syndeformational fluid trapping in quartz determining the pressure temperature conditions of deformation from fluid inclusions and the formation of pure co2fluid inclusions during grain boundary migration observations and microthermometric data on fluid inclusions from a terrane that underwent deformation following peak metamorphic conditions show that grain boundary migration recrystallization favours the entrapment of carbonic inclusions whereas microfracturing during brittle deformation favours the infiltration and eventual entrapment of aqueous fluids our results imply that pure co2 fluid inclusions in metamorphic rocks are likely to be the residue of deformation recrystallization process rather than representing a primary metamorphic fluid where the temperature of deformation can be deduced by other means the densities of fluid inclusions trapped during recrystallization which we call recrystallization primary fluid inclusions can be used to constrain the ambient pressure during deformation using these constraints the data imply that the post metamorphic hercynian exhumation in sardinia brought rocks at 300 c to within 3km of the surface this conclusion is similar to that described for the rapidly uplifted southern alps in new zealand

recurrent morphogenic earthquakes in the past millennium along the strike slip yushu fault central tibetan plateau abstract the magnitude m w 6 9 m s 7 1 yushu earthquake of 14 april 2010 ruptured the yushu fault of the preexisting strike slip ganzi yushu fault zone which is an extension of the xianshuihe fault the earthquake resulted in widespread damage in high mountain regions of the central tibetan plateau field surveys and analyses of an excavated trench and outcrop reveal that three morphogenic earthquakes have occurred on the yushu fault in the past millennium paleoseismic evidence historical records and radiocarbon age data show that 1 the penultimate large magnitude earthquake i e prior to the 2010 yushu earthquake occurred within the past 570 yr corresponding to the 1738 m 7 1 earthquake and 2 the third most recent event occurred between a d 650 and a d 1100 suggesting a recurrence interval of 450 680 yr for large earthquakes associated with surface rupture of the yushu fault in the past millennium an average slip rate of 2 5 mm yr is estimated for the yushu fault these results are consistent with those obtained from long term geological evidence and gps observations most of the strain energy on the ganzi yushu fault zone resulting from northeastward motion of the tibetan plateau in response to north south shortening of the plateau due to ongoing northward penetration of the indian plate into the eurasian plate is released as seismic slip

present day south american climate abstract this paper documents the main features of the climate and climate variability over south america on the basis of instrumental observations gathered during the 20th century it should provide a modern reference framework for paleoclimate research in south america targeting high resolution proxies over the past few centuries several datasets suitable for present day climate research are first described highlighting their advantages as well as their limitations we then provide a basic physical understanding of the mean annual cycle of the precipitation and atmospheric circulation over the continent and the adjacent oceans in particular the diversity of precipitation temperature and wind patterns is interpreted in terms of the long meridional extent of the continent and the disruption of the large scale circulation caused by the andes cordillera the contrasting oceanic boundary conditions and the landmass distribution similarly the intensity and timing of the interannual and interdecadal climatic fluctuations exhibit considerable geographical dependence as some regions are more influenced by large scale phenomena rooted in the tropical oceans while others are more influenced by high latitude phenomena the impact of these large scale phenomena over south america is documented by a regression analysis between selected atmospheric indices and the precipitation and temperature fields we have included a discussion on the seasonality and long term stability of such impacts and complemented our general description by an updated review of the literature on climate variability over specific regions

statistical microthermometry of synthetic fluid inclusions in quartz during decompression reequilibration fluid inclusion microthermometric data are often reported as homogenization temperature frequency histograms interpretation of such histograms for a single fluid inclusion assemblage fia of non reequilibrated fluid inclusions is usually straightforward and provides an accurate determination of the original density th of that fia however interpretation of such histograms for reequilibrated inclusions is more problematic decompression experiments using synthetic inclusions in natural quartz and conducted at 2 5 kbar and 600 700 c with a maximum internal overpressure of 2 kbar indicate that histogram shape reflects the sample s p t history our results further indicate that the mean mode range standard deviation extreme values etc all have a significance with respect to the p t history of the sample thus a mound shaped unimodal histogram with low range is indicative of a nearly isochoric cooling p t path a unimodal histogram that is slightly skewed to the right and with a low standard deviation but high range results from inclusion deformation in the plastic regime high temperature low strain rates fluid inclusions deformed plastically show no correlation between size and density histogram outliers should not be ignored and may be used to determine an isochore that passes close to the conditions of entrapment minimum th or close to the final reequilibration conditions maximum th the histogram mean th value corresponds to an isochore that represents the internal overpressure about 1 kbar that can be maintained over geologic time by a majority of reequilibrated fluid inclusions a multimodal histogram with high range and high standard deviation indicates inclusion brittle deformation low temperature high strain environments fluid inclusions deformed in a brittle manner show strong positive correlation between size and density histograms produced in the laboratory show many similarities to histograms for natural samples offering the hope that laboratory results may be used to interpret p t histories of natural samples

synthetic fluid inclusions vii re equilibration of fluid inclusions in quartz during laboratory simulated metamorphic burial and uplift p t conditions inferred from fluid inclusions in metamorphic rocks often disagree with the values predicted from mineral equilibria calculations these observations suggest that inclusions formed during early stages of regional metamorphism continue to re equilibrate during burial and subsequent uplift in response to differential pressure p t conditions accompanying burial and uplift were experimentally simulated by initially forming pure h2o inclusions in quartz at elevated temperatures and pressures and then re equilibrating the inclusions in the presence of a 20 wt nacl solution such that final confining pressures ranged from 5 kbar above to 4 kbar below the initial internal pressure of the inclusions at the temperature of re equilibration in all samples re equilibrated at confining pressures below the internal pressure some inclusions were formed that had compositions of 20 wt nacl and densities in accord with the final p t conditions additionally some inclusions were observed to contain fluids of intermediate salinities between 0 and 20 wt nacl densities of these inclusions were also consistent with formation at the re equilibration p t conditions the remainder of the fluid inclusions observed in these samples contained pure h2o and their homogenization temperatures corresponded to densities intermediate between the initial and final p t conditions in short term experiments 7 days where the initial internal overpressure exceeded 1 kbar no inclusions were found that contained the original density and none were found to have totally re equilibrated instead most h2o inclusions re equilibrated until their internal pressures were between 750 and 1500 bars above the confining pressure regardless of the initial pressure differential in a long term experiment 52 days inclusions re equilibrated at a lower confining pressure than the initial internal pressure displayed homogenization temperatures corresponding to a range in final internal pressures between 0 kbar i e total re equilibration and 1 2 kbar above the confining pressure in experiments where the confining pressure during re equilibration exceeded the initial internal pressure densities of pure h2o inclusions increased to values intermediate between the initial and final p t conditions additionally these inclusions were generally surrounded by a three dimensional halo of smaller inclusions also of intermediate density resulting in a texture similar to that previously ascribed to decrepitation from internal overpressure in extreme cases where confining pressures were 4 5 kbar above the initial pressure the parent inclusion almost completely closed leaving only the three dimensional array of small 5 m inclusions the outline of which may be several times the volume of the original inclusion groups of such inclusions closely resemble textures commonly observed in medium to high grade metamorphic rocks inclusions containing 10 and 42 wt nacl solutions trapped at 600 c and 3 kbar were re equilibrated at 600 c and 1 kbar for 5 days in dry argon to evaluate the importance of h2o diffusion as a mechanism of lowering the inclusion bulk density salinities of re equilibrated inclusions obtained from freezing point depressions and halite dissolution temperatures indicate that original compositions were preserved density changes similar to those previously described were noted in these experiments in inclusions showing no visible microfractures therefore density variations observed in inclusions in this study re equilibrated under rapid deformation conditions are considered to result from a change in the inclusion volume without significant loss of contents by diffusion or leakage

the evolution of the patagonian ice sheet from 35 ka to the present day patice abstract we present patice a gis database of patagonian glacial geomorphology and recalibrated chronological data patice includes 58 823 landforms and 1 669 geochronological ages and extends from 38 s to 55 s in southern south america we use these data to generate new empirical reconstructions of the patagonian ice sheet pis and subsequent ice masses and ice dammed palaeolakes at 35 ka 30 ka 25 ka 20 ka 15 ka 13 ka synchronous with the antarctic cold reversal 10 ka 5 ka 0 2 ka and 2011 ad at 35 ka the pis covered of 492 6 x103 km2 had a sea level equivalent of 1 496 mm was 350 km wide and 2090 km long and was grounded on the pacific continental shelf edge outlet glacier lobes remained topographically confined and the largest generated the suites of subglacial streamlined bedforms characteristic of ice streams the pis reached its maximum extent by 33 28 ka from 38 s to 48 s and earlier around 47 ka from 48 s southwards net retreat from maximum positions began by 25 ka with ice marginal stabilisation then at 21 18 ka which was then followed by rapid irreversible deglaciation by 15 ka the pis had separated into disparate ice masses draining into large ice dammed lakes along the eastern margin which strongly influenced rates of recession glacial readvances or stabilisations occurred at least at 14 13 ka 11 ka 6 5 ka 2 1 ka and 0 5 0 2 ka we suggest that 20th century glacial recession a 1 is occurring faster than at any time documented during the holocene

response and feedback of the indian summer monsoon and the southern westerly winds to a temperature contrast between the hemispheres during the last glacial interglacial transitional period abstract the hypothesis that an interhemispheric thermal gradient or a temperature contrast between the hemispheres tcbh drives shifts in the latitudinal position of the intertropical convergence zone itcz and the southern westerly winds sww is considered one of the most important climate change mechanisms proposed in the last few decades however the controversy over the shifting magnitude and direction of the itcz and the sww brings uncertainty to the hypothesis here we further examine the shifting characteristics of the itcz and its relationship with the intensity variation of the indian summer monsoon ism based on synthesis and summary of previously published literature data in particular we evaluate regional distribution patterns of the dry and wet climatic changes in southern south america during the last glacial interglacial transitional period including the heinrich event 1 the antarctic cold reversal and the younger dryas the results show that in response to the northern hemisphere wide cooling and the southern hemisphere wide warming the northern hemisphere wide warming and the southern hemisphere wide cooling during the period the itcz over the asian and northern south american continents and the sww shift poleward equatorward while the intensity of the ism decreases increases however the shifting characteristics of the itcz over the vast pacific ocean remain unclear which implies that the relationship between the tcbh and the el nino southern oscillation in the tropical pacific ocean needs to be studied in addition there may be a relatively stable core region in the sww this core region is located in central patagonia at approximately 47 s where the local climate is wetter during the all transition period showing the continuous influence of the sww on this region the position shift of the sww in response to the tcbh phase changes seems to behave as a swing process with an axis of approximately 47 s the poleward swing of the sww may trigger the self repairing process of the global climate system after the catastrophic impacts of the meltwater including the pulling effect of the enhanced upwelling on the atlantic meridional overturning circulation the influence of co2 released from the deep sea and the impact of the gradual strengthening of the ism these results support and reinforce the hypothesis that the tcbh drives global climate change highlight the global teleconnection characteristics of the key physical processes in the earth s climate system and the important role of the sww in this teleconnection and provide a basis for further simulating the climate connections in the two hemispheres especially the impact of the sww on the global climate change

abrupt vegetation changes during the last glacial to holocene transition in mid latitude south america a pollen record from the huelmo site ca 41 30 s shows that vegetation and climate changed at millennial time scales during the last glacial to holocene transition in the mid latitude region of western south america the record shows that a nothofagus parkland dominated the landscape between 16 400 and 14 600 14c yr bp along with magellanic moorland and cupressaceous conifers evergreen north patagonian rainforest taxa expanded in pulses at 14 200 and 13 000 14c yr bp following a prominent rise in nothofagus at 14 600 14c yr bp highly diverse closed canopy rainforests dominated the lowlands between 13 000 and 12 500 14c yr bp followed by the expansion of cold resistant podocarps and nothofagus at ca 12 500 and 11 500 14c yr bp local disturbance by fire favoured the expansion of shade intolerant opportunistic taxa between 10 900 and 10 200 14c yr bp subsequent warming pulses at 10 200 and 9100 14c yr bp led to the expansion of thermophilous summer drought resistant valdivian rainforest trees until 6900 14c yr bp our results suggest that cold and hyperhumid conditions characterised the final phase of the last glacial maximum lgm between 16 400 and 14 600 14c yr bp the last ice age termination commenced with a prominent warming event that led to a rapid expansion of north patagonian trees and the abrupt withdrawal of andean ice lobes from their lgm positon at ca 147 000 14c yr bp hyperhumid conditions prevailed between 16 400 and 13 000 14c yr bp what we term the extreme glacial mode of westerly activity this condition was brought about by a northward shift and or intensification of the southern westerlies the warmest driest conditions of the last glacial interglacial transition occurred between 9100 and 6900 14c yr bp during this period the westerlies shifted to an extreme interglacial mode of activity via a poleward migration of stormtracks our results indicate that a highly variable climatic interval lasting 5500 14c years separate the opposite extremes of vegetation and climate during the last glacial interglacial cycle i e the end of the lgm and the onset of the early holocene warm and dry period copyright 2003 john wiley sons ltd

climatic and lacustrine morphometric controls of diatom paleoproductivity in a tropical andean lake abstract the coupling of lake dynamics with catchment biogeochemistry is considered the key element controlling primary production in mountain lakes at time scales of a few decades to millennia yet little is known on the impacts of the morphometry of lakes throughout their ontogeny as lake chungara central andean altiplano northern chile experienced long term lake level fluctuations that strongly modified its area volume ratio it is an ideal system for exploring the relative roles that long term climatic shifts and lake morphometry play on biosiliceous lacustrine productivity in this paper we review previous data on the percent contents of total organic carbon total inorganic carbon total nitrogen total biogenic silica isotopic composition of organic matter carbonates and diatom frustules as well as data on the abundance of the chlorophycean botryococcus braunii in this lake for the period 12 400 1300 cal yr bp we also include new data on organic carbon and biogenic silica mass accumulation rates and the diatom assemblage composition of an offshore core dated using 14 c and u th biosiliceous productivity in lake chungara was influenced by shifts in allochthonous nutrient inputs related to variability in precipitation humid phases dated at approx 12 400 to 10 000 and 9600 to 7400 cal yr bp coincide with periods of elevated productivity whereas decreases in productivity were recorded during arid phases dated at approx 10 000 to 9600 and 7400 to 3550 cal yr bp andean mid holocene aridity period however morphometry related in lake controls led to a lack of a linear response of productivity to precipitation variability during the late glacial to early holocene lowstands facilitated complete water column mixing prompting episodic massive blooms of a large centric diatom cyclostephanos cf andinus thus moderate productivity could be maintained regardless of aridity by this phenomenon of morphometric eutrophy during the early history of the lake the subsequent net increase in lake level introduced modifications in the area of the epilimnion sediments versus the total volume of the epilimnion preventing complete overturn surpassing a certain depth threshold at approx 8300 cal yr bp caused cessation of the morphometric eutrophy conditions associated with cyclostephanos cf andinus superblooms after 7300 cal yr bp the lake experienced a decrease in biosiliceous productivity and a change of state that involved a stronger dependence on precipitation variability with a lesser contribution of diatoms to the total primary productivity our results show that the interpretation of lacustrine paleoproductivity records as paleoclimatic archives needs to take into account the effects of changes in the epilimnion sediment area to epilimnion volume ratio in association with lake ontogeny

interpreting modern and fossil pollen data along a steep environmental gradient in northern patagonia vegetation reconstructions rest on modern vegetation pollen rain relationships and deductive reasoning establishing this relationship is a nontrivial task because differences among pollen assembla

a 14kyr record of the tropical andes the lago chungara sequence 18 s northern chilean altiplano abstract high resolution geochemical analyses obtained using an x ray fluorescence xrf core scanner as well as mineralogical data from the lago chungara sedimentary sequence in the northern andean chilean altiplano 18 s provided a detailed reconstruction of the lacustrine sedimentary evolution during the last 14 000 cal yr bp the high resolution analyses attained in this study allowed to distinguish abrupt periods identify the complex structures of the early and mid holocene arid intervals and to compare their timing with titicaca lake and sajama ice records three main components in the lake sediments have been identified a biogenic component mainly from diatoms b volcanics ash layers from the nearby parinacota volcano and c endogenic carbonates the correlation between volcanic input in lago chungara and the total particles deposited in the nevado sajama ice core suggests the parinacota volcano as the common source the geochemical record of lago chungara indicates an increase in siliceous productivity during the early holocene lagging behind the rise in temperatures inferred from the nevado sajama ice core the regional mid holocene aridity crisis can be characterized as a number of short events with calcite and aragonite precipitation in the offshore lake zones

climatic controls of holocene fire patterns in southern south america holocene fire climate vegetation linkages are mostly understood at individual sites by comparing charcoal and pollen records with other paleoenvironmental proxy and model simulations this scale of reconstruction often obscures detection of large scale patterns in past fire activity that are related to changes in regional climate and vegetation a network of 31 charcoal records from southern south america was examined to assess fire history along a transect from subtropic to subantarctic biomes the charcoal data indicate that fire activity was greater than present at ca 12 000 cal yr bp and increased further and was widespread at 9500 cal yr bp fire activity decreased and became more spatially variable by 6000 cal yr bp and this trend continued to present atmospheric circulation anomalies during recent high fire years show a southward shift in westerlies and paleoclimate model simulations and data syntheses suggest that such conditions may have prevailed for millennia in the early holocene when the pole to equator temperature gradients were weaker and annual temperatures were higher than present in response to orbital time scale insolation changes

climatic and disturbance influences on the temperate rainforests of northwestern patagonia 40 s since 14 500 cal yr bp abstract we present a detailed record from lago pichilafquen to unravel the vegetation climate and disturbance history of the lowlands of northwestern patagonia 40 s since 14 500 cal yr bp the presence of 30 tephras throughout the record attest for the proximity of the site to active volcanic centres and allows assessment of the role of volcanic disturbance on past vegetation and fire regime shifts we interpret alternations in dominance between north patagonian and valdivian rainforests driven by changes in temperature and precipitation of westerly origin at multi millennial and millennial timescales these trends were punctuated by centennial scale changes most of which were coeval with or immediately followed the deposition of tephras and or paleofires we identify departures of the local vegetation from the regional trend between 2400 and 7100 cal yr bp which we interpret as a response of rainforest vegetation and local fire regimes to the disturbance effect of tephra deposition near lago pichilafquen we also find that volcanic disturbance promoted consistent increases in eucryphia caldcluvia within 30 years and paleofires between 60 and 120 years following tephra deposition comparisons with palynological records having similar span time resolution and age control suggest that regional climate has played a central role on the establishment composition and maintenance of temperate rainforests this influence is overprinted by disturbance regimes at the local and landscape level driving divergences and heterogeneity especially at times of relatively weak climatic forcing

a 7000 year high resolution lake sediment record from coastal central chile lago vichuquen 34 s implications for past sea level and environmental variability we present a 7 ka environmental reconstruction based on sedimentological and geochemical data from lago vichuquen a coastal eutrophic lake in central chile 34 48 s 72 03 w 4 m a s l a relatively shallow and restricted marine environment with low productivity high detrital input and dominant anoxic conditions in the vichuquen basin occurred from 7 0 to 6 5 cal ka bp rapid onset of a holocene marine transgression at 6 5 cal ka bp favoured deeper and more biologically productive environments that existed until 2 8 cal ka bp bioproductivity changes during the mid holocene 6 5 4 2 cal ka bp were related to upwelling dynamics controlled by the intensity of the south east pacific anticyclone spa periods with lower organic productivity and dominant anoxic conditions reflect an increased intensity of spa increased upwelling and decreased precipitation a shift at 4 0 cal ka bp reflects the onset of modern southern westerly winds and el nino southern oscillation patterns tectonic uplifting and geormorphological activity dune advancement are possible reasons behind the vichuquen basin closure at 1 2 cal ka bp leading to a low bioproductivity lacustrine environment which has developed until the present

mid latitude trans pacific reconstructions and comparisons of coupled glacial interglacial climate cycles based on soil stratigraphy of cover beds abstract south westland new zealand and southern chile are two narrow continental corridors effectively confined between the pacific ocean in the west and high mountain ranges in the east which impart significant influence over regional climate vegetation and soils in both these southern mid latitude regions evidence for extensive and repeated glaciations during cold phases of the quaternary is manifested by arrays of successively older glacial drift deposits with corresponding outwash plain remnants in south westland these variably aged glacial landforms are mantled by layered multisequal soils characterised by slow loess accretion and pedogenesis in an extreme leaching and weathering environment these cover bed successions have undergone repeated coupled phases of topdown and upbuilding soil formation that have been related to fluctuating cycles of interglacial warm and glacial cold climate during the quaternary in this study we recognise multisequal soils overlying glacial landforms in southern continental chile but unlike the spodic podzolic soil sequences of south westland these are of dominantly volcanigenic andic provenance and are very similar to multisequal soils of andic provenance that predominate in and adjacent to areas of rhyolitic to andesitic volcanism in north island new zealand here we develop a soil stratigraphic model to explain the observed occurrence of multisequal soils mantling dominantly glacial landforms of southern continental chile based on proxy data from southern chile we propose that persistent vegetation cover and high precipitation on the western side of the andes during colder than present episodes tended to suppress the widespread production of glacially derived loessial materials despite the pervasive occurrence of glacial and glacio fluvial deposits that have frequently inundated large tracts of this landscape during the quaternary given the lack of loess cover beds that have traditionally assisted in the relative dating of glacial episodes prior to the late quaternary surface exposure dating techniques could provide another chronological alternative to address this issue however there have been two main obstacles to successfully apply this dating technique in patagonia first minimum exposure ages may be obtained on moraines older than the last glacial cycle due to erosion although dating outwash plains is more robust second on the wet western side adjacent to the andes persistent vegetation cover during both glacial and post glacial times as well as widespread inundation by volcanic mass flows appear preventive we make a case that soil genesis within this region appears to be dominated by a constant flux of intermittently erupted andean sourced tephra which has continued to upbuild soils at the ground surface separated by intervals where topdown weathering processes are intensified as already demonstrated by new zealand studies multisequal soil successions have a clear implied connection to coupled glacial and interglacial climate cycles of the quaternary on this basis similar sequences in northwest patagonia provide a relatively untapped archive to enable quaternary glacial and environmental changes in this pervasively glaciated volcanic region to be constructed

post entrapment modification of fluid inclusions due to overpressure evidence from natural samples effects of post entrapment fluid inclusion modification are examined with reference to retrogression related quartz veins from the caledonian ose thrust northern norway the inclusions occur in secondary trails and contain high density hypersaline aqueous fluids on morphological characteristics they are subdivided into type a elongate ellipsoidal and or irregular inclusions and type b more equant regular and or negative crystal form with reference to previous research on post entrapment modification of inclusions in quartz it is proposed that type a inclusions experienced little or no post entrapment modification whereas type b inclusions show features characteristic of post entrapment permanent inelastic stretching and or leakage this produces increased homogenization temperatures th associated with increased inclusion volume and lowering of density whilst maintaining constant salinity the similarity of data for degree of fill and salinity between type a and type b inclusions indicates that type b inclusions have primarily modified by stretch rather than leakage however the spread towards slightly larger volume of vapour in type b inclusions suggests that some leakage has also occurred because stretched and or partially leaked inclusions have increased th isochore projections significantly underestimate trapping pressure pt relative to unmodified inclusions therefore recognition of post entrapment inclusion modification due to overpressure is crucial to avoid misinterpretation of data but has considerable potential for constraining the detail of p t trajectories of individual rocks on this basis rocks from the ose thrust zone north norway are shown to have experienced rapid uplift on a clockwise p t t path during the final stages of caledonian scandian orogenesis

compositional re equilibration of fluid inclusions in quartz compositional modifications to salt water fluid inclusions in quartz were observed following exposure to disequilibrium conditions in a series of laboratory experiments in which samples containing inclusions of known composition were annealed at 3 kbar and 600 t 825 c in the presence of fluids having different compositions for time intervals ranging from a few days to one month changes in inclusion compositions following re equilibration were monitored using salt crystal dissolution temperatures and or ir infra red spectroscopy the behaviors of both synthetic and natural fluid inclusions were studied the synthetic samples were re equilibrated under pint pconf conditions to minimize stress in the crystal surrounding the inclusions and were subjected to both fh2ointfh2oconf and fh2ointfh2oconf after re equilibration for four days at t 600 c most inclusions displayed significant compositional changes without decrepitation salinity variations as large as 25 wt were inferred for brine inclusions exposed to fh2oint fh2oconf for 16 days at 825 c the majority of our observations are consistent with the net diffusion of water toward the reservior having the lowest h2o i e synthetic nacl h2o fluid inclusions exhibited increased tm nacl s implying lower relative h2o contents when re equilibrated in the presence of fluids having lower h2o whereas similar and in some cases the same inclusions exhibited decreased tm nacl s implying higher h2o contents after exposure to fluids having higher h2o the behavior of natural salt water fluid inclusions during re equilibration was generally consistent with corresponding observations on synthetic samples verifying that compositional changes are not restricted to synthetic inclusions our results clearly show that there was chemical communication between fluids trapped as inclusions in quartz and the external fluid reservoir additionally it is evident that although applied stress can significantly enhance the re equilibration rate strain in the crystal host around the inclusions resulting from large pressure differentials between the internal and confining fluids is not a necessary prerequisite for compositional change finally because significant compositional changes can be induced in brine inclusions in quartz during shortterm exposure to non equilibrium conditions at 600 t 825 c in the laboratory it is likely that similar changes may result at much lower temperatures during exposure of natural rocks to non equilibrium conditions over geologic time

the deglaciation of the americas during the last glacial termination this paper reviews current understanding of deglaciation in north central and south america from the last glacial maximum to the beginning of the holocene together with paleoclimatic and paleoceanographic data we compare and contrast the pace of deglaciation and the response of glaciers to major climate events during the global last glacial maximum glgm 26 5 19 ka average temperatures decreased 4 to 8 c in the americas but precipitation varied strongly throughout this large region many glaciers in north and central america achieved their maximum extent during the glgm whereas others advanced even farther during the subsequent heinrich stadial 1 hs 1 glaciers in the andes also expanded during the glgm but that advance was not the largest except on tierra del fuego hs 1 17 5 14 6 ka was a time of general glacier thickening and advance throughout most of north and central america and in the tropical andes however glaciers in the temperate and subpolar andes thinned and retreated during this period during the bolling allerod interstadial b a 14 6 12 9 ka glaciers retreated throughout north and central america and in some cases completely disappeared many glaciers advanced during the antarctic cold reversal acr 14 6 12 9 ka in the tropical andes and patagonia there were small advances of glaciers in north america central america and in northern

a continuous record of vegetation fire regime and climatic changes in northwestern patagonia spanning the last 25 000 years abstract we present a high resolution precisely dated terrestrial paleovegetation paleoclimate record from lago pichilaguna northwestern patagonia 40 44 s which spans continuously from the last glacial maximum lgm to the present we find abundant and continuous presence of arboreal pollen chiefly nothofagus during the lgm accompanied by other trees shrubs and alpine herbs these results suggest subantarctic parkland and or scattered woodlands under a cold and hyperhumid climate during the lgm 25 000 17 800 cal yr bp with expansion of nothofagus under relatively warm interstadial conditions between 25 000 and 19 200 cal yr bp this was followed by cooling and a precipitation increase between 19 200 and 17 800 cal yr bp which was contemporaneous with the youngest lgm advance of andean glaciers in the region and maximum influence of the southern westerly wind sww the last glacial termination t1 started at 17 800 cal yr bp and featured the spread of thermophilous trees and ferns characteristic of north patagonian rainforests along with lake level lowering these results suggest a warm pulse and southward shift of the sww concurrent with a rapid collapse of andean glacier lobes subsequent changes led to the establishment of closed canopy rainforests under peak interstadial warmth between 16 000 and 15 000 cal yr bp we detect a shift to cold wet conditions during the antarctic cold reversal 14 800 12 700 cal yr bp and a precipitation decline during younger dryas time followed by maximum temperature relatively lower lake level and minimum sww influence between 11 300 and 7700 cal yr bp precipitation then rose punctuated by centennial scale variations since 6200 cal yr bp chilean european deforestation and spread of invasive exotic species started at 350 cal yr bp aided by fire we conclude that temperate rainforests have persisted with little interruption since t1 with major changes in floristic composition driven by climate change and fires rainforest composition and heterogeneity declined in response to chilean european disturbance during the 1600s and intensified since the 1800s these events constitute the fastest largest magnitude vegetation changes of the last 25 000 years

a multi methodological re evaluation of the volcanic events during the 1580 ce and 1808 eruptions at sao jorge island azores archipelago portugal abstract among all eruptions that took place on the azores archipelago since the portuguese settlement in the xvi century those of 1580 and 1808 in the island of sao jorge were unusual the magma erupted in 1580 ascended from at least 23 km and ponded at a minimum depth of 16 km here residual magma fractionated mafic phases and plagioclase during 228 years before erupted again in 1808 magma emission occurred from numerous fissures active at the same time and opening for several kilometres following a local tectonic trend hydro volcanic outbursts and hot rock fall over steep slopes caused casualties and injuries and lava flows and heavy tephra fallout affected the local economy despite of all these dramatic consequences the memory of these eruptions is almost vanished representative geosites and morphological landforms if not hindered by lush vegetation have been reshaped by diffuse quarries and reworked to recover croplands and pastures aiming at a better comprehension of the multiple hazards associated with volcanic eruptions at sao jorge island we retraced the volcanic events of these two eruptions by matching our re interpretation of historic reports with field data and photogrammetry and with fluid inclusions petrography and geochemical data of erupted products

trans pacific glacial response to the antarctic cold reversal in the southern mid latitudes abstract elucidating the timing and regional extent of abrupt climate events during the last glacial interglacial transition 18 11 5 ka is critical for identifying spatial patterns and mechanisms responsible for large magnitude climate events the record of climate change in the southern hemisphere during this time period however remains scarce and unevenly distributed we present new geomorphic chronological and equilibrium line altitude ela data from a climatically sensitive mountain glacier at monte san lorenzo 47 s central patagonia twenty four new cosmogenic 10be exposure ages from moraines provide a comprehensive glacial record in the mid latitudes of south america which constrain the timing spatial extent and magnitude of glacial fluctuations during the antarctic cold reversal acr 14 5 12 9 ka rio tranquilo glacier advanced and reached a maximum extent at 13 9 0 7 ka three additional inboard moraines afford statistically similar ages indicating repeated glacier expansions or marginal fluctuations over the acr our record represents the northernmost robust evidence of glacial fluctuations during the acr in southern south america documenting not only the timing of the acr maximum but also the sequence of glacier changes within this climate event based on ela reconstructions we estimate a cooling of 1 6 1 8 c at the peak of the acr the rio tranquilo record along with existing glacial reconstructions from new zealand 43 s and paleovegetation records from northwestern 41 s and central west 45 s patagonia suggest an uniform trans pacific glacier climate response to an acr trigger across the southern mid latitudes we posit that the equatorial migration of the southern westerly winds provides an adequate mechanism to propagate a common acr signal across the southern hemisphere

density changes of fluid inclusions in high pressure low temperature metamorphic rocks from crete a thermobarometric approach based on the creep strength of the host minerals abstract the densities of fluid inclusions in quartz from high pressure low temperature metamorphic rocks are generally inconsistent with the p t conditions derived from solid phase equilibria therefore some process of change must regularly have occurred during exhumation however evidence of decrepitation is frequently lacking consideration of the rates of change of p and t in metamorphic rocks shows that very low strain rates are sufficient for volume adaptation dislocation creep appears to be a feasible deformation mechanism allowing for continuous ballooning driven by a small differential pressure during decompression down to temperatures of about 300 c in quartz decrepitation requires a higher differential pressure in natural rocks it is therefore restricted to relatively low temperatures this concept was tested on inclusions in the phyllite quartzite unit of crete in these rocks cooling to below ca 300 c at confining pressures of 3 to 4 kbar is indicated corresponding to depths of 10 to 13 km it is anticipated that in metamorphic rocks the isochores of all fluid inclusions in quartz that have been formed at higher temperatures and remain unaffected by decrepitation should intersect close to the 300 c isotherm thereby defining a point on the p t paths rarely accessible by other methods extension of this concept to other minerals with known mechanical properties is straightforward and can under favourable circumstances be used to fix several points on p t paths

synthetic fluid inclusions vi quantitative evaluation of the decrepitation behaviour of fluid inclusions in quartz at one atmosphere confining pressure the decrepitation behaviour of fluid inclusions in quartz at one atmosphere confining pressure has been evaluated using pure h2o synthetic inclusions formed by healing fractures in natural quartz three different modes of non elastic deformation referred to as stretching leakage or partial decrepitation and total decrepitation have been observed the internal pressure required to initiate non elastic deformation is inversely related to inclusion size according to the equation internal pressure kbar 4 26 d 0 423 where d is the inclusion diameter in microns regularly shaped inclusions require a higher internal pressure to initiate non elastic deformation than do irregularly shaped inclusions of similar size heating inclusions through the quartz inversion results in mechanical instability in the quartz crystal and leads to mass decrepitation of inclusions owing to structural mismatches generated by pressure gradients in the quartz around each inclusion long term heating experiments 2 years suggest that the internal pressure required to initiate non elastic deformation does not decrease significantly with time and indicates that short lived thermal fluctuations in natural systems should not alter the inclusion density and homogenization temperature inclusions that do exhibit decreased density higher homogenization temperature are however always accompanied by a change in shape from irregular to that of a negative crystal observations of this study are consistent with elasticity theory related to fracture generation and propagation around inclusions in minerals these results indicate that an inclusion will not be influenced by a neighbouring inclusion or other defect in the host phase as long as the distance between the two is 2 4 diameters of the larger of the two inclusions

experimental stretching of fluid inclusions in calcite implications for diagenetic studies homogenization temperatures of fluid inclusions trapped in calcite crystals may change with increased heating beyond the homogenization temperature fluid inclusions trapped in calcite during basin subsidence will tend to yield homogenization temperatures approaching maximum burial temperatures diagenetic studies that depend on these data will be biased coarse crystalline calcite containing saline fluid inclusions was used to examine the influence of increased temperatures and pressures on measured homogenization temperatures stepped heating experiments were conducted at 1 atm over a temperature range of 90 to 245 c along with hydrothermal experiments at confining pressures of 173 and 691 bar and temperatures of 160 250 and 350 c in all cases significant increases in the homogenization temperatures of the inclusion population were recorded presumably stresses generated during heating of the fluid inclusions exceeded the combined strength of the calcite crystal and the external pore pressure and thus caused fluid inclusion stretching size is a secondary factor that controls fluid inclusion reequilibration

experimental diffusion of hydrogen into synthetic fluid inclusions in quartz quartz hosted synthetic co2 h2o fluid inclusions behave as open systems with respect to diffusional transfer of hydrogen during laboratory simulated metamorphic re equilibration at 650 750 and 825 c and 1 5 kbar total pressure with fo2 defined by the c ch4 buffer microthermometry and raman spectroscopy show that the initial co2 h2o inclusions become co2 ch4 h2 h2o inclusions after diffusive influx of hydrogen from the reducing confining medium measurable changes are observed in inclusion compositions after only 15 days of re equilibration implying significant hydrogen mobility at still lower temperatures over geological time spans results of synthetic inclusion re equilibrium experiments have profound implications for the interpretation of natural fluid inclusion data failure to account for potential hydrogen migration in inclusions from high temperature geological environments may lead to erroneous estimates of p t and or the compositions of metamorphic fluids

chilean and southeast pacific paleoclimate variations during the last glacial cycle directly correlated pollen and δ18o records from odp site 1234 abstract joint pollen and oxygen isotope data from ocean drilling program site 1234 in the southeast pacific provide the first continuous record of temperate south american vegetation and climate from the last 140 ka located at 36 s 65 km offshore of concepcion chile site 1234 monitors the climatic transition zone between northern semi arid summer dry winter wet climate and southern year round rainy cool temperate climate dominance of onshore winds suggests that pollen preserved here reflects transport to the ocean via rivers that drain the region and integrate conditions from the coastal mountains to the andean foothills down hole changes in diagnostic pollen assemblages from xeric lowland deciduous forest characterized by grasses herbs ferns and trees such as deciduous beech nothofagus obliqua mesic valdivian evergreen forest including conifers such as the endangered prumnopitys andina and subantarctic evergreen rainforest comprised primarily of southern beech n dombeyi reveal large rapid shifts that likely reflect latitudinal movements in atmospheric circulation and storm tracks associated with the southern westerly winds during glacial intervals mis 2 4 and 6 rainforests and parkland dominated by nothofagus moved northward into the region at the mis 6 5e transition coeval with the rapid shift to lower isotopic values rainforest vegetation was rapidly replaced by xeric plant communities associated with mediterranean type climate an increased prominence of halophytic vegetation suggests that mis 5e was more arid and possibly warmer than mis 1 although rainforest pollen rises again at the end of mis 5e lowland deciduous forest pollen persists through mis 5d and 5c into mis 5b substantial millennial scale variations occur in both interglacial and glacial regimes attesting to the sensitivity of the southern westerly belt to climate change comparison of the cool mesic n dombeyi rainforest assemblage from site 1234 with 18 o in the byrd ice core shows that on time scales longer than 10 ka cool moist conditions in central chile were coherent with and occurred in phase with antarctic cooling this is also likely at millennial scales although rainforest pollen lags antarctic cooling with exponential response times of about 1000 years which plausibly reflects the ecological response time to regional climate change

the last glacial termination a major puzzle of paleoclimatology is why after a long interval of cooling climate each late quaternary ice age ended with a relatively short warming leg called a termination we here offer a comprehensive hypothesis of how earth emerged from the last global ice age a prerequisite was the growth of very large northern hemisphere ice sheets whose subsequent collapse created stadial conditions that disrupted global patterns of ocean and atmospheric circulation the southern hemisphere westerlies shifted poleward during each northern stadial producing pulses of ocean upwelling and warming that together accounted for much of the termination in the southern ocean and antarctica rising atmospheric co2 during southern upwelling pulses augmented warming during the last termination in both polar hemispheres

changes in fire regimes since the last glacial maximum an assessment based on a global synthesis and analysis of charcoal data fire activity has varied globally and continuously since the last glacial maximum lgm in response to long term changes in global climate and shorter term regional changes in climate vegetation and human land use we have synthesized sedimentary charcoal records of biomass burning since the lgm and present global maps showing changes in fire activity for time slices during the past 21 000 years as differences in charcoal accumulation values compared to pre industrial there is strong broad scale coherence in fire activity after the lgm but spatial heterogeneity in the signals increases thereafter in north america europe and southern south america charcoal records indicate less than present fire activity during the deglacial period from 21 000 to 11 000 cal yr bp in contrast the tropical latitudes of south america and africa show greater than present fire activity from 19 000 to 17 000 cal yr bp and most sites from indochina and australia show greater than present fire activity from 16 000 to 13 000 cal yr bp many sites indicate greater than present or near present activity during the holocene with the exception of eastern north america and eastern asia from 8 000 to 3 000 cal yr bp indonesia and australia from 11 000 to 4 000 cal yr bp and southern south america from 6 000 to 3 000 cal yr bp where fire activity was less than present regional coherence in the patterns of change in fire activity was evident throughout the post glacial period these complex patterns can largely be explained in terms of large scale climate controls modulated by local changes in vegetation and fuel load

deglacial and postglacial climate history in east central isla grande de chiloe southern chile 43 s abstract palynologic and stratigraphic data from laguna tahui 42 50 s 73 30 w indicate cool temperate and humid conditions there between 14 000 and 10 000 14c yr b p followed by warmer and drier than present conditions between 10 000 and 7000 14c yr b p and subsequent cooling and rise in precipitation over the last 5800 14c yr the thermophilous valdivian trees eucryphia cordifolia and caldcluvia paniculata reached their maximum abundance during the early holocene warm dry phase 10 000 7000 14c yr b p followed by a rise in lake levels and reexpansion of north patagonian conifers starting at 7000 and 5800 14c yr b p respectively variations in the stratigraphic and geographic distribution of temperate rainforests in southern chile suggest multimillennial trends in temperature and westerly activity which are spatially and temporally coherent with paleoclimate records from neighboring regions climate variability at millennial and submillennial time scales may account for the establishment and persistence of fine scale mosaics of valdivian and north patagonian rainforest species in low to mid elevation communities since 5800 14c yr b p

rheology of the plate interface dissolution precipitation creep in high pressure metamorphic rocks abstract subduction zone models invoke deformation to be concentrated along the plate interface in a region of particularly low temperature geophysical observations do not provide constraints on temperature stress and deformation patterns with desired resolution in contrast the record of high pressure metamorphic rocks exhumed from subduction zones provides details on p t history deformation mechanisms and stress state albeit not readily correlated with the former dynamic situation on larger scale here we review available information on dissolution precipitation creep dpc in high pressure metamorphic rocks which if representative for subduction zones in general can pose constraints on conditions rheology and flow patterns along the plate interface the key observations and conclusions are that 1 deformation is typically highly inhomogeneous and localized into shear zones 2 stresses are generally too low to drive crystal plastic deformation 3 microfabrics suggest dissolution precipitation creep to be the predominant deformation mechanism 4 an aqueous fluid at quasi lithostatic pressure is available throughout allowing for tensile fracturing and crack healing or sealing 5 low stress combined with high strain rates required for localized deformation at typical subduction rates implies low viscosity and 6 contribution of shear heating to the thermal budget of subduction zones should be moderate the dominant deformation mechanism dpc is reviewed in some detail including experimental and theoretical approaches various examples of dpc in high pressure metamorphic rocks are illustrated emphasizing the role of interphase boundaries as sites of dissolution rheology governed by dpc is proposed to control interplate coupling and development of a subduction channel with return flow being a likely candidate for rapid exhumation of high pressure metamorphic rocks

enrichment of co2 in fluid inclusions in quartz by removal of h2o during crystal plastic deformation abstract ductile strain induced leakage of h 2 o from mixed co 2 h 2 o fluid inclusions in quartz is proposed as a mechanism for producing occurrences of pure co 2 fluid inclusions in metamorphic rocks the h 2 o needed for hydrolytic weakening of quartz under stress may be provided by the h 2 o in fluid inclusions with dislocation creep as dislocations nucleate on the walls of fluid inclusions or intersect them h 2 o can be transported with the dislocations from the inclusion to the grain boundaries the process should continue so long as there is stress on the host quartz and the inclusion contains h 2 o the h 2 o taken to the grain boundaries would due to its wetting properties be wicked out along the grain boundaries if the h 2 o is totally removed from an inclusion by a flux of dislocations through the quartz during the crystal plastic flow then a residual inclusion bearing components other than water should remain a mixed co 2 h 2 o inclusion would as a consequence of the process become a pure co 2 fluid inclusion during dynamic recrystallization the co 2 would collect at grain boundary triple junctions and following grain boundary migration would become incorporated into the recrystallized quartz as fluid inclusions this mechanism of generating pure co 2 inclusions could result in co 2 fluid inclusions having densities appropriate for the pressure temperature conditions during deformation using estimates of temperature of deformation the total confining pressure during deformation could be determined from the density of the co 2 fluid in these inclusions

timing and structure of vegetation fire and climate changes on the pacific slope of northwestern patagonia since the last glacial termination abstract by virtue of its location in the southern mid latitudes northwestern patagonia 40 44 s offers the opportunity to unravel the mechanisms involved in the initiation and propagation of paleoclimate signals of hemispheric and global significance of particular importance is deciphering the evolution of the southern westerly winds sww considering their influence at continental zonal hemispheric and global scale here i present a multi decadal record from lago proschle a small closed basin lake located on the pacific slope of northwestern patagonia to examine the timing and structure of vegetation fire and climate change along a continuum since the onset of the last glacial termination t1 the record shows rapid glacier recession during t1 reaching the western andean foothills in 400 years or less nothofagus dominated forests established between 17 4 17 ka followed by closed canopy north patagonian rain forests nprf with shade tolerant thermophilous trees between 16 3 15 4 ka these changes suggest an abrupt warming trend and an increase in precipitation at 16 3 ka associated with a northward shift of the sww subsequent increases in cold tolerant hygrophilous trees between 15 4 12 8 ka imply a shift to cold more humid conditions during the antarctic cold reversal suggesting stronger sww influence this was followed by stand replacing fires brought by a sudden decline in summer precipitation at 12 8 ka associated with a millennial scale southward shift of the sww which was contemporaneous with the onset of the younger dryas dominance of thermophilous summer drought tolerant valdivian rainforest trees and high fire activity ensued between 10 3 7 8 ka suggesting peak warmth and overall decline in annual precipitation associated with weakening of the sww during the early holocene a multi millennial cooling and wetting trend started at 7 8 ka brought by stronger sww influence followed by recurrent centennial scale variations in temperature and precipitation starting at 6 4 ka deforestation fire and spread of non native herbs by chilean european settlers began during the late 18th century abrupt vegetation changes in the lago proschle record were driven by rapid climate changes over the last 17 400 years amplified in some instances by fire disturbance

onset of deglacial warming in west antarctica driven by local orbital forcing an annually resolved ice core record from west antarctica indicates that warming driven by local insolation resulting from sea ice decline began in that region about 2 000 years before warming in east antarctica reconciling two alternative explanations for deglacial warming in the southern hemisphere

deformation by solution deposition and re equilibration of fluid inclusions in crystals depending on temperature internal pressure and stress abstract changes of shape and density of fluid inclusions in crystals were demonstrated when these crystals were subjected to temperatures and internal pressures greater than those of their growth experimental relations have been established between the rate of length change of the inclusions and the different parameters of the experiment nature of the crystal temperature and internal pressure state of stress on the crystal geometric characters of the inclusion length width orientation of the inclusion with respect to the optical axes of host mineral it is essentially the effect of the variation of surface energy with the curvature around the cavity which causes a mass transfer of the host crystal by diffusion through the fluid under pressure the rate of length change is limited by the rate of dissolution at the median part of elongate inclusions this change of shape and density is known to occur in naturally deformed crystals an example of such a behaviour is given which allowed us to use the inclusions as markers of the conditions of temperature and pressure subsequent to the growth of crystal

methane in fluid inclusions from granulites a product of hydrogen diffusion many fluid inclusion studies of granulite grade rocks reveal the presence of co2 rich inclusions that appear to have been trapped near the peak of metamorphism final melting temperatures of co2 tm co2 reported for these inclusions are often below the co2 triple point of 56 6 c and some are below 60 c this freezing point lowering is usually attributed to the presence of a second volatile component such as ch4 and the presence of ch4 has been confirmed in some cases by raman or mass spectroscopy a co2 melting temperature near 56 6 c is commonly offered as evidence that the inclusions contain nearly pure co2 however significant amounts of ch4 may be present but cause seemingly insignificant freezing point depressions c o h fluid speciation calculations for conditions representative of granulite facies metamorphism indicate that ch4 may comprise a significant portion of peak metamorphic fluids when graphite is present but it is never a significant species in co2 rich fluids in most cases the amount of ch4 should be virtually undetectable with microthermometric or spectroscopic techniques only in aqueous fluid inclusions can co2 and ch4 both be significant species post trapping speciation changes to fluid inclusions at constant mass cannot account for the reported compositions unless graphite precipitates in the inclusions thus the observed compositions require post trapping compositional changes due to loss or gain of components we have modeled variations in the fugacities of molecular fluid species in inclusion and matrix fluids during uplift from 6 kb and 800 c assuming hypothetical uplift pressure temperature paths which are concave or convex toward the temperature axis t concave and t convex respectively our results suggest that for rocks buffered at o2 within one log unit of the fayalite magnetite quartz equilibrium fmq 1 most uplift paths result in external h2 overpressures of bars to tens of bars at temperatures 400 c the highest overpressures are generated during t concave uplift compositional changes resulting from equilibration of such gradients via diffusive addition of hydrogen to peak metamorphic fluid inclusions and concomitant reduction of co2 by conversion to ch4 and h2o are consistent with the compositions of fluid inclusions reported from granulite terranes previous workers have postulated that co2 rich fluid inclusions in granulites could originate from post trapping diffusive loss of h2o from h2o co2 inclusions in response to an h2o gradient between the inclusion and matrix fluids the results of the present study suggest that for fluids buffered by fmq 1 this is possible only if 1 1 uplift is t convex and the matrix fluid composition remains nearly constant or 2 2 the matrix fluid evolves toward relatively h2o poor compositions the latter could occur if influx of co2 rich fluids occurs during uplift

vegetation fire and climate change in central east isla grande de chiloe 43 s since the last glacial maximum northwestern patagonia abstract we present a detailed record from lago lepue to examine vegetation climate and fire regime changes since the last glacial maximum lgm in central east isla grande de chiloe 43 s northwestern patagonia precipitation in this region correlates with the intensity of the southern westerly winds sww allowing reconstruction of past sww behavior through precipitation sensitive sensors recession from the lgm glacier margins exposed the central east sector of isla grande de chiloe by 17 800 cal yr bp followed by the immediate colonization of pioneer cold resistant herbs shrubs and rapid establishment of closed canopy nothofagus forests by 17 000 cal yr bp broad leaved temperate rainforests have persisted since then with compositional changes driven by changes in temperature hydrologic balance and disturbance regimes we detect low lake levels and enhanced fire activity between 800 2000 4000 4300 8000 11 000 and 16 100 17 800 cal yr bp implying southward shifts and or weaker sww flow that alternated with cold humid phases with muted fire activity covariation in paleoclimate trends revealed by the lago lepue record with tropical and antarctic records since the lgm suggests that the sww have been a highly dynamic component of the climate system capable of linking climate changes from low and high southern latitudes during the last glacial termination and the current interglacial

centennial and millennial scale hydroclimate changes in northwestern patagonia since 16 000 yr bp abstract we examine hydroclimate changes at centennial millennial timescales since 16 000 yr bp in northwestern patagonia based on the pollen and charcoal record from lago el salto a small closed basin lake located in the chilean lake district 41 38 48 02 s 73 5 48 42 w we observe cold wet conditions between 14 500 16 000 yr bp followed by further cooling with increased precipitation until 13 000 yr bp enhanced precipitation seasonality and or variability between 11 600 13 000 yr bp and an extended warm and dry interval between 7600 and 11 300 yr bp with peak paleofire activity colder and wetter than present conditions and muted paleofire activity prevail between 5300 and 7600 yr bp followed by alternating cold wet and centennial scale warm dry phases starting at 5300 yr bp with three conspicuous megadroughts since 2500 yr bp the most recent megadrought occurred during the medieval climate anomaly we identify a cold reversal that spans the antarctic cold reversal acr and the younger dryas yd chrons with stronger than present westerly influence during the former and enhanced variability during the latter these results extend the northern limit of strong cooling and increase in precipitation during the acr and the southern limit of influence of strong hydrologic variations during the yd in terrestrial environments suggesting an overlap in the spheres of influence of processes originating from southern and northern polar latitudes an extended warm southern westerly wind sww minimum interval is evident between 7600 and 11 300 yr bp followed by a rapid shift to cool moist conditions between 5300 and 7600 yr bp brought by a mid holocene sww maximum since then we observe centennial scale hydroclimate variability which has driven biodiversity and fire regime shifts of evergreen temperate rainforests

calculated fluid evolution path versus fluid inclusion data in the cohn system as exemplified by metamorphic rocks from rogaland south west norway fluid evolution paths in the cohn system can be calculated for metamorphic rocks if there are relevant data regarding the mineral assemblages present and regarding the oxidation and nitrodation states throughout the entire p t loop the compositions of fluid inclusions observed in granulitic rocks from rogaland south west norway are compared with theoretical fluid compositions and molar volumes the fluid parameters are calculated using a p t path based on mineral assemblages which are represented by rocks within the pigeonite in isograd and by rocks near the orthopyroxene in isograd surrounding an intrusive anorthosite massif the oxygen and nitrogen fugacities are assumed to be buffered by the coexisting fe ti oxides and cr carlsbergite respectively many features of the natural fluid inclusions including 1 the occurrence of co2 n2 rich graphite absent fluid inclusions near peak m2 metamorphic conditions 927 c and 400 mpa 2 the non existence of intermediate ternary co2 ch4 n2 compositions and 3 the low molar volume co2 rich fluid inclusions 36 42 cm3 mol 1 are reproduced in the calculated fluid system the observed co2 ch4 rich inclusions with minor n2 5 mol should also include a large proportion of h2o according to the calculations the absence of h2o from these natural high molar volume co2 ch4 rich inclusions and the occurrence of natural ch4 n2 rich inclusions are both assumed to result from preferential leakage of h2o this has been previously experimentally demonstrated for h2o co2 rich fluid inclusions and has also been theoretically predicted fluid deficient conditions may explain the relatively high molar volumes but cannot be used to explain the occurrence of ch4 n2 rich inclusions and the absence of h2o

stratigraphy age and correlation of lepue tephra a widespread c 11 000 cal a bp marker horizon sourced from the chaiten sector of southern chile we describe the stratigraphy age and correlation of a prominent tephra marker named lepue tephra extensively distributed in north western patagonia lepue tephra is well dated at c 11 000 cal a bp from numerous lake and soil cover bed sequences and its recognition is useful for assessing the rate and timing of deglaciation as well as associated environmental changes in this region during the last glacial termination and early holocene lepue tephra has attributes typical of a complex and compositionally zoned phreatomagmatic eruptive while the initial rhyolitic phase can be readily distinguished from multiple eruptive products sourced from the adjacent volcan chaiten the main erupted end member is of basaltic andesitic bulk composition similar to younger tephras sourced from holocene monogenetic cones adjacent to the volcan michimahuida massif tmim lepue tephra can be correlated to an equivalent aged pyroclastic flow deposit amarillo ignimbrite prominently distributed in the south eastern sector of tmim the source vent for these co eruptive events is obscured by an extensive ice field and is currently unknown the widespread radially symmetrical distribution of lepue tephra centred on tmim cannot be attributed solely to volcanological considerations reduced southern hemisphere westerly wind influence interpreted from climate proxies at the time of eruption are also implicated

synthetic fluid inclusions xv tem investigation of plastic flow associated with reequilibration of fluid inclusions in natural quartz the nature and abundance of dislocations in quartz surrounding fluid inclusions were studied to obtain a better understanding of processes associated with fluid inclusion reequilibration synthetic fluid inclusions containing 10 wt nacl aqueous solution were formed in three samples at 700 c and 5 kbar one of the samples was quenched along an isochore to serve as a reference sample the other two samples were quenched along a p t path that generated internal pressures in excess of the confining pressure the two samples were held at the final reequilibration p t conditions of 625 c and 2 kbar for 30 and 180 days respectively following the experiments microstructures associated with fluid inclusions were examined with the tem quartz in healed fractures in the reference sample that was quenched isochorically shows a moderate dislocation activity quartz adjacent to reequilibrated fluid inclusions in the other two samples however showed a marked increase in dislocation activity compared to the un reequilibrated sample deformation of the inclusion walls occurred anisotropically by expansion of mobile dislocations in their slip systems dislocation expansion was controlled by glide in the rhombohedral planes 1 0 1 1 that was restricted to narrow zones 3 m in the immediate vicinity of the fluid inclusion walls outside of the healed fracture plane these plastic zones were observed after both short term 30 days and long term 180 days experiments and are attributed to hydrolytic weakening of quartz around fluid inclusions owing to diffusion of water into the quartz matrix during the experiment the close spatial association of submicroscopic water bubbles with dislocations and the rarity of water bubbles in the reference sample show clearly that in both the 30 and 180 day experiments reequilibration involves water loss from the fluid inclusions our results indicate that synthetic fluid inclusions in this study recover chemically and volumetrically even at relatively fast experimental loading rates such that internal stresses never reach the point of brittle failure the driving force for fluid inclusion deformation involves two related mechanisms plastic deformation of hydrolytically weakened wet quartz in the healed fracture and water leakage associated with preexisting and strain induced dislocations

mechanical re equilibration of fluid inclusions in san carlos olivine by power law creep fluid inclusions in san carlos olivine stretch via plastic mechanisms when heat treated at 1400 c and 0 1 mpa in controlled f o 2 atmospheres for several days measurable changes in both inclusion dimensions and fluid densities occur densities decrease from 1 0 to 0 7 g cc stretching is fastest along 100 and slower along 001 and 010 the dislocation microstructure around the inclusions suggests that creep mechanisms operate uncertainties in the experimental determinations of stretching rates result from optical resolution limits errors inherent in measuring homogenization temperatures uncertainties in the fluid equation of state and changes in fluid chemistry during the heat treatment inclusion stretching by dislocation creep can be treated using a model developed for hot isostatic pressing in this model we assume spherical symmetry of plastic flow that the material yields by steady state power law creep and that the parameters for the constitutive law and fluid equation of state are known stretching rates are predicted to depend on the difference between the fluid pressure and the external pressure the temperature the constitutive law governing power law creep and geometry predicted stretching rates show fair but not exact agreement with experimentally measured rates the amount of stretching predicted by the model is in rough agreement with estimates based on dislocation microstructures around natural inclusions if xenolith ascent rates are of the order of 1 cm s or faster

the deuterium excess records of epica dome c and dronning maud land ice cores east antarctica new high resolution deuterium excess d data from the two epica ice cores drilled in dronning maud land edml and dome c edc are presented here the main moisture sources for precipitation at edc and edml are located in the indian ocean and atlantic ocean respectively the more southward moisture origin for edml is reflected in a lower present day d value compared to edc the edml and edc isotopic records 18o and d show the main climate features common to the east antarctic plateau and similar millennial scale climate variability during the last glacial period however quite large 18o and d differences are observed during mis5 5 and the glacial inception with a long term behaviour a possibility for this long term difference could be related to uncertainties in past accumulation rate which are used in the glaciological models regional climate anomalies between the two sites during mis5 5 could also be consistent with the observed edml edc 18o and d gradient anomalies simulations performed with the general circulation model echam4 for different time slices provide a temporal temperature isotope slope for the edml region in fair agreement to the modern spatial slope tsite and tsource records are extracted from both ice cores using a modelling approach after corrections for past 18o seawater and elevation changes a limited impact of d on antarctic temperature reconstruction at both edml and edc has been found with a higher impact only at glacial inception the aim antarctic isotope maximum events in both ice cores are visible also after the source correction suggesting that these are real climate features of the glacial period the different shape of the aim events between edc and edml as well as some climate features in the early holocene points to a slightly different climate evolution at regional scale a comparison of our temperature reconstruction profiles with the aerosol fluxes show a strong coupling of the nssca fluxes with antarctic temperatures during glacial period and a tighter coupling of 18o and tsite with ssna flux at edml compared to edc during the glacial period and mis5 5

temperate rainforest response to climate change and disturbance agents in northwestern patagonia 41 s over the last 2600 years abstract we present detailed pollen and charcoal records from lago pichilafquen 41 s to decipher the effects of climate change and varying disturbance regimes on the composition and structure of the vegetation on the andean foothills of northwestern patagonia during the last 2600 yr here temperate rainforests have dominated the landscape since 2600 cal yr bp with variations ranging from cool temperate and wet north patagonian rainforests to relatively warm and summer drought resistant valdivian rainforests we interpret relatively warm dry conditions between 1900 2600 690 750 and 320 430 cal yr bp alternating with cold wet conditions between 1500 1900 750 1100 and 430 690 cal yr bp rapid deforestation and spread of plants introduced by europeans occurred at 320 and 140 cal yr bp the record includes five tephras with ages of 2130 1460 1310 1210 and 340 cal yr bp all of which precede local fire events and increases in trees favored by disturbance by less than 100 yr we conclude that centennial scale changes in the southern westerlies were the primary driver of vegetation shifts in northwestern patagonia over the last 2600 yr within this interval local disturbance regimes altered the structure composition and dynamics of the lowland rainforest vegetation during several discrete short lived episodes

understanding the sam influence on the south pacific enso teleconnection the relationship between the el nino southern oscillation enso and the southern hemisphere annular mode sam is examined with the goal of understanding how various strong sam events modulate the enso teleconnection to the south pacific 45 70 s 150 70 w the focus is on multi month multi event variations during the last 50 years a significant p 0 10 relationship is observed most marked during the austral summer and in the 1970s and 1990s in most cases the significant relationship is brought about by la nina el nino events occurring with positive negative phases of the sam more often than expected by chance the south pacific teleconnection magnitude is found to be strongly dependent on the sam phase only when enso events occur with a weak sam or when a la nina el nino occurs with a positive negative sam phase are significant south pacific teleconnections found this modulation in the south pacific enso teleconnection is directly tied to the interaction of the anomalous enso and sam transient eddy momentum fluxes during la nina sam and el nino sam combinations the anomalous transient momentum fluxes in the pacific act to reinforce the circulation anomalies in the midlatitudes altering the circulation in such a way to maintain the enso teleconnections in la nina sam and el nino sam cases the anomalous transient eddies oppose each other in the midlatitudes overall acting to reduce the magnitude of the high latitude enso teleconnection

tracing bottom water oxygenation with sedimentary mn fe ratios in lake zurich switzerland abstract redox dynamics of manganese mn were studied in the sediment of lake zurich using precise sediment core age models monthly long term oxygen o 2 monitoring data of the water column 1936 2010 and high resolution xrf core scanning the age models were based on bi annual lamination and calcite precipitation cycles if present mn exhibits distinct maxima which coincide with the annual maximum deep water o 2 concentrations in spring according to the monitoring data in contrast the iron fe signal is mainly the result of calcite dilution as indicated by a strong negative correlation between fe and calcium ca xrf data the mn fe ratio in the core from the maximum lake depth zh10 15 137 m revealed a moderate correlation with o 2 measurements in the lake bottom water confirming the successful application of the mn fe ratio to semi quantitatively reconstruct bottom water oxygenation in the lake mostly low ratios were observed between 1895 and the mid 1960s as a result of eutrophication however geochemical focusing and sedimentological factors can reduce the applicability of the mn fe ratio in reconstructing o 2 concentrations in the bottom water of lakes

have the southern westerlies changed in a zonally symmetric manner over the last 14 000 years a hemisphere wide take on a controversial problem the prevailing view in the palaeoclimate literature of the last 20 years is that the southern westerly winds sww were intensified over southern australia and tasmania during the warmer than present early holocene 11e8 ka at similar latitudes on the opposite side of the southern mid latitudes palaeoclimate studies have suggested a poleward shift of the northern edge of the westerlies and focusing at 49 s in southern south america this zonal asymmetry contrasts with the modern day zonal symmetry displayed by the sww and poses a formidable challenge to an understanding of the modes of climatic variability of the southern extra tropics this paper presents an updated synthesis of continuous radiocarbon dated palaeoenvironmental data from the westerlies zone of influence in all southern hemisphere continents synchronous multi millennial trends in moisture vegetation fire and hydrologic balance are remarkably consistent with the way the sww changes impact upon the climate in southern hemisphere landmasses in the modern climate considering the modern relationships between local precipitation and zonal wind speeds it is suggested that the sww changed in a zonally symmetric manner at multi millennial scale between 14 and 5 ka regional asymmetry develops after 5 ka across the southern hemisphere with a pattern of precipitation anomalies akin to the modern functioning of el nino e southern oscillation which started w6200 years ago

a mechanism for preferential h 2 o leakage from fluid inclusions in quartz based on tem observations preferential leakage of h2o from fluid inclusions containing multiple gas components has been suspected in natural metamorphic rocks and has been demonstrated experimentally for synthetic h2o co2 rich inclusions in natural quartz knowledge of the physical and chemical characteristics of the leakage mechanism which may be very complex increases the value of natural fluid inclusions to metamorphic geology it is proposed that crystal defects play a major role in nondecrepitative preferential h2o leakage through quartz and remain effective during metamorphism inclusions with either an internal overpressure or underpressure produce strain in the adjacent quartz crystal via the nucleation of many dislocations and planar defects like dauphine twin boundaries these defects allow preferential loss of h2o from h2o co2 rich inclusions at supercritical conditions the transport capacity of this leakage mechanism is enhanced by nucleation of small bubbles on defect structures the nucleation of these bubbles seems to be a recovery process in strained crystals solubility gradients of quartz in water in a crystal with internally underpressurized inclusions may result in optical visible implosion halos in a three dimensional spatial arrangement caused by the growth of small bubbles at the expense of the larger original fluid inclusion natural fluid inclusions from naxos greece are always associated with numerous interlinked dislocations these dislocations may have been produced by plastic derormation or by crystal growth related processes e g crack healing the presence of small bubbles on these dislocations indicates that a similar leakage mechanism for h2o must have occurred in these rocks

radiocarbon chronology of the last glacial maximum and its termination in northwestern patagonia abstract we examine the timing and magnitude of the last glacial maximum lgm and the last glacial termination lgt in northwestern patagonia situated in the middle latitudes of south america our data indicate that the main phase of the lgt began with abrupt warm pulses at 17 800 and 17 100 cal yrs bp accompanied by rapid establishment of evergreen temperate rainforests and extensive deglaciation of the andes within 1000 years this response shows that south american middle latitude temperatures had approached average interglacial values by 16 800 cal yrs bp the temperature rise in northwestern patagonia coincides with the beginning of major warming and glacier recession in the southern alps of new zealand at southern mid latitudes on the opposite side of the pacific ocean from this correspondence the warming that began at 17 800 cal yrs bp appears to have been widespread in middle latitudes of the southern hemisphere accounting for at least 75 of the total temperature recovery from the lgm to the holocene moreover this warming pulse is coeval with the first half of the heinrich stadial 1 hs1 in the north atlantic region hs1 featured a decline of north atlantic meridional overturning circulation a southward shift of the westerly wind belt in both hemispheres and of the intertropical convergence zone as well as a weakening of the asian monsoon along with the initiating trigger identifying the mechanisms whereby these opposing climate signals in the two polar hemispheres interacted whether through an oceanic or an atmospheric bipolar seesaw or both lies at the heart of understanding the lgt

experimental decrepitation and re equilibration of fluid inclusions in synthetic quartz abstract strong discrepancies between densities of the fluids trapped in fluid inclusions f i and p tp couples deduced from other geological considerations are common so it was decided to test experimentally the possible f i re equilibrations when bringing the host crystal in p tp conditions different from trapping conditions runs were conducted on synthetic quartz in a gas apparatus and in a griggs solid medium apparatus the following modifications of the f i were observed 1 1 drastic shape changes of the primary f i and appearance of clusters or trails of small secondary inclusions sometimes related to a crack 2 2 lowering of the fluid densities such a re equilibration is a decrepitation phenomenon first hydraulic fracturing then sealing of the cracks with appearance of secondary inclusions when using the gas apparatus the new measured densities are in very good accordance with the nominal p tp conditions when using the solid medium apparatus the new densities are surprisingly low relative to the nominal p t conditions probably due to a strongly anisotropic stress state in the apparatus

textural evolution of synthetic fluid inclusions in quartz during reequilibration with applications to tectonic reconstruction experimental reequilibration of synthetic 10 wt nacl h2o inclusions in natural quartz reveals that reequilibration textures show distinct differences depending upon the p t path followed by the inclusion after formation these differences combined with other geological information may be used to determine whether the sample rock followed a dominantly isothermal or isobaricp t path following entrapment the intensity and style of inclusion reequilibration features is related to the direction and magnitude of the departure of thep t path from the original isochore for the inclusion thus fluid inclusion reequilibration textures not only permit inclusionists to determine whether the rocks followed an isothermal or isobaric retrogradep t path but also the magnitude of departure of this path from one that is isochoric