the record of the messinian salinity crisis in the tertiary piedmont basin nw italy the alba section revisited abstract the alba succession tertiary piedmont basin nw italy preserves the northernmost record of the messinian salinity crisis msc and was deposited on the southern margin of a wide wedge top basin related to the involvement of the piedmont basin in the apennine compressional tectonics pre msc sediments consist of a cyclic succession of marine euxinic shales and calcareous marls deposited under the influence of precession modulated climate changes and document the progressive restriction of the basin prior to the onset of the msc they are followed by the primary lower gypsum unit plg deposited during the first msc stage from 5 96 to 5 60 ma these sediments show a clear precession related cyclic stacking pattern and record the lateral transition from a shallow water marginal setting in the sw to a deeper one in the ne in marginal settings six plg cycles are recognised truncated by an erosional unconformity placed at the base of the post evaporitic sediments the lowermost five cycles are composed of massive and banded selenite beds separated by thin shale intervals a sharp change evidenced by the appearance of the branching selenite facies is recorded by the 6th gypsum bed that represents a distinctive marker bed here called sturani key bed that can be mapped throughout the study area basinward the lower plg cycles are transitional to decimetre thick carbonate rich layers interbedded to euxinic shales that are overlain by the sturani key bed above the marker bed other seven plg cycles are present the gypsum beds form thinner bodies compared to the sturani key bed and are characterised by a greater amount of fine grained terrigenous fraction suggesting an increase of continental runoff related in turn to humid climate conditions at the end of the first msc stage plg cycles are followed by slumped mudstones and clastic gypsum beds that correspond to the resedimented and chaotic facies resedimented lower gypsum deposited in the mediterranean basins during the second msc stage from 5 60 to 5 55 ma they are in turn overlain by continental and brackish water facies with lago mare fossil assemblages recording the final stage of the msc the messinian succession of alba provides the opportunity to reconstruct the lateral facies transition between marginal and distal settings and to shed new light on the deep water msc sedimentary record moreover the appearance of the branching selenite facies from the 6th plg cycle upward provides a tool for properly placing the piedmont record in the msc chronostratigraphic framework allowing us to investigate the influence of climate gradients on the sedimentary response to the mediterranean salinity crisis

the northern apennines palynological record as a contribute for the reconstruction of the messinian palaeoenvironments abstract the messinian stage has long been associated with an overall warm and dry climate whereas recent researches indicate either a warm and humid or a cool and dry climate the integrated stratigraphic record of vegetation and climatic changes from northern apennines sites provides the solution to this apparent contradiction its integration with the updated geological and sedimentological studies provides additional data for the reconstruction of the depositional palaeoenvironments in both marginal and deeper sub basins of the apennines foredeep the onset of the mediterranean salinity crisis msc is recorded in the gessoso solfifera of the vena del gesso marginal sub basin cyclical humid conditions corresponding to precession minima developed during the deposition of the shales interbedded with the gypsum 5 9 to 5 6 ma some cooler events took also place under the effects of global glacial stadials and regional factors apennines uplift at present no major changes from moist to dry conditions are attested to just before the salinity crisis as well as in sicily so climate did not play a major role in the onset of the msc despite the favourable context provided by inferred thermo xeric conditions in southern italy a drier episode indicated by the expansion of the open vegetation including the northward migration of lygeum postdates the onset of the salinity crisis of about 400 kyr in the lower post evaporitic deposits of maccarone deeper sub basin it falls within a period of global warming whereas at a regional scale it could correlate p p to the evaporite deposition in deeper basins and to hiatuses in the marginal basins of sicily and of the western sector of northern apennines its sudden end about 100 kyr later in coincidence with a significant increase of pinaceae indicates a turnover in the terrestrial setting not linked to major climate changes but possibly to a complex interaction between other palaeoenvironmental factors e g tectonics and eustatism in contrast organic walled dinoflagellate cysts exclude significant modifications in aquatic settings insaturation of either open marine or brackish conditions in the latter a later change is marked by the arrival of impagidinium sp 1 a species here referred instead to caspidinium rugosum about 7 m below the first colombaccio this occurrence together with the spread of pediastrum indicates a freshwater dilution i e the lago mare event during wetter climatic conditions on the adjacent landmass increase of tsuga and cedrus the successive arrival and or dominance of other paratethyan taxa such as i sp 2 i sp 3 and galeacysta etrusca indicate highly variable water environments marine vs continental water inputs during the deposition of the uppermost post evaporitic deposits the lago mare is stratigraphically sandwiched between an ash layer 130 m below dated at 5 5 ma and the beginning of the pliocene where a peak of impagidinium patulum marks the onset of open marine conditions the dominant humid subtropical to warm temperate climate indicates differences in both temperature and moisture values with respect to the coeval southern sections revealing climatic gradients within the mediterranean at least from the messinian no dramatic vegetation and climate changes have been recorded during the msc major changes occurred later as indicated by the palynological record from 2 6 ma this palynostratigraphic record is a good reference for more recent models of the development of the msc and for establishing time relationships between the apennine and sicilian successions

sedimentary stable isotope and micropaleontological records of paleoceanographic change in the messinian tripoli formation sicily italy abstract the tripoli formation 6 96 5 98 ma of the central sicilian basin provides a good record of the paleoceanographical changes that affected the mediterranean during the transition from slightly restricted conditions to the onset of the messinian salinity crisis the falconara gibliscemi section has been selected for an integrated approach at a high resolution scale using sedimentology stable isotopes of the carbonates and microfossils the sedimentary succession includes 46 precession controlled cycles resulting from the periodical increase in biosiliceous productivity diatomites that followed the deposition of marls and pinkish laminites which appear as sapropel type deposits induced by the oceanic fertilization by terrestrial nutrients during wet periods higher scale environmental changes are superimposed to this precession forced rhythmicity there is a general trend of increasing basin restriction from near marine conditions at the base of the tripoli to semi closed settings in its uppermost part which are the prelude of the salinity crisis this pattern reflects the hydrological response of the mediterranean to the progressive decrease of the atlantic inputs and an enhanced influence of the climate on depositional conditions however this evolution is not linear and shows successive phases of different duration during the first period until 6 71 ma open atlantic mediterranean exchanges maintained relatively stable marine conditions the second period 6 71 6 29 ma marks an important step in the basin restriction with a wider range of salinity fluctuations and an increased bottom stagnation the 6 71 ma event which is correlated at a mediterranean scale may have resulted from shallowing of the mediterranean gateway under a tectonic control this shallowing reduced the oceanic inputs resulting in an increased climatic constraint of the mediterranean hydrology during the third period 6 29 6 03 ma an increase of the surface water salinity resulted in stressful conditions for the marine microfauna the 6 29 ma change is a major step in the restriction that may be correlated with the intensification of the glaciation recorded in the atlantic which could have enhanced the effects of the tectonic closure the last two cycles 48 and 49 that underlie the calcare di base witnessed the rapid transition to a semi closed mediterranean setting characterized by large variations of salinity from diluted to hypersaline conditions under a dominant climatic control and by the nearly complete disappearance of the marine organisms long trend environmental changes recognized within the tripoli formation resulted from a complex set of interfering factors controlling the water fluxes exchanged between the mediterranean and the world ocean most of the rapid changes identified in falconara gibliscemi at 7 16 6 71 and 6 29 ma that occurred simultaneously in the western and eastern mediterranean were mainly controlled by the stepwise tectonic closure of the atlantic connections although a glacio eustatic overprint cannot be completely excluded

structural controls on the orientation of erosion gullies in mid western new south wales australia abstract the role of geology in determining the drainage network of gullying has been evaluated by quantitative methods of analysis at gully erosion sites in new south wales field evidence suggests that soil cracks are sites of preferential flow and erosion at both the surface and subsurface soil fabric and rock structure and weathering studies were undertaken to establish the inheritance of soil cracks from the underlying parent material gully orientation was correlated with the strike of joints and bedding planes in a range of rock materials including sedimentary intrusive and extrusive igneous and thermal and regional metamorphic rocks these units vary not only in terms of mineralogy but also in degree of weathering however all are steeply dipping structures usually exceeding 60 correlations exist between gully orientation and joints in the underlying material but the strength of the relationship varies according to the parent material in the ordovician hornfels where no correlation between joints and gully orientation occurred the evidence showed that gullying was controlled by faulting along the hornfels granite boundary these relationships support the view that throughflow processes are dominant in the development of gullies since convergence of runoff would not be expected to align with subsurface soil discontinuities

the messinian calcare di base sicily italy revisited three different types of carbonate deposits are included within the calcare di base commonly envisaged to record the messinian salinity crisis onset type 1 consists of sulfur bearing limestones representing the biogenic product of bacterial sulfate reduction after original gypsum type 2 comprises dm thick laminated dolomitic limestones interbedded with diatomites sapropels and marls found at the top the tripoli formation type 3 the most common variety consists of m thick brecciated limestones interbedded with shales and clastic gypsum type 3 shows sedimentary features suggesting a clastic origin and deposition from high to low density gravity flows thus these deposits can be regarded as an end member of a large variety of evaporite bearing gravity flow deposits with a dominant carbonate component the genetic and stratigraphic characterization of these carbonates has strong implications for a better comprehension of messinian events the three types of calcare di base seem to have formed during different stages of the messinian salinity crisis msc type 2 formed in the first stage 5 96 5 60 ma and is the only type that can be regarded as the lower gypsum time equivalent type 3 was deposited in the second stage 5 60 5 55 ma and its base is associated with a regional scale hiatus and erosion messinian erosional surface type 1 formed even later likely in post messinian time through diagenetic processes affecting resedimented gypsum deposited during the second stage of the msc it follows that not all the calcare di base deposits record the onset of the messinian salinity crisis as commonly thought thus a detailed facies characterization of these carbonate deposits is fundamental for both stratigraphic reconstructions and a better comprehension of messinian events

the abad composite se spain a messinian reference section for the mediterranean and the apts a high resolution integrated stratigraphy is presented for the abad marls of the sorbas and nijar basins in se spain preevaporitic messinian of the western mediterranean detailed cyclostratigraphic and biostratigraphic analyses of partially overlapping subsections were needed to overcome stratigraphic problems in particular encountered at the complex transition from the lower to the upper abad the resulting abad composite section contains a continuous stratigraphic record from the tortonian messinian boundary up to the transition to the messinian evaporites of the yesares member all together 18 calcareous plankton events were recognized which were shown to be synchronous throughout the mediterranean by means of detailed bed to bed cyclostratigraphic correlations the magnetostratigraphy allowed the identification of the four magnetic reversals of chron c3an in the upper abad details in the sedimentary cycle patterns allowed the abad composite to be astronomically calibrated this calibration to the 658n summer insolation curve of solution la90 1 1 yielded astronomical ages for all sedimentary cycles calcareous plankton bioevents ash layers and paleomagnetic reversals up to now the abad composite is the only astronomically well calibrated section that provided a reliable cyclostratigraphy magnetostratigraphy and calcareous plankton biostratigraphy as such it will serve as a reference section both for the pre evaporite messinian in the mediterranean as well as for the messinian interval in the astronomical polarity time scale q 2001 elsevier science b v all rights reserved

a stable isotope study of microbial dolomite formation in the coorong region south australia abstract the coorong region of south australia is a classic location for the study of modern dolomite formation a number of ephemeral lakes here contain dolomite whilst other lakes in close proximity contain aragonite with minor magnesite our previous field and experimental work has revealed that sulphate reducing bacteria play a key role in overcoming kinetic inhibitors to dolomite formation in this area we here use a combination of oxygen carbon and sulphur isotopes to help to further constrain the processes leading to dolomite precipitation in modern hypersaline environments we report isotopic data from four dolomite and three aragonite containing lakes 34 s data for dissolved lake and porewater sulphates reveal 34 s enrichment of residual sulphate in all seven lakes consistent with bulk closed system microbial fractionation by sulphate reducing bacteria calculations using temperature dependent oxygen isotope fractionation factors between dolomite and the solution from which it precipitated are consistent with a strong microbial component to carbonate precipitation in these lakes a comparison of 18 o data from dolomite and aragonite sediment and from their associated lakewaters indicates seasonal mineral precipitation occurs late in the evaporative cycle of the lakes within a yoghurt like saturated mud horizon coincident with the zone of sulphate reduction surprisingly 13 c data from the carbonates do not show the characteristic wide range of values often associated with organogenic carbonates but instead show that these bacterially mediated precipitates incorporate carbon primarily from the inorganic lakewater reservoir partially diluted by an organic component a coorong type microbial model of dolomite formation may be particularly applicable to for example precambrian sedimentary dolomites where benthic microbial communities which are today restricted to extreme environments dominated the shallow marine ecosystem prior to the emergence of metazoa

a shallow water record of the onset of the messinian salinity crisis in the adriatic foredeep legnagnone section northern apennines abstract the legnagnone section north eastern apennines represents one of the few shallow water records of the onset of the messinian salinity crisis here we present a detailed description of a 200 kyr time interval encompassing the pre syn evaporitic transition based on a multidisciplinary approach integrating sedimentological bio magnetostratigraphical palaeontological and stable isotope data such a shallow water setting is potentially more sensitive to the palaeoenvironmental change leading to the msc than the more often studied deeper mediterranean basin the aquatic palaeoenvironmental reconstruction proposed here is based on the study of foraminifer ostracod and mollusc assemblages it depicts a change from infralittoral 20 50 m to inner circalittoral environment 60 100 m that since 6 12 ma was progressively affected by a reduction of oxygen at the sea floor punctuated by short lived anoxic events at least three cooling events have been recognized on the basis of relative abundance data in mid to high altitude pollen which before 6 03 ma are in phase with abundance peaks of turborotalia spp a taxon indicating eutrophic and cool surface waters the absence of stress tolerant benthic foraminifers during these peaks points to strong ventilation episodes triggered by a generally cooler climate the proximity of a deltaic system and the consequent riverine input probably caused a salinity decrease of the surface waters hindering the proliferation of planktonic foraminifers in the water column which prevalently occur in short influxes and disappear at ca 6 ma our results suggest that the onset of the crisis occurred during a phase of relative sea level high stand whereas no evidences of sea level drop can be envisaged the palaeoclimatic reconstruction based on palynological data indicates the dominance of a subtropical humid forest vegetation type where fresh water swamps are well represented from 6 03 ma onward the transition to the salinity crisis is marked by more pronounced cyclical expansions of the temperate broad leaved deciduous forest along with herbaceous taxa the establishment of the strongly evaporative condition at the crisis onset is not associated with major vegetational changes towards drier conditions but linked to a sudden increase of 18o and the disappearance of benthic foraminifers just prior to the deposition of the 1st laminated carbonate which represents the base of the primary lower gypsum unit

a reconstruction of late miocene mediterranean circulation patterns using benthic foraminifera abstract extensive research on the late miocene mediterranean has solved a number of questions concerning the development of the area but questions remain on for instance the mediterranean water circulation patterns knowledge of preferably quantitative oxygen contents of water masses could be of help to reconstruct paleo circulation and understand how this contributed to the development of the mediterranean messinian salinity crisis msc bottom water oxygenation is usually estimated qualitatively or semi quantitatively at best from abundances of infaunal benthic foraminifera from stable carbon isotope data or redox sensitive elements we present data from six mediterranean land sections and one section located at the atlantic side of the rifian corridor as an atlantic reference location we introduce a semi quantitative reconstruction of oxygen levels at the sediment water interface employing a simple index that operates on a scale from 1 low oxygen to 5 normal to high oxygen using this method we present a tentative reconstruction of the mediterranean water circulation in the period preceding the continuous development towards the msc which started at 7 17 ma we found that during the late miocene an anti estuarine circulation was likely quite comparable to the modern pattern deep water formation appears to have existed in the central northeastern part of the basin around 7 2 ma constriction of the rif corridor morocco led to restricted exchange of mediterranean and atlantic water masses a reduction of the deep circulation and decreasing bottom water ventilation deep water formation weakened and the mediterranean hydrography changed thoroughly eventually contributing to the development of the msc

messinian carbonate rich beds of the tertiary piedmont basin nw italy microbially mediated products straddling the onset of the salinity crisis abstract the seven messinian microbial carbonate rich layers cropping out in the pollenzo section tertiary piedmont basin nw italy are interbedded with a precession related cyclic succession composed of euxinic shale marl couplets and straddle the onset of the messinian salinity crisis msc a sharp change of sedimentological compositional and geochemical characteristics was observed from the onset of the msc onward suggesting strong differences in the mechanisms responsible for carbonate precipitation pre msc beds are mainly composed of dolomite and are interpreted as the product of early diagenesis formed by bacterial sulphate reduction in the shallow subsurface along the sulphate methane interface dolomite precipitation was temporarily enhanced by an upward flux of methane rich fluids possibly sourced by gas hydrate destabilisation conversely from the onset of the msc onward carbonate beds are thinly laminated and show abundant filaments interpreted as beggiatoa like bacteria while calcite and aragonite are the dominant authigenic phases these beds are interpreted as microbialites resulting from the lithification of chemotrophic bacterial mats dominated by sulphide oxidizing bacteria the carbonate necessary for their preservation was provided by bacterial sulphate reduction these microbialites that appear as the deeper water counterpart of bottom grown selenite layers deposited in the marginal part of the basin formed on an anoxic sea bottom under a density stratified water column the high sulphate concentration in the pore waters related to the presence of concentrated brines and to the regeneration of sulphate by sulphide oxidizing bacteria is considered as the driving factor controlling the mineralogical change from dolomite to calcite and aragonite finally the sharp shift towards negative 18 o values of carbonates observed from the onset of the msc onward was probably related to fractionation processes operated by sulphate reducing bacterial communities in the pore waters this suggests that care must be taken when dealing with microbial carbonates in the interpretation of the oxygen isotope values in terms of fluctuating salinity condition of the water mass in conclusion this study suggests that the onset of the msc had a strong impact on microbial populations governing carbonate precipitation in a sector of the basin dominated by depositional conditions not suitable for gypsum precipitation

sedimentary and tectonic evolution of the vena del gesso basin northern apennines italy implications for the onset of the messinian salinity crisis the integration of field and subsurface data permits a substantial revision of the sedimentary evolution of the vena del gesso basin a thrust top basin in the northern apennines where shallow water primary gypsum deposits related to the messinian salinity crisis were well developed and preserved as inferred from lateral and vertical facies changes within the underlying deep marine turbidites of the marnoso arenacea formation evaporite precipitation occurred in a basin bounded to the north and to the east by a thrust related anticline actively growing since the late tortonian both gypsum deposition and subsequent deformation were strongly controlled by evolving paleobathymetry driven by tectonics primary gypsum precipitated in a shallow silled basin while in the adjacent deeper and larger foredeep basin organic rich shales were deposited gypsum deposits underwent severe postdepositional deformation related to large scale gravitational collapse as a result of a regional uplift event also coincident with the end of the evaporitic phase along the inner shallower dipping limb of the anticline bounding the basin large scale poorly deformed gypsum slabs moved downslope along a detachment surface developed at the contact with the underlying euxinic shales forming both extensional and compressional features and showing an overall southwestern vergence the identification of a south southwest dipping paleoslope here pointed out for the first time suggests that the deformational features affecting the gypsum unit were probably driven by gravity and not by active thrusting as thought up to now the steeper frontal limb of the anticline promoted the transformation of gypsum slides into debris flows and turbidite currents that deposited their load in the adjacent deeper basin this gravitational deformation was sealed by postevaporitic upper messinian lagomare deposits the sedimentary history of the vena del gesso basin suggests that the messinian salinity crisis in the apennine foredeep as well as in the balearic tyrrhenian sicily and eastern mediterranean basins was tightly linked to tectonic processes the large scale postdepositional collapse of primary evaporitic deposits is a widespread feature in the mediterranean basins and it may have altered the original stratigraphic relationships in some places this finding has potentially important implications for a correct paleoenvironmental reconstruction of the onset of the messinian salinity crisis

the deep water counterpart of the messinian lower evaporites in the apennine foredeep the fanantello section northern apennines italy abstract a possible deep water non evaporitic unit equivalent of the messinian lower evaporites has been recognised in the northern apennine foredeep this unit whose existence is implicitly admitted in the two step model of the mediterranean messinian salinity crisis is documented here for the first time it occurs throughout the apennine foredeep basin below a thick horizon of resedimented gypsum deposits usually ascribed to the lower evaporites actually the lower evaporites of the apennine foredeep basin include both shallow water in situ precipitated facies and deep water resedimented facies deposited in distinct depocenters the usually envisaged coeval nature of the two deposits has been recently challenged in several works based on a physical stratigraphic considerations about the downbasin correlation of the messinian erosional surface cutting on top the in situ evaporites with the sharp base of the resedimented evaporites unit and b the common occurrence of a barren unit below the resedimented evaporites which has no obvious equivalents in pre evaporitic successions underlying the in situ precipitated evaporites in this work a multidisciplinary study has been carried out on a 140 m thick composite section fanantello section to definitely assess the age and palaeoenvironmental characteristics of the unit underlying the resedimented gypsum deposits the topmost part of the section comprises a 60 m thick succession of barren euxinic shales falling entirely within a reversed polarity chron and characterised by a the complete disappearance of foraminifera b the occurrence of high salinity tolerant thecosomatous pteropods creseis sp c the abundance peaks of the calcareous nannofossil sphenolithus abies interpreted as related to highly stressed likely hyperhaline conditions d the appearance of hyperhaline and or stratified water molecular indicators gammacerane based on a multidisciplinary integrated stratigraphic approach this barren interval is here proposed to be a deeper water time equivalent of the in situ primary lower evaporites thus allowing to assess the events connected to the onset and the first phase of the messinian salinity crisis from a basinal perspective these data lend support to the hypothesis that the resedimented evaporite deposits of the apennine foredeep basin postdate the in situ evaporites thus implying that the term lower evaporites actually comprises rock bodies with different origins and separated in time and space by the messinian erosional surface and its correlative conformity this could be true also for other mediterranean basins where the stratigraphy of deep water successions should be carefully re examined

foraminiferal record of environmental changes messinian of the los yesos area sorbas basin se spain the late messinian of the sorbas basin betic cordillera se spain has been sampled to estimate 1 the paleoenvironmental changes recorded by the benthic foraminifers in pre evaporitic and evaporitic units and 2 the impact of the messinian salinity crisis on the foraminiferal biodiversity in the pre evaporitic unit foraminifers indicate a circalittoral to bathyal environments and show significant changes in bottom water oxygenation simultaneously the occurrences of epiphytic damaged foraminifers and the blocks of porites point out the presence of plant substrates and coral reefs on the infralittoral zone the overlying evaporitic unit is characterized by four subaqeous selenitic gypsum layers and three marine fossiliferous intercalations each episode of gypsum deposition ends with a desiccation event each fossiliferous intercalations traduce a rapid reflooding of the basin by marine waters corresponding to infralittoral to upper bathyal environments with normal marine conditions during the evaporitic period the ecological conditions in the water column were intermittently favorable to the development of marine organisms and moreover the marginal basins of the betic cordillera were not continuously desiccated during the messinian the low percentage of extinct species 5 at the messinian pliocene boundary and the occurrences of benthic foraminifers in the evaporitic unit indicate that the infralittoral to upper bathyal environments have not been completely modified and or barren during the messinian salinity crisis i e the messinian salinity crisis is not associated with a biological crisis

environmental constraints of foraminiferal assemblages distribution across a brackish tidal marsh caminha nw portugal abstract foraminiferal living assemblages from a brackish tidal marsh were studied across three sampling transects under spring and autumn conditions foraminiferal analysis was also extended to the dead assemblages of spring samples altimetric control of each sampling point was acquired through the connection to the national datum by gps differential positioning combined with a regional geoid model the influence of the geochemical characteristics on the assemblages including chemical composition of the estuarine and marsh surface sediments in addition to salinity ph and calcite saturation of estuarine and marsh interstitial waters was evaluated a high affinity was found between spring and autumn living assemblages probably related to the low number of representative species the affinity also found between living and dead assemblage was seen as a consequence of low ph and calcite undersaturation that prevent the accumulation effect of several generations of foraminifera salinity appears as a clear constraint to the foraminiferal assemblages composition that is enhanced by calcite undersaturation in brackish marshes interstitial waters and sediments generally abundant marsh species like trochammina inflata jadammina macrescens and the calcareous foraminifera are limited to an episodic presence foraminiferal assemblages distribution across brackish tidal marsh can be assumed as an elevation proxy the high marsh ib sub zone is dominated by haplophragmoides sp and haplophragmoides manilaensis low marsh zone ii is characterised by the dominance of miliammina fusca but can be subdivided in an iia upper part where is followed by pseudothurammina limnetis and in a iib lower part defined by a subsidiary presence of psammosphaera sp haplophragmoides manilaensis dominance between 1 55 m and 1 67 m at living as well as dead assemblages suggests this species as a potential sea level indicator for the brackish tidal marshes

regional climate and glacial control on high resolution oxygen isotope records from ain el beida latest miocene northwest morocco a cyclostratigraphic analysis in the depth and time domain 1 high resolution benthic and planktonic stable oxygen isotope records are presented for the upper miocene ain el beida aeb section in northwestern morocco and reveal the clear imprint of the climatic precession obliquity and eccentricity cycles in the interval between 6 5 and 5 5 ma the 18o depth series were transformed into time series using astronomical tuning of the sedimentary color cycles to the 65 n summer insolation curve of the la93 solution with present day values for tidal dissipation and dynamical ellipticity spectral analysis and band pass filtering show that the ratios of the astronomically related spectral peaks are not consistent in the depth and time domain the inconsistencies are mainly due to variations in sedimentation rate that are positively correlated with precession amplitude i e modulated by eccentricity in addition they result from a long term trend in sedimentation rate a simple model of nonlinear response of the sedimentation rate to the eccentricity modulation of precession was used to simulate the observed shifts in the relative position of the spectral peaks in the depth domain cross spectral analysis was carried out on the 18o time series and a combined eccentricity tilt obliquity and precession etp curve the precession controlled 18o signal varies in phase with etp partly as a result of the tuning procedure while the obliquity related signal reveals a small lag of 2 3 kyr relative to obliquity this lag is slightly reduced at the time of the messinian salinity crisis msc and increases to 5 6 kyr if the tidal dissipation term in the astronomical solution is reduced to half its present day value the obliquity related lag is most likely associated with the slow buildup of ice caps whereas the precession signal is interpreted as to dominantly reflect regional climate changes comparable to those associated with mediterranean sapropels finally the benthic 18o record is compared with open ocean records and discussed in terms of an astronomically tuned oxygen isotope stratigraphic framework

paleoenvironmental evolution of the eastern mediterranean during the messinian constraints from integrated microfossil data of the pissouri basin cyprus abstract integrated data of calcareous nannofossils as well as planktonic and benthic foraminifera from the pissouri motorway section on cyprus allow the reconstruction of surface and bottom water paleoenvironments of the eastern mediterranean during the interval preceding the messinian salinity crisis msc contrary to deeper water locations where benthic foraminifera faunas are suppressed or absent just after the tortonian messinian boundary sediments deposited at intermediate water depths do contain benthic assemblages from the earliest messinian onwards a development towards increasingly unfavourable paleoenvironments is reflected in the planktonic and benthic microfossil records of the pissouri section and proceeds with rather discrete time steps that can be correlated to sequences throughout the mediterranean shortly after the tortonian messinian boundary a transition is recorded in the sedimentology and the open marine deeper water taxa disappear from the benthic foraminifera assemblages subsequently the diversity of all fauna groups diminishes the changes recorded at species level in both surface water and sea floor dwelling taxa suggest decreasing circulation of the bottom waters associated with changes in the surface waters most likely due to increasing stratification from 6 73 ma onwards our data indicate a prominent change to more restricted conditions and increasing salinity at the sea floor together with intermittently rising surface water salinity the dominance of oligotypic and monospecific assemblages and the frequent shifts in assemblage compositions of all microfossil groups indicate severely stressed environments after 6 4 ma probably related to increased salinity the major changes in paleoenvironmental conditions including oxygen deprivation due to stagnation and hypersalinity can be explained by hydrographical changes in the mediterranean basin which are probably caused by tectonic movements in the rif corridor acting in concert with astronomical cyclicity evaluation of the paleodepth proxies indicates that the depth of the pissouri basin remained rather constant at 300 500 m with a minimum of 200 m until deposition of the barre jaune the transitional interval towards the evaporites and that early shallowing to neritic depths as was proposed before is highly unlikely

surface water evolution of the eastern east china sea during the last 36 000 years abstract planktic foraminifera have been studied in two high resolution cores raised from the continental slope of the eastern east china sea ecs to reconstruct the surface water history ams 14c dating on fifteen horizons revealed that the two cores kh82 4 14 and rn80 pc3 contain continuous records of the last 36 and 17 thousand cal years respectively thirty one planktic foraminiferal species which are commonly found in the present western north pacific and the ecs are recognized in down core samples three faunal phases iii ii and i distinguished by characteristic planktic foraminiferal assemblages suggest three major paleoenvironmental stages of the surface water of the eastern ecs since 36 000 yr b p 1 a stage influenced by coastal water from 36 000 to 19 500 yr b p 2 a stage also influenced by coastal water and extremely low salinity from 19 500 to 10 500 yr b p and 3 a stage controlled by the modern open sea water related to the kuroshio with both higher temperature and higher salinity since 10 5 8 5 thousand years b p oxygen isotope records of the planktic foraminiferal species g bulloides show that the three planktic foraminiferal faunal phases correspond to the last glacial deglacial and postglacial stages respectively the planktic foraminiferal assemblage during the deglacial stage which is represented by high percentages of g quinqueloba is quite different from those during the glacial and postglacial stages linked to a large amount of river discharge from the chinese continent a negative oxygen isotope excursion in g bulloides during the same period is highly correlated to the g quinqueloba anomaly also indicating a decrease in surface water salinity furthermore the sedimentation rate of core kh82 4 14 during 19 15 thousand years b p is much higher than the rates during the glacial and postglacial stages suggesting a great increase in the supply of terrigenous material related to an increased river and sediment discharge during the early deglaciation the coastal water influenced stage of the eastern ecs terminated gradually at 10 5 8 5 thousand years b p since the warm kuroshio current and its branches flowed in the eastern ecs as today the formation of the postglacial surface water circulation pattern in the eastern ecs was closely related to the flow patterns of the kuroshio current

chronology causes and progression of the messinian salinity crisis the messinian salinity crisis is widely regarded as one of the most dramatic episodes of oceanic change of the past 20 or so million years 1 3 earliest explanations were that extremely thick evaporites were deposited in a deep and desiccated mediterranean basin that had been repeatedly isolated from the atlantic ocean1 2 but elucidation of the causes of the isolation whether driven largely by glacio eustatic or tectonic processes have been hampered by the absence of an accurate time frame here we present an astronomically calibrated chronology for the mediterranean messinian age based on an integrated high resolution stratigraphy and tuning of sedimentary cycle patterns to variations in the earth s orbital parameters we show that the onset of the messinian salinity crisis is synchronous over the entire mediterranean basin dated at 5 96 0 02 million years ago isolation from the atlantic ocean was established between 5 59 and 5 33 million years ago causing a large fall in mediterranean water level followed by erosion 5 59 5 50 million years ago and deposition 5 50 5 33 million years ago of non marine sediments in a large lago mare lake sea basin cyclic evaporite deposition is almost entirely related to circum mediterranean climate changes driven by changes in the earth s precession and not to obliquity induced glacio eustatic sea level changes we argue in favour of a dominantly tectonic origin for the messinian salinity crisis although its exact timing may well have been controlled by the 400 kyr component of the earth s eccentricity cycle

the primary lower gypsum in the mediterranean a new facies interpretation for the first stage of the messinian salinity crisis abstract the detailed facies and physical stratigraphic analysis of the primary lower gypsum in the mediterranean indicates a surprising bed by bed correlation at basin scale spain italy hellenic arc and cyprus arc that is tuned to the orbital calibration for the first stage of the messinian salinity crisis from 5 96 to 5 61 ma ago a total of 16 precessionally controlled gypsum cycles were deposited rapidly in less than 350 ka forming sequences up to 300 m thick the lack of subaerial exposure features and the common facies associations and stacking pattern for sections located thousands of kilometers apart in different geological settings indicates a modest depositional depth not extremely shallow selenite deposition occurred only at the bottom of restricted marginal basins less than 200 m deep while no gypsum could precipitate in the deeper euxinic mediterranean portions where only thin and barren shale dolostone couplets formed the lowermost selenite beds pass laterally to dolomite rich limestones interbedded with barren euxinic shales in poorly oxygenated settings indicating that the gypsum sedimentation was diachronous and did not necessarily mark the onset on the messinian salinity crisis evaporite facies sequences ef1 to 8 within individual gypsum beds show small scale subaqueous sedimentary cycles that mimic regressive transgressive cycles a initial evaporite precipitation at relatively low supersaturation produced the massive selenite facies ef3 in a relatively deep setting b continuous evaporation and drawdown by oscillating brine level formed the banded selenite ef4 at the aridity acme of the precessionally controlled cycle c general progressive brine level rise with strong brine flow led to the formation of large selenite supercones branching laterally supercones in spain and branching selenite ef5 in the rest of the mediterranean and d flooding by undersaturated continental water terminated gypsum precipitation with the deposition of argillaceous sediments ef1 northern apennines and or limestone ef2 sicily and spain during the humid phase in the precession climate cycle the stacking pattern and selenite facies associations suggest an overall shallowing upward trend with a basin wide hydrologic change starting from the 6th cycle 5 84 ma which is marked by the appearance of the branching selenite facies supercones in spain and indicates that the brines became current dominated the sr isotope stratigraphy suggests that in the northern apennines the brines were strongly modified by continental waters 87 sr 86 sr 0 708893 to 0 708998 and received direct pulses of atlantic seawater 87 sr 86 sr 0 70900 to 0 709024 only in the upper part of the section in areas away from the mainland such as sicily the continental input was by far less important

erosional processes and paleo environmental changes in the western gulf of lions sw france during the messinian salinity crisis abstract current interpretation of the messinian salinity crisis msc involves partial desiccation of the mediterranean sea coupled with the deposition of thick evaporites in the deep basins new sets of seismic reflection profiles in the western part of the gulf of lions confirm the basinward extension of the messinian erosion and enable the mapping of distinctive seismic markers indicating the messinian erosional surface or messinian unconformity the basin margin detrital deposits and the deep evaporite sequence the geometrical relationship between these three elements and their relationship to the paleogeography of the margin during the msc provide new information about the evolution of the study area during the messinian the messinian erosional surface mes commonly correlated with the desiccation phase and the deposition of deep evaporites during the apogee of the event is generally interpreted as a subaerial feature in the gulf of lions it is a complex diachronic polygenic erosional surface observed at the base of the prograding plio quaternary sequence beneath the shelf and slope it extends downslope beneath the deep basin upper evaporites and the salt and possibly correlates conformably with the base of the so called deep lower evaporites the whole morphology of the mes reflects a buried drainage pattern supporting the interpretation of fluvial erosion driven by a substantial drop in sea level our results also suggest that large submarine gravity flows occurred prior to any significant accumulation of salt in the basin and prior to the upper evaporites consequently interbedded clastic deposits may partly account for the parallel reflectors of the lower evaporites since river erosion persisted throughout the msc the salt and upper evaporite units may also contain a large amount of detrital sediments the good quality of the new seismic data clearly reveals fan shaped messinian deposits in the downstream part of the main messinian valleys i e the nile var and spanish rivers the depositional scenarios generally involve a substantial sea level fall coupled with deltaic prodeltaic accumulations a chaotic seismic unit unit d filling messinian lows and extending beneath the salt within the study area is interpreted as a messinian clastic unit we propose a polyphase scenario of detrital fan deposition involving pre syn and post salt deposition in subaqueous subaerial environments in the gulf of lions a late miocene tectonic phase that affected the western shelf also played an important role in controlling a the pattern of the messinian fluvial network b the location of maximum erosion on the shelf and c the location of the detrital fan depocentre downslope

orbitally controlled oscillations in planktic communities and cyclic changes in western mediterranean hydrography during the messinian we use quantitative analyses of the planktic foraminiferal assemblages and stable isotope analyses of the sorbas section in the western mediterranean to reconstruct the cyclical changes in surface and deep water hydrographic conditions during the late miocene prior to the messinian salinity crisis oscillations in winter and summer temperatures linked to cyclical fluctuations in the hydrographic conditions and nutrient availability were the main mechanisms driving the cyclical changes in the planktic foraminiferal assemblages during the messinian the winter intensification and southward expansion of the northern cool and dry winds during precession maxima lowered sea surface temperatures below 14 15 c favoring water convection and the upward mixing of nutrients with the consequent increase in the proportion of cold eutrophic water foraminifera the low summer temperatures below 24 c inhibited the growth of warm oligotrophic water foraminifera as occurs today in the mediterranean by contrast at times of precession minima the low influence of the high latitude air masses caused winter temperatures to remain relatively high which combined with the lower surface salinities led to the formation of a permanent pycnocline winter conditions prevented the growth of cold eutrophic water foraminifera while high summer temperatures and the formation of a permanent pycnocline stimulated the growth of warm oligotrophic water foraminifera the prevalence of stable water stratification during winter due to the large density gradient between the surface and intermediate waters prevented deep water formation and slowed down the rates of oxygen supply to the bottom resulting in the formation of the sapropels a sharp decrease in 13c of benthic and planktic foraminifera that occurred between 6 8 and 6 7 myr is related to an increase in the residence time of mediterranean waters because similar changes have been observed in other regions of the mediterranean we conclude that this change records a significant reduction in the atlantic mediterranean water exchange at that time mediterranean climatic amplification increased throughout the messinian as the atlantic mediterranean water exchange was progressively more limited and oscillations in the ratio of planktic benthic foraminifera and of warm oligotrophic cold eutrophic species are good records of this increasing amplification which culminated at 5 95 myr with the deposition of gypsum pelitic layers that mark the onset of the messinian salinity crisis

transition from marine to hypersaline conditions in the messinian tripoli formation from the marginal areas of the central sicilian basin abstract three sections of the early messinian tripoli formation from the northern and southern margins of the central sicilian basin serra pirciata torrente vaccarizzo and marianopoli have been studied with the aim to reconstruct the sedimentary and environmental changes which occurred during the transition between marine conditions and the evaporitic events of the salinity crisis recorded in the overlying calcare di base formation a detailed biostratigraphic and cyclostratigraphic study provided the opportunity of cycle by cycle correlations between the marginal sections and the reference section of falconara the main paleoenvironmental changes are recorded by 1 the evolution of calcareous microfossils towards low diversity and their complete disappearance 2 the composition of the carbonate fraction which commonly changes from calcite mostly related to calcareous microfossils to authigenic carbonate phases consisting of either calcite dolomite and or aragonite 3 the appearance of shallow water deposits and evaporite pseudomorphs 4 the variation of the stable isotope composition of the carbonate fraction indicative of large fluctuations of the freshwater dilution evaporation balance with a general trend towards hypersaline conditions both mineralogical and isotope data indicate that the dolomite precipitated generally from concentrated pore waters while other carbonates formed in the water column submitted to large fluctuations of salinity except locally the increase in salinity did not reach concentrations high enough to precipitate significant volumes of evaporites as during the deposition of the overlying calcare di base the transition from normal marine to hypersaline conditions is recorded diachroneously in the three sections respectively in cycle 34 6 32 ma at serra pirciata cycle 42 6 15 ma at torrente vaccarrizzo and cycle 44 6 12 ma at marianopoli these changes represent the hydrological and sedimentary response to the fragmentation of a large marine basin into different subbasins which ended in the more or less complete closure recorded by the deposition of the overlying evaporite rich calcare di base fm true onset of the evaporitic event two hypotheses not exclusive may explain this change either the regional consequence of the compressive tectonics or the incipient drop of the global sea level which led to the salinity crisis our results confirm that the salinity crisis was preceded by evaporative episodes in the evolution towards hypersaline conditions which occurred diachroneously as a response to the diversity of paleogeographical settings even if the paroxysmal phase seems to have affected the basin at the same time

cyclostratigraphy and astrochronology of the tripoli diatomite formation pre evaporite messinian sicily italy the ongoing debate about the messinian salinity crisis in the mediterranean is fuelled in part by the lach of an adequate time control the most accurate and at the same time detailed constrains are nowadays provided by the astronomical dating technique here we present an astronomical age model for the cyclically bedded tripoli diatomite formation on scily pre evaporite messinian italy based on an intergrated stratigraphic study of three key sections falconara gibliscemi and capodarso characteristic sedimentary cycle pattenrs allow i the sections to be cyclostratigraphically correlated the bed to bed correlations being confirmed by high resolution planktonic foraminiferal biostratigraphy and ii the tripoli cycles to thecalibrated to the astronomical record despite minor misfits the correctness of thetuning is evident from the match between precession obliquity interference in the astronomical target and its reflection in the sedimentary cycle record the tuning provides absolute astronomically dated at 7 005 ma indicating that the onset of diatomite formation is diachronous in the mediterranean since itstarted 300 000 years earlier on sicilt than on gavdos south of crete the top of the tripoli and thus the onset of the salinity crisis proper on sicily arrives at 5 98 ma

age refinement of the messinian salinity crisis onset in the mediterranean we propose a revised age calibration of the messinian salinity crisis onset in the mediterranean at 5 971 ma based on the recognition of an extra gypsum cycle in the transitional interval of the perales section sorbas basin spain and the revision of the magnetostratigraphy of the monticino section vena del gesso basin italy this age re calibration allows to state more accurately that i the interval encompassing the msc onset is continuous thus ruling out any erosional feature or stratigraphic hiatus related to a major sea level fall affecting the mediterranean ii the first gypsum was deposited during the summer insolation peak at 5 969 ma associated with an eccentricity minimum and roughly coincident with glacial stage tg32 iii the msc onset was preconditioned by the tectonically driven reduction of the hydrological exchanges with the atlantic ocean and finally triggered by glacial conditions in the northern hemisphere and by arid conditions in northern africa

variation of volcanic gas composition at a poorly accessible volcano sakurajima japan abstract volcanic gas compositions are estimated based on volcanic plume measurement with multi gas at a frequently erupting sakurajima volcano by application of airborne methods and automatic monitoring station on the flank during 2013 2019 the airborne measurements of co2 and h2o concentrations often suffer from large fluctuation of background likely due to entrainment of the atmosphere derived from different altitude by removing the background effect a representative volcanic co2 so2 mole ratio is estimated as 0 4 0 1 and we did not observe clear temporal variation the volcanic h2o so2 ratios are estimated as 30 70 with a large uncertainty because of the strong atmospheric perturbation the so2 h2s ratios show quite a large variation ranging from 1 to 800 the large so2 h2s ratios larger than 30 are observed during ash eruption and are suggested as a result of oxidation by atmosphere on hot ashes the small ratios less than 10 are observed when frequency of explosions is low variation of the so2 h2s ratios of the small values can be caused by variation of degassing pressure however the small variation of the co2 so2 ratio suggests a limited range of the pressure variation

paleoenvironmental changes in the northern area of the east china sea during the past 42 000 years a 33 65 m long images md982195 core with very high sedimentation rate ca 80 cm kyr retrieved from the northern part of the east china sea was analyzed at 10 cm intervals about 125 years for oxygen carbon isotope of globigerinoides ruber sensu stricto sea surface temperature sst from alkenones u37 k and principal component analysis of planktonic foraminiferal assemblage the general pattern of the 18o curve resembling the alkenone sst curve is similar to the standard open ocean oxygen isotope curve it reveals many light 18o peaks apparently corresponding to dansgaard oeschger d o cycles as observed in greenland ice cores for the last 42 ka the alkenone sst at the core top is 24 c which is close to the modern annual mean sst around the core site on the other hand sst during the last glacial maximum lgm was about 5 c lower than that in the present day alkenone derived sst does not correlate with the light negative 18o peaks corresponding to the d o cycles the oxygen isotope ratios for the surface waters based on oxygen isotopes of g ruber and alkenone ssts indicate approximately 1 0 increase on average during the lgm and many light peaks at the warm d o events this suggests that fresh water was supplied to the core site during these events the meandering of the westerlies during the cold and warm d o cycles would have caused an atmospheric tele connection between east asia and greenland the core was divided into four periods based on q mode factor analysis of the planktonic foraminiferal assemblage i e 1 a strong upwelling period from 42 to 24 ka indicated by abundant occurrence of globigerina bulloides 2 a cold and low salinity water mass period from 24 to 14 ka suggested by increase of neogloboquadrina pachyderma neogloboquadrina incompta and globigerina quinqueloba 3 a transitional period from cold to warm water masses from 14 to 8 ka as indicated by the increase of warm water species such as pulleniatina obliquiloculata and globigerinoides ruber and 4 the present day warm kuroshio current condition after 8 ka the kuroshio current flowed into the ecs since the last 42 ka and weakened during the last glacial maximum lgm due to the expansion of the coastal water in the northern part of the ecs

the messinian salinity crisis looking for a new paradigm abstract the importance of the sedimentary record of messinian events in the apennines foredeep is due to its geological and structural settings which allow the reconstruction of the relationships between marginal and basinal settings and provide fundamental insights into some important issues a geologic stratigraphic model of the messinian apennine foredeep indicating a possible solution for closing the last messinian gap is here presented moreover the establishment of a preliminary high resolution stratigraphy for the terminal lago mare stage allows us to attempt mediterranean scale correlations across different structural settings the messinian evolution of the apennine foredeep and some considerations of adjacent areas suggest the great importance of tectonic deformation in controlling messinian events the intra messinian unconformity is a common feature of the marginal basins of the mediterranean and it is associated in many cases to the collapse and resedimentation of primary evaporites the genesis of such unconformity seems to be strictly related to a general tectonic reorganization of the mediterranean area preliminary observation on the stratigraphy of the lago mare stage suggest that the high frequency lithological cyclicity observed in the non marine deposits of this stage as well as the superimposed transgressive trend are common to many mediterranean basins these characteristic features might reflect the interplay between a longer term tectonic trend and higher frequency precession related climatic changes this could represent a fundamental tool for establishing a high resolution stratigraphic framework of the latest messinian allowing long distance correlations between terrestrial and marine ecosystems and hence more accurate palaeoenvironmental studies

late tortonian early messinian stepwise disruption of the mediterranean atlantic connections constraints from benthic foraminiferal and geochemical data abstract late miocene marine land based sections in the mediterranean area contain important information on the prelude to the messinian salinity crisis msc integrated bio magneto tephra and cyclo stratigraphy allows for bed to bed correlations of sections throughout the mediterranean and its borderlands and enables correlation with extra mediterranean atlantic sites benthic foraminiferal and geochemical data from five sections were compared to literature data and indicate that a restriction of the mediterranean from the atlantic ocean started during the late tortonian b the continuous development towards the msc started as early as 7 2 ma in the deeper parts of the basin and was enhanced by astronomical forcing and 3 the onset of the msc must have been to a large extent related to differential vertical movements at the betic and rifian corridors the miocene connections between the mediterranean and the atlantic

carbonate stromatolites from a messinian hypersaline setting in the caltanissetta basin sicily petrographic evidence of microbial activity and related stable isotope and rare earth element signatures lower messinian stromatolites of the calcare di base formation at sutera in sicily record periods of low sea level strong evaporation and elevated salinity thought to be associated with the onset of the messinian salinity crisis overlying aragonitic limestones were precipitated in normal to slightly evaporative conditions occasionally influenced by an influx of meteoric water evidence of bacterial involvement in carbonate formation is recorded in three dolomite rich stromatolite beds in the lower portion of the section that contain low domes with irregular crinkly millimetre scale lamination and small fenestrae the dominant microfabrics are i peloidal and clotted dolomicrite with calcite filled fenestrae ii dolomicrite with bacterium like filaments and pores partially filled by calcite or black amorphous matter and iii micrite in which fenestrae alternate with dark thin wispy micrite the filaments resemble beggiatoa like sulphur bacteria under scanning electron microscopy the filaments consist of spherical aggregates of dolomite interpreted to result from calcification of bacterial microcolonies the dolomite crystals are commonly arranged as rounded grains that appear to be incorporated or absorbed into developing crystal faces biofilm like remains occur in voids between the filaments the dolomite consistently shows negative d 13 c values down to 11ae3 and very positive d 18 o mean value 7ae9 that suggest formation as primary precipitate with a substantial contribution of organic co2 very negative d 13 c values down to 31ae6 of early diagenetic calcite associated with the dolomite suggest contribution of co2 originating by anaerobic methane oxidation the shale normalized rare earth element patterns of sutera stromatolites show features similar to those in present day microbial mats with enrichment in light rare earth elements and m type tetrad effects enrichment around pr coupled to a decline around nd and a peak around sm and eu taken together the petrography and geochemistry of the sutera stromatolites provide diverse and compelling evidence for microbial influence on carbonate precipitation