calcic amphibole equilibria and a new amphibole plagioclase geothermometer there is currently a dearth of reliable thermobarometers for many hornblende and plagioclase bearing rocks such as granitoids and amphibolites a semi empirical thermodynamic evaluation of the available experimental data on amphibole plagioclase assemblages leads to a new thermometer based on the aliv content of amphibole coexisting with plagioclase in silica saturated rocks the principal exchange vector in amphiboles as a function of temperature in both the natural and experimental studies is left na square 1 right a left alsi 1 right t1 we have analysed the data using 3 different amphibole activity models to calibrate the thermometer reactions 1 edenite 4 quartz tremolite albite 1 2 pargasite 4 quartz hornblende albite 2 the equilibrium relation for both 1 and 2 leads to the proposed new thermometer t frac 0 677p 48 98 y 0 0429 0 008314 ln k and k left frac si 4 8 si right x ab plag where si is the number of atoms per formula unit in amphiboles with p in kbar and t in k the term y represents plagioclase non ideality rtln ab from darken s quadratic formalism dqf with y 0 for xab 0 5 and y 8 06 25 5 1 xab 2 for xab 0 5 the best fits to the data were obtained by assuming complete coupling between al on the t1 site and na in the a site of amphibole and the standard deviation of residuals in the fit is 38 c the thermometer is robust to ferric iron recalculation procedures from electron probe data and should yield temperatures of equilibration for hornblende plagioclase assemblages with uncertainties of around 75 c for rocks equilibrated at temperatures in the range 500 1100 c the thermometer should only be used in this temperature range and for assemblages with plagioclase less calcic than an92 and with amphiboles containing less than 7 8 si atoms pfu good results have been attained on natural examples from greenschist to granulite facies metamorphic rocks as well as from a variety of mafic to acid intrusive and extrusive igneous rocks our analysis shows that the pressure dependence is poorly constrained and the equilibria are not suitable for barometry

age and cooling history of the manaslu granite implications for himalayan tectonics abstract the manaslu granite is one of the high himalayan leucogranites which are believed to be derived by partial melting of quartzofeldspathic gneissess of the high himalayan crystallines hhc and emplaced at the contact between the hhc and the tethyan sedimentary series we have analyzed a suite of muscovite 15 biotite 3 and alkali feldspar 10 by the 40 ar 39 ar method to help constrain the age and cooling history of the granite 40 ar 39 ar ages ranges are 18 4 to 13 3 ma 17 0 to 14 7 and 16 4 to 3 4 for muscovite biotite and k feldspar respectively based on the muscovite analyses and a re interpretation of a previously published u pb monazite age we conclude that the crystallization age of the manaslu granite is everywhere 20 ma the postcrystallization cooling history given by the micas and the feldspars suggests the presently exposed parts of the pluton were emplaced at depths of 8 to 15 km these data place a minimum age of movement on the mct in this area of 20 ma we estimate the time of magma segregation and transport to be no more than 5 ma

oxygen diffusion in quartz diffusional oxygen exchange between quartz and water was studied by determining 18o profiles in the quartz using an ion microprobe inverse error function plots of the data are linear as required for a diffusion mechanism one natural and two synthetic samples were used and although they had different impurity concentrations oh na and al per 106 si atoms are 7 4000 35 835 and 67 127 respectively the d values were the same within experimental uncertainty diffusion parallel to c is about 2 orders of magnitude faster than that normal to c at 700 c and diffusion normal to the rhombohedron is intermediate the data indicate a change in slope on an arrhenius plot at the boundary at 100 mpa 1 kbar water pressure the preexponential factors do in square centimeters per second and activation energies q in kilojoules per mole for quartz 500 550 c are as follows do 190 and q 284 parallel to c and do 8 10 2 and q 238 normal to the rhombohedron for quartz 600 800 c do 4 10 7 and q 142 parallel to c do 9 10 7 and q 155 normal to the rhombohedron and do 1 10 4 and q 234 normal to c d increases with ph 2 o and between 25 and 350 mpa log d versus log h 2 o has a slope of approximately 1 1 these d values are all several orders of magnitude larger than previously reported values for oxygen diffusion in water free systems

correlation between melting deformation and fluid interaction in the continental crust of the high himalayas langtang valley nepal combined metamorphic stable isotope and structural studies from the high himalayan crystalline sequence in the langtang valley of north central nepal reveal a strong positive correlation between distance above the base of the section the main central thrust the amount of melt material and evidence of prolonged fluid and deformation histories thus suggesting that these processes are strongly interdependent kyanite grade rocks at the base of the section are unmelted and have undergone little syn or post metamorphic internal deformation and little prograde or retrograde fluid rock interaction by contrast sillimanite grade rocks higher in the section contain progressively larger volumes of melt have suffered increasingly complex syn and post metamorphic deformation and show increasing evidence for the presence of fluids although the factors that initiated these processes remain problematic it is suggested that fluid distributions within the langtang section have been passively controlled by the movement of melts these melts may have provided a primary control on deformation during both the magmatic stage and subsequently through the exsolution of exsolved aqueous fluids

heat sources for tertiary metamorphism and anatexis in the annapurna manaslu region central nepal following the collision of india with southern tibet crustal rocks of the leading edge of india 1 underwent regional metamorphism to upper amphibolite grade 2 melted locally to produce anatectic granitoids and 3 were sheared and thrust onto lower grade rock along the main central thrust yielding an inverted metamorphic sequence this sequence is exemplified in the annapurna manaslu region we use simple physical calculations to examine the heat sources involved in the different phases of metamorphism the regional metamorphism apparently is due to the burial of the northern edge of india beneath the accretionary prism along the southern edge of tibet the observed temperatures and pressures of this first phase of metamorphism are consistent with the thermal relaxation during the 10 30 m y before slip on the main central thrust began of thickened continental lithosphere whose original surface heat flux was between 50 and 70 mw m 2 the release of water from the footwall of the main central thrust apparently facilitated melting of the overlying crust in the second phase such melting could have occurred in the first million years or so of thrusting if warm 550 650 c crust in the footwall contained the necessary water if melting did not occur in the earliest stages of slip on the main central thrust dissipative heating with shear stresses of 10 to 100 mpa is required for temperatures near the main central thrust to have remained high enough to generate melting above the fault during the underthrusting of cold material the thickness 6 8 km of the zone of inverted isograds associated with the fault if undisrupted and due solely to thermal diffusion implies that the time required to carry the rocks preserving the inverted metamorphism from the surface to depths of 30 40 km was 4 8 m y the apparent inverted temperature gradients about 10 25 c km in this zone can be understood as the combined result of two processes diffusion of heat from hot rock thrust over cold rock expunged the original temperature gradient near the fault and could have created an inverse gradient of 10 20 c km the peak temperatures in such a zone however would not have exceeded about 350 c without an additional source of heat dissipative heating at shear stresses of about 100 mpa can account for peak temperatures in excess of 600 c during slip on the fault and would have contributed as much as 13 c km to the inverse gradient although inversion of metamorphic isograds could have occurred as a result of deformation within the main central thrust zone the high temperatures during slip on this zone still require dissipative heating unless the duration of slip exceeded 25 m y

possible thermal buffering by crustal anatexis in collisional orogens thermobarometric evidence from the nepalese himalaya one dimensional thermal models suggest that large thrust faults may exert first order control on the thermal structure of collisional orogenic belts and an increasing body of petrologic data may be interpreted as consistent with these models we present new thermobarometric data from the central nepalese himalaya which imply that large sections of the himalayan orogen may have been at roughly uniform temperatures during active thrusting a phenomenon that is not predicted by existing models we attribute this phenomenon to thermal buffering as a consequence of widespread in situ anatexis if this process is common in the intermediate and lower crust of active orogens and if it is localized spatially one dimensional thermal models may produce an extremely oversimplified picture of heat transfer processes during collisional orogenesis

badrinath gangotri plutons garhwal india petrological and geochemical evidence for fractionation processes in a high himalayan leucogranite the gangotri leucogranite is the western end of the badrinath granite one of the largest bodies of the high himalayan leucogranite belt hhl it is a typical fine grained tourmaline muscovite biotite leucogranite the petrography shows a lack of restitic phases the inferred crystallization sequence is characterized by the early appearance of plagioclase quartz and biotite and by the late crystallization of the k feldspar this suggests that in spite of being of near minimum melt composition the granite probably had long crystallization or melting interval in agreement with previous experimental studies tourmaline and muscovite have a mainly magmatic origin even though the major element composition is homogeneous there are several geochemical trends when cao decreases there is an increase in na2o rb sn u b f and a decrease in k2o fe2o3 tio2 sr ba zr ree th which are best explained by a fractionation process with early crystallizing phases experimental solubility models for zircon and monazite in felsic melt support a magmatic origin for these two accessory phases as well rb sr isotope data show this granite to have like other hhl heterogeneous isotopic values for sr initial 87sr 86sr ratios calculated at 20 ma range between 0 765 and 0 785 therefore no mixing i e no convection occurred between the different batches of magma in contrast 18o data show little variation 13 04 0 25 implying a source with homogeneous 18o values differences in timing between fluid infiltration and the onset of melting related to differences in temperature of the source could explain why source homogenization occurred for the gangotri and not for the manaslu granite the use of experimental results for solubility and the position of the accessory minerals during melting predict a low viscosity for the melt during its extraction this in turn explains the lack of restitic phases major and accessory in the granite as well as some field features lensoid shape pronounced magmatic layering based on the petrographic and isotopic studies it is suggested that the mechanism of ascent was not diapiric but rather that the melt ascended along several fractures and the level of emplacement was partialy controlled by the density contrast between the melt and host rocks

effect of cooling on the water content and mechanical behavior of metamorphosed rocks calculations of the decline in f h2o in equilibrium with typical metamorphic assemblages during cooling indicate that there will be a large drop in pore water pressure within 100 of the metamorphic maximum the loss of pore fluid and the generation of large effective pressures across grain boundaries will inhibit rock deformation by those mechanisms that depend on the presence of an aqueous fluid phase in many metamorphic belts extensive deformation occurs below the metamorphic maximum during heating that is while fluid is being generated whereas rocks do not deform in the same ductile manner on cooling even while temperature is high this may reflect changing mechanical properties of the rocks rather than merely changes in regional stresses mobile belts could be made rigid in this way in about 20 m y

north south extension within the convergent himalayan region recent work by burg et al 1984 indicates the presence of east west striking gently north dipping normal faults in the higher himalayas and southern tibet that formed during postcollisional convergence of india and tibet these faults extend for at least 800 km along strike we interpret these normal faults as probable late miocene extensional features with perhaps several tens of kilometres of down to the north displacement a simple elastic model suggests that these normal faults may have formed during gravitational collapse of the miocene topographic front between india and tibet in this interpretation gravitational collapse occurred by southward motion relative to india and tibet of a wedge of crustal rocks bounded above by gently north dipping normal faults and below by thrust faults that probably dip north north south extension produced in this way is probably confined to upper crustal levels only and does not reflect regional extension of the entire lithosphere

the younger dryas and late pleistocene peoples of the great lakes region abstract the late pleistocene archaeological record of the great lakes drainage area shows that there were several albeit spatially variable changes in that record in a time period corresponding to the younger dryas yd climatic reversal at ca 10 800 10 000 14 c bp notable here are declines in some areas in the mobility of paleoindian groups as measured by distance to the main lithic source employed declines in the overall frequency of sites findpots particularly in the western great lakes where some northern areas seem to have been largely abandoned and an increasing association of occupation locales with glacial lake shores or extensive wetlands left by recently drained glacial lakes some of the changes as in range mobility most likely relate to the colonization of new areas rather than directly to the yd specifically the earliest groups were able to target rich but widely dispersed resource locales due to an absence of competing groups however the declines in locale frequencies and shifting distributions of those locales may be due to yd influence notably to an eventual drying out of the area that resulted in less productive environments overall and made the lake shores and wetland areas more attractive environmental niches for human occupation

the influence of deformation on the formation of axial planar leucosomes and the segregation of small melt bodies within the migmatitic napperby gneiss central australia in the napperby gneiss central australia a distinctive group of elongate leucosomes occurs along the axial planes of mesoscopic crenulations that have harmonic two dimensional kink band like geometries the leucosomes truncate a fabric defined by biotite quartz k feldspar plagioclase sillimanite and are chiefly composed of k feldspar and quartz with or without plagioclase they are characterized by accessory garnet or aggregates of intergrown ilmenite and magnetite produced during the melting reactions bi plag q sill g ksp melt and bi plag q ru ilm mt ksp melt the absence of garnet and intergrown ilmenitemagnetite aggregates in the gneiss surrounding the crenulation zones indicates that these melting reactions preferentially occurred in the deformation zones in spite of a homogeneous distribution of reactant phases in the gneiss this means that strain partitioning and partial melting are coupled processes in which the garnet and ilmenite magnetite producing melt reactions initially occurred in high strain zones where the melting reaction activation energy was first overstepped this was a consequence of an additional strain induced matrix free energy component on top of the temperature effect once reaction product nucleation had occurred the deformation zones became the sites for continued melting which was energetically favoured over nucleating garnet and ilmenite magnetite elsewhere the melt reactions producing garnet and ilmenite magnetite resulted in the formation of grain supported leucosomes with a higher melt component than the surrounding gneiss and the leucosomes were therefore relatively incompetent in a differential stress field diffusional processes will cause elongation of the leucosome in a plane normal to 1 parallel to the axial planes of folds if sufficient melting has occurred an interconnected leucosome network will result creating a potentially important buoyancy driven melt drainage system in the napperby gneiss interconnected leucosome bearing crenulation zones are mostly vertical which is an ideal orientation for buoyancy driven diffusive melt migration however melt segregations remained small due to a melt impermeable lithological boundary overlying the gneiss

water contents of silicic to intermediate magmas silicic to intermediate magmas have water contents that range from 1 wt to around 7 wt depending on the character and depth of the magma source type of melting reaction and the degree of differentiation the condition of water saturation is rare implying that crustal magma genesis generally takes place under fluid absent conditions or that any fluid present must contain volatile species other than h2o the source and quantity of water present during partial melting profoundly affect the types of melting reactions residues and magmas as well as subsequent magma evolution for s type granitic magmas melting reactions involving muscovite breakdown in pelites yield low temperature wet melts that form veins pockets and small plutons in regional metamorphic terranes biotite breakdown in pelites near the amphibolite granulite facies transition yields hotter magmas with variable water contents these are emplaced at medium to high levels under granulite facies conditions biotite breakdown in quartzofeld spathic rocks yields high temperature dry magmas emplaced as subvolcanic batholiths and volcanics

manaslu leucogranite a collision signature of the himalaya a model for its genesis and emplacement the manaslu pluton is one of 10 leucogranites that formed in the overthrusted higher himalaya after the indo eurasian collision field and analytical data indicate that the underlying migmatites of the tibetan slab may be where the leucogranitic melts were generated the himalayan crustal thrusting of a hot slab over a rather cold volcano sedimentary pile le fort 1975a provides the necessary release of fluids these fluids cross the main central thrust mct induce the partial anatexis of the overheated tibetan slab and produce a leucogranitic magma the emplacement of the magma at first is located along the main disharmonic plane above the mct between the infrastructure and the superstructure there it generates a convective hydrothermal system extending very far laterally according to the stratification of permeabilities progressive emplacement of the granite proceeds as the convected fluids including the fluids released by the saturated magma dissolve the mainly calcareous host rocks of tibetan sedimentaries a frozen image of this caving out progression is given by the extensive network of granitic dikes outside the pluton the two quite independant fluid cycles of the generation and of the emplacement were triggered or guided by the tectonics due to collision this two fold model dominated by fluid activity may be of importance for other leucogranites and granites

zanskar shear zone northeast southwest extension within the higher himalayas ladakh india a complete geologic section through the northwestern himalayas is well exposed in ladakh india the collision between the indian shield and the tibetan platform caused large scale intracrustal thrusting and piling up of the himalayan nappes this compressional event was accompanied by prograde regional metamorphism the metamorphism ranges from low grade anchimetamorphism in the indus suture zone in the northeast to upper amphibolite grade in the higher himalaya tectonic unit in the southwest in the zanskar area a well exposed and morphologically prominent shear zone 2 25 to 6 75 km wide can be followed from the northwest to the southeast for at least 80 km in contrast to the main compressional tectonics this shear zone indicates an extensional event within the higher himalaya tectonic unit the zanskar shear zone involves granitic rocks leucogranites of miocene age and various metasediments and in general separates the late precambrian early cambrian sedimentary sequence phe formation from the underlying crystalline basement zanskar crystalline unit a normal sense of shear has been determined by using asymmetric macroscopic and microscopic structures such as pegmatite boudins feldspar augen and crystallographic fabrics the metamorphic isograds are very close within this shear zone as a result of shear deformation a gradual transition from upper amphibolite to lower greenschist facies occurs within 200 m movement in this zone occurred late in the metamorphic history under greenschist or lower metamorphic conditions the minimum horizontal extension and vertical displacement are on the order of 16 and 19 km respectively

diffusion effects on oxygen isotope temperatures of slowly cooled igneous and metamorphic rocks recently obtained data on oxygen diffusion in feldspars quartz and hornblende permit the prediction of the apparent18o16o temperatures that would be measured in a rock that consisted only of those three minerals and cooled slowly from high temperature the computed temperatures would be based on the differences in the18o16o ratios between coexisting pairs of minerals the present calculation takes into account the diffusion rates for oxygen as a function of temperature the cooling rate of the rock the mineral grain sizes and the mode of the rock for mineral grains 1 mm in radius and a cooling rate of 10 c m y the minimum difference in apparent temperature between quartz feldspar and feldspar hornblende pairs will be 115 c despite the assumption of a normal uneventful slow cooling history to room temperature further the apparent quartz hornblende temperature will range over 30 c 590 620 c depending on the mode of the rock for a cooling rate of 1000 c m y the apparent difference in temperature can be as much as 400 c consequently consistency in temperatures obtained by oxygen isotope analysis should not be expected in most high grade metamorphic rocks or igneous rocks which are cooled slowly departures from the pattern of temperatures obtained in this model would imply a very rapid quench from high temperature or a complex history for the rock for some minerals including hornblende the relation between temperature and the equilibrium fractionation of oxygen isotopes between coexisting phases has been derived from observed relations in natural specimens the choice of the specimens used for such calibrations needs to be re evaluated in light of these findings this may result in a change in the equilibrium equation constants an example from the literature the san jose tonalite baja california mexico was modelled and yields 18o concentrations in the minerals that correspond closely with the measured values this suggests that the model used is appropriate that the rock has had a simple thermal history and that it cooled at 100 200 c m y over the temperature range 800 500 c the set of paleotemperatures obtained for a rock will in general yield neither the mineral closure temperatures nor the formation or crystallization temperatures on the other hand the cooling rate of the rock may be derived from the data this in turn may have important tectonic implications with regard to denudation and uplift rates

granite magma generation ascent and emplacement within a transpressional orogen crustal thickening during transpressive orogenesis may produce anatectic granites which may then localize deformation leading to transcurrent movement granites may be transported from sites of generation through the mid crust in dyke like channelways within relatively narrow strike slip shear zones which link to major fault zones in the upper crust extensional jogs within fault systems provide developing sites for the assembly of plutons from magma arriving from below the model is based upon observations from the cadomian belt of nw france which exposes sections through middle and upper levels of the late precambrian crust within different elements of the orogen the mechanism provides a favourable alternative to diapirism and explains the common collocation of granites and shear zone fault systems within orogenic belts

melt enhanced deformation a major tectonic process convergent tectonics between continental crustal blocks result in deep burial and anatexis of supracrustal rocks anatectic and or mantle derived melts combine to form a melt weakened zone in the thickened lower crust the accumulation of melt eventually leads to crustal failure along melt lubricated shear zones rapid 1 mm yr vertical component movements of large crustal blocks result we refer to these crustal displacements as tectonic surges the melt lubricated shears are characterized by the close association of sheared country rocks with foliated or massive igneous sills and plutons rocks that formed at different crustal levels are juxtaposed across these shear zones one result of surges with large lateral component of movement is metamorphic inversion with high pressure and high temperature metamorphic rocks structurally over lower pressure and temperature assemblages large and rapid vertical surges may displace crust containing abundant melt and may result in high t p including granulite facies metamorphism and preservation of metamorphic textures caused by rapid decompression

deformation of leucogranites of the crystalline main central sheet in southern tibet china abstract towards the top of the main central sheet in southern tibet china leucogranites intrude metamorphic rocks related to rocks of the main central thrust in the himalayas our study shows that the leucogranites suffered a northward shear deformation the significance of this event is discussed in terms of gravity driven decollement of the 10 000 m thick tethyan sedimentary pile over its crystalline basement

thermobarometric constraints on the thermal history of the main central thrust zone and tibetan slab eastern nepal himalaya the main central thrust mct south of mt everest in eastern nepal is a 3 to 5km thick shear zone separating chlorite bearing schist in the lower plate from sillimanite bearing migmatitic gneiss in the overlying tibetan slab the metamorphic grade increases through the mct zone toward structurally higher levels previous workers have suggested that either post or synmetamorphic thrust movement has caused this inversion of metamorphic isograds in an effort to quantify the increase in grade and to constrain proposed structural relations between metamorphism and slip on the fault four well calibrated thermobarometers were applied to pelitic samples collected along two cross strike transects through the mct zone and tibetan slab results show an increase in apparent temperature up section in the mct zone from 778 k to 990 k and a decrease in temperature to 850 k in the lower tibetan slab which is consistent with synmetamorphic thrust movement a trend in calculated pressures across this section is less well defined but on average decreases up section with a gradient of 28mpa km resembling a lithostatic gradient pressure temperature paths for zoned garnets from samples within the mct zone modelled using the gibbs method show a significant decrease in temperature and a slight decrease in pressure from core to rim which might be expected for upper plate rocks during synmetamorphic thrust movement samples from the uppermost tibetan slab yield higher temperatures and pressures than those from the lower tibetan slab which may be evidence for later resetting of thermobarometers by intrusion of the large amounts of leucogranite at that structural level

hydrogen and oxygen isotope variations in the high himalaya peraluminous manaslu leucogranite evidence for heterogeneous sedimentary source abstract the manaslu granite belongs to the high himalaya leucogranitic belt which was produced by melting of the crust during postcollisional thrusting d and 18o values have been determined for whole rock and coexisting minerals from the 8 km thick manaslu massif and its 50 km long dyke sheet its country rocks and the formation 1 f1 paragneisses which are the source of the granite for the granite dmusc range from 70 to 85 and 18o w r from 10 9 to 12 8 h and o isotope fractionations among minerals are consistent with high temperature equilibrium and for oxygen closed system evolution a few samples coming mainly from the dyke swarm have very low d values down to 188 and biotite muscovite h isotope fractionations indicative of disequilibrium the d h ratios of associated magmatic tourmaline are essentially unmodified from the distribution of d values in the granite and its country rocks circulation of very low deuterium meteoric hydrothermal waters was extremely localized because these waters are depleted in deuterium by up to 50 relative to modern meteoric waters the manaslu area was either at an altitude substantially higher than that of today 2500 6000 m for the analyzed samples or a mountain chain once existed to the south the f1 gneisses have 18oquartz between 12 and 14 3 which confirms that the granite was generated from f1 but d values are 20 higher than in the granite such a difference can be a result of degassing of the magma and or introduction of fluid in the melting zone infiltration of low d fluid 90 into the hot but dry f1 probably triggered partial melting these fluids could have come from the dehydration of the midlands sediments which are separated from the overlying f1 by the main central thrust the correlations among 18o 87 sr 86 sr 20 ma and nd values in both f1 and the granite indicate that the variations of these isotopic ratios in the manaslu are inherited from those in f1 at the time of melting in turn these ratios in f1 are related to the proportion of quartz and phyllosilicates for the isotopic ratios of nd and o and to the quantity of radiogenic sr generated within the sediment which is a function of age and rb content amount of phyllosilicate some other himalayan leucogranites require either other crustal source rocks or the 18o and 87 sr 86 sr ratios of f1 vary along the himalaya

thermal evolution of the greater himalaya garhwal india the hanging wall of the main central thrust mct in garhwal india roughly 79 n 80 e 30 n 31 n exhibits an inverted metamorphic gradient sillimanite potassium feldspar assemblages near the top of the hanging wall or greater himalayan sequence are underlain by kyanite grade rocks near the fault textural relationships in pelitic samples from the alaknanda and dhauli river valleys indicate that the inversion is the product of two distinct metamorphic events an early harrovian event m1 which affected the entire greater himalayan sequence and a later buchan event m2 the effects of which are most obvious in the upper part of the sequence rim thermobarometry garnet inclusion thermobarometry and thermodynamic modeling of garnet zoning reveal that the basal portions of the metamorphic sequence experienced peak m1 conditions of 900 k and 960 mpa roughly 36 km depth before following an erosion controlled uplift path e g england and richardson 1977 m2 metamorphic temperatures in the upper part of the sequence also exceeded 900 k but maximum pressures 317 523 mpa indicate paleodepths of only 12 19 km calculated pressure temperature paths indicate that m2 was characterized by temperature increases of 80 k and roughly 5 km of tectonic burial we attribute m1 to tectonic burial of the greater himalayan sequence during the early stages of india eurasia collision we believe that the uplift and cooling path of the sequence was interrupted in late oligocene miocene time by a second burial and heating event m2 related to thrust imbrications in southern tibet this burial was coincident with the generation of leucogranites which are abundant near the top of the greater himalayan sequence but are virtually absent near the mct field relations do not constrain whether the leucogranites were derived from some presently unexposed portion of the greater himalayan sequence and were injected at their present structural level or were melted in situ if the granites were injected then they may have provided some of the heat necessary for m2 metamorphism although our data suggest no direct relationship between the main central thrust as mapped in garhwal and metamorphism in the greater himalaya anatectic melting of an unexposed portion of the greater himalayan sequence could have been associated with movement along a blind thrust with characteristics similar to the mapped mct in central nepal cf le fort 1981 if the granites were produced by in situ m2 melting then we must appeal to a heat source within the upper part of the greater himalayan sequence such as locally high concentrations of heat producing elements cf pinet and jaupart 1987

volume self diffusion of oxygen in biotite muscovite and phlogopite micas the kinetics of oxygen self diffusion have been measured in natural samples of biotite muscovite and phlogopite micas under hydrothermal conditions using both bulk exchange and profiling analyses all experiments were run at 1000 bars 100 mpa water pressure except those designed to measure water pressure dependence which ranged from 200 to 2000 bars the arrhenius relations obtained for layer parallel diffusive transport in the three micas by bulk exchange experiments fit to an infinite cylinder model are mineral biotite muscovite phlogopite 34 2 39 5 42 3 9 1 10 6 7 7 10 5 1 4 10 4 t c 500 800 512 700 600 900 the results of ion microprobe sims depth profiling perpendicular to the layers parallel to c axis yield diffusion coefficients 3 to 4 orders of magnitude lower than for transport parallel to the layers a single layer parallel step profiling experiment yields a diffusion coefficient identical within uncertainty to those obtained from bulk exchange experiments a slight dependence of diffusion rate on water pressure may obtain in phlogopite however the difference is approximately within the uncertainty of the measurement diffusion rates are similar within about a half an order of magnitude for a range of biotite composition from annite4 to annite63 as well as for muscovite comparison of oxygen diffusion rates in biotite from this study with ar k and rb diffusion from published data supports the idea that water is the oxygen bearing species in hydrothermal diffusion experiments the implication of these results for natural systems is that the micas especially biotite will continue to exchange oxygen isotopes via volume diffusion down to temperatures as low as 300 c the rapid diffusion kinetics may explain biotite oxygen isotope disequilibrium which is commonly observed even in rocks where other mineral phases preserve equilibrium compositions full size table table options view in workspace download as csv

intercrystalline stable isotope diffusion a fast grain boundary model we formulated a numerical model for stable isotope interdiffusion which predicts the temperatures recorded between two or more minerals and the intragranular distribution of stable isotopes in each mineral as functions of mineral grain sizes and shapes diffusivities modes equilibrium isotopic fractionations and the cooling rate of a rock one of the principal assumptions of the model is that grain boundaries are regions of rapid transport of stable isotopes this fast grain boundary fgb model describes interdiffusion between any number of mineral grains assuming that local equilibrium and mass balance restrictions apply on the grain boundaries throughout the volume modeled the model can be used for a rock containing any number of minerals and number of grain sizes of each mineral several grain shapes and any thermal history or domain size desired previous models describing stable isotope interdiffusion upon cooling have been based on dodson s equation or an equivalent numerical analogue the closure temperature of dodson is the average bulk temperature recorded between a mineral and an infinite reservoir by using dodson s equation these models have treated the closure temperature as an innate characteristic of a given mineral independent of the amounts and diffusion rates of other minerals such models do not accurately describe the mass balance of many stable isotope interdiffusion problems existing models for cation interdiffusion could be applied to stable isotopes with some modifications but only describe exchange between two minerals under specific conditions the results of fgb calculations differ considerably from the predictions of dodson s equation in many rock types of interest actual calculations using the fgb model indicate that closure temperature and diffusion profiles are as strongly functions of modal abundance and relative differences in diffusion coefficient as they are functions of grain size and cooling rate closure temperatures recorded between two minerals which exchanged stable isotopes by diffusion are a function of modal abundance and differences in diffusion coefficient and may differ from that predicted by dodson s equation by hundreds of degrees c either or both of two minerals may preserve detectable zonation which may in some instances be larger in the faster diffusing mineral rocks containing three or more minerals can record a large span of fractionations resulting from closed system processes alone the results of fgb diffusion modeling indicate that the effects of diffusive exchange must be evaluated before interpreting mineral fractionations concordant or discordant recorded within any rock in which diffusion could have acted over observable scales the predictions of this model are applicable to thermometry evaluation of open or closed system retrogression and determination of cooling rates or diffusion coefficients

pressure temperature and time constraints on himalayan metamorphism from eastern kashmir and western zanskar himalayan metamorphism in the kashmir and zanskar sector of the high himalaya resulted from thrust and fold related crustal thickening within the indian plate following the collision of india and asia at c 50 ma interbanded metapelites marbles calcareous schists amphibolites and quartzites represent metamorphosed equivalents of the palaeozoic lower mesozoic continental margin rocks granitic rocks include pre collision k feldspar megacrystic and biotite granites and post collision two mica garnet tourmaline granites average pressure temperature conditions of equilibration using the self consistent thermodynamic data set of holland powell 1990 are presented across a 45 km traverse of the eastern kashmir western zanskar high himalaya kyanite is the stable aluminosilicate phase across 35 km outcrop width in the middle of the slab complex microstructures indicate that prograde metamorphism up to kyanite grade and fabric development in the upper structural nappes is early and unrelated to the main central thrust diachronous metamorphism propagated southwards with the overall structural evolution early isograds and thrust fold structures were carried passively in the hanging wall of the main central thrust peak metamorphism based on 40 ar 39 ar hornblende ages occurred pre 30 7 2 0 ma at the top of the slab and in the middle of the slab was pre 22 1 0 ma probably 25 28 ma the lower structural levels in zanskar record peak metamorphic conditions around 700 750 c and 8 kbar reflecting depths of burial of 28 30 km a new younger schistosity which is not present in the higher structural levels was developed under kyanite grade conditions the regional distribution of high temperatures recorded by thermo barometry does not support the concept of additional heat being supplied by frictional heating along the main central thrust or magmatic heat resulting from anatexis exhumation of the himalayan metamorphic rocks was achieved by three major processes erosion as a result of crustal thickening uplift of the rocks along the hangingwall of the main central thrust above a major frontal ramp in the kishtwar window area and extensional unroofing along the footwall of a large scale ne dipping normal fault at upper crustal levels probably synchronous with compression at depth

oxygen diffusion rates in quartz exchanged with co2 oxygen self diffusion rates were determined in quartz samples exchanged with18o enriched co2 between 745 and 900 c and various pressures and the diffusion profiles were measured using an ion microprobe the activation energy q and preexponential factor d0 at p co2 p tot 100 bar for diffusion parallel to the c axis are 159 13 kj g atom and 2 10 0 75 0 55 10 8 cm2 s this rate is approximately 100 times slower than that obtained from hydrothermal experiments and 100 times faster than a previous 1 bar quartz o2 exchange experiment the oxygen diffusion rate measured at 0 6 bar 888 c and at 900 c in vacuum is in agreement with the previous 1 bar exchange experiments with18o2 the effect of higher co2 pressures is small at 900 c the diffusion rate exchanged with co2 is 2 35 10 15 cm2 s at 100 bar 2 24 10 15 cm2 s at 3 45 kbar and 8 13 10 15 cm2 s at 7 2 kbar there is probably a diffusing species other than oxygen that enhances the oxygen diffusion rate in these quartz co2 systems relative to that occurring at very low pressures or in a vacuum the effect of this diffusing species however is not as strong as that associated with h2o preserved oxygen isotope fractionations between coexisting minerals in a slowly cooled high grade metamorphic terrane will vary depending upon whether a water rich phase was present or not closure temperatures will be approximately 100 c higher in rocks where no water rich phase was present during cooling the measured fractionations between coexisting minerals in metamorphic rocks may potentially be used as a sensor of water presence during retrogression

linked fluid and tectonic evolution in the high himalaya mountains nepal fluid inclusions were studied in a quartz lens from the structurally highest unit of the himalaya mountains in nepal from a textural geometrical chemical and isotopic point of view six types of fluid inclusions were distinguished one of these types consists of annular inclusions this shape is attributed to a confining pressure increase in a non isotropic stress field two successive stress fields were deduced from the orientation of the inclusion planes relative to the schistosity the bulk composition of the fluid was dominated by co2 84 mol and h2o the composition remained constant during the whole history of the sample indicating that it was buffered by the carbonaceous host rock and or that one single fluid was reworked in situ by decrepitation stable isotope of fluids and minerals indicate 1 that fluids were buffered by surrounding rocks for o and c and 2 that at least two types of water metamorphic and meteoric were involved finally a p t t e path is proposed for the sample taking into account the southward thrusting along the main central thrust the northward tectonic denudation of the himalaya mountains inducing tectonic burying below the annapurna range and lastly rapid uplift

the metamorphism in the central himalaya all along the himalayan chain an axis of crystalline rocks has been preserved made of the higher himalaya crystalline and the crystalline nappes of the lesser himalaya the salient points of the metamorphism as deduced from data collected in central himalaya central nepal and kumaun are 1 the higher himalaya crystalline also called the tibetan slab displays a polymetamorphic history with a first stage of barrovian type overprinted by a lower pressure and or higher temperature type metamorphism the metamorphism is due to quick and quasi adiabatic uplift of the tibetan slab by transport along an mct ramp accompanied by thermal refraction effects in the contact zone between the gneisses and their sedimentary cover the resulting metamorphic pattern is an apparent diachronic inverse zonation with the sillimanite zone above the kyanite zone 2 conversely the famous inverted zonation of the lesser himalaya is basically a primary pattern acquired during a one stage prograde metamorphism its origin must be related to the thrusting along the mct with heat supplied from the overlying hot tibetan slab as shown by synmetamorphic microstructures and the close geometrical relationships between the metamorphic isograds and the thrust 3 thermal equilibrium is reached between units above and below the mct far behind the thrust tip there is good agreement between the maximum temperature attained in the hanging wall and the temperature of the tibetan slab during the second metamorphic stage but closer to the mct front the thermal accordance between both sides of the thrust is due to a retrogressive metamorphic episode in the basal part of the tibetan slab

contrasting18o enrichment and origins of high himalayan and transhimalayan intrusives abstract twelve analysed leucogranites of the high himalaya in bhutan chung la monlakarchung and garhwal badrinath are among the most 18 o enriched granites known 11 5 12 4 18 o smow with two exceptions and separate minerals show good isotopic concordance the data strongly support an origin of the granites by anatexis of continental basement such as the indian crystalline basement sheet or slab undercut by the main central thrust of which five samples were analysed in contrast the pre collision transhimalayan gangdese batholiths to the north of the indus tsangpo suture as exemplified by the ladakh intrusives show an initially oceanic trend of 18 o vs sio 2 that becomes gradually somewhat enriched with respect to hachijo jima while not completely outside the range of enrichment that seems possible by fractional crystallisation this could tie in with the 87 sr inhomogeneities reported by honegger et al 9 which may be due to assimilation of variably radiogenic eurasian continental basement for both the leucogranites and ladakh intrusives the 18 o levels and the concordance between minerals rule out significant cumulative water rock ratios in syn or post magmatic interaction with subsurface waters

atmospheric circulation during warm geologic periods is the equator to pole surface temperature gradient the controlling factor paleoclimatologists have hypothesized that the equator to pole surface temperature gradient is a dominant control on the paleocirculation of the oceans and the atmosphere atmospheric simulations using realistic cretaceous 100 m y ago geography are used to examine quantitatively the relationships between paleogeography surface temperature gradients and the nature of the atmospheric circulation these results raise questions concerning the classical theories and interpretations of warm paleoclimates and suggest that paleogeography is an important factor governing the nature of the circulation