 magnetites in five of these six characteristics observed for biogenically controlled mineralization of magnetite crystals

rock magnetism of late neogene and pleistocene deep sea sediments relationship to sediment source diagenetic processes and sediment lithology we use bivariate scatter plots to illustrate variations in selected rock magnetic properties low field susceptibility anhysteretic and isothermal remanence of late neogene and pleistocene deep sea sediments from 16 sites in the arctic ocean north atlantic equatorial atlantic and north pacific ocean and the arabian sea our intention is to examine the ability of the rock magnetic properties to differentiate the sediments according to factors such as lithology geographical area and the dominant mode of terrigenous sedimentation which at these sites is via ice rafting via bottom currents or via eolian processes overall correlations between sediment magnetic properties and gross lithology is poor and factors such as the source and transport path of terrigenous sediment and detrital magnetic minerals together with the action of reductive diagenetic processes are the major controls on the magnetic properties on the bivariate scatter plots sites with major ice rafted contributions tend to have high sedimentary ferrimagnetic mineral concentrations relatively coarse ferrimagnetic grain sizes and scattered sample point distributions in contrast sites where we infer significant bottom current supply of terrigenous material have tightly grouped sample point distributions carbonate sediments in which the terrigenous component is supplied by eolian processes tend to have a broad range of magnetic mineral concentration caused by glacial interglacial fluctuations in carbonate accumulation and eolian activity sediments containing significant volcanogenic material have high concentrations of relatively coarse grained ferrimagnetic material reductive diagenesis is a significant determinant of sediment magnetic properties in high productivity areas and has the effect of preferentially removing the fine grained ferrimagnetic fraction causing a coarsening of the ferrimagnetic grain size distribution and a rise in the antiferromagnetic ferrimagnetic ratio

magnetostratigraphic dating of shallow water carbonates from san salvador bahamas magnetostratigraphic results are reported here from a sequence of late neogene quaternary shallow water carbonate sediments from a continuous core drilled on the island of san salvador bahamas on the basis of the remanent magnetism of 136 samples from a 91 m measured section of core the polarity sequence can be correlated with the magnetic polarity time scale from the gilbert chron early pliocene through the late brunhes chron late pleistocene holocene magnetic polarities were determined on the basis of relative up down direction in the unoriented core extraction studies of the magnetic particles reveal the presence of single domain crystals of magnetite resembling those produced by the magnetotactic bacteria and algae the sequence of reversals provides a minimum of six new major chronostratigraphic markers for the pliocene pleistocene of the bahamas it confirms and refines the local timing of both the lithologic change from skeletal to nonskeletal sediments and the disappearance of coral and molluscan species from the bahamas as upper late pliocene between 2 6 and 2 7 ma that the primary magnetic remanence is preserved in shallow water carbonates including replacement dolomites suggests that this technique could be used to date similar tertiary and possibly even older carbonate sequences the establishment of a reliable magnetostratigraphy provides refined dating of shallow water carbonates and regional faunal appearances or disappearances sediment accumulation rates subsidence and depositional events

evidence for bacterial palaeoecological origin of mineral magnetic cycles in oxic and sub oxic tasman sea sediments abstract sediments from the tasman basin in the southwest pacific ocean show a cyclic pattern of variation in mineral magnetic properties including susceptibility and remanence over the brunhes chron the magnetic pattern is dominated by fluctuations in the concentration of a single domain ferrimagnetic component identified as bacterial magnetofossils by tem investigation of the magnetic fraction the intervals of low bacterial magnetite concentration occurring in glacial periods are accompanied by a change of the bacterial magnetosome morphology assemblage interpreted as recording a change in bacterial species assemblage there is no evidence of iron or sulphate reducing conditions during low bacterial magnetite intervals concentrations of bacterial magnetite are low when oxygen concentrations in surface sediment pore waters dropped either as the result of variation in bottom water oxygen concentration or sedimentation rate the variations in the magnetic signal are therefore interpreted as resulting primarily from bacterial palaeoecological control rather than dissolution or alteration the bacteria in this deep sea environment are apparently aerophilic and grow near the sediment surface within the oxic zone implying that magnetic remanence is also acquired near the surface but up to tens of centimetres below where the oxic zone is very thick

magnetic properties and geochemistry of the active oxidation front and the youngest sapropel in the eastern mediterranean sea summary magnetic properties irm arm xin s ratio at 0 3 t room temperature rt hysteresis and thermomagnetic curves and geochemical data fe s mn al ti organic c were studied in two eastern mediterranean boxcores abc26 and bc19 at a resolution of 3 5 mm the boxcores contain sapropel s1 9 6 kyr bp at a few decimetres below seafloor the magnetic fraction consists predominantly of single domain sd to pseudo singledomain psd magnetite in the entire cores the original input of magnetic grains comes from two sources aeolian dust both cores and volcanic ash from the minoan eruption of santorini core bc19 only non steady state diagenesis has changed the magnetic mineralogy considerably in these alternating organic rich organic poor sediments during deposition of sapropel s1 reductive diagenesis and pyritization in and just below the sapropel caused lower magnetic intensities coarser magnetic grain sizes and partial maghemitization in thermomagnetic curves two types of pyrite can be identified one oxidizes below 450 uc and the other above 450 uc the higher oxidation temperature is predominantly found below the sapropel this may be related to the microtexture of pyrite which is euhedral below sapropels and mainly framboidal within sapropels since the end of sapropel deposition a downward moving oxidation front has oxidized the upper half c 5 cm of the sapropel the oxidized part of the sapropel is enriched in diagenetically formed fe oxides with relatively high coercivity and arm the maximum coercivity is found in a distinct layer between the present day mn and fe redox boundaries at the top of the unoxidized sapropel the freshly precipitated fe oxides in this centimetre thick layer contain a mixture of superparamagnetic sp grains and high coercivity sd magnetite higher in the oxidized zone the freshly precipitated fe oxides have aged into generally slightly lower coercivity sd grains with relatively high arm in addition to the diagenetic formation of fe oxides at the top of the sapropel formation of a ferrimagnetic fe monosulphide may have occurred within the sapropel during later stages of diagenesis which may have enhanced the arm signal in the organic rich interval in particular

magnetic properties of pelagic marine carbonates abstract pelagic carbonates are deposited far from continents usually at water depths of 3000 6000 m at rates below 10 cm kyr and are a globally important sediment type recent advances with recognition of widespread preservation of biogenic magnetite the inorganic remains of magnetotactic bacteria have fundamentally changed our understanding of the magnetic properties of pelagic carbonates we review evidence for the magnetic minerals typically preserved in pelagic carbonates the effects of magnetic mineral diagenesis on paleomagnetic and environmental magnetic records of pelagic carbonates and what magnetic properties can tell us about the open ocean environments in which pelagic carbonates are deposited we also discuss briefly late diagenetic remagnetisations recorded by some carbonates despite recent advances in our knowledge of these phenomena much remains undiscovered we are only at early stages of understanding how biogenic magnetite gives rise to paleomagnetic signals in sediments and whether it carries a poorly understood biogeochemical remanent magnetisation recently developed techniques have potential for testing how different magnetotactic bacterial species which produce different magnetite morphologies respond to changing nutrient and oxygenation conditions future work needs to test whether it is possible to develop proxies for ancient nutrient conditions from well calibrated modern magnetotactic bacterial occurrences a tantalizing link between giant magnetofossils and paleogene hyperthermal events needs to be tested much remains to be learned about the relationship between climate and the organisms that biomineralised these large and novel magnetite morphologies rather than being a well worn subject that has been studied for over 60 years the magnetic properties of pelagic carbonates hold many secrets that await discovery

magnetic mineral diagenesis in suboxic sediments at bettis site w n ne pacific ocean the effects of iron diagenesis on paleomagnetism and rock magnetism were examined in suboxic sediments from bettis site w n in the ne pacific ocean as part of the oxidative decomposition of organic matter ultrafine grained authigenic magnetites are produced immediately above the iron reduction zone this zone is commonly observed in deep sea sediments as a prominent color change from brown to greenish grey the magnetite authigenesis is evidenced by systematic increases in natural magnetic intensities and stabilities and by comparable shifts in other rock magnetic properties the magnetites are composed of relatively pure fe3o4 and fall within a restricted size range of 0 06 0 12 m which is nominally single domain some of these finest grained magnetites are rapidly destroyed during burial upon entering the zone of iron reduction leaving a relatively coarser population magnetite dissolution appears to continue with depth according to a first order surface area reaction process when at steady state iron reduction is independent of sulfide formation in these sediments because solid sulfur profiles show no increase at depth and most of the sulfur occurs as barite despite a well constrained carbonate stratigraphy comparisons of paleomagnetic directions between nearby cores show little agreement suggesting that the directions are composed of a complex mixture of remanences acquired at different depths subsurface magnetic peaks may represent paleoredox markers preserved by non steady state redox conditions caused by climatically induced variations in organic matter flux and sedimentation rates

dissolution and pyritization of magnetite in anoxie marine sediments concentrations of magnetite were determined with depth in sediments of varying h2s content taken from long island sound foam nwc and sachem sites and from a site in the rapidly depositing subaqueous portion of the mississippi delta for the three long island sound sites dissolution of magnetite during burial is clearly demonstrated and for all four sites the rate of magnetite dissolution is proportional to the concentration of dissolved pore water sulfide by combining magnetite depth distributions with sedimentation rate data and measurements of dissolved sulfide we find that magnetite dissolution is well described by the following rate law dcmagdt 1 1 10 5c0 5bcmagamag where cmag is the concentration of magnetite grams per gram of sediment cs is the concentration of dissolved sulfide mm and amag is the specific surface area of magnetite in the sediment cm2 per gram of magnetite this equation means that for a typical range of magnetite surface areas and dissolved sulfide concentrations the half life of magnetite in anoxic marine sediments ranges from about 50 to 1000 years sem observations of magnetite grains from the different sediment sites reveal that magnetite dissolution may be accompanied by extensive replacement by pyrite this only occurs if magnetite is in contact with high concentrations of h2s 1 mm for relatively long periods of time several hundred years with low concentrations of h2s 1 mm magnetite dissolution occurs without identifiable pyrite replacement we suggest that this feature of magnetite diagenesis may prove to be a useful paleosulfide indicator

a paleomagnetic and geochemical record of the upper cochiti reversal and two subsequent precessional cycles from southern sicily italy abstract a detailed paleomagnetic and geochemical study of the upper cochiti n r reversal recorded in marine marls on southern sicily shows two consecutive and very rapid transitions r n and n r that coincide with distinct lithological boundaries a fe migration model is presented in which magnetite is formed under different diagenetic conditions during sulphate reduction originally formed primary magnetite is preserved this primary magnetite has recorded the pre transitional normal polarity after burial migration of ferrous iron occurs and subsequent oxidation produces secondary magnetite which records the post transitional reversed polarity and produces the two apparent transitions in addition low temperature lt and high temperature ht components record the reversal in a slightly different way the ht component being acquired with a delay it is probable that both components reside in magnetite but have a different origin and grain size distribution giving different blocking temperature spectra the actual upper cochiti reversal occurs at a level with an estimated astronomically calibrated age of 4 165 ma

wasp waisted hysteresis loops mineral magnetic characteristics and discrimination of components in mixed magnetic systems rock magnetic studies of complex systems that contain mixtures of magnetic minerals or mixed grain size distributions have demonstrated the need for a better method of distinguishing between different magnetic components in geological materials hysteresis loops that are constricted in the middle section but are wider above and below the middle section are commonly observed in mixed magnetic assemblages such wasp waisted hysteresis loops have been widely documented particularly with respect to rare earth permanent magnets basaltic lava flows remagnetized paleozoic carbonate rocks and an increasingly wide range of other rocks our modelling combined with a review of previous work indicates that there are several conditions that give rise to as well as magnetic properties that are characteristic of wasp waisted hysteresis loops first at least two magnetic components with strongly contrasting coercivities must coexist this condition can arise from either mixtures of grain sizes of a single magnetic mineral or a combination of magnetic minerals with contrasting cocrcivities or a combination of these two situations second materials that give rise to wasp waisted hysteresis loops will have relatively high ratios of the coercivity of remanence to coercive force b cr b c because b0 is controlled by the soft low coercivity component whereas bcris controlled by the hard high coercivity component third values of b cr b c 10 usually only occur for strongly wasp waisted loops when the low coercivity component comprises an overwhelmingly large fraction of the total volume of magnetic grains fourth a given mixture of superparamagnetic and single domain sd grains is more likely to give rise to wasp waisted hysteresis loops than an equivalent mixture of sd and multidomain grains fifth our results provide empirical confirmation that the total magnetization of a material is the sum of the weighted contributions of each component in the absence of significant magnetic interaction between particles thus to contribute significantly to wasp waisted behavior a mineral magnetic component must give rise to a significant portion of the total magnetization of the rock as a result minerals with weak magnetic moments such as hematite need to occur in large concentrations to cause wasp waistedness in materials that also contain ferrimagnetic minerals we outline a method for determining the magnetic components that can give rise to wasp waisted hysteresis loops this method is based on high and low temperature magnetic measurements that are used to identify the dominant remanence bearing mineral s and on mineral magnetic techniques that are used to discriminate between different magnetic domain states the method is illustrated with several examples from archaeological geological and synthetic materials

hemipelagic sedimentation in a region of crustal doming between the mendocino and pioneer fracture zones abstract pacific study area w n lies 300 km west of california south of the gorda ridge between the mendocino and pioneer fracture zones hemipelagic mud covers the seafloor over a broad low rise and grades eastward into distal turbidite deposits of the delgada fan 3 5 khz profiles show three kinds of acoustic character for the seafloor strongly reflecting turbidite deposits depositionally draped hemipelagic sediment and an unusual morphology characterized by low relief closely spaced hills these small hills occur in the same area as the low rise implying a common origin calculations of the plate motions for this small corner of the pacific plate suggest that it is overriding the upper mantle thermal trace of the gorda ridge magma chamber this heat source apparently causes doming offsets in the layered hemipelagic sediment and formation of the closely spaced small hills

nannobacteria and the precipitation of carbonate in unusual environments abstract nannobacteria are abundant not only in normal marine limestones but also in other environments such as continental caliches fresh water streams springs water pipes caves etc cells are typically 50 to 200 nm in diameter