sedimentary pyrite formation an update sedimentary pyrite formation during early diagenesis is a major process for controlling the oxygen level of the atmosphere and the sulfate concentration in seawater over geologic time the amount of pyrite that may form in a sediment is limited by the rates of supply of decomposable organic matter dissolved sulfate and reactive detrital iron minerals organic matter appears to be the major control on pyrite formation in normal non euxinic terrigenous marine sediments where dissolved sulfate and iron minerals are abundant by contrast pyrite formation in non marine freshwater sediments is severely limited by low concentrations of sulfate and this characteristic can be used to distinguish ancient organic rich fresh water shales from marine shales under marine euxinic conditions sufficient h2s is produced that the dominant control on pyrite formation is the availability of reactive iron minerals calculations based on a sulfur isotope model indicate that over phanerozoic time the worldwide average organic carbon to pyrite sulfur ratio of sedimentary rocks has varied considerably high cs ratios during permo carboniferous time can be explained by a shift of major organic deposition from the oceans to the land which resulted in the formation of vast coal swamps at that time low cs ratios compared to today during the early paleozoic can be explained in terms of a greater abundance of euxinic basins combined with deposition of a more reactive type of organic matter in the remaining oxygenated portions of the ocean the latter could have been due to lower oceanic oxygen levels and or a lack of transportation of refractory terrestrial organic matter to the marine environment due to the absence of vascular land plants at that time

burial of organic carbon and pyrite sulfur in sediments over phanerozoic time a new theory in present day marine sediments almost all of which are deposited in normal oxygenated seawater rates of burial of organic carbon c and pyrite sulfur s correlate positively and bear a constant ratio to one another c s 3 on a weight basis by contrast calculations based on the isotopic model of garrels and lerman 1981 indicate that at various times during the phanerozoic the worldwide burial ratio must have been considerably different than the present day value this ratio change is caused by the requirement that increases in the worldwide mass of organic carbon must be accompanied by equivalent decreases in the mass of sedimentary pyrite sulfur in order to maintain a roughly constant level of o2 in the atmosphere such apparently contradictory behavior can be explained if the locus of major organic carbon burial has shifted over time from normal marine environments as at present to non marine freshwater or to euxinic environments in the geologic past a shift to predominantly freshwater burial can help explain predicted high c s ratios in permo carboniferous sediments and a shift to euxinic environments can help explain predicted low c s ratios during the early paleozoic it is demonstrated that the three environments today exhibit distinguishably different average c s ratios

sedimentological characteristics heavy metal distribution and magnetic properties in subtidal sediments ria de pontevedra nw spain the rias of nw spain are coastal ecosystems of high biological productivity and great economic importance they are intensively exploited by man for fish and shellfish there are a number of important centres of population and industrial activity along their margins which serve as sources of contamination in this context it is desirable to achieve the best possible understanding of the physico chemical processes that control spatial and temporal variations in the geochemical mineralogical and sedimentological characteristics of near surface sediments in the ria de pontevedra and in particular the distribution and mobility of heavy metal contaminants thus adequate environmental planning can be achieved for this site and understanding gained for comparable contexts core samples were examined from the inner middle and outer parts of the ria grain size distributions reflect the presence of two main populations one dominated by silt and clay derived mainly from terrestrial sources and the other by fine sand to coarse silt which is derived mainly from continental shelf and ria mouth sources mineralogical analysis shows an abundance of terrestrial intensive weathering products near the ria head a dominance of shelf derived sediment towards the mouth and the presence of several diagenetic minerals whose nature varies with location within the ria in the inner ria the near surface sediments are slightly enriched in pb cu and zn from anthropogenic sources these sediments are fine grained and have a high organic content hence they have a higher potential to sorb contaminants than the coarser grained less organic rich sediments of the mid and outer ria the estimated sedimentation rates for the fine grained organic rich sediments from the inner part of the ria are about 1 mm year 1 the dominant authigenic minerals in the inner ria are iron sulphides whereas in the mid and outer ria iron silicates and oxyhydroxides are more important these differences in authigenic iron mineralogy are clearly reflected by the magnetic properties of the sediments

sea level anomalies in the tropical atlantic from geosat data assimilated in a linear model 1986 1988 dong track sea level anomalies derived from geosat altimeter data from november 1986 to november 1988 are assimilated by kalman filtering into a wind forced second baroclinic vertical mode linear model of the tropical atlantic ocean to save computer time the filter is degraded mostly by king the error covariance matrix of the estimate once the filter has reached its asymptotic behavior geosat altimeter data have been processed using improved corrections the sea surface height variability signal is extracted using the classical along track technique relative to a complete reference cycle and using only tracks longer than 2200 km this processing has preserved oceanic signals both on large scales above 1000 km and on the mesoscale around 200 km sea level anomalies predicted at principe island are close to in situ tide gage data though some differences can be partly related to tidal or orbit error corrections oceanographic signals are analyzed from two different sets of fields one issued from anisotropic space time objective analysis of geosat data and the other from the model assimilation the latter appears as an interesting method to extract low frequency and propagating signals along the equator eastward propagating features are consistent with kelvin waves correlated with mnal wind stress anomalies upwelling in the gulf of guinea is 1 month earlier in 1987 than in 1988 after elimination of the annual and semiannual signals by harmonic analysis the residual signal over the whole tropical basin decomposed into complex empirical orthogonal functions is found dominated by variations between the 2 years equatorial and tropical signals being anticorrelated

the effects of wind forcing and background mean currents on the latitudinal structure of equatorial rossby waves abstract the latitudinal structure of annual equatorial rossby waves in the tropical pacific ocean based on sea surface height ssh and thermocline depth observations is equatorially asymmetric which differs from the structure of the linear waves of classical theory that are often presumed to dominate the variability the nature of this asymmetry is such that the northern ssh maximum along 5 5 n is roughly 2 times that of the southern maximum along 6 5 s in addition the observed westward phase speeds are roughly 0 5 times the predicted speed of 90 cm s 1 and are also asymmetric with the northern phase speeds about 25 faster than the southern phase speeds one hypothesized mechanism for the observed annual equatorial rossby wave amplitude asymmetry is modification of the meridional structure by the asymmetric meridional shears associated with the equatorial current system another hypothesis is the asymmetry of the annually varying wind forcing which is stronger north of the equator a reduced g

diagenetic magnetic enhancement of sapropels from the eastern mediterranean sea diagenetic dissolution of magnetic minerals has been widely observed in organic rich sediments from many environments organic rich sediments from the eastern mediterranean sea sapropels recovered during leg 160 of the ocean drilling program reveal a surprising catalogue of magnetic properties sapropels from all sites studied across the eastern mediterranean sea are strongly magnetic and the magnetization is directly proportional to the organic carbon content the magnetization of the sapropels is dominated by a low coercivity probably single domain magnetic mineral with an inverse magnetic fabric that exhibits a clear decay in magnetic properties when exposed to air during heating the magnetic particles irreversibly break down between 360 and 400 c the contrast between the magnetic properties of sapropels and surrounding sediments is marked with remanence intensities of sapropels often being more than three orders of magnitude higher than those of underlying sediments the contrast between the magnetic properties of sapropels and the surrounding sediments is apparently controlled by non steady state diagenesis sulphate reducing conditions dominated during sapropel deposition while overlying sediments were deposited under oxic conditions the mineral responsible for the magnetic properties of sapropels is most likely to have formed under sulphate reducing conditions that existed during times of sapropel formation attempts to identify this mineral have been unsuccessful but several lines of evidence point toward an unknown ferrimagnetic iron sulphide phase the influence of diagenesis on the magnetic properties of cyclically deposited eastern mediterranean sedimentary sequences suggests that magnetic parameters may be a useful proxy for diagenesis in these sediments

recent sedimentation and sedimentary budgets on the western iberian shelf abstract thus study is based on 31 box core samples collected mainly from the mud patches of the galician and north portuguese shelf each of these cores some decimetres in length have been described radiographied and sampled each centimetre for grain size analysis and measurement of the particulate organic carbon corg content 210pb excess profiles have been measured using gamma spectrometry which combined with the analysis of the vertical variations of the sedimentary facies have allowed estimates of sedimentation rates these rates were found to vary between 0 05 and 0 40 cm yr 1 considering the latitudinal variation of sedimentation rates around the 100m contour we note that the maximum rates occurred off the douro estuary in the southern sector and also near the galician rias to the north the organic content corg of sediments varied between 0 4 and 2 latitudinally corg showed a decrease from the south to the north these results coupled with the sedimentary map see dias gonzalez garcia diaz del rio 2001 have permitted us to establish the detrital mass budget and an inventory of corg burial

high resolution analysis of early diagenetic effects on magnetic minerals in post middle holocene continental shelf sediments from the korea strait 1 two studied sediment cores from the korea strait contain mud sequences 14 m and 32 62 m in thickness that were deposited during the last 6 000 years the sediments have uniform lithology and geochemical properties however marked down core changes in magnetic properties suggest that diagenesis has significantly impacted the magnetic properties an expanded view of early diagenetic reactions that affect magnetic mineral assemblages is evident in these rapidly deposited continental shelf sediments compared to deep sea sediments the studied sediments are divided into four descending intervals based on magnetic property variations interval 1 is least affected by diagenesis and has the highest concentrations of detrital magnetite and hematite and the lowest solid phase sulfur contents interval 2 is characterized by the presence of paramagnetic pyrite and sharply decreasing magnetite and hematite concentrations which suggest active reductive dissolution of detrital magnetic minerals interval 3 is marked by a progressive loss of hematite with depth and coincides with the minimum magnetite concentration interval 4 has an increasing down core enhancement of authigenic greigite which apparently formed at depths of 3 30 m below the sediment water interface due to arrested pyritization reactions these results indicate delays of thousands of years for acquisition of magnetizations carried by greigite which suggests that studies of geomagnetic field behavior from greigite bearing continental shelf sediments should be conducted with care also virtually complete destruction of detrital magnetic minerals at depth suggests that magnetic studies of rapidly deposited shelf sediments are unlikely to provide a meaningful signature associated with syn depositional environmental processes

a new proxy for bottom water ventilation in the eastern mediterranean based on diagenetically controlled magnetic properties of sapropel bearing sediments magnetic properties of eastern mediterranean sediments recovered during leg 160 of the ocean drilling program odp provide insight into non steady state diagenetic reactions associated with accumulation and degradation of organic matter in sapropels according to their magnetic properties sapropels can be classified as one of three types that correspond to increasingly anoxic conditions at the time of sapropel formation a combination of magnetic and geochemical data suggests a causal relationship that enables determination of the relative role of bottom water ventilation versus productivity in the resulting diagenetic stage reached for the three types of sapropels it appears that increased productivity is a prerequisite for sapropel formation but once organic matter is available in sufficient amounts variable efficiencies in bottom water ventilation are more important for modulating the diagenetic context in which different types of sapropels formed magnetic properties are more sensitive to variations in bottom water ventilation than to productivity and can be used to establish relative variations in bottom water ventilation both at and after periods of sapropel formation magnetic results and the distribution and type of sapropels at odp site 966 eratosthenes seamount between 2 3 and 4 0 ma suggest that bottom water ventilation was modulated by the orbital eccentricity component with ventilation being restricted during 400 kyr eccentricity maxima and enhanced during eccentricity minima enhanced ventilation during eccentricity minima as indicated by magnetic data is consistent with the occurrence of red intervals at site 966 and at other eastern mediterranean sites drilled during odp leg 160 and also with astronomically modulated variations in caco3 content found in mediterranean land sections this suggests that variations in bottom water ventilation modulated by 400 kyr eccentricity cycles operated at a basin wide scale

early diagenesis of magnetic minerals in marine transitional environments geochemical signatures of hydrodynamic forcing abstract the low field magnetic susceptibility of surficial sediments from the ria de pontevedra nw spain shows a characteristic hydrodynamically driven textural control where diamagnetic sandy bioclastic carbonates occur toward the coastline leaving the finer muddy sediments to be deposited in the central and deeper areas of the ria three gravity cores were collected from the inner core 1 middle core 2 and outer core 3 zones of the clayey rich central axis of the ria from which the magnetic properties geochemical characteristics and hydrodynamic regime of the uppermost 90 cm of the sediment record were reconstructed profiles have a distinctive pattern that is controlled by depth isothermal remanent magnetization irm acquisition curves facilitated the identification of three well defined zones with depth depending on their degree of magnetic saturation and thus of their dominant magnetic behaviour magnetite like goethite like and greigite like this zonation is interpreted as the result of mineralogical changes during early diagenesis the relative depths of each zone are mostly dependent on distance to the open sea with the magnetite like zones being thicker in the outermost part of the ria toward the inner part of the ria the three zones become shallower and thinner in the innermost areas only greigite like coercivities are observed good correlation between magnetic and geochemical parameters such as vs 2fe s or h cr vs c s demonstrates that magnetic property variations with depth are diagenetically controlled and that these parameters can be used as magnetic proxies for early diagenesis similar significant positive correlations were found between of the clay fraction and modelled wave heights and between other magnetic and hydrodynamic parameters providing magnetic evidence of cryptic wave climate forcing of the diagenetic pathway the combined analysis of the magnetic geochemical and hydrodynamic data ultimately indicates that the sediment distribution and subsequent diagenetic pathway in this type of transitional environment mostly depend on the local distribution of wave energy and water depth rather than on estuarine like circulation processes

early diagenesis in an organic rich turbidite and pelagic clay sequence from the cape verde abyssal plain ne atlantic magnetic and geochemical signals abstract processes of early diagenesis in sediments from the cape verde abyssal plain are investigated using the complimentary techniques of environmental magnetism and solid phase geochemistry the sequence captured by a 2 m long box core comprises an organic rich turbidite derived from the nw african continental margin emplaced ca 330 ka bp overlain by brown pelagic clay diagenesis in the pelagic clay mainly involves slow in situ oxidation of the iron oxide phases present which mossbauer effect data suggest are detrital haematite and magnetite possibly maghaemitised in the turbidite diagenesis has proceeded in two stages the first involving suboxic reductive processes following depletion of porewater o2 and the second involving oxidative processes associated with the slow descent of an oxidation front through the bed due to diffusion of o2 from the overlying seawater carbonate free magnetic parameters interparametric quotients and remanence acquisition demagnetisation and coercivity measurements of the core reveal that significant depletion of detrital ferrimagnetic iron fe2 fe3 oxide grains like titano magnetite has occurred within the turbidite during suboxic diagenesis and confirm previous suggestions that reductive dissolution of such components is a grain size selective process however the higher oxidation state fe3 canted antiferromagnetic iron oxide grains like haematite and goethite are much less susceptible to reductive diagenesis remobilisation of transition metal ions from below the oxidation front in the turbidite has led to authigenic precipitation of ferrimagnetic fe mn micronodules in a distinct layer immediately overlying the front and above this a further interval of mn enriched diagenetic laminae however within the suboxic organic rich zone of the turbidite well below the oxidation front there is clear evidence for the presence of a significant concentration of fine single domain ferrimagnetic iron oxide grains which are most probably associated with a population of live magnetotactic bacteria between this zone and the oxidation front there is a transitional interval in which the number of live magnetotactic bacteria declines rapidly and fossil magnetosomes in the sediment are being reductively dissolved progressively up sequence these results are broadly similar though differing in some respects to magnetic and geochemical studies of hemipelagic and high productivity pelagic sediments in which mn and fe redox boundaries have been recognised and further illustrate the value of environmental magnetic parameters for characterising early diagenetic processes in sediments of this kind

fitting dynamic models to the geosat sea level observations in the tropical pacific ocean i a free wave model abstract free equatorially trapped sinusoidal wave solutions to a linear model on an equatorial beta plane are used to fit the geosat altimetric sea level observations in the tropical pacific ocean the kalman filter technique is used to estimate the wave amplitude and phase from the data the estimation is performed at each time step by combining the model forecast with the observation in an optimal fashion utilizing the respective error covariances the model error covariance is determined such that the performance of the model forecast is optimized it is found that the dominant observed features can be described qualitatively by basin scale kelvin waves and the first meridional mode rossby waves quantitatively however only 23 of the signal variance can be accounted for by this simple model

rock magnetic characterization of early redoxomorphic diagenesis in turbiditic sediments from the madeira abyssal plain rock magnetic measurements of two sediment cores from the madeira abyssal plain map north atlantic are used to investigate post depositional changes in the concentration grain size and composition of magnetic minerals in the sediments that have occurred within organic rich turbidite horizons the changes are associated with an initial stage of suboxic reductive diagenesis following depletion of porewater o2 and a later stage of oxidative diagenesis associated with the slow descent of an oxidation front through the sediment as a result of diffusion of o2 from the overlying sea water the turbidites are of late quaternary age 18o stages 1 3 and derive both from different sites on the nw african continental margin and from the flanks of the canary islands thus the turbidites are variable compositionally especially in terms of carbonate detrital magnetic mineral and organic carbon content diagenetic changes in these sediments have been identified using solid phase geochemical data u mn corg and caco3 reported previously in more than one study rock magnetic parameters of the sediments when expressed on a carbonate free basis reveal that significant depletion of detrital ferrimagnetic iron fe2 fe3 oxide grains has occurred within organic rich turbidites during redoxomorphic diagenesis normalized quotients of magnetic parameters also show that reductive diagenesis is a ferrimagnetic grain size selective process but it has a minimal effect on the canted antiferromagnetic fe3 oxides in the sediment such components if present therefore become relatively enriched in magnetic assemblages as the ferrimagnetic grains are dissolved progressively and bulk magnetic concentration is thus depleted there is clear evidence in both cores for the existence of ultrafine ferrimagnetic grains at depth within the suboxic zone of the organic rich turbidites beneath both active and fossil oxidation fronts these grains are most probably associated with populations of live magnetotactic bacteria which commonly inhabit such organic rich horizons and play a part in the chain of bacterially mediated reactions normally associated with suboxic diagenesis these results show that simple and rapid rock magnetic techniques can be used to characterize early diagenetic processes involving iron phases in deep sea sediments at least as effectively as more laborious time consuming and sample destructive geochemical measurements

magnetite diagenesis in marine sediments from the oregon continental margin the magnetochemistry of sediments from the oregon continental margin is examined to determine the effects of iron sulfur diagenesis on the paleomagnetic record magnetic mineral dissolution and transformation into iron sulfides are a common feature in these suboxic to anoxic lutites these processes are evidenced in rapid decreases in natural remanent magnetization intensities and stabilities systematic changes in other rock magnetic properties and increases in solid phase sulfur concentrations with depth hysteresis measurements are used to evaluate downcore changes in magnetite concentration and grain size magnetite abundances decrease downcore from initial values of about 0 1 and nominal grain diameters lie within a narrow pseudosingle domain range of 0 08 to 0 6 m a first order surface area reaction model da dt ka is proposed to explain the magnetite dissolution mechanism where a is the total magnetite surface area and k is the rate constant the solution of this equation predicts that the surface area and concentration decrease exponentially and the concentration in addition depends on grain size application of this model in two cores where grain size varies with depth successfully explains the downcore profiles of both concentration and surface area despite extensive magnetite destruction magnetic directions in such sediments appear to reliably record long wavelength trends of the geomagnetic field

a new geochemical classification of sedimentary environments because of the relative constancy of ph in most subaqueous sediments and the general lack of measurability of eh these parameters are not practically useful for classifying sedimentary environments in their place a new classification is offered which derived from studies of modern sediments is based on the presence or absence of dissolved oxygen and dissolved sulfide in the sediments at the time of authigenic mineral formation sedimentary environments are first of all divided into oxic and anoxic depending upon the presence or absence of measurable dissolved oxygen anoxic environments in turn are divided into sulfidic and non sulfidic depending upon the presence of measurable dissolved sulfide anoxic nonsulfidic environments are further divided into postoxic or resulting from oxygen removal without sulfate reduction weakly reducing and methanic or resulting from complete sulfate reduction with consequent methane formation strongly reducing the environments are shown to succeed one another during early diagenesis in the order oxic post oxic sulfidic methanic iron and manganese minerals characteristic and stable in each environment are listed and discussed so that they may be used to distinguish the environments when studying the ancient geological record

focal mechanisms and locations of earthquakes in the vicinity of the 1975 kalapana earthquake aftershock zone 1970 1979 implications for tectonics of the south flank of kilauea volcano island of hawaii the november 29 1975 kalapana earthquake of magnitude 7 1 on the south flank of kilauea volcano hawaii represents a major rift tectonic event it is generally understood that the earthquake resulted from movement on a nearly horizontal fault plane with the crustal block south of kilauea s east rift zone moving south southeastward up to several meters well recorded earthquakes on the south flank of kilauea from 1970 to 1979 were analyzed and focal mechanisms determined to obtain a better understanding of the details of south flank tectonics included are a large number of earthquakes from the aftershock sequence of the 1975 earthquake hypocenters are distributed in a subplanar zone that dips 2 to 3 to the west at a depth of about 8 9 km depth we interpret this pattern to coincide with a portion of the slip plane of the kalapana earthquake and to be consistent with the notion of the slip plane occurring in a weak layer at the top of the old oceanic crust focal mechanisms are remarkably constant throughout this time period both before and after the 1975 event and closely agree with the mainshock mechanism p axis azimuths and slip vectors for the low angle fault planes are normal to the middle and lower east rift zones of kilauea there is suggestion of a change in the orientation of p axes from shallower to steeper plunge at the time of the kalapana earthquake such a change is consistent with a general reduction in the horizontal compressional stress normal to the rift zone at the time of the large earthquake no other evidence of precursory reorientation of the stress field was found and the precise predictability of this event remains in doubt however a general model of the tectonics of the volcanic rift system is now available that satisfies a number of geological and geophysical observations

an unusual two layered tidal circulation induced by stratification and wind in the ria of pontevedra nw spain abstract a two layered tidal circulation pattern has been observed in the ria of pontevedra at an anchored station 24 m deep located at 42 3917 n and 8 7380 w during a tidal cycle water leaves the estuary continuously through surface layers till 8 12 m depth and enters the estuary through bottom layers this unusual pattern in a partially mixed estuary is observed to depend on the particular summer stratification conditions and on the presence of easterly winds inside the estuary the vertical stratification is generated by solar heating and favourable upwelling conditions on the adjacent shelf which reinforces the estuarine positive circulation and provokes the inflow of typical upwelling water enaw through bottom layers on the other hand the easterly winds inside the estuary are strong enough around 8 m s 1 to force the surface water to move even against tide this situation is compared to two typical patterns observed in the estuary a winter situation where wind drives the surface water against tidal forcing and a spring situation where the water column follows the tidal pattern in both cases bottom layers are hardly influenced by wind forcing

authigenic magnetite formation in suboxic marine sediments the resolution and reliability of magnetostratigraphy and reconstructed time series of geomagnetic field behaviour depend critically on where remanence is acquired and fixed in the sediment column and whether the magnetization is altered chemically after deposition if authigenic magnetic minerals are formed at depth or if the magnetic carriers are changed after deposition then the nature and timing of magnetic events can be affected by depth offsets in remanence acquisition and mixing of detrital and authigenic signals using palaeo and rock magnetic and sediment geochemical analyses we have studied how early diagenesis affects the magnetic properties of suboxic hemipelagic sediments here we report evidence of the formation of fine grained authigenic magnetites near the commonly observed brown tan green colour boundary which marks the transition from fe oxidizing to fe reducing conditions we propose that biogenic magnetite produced by magnetotactic bacteria forms as part of the microbially mediated sequence of reactions involved in the oxidation of organic matter the magnetite is created as a metabolic by product of the microorganisms use of iron redox transitions as a source of energy active magnetite formation appears to be restricted to a zone between the levels of nitrate and iron reduction

equatorially trapped rossby waves in the presence of meridionally sheared baroclinic flow in the pacific ocean topex poseidon altimeter data are analyzed for the 8 5 year period november 1992 to may 2001 to investigate the sea surface height ssh and geostrophic velocity signatures of quasi annual equatorially trapped rossby waves in the pacific the latitudinal structures of ssh and both components of geostrophic velocity are found to be asymmetric about the equator across the entire pacific with larger amplitude north of the equator the westward phase speeds are estimated by several different methods to be in the range 0 5 0 6 m s 1 these observed characteristics are inconsistent with the classical theory for first vertical first meridional mode equatorially trapped rossby waves which predicts a phase speed of about 0 9 m s 1 with latitudinally symmetric structures of ssh and zonal velocity and antisymmetric structure of meridional velocity the observations are even less consistent with the latitudinal structures of ssh and geostrophic velocity components for other modes of the classical theory the latitudinal asymmetries deduced here have also been consistently observed in past analyses of subsurface thermal data and altimeter data and have been variously attributed to sampling errors in the observational data a superposition of multiple meridional rossby wave modes asymmetric forcing by the wind and forcing by cross equatorial southerly winds in the eastern pacific we propose a different mechanism to account for the observed asymmetric latitudinal structure of low frequency equatorial rossby waves from the free wave solutions of a simple 1 5 layer model it is shown that meridional shears in the mean equatorial current system significantly alter the potential vorticity gradient in the central and eastern tropical pacific the observed asymmetric structures of sea surface height and geostrophic velocity components are found to be a natural consequence of the shear modification of the potential vorticity gradient the mean currents also reduce the predicted westward phase speed of first meridional mode rossby waves improving consistency with the observations

comment on focal mechanism and locations of earthquakes in the vicinity of the 1975 kalapana earthquake aftershock zone 1970 1979 implications for tectonics of the south flank of kilauea volcano island of hawaii by r s crosson and e t endo

joint statistical determination of fault plane parameters abstract joint treatment of first motion data for sets of earthquakes has great advantages over determinations of individual solutions an algorithm is used to find maximum likelihood estimates of the orientations of the p and t axes and of the fault planes and their variances together with two precision parameters i that weights each event according to its agreement with the group solution and j that weights each station according to its performance the method has been applied to two sets of earthquakes having different characteristics the first is formed by 19 earthquakes in bear valley ca with magnitudes of 3 and recording distances less than 200 km and the second by 29 microearthquakes with magnitudes of 1 5 and recorded at distances less than 60 km in the pyrenees the data from bear valley form a single homogeneous group having a mechanism related to motion on the san andreas fault the data from the pyrenees are divided into five groups having different mechanisms

pyrite and organic matter in phanerozoic normal marine shales data have been obtained from our own chemical analyses and from the literature for the concentrations of organic carbon c and pyrite sulfur s in over 600 samples of cambrian to recent normal marine shales normal marine refers to deposition in oxygenated bottom water as evidenced by the presence of benthic fossils and or indicators of bioturbation all samples were selected to minimize 1 1 loss of c and or s due to weathering at the outcrop by emphasizing the use of drill core material 2 2 analytical errors and non diagenetic effects by avoiding sediments low in c or s content such as sandstones 3 3 fe limitation of pyrite formation by avoiding limestones cherts and euxinic shales 4 4 metamorphic loss of c relative to s by avoiding rocks obviously subjected to even low grade metamorphism our results indicate that 1 there is generally a good positive linear correlation between organic c and pyrite s for normal marine shales of all ages and 2 the mean cs ratio for normal marine shales has varied over time devonian to tertiary shales exhibit mean cs weight ratios 1 8 0 5 somewhat lower than quaternary sediments meancs 2 8 this we believe is due to preferential c loss relative to s during biogenic methanogenesis plus diagenetic heating distinctly lower mean c s values for the cambrian and ordovician 0 5 0 1 cannot be explained solely in terms of diagenetic c loss and instead must represent low original ratios the low original ratios we suggest were due mainly to the absence of bacterially refractory organic matter added to the marine environment by rivers at that time because the major source of such material vascular land plants had not yet evolved this along with a possibly lower degree of bioturbation contributed to enhanced pyrite formation and preservation and thus lower early paleozoic cs ratios

environmental magnetism past present and future environmental magnetism involves the application of rock and mineral magnetic techniques to situations in which the transport deposition or transformation of magnetic grains is influenced by environmental processes in the atmosphere hydrosphere and lithosphere the first explicit description of environmental magnetism as a distinct field was in 1980 since that time environmental magnetism has become a broad field that is finding application in an ever increasing array of scientific disciplines in this review of the present state of environmental magnetic studies we divide the field into three broad but arbitrary categories the first involves the use of mineral magnetic assemblages in the geological record to study physical processes in depositional environments this category includes the correlation of sediment cores using magnetic susceptibility measurements studies of geomagnetic field behavior the analysis of depositional and postdepositional mechanical processes that affect sediments and the examination of magnetic parameters that might represent proxies for paleoclimatic variation the second category encompasses studies of the processes responsible for variations in the magnetic minerals brought into a sedimentary environment these provenance investigations include studies of changes in catchment derived sediment in lakes fluctuations in contributions from terrigenous aeolian and glaciogenic components in deep sea sediments and the origin of atmospheric particulates the final category addresses in situ changes and transformations of magnetic minerals in sedimentary environments including pedogenesis authigenetic diagenetic formation of ferrimagnetic phases dissolution of magnetic minerals due to reductive diagenesis and contributions of biomagnetism to sedimentary magnetism because environmental magnetism can address problems in so many disciplines and because many of these problems may be inaccessible to other techniques it is likely that the scope of environmental magnetism will continue to expand rapidly environmental magnetism is capable of providing important data for studies of global environmental change climatic processes and the impact of humans on the environment all of which are major research initiatives in the international scientific community these factors suggest that environmental magnetism has a bright and diverse future

reply to comment on focal mecahnism and locations of earthquatkes in the vicinity of the 1975 klapana eartquake aftershock zone 1970 1979 implications for tectonics of the south flank of kilauea volcano island of hawaii

rock magnetism of late neogene and pleistocene deep sea sediments relationship to sediment source diagenetic processes and sediment lithology we use bivariate scatter plots to illustrate variations in selected rock magnetic properties low field susceptibility anhysteretic and isothermal remanence of late neogene and pleistocene deep sea sediments from 16 sites in the arctic ocean north atlantic equatorial atlantic and north pacific ocean and the arabian sea our intention is to examine the ability of the rock magnetic properties to differentiate the sediments according to factors such as lithology geographical area and the dominant mode of terrigenous sedimentation which at these sites is via ice rafting via bottom currents or via eolian processes overall correlations between sediment magnetic properties and gross lithology is poor and factors such as the source and transport path of terrigenous sediment and detrital magnetic minerals together with the action of reductive diagenetic processes are the major controls on the magnetic properties on the bivariate scatter plots sites with major ice rafted contributions tend to have high sedimentary ferrimagnetic mineral concentrations relatively coarse ferrimagnetic grain sizes and scattered sample point distributions in contrast sites where we infer significant bottom current supply of terrigenous material have tightly grouped sample point distributions carbonate sediments in which the terrigenous component is supplied by eolian processes tend to have a broad range of magnetic mineral concentration caused by glacial interglacial fluctuations in carbonate accumulation and eolian activity sediments containing significant volcanogenic material have high concentrations of relatively coarse grained ferrimagnetic material reductive diagenesis is a significant determinant of sediment magnetic properties in high productivity areas and has the effect of preferentially removing the fine grained ferrimagnetic fraction causing a coarsening of the ferrimagnetic grain size distribution and a rise in the antiferromagnetic ferrimagnetic ratio

rock magnetic evidence for the dissolution and authigenic growth of magnetic minerals within anoxic marine sediments of the california continental borderland the rock magnetic properties of marine sediments from the california continental borderland san pedro santa catalina and san nicolas basins have been studied in order to quantitatively assess the effects of sediment diagenesis on magnetic minerals previous studies have noted that the natural remanent magnetization in these sediments primarily carried by detrital magnetite decays to 10 or less of its surface value soon after deposition this decrease is caused by magnetite dissolution related to sediment diagenesis and is unrelated to paleoclimatic variations or changes in the regional influx of detrital magnetic material detailed rock magnetic measurements show that shifts to softer remanent coercivity and differences in the rate and degree of magnetic intensity loss with depth can be related to the dissolution process the shift to softer remanent coercivity is related to a coarsening of the magnetic mineral grain sizes with depth due to preferential dissolution of the finest grained magnetic material the intensity decreases which are linearly proportional to magnetite concentration decreases indicate that dissolution occurs with rate constants ranging from 0 3 to 1 6 kyr 1 the rate constants sulfide concentrations and magnetite grain size estimates from the borderland are consistant with previous studies of magnetite dissolution our results demonstrate the importance of both sulfide and magnetite surface area in the dissolution process anomalous peaks in viscous remanence within the sediments suggest the authigenic growth of greigite and its subsequent transformation to pyrite

dissolution and pyritization of magnetite in anoxie marine sediments concentrations of magnetite were determined with depth in sediments of varying h2s content taken from long island sound foam nwc and sachem sites and from a site in the rapidly depositing subaqueous portion of the mississippi delta for the three long island sound sites dissolution of magnetite during burial is clearly demonstrated and for all four sites the rate of magnetite dissolution is proportional to the concentration of dissolved pore water sulfide by combining magnetite depth distributions with sedimentation rate data and measurements of dissolved sulfide we find that magnetite dissolution is well described by the following rate law dcmagdt 1 1 10 5c0 5bcmagamag where cmag is the concentration of magnetite grams per gram of sediment cs is the concentration of dissolved sulfide mm and amag is the specific surface area of magnetite in the sediment cm2 per gram of magnetite this equation means that for a typical range of magnetite surface areas and dissolved sulfide concentrations the half life of magnetite in anoxic marine sediments ranges from about 50 to 1000 years sem observations of magnetite grains from the different sediment sites reveal that magnetite dissolution may be accompanied by extensive replacement by pyrite this only occurs if magnetite is in contact with high concentrations of h2s 1 mm for relatively long periods of time several hundred years with low concentrations of h2s 1 mm magnetite dissolution occurs without identifiable pyrite replacement we suggest that this feature of magnetite diagenesis may prove to be a useful paleosulfide indicator

quaternary shelf sea palaeoceanography recent developments in europe abstract high quality palaeoceanographic reconstructions based on sequences preserved in shallow marine environments demonstrate that these constitute significant archives of climatic and oceanographic change such sequences are important first because their often very high resolution sometimes laminated nature enables high frequency cycles to be resolved and provides the basis for establishing spatial and temporal variability in the marine radiocarbon reservoir effect second sea level index points from shelves are important for the validation of glacio hydro isostatic geophysical models and for understanding sea level change during early deglaciation third shallow marine sequences contain excellent records of land ocean interaction often preserving paired terrestrial marine proxies in the same stratigraphic sequence a new development in shelf sea palaeoceanography is documenting the long term dynamics of shelf sea stratification this is the dominant hydrodynamic phenomenon of tide dominated shelf seas in the middle and high latitudes and has a profound influence on productivity and therefore global change through the carbon cycle detailing the evolution of seasonal stratification during eustatic highstands is therefore of relevance to the climate system

magnetic properties of sedimentary greigite fe3s4 new data are presented here that document the previously poorly known magnetic characteristics of sedimentary greigite fe3s4 several diagnostic magnetic properties can be used in conjunction to rapidly screen sediments to detect the presence of greigite such discriminants are necessary because greigite displays a similar or higher range of coercivities compared to most ferrimagnetic minerals and the commonly used method of alternating field demagnetization cannot be used to distinguish between palaeomagnetic remanence components due to greigite and other ferrimagnetic minerals sedimentary greigite has high ratios of the saturation isothermal remanent magnetization to magnetic susceptibility mrs which are accompanied by hysteresis ratios of mrsms 0 5 and bcr bc 1 5 ms is the saturation magnetization bc is the coercive force and bcr is the coercivity of remanence greigite has no low temperature phase transition whereas the ferrimagnetic iron sulphide pyrrhotite undergoes a major phase transition at about 34 k and unoxidized magnetite displays the verwey transition at 118 k low temperature measurements may therefore prove valuable in distinguishing between magnetite pyrrhotite and greigite although the absence of a low temperature transition cannot be taken as definitive evidence for the presence of greigite greigite also displays characteristic high temperature behaviour with a major drop in magnetization between 270 and 350 c determination of the mrs ratio is an excellent means of rapidly screening sediments to identify stratigraphic intervals that may contain greigite subsequent low and high temperature analyses can then provide unambiguous identification of greigite and enable the evaluation of the presence of other magnetic minerals