h2o fluid saturated melting of subducted continental crust facilitates exhumation of ultrahigh pressure rocks in continental subduction zones we present two dimensional numerical models of plate subduction and collision inspired by the scandinavian caledonian orogeny to investigate the possible impact of continental crust partial melting on the exhumation of ultra high pressure metamorphic rocks three possible reactions were tested low temperature solidus representing h2o fluid saturated partial melting and two end member reaction curves for dehydration melting thermo mechanical effects of partial melting were implemented as 1 a viscosity decrease as a determined rheologically critical melt percentage was reached here 0 1 2 a change in effective heat capacity and adiabatic heating cooling accounting for a latent heat term in the heat equation among the 3 tested reactions only h2o fluid saturated partial melting drastically modifies the collision dynamics from the non melting reference model holding all other parameters constant a substantially low general viscosity truncation here 1017 pa s is needed to properly resolve the effect of partial melting on deep collision processes low temperature melting indeed induces the development of a low viscosity buoyant plume prior to slab detachment where migmatites exhume from uhp conditions at rates and with pressure temperature paths similar to the natural values acknowledged for the norwegian caledonides high temperature melting has no drastic influence on early collision dynamics while positive buoyancy remains the first order driver for the exhumation of buried continental rocks exhumation initiates in these cases with eduction subsequent to slab detachment melting and formation of a migmatite plume can later occur along decompression path while continental crust undergoes thermal reequilibration at temperatures above 900 c some of the partially molten material can also relaminate in the overriding plate rather than exhume within the collision zone even if minor in terms of amount of magma produced h2o fluid saturated partial melting at uhp conditions could therefore have a dramatic rheological effect and actually limits continental rocks subduction and facilitates their exhumation

partial transformation of gabbro to coesite bearing eclogite from yangkou the sulu terrane eastern china an ultra high pressure uhp metamorphic slab at yangkou beach near qingdao in the sulu region of china consists of blocks of eclogite facies metagabbro metagranitoid ultramafic rock and mylonitic orthogneisses enclosed in granitic gneiss a gradational sequence from incipiently metamorphosed gabbro to completely recrystallized coesite eclogite formed at ultra high pressures was identified in a single 30 m block metagabbro is preserved in the core whereas coesite eclogite occurs along the block margins the metagabbro contains an igneous assemblage of pl aug opx qtz bt ilm ti mag it shows relict magmatic textures and reaction coronas fine grained garnet developed along boundaries between plagioclase and other phases primary plagioclase broke down to ab ky ms zo grt amp augite is rimmed by sodic augite or omphacite whereas orthopyroxene is rimmed by a corona of cum act and omp qtz layers or only omp qtz in transitional rocks augite and orthopyroxene are totally replaced by omphacite and the lower pressure assemblage ab ky phn zo grt coexists with domains of omp jd70 73 ky phn in pseudomorphs after plagioclase both massive and weakly deformed coesite bearing eclogites contain omp ky grt phn coe qtz rt and preserve a faint gabbroic texture coesite inclusions in garnet and omphacite exhibit limited conversion to palisade quartz some intergranular coesite and quartz pseudomorphs after coesite also occur assemblages of the coronal stage transitional and uhp peak occurred at about 540 50 c at c 13 kbar 600 800 c at 15 25 kbar and 800 850 c at 30 kbar respectively garnet from the coronal through the transitional to the eclogite stage rocks show a decrease in almandine and an increase in grossular pyrope components garnet in low grade rocks contains higher mno and lower pyrope components the growth textures of garnet within pseudomorphs after plagioclase or along grain boundaries between plagioclase and other phases are complex the application of garnet zoning to estimate p t should be carried out with caution some garnet enclosing quartz aggregates as inclusions shows radial growth boundaries these quartz aggregates as well as other primary and low p phases persisted metastably at uhp conditions due to sluggish reactions resulting from the lack of fluid during prograde and retrograde p t evolution

u pb age trace element and hf isotope compositions of zircon in a quartz vein from eclogite in the western dabie mountains constraints on fluid flow during early exhumation of ultrahigh pressure rocks quartz veins in high pressure hp to ultrahigh pressure uhp rocks are the products of fluid rock interaction and thus provide insight into fluid processes in subduction zones in this paper we report an integrated study of mineral inclusion trace element u pb age and lu hf isotope compositions of hydrothermal zircon grains from a quartz vein within an uhp eclogite outcrop from the hong an area western dabie mountains these data are used to decipher the age conditions of formation and source of fluid for zircon formation during the exhumation of uhp rocks zircon grains from the vein have perfect euhedral shape and show sector zoning or weak zoning indicating that they precipitated from the aqueous fluid responsible for the vein formation raman spectroscopy analysis reveals that the zircon grains contain inclusions of garnet omphacite rutile quartz and h2o implying that they crystallized from aqueous fluid under hp eclogite facies conditions the zircon grains show low th u and lu hf ratios nearly flat hree patterns absent eu anomalies and low lree contents these characteristics are consistent with their precipitation in the presence of garnet and epidote and absence of feldspar and thus suggest that trace element concentrations in hydrothermal zircon are controlled by co precipitation of mineral assemblages crystallization temperatures of 670 to 712 c which were calculated using the ti content of zircon are consistent with their formation under eclogite facies conditions and may correspond to the temperature of the infiltrating fluid the weighted mean 206pb 238u age of 224 7 1 3 ma is taken as the best estimate for the age of quartz vein formation and records aqueous fluid flow during the early exhumation stage of uhp rocks the zircon grains in the quartz vein have hf compositions similar to those in the host eclogite which demonstrates isotopic equilibrium between fluid and rocks and that the fluid rock ratio was likely low

ultrahigh pressure minerals and metamorphic terranes the view from china abstract ultrahigh pressure uhp metamorphism refers to mineralogical modifications of continental and oceanic crustal protoliths associated mafic ultramafic rocks initially formed or emplaced in shallow levels of the lithosphere but which subsequently have experienced p t conditions within or above the coesite stability field 2 7 gpa 700 c typical products include eclogite garnet peridotite and uhp varieties of metapelite quartzite marble paragneiss and orthogneiss uhp metamorphic assemblages require relatively cold lithospheric subduction to mantle depths some recrystallization even occurs under forbidden p t conditions characterized by a geotherm of the current explosion of research on continental uhp terranes reflects their significance for mantle dynamics and the tectonics of continental subduction collision exhumation mantle slab interactions and geochemical recycling a further characterization of uhp phases and positive identification of uhp minerals requires new experimental studies coupled with state of the art analyses for example the very rare occurrence of microdiamond inclusions in zircons from dabie sulu uhp rocks may reflect high f o 2 attending recrystallization inasmuch as epidote is rather common rutile needles within garnets from sulu uhp eclogitic rocks may not be the result of exsolution so in such cases the apparent uhp pressure may have been over estimated hadean igneous microdiamond inclusions in jack hills detrital zircons could have originated from mantle xenoliths whereas abundant detrital phanerozoic diamonds containing inclusions of coesite and other eclogitic minerals from new south wales might have been derived from unexposed uhp metamorphic terranes micro mineral intergrowth and nano size minerals may hold important key to deciphering the actual p t paths of subduction and mantle return flow although most exhumed terranes have returned surfaceward relatively rapidly after short time of uhp condition the long duration of storage at great depth and slow exhumation for the largest uhp terranes remain as major problems

zircon u pb ages ree concentrations and hf isotope compositions of granitic leucosome and pegmatite from the north sulu uhp terrane in china constraints on the timing and nature of partial melting granitic leucosome and pegmatite are widely distributed within biotite bearing orthogneiss in the northern part of the sulu ultrahigh pressure uhp metamorphic terrane eastern china a combined study of mineral inclusions cathodoluminescence cl images u pb shrimp dates and in situ trace element and lu hf isotope analyses of zircons provided insight into the nature and timing of partial melting in these rocks zircon grains separated from biotite bearing orthogneiss typically have three distinct domains 1 pre metamorphic magmatic cores with qtz kfs pl ap inclusions which record a neoproterozoic protolith age of 790 ma 2 mantles with coe phe ap inclusions that record triassic uhp age at 227 3 ma and 3 narrow rims with quartz inclusions that record hp granulite facies retrograde metamorphism at 210 3 ma in contrast zircons separated from granitic leucosome have only two distinct domains 1 the central uhp areas with coe phe ap inclusions record triassic uhp age of 227 3 ma and 2 outer magmatic areas with qtz kfs ab ap inclusions that record partial melting time of 212 2 ma zircons separated from pegmatite contain mineral inclusions of qtz kfs ap and show regular magmatic zoning from centre to edge the centres record partial melting time of 212 2 ma in line with the outer domains of granitic leucosome whereas the edges give a younger age of 201 2 ma related to pb loss and partial recrystallization during late triassic regional amphibolite facies retrogression these data indicate that partial melting in the north sulu uhp gneissic rocks took place during post uhp retrograde hp granulite facies metamorphism pre metamorphic magmatic zircon cores from biotite bearing orthogneiss give uniform 176hf 177hf of 0 28187 0 00003 2 sd standard deviation corresponding to ehf 790 and hf model ages tdm2 of about 16 3 and 2 41 ga respectively this is consistent with the generation of its protolith by reworking of paleoproterozoic to late archean crust in contrast uhp zircon domains from biotite bearing orthogneiss and granitic leucosome are characterized by distinct trace element composition with low lu hf 0 006 low th u 0 1 and considerably higher 176hf 177hf 0 28233 0 00002 2 sd than the pre metamorphic cores the uniform but significantly different hf isotope composition between the uhp ehf 227 14 6 0 8 2 sd and pre metamorphic ehf 227 27 7 domains indicates equilibration of the lu hf isotope system only within the uhp metamorphic mineral assemblage the disequilibrium between whole rock and uhp zircon suggests that about two thirds of the whole rock hf retained in the pre metamorphic zircon domains zircon domains crystallized during partial melting at 212 ma in granitic leucosome and pegmatites have a hf isotope composition indistinguishable from that of the uhp zircon domains this suggests that only hf and zr equilibrated during uhp metamorphism was remobilized during partial melting while pre metamorphic zircon remained stable or was not accessible in contrast the magmatic zircon edges from pegmatite have somewhat lower 176hf 177hf 0 28216 and ehf t 17 6 1 2 2 sd indicating some release of less radiogenic hf for instance by dissolution of pre metamorphic zircon during late regional amphibolite facies retrogression

factors in the preservation of coesite the importance of fluid infiltration the survival of coesite in ultrahigh pressure uhp rocks is most commonly attributed to rapid exhumation continuous cooling during uplift and inclusion in strong phases that can sustain a high internal over pressure during decompression exceptions to all of these criteria exist perhaps less attention has been paid to the role of fluid infiltration in the preservation of coesite we used infrared spectroscopy to measure water contents of coesite and coesite pseudomorphs in a variety of uhp rocks in all cases oh concentrations in coesite are below the detection limit of 100 ppm h2o the silica phases surrounding coesite however show varying amounts of h2o this is most spectacularly observed in pyrope quartzites from the dora maira massif that contain at least three phases of silica replacing coesite also distinguished by varying color of cathodoluminescence cl palisade textured quartz 100 ppm h2o red violet cl mosaic quartz which is actually chalcedony up to 0 4 wt h2o yellow brown cl and a rare highly hydrated silica phase interpreted to be opal 7 wt h2o dark blue cl very similar signatures are observed in a grospydite xenolith from the roberts victor kimberlite the quartz replacing coesite in other uhp samples studied contains on the order of 500 ppm h2o or less and most measurements are under the detection limit of our technique we infer that palisade quartz forms under dry or nearly dry conditions and at high temperatures during dilation of the host phase the formation of hydrous silica phases such as chalcedony and opal however must take place at much lower temperatures after cracking of the host phase which allows external fluids to infiltrate delay of fluid infiltration to low temperatures where kinetics are slow even in the presence of water is the most critical factor in the preservation of coesite

exhumation mechanisms of melt bearing ultrahigh pressure crustal rocks during collision of spontaneously moving plates a series of 2d petrological thermomechanical numerical experiments was conducted to i characterize the variability of exhumation mechanisms of ultrahigh pressure metamorphic uhpm rocks during collision of spontaneously moving plates and ii study the possible geodynamic effects of melting at ultrahigh pressure conditions for the exhumation of high temperature ultrahigh pressure metamorphic ht uhpm rocks to this end the models include fluid and melt induced weakening of rocks five distinct modes of exhumation of u hpm rocks associated with changes in several parameters in the models of plate collision and continent subduction are identified as follows vertical crustal extrusion large scale crustal stacking shallow crustal delamination trans lithospheric diapirism and channel flow the variation in exhumation mechanisms for u hpm rocks in numerical models of collision driven by spontaneously moving plates contrasts with the domination of the channel flow mode of exhumation in a majority of the published results from numerical models of collision that used a prescribed plate convergence velocity and or did not include fluid and melt induced weakening of rocks this difference in the range of exhumation mechanisms suggests that the prescribed convergence velocity condition and the neglect of fluid and melt related weakening effects in the earlier models may inhibit development of several important collisional processes found in our experiments such as slab breakoff vertical crustal extrusion large scale stacking shallow crustal delamination and relamination and eduction of the continental plate consequently the significance of channel flow for the exhumation of uhpm rocks may have been overstated based on the results of the earlier numerical experiments in addition the results from this study extend over a larger proportion of the high temperature range of p t conditions documented from uhpm rocks including those retrieved from ht uhpm rocks than the results of experiments from previous numerical models in particular the highest peak metamorphic temperatures up to 1000 degrees c are recorded in the case of the vertical crustal extrusion model in which subducted continental crust is subjected to a period of prolonged heating by asthenospheric mantle abutting the continental side of the vertically hanging slab nonetheless some extreme temperature conditions which have been suggested for the kokchetav and bohemian massifs perhaps up to 1100 1200 degrees c are still to be achieved in experiments using numerical models

prograde metamorphism decompressional partial melting and subsequent melt fractional crystallization in the weihai migmatitic gneisses sulu uhp terrane eastern china abstract in order to decipher fluid melt activity during subduction and subsequent exhumation of felsic continental crust we carried out a combined study of zircon internal structure zircon u pb age zircon trace element composition and whole rock geochemistry on migmatitic gneisses from the weihai region in the sulu ultra high pressure uhp metamorphic terrane eastern china the weihai migmatitic gneisses are composed of intercalated compositional layers of melanosome and plagioclase pl rich leucosome and k feldspar kfs rich pegmatite veins whole rock geochemistry suggests that mgo fe2o3t cao tio2 p2o5 rare earth elements ree and large ion lithophile elements hfse are nearly completely retained in the melanosome whereas significant amounts of lile e g rb ba k sr pb and u are partitioned into the pl rich leucosome and the kfs rich pegmatite veins the kfs rich pegmatite vein has much higher k2o u pb and rb but lower cao and na2o contents than those of the pl rich leucosome layer protolith magmatic zircon domains with an upper intercept age of about 780 ma are common in the cores of zircon grains from the melanosome and the pl rich leucosome layers indicating that the protolith of the migmatitic gneiss is mid neoproterozoic magmatic rock metamorphic zircons with concordant ages ranging from 243 to 256 ma occur as overgrowth mantles on the protolith magmatic zircon cores they are characterized by remarkably flat heavy rare earth element hree patterns without obviously negative eu anomalies and have low y and th contents low th u and high hf y ratios indicating a prograde metamorphism in the hp eclogite facies during subduction recrystallized rims of zircons 228 2 ma in the pl rich leucosome layer are similar to magmatic zircons in terms of their hree enriched patterns with negative eu anomalies high y and low th contents and low hf y and th u ratios this indicates that the gneiss has experienced decompressional partial melting and the pl rich leucosome layers were formed by fractional crystallization of the primary melt during the early stage hot exhumation zircon grains 219 2 ma in the kfs rich veins are characterized by aqueous fluid melt related signatures with strongly hree enriched patterns high u pb and low th contents and low th u and high lu hf ratios indicating that the pegmatite vein was formed by crystallization of residual aqueous melt after the crystallization of pl rich leucosome layers during later stage cooling during exhumation our results suggest that the migmatitic gneiss successively recorded information concerning the protolith prograde hp metamorphism during subduction fractional crystallization of primary melt and crystallization of the residual melt during exhumation

high pressure veins in eclogite from new caledonia and their significance for fluid migration in subduction zones abstract this paper describes the petrology and geochemistry of high pressure veins and associated metasomatic selvages that are hosted by eclogite in the pouebo eclogite melange of northern new caledonia isotopic and geochemical evidence indicates that the mafic host rock represents seafloor altered fractionated morb that underwent eclogite facies metamorphism in a subduction zone within the host rock are cm thick garnet quartz phengite veins that are enveloped by garnet poor omphacite rich selvages or bleach zones petrography thermometry oxygen isotope characteristics and mass balance calculations are used to show that the veins largely formed by fluid mediated mass transfer from the bleach zones during prograde metamorphism minerals in the veins are free of inclusions but the vein garnets preserve complex chemical zoning features that are not present in the host rock garnets vein garnets have mn and hree zoning patterns that are indicative of progressive garnet growth during prograde metamorphism whereas mg and ca contents reveal prominent sector zoning and fine scale intergrowth features we propose that the veins formed over a prolonged period during subduction by local circulation of fluid that was sourced from prograde dehydration of minerals in the host rock fluid circulation may have been driven by episodic microcracking sealing around garnet porphyroblasts which led to significant mass transfer and progressive vein growth mass balance calculations and phengite trace element compositions also require the additional of pelite derived components to the veins these components were probably introduced into the veins at conditions close to peak metamorphism via a relatively small external fluid flux this model for vein formation is consistent with previous studies that suggest fluid flow in deeply subducted oceanic crust is highly restricted in many cases the delay of fluid migration after hydrous mineral breakdown may provide an important source of water for arc magmas as free fluid is transported to deeper levels in subduction zones

multiphase solid inclusions in uhp rocks su lu china remnants of supercritical silicate rich aqueous fluids released during continental subduction abstract primary multiphase solid ms inclusions without preserved fluid are found within peak minerals in kyanite quartzite topaz and kyanite phengite epidote eclogite from donghai area su lu terrane typical mineral association in inclusions is paragonite muscovite anhydrite corundum alunite type sulphate zircon calcite chlorite sio 2 barite pyrite apatite in quartzites and paragonite rutile apatite amphibole zn staurolite magnetite plagioclase zircon pyrite alunite type sulphate zn mg fe al ti spinel in eclogites on the basis of the fluid inclusion textures and of the daughter phase assemblage calculated fluid composition is as follows in quartzites 24 wt sio 2 30 wt al 2 o 3 9 wt cao 5 wt k 2 o 3 wt na 2 o 11 wt so 3 18 wt h 2 o with traces of tio 2 fe 2 o 3 feo mgo bao p 2 o 5 cl f and co 3 2 and in eclogites 26 wt sio 2 21 wt tio 2 20 wt al 2 o 3 2 wt mgo 4 wt feo 6 wt fe 2 o 3 7 wt cao 3 wt na 2 o 3 wt p 2 o 5 7 wt h 2 o 1 wt cl and traces of zno mno k 2 o so 3 and f originally trapped chloride poor aqueous fluids contained very high amounts in the order of tens of wt of si 4 al 3 and ti 4 solute species reflect the chemical composition of the host rocks mg 2 fe 2 ti 4 p 5 and na are abundant in the fluids present in eclogites while fluids are enriched in al 3 k na so 4 2 co 3 2 in quartzites we propose that multiphase solid inclusions represent remnants of high density supercritical silicate rich aqueous fluids that were in equilibrium with peak minerals at uhp conditions these fluids show characters which are transitional between aqueous fluids and silicate melts and were probably produced by dehydration reactions of the host rocks during the latest stages of subduction

trace element rich brines in eclogitic veins implications for fluid composition and transport during subduction primary and pseudosecondary fluid inclusions occur in oscillatory and sector zoned omphacite in eclogitic veins from the monviso ophiolitic complex in the western alps the inclusions contain aqueous brines and daughter crystals of halite sylvite calcite dolomite albite anhydrite and or gypsum barite baddeleyite rutile sphene fe oxides pyrite and monazite this daughter mineral suite indicates high solubilites of na k ca mg fe zr ti p ba ce la th and s species and provides direct evidence for transport of high fieldstrenght large ion lithophile and light rare earth elements as dissolved species during subduction fluid inclusion heterogeneities preserved within and between adjacent grains in the veins however suggest that the scale of fluid equilibration was small a crack seal geometry in some of the veins implies that fluid release in pulses rather than steady flow controlled mineral deposition and growth in the veins from these observations we develop a model of fluid release and entrapment in which pulses of fluid are associated in time with increments of shear and tensile failure the rate of fluid release and the reduction in porosity both depend on the rate of plastic flow vein fluids may initially be derived from decreptitation of early fluid inclusions in the host eclogites small scale fluid heterogeneities implied by the fluid inclusions in the veins are best interpreted in terms of limited fluid flow and hence limited metasomatism we conclude that element recycling into the mantle wedge during subduction will depend at least as strongly on fluid transport mechanisms as on element solubilities in the fluid phase at monviso despite evidence for high trace element solubilities in saline brines the elements were not removed from the downgoing slab prior to teaching depths of 40 km

geodynamic regimes of subduction under an active margin effects of rheological weakening by fluids and melts the dynamics of subduction under an active margin are analysed by using a 2d coupled petrological thermomechanical numerical model of an oceanic continental subduction system the model includes spontaneous slab bending dehydration of the subducted crust aqueous fluid transport partial melting of both crustal and mantle rocks as well as melt extraction processes resulting in magmatic arc crust growth based on our models the following five geodynamic regimes of subduction which may potentially form at active margins are identified i stable subduction with no backarc spreading centre and without plumes in the mantle wedge ii retreating subduction with a focused backarc spreading centre and without plumes iii retreating subduction with distributed intra arc extension and trans lithospheric sedimentary plumes iv advancing subduction with underplating laterally extending sub lithospheric plumes and v stable to advancing subduction with stationary laterally limited sub lithospheric plumes transitions between these different regimes are mainly caused by the concurrence of rheological weakening effects of i aqueous fluids percolating from the subducting slab into the mantle wedge and ii melts propagating from the partially molten areas formed in the mantle wedge towards the surface the aqueous fluids mainly affect the forearc region strong fluid related weakening promotes plate decoupling and reduces subduction drag and thus results in stacking of sediments in the accretion prism in contrast reduced weakening by fluids results in strong coupling of the plates and leads to advancing collision like subduction with enhanced subduction erosion thickening of the overriding plate and large sedimentary plumes in the mantle wedge are the consequences on the other hand melts extracted from the hot regions above the slab rheologically weaken the lithosphere below the arc which thus controls overriding plate extension and shortening strong rheological weakening by melts in combination with weak plate coupling trigger retreating subduction with a pronounced backarc spreading centre also weakening of the continental lithosphere by melts extracted from trans lithospheric sedimentary plumes generate a weak channel through which these structures may be emplaced into subarc crust if there is insufficient melt related weakening plumes cannot ascend but extend horizontally and thus underplate the lithosphere

decrepitated uhp fluid inclusions about diverse phase assemblages and extreme decompression rates erzgebirge germany minute polyphase inclusions in garnet of quartzofeldspathic rocks saidenbachite from the saxonian erzgebirge germany contain microdiamond or graphite phlogopite quartz paragonite phengite and other minerals in minor amounts these inclusions are interpreted to represent an original dense coh silicate fluid trapped in crystallizing garnet at depths of 150 km inspection of the inclusion population in a single garnet by sem reveals two characteristic features i the shape of most inclusions indicates healed radial cracks in the host garnet and thus the buildup of a significant differential pressure p i e a contrast in pressure between the inclusion pi and the host mineral pe the mineral assemblages sealing the cracks and showing an equilibrated microstructure indicate temperatures of 750 50 c and pressures below 2 5 gpa ii the diverse types of inclusions appear to be randomly distributed in the garnet host thus the variable phase assemblages do not reflect a compositional evolution of the fluid trapped in the garnet combining observations i and ii we propose that the diversity of the phase assemblage in the inclusions is the result of decrepitation at different times and thus of distinct histories of pi as p at decrepitation is primarily controlled by inclusion size and shape applying a flow law for dislocation creep of garnet a low strength of garnet at 750 50 c for low geological strain rates is predicted thus differential pressure should have been kept low i e pi pe by continuous stretching of the inclusion for typical exhumation rates of metamorphic rocks to attain the differential pressure pi pe required for catastrophic brittle failure of the garnet host the decompression rate must have been extremely high as a robust lower bound a minimum exhumation rate on the order of 100 m year 1 is suggested which corresponds to ascent rates of magma

large areal extent of ultrahigh pressure metamorphism in the sulu ultrahigh pressure terrane of east china new implications from coesite and omphacite inclusions in zircon of granitic gneiss abstract coesite and omphacite inclusions have been identified for the first time as minute inclusions in zircon from amphibolite facies granitic orthogneiss in the sulu ultrahigh pressure uhp metamorphic terrane of eastern china by raman spectroscopy and microprobe analyses the occurrences of these minerals in the voluminous granitic gneiss of sulu support a regional and pervasive uhp metamorphic event that predated regional amphibolitic retrogression taking into account the widespread discoveries of coesite in other lithologies we thus conclude that a substantial crustal component in the sulu uhp metamorphic terrane appears to have shared a common history of triassic subduction to mantle depths and later exhumation

rutile saturation in hydrous siliceous melts and its bearing on ti thermometry of quartz and zircon the tio2 solubility of rutile saturated hydrous siliceous melts has been investigated at p 1 gpa and t 650 1000 c for several representative felsic compositions the dissolution of a rutile crystal into a tio2 undersaturated melt provides information on both tio2 solubility and ti diffusion results of this study confirm that tio2 solubility is strongly dependent on both temperature and melt composition but not on the amount of h2o present for a given t t io2 content decreases as the melts become more felsic the solubility of tio2 is given by log ti ppm 7 95 5305 t 0 124fm

melting induced fluid flow during exhumation of gneisses of the sulu ultrahigh pressure terrane abstract hydrothermally altered rocks are products of fluid rock interactions and typically preserve numerous quartz veins that formed as chemical precipitates from fluids that fill up cracks thus quartz veins are the record of the fluid system that involved fracture flow in the direction of changing temperature or pressure in order to decipher the fluid activity in the sulu ultrahigh pressure uhp terrane in eastern china quartz veins together with an adjacent eclogite lens and the host gneiss were studied in one location a deformed quartz vein is located at the boundary between the host gneiss and the eclogite lens the amphibolite facies overprinting of the eclogite lens decreases from the rim to the core of the lens with fresh eclogite preserved in the core the foliated biotite gneiss contains felsic veins and residual phengites zircon rims from the gneiss are characterized by melt related signatures with steep hree patterns high hf contents and negative eu anomalies and a pool of weighted average 206 pb 238 u analyses reveal an age of 219 3 ma 2 which is younger than the uhp metamorphic age 236 2 ma 2 recorded by zircons from the eclogite lens this suggests that the gneiss in the sulu uhp terrane could have suffered from partial melting due to phengite dehydration during the hot exhumation stage the formation age of the quartz vein 219 2 ma 2 defined by zircon rims agrees well with the partial melting time 219 3 ma 2 of the host gneiss the initial 176 hf 177 hf ratios of zircon rims from the quartz vein are obviously lower than zircons from the eclogite lens but overlap with the coeval zircon domains from the nearby granite dikes produced by partial melting of orthogneiss these observations suggest that the quartz vein and corresponding fluid flow could be associated with partial melting of the host gneiss on the other hand amphibole bearing and hree rich zircon rims from the amphibolite pool an amphibolite facies metamorphic age of 217 5 ma 2 overlap with the formation age of the quartz vein this implies that retrogression of the eclogite lens could have been caused by melting induced fluid flow based on the above observations we speculate that partial melting of the gneiss in the continental subduction related uhp belt could have induced a significant fluid flow during the exhumation stage and thus contributed significantly to the extensive retrogression of eclogites in the sulu uhp terrane

metamorphic growth and recrystallization of zircon distinction by simultaneous in situ analyses of trace elements u th pb and lu hf isotopes in zircons from eclogite facies rocks in the sulu orogen simultaneous in situ analyses of trace elements u th pb and lu hf isotopes were carried out on distinct domains of zircons in ultrahigh pressure uhp eclogite facies metamorphic rocks from the main hole of the chinese continental scientific drilling ccsd in the sulu orogen for the first time trace elements are directly linked to lu hf isotopes in metamorphic zircons with reference to their u pb dates this enables methodological integration to distinguish four types of metamorphic zircon solid state replacement and dissolution recrystallizations of protolith zircons and new growth from the aqueous fluid metamorphically grown zircons are characterized by concordant u pb ages for the metamorphism flat hree patterns typical of the garnet effect low contents of ree especially hree y nb ta and th u high contents of hf low lu gd n lu hf and th u 0 1 ratios and elevated 176hf 177hf ratios relative to solid state recrystallized zircons this suggests the effects of both garnet and fluid on the growth of metamorphic zircons in contrast metamorphic recrystallization has reset the u th pb isotope system of protolith zircons to different extents depending on the extents of fluid action during metamorphism solid state recrystallized zircons exhibit the lowest degrees of resetting and thus almost inherit all geochemical features from the protolith zircons which are characterized by discordant u pb ages close to or below the protolith age steep mree hree patterns typical of magmatic origin high contents of trace elements and their ratios and low 176hf 177hf ratios on the other hand dissolution recrystallized zircons show the highest degrees of reworking and thus have concordant or nearly concordant u pb ages for the metamorphism steep mree hree patterns lowered contents of trace elements such as ree th u y nb ta and ti relative to the protolith zircons and almost unchanged hf isotope ratios replacement recrystallized zircons display intermediate degrees of reworking and thus have their many features of elements and isotopes in between while the metamorphic growth in the presence of both garnet and fluid is characterized by both depletion of hree with flat pattern and the low contents of trace elements the metamorphic recrystallization in the presence of aqueous fluid is indicated by gradual decreases of mree to hree without the flat hree pattern therefore the simultaneous in situ analyses of metamorphic zircons have the advantage over single term analyses in making distinction between the new growth and the different types of recrystallization

metamorphic veining and mass transfer in a chemically closed system a case study in alpine metabauxites western vanoise in western vanoise french alps karstic pockets of triassic to jurassic metabauxites embedded in carbonate rocks and containing several generations of metamorphic veins were studied during blueschist facies metamorphism a cumulative amount of 13 vol of water is inferred to have been produced locally by successive dehydration reactions and part of this fluid remained in the bauxitic lenses during most of the metamorphic cycle field and geochemical evidence show that these rocks have been isolated from large scale fluid flow closed system behaviour it is proposed that the internally derived fluid has promoted the opening of fluid filled open spaces as attested by the euhedral habits of vein minerals and served as medium for mass transfer from rock to vein indeed the vein infill is obviously the result of chemical interactions at the millimetre to centimetre scale between the rock minerals and the locally produced aqueous fluid two vein types can be distinguished based on mineralogical and textural features i some veins are filled with newly formed products of either prograde chloritoid or retrograde chlorite metamorphic reactions in this case fluid filled open spaces seem to offer energetically favourable nucleation growth sites ii the second vein type is infilled with cookeite or pyrophyllite that were present in the host rock prior to the vein formation in this closed chemical system the components for the vein infill minerals have been transferred from rock to vein through the fluid in a dissolution transport precipitation process possibly stress assisted these different vein generations all contain al rich mineral infills suggesting that al was a mobile element cm scale during metamorphism in these hp rocks fluid flow may have been restricted and if so mass transfer occurred by diffusion in an almost stagnant fluid metamorphic veins can be seen as witnesses of fluid and mass redistribution that partly accommodate the rock deformation lateral segregation

occurrence and field relationships of ultrahigh pressure metagranitoid and coesite eclogite in the su lu terrane eastern china coesite eclogite is associated with metagranitoid in a 50 100 m 2 outcrop within the regionally developed amphibolite facies su lu orthogneiss primary intrusive relationships between the metagranitoid and basic rocks and bulk chemistry analyses show that together they represent a composite igneous body that has subsequently been strongly deformed and metamorphosed the presence of rutile sodie pyroxene corona garnet and possible pseudomorphs after coesite all suggest very high pressures of metamorphism in the metagranitoid this is the first documented occurrence of ultrahigh pressure uhp metagranitoid outside of the european alps the existence of uhp metagranitoid shows that low density of rocks does not necessarily prevent subduction to mantle depths even at peak metamorphic conditions the uhp composite igneous body reported here would have a bulk density less than the mantle buoyancy forces may therefore have been important in the early exhumation of this unit other outcrops of coesite eclogite in the su lu region may also have been originally metamorphosed along with low density granitoid rocks

mantle regulation of core cooling a geodynamo without core radioactivity abstract the case for radioactivity in the core based on the power requirements of the geodynamo is re evaluated previous calculations of mantle regulation of core thermal evolution have used an inappropriate formula new calculations with a more appropriate formula yield lower core heat loss in the past thus mitigating the implication of unreasonably high past core and mantle temperatures multiple thermal evolutions leading to present heat flows are also demonstrated depending on the efficiency of mantle removal of core heat some with moderately high past core heat loss and some with low and steady core heat loss the latter would permit a low or moderate power dynamo without core radioactivity key uncertainties are the efficiency of core cooling by the mantle the thermal conductivity of the core and the energy or entropy flow required to maintain the dynamo the present rate of heat loss from the core is argued to be still rather uncertain and a commonly used estimate of the thermal conductivity of the core is shown plausibly to be too high and in any case to be uncertain by perhaps a factor of 2 the geochemical difficulties associated with postulating radioactive heat sources in the core are stressed

structural geometry of an exhumed uhp terrane in the eastern sulu orogen china implications for continental collisional processes high precision 1 200 1 1000 mapping of yangkou bay eastern sulu orogen defines the structural geometry and history of one of the world s most significant uhp ultrahigh pressure belts at least four stages of folds are recognized in uhp eclogites and associated quartzo feldspathic gneiss uhp eclogite facies rootless f1 and isoclinal f2 folds are preserved locally in coesite eclogite mylonitic to ultramylonitic quartzo feldspathic and coesite eclogite shear zones separate small scale 5 10 m thick nappes of ultramafic mafic uhp rocks from banded quartzo feldspathic gneiss these shear zones are folded and progressively overprinted by amphibolite greenschist facies shear zones the prograde to retrograde d1 d5 deformation sequence is explained by deep subduction of offscraped thrust slices of lower continental or oceanic crust from the down going plate caught between the colliding north and south china cratons in the mesozoic after these slices were structurally isolated along the plate interface they were rolled in the subduction channel during exhumation and structural juxtaposition with quartzo feldspathic gneisses forming several generations of folds sequentially lower grade foliations and lineations and intruded by in situ and exotically derived melts shear zones formed during different deformation generations are wider with lower grades suggesting that deep crustal upper mantle deformation operates more efficiently perhaps with more active crystallographic slip systems than deformation at mid upper crustal levels

u pb hf and o isotope evidence for two episodes of fluid assisted zircon growth in marble hosted eclogites from the dabie orogen abstract a combined study of internal structure u pb age and hf and o isotopes was carried out for metamorphic zircons from ultrahigh pressure eclogite boudins enclosed in marbles from the dabie orogen in china cl imaging identifies two types of zircon that are metamorphically new growth and recrystallized domain respectively the metamorphic zircons have low th and u contents with low th u ratios yielding two groups of 206 pb 238 u age at 245 3 to 240 2 ma and 226 4 to 223 2 ma respectively anomalously high 18 o values were obtained for refractory minerals with 9 9 to 21 4 for garnet and 16 9 for zircon this indicates that eclogite protolith is sedimentary rocks capable of liberating aqueous fluid for zircon growth during continental subduction zone metamorphism most of the zircons are characterized by very low 176 lu 177 hf ratios of 0 000001 0 000028 indicating their growth in association with garnet recrystallization a few of them falling within the older age group have comparatively high 176 lu 177 hf ratios of 0 000192 0 000383 suggesting their growth prior to the formation of garnet in the late stage of subduction the variations in the lu hf ratios for zircons can thus be used to correlate with garnet growth during eclogite facies metamorphism in either case the zircons have variable e hf t values for individual samples suggesting that their protolith is heterogeneous in hf isotope composition with localized fluid availability in the bulk processes of orogenic cycle nevertheless a positive correlation exists between 206 pb 238 u ages and lu hf isotope ratios for the metamorphically recrystallized zircons suggesting that eclogite facies metamorphism in the presence of fluid has the identical effect on zircon lu hf and u th pb isotopic systems we conclude that the zircons of the older group grew in the presence of fluid during the subduction prior to the onset of peak ultrahigh pressure metamorphism whereas the younger zircons grew in the presence of fluid released during the initial exhumation toward high pressure eclogite facies regime

fluid generation and evolution during exhumation of deeply subducted uhp continental crust petrogenesis of composite granite quartz veins in the sulu belt china

complete miscibility between silicate melts and hydrous fluids in the upper mantle experimental evidence and geochemical implications the phase relationships between silicate melts and hydrous fluids were studied by direct visual observation in an externally heated diamond anvil cell complete miscibility of silicate melt and water was observed for a wide range of melt compositions including nepheline jadeite dacite haplogranite and ca bearing granite some evidence for complete miscibility was also observed in the system basalt h2o the critical temperatures in all systems decrease rapidly with pressure at 15 kbar the critical temperature for nepheline is around 550 c for jadeite around 800 c and for granitic compositions it is close to 900 c in general the critical temperatures appear to increase with silica content in the system our results suggest that there is complete miscibility between silicate melts and water in most of the upper mantle except at very shallow depths this means that a water saturated solidus cannot be defined any more in the deeper parts of the upper mantle very silica rich melt inclusions found in spinel lherzolites associated with fluid inclusion are probably the result of the unmixing of a supercritical fluid containing comparable amounts of water and silicate components the decomposition of amphibole in a subducted slab occurs at conditions where the miscibility gap between fluid and silicate melt is not yet closed while the decomposition of phengite and lawsonite occurs far beyond the critical curve accordingly the fluids released by the breakdown of these minerals should have very different properties highly mobile hydrous fluids containing little dissolved silicate should be produced by amphibole breakdown while the decomposition of lawsonite and phengite will lead to much more silicate rich and less mobile fluid phases

primary fluids entrapped at blueschist to eclogite transition evidence from the tianshan meta subduction complex in northwestern china the tianshan is the first locality worldwide where primary fluids at blueschist to eclogite transition have been documented veins containing high pressure minerals in massive host eclogites transitional to blueschists or eclogite boudins surrounded by blueschists indicate that a free fluid phase was present at the time of eclogitization the high pressure veins are predominantly composed of omphacite fibers with minor quartz or calcite the transition from blueschist to eclogite facies parageneses occurs as dehydration halos around these veins clinozoisite paragonite glaucophane and omphacite inclusions preserved in garnet porphyroblasts in wall eclogites document the transformation of blueschist to eclogite c axis parallel non planar populations of fluid inclusions were trapped during the growth of omphacite in high pressure veins and dehydrated wall rocks low salinity h2o nacl solid bearing inclusions are preserved in omphacite fibers in veins and matrix omphacite of wall rocks none of the isochores of these low salinity aqueous fluid inclusions intersect peak eclogite facies metamorphic conditions suggesting that although the textural evidence constrains the entrapment of fluid inclusions to peak metamorphic conditions their densities must have been modified during exhumation the fluids are interpreted to have been derived from the host blueschist as a result of dehydration reactions such as 13 gln 5 czo 9 prp 26 jd 12 di 19 qtz 15 h2o and gln pg prp 3 jd 2 otz 2 h2o the similarity of vein and wall rock mineral compositions fluid inclusion characteristics and o isotope data also favor an internal source for the fluids the major element composition of veins indicate that si na and ca rich aqueous fluids were released during dehydration at a depth of 50 10 km within a paleozoic subduction zone

assessing the age weathering correspondence of cosmogenic 21ne dated pleistocene surfaces by the schmidt hammer the schmidt hammer sh method is used to quantify the rock weathering degree and has been proposed as a relative dating tool terrestrial cosmogenic nuclide tcn methods provide absolute exposure ages for erosive surfaces few works combine both methods for surfaces older than the holocene we compare data obtained by both methods for c 150 ka bp glacial and fluvial erosive granite surfaces from northwest spain rebound values r have been firstly compared with the rock density to assess the correlation with the rock strength independently from influence of factors such as wetness and roughness in the r values for erosive glacial surfaces older than 100 ka r values are confined in a narrow range with no differences within errors stepped fluvial surfaces of 700 m to 70 m above present sea level show an inverse correspondence between tcn ages and r values although no age predictions can be done on the basis of the r values thus age inferences exclusively based on r values may not be realistic but sh studies could be a useful tool for selecting surfaces for tcn dating copyright 2009 john wiley sons ltd

petrofabrics and seismic properties of garnet peridotite from the uhp sulu terrane china implications for olivine deformation mechanism in a cold and dry subducting continental slab abstract lattice preferred orientations lpo of olivine diopside enstatite and garnet from the zhimafang garnet peridotite body in the sulu ultrahigh pressure uhp metamorphic terrane china were measured using the electron backscatter diffraction ebsd technique the peridotite was captured from a mantle wedge immediately adjacent the subducted yangtze slab and then experienced the uhp metamorphism at 750 950 c and 4 7 gpa the olivine lpo is characterized by the 001 axis close to the stretching lineation and the 100 plane subparallel to the foliation indicating the prevailing of 100 001 slip enstatite lpo displays the dominance of 100 001 slip diopside developed complex lpo patterns that are difficult to explain using a single slip system of 100 001 garnet is almost randomly oriented due to its low volume fractions cubic symmetry and the presence of numerous slip systems calculated seismic properties of the peridotite yield a maximum p wave velocity normal to the foliation and a minimum along the foliation with anisotropy up to 8 in strongly sheared samples the s wave velocity pattern is complex but the fast polarization plane generally normal to the foliation the inferred shear sense from the olivine lpo is top to se in contrary to exhumation induced top to nw thrusting recorded in the quartz lpo implying that the olivine lpo formed at early uhp metamorphic conditions the olivine crystals have relatively low water contents 141 475 h 106 si indicating a fluid deficient environment for the lpo formation the present study suggests that a combination of low temperature and uhp plays a much more important role than the water content to promote the activation of 100 001 slip in olivine

raman confirmation of microdiamond in the svartberget fe ti type garnet peridotite western gneiss region western norway introductionvestiges of ultra high pressure meta morphism uhpm havebeenfoundincontinental and oceanic rocks of dif ferentorogensworldwide smith 1988 coleman and wang 1995 carswelland compagnoni 2003 indirectuhpmevidencecomesfromtheappli cation of geothermobarometric tech niques lappin and smith 1978 ravna krogh and paquin 2003 ap plied to uhpm mineral assemblagesand directly from mineralogical indi cators such as coesite diamond andmajoritic garnet chopin 1984 smith 1984 sobolev and shatsky 1990 do brzhinetskaya et al 1995 van roer mund and drury 1998 nasdala andmassonne 2000 mposkos andkosto poulos 2001 van roermund et al 2002 godard et al 2003 neverthe less the mechanisms responsible forthe formation preservation and exhu mation of uhpm rocksin orogens arestill not fully understood the volume and spatial distributionof uhpm rocks within uhpm terr anes including the observed contrastin metamorphic grade between rocksthat contain uhpm minerals andadjacent country rocks that do notcontain them have led to di erentexplanations concerning the origin emplacement and preservation ofthese rocks to explain the occur rence volume and areal extent ofuhpm rocks in the western gneissregion wgr the following mecha nisms that assume a continental sub duction scenario have been proposed a the existence of major and orminor post uhpm tectonic contactssuch as nappes and or tectonic mel anges e g lappin and smith 1978 smith 1984 1988 wain 1997 cuth bert et al 2000 terry and robinson 2003 2004 or b the presence of uids and or deformation leading todi erential prograde or retrogradereactions and di erences in reaction kinetics between rock types austr heim et al 1997 cuthbert et al 2000 wain et al 2001 carswell andcuthbert 2003 cuthbert and car swell 2003 hypotheses that do notnecessarily involve continental sub duction may involve local regional tectonic overpressure in rocks smith 1984 mancktelow 1993 petrini and podladchikov 2000 it isconsidered here that the volume andareal extent of uhpm domains withina single metamorphic terrain are thusimportant parameters to determine asthey can modify or identify the loca tions of inferred or observed tectoniccontacts the relations between uidsand uhpm and or the scales atwhich continental crust subductionor tectonic overpressure might act here we report raman data thatcon rm the previously reported butnot proven presence of microdia monds at the svartberget uhpmlocality in the wgr of norway vrijmoed et al 2006 micro diamond con rmation is consistentwith the results of vrijmoed et al 2006 that the volume and arealextent of the northern uhpm domainof the wgr fig 1 are considerablyexpanded eastwards and followingthe reasoning in the paragraph above the new microdiamond nding willput important constraints on themodels described above ultra high pressure metamorphismin the western gneiss regionthe wgr represents a window inthe scandinavian caledonides wherescandian reworked high grade gneis sic rocks of proterozoic age presum ably belonging to the baltic plate are exposed in addition variableamounts of metadolerites amphi abstract

heterogeneity of water in garnets from uhp eclogites eastern dabieshan china abstract garnets in uhp eclogites from bixiling in dabieshan were investigated by fourier transform infrared spectroscopy ftir the results indicate that all garnets contain structural water that occurs as hydroxyl oh and non structural molecular water h 2 o possibly in the form of sub microscopic fluid inclusions the structural hydroxyl contents range from 92 to 1735 ppm h 2 o wt and most are between 200 and 1000 ppm therefore garnet in eclogite can recycle surface water into the mantle various water contents were observed among different samples of the same outcrop 150 m and in different domains of the same sample 1 cm this variability in structural h 2 o contents suggests that the mobility of fluids during uhp metamorphism was very limited and that both subduction and exhumation processes of uhp rocks occurred in a short time interval

record of multiple stage channelized fluid and melt activities in deeply subducted slab from zircon u pb age and hf o isotope compositions abstract geochemical features of island arc rocks require two slab derived components of a melt and a fluid added to their sources these two liquids may unite to an intermediate aqueous melt at the base of volcanic arc direct evidence of this process has been scarce yet here we present an integrated study of in situ u pb age trace element and o hf isotope for zircons from a suite of a quartz vein a felsic vein their host eclogite and surrounding gneiss at the xitieshan uhp terrane of the north qaidam metamorphic belt nqmb oscillatory zoned zircons from the quartz vein are enriched in u li nb and ree with a formation age of 442 6 ma consistent with the timing of the peak uhp metamorphism this demonstrates there is no temporal gap between the uhp metamorphism and fluid flow in the xitieshan terrane in particular the oscillatory zoned zircons of the quartz vein have similar hf isotope compositions to zircons from the surrounding gneiss but variable o isotope compositions between the host eclogite and surrounding gneiss the fluid from surrounded gneiss was thus an aqueous melt with high transport ability for lu and hf and o while the fluid from the host eclogite was an aqueous fluid only with the ability to transport o according to the similar behaviors of granitic rock and sediment it is inferred that a channelized hydrous melt can be formed in the downgoing sediment layer where an aqueous fluid can be formed from underlying basalt and or peridotite layers at the sub arc depth the two types of fluid are fed to the overlying mantle wedge from subducting slab to form island arc rock by contrast the zircons in the felsic vein yield a weighted mean 206pb 238u age of 420 4 ma which can be regard as the timing of partial melting during the exhumed stage for the xitieshan uhp rocks the zircon o and hf isotopic features of the felsic vein are between the country gneiss and host eclogite compatible with their emanating from hydrous melt of both the eclogite and gneiss during the exhumation stage of the uhp rocks this indicates that hydrous melt would be released from both the sediment and basalt or peridotite layers of the subducting slabs at relatively shallow depth

metamorphic growth and recrystallization of zircons in extremely 18o depleted rocks during eclogite facies metamorphism evidence from u pb ages trace elements and o hf isotopes abstract a combined in situ sims and la mc icpms study of u pb ages trace elements o and lu hf isotopes was conducted for zircon from eclogite facies metamorphic rocks in the sulu orogen the two microbeam techniques sampled various depths of zircon domains revealing different element and isotope relationships between residual magmatic cores and new metamorphic rims and thus the geochemical architecture of metamorphic zircons which otherwise cannot be recognized by the single microbeam technique this enables discrimination of metamorphic growth from different subtypes of metamorphic recrystallization magmatic cores with u pb ages of 769 9 ma have positive 18o values of 0 1 10 1 high th u and 176lu 177hf ratios high ree contents and steep mree hree patterns with negative eu anomalies they are interpreted as crystallizing from positive 18o magmas during protolith emplacement in contrast newly grown domains have concordant u pb ages of 204 4 to 252 7 ma and show negative 18o values of 10 0 to 2 2 low th u and 176lu 177hf ratios low ree contents and flat hree patterns with weak to no eu anomalies they are interpreted as growing from negative 18o fluids that were produced by metamorphic dehydration of high t glacial hydrothermally altered rocks during continental subduction zone metamorphism differences in 18o between different domains within single grains vary from 0 8 to 12 5 suggesting different degrees of o isotope exchange between the positive 18o magmatic core and the negative 18o metamorphic fluid during the metamorphism the magmatic zircons underwent three subtypes of metamorphic recrystallization depending on their accessibility to negative 18o fluids the zircons recrystallized in solid state maintained positive 18o values and ree and lu hf isotopes of protolith zircon but their u pb ages are lowered the zircons recrystallized through dissolution exhibit negative 18o values similar to the metamorphic growths almost completely reset u pb ages and partially reset ree systems the zircons recrystallized through replacement show variably negative 18o values and partially reset ree and u pb and lu hf isotopic systems therefore this study places robust constraints on the origin of metamorphic zircons in eclogite facies rocks and provides a methodological framework for linking the different types of metamorphic zircons to petrological processes during continental collision