the temperature dependence of hydrogen isotope fractionation between clay minerals and water evidence from a geopressured system abstract d values of water samples from two gulf coast geopressured fields vary linearly with temperature while the d values from the coexisting clays remain constant and are independent of temperature fluid how rates on the order of millimeters per year characteristic of gulf coast geopressured systems provide adequate residence time for hydrogen isotope equilibrium to be achieved between the extant porewaters and clay minerals since equilibrium is achieved these d values are used to calculate the temperature dependence of the hydrogen isotope fractionation factor between illite smectite and water clay waterh between 0 and 150 c 1000 in clay water h 45 3 10 3 t 94 7 this equation predicts values for clay waterh at 96 c which are equal to those predicted by a similar equation derived by yeh 1980 above and below 96 c this new equation predicts values which diverge from those predicted by the equation of yeh 1980 with a difference of 9 at 150 c and 25 at 0 c the possibility is raised that the very slow upward component of flow characteristic of gulf coast geopressured sediments combined with the slow downward subsidence of the clay rich sediments can result in a system which is rock dominated with respect to hydrogen

stable isotopic investigation of clay minerals and pedogenesis in an interfluve paleosol from the cenomanian dunvegan formation n e british columbia canada abstract mineralogical and stable hydrogen and oxygen isotopic compositions have been obtained for clay minerals comprising an interfluve paleosol clayhurst ch 2 from the early to middle cenomanian dunvegan formation british columbia canada this paleosol provides a special opportunity to determine the stable isotopic composition of early late cretaceous paleoprecipitation on the western coast of the western interior seaway at a very northerly paleolatitude 65 detrital kaolinite and illite and complex dioctahedral mixed layer clay minerals of pedogenic origin are abundant throughout the paleosol in the d values of 93 to 81 and 18 o values of 12 9 to 11 6 were generally obtained for the ancient soil water and hence paleoprecipitation for one thin interval near the top of the paleosol higher values are indicated for the ancient soil water these results may indicate processes arising from a westward transgression of the western interior seaway

an extensive deposit of fossil conifer wood from the mesozoic of mali southern sahara abstract examination of an extensive deposit of silicified fossil wood in continental intercalaire rocks of northeastern mali suggests that the logs found at this locality were deposited under high energy conditions sometime between the late jurassic and the early cretaceous the woods have been identified as metapodocarpoxylon libanoticum edwards duperon laudoueneix and pons an extinct member of the podocarpaceae which has a restricted geographic and stratigraphic distribution northern gondwana and tethys from late jurassic to early cretaceous time anatomical analysis indicates that the tree rings are indistinct which supports previous suggestions that west africa was under an equable climate during this part of the mesozoic

a palaeoclimate model for the kimmeridgian abstract most attempts at using numerical general circulation model gcm to simulate mesozoic climates have studied the late cretaceous and have focused on the enigmaof apparently equable global climates however this climate regime lasted throughout the mesozoic and it is of interest to examine other periods we present the results of an integration for the late jurassic using a relatively detailed and high resolution model there is generally good agreement between the model climate and the existing geological data in particular the simulation predicts no permanent ice cover near either pole arid conditions over the southwestern usa seasonally arid climate over southern europe and winter storminess over europe and australia however the surface temperatures over siberia and southeastern gondwanaland drop below zero for a significant part of the winter

a proterozoic rift origin for the structure and the evolution of the cratonic congo basin abstract we interpret the cratonic congo basin a large circular cuvette centrale filled with up to 9 km of proterozoic to neogene sediments as the consequence of a neo proterozoic rift firstly the magnitude and the long term subsidence are consistent with the thermal time constant of a 200 250 km thick lithosphere inferred from several tomographic studies secondly the surface accumulation of sediments is compensated at depth by crustal thinning whose magnitude can be estimated from the analysis of the surface gravity after backstripping the effect of the sediments a residual nw se positive and narrow gravity anomaly is observed across the cuvette centrale and is interpreted as the remaining crustal thinning associated with this rift assuming that isostasy is governed by a necking level and a flexural response to sediment loads we have estimated the combination of the depth of necking and the equivalent elastic thickness of the lithosphere that provide the best fit with the residual gravity i e 10 km and 100 km respectively the corresponding uplift of the upper mantle is in the continuity of the mbuji mayi supergroup to the se and the liki bembian group to the nw these two groups represent older stages of rifting in the congo craton which shows that rifting has periodically affected and weakened the cuvette centrale during a long period of time

aspects of climatic influence on the clay mineralogy and geochemistry of soils palaeosols and clastic sedimentary rocks climate strongly influences soil clay mineralogy and bulk chemical composition in humid climates chemical weathering is at its most intense and virtually all primary bedrock minerals suffer complete breakdown they are replaced by authigenic hydrated oxides of fe and al together with halloysite and kaolinite in deep profiles these minerals develop where the residence time of water in the soil is slight longer residence times lead to higher solute concentrations and the stabilization of smectite authigenic palygorskite and sepiolite may form in highly saline alkaline soils the stability of these precipitated minerals is problematic they may be metastable or even unstable all other clays found in soils are unstable being incomplete solid state hydrolysis products of substrate minerals the balance between stable metastable and unstable minerals and the rate of profile development are both much influenced by temperature rainfall and activities of soil biota themselves reflecting climate bedrock influence is greatest under conditions of low to moderate precipitation where unstable minerals persist local topography however also strongly influences both the rate and products of chemical weathering quite independently of climate on the grand scale tectonic factors may constrain the time available for profiles to develop hence the extent to which bedrock minerals survive or are altered mountain soils reflect local climate and bedrock composition much more than latitude the sediments delivered to major basins today do not reflect global soil distribution patterns the bulk composition of suspended sediment entering the indian ocean for example is rather similar to that entering the arctic ocean sediment dispersal patterns can also confuse climatic signals a problem not encountered with palaeosols authigenic clays formed within sedimentary basins and post depositional burial alteration of both sediments and buried soil profiles must lead to interpretational ambiguities climatic signals are likely to survive best in bulk compositional data although diagenetic reactions at depths in excess of about 2 km do not appear to be isochemical and in the distribution of more stable yet climatically sensitive minerals kaolinite as opposed to illite chlorite

dinosaurs and other fossil vertebrates from fluvial deposits in the lower cretaceous of southern tunisia remains of dinosaurs and other vertebrates sharks bony fishes coelacanths turtles crocodilians pterosaurs are reported from the chenini formation of the tataouine region in southern tunisia the formation is part of the continental intercalaire a succession of continental deposits of early to late cretaceous age distributed over the whole of north africa and the sahara it consists of bar and channel deposits of broad rivers that flowed nnw from the mid sahara region towards the southern shore of tethys dinosaur bearing units in the continental intercalaire have been dated to the hauterivian to cenomanian and the chenini formation is possibly albian in age dinosaur fossils include abundant teeth of the theropods carcharodontosaurus and spinosaurus as well as postcranial elements of theropods and a medium sized sauropod a tooth of an ornithocheirid is the first report of a pterosaur from the region the dinosaur bones and teeth were transported some distance and deposited in a channel lag associated with less damaged locally derived material such as fern fronds coprolites fish teeth and scales and crocodilian scutes

palaeoenvironments of vertebrates on the southern shore of tethys the nonmarine early cretaceous of tunisia abstract through the late jurassic and early cretaceous the southern shore of the tethys ocean migrated north and south over short distances these vicissitudes are documented in the continental intercalaire a long series of mainly non marine sediments deposited across north africa a combined taxonomic physical and chemical taphonomic study provides independent lines of evidence for reconstruction of palaeoenvironments within this marginal marine setting the douiret chenini and oum ed diab formations from the tataouine basin of southern tunisia span the later part of the early cretaceous microvertebrates from four sites in these formations show different modes of physical abrasion time averaging and mixing based on a taphonomic analysis using a combination of physical and chemical methods the taxonomic composition of each assemblage and trends in rare earth element ree compositions of bones from each locality were used as independent lines of evidence to indicate differences in early depositional environments the jebel boulouha assemblage douiret formation is interpreted as a terrestrial carbonate rich environment with relatively little mixing the touil el mra assemblage oum ed diab formation suggests a marginal marine environment with some mixing of previously interred bones the oued el khil assemblage chenini formation and the oum ed diab assemblage oum ed diab formation are more equivocal suggesting mixed freshwater and marine influences interpreting salinity in marginal marine settings is difficult and best attempted from multiple independent lines of evidence we suggest that ree geochemistry can contribute to palaeoenvironmental reconstruction when used in combination with other independent physical palaeontological and or geochemical methods

a review of mesozoic climates there is overwhelming evidence based on the distribution of distinctive sediments and fossils and oxygen isotope data that the climate of the mesozoic world was appreciably more equable than that of today with no polar ice caps but precise quantitative data are not available except for an episode of late cretaceous cooling there is no good documentation of any significant change in global temperature distributions through the era the distribution of coals and evaporites together with other criteria indicates a pattern of humid arid and zones appreciably different in important respects from that of today during the triassic and jurassic western pangaea in low to middle latitudes was largely arid but in the early cretaceous the lands on the margin of the newly opening central atlantic and western tethys experienced a humid climate by late cretaceous times arid zones had become very restricted in extent because of insufficient suitable data attempts at climatic modelling have had only modest success and only to a limited extent can the major long term changes in climate between the permian and the present be explained in terms of changing geography the most probable explanation of mesozoic equability is an increased atmospheric co 2 content a number of enigmas remain such as the existence of flourishing forests in polar palaeolatitudes whereas for the late cenozoic short term climatic changes can be related successfully to variations in the geometry and mechanics of the earth sun system there is a long way to go before comparable success can be claimed for the mesozoic

high temperature environments of human evolution in east africa based on bond ordering in paleosol carbonates many important hominid bearing fossil localities in east africa are in regions that are extremely hot and dry although humans are well adapted to such conditions it has been inferred that east african environments were cooler or more wooded during the pliocene and pleistocene when this region was a central stage of human evolution here we show that the turkana basin kenya today one of the hottest places on earth has been continually hot during the past 4 million years the distribution of 13c 18o bonds in paleosol carbonates indicates that soil temperatures during periods of carbonate formation were typically above 30 c and often in excess of 35 c similar soil temperatures are observed today in the turkana basin and reflect high air temperatures combined with solar heating of the soil surface these results are specific to periods of soil carbonate formation and we suggest that such periods composed a large fraction of integrated time in the turkana basin if correct this interpretation has implications for human thermophysiology and implies a long standing human association with marginal environments

paleoenvironmental reconstruction from chemical and isotopic compositions of permo pennsylvanian pedogenic minerals mineralogical and chemical analysis of late pennsylvanian and early permian paleosols from the eastern shelf of the midland basin north central texas usa are used to test hypothesized climate change in late paleozoic western equatorial pangea previously defined independently on the bases of sedimentologic and paleontologic proxies and climate models the 0 2 m size phyllosilicate fraction in the studied paleosols exhibits down profile trends in mineralogy and chemical composition that are consistent with modern weathering profiles suggesting a dominantly pedogenic origin a stratigraphic trend from kaolinite dominated profiles in upper pennsylvanian paleosols to profiles dominated by smectite and hydroxy interlayered 2 1 phyllosilicates in lower permian paleosols indicates a relatively rapid decrease in soil weathering and leaching in the latest pennsylvanian followed by a more gradual decrease in leaching throughout the early permian the chemical composition cation ratios and exchange capacity of these phyllosilicates further corroborates this shift toward less intensive leaching presumably in response to climate change from humid to progressively more arid conditions the phyllosilicates in the 0 2 m size fraction and contemporaneous pedogenic calcites from the permo pennsylvanian paleosols exhibit a long term stratigraphic increase in their 18o values of as much as 3 2 and 5 2 respectively this long term trend is consistent with a transition throughout the latest pennsylvanian through early permian toward progressively more evaporatively enriched soil waters superimposed on the long term trend is an apparent rapid enrichment 1 5 to 2 in phyllosilicate 18o values immediately above the pennsylvanian permian boundary observed oxygen isotope fractionation between the phyllosilicates and calcites within individual paleosols indicate isotopic disequilibrium between mineral pairs this is attributed to a minor detrital component in the pedogenic clay dominated phyllosilicate fraction coupled with the effects of seasonality of mineral formation inferred 18o compositions of late paleozoic meteoric water 2 to 4 are compatible with less intensive soil leaching under conditions of increasing aridity possibly coupled with a shift in local precipitation from a continental source to a marine source

co2 forced climate thresholds during the phanerozoic abstract the correspondence between atmospheric co2 concentrations and globally averaged surface temperatures in the recent past suggests that this coupling may be of great antiquity here i compare 490 published proxy records of co2 spanning the ordovician to neogene with records of global cool events to evaluate the strength of co2 temperature coupling over the phanerozoic last 542 my for periods with sufficient co2 coverage all cool events are associated with co2 levels below 1000 ppm a co2 threshold of below 500 ppm is suggested for the initiation of widespread continental glaciations although this threshold was likely higher during the paleozoic due to a lower solar luminosity at that time also based on data from the jurassic and cretaceous a co2 threshold of below 1000 ppm is proposed for the initiation of cool non glacial conditions a pervasive tight correlation between co2 and temperature is found both at coarse 10 my timescales and fine resolutions up to the temporal limits of the data set million year timescales indicating that co2 operating in combination with many other factors such as solar luminosity and paleogeography has imparted strong control over global temperatures for much of the phanerozoic

formation of analcime and moganite at lake lewis central australia significance of groundwater evolution in diagenesis abstract lake lewis basin in the northern territory is a hydrologically closed intermontane basin in which clay rich palaeolacustrine sediments are infused with highly evolved brines acquisition of dissolved silica and sodium by groundwaters from the proterozoic arunta granite gneiss terrain and from arkosic alluvium and weathering products sourced from these bedrocks is important to diagenesis at the salt lake supersaturation of groundwaters with respect to sio 2 and the availability of catalytic ions coupled with high rates of evaporation favour neoformation of opal and chalcedonic silica from solution near the groundwater discharge zone moganite a distinctive silica polymorph that is commonly associated with evaporites has been identified amongst precipitated silica species down gradient from the zone of silica precipitation beneath the playa brines are sio 2 deficient long periods of weathering and diagenesis of lacustrine clays immersed in semi stagnant brines has transformed detrital minerals into substantial proportions of amorphous or gelatinous aluminosilicate material aluminosilicate phases have become metastable in the presence of evolved sio 2 deficient interstitial brine analcime a sodium bearing zeolite group mineral is stable in the presence of the na rich brine and is crystallizing authigenically below the watertable from the amorphous aluminosilicate material in the lacustrine sediment no volcanic rocks or pyroclastic sediments are involved in this diagenetic occurrence of analcime the appearance of analcime in the evolution of the salt lake system probably commenced within the last 100 000 years and is occurring in the present day hydrologic and climatic regime of this arid zone area

oxygen and hydrogen isotope compositions in clay minerals a potential single mineral geothermometer the opposite slopes of the isotopic fractionation of hydrogen and oxygen in the clay water system and the well known relationship between d and 18o in meteoric waters allow the isotopic composition of clay minerals to be used as a single mineral geothermometer equations can be derived which are valid for continental systems where meteoric waters are common the following equation was derived for smectite 3 54 106t 2 18osm 0 125 dsm 8 95 0 150 this equation was used to determine the isotopic composition and temperature of the waters involved in the transformation of volcanic rock to bentonite at the cortijo de archidona southeastern spain site the values obtained 6 t 21 c i e environmental temperatures confirm the reliability of this equation

recent advances in petroleum isotope geochemistry abstract organic matter is isotopically heterogeneous lipids tend to be depleted in the heavy carbon and hydrogen isotopes as compared to carbohydrates and lignite the c and h isotopic composition of kerogens is determined by many factors such as environmental conditions during formation and deposition and variability of sources of organic matter stable isotope concentrations in mature kerogens are not significantly altered during maturation and hence reflect the variability of the organic matter during deposition isotope variations in kerogens therefore reflect to some extent the paleogeographic situation and can be used for paleoreconstruction a basin facies with anoxia and a marginal facies with detrital input can be differentiated isotopically in the toarcian of central europe coals are isotopically heterogeneous due to different isotopic composition of macerals inertinite and vitrinite tends to be enriched in deuterium as compared to exinite also boghead coals tend to be depleted in dueterium which possibly reflects various lipid contents of respective precursor materials petroleums can be genetically classified through the patterns of covariance of their compound classes carbonate and shale sourced petroleums may be additionally differentiated through their deuterium content the general world wide applicability of such genetic differentiations needs still to be proved carbon and hydrogen isotope variations in methane are genetically controlled bacterial methane in freshwater environments is characteristically depleted in deuterium even complex origins of natural gases can be unraveled using compositional and isotopic variations new analytical developments led to the application of carbon isotope analyses of gaseous hydrocarbons desorbed from sediments for geochemical surface exploration a discussion reveals that processes such as isotope effects during degassing and bacterial oxidation as well as indigenous formation of hydrocarbons may completely obscure the results

climate of the supercontinent pangea numerous climate models predict that the geography of the supercontinent pangea was conducive to the establishment of a megamonsoonal circulation in general geologic evidence supports the hypothesis of a megamonsoon that reached maximum strength in the triassic pangea in the late carboniferous had widespread peat formation in what is now central and eastern north america and europe and relatively dry conditions on the colorado plateau the equatorial region of the continent became drier through the end of the carboniferous by the permian the equatorial region of pangea was dry and indicators of aridity and rainfall seasonality became more widespread wind directions from colorado plateau eolian sandstones are consistent with an increasing influence of monsoonal circulation at this time in the triassic climate in the colorado plateau region became relatively wet though still seasonal and the few eolian sandstones indicate a major shift in wind direction at that time in addition sedimentation

addendum to inclusion of the weathering of volcanic rocks in the geocarbsulf model r a berner 2006 v 306 p 295 302 in the paper by berner 2006a 1 the compiled data presented by dessert and others 2001 2 for different values of the relative weathering rates of basalts versus granites was missed the term granite is used here to refer to all granitoid rocks including gneisses it is the primary

late jurassic paleoclimate of central africa abstract paleopedology and geochemical analysis of upper jurassic deposits in the stanleyville group of central africa indicate harsh late jurassic paleoclimates in the interior of gondwana subsurface samples collected from the samba borehole near the center of the congo basin show only weak morphological evidence of pedogenesis but are characterized by an abundance of shrink swell vertic features and rare calcium carbonate nodules indicating seasonal variations in moisture availability and net soil moisture deficiency respectively x ray diffraction analysis of paleosol matrix material reveals the presence of analcime and the clay mineral palygorskite strong indicators of hot arid climatic conditions the 18 o and d values of clay minerals from paleosol profiles range from 22 3 to 25 4 and 44 4 to 39 6 smow respectively and correspond to crystallization temperatures between 25 c and 40 c these crystallization temperatures compare favorably with austral summer surface temperature estimates for central africa that result from late jurassic global circulation models calculations of soil co 2 production using the 13 c values of pedogenic carbonates and plant derived organic matter produce lower co 2 production estimates for the stanleyville group relative to the roughly contemporary morrison formation of the western u s these low soil co 2 production estimates provide further support for arid late jurassic climate conditions in the congo basin the paleoclimatic conditions inferred here from the stanleyville group are similar to those reconstructed from other upper jurassic african continental localities between 5 s and 20 s paleolatitude however penecontemporaneous terrestrial coastal sites within this latitudinal belt of gondwana retain evidence of generally wetter conditions suggesting that those regions may have received more rainfall than the continental interior the paleoclimatic setting reconstructed here from geologic indicators and geochemical proxies suggests that general circulation models accurately predict unique paleoenvironmental conditions that lack modern analogs

classification of paleosols despite increased interest in paleosols during the past decade no satisfactory classification is in current use presented here is a largely descriptive classification system that utilizes those pedogenic features that have the highest preservation potential in the rock record emphasized in the classification are morphological and mineralogical features that are easily recognizable in the field and through the petrographic microscope the classification is based on evaluation of the relative prominence in a paleosol of six pedogenic features or processes organic matter content horizonation redox conditions in situ mineral alteration illuviation of insoluble minerals compounds and accumulation of soluble minerals the most prominent of these six features processes provides the key to classifying a paleosol into one of nine orders four of the order names are borrowed from soil taxonomy histosol spodosol oxisol vertisol whereas the other five order names are presented here for the first time calcisol gypsisol gleysol argillisol protosol the orders may be preceded by one or more subordinate modifiers that describe other important features of the paleosol the classification is relatively easy to apply to the rock record and should enhance communication and aid in the standardization of terminology

botryococcane in a new class of australian non marine crude oils there are few documented examples of source specific hydrocarbons in non marine petroleum and most of these are related to land plant precursors1 3 one such biological marker of algal origin is botryococcane c34h70 a geologically rare acyclic alkane derived from the freshwater green alga botryococcus braunii4 5 first discovered in several sumatran crude oils6 7 and here identified in a suite of coastal bitumens from 10 different stranding sites between kingston south australia and portland victoria table 1 figs 1 2 biological marker and carbon isotope analyses of these bitumens provide evidence for a new class of australian non marine crude oils the bitumens are inspissated waxy residues of paraffinic and paraffinic naphthenic crude oils that emanate from submarine seeps in the western otway basin8 12 and are characterized by high concentrations of botryococcane unlike other high wax australian oils13 14 the coastal bitumens contain up to 2 6 sulphur and seem to be primarily of algal origin their geochemistry can be used to predict the occurrence of extensive organic rich source beds that were deposited in deep meromictic lakes along australia s southern continental margin

biological markers in the rhaetian black shales of south west britain abstract in the light of renewed interest in on shore petroleum exploration within the united kingdom we have investigated the aliphatic hydrocarbon distributions of contemporaneously deposited black shales from rhaetian upper triassic westbury formation outcrops and subcrops in the worcester graben and bristol channel trough the aliphatic hydrocarbon compositions of six samples three from each tectonic basin are examined by gas chromatography mass spectrometry although there are close similarities in the hydrocarbon content of the individual members of each sample suite there are significant differences between the two suites most notably the polycyclic components of the worcester graben samples are dominated by 4 methylsteroids thought to be products derived from dinoflagellate 4 methylsterols and also hopanes indeed polycyclic components are generally more abundant in the worcester graben all the samples show evidence of minor terrigenous inputs i e plant waxes from the prominence of the odd numbered higher n alkane components in the range n c 25 n c 35 the distributions of biological marker compounds in the samples indicate that none is sufficiently mature to have generated oil the shales from the bristol channel trough are however more mature than those from the worcester graben

structure and evolution of the intracratonic congo basin 1 surface wave tomography heat flow and crustal thickness measurements have demonstrated that the thickness of the continental lithosphere varies by at least a factor of 2 since the thermal time constant of the lithosphere depends upon the square of its thickness subsidence records of extensional sedimentary basins offer a potential way of extending these observations into the past here we examine the congo basin a large and iconic intracratonic sedimentary basin in central africa this roughly circular basin covers an area in excess of 1 4 106 km2 with more than 5 km thickness of sedimentary rocks the oldest parts of which are late precambrian in age first we assess the thickness of the lithosphere we have estimated its thickness across africa using maps of shear wave velocity obtained by inversion of fundamental and higher mode surface waveforms the congo basin sits on 220 30 km thick lithosphere and appears to be part of a southern core to the continent encompassing both archean cratons and proterozoic mobile belts this thickness is consistent with published estimates from kimberlites reappraisal of legacy seismic reflection images demonstrates that the sedimentary section is underlain by a late precambrian rift zone and that the basin is still subsiding today subsidence modeling of two deep wells is consistent with uniform extension and cooling of the lithosphere by a factor of 1 2 during latest precambrian and cambrian time we argue that the exceptional 0 55 ga history of the basin is a direct consequence of the lithospheric thermal time constant being a factor of 4 longer than normal today the basin coincides with a long wavelength 30 to 40 mgal gravity anomaly we interpret this gravity anomaly as the surficial manifestation of 400 600 m of recent mantle convective drawdown in response to the onset of upwelling plumes around the flanks of the southern african continent the alternative explanation that it is the static manifestation of locally thick lithosphere is inconsistent with global trends of mantle density depletion our interpretation is consistent with fast seismic velocities observed throughout the sublithospheric upper mantle underneath the basin and recent geodynamic modeling

tectonic evolution of the cuvette centrale zaire the cuvette centrale central basin of zaire is an infra cambrian to recent basin with up to 9 km of sedimentary section basin subsidence can be largely explained by a postulated late proterozoic failed rift and subsequent thermal relaxation seismic reflection profiles and well data reveal a palaeozoic development of the basin punctuated by two regional deformational episodes one in the early palaeozoic late cambrian and a second in the late palaeozoic late permian triassic both episodes result from ne sw contraction with the late palaeozoic episode being largely a reactivation of the early palaeozoic structures the timing of the two deformations correlates with collisional events at continental margins some distance from the congo basin in the early palaeozoic the deformation appears to be related to the late stages of the west congolian fold and thrust belt and coincides regionally with the pan african event sensu stricto the late palaeozoic deformation coincides with collisional tectonics along the southern margin of gondwana and the generation of the cape and sierra ventana foldbelts it is postulated that in both the early and late palaeozoic africa and gondwana experienced widespread intracontinental deformation generated by distant collisional processes much as central asia is experiencing today

considerations on the age of the tiouaren formation iullemmeden basin niger africa implications for gondwanan mesozoic terrestrial vertebrate faunas abstract pre aptian mid mesozoic terrestrial vertebrates from the african continent are still very poorly known in niger the tiouaren formation in the iullemmeden basin has yielded dinosaur and other vertebrate remains and this unit has been dated as early cretaceous most probably pre aptian on the basis of its fish fauna and geological relations to other units in the basin a review of the fish fauna and invertebrates from this formation does not provide any evidence for such an age and the geological relations only help to constrain the upper limit for the age of the formation aptian in contrast the described dinosaur taxa are phylogenetically nested with late middle jurassic to early late jurassic taxa from other localities and thus indicate a pre kimmeridgian probably late middle jurassic age for the tiouaren formation under the assumption of such an age the dinosaur fauna of this formation provides new insights into dinosaur faunal provincialism during the latest middle jurassic northern gondwanan faunas of that time seem to have been different from southern gondwanan faunas and show closer affinities to eurasian faunas than to the latter a possible explanation for this might be a climatically controlled geographic barrier due to pronounced arid conditions and thus desert environments in central gondwana during this time

palaeosols as indicators of geomorphic stability in two old red sandstone alluvial suites south wales palaeosols fossil soils are abundant in the alluvial late silurian early devonian moor cliffs formation and rat island mudstone freshwater west formation of south dyfed south wales the palaeosols occur in thick mudstones deposited on floodplains under a seasonal semi arid climate and represent vertisol type soils simple single profiles are rare and most of the mudstone intervals exhibit complex overprinted profiles however a major difference exists between the palaeo vertisols in each of the two units studied the moor cliffs formation contains thick floodplain intervals with evidence of frequent erosion and reactivation of earlier soil horizons the associated coarser channel deposits mainly represent ephemeral streams the alluvial system was unstable flashy and prone to extensive stripping of stored floodplain sediment arroyos unstable ephemeral stream channels probably developed during this interval evidence for any marine influence on soil development is missing and previous speculations that the formation may represent deposition in an upper intertidal or supratidal system are not supported the rat island mudstone represents a complete contrast in that there was little or no stripping of floodplain sediments the channel deposits are typically of the fining upwards type representing more stable low sinuosity channels and with ephemeral stream floods by integrating the palaeosols a more detailed picture of the geomorphic history of these units can be formulated comparison with contemporary drainage basins indicates that a change in climate was a possible cause for the differences between the two units less frequent and more severe storms occurring during the deposition of the rat island mudstone

the hydrogen and oxygen isotope geochemistry of pedogenic clay minerals principles and theoretical background abstract the 18 o 16 o and d h ratios of the structural oxygen and hydrogen of naturally occurring clay minerals carry information about the conditions under which the minerals formed clays generally form in isotopic equilibrium with the environment and hence have isotopic compositions that reflect the temperature of formation and the 18 o 16 o and d h ratios of water in the micro environment the isotopic signature of water in the weathering environment is a reflection of the climate once formed clays are resistant to isotopic alteration under surface and near surface conditions except when they undergo subsequent mineralogical alteration in some instances this alteration may be subtle as in the case of conversion of kaolinite with a high degree of crystalline order as measured by the hinckley index to kaolinite of low crystalline order in a pedogenic profile isotopic studies of pedogenic clays may be expected to yield more information about pedogenesis and paleoclimate when both 18 o 16 o and d h ratios of the clays are measured however few studies have incorporated the use of the two isotope ratios

permian paleoclimate data from fluid inclusions in halite abstract this study has yielded surface water paleotemperatures from primary fluid inclusions in mid permian nippewalla group halite from western kansas a cooling nucleation method is used to generate vapor bubbles in originally all liquid primary inclusions then surface water paleotemperatures are obtained by measuring temperatures of homogenization to liquid homogenization temperatures ranged from 21 c to 50 c and are consistent along individual fluid inclusion assemblages indicating that the fluid inclusions have not been altered by thermal reequilibration homogenization temperatures show a range of up to 26 c from base to top of individual cloudy chevron growth bands petrographic and fluid inclusion evidence indicate that no significant pressure correction is needed for the homogenization temperature data we interpret these homogenization temperatures to represent shallow surface water paleotemperatures the range in temperatures from base to top of single chevron bands may reflect daily temperatures variations these permian surface water temperatures fall within the same range as some modern evaporative surface waters suggesting that this permian environment may have been relatively similar to its modern counterparts shallow surface water temperatures in evaporative settings correspond closely to local air temperatures therefore the permian surface water temperatures determined in this study may be considered proxies for local permian air temperatures

quantitative paleoenvironmental and paleoclimatic reconstruction using paleosols abstract paleosols fossil soils are preserved throughout the geologic record in depositional settings ranging from alluvial systems to between basalt flows until recently paleosols were studied using primarily qualitative methods in recent years paleopedology has shifted from a largely qualitative field based on comparisons with modern analogues to an increasingly quantitative endeavor some of this change has been a result of applying existing techniques to new materials but many of the innovations have been the result of applying new techniques to new materials including thermodynamic modeling of soil formation isotope geochemistry and applications of empirical relationships derived from modern soils a variety of semi quantitative and quantitative tools has been developed to examine past weathering and pedogenesis and to reconstruct both paleoenvironmental and paleoclimatic conditions at the time that the paleosols formed though it is often not possible to achieve the same temporal resolution as with marine records for paleoclimatic reconstructions proxies based on paleosols are potentially a much more direct means of making paleoclimatic reconstructions because soils form at the earth s surface in direct contact with the atmospheric and climatic conditions at the time of their formation paleoclimatic and environmental properties that may be reconstructed using the new proxies include provenance weathering intensity mean annual precipitation and temperature during pedogenesis nutrient fluxes into and out of the paleosols the atmospheric composition of important gases including co2 and o2 the moisture balance during pedogenesis the soil gas composition reconstructed vegetative covering and paleo altitude

geometry of ionic arrangements and magnetic interactions in ordered ferri ilmenite solid solutions and its effect on low t magnetic behavior 1 the magnetic properties of metastable chemically ordered ilmenite rich fe2o3 fetio3 solid solutions in the temperature range 500 0 k represent a complex amalgam of the incompatible properties of the end members while hematite is controlled by adjacent layer antiferromagnetic interactions ilmenite is controlled by double layer antiferromagnetic interactions the complex geometry of the exchange coupled ions is visualized and tentative explanations of property changes with temperature are provided by schematic 2 d ionic images along a common 1 1 2 0 plane showing the exchange interactions in the end members and in ilm 90 80 and 70 solid solutions accompanied by parallel temperature and frequency dependent susceptibility diagrams to provide a larger scale visualization of the extent of exchange clusters and networks 3 d images of ilm 95 90 85 80 75 and 70 containing 2592 atomic positions were also constructed both types of images together provide a conceptual overview of the physical mechanisms governing this complex solid solution system and its low temperature magnetic behavior even though the geometric approach does not in itself provide a quantitative model of physical properties it is an indispensable prerequisite for designing realistic quantitative models judging their validity and interpreting model results it also supplies information on the distributions numbers and orientations of magnetic exchange interactions which can become guidelines for more sophisticated calculations

early archean foredeep sedimentation related to crustal shortening a reinterpretation of the barberton sequence southern africa abstract the upper dominantly terrigenous sedimentary successions of the early archean barberton sequence kaapvaal province record an evolution similar to that of phanerozoic foredeeps and may represent the oldest known foredeep sequence rather than a passive continental margin sequence as previously proposed pre foredeep ocean crust the 3 5 ga old onverwacht group consists of bimodal volcanics with intercalated shallow water sediments gravity modeling and boundary shear zones indicate that deformed onverwacht crust was obducted northward onto sialic continental crust immediately before during or after burial by the synorogenic terrigenous clastic fill foredeep basin deepening due to crustal loading from the south is recorded by basinal iron formation chert and mudstone of the basal fig tree group which accumulated paraconformably on the onverwacht overlying sediments of the fig tree group consist of 2 km of submarine fan greywackes and mudstones shoaling of the basin is indicated by the transition to the overlying braided alluvial and shallow marine sediments of the ca 3 3 ga old moodies group 3 km thick changing ree patterns and relative abundances of ni cr sr th and ur in the sediments of the fig tree and moodies groups indicate a significant ultramafic mafic volcanic component diluted upward in the stratigraphic sequence by an increasing granitic contribution a similar trend is reflected in sandstone petrography in which the ratio of extrusive to intrusive rock fragments decreases upwards in the fig tree group whereas the moodies group sediments are enriched in quartz and potassium feldspar a persistent chert component in both units suggests that the tectonic setting of the basin is analogous to that of phanerozoic recycled orogens the distribution of facies in the fig tree and moodies groups and paleocurrent petrographic and geochemical data indicate progressive unroofing of a southerly source terrane consisting of the onverwacht volcanics and intercalated sediments and the 3 5 3 2 ga old ancient gneiss complex agc in addition older components of the fig tree group were recycled into overlying stratigraphie units the agc consists of mantle derived 3 5 ga old bimodal metavolcanics and metasediments a tonalite gneiss batholith metabasite dikes and meta anorthosites its structures record progressive northwestward uplift beginning around 3 4 ga ago intense homogeneous ductile strains were overprinted by northwest verging major folds rotated by large scale northwestward simple shear followed by imbricate faulting and pseudotachylite formation by 3 3 ga ago the fig tree and moodies groups had also shortened with similar kinematics to those of the agc by partly syndepositional folding and volume loss during the formation of transecting cleavage further folding and slide formation followed during subsolidus diapiric rise of the initially tabular kaap valley tonalite by 3 2 ga and emplacement of trondhjemite plutons from 3 3 to 3 0 ga ago

clay mineral assemblages and analcime formation in a palaeogene fluvial lacustrine sequence maiz gordo formation palaeogen from northwestern argentina abstract the palaeogene maiz gordo formation is one of the main lacustrine events recorded in northwestern argentina it consists of sandstone mudstone and limestone beds 200 m thick deposited in a brackish alkaline lake and braided alluvial systems the maiz gordo lake evolved mainly as a closed system with brief periods as an open one x ray diffraction xrd and scanning electron microscopy sem were used to study samples from seven sites corresponding respectively to proximal intermediate and transitional positions of the fluvial environment and marginal and inner lake environment focusing on the clay mineralogy and analcime formation the basinward zonation of diagenetic minerals identified in the maiz gordo lake was mordenite analcime k feldspar although not a typical zonation of saline alkaline lakes it does indicate an increase in salinity and alkalinity towards the centre in proximal fluvial settings smectite predominates at the base of the sequence with scarce kaolinite towards the top a striking increase in kaolinite content suggests a change from a relatively arid climate with alternating humid and dry seasons towards a warm and humid climate kaolinite content clearly decreases in a basinward direction such a variation is attributable to changes in hydro geochemistry denoting the progressive influence of the brackish and alkaline lake water on interstitial pores sem images of intermediate fluvial samples reveal authigenesis of illite at the expense of kaolinite booklets in littoral and inner lake settings the clay fraction is composed of muscovite sometimes with subordinate smectite analcime occurs in variable amounts in all sedimentary facies in rock pores or filling veins it forms subhedral square to hexagonal or anhedral rounded crystals denoting that they coarsened at low to moderate degrees of supersaturation although the mordenite identified in a fluvial level would have been the precursor of analcime in the maiz gordo basin no textural evidence of analcime formation through replacement of mordenite or other precursor zeolite was found hence it is more probable that analcime formation took place by direct authigenic precipitation or through the reaction between interstitial brines and clay minerals or plagioclase

inclusion of the weathering of volcanic rocks in the geocarbsulf model the carbon cycle model geocarbsulf is extended by dividing the weathering of silicates into volcanic and non volcanic rocks the proportion of volcanic weathering is calculated as a function of time from the oceanic record of 87sr 86sr the volcanic proportion is then used to modify the equations for calculating atmospheric co2 by the addition of a new non dimensional volcanic weathering factor the effect of uplift and physical erosion on weathering is also modified by using only the distribution over time of the abundance of sandstones and shales and not sr isotopic data that had been used previously results indicate moderate change from geocarbsulf in the distribution of atmospheric co2 over phanerozoic time this includes an increased minimum in co2 during the late ordovician in agreement with the presence of a continental glaciation at that time and a shift of maximum mesozoic values from the jurassic to the early cretaceous

a review of the broad pattern of jurassic sea level changes and their possible causes in the light of current knowledge abstract an assessment is made of the current state of research into jurassic sea level changes based on new insights into depositional patterns in relation to these changes and new stratigraphic information from several widely separated regions across the world the bearing of this information on alternative models respectively involving sea level rise interrupted by stillstands or falls is then evaluated the gross pattern appears to be one of more or less gradual rise of sea level through the period interrupted by episodes of comparative stillstand rather than eustatic fall and several episodes of significant regression are shown to be the result of regional tectonics major episodes of eustatic rise took place in the early hettangian early sinemurian early pliensbachian early toarcian early and late bajocian middle callovian and late oxfordian to kimmeridgian a significant episode of rapid and very extensive regression possibly global took place at the end of the triassic but other regressive episodes in the late aalenian bathonian late oxfordian kimmeridgian and tithonian are clearly only regional in extent there is no evidence for glacioeustasy and most if not all of the regional or global changes recognised can readily be related to plate tectonics the events at the triassic jurassic boundary seem to be the result of mantle plume activity centred on the central atlantic region

paleoenvironmental and paleoclimatic reconstruction of cretaceous aptian cenomanian terrestrial formations of texas and oklahoma using phyllosilicates abstract clay mineralogy chemistry and stable oxygen and hydrogen isotope compositions of 11 phyllosilicate samples from cretaceous paleosol profiles were determined in order to evaluate early to late cretaceous paleoenvironments and paleoclimates around north central texas and southern oklahoma samples consist of mineralogical mixtures of illite smectite and kaolinite samples from the albian antlers formation in southern oklahoma and the cenomanian woodbine formation are dominated by kaolinite while the remaining samples are dominated by smectite and illite major element compositions of paleosol matrix materials are used to calculate calmag weathering values that range from 31 to 84 and correspond to cretaceous paleoprecipitation estimates ranging from 270 to 1490 mm yr paleosol phyllosilicate hydrogen and oxygen stable isotope values range from 50 to 67 to 18 5 to 21 7 respectively and in conjunction with their respective mineral and chemical compositions correspond to in situ soil crystallization temperatures ranging from 26 3 c to 31 c paleoprecipitation trends exhibit two marked increases in precipitation from the early to late cretaceous in the albian antlers formation and cenomanian woodbine formation stratigraphic intervals with phyllosilicates that yield cooler temperature estimates coincide with stratigraphic intervals with markedly higher precipitation estimates based on calmag values importantly cool high precipitation intervals correlate with periods of extensive shallow seas upon the north american craton comparison of cretaceous temperature precipitation and meteoric water estimates to modern analogs supports the presence of climates similar to modern tropical climates during the cretaceous at subtropical or temperate paleolatitudes in what is now texas and oklahoma consistent with general circulation models and energy balance models suggesting a pervading cretaceous greenhouse

continental humid and arid zones during the jurassic and cretaceous abstract the global distribution of climatically significant criteria is surveyed for six successive time intervals hettangian toarcian aalenian callovian oxfordian tithonian berriasian barremian aptian cenomanian and turonian maastrichtian the criteria are primarily mineralogical evaporites coals bauxites ironstones and kaolinite but include sedimentological and palaeontological aspects of facies e g aeolian sands fossil ferns and xerophytes fresh water invertebrates in early and mid jurassic times an arid zone can be distinguished in low to mid latitudes in western pangaea with humid zones elsewhere in the late jurassic this arid zone spread northwards to embrace much of southern eurasia there followed in the early cretaceous a sharp reversal to more humid conditions over a large area extending from the eastern margin of north america to the middle east a major consequence of which was the widespread replacement of carbonates by coarse siliciclastic facies by late cretaceous times humid conditions were well established also in north america and the south atlantic margins and the tropical arid zone had contracted to a minimum the 87 sr 86 sr ratio of marine carbonates provides an independent monitor of continental runoff which is related to a area and b extent of aridity changes in the ratio confirm that taking sea level stand into account the late cretaceous was appreciably more humid than the late jurassic these climatic changes are related primarily to the progressive breakup of pangaea in the late jurassic and cretaceous which together with sea level rise in the mid to late cretaceous caused a significant increase in maritime influence this implies that monsoonal winds probably had a major role in promoting higher precipitation rates a puzzle remains as to why there was a spread of aridity in the late jurassic finally some implications for terrestrial plant evolution are noted

application of ostracoda and charophyta from the late jurassic to early cretaceous tendaguru formation at tendaguru tanzania east africa biostratigraphy palaeobiogeography and palaeoecology abstract revisitation of the famous late jurassic early cretaceous dinosaur locality of tendaguru by a german tanzanian expedition in summer 2000 resulted in a new standard section micropalaeontologic samples from this section yielded a marine and nonmarine partially mixed ostracod fauna consisting of 40 taxa and some charophyte gyrogonites and utriculi a few marine taxa provided biostratigraphic information although comparable faunas from the west indian madagascan east african faunal province are stratigraphically older middle late jurassic fully marine and strongly endemic an middle oxfordian age is suggested for the lower part of the tendaguru formation nodosoclavatoroid utriculi charophyta suggest that the jurassic cretaceous boundary may be located lower in the section than supposed previously i e in the trigonia smeei member rather than in the upper saurian member in biogeographical terms the marine ostracod fauna is relatively endemic and has most similarities with that known from eastern tanzania only a few faunal links to madagascar northwest india and somalia exist and there are no links to south africa ostracods and charophytes also provided palaeoecological data for specific horizons in the lower part of the middle saurian member a regression is documented while the nonmarine late jurassic early cretaceous ostracods of tendaguru are not applicable to biostratigraphy so far they are important because the nonmarine setting is unique in this area of the tethys

influence of mantle flow on the drainage of eastern australia since the jurassic period recent studies of the past eastern australian landscape from present day longitudinal river profiles and from mantle flow models suggest that the interaction of plate motion with mantle convection accounts for the two phases of large scale uplift of the region since 120 ma we coupled the dynamic topography predicted from one of these mantle flow models to a surface process model to study the evolution of the eastern australian landscape since the jurassic period we varied the rainfall regime erodibility sea level variations dynamic topography magnitude and elastic thickness across a series of experiments the approach accounts for erosion and sedimentation and simulates catchment dynamics despite the relative simplicity of our model the results provide insights on the fundamental links between dynamic topography and continental scale drainage evolution based on temporal and spatial changes in longitudinal river profiles as well as erosion and deposition maps we show that the motion of the australian plate over the convecting mantle has resulted in significant reorganization of the eastern australian drainage the model predicts that the murray river drained eastward between 150 and 120 ma and switched to westward draining due to the tilting of the australian plate from 120 ma first order comparisons of eight modeled river profiles and of the catchment shape of modeled murray darling basin are in agreement with present day observations the predicted denudation of the eastern highlands is compatible with thermochronology data and sedimentation rates along the southern australian margin are consistent with cumulative sediment thickness

stable isotope records of hydrologic change and paleotemperature from smectite in cenozoic western north america abstract the oxygen and hydrogen isotopic composition of soil water 18ow and dw hereafter reflect the history of water through processes such as source evaporation precipitation and vapor recycling temperature humidity evaporation and post condensation processes can affect 18ow and dw as such isotope proxy records are often limited in their ability to constrain paleoclimate paleoecology or paleoelevation without independently corroborating data smectite preserves both the hydrogen and oxygen isotope signature of parent water and therefore provides critical insight into meteoric water line relationships and paleotemperature here we use in situ pedogenic smectite 18o and d records to characterize the evolution of the hydrologic cycle in cenozoic western north america we incorporate 192 samples 119 of which are previously unpublished from 11 cenozoic basins representing a range of environments in the basin and range rocky mountains and great plains our results indicate that the processes controlling smectite isotopic compositions vary both regionally and temporally in some localities such as oligocene to pleistocene western nebraska change in temperature is the primary control on smectite isotopic composition in other basins such as in miocene trapper creek id isotope values lie along the meteoric water line suggesting change in meteoric water composition is responsible for the variation in most basins especially those in the neogene basin and range smectite line slope suggests either evaporation of previously meteoric water or a combination of change in paleotemperature and meteoric water composition smectite geothermometry suggests mineral formation temperatures of 30 40 c in the middle miocene in the rocky mountains great plains and basin and range and a decrease of 10 15 c since the middle miocene climatic optimum consistent with clumped isotope and paleofloral temperature estimates

distal alluvial fan sediments from the upper jurassic of portugal controls on their cyclicity and channel formation the lusitanian basin of west central portugai is an iberian atlantic margin basin during a late jurassic rifting event a series of alluvial fans distributed coarse basement derived clastics southeastward from the western margin of the basin the distal part of this sequence which is about 140 m thick consists of heterolithic massive sandstone and massive mudrock facies arranged in crude fining upwards cycles 1 15 m thick these form discrete packets of sediment in a strongly aggrada tional sequence and are interpreted as the products of sheetflooding as the active area of sedimenta tion on the fan surface switched channelized flow was not necessarily an early feature of cycle development considerable fluctuations in discharge occurred and were probably related to climatic factors large quantities of tractional and suspended sediment were transported at high stages and were rapidly deposited as flows waned caliche soil profiles indicate a seasonal semi and climate however other features such as widespread soft sediment deformation the lack of desiccation structures and the absence of evaporites suggests that areas of active sedimentation often remained wet three fining upward megacycles are distinguished these indicate rapid advance of fan toes triggered by tectonic activity followed by gradual retreat

geocarbsulf a combined model for phanerozoic atmospheric o2 and co2 abstract a model for the combined long term cycles of carbon and sulfur has been constructed which combines all the factors modifying weathering and degassing of the geocarb iii model berner r a kothavala z 2001 geocarb iii a revised model of atmospheric co2 over phanerozoic time am j sci 301 182 204 for co2 with rapid recycling and oxygen dependent carbon and sulfur isotope fractionation of an isotope mass balance model for o2 berner r a 2001 modeling atmospheric o2 over phanerozoic time geochim cosmochim acta 65 685 694 new isotopic data for both carbon and sulfur are used and new feedbacks are created by combining the models sensitivity analysis is done by determining 1 the effect on weathering rates of using rapid recycling rapid recycling treats carbon and sulfur weathering in terms of young rapidly weathering rocks and older more slowly weathering rocks 2 the effect on o2 of using different initial starting conditions 3 the effect on o2 of using different data for carbon isotope fractionation during photosynthesis and alternative values of oceanic 13c for the past 200 million years 4 the effect on sulfur isotope fractionation and on o2 of varying the size of o2 feedback during sedimentary pyrite formation 5 the effect on o2 of varying the dependence of organic matter and pyrite weathering on tectonic uplift plus erosion and the degree of exposure of coastal lands by sea level change 6 the effect on co2 of adding the variability of volcanic rock weathering over time berner r a 2006 inclusion of the weathering of volcanic rocks in the geocarbsulf model am j sci 306 in press results show a similar trend of atmospheric co2 over the phanerozoic to the results of geocarb iii but with some differences during the early paleozoic and for variable volcanic rock weathering lower co2 values during the mesozoic atmospheric oxygen shows a major broad late paleozoic peak with a maximum value of about 30 o2 in the permian a secondary less broad peak centered near the silurian devonian boundary variation between 15 and 20 o2 during the cambrian and ordovician a very sharp drop from 30 to 15 o2 at the permo triassic boundary and a more or less continuous rise in o2 from the late triassic to the present

pedogenic carbonates as a proxy for palaeo co2 in the palaeozoic atmosphere abstract according to a model by cerling cerling t e 1991 carbon dioxide in the paleoatmosphere evidence from cenozoic and mesozoic paleosols am j sci 291 377 400 cerling t e 1999 stable carbon isotopes in palaeosol carbonates in thiry m simon coincon r eds palaeoweathering palaeosurfaces and related continental deposits vol 27 of spec publ int assoc sediment pp 43 60 the carbon isotope composition of calcretes should depend on the soil type and the co 2 concentration in the atmosphere we have tested cerling s model by investigating 14 palaeozoic sections with soil profiles a large number of carbonate types of different genetic origin exist in the localities examined comparing the palaeozoic samples with recent and subrecent calcretes it can be demonstrated that anhedral cryptocrystalline 2 concentration

paleosols as indicators of paleoenvironment and paleoclimate paleosols are ancient soils that have been incorporated into the geological record soils form in response to interactions among the lithosphere hydrosphere biosphere and atmosphere so paleosols potentially record physical biological and chemical information about past conditions near earth s surface as a result paleosols are an important resource for terrestrial environmental and climatic reconstructions long standing paleosol research topics include morphology classification and clay mineralogy all of which provide information about pedogenic processes and local paleoenvironments paleosols are also used to infer processes involved in the development of stratigraphic architecture and basin evolution recent paleosol research has introduced semiquantitative and quantitative measures for environmental and chronometric reconstructions that provide insight into major regional to global changes in temperature precipitation and atmospheric pco2 these new proxies focus on morphological and chemi

paleoclimate and the global distribution of paleosols a theoretical model is developed for the relationship between paleoclimate and paleosols for the time interval following the widespread appearance of vascular land plants the model defines four paleoclimatic zones 1 a wet equatorial zone primarily characterized by oxisols and secondarily by argillisols and histosols 2 a subtropical dry zone containing calcisols and less commonly gypsisols and vertisols 3 a moist mid latitude zone with argillisols spodosols gleysols and histosols and 4 a polar zone featuring protosols and gleysols the model is general in nature and its application to the geologic past will be affected by variability through time in paleogeography and paleoclimatic parameters

biological marker compounds as indicators of the depositions history of the maoming oil shale abstract the eocene maoming oil shale from guangdong province occurs as a laterally uniform stratigraphic section typically 20 25 m thick from which the aliphatic hydrocarbon constituents of six representative samples were investigated using gc and c gc ms the sediments evaluated included the basal lignite a vitrinite lens from the overlying claystone and four intervals from the massive oil shale bed as expected the lignite and vitrinite differ markedly from the oil shales the lignite is dominated by bacterial hopanoids and components of higher plant origin including c 29 steroids and triterpenoids such as oleanenes visually the oil shale samples show corroded and degraded phytoclasts spores wispy particles of fluorescent organic material attributable to dinoflagellates and especially in the uppermost sample colonial algal bodies the distributions of biological markers in the oil shales show many features in common notably a dominance of dinoflagellate derived 4 methylsteroids and a significant proportion of higher plant derived n alkanes with marked odd over even carbon number predominance overall they exhibit several features that resemble characteristics of the messel shale the hydrocarbons of the lowest shale horizon suggest that there may have been a gradual transition between deposition of the original peat and the subsequent oil shales the aliphatic hydrocarbons of the uppermost shale are dominated by a number of c 31 and c 33 botryococcane homologues and other unusual branched alkanes possibly derived from green algae all of the samples are immature overall molecular and microscopic examination of the stratigraphic succession of the maoming oil shale suggests a shallow lacustrine environment within which peats were deposited this lake subsequently deepened to support abundant algal populations especially dinoflagellates culminating in a dominance of botryococcoid algae

goethite calcite and organic matter from permian and triassic soils carbon isotopes and co2 concentrations abstract pedogenic goethites in each of two early permian paleosols appear to record mixing of two isotopically distinct co2 components atmospheric co2 and co2 from in situ oxidation of organic matter the 13c values measured for the fe co3 oh component in solid solution in these permian goethites are 13 5 for the lower leonardian 283 ma bp paleosol mcgoeth and 13 9 for the upper leonardian 270 ma bp paleosol sap these goethites contain the most 13c rich fe co3 oh measured to date for pedogenic goethites crystallized in soils exhibiting mixing of the two aforementioned co2 components 13c measured for 43 organic matter samples in the lower leonardian waggoner ranch fm has an average value of 20 3 1 1 1s the average value yields a calculated early permian atmospheric p co 2 value of about 1 pal but the scatter in the measured 13c values of organic matter permits a calculated maximum p co 2 of 11 pal pal present atmospheric level measured values of the mole fraction of fe co3 oh in mcgoeth and sap correspond to soil co2 concentrations in the early permian paleosol profiles of 54 000 and 50 000 ppmv respectively such high soil co2 concentrations are similar to modern soils in warm wet environments the average 13c values of pedogenic calcite from 9 paleosol profiles stratigraphically associated with mcgoeth waggoner ranch fm range from 6 5 to 4 4 with a mean 13c value for all profiles of 5 4 thus the value of 13c between the pedogenic calcite data set and mcgoeth is 8 1 0 9 which is in reasonable accord with the value of 7 7 expected if atmospheric p co 2 and organic matter 13c values were the same for both paleosol types furthermore the atmospheric p co 2 calculated for the early permian from the average measured carbon isotopic compositions of the paleosol calcite and organic matter is also analytically indistinguishable from 1 pal with a maximum calculated atmospheric p co 2 permitted by one standard deviation of the organic matter 13c value of 5 pal if however measured average 13c values of the plant organic matter are more positive than the original soil organic matter as a result of diagenetic loss of 13c depleted labile organic compounds calculated permian atmospheric p co 2 using these 13c enriched organic values would underestimate the actual atmospheric p co 2 using either goethite or calcite this is the first stratigraphically constrained intrabasinal study to compare ancient atmospheric co2 concentrations calculated from pedogenic goethite and calcite these results demonstrate that the two different proxies record the same information about atmospheric co2 the fe co3 oh component in pedogenic goethite from a triassic paleosol in utah is significantly enriched in 13c relative to fe co3 oh in goethites from soils in which there are mixtures of two isotopic co2 components field relationships and the 13c value 1 9 of the triassic goethite indicate that this ancient paleosol profile experienced mixing of three isotopically distinct co2 components at the time of goethite crystallization the three components were probably atmospheric co2 co2 from in situ oxidation of organic matter and co2 from in situ dissolution of preexisting calcite although mixing of three isotopically distinct co2 components as recorded by fe co3 oh in goethite has been described in modern soil this is the first example from a documented paleosol its preservation affirms the need for careful case by case assessment of ancient paleosols to establish that goethite in any particular soil is likely to be a valid proxy of atmospheric p co 2

mesozoic climates general circulation models and the rock record abstract general circulation models gcms use the laws of physics and an understanding of past geography to simulate climatic responses they are objective in character however they tend to require powerful computers to handle vast numbers of calculations nevertheless it is now possible to compare results from different gcms for a range of times and over a wide range of parameterisations for the past present and future e g in terms of predictions of surface air temperature surface moisture precipitation etc gcms are currently producing simulated climate predictions for the mesozoic which compare favourably with the distributions of climatically sensitive facies e g coals evaporites and palaeosols they can be used effectively in the prediction of oceanic upwelling sites and the distribution of petroleum source rocks and phosphorites models also produce evaluations of other parameters that do not leave a geological record e g cloud cover snow cover and equivocal phenomena such as storminess parameterisation of sub grid scale processes is the main weakness in gcms e g land surfaces convection cloud behaviour and model output for continental interiors is still too cold in winter by comparison with palaeontological data the sedimentary and palaeontological record provides an important way that gcms may themselves be evaluated and this is important because the same gcms are being used currently to predict possible changes in future climate the mesozoic earth was by comparison with the present an alien world as we illustrate here by reference to late triassic late jurassic and late cretaceous simulations dense forests grew close to both poles but experienced months long daylight in warm summers and months long darkness in cold snowy winters ocean depths were warm 8 c or more to the ocean floor and reefs with corals grew 10 of latitude further north and south than at the present time the whole earth was warmer than now by 6 c or more giving more atmospheric humidity and a greatly enhanced hydrological cycle much of the rainfall was predominantly convective in character often focused over the oceans and leaving major desert expanses on the continental areas polar ice sheets are unlikely to have been present because of the high summer temperatures achieved the model indicates extensive sea ice in the nearly enclosed arctic seaway through a large portion of the year during the late cretaceous and the possibility of sea ice in adjacent parts of the midwest seaway over north america the triassic world was a predominantly warm world the model output for evaporation and precipitation conforming well with the known distributions of evaporites calcretes and other climatically sensitive facies for that time the message from the geological record is clear through the phanerozoic earth s climate has changed significantly both on a variety of time scales and over a range of climatic states usually baldly referred to as greenhouse and icehouse although these terms disguise more subtle states between these extremes any notion that the climate can remain constant for the convenience of one species of anthropoid is a delusion although the recent rate of climatic change is exceptional

isomerisation rearrangement and aromatisation of steroids in distinguishing early stages of diagenesis abstract the distributions of proposed reactants and products of stages of early diagenesis of steroid hydrocarbons have been studied by gc and gc ms in a variety of downhole sequences of dsdp cores of various ages which include the san miguel gap walvis ridge gulf of california and falkland plateau the compounds comprise aliphatic and aromatic hydrocarbons such as diasterenes monoaromatic anthrasteroids and spirosterenes from the study of the progress of proposed reactions and of presumed product reactant relationships a pattern emerges that extractable lipid distributions can provide a means of distinguishing levels of early diagenesis which cannot be recognised readily from other methods a number of diagentic trends are evident such as progressive isomerisation at c 20 in diasterenes which occurs at different relative rates and temperature ranges in sediment sequences with different heat fluxes such studies allow investigation of the changes in biological marker compounds in the part of the continuum between changes during sediment deposition and the advent of catagenesis

the origin and fate of 4 methyl steroid hydrocarbons i diagenesis of 4 methyl sterenes abstract treatment of 4 methylcholest 4 ene under mild acid conditions at low temperatures gives chemical evidence for certain features seen in the distributions of sedimentary 4 methyl steroid hydrocarbons and further indicates that many low temperature diagenetic reactions of steroids are explicable in terms of acid catalysed rearrangements specifically the results provide i indirect evidence that the 4 ene skeleton is a key intermediate in the dehydration of 4 methyl stanols in sediments ii an explanation for the distribution of 4 methyl sterenes and a nor sterenes in the lacustrine messel shale eocene iii an explanation for the presence of 4 methyl steranes in relatively immature sedimentary rocks despite the precursor stanols having the 4 methyl configuration with increasing maturity in the paris basin shales lower toarcian the less stable 4 methyl steranes decrease gradually in abundance relative to their 4 methyl counterparts at a rate fairly similar to the change in pristane stereochemistry