the structure of methane gas hydrate bearing sediments from the krishna godavari basin as seen from micro ct scanning abstract the indian national gas hydrate program nghp expedition 1 of 2006 cored through several methane gas hydrate deposits on the continental shelf around the coast of india the pressure coring techniques utilized during the expedition hyacinth and pcs enabled recovery of gas hydrate bearing fine grained sediment cores to the surface after initial characterization core sections were rapidly depressurized and submerged in liquid nitrogen preserving the structure and form of the hydrate within the host sediment once on shore high resolution x ray ct scanning was employed to obtain detailed three dimensional images of the internal structure of the gas hydrate using a resolution of 80 m the detailed structure of the hydrate veins present in each core could be observed and allowed for an in depth analysis of orientation width and persistence of each vein hydrate saturation estimates could also be made and saturations of 20 30 were found to be the average across the core section with some portions showing highs of almost 60 saturation the majority of hydrate veins in each core section were found to be orientated between 50 and 80 to the horizontal analysis of the strikes of the veins suggested a slight preferential orientation in individual sample sections although correlation between individual sections was not possible due to the initial orientation of the sections being lost during the sampling stage the preferred vein orientation within sample sections coupled with several geometric features identified in individual veins suggest that hydraulic fracturing by upward advecting pore fluids is the main formation mechanism for the veined hydrate deposits in the k g basin

mount elbert gas hydrate stratigraphic test well alaska north slope coring operations core sedimentology and lithostratigraphy abstract in february 2007 bp exploration alaska the u s department of energy and the u s geological survey completed the bpxa doe usgs mount elbert gas hydrate stratigraphic test well mount elbert well in the milne point unit on the alaska north slope the program achieved its primary goals of validating the pre drill estimates of gas hydrate occurrence and thickness based on 3 d seismic interpretations and wireline log correlations and collecting a comprehensive suite of logging coring and pressure testing data the upper section of the mount elbert well was drilled through the base of ice bearing permafrost to a casing point of 594 m 1950 ft approximately 15 m 50 ft above the top of the targeted reservoir interval the lower portion of the well was continuously cored from 606 m 1987 ft to 760 m 2494 ft and drilled to a total depth of 914 m ice bearing permafrost extends to a depth of roughly 536 m and the base of gas hydrate stability is interpreted to extend to a depth of 870 m coring through the targeted gas hydrate bearing reservoirs was completed using a wireline retrievable system the coring program achieved 85 recovery of 7 6 cm 3 in diameter core through 154 m 504 ft of the hole an onsite team processed the cores collecting and preserving approximately 250 sub samples for analyses of pore water geochemistry microbiology gas chemistry petrophysical analysis and thermal and physical properties eleven samples were immediately transferred to either methane charged pressure vessels or liquid nitrogen for future study of the preserved gas hydrate additional offsite sampling analyses and detailed description of the cores were also conducted based on this work one lithostratigraphic unit with eight subunits was identified across the cored interval subunits ii and va comprise the majority of the reservoir facies and are dominantly very fine to fine moderately sorted quartz feldspar and lithic fragment bearing to rich sands lithostratigraphic and palynologic data indicate that this section is most likely early eocene to late paleocene in age the examined units contain evidence for both marine and non marine lithofacies and indications that the depositional environment for the reservoir facies may have been shallower marine than originally interpreted based on pre drill wireline log interpretations there is also evidence of reduced salinity marine conditions during deposition that may be related to the paleo climate and depositional conditions during the early eocene

physical properties and rock physics models of sediment containing natural and laboratory formed methane gas hydrate this paper presents results of shear strength and acoustic velocity p wave measurements performed on 1 samples containing natural gas hydrate from the mallik 2l 38 well mackenzie delta northwest territories 2 reconstituted ottawa sand samples containing methane gas hydrate formed in the laboratory and 3 ice bearing sands these measurements show that hydrate increases shear strength and p wave velocity in natural and reconstituted samples the proportion of this increase depends on 1 the amount and distribution of hydrate present 2 differences in sediment properties and 3 differences in test conditions stress strain curves from the mallik samples suggest that natural gas hydrate does not cement sediment grains however stress strain curves from the ottawa sand containing laboratory formed gas hydrate do imply cementation is present acoustically rock physics modeling shows that gas hydrate does not cement grains of natural mackenzie delta sediment natural gas hydrates are best modeled as part of the sediment frame this finding is in contrast with direct observations and results of ottawa sand containing laboratory formed hydrate which was found to cement grains waite et al 2004 it therefore appears that the microscopic distribution of gas hydrates in sediment and hence the effect of gas hydrate on sediment physical properties differs between natural deposits and laboratory formed samples this difference may possibly be caused by the location of water molecules that are available to form hydrate models that use laboratory derived properties to predict behavior of natural gas hydrate must account for these differences

a reevaluation of using laboratory shear tests the expression for the average undrained shear strength mobilized on a slip surface in the field resulted from in situ vane and oedometer data combined with a correction factor obtained from the computed factor of safety of unstable embankments footings and excavations it is shown here that the same expression for mobilized undrained strength of soft clays is also obtained from laboratory shear tests by taking into account anisotropy and time effects this result is highly significant since the laboratory undrained shear strength data as well as the correction factor for the time effect are completely unrelated to the in situ data that previously resulted in the expression for field mobilized undrained shear strength key words mobilized undrained shear strength in situ vane test laboratory shear tests

extent of gas hydrate filled fracture planes implications for in situ methanogenesis and resource potential 1 high angle gas hydrate filled fracture planes were identified along a 31 m interval in logging while drilling images in two holes located 11 m apart drilled during the indian national gas hydrate program expedition 01 offshore india using monte carlo simulations to account for uncertainty in hole location hole deviation strike and dip we assert with 95 confidence that the fracture planes in the two holes are not the same the gas hydrate filled fracture planes likely only extend a few meters laterally from each borehole and occur in an isolated interval in the middle of the gas hydrate stability zone this suggests gas generated microbially within in the gas hydrate stability zone may have supplied the gas hydrate filled fracture interval production of methane from these reservoirs using conventional methods may be quite challenging

effective medium modeling of gas hydrate filled fractures using the sonic log in the krishna godavari basin offshore eastern india 1 indian national gas hydrate program expedition 01 has established that clay rich marine sediment from the krishna godavari kg basin in the eastern indian margin hosts one of the richest gas hydrate deposits in the world resistivity at bit images and pressure cores reveal that the gas hydrate morphology in clay rich sediment varies from complex vein structures grain displacing to invisible pore filling existing rock physics models which relate acoustic data to in situ gas hydrate concentrations generally assume isotropic pore filling gas hydrate which yields misleading concentration estimates for fractured fine grained sediments the anisotropic kg basin sediment presents additional complications here we apply differential effective medium theory to incorporate grain displacing morphologies by which gas hydrate is included as vertical ellipsoids with aspect ratios ranging from those of thin veins up to those of nodules in an elastic anisotropic background we have estimated gas hydrate concentrations from sonic velocities at hole 10d in the kg basin considering three basic gas hydrate morphologies i pore filling ii grain displacing and iii a combination of grain displacing and pore filling average gas hydrate saturations for these three cases are 35 42 27 30 and 33 41 of the total porosity respectively in the depth range 60 140 m below seafloor mbsf saturation is highest at 67 mbsf for any morphology but the values differ between morphologies for the pore filling morphology the maximum gas hydrate saturation of 56 is 18 22 higher than the grain displacing morphology and 2 9 higher than the combined morphology estimates differ by 6 of the sediment volume with rotations of gas hydrate veins from vertical to horizontal

comparison of the physical and geotechnical properties of gas hydrate bearing sediments from offshore india and other gas hydrate reservoir systems abstract the sediment characteristics of hydrate bearing reservoirs profoundly affect the formation distribution and morphology of gas hydrate the presence and type of gas porewater chemistry fluid migration and subbottom temperature may govern the hydrate formation process but it is the host sediment that commonly dictates final hydrate habit and whether hydrate may be economically developed in this paper the physical properties of hydrate bearing regions offshore eastern india krishna godavari and mahanadi basins and the andaman islands determined from expedition nghp 01 cores are compared to each other well logs and published results of other hydrate reservoirs properties from the hydrate free kerala konkan basin off the west coast of india are also presented coarser grained reservoirs permafrost related and marine may contain high gas hydrate pore saturations while finer grained reservoirs may contain low saturation disseminated or more complex gas hydrates including nodules layers and high angle planar and rotational veins however even in these fine grained sediments gas hydrate preferentially forms in coarser sediment or fractures when present the presence of hydrate in conjunction with other geologic processes may be responsible for sediment porosity being nearly uniform for almost 500 m off the andaman islands properties of individual nghp 01 wells and regional trends are discussed in detail however comparison of marine and permafrost related arctic reservoirs provides insight into the inter relationships and common traits between physical properties and the morphology of gas hydrate reservoirs regardless of location extrapolation of properties from one location to another also enhances our understanding of gas hydrate reservoir systems grain size and porosity effects on permeability are critical both locally to trap gas and regionally to provide fluid flow to hydrate reservoirs index properties corroborate more advanced consolidation and triaxial strength test results and can be used for predicting behavior in other nghp 01 regions pseudo overconsolidation is present near the seafloor and is underlain by underconsolidation at depth at some nghp 01 locations

hydrate morphology physical properties of sands with patchy hydrate saturation 1 the physical properties of gas hydrate bearing sediments depend on the volume fraction and spatial distribution of the hydrate phase the host sediment grain size and the state of effective stress determine the hydrate morphology in sediments this information can be used to significantly constrain estimates of the physical properties of hydrate bearing sediments including the coarse grained sands subjected to high effective stress that are of interest as potential energy resources reported data and physical analyses suggest hydrate bearing sands contain a heterogeneous patchy hydrate distribution whereby zones with 100 pore space hydrate saturation are embedded in hydrate free sand accounting for patchy rather than homogeneous hydrate distribution yields more tightly constrained estimates of physical properties in hydrate bearing sands and captures observed physical property dependencies on hydrate saturation for example numerical modeling results of sands with patchy saturation agree with experimental observation showing a transition in stiffness starting near the series bound at low hydrate saturations but moving toward the parallel bound at high hydrate saturations the hydrate patch size itself impacts the physical properties of hydrate bearing sediments for example at constant hydrate saturation we find that conductivity electrical hydraulic and thermal increases as the number of hydrate saturated patches increases this increase reflects the larger number of conductive flow paths that exist in specimens with many small hydrate saturated patches in comparison to specimens in which a few large hydrate saturated patches can block flow over a significant cross section of the specimen

gas hydrate saturation in the krishna godavari basin from p wave velocity and electrical resistivity logs abstract during the indian national gas hydrate program nghp expedition 01 a series of well logs were acquired at several sites across the krishna godavari kg basin electrical resistivity logs were used for gas hydrate saturation estimates using archie s method the measured in situ pore water salinity seafloor temperature and geothermal gradients were used to determine the baseline pore water resistivity in the absence of core data arp s law was used to estimate in situ pore water resistivity uncertainties in the archie s approach are related to the calibration of archie coefficient a cementation factor m and saturation exponent n values we also have estimated gas hydrate saturation from sonic p wave velocity logs considering the gas hydrate in frame effective medium rock physics model uncertainties in the effective medium modeling stem from the choice of mineral assemblage used in the model in both methods we assume that gas hydrate forms in sediment pore space combined observations from these analyses show that gas hydrate saturations are relatively low s h 15 20 in two zones between 168 and 198 mbsf site nghp 01 05 s h 35 38 in two discrete zone between 70 and 90 mbsf and site nghp 01 07 shows the gas hydrate saturation more than 25 in two zones between 75 and 155 mbsf a total of 10 drill sites and associated log data regional occurrences of bottom simulating reflectors from 2d and 3d seismic data and thermal modeling of the gas hydrate stability zone were used to estimate the total amount of gas hydrate within the kg basin average gas hydrate saturations for the entire gas hydrate stability zone seafloor to base of gas hydrate stability sediment porosities and statistically derived extreme values for these parameters were defined from the logs the total area considered based on the bsr seismic data covers 720 km 2 using the statistical ranges in all parameters involved in the calculation the total amount of gas from gas hydrate in the kg basin study area varies from a minimum of 5 7 trillion cubic feet tcf to 32 1 tcf

physical properties of sediments from the ulleung basin east sea results from second ulleung basin gas hydrate drilling expedition east sea korea abstract physical properties including basic index properties undrained shear strength and thermal conductivities were measured on conventional cores retrieved from the ulleung basin during the second ulleung basin gas hydrate expedition ubgh2 the ubgh2 logged 13 sites and cored 10 sites to locate potential sites for an offshore test production a total of 211 conventional cores were recovered undrained shear strength thermal conductivity and index properties including porosity and grain density were measured onboard mineral composition analyses and grain size analyses were completed onshore after the expedition the averaged porosity at each site ranges from 65 to 71 the averaged grain density at each site ranges from 2 57 to 2 66 g cm3 and the mean grain size mostly lies between 4 m and 25 m with sparsely scattered coarse grained intervals the relatively high porosity and low grain density are due to the large portion of diatomaceous sediments the thermal conductivities average around 0 8 w mk and the low porosity and the abundance of clay mineral and oapl a may have caused the relatively low thermal conductivity in the ulleung basin the geomechanical analyses revealed a few relevant findings important for sediment physical behaviors during gas hydrate production the particle migration in coarse grained layers during production necessitates proper measure for sand productions while fine grained layers are mostly self filtering the vertical deformation estimated from the compression index suggested that the subsidence induced by the pore pressure change from the depressurization is much higher than those induced by the lost of gas hydrate particles from dissociation massive vertical deformation in fine grained layers has been predicted to occur due to the pore pressure change from depressurization induced gas hydrate production the drilling mud weight induced pressure window is mostly determined by the water depth in deep sea drilling but caution should be taken in determination of fracture pressures in hydrate bearing sediments because gas hydrate saturations alter poisson s ratio

mount elbert gas hydrate stratigraphic test well alaska north slope overview of scientific and technical program abstract the mount elbert gas hydrate stratigraphic test well was drilled within the alaska north slope ans milne point unit mpu from february 3 to 19 2007 the well was conducted as part of a cooperative research agreement cra project co sponsored since 2001 by bp exploration alaska inc bpxa and the u s department of energy doe in collaboration with the u s geological survey usgs to help determine whether ans gas hydrate can become a technically and commercially viable gas resource early in the effort regional reservoir characterization and reservoir simulation modeling studies indicated that up to 0 34 trillion cubic meters tcm 12 trillion cubic feet tcf gas may be technically recoverable from 0 92 tcm 33 tcf gas in place within the eileen gas hydrate accumulation near industry infrastructure within ans mpu prudhoe bay unit pbu and kuparuk river unit kru areas to further constrain these estimates and to enable the selection of a test site for further data acquisition the usgs reprocessed and interpreted mpu 3d seismic data provided by bpxa to delineate 14 prospects containing significant highly saturated gas hydrate bearing sand reservoirs the mount elbert site was selected to drill a stratigraphic test well to acquire a full suite of wireline log core and formation pressure test data drilling results and data interpretation confirmed pre drill predictions and thus increased confidence in both the prospect interpretation methods and in the wider ans gas hydrate resource estimates the interpreted data from the mount elbert well provide insight into and reduce uncertainty of key gas hydrate bearing reservoir properties enable further refinement and validation of the numerical simulation of the production potential of both mpu and broader ans gas hydrate resources and help determine viability of potential field sites for future extended term production testing drilling and data acquisition operations demonstrated that gas hydrate scientific research programs can be safely effectively and efficiently conducted within ans infrastructure the program success resulted in a technical team recommendation to project management to drill and complete a long term production test within the area of existing ans infrastructure if approved by stakeholders this long term test would build on prior arctic research efforts to better constrain the potential gas rates and volumes that could be produced from gas hydrate bearing sand reservoirs

electrical anisotropy due to gas hydrate filled fractures in 2006 the indian national gas hydrate program expedition01 ornghp 01 discoveredgashydrateasfillinnearvertical fractures in unconsolidated sediments at several drillingsitesontheindiancontinentalmargins thesegashydrate filled fractures were identified on logging while drilling resistivity images the gas hydrate filled fracture intervals coincide with high measured resistivity at the nghp 01 sites high measured resistivity translates into high hydrate saturationsviaarchie sequation however thesehighsaturations contradict lower gas hydrate saturations determined from pressure core and chlorinity measurements also in intervalswithnear verticalgashydrate filledfractures thereis considerable separation between phase shift and attenuation resistivity logs with 2 mhz resistivity measurements being significantly higher than 400 khz resistivity measurements we modeled the sensitivity of the propagation resistivity measurements in the gas hydrate filled fracture intervals at nghp 01 sites 5 and 10 near vertical hydrate filled fracturescancausetheabnormallyhighresistivitymeasurements in vertical holes due to electrical anisotropy the model suggests the gas hydrate saturations in situ are usually significantlylowerthanthosecalculatedfromarchie sequation in addition these modeled gas hydrate saturations generally agree with the lower gas hydrate saturations obtained from pressure core and chlorinity measurements at nghp 01 sites5and10

permafrost associated natural gas hydrate occurrences on the alaska north slope abstract in the 1960s russian scientists made what was then a bold assertion that gas hydrates should occur in abundance in nature since this early start the scientific foundation has been built for the realization that gas hydrates are a global phenomenon occurring in permafrost regions of the arctic and in deep water portions of most continental margins worldwide in 1995 the u s geological survey made the first systematic assessment of the in place natural gas hydrate resources of the united states that study suggested that the amount of gas in the gas hydrate accumulations of northern alaska probably exceeds the volume of known conventional gas resources on the north slope researchers have long speculated that gas hydrates could eventually become a producible energy resource yet technical and economic hurdles have historically made gas hydrate development a distant goal this view began to change in recent years with the realization that this unconventional resource could be developed with existing conventional oil and gas production technology one of the most significant developments was the completion of the bpxa doe usgs mount elbert gas hydrate stratigraphic test well on the alaska north slope which along with the mallik project in canada have for the first time allowed the rational assessment of gas hydrate production technology and concepts almost 40 years of gas hydrate research in northern alaska has confirmed the occurrence of at least two large gas hydrate accumulations on the north slope we have also seen in alaska the first ever assessment of how much gas could be technically recovered from gas hydrates however significant technical concerns need to be further resolved in order to assess the ultimate impact of gas hydrate energy resource development in northern alaska

methane migration within the submarine gas hydrate stability zone under deep water conditions abstract possible pathways of methane migration and associated gas hydrate accumulation are considered gas hydrates precipitate in water filtration routes when the methane concentration in water exceeds its solubility which significantly decreases within the hydrate stability zone towards the sea floor in the vicinity of the ascending free gas flows gas hydrates are formed within a diffusion aureole resulting from the difference between chemical potentials of gaseous and water dissolved methane the role of diffusion is also essential in the vicinity of gas saturated water flows as well as within and above the sections where biochemical methane is intensively generated a chemical potential gradient of dissolved methane which is a necessary condition for gas hydrate accumulation is created due to inhomogeneity of the geological medium manifested as temperature and water salinity gradients or changes of permeability the thermobaric gas hydrate stability zone is a geochemical barrier for hydrocarbon gas emigrating from sediments into the water column however methane is not completely preserved in a hydrate state it is unknown yet which fraction of migrating methane is detained on this barrier

physical properties of sediment from the mount elbert gas hydrate stratigraphic test well alaska north slope this study characterizes cored and logged sedimentary strata from the february 2007 bp exploration alaska department of energy u s geological survey bpxa doe usgs mount elbert gas hydrate stratigraphic test well on the alaska north slope ans the physical properties program analyzed core samples recovered from the well and in conjunction with downhole geophysical logs produced an extensive dataset including grain size water content porosity grain density bulk density permeability x ray diffraction xrd mineralogy nuclear magnetic resonance nmr and petrography this study documents the physical property interrelationships in the well and demonstrates their correlation with the occurrence of gas hydrate gas hydrate gh occurs in three unconsolidated coarse silt to fine sand intervals within the paleocene and eocene beds of the sagavanirktok formation unit d gh 614 4 m 627 9 m unit c gh1 649 8 m 660 8 m and unit c gh2 663 2 m 666 3 m these intervals are overlain by fine to coarse silt intervals with greater clay content a deeper interval unit b is similar lithologically to the gas hydrate bearing strata however it is water saturated and contains no hydrate in this system it appears that high sediment permeability k is critical to the formation of concentrated hydrate deposits intervals d gh and c gh1 have average plug intrinsic permeability to nitrogen values of 1700 md and 675 md respectively these values are in strong contrast with those of the overlying gas hydrate free sediments which have k values of 5 7 md and 49 md respectively and thus would have provided effective seals to trap free gas the relation between permeability and porosity critically influences the occurrence of gh for example an average increase of 4 in porosity increases permeability by an order of magnitude but the presence of a second fluid e g methane from dissociating gas hydrate in the reservoir reduces permeability by more than an order of magnitude published by elsevier ltd

temporal and population trends in human exploited pinnipeds from tierra del fuego abstract archaeological sites on the coast of tierra del fuego argentina provide a biogeochemical record that can inform us about those ecological dynamics an abundance of southern fur seal arctocephalus australis and southern sea lion otaria flavescens remains provide a valuable resource to reconstruct ancient and modern food webs to quantify ecological relationships we measured bulk stable isotope ratios from bone collagen in otariids and other associated animals several of which are potential otariid prey variations in bulk stable isotope ratios of carbon 13c and nitrogen 15n are linked to potential dietary differences and habitat specialization between coastal areas or the open ocean in populations ranging in age from 7000 cal years bp to modern we observed increases in the variability of these isotopic compositions over time which suggests a diversity in the diets and habitats of otariids shifts in marine food webs occurred during the transition from subsistence hunting of otariids to industrial hunting and expanded human influence we conclude that direct human influences such as hunting and habitat alteration were the major drivers of ecological change in southern south american marine ecosystems

gas hydrate destabilization enhanced dewatering benthic material turnover and large methane plumes at the cascadia convergent margin mixed methane sulfide hydrates and carbonates are exposed as a pavement at the seafloor along the crest of one of the accretionary ridges of the cascadia convergent margin vent fields from which methane charged low salinity fluids containing sulfide ammonia 4he and isotopically light co2 escape are associated with these exposures they characterize a newly recognized mechanism of dewatering at convergent margins where freshening of pore waters from hydrate destabilization at depth and free gas drives fluids upward this process augments the convergence generated overpressure and leads to local dewatering rates that are much higher than at other margins in the absence of hydrate discharge of fluids stimulates benthic oxygen consumption which is orders of magnitude higher than is normally found at comparable ocean depths the enhanced turnover results from the oxidation of methane hydrogen sulfide and ammonia by vent biota the injection of hydrate methane from the ridge generates a plume hundreds of meters high and several kilometers wide a large fraction of the methane is oxidized within the water column and generates 13c anomalies of the dissolved inorganic carbon pool

seismic imaging of a fractured gas hydrate system in the krishna godavari basin offshore india gas hydrate was discovered in the krishna godavari kg basin during the india national gas hydrate program nghp expedition 1 at site nghp 01 10 within a fractured clay dominated sedimentary system logging while drilling lwd coring and wire line logging confirmed gas hydrate dominantly in fractures at four borehole sites spanning a 500 m transect three dimensional 3d seismic data were subsequently used to image the fractured system and explain the occurrence of gas hydrate associated with the fractures a system of two fault sets was identified part of a typical passive margin tectonic setting the lwd derived fracture network at hole nghp 01 10a is to some extent seen in the seismic data and was mapped using seismic coherency attributes the fractured system around site nghp 01 10 extends over a triangular shaped area of 2 5 km2 defined using seismic attributes of the seafloor reflection as well as seismic sweetness at the base of the gas hydrate occurrence zone the triangular shaped area is also showing a polygonal nearly hexagonal fault pattern distinct from other more rectangular fault patterns observed in the study area the occurrence of gas hydrate at site nghp 01 10 is the result of a specific combination of tectonic fault orientations and the abundance of free gas migration from a deeper gas source the triangular shaped area of enriched gas hydrate occurrence is bound by two faults acting as migration conduits additionally the fault associated sediment deformation provides a possible migration pathway for the free gas from the deeper gas source into the gas hydrate stability zone it is proposed that there are additional locations in the kg basin with possible gas hydrate accumulation of similar tectonic conditions and one such location was identified from the 3d seismic data 6 km nw of site nghp 01 10

did stones speak about people flint catchment and neanderthal behavior from area 3 canaveral madrid spain abstract middle paleolithic catchment patterns have been exhaustively studied in the past however it is essential to clearly define neanderthal technical and strategic abilities in relation to raw materials self provide from a temporal perspective here we present a study of quarrying activities in open air sites occupied during mousterian period in madrid spain with different patterns of lithic catchment at the el canaveral archaeological complex several sites have been identified in relation with natural flint outcrops from these we have gained information about flint supplying patterns both in primary and secondary deposits in addition different operative chains and diverse systems of ramification and recycling were employed depending on the final objectives we were able to appreciate additional actions by analyzing the diacritic superposition of knapping series in blanks cores and supports of different qualities changes in categories dimensions and raw material qualities allow a first identification of lithic actions throughout time as a proxy of standardized or random human behavior when catchment actions took place

energy resource potential of natural gas hydrates the discovery of large gas hydrate accumulations in terrestrial per mafrost regions of the arctic and beneath the sea along the outer continental margins of the world s oceans has heightened interest in gas hydrates as a possible energy resource however significant to potentially insurmountable technical issues must be resolved be fore gas hydrates can be considered a viable option for affordable supplies of natural gas the combined information from arctic gas hydrate studies shows that in permafrost regions gas hydrates may exist at subsurface depths ranging from about 130 to 2000 m the presence of gas hydrates in offshore continental margins has been inferred mainly from anomalous seismic reflectors known as bottom simulating reflectors that have been mapped at depths below the sea floor ranging from about 100 to 1100 m current estimates of the amount of gas in the world s marine and permafrost gas hydrate accumulations are in rough accord at about 20 000 trillion m3 disagreements over fundamental issues such as the volume of gas stored within delineated gas hydrate accumulations and the concentration of gas hydrates within hydrate bearing strata have demonstrated that we know little about gas hydrates recently however several countries including japan india and the united states have launched ambitious national projects to further examine the resource potential of gas hydrates these projects may help answer key questions dealing with the properties of gas hydrate reservoirs the design of production systems and most important the costs and economics of gas hydrate production

thermal conductivity of methane hydrate bearing ulleung basin marine sediments laboratory testing and numerical evaluation the thermal conductivity of gas hydrate bearing sediments is a key parameter used to evaluate the heat transfer process relevant to phase transformation during gas hydrate production and to assess heat flux properties within the hydrate stability zone relatively few thermal conductivity values for in situ hydrate bearing sediments and laboratory hydrate bearing sediments have been reported for under saturated conditions with vertical effective stress in this study we used sandy sediments obtained during the ulleung basin gas hydrate expedition 2 ubgh2 expedition in korea to synthesize methane hydrate bearing sediments with saline pore fluid the transient plane source method was implemented to measure the thermal conductivity of specimens with variable gas hydrate saturations the measured thermal conductivity was 1 47 w m k and was independent of hydrate saturation results from additional tests of ice and water unsaturated sediments were also compared to our findings both geometric mean and 3d thermal network models corroborated the experimentally measured thermal conductivities assuming expected physical properties

physical property changes in hydrate bearing sediment due to depressurization and subsequent repressurization physical property changes in hydrate bearing sediment due to depressurization and subsequent repressurization w f waite 1 t j kneafsey 2 w j winters 1 d h mason 1 u s geological survey 384 woods hole road woods hole ma 02543 usa lawrence berkeley national laboratory 1 cyclotron rd ms 90r1116 berkeley ca 94720 usa