early hettangian benthic planktonic coupling at doniford sw england palaeoenvironmental implications for the aftermath of the end triassic crisis abstract this paper presents a high resolution micropalaeontological study integrated with geochemical and sedimentological analyses of the triassic jurassic tr j transition at the doniford section sw england our analyses indicate the renewal of surface carbonate production in the blue lias formation early hettangian after the end triassic mass extinction based on the high abundance of surface carbonate producers schizosphaerellids which occurred in phase with development at sea floor of calcareous hyaline benthic foraminifers we deduce that a benthic pelagic coupling resulted in both the initial restoration of the biological carbonate pump and also a more efficient export production the presence of monospecific phytoplankton assemblages and benthic foraminiferal assemblages typical of poorly oxygenated environments suggest that the environmental stress continued after the end triassic maximal perturbation complete environmental recovery was prevented by a succession of alternating dysaerobic and anoxic phases that favoured the deposition of black shale sediments the hypothesis of a methane release mechanism as a trigger for the global carbon cycle perturbation and greenhouse conditions during the early jurassic is discounted based on evidence from the decoupled carbon isotope records of carbonate and organic matter apart from local control of a high amplitude sea level change across the tr j boundary the succession and nature of events at doniford are consistent with a scenario of global environmental and biotic changes triggered by the physical and chemical effects of the central atlantic magmatic province camp volcanism a super greenhouse climate in the aftermath of the end triassic mass extinction appears to be the results of the combination of the long term co2 accumulation in the atmosphere system due to the camp volcanic activity as well as the inefficiency of the biological pump due to reduced export production

palustrine lacustrine and alluvial facies of the norian owl rock formation chinle group four corners region southwestern u s a implications for late triassic paleoclimate abstract the upper triassic norian owl rock formation was deposited in a low gradient floodbasin at a subtropical paleolatitude the lower part of the formation consists predominantly of fine grained siliciclastic lithofacies deposited by sheetflood and sinuous streams on a muddy floodplain during a period of continuous basin aggradation nodular calcretes are increasingly mature higher in the formation suggesting increasingly episodic depositional conditions the upper part of the formation consists mostly of interbedded fine grained siliciclastic facies and laterally continuous ledges of limestone and sandstone the predominant limestone facies has brecciated to peloidal fabrics spar filled circumgranular cracks and root channeling the subordinate limestone facies displays wavy to irregular argillaceous lamination desiccation cracks and oscillation ripples and is vertically and laterally gradational with the brecciated facies the upper owl rock formation records deposition of aggrading sequences of alluvial sediments deposited during base level rise capped by highstand carbonates deposited in small perennial and ephemeral carbonate lakes and ponds base level lowstand in an overall semiarid climate resulted in extensive pedogenesis of the limestone and laterally equivalent alluvial facies basin wide variations in base level are interpreted as resulting from climatic fluctuations this depositional model is consistent with an interpreted trend towards aridification on the colorado plateau during the late triassic as pangea drifted northward from one climate zone to another

carbon isotopes in continental weathering environments and variations in ancient atmospheric co2 pressure abstract abundance and carbon isotope data from an fe co3 oh component in apparent solid solution in oolitic goethites have been used to infer ancient atmospheric co2 pressures a test of the validity of these estimates might be comparisons of the carbon isotope compositions of fe co3 oh in oolitic goethites with time equivalent pedogenic calcites temporal trends of the oolitic goethite and pedogenic calcite 13c values are generally similar but time equivalent samples from each of these two groups are not common in the existing data to facilitate discussion of the concept comparisons were made of available goethite and calcite samples even though ages of the compared samples in each pair were not identical in four out of the five comparisons fe co3 oh abundance and 13c data were combined with pedogenic calcite 13c data to calculate physically reasonable soil co2 concentrations for the ancient calcitic soids this suggests that the compared oolitic goethite and pedogenic calcite systems were responding to the same global scale phenomenon i e atmospheric co2 atmospheric pco2 as determined from the goethites in these four well behaved cases ranged from values indistinguishable from modern within analytical uncertainty to values up to approximately 16 time modern modern atmospheric pco2 was taken to be 10 3 5 atm one interpretation of the fifth anomalous comparison is that atmospheric co2 levels increased from about 3 times modern to about 18 times modern from the triassic into the early jurassic this inferred value for the pco2 of the early jurassic atmosphere is not uniquely constrained by the existing data and needs to be substantiated however even considerably lower early jurassic atmospheric pco2 values of 6 to 9 times modern i e 1 3 to 1 2 of the estimated value of 18 times modern would still indicate significant differences between the global carbon cycles then and now these results highlight the need for more research on the behavior of the atmosphere during and after the triassic jurassic transition

scratching the surface estimating dimensions of large igneous provinces a study of five major basaltic provinces including oceanic plateaus volcanic passive margins and continental flood basalts shows that they are voluminous constructions of extrusive igneous rock underlain by intrusive rock crustal thickness ranges from 20 to 40 km and lower crust is characterized by high 7 0 7 6 km s seismic velocities volumes and emplacement rates derived for two oceanic plateaus the ontong java and kerguelen broken ridge reveal short lived pulses of increased global crustal production and suggest an origin involving the lower mantle the ontong java rate of emplacement may have exceeded the contemporaneous global production rate of the entire mid ocean ridge system despite the importance off large igneous provinces in studies of mantle dynamics and the global environment scarce age and deep crustal data necessitate intensified efforts in seismic imaging and scientific drilling in a range of such features

time calibration of triassic jurassic microfloral turnover eastern north america abstract palynological data from the newark basin of the newark supergroup reveal a spike in the spore pollen ratio at the triassic jurassic boundary this spore spike is coincident with a 60 regional extinction of the palynoflora and approximately synchronous with terrestrial vertebrate extinctions orbitally controlled sedimentary cycles allow stratigraphic sections to be calibrated in time constraining the duration of the microfloral turnover to an interval of 21 ky the geologically brief palynofloral break is similar to cretaceous tertiary boundary fern spikes these data support a triassic jurassic boundary impact extinction scenario

stratigraphic record of the early mesozoic breakup of pangea in the laurasia gondwana rift system rift basins of the central atlantic margins cam of north america and morocco preserve largely continental sequences of sedimentary strata and less important minor basalt flows spanning much of the early mesozoic the best known is the newark basin of new jersey new york and pennsylvania where an astronomically calibrated magnetic polarity time scale is developed lacustrine cycles of milankovitch origin are commonly present in cam basins with the period changing from 10 ky paleoequator with coals to 20 ky 4 10n to perhaps 40 ky northward with evaporites cycles of100 ky 413 ky and2 my are also important four mostly unconformity bounded tectonostratigraphic sequences are present the anisian ts i is fluvial and eolian ts ii ts iv late triassic to early jurassic consist of tripartite lacustrine sequences caused by extension pulses the newark basin accumulation rate history allows comparison with quantitative rift basin models the north american plate s slow northward drift resulted in a relative shift of climate although the rapid humidification during the latest triassic and early jurassic is associated with a sea level rise the triassic jurassic mass extinction is of independent origin plausibly impact related

biogeochemical constraints on the triassic jurassic boundary carbon cycle event 1 the end triassic mass extinctions represent one of the five most severe biotic crises in earth history yet remain one of the most enigmatic ongoing debate concerns the environmental effects of the central atlantic magmatic province camp eruptions and their linkage with the mass extinction event across the triassic jurassic boundary there is conflicting paleo evidence for changes in atmospheric pco2 during the extrusion of the camp basalts studies on sediments from european and pacific localities have however identified a substantial negative isotopic anomaly up to 3 5 across the tr j boundary providing an important indicator of changes in the operation of the ancient global carbon cycle we sought to explain the paleo evidence by utilizing a carbon cycle model for the hothouse world of the end triassic that emphasizes the chemical weathering of silicate and carbonate rocks and the ocean carbonate chemistry we find that volcanic co2 outgassing fails to fully account for either a sufficient rise in atmospheric pco2 indicated by the stomata of fossil leaves or the sedimentary isotopic fingerprint instead the scenario that best fits all of the geologic evidence is a positive feedback loop in which warming due to a buildup of volcanically derived co2 triggers destabilization of seafloor methane hydrates and the catastrophic release of ch4 palfy et al 2001 we calculate that this carbon cycle perturbation was huge involving the release of 8000 9000 gt c as co2 during the camp basaltic eruptions and 5000 gt c as ch4 in the model the initial isotopic excursion is assumed to take place over 70 kyr while complete reequilibration of the ocean atmosphere system with respect to co2 is accomplished over 700 1000 kyr our results thus provide a preliminary theoretical explanation for the bioevents estimated pco2 changes and isotopic excursions observed in marine and continental sediments at this time

triassic climates state of the art and perspectives abstract the climate of the triassic period was characterized by a non zonal pattern dictated by a strong global monsoon system with effects that are most evident in the tethys realm this strong monsoonal regime is related to the aggregation of the pangaean supercontinent which by triassic time was already completed climate oscillations existed within this framework the harsh hot house climatic conditions that characterized the late permian and perhaps precipitated the end permian mass extinction were probably maintained during the early triassic and may account for the impoverished but distinctive faunal and floral lower triassic associations although metazoan reef builders were probably the most affected group carbonate production remained high at least in the western tethys realm the middle triassic was characterized locally by humid episodes although their geographical distribution has yet to be clarified the carnian pluvial event marks an episode of increased rainfall documented worldwide was the most distinctive climate change within the triassic different hypotheses have been proposed for its causes changes of atmospheric or ocean circulation driven by plate tectonics a peak of the global monsoon due to maximum continent aggregation or triggering by the eruption of a large igneous province subsequently the late carnian and norian seem to have been climatically stable although minor climatic changes have recently been described even from this time period finally the end triassic extinction event is also associated with climate change specifically warming and increased rainfall but this evidence comes mostly from the northern parts of the central atlantic magmatic province and the global pattern of climate change at the triassic jurassic boundary has still to be resolved many facets of triassic climate are intriguing and deserve further research however palaeoclimate studies on the triassic have so far been carried out only locally with different proxies those proxies will require inter calibration in order to depict correctly the temporal and geographical patterns of triassic climate

changing co2 conditions during the end triassic inferred from stomatal frequency analysis on lepidopteris ottonis goeppert schimper and ginkgoites taeniatus braun harris abstract end triassic fluctuations in atmospheric carbon dioxide co2 concentration were reconstructed by the use of stomatal frequency analysis on a single plant species the seedfern lepidopteris ottonis goeppert schimper stomatal index showed no distinct intra and interpinnule variation which makes it a suitable proxy for past relative co2 changes records of decreasing stomatal index and density from the bottom to the top of the rhaetian hettangian wustenwelsberg section bavaria germany indicate rising co2 levels during the triassic jurassic transition additionally stomatal frequency data of fossil ginkgoalean leaves ginkgoites taeniatus braun harris suggest a maximum palaeoatmospheric co2 concentration of 2750 ppmv for the latest triassic

sea level change and facies development across potential triassic jurassic boundary horizons sw britain the late triassic to early jurassic aged succession of sw britain the penarth and lower lias groups comprises mudstone sandstone and limestone strata deposited in a variety of marine to non marine environments faunal and floral characteristics of these successions have led to the proposal that one location in sw england st audrie9s bay should serve as the global stratotype section and point gssp for the base of the hettangian stage and thus for the triassic jurassic tr j boundary the sections of sw britain have also been used previously to infer sea level change history and relate this to potential kill mechanisms associated with the tr j boundary mass extinction chemostratigraphic biofacies and lithofacies data are used here to suggest alternative models of sea level change in relation to possible tr j boundary horizons in the sections of sw britain a sea level lowstand surface of erosion is inferred to occur within the cotham member of the lilstock formation a unit deposited in an environment that was often subaerially exposed in contrast to previous interpretations the top surface of the overlying langport member here inferred to be deposited on a carbonate ramp of depositional or tectonic origin represents a drowning event of at least regional extent all horizons regarded as plausible levels at which to place the tr j boundary based on fossil distributions lie within strata deposited during relative sea level rise however it is doubtful whether the higher horizons proposed to mark the boundary faithfully record times of true biotic change on a global scale and additionally there is no positive evidence that sea level fall had any relation to the genesis of proposed tr j marker horizons it is unlikely that sea level fall played a significant role in the tr j boundary extinctions in either a local or a global context

mass extinctions and sea level changes abstract review of sea level changes during the big five mass extinctions and several lesser extinction events reveals that the majority coincide with large eustatic inflexions the degree of certainty with which these eustatic oscillations are known varies considerably thus the late ordovician and end cretaceous extinctions are associated with unequivocal major regressions demonstrated from numerous widespread regions in contrast the multiple high frequency sea level changes reported for the frasnian famennian crisis based on the supposed depth preferences of conodont taxa have little support from sequence stratigraphic analyses which reveals the interval to be one of highstand the end permian mass extinction has long been related to a severe first order lowstand of sea level newell n d 1967 revolutions in the history of life geol soc am spec pap 89 63 91 based primarily on the widespread absence of latest permian ammonoid markers but field evidence reveals that the interval coincides with a major transgression newell s hypothesis that marine extinctions are related to shelf habitat loss during severe regression remains tenable for the end guadalupian and end triassic extinction events but not for other crises rapid high amplitude regressive transgressive couplets are the most frequently observed eustatic changes at times of mass extinction with the majority of extinctions occurring during the transgressive pulse when anoxic bottom waters often became extensive the ultimate cause of the sea level changes is generally unclear a glacioeustatic driving mechanism can only be convincingly demonstrated for the end ordovician and end devonian events at other times it is speculated that they may relate to the widespread regional doming and subsequent collapse caused by the impingement of superplumes and ultimate eruption on the base of the lithosphere

response of the marine infauna to triassic jurassic environmental change ichnological data from southern england abstract the trace fossil record through the triassic jurassic boundary interval is examined at three sites in central and southern england st audrie s bay somerset pinhay bay devon and long itchington warwickshire the lower pre planorbis beds of the blue lias formation record low ichnotaxonomic diversity low bioturbation intensity small burrow diameters and an absence of deep tier bioturbation the stepwise reappearance of ichnotaxa following this interval is similar at the three sites suggesting similar rates of recovery in the benthic marine ecosystem and highlighting the potential contribution of these trace fossils to stratigraphic correlation mass extinction in the late triassic is increasingly linked to the emplacement of the central atlantic magmatic province camp timing of the onset of camp volcanism in the uk is currently imperfectly known but potentially occurred within either the westbury formation or the lilstock formation if the onset of camp was within the lilstock formation the modestly diverse trace fossil assemblage of the langport member of the lilstock formation suggests that emplacement of camp had little lasting effect on the marine benthos in central and southern england the decline in benthic activity recorded in the pre planorbis beds appears to be unrelated to the onset of camp and any associated environmental change it is more likely related to an episode of marine anoxia an episode of marine anoxia also provides a suitable causal mechanism for the reduction of infaunal tiering

stability of atmospheric co2 levels across the triassic jurassic boundary the triassic jurassic boundary 208 million years ago is associated with widespread extinctions in both the marine and terrestrial biota the cause of these extinctions has been widely attributed to the eruption of flood basalts of the central atlantic magmatic province this volcanic event is thought to have released significant amounts of co2 into the atmosphere which could have led to catastrophic greenhouse warming but the evidence for co2 induced extinction remains equivocal here we present the carbon isotope compositions of pedogenic calcite from palaeosol formations spanning a 20 myr period across the triassic jurassic boundary using a standard diffusion model we interpret these isotopic data to represent a rise in atmospheric co2 concentrations of about 250 p p m across the boundary as compared with previous estimates of a 2 000 4 000 p p m increase the relative stability of atmospheric co2 across this boundary suggests that environmental degradation and extinctions during the early jurassic were not caused by volcanic outgassing of co2 other volcanic effects such as the release of atmospheric aerosols or tectonically driven sea level change may have been responsible for this event

disentangling the hettangian carbon isotope record implications for the aftermath of the end triassic mass extinction 1 this study provides an organic carbon stable isotope 13corg record calibrated with detailed ammonite biostratigraphy following the end triassic biological crisis precise correlation between this crucial fossil group and the 13corg record is key to understanding feedbacks between biological and environmental events following mass extinction the latest triassic and hettangian 13corg record shows several negative and positive excursions the end triassic negative shift coinciding with the mass extinction interval is followed by a positive excursion in the earliest hettangian psiloceras spelae beds which marks the onset of recovery in the marine ecosystem this positive trend is interrupted by a second negative 13corg excursion in the p pacificum beds related to a minor ammonite extinction event this pattern of the 13corg curve culminates in the uppermost hettangian angulata zone major positive excursion this indicates that both the ecosystem and the carbon cycle remained in a state of perturbation for at least 2 ma although the recovery of some pelagic taxa already began at the base of jurassic the early and late hettangian positive 13corg excursions have been confused in several recent papers here we show that during the hettangian there are indeed two distinct positive 13corg excursions phases of anoxia and further pulses of central atlantic magmatic province volcanism during the hettangian might have inhibited the full recovery for that interval of time the main liasicus angulata organic positive cie carbon isotope excursion during the late hettangian might be related to gradual decreasing of pco2 due to protracted high organic burial and coincides with a second phase of recovery as indicated by a pulse of ammonoid diversification

rising atmospheric co2 as a possible trigger for the end triassic mass extinction the end triassic mass extinction one of the five largest extinctions in earth history was a severe catastrophe in which 80 of all species were wiped out the cause of the extinction is controversial but any mechanism must account for mass extinction in both marine and terrestrial environments one smoking gun the eruption of the central atlantic magmatic province camp has prompted the hypothesis that co2 degassing to the atmosphere may have induced an environmental catastrophe at the end triassic in this study we use a numerical coupled ocean atmosphere climate model of the late triassic to determine environmental stresses associated with a rapid increase in atmospheric co2 a series of sensitivity experiments with co2 levels that bracket estimated end triassic pco2 estimates 2 8 pre industrial levels predict extreme environmental conditions on land increasing co2 from 2 to 8 pre industrial levels causes an increase in the number and severity of hot days and days without precipitation an exponential increase in continental area experiencing hot days and enhanced seasonal fluctuation in the ocean wind driven circulation decreases and meridional overturning diminishes by a factor of 4 leading to enhanced ocean stratification a three box model of the deep ocean predicts a decline of 85 mol l in deep ocean oxygen concentration with a 4 fold increase in atmospheric co2 consequently while terrestrial organisms would have been subject to severe heat and water stress marine fauna would have experienced oxygen deprivation additional sensitivity experiments indicate that variations in milankovitch orbital parameters may further contribute to faunal stress by intensifying continental heating and seasonal fluctuations in sum model results predict that rising atmospheric co2 would have significantly impacted both marine and continental environments providing a link between turnover on land and ocean during the late triassic

new early jurassic tetrapod assemblages constrain triassic jurassic tetrapod extinction event the discovery of the first definitively correlated earliest jurassic 200 million years before present tetrapod assemblage fundy basin newark supergroup nova scotia allows reevaluation of the duration of the triassic jurassic tetrapod extinction event present are tritheledont and mammal like reptiles prosauropod theropod and ornithischian dinosaurs protosuchian and sphenosuchian crocodylomorphs sphenodontids and hybodont semionotid and palaeonisciform fishes all of the families are known from late triassic and jurassic strata from elsewhere however pollen and spore radiometric and geochemical correlation indicate an early hettangian age for these assemblages because all typical triassic forms are absent from these assemblages most triassic jurassic tetrapod extinctions occurred before this time and without the introduction of new families as was previously suggested by studies of marine invertebrates this pattern is consistent with a global extinction event at the triassic jurassic boundary the manicouagan impact structure of quebec provides dates broadly compatible with the triassic jurassic boundary and following the impact theory of mass extinctions may be implicated in the cause

a two and three dimensional analysis of gravity anomalies associated with the east pacific rise at 9 n and 13 n we have used a unique data set collected during the 1985 east pacific rise multichannel seismic experiment to reevaluate the constraints that gravity data can place on the crustal structure of the east pacific rise epr the close spacing of track lines within the two main survey areas 8 45 n 9 55 n and 12 20 13 30 n allowed us to perform three dimensional analyses of high quality gravity data 1 mgal uncertainity obtained with the bell aerospace bgm 3 gravity meter our gravity modeling was enhanced by the availability of high resolution sea beam bathymetric data and by independent structural constraints provided by seismic reflection and refraction data to model the crustal and upper mantle density structure at the ridge axis we first calculated the gravity anomalies due to the density contrasts at the water crust and crust mantle boundaries and the changes in density caused by the cooling of the lithosphere with age and subtracted these predictable signals from the observed free air anomaly the residual anomalies were then used to place constraints on the magnitude and distribution of anomalous mass at the epr our results show that over 90 of the power in the observed free air anomaly can be modeled by these predictable components of the gravity signal the amplitude and wavelength of the small residual anomaly can be modeled by a broad region 20 km wide centered on the rise axis of slightly lower than normal crustal and or upper mantle densities 0 03 mg m 3 this region of anomalous mass and density variations in the underlying mantle provide the principle isostatic support for the axial topographic high the anomalies are consistent with but do not require the presence of a low density crustal magma chamber at the rise axis if a largely molten magma chamber exists then the gravity data require that it be a narrow volumetrieally small body there are first order differences in the distribution of anomalous mass between the two survey areas with the 9 n region generally being characterized by lower densities in the axial region along axis variations in anomalous mass within each of the survey areas correlate with first order changes in the depth and cross sectional shape of the epr axial high we attribute these differences in axial morphology and the amplitude of the associated gravity anomalies to along strike changes in the size of the crustal magma chamber the width of the surrounding zone of cooling crustal rocks and densities in the uppermost mantle beneath the rise axis

a trace element geochemical model for imperfect fractional crystallization associated with the development of crystal zoning abstract although many petrological studies of volcanic rocks have suggested that crystallization proceeds within magma bodies highly compatible trace elements do not display the marked variations and extreme depletions predicted to result from perfect fractional crystallization imperfect crystal liquid separation is a key process in explaining this paradox the presence of suspended crystals greatly affects variations in highly compatible elements and has been quantitatively modeled by assuming perfect equilibrium between the suspended crystals and the liquid equilibrium crystallization and imperfect separation ecis however volcanic rocks generally contain zoned phenocrysts that reflect the absence of solid state equilibration the present study develops a mass balance model for zoned crystallization and imperfect separation zcis the zcis process is more efficient than the conventional ecis process in generating depleted compatible elements these two end member models are able to explain the compositional range of igneous rocks that experienced imperfect fractional crystallization under natural conditions the predicted compositional regions in bivariate trace element diagrams successfully account for the sizes and shapes of the regions defined by whole rock and melt inclusion data from the bishop tuff ca usa

events around the triassic jurassic boundary in northern and eastern spain a review abstract more than 20 successions containing the triassic jurassic t j boundary were studied in five of the major geological units of spain the data are from outcrop cored boreholes and interpreted well logs a consistent 3 4 13 c org isotope excursion starting in the rhaetian and continuing in the hettangian was recorded in asturias climate changes in the t j transition show a warming episode in the early hettangian other climate changes are indicated by an increase in hygrophytic miospores above the t j boundary this reflects a more humid episode at the beginning of the hettangian the messejana dyke in southeastern iberia is part of the central atlantic magmatic province camp co 2 outgassing related to extensive magmatic activity in the camp is thought to be one of the possible factors responsible for the end triassic mass extinction no major sea level changes or unconformities were recorded at the t j boundary only in the asturias area was there a well defined shallow carbonate platform during the t j transition the other areas of eastern and northern spain were occupied by coastal playas and sabkhas that developed in arid climatic conditions the biotic crisis around the t j boundary is reflected in the palynomorph record in asturias seven species do not persist beyond the late rhaetian and only six appeared in the triassic jurassic transition however 22 taxa appeared in the early hettangian

timing the end triassic mass extinction first on land then in the sea the end triassic marks one of the five biggest mass extinctions but current geologic time scales are inadequate for understanding its dynamics a tuff layer in marine sedimentary rocks encompassing the triassic jurassic transition yielded a u pb zircon age of 199 6 0 3 ma the dated level is immediately below a prominent change in radiolarian faunas and the last occurrence of conodonts additional recently obtained u pb ages integrated with ammonoid biochronology confirm that the triassic period ended ca 200 ma several million years later than suggested by previous time scales published dating of continental sections suggests that the extinction peak of terrestrial plants and vertebrates occurred before 200 6 ma the end triassic biotic crisis on land therefore appears to have preceded that in the sea by at least several hundred thousand years

isotopic imprint of climate and hydrogeochemistry on terrestrial strata of the triassic jurassic hartford and fundy rift basins abstract late triassic to early jurassic terrestrial sequences in the hartford and fundy rift basins have distinctive carbon and oxygen isotopic compositions of calcite and dolomite the isotopic data mostly reflect paleoclimatic fluctuations and hydrogeochemistry of the lacustrine playa and fluvial environments dolomites from laminae in three sequences of playa red mudstones and lacustrine gray to black mudstones in the hartford basin have variable isotopic compositions 13c 5 8 to 1 8 pdb 18o 7 2 to 0 7 pdb within any single symmetrical cycle of playa red mudstone lacustrine gray black gray mudstone playa red mudstone there is a systematic change to relatively enriched 13c compositions in dolomite in the grayish black and black mudstones in the center of the cycle these carbon isotopic data suggest that the lacustrine sequences formed as the lakes changed from well mixed with anoxic bottom waters to stratified with anoxic bottom waters where 13c depleted carbon was concentrated in organic matter that was then buried calcites from lacustrine micritic and biomicritic limestones of the scots bay formation of the fundy basin have stable isotopic compositions 13c 4 6 to 2 2 pdb 18o 6 1 to 3 0 pdb that become more enriched in 18o and 13c upward in shallowing depositional sequences these isotopic data reflect initial calcite precipitation when a high inflow of fresh water produced high lake levels followed by progressively lower inflow resulting in lower lake stands and higher salinity due to continuing evaporative loss of surface wat r the lake waters were well oxygenated at all times in the hartford basin caliche calcites in fluvial mudstones and sandstones have isotopic compositions 13c 7 3 to 3 8 pdb 18o 8 0 to 5 6 pdb that reflect paleosol processes during climatic conditions that varied from warm and dry in late triassic time to relatively cooler and probably wetter in the early jurassic isotopic compositions of caliche calcites in redbeds in the fundy basin indicate a parallel climate change from late triassic to early jurassic time but also that the climate was relatively hotter and probably drier over the entir interval as compared to the hartford basin