the stable isotopic composition of modern soil carbonate and its relationship to climate the oxygen isotopic composition of modern soil carbonate is well correlated with the isotopic composition of local meteoric water the carbon isotopic cycle for co 2 in soils can be described in terms of the proportion of biomass using the c 4 photosynthetic pathway and the co 2 respiration rate of the soil at low soil respiration rates significant atmospheric co 2 mixing can occur in general the carbon isotopic composition of soil carbonate is related to the proportion of c 4 biomass present in soil but soils that freeze to the depth of carbonate formation often have a significant atmospheric component this suggests that freezing of the soil solution should be considered as another important mechanism for soil carbonate formation because of these relationships the isotopic composition of soil carbonate may be a paleoclimatic and paleoecologic indicator in cases in which diagenetic alteration has not occurred

bounds on the viscosity coefficient of continental lithosphere from removal of mantle lithosphere beneath the altiplano and eastern cordillera 1 the rapid rise of the central andean plateau between 10 and 6 8 ma implies that mantle lithosphere including eclogitized lower crust was removed from beneath the region in that time interval we infer from that removal that the average viscosity coefficient of mantle lithosphere was quite low when removal occurred using scaling laws for the growth of perturbations to the thickness of a dense layer over an inviscid substratum rayleigh taylor instability we place bounds on the average viscosity coefficient for central andean lithosphere when compared with laboratory measurements of flow laws for olivine and eclogite the allowed range of viscosity coefficients yields bounds on the temperature of 500 800 c at the moho beneath this region and suggests that mean stresses across mantle lithosphere during continental deformation are less than 50 mpa this range of temperature is comparable with if a slightly lower than we might expect for lithosphere approximately doubled in thickness and not yet equilibrated with the doubled crustal radioactivity the mean deviatoric stress is comparable to that associated with stresses that drive plates and hence shows that lithospheric material is not too strong to prevent removal of its mantle part

uplift history of the central and northern andes a review the elevation of the andean cordillera is a crucial boundary condition for both climatic and tectonic studies the andes affect climate because they form the only barrier to atmospheric circulation in the southern hemisphere and they intrigue geologists because they have the highest plateau on earth formed at a noncollisional plate margin the altiplano puna yet until recently few quantitative studies of their uplift history existed this study presents both 1 a review of the quantitative paleoelevation estimates that have been made for the central and colombian andes and 2 an examination of the source and magnitude of error for each estimate in the central andes paleobotanical evidence suggests that the altiplano puna had attained no more than a third of its modern elevation of 3700 m by 20 ma and no more than half its modern elevation by 10 7 ma these data imply surface uplift on the order of 2300 3400 m since the late miocene at uplift rates of 0 2 0 3 mm yr paleobotanical and geomorphological data suggest a similar uplift history for the eastern cordillera namely no more than half the modern elevation present by 10 ma no evidence exists for an exponential increase in uplift rate as has been interpreted from fissiontrack data these uplift rates mostly reflect mean surface uplift rather than rock uplift that is uplift of material points because little dissection of the western eastern cordillera has occurred south of lat 19 s and of the altiplano puna thus the central andean plateau appears to be young in the colombian andes paleobotanical data imply rapid uplift of the eastern cordillera between 2 and 5 ma at rates on the order of 0 6 3 mm yr however some of this uplift is likely rock uplift due to erosion driven isostatic rebound rather than mean surface uplift

hydrological modelling of a pleistocene landslide dammed lake in the santa maria basin nw argentina abstract around 30 000 14 c yr bp multiple landslides in the quebrada de cafayate 26 s 66 w dammed the rio de las conchas and caused a lake in the santa maria basin nw argentina since climate could have played a major role in landslide generation we used a lake balance model to compare the present day climate with the conditions during landsliding this model reveals that a hypothetical present day lake would stabilize around 70 m below the reconstructed paleolake level the volume of the water body would be one third of the corresponding paleolake volume however a minimum 10 15 increase in mean annual precipitation accompanied by at least a 3 4 c drop in temperature would result in a stable lake level at the reconstructed elevation this result implies wetter and cooler conditions at 30 000 14 c yr bp as compared to the present wetter climate in turn could help to explain enhanced landsliding in the quebrada de cafayate during this time

temperatures of aqueous alteration and evidence for methane generation on the parent bodies of the cm chondrites aqueous alteration of primitive meteorites was among the earliest geological processes during the evolution of our solar system clumped isotope thermometry of carbonates in the cm chondrites cold bokkeveld murray and murchison demonstrates that they underwent aqueous alteration at 20 71 c from a fluid with 18 o vsmow of 2 0 to 8 1 and 17 o vsmow of 0 1 to 3 0 the 13 c vpdb values of these carbonates exhibit a negative correlation with the 18 o vsmow of their formation waters consistent with formation and escape of 13 c depleted ch 4 during aqueous alteration methane generation under these conditions implies that the alteration fluid was characterized by an eh 0 67 and ph 12 5 or lower at the highest alteration temperatures our findings suggest that methane generation may have been a widespread consequence of planetesimal and planetary aqueous alteration perhaps explaining the occurrence of methane on titan triton pluto and other kuiper belt objects

style and history of andean deformation puna plateau northwestern argentina topographically the puna plateau of northwestern argentina is the southern continuation of the bolivian altiplano its thickening and consecutive uplift result from the andean orogeny to better constrain the structural style and its progressive development we have studied field data topographic and satellite imagery balanced cross sections seismic reflection data kinematic analysis of fault slip data anisotropy of magnetic susceptibility ams paleomagnetic data and apatite fission track aft data across the puna plateau precambrian and paleozoic basement ranges bounded by high angle reverse faults dips 60 alternate with cenozoic intermontane basins major thrusts trend nne ssw and do not show a preferred vergence intermontane basins have various degrees of symmetry depending on the geometries and attitudes of associated thrusts as well as on the magnitudes of their offsets there is a close correlation between the surface expression of a basin and the amount of internal deformation a line balanced cross section of the puna at 25 s has yielded a cenozoic shortening of 10 15 in a direction subperpendicular to the orogen by kinematic analysis of cenozoic fault slip data we have obtained principal directions of strain rate across the puna shortening axes are subhorizontal and trend on average wnw ese n110 stretching axes are subvertical and intermediate axes are subhorizontal and trend on average nne ssw strain ellipsoids are dominantly of plane strain type and they represent dip slip thrusting from paleomagnetic and ams data shortening axes form a radial pattern around the eastern edge of the central andes the pattern is attributed to an inhomogeneous stress field reflecting the eastward convex shape of the central andean thrust front from the history of burial and uplift andean shortening reached the northeastern part of the puna in the late eocene and the adjacent eastern cordillera in the late eocene or early oligocene this shortening was presumably due to the incaic phase of the andean orogeny in the eastern part of the orogen the onset of shortening was probably guided by preexisting paleozoic and mesozoic structures so that andean deformation propagated unevenly eastward

influence of climate change and uplift on colorado plateau paleotemperatures from carbonate clumped isotope thermometry the elevation history of earth s surface is key to understanding the geodynamic processes responsible for the rise of plateaus we investigate the timing of colorado plateau uplift by estimating depositional temperatures of tertiary lake sediments that blanket the plateau interior and adjacent lowlands using carbonate clumped isotope paleothermometry a measure of the temperature dependent enrichment of 13 c 18 o bonds in carbonates comparison of modern and ancient samples deposited near sea level provides an opportunity to quantify the influence of climate and therefore assess the contribution of changes in elevation to the variations of surface temperature on the plateau analysis of modern lake calcite from 350 to 3300 m elevation in the southwestern united states reveals a lake water carbonate temperature lct lapse rate of 4 2 0 6 c km analysis of miocene deposits from 88 to 1900 m elevation in the colorado river drainage suggests that the ancient lct lapse rate was 4 1 0 7 c km and temperatures were 7 7 2 0 c warmer at any one elevation than predicted by the modern trend the inferred cooling is plausible in light of pliocene temperature estimates off the coast of california and the consistency of lapse rates through time supports the interpretation that there has been little or no elevation change for any of the samples since 6 ma together with previous paleorelief estimates from apatite u th he data from the grand canyon our results suggest most or all of the plateau s lithospheric buoyancy was acquired 80 60 ma and do not support explanations that ascribe most plateau uplift to oligocene or younger disposal of either the farallon or north american mantle lithosphere

effects of the submesoscale on the potential vorticity budget of ocean mode waters abstractnonconservative processes change the potential vorticity pv of the upper ocean and later through the subduction of surface waters into the interior affect the general ocean circulation

eocene exhumation and basin development in the puna of northwestern argentina 1 the puna is part of the larger puna altiplano plateau also known as the central andean plateau characterized by high elevation low relief and aridity located in the central andes of bolivia and argentina tertiary sedimentary rocks preserved within the puna contain a unique archive of information regarding the paleogeography depositional environments and timing of sediment source exhumation during the early stages of andean mountain building the eocene geste formation in the salar de pastos grandes area within the central puna of northwestern argentina consists of deposits that are the result of confined to unconfined flows in a sandy to gravelly braided fluvial system and alluvial fans proximal to the source terrane paleocurrent data document an overall eastward flow direction up section coarsening of the geste formation suggests that topographic relief in the source area increased through time possibly owing to enhanced tectonic activity and source terrane unroofing sandstone petrography and conglomerate clast count data document quartzose and phyllitic compositions typical of ordovician rocks preserved just west of the salar de pastos grandes area paleocene eocene detrital apatite fission track age populations p1 35 52 ma p2 52 65 ma of the geste formation and their consistent trends up section suggest moderate to rapid 0 4 mm a to 1 mm a exhumation of western sediment sources during the early to mid tertiary stages of andean mountain building sedimentation rates increase up section from 0 1 mm a to 1 mm a our data when combined with other structural stratigraphic and seismic evidence from surrounding regions suggest that the geste formation was deposited in response to crustal shortening and resulting erosion and sedimentation which started as early as cretaceous in the chilean cordillera de domeyko and in the salar de pastos grandes area by eocene time the geste formation could be interpreted either as a local wedge top accumulation on the eastward propagating central andean orogenic wedge or as a local intermontane basin the similarities between wedge top deposits preserved in bolivia and eocene deposits in northwestern argentina south of 25 s lead us to favor the wedge top scenario for the geste formation if correct this implies that the deformation front of the andean orogenic wedge incorporated both thin and thick skinned structures as it migrated possibly unsteadily from the cordillera de domeyko during the cretaceous paleocene to areas within the puna and eastern cordillera by mid late eocene time contemporaneously a regional scale foreland basin system developed over an along strike distance of at least 650 km

apatite triple dating and white mica 40ar 39ar thermochronology of syntectonic detritus in the central andes a multiphase tectonothermal history we applied apatite u pb fission track and u th he triple dating and white mica 40 ar 39 ar thermochronology to syntectonic sedimentary rocks from the central andean puna plateau in order to determine the source area geochronology and source sedimentary basin thermal histories and ultimately the timing of multiple tectonothermal events in the central andes apatite triple dating of samples from the eocene geste formation in the salar de pastos grandes basin shows late precambrian devonian apatite u pb crystallization ages eocene apatite fission track aft and eocene miocene u th he ca 8 47 ma cooling ages double dating of cobbles from equivalent strata in the arizaro basin documents early eocene 46 2 3 9 ma and cretaceous 107 6 7 6 109 5 7 7 ma aft and eocene oligocene ca 55 30 ma u th he ages thermal modeling suggests relatively rapid cooling between ca 80 and 50 ma and reheating and subsequent diachronous basin exhumation between ca 30 ma and 5 ma the 40 ar 39 ar white mica ages from the same samples in the salar de pastos grandes area are mainly 400 350 ma younger than apatite u pb ages suggesting source terrane cooling and exhumation during the devonian early carboniferous together these data reveal multiple phases of mountain building in the paleozoic and cenozoic basin burial temperatures within the plateau were limited to

paleosurfaces paleoelevation and the mechanisms for the late miocene topographic development of the altiplano plateau abstract we construct a topographic datum across the central andes between 18 s and 22 s using extensive well preserved paleosurfaces that span the entire range this datum combined with estimates of topographic change from paleoaltimetry in the altiplano and geomorphic relief generation estimates from the plateau flanks allow us to reconstruct the paleo topography of the range at 10 ma using the 10 ma topography we explore which geophysical processes can create the observed topographic change over the

carbonate clumped isotope bond reordering and geospeedometry carbonate clumped isotope thermometry is based on the preference of 13c and 18o to form bonds with each other at elevated temperatures such bond ordering is susceptible to resetting by diffusion of c and o through the solid mineral lattice this type of bond reordering has the potential to obscure primary paleoclimate information but could also provide a basis for reconstructing shallow crustal temperatures and cooling rates we determined arrhenius parameters for solid state reordering of c o bonds in two different calcites through a series of laboratory heating experiments we find that the calcites have different susceptibilities to solid state reordering reaction progress follows a first order rate law in both calcites but only after an initial period of non first order reaction that we suggest relates to annealing of nonequilibrium defects when the calcites are first heated to experimental temperature we show that the apparent equilibrium temperature equations or closure temperature equations for carbonate clumped isotope reordering are analogous dodson s equations for first order loss of daughter isotopes for each calcite the sensitivity of apparent equilibrium temperature to cooling rate is sufficiently high for inference of cooling rates within a factor of 5 or better for cooling rates ranging from tens of degrees per day to a few degrees per million years however because the calcites have different susceptibilities to reordering each calcite defines its own cooling rate apparent equilibrium temperature relationship the cooling rates of carrara marble inferred from carbonate clumped isotope geospeedometry are 10 6 10 3 degrees per annum and are in broad agreement with rates inferred from thermochronometric methods cooling rates for 13c depleted calcites from the late neoproterozoic doushantou cap carbonates in south china are on the order of 102 104 degrees per annum consistent with rapid cooling following formation of these calcites by a short lived hydrothermal event bristow et al 2011 nature v 474 p 68 71 most of the uncertainty in these estimates relates to uncertainty in arrhenius parameters for different calcites thus while the carbonate clumped isotope geospeedometer shows promise for recording cooling rates in settings and lithologies where other geospeedometers may not be applicable the uncertainty in cooling rate will be large without independent knowledge of the reordering kinetics of each study material thus the full potential of the method will only be realized if reordering kinetics can be accurately determined for each study material or predicted on the basis of mineral composition texture or other observable parameters

repeated crustal thickening and recycling during the andean orogeny in north chile 21 26 s posttectonic granitoids 2 lower crustal p wave velocities of 7 3 7 7 km s 1 compatible with underplated mafic crust and 3 results from recent experimental petrologic work showing garnet stability in mafic mineralogies 12 kbar 40 km crustal thickness analogous to older andean magmatic episodes in north chile newly underplated basaltic crust may account for the remaining deficit in neogene crustal thickening similar evolutionary patterns in geochemistry and initial sr and nd isotopic characteristics of andean 200 ma to present magmatic rocks suggest that the andean orogeny in this region evolved by a combination of processes of repeated arc migration tectonic and magmatic crustal thickening and igneous recycling which was controlled by periodically changing plate convergence rates and obliquity and corresponding changes in the rheologic behavior of the continental crust index terms 1020 geochemistry composition of the crust 1030 geochemistry geochemical cycles 0330 8159 evolution of the earth rheology crust and lithosphere 9360 information related to geographic region south america keywords andean orogeny continental crust recycling adakite ttg crustal thickening

oligocene range uplift and development of plateau morphology in the southern central andes 1 the puna altiplano plateau in south america is a high elevation low internal relief landform that is characterized by internal drainage and hyperaridity thermochronologic and sedimentologic observations from the sierra de calalaste region in the southwestern puna plateau argentina place new constraints on early plateau evolution by resolving the timing of uplift of mountain ranges that bound present day basins and the filling pattern of these basins during late eocene miocene time paleocurrent indicators sedimentary provenance analyses and apatite fission track thermochronology indicate that the original paleodrainage setting was disrupted by exhumation and uplift of the sierra de calalaste range between 24 and 29 ma this event was responsible for basin reorganization and the disruption of the regional fluvial system that has ultimately led to the formation of internal drainage conditions which in the salar de antofalla were established not later than late miocene upper eocene oligocene sedimentary rocks flanking the range contain features that suggest an arid environment existed prior to and during its uplift provenance data indicate a common similar source located to the west for both the southern puna and the altiplano of bolivia during the late eoceneoligocene with sporadic local sources this suggests the existence of an extensive longitudinally oriented foreland basin along the central andes during this time citation carrapa b d adelmann g e hilley e mortimer e r sobel and m r strecker 2005 oligocene range uplift and development of plateau morphology in the southern central andes tectonics 24 tc4011 doi 10 1029 2004tc001762

hot or not impact of seasonally variable soil carbonate formation on paleotemperature and o isotope records from clumped isotope thermometry quantifying the timing and temperature of soil carbonate formation is important for interpreting isotopic records of earth surface temperature and soil water composition from paleosols pedogenic carbonates typically have been assumed to form at mean annual temperature but recent work suggests warm season bias in carbonate formation could impact the interpretation of d 18 o values and carbonate

influence of tidal range change and sediment compaction on holocene relative sea level change in new jersey usa we investigated the effect of tidal range change and sediment compaction on reconstructions of holocene relative sea level rsl in new jersey usa we updated a published sea level database to generate 50 sea level index points and ten limiting dates that define continuously rising rsl in new jersey during the holocene there is scatter among the index points particularly those older than 7 ka a numerical model estimated that paleotidal range was relatively constant during the mid and late holocene but rapidly increased between 9 and 8 ka leading to an underestimation of rsl by 0 5 m we adjusted the sea level index points using the paleotidal model prior to assessing the influence of compaction on organic samples with clastic deposits above and below an intercalated sea level index point we found a significant relationship p 0 01 with the thickness of the overburden r 0 85 we altered the altitude of intercalated index points using this simple stratigraphic relationship which reduced vertical scatter in sea level reconstructions we conclude that rsl rose at an average rate of 4 mm a 1 from 10 ka to 6 ka 2 mm a 1 from 6 ka to 2 ka and 1 3 mm a 1 from 2 ka to ad 1900

rapid late miocene rise of the bolivian altiplano evidence for removal of mantle lithosphere abstract the oxygen isotopic compositions of carbonates deposited in the northern altiplano demonstrate a rapid change in late miocene time which we attribute to an increase in elevation rainfall samples over an elevation transect adjacent to the altiplano of northern bolivia display a systematic decrease in mean annual 18 o values and define a local 18 o vs altitude gradient r gonfiantini m a roche j c olivry j c fontes g m zuppi the altitude effect on the isotopic composition of tropical rains chem geol 181 2001 147 167 which we apply to paleo meteoric water values determined from carbonates age constraints from magnetostragraphy and paleoelevation estimates suggest surface uplift of 2 5 to 3 5 km occurred between 10 3 ma and 6 8 0 4 ma when the altiplano rose to its current elevation only the removal of dense eclogitic lower crust and mantle lithosphere can generate a change of this magnitude and rapidity this change coincides with an 30 decrease in the rate of convergence between the south america and nazca plates and the propagation of deformation into the eastern subandean zone which we infer to have resulted from the increase in the force per unit length applied by the elevated andean plateau to the surrounding lowlands

cenozoic foreland basin system in the central andes of northwestern argentina implications for andean geodynamics and modes of deformation 1 cenozoic strata in the central andes of northwestern argentina record the development and migration of a regional foreland basin system analogous to the modern chaco parana alluvial plain paleocene lower eocene fluvial and lacustrine deposits are overlain by middle upper eocene hypermature paleosols or an erosional disconformity representing 10 15 myr this supersol disconformity zone is traceable over a 200 000 km2 area in the andean thrust belt and is overlain by 2 6 km of upward coarsening eastward thinning upper eocene through lower miocene fluvial and eolian deposits middle miocene pliocene fluvial lacustrine and alluvial fan deposits occupy local depocenters with contractional growth structures paleocurrent and petrographic data demonstrate westerly provenance of quartzolithic and feldspatholithic sediments detrital zircon ages from cenozoic sandstones cluster at 470 491 522 544 555 994 and 1024 1096 ma proterozoic mesozoic clastic and igneous rocks in the puna and cordillera oriental yield similar age clusters and served as sources of the zircons in the cenozoic deposits arc derived zircons become prominent in oligo miocene deposits and provide new chronostratigraphic constraints sediment accumulation rate increased from 20 m myr during paleocene eocene time to 200 600 m myr during the middle to late miocene the new data suggest that a flexural foreland basin formed during paleocene time and migrated at least 600 km eastward at an unsteady pace dictated by periods of abrupt eastward propagation of the orogenic strain front despite differences in deformation style between bolivia and northwestern argentina lithosphere in these two regions flexed similarly in response to eastward encroachment of a comparable orogenic load beginning during late paleocene time

temporal variations in lake water temperature paleoenvironmental implications of lake carbonate δ18o and temperature records abstract 18 o and clumped isotope measurements of lacustrine carbonates provide important records of past terrestrial climate and paleoelevation however one of the primary challenges interpreting these data is constraining the relationship between mineral formation temperature and seasonal and mean annual climate we examined surface water temperature records from 88 lakes across the globe to develop transfer functions that relate seasonal water surface temperature to mean annual air temperature these transfer functions provide a means of reconciling proxy measures of water temperature with annual climatic conditions mean annual surface water temperature is related to mean annual air temperature maat 0 0318 t water 2 2 195 t water 12 607 r 2 0 96 independent of lake size with consistently higher mean water temperatures than air n hemisphere spring april june mean lake surface temperatures maat 0 0097 t water 2 1 379 t water 8 227 r 2 0 94 are only slightly warmer than maat for lakes in all climate zones while summer water temperatures jja maat 0 0055 t water 2 1 476 t water 18 915 r 2 0 90 may be 10 20 c warmer than maat for cold climate lakes comparison of carbonate stable isotopic data from sites with different timescales of carbonate formation such as found along latitude or elevation gradients can lead to large over or underestimates of past temperature accurate paleoclimatic interpretation of isotopic proxies or use of temperature proxy constraints i e fossil leaves to estimate lake temperature and calculate water 18 o thus requires appropriate application of water temperature air temperature transfer functions particularly when considering ancient cool high elevation lake systems

stable carbon and oxygen isotopes of pedogenic carbonates ajo mountains southern arizona implications for paleoenvironmental change abstract in this study we compare the stable isotope composition of late holocene pedogenic carbonate from a late holocene soil developed on the pediment below the ajo mountains in southern arizona usa with measurements of the 18 o of the soil water throughout the seasonal cycle and with 18 o and 13 c measurements on older dated soils the comparison with the soil water composition shows that the pedogenic carbonate is forming in equilibrium with highly evaporated soil water at the highest summer temperatures the 13 c of the carbonate apparently reflects equilibrium with co 2 of an isotopic composition consistent with the present mixture of c3 desert shrubs and cam cactus comparison with glacial period soil carbonates shows that there has been little change in the 18 o but that the 13 c was about 4 5 heavier independent evidence indicates that glacial period summer temperatures were probably much cooler and that the 18 o of precipitation was also lighter the increase in the carbonate water fractionation factor with decreasing temperature probably counteracted the decrease in the 18 o of precipitation producing little net change in the 18 o of the soil carbonate we attribute the decrease in the 13 c to replacement of a glacial period c4 grassland by holocene c3 cam desert shrubs and succulents this replacement was probably in response to an increase in temperature and reduction in summer precipitation at the end of the last glacial period the 13 c of older soil carbonates indicates that landscape was dominated by grassland for most of the past 700 ka and that the present vegetation likely represents a relatively brief anomaly

uplift of the central andes of nw argentina associated with upper crustal shortening revealed by multiproxy isotopic analyses this study contributes to the uplift history of the andes which has received increasing attention in recent years because of its implications for geodynamic models and climate feedbacks shortening resulting in crustal thickening and removal of gravitationally unstable mantle lithosphere has been proposed to control deformation and uplift of cordillera type orogenic systems such as the puna plateau of the central andes and its eastern margin the eastern cordillera we present new clumped isotope 47 18o and 2 data from carbonate nodules marlstone spring deposits and volcanic ashes from the puna plateau and eastern cordillera of nw argentina when combined with other geological evidence our data indicate that the puna plateau was near its present elevation since at least 10 ma whereas the eastern cordillera rose 1 5 km between 14 and 7 ma this history of uplift correlates with active shortening in the eastern cordillera and with incorporation of a regional foreland into the propagating orogenic wedge our study suggests that the elevation of the puna plateau changed little during the miocene pliocene whereas the margin experienced significant uplift associated with active deformation and crustal thickening

stable isotope paleoaltimetry a critical review stable isotope paleoaltimetry makes use of systematic trends in the distribution and isotopic composition of modern precipitation with climate and topography and of the potential to estimate the isotopic composition of paleoprecipitation from authigenic in situ formed minerals to illustrate the usefulness as well as potential limitations of this method we review 1 processes controlling the isotopic composition of modern precipitation 2 stable isotope data from modern precipitation across regions of high topography and 3 stable isotope data from authigenic minerals that have been used to infer paleotopography from this we conclude that stable isotope studies of authigenic minerals can permit useful inferences on paleotopography with uncertainties that critically depend on a detailed understanding of local to global scale paleoclimate during the time interval of interest

clumped isotope evidence for diachronous surface cooling of the altiplano and pulsed surface uplift of the central andes spatially extensive paleoelevation records of the altiplano plateau are critical to determining the geodynamic mechanisms that formed and support high elevations over a broad area prior stable isotope data reveal a climate history for the northern bolivian altiplano that has been interpreted to show rapid surface uplift of 2 5 1 0 km between 10 and 6 ma this study applies clumped isotope paleothermometry to paleosol carbonates formed at both a low elevation site and temporally overlapping high elevation sites in the southern altiplano eastern cordillera during the middle to late miocene surface paleotemperature decreased by 14 c in the southern altiplano eastern cordillera relative to stable low elevation paleotemperatures implying surface elevation increase of 1 9 0 7 km between 16 and 13 ma and an additional 0 7 0 6 km between 13 and 9 ma both the large magnitude of surface temperature decrease and earlier onset 7 4 myr in the south as compared to the north suggest rapid elevation increase by piecemeal removal of lower lithosphere beneath the plateau and possible northward lower crustal flow

comment on rapid uplift of the altiplano revealed through 13c 18o bonds in paleosol carbonates based on stable isotope measurements ghosh et al reports 27 january 2006 p 511 concluded that the bolivian altiplano uplifted 3 to 4 kilometers between 10 3 and 6 7 million years ago as a result of gravitational loss of dense lithosphere this result stands at odds with current geological knowledge of the central andes and we propose a test for the reliability of the paleoaltimetry method

patterns and timing of exhumation and deformation in the eastern cordillera of nw argentina revealed by u th he thermochronology 1 the eastern cordillera ec and related ranges of bolivia and argentina exhibit a wide variety of structural features both thick and thin skinned that make this region a prime area to study the evolution of these two contrasting styles using a combination of structural geochronological and thermochronological techniques this study investigates how and in what order the various structures of the argentinean ec from 25 to 26 s have developed during the cenozoic new mapping in the angastaco area preserves one of the thickest cenozoic stratigraphic sections and records a complex structural evolution during the neogene characterized by inversion of cretaceous salta rift structures detrital zircon u pb geochronology combined with stratigraphic and structural features typical of synsedimentary deformation constrains the age of orgenic growth in the area to 14 ma detrital apatite u th he thermochronology on samples collected across the width of the southernmost ec at this latitude document an eastward younging of ages interpreted as the result of sequential eastward propagation of exhumation and inferred deformation from 14 to 3 ma at a rate of 8 3 mm a our data when compared with existing data show that the puna plateau of nw argentina was exhuming and deforming at the same time as the ec and inter andean regions of bolivia suggesting that the deformation front connects along strike despite of the differences in structural style whereas the deformation front reached the sub andes of bolivia by 10 ma deformation localized in the ec of nw argentina until 4 ma rates of propagation through the whole region seem to be quasi uniform regardless of different structural styles

the nature of orogenic crust in the central andes 1 the central andes 16 22 s are part of an active continental margin mountain belt and the result of shortening of the weak western edge of south america between the strong lithospheres of the subducting nazca plate and the underthrusting brazilian shield we have combined receiver function and surface wave dispersion results from the banjo seda project with other geophysical studies to characterize the nature of the continental crust and mantle lithospheric structure the major results are as follows 1 the crust supporting the high elevations is thick and has a felsic to intermediate bulk composition 2 the relatively strong brazilian lithosphere is underthrusting as far west 65 5 w as the high elevations of the western part of the eastern cordillera ec but does not underthrust the entire altiplano 3 the subcrustal lithosphere is delaminating piecemeal under the altiplano ec boundary but is not completely removed beneath the central altiplano the altiplano crust is characterized by a brittle upper crust decoupled from a very weak lower crust that is dominated by ductile deformation leading to lower crustal flow and flat topography in contrast in the high relief inland sloping regions of the ec and sub andean zone the upper crust is still strongly coupled across the basal thrust of the fold thrust belt to the underthrusting brazilian shield lithosphere subcrustal shortening between the altiplano and brazilian lithosphere appears to be accommodated by delamination near the altiplano ec boundary our study suggests that orogenic reworking may be an important part of the felsification of continental crust

paleoelevation estimates for the northern and central proto basin and range from carbonate clumped isotope thermometry 1 quantitative paleoelevation histories can help explain both why and how widespread cenozoic extension occurred in the basin and range province of western north america we present new estimates of preextensional paleoelevations for the northern and central basin and range using clumped isotope 47 thermometry of lacustrine carbonates collected from each region comparison of carbonate 47 derived mean annual air temperature maat estimates 16 c 20 c for the late cretaceous eocene sheep pass basin of east central nevada with published maat estimates for the eocene coastal northern sierra nevada 20 c 25 c suggests that the early paleogene sheep pass basin had a paleoelevation of 2 km such a modest paleoelevation suggests that either 1 the proto northern basin and range did not attain maximum paleoelevations of 3 4 km until the late eocene early oligocene or 2 the sheep pass basin was a local high relief 1 km setting contained within a 3 km orogenic highland nevadaplano similarity of 47 derived maat estimates 17 c 24 c for carbonates from the central basin and range and the near sea level southern sierra nevada bena basin indicate that middle miocene paleoelevations in the death valley region were 1 5 km these fairly low paleoelevations are incompatible with preextensional crustal thicknesses 52 km and indicate that mean elevation change was minor 500 m and lithospheric mass was not conserved during 100 neogene extension of the central basin and range but was instead likely compensated by synextensional magmatic additions to the crust

rapid uplift of the altiplano revealed through 13c 18o bonds in paleosol carbonates the elevation of earth s surface is among the most difficult environmental variables to reconstruct from the geological record here we describe an approach to paleoaltimetry based on independent and simultaneous determinations of soil temperatures and the oxygen isotope compositions of soil waters constrained by measurements of abundances of 13 c 18 o bonds in soil carbonates we use this approach to show that the altiplano plateau in the bolivian andes rose at an average rate of 1 03 0 12 millimeters per year between 10 3 and 6 7 million years ago this rate is consistent with the removal of dense lower crust and or lithospheric mantle as the cause of elevation gain

the paleoaltimetry of tibet an isotopic perspective stable isotopes provide a valuable perspective on the timing of elevation change of the tibetan plateau we begin our paper by looking in depth at isotopic patterns in modern tibet we show that the 18 o value of surface waters decreases systematically up the himalayan front in central nepal by about 2 8 km in agreement with the patterns documented and modeled by previous research on the tibetan plateau itself there is no apparent correlation between elevation and the 18 o value of flowing surface waters both surface waters and soil carbonates display a northward increase in 18 o values of about 1 5 north of the himalayan crest even though elevation increases modestly the isotopic increase with latitude reduces the isotope elevation gradient for water in the northernmost plateau to 1 to 2 km carbonates in both soils and lakes form at higher temperatures than assumed by previous studies on the plateau temperature estimates from clumped isotope 47 analyses of modern soil carbonates significantly exceed mean annual air t and modeled maximum summer soil temperatures by 15 8 2 8 and 9 7 2 5 c respectively similarly elevated temperatures best account for the 18 o values observed in modern soil and lake carbonates we recalculated paleoelevations from previous studies on the plateau using both higher formation temperatures and latitude corrected isotopic values with one notable exception our revised model produces paleoelevation estimates very close to previous estimates the exception is the reconstruction from late eocene age deposits at xoh xil for which we calculate elevations that are higher and much closer to the current elevation than previously reconstructed therefore there is no evidence for northward progression through time of tibetan elevation change instead the available but admittedly very scanty evidence suggests that much of tibet attained its modern elevation by the mid eocene a truly robust test of the various geodynamic models of uplift await expansion and replication of isotopic records all across tibet especially in the center and north and for 15 ma

spatial temporal changes in andean plateau climate and elevation from stable isotopes of mammal teeth abstract paleoelevation constraints from fossil leaf physiognomy and stable isotopes of sedimentary carbonate suggest that significant surface uplift of the northern andean plateau on the order of 2 5 1 km occurred between 10 3 and 6 4 ma independent spatial and temporal constraints on paleoelevation and paleoclimate of both the northern and southern plateau are important for understanding the distribution of rapid surface uplift and its relation to climate evolution across the plateau this study focuses on teeth from modern and extinct mammal taxa including notoungulates pyrotheres and litopterns spanning 29 ma to present collected from the altiplano and eastern cordillera of bolivia 16 2 s to 21 4 s and lowland brazil tooth enamel of large water dependent mammals preserves a record of surface water isotopes and the type of plants that animals ingested while their teeth were mineralizing previous studies have shown that the 18o of modern precipitation and surface waters decrease systematically with increasing elevations across the central andes our results from high elevation sites between 3600 and 4100 m show substantially more positive 18o values for late oligocene tooth samples compared to