oxygen isotope signatures from land snail helix melanostoma shells and body fluid proxies for reconstructing mediterranean and north african rainfall abstract in this paper we show that oxygen isotope ratios from the shell carbonate of the land snail helix melanostoma reflect local rainfall parameters stable oxygen isotopes were measured in the body fluid 18 o body and shells 18 o shell of live collected h melanostoma along a north south transect across the gebel akhdar in northeast libya 18 o body ranged between 8 1 and 13 0 whilst 18 o shell ranged between 1 0 and 2 8 to investigate the relationship between snail oxygen isotope composition and climate these measurements were correlated with ambient air temperature relative humidity rainfall amount and the 18 o composition of rainwater 18 o rain strong and significant correlations were found between 18 o shell and 18 o rain and between 18 o shell and rainfall amount r 2 0 79 and 0 85 respectively suggesting that h melanostoma shells can be used as a proxy for past rainfall conditions when combined in multiple linear regressions 18 o rain and rainfall amount explained 90 of the variance in 18 o shell r 2 0 90 simple and multiple linear regressions were used to develop predictive models for these climate parameters as h melanostoma shells are commonly found in mediterranean and north african archaeological and geological deposits the predictive equations developed in this study hold great potential for reconstructing pleistocene to holocene rainfall and aridity patterns in the gebel akhdar and for assessing the relationship between environmental changes and human behavioural changes

the influence of diet on the δ13c of shell carbon in the pulmonate snail helix aspersa abstract the influence of diet and atmospheric co2 on the carbon isotope composition of shell aragonite and shell bound organic carbon in the pulmonate snail helix aspersa raised in the laboratory was investigated three separate groups of snails were raised on romaine lettuce c3 plant 13c 25 8 corn c4 plant 13c 10 5 and sour orange 12c enriched c3 plant 13c 39 1 the isotopic composition of body tissues closely tracked the isotopic composition of the snail diet as demonstrated previously however the isotopic composition of the acid insoluble organic matrix extracted from the aragonite shells does not track diet in all groups in snails that were fed corn the isotopic composition of the organic matrix was more negative than the body by as much as 5 whereas the matrix was approximately 1 heavier than the body tissues in snails fed a diet of c3 plant material these results indicate that isotopic composition of the organic matrix carbon cannot be used as an isotopic substrate for paleodietary reconstructions without first determining the source of the carbon and any associated fractionations the isotopic composition of the shell aragonite is offset from the body tissues by 12 3 in each of the culture groups this offset was not influenced by the consumption of carbonate and is not attributable to the diffusion of atmospheric co2 into the hemolymph the carbon isotopic composition of shell aragonite is best explained in terms of equilibrium fractionations associated with exchange between metabolic co2 and hco3 in the hemolymph and the fractionation associated with carbonate precipitation these results differ from previous studies based primarily on samples collected in the field that have suggested atmospheric carbon dioxide contributes significantly to the shell 13c the culture results indicate that the 13c of aragonite is a good recorder of the isotopic composition of the snail body tissue and therefore a better recorder of diet than is the insoluble shell organic carbon because the systematic fractionation of carbon isotopes within the snail is temperature dependent the 13c of the shell could provide an independent technique for estimating paleotemperature changes

early mid pleistocene environments in the valsequillo basin central mexico a reassessment the valsequillo basin in central mexico has been of interest due to the presence of megafauna and evidence for early human occupation but research has been controversial it has been suggested that extensive and deep lakes characterised the early pleistocene environment but sediment exposure is highly fragmentary and reliable dating has been difficult here we report for the first time early pleistocene palaeoenvironmental reconstructions using stable isotopes diatoms tephra and pollen we studied several stratigraphic sections of mainly non volcanic rocks containing the 1 3 ma xalnene ash as a stratigraphic marker the isotope and other proxy data show that topographically low points in the basin were occupied by spring fed shallow water lakes during the early mid pleistocene with a trend to drier conditions the basin was a dynamic volcaniclastic environment during this period with the production of the toluquilla volcano sequence and other rhyolitic dacitic volcanic ashes interbedded with the lake sediments at the sections studied there is no evidence from the sections for extensive and deep lakes before or after the xalnene ash deposition the presence of lakes in the basin during the early pleistocene would have made it attractive for megafauna

calibration of the stable isotope composition and body size of the arid dwelling land snail sphincterochila candidissima a climatic archive abundant in mediterranean archaeological deposits land snails recovered from archeological deposits may be used to deduce climatic conditions during prehistoric occupation because their aragonitic skeletons are usually well preserved and document valuable climatic information in the form of isotope codes since the snail sphincterochila candidissima is common in archeological sites along the western mediterranean but has been minimally investigated the present work examines the relationship between the oxygen 18o and carbon 13c stable isotopes of modern specimens and relevant meteorological data individuals of sphincterochila were regularly live collected throughout 1 year from september 2013 to october 2014 in tarragona ne spain and the 18o and 13c values were measured at the shell lip or aperture which depicts the last growth episode closest to specimens collection date shell margin 18o values varied from 3 1 in september to 0 8 in april average shell margin 18o values per collection date positively correlated with monthly avera

stable carbon isotope record of middle to late holocene climate changes from land snail shells at hinds cave texas abstract stable carbon isotope ratios of shell carbonate and shell organic matter from land snails rabdotus alternatus from hinds cave texas are used to reconstruct the climate history of the drier western part of the southern great plains present mean annual rainfall of 400 mm over the last ca 5000 yr ams radiocarbon analyses of four individual shells from each of two strata indicate that there are no problems of reworking or age mixtures within strata however burning is evident in many shells amino acid composition and racemization were used to identify shells that had been significantly heated and these were rejected for isotopic analysis because of possible alteration of the isotopic signal fourteen samples of snails from hinds cave each consisting of 2 6 individual shells from the same provenience were radiocarbon dated by ams and analyzed for stable carbon isotopes in addition a sample collected alive ca ad 1890 from a nearby site was analyzed to represent modern conditions the shells show no decrease in organic content with age indicating good preservation of shell organic matter both the organic and carbonate isotope values show similar temporal trends the oldest samples 4100 4600 cal yr bp are relatively depleted in 13 c maximum 13 c values are reached at ca 3500 cal yr bp thereafter there is a regular depletion in 13 c with the recent sample showing the lowest 13 c value the change in the isotopic values over time is quite large range of 4 5 for organic matter and indicates substantial climatic changes the variations in isotopic values are interpreted as resulting primarily from changes in moisture conditions affecting the abundance of drought adapted cam crassulacean acid metabolism plant species enriched in 13 c thus relatively moist mid holocene conditions are indicated with increasingly dry conditions reaching a maximum at ca 3500 cal yr bp followed by progressively moister conditions through the late holocene

sta cruz atizapan a 22 ka lake level record and climatic implications for the late holocene human occupation in the upper lerma basin central mexico abstract the upper lerma is a high altitude basin with three water bodies linked by the lerma river this basin has a long archaeological history characterised by the establishment of settlements within the lacustrine ecosystem itself man made islands during the late classic to epiclassic ad 550 900 which were abandoned by the end of the epiclassic the upper lerma is an ideal site to study climatic and environmental conditions during the period of human occupation as well as during the last full glacial interglacial cycle two sediment cores stcrz 9 54 m and almoloya del rio 5 12 m were recovered from the highest lake in the system chignahuapan ten radiocarbon dates provide chronologies for these sequences in which the tres cruces tephra c 8500 yr bp and the upper toluca pumice c 11 600 yr bp serve as stratigraphic markers magnetic properties loss on ignition and diatom analyses were used to infer lake level fluctuations during the last c 22 000 yr bp the late pleistocene environment was characterised by a freshwater lake high sediment input and variable lake levels are recorded during the last glacial maximum c 19 000 16 000 yr bp while slightly higher water levels and reduced sediment input are recorded during the late glacial c 16 000 11 000 yr bp a short episode of shallow conditions is inferred by c 12 400 yr bp holocene lake levels were generally shallower and three episodes of very shallow slightly alkaline waters are identified the first dates to the early holocene c 11 000 7000 yr bp the second is centred at c 4600 4500 yr bp the third occurred between c 2000 and 800 yr bp c 200 bc ad 1100 calibrated ages with very shallow water after c 1400 yr bp ad 550 calibrated age lake level increased after c 800 yr bp these three shallow water events are also recorded at other sites in central mexico indicating regional climatic trends rather than local events a deeper water phase occurred between 7000 and 6400 6200 yr bp the last shallow water phase correlates with the classic and epiclassic periods ad 200 900 and shallowest conditions occurred in the late classic to epiclassic c ad 550 900 when the construction of man made islands reached a peak an increase in lake level after c 800 yr bp ad 1100 calibrated age may have led to the abandonment of this life strategy

stable isotope δ18o δ13c and δd signatures of recent terrestrial communities from a low latitude oceanic setting endemic land snails plants rain and carbonate sediments from the eastern canary islands abstract stable isotopes of oxygen and carbon extracted from fossil land snail shells have been used increasingly to interpret past environments to evaluate the utility of this approach for low latitude oceanic islands populations of the modern helicid land snail theba geminata a species also abundant in the quaternary fossil record of the region were sampled at ten low altitude d and 2 v smow for 18 o ranging from 11 to 2 v smow and from 2 6 to 0 7 v smow respectively the local vegetation is heterogeneous including c 3 c 4 and cam plants 13 c values vary from 13 0 to 29 0 v pdb across plant species of the 24 species five are c 4 15 are c 3 and four are cam plants the 18 o values for shells represent a narrow range of values from 0 3 to 2 5 v pdb which is consistent with the low climate seasonality typifying low latitude oceanic settings hypothetical model of the expected 18 o value for shell aragonite precipitated in equilibrium suggests that the most negative 18 o shell represent the closest estimate for 18 o rain water the 13 c values of shells range from 9 4 to 1 7 v pdb the most positive 13 c values are attributed to a diet based on c 4 plants the comparison of 13 c values of soft tissues and shells suggests that snails ingested notable amounts from 20 up to 40 of foreign carbonates consequently fossil shells with the most negative 13 c values should be selected for radiocarbon dating in future geochronological studies of the region the 13 c values of body tissues vary from 12 0 to 27 2 v pdb indicating that land snails consumed c 3 and c 4 plants indiscriminately the mean carbon isotopic composition averaged across multiple fossil specimens may thus provide a useful tool for reconstructing paleoclimates and paleoenvironments throughout the quaternary history of the canary islands and other comparable low latitude oceanic settings

study of the diet effect on δ13c of shell carbonate of the land snail helix aspersa in experimental conditions abstract this study aims to demonstrate the influence of the metabolic co2 derived from the diet and of the atmospheric co2 on the shell carbonate 13c of the pulmonate snail helix aspersa maxima raised under controlled conditions adult snails were analyzed and compared with three hatching and 1 day old young snails stemming from the same breeding one day after the 2 day old individuals were raised during 1 month three groups of gastropods were fed with fresh lettuce c3 plant 13c 27 49 three groups with corn c4 plant 13c 11 7 and three groups ate alternately both c3 c4 the difference between the average 13c values of the adult snails on the one hand and the hatched and 1 day old snails on the other hand indicates a depletion of 2 47 therefore the isotopic parents offspring signal is not preserved the depleted ingested albumen by the snail embryo in the egg during the building of the shell could explain this depletion the c3 diet experiment gave the expected isotopic composition difference between the diet lettuce and the shells average 13cshell lettuce 13 75 0 52 this result shows a clear diet effect on the isotopic composition of the snail shells for the c4 experiment the difference in carbon isotope composition between the corn and the shell 13cshell corn yielded an average value of 4 89 0 87 the main result is that 13c is not constant and appears to depend on the type of ingested food several hypotheses can arise from this study to explain the different fractionations a differences in the quality of the two diets b differences in turnover rate for c3 and c4 feeders the groups regularly fed with mixed diet yielded 13c values showing a preferential use of c3 food for most values the c3 c4 mixed dietary alternation probably led snails to use mainly the lettuce instead of the corn powder

palaeoclimate interpretation of stable isotope data from lake sediment archives the isotope composition of authigenic and biogenic carbonates and diatom silica are commonly used as palaeoclimate proxies from lake sediments this article reviews the controls on the isotope composition of lacustrine skeletal and non skeletal deposits and illustrates how stable isotope studies contribute to an understanding of changes in temperature precipitation patterns evaporation and the carbon cycle it highlights the differences in the palaeoclimate potential of a wide range of lakes ranging from open to closed lake basins a large number of the case histories but not all are drawn from studies of temperate lakes from europe large closed lake systems in the tropics and elsewhere lose water predominantly through evaporation and contain sediments with variable and generally high 18o values fluctuations in the isotope composition of authigenic or biogenic minerals are mainly a function of long term changes in the precipitation evaporation ratio in contrast small open lakes which have a degree of through flow typically contain sediments with 18o values that vary by no more than a few these variations are generally ascribed to variations in temperature or the isotope composition of precipitation p from which either an annual or seasonally specific signal can be gained these types of lakes are common in northern europe and at high altitudes the interpretation of isotope data from a lacustrine succession requires a knowledge of the local processes that might control and modify the signal their effects need to be quantified and a robust calibration using the modern lake system is necessary to establish the relationship between the measured signal the isotopic composition of the host waters and climate

structural assemblage of high pressure mantle and crustal rocks in a subduction channel cabo ortegal nw spain 1 high pressure metamorphic fold nappes and ductile thrusts occur in the cabo ortegal upper allochthons they involve arc root lithospheric mantle peridotites high pressure volcanic arc granulites normal mid oceanic ridge basalt eclogites and shallow crustal volcanosedimentary high pressure gneiss units confluence of units from such disparate tectonic settings occurred at an eo hercynian convergent plate margin their internal deformation juxtaposition and high pressure synmetamorphic reworking resulted from kinematically simple but intense and polyphase ductile deformations fold nappes exhibit a remarkable sheath like form and contain mineral and stretching lineations defined by high pressure mineral assemblages subparallel to fold axes we argue that these structures outline the internal organization of high pressure sheets at deep tectonic realms of an oblique subduction collision orogenic channel

long and short term change in the patzcuaro basin central mexico abstract data are presented from four new cores from the patzcuaro basin in the volcanic highlands of central mexico which provide new insights into climate change and human impact over the last 23 000 cal yr 19 000 14c yr bp the cores have been analysed for a range of proxies including mineral magnetic properties loss on ignition diatoms and stable isotope composition 18o and 13c high lake levels are recorded in the late pleistocene and early holocene with a probable shift from winter precipitation from the pacific in the late pleistocene to the modern summer regime in the early holocene gradual drying and increased climatic variability are indicated from the early holocene but particularly since 4000 cal bp consistent with southward displacement of the itcz the changing chemical composition and depth of the lake led to the accumulation of ostracod layers the timing of the late holocene dry intervals corresponds to global periods of rapid change driven by bond and or solar cycles by combining a range of proxies we have been able to identify climatic change even within a period of significant human disturbance the use of multiple cores indicates that a coherent climatic signal is recorded even in a basin subject to tectonic disturbance this study also provides new data to support the interpretation of major human impact on the basin in both the pre and post hispanic periods refuting continued suggestions that basin wide erosion occurred only after the spanish conquest a new model of sediment un mixing has been applied to identify different source materials contributing to deposition

limnologic history of lago de patzcuaro michoacan mexico for the past 48 000 years impacts of climate and man abstract lago de patzcuaro lies at an elevation of 2035 m 19 36 n 101 39 w on the west part of the volcanic meseta central of mexico about 50 km east southeast of morelia pollen diatom and geochemical records from a 15 m core taken in 6 m of water continuously track vegetation and limnological changes in the patzcuaro basin for the past 48 ky calendar years pine oak and alder pollen dominate both the wisconsin and holocene vegetation record and indicate that this region did not witness strongly arid climates during that time before the holocene juniperus type and artemisia pollen document cooler climates of more effective moisture at least seasonally isoetes characterizes the full and late glacial interval 25 13 ka and implies along with the diatoms aulacoseira and stephanodiscus cool deep freshwater conditions at lago de patzcuaro the freshest and deepest lacustrine phase in the lake occurred 38 to 25 ka during this time lago de patzcuaro may have drained into the lerma river system between 30 and 10 ka diatom species that bloom in the winter and early spring imply moisture during those seasons evaluation of contemporaneous marine and terrestrial records west and east of lago de patzcuaro suggests that this moisture probably originated from westerly storm tracks shifted south by the laurentide ice sheet after 10 ka lago de patzcuaro became shallower and more eutrophic rooted aquatic plants prospered under a climate regime of negative hydrologic budgets increased seasonality and moisture arriving during the summer as it does today the lake became alkaline enough by the mid holocene to deposit ostracode rich marls at the core site for the first time in the past 48 ky indigenous agriculture in the patzcuaro drainage and around the lake appears about 4 ka with the appearance of zea and chenopodiineae pollen iron and potassium track increased soil erosion and planktic diatoms cyclostephanos record nutrients flushed into the lake from the drainage basin

oxygen isotope composition of living land snail shells data from italy sixty seven shells of living land snails were selected from 31 different localities across italy to investigate the relationships between their oxygen isotopic composition 18os and the mean value of local rainfall 18op despite the difficulty for some localities to correctly estimate the oxygen isotopic composition of local rainfall a good relationship was found this indicates that the oxygen isotopic composition of environmental water used by the snails is in italy strictly related to that of the local meteoric precipitation however the relationship found is substantially different from that previous established for central europe indicating that regional climatic conditions are important in defining the final isotopic composition of land snail shells moreover these equations may not hold for different climatic conditions existing during for instance glacial and interglacial periods the data also show that isotopic differences among species are relatively narrow and that they may depend on ecological factors i e style of life rather than any clearly identifiable different vital offset

stable isotope composition of land snail body water and its relation to environmental waters and shell carbonate abstract day to day and within day diel variations in d and 18 o of the body water of the land snail theba pisana were studied at a site in the southern coastal plain of israel three phases of variation which relate to isotopic changes in atmospheric water vapor were distinguished 1 on rain days snail water becomes isotopically depleted approximately in the direction of the rain isotope values but always less depleted in d as is atmospheric water vapor 2 during the 1 3 days following a rain the snail water becomes isotopically enriched along a line with slope 18 o space this relates to an increasing influence of humidity derived from the mediterranean sea 3 a period of relative stability of the isotopic composition persists until the next rain event the isotopic variations can be explained by isotopic equilibration with atmospheric water vapor and or uptake of dew derived therefrom during the winter when the snails are active there is only very minor enrichment in 18 o relative to equilibrium with water vapor or dew apparently as a result of metabolic activity but this enrichment becomes pronounced after long periods of inactivity within day variation in body water isotopic composition is minor on non rain days shell carbonate is enriched in 18 o by ca 1 2 relative to equilibrium with body water in most regions the isotopic composition of atmospheric water vapor or dew is a direct function of that of rain because the isotopic composition of snail body water is related to that of atmospheric water vapor and the isotopic composition of shell carbonate in turn is related to that of body water land snail shell carbonate 18 o should provide a reliable indication of rainfall 18 o however local environmental conditions and the ecological properties of the snail species must be taken into account

age constraints on alleged footprints preserved in the xalnene tuff near puebla mexico impressions in a basaltic tuff located around valsequillo reservoir near puebla mexico have been interpreted as human and animal footprints along an ancient lakeshore and are cited as evidence of the presence of humans in north america at 40 ka b p in this paper we present new data that challenge this interpretation paleomagnetic analyses of the xalnene tuff and lavas from the volcano from which it erupted yield fully reversed magnetic polarities indicating that the tuff was deposited prior to the last geomagnetic reversal the brunhesmatuyama ca 790 ka 40 ar 39 ar dating of xalnene lapilli and lava from the source volcano yields indistinguishable ages of 1 3 ma consistent with a period of reversed magnetic polarity c1r 2r additional paleomagnetic measurements of individual millimeter size lapilli indicate that the pyroclastic grains within the xalnene tuff have not been disturbed or rotated since their initial deposition thereby ruling out the possibility that the tuff was reworked by wave action along the shores of an ancient lacustrine environment this and other evidence indicate that the marks observed in the stone quarry site are not human ichnofossils

lake levels since about 40 000 years ago at lake chalco near mexico city abstract diatoms magnetic susceptibility organic content and14c ages of sediments from a 26 m core suggest that lake chalco in the southern part of the basin of mexico went through a series of major fluctuations during the late pleistocene and the holocene before ca 39 00014c yr b p the lake was very deep about 8 10 m alkaline and saline it then became shallow

carbon isotope signatures from land snail shells implications for palaeovegetation reconstruction in the eastern mediterranean in this study we compare carbon isotope values in modern helix melanostoma shell carbonate 13cshell from the gebel al akhdar region of libya with carbon isotope values in h melanostoma body tissue 13cbody local vegetation 13cplant and soil 13csoil all vegetation in the study area followed the c3 photosynthetic pathway however the 13cplant values of different species formed two distinct isotopic groups this can be best explained by different water use efficiencies with arid adapted species having significantly more positive 13cplant values than less water efficient species the ranges and means of 13cbody and 13cplant were statistically indistinguishable from one another suggesting that 13cbody was primarily a function of local vegetation composition h melanostoma 13cshell reflected the 13cplant of local vegetation with a positive offset between body diet and shell of 14 5 1 4 therefore in the gebel al akhdar where only c3 plants are present higher mean 13cshell values likely reflect greater abundances of water efficient c3 plants in the snails diet and therefore in the landscape whilst lower mean 13cshell values likely reflect the consumption of less water efficient c3 plants the distribution of these plants is in turn affected by environmental factors such as rainfall these findings can be applied to archaeological and geological shell deposits to reconstruct late pleistocene to holocene vegetation change in the southeast mediterranean

reconstruction of late pleistocene climate in the valsequillo basin central mexico through isotopic analysis of terrestrial and freshwater snails we aim to reconstruct the climatic and environmental conditions in the valsequillo basin during the deposition of the valsequillo gravels between c 40 000 and 8000 years ago when large mega fauna and potentially humans occupied the basin fossil freshwater fossaria sp and sphaeriidae family and terrestrial polygyra couloni holospira sp and cerionidae family snail shells from sections within the barranca caulapan were collected for oxygen and carbon stable isotope analysis oxygen and carbon isotopes in terrestrial and freshwater snail shells relate to local climatic parameters and environmental conditions prevailing during the lifetime of the snail whole shell isotope analysis showed that c 35 000 years ago climate in the valsequillo basin was similar to the present day between c 35 000 and 20 000 bp conditions became increasingly dry after which conditions became wetter again although this record is truncated intra shell isotopic analyses show that the amount of precipitation varied seasonally during the late pleistocene if people did reach this part of the americas in the late pleistocene they would have experienced changing long term and seasonal climatic conditions and would have had to adapt their life strategies accordingly

holocene snail shell isotopic record of millennial scale hydrological conditions in western mediterranean data from bauma del serrat del pont ne iberian peninsula land snail shells are a common component in mediterranean holocene archaeological deposits providing the opportunity to explore their potential as source of information concerning human behaviour and palaeoclimatic conditions many well preserved shells of the caenogastropod pomatias elegans were recovered along the holocene succession of bauma del serrat del pont bsp in the iberian peninsula their oxygen 18os and carbon 13cs isotopic compositions were analysed and compared with that of modern shells of the same species collected in two distinct areas near the archaeological site modern shells from site a shady and b sunny show distinctly different oxygen isotopic ratios possibly due to the effect of microenvironmental conditions e g temperature and relative humidity carbon isotopes by contrast reveal similar values isotope mass balance suggests a prevalent contribution of vegetation 70 integrated with foreign carbonates 30 to 13cs of modern snails early late holocene shells 9 2 5 cal ka bp have lower 18os compared with modern counterparts which is consistent with prevailing wetter conditions compared with present day the 13cs reveals distinct hydrological regimes wet and dry conditions from early to late holocene respectively in general shell isotopic records from western and central mediterranean regions suggest wetter conditions during the middle holocene with a possible reduction in humidity from 4 cal ka bp the 18os indicates a possible latitudinal difference in hydrological balance between mediterranean and atlantic europe as inferred by previous studies of regional palaeoclimatic records carbon isotopes by contrast do not provide a clear climatic picture probably due to the effect of distinct vegetation structure and composition comparisons with other environmental archives reinforce the concept of regional shell oxygen isotopic response to millennial scale changes in hydrological condition over the western and central mediterranean during the late quaternary

late quaternary lacustrine paleoenvironments in the cuenca de mexico abstract a late quaternary paleolimnological history from the mexican highlands has been obtained by diatom analysis of short cores and stratigraphic sections of lake and marsh sediments from the cuenca de mexico the large endorheic graben basin that holds mexico city the records dated by radiocarbon and tephrochronologic methods extend back to about 30 ka bp and document the presence of extensive saline lakes in the basin until 25 ka bp thereafter lake levels fell and marginal sites became shallow and fresh under the influence of surficial drainage and especially spring discharge a shallow saline lake existed 18 ka bp in texcoco the central and lowest basin in the system reflecting moderately increased effective moisture at that time by 16 ka bp lake texcoco had become so shallow that diatoms were no longer preserved however marginal sites nourished by spring flow recorded changes in the local hydrologic balance resulting from increased infiltration at higher elevations these changes appear to coincide with glacial advances between about 14 and 10 ka bp on the volcanic mountains surrounding the basin dry climates with reduced infiltration characterized the early holocene but by 5 ka bp a modest increase in precipitation established the modern climatic regime these lacustrine records offer important insights for evaluating the paleoenvironmental history of the cuenca de mexico based on other evidence they confirm glaciological stratigraphic and palynologic data that suggest dry climates and the absence of large pluvial lakes in the cuenca de mexico during and after the full glacial but document climates of significantly increased precipitation at least 10 ka prior to 18 ka bp

human footprints in central mexico older than 40 000 years abstract the timing route and origin of the first colonization to the americas remains one of the most contentious topics in human evolution a number of migration routes have been suggested and there are different views as to the antiquity of the earliest human occupation some believe that settlement happened as early as 30 ka bp but most of the currently accepted early sites in north america date to the latest pleistocene related to the expansion of the clovis culture while the oldest directly radiocarbon dated human remains are 11 5 ka bp in this context new evidence is presented in this paper in the form of human footprints preserved in indurated volcanic ash to suggest that central mexico was inhabited as early as over 40 ka bp human and animal footprints have been found within the upper bedding surfaces of the xalnene volcanic ash layer that outcrops in the valsequillo basin south of puebla mexico this ash layer was produced by a subaqueous monogenetic volcano erupting within a palaeo lake dammed by lava within the valsequillo basin during the pleistocene the footprints were formed during low stands in lake level along the former shorelines and indicate the presence of humans deer canids big felids and probably camels and bovids the footprints were buried by ash and lake sediments as lake levels rose and transgressed across the site the ash has been dated to at least 40 ka bp by osl dating of incorporated baked lake sediments

solar wind interaction with the martian upper atmosphere crustal field orientation solar cycle and seasonal variations a comprehensive study of the solar wind interaction with the martian upper atmosphere is presented three global models the 3 d mars multifluid block adaptive tree solar wind roe upwind scheme mhd code mf mhd the 3 d mars global ionosphere thermosphere model m gitm and the mars exosphere monte carlo model adaptive mesh particle simulator m amps were used in this study these models are one way coupled i e the mf mhd model uses the 3 d neutral inputs from m gitm and the 3 d hot oxygen corona distribution from m amps by adopting this one way coupling approach the martian upper atmosphere ion escape rates are investigated in detail with the combined variations of crustal field orientation solar cycle and martian seasonal conditions the calculated ion escape rates are compared with mars express observational data and show reasonable agreement the variations in solar cycles and seasons can affect the ion loss by a factor of 3 3 and 1 3 respectively the crustal magnetic field has a shielding effect to protect mars from solar wind interaction and this effect is the strongest for perihelion conditions with the crustal field facing the sun furthermore the fraction of cold escaping heavy ionospheric molecular ions 2 and or 2 total are inversely proportional to the fraction of the escaping ionospheric and corona atomic ion o total whereas 2 and 2 ion escape fractions show a positive linear correlation since both ion species are ionospheric ions that follow the same escaping path

a high elevation holocene pollen record from iztaccihuatl volcano central mexico pollen data from 3860 m in the agua el marrano valley on the northwest side of iztaccihuatl volcano southeastern part of the basin of mexico 198n combined with data on the glacial chronology and tephrochronology document holocene climatic and vegetation changes near the present timberline glacial advances occurred between 12 000 and 10 500 cal yr bp milpulco 1 and between 8300 and 7300 cal yr bp milpulco 2 a 450 cm core was drilled in sediments accumulated in a milpulco 1 moraine depression the sequence covers the last 11 000 cal yr bp according to three 14 c dates and the presence of a distinctive pumice deposit dated elsewhere at 5700 cal yr bp the pollen record of agua el marrano shows barren conditions after glacier retreat followed by a gradual colonization by elements of the alpine grasslands around 10 900 cal yr bp this plant community remained until c 7200 cal yr bp between c 7200 cal yr bp and 6500 cal yr bp coniferous forest grew close to or at the site but alpine grasslands were re established between 6500 cal yr bp and c 5000 cal yr bp apparently in connection with mid holocene dry conditions recorded in central mexico the upper timberline attained its modern altitude 4000 m in the last 3000 years during this period no significant changes are observed in the pollen spectra comparison with other palaeoecological records from central mexico suggests that the timberline fluctuated in response to both temperature and precipitation changes during the holocene

tepexpan palaeoindian site basin of mexico multi proxy evidence for environmental change during the late pleistocene late holocene the tepexpan palaeoindian skeleton was discovered in 1947 close to the former lake texcoco margin in the basin of mexico the find has been the object of considerable interest and discussion over the last 60 years regarding its real age and archaeological interpretation here we report new ams radiocarbon dates associated with the sedimentary succession at tepexpan with ages between 19 110 90 and 612 22 14c years bp and a new uranium series date for the skeleton with an age of 4700 200 years bp that indicates a mid holocene age the sedimentary succession was studied in detail using stable isotopes diatoms organic geochemistry and tephrochronology the multi proxy evidence suggests large changes around the margins of lake texcoco in terms of the balance between aquatic and terrestrial plants c3 and c4 plants saline alkaline and freshwater conditions volcanic activity marginal reworking of lake sediments and input from the drainage basin through the late pleistocene late holocene these changes had large impacts on the prehistoric human populations living by the lake shores since the late pleistocene in the basin of mexico

buried palaeosols of the nevado de toluca an alternative record of late quaternary environmental change in central mexico buried palaeosols of central mexico not previously analysed from a palaeopedological standpoint have helped to develop a reliable regional model of late quaternary climatic change this paper focuses upon morphological and micromorphological properties particle size distribution and extractable fe al and si of seven palaeosols named pt1 pt7 in the vicinity of the nevado de toluca volcano the characteristics of andic cambisol pt1 similar to those of modern soils in semi arid environments indicate a drier climate in the first half of the holocene humic andosols pt2 pt4 are analogous to modern volcanic soils of humid forest environments they show evidence that a moist palaeoclimate prevailed during marine oxygen isotope stages ois 2 and 3 luvisols pt5 and pt6 which are assumed to have formed at the end of marine ois 5 to marine ois 4 also indicate humid conditions we attribute the differences between andosols pt2 pt4 and luvisols pt5 pt7 to variations in the duration in the pedogenesis rather than to changes in palaeoclimate micromorphological features of andosol to luvisol transition confirm that these soils form an evolutionary sequence being for the most part consistent with lacustrine records the palaeosol properties do not reflect the episodes of drier climate during the last glacial maximum however as shown by diatom and palynological data from lake sediments mesoclimate variations and or incompleteness of soil memory reflecting mostly periods of humid pedogenesis probably provide the reason for this disagreement copyright 2001 john wiley sons ltd

oxygen and carbon isotope ratios in gastropod shells as indicators of paleoenvironments in the afar region of ethiopia abstract the oxygen and carbon isotope ratios in the shells of ancient freshwater gastropods coupled with geological geographical and hydrological data from their area and time of origin can yield information concerning general climatic conditions prevailing at the time the gastropod lived in addition sequential oxygen isotope analyses along the growth spiral of the shell provides indications of seasonal variability in the life span of the organisms such data were collected for some freshwater gastropods collected from two lakes and two springs in the afar region of ethiopia spanning late pleistocene to modern age episodes of high rainfall in the ethiopian highlands were clearly evident in the depleted 18o values in some shells whiel arid spells produced enriched levels in others hot springs introduced an added complication to the isotope record this study on a region of particularly complex hydrology and highly variable environmental history indicates the utility of stable isotope analyses as proxies for past climates but also emphasizes the problems involved

carbon and oxygen isotope composition of shell carbonate of desert land snails abstract variation in 13 c 12 c and 18 o 16 o ratios in the shell carbonate of several species of land snails was studied along a climatic gradient in semi arid to arid areas in the southern levant 13 c was found to be enriched in snails from communities having plants with a c 4 photosynthetic pathway depleted 13 c values were found in areas with high mean annual rainfall apparently due to higher input of metabolic co 2 as a result of greater snail activity shell carbonate 18 o values show a weak relation to the 18 o values of rainwater the shell 18 o values are enriched by 2 8 relative to isotopic equilibrium with environmental waters enrichment is suggested to result from metabolic effects on body water with lower activity producing greater enrichment but evaporation could also be a factor consistent differences in both 13 c and 18 o were found among species and may relate to the time when shell deposition occurs as with most paleoenvironmental indicators the application of shell isotopes is complicated by the multiplicity of controls of isotopic composition

spatial variability of environment change in the teotihuacan valley during the late quaternary paleopedological inferences the teotihuacan valley mexico has been the object of considerable interest because of its importance in the context of human history in america although archeological research has been extensively conducted to understand causes of the decline of teotihuacan culture no sufficient scientific evidence has been provided this paper is focused on paleopedological evidence especially properties that constitute soil memory in order to reconstruct the spatial distribution of environment variability during the late pleistocene and holocene three profiles that include modern soils and buried paleosols were studied in different geomorphic positions uplands cerro gordo site cg lower talus slope transition to valley bottom maseca ma and the mouth of the valley at the ancient border of the former texcoco lake this last site is near tepexpan te where some of the oldest human remains in mexico were recovered the oldest paleosol is at cg at 3000 m a s l it is dated at 22 000 yr bp and exhibits a truncated profile with a very well developed bt horizon dominated by kaolinite with phytoliths of c3 plants all of its features are related to a humid probably warm environment it was classified as a luvisol this paleosol is buried by another luvisol dated at 13 000 yr bp with morphological characteristics similar to the previous soil although clay mineralogy consists mostly of halloysite and a higher percentage of c4 plant phytoliths is apparent in ma the oldest paleosol was not recognized it is probable that the two paleosols found in cg merge into one at ma which shows strong redoximorphic features but high percentages of c4 plant phytoliths and halloysitic clays at the te site paleosols are less developed fluvisols modern soil cover also varies in relation to its geomorphic position in cg it is a phaeozem while in ma and te present day soils have carbonate accumulation we interpret prevailing conditions during the last glacial maximum in the teotihuacan valley to be humid with a tendency towards drying at the end of pleistocene dry conditions prevail in the valley today

record of the north american southwest monsoon from gulf of mexico sediment cores summer monsoonal rains the southwest monsoon are an important source of moisture for parts of the southwestern united states and northern mexico improved documentation of the variability in the southwest monsoon is needed because changes in the amount and seasonal distribution of precipitation in this semiarid region of north america influence overall water supply and fire severity comparison of abundance variations in the planktic foraminifer globigerinoides sacculifer in marine cores from the western and northern gulf of mexico with terrestrial proxy records of precipitation tree ring width and packrat midden occurrences from the southwestern united states indicate that g sacculifer abundance is a proxy for the southwest monsoon on millennial and submillennial time scales the marine record confirms the presence of a severe multicentury drought centered ca 1600 calendar cal yr b p as well as several multidecadal droughts that have been identified in a long tree ring record spanning the past 2000 cal yr from west central new mexico the marine record further suggests that monsoon circulation and thus summer rainfall was enhanced in the middle holocene ca 6500 4500 14 c yr b p ca 6980 4710 cal yr b p the marine proxy provides the potential for constructing a highly resolved well dated and continuous history of the southwest monsoon for the entire holocene

implications for late holocene climate from stable carbon and oxygen isotopic variability in soil and land snail shells from archaeological site 41km69 in texas usa abstract well preserved fossil land snail shell collected in a 115 cm soil profile from archaeological site 41km69 in texas usa minimally span the past 2200 years and provide an opportunity to explore the paleoclimate implications of isotopic variability in shell carbonates bulk soil carbonates and soil organic matter carbon isotopic compositions 13 c values of modern and archaeological adult snail shell carbonates suggest significant 60 dietary input of c 3 plants during all periods oxygen isotopic compositions of shells suggest that the isotopic composition of environmental water available at the time of shell growth has changed little over the period of the profile a linearly decreasing trend in 13 c of soil organic matter from 22 8 at the bottom of the profile 115 cm below surface to 25 6 for modern surface samples indicate an overall 20 increase in abundance of c 3 plants this implies a progressively wetter climate and less severe water stress conditions or decreasing summer rainfall that is in agreement with other studies on late holocene climate change in the southern great plains usa these results strongly suggest a stable climate that favored c 3 vegetation in this portion of texas during this period

quantitative estimates of orbital and millennial scale climatic variability in central mexico during the last 40 000 years abstract diatom based transfer functions for salinity precipitation and temperature were developed using a training set that included data from 40 sites along central mexico these transfer functions showed good performance parameters and were subsequently applied to the previously published diatom record from lake chalco southern basin of mexico heinrich stadials hs 3 to hs 0 were reconstructed as cold and dry events with hs 2 representing the coldest and driest conditions while hs 1 shows a complex bimodal cooling pattern orbital scale variability is also recorded high and variable lake salinities from 34 to 29 ka bp marine isotope stage 3 mis 3 corresponded with times of maximum summer insolation and evidences of frequent fires mis 2 was identified as a cold period with low lake salinity associated with low evaporation with two cold intervals during the minima in spring 25 5 ka bp and summer 20 ka bp insolation the 20 ka bp cold event together with hs 2 24 23 ka bp defined a bimodal maximum cooling during the last glacial maximum lgm 24 5 19 5 ka bp within the range of pollen based estimates further supporting a maximum tropical cooling of 4 5 c for the lgm the deglacial 19 5 11 5 ka bp showed the highest precipitation anomalies with three peaks that closely correlated with glacier advances in the nearby mountains iztaccihuatl the early holocene marked a change towards high lake salinities and the highest positive temperature anomalies 3 5 c during a peak in summer insolation even though at orbital scale chalco showed a nearly opposite trend to the record from the more southerly lake peten itza guatemala at millennial scale it showed a common pattern of cold and dry conditions during hss comparable to other tropical latitude sites in the northern hemisphere and further supporting the idea that there is a strong coupling between tropical and higher latitudes climates in particular with the north atlantic

environmental significance of 13c 12c and 18o 16o ratios of modern land snail shells from the southern great plains of north america c 12 c and 18 o 16 o ratios of aragonite shells of modern land snails from the southern great plains of north america were measured for samples from twelve localities in a narrow east west corridor that extended from the flint hills in north central oklahoma to the foothills of the sangre de cristo mountains in northern new mexico usa across the study area shell y 18 o values pdb scale ranged from 4 1x to 1 2x while y 13 c values ranged from 13 2x to 0 0x y 18 o values of the shell aragonite were predicted with a published steady state evaporative flux balance model the predicted values differed with one exception by less than 1x from locality averages of measured y 18 o values this similarity suggests that relative humidity at the time of snail activity is an important control on the y 18 o values of the aragonite and emphasizes the seasonal nature of the climatic information preserved in the shells correlated y 13 c values of coexisting vallonia and gastrocopta suggest similar feeding habits and imply that these genera can provide information on variations in southern great plains plant ecology although there is considerable scatter multispecies transect average y 13 c values of the modern aragonite shells are related to variations in the type of photosynthesis i e c3 c 4 in the local plant communities the results of this study emphasize the desirability of obtaining isotope ratios representing averages of many shells in a locale to reduce possible biases associated with local variations among individuals species etc and thus better represent the bneighborhoodq scale temporal and or spatial environmental variations of interest in studies of modern and ancient systems d 2004 university of washington all rights reserved

deciphering late quaternary land snail shell δ18o and δ13c from franchthi cave argolid greece this paper investigates the stable isotopic composition from late pleistocene holocene 13 to 10 5 cal ka bp shells of the land snail helix figulina from franchthi cave greece it explores the palaeoclimatic and palaeoenvironmental implications of the isotope palaeoecology of archaeological shells at the time of human occupation of the cave modern shells from around the cave were also analysed and their isotopic signatures compared with those of the archaeological shells the carbon isotope composition of modern shells depicts the consumption of c3 vegetation shell oxygen isotopic values are consistent with other mediterranean snail shells from coastal areas combining empirical linear regression and an evaporative model the 18os suggest that modern snails in the study area are active during periods of higher relative humidity and lower rainfall 18o probably at night late glacial and early holocene 18os show lower values compared to modern ones early holocene 18os values likely track enhanced moisture and isotopic changes in the precipitation source by contrast lower late glacial 18o could reflect lower temperatures and 18op compared to the present day shell carbon isotope values indicate the presence of c3 vegetation as main source of carbon to late glacial and early holocene snails