oceanic anoxic cycles orbital prelude to the bonarelli level oae 2 abstract the prelude to the second global oceanic anoxic event of the cretaceous oae 2 as recorded in the classic sections of the scaglia bianca formation in the umbria marches region of italy is characterized by an oscillation between black to gray organic rich cherts and white pelagic limestones spectral analysis of these lithologic alternations reveals a robust set of cycles whose periods are remarkably similar to the orbital cycles calculated by laskar et al laskar j robutel p joutel f gastineau m correia a c m levrard b 2004 a long term numerical solution for the insolation quantities of the earth astronomy and astrophysics 428 261 285 bandpass filtering shows that the 140 80 kyr signal approximates the envelope of the 26 16 kyr signal just as expected if these components represent responses to orbital eccentricity and precession matching the presumed eccentricity signal to the theoretical eccentricity of laskar et al yields an age for the base of the bonarelli level onset of oae 2 in italy of 94 21 ma 93 72 ma provides an alternative consistent with radiometric constraints from a correlative section in the western united states given the strong orbital control on the cyclic deposition of the organic rich precursors of oae 2 within the scaglia bianca formation we hypothesize that the timing of oae 2 itself is similarly controlled by astronomical variations indeed the occurrence of oae 2 coincides with a protracted period of unusually low insolation variation owing to simultaneous nodes in all orbital parameters we speculate that other oaes similarly coincided with insolation nodes and dampened seasonality from this perspective some but perhaps not all of the oaes may be periodic events reflecting cycles of oceanic anoxia that predictably punctuated a 50 myr period of cretaceous climate

late cenomanian to middle turonian high resolution carbon isotope stratigraphy new data from the munsterland cretaceous basin germany abstract new high resolution carbon isotope stratigraphies from two basinal pelagic carbonate successions in northern germany halle and oerlinghausen munsterland cretaceous basin resolve late cenomanian to early mid turonian carbon cycle variations at timescales of less than 100 kyr beside the major carbon isotope excursion of the late cenomanian oceanic anoxic event oae 2 11 small scale distinct features are precisely resolved in the 13c carbonate curve and related to boreal macrofossil zonations the small scale carbon isotope events correspond to secular 13c carbonate variations identified previously in the english chalk the boreal high resolution 13c carbonate curve shows a detailed coincidence with two tethyan 13c curves from italy what demonstrates the interregional significance of the 13c dates and allows their correlation within error limits of 40 kyr furthermore the new 13c curve enables the calibration of boreal and tethyan macro and microfossil zonations accordingly the tethyan calcareous nannoplankton boundary nc13 nc14 corresponds to the boreal fo of c woollgari the index taxon for the lower middle turonian boundary the cyclic appearance and the temporal spacing of the small scale carbon isotope events suggest that orbital forcing exerted control on surface water productivity and organic matter preservation at the sea floor

orbital time scale and new c isotope record for cenomanian turonian boundary stratotype previous time scales for the cenomanian turonian boundary ctb interval containing oceanic anoxic event ii oae ii vary by a factor of three in this paper we present a new orbital time scale for the ctb stratotype established independently of radiometric biostratigraphic or geochemical data sets update revisions of ctb biostratigraphic zonation and provide a new detailed carbon isotopic record for the ctb study interval the orbital time scale allows an independent assessment of basal biozone ages relative to the new ctb date of 93 55 ma gts04 the d 13 corg data document the abrupt onset of oae ii significant variability in d 13 corg values and values enriched to almost 222 these new data underscore the difficulty in defining oae ii termination using the new isotope curve and time scale estimates of oae ii duration can be determined and exported to other sites based on integration of well established chemostratigraphic and biostratigraphic datums the new data will allow more accurate calculations of biogeochemical and paleobiologic rates across the ctb

orbital control on carbon cycle and oceanography in the mid cretaceous greenhouse we established a new high resolution carbonate carbon isotope record of the albian interval of the marne a fucoidi formation central apennines italy which was deposited on the southern margin of the western tethys ocean bulk carbonate sampled with 10 15 cm spacing was used for the construction of a continuous carbon isotope curve through the albian stage spectral analyses reveal prominent 400 kyr cyclicity in the 13c curve which correlates with milankovitch long eccentricity changes cycles occurring in our record resemble those observed in several cenozoic 13c records suggesting that a link between orbital forcing and carbon cycling existed also under mid cretaceous greenhouse conditions based on comparisons with cenozoic eccentricity carbon cycle links we hypothesize that 400 kyr cycles in the mid cretaceous were related to a fluctuating monsoonal regime coupled with an unstable oceanic structure which made the oceanic carbon reservoir sensitive to orbital variations in the tethys these oceanographic conditions lasted until the late albian and then were replaced by a more stable circulation mode less sensitive to orbital forcing

correlation of early cretaceous carbon isotope stratigraphy and platform drowning events a possible link the early cretaceous carbonate carbon isotope record is marked by three positive high amplitude 1 5 excursions each covering time spans of more than 106 years they are of late valanginian hauterivian and early and late aptian age in a case study along a transect across the western tethys ocean we identified a coincidence between 13c excursions black shale formation and widespread carbonate platform drowning events we conclude that the 13c excursions reflect a change in partitioning of carbon between the organic and carbonate carbon sinks which was triggered by climate induced ecological changes in cretaceous pelagic and neritic environments episodes of intensified greenhouse climate conditions led to an increase in weathering erosion and runoff rates and to elevated nutrient transfer rates from continents into oceans the resulting increase in oceanic nutrient levels favoured marine phytoplankton production and black shale deposition while conditions for carbonate producing biotas became unfavourable partial choking of carbonate production along river influenced coasts resulted in widespread carbonate platform drowning during times of sea level rise in the valanginian and aptian widespread contemporaneous black shale deposits and drowned carbonate platforms therefore reflect the contrasting response of the marine organic and carbonate carbon pumps to nutrient enhanced phytoplankton productivity the change in marine carbon partitioning is mirrored in a shift of the 13c record towards more positive values the transition to the 13c peak values lasted up to several hundred thousand years the peaks of the excursions also covering a time span of up to several hundred thousand years reflect a new stabilisation of the carbon partitioning between carbonate and organic carbon sinks a renewed intensification of carbonate sedimentation under mesotrophic conditions was facilitated by stabilisation of the sea level rise at a high level decreasing 13c values record increasing carbonate carbon burial rates at constant or decreasing organic carbon accumulation rates these changes contributed to the stabilisation of the marine carbon budget and the global carbon cycle up to millions of years after its initial perturbation

axial obliquity control on the greenhouse carbon budget through middle to high latitude reservoirs carbon sources and sinks are key components of the climate feedback system yet their response to external forcing remains poorly constrained particularly for past greenhouse climates carbon isotope data indicate systematic million year scale transfers of carbon between surface reservoirs during and immediately after the late cretaceous thermal maximum peaking in the cenomanian turonian circa 97 91 million years myr ago here we calibrate albian to campanian 108 72 myr ago high resolution carbon isotope records with a refined chronology and demonstrate how net transfers between reservoirs are plausibly controlled by 1 myr changes in the amplitude of axial obliquity the amplitude modulating terms are absent from the frequency domain representation of insolation series and require a nonlinear cumulative mechanism to become expressed in power spectra of isotope time series mass balance modeling suggests that the residence time of carbon in the ocean atmosphere system is by itself insufficient to explain the myr scale variability it is proposed that the astronomical control was imparted by a transient storage of organic matter or methane in quasi stable reservoirs wetlands soils marginal zones of marine euxinic strata and potentially permafrost that responded nonlinearly to obliquity driven changes in high latitude insolation and or meridional insolation gradients while these reservoirs are probably underrepresented in the geological record due to their quasi stable character they might have provided an important control on the dynamics and stability of the greenhouse climate

a high resolution carbon isotope record of the turonian stage correlated to a siliciclastic basin fill implications for mid cretaceous sea level change turonian strata of the bohemian cretaceous basin central europe preserve a basin scale record of shoreline transgressions and regressions previously interpreted to have been strongly influenced by short term eustatic cycles here nearshore siliciclastic strata in two separate sub basins are correlated to a multi stratigraphic dataset generated from a new research core bch 1 drilled in offshore marine sediments of the central basin a high resolution 13corg record from bch 1 is presented along with major and minor element proxies toc carbonate content terrestrial to marine palynomorph ratios and detailed macro and microfossil biostratigraphy the 400 m thick turonian through lower coniacian interval permits correlation to the highest resolution c isotope curves available all carbon isotope events demonstrated by 13ccarb studies in the british chalk nw germany and other reference sections in europe are recognized in the 13corg curve from bch 1 a number of short term basin wide regressions in the bohemian cretaceous basin most likely reflecting eustatic falls show a recurrence interval of 100 kyr or less this is an order of magnitude shorter than the timing of sea level falls inferred from the new jersey margin and the apulian platform interpreted to be driven by glacioeustacy the estimated magnitude of the bohemian basin sea level falls typically 10 20 m and generally 40 m indicates that the 2 4 myr period suggested by others to generate 3rd order cycles is too long to be the principal cycle generating unconformities in rapidly subsiding basins where the rate of eustatic fall must exceed the subsidence rate unconformities in low accommodation settings such as passive margins most likely represent amalgamated records of multiple cycles of sea level fluctuations of 100 kyr scale recognizable only in high resolution datasets from expanded successions comparison of the 13c excursions to the interpreted sea level record has not yielded a clear causal link a long term background 13c cycle shows a duration close to the 2 4 myr long eccentricity cycle and shorter term 1 myr scale highs and lows in 13c appear to broadly correspond to intervals characterised by more pronounced short term sea level highs and lows respectively however on the scale of intermediate to short term 13c fluctuations no systematic relationship between 13c and sea level change can be demonstrated

new oxygen isotope evidence for long term cretaceous climatic change in the southern hemisphere a new composite 18 o record generated from calcareous fine fraction and bulk sediments from the exmouth plateau details long term cretaceous climatic change at mid latitudes in the southern hemisphere assessment of new and previously published 18 o data indicates that a mid cretaceous global climatic optimum was achieved sometime between the time of the cenomanian turonian boundary and the middle turonian when surface ocean paleotemperatures were the highest of the past 115 m y periods of cooling and warming that reversed the general patterns were superimposed on long term aptian turonian warming and turonian maastrichtian cooling trends respectively extrapolation of southern hemisphere paleotemperature trends to maastrichtian paleotemperature data from a low latitude pacific guyot implies that maximum mid cretaceous low latitude paleotemperatures could have been in excess of 33 c

cool episodes in the cretaceous exploring the effects of physical forcings on antarctic snow accumulation the question whether large scale glaciations on antarctica were possible in a late mesozoic greenhouse climate such as the late cretaceous is an intriguing one the most recent years have provided an increasing number of studies investigating the growth and decay of paleo continental ice sheets on antarctica possibly large enough to affect sea level since the outcome of these studies doesn t provide a basis for a conclusive decision we have performed a number of model runs using an atmospheric general circulation model agcm to test whether large volumes of snow might have accumulated even under late cretaceous greenhouse conditions by varying orbital parameters as well as topography and atmospheric co2 concentrations our models indicate the possibility of an antarctic ice shield build up large enough to drive sea level fluctuations on the order of tens of meters within 20 000 years this is supported under the assumption of pco2 levels 800 ppm low insolation and elevated topography the growth of a major antarctic ice sheet would be possible on reasonable time scales to accumulate about half the present day snow ice volume which is required to explain the documented shifts in oxygen isotopes our model results suggest a time span between 20 000 and 80 000 years for these ice volumes to accumulate

sulfur isotopes track the global extent and dynamics of euxinia during cretaceous oceanic anoxic event 2 the mesozoic era is characterized by numerous oceanic anoxic events oaes that are diagnostically expressed by widespread marine organic carbon burial and coeval carbon isotope excursions here we present coupled high resolution carbon and sulfur isotope data from four european oae 2 sections spanning the cenomanian turonian boundary that show roughly parallel positive excursions significantly however the interval of peak magnitude for carbon isotopes precedes that of sulfur isotopes with an estimated offset of a few hundred thousand years based on geochemical box modeling of organic carbon and pyrite burial the sulfur isotope excursion can be generated by transiently increasing the marine burial rate of pyrite precipitated under euxinic i e anoxic and sulfidic water column conditions to replicate the observed isotopic offset the model requires that enhanced levels of organic carbon and pyrite burial continued a few hundred thousand years after peak organic carbon burial but that their isotope records responded differently due to dramatically different residence times for dissolved inorganic carbon and sulfate in seawater the significant inference is that euxinia persisted post oae but with its global extent dwindling over this time period the model further suggests that only 5 of the global seafloor area was overlain by euxinic bottom waters during oae 2 although this figure is 30 greater than the small euxinic fraction present today 0 15 the result challenges previous suggestions that one of the best documented oaes was defined by globally pervasive euxinic deep waters our results place important controls instead on local conditions and point to the difficulty in sustaining whole ocean euxinia

late cretaceous climate changes recorded in eastern asian lacustrine deposits and north american epieric sea strata abstract cretaceous climate data of the long lived cretaceous songliao basin sb in eastern asia is correlated and compared with the western interior seaway wis on the northern american plate in order to understand better the dynamics of the earth s past greenhouse climates nearly continuous late cretaceous terrestrial deposition in the songliao basin is represented by two cores totaling 2431 m in length the turonian maastrichtian age of the section is based on integrated stratigraphy and is comparable in age with upper cretaceous strata in the wis being consistent with global trends the dynamic late cretaceous climates of both the sb and wis gradually cooled from the warmest albian cenomanian time to the end of the maastrichtian with several intervening warm periods as did the global climate however regional differences existed the songliao basin climate was humid to semi humid warm temperate subtropical and the western interior seaway was in the humid warm temperate zone and experienced only moderate climatic changes the shifts of oxygen isotope data in the songliao basin were frequent and abrupt whereas wis records more gradual change affected mainly by fresh water runoff mixing with southern tethyan and northern arctic waters sedimentary cycles of eccentricity obliquity and precession bands are recorded in both the sb and wis basins the sedimentary cycles in the wis and sb are interpreted to be related to variations of the wet dry runoff cycles which indicate that orbital forcing played an important role in global climate change in late cretaceous the most favorable condition for organic carbon burial in both the sb and wis basin was bottom water anoxia regardless of the cause of the anoxia but the organic carbon burial rate was usually much higher in the songliao lake than in the wi epeiric sea suggesting that giant lakes may serve as important sinks of atmospheric co 2 in both basins organic rich deposits formed during a rise in water level and incursion of saline waters the integration of paleoclimate data from cretaceous marine deposits and terrestrial sedimentary record will promote our understanding of the cretaceous greenhouse climate change and may provide insights for a future greenhouse world

detailed reconstructions of holocene climate and environmental changes in the taman peninsula kuban river delta region and their correlation with rapid sea level fluctuations of the black sea abstract the paper presents results of a detailed subdivision of holocene sediments in the region of the kuban river delta into climate stratigraphic units and reconstructions of the vegetation climate and depositional environment changes on the taman peninsula ne black sea region during the last 7400 years the reconstructions are based on data from geological geomorphological and lithological facies analysis palynological studies and radiocarbon dating of six sections penetrated by boreholes in various parts of the kuban river delta the studied lithological sequences present an assortment of liman fluvial lacustrine and marsh sediments as well as subaerial deposits that accumulated in the course of the delta development the factual materials thus obtained provided the basis for reconstructing changes in zonal vegetation types and transformations of zonal and intra zonal formations in the holocene landscapes of the taman peninsula induced by changes in edaphic conditions and regional climate seventeen phases stages have been recognized in the evolution of vegetation and climate through the middle and late holocene and a detailed description is given to every phase a detailed pollen climate chronostratigraphic scheme of the black sea level fluctuations over the last 7400 years is proposed steppe and forest steppe landscapes were dominant on the taman peninsula over the greater part of the studied period of the holocene the warmest and most arid conditions were typical of the phases dominated by steppes with grass herb and grass and pigweed wormwood chenopodiaceae artemisia plant communities such phases were dated to intervals 4660 4400 3780 3430 2910 2280 1540 1230 and 900 830 730 cal yr bp the most humid intervals within the studied period are dated at 5160 4900 4400 3780 2280 1540 cal yr bp they were distinct because of the dominance of broadleaf mostly beech oak hornbeam forests those humid intervals most likely correspond to the maxima of the kalamitian dzemetinian and nimphaean black sea transgressions the climatic indexes and zonal attribution of the dominant plant communities can be matched with six transgressive and seven regressive sea level fluctuations of various ranks over the last 7400 years of the six transgressive stages one stage was marked by a relatively cool and humid climate whereas five others occurred under warm and wet conditions the regressive stages include four phases of relatively warm and dry climate and three periods of dry and relatively cold or cool climate

simulating the biogeochemical effects of volcanic co2 degassing on the oxygen state of the deep ocean during the cenomanian turonian anoxic event oae2 cretaceous anoxic events may have been triggered by massive volcanic co2 degassing as large igneous provinces lips were emplaced on the seafloor here we present a comprehensive modeling study to decipher the marine biogeochemical consequences of enhanced volcanic co2 emissions a biogeochemical box model has been developed for transient model runs with time dependent volcanic co2 forcing the box model considers continental weathering processes marine export production degradation processes in the water column the rain of particles to the seafloor benthic fluxes of dissolved species across the seabed and burial of particulates in marine sediments the ocean is represented by twenty seven boxes to estimate horizontal and vertical fluxes between boxes a coupled ocean atmosphere general circulation model aogcm is run to derive the circulation patterns of the global ocean under late cretaceous boundary conditions the aogcm modeling predicts a strong thermohaline circulation and intense ventilation in the late cretaceous oceans under high pco2 values with an appropriate choice of parameter values such as the continental input of phosphorus the model produces ocean anoxia at low to mid latitudes and changes in marine 13c that are consistent with geological data such as the well established 13c curve the spread of anoxia is supported by an increase in riverine phosphorus fluxes under high pco2 and a decrease in phosphorus burial efficiency in marine sediments under low oxygen conditions in ambient bottom waters here we suggest that an additional mechanism might contribute to anoxia an increase in the c p ratio of marine plankton which is induced by high pco2 values according to our aogcm model results an intensively ventilated cretaceous ocean turns anoxic only if the c p ratio of marine organic particles exported into the deep ocean is allowed to increase under high pco2 conditions being aware of the uncertainties such as diagenesis this modeling study implies that potential changes in redfield ratios might be a strong feedback mechanism to attain ocean anoxia via enhanced co2 emissions the formation of c enriched marine organic matter may also explain the frequent occurrence of global anoxia during other geological periods characterized by high pco2 values

cretaceous oceanic anoxic event 2 triggered by a massive magmatic episode oceanic anoxic events oaes were episodes of widespread marine anoxia during which large amounts of organic carbon were buried on the ocean floor under oxygen deficient bottom waters oae2 occurring at the cenomanian turonian boundary about 93 5 myr ago is the most widespread and best defined oae of the mid cretaceous although the enhanced burial of organic matter can be explained either through increased primary productivity or enhanced preservation scenarios the actual trigger mechanism corresponding closely to the onset of these episodes of increased carbon sequestration has not been clearly identified it has been postulated that large scale magmatic activity initially triggered oae2 refs 4 5 but a direct proxy of magmatism preserved in the sedimentary record coinciding closely with the onset of oae2 has not yet been found here we report seawater osmium isotope ratios in organic rich sediments from two distant sites we find that at both study sites the marine osmium isotope record changes abruptly just at or before the onset of oae2 using a simple two component mixing equation we calculate that over 97 per cent of the total osmium content in contemporaneous seawater at both sites is magmatic in origin a approximately 30 50 fold increase relative to pre oae conditions furthermore the magmatic osmium isotope signal appears slightly before the oae2 as indicated by carbon isotope ratios suggesting a time lag of up to approximately 23 kyr between magmatism and the onset of significant organic carbon burial which may reflect the reaction time of the global ocean system our marine osmium isotope data are indicative of a widespread magmatic pulse at the onset of oae2 which may have triggered the subsequent deposition of large amounts of organic matter

obliquity forcing of organic matter accumulation during oceanic anoxic event 2 1 an analysis of orbitally influenced climate sensitive sedimentation is conducted across a meridional transect of the proto north atlantic to reconstruct the behavior of the carbon cycle and climate during oceanic anoxic event 2 oae 2 94 ma midlatitude to near equatorial sites spanning deep ocean to shelf environments are evaluated using a new inverse method for the identification and calibration of orbital influence in ancient strata the results yield consistent independent astrochronologies at each location compatible with the recently published radioisotopic astrochronologic time scale at the cenomanian turonian gssp and thus provide a unified high resolution temporal context for evaluation of the event the proto north atlantic astrochronologies document an amplification of obliquity power during oae 2 indicating that obliquity was the dominant pacemaker of organic matter accumulation by the latter portion of the event the strong obliquity signal suggests an influence of high latitude climate processes across midlatitude deep ocean to tropical shelf environments changes in oceanic circulation during oae 2 represent a likely mechanism for the propagation of a high latitude signal and proxy data from demerara rise reveal the development of a new intermediate water mass source synchronous with the record of obliquity amplification we hypothesize that a dense high latitude water mass displaced a pre existing nutrient rich anoxic deep water layer in the proto north atlantic augmented by enhanced volcanism driving an episode of high productivity that lasted 700 800 ka the development and intensification of the new intermediate deep water source was potentially driven by eustatic sea level rise which created expansive seaways in mid to high latitudes

synchronous mid miocene upper and deep oceanic δ13c changes in the east equatorial pacific linked to ocean cooling and ice sheet expansion abstract we present mid miocene 12 0 16 0 ma high resolution 3 8 kyr deep thermocline planktonic foraminiferal 18 o and 13 c records at iodp site u1337 from the eastern equatorial pacific the benthic and planktonic 18 o records of site u1337 have a similar long term cooling trend but display obvious amplitude differences of glacial interglacial cycles after 13 9 ma planktonic 18 o cycles are usually larger than 1 0 nearly 2 times those of the benthic 18 o the post 13 9 ma change is probably caused by intensified upwelling along with ocean cooling but may include upper ocean circulation changes both the benthic and planktonic 13 c records at site u1337 reveal marked 400 kyr carbon isotope cycles during the mmco middle miocene climate optimum with a trend toward lower 13 c from 16 0 ma to 12 0 ma the similarity in response between surface and deep carbon isotopes indicates that the mid miocene carbon excursions in the east equatorial pacific involved the whole ocean basin water column and thus are a global signal box model simulations reveal that the long eccentricity 400 kyr paced carbon inputs from weathering changed the burial ratio of carbonates to organic carbon and helped to produce the significant 400 kyr cycles in oceanic 13 c the increased weathering of carbonate silicate and kerogen rocks are the major factors controlling the long term decrease in oceanic 13 c after 16 0 ma

high resolution stable isotope records from the upper cretaceous rocks of italy and spain glacial episodes in a greenhouse planet high resolution 13c and 18o records from upper albian to lower santonian pelagic carbonates of the contessa quarry section in italy exhibit large positive oxygen isotopic excursions of 1 in the lower cenomanian and upper turonian coniacian strata within the uncertainties of biostratigraphic correlation these positive excursions appear to correspond to times of large sea level regressions in global sequence stratigraphic sea level curves several lines of evidence suggest that the major 18o excursions in contessa reflect episodes of global cooling and not differential diagenesis numerical models of oxygen isotope exchange during diagenesis show that a high contrast in the degree of alteration would be required to produce these signals as artifacts of diagenesis and lithological data provide no evidence for such large contrasts in the degree of alteration furthermore although precise correlation with a section in the south of spain is hampered by stratigraphic complexities the general sequence of major positive 18o excursions is reproduced it is unlikely that differential diagenesis would produce similar artifacts in multiple sites one explanation for the link between episodes of global cooling and sea level falls is that global cooling events led to polar ice sheet accumulation lowering sea level although ice free conditions have been inferred from evidence for a much warmer climate in late cretaceous time our results suggest that the relationship between continental high latitude ice sheets and overall climatic warmth warrants further examination

geochemical and climatic effects of increased marine organic carbon burial at the cenomanian turonian boundary perhaps the most significant event in the cretaceous record of the carbon isotope composition of carbonate1 2 other than the 1 2 5 negative shift in the carbon isotope composition of calcareous plankton at the cretaceous tertiary boundary3 is the rapid global positive excursion of 2 13c enrichment which took place between 91 5 myr and 90 3 myr late cenomanian to earliest turonian c t boundary event 1 4 5 this excursion has been attributed to a change in the isotope composition of the marine total dissolved carbon tdc reservoir resulting from an increase in rate of burial of 13c depleted organic carbon which coincided with a major global rise in sea level5 during the so called c t oceanic anoxic event oae 6 here we present new data from nine localities which demonstrate that a positive excursion in the carbon isotope composition of organic carbon at or near the c t boundary7 8 is nearly synchronous with that for carbonate and is widespread throughout the tethys and atlantic basins fig 1 as well as in more high latitude epicontinental seas the postulated increase in the rate of burial of organic carbon may have had a significant effect on co2 and o2 concentrations in the oceans and atmosphere and consequent effects on global climate and sedimentary facies

mid cretaceous albian santonian sea surface temperature record of the tropical atlantic ocean paleoclimate records of geologic time periods characterized by extreme global warmth such as the mid cretaceous are important for a better understanding of the earth9s climate system operating in an exceptionally warm mode here we applied an organic geochemical proxy tex 86 on organic matter rich albian santonian sediments recovered from ocean drilling program leg 207 sites 1258 and 1259 on demerara rise to reconstruct sea surface temperatures ssts in the western equatorial atlantic preceded by a stepwise cenomanian warming trend 31 35 c the onset of the cretaceous thermal maximum coincided here with the cenomanian turonian boundary event once established this extreme warm climate regime characterized by averaged tropical ssts close to 35 c lasted up to the turonian coniacian transition two pronounced cooler intervals 2 3 c interrupt this otherwise remarkably stable record providing the first 18 o independent evidence for middle turonian cooling that previously has been attributed to glacioeustatic sea level lowering coniacian ssts decline stepwise reaching a minimum in the santonian 32 33 c where cooling is most pronounced presumably concomitant with the first progressive opening of a deep water passage through the equatorial atlantic gateway

insolation control on the late cretaceous hydrological cycle and tropical african climate global climate modelling linked to marine climate records data from late cretaceous paleoclimate simulations and their linkage to a geological model derived from long term high resolution proxy data indicate and support strong relationships between african climate and tropical atlantic sedimentation here we present results from an interdisciplinary study by varying only one parameter in the set of orbital boundary conditions of the numeric model we focus on the climatic impact of precessional forcing on the global and regional climate system as a result new insights to the internal dynamics of climate the different compartments and fluxes of the hydrological cycle and finally the sedimentary response within the oceanic realm during greenhouse conditions have been approached the climate models suggest that insolation changes at 25 55 s are the trigger for cyclic variations of the tropical hydrological cycle of northern africa between the various models a maximum difference in insolation at the top of the atmosphere of 14 w m2 is needed to produce the documented changes in the hydrological cycle first of all the simulations do not suggest any substantial latitudinal movement of the itcz over the course of one precessional cycle the models rather indicate cross latitudinal variation of pressure systems and variation in the magnitude and direction of surface winds linking tropical africa to the mid southern latitudes this cross latitudinal atmospheric teleconnection denotes a reduced role of the tropics as driver of cretaceous climate system therefore the linkage of proxy based geological and numeric models rather supports the idea that tropical atlantic black shale formation in the late cretaceous was ultimately triggered by climate change in mid southern latitudes with precipitation and river discharge being the transport mechanisms as a hypothesis that will be tested in the near future we speculate that the mid latitudes represent the ultimate region of climate signal formation during times of extreme global warmth

porewater ph and authigenic phases formed in the uppermost sediments of the santa barbara basin abstract in this paper porewater and solid phase analyses are used in combination with in situ o 2 and ph microelectrode measurements to characterize early diagenetic processes in the uppermost sediments of the santa barbara basin california rapid reduction of dissolved oxygen nitrate solid phase manganese and iron and dissolved sulfate is observed between sediment depths of 0 and 2 cm reductive solubilization of ferric iron phases releases fe 2 adsorbed phosphate and fluoride to the porewaters and contributes to a sharp increase in porewater ph between 2 and 4 cm sulfate reduction rates peak ph levels off and acid volatile sulfides and pyrite become the dominant forms of solid phase iron saturation state calculations which depend largely on ph indicate that the porewaters of the santa barbara basin become saturated with respect to carbonate fluorapatite and calcite within the first 0 25 mm of the sediment and are highly supersaturated by and below 2 cm in spite of this result porewater evidence of phosphate and fluoride removal into a solid phase is observed only in the first 5 cm of some cores whereas dissolved ca profiles suggest dispersed calcite precipitation throughout the sediment column this finding is interpreted as an indication of the nonsteady state nature of the surface reactions that may given sufficient nucleation sites and time lead to carbonate fluorapatite genesis in anoxic sediments finally microelectrode ph profiles from two other basins in the california borderlands are presented these demonstrate that the porewaters of the santa barbara basin are more alkaline than those of other basins this outcome is attributed to the lack of particle mixing and a unique interplay between fe liberation and fes precipitation reactions in the santa barbara basin

periodic mid cretaceous oceanic anoxic events linked by oscillations of the phosphorus and oxygen biogeochemical cycles 1 a series of oceanic anoxic events oaes occurred in the mid cretaceous warm period 120 80 ma that have been linked with high rates of organic carbon burial warm high and low latitude temperatures and sea level changes oaes have been studied individually but a causal mechanism that connects them has been lacking we show that peaks in phosphorus accumulation in marine sediments broadly coincide with oaes 1a 1b 1d 2 and 3 and exhibit a 5 6 myr periodicity which for reactive p is prominent over 100 80 ma oxic anoxic oscillations of this frequency are also found in a model of the coupled n p c and o2 biogeochemical cycles these oscillations are maintained by positive feedbacks between phosphate concentration biological productivity and anoxia in the global ocean and counteracting but slower negative feedbacks involving changes in atmospheric oxygen an increase in phosphorus weathering rate above a critical threshold can shift the system into self sustaining oscillation this could have been caused by tectonic and volcanic forcing increasing atmospheric co2 and global warmth 120 80 ma augmented by the rise of flowering plants around 100 ma with a plausible forcing scenario we are able to reproduce the approximate timing of oaes 1a 1b 1d 2 and 3 in the model

late cretaceous orbitally paced carbon isotope stratigraphy from the bottaccione gorge italy abstract a refined astronomical tuning of the upper albian lower campanian is proposed from the bottaccione reference section gubbio central italy long term eccentricity cycles filtered from a high resolution 13c record were tuned to the highly stable 405 kyr cycles of the new la2010 astronomical solution for the earth s orbital elements the achieved orbital tuning provides a new precise and accurate age model for dating biostratigraphic magnetostratigraphic and carbon isotope events through a 23 myr long record cycles of 8 0 4 7 3 4 and 2 4 myr modulate the entire 13c record thus extending their detection from the cenozoic to 100 ma and represent primary and stable long term oscillation modes of earth s climate ocean system although an ultimate driver of these long term periodicities is lacking we speculate that specifically the periodicity at 4 7 myr represents a homologue of the present eccentricity grand cycles evolved by the chaotic behaviour of solar system planets during the mesozoic the long term periodicities potentially reflect an unexplored expression of the low frequency response of the carbon cycle to global biogeochemical dynamics of major nutrients particularly phosphorus associated with modulation of inputs to the ocean in turn triggered by high order marine transgressions and formation of highly productive shelf seas this very long term eccentricity control modulated by periodic low energy cycles is suggested to play a crucial role in carbon cycling controlling a chain of climate sensitive global biogeochemical processes on the earth finally these grand cycles provide a potential tool for geological correlation and provide a robust constraint for accurate calculation of the orbital evolution of the solar system

on the origin of cenozoic and mesozoic third order eustatic sequences abstract the origin of third order eustatic sequences is reviewed by comparing recent sequence stratigraphic data to the latest best constrained astronomical model middle eocene to holocene icehouse sequences correspond to 1 2 myr obliquity cycles constraints from oxygen isotope records highlight the link between icehouse sea level lowerings sequence boundaries and 1 2 myr obliquity nodes mesozoic greenhouse sequences show some relation with the 2 4 myr eccentricity cycles suggesting that orbital forcing contribute to sea level change we suggest that during the icehouse large ice sheets associated with significant glacioeustatic changes 25 m up to 120 m changes were mainly governed by obliquity forcing during icehouse worlds obliquity forcing was the stongest control on global sea level and depositional sequences additionally during the middle eocene third order sequences were glacioeustatically driven in tune with 1 2 myr obliquity cycle suggesting that the presence of significant ice sheets is earlier than previously supposed i e early eocene in contrast during greenhouse worlds e g ephemeral small to medium sized or no ice sheets 0 25 m glacioeustatic changes the expression of obliquity in the sedimentary record is weak and intermittent instead the eccentricity signature which is the modulator of climatic precession is documented moreover we presume that greenhouse sequences on the myr scale are global and hence cannot be caused by regional tectonism e g intraplate stress or mantle hot blobs instead the eccentricity link implies a weaker glacioeustatic control because thermoeustasy is too small to explain the sea level changes stratigraphically well documented fourth order sequences may be linked to the astronomically stable strongest amplitude 405 kyr eccentricity cycle and possibly to 160 200 kyr obliquity modulation cycles fifth order sequences to the short 100 kyr eccentricity cycles and finally sixth order sequences to the fundamental obliquity 40 kyr and climatic precession 20 kyr cycles these astronomical cycles could be preserved in the sedimentary record and have been demonstrated to control sea level changes accordingly by placing depositional sequence orders into a high resolution temporal framework i e orbital periodicities standardization of eustatic sequence hierarchy may be possible

a critical evaluation of carbon isotope stratigraphy and biostratigraphic implications for late cretaceous global correlation abstract climate variability is driven by a complex interplay of global scale processes and our understanding of them depends on sufficient temporal resolution of the geologic records and their precise inter regional correlation which in most cases cannot be obtained with biostratigraphic methods alone chemostratigraphic correlation based on bulk sediment carbon isotopes is increasingly used to facilitate high resolution correlation over large distances but complications arise from a multitude of possible influences from local differences in biological diagenetic and physico chemical factors on individual 13c records that can mask the global signal to better assess the global versus local contribution in a 13c record it is necessary to compare numerous isotopic records on a global scale as a contribution to this objective this paper reviews bulk sediment 13ccarb records from the late cretaceous in order to identify differences and similarities in secular 13c trends that help establish a global reference 13c record for this period the study presents a global scale comparison of twenty 13c records from sections representing various palaeo latitudes in both hemispheres and different oceanic settings from the boreal tethys western interior indian ocean and pacific ocean and with various diagenetic overprinting the isotopic patterns are correlated based on independent dating with biostratigraphic and paleomagnetic data and reveal good agreement of the major isotope events despite offsets in absolute 13c values and variation in amplitude between the sites these differences reflect the varying local influences e g from depositional settings bottom water age and diagenetic history whereas the concordant patterns in 13c shifts might represent 13c fluctuations in the global seawater dissolved inorganic carbon the latter is modulated by variations in organic matter burial relative to re mineralization in the global scale formation of authigenic carbonate and in partitioning of carbon between organic carbon and carbonate sinks these variations are mainly controlled by changes in climate and eustasy additionally some globally synchronous shifts in the bulk 13ccarb records could result from parallel variation in the contribution of authigenic carbonate to the sediment formation of these cements through biologically mediated early diagenetic processes is related to availability of oxygen and organic material and thus can be globally synchronized by fluctuations in eustasy atmospheric and oceanic oxygen levels or in large scale oceanic circulation because the influence of early diagenetic cements on the bulk 13ccarb signal can but need not be synchronized chemostratigraphy should not be used as a stand alone method for trans continental correlation and especially minor isotopic shifts have to be interpreted with utmost care nevertheless the observed consistency of the 13c correlations confirms global scale applicability of bulk sediment 13c chemostratigraphy for the late cretaceous including sediments that underwent lithification and burial diagenesis such as the sediments from the himalayan and alpine sections limitations arise from increased uncertainties 1 in sediments with very low carbonate content 2 from larger 13c variability in sediments from very shallow marine environments 3 from unrecognized hiatuses or strong changes in sedimentation rates and 4 in sections with short stratigraphic coverage or with few biostratigraphic marker horizons the combination of chemostratigraphy with biostratigraphy and magnetostratigraphy substantially increases the precision and temporal resolution of inter regional correlations and helps overcome problems that arise from differences in biostratigraphic schemes facies or provincialism of key fossils by using an iterative approach to stepwise increase precision of the correlations isochroneity of first and last occurrences of marker species versus chemostratigraphy is tested which helps to improve biostratigraphic zonations to assess zonal boundary ages and to identify useful criteria for defining late cretaceous stage boundaries many of which are still not formally defined the presented correlations indicate a consistent position for most planktic foraminifer zonal boundaries relative to corresponding isotope shifts during the mid cretaceous sea level high whereas diachroneity appears to be more pronounced during the late campanian and maastrichtian global sea level fall a similar pattern is observed for trans continental consistency in the 13c shifts graphic correlation of isotopic shifts magnetostratigraphic and biostratigraphic events among the compared sections is used to detect hiatuses or relative changes sediment accumulation rates and visualizes consistency or offsets of individual biostratigraphic markers relative to chemo and magnetostratigraphy finally an attempt of a global average 13c stack is presented for the turonian through maastrichtian

ocean overturning since the late cretaceous inferences from a new benthic foraminiferal isotope compilation 1 benthic foraminiferal oxygen isotopic d 18 o and carbon isotopic d 13 c trends constructed from compilations of data series from multiple ocean sites provide one of the primary means of reconstructing changes in the ocean interior these records are also widely used as a general climate indicator for comparison with local and more specific marine and terrestrial climate proxy records we present new benthic foraminiferal d 18 o and d 13 c compilations for individual ocean basins that provide a robust estimate of benthic foraminiferal stable isotopic variations to 80ma andtentatively to 110ma first order variations ininterbasinal isotopicgradients delineate transitions from interior ocean heterogeneity during the late cretaceous 65 ma to early paleogene 35 65 ma homogeneity and a return to heterogeneity in the late paleogene early neogene 35 0 ma we propose that these transitions reflect alterations in a first order characteristic of ocean circulation the ability of winds to make water in the deep ocean circulate we document the initiation of large interbasinal d 18 o gradients in the early oligocene and link the variations in interbasinal d 18 o gradients from the middle eocene to oligocene with the increasing influence of wind driven mixing due to the gradual tectonic opening of southern ocean passages and initiation and strengthening of the antarctic circumpolar current the role of wind driven upwelling possibly associated with a tethyan circumequatorial current in controlling late cretaceous interior ocean heterogeneity should be the subject of further research

lithium isotope evidence for enhanced weathering during oceanic anoxic event 2 the ocean anoxic event 2 oae2 about 93 5 million years ago was marked by high atmospheric co2 concentration rapid global warming and marine anoxia and euxinia the event lasted for about 440 000 years and led to habitat loss and mass extinction the marine anoxia is thought to be linked to enhanced biological productivity but it is unclear what triggered the increased production and what allowed the subsequent rapid climate recovery here we use lithium isotope measurements from carbonates spanning the interval including oae2 to assess the role of silicate weathering we find the lightest values of the li isotope ratio 7li during oae2 indicating high levels of weathering and therefore atmospheric co2 removal which we attribute to an enhanced hydrological cycle we use a geochemical model to simulate the evolution of 7li and the ca sr and os isotope tracers our simulations suggest a scenario in which the eruption of a large igneous province led to high atmospheric co2 concentrations and rapid global warming which initiated oae2 the simulated warming was accompanied by a roughly 200 000 year pulse of accelerated weathering of mafic silicate rocks which removed co2 from the atmosphere the weathering also delivered nutrients to the oceans that stimulated primary productivity we suggest that this process together with the burial of organic carbon allowed the rapid recovery and stabilization from the greenhouse state

fluviodeltaic response to sea level perturbations amplitude and timing of shoreline translation and coastal onlap 1 alluvial river systems respond to changing sea level by adjusting channel length through shoreline translation and coastal onlap offlap at the alluvial basement transition the magnitude and timing of shoreline translation and coastal onlap offlap relative to the driving sea level signal depend on the dynamics of the fluvial system and have important implications for interpreting ancient fluviodeltaic deposits i obtain analytical solutions to a diffusive geometric model of fluviodeltaic response to sea level perturbations that treats the shoreline and alluvial basement transition as moving boundaries fluviodeltaic behavior is most sensitive to the ratio of the period of eustatic cycling to the fluvial response time which varies with the length and water discharge of the fluvial system the square root of this ratio provides a first order estimate of the fraction of the fluvial long profile affected by eustatic forcing the fluviodeltaic system behaves as a low pass filter with respect to eustatic cycling the amplitude of both shoreline translation and coastal onlap offlap increase with increasing cycle period within a relatively narrow bandwidth in which the fluvial response time is comparable to the cycle period only small time lags develop between shoreline response and eustatic forcing the time lag between maximum coastal onlap and maximum sea level increases without bound as the forcing period decreases relative to the fluvial response time model predictions agree with experimental data and differ considerably from the model predictions of pitman 1978 and angevine 1989 which suggest that fluviodeltaic systems are strong high pass filters to sea level cycling

orbital climate forcing of δ13c excursions in the late paleocene early eocene chrons c24n c25n 1 high resolution stable carbon isotope records for upper paleocene lower eocene sections at ocean drilling program sites 1051 and 690 and deep sea drilling project sites 550 and 577 show numerous rapid 40 60 kyr duration negative excursions of up to 1 we demonstrate that these transient decreases are the expected result of nonlinear insolation forcing of the carbon cycle in the context of a long carbon residence time the transients occur at maxima in earth s orbital eccentricity which result in high amplitude variations in insolation due to forcing by climatic precession the construction of accurate orbital chronologies for geologic sections older than 35 ma relies on identifying a high fidelity recorder of variations in earth s orbital eccentricity we use the carbon isotope records as such a recorder establishing a robust orbitally tuned chronology for latest paleocene earliest eocene events moreover the transient decreases provide a means of precise correlation among the four sites that is independent of magnetostratigraphic and biostratigraphic data at the 105 year scale while the eccentricity controlled transient decreases bear some resemblance to the much larger amplitude carbon isotope excursion cie that marks the paleocene eocene boundary the latter event is found to occur near a minimum in the 400 kyr eccentricity cycle thus the cie occurred during a time of minimal variability in insolation the dominant mechanism for forcing climate change on 104 year scales we argue that this is inconsistent with mechanisms that rely on a threshold climate event to trigger the paleocene eocene thermal maximum since any threshold would more likely be crossed during a period of high amplitude climate variations

the phosphorus cycle phosphogenesis and marine phosphate rich deposits abstract phosphorus in the form of phosphate is an essential nutrient and energy carrier on many different levels of life and a key element in mediating between living and lifeless parts of the biosphere one of the most important aspects of the phosphorus cycle is its vital role in governing productivity thereby interacting with the exogenic part of the carbon cycle which in turn is important in regulating earth s climate phosphorus is a prime element to be traced in earth s history because it allows for the reconstruction of long term feedback mechanisms between climate environment and ecology and of global change as such marine sedimentary phosphate deposits are particularly suited to study aspects of the phosphorus cycle because in the case of ubiquity their origin may result from a general acceleration of the global phosphorus cycle sources of sedimentary phosphate are microbial breakdown of buried organic matter and redox driven phosphate desorption from iron and manganese oxyhydroxides dissolved sea water phosphate represents an additional source which may become important in the formation of phosphatic hardgrounds the main locus of phosphogenesis is near the sediment water interface but phosphogenesis also occurs at greater sediment depths current induced winnowing and transport processes along the sea floor concentrate phosphate precipitates into deposits which exhibit internal stratification patterns typical for the prevailing hydraulic energy regime in a sequence stratigraphic context phosphate deposits preferentially occur along marine or maximum flooding surfaces consequent sedimentary reworking may result in the transfer of phosphates to highstand or lowstand deposits bio chemical weathering on continents represents the most significant source of bioavailable phosphorus this implies that long term changes in marine phosphorus levels and with these changes in marine ecology productivity rates and ratios of exported carbonate carbon and organic carbon are a response to changes in continental weathering rates a compilation of marine sedimentary phosphorus burial rates for the last 160 myr suggests that natural variations have occurred that span one order of magnitude for the late jurassic cretaceous and most of the paleogene the phosphorus cycle appears to have been accelerated in times of climate warming which was most likely due to the spreading of zones of humid climate and more intense continental weathering in the neogene the phosphorus cycle appears to have responded to changes in glacially induced weathering this suggests that uniform interpretations with respect to the emplacement of major phosphorite deposits should be treated with caution integrated analyses of the sedimentary and biogeochemical context of phosphorite occurrences may help to identify paleoenvironmental conditions as well as to improve our understanding of periods of enhanced phosphate accumulation periods which were usually characterized by steep gradients in the development of climate and environment with regard to the complexity of feedback mechanisms between the phosphorus cycle and the biosphere the present day input rates of phosphate into the world s oceans should be of great concern they are more than doubled by anthropogenic means and affect ecological systems on a rapidly increasing scale

understanding long term carbon cycle trends the late paleocene through the early eocene 1 the late paleocene to the early eocene 58 52 ma was marked by significant changes in global climate and carbon cycling the evidence for these changes includes stable isotope records that reveal prominent decreases in i 18 oa ndi 13 c suggesting a rise in earth s surface temperature 4 i c and a drop in net carbon output from the ocean and atmosphere concurrently deep sea carbonate records at several sites indicate a deepening of the calcite compensation depth ccd here we investigate possible causes e g increased volcanic degassing or decreased net organic burial for these observations but from a new perspective the basic model employed is a modified version of geocarb iii however we have coupled this well known geochemical model to loscar long term ocean atmosphere sediment carbon cycle reservoir model which enables simulation of seawater carbonate chemistry the ccd and ocean i 13 c we have also added a capacitor in this case represented by gas hydrates that can store and release 13 c depleted carbon to and from the shallow geosphere over millions of years we further consider accurate input data e g i 13 c of carbonate on a currently accepted timescale that spans an interval much longer than the perturbation several different scenarios are investigated with the goal of consistency amongst inferred changes in temperature the ccd and surface ocean and deep ocean i 13 c the results strongly suggest that a decrease in net organic carbon burial drove carbon cycle changes during the late paleocene and early eocene although an increase in volcanic activity might have contributed importantly a drop in net organic carbon burial may represent increased oxidation of previously deposited organic carbon such as stored in peat or gas hydrates the model successfully recreates trends in earth surface warming as inferred from i 18 o records the ccd and i 13 c at the moment however our coupled modeling effort cannot reproduce the magnitude of change in all these records collectively similar problems have arisen in simulations of short term hyperthermal events during the early paleogene paleocene eocene thermal maximum suggesting one or more basic issues with data interpretation or geochemical modeling remain

a new model for atmospheric oxygen over phanerozoic time a mathematical model has been constructed that enables calculation of the level of atmospheric o2 over the past 570 my from rates of burial and weathering of organic carbon c and pyrite sulfur s burial rates as a function of time are calculated from an assumed constant worldwide clastic sedimentation rate and the relative abundance and c and s contents of the three rock types marine sandstones and shales coal basin sediments and other non marine clastics red beds arkoses by our model values of o2 versus time using a constant total sedimentation rate agree with those for variable sedimentation derived from present day rock abundances and estimates of erosional losses since deposition this agreement is the result of our reliance on the idea that any increase in total worldwide sediment burial with consequently faster burial of c and s and greater o2 production must be accompanied by a corresponding increase in erosion and increased exposure of c and s on the continents to o2 consumption via weathering it is the redistribution of sediment between the three different rock types and not total sedimentation rate that is important in o2 control to add stability to the system negative feedback against excessive o2 fluctuation was provided in the modeling by the geologically reasonable assignment of higher weathering rates to younger rocks resulting in rapid recycling of c and s we did not use direct o2 negative feedback on either weathering of c and s or burial of c because weathering rates are assumed to be limited by uplift and erosion and the burial rate of c limited by the rate of sediment deposition the latter assumption is the result of modern sediment studies which show that marine organic matter burial occurs mainly in oxygenated shallow water and is limited by the rate of supply of nutrients to the oceans by rivers results of the modeling indicate that atmospheric o2 probably has varied appreciably over phanerozoic time during the late carboniferous and permian periods o2 was higher than previously because of the rise of vascular land plants and the widespread burial of organic matter in vast coal swamps a large decrease in o2 during the late permian was due probably to the drying up of the coal swamps and deposition of a large proportion of total sediment in c and s free continental red beds sensitivity study shows that major parameters affecting results are the mean c concentration in coal basins and the relative sizes of the reservoirs of young rapidly recycled versus old rocks less sensitivity was found for changes over time in total land area undergoing weathering and the use of direct o2 negative feedback on marine carbon burial good agreement for rates of c burial calculated via our model and via independent models which are based on the use of stable carbon isotopes indicates that the dominant factor that has brought about changes in atmospheric o2 level and the isotopic composition of dissolved inorganic carbon in seawater over phanerozoic time is sedimentation and not weathering or higher temperature phenomena such as basalt seawater reaction

seeing red in cyclic stratigraphy spectral noise estimation for astrochronology 1 fundamental to the development of astronomical time scales is the recognition of oscillatory variability within stratigraphic data and its evaluation relative to a null noise hypothesis in this study monte carlo simulations are used to investigate the suitability of two commonly used noise hypotheses the conventional and robust ar1 approaches and the results highlight important limitations in both for cyclostratigraphic application perhaps most problematic the robust ar1 method can result in inflated confidence level estimates and excessive clumping of false positives within the low frequency portion of the spectrum especially when the underlying noise process has a high lag 1 autocorrelation given typical cyclostratigraphic records this technique will often impose significant eccentricity band variability even in the case of pure ar1 noise an alternative spectral noise estimation method is proposed to overcome these problems which simultaneously allows for departures from the ar1 assumption and obtains high statistical power that is the ability to accurately identify astronomical signals when they are present in the data we apply the method to un tuned 18o data from miocene sediments of the ceara rise indicating statistically significant spectral power at frequencies that are consistent with the published orbital interpretation of weedon et al 1997 furthermore evaluation of the frequency arrangement of the significant spatial bedding periods using the average spectral misfit method for astrochronologic testing reveals that the null hypothesis of no orbital influence can be rejected with a high degree of confidence the 99 8 confidence level

intercalibration of radioisotopic and astrochronologic time scales for the cenomanian turonian boundary interval western interior basin usa we develop an intercalibrated astrochronologic and radioisotopic time scale for the cenomanian turonian boundary ctb interval near the global stratotype section and point in colorado usa where orbitally influenced rhythmic strata host bentonites that contain sanidine and zircon suitable for 40ar 39ar and u pb dating paired 40ar 39ar and u pb ages are determined from four bentonites that span the vascoceras diartianum to pseudaspidoceras flexuosum ammonite biozones utilizing both newly collected material and legacy sanidine samples of j obradovich comparison of the 40ar 39ar and u pb results underscores the strengths and limitations of each system and supports an astronomically calibrated fish canyon sanidine standard age of 28 201 ma the radioisotopic data and published astrochronology are employed to develop a new ctb time scale using two statistical approaches 1 a simple integration that yields a ctb age of 93 89 0 14 ma 2 total radioisotopic uncertainty and 2 a bayesian intercalibration that explicitly accounts for orbital time scale uncertainty and yields a ctb age of 93 90 0 15 ma 95 credible interval total radioisotopic and orbital time scale uncertainty both approaches firmly anchor the floating orbital time scale and the bayesian technique yields astronomically recalibrated radioisotopic ages for individual bentonites with analytical uncertainties at the permil level of resolution and total uncertainties below 2 using our new results the duration between the cenomanian turonian and the cretaceous paleogene boundaries is 27 94 0 16 ma with an uncertainty of less than one half of a long eccentricity cycle

a long marine history of carbon cycle modulation by orbital climatic changes pacing of the marine carbon cycle by orbital forcing during the pliocene and pleistocene ice ages past 2 5 million years myr is well known as older deep sea sediment records are being studied at greater temporal resolution it is becoming clear that similar fluctuations in the marine carbon system have occurred throughout the late mesozoic and tertiary despite the absence of large continental ice sheets over much of this time variations in both the organic and the calcium carbonate components of the marine carbon system seem to have varied cyclically in response to climate forcing and carbon and carbonate time series appear to accurately characterize the frequency spectrum of ancient climatic change for the past 35 myr much of the variance in carbonate content carries the polar signal of obliquity 41 000 years 41 kyr forcing over the past 125 myr there is evidence from marine sediments of the continued role of precessional 21 kyr climatic cycles repeat patterns of sedimentation at about 100 400 and 2 400 kyr the modulation periods of precession persistently enter into marine carbon cycle records as well these patterns suggest a nonlinear response of climate and or the sedimentation of organic carbon and carbonates to precessional orbital perturbations nonlinear responses of the carbon system may help to amplify relatively weak orbital insolation anomalies into more significant climatic perturbations through positive feedback effects nonlinearities in the carbon cycle may have transformed orbital climatic cycles into long wavelength features on time scales comparable to the residence times of carbon and nutrient elements in the ocean

climate induced sediment palaeosol cycles in a late cretaceous dry aeolian sand sheet marilia formation north west bauru basin brazil aeolian sand sheets which are characterized by low relief surfaces that lack dunes are common in arid and semi arid climatic settings the surface of an aeolian sand sheet can either be stable and subject to pedogenetic effects or unstable such that it is affected by deflation or sedimentation the maro lia formation late cretaceous may be interpreted as an ancient aeolian sand sheet area where alternating phases of stability and instability of the accumulation surface have been recorded detailed field studies were carried out in several sections of the maro lia formation where cyclic alternations of palaeosols and aeolian deposits were evident using palaeopedological and facies analysis methods supported in the laboratory by the analysis of rock samples cut and polished in slabs thin sections scanning electron microscope images and x ray diffraction data from the clay minerals the deposits comprise three lithofacies that in order of abundance are characterized by i translatent wind ripple strata ii flood deposits and iii ephemeral river channel deposits palaeosols constitute on average 65 of the vertical succession three types of palaeosols pedotypes are recognized i aridisols ii entisols and iii vertisols erosional surfaces due to aeolian deflation divide the top of the palaeosol profiles from the overlying aeolian deposits the palaeoenvironmental interpretation of the deposits and the palaeosols allows the depositional system of the maro lia formation to be defined as a flat area dominated by aeolian sedimentation with subordinate ephemeral river sedimentation and characterized by a dry climatic setting with occasional rainfall the climate is the main forcing factor controlling the alternation between episodes of active sedimentation and periods of palaeosol development a climate controlled model is proposed in which i the palaeosols are indicative of a stable surface that is developed during the more humid climatic phases and ii the erosional surfaces and the overlying aeolian sediments attest to periods of deflation and subsequent sedimentation thereby increasing the availability of sediment during the drier climatic phases the ephemeral fluvial deposits mark the more humid climatic conditions and contribute to the lagged sediment influx caused during the drier periods by the erosion of previously stored sediment

climatic importance of the modulation of the 100 kyr cycle inferred from 16 m y long miocene records the variations of the amplitude of the 100 kyr cycle are not yet clearly understood although the timing of the appearance of these cycles in the pleistocene is well established very little is known about the occurrence of such cycles and their evolution in most of the neogene two detailed and continuous 16 m y long miocene records of paleoceanographic significance are analyzed in order to study the dynamics of the 100 kyr cycle one record results from counts of the relative abundance of the calcareous nannoplankton coccolithus pelagicus in about 1000 samples taken in the neogene section recovered from ocean drilling program site 747 southern indian ocean this record in which the chronologic resolution is 17 kyr is interpreted as reflecting migrations of the antarctic polar front through time the record of the wet bulk density in the same section which is interpreted as reflecting variations of paleoproductivity constitutes the second 16 m y record it has a chronologic resolution of 3 5 kyr the two series reveal the presence of 100 kyr cycle during the miocene this cycle is not stable through time and vary similarly in the two series the amplitude of the 100 kyr cycle fluctuates quasi periodically with primary periods close to 2 38 1 14 and 0 8 m y equivalent to those of the modulation of the orbital parameters obliquity and eccentricity in addition the amplitude of the 100 kyr cycle is stronger during cooler times the interactions between climate and modulation of the eccentricity or the obliquity cycles are good candidates to explain that change in amplitude it is concluded that the long term modulation of the orbital parameter has a significant influence on global climate

filtering of milankovitch cycles by earth s geography abstract earth s land sea distribution modifies the temperature response to orbitally induced perturbations of the seasonal insolation we examine this modification in the frequency domain by generating 800 000 yr time series of maximum summer temperature in selected regions with a linear two dimensional seasonal energy balance climate model previous studies have demonstrated that this model has a sensitivity comparable to general circulation models for the seasonal temperature response to orbital forcing on land although the observed response in the geologic record is sometimes significantly different than modeled here differences attributable to model limitations and feedbacks involving the ocean atmosphere cryosphere system there are several results of significance 1 in mid latitude land areas the orbital signal is translated linearly into a large 10 c seasonal temperature response 2 although the modeled seasonal response to orbital forcing on antarctica is 6 c the annual mean temperature effect

interpreting carbon isotope excursions carbonates and organic matter abstract variations in the carbon isotopic compositions of marine carbonate and organic carbon provide a record of changes in the fraction of organic carbon buried through time and may provide clues to changes in rates of weathering and sources of organic carbon paired carbonate and organic carbon isotope determinations provide a possibility of interpreting not only changes in the global carbon cycle through time but changes in atmospheric pco2 as well interpretations of these types of data are typically rather qualitative a quantitative basis is required to develop a better understanding of changes in the carbon cycle for this purpose we employ a simple model of the global carbon cycle which is subjected to a number of different perturbations each lasting 500 ky i e much longer than the residence times of carbon and phosphorus in the ocean atmosphere system in addition to standard considerations of carbon mass and isotopic fluxes to the ocean atmosphere system from weathering and volcanism and fluxes of organic carbon and carbonate carbon to sediments the model incorporates sensitivity of the photosynthetic carbon isotope effect to changes in pco2 the inclusion of this parameter leads to unexpected carbon isotope responses to forcing that causes increased rates of organic carbon burial a series of simple to more complex simulations illustrates the significant effects of varying differences between the carbon isotopic composition of sedimented carbonate and organic carbon b with constant b a 50 increase in organic carbon burial produces a parallel increase in carbonate and organic carbon isotopic compositions however the same simulation with b responsive to pco2 changes produces an initial parallel 13 c increase but this is followed by an even greater 13 c enrichment in organic carbon because pco2 falls in response to increased organic carbon burial the counterintuitive overall result of the enhanced organic carbon burial event is that the carbonate carbon isotopic composition actually decreases because of the more substantial increase in 13 c org in addition we illustrate the effects on carbon isotopic compositions of the oceanic inorganic carbon reservoir and buried organic matter of a 50 increase in volcanic co2 outgassing a 50 increase in weathering rate with coupled phosphate and riverine carbon flux responses a 50 decrease in shale associated organic carbon weathering a 50 decrease in silicate weathering rate and the possible effects of the rise in abundance of c4 plants in the late miocene to recent we compare the model simulated carbon isotopic responses for some of these experiments to paired carbonate and organic carbon records to illustrate how these records might be interpreted in light of the model response

a mechanism for brief glacial episodes in the mesozoic greenhouse 1 the mesozoic perhaps the longest period of warmth during the phanerozoic earth history has been repeatedly affected by short lived cold interludes lasting about one million years while the origin of these cold snaps has been classically attributed to a temporary atmospheric co2 drawdown quantified mechanisms explaining these instabilities of the carbon cycle are still lacking based on a climate carbon cycle model we show that the general demise of carbonate platforms accompanying these short lived cold interludes is a powerful mechanism capable of generating a fast atmospheric co2 decrease and a moderate sea level drop associated with ice sheet buildup the temporary nature of the carbonate production decline explains the relative short time of these cold events but makes it possible to account for ice sheet waxing and waning

astrochronology of the late turonian implications for the behavior of the carbon cycle at the demise of peak greenhouse abstract a series of prominent carbon cycle perturbations indicated by carbon isotope excursions of up to 2 marked climatic and oceanographic changes that followed the peak mid cretaceous greenhouse the nature and forcing mechanisms of these changes remain poorly understood partly due to the lack of a detailed temporal control in this interval here we present an orbitally calibrated time scale which is based on hemipelagic rhythmites in the bohemian cretaceous basin and which can be linked to the established chronostratigraphic framework using inoceramid biostratigraphy and carbon isotope signature in the new age model the late turonian defined by the first occurrence of i perplexus below and the first occurrence of c deformis erectus above spans 1 56 0 07 myr when anchored to the newly refined age of the turonian coniacian boundary sageman et al in press the onset of the late turonian is 91 31 0 45 ma inoceramid zones i perplexus and m scupini span 0 76 0 05 myr and 0 80 0 05 myr respectively a time domain record of carbon isotope variations was obtained by pinning published 13ccarb data to the orbital time scale using 9 biostratigraphic and carbon isotope markers the timing of major carbon isotope excursions suggests a link to 405 kyr eccentricity changes and in the early late turonian to 100 kyr eccentricity variations however over 80 of the variance in the late turonian 13 c occurs at longer million year scales the key features of the 13ccarb signature including the amplified long term variance can be reproduced with simple models of orbitally driven isotopic mass balance at a constant carbon isotope fractionation the best fit to the 13ccarb signature is obtained with enhanced organic burial at high eccentricity in accordance with monsoonal forcing of organic accumulation in the low latitude atlantic and or buildup of low latitude terrestrial carbon reservoirs alternative solutions should consider changing carbon isotope fractionation due to pco2 and or nutrient flux changes

why are the δ13corg values in phanerozoic black shales more negative than in modern marine organic matter the 13corg values of phanerozoic black shales average 27 whereas those of modern marine organic matter average 20 the black shale isotopic values mimic those of continental organic matter yet their organic geochemical properties mandate that they contain predominantly marine organic matter hypotheses that proposed to explain the low 13c values of black shales include diagenetic losses of isotopically heavier organic matter components releases of isotopically light carbon from methane clathrates or extensive magmatic events greater photosynthetic discrimination against 13c during times of higher atmospheric pco2 and greenhouse climate stratification of the surface ocean that magnified photic zone recycling of isotopically light organic matter although the last possibility seems contrary to the vertical mixing that leads to the high productivity of modern oceanic upwelling systems it is consistent with the strongly stratified conditions that accompanied deposition of the organic carbon rich pliocene pleistocene sapropels of the mediterranean sea because most phanerozoic black shales contain evidence of photic zone anoxia similar to the sapropels well developed surface stratification of the oceans was likely involved in their formation existence of isotopically light land plant organic matter during several episodes of extensive magmatism that accompanied black shale deposition implies massive release of mantle co2 that added to the greenhouse conditions that favored oceanic stratification the 13c depletion common to most phanerozoic black shales apparently resulted from a greenhouse climate associated with elevated atmospheric pco2 that led to a strongly stratified ocean and photic zone recycling of organic matter in augmented by magmatic co2 releases

dolomite formation in the dynamic deep biosphere results from the peru margin early diagenetic dolomite beds were sampled during the ocean drilling programme odp leg 201 at four reoccupied odp leg 112 sites on the peru continental margin sites 1227 684 1228 680 1229 681 and 1230 685 and analysed for petrography mineralogy 13c 18o and 87sr 86sr values the results are compared with the chemistry and 13c and 87sr 86sr values of the associated porewater petrographic relationships indicate that dolomite forms as a primary precipitate in porous diatom ooze and siliciclastic sediment and is not replacing the small amounts of precursor carbonate dolomite precipitation often pre dates the formation of framboidal pyrite most dolomite layers show 87sr 86sr ratios similar to the composition of quaternary seawater and do not indicate a contribution from the hypersaline brine which is present at a greater burial depth also the 13c values of the dolomite are not in equilibrium with the 13c values of the dissolved inorganic carbon in the associated modern porewater both petrography and 87sr 86sr ratios suggest a shallow depth of dolomite formation in the uppermost sediment 30 m below the seafloor a significant depletion in the dissolved mg and ca in the porewater constrains the present site of dolomite precipitation which co occurs with a sharp increase in alkalinity and microbial cell concentration at the sulphate methane interface it has been hypothesized that microbial hot spots such as the sulphate methane interface may act as focused sites of dolomite precipitation varying 13c values from 15 to 15 for the dolomite are consistent with precipitation at a dynamic sulphate methane interface where 13c of the dissolved inorganic carbon would likewise be variable a dynamic deep biosphere with upward and downward migration of the sulphate methane interface can be simulated using a simple numerical diffusion model for sulphate concentration in a sedimentary sequence with variable input of organic matter thus the study of dolomite layers in ancient organic carbon rich sedimentary sequences can provide a useful window into the palaeo dynamics of the deep biosphere

on the structure and origin of major glaciation cycles 2 the 100 000 year cycle climate over the past million years has been dominated by glaciation cycles with periods near 23 000 41 000 and 100 000 years in a linear version of the milankovitch theory the two shorter cycles can be explained as responses to insolation cycles driven by precession and obliquity but the 100 000 year radiation cycle arising from eccentricity variation is much too small in amplitude and too late in phase to produce the corresponding climate cycle by direct forcing we present phase observations showing that the geographic progression of local responses over the 100 000 year cycle is similar to the progression in the other two cycles implying that a similar set of internal climatic mechanisms operates in all three but the phase sequence in the 100 000 year cycle requires a source of climatic inertia having a time constant similar to 15 000 years much larger than the other cycles similar to 5 000 years our conceptual model identifies massive northern hemisphere ice sheets as this larger inertial source when these ice sheets forced by precession and obliquity exceed a critical size they cease responding as linear milankovitch slaves and drive atmospheric and oceanic responses that mimic the externally forced responses in our model the coupled system acts as a nonlinear amplifier that is particularly sensitive to eccentricity driven modulations in the 23 000 year sea level cycle during an interval when sea level is forced upward from a major low stand by a milankovitch response acting either alone or in combination with an internally driven higher frequency process ice sheets grounded on continental shelves become unstable mass wasting accelerates and the resulting deglaciation sets the phase of one wave in the train of 100 000 year oscillations whether a glacier or ice sheet influences the climate depends very much on the scale the interesting aspect is that an effect on the local climate can still make an ice mass grow larger and larger thereby gradually increasing its radius of influence

black shale deposition atmospheric co2 drawdown and cooling during the cenomanian turonian oceanic anoxic event 1 oceanic anoxic event 2 oae2 spanning the cenomanian turonian boundary ctb represents one of the largest perturbations in the global carbon cycle in the last 100 myr the 13ccarb 13corg and 18o chemostratigraphy of a black shale bearing ctb succession in the vocontian basin of france is described and correlated at high resolution to the european ctb reference section at eastbourne england and to successions in germany the equatorial and midlatitude proto north atlantic and the u s western interior seaway wis 13c offset between 13ccarb and 13corg is shown to be a good pco2 proxy that is consistent with pco2 records obtained using biomarker 13c data from atlantic black shales and leaf stomata data from wis sections boreal chalk 18o records show sea surface temperature sst changes that closely follow the 13c pco2 proxy and confirm tex86 results from deep ocean sites rising pco2 and sst during the late cenomanian is attributed to volcanic degassing pco2 and sst maxima occurred at the onset of black shale deposition followed by falling pco2 and cooling due to carbon sequestration by marine organic productivity and preservation and increased silicate weathering a marked pco2 minimum 25 fall occurred with a sst minimum plenus cold event showing 4 c of cooling in 40 kyr renewed increases in pco2 sst and 13c during latest cenomanian black shale deposition suggest that a continuing volcanogenic co2 flux overrode further drawdown effects maximum pco2 and sst followed the end of oae2 associated with a falling nutrient supply during the early turonian eustatic highstand

astrochronology of the early turonian early campanian terrestrial succession in the songliao basin northeastern china and its implication for long period behavior of the solar system abstract the first complete early turonian early campanian lacustrine succession has been recovered from the sk i south sk is borehole in the songliao basin slb northeastern china we conducted a detailed cyclostratigraphic study of natural gamma ray gr log thorium th log and magnetic susceptibility ms data from this core spectral analysis of the upper quantou formation k 2 q 3 4 qingshankou formation k 2 qn yaojia formation k 2 y and lower nenjiang formation k 2 n 1 2 reveals a hierarchy of meter to decameter scale cycling in the data the wavelength ratios of the cycles in these stratigraphic units are 20 5 2 1 corresponding with those of milankovitch cycle periods of 405 kyr long eccentricity 100 kyr short eccentricity 37 kyr obliquity 20 kyr precession indicating astronomical control on sedimentation an astronomical time scale ats was established by tuning interpreted 405 kyr cycles to a 405 kyr orbital eccentricity target curve and to four sims u pb zircon radioisotope ages this absolute ats provides precise numerical ages for stratigraphic boundaries biozones geological and geophysical events and serves as a basis for correlation of strata and events between marine and terrestrial systems the ages of the c33r c34n geomagnetic polarity boundary in k 2 n 2 and three short reversal events in k 2 y are estimated as 83 633 ma 84 819 84 862 ma 84 982 85 092 ma and 85 240 85 629 ma respectively long period amplitude modulations in the obliquity and eccentricity bands of the 405 kyr tuned gr th series provide strong evidence that long period orbital forcing influenced climate change and depositional processes in the slb the extracted amplitude modulations provide evidence that the orbits of earth and mars were not in secular resonance and were undergoing chaotic interactions during this time although the modulations do not match those of recent astronomical models

integrated quantitative stratigraphy of the cenomanian turonian bridge creek limestone member using evolutive harmonic analysis and stratigraphic modeling abstract secular changes in bulk sedimentation have a significant impact on the preservation of climatic signals in rhythmically bedded strata in this study a quantitative cyclostratigraphic methodology is developed to use these signal distortions as a means to reconstruct sedimentation the method exploits a moving window fourier technique that we designate evolutive harmonic analysis eha we calibrate this methodology to a specific set of geologic conditions i e changes in bulk sedimentation using a series of stratigraphic models and then apply the technique to the cenomanian turonian greenhorn formation of the western interior basin application of eha to strata that preserve a record of orbital forcing allows the reconstruction of a high resolution sedimentation history in which bulk sedimentation rates and hiatuses are quantified using the data on bulk sedimentation rate rates of accumulation for geochemical proxies representing detrital biogenic and authigenic contributions to the sediment can be calculated by integrating these quantitative assessments of siliciclastic dilution primary production and depositional redox conditions within a high resolution chronostratigraphic framework we are able to deconvolve secular trends in hemipelagic sedimentation during the late cenomanian early turonian in the western interior basin this integrated quantitative stratigraphic approach allows a reevaluation of hypotheses for the accumulation of excess organic matter in the western interior basin during the interval representing oceanic anoxic event ii

a 100 myr history of the carbon cycle based on the 400 kyr cycle in marine δ13c benthic records documenting the past coevolution of earth temperatures and of the carbon cycle is of paramount importance for our understanding of climate dynamics atmospheric co2 is well constrained over the last million years through direct measurements in air bubbles from antarctic ice cores for older times many different and sometimes conflicting proxies have been suggested here we provide a new methodology to constrain the carbon cycle in the past based on marine benthic 13c records marine 13c data are recording a persistent 400 kyr cycle with an amplitude primarily linked to the total amount of carbon in the ocean or dissolved inorganic carbon dic by extracting this amplitude from published records we obtain a new strong constraint on the 100 myr history of earth s carbon cycle the obtained cenozoic evolution of dic is in surprisingly in a good agreement with existing reconstructions of pco2 suggesting that pco2 is mostly driven by dic changes over this period in contrast we find no strong decreasing trend in dic between the cretaceous and the cenozoic suggesting that cretaceous atmospheric pco2 levels were limited and high temperatures at this time should be explained by other mechanisms alternatively high cretaceous atmospheric pco2 could occur as a consequence of changes in oceanic chemistry but not carbon content

marine carbon burial flux and the carbon isotope record of late cretaceous coniacian santonian oceanic anoxic event iii abstract episodes of widespread distribution of organic rich marine facies within relatively narrow stratigraphic intervals have been interpreted as oceanic anoxic events oaes there are a number of such intervals in the upper cretaceous some of which also exhibit significant positive excursions in carbon isotope records as a result a general model of the relationship between enhanced organic carbon burial and positive c isotope shifts has emerged carbon isotope stratigraphy has therefore developed the dual utility of a chronostratigraphic tool and a means to help identify and define intervals of exceptional organic matter burial and preservation however variations in regional carbon isotope records of globally documented events suggest that the relationship between organic carbon burial flux and magnitude of carbon isotope excursion may not be entirely straightforward for example strata of coniacian santonian age have long been recognized for enhanced organic content in many areas but the designation of oceanic anoxic event iii for this interval has been rather equivocal in the literature mostly due to the weak positive 13 c excursion 0 5 yet in some areas organic carbon accumulation rates for coniacian santonian strata are roughly double that of the older oae ii which is marked by a 2 4 shift in 13 c interestingly the burial flux of carbonate which leads to depletion rather than enrichment of the c isotope signal is also significantly elevated during coniacian santonian time in this study the role of variations in organic carbon and carbonate accumulation rates on carbon isotopic expression are explored through application of data on the composition accumulation rate and areal distribution of end member facies types to the development of a global carbon isotopic mass balance model the results are used to explore the hypothesis that net organic carbon burial during oae iii was not accurately represented in the carbon isotopic record these results have important implications for interpretation of c isotope records related to past perturbations of the global carbon cycle

thermal evolution of cretaceous tethyan marine waters inferred from oxygen isotope composition of fish tooth enamels 1 the evolution of subtropical 30 35 n upper ocean temperatures through the cretaceous is inferred from the oxygen isotope compositions of 64 fish teeth enamel coming from the western tethyan platform mean 18o values of 22 at the berriasian valanginian boundary decrease with oscillations to 18 5 around the cenomanian turonian boundary and progressively increase to 21 5 by the end of the cretaceous the similarity of this oxygen isotope curve for bioapatites from platform environments with those for foraminifera and bulk carbonates that were deposited in deeper waters and at other paleolatitudes indicates that they record global climatic signals major cooling events at the million year scale can be distinguished 1 at the berriasian valanginian boundary and 2 during the earliest late valanginian a third cooling event is detected during the earliest aptian these events already proposed as icehouse interludes during the lower cretaceous are also recorded at subtropical latitudes a progressive warming is identified from the aptian to the cenomanian turonian interval that corresponds to a thermal optimum and then upper ocean temperatures decreased to the maastrichtian minimum isotopic temperatures range from 15 c to 28 c assuming a 18oseawater of 1 for an ice free world taking more realistic 18oseawater values of 0 for tropical waters during glacial periods within the berriasian valanginian interval and earliest aptian or with above average salinities possibly the maastrichtian temperatures are increased by 4 5 c temperature differences between climatic extremes of the valanginian and cenomanian turonian are estimated to have been 10 c latitudinal thermal gradients for the albian cenomanian turonian and maastrichtian were 0 2 0 3 c latitude and thus weaker than modern oceanic values at about 0 4 c latitude

plate tectonic trigger of changes in pco2 and climate in the oxfordian late jurassic carbon isotope and modeling evidence abstract the transition from the middle to the late jurassic was characterized by significant changes in oceanography and climate and by changes in global carbon cycle as shown in the c isotope record a prominent mid oxfordian positive excursion in bulk carbonate carbon isotope values 13 c carb with an amplitude of more than 1 has been documented from many sections in the northern tethys realm in this study we present new bulk organic matter c isotope data 13 c org from northwestern tethys that do not record the mid oxfordian positive excursion in carbonate carbon on the contrary 13 c org decreases during the interval of the most rapid increase in 13 c carb we demonstrate that this decrease is not due to a changing marine terrestrial organic carbon partitioning but that the contrasting isotope trends record peculiar environmental and climate changes which occurred near the beginning of the late jurassic using a simple carbon cycle model we show that an increase in atmospheric p co 2 starting at modern levels could be the cause of contrasting trends in 13 c carb and 13 c org we suggest that a reorganisation of ocean currents related to the opening and or widening of the tethys atlantic pacific seaway and a massive spread of shallow sea carbonate production led to higher p co 2 model simulations indicate that this increase in p co 2 may have triggered changes in the biological carbon pump and in organic carbon burial that can explain the middle oxfordian c isotope record

direct coupling between carbon release and weathering during the toarcian oceanic anoxic event silicate weathering represents a major feedback mechanism in the earth s climate system helping to stabilize atmospheric co2 levels and temperature on million year time scales on shorter time scales of greater relevance to understanding the fate of anthropogenic co2 the efficacy and responsiveness of weathering is less clear here we present high resolution osmium isotope data that reflect global chemical weathering from a stratigraphically thick record of the early toarcian oceanic anoxic event t oae ca 182 ma a pronounced decrease in the carbon isotope composition of exogenic carbon reservoirs during this event has been linked to the large scale release of 12c enriched carbon our data indicate that the flux of radiogenic osmium to the oceans increased in lockstep with the decrease in carbon isotope values demonstrating a geologically synchronous coupling between massive carbon release and enhanced global continental crust weathering we show that abrupt shifts in carbon isotopes previously interpreted as millennial scale methane hydrate melting or terrestrial carbon release events are coeval with rapid increases in weathering global weathering may have increased by 40 across each of these intervals of rapid carbon injection our results help to reconcile previous estimates of weathering change during the t oae and support the view that overall global weathering rates may have increased six fold through the entire event

simulation of long eccentricity 400 kyr cycle in ocean carbon reservoir during miocene climate optimum weathering and nutrient response to orbital change 1 deep sea foraminiferal 13c records contain abundant 400 kyr cycles indicating a link between eccentricity forcing and ocean carbon reservoir change here we simulate the oceanic 13c maxima events forced by the earth s orbital geometry during the miocene climate optimum mco 17 14 ma using a box model the simulated results of both surface and deep water 13c display co varying 400 kyr cycle modulated by orbital parameters weathering induced carbon input will change the burial ratio of carbonates to organic carbon and further result in periodic changes in the oceanic 13c the increase of riverine nutrient input which is synchronous with riverine carbon input often stimulates primary productivity and burial of organic carbon our results support that eccentricity maxima minima enhance reduce weathering intensity and nutrient supply which lead to minima maxima of 13c the prominent 400 kyr cycle of ocean carbon reservoir is interpreted as likely caused by a long memory of carbon in the ocean

trace element abundances in the rock canyon anticline pueblo colorado marine sedimentary section and their relationship to caribbean plateau construction and oxygen anoxic event 2 1 rapid eruption of submarine lava flows during formation of the caribbean plateau correlates closely with ocean anoxic event 2 oae2 which bracketed the cenomanian turonian boundary 93 5 ma these events also correspond with a positive excursion in carbon isotopic composition of seawater hydrothermal activity associated with large scale submarine volcanism may have been responsible for this abrupt change in ocean chemistry we determined the distribution of major minor and trace element abundances in the rock canyon marine sedimentary section pueblo colorado after normalizing element concentrations to zr to remove the variable contribution of terrigenous material to these sediments we detected an interval of concentrated metal abundance anomalies that coincides with the abrupt beginning of the positive 13c isotope excursion the metal abundance anomalies indicate that intermittent hydrothermal activity in the form of both water rock exchange and magmatic degassing introduced large concentrations of trace metals into the cretaceous ocean at the same time that extinctions of benthic species turnover in plankton communities and increases in isotopically light organic carbon burial occurred the stratigraphic position of this interval of trace metal anomalies matches events associated with oae2 and indicates that intermittent hydrothermal activity on a massive scale triggered abrupt changes in carbon burial and deep ocean oxygen contents

the 41 kyr world milankovitch s other unsolved mystery 1 for most of the northern hemisphere ice ages from 3 0 to 0 8 m y global ice volume varied predominantly at the 41 000 year period of earth s orbital obliquity however summer or summer caloric half year insolation at high latitudes which is widely believed to be the major influence on high latitude climate and ice volume is dominated by the 23 000 year precessional period thus the geologic record poses a challenge to our understanding of climate dynamics here we propose that variations in the insolation gradient between high and low latitudes control high latitude climate and ice volume during the late pliocene and early pleistocene the differential heating between high and low latitudes driven by obliquity controls the atmospheric meridional flux of heat moisture and latent energy which may exert the dominant control on high latitude climate on milankovitch timescales in the two dimensional zonal energy balance models typically used to study the long term evolution of climate the meridional atmospheric moisture flux is usually kept fixed the hypothesis that insolation gradients control the poleward energy fluxes precipitation and ice volume at high latitudes has never been directly examined within the context of an ice sheet model in light of what we know about modern energy fluxes and their relative influence on high latitude climate this possibility should be examined

a 9 myr cycle in cenozoic δ13c record and long term orbital eccentricity modulation is there a link abstract the 65 myr long cenozoic carbon isotope record 13 c of zachos et al 2001 2008 documents a strong long term cycle with a mean pseudoperiodicity close to 9 myr this cyclicity modulates the 2 4 myr eccentricity cycle amplitude hinting at a possible link between long term astronomical and geological variations some phase shifts between 9 myr 13 c and astronomical cycles suggest that additional processes e g tectonics contribute to these long term carbon cycle variations the strong response of 13 c to long term eccentricity periods 9 myr 2 4 myr 400 kyr supports the hypothesis that the long time residence of carbon in the oceans amplifies lower frequency or dampens higher frequency orbital variations additionally the strong expression of low amplitude 9 myr eccentricity cycle in the 13 c record could be explained by energy transfer process from higher to lower frequency cycles and all eccentricity components modulate the carrier climatic precession cycles finally the paleocene eocene thermal maximum petm 55 9 ma event which corresponds to a pronounced 13 c negative excursion is situated within a strong decrease in the most prominent 9 myr 13 c cycle hinting at a link between accelerated rates in 13 c variations and the petm this specific 9 myr 13 c cycle seems to be amplified by non orbital mechanisms in atmosphere continent ocean system such as previously suggested methane release from gas hydrate and volcanism

shallow water methane derived authigenic carbonate mounds at the codling fault zone western irish sea abstract methane derived authigenic carbonate mdac mound features at the codling fault zone cfz located in shallow waters 50 120 m of the western irish sea were investigated and provide a comparison to deep sea mdac settings carbonates consisted of aragonite as the major mineral phase with 13 c depletion to 50 and 18 o enrichment to 2 these isotope signatures together with the co precipitation of framboidal pyrite confirm that anaerobic oxidation of methane aom is an important process mediating methane release to the water column and the atmosphere in this region 18 o enrichment could be a result of mdac precipitation with seawater in colder than present day conditions or precipitation with 18 o enriched water transported from deep petroleum sources the 13 c depletion of bulk carbonate and sampled gas 70 suggests a biogenic source but significant mixing of thermogenic gas and depletion of the original isotope signature cannot be ruled out active seepage was recorded from one mound and together with extensive areas of reduced sediment confirms that seepage is ongoing the mounds appear to be composed of stacked pavements that are largely covered by sand and extensively eroded the cfz mounds are colonized by abundant sabellaria polychaetes and possible nemertesia hydroids which benefit indirectly from available hard substrate in contrast to deep sea mdac settings where seep related macrofauna are commonly reported seep specialist fauna appear to be lacking at the cfz in addition unlike mdac in deep waters where organic carbon input from photosynthesis is limited lipid biomarkers and isotope signatures related to marine planktonic production e g sterols alkanols were most abundant evidence for microbes involved in aom was limited from samples taken possibly due to this dilution effect from organic matter derived from the photic zone and will require further investigation

miocene evolution of atmospheric carbon dioxide changes in pco2 or ocean circulation are generally invoked to explain warm early miocene climates and a rapid east antarctic ice sheet eais expansion in the middle miocene this study reconstructs late oligocene to late miocene pco2 from ep values based on carbon isotopic analyses of diunsaturated alkenones and planktonic foraminifera from deep sea drilling project sites 588 and 608 and ocean drilling program site 730 our results indicate that highest pco2 occurred during the latest oligocene 350 ppmv but decreased rapidly at 25 ma the early and middle miocene was characterized by low pco2 260 190 ppmv lower intervals of pco2 correspond to inferred organic carbon burial events and glacial episodes with the lowest concentrations occurring during the middle miocene there is no evidence for either high pco2 during the late early miocene climatic optimum or a sharp pco2 decrease associated with eais growth paradoxically pco2 increased following eais growth and obtained preindustrial levels by 10 ma although we emphasize an oceanographic control on miocene climate low pco2 could have primed the climate system to respond sensitively to changes in heat and vapor transport

secular variation in late cretaceous carbon isotopes a new δ13c carbonate reference curve for the cenomanian campanian 99 6 70 6 ma carbon stable isotope variation through the cenomanian santonian stages is characterized using data for 1769 bulk pelagic carbonate samples collected from seven chalk successions in england the sections show consistent stratigraphic trends and 13c values that provide a basis for highresolution correlation positive and negative 13cexcursions and inflection points on the isotope profiles are used to define 72 isotope events key markers are provided by positive 13c excursions of up to 2 the albian cenomanianboundary event mid cenomanian event i thecenomanian turonian boundary event the bridgewick hitch wood and navigation events of late turonian age and the santonian campanian boundary event isotope events are isochronous within a framework provided by macrofossil datum levels and bentonite horizons an age calibrated composite 13c reference curve and an isotope event stratigraphy are constructed using data from the english chalk the isotope stratigraphy is applied to successions in germany france spain and italy correlation with pelagic sections at gubbio central italy demonstrates general agreement between biostratigraphic and chemostratigraphic criteria in the cenomanian turonian stages confirming established relationships between tethyan planktonic foraminiferal and boreal macrofossil biozonations correlation of the coniacian santonian stages is less clear cut magnetostratigraphic evidence for placing the base of chron 33r near the base of the upper santonian is in good agreement with the carbon isotope correlation but generates significant anomalies regarding the placement of the santonian and campanian stage boundaries with respect to tethyan planktonic foraminiferal and nannofossil zones isotope stratigraphy offers a more reliable criterion for detailed correlation of cenomanian santonian strata than biostratigraphy with the addition of campanian 13c data from one of the english sections a composite cenomanian campanian age calibrated reference curve is presented that can be utilized in future chemostratigraphic studies the cenomanian campanian carbon isotope curve is remarkably similar in shape to supposedly eustatic sea level curves increasing 13c values accompanying sea level rise associated with transgression and falling 13c values characterizing sea level fall and regression the correlation between carbon isotopes and sea level is explained by variations in epicontinental sea area affecting organic matter burial fluxes increasing shallow sea floor area and increased accommodation space accompanying sea level rise allowedmore efficient burial ofmarine organic matter with the preferential removal of 12c from the marine carbon reservoir during sea level fall reduced seafloor area marine erosion of previously deposited sediments and exposure of basin margins led to reduced organiccarbon burial fluxes and oxidation of previously deposited organic matter causing falling 13c values additionally drowning of carbonate platforms during periods of rapid sea level rise may have reduced the global inorganic relative to the organic carbon flux further enhancing 13c values while renewed platform growth during late transgressions and highstands prompted increased carbonate deposition variations in nutrient supply changing rates of oceanic turnover and the sequestration or liberation of methane from gas hydrates may also have played a role in controlling carbon isotope ratios