neoproterozoic snowball earth simulations with a coupled climate ice sheet model ice sheets may have reached the equator in the late proterozoic era 600 800 myr ago according to geological and palaeomagnetic studies possibly resulting in a snowball earth but this period was a critical time in the evolution of multicellular animals posing the question of how early life survived under such environmental stress here we present computer simulations of this unusual climate stage with a coupled climate ice sheet model to simulate a snowball earth we use only a reduction in the solar constant compared to present day conditions and we keep atmospheric co2 concentrations near present levels we find rapid transitions into and out of full glaciation that are consistent with the geological evidence when we combine these results with a general circulation model some of the simulations result in an equatorial belt of open water that may have provided a refugium for multicellular animals

two cryogenian glacial successions compared aspects of the sturt and elatina sediment records of south australia abstract two cryogenian glacial sequences the sturt and elatina occur within the adelaide rift complex s australia and are part of an 8 km thick succession recording rodinia fragmentation and subsequent passive margin development we compare and contrast these glacial successions presenting new data including detailed logged sections for both glacial sequences facies analysis reveals a total of six facies associations recording a range of glacial and glacially related processes these are a diamictite facies association ice proximal debris flows a sheet sandstone facies association fluvial deposits a flaser and rhythmically bedded facies association tidal flat a hummocky cross stratified sandstone facies association shoreface to offshore transition zone deposits and an underflow facies association recording offshore deposition a sixth facies association a ferruginous lonestone bearing siltstone is restricted to the top of the elatina formation and records rapid environmental amelioration and emergence from glaciation in the central flinders ranges the sturt succession commences with a glacial erosion surface ges which in agreement with previous workers was probably enhanced by rifting this ges is overlain in ascending order by the pualco tillite holowilena ironstone and wilyerpa formation with the warcowie dolomite member at the base of this latter formation a second ges is preserved within this latter unit and is overlain by a stratigraphic motif that records an alternation of offshore transition zone and offshore deposits significant base level falls within the wilyerpa formation are identified by fluvial deposits sitting disconformably upon offshore deposits in contrast within the elatina formation a single ges is proposed which defines the base of the formation the elatina formation is split into two informal members on the basis of analysis of sediment stacking patterns and the recognition of a sharp stratigraphic surface that divides the formation apart from a locally preserved basal diamictite the lower member consists of fluvial deposits whereas the upper member is dominated by a mixture of tidal flat sediments and debris flow deposits the boundary between these units is therefore interpreted as a hybrid surface recording tidal ravinement in some areas and a glacial advance in others deglaciation left contrasting deposits the sturt deglaciation culminated in deposition of black shale of the tindelpina shale member of the tapley hill formation seemingly as a sheet like deposit over the adelaide rift complex and beyond into the amadeus basin of central australia the elatina deglaciation meanwhile began first with deposition of the sixth facies association ferruginous dropstone bearing siltstone then proceeded with deposition of cap dolostone of the nuccaleena formation

some guidelines in reconstructing ancient sea conditions from wave ripplemarks abstract the collection of substantial field data on wave ripple mark spacing wavelength steepness grain size and symmetry index from the miocene burdigalian sandstones of western switzerland has allowed apparently close reconstruction of sea conditions results indicate however that ancient wave reconstructions must be restricted at present to data from relatively steep ripple marks vfi less than 7 5 i e vortex ripples data from the flatter ripple marks post vortex types formed at high oscillatory shear stresses do not provide reasonable estimates of wave conditions penecontemporaneous overwashing and or post depositional compaction ripple formation near the destruction condition rather than the threshold of sediment movement orbital diameters far exceeding ripple spacing and superimposed unidirectional currents are all factors which seriously affect wave reconstructions evaluation of ancient wave conditions provides insight into geologically important phenomena such as local water depth and basin size

extreme winds and waves in the aftermath of a neoproterozoic glaciation the most severe excursions in the earth s climatic history are thought to be associated with proterozoic glaciations according to the snowball earth hypothesis the marinoan glaciation which ended about 635 million years ago involved global or nearly global ice cover at the termination of this glacial period rapid melting of continental ice sheets must have caused a large rise in sea level here we show that sediments deposited during this sea level rise contain remarkable structures that we interpret as giant wave ripples these structures occur at homologous stratigraphic levels in australia brazil canada namibia and svalbard our hydrodynamic analysis of these structures suggests maximum wave periods of 21 to 30 seconds significantly longer than those typical for today s oceans the reconstructed wave conditions could only have been generated under sustained high wind velocities exceeding 20 metres per second in fetch unlimited ocean basins we propose that these extraordinary wind and wave conditions were characteristic of the climatic transit and provide observational targets for atmospheric circulation models

stratigraphy sedimentology and isotopic geochemistry of australian neoproterozoic postglacial cap dolostones deglaciation delta 13 c excursions and carbonate precipitation abstract thin d13c excursions in the geologic record they are interpreted to record a brief postglacial anomaly in ocean chemistry in australia the marinoan varanger equivalent 600 ma cap dolostone units exhibit many of the characteristics displayed by such deposits elsewhere around the globe including fine grained dolomitic mineralogy lateral persistenc at basinal scales thin laminae graded beds intervals with abundant marine cements crystal fans and a distinctive negative d13c isotopic signature of up to 5 pdb on the basis of these features the australian examples are interpreted here to be deeper water deposits below storm wave base resulting from an anomalous flux of inorganic carbonate to the sea floor during postglacial transgression detailed isotopic analysis of australian cap dolostones indicates d13c values ranging from 1 to 5 and gen rally becoming more depleted in 13c upsection trace element data indicate some diagenetic stabilization but textural evidence and the presence of similar profiles in different basins argue against a pervasive recrystallization event the range in d13c values between sections as well as more negative 13c values appear to correlate with greater paleobathymetry within basins this implies either 1 only partial preservation of the complete oceanic variation of d13c or 2 precipitation of this peculiar facies owes its genesis to basinal specific oceanographic processes such as proximi y of a given section to a postglacial upwelling zone in the later case d13c values would not represent whole ocean values stratigraphic constraints and paleoenvironmental interpretations suggest that much of this excursion lies within the geologically brief period of postglacial transgression this implies that the cause s of d13c variation likely operated on time scales significantly less than the residence time of carbon in the oceans 105 yr the continent wide and perhaps global nature of cap dolostones indicates that large volumes of carbonate were precipitated during the postglacial transgressive period such large scale carbonate precipitation over the hypothesized short time interval of postglacial transgression must have caused or have been the product of profound changes in the carbon cycle and global climate at tha time similar evidence for transgression and increased carbonate deposition in the holocene are attributed to the changing basin shape and ph of the oceans the coral reef hypothesis of berger 1982 cap dolostones may record a proterozoic equivalent of this process with the substitution of abiotic carbonate precipitation for skeletal precipitation by reef organisms

late proterozoic aragonitic cement crusts bambui group minas gerais brazil the late proterozoic pedro leopoldo facies bambui group in the vicinity of belo horizonte brazil comprises alternating laminated microsparitic limestones 10 35 mm thick beds and fibrous limestones 10 55 mm thick the latter are composed of a mosaic of sparry calcite crystals these irregularly crosscut rays and fans are composed of feathery precursor crystal bundles with squared off growth zones ghosts of an original fibrous mineral hexagonal in cross section are visible the petrographic characteristics very high strontium content and low magnesium content of the fibrous beds as well as microspar beds strongly argue for an original aragonitic mineralogy the rays are interpreted as having formed by precipitation at the sediment water interface whereas the micrite was precipitated from the water column prior to deposition on the sea floor the lack of emergence features suggests widespread aragonite precipitation under persistently subtidal conditions

digital photogrammetric analysis and electrical resistivity tomography for investigating the picerno landslide basilicata region southern italy abstract digital photogrammetric analysis and electrical resistivity tomography ert techniques were applied to evaluate the volume of material involved in a complex roto translational slide occurred in the territory of picerno basilicata region southern italy analytical and digital photogrammetric techniques facilitated a multi temporal analysis of aerial photos for the years 1997 2004 and 2006 in order to identify different geomorphologic features scarps terraces and trenches of the landslide and their development the analytical and digital photo interpretation was performed at the maximum scale of 1 5000 geological and geomorphological surveys were carried out to verify photo interpretation results digital elevation models dems for 1997 2004 and 2006 were produced by applying the grid adaptive method the differential dems 2006 1997 2006 2004 2004 1997 for the most dangerous part of the landslide allowed us to recognize the areas affected either by deposition or erosion and also estimate any altitudinal changes in each geomorphologic unit to detect the sliding surface and estimate the thickness of the sliding material several transversal and longitudinal ert profiles were obtained the electrical images of subsurface supported by stratigraphical data from boreholes were integrated with the information from the dems the altitudinal changes and the sizes of the source and accumulation areas allowed us to estimate the volume of material involved in the mass movement the fusion of data from different sensors allows us to gather indications on the surface and subsurface characteristics of the landslide providing useful information for landslide mitigation activities such an approach can help both to improve our knowledge and overcome the drawbacks of each methodology

reconstruction of ancient sea conditions with an example from the swiss molasse ancient sea conditions can be estimated from the grain size spacing and steepness of preserved ripple marks the element of greatest uncertainty in such reconstructions is the relationship between near bed orbital diameter of water particles and the ripple spacing this relationship is simple for vortex ripples of high steepness but is problematical for the low steepness forms known as post vortex rolling grain or anorbital ripples the existence field for wave ripples is between the threshold velocity for sediment movement and the onset of sheet flow most low steepness forms occurring close to the bed planation threshold a range of maximum period of formative waves can be obtained using combinations of orbital diameter and orbital velocity assuming linear wave theory to be a reasonable approximation probable wave heights wave lengths and water depths can be investigated using the transformation of wave parameters in shallowing waters and the constraints on wave dimensions provided by the wave breaking condition given reasonable estimates of wave height crude estimates of wave power allow a comparison of ancient wave influenced sequences with modern counterparts wave ripple marks preserved in the upper marine molasse of western switzerland have been investigated results which are in agreement with regional geology suggest deposition in a seaway of approximately 100 km width where moderate period waves t 3 6 s were generated the depositional facies belts were adjusted to the prevailing waves tides and fluvial outflows

evolution of the margin of the gulf of california near loreto baja california peninsula mexico the gulf of california is a prime example of a young oblique divergent plate boundary this type of plate boundary is much less well understood than classic rifts and passive margins in divergent plate settings a complexity in the gulf of california is that the modern oblique rifting was preceded by a stage of orthogonal rifting we have used extensive mapping as well as stratigraphic geomorphic and structural analysis to determine the history of deformation near loreto on the southern baja california peninsula during formation of the gulf of california our data support the suggestion that middle to late miocene protogulf stage 12 to ca 6 ma orthogonal rifting was overprinted by transtensional structures during pliocene to quaternary time though we cannot closely define the time of change we further demonstrate that the plate margin was structurally segmented in the protogulf stage and then complexly overprinted by transtensional structures that suggest one type of process for initiating transform faults the loreto segment is 85 km long along the rift and is bounded on the west by a discontinuous series of aligned down tothe east extensional monoclines and normal faults these structures lie along or as far as 4 km in front east of a steep 1000 1600 m high main gulf escarpment that defines the western topographic margin of the rift zone the loreto segment is further defined by a rise in elevation of the main gulf escarpment of up to 1 km and an 500 800 m increase in structural relief of prerift strata in the escarpment from the segment boundaries to the center of the segment structural analysis of secondary faults of the loreto segment shows that fault populations that are known to be pliocene to quaternary in age are mixed normal and dextral normal faults with a bulk extension direction of west northwest eastsoutheast 2808 1008 in contrast fault populations that cut only prerift oligocene middle miocene volcanic and sedimentary rocks are mainly normal faults with northeast southwest to east northeast west southwest bulk extension directions that average 2458 658 these faults are interpreted to be late miocene in age and formed during protogulf orthogonal rifting thus the pliocene faults record a major change of extension direction of 358 from latest miocene to pliocene time compatible with the onset of oblique rifting in the gulf of california oblique divergent overprinting is mainly expressed as the loreto fault and loreto basin in the northern part of the segment the loreto fault and basin evolved with major fault reorganizations and partial basin inversion many observations suggest that the pliocene loreto fault was linked to two nascent transform faults in the gulf and that carmen island rotated 358 408 clockwise within the complex fault system

aftermath of a snowball earth 1 using a simple 3 box model of the ocean atmosphere system we simulate the cycling of carbon and strontium in the aftermath of a global glaciation model simulations include the delivery of alkalinity to seawater from intense carbonate and silicate weathering under high pco2 conditions as well as ocean mixing air sea gas exchange and biological productivity the 13c of the first carbonate precipitated after the glaciation depends on the pco2 temperature the saturation state of the surface ocean and kinetic effects associated with mineral precipitation with no biological productivity the model produces 13c values between 1 and 3 consistent with observations this is in direct contradiction with arguments by kennedy et al 2001a who suggest that the 13c value of dissolved carbon in a snowball ocean and directly afterward must be 5 kennedy et al assume the carbon isotope cycle is in steady state which does not apply to a global glaciation and also neglect any effect of high pco2 on the carbonate chemistry of seawater a major difference between our findings and the qualitative predictions of hoffman et al 1998 is our interpretation of the cap dolostone as representing an interval dominated by carbonate weathering of exposed continental shelves as a result the 2 drop in the 13c observed in the cap dolostone is unlikely to be the product of rayleigh distillation of atmospheric co2 via silicate weathering instead we interpret the 2 drop in the 13c values as indicative of an increase in sea surface temperature which lowers the fractionation between co2 and carbonate kinetic isotope effects associated with rapid precipitation from a highly supersaturated surface ocean may also be important rayleigh distillation of atmospheric co2 via silicate weathering is a viable explanation for the continued drop in the 13c values in the limestone sequence above the cap dolostone with biological productivity and carbonate weathering driving a slow increase in 13c values once pco2 levels decline our study also simulates the cycling of strontium in seawater in contrast to the finding of jacobsen and kaufman 1999 and kennedy et al 2001a model simulations show a drop in 87sr 86sr of less than 0 001 during 5 million years of global glaciation and an increase of less than 0 001 over the entire episode of silicate weathering our calculations emphasize the importance of considering the changes in seawater chemistry due to high pco2 in evaluating the snowball earth hypothesis

zinc and cadmium stable isotopes in the geological record a case study from the post snowball earth nuccaleena cap dolostone abstract zinc and cadmium are important biologically cycled nutrients in the modern ocean recent analytical advances and sampling efforts such as geotraces have led to measurements of the global distribution of zn and cd and their stable isotope ratios 66zn and 114cd providing an understanding of how biological processes cycle these elements and their isotopes in the modern ocean this opens the door to better application of 66zn and 114cd as tracers of biogeochemical processes archived in the geological record here we present new measurements of cd and 114cd on samples from the nuccaleena cap dolostone in south australia which was deposited during deglaciation of the ca 635 ma old marinoan snowball earth our new data are combined with previously measured 66zn data from the same samples the combined record of 114cd and 66zn is used to explore various hypotheses about the sources and sinks of cd and zn in the post marinoan ocean key features of this record are that zn and cd remain relatively similar throughout that 66zn and 114cd change at the same stratigraphic level and in the same direction and that 66zn changes are about four times larger than 114cd changes even though both quantities reflect a similar fractional mass difference we suggest that both zn and cd concentration and isotopic data are consistent with a change in the sink by which zn and cd are removed from the oceans we propose that no isotope fractionation is expressed during removal of zn and cd as sulfides while zn and cd removed with biological material are about 0 6 and 0 2 lighter than deep ocean 66zn and 114cd respectively many previous studies attribute the burial of isotopically light biological zn to preferential assimilation of isotopically lighter zn by phytoplankton in contrast we propose that lighter biological 66zn occurs mostly because isotopically heavy zn was scavenged by organic matter which causes dissolved 66zn in the surface ocean to be lighter than deep ocean 66zn the organic matter originated from primary producers that thrived in the surface ocean during deglaciation for cd whose isotope cycling in the modern ocean is dominated by preferential assimilation of isotopically lighter cd by phytoplankton much less biological fractionation is expressed the combined analyses of 66zn and 114cd provide insight into the biogeochemical processes which occurred after the marinoan snowball earth glaciation and may be a useful new tool to explore the history of life on earth in other geological records as well

flow characteristics in the interfacial shear layer between a fluid and a granular bed 1 the shear layer that forms at the interface between a fluid in motion and a granular bed is shown to be tractable in the most general case including the occurrence of flow separation from the grains which appears to be the most common situation the phenomenon of separation produces fundamental leading order effects especially in relation to the mean flow between grains and also in the generation of a disturbed ensemble averaged flow which previous formulations were unable to detect in this respect we argue that some known results pertaining to the jet regime recently introduced by the authors can be directly extended outside that regime in particular the mean force that bed grains exert on the fluid which appears to be generally applicable provided only that separation occurs furthermore the maximum pressure disturbances as well as the velocity disturbances at the outer edge of the shear layer can be evaluated just as in the jet regime this extension permits very general estimates of the main forces and the thickness of the shear layer above and beneath the bed surface in particular the forces on the grains are shown to exhibit a spectrum we present very simple expressions for the mean force as well as for the maximum force which are compared with existing observations on sediment motion initiation under oscillatory flow showing an excellent agreement

highest natural bed forms 1 fluid flow interacts with sedimentary beds forming waves of different kinds which are of considerable practical importance since they influence significantly the near bed flow both over and below the bed sediment transport and wave height attenuation we focus here on steep bed forms capable of producing flow separation in this case the large scale vorticity generated in the phenomenon of separation rules the process of friction which appears to be practically unaffected by sediment motion under the crests of the bed forms the mean shear force due to friction is balanced by the force that bed forms exert on the flow via pressure which can be calculated from the work of gimenez curto and corniero 2002 bed forms grow until they have a height such that friction at their troughs is negligible thus ceasing the motion of fluid and sediment this condition leads to a very simple expression for the limiting steepness which compares favorably with existing observations on bed form geometry under steady open channel flow as well as under oscillatory flow

late neoproterozoic cap carbonates mackenzie mountains northwestern canada precipitation and global glacial meltdown the 3 27 m thick cap carbonate overlying marinoan ice brook formation glacigene sediments and keele formation carbonate and terrigenous clastic rocks consists of two distinctive stratigraphic units a lower splintery buff weathering microcrystalline dolostone of extensive lateral uniformity comprises mm laminated peloidal sediment with local low angle hummocky like cross stratification micro ridges and synsedimentary tepees all elongated per pendicular to depositional strike this dolostone is unconformably overlain by an upper limestone that exhibits pro nounced facies variation from inboard peloidal lime grainstone and mudstone to shelf edge cementstone to outboard lime wackestone and mudstone calcite cementstones range from isolated crystal fans in laminated limestone to huge decimetre scale crystal arrays to hemispherical and elongate crystal stromatolites wholly composed of acicular crystals that form decametre scale reeflike structures crystal stromatolites are precipitates and replaced microbiolites that con structed biostromes and bioherms like those on many flat topped reef rimmed platforms the calcite crystals have all the physical and chemical attributes of neomorphosed aragonite this aragonite extensively replaced sediment and microbiolite just below the sea floor and grew upward into the overlying water column such interpreted massive synsedimentary replacement is rare in geological history and attests to the highly saturated state of the immediate postglacial ocean all sediment is interpreted to have been caco3 originally low and constant 18 o values reflect diagenetic modification of these carbonates although chemical attributes such as sr and c isotopes in some lithologies are near pristine lower dolostones virtually identical to most other coeval marinoan caps worldwide were part of a global precipitation event of remarkable similarity upper limestones are a more local phenomenon deposited during sea level rise in an aragonitic sea returning to equilibrium after global glaciation low 87 sr 86 sr ratios and varying 13 c values with carbonate sedimentary facies indicate that both units must have formed relatively rapidly prior to significant flu vioglacial runoff or that the influence of this runoff on the chemistry of seawater along continental shelves was mini mal the cap carbonate is thus interpreted to have formed in two steps 1 during initial marine ice melting accompanied by oceanic overturn and upwelling preceding continental margin rebound and 2 during initial stages of sea level rise accompanying continental deglaciation while confirming brief but extensive carbonate precipitation from an ocean highly perturbed by global glaciation the rocks also suggest that this event did not permanently affect either late neoproterozoic ocean chemistry or the contained marine biosphere 1262

a review of the origin and setting of tepees and their associated fabrics carbonate hardgrounds often occur at the surface of shallow subtidal to supratidal lacustrine and subaerial carbonate shelf sediments these are commonly disrupted and brecciated when the surface area of these crusts increases in the subtidal environment megapolygons form when cementation of the matrix causes the surface area of the hardgrounds to expand similar megapolygons form in the supratidal lacustrine and subaerial settings when repeated incremental fracturing and fracture fill by sediment and or cement also causes the area of the hardgrounds to expand the arched up antiform margins of expansion megapolygons are known as tepees the types of tepees found in the geological record include 1 submarine tepees which form in shallow carbonate saturated waters where fractured and bedded marine grainstones are bound by isopachous marine phreatic acicular and micritic cements the surfaces of these brecciated crusts have undergone diagenesis and are bored unlike tepees listed below they contain no vadose pisolites or gravity cements 2 peritidal and lacustrine tepees are formed of crusts characterized by fenestral pisolitic and laminar algal fabrics this similarity in fabric makes these tepees of different origins difficult to separate peritidal tepees occur where the marine phreatic lens is close to the sediment surface and the climate is tropical they are associated with fractured and bedded tidal flat carbonates their fracture fills contain geopetal asymmetric travertines of marine vadose origin and or marine phreatic travertines and or terra rossa sediments the senile form of these peritidal tepees are cut by labyrinthic dissolution cavities filled by the same material lacustrine tepees form in the margins of shallow salinas where periodic groundwater resurgence is common they include groundwater tepees which form over evaporitic boxwork carbonates and extrusion tepees which also form where periodic groundwater resurgence occurs at the margins of shallow salinas but the dominant sediment type is carbonate mud these latter tepee crusts are coated and crosscut by laminated micrite the laminae extend from the fractures downward into the underlying dolomitic micrite below the crust both peritidal and lacustrine tepees form where crusts experience alternating phreatic and vadose conditions in time intervals of days to years cement morphologies reflect this and the crusts often contain gravitational meniscus vadose cements as well as phreatic isopachous cement rinds 3 caliche tepees which are developed within soil profiles in a continental setting they are formed by laminar crusts which contain pisolites and fractures filled by micritic laminae microspar spar and terra rossa most of the cements are gravitational and or meniscoid in ancient carbonates when their cementation and diagenetic fabric can be interpreted tepee structures can be used as environmental indicators they can also be used to trace the evolution of the depositional and hydrological setting

hydrodynamics and sedimentation in wave dominated coastal environmentsreconstruction of ancient sea conditions with an example from the swiss molasse ancient sea conditions can be estimated from the grain size spacing and steepness of preserved ripple marks the element of greatest uncertainty in such reconstructions is the relationship between near bed orbital diameter of water particles and the ripple spacing this relationship is simple for vortex ripples of high steepness but is problematical for the low steepness forms known as post vortex rolling grain or anorbital ripples the existence field for wave ripples is between the threshold velocity for sediment movement and the onset of sheet flow most low steepness forms occurring close to the bed planation threshold a range of maximum period of formative waves can be obtained using combinations of orbital diameter and orbital velocity assuming linear wave theory to be a reasonable approximation probable wave heights wave lengths and water depths can be investigated using the transformation of wave parameters in shallowing waters and the constraints on wave dimensions provided by the wave breaking condition given reasonable estimates of wave height crude estimates of wave power allow a comparison of ancient wave influenced sequences with modern counterparts wave ripple marks preserved in the upper marine molasse of western switzerland have been investigated results which are in agreement with regional geology suggest deposition in a seaway of approximately 100 km width where moderate period waves t 3 6 s were generated the depositional facies belts were adjusted to the prevailing waves tides and fluvial outflows

estimating palaeo water depth from the physical rock record abstract palaeo water depth and its change with time is a key factor in environmental analysis and in sedimentology in general the literature published on this topic and on related subjects however is substantial albeit scattered within and between different communities geologists oceanographers engineers physicists etc here i focus on proxies for palaeo bathymetry as obtained from the physical rock record floral faunal and chemical evidence for palaeo water depth being equally important must be dealt with elsewhere an assessment of the main depth related parameters in actualistic settings is presented and their applicability to the fossil sedimentary record discussed the outcome reveals the full complexity of this topic there is for example no such thing as an average wave base depth applicable to a wide range of fossil case settings this because wave and current climates in general and particularly so in neritic and coastal settings are intriguingly complex furthermore observations from modern oceans are not a priori applicable to fossil ones acknowledging these problems and limitations critically evaluated quantitative proposals for depth indicative facies and features in the sedimentary record are presented and error bars discussed

chemostratigraphy of neoproterozoic cap carbonates from the volta basin west africa abstract the neoproterozoic era includes some of the most extreme ice ages in earth history the exact number of glaciations is unknown although there were at least two events of global reach and possibly an equal number of lesser advances neoproterozoic glacial deposits in west africa have proven particularly difficult to correlate with better constrained successions elsewhere in most west african successions only a single glaciogenic deposit is present generally within a stratigraphic triad of tillite carbonate and bedded chert the age of these deposits and their synchroneity across the craton remain controversial we report isotopic data from carbonates that cap tillites in the volta basin sud banboli group in the three sections measured 13 c pdb begins at 2 to 3 and drops to 5 to 8 correlated with a drop in both 18 o and mg ca this pattern both the drop in 13 c and its correlation with 18 o and lithology has been observed in neoproterozoic cap carbonates on other cratons suggesting that it reflects primary depositional variations in addition the strong positive correlation among lithology 13 c and 18 o suggests that lithological variation may have exerted a principal control on isotopic variation implying that the dolomite formed in isotopic equilibrium with seawater as a primary precipitate or very early diagenetic replacement this would require low levels of sulfate estimated to be 1 mm or less consistent with available s isotopic data the presence of barite crusts in association with some cap carbonates and the conditions of seawater chemistry hypothesized in the aftermath of a snowball earth the stratigraphic pattern of carbon isotope variation in the volta basin cap carbonates suggests that underlying tillites are likely marinoan 650 600 ma in age this interpretation is supported by distinctive lithological characters observed in volta basin cap carbonates and accepted marinoan correlatives tillites elsewhere on the craton have been assigned latest proterozoic or early cambrian ages either the basis for these proposals requires reexamination or west african tillites record more than one glacial event

soft sediment deformation at the base of the neoproterozoic puga cap carbonate southwestern amazon craton brazil confirmation of rapid icehouse to greenhouse transition in snowball earth stratigraphic and isotopic data identify the lower 45 m of the araras group on the southwest margin of the amazon craton as a neoproterozoic platform cap carbonate deposited below wave base upon varanger glacial diamictites of the puga formation the basal beds consist of moderately deep water pinkish dolomudstone with stratiform to wavy fenestral microbialites locally cut by tube like structures and fenestral nonmicrobial planar laminites with tepee like features above the basal carbonates are deep water bituminous lime mudstones with alternating thin calcite crusts and lime mudstone laminae commonly disrupted by calcite crystal fans pseudomorphs after aragonite the basal contact of the puga cap exhibits soft sediment deformational structures principally load casts that are here attributed to rebound induced seismicity acting upon both recently deposited carbonate sediments and underlying unconsolidated diamictite these features constitute the first clearly recognized sedimentological evidence for the rapid change from icehouse to greenhouse conditions as postulated in the snowball earth model of neoproterozoic glaciation

an organodiagenetic model for marinoan age cap carbonates abstract the nuccaleena formation cap carbonate is the global stratotype for the marinoan glaciation and ediacaran gssp a designation that emphasises the importance of cap carbonates to our current understanding of global neoproterozoic biogeochemistry sedimentology and stratigraphy however to date there is no agreed depositional model for cap carbonates and there remains minimal detailed paragenetic data for developing process based depositional models here an early diagenetic organodiagenetic dolomite cementation model for marinoan cap carbonate formation is hypothesised and explored it is demonstrated how this process based model can explain the three main atypical sedimentary structures that are the basis for correlation of marinoan age cap carbonates giant tepee like structures sheet veins and tubestones these features are interpreted to be products of fluid overpressure deformation induced by organodiagenetic expansive cementation giant tepee like structures the hallmark of marinoan cap carbonates conform to a simple structural analysis that is consistent with the predicted stress field induced by expansive cementation driven fluid overpressure the undeformed to highly deformed gradient of deformation features in cap carbonates is consistent with the range of rheologies in a shallowly buried cementing carbonate modification of matrix textures and bedding surfaces also conforms to the range of expected textures within this model overall it is hypothesised that the aggradational condensed section architecture of cap carbonates was the primary control over the generation of these atypical sedimentary features the available paragenetic analysis suggests that the geochemical data particularly the c isotopic data can be reinterpreted as supportive of the organodiagenetic model and that the neoproterozoic ocean was perhaps similar to that of today the proposed model indicates that the current criteria for the placement of the ediacaran gssp are non unique and potentially non isochronous perhaps the most important aspect of this model is that it is testable and is a call for focused research on the much overlooked paragenesis of cap carbonates