a high resolution paleointensity stack of the past 14 to 68 ka from black sea sediments abstract detailed paleo and mineral magnetic analyses of a sediment composite record from the southeastern black sea yielded a high resolution well dated paleointensity record though hampered by some larger hiatuses in some cores and contaminated by diagenetically formed greigite the paleomagnetic composite record obtained from the preserved primary detrital magnetite phase reflects a highly dynamic geomagnetic field during the last glacial period relative variations of paleointensity inferred from the sediments magnetisations were converted into a record of the virtual axial dipole moment vadm lowest vadm values are linked with the laschamp 0 50 10 22 a m 2 at 41 0 ka the norwegian greenland sea 1 5 10 22 a m 2 at 64 5 ka and the mono lake 3 0 10 22 a m 2 at 34 5 ka geomagnetic excursions the fully reversed field during the laschamp excursion exhibits a vadm of 2 0 10 22 a m 2 which is more than 25 of the present day axial dipole moment 7 628 10 22 a m 2 rates of change calculated from the black sea vadm record also give some information on how to assess the global decay of the present day geomagnetic field which is significantly enhanced in the area of the south atlantic anomaly comparison with provided c 14 and 10 be records confirm partly in the very detail the non linear anti correlation of geomagnetic field intensity and the production of cosmogenic radionuclides in the earth s upper atmosphere however discrepancies in the timing of lows and highs in the compiled records points out that the combination of different data sets from different archives remains a challenge

evidence of surface wave enhancement in the southwest indian ocean from satellite altimetry wave height data from geosat over the period november 1986 to february 1989 were used to survey the occurrence of wave amplification attenuation in the southwest indian ocean more than half of the wave profiles that were inspected revealed some enhancement in the agulhas current with 17 of the profiles showing fractional amplification of more than 40 relative to the background wave height other aspects that were considered included attenuation of wave height in the shelf region and the characterization of the agulhas return current by wave height variations

alternating field characteristics of pseudo single domain 2 14 μm and multidomain magnetite abstract we report normalized af demagnetization curves of anhysteretic remanences arm s produced by 1 10 and 40 oe steady fields and of saturation isothermal remanence irm s in a suite of dispersed unannealed magnetite powders with median sizes of 2 4 6 10 and 14 m pseudo single domain or psd size range and 100 m multidomain or md size interpreted in the light of the domain structure test first proposed by lowrie and fuller 12 the relative stability trend of curves for the 2 m sample is of single domain sd type the 1 oe arm being most resistant to demagnetization followed by the 10 oe and 40 oe arm s and irm s for the 100 m sample the trend is exactly reversed and is of md type in the 4 14 m samples hitherto undescribed transitional trends between sd type and md type occur at 6 m 1 oe 10 oe and 40 oe arm s preserve an sd type trend but for all af s 75 oe irm s is more resistant than any of these remanences at 10 m this trend is unmistakable and only at 14 m do the 1 oe 10 oe and 40 oe arm curves merge we conclude 1 that the lowrie fuller test distinguishes between small md grains enhanced by psd remanence and large md grains lacking psd remanence rather than between sd and md structures per se and 2 that in the psd transition region from 6 to 14 m in magnetite irm s changes over to md type relative stability around 6 m whereas 10 oe and 40 oe arm s achieve an md type trend around 14 m in accord with the predicted field dependence of the psd threshold size our theoretical interpretation assumes that the intrinsic internal field coercive force spectra of weak field and strong field remanences are identical but that the observed external field spectrum is shifted to lower fields as a result of the internal demagnetizing field nj r of the remanence j r the effect is slight for weak field j r s but substantial for irm s since all coercivities high as well as low are shifted the result of the lowrie fuller test is determined simply by the shape of the intrinsic coercivity spectrum or the corresponding af demagnetization curve depending on the model of self demagnetization used either subexponential or sublinear af decay curves of weak field remanence will automatically lead to an md type trend whereas by either model the decay curves that characterize sd and psd remanences decaying slowly initially and then more rapidly will always produce and sd type trend

magnetic petrology of equatorial atlantic sediments electron microscopy results and their implications for environmental magnetic interpretation 1 the magnetic microparticle and nanoparticle inventories of marine sediments from equatorial atlantic sites were investigated by scanning and transmission electron microscopy to classify all present detrital and authigenic magnetic mineral species and to investigate their regional distribution origin transport and preservation this information is used to establish source to sink relations and to constrain environmental magnetic proxy interpretations for this area magnetic extracts were prepared from sediments of three supralysoclinal open ocean gravity cores located at the ceara rise geob 1523 1 3 49 9 n 41 37 3 w the mid atlantic ridge geob 4313 2 4 02 8 n 33 26 3 w and the sierra leone rise geob 2910 1 4 50 7 n 21 03 2 w sediments from two depths corresponding to marine isotope stages 4 and 5 5 were processed this selection represents glacial and interglacial conditions of sedimentation for the western central and eastern equatorial atlantic and avoids interferences from subsurface and anoxic processes crystallographic elemental morphological and granulometric data of more than 2000 magnetic particles were collected by scanning and transmission electron microscopy on basis of these properties nine particle classes could be defined detrital magnetite titanomagnetite fragmental and euhedral titanomagnetite hemoilmentite intergrowths silicates with magnetic inclusions microcrystalline hematite magnetite spherules bacterial magnetite goethite needles and nanoparticle clusters each class can be associated with fluvial eolian subaeric and submarine volcanic biogenic or chemogenic sources large scale sedimentation patterns are delineated as well detrital magnetite is typical of amazon discharge fragmental titanomagnetite is a submarine weathering product of mid ocean ridge basalts and titanomagnetite hemoilmenite intergrowths are common magnetic particles in west african dust this clear regionalization underlines that magnetic petrology is an excellent indicator of source to sink relations hematite encrustations magnetic spherules and nanoparticle clusters were found at all investigated sites while bacterial magnetite and authigenic hematite were only detected at the more oxic western site at the eastern site surface pits and crevices were seen on the crystal faces indicating subtle early diagenetic reductive dissolution it was observed that paleoclimatic signatures of magnetogranulometric parameters such as the ratio of anhysteretic and isothermal remanent magnetizations can be formed either by mixing of multiple sources with separate relatively narrow grain size ranges western site or by variable sorting of a single source with a broad grain size distribution eastern site hematite goethite and possibly ferrihydrite nanoparticles occur in all sediment cores studied and have either high coercive or superparamagnetic properties depending on their partly ultrafine grain sizes these two magnetic fractions are generally discussed as separate fractions but we suggest that they could actually be genetically linked

distribution and dispersal of surface sediments on the continental margins of india abstract the vast area varying climate regimes diverse source terrain lithology of the mainland india generate complex weathering and erosional patterns and leads to diverse sediment distribution and dispersal on the surrounding continental margins of india thus to delineate the sources distribution and sediment dispersal pathways around india 254 sediment cores from the eastern and western continental margins of india were investigated for physical properties using non destructive whole core logging technique combined with grain size analyses the distribution of magnetic susceptibility gamma ray density and grain size traces the sources in the indian landmass which contribute sediments to the margins and demarcates their extent of influence the results from the magnetic susceptibility distribution indicate that the dominant influx of modern high susceptibility sediment into the margins of india originates from the weathering of deccan basalts and its subsequent transportation by narmada and tapti rivers in the west coast and krishna and godavari rivers in the east coast though the himalayan sources are the second largest supplier of magnetic minerals to the shelf their contribution when compared to the deccan sediments is not significant the lack of present day sedimentation in the outer shelf regions of margins of india is evident from the gamma ray density distribution and is confirmed by the discrete sample grain size analysis gamma ray density variations in the margins follow the same pattern as the grain size variations and demarcate the boundary between inner shelf modern clayey sediments and the outer shelf relict carbonate sands regional distribution maps of physical properties and grain size for both the margins of india are presented and geographical limits of each provenance are defined thus providing a comprehensive picture of sediment distribution and dispersal patterns in the area and highlights the use of magnetic susceptibility as a powerful tool in deciphering the source to sink pathways of sediments

diagenetic fate of biogenic soft and hard magnetite in chemically stratified sedimentary environments of mamangua ria brazil d r and l j acknowledge funding from fapesp grants 2012 212123 and 2011 22018 3 respectively f a acknowledges funding from faperj cnpq and capes a p r acknowledges funding from the australian research council grants dp140104544 and dp160100805

sedimentation at manop site h eastern equatorial pacific over the past 400 000 years climatically induced redox variations and their effects on transition metal cycling gravity cores recovered from manganese nodule project site h 6 33 n 92 49 w show marked downcore variations in the abundance of calcium carbonate organic carbon opal manganese and other components deposited over the past 400 000 years variations in the downcore abundance of organic carbon which ranges from 0 2 to 1 0 can be used to hindcast redox conditions in the surface sediments over this time the results indicate that the depth to the manganese redox boundary varied from about 5 to 25 cm below the seafloor during four major cycles downcore variations in solid phase mn ni and cu can be produced by such changes in redox conditions a model which predicts that solid phase mn can be trapped and buried when the mn redox boundary migrates rapidly upward is consistent with the observed organic carbon and mn records and supports the reconstructed redox variations the history of redox variations at site h can be explained by changes with time in surface water productivity major productivity variations at the site occur over 100 kyr cycles with relatively higher productivity occurring during glacial stages thus quaternary climate changes influence surface water productivity redox conditions in sediments and the cycling of transition metals

increased productivity in the eastern equatorial pacific during the last glacial maximum 19 000 to 14 000 yr b p a widespread pronounced enrichment in the organic carbon content occurs at shallow depths in eastern equatorial pacific sediments the c org peak is shown by radiocarbon dating to be temporally coincident with the last stage 2 or wisconsin glacial maximum in contrast caco 3 profiles show less overall variation which appears to be partly a function of the location of the sediments relative to the lysocline consideration of the iodine c org ratio in the sediments rules out enhanced preservation as a cause of the stage 2 organic carbon enrichment the peak instead must have resulted from a significant increase in productivity during the glacial maximum

the upper and lower nunivak sedimentary geomagnetic transitional records from southern sicily van hoof a a m van os b j h and langereis c g 1993 the upper and lower nunivak sedimentary geomagnetic transitional records from southern sicily phys earth planet inter 77 297 313 the detailed paleomagnetic records of the upper and lower nunivak polarity transitions have been determined from pliocene marine marls in southern sicily magnetites are the most important carrier of the remanence in both records the transitions are recorded in two components a low temperature and a high temperature component the two components do not represent the geomagnetic field because the changes in these components take place at lithological boundaries in addition the directional changes do not completely match directional changes of the same transitions recorded in calabria some 250 km away the character of the virtual geomagnetic poles paths is probably caused by smoothing of the stable directions before and after the transitions the directional changes as well as the smoothing mechanism can be explained by the diagenetic magnetite formation model van hoof et al 1992 in which shortly after burial the remanence carried by newly formed secondary magnetites is superposed on the initial remanence carried by primary magnetite

shuttle imaging radar experiment the shuttle imaging radar sir a acquired images of a variety of the earth s geologic areas covering about 10 million square kilometers structural and geomorphic features such as faults folds outcrops and dunes are clearly visible in both tropical and arid regions the combination of sir a and seasat images provides additional information about the surface physical properties topography and roughness ocean features were also observed including large internal waves in the andaman sea

dissolution of titanomagnetite and sulphidization in sediments from lake kinneret israel summary magnetic extracts obtained from sediment cores recovered from lake kinneret israel were subjected to comprehensive scanning electron microscope and in line energy dispersive x ray spectroscopy analyses a variety of ferrimagnetic iron oxides and iron sulphide particles were identified along with apparently non magnetic iron sulphides the majority of the iron oxides are titanomagnetites that have undergone pervasive dissolution and in many cases were only preserved as skeletal 3 d lattices of ilmenite lamellae often the spaces between the submicron ilmenite lamellae are empty also sponge like dissolution features are observed in some residual titanomagnetite grains another group of titanomagnetite grains is characterized by superficial shrinkage cracks which indicate low temperature maghemitization in some cases these cracks appear to be where dissolution started most titanomagnetites contain impurities of al mg si and mn on the order of 1 per cent chromium magnetites with minor ti mg and al content on the order of a few percent but without mn were also found chromium magnetites mostly occur as octahedra in a well preserved state which indicates that they are less prone to dissolution magnetite spherules of 40 60 m in size which were mostly hollow were only found in material collected from the outer zone of the core section that was in contact with the steel core barrel these spherules were not found in material collected from the centre of the core they are therefore interpreted as contaminants that were produced during fabrication of the steel core barrel iron sulphides are present as pyrite either as larger aggregates of cubic crystals each of up to 20 m in size or as 5 10 m framboidal aggregates consisting mostly about 0 3 m idiomorphic octahedra the cubic pyrite crystals have heterogeneous compositions pure pyrite should be non magnetic but even aggregates of up to 150 m in size were magnetically separated they probably therefore contain a magnetic core of greigite or overgrown titanomagnetite the latter possibility is supported by observations of residual titanomagnetites with individual pyrite crystals residing directly on their surfaces or filling space between ilmenite lamellae irregular aggregates of flaky submicron iron sulphides were also found which are interpreted to be greigite the greigite has a low degree of visible crystallization pyrite and or greigite grains were found inside the aggregates or in agglomerates with organic remnants together visual observations and elemental analyses provide clear evidence of pervasive dissolution of primary titanomagnetite and concurrent sulphidization of sediments from lake kinneret

reductive diagenesis magnetite dissolution greigite growth and paleomagnetic smoothing in marine sediments a new view abstract in many anoxic sedimentary environments the onset of sulfate reduction and pyritization of detrital iron bearing minerals leads to a precipitous decline in magnetic mineral concentration during early diagenesis the usefulness of the surviving paleomagnetic record in such environments is usually argued to depend on how much of the primary detrital magnetic assemblage survives diagenetic dissolution detailed rock magnetic and electron microscope analyses of rapidly deposited 7 cm kyr latest pleistocene holocene sediments from the continental margins of oman 22 22 4 n 60 08 0 e and northern california 38 24 8 n 123 58 2 w demonstrate that pyritization during early diagenesis also leads to the progressive down core growth of the ferrimagnetic iron sulfide greigite greigite growth begins with nucleation of large concentrations of superparamagnetic sp nanoparticles at the inferred position of the sulfate methane transition which can explain the apparently paradoxical suggestion that diagenetically reduced sediments contain enhanced concentrations of sp particles looping of hysteresis parameters on a day plot records the dissolution of single domain sd titano magnetite and the formation of sp greigite which then slowly and progressively grows through its sd blocking volume and acquires a stable paleomagnetic signal this looping trend is also evident in data from several published records oregon margin korea strait japan sea niger fan argentine margin and the ontong java plateau indicating that these processes may be widespread in reducing environments our observations have profound implications for paleomagnetic records from sulfate reducing environments the paleomagnetic signal recorded by greigite is offset from the age of the surrounding sediments by 10 s of kyr and ongoing growth of greigite at depth results in smoothing of the recorded signal over intervals of 10 s to 100 s of kyr we therefore expect the presence of greigite to compromise paleomagnetic records in a wide range of settings that have undergone reductive diagenesis

the early diagenesis of iron in pelagic sediments a multidisciplinary approach abstract biogeochemical reactions of iron within pelagic sediments from the eastern and western equatorial atlantic are investigated by means of pore water chemistry chemical leaching experiments and total elemental determinations color reflectance spectroscopy rock magnetic measurements and tem observations of the magnetic fraction results indicate that in the presence of nitrate ascorbate a weak reducing agent leachable iron decreased with depth from the sediment surface within this upper sediment region iron assimilation by bacteria is indicated as magnetosomes were found by tem observations throughout the whole core extractions with a strong reducing agent dithionite representing iron bound to iron oxides correlated linearly with the concentration of highly coercive magnetic minerals and with the reflection intensity of red color within the same iron redox zone the abrupt decrease of red color reflection intensity relative to the amount of iron oxides below the iron redox boundary is the result of a decrease in the specific surface area of iron oxyhydroxide oxides magnetic parameters imply a smaller average grain size of the magnetic fraction below the iron redox boundary arising from an increase in biogenic magnetite formed by magnetotactic assimilatory bacteria dissolution of very fine grained magnetite and the gradual decrease of coarser grained terrigenous titano magnetite with depth the early diagenetically formed magnetic fraction withstands subsequent dissolution and gives pronounced peaks of magnetic parameters within sediments with high carbonate and low terrigenous matter content

investigation of ocean surface wave refraction using terrasar x data as a scientific and technological continuation of the x band synthetic aperture radar x sar and shuttle radar topography mission srtm missions the new x sar namely terrasar x tsx was launched on june 15 2007 since then it has provided numerous high quality data over land and ocean operationally in this paper surface wave refraction and diffraction are investigated using tsx imagery acquired over the coast of terceira island situated in the north atlantic peak wavelength and wave direction are determined by sar 2 d image spectra they are compared to measurements of x band marine radar and results of the wave prediction model wam significant wave height in the near shore shallow water region is estimated from tsx spotlight mode data following the wave refraction laws and using the developed xwave empirical algorithm image spectra of the tsx subscenes in the full coverage region are given to investigate significant changes of wave direction and length by analyzing another tsx image acquired in stripmap mode a shadow zone in the lee side of terceira island is identified it is influenced jointly by wave refraction and diffraction furthermore a cross sea pattern revealed in the image spectra is investigated the cross sea is generated by the diffracted wave rays from the northern and southern coasts of the island less wave directional spreading for the cross sea situation is observed as well when compared to the image spectra at the origin of diffraction

fracture network analysis of the st eustache quarry quebec canada for groundwater resources management a detailed structural survey has been conducted on a fractured sedimentary rock formation in the st eustache quarry quebec canada to supplement a hydrogeological study the two main types of dis

magnetic mineralogy of sandstones from the lunde formation late triassic northern north sea uk origin of the palaeomagnetic signal the minerals responsible for the magnetic properties of the late triassic lunde formation have been examined using a combination of magnetic mineral extraction microscopy and rock magnetic measurements the magnetic mineralogy is controlled by the depositional environment and the effects of diagenesis by a process of differential preservation and modification of the original detrital minerals the magnetic susceptibility and remanence properties of the sediments are strongly influenced by the proportion of silt and clay sized clastic material which contains most of the magnetic minerals paramagnetic minerals both of depositional origin and produced during diagenesis are largely responsible for the magnetic susceptibility a suite of residual ferrimagnetic oxides chromite and mn substituted magnetite is responsible for the remanence properties in grey sandstones because most of the originally deposited magnetic fe ti oxides have been removed by reducing conditions during diagenesis however a small number of reddened horizons preserve a higher proportion of original detrital fe ti oxides ferrimagnetic ilmenite ferrimagnetic chromite and magnetite although authigenic hematite has replaced most of the original mineralogy in the reddened horizons magnetic oxide inclusions in quartz and feldspars are important contributors to the remanence signal particularly in horizons which have a low content of discrete detrital ferrimagnetic grains either through diagenetic dissolution or paucity of the silt and clay fraction within the grey sandstones the triassic palaeomagnetic signal is carried by magnetite as inclusions in detrital silicates with a contribution from detrital ferrimagnetic chromite a model of the effects of diagenesis on the magnetic mineralogy in deeply buried sequences is proposed

geochemical and sedimentological control of the magnetic properties of hemipelagic sediments owing to their high sedimentation rates and wide areal extent hemipelagic sediments along continental borderlands are potentially important high resolution recorders of geomagnetic secular variation to assess this possibility we studied suboxic hemipelagic muds from the oregon continental slope and anoxic laminated diatomaceous oozes from the gulf of california these sediments were rapidly deposited with average sedimentation rates of 121 and 135 cm kyr respectively bulk sediment sedimentological and geochemical analyses indicate that the two areas represent contrasting depositional regimes the remanence in both environments resides in fine grained magnetite particles although minor amounts of hematite were observed in the topmost gulf of california sediments despite first order differences the sediments from both areas show similar downcore patterns of systematic increases in solid sulfur mainly as pyrite dramatic decreases in natural nrm anhysteretic and isothermal remanent magnetization intensities and accompanying shifts in the magnetic stabilities these changes are consistent with reduction and dissolution of the ferrimagnetic iron oxides with depth due to early diagenesis of organic matter the magnetic grain size distribution first appears to rapidly coarsen downcore as the smallest and most abundant grains are removed then slowly grows finer as the remaining particles dissolve no evidence was observed for authigenic formation of magnetite provided sufficient concentration and stability of the detrital magnetic particles paleomagnetic directions can survive this dissolution diagenesis however relative paleointensity determinations based on normalization of nrm by concentration in related parameters will give erroneous estimates of paleofield behavior in such diagenetically altered sediments

numerical simulation and evaluation of groundwater resources in a fractured chalk aquifer a case study in zinder well field niger groundwater is often a unique water source for agriculture industry and domestic use for local inhabitants in semi arid african continent owing to shortage of surface water and rainfall it is of significance to quantify and assess the groundwater resources for local sustainable development in order to correctly evaluate groundwater resources of zinder well field with fractured media in zinder niger a conceptual model of hydrogeology was set up by a geological and hydrogeological survey for simulating the real conditions a large multi well pumping test with designed pumping rate was conducted in addition a two dimensional finite element transient flow model was developed to simulate groundwater flow at the site results show that generally good agreements have been found between the simulated and observed hydrogeology heads for the test the hydraulic parameters were obtained from the pumping test a 11 year prediction of groundwater resources has been made under three exploitation schemes respectively and it indicates that the well field can offer 7 000 m3 day when the aquifer remains confined an optimal scheme of exploitation is provided

mineral magnetic properties of holocene sediments in the subaqueous yangtze delta and the implications for human activity and early diagenesis abstract this study examines the temporal and spatial distribution of magnetic properties in holocene sediment cores taken from the subaqueous yangtze delta china to evaluate depositional environmental changes including the sediment with an anthropogenic provenance and changes in the bottom water chemistry our approach is to compare the magnetic properties in holocene cores with those from a suite of surficial sediment samples taken at various locations from the yangtze delta and the adjacent continental shelf the results indicate that the magnetic properties in sediment cores change generally with sedimentary facies mainly due to their in phase changes with sediment grain size and redox conditions but that they have also been significantly altered by effects of human activity and early diagenesis magnetic parameters that exhibit soil erosion associations show remarkable increases over the past 800 years reflecting an increase in the terrestrial supply of fine grained magnetic minerals induced by the intensification of human activity in the yangtze river catchment early diagenesis was strong in core hzk8 located at the depocenter of the subaqueous yangtze delta including dissolution of fine grained ferrimagnetic minerals and the precipitation of authigenic greigite and pyrite as evidenced by both room temperature and thermo magnetic analyses the dissolution of ferrimagnetic minerals coincides with changes in sedimentation rate at different sites and time periods suggesting that this factor is important for controlling the rate of early diagenesis authigenic iron sulfides suggest the function of sulfate reducing bacteria which implies a hypoxic environment at this site from 6000 cal yr bp

quantitative extraction and analysis of carriers of magnetization in sediments we have applied an integrated procedure for quantitative magnetic mineral extraction based on the separation method of petersen von dobeneck vali 1986 to a range of sediment types to examine the efficiency and representative nature of the extraction process carriers of magnetization have been identified by rock magnetic measurements microscopy and x ray diffraction quantification of the extraction efficiencies is achieved by before and after extraction rock magnetic measurements susceptibility anhysteretic and isothermal remanences these magnetic measurements show that our modified extraction method extracts large proportions of the magnetization carriers in a range of sediment types e g over 75 per cent for magnetite dominated sediments the extraction efficiency is dependent on the sample magnetic mineralogy and whether the magnetic grains occur as discrete grains or as inclusions within host grains susceptibility extraction efficiencies are strongly dependent on whether the susceptibility is of paramagnetic or ferrimagnetic origin the amount of material recovered in the extract shows some inverse correlation with the density of the sediment suspension used during extraction in terms of the mineralogies extracted we identify a diverse and complex range of mineral assemblages all sizes of discrete grains of magnetite are extracted including single domain and superparamagnetic grains and chains of bacterial magnetite other commonly extracted iron and titanium oxides are haematite and ilmenite ferrimagnetic chromites and sulphides were also obtained from some samples considerable amounts of quartz and feldspar are extracted due to the presence of magnetic inclusions within these diamagnetic host grains in the deep sea sediments we examined feldspars constitute a large proportion of the extracts but are significantly less abundant in other sediments where quartz is dominant a wide variety of paramagnetic minerals was identified in the extracts including pyroxenes amphiboles chlorites micas mg cr spinels garnets ti oxides apatites tourmaline and zircon many of which contain ferrimagnetic inclusions possibly less than 0 1 m in grain size dissolution of ultrafine grains of magnetite during pre extraction carbonate dissolution as suggested by sun jackson 1994 does not occur in our samples

air sea interaction and feasibility of tsunami detection in the open ocean 1 recent observations of tsunami shadows i e extended darker strips on the ocean surface along a front of a weak tsunami off oahu hawaii suggest that tsunamis in the deep ocean may be remotely detected through changes in ocean surface roughness in this paper physical mechanisms responsible for the formation of tsunami shadows are considered the hypothesis that the change in surface roughness is due to an air sea interaction is examined using an eddy viscosity model for the average reynolds stresses in turbulent flow a theory is developed to model tsunami induced perturbations in the atmospheric boundary layer it is demonstrated that in the lowest tens of centimeters of the atmosphere tsunami induced perturbations of the mean wind velocity are much greater than current velocities in the water and can be comparable to the unperturbed wind velocity enhancement of tsunami induced wind velocity perturbations compared to currents in the tsunami wave occurs because of a generation of a viscous wave in the air by a coherent elevation of large expanses of the ocean surface in the tsunami wave the ratio of the maximum wind velocity perturbation to the amplitude of the current velocity approximately equals d 4 2 ln2 u 2 cz0 where is the von karman constant u is the friction velocity of a background wind z0 is the roughness length of the ocean surface d is ocean depth and and c are the tsunami wavelength and velocity respectively the results are shown to be robust with respect to a choice of a closure model for reynolds stresses dependence of the tsunami induced atmospheric perturbations on background wind velocity and direction tsunami period and amplitude and ocean depth is studied implications of the theoretical predictions on the feasibility of a satellite based system relying on radars and or microwave radiometers for early tsunami warning are discussed

diagenetic magnetic enhancement of sapropels from the eastern mediterranean sea diagenetic dissolution of magnetic minerals has been widely observed in organic rich sediments from many environments organic rich sediments from the eastern mediterranean sea sapropels recovered during leg 160 of the ocean drilling program reveal a surprising catalogue of magnetic properties sapropels from all sites studied across the eastern mediterranean sea are strongly magnetic and the magnetization is directly proportional to the organic carbon content the magnetization of the sapropels is dominated by a low coercivity probably single domain magnetic mineral with an inverse magnetic fabric that exhibits a clear decay in magnetic properties when exposed to air during heating the magnetic particles irreversibly break down between 360 and 400 c the contrast between the magnetic properties of sapropels and surrounding sediments is marked with remanence intensities of sapropels often being more than three orders of magnitude higher than those of underlying sediments the contrast between the magnetic properties of sapropels and the surrounding sediments is apparently controlled by non steady state diagenesis sulphate reducing conditions dominated during sapropel deposition while overlying sediments were deposited under oxic conditions the mineral responsible for the magnetic properties of sapropels is most likely to have formed under sulphate reducing conditions that existed during times of sapropel formation attempts to identify this mineral have been unsuccessful but several lines of evidence point toward an unknown ferrimagnetic iron sulphide phase the influence of diagenesis on the magnetic properties of cyclically deposited eastern mediterranean sedimentary sequences suggests that magnetic parameters may be a useful proxy for diagenesis in these sediments

a comparison of sir b directional ocean wave spectra with aircraft scanning radar spectra directional ocean wave spectra derived from shuttle imaging radar b sir b l band imagery collected off the coast of southern chile on 11 and 12 october 1984 were compared with independent spectral estimates from two airborne scanning radars in sea states with significant wave heights ranging from 3 to 5 meters the sir b derived spectra at 18 and 25 off nadir yielded reasonable estimates of wavelengths directions and spectral shapes for all wave systems encountered including a purely azimuth traveling system a sir b image intensity variance spectrum containing predominantly range traveling waves closely resembles an independent aircraft estimate of the slope variance spectrum the prediction of a u s navy global spectral ocean wave model on 11 october 1984 exhibited no significant bias in dominant wave number but contained a directional bias of about 30 espect to the mean of the aircraft and spacecraft estimates

observations of wind waves in the gulf stream frontal zone experimental results of a study of wind waves in the gulf stream frontal zone are presented measurements of two dimensional radar spectra of surface waves and surface current were performed during ship crossings of the gulf stream under different wind conditions waves reflected from the gulf stream were observed on the windward side for an along current wind these effects resulted in a widening of the spectrum angular distribution and a deviation of the mean wave direction from that of the wind trapped waves were observed under against current winds depending on wave age the trapped waves were either locally generated developing waves or entered into the jet downstream nearly fully developed waves trapped waves significantly increased the wave energy locally the experimental data are interpreted in terms of wave kinematics and the equation of spectrum evolution in the relaxation approximation

effects of the gulf stream on ocean waves in the present study a third generation numerical wave model is used to study effects of a straight gulf stream and a gulf stream ring on ocean waves in swell and storm conditions the model accounts for all relevant processes of propagation generation and dissipation of the waves including current effects without imposing a priori restraints on the spectral development of the waves the dominating mechanism affecting the waves appears to be current induced refraction even though the short crestedness of the incoming waves tends to mask its effects also in swell conditions depending on wind and wave conditions refraction may trap locally generated waves in the straight gulf stream or it may reflect wave energy back to the open ocean in the gulf stream ring refraction induces a considerable variation in significant wave height and short crestedness but it hardly affects the mean wave direction in storm conditions the processes of generation and dissipation are considerably enhanced in countercurrent situations and reduced following current situations

storm waves focusing and steepening in the agulhas current satellite observations and modeling strong ocean currents can modify the height and shape of ocean waves possibly causing extreme sea states in particular conditions the risk of extreme waves is a known hazard in the shipping routes crossing some of the main current systems modeling surface current interactions in standard wave numerical models is an active area of research that benefits from the increased availability and accuracy of satellite observations we report a typical case of a swell system propagating in the agulhas current using wind and sea state measurements from several satellites jointly with state of the art analytical and numerical modeling of wave current interactions in particular synthetic aperture radar and altimeter measurements are used to show the evolution of the swell train and resulting local extreme waves a ray tracing analysis shows that the significant wave height variability at scales 100 km is well associated with the current vorticity patterns predictions of the wavewatch iii numerical model in a version that accounts for wave current interactions are consistent with observations although their effects are still under predicted in the present configuration from altimeter measurements very large significant wave height gradients are shown to be well captured and also associated with the current vorticity patterns at global scale

sediment chemistry and magnetic properties in an anomalously reducing core from the eastern mediterranean sea abstract in core kc19c 19 6 m long recovered in the abyssal plain between crete and cyprus in the eastern mediterranean a large number of organic rich layers sapropels occur which correlate to maxima in the insolation curve in contrast to other sites in the eastern mediterranean porewaters contain sulfide below a few meters below seafloor mbsf geochemical analyses were performed on the porewaters ammonium alkalinity sulfate manganese iron bisulfide chloride eh ph and sediments organic carbon barium total sulfur total iron manganese pyrite dithionite extractable iron in addition a series of magnetic parameters and ratios nrm arm irm in arm irm s ratio arm 20mt arm in were determined in the top of the sediments fe and mn hydr oxides occur at the oxic suboxic boundary just above the youngest sapropel si2 these hydr oxides appear to be more easily demagnetized by means of alternating fields than deeper hydr oxides which presumably are of detrital origin the transition from suboxic to anoxic sediments is located at 2 mbsf sulfide is produced possibly during sulfate reduction through anoxic methane oxidation at 17 5 mbsf from 17 5 mbsf sulfide migrates upward titrating reactive fe resulting in pyrite formation in the entire sediment column up to 2 mbsf at this depth the upward sulfide flux has been totally consumed by reaction with solid phase fe and dissolved fe ii diffusing downward from the suboxic zone above from 2 mbsf downward magnetic intensities are significantly reduced indicating reductive dissolution of fe oxide minerals and pyrite formation as a consequence no reliable nrm data can be obtained in the lower half of the core

closed form flow model of a damped slug test in a fractured bedrock borehole summary an existing closed form model is modified to describe the damped response of groundwater in a fractured bedrock borehole with variable apertures and dips to a slug test the existing theory which requires single sized horizontal fractures is accurately calibrated by slug test data from three uncased bedrock boreholes in the dedham granite and an observation well screened just below the contact surface with a till drumlin apertures and dips vary however so the ability of the modified theory to accommodate different sizes and inclinations improves upon the physical validity of its predecessor when fracture information accompanies slug test data geophysical logs identify a large number and dip of fractures in the uncased boreholes in the dedham granite in this regard a lognormally distributed horizontal aperture calibration of the slug tests in the uncased boreholes retains the accuracy of the single size model and yields aperture statistics more consistent with literature values the slug test in the screened observation well is accurately calibrated with the modified horizontal theory for discrete two sizes based upon the average fracture spacing found in the uncased boreholes all four results yield comparable compressibility estimates which depend on fracture spacing but not size or dip the calibrated aperture size and calculated fracture porosity and permeability decrease with length of the borehole into the dedham granite the measured dip and aperture for flowing and nonflowing fractures in one of the boreholes accurately calibrates the modified theory the inclusion of dip reduces the calibrated permeability because of the increased ellipsoidal area at the interface of the borehole and the inclined fractures

magnetofossils in the sediment of lake baikal siberia abstract a multidisciplinary approach involving rock magnetics transmission electron microscopy and x ray diffraction was used to identify a biogenic magnetite component in the lake baikal siberia sedimentary magnetic record the distinctive biogenic component to the magnetic record occurs as chains of single domain elongate hexagonal and tear drop cone shaped magnetite particles these magnetofossils are inferred to be magnetosomes produced by magnetotactic bacteria living in the surficial sediment throughout lake baikal postdepositional reduction diagenesis results in the loss of the fine grained magnetofossils at depth in addition this study shows that the fine grained magnetofossils are removed by the process of storage diagenesis during long periods 21 months of core storage which results in a change to a coarser grained slightly higher coercivity bulk magnetic mineral assemblage although the lake baikal sedimentary magnetic record has several distinct and complex components by determining their origin this study has shown that the sediments are well suited for environmental magnetic study

magnetotactic bacteria and their magnetofossils in sediments abstract living magnetotactic bacteria from freshwater environments show under natural and laboratory conditions a great variety of morphological appearances their magnetosomes vary in number shape and size one species of bacteria yields up to 1000 magnetosomes per cell individual particles reach a size of up to 200 nm as a rule they form elongated chains in bacteria which are held under laboratory conditions loop shaped arrangements and nearly unordered clusters are also found during the laboratory experiments different species of bacteria periodically dominated freshwater samples always exhibited a great variety of different magnetosomes on the other hand samples from marine environment clearly showed the preponderance of one type of particle these observations may reflect specific properties of the physico chemical milieu in which the bacteria grew at the end of our experiments north and south seeking bacteria co existed in roughly equal quantities quaternary unconsolidated sediments from the ammersee bavaria and the antarctic quaternary to tertiary deep sea sediments from the atlantic and pacific and jurassic limestones from the sonnwendgebirge tyrol austria were analyzed for fossil magnetosomes we found that fossil magnetosomes were morphologically similar to those from living bacteria but seemed to be corroded in some cases the observed differences in quantity size and shape of magnetosomes from various sediments may be influenced by variations in bacterial viability and particle stability at different sites but are not determined by geographical latitude

fossil bacterial magnetite in deep sea sediments from the south atlantic ocean the magnetostratigraphy of deep sea sediment cores has proven to be a powerful and high resolution method of dating and comparing sedimentary records in contrast to this widespread application relatively few attempts have been made to analyse and identify the mineralogy grain size and origin of the carrier of the remanent magnetization1 2 it is widely assumed that dominant ferrimagnetic minerals in deep sea sediments are of lithogenic origin that is that they derive from oceanic or continental detritus volcanic ashfalls micrometeorites hydrothermal precipitation or chemical mineralization processes a very different view was taken by kirschvink and lowenstam3 who suggested that fossil remnants of magnetite mineralizing organisms in particular magnetotactic bacteria might play an important part in the magnetization of sediments deposited in certain detritus poor aquatic systems we have used rock magnetic diagnostic methods to characterize the magnetic phases in deep sea sediments from the south atlantic these phases were then extracted and studied with the electron microscope our results indicate that fossil bacterial magnetite is the main carrier of the natural remanent magnetization in sediments ranging in age from quarternary to eocene different types of bacterial magnetosomes were detected most of them occurring in chains of identical particles and nearly all of them falling into the theoretically determined4 size range of single domain magnetitite

the upper kaena sedimentary geomagnetic reversal record from southern sicily a detailed paleomagnetic and rock magnetic record of the upper kaena polarity reversal was determined from late pliocene marine marls in southern sicily two separate characteristic magnetization components were distinguished a low temperature lt component between 200 and 50 c and a high temperature ht component between 500 and 580 610 c the two components record the reversal in a slightly different way but both were acquired in an early stage following deposition most probably by authigenic biogenic formation of magnetic minerals the actual r n reversal via e and horizontal inclinations seems to take 3 3 kyr and is followed by a stable normal interval 3 3 kyr and subsequently by a significant excursion 50 60 in declination 3 6 kyr relative intensities were lower during a time span of 5 6 kyr and show a minimum of 10 of the nontransitional values but during the excursion no intensity changes are apparent the vgps of the ht component are confined to a longitude between india and australia those of the lt component oscillate between this same longitude and one passing over north and south america we conclude that most if riot all observed features are largely determined by the remanence acquisition process which is complicated by authigenic formation of magnetic minerals and cyclically fluctuating paleoredox conditions this has not only resulted in considerable smoothing but also in delayed nrm acquisition in specific sedimentary intervals we believe that the observed excursion is a sedimentary artifact and not related to geomagnetic field behavior during transitions we emphasize that many reported geomagnetic features may in fact be due to the sedimentary remanence acquisition process

spatial variations of ocean wave directional spectra from the seasat synthetic aperture radar seasat synthetic aperture radar ocean wave spectra for a 900 km pass are analyzed and interpreted in the context of both their probable generation sources and their surface current and bathymetric modifiers systematic vector wavenumber variations of several times the standard error of determination 1 5 in magnitude and 0 9 in direction occur along the entire 900 km pass the large scale spatial variation of a 200 m swell system can be accurately accounted for as a result of dispersion from a distant storm the more local variations are qualitatively well correlated in position with known currents and bathymetry but show systematic biases that appear partly due to an environmentally dependent instrument transfer function in the regions of high current and highest sea state there is also substantial evidence that a large angular deviation in the center of the pass is the result of a mesoscale eddy just to the east

a multidisciplinary fractured rock characterization study at raymond field site raymond ca abstract a dedicated field site was developed and a suite of experiments were conducted in the sierra nevada foothills near the town of raymond ca to develop and test a multi disciplinary approach to the characterization of groundwater flow and transport in fractured rocks a wealth of geologic hydrologic and geophysical data was collected at the site using a variety of unique tools a cluster of nine approximately 90 m deep boreholes were drilled at the site in a v shaped pattern with an angle of 60 the boreholes are spaced 7 5 15 30 and 60 m from the central borehole various geophysical and hydrologic tests were conducted in and between these boreholes integration of cross hole radar and seismic tomography borehole flow surveys and images from a new digital borehole scanner indicated that groundwater flow is mainly confined to a few sub horizontal fracture zones a unique suite of hydraulic tests were conducted in which three to four intervals in each of the nine boreholes were isolated using pneumatic packers some 130 injection tests were conducted and more than 4100 cross hole transient pressure measurements were obtained a computer algorithm was developed to analyze such massive interference data systematically as a result of the analysis an image of the fracture connections emerged which is consistent with the geophysical data high precision tiltmeters were effective in remotely characterizing the preferential flow path several radial convergent tracer tests were conducted by injecting a mixture of several conservative tracers and one sorbing tracer deuterium fluorescein lithium bromide and polystyrene micro spheres some differences between the breakthrough curves are observed which may be due to possible differences among so called conservative tracers some characterization tools were found to be more effective than others in locating flowing fractures however no single tool was almighty characterization of fractured rock is extremely challenging and requires a stepwise and well thought approach which is basically a good old scientific approach prediction of transport based on the characterization results is even more challenging and one should always bear in mind that it is virtually impossible to uniquely characterize a fractured rock

magnetotactic bacterial abundance in pelagic marine environments is limited by organic carbon flux and availability of dissolved iron article i nfo article history magnetotactic bacteria intracellularly biomineralize magnetite of an ideal grain size for recording palaeomagnetic signals however bacterial magnetite has only been reported in a few pre quaternary records because progressive burial into anoxic diagenetic environments causes its dissolution deep sea carbonate sequences provide optimal environments for preserving bacterial magnetite due to low rates of organic carbon burial and expanded pore water redox zonations such sequences often do not become anoxic for tens to hundreds of metres below the seafloor nevertheless the biogeochemical factors that control magnetotactic bacterial populations in such settings are not well known we document the preservation of bacterial magnetite which dominates the palaeomagnetic signal throughout eocene pelagic carbonates from the southern kerguelen plateau southern ocean we provide evidence that iron fertilization associated with increased aeolian dust flux resulted in surface water eutrophication in the late eocene that controlled bacterial magnetite abundance via export of organic carbon to the seafloor increased flux of aeolian iron bearing phases also delivered iron to the seafloor some of which became bioavailable through iron reduction our results suggest that magnetotactic bacterial populations in pelagic settings depend crucially on particulate iron and organic carbon delivery to the seafloor

relative paleointensity of the geomagnetic field during the brunhes chron abstract we conducted a paleomagnetic study of four sediment cores taken from different regions in the low latitudes of the pacific ocean in order to recover relative paleointensity variations during the brunhes chron three cores have good age control from oxygen isotope stratigraphy we extensively examined rock magnetic uniformity by the iso thermal remanent magnetization irm acquisition and the alternating field demagnetization of the anhysteretic remanent magnetization arm and the irm only rock magnetically homogeneous sediments were used biogenic magnetites were found in all but one core and their dissolution in early diagenesis was not significant the four cores showed coherent variations of the remanent intensity normalized by the arm implying that these variations represent the behavior of the geomagnetic field long term paleointensity variations during the brunhes chron are characterized by an asymmetric pattern rapid increases in the intensity occurred just after the brunhes matuyama transition in the mid brunhes from about 500 to 400 ka and during the last 100 ka and gradual decreases between them the first one supports the idea of rapid regeneration of the geomagnetic field after polarity reversals 1 the other two may have been triggered by very short polarity reversals

early diagenesis in an organic rich turbidite and pelagic clay sequence from the cape verde abyssal plain ne atlantic magnetic and geochemical signals abstract processes of early diagenesis in sediments from the cape verde abyssal plain are investigated using the complimentary techniques of environmental magnetism and solid phase geochemistry the sequence captured by a 2 m long box core comprises an organic rich turbidite derived from the nw african continental margin emplaced ca 330 ka bp overlain by brown pelagic clay diagenesis in the pelagic clay mainly involves slow in situ oxidation of the iron oxide phases present which mossbauer effect data suggest are detrital haematite and magnetite possibly maghaemitised in the turbidite diagenesis has proceeded in two stages the first involving suboxic reductive processes following depletion of porewater o2 and the second involving oxidative processes associated with the slow descent of an oxidation front through the bed due to diffusion of o2 from the overlying seawater carbonate free magnetic parameters interparametric quotients and remanence acquisition demagnetisation and coercivity measurements of the core reveal that significant depletion of detrital ferrimagnetic iron fe2 fe3 oxide grains like titano magnetite has occurred within the turbidite during suboxic diagenesis and confirm previous suggestions that reductive dissolution of such components is a grain size selective process however the higher oxidation state fe3 canted antiferromagnetic iron oxide grains like haematite and goethite are much less susceptible to reductive diagenesis remobilisation of transition metal ions from below the oxidation front in the turbidite has led to authigenic precipitation of ferrimagnetic fe mn micronodules in a distinct layer immediately overlying the front and above this a further interval of mn enriched diagenetic laminae however within the suboxic organic rich zone of the turbidite well below the oxidation front there is clear evidence for the presence of a significant concentration of fine single domain ferrimagnetic iron oxide grains which are most probably associated with a population of live magnetotactic bacteria between this zone and the oxidation front there is a transitional interval in which the number of live magnetotactic bacteria declines rapidly and fossil magnetosomes in the sediment are being reductively dissolved progressively up sequence these results are broadly similar though differing in some respects to magnetic and geochemical studies of hemipelagic and high productivity pelagic sediments in which mn and fe redox boundaries have been recognised and further illustrate the value of environmental magnetic parameters for characterising early diagenetic processes in sediments of this kind

magnetite diagenesis in marine sediments from the oregon continental margin the magnetochemistry of sediments from the oregon continental margin is examined to determine the effects of iron sulfur diagenesis on the paleomagnetic record magnetic mineral dissolution and transformation into iron sulfides are a common feature in these suboxic to anoxic lutites these processes are evidenced in rapid decreases in natural remanent magnetization intensities and stabilities systematic changes in other rock magnetic properties and increases in solid phase sulfur concentrations with depth hysteresis measurements are used to evaluate downcore changes in magnetite concentration and grain size magnetite abundances decrease downcore from initial values of about 0 1 and nominal grain diameters lie within a narrow pseudosingle domain range of 0 08 to 0 6 m a first order surface area reaction model da dt ka is proposed to explain the magnetite dissolution mechanism where a is the total magnetite surface area and k is the rate constant the solution of this equation predicts that the surface area and concentration decrease exponentially and the concentration in addition depends on grain size application of this model in two cores where grain size varies with depth successfully explains the downcore profiles of both concentration and surface area despite extensive magnetite destruction magnetic directions in such sediments appear to reliably record long wavelength trends of the geomagnetic field

a synchronous alpine and corsica sardinia rotation 1 we report on the paleomagnetism of 34 sites from lower oligocene middle miocene sediments exposed in the tertiary piedmont basin tpb northern italy the tpb is formed by a thick 4000 m and virtually undeformed sedimentary succession unconformably lying upon alpine nappes decapitated by extensional exhumation which in turn are tectonically stacked over the adriatic foreland paleomagnetic directions from 23 mostly oligocene sites were chronologically framed using new biostratigraphic evidence from calcareous nannoplankton our data along with published paleomagnetic results show that the tpb rotated 50 counterclockwise with respect to africa in aquitanian serravallian times the rotation was likely driven by underneath nappe stacking and was synchronous with further bending of the alpine chain both the rotation magnitude and its timing are similar to those documented for the corsica sardinia microplate therefore the formation of the western alpine arc or at least part of its present day curvature occurred during the rollback of the apenninic slab and related back arc spreading of the liguro provencal basin and drift of the corsica sardinia block this suggests a common dynamics driving both the alpine and the apennine slab motions paleomagnetic data also document that the adriatic plate has undergone no paleomagnetic rotation since mid late miocene times anisotropy of magnetic susceptibility data suggests that the tpb an enigmatic basin arising from a controversial tectonic setting formed in an extensional regime characterized by a stretching direction approximately orthogonal to the main trend of the underlying chain

effects of diagenesis on magnetic mineralogy in a jurassic claystone limestone succession from the paris basin we performed detailed rock magnetic and geochemical analyses on a previously published early jurassic magnetostratigraphic section the results improve our understanding of acquisition and preservation processes of magnetization in a series of alternating claystones and limestones the main carrier of magnetization is magnetite anhysteretic remanent magnetization arm varies by a factor of 40 and the arm variations are linked to magnetite grain size comparison of magnetic and geochemical data shows that when carbonate content is high 30 and 13 c0 magnetite is characterized by small grain sizes whereas when carbonate content is low 20 magnetite is coarse grained it appears that the oxidation of organic matter by sulfate reduction controls both 13 c and magnetite grain size h 2 s produced during sulfate reduction causes partial dissolution of magnetite grains with the finest magnetite grains those that best record the magnetic signal being dissolved first despite this partial dissolution both the direction and polarity of the original remanent magnetization are preserved

environmental magnetism principles and applications 1 in environmental magnetism rock and mineral magnetic techniques are used to investigate the formation transportation deposition and postdepositional alterations of magnetic minerals under the influences of a wide range of environmental processes all materials respond in some way to an applied magnetic field and iron bearing minerals are sensitive to a range of environmental processes which makes magnetic measurements extremely useful for detecting signals associated with environmental processes environmental magnetism has grown considerably since the mid 1970s and now contributes to research in the geosciences and in branches of physics chemistry and biology and environmental science including research on climate change pollution iron biomineralization and depositional and diagenetic processes in sediments to name a few applications magnetic parameters are used to routinely scan sediments but interpretation is often difficult and requires understanding of the underlying physics and chemistry thorough examination of magnetic properties and of the environmental processes that give rise to the measured magnetic signal is needed to avoid ambiguities complexities and limitations to interpretations in this review we evaluate environmental magnetic parameters based on theory and empirical results we describe how ambiguities can be resolved by use of combined techniques and demonstrate the power of environmental magnetism in enabling quantitative environmental interpretations we also review recent developments that demonstrate the mutual benefit of environmental magnetism from close collaborations with biology chemistry and physics finally we discuss directions in which environmental magnetism is likely to develop in the future

ocean wave directional spectra and wave current interaction in the agulhas from the shuttle imaging radar b synthetic aperture radar sir b synthetic aperture radar ocean wave spectra for a 200 km pass crossing the agulhas current off the coast of africa are analyzed a significant enhancement of one spectral peak along the northern edge of the current is attributed both to amplification of the waves by refraction dominated wave current interaction and to transient specular backscatter contributions spatially correlated to the waves

magnetic anisotropy as a correction for compaction caused palaeomagnetic inclination shallowing summary a theoretical model presented by jackson et al 1991 suggests that the anisotropy of anhysteretic remanence aar can be used to recognize and correct for compaction caused inclination shallowing in sediments and sedimentary rocks however we have conducted experiments in which inclination shallowing is more strongly dependent on magnetic anisotropy during compaction of synthetic clay rich sediments containing 0 45 m acicular magnetite than predicted by the jackson et al model this discrepancy can be explained if randomization or disturbance of subvertical magnetite particles is the cause of inclination shallowing early in the compaction process the principal experimental evidence for this effect is a decrease in magnetization intensity coincident with inclination shallowing an intensity decrease during inclination shallowing is also observed in some dsdp cores suggesting that this randomization process may also occur in nature after randomization magnetite particles become firmly attached to clay particles and both magnetic anisotropy and inclination shallowing show a regular increase during compaction consistent with the jackson et al model we suggest that models like that of jackson et al can be used to correct for inclination shallowing if they are used in conjunction with an experimentally derived relationship between inclination shallowing and magnetic anisotropy for a particular sediment

from field data to fracture network modeling an example incorporating spatial structure this paper describes a technique for processing field data for a fracture network model which accounts for the observed spatial variability this has been done by generating a network subregion by subregion where the properties of each subregion are predicted through geostatistics once the geometry of a particular realization is specified flow through the network is studied we develop the method for a two dimensional analysis based on data from fanay augeres a uranium mine in france we plan to extend the analysis to three dimensions and compare the results with in situ test results in particular we have focused on the data collected in a long section of a drift where fractures have been mapped and steady state permeability tests have been performed in 10 boreholes in order to generate fractures in a statistically heterogeneous region we first divided the region into statistically homogeneous subregions in each subregion and for each fracture set we must specify the areal fracture density and the orientation length and aperture distributions we divided the fractures into five sets based on tectonic history and observed that for each set fractures spaced close together tended to have similar orientations this was built into the simulation an estimate of the aperture distribution for each set was made by assuming that the hydraulic apertures of the fractures intersecting a well test zone were proportional to the fracture opening observed in the core data input to the geostatistical analysis for each set consisted of 16 values of mean length and density of fractures in each 5 m by 2 m section of the drift wall the results of the simulation are tables of values for mean length and fracture density for each of the five sets the value of density simulated for each subregion was used directly to determine the number of fractures to be generated of that set in the subregion the value of mean length was used as the mean of the length distribution in the subregion the local coefficient of variation for length was the same in every subregion using the data described above we generated a 100 m by 100 m fracture network in a series of 100 statistically homogeneous subregions the fractured region generated has a total of 65 740 fractures a 70 m by 70 m region was isolated for directional permeability testing results show that the system is barely connected about 0 1 of the fractures essentially control permeability in the language of percolation theory this mesh is close to the critical density for which infinite clusters of fractures are found problems remaining include that 1 the analysis should be extended to three dimensions 2 the geostatistical simulation and network simulation should be combined rather than used as two separate operations and 3 the nature of flow through single fractures at fanay augeres should be investigated

mineral magnetic and textural interpretations of sedimentation in the skagerrak eastern north sea abstract the mineral magnetic properties of surface sediments in the northern skagerrak show systematic trends which allow the identification of sediment provinces and the interpretation of transport pathways this application is especially valuable considering the importance and difficulty of environmental analyses involving fine grained deposits magnetic susceptibility and saturation isothermal remanent magnetisation sirm have different geographic patterns but their individual trends are consistent in the skagerrak muds clay content 25 60 over the entire studied area the values correlate positively with general trends in particle size whereas sirm does not show particle size dependency the present study confirms that the majority of sediments accumulating in the northern skagerrak are supplied from the south the mineral magnetic parameters facilitate detailed tracking of the counterclockwise transport of sediments around and into the norwegian trench

discharge of hydrothermal fluids through sediment at the escanaba trough gorda ridge odp leg 169 assessing the effects on the rock magnetic signal an integrated rock magnetic and multivariate statistical analysis of a suite of sediment samples recovered from odp sites 1037 and 1038 leg 169 escanaba trough gorda ridge spreading center ne pacific ocean has been carried out to assess the use of the sediment magnetic signal as a tracer of post depositional alteration related to the discharge of hydrothermal fluids through these sediments the uppermost above 40 mbsf section of three separate holes holes 1037 b 1038 i and 1038 g was sampled previous sedimentological and geochemical studies indicated that these holes represent a transect from unaltered to strongly hydrothermally influenced sediments analysis of nrm arm anisotropy of magnetic susceptibility ams hysteresis parameters and low temperature magnetic properties suggest increasing alteration of the magnetic minerals with increasing circulation of hydrothermal circulation of fluids fuzzy c means clustering combined with non linear mapping yields a more elaborate picture because similar alteration groupings at different holes can be compared at hole 1037 b a sedimentary reference site drilled away from the area of high heat flow the rock magnetic signal is a sensitive record of changes in detrital inputs magnetite and some monoclinic pyrrhotite are detected the detrital magnetic signal is still apparent at intermediate hole 1038 i but cluster analysis detects an increasing hydrothermal influence on the magnetomineralogy in the lower part of the hole strong hydrothermal alteration at hole 1038 g results in a complete loss of the detrital diagenetic magnetic signal which is replaced by a much weaker hydrothermal signal composed of monoclinic pyrrhotite and pyrite the alteration of the magnetic signal is not restricted to the uppermost few meters of the sediment column and the magnetic properties of the sediment can be used to trace even minor alterations of marine sediments related to the lateral and vertical advection of hydrothermal fluids which may easily be overlooked by more traditional methods fl 2000 elsevier science b v all rights reserved

paleomagnetic evidence for fossil biogenic magnetite in western crete abstract previous paleomagnetic research has shown that the concentration of fine grained magnetite preserved in miocene marine clays of western crete drops during two successive geomagnetic transitions although the mechanism responsible for this effect was not known magnetite precipitation by magnetotactic bacteria offers a straightforward explanation for this decrease reduced field strengths during a reversal will strain the competitive advantage of having intracellular magnetite and will force bacteria to precipitate correspondingly more magnetite if they are to maintain the same alignment in the geomagnetic field their ability to do this is limited by several magnetophysical constraints which should act to reduce the numbers of magnetite precipitating cells particularly in fields of less than about 12 of the present level this would lead to a decrease in the supply of bacterial magnitude to the sediments recovery of intact magnetotactic bacterial fossils may lead to a new method for estimating paleointensities from sedimentary rocks

wave current interaction near the gulf stream during the surface wave dynamics experiment this paper presents a case study on the wave current interaction near the local curvature of a gulf stream meander the wave data were obtained from in situ measurements by a pitch roll discus buoy during the surface wave dynamics experiment swade conducted off wallops island virginia from october 1990 to march 1991 owing to the advection of the gulf stream by the semidiurnal tide the discus buoy was alternately located outside and inside the gulf stream the directional wave measurements from the buoy show the changes in wave direction wave energy and directional spreading when waves encountered the current in the gulf stream meanders a wave refraction model using the ray tracing method with an estimated gulf stream velocity field and meandering condition was used to simulate wave refraction patterns and to estimate wave parameters at relative locations corresponding to buoy measurements the numerical simulation shows that a focusing zone of wave rays was formed near the boundary and behind the crest of a simulated gulf stream meander the focusing of wave rays causes changes in wave direction increases in wave energy and decreases in wave directional spreading which are in good agreement with the results from the buoy measurements

magnetotactic bacteria and single domain magnetite in hemipelagic sediments remanent magnetism in marine sediments has been used extensively over the past twenty years to calibrate the geological time scale study geomagnetic reversals and secular variation and measure the rates of seafloor spreading although these sediments may contain different magnetic minerals magnetite is the most commonly observed and magnetically stable phase and its size shape and post depositional fate affect the magnetic remanence of the sediments biogenic magnetites are single domain with a high natural magnetic remanence nrm and have been suggested as a significant source of magnetic remanence in marine sediments we have studied surface sediments from the santa barbara basin and report the occurrence of living magnetotactic bacteria and the deposition of biogenic ultra fine grained single domain magnetite using a novel extraction technique transmission electron microscopy and squid magnetometry we show that these bacteria and the magnetite they produce are the major source of stable remanent magnetism in these sediments

regional hydrogeology of the silurian and ordovician sedimentary rock underlying niagara falls ontario canada abstract due to concern over the potential for widespread groundwater contamination in the sedimentary rock underlying the niagara falls area this study was done to investigate the hydrogeology of the silurian and ordovician stratigraphy underlying the upper niagara river and the eastern niagara peninsula seven boreholes up to 150 m deep were drilled instrumented with multiple packer casing tested for permeability sampled for inorganic and organic solutes and monitored for hydraulic head to provide data for a conceptual model of regional groundwater flow results show that there are at least three distinct groundwater flow regimes in the bedrock the uppermost regime consists of fracture zones in the guelph and lockport formations within which hydraulic conductivity hydraulic head measurements and geochemical analyses indicate active groundwater circulation primarily discharging towards the niagara gorge and escarpment underlying the lockport formation are an overpressured high hydraulic head regime in the clinton upper cataract lower queenston formation and an underpressured low hydraulic head regime in the lower cataract upper queenston formation in both regimes geochemical analyses and permeability measurements indicate very old and saline groundwater which probably has undergone minimal migration since pre pleistocene time the implication based on the study so far is that potential groundwater contamination below the bottom of the lockport formation is probably not significant in the niagara falls area except adjacent to the niagara gorge where vertical permeability in the lower flow regimes may be enhanced

authigenic magnetite formation in suboxic marine sediments the resolution and reliability of magnetostratigraphy and reconstructed time series of geomagnetic field behaviour depend critically on where remanence is acquired and fixed in the sediment column and whether the magnetization is altered chemically after deposition if authigenic magnetic minerals are formed at depth or if the magnetic carriers are changed after deposition then the nature and timing of magnetic events can be affected by depth offsets in remanence acquisition and mixing of detrital and authigenic signals using palaeo and rock magnetic and sediment geochemical analyses we have studied how early diagenesis affects the magnetic properties of suboxic hemipelagic sediments here we report evidence of the formation of fine grained authigenic magnetites near the commonly observed brown tan green colour boundary which marks the transition from fe oxidizing to fe reducing conditions we propose that biogenic magnetite produced by magnetotactic bacteria forms as part of the microbially mediated sequence of reactions involved in the oxidation of organic matter the magnetite is created as a metabolic by product of the microorganisms use of iron redox transitions as a source of energy active magnetite formation appears to be restricted to a zone between the levels of nitrate and iron reduction

comparison of shuttle imaging radar b ocean wave image spectra with linear model predictions based on aircraft measurements during october 1984 coincident shuttle imaging radar b synthetic aperture radar sar imagery and wave measurements from airborne instrumentation were acquired the two dimensional wave spectrum was measured by both a radar ocean wave spectrometer and a surface contour radar aboard the aircraft in this paper we compare two dimensional sar image intensity variance spectra with these independent measures of ocean wave spectra to verify previously proposed models of the relationship between such sar image spectra and ocean wave spectra the results illustrate both the functional relationship between sar image spectra and ocean wave spectra and the limitations imposed on the imaging of short wavelength azimuth traveling waves

wave current interaction study in the gulf of alaska for detection of eddies by synthetic aperture radar high resolution ers i synthetic aperture radar sar images are used to detect a mesoscale eddy such features limit dispersal of pollock larvae and therefore likely influence recruitment of fish in the gulf of alaska during high sea states and high winds the direct surface signature of the eddy was not clearly visible but the wave refraction in the eddy area was observed the rays of the wave field are traced out directly from the sar image the ray pattern gives information on the refraction pattern and on the relative variation of the wave energy along a ray through wave current interaction these observations are simulated by a ray tracing model which incorporates a surface current field associated with the eddy the numerical results of the model show that the waves are refracted and diverge in the eddy field with energy density decreasing the model data comparison for each ray shows the model predictions are in good agreement with the sar data

on the estimation of wave slope and height varnance spectra from sar imagery a procedure is described for using synthetic aperture radar sar imagery to estimate two dimensional ocean wave slope and height variance spectra the logic underpinning the procedure is based both on the results of the numerical simulation of sar wave imagery and analytic descriptions of the sar imaging process the procedure when applied to sar imagery of waves acquired during the recent shuttle imaging radar mission sir b is shown to produce spectra that agree with independent measures of both the two dimensional slope and height variance spectra the implications of these results for future sar missions aimed at measuring ocean waves are considered

environmental magnetism past present and future environmental magnetism involves the application of rock and mineral magnetic techniques to situations in which the transport deposition or transformation of magnetic grains is influenced by environmental processes in the atmosphere hydrosphere and lithosphere the first explicit description of environmental magnetism as a distinct field was in 1980 since that time environmental magnetism has become a broad field that is finding application in an ever increasing array of scientific disciplines in this review of the present state of environmental magnetic studies we divide the field into three broad but arbitrary categories the first involves the use of mineral magnetic assemblages in the geological record to study physical processes in depositional environments this category includes the correlation of sediment cores using magnetic susceptibility measurements studies of geomagnetic field behavior the analysis of depositional and postdepositional mechanical processes that affect sediments and the examination of magnetic parameters that might represent proxies for paleoclimatic variation the second category encompasses studies of the processes responsible for variations in the magnetic minerals brought into a sedimentary environment these provenance investigations include studies of changes in catchment derived sediment in lakes fluctuations in contributions from terrigenous aeolian and glaciogenic components in deep sea sediments and the origin of atmospheric particulates the final category addresses in situ changes and transformations of magnetic minerals in sedimentary environments including pedogenesis authigenetic diagenetic formation of ferrimagnetic phases dissolution of magnetic minerals due to reductive diagenesis and contributions of biomagnetism to sedimentary magnetism because environmental magnetism can address problems in so many disciplines and because many of these problems may be inaccessible to other techniques it is likely that the scope of environmental magnetism will continue to expand rapidly environmental magnetism is capable of providing important data for studies of global environmental change climatic processes and the impact of humans on the environment all of which are major research initiatives in the international scientific community these factors suggest that environmental magnetism has a bright and diverse future

elongated prismatic magnetite crystals in alh84001 carbonate globules potential martian magnetofossils using transmission electron microscopy tem we have analyzed magnetite fe 3o 4 crystals acid extracted from carbonate globules in martian meteorite alh84001 we studied 594 magnetites from alh84001 and grouped them into three populations on the basis of morphology 389 were irregularly shaped 164 were elongated prisms and 41 were whisker like as a possible terrestrial analog for the alh84001 elongated prisms we compared these magnetites with those produced by the terrestrial magnetotactic bacteria strain mv 1 by tem again we examined 206 magnetites recovered from strain mv 1 cells natural darwinian selection in terrestrial magnetotactic bacteria appears to have resulted in the formation of intracellular magnetite crystals having the physical and chemical properties that optimize their magnetic moment in this study we describe six properties of magnetite produced by biologically controlled mechanisms e g magnetotactic bacteria properties that collectively are not observed in any known population of inorganic magnetites these criteria can be used to distinguish one of the modes of origin for magnetites from samples with complex or unknown histories of the alh84001 magnetites that we have examined the elongated prismatic magnetite particles 27 of the total are indistinguishable from the mv 1 magnetites in five of these six characteristics observed for biogenically controlled mineralization of magnetite crystals

rock magnetism of late neogene and pleistocene deep sea sediments relationship to sediment source diagenetic processes and sediment lithology we use bivariate scatter plots to illustrate variations in selected rock magnetic properties low field susceptibility anhysteretic and isothermal remanence of late neogene and pleistocene deep sea sediments from 16 sites in the arctic ocean north atlantic equatorial atlantic and north pacific ocean and the arabian sea our intention is to examine the ability of the rock magnetic properties to differentiate the sediments according to factors such as lithology geographical area and the dominant mode of terrigenous sedimentation which at these sites is via ice rafting via bottom currents or via eolian processes overall correlations between sediment magnetic properties and gross lithology is poor and factors such as the source and transport path of terrigenous sediment and detrital magnetic minerals together with the action of reductive diagenetic processes are the major controls on the magnetic properties on the bivariate scatter plots sites with major ice rafted contributions tend to have high sedimentary ferrimagnetic mineral concentrations relatively coarse ferrimagnetic grain sizes and scattered sample point distributions in contrast sites where we infer significant bottom current supply of terrigenous material have tightly grouped sample point distributions carbonate sediments in which the terrigenous component is supplied by eolian processes tend to have a broad range of magnetic mineral concentration caused by glacial interglacial fluctuations in carbonate accumulation and eolian activity sediments containing significant volcanogenic material have high concentrations of relatively coarse grained ferrimagnetic material reductive diagenesis is a significant determinant of sediment magnetic properties in high productivity areas and has the effect of preferentially removing the fine grained ferrimagnetic fraction causing a coarsening of the ferrimagnetic grain size distribution and a rise in the antiferromagnetic ferrimagnetic ratio

wasp waisted hysteresis loops mineral magnetic characteristics and discrimination of components in mixed magnetic systems rock magnetic studies of complex systems that contain mixtures of magnetic minerals or mixed grain size distributions have demonstrated the need for a better method of distinguishing between different magnetic components in geological materials hysteresis loops that are constricted in the middle section but are wider above and below the middle section are commonly observed in mixed magnetic assemblages such wasp waisted hysteresis loops have been widely documented particularly with respect to rare earth permanent magnets basaltic lava flows remagnetized paleozoic carbonate rocks and an increasingly wide range of other rocks our modelling combined with a review of previous work indicates that there are several conditions that give rise to as well as magnetic properties that are characteristic of wasp waisted hysteresis loops first at least two magnetic components with strongly contrasting coercivities must coexist this condition can arise from either mixtures of grain sizes of a single magnetic mineral or a combination of magnetic minerals with contrasting cocrcivities or a combination of these two situations second materials that give rise to wasp waisted hysteresis loops will have relatively high ratios of the coercivity of remanence to coercive force b cr b c because b0 is controlled by the soft low coercivity component whereas bcris controlled by the hard high coercivity component third values of b cr b c 10 usually only occur for strongly wasp waisted loops when the low coercivity component comprises an overwhelmingly large fraction of the total volume of magnetic grains fourth a given mixture of superparamagnetic and single domain sd grains is more likely to give rise to wasp waisted hysteresis loops than an equivalent mixture of sd and multidomain grains fifth our results provide empirical confirmation that the total magnetization of a material is the sum of the weighted contributions of each component in the absence of significant magnetic interaction between particles thus to contribute significantly to wasp waisted behavior a mineral magnetic component must give rise to a significant portion of the total magnetization of the rock as a result minerals with weak magnetic moments such as hematite need to occur in large concentrations to cause wasp waistedness in materials that also contain ferrimagnetic minerals we outline a method for determining the magnetic components that can give rise to wasp waisted hysteresis loops this method is based on high and low temperature magnetic measurements that are used to identify the dominant remanence bearing mineral s and on mineral magnetic techniques that are used to discriminate between different magnetic domain states the method is illustrated with several examples from archaeological geological and synthetic materials

magnetostratigraphic dating of shallow water carbonates from san salvador bahamas magnetostratigraphic results are reported here from a sequence of late neogene quaternary shallow water carbonate sediments from a continuous core drilled on the island of san salvador bahamas on the basis of the remanent magnetism of 136 samples from a 91 m measured section of core the polarity sequence can be correlated with the magnetic polarity time scale from the gilbert chron early pliocene through the late brunhes chron late pleistocene holocene magnetic polarities were determined on the basis of relative up down direction in the unoriented core extraction studies of the magnetic particles reveal the presence of single domain crystals of magnetite resembling those produced by the magnetotactic bacteria and algae the sequence of reversals provides a minimum of six new major chronostratigraphic markers for the pliocene pleistocene of the bahamas it confirms and refines the local timing of both the lithologic change from skeletal to nonskeletal sediments and the disappearance of coral and molluscan species from the bahamas as upper late pliocene between 2 6 and 2 7 ma that the primary magnetic remanence is preserved in shallow water carbonates including replacement dolomites suggests that this technique could be used to date similar tertiary and possibly even older carbonate sequences the establishment of a reliable magnetostratigraphy provides refined dating of shallow water carbonates and regional faunal appearances or disappearances sediment accumulation rates subsidence and depositional events

evidence for bacterial palaeoecological origin of mineral magnetic cycles in oxic and sub oxic tasman sea sediments abstract sediments from the tasman basin in the southwest pacific ocean show a cyclic pattern of variation in mineral magnetic properties including susceptibility and remanence over the brunhes chron the magnetic pattern is dominated by fluctuations in the concentration of a single domain ferrimagnetic component identified as bacterial magnetofossils by tem investigation of the magnetic fraction the intervals of low bacterial magnetite concentration occurring in glacial periods are accompanied by a change of the bacterial magnetosome morphology assemblage interpreted as recording a change in bacterial species assemblage there is no evidence of iron or sulphate reducing conditions during low bacterial magnetite intervals concentrations of bacterial magnetite are low when oxygen concentrations in surface sediment pore waters dropped either as the result of variation in bottom water oxygen concentration or sedimentation rate the variations in the magnetic signal are therefore interpreted as resulting primarily from bacterial palaeoecological control rather than dissolution or alteration the bacteria in this deep sea environment are apparently aerophilic and grow near the sediment surface within the oxic zone implying that magnetic remanence is also acquired near the surface but up to tens of centimetres below where the oxic zone is very thick

sun glitter imagery of surface waves part 2 waves transformation on ocean currents under favorable imaging conditions the sentinel 2 multi spectral instrument msi can provide spectacular and novel quantitative ocean surface wave directional measurements in satellite sun glitter imagery ssgi owing to a relatively large swath with high spatial resolution 10 m ocean surface roughness mapping capabilities changes in ocean wave energy and propagation direction can be precisely quantified at very high resolution across spatial distances of 10 km and more this provides unique opportunities to study ocean wave refraction induced by spatial varying surface currents as expected and demonstrated over the grand agulhas current area the mesoscale variability of near surface currents documented and reconstructed from satellite altimetry can significantly deflect in coming south western swell systems based on ray tracing calculations and unambiguously revealed from the analysis of sentinel 2 msi ssgi measurements the variability of the near surface current explains significant wave current refraction leading to wavetrapping phenomenon and strong local enhancement of the total wave energy in addition to its importance for wave modeling and hazard prediction these results open new possibilities to combine different satellite measurements and greatly improve the determination of the upper ocean mesoscale vorticity motions

estimating aircraft sar response characteristics and ocean wave spectra in the labrador sea extreme waves experiment the labrador extreme waves experiment lewex was an international effort to assess methods of measuring and modeling the directional aspects of wind generated ocean waves especially their evolution in the presence of rapidly turning winds the author describes data processing methods that have been developed to derive estimates of two dimensional wave height variance spectra from the ocean imagery obtained in lewex by a c band synthetic aperture radar sar system aboard a canadian cv 580 aircraft sar spectra at altitudes of 20000 and 12000 ft are compared for both large approximately 50 degrees and small approximately 25 degrees radar look angles independence spectral estimates from both a surface contour radar and a radar ocean wave spectrometer aboard a nasa aircraft are used to verify the surface wave spectrum

magnetic properties and geochemistry of the active oxidation front and the youngest sapropel in the eastern mediterranean sea summary magnetic properties irm arm xin s ratio at 0 3 t room temperature rt hysteresis and thermomagnetic curves and geochemical data fe s mn al ti organic c were studied in two eastern mediterranean boxcores abc26 and bc19 at a resolution of 3 5 mm the boxcores contain sapropel s1 9 6 kyr bp at a few decimetres below seafloor the magnetic fraction consists predominantly of single domain sd to pseudo singledomain psd magnetite in the entire cores the original input of magnetic grains comes from two sources aeolian dust both cores and volcanic ash from the minoan eruption of santorini core bc19 only non steady state diagenesis has changed the magnetic mineralogy considerably in these alternating organic rich organic poor sediments during deposition of sapropel s1 reductive diagenesis and pyritization in and just below the sapropel caused lower magnetic intensities coarser magnetic grain sizes and partial maghemitization in thermomagnetic curves two types of pyrite can be identified one oxidizes below 450 uc and the other above 450 uc the higher oxidation temperature is predominantly found below the sapropel this may be related to the microtexture of pyrite which is euhedral below sapropels and mainly framboidal within sapropels since the end of sapropel deposition a downward moving oxidation front has oxidized the upper half c 5 cm of the sapropel the oxidized part of the sapropel is enriched in diagenetically formed fe oxides with relatively high coercivity and arm the maximum coercivity is found in a distinct layer between the present day mn and fe redox boundaries at the top of the unoxidized sapropel the freshly precipitated fe oxides in this centimetre thick layer contain a mixture of superparamagnetic sp grains and high coercivity sd magnetite higher in the oxidized zone the freshly precipitated fe oxides have aged into generally slightly lower coercivity sd grains with relatively high arm in addition to the diagenetic formation of fe oxides at the top of the sapropel formation of a ferrimagnetic fe monosulphide may have occurred within the sapropel during later stages of diagenesis which may have enhanced the arm signal in the organic rich interval in particular

small scale open ocean currents have large effects on wind wave heights tidal currents and large scale oceanic currents are known to modify ocean wave properties causing extreme sea states that are a hazard to navigation recent advances in the understanding and modeling capability of open ocean currents have revealed the ubiquitous presence of eddies fronts and filaments at scales 10 100 km based on realistic numerical models we show that these structures can be the main source of variability in significant wave heights at scales less than 200 km including important variations down to 10 km model results are consistent with wave height variations along satellite altimeter tracks resolved at scales larger than 50 km the spectrum of significant wave heights is found to be of the order of 70 hs 2 g2 tm0 1 2 times the current spectrum where hs is the spatially averaged significant wave height tm0 1 is the energy averaged period and g is the gravity acceleration this variability induced by currents has been largely overlooked in spite of its relevance for extreme wave heights and remote sensing

magnetic properties of pelagic marine carbonates abstract pelagic carbonates are deposited far from continents usually at water depths of 3000 6000 m at rates below 10 cm kyr and are a globally important sediment type recent advances with recognition of widespread preservation of biogenic magnetite the inorganic remains of magnetotactic bacteria have fundamentally changed our understanding of the magnetic properties of pelagic carbonates we review evidence for the magnetic minerals typically preserved in pelagic carbonates the effects of magnetic mineral diagenesis on paleomagnetic and environmental magnetic records of pelagic carbonates and what magnetic properties can tell us about the open ocean environments in which pelagic carbonates are deposited we also discuss briefly late diagenetic remagnetisations recorded by some carbonates despite recent advances in our knowledge of these phenomena much remains undiscovered we are only at early stages of understanding how biogenic magnetite gives rise to paleomagnetic signals in sediments and whether it carries a poorly understood biogeochemical remanent magnetisation recently developed techniques have potential for testing how different magnetotactic bacterial species which produce different magnetite morphologies respond to changing nutrient and oxygenation conditions future work needs to test whether it is possible to develop proxies for ancient nutrient conditions from well calibrated modern magnetotactic bacterial occurrences a tantalizing link between giant magnetofossils and paleogene hyperthermal events needs to be tested much remains to be learned about the relationship between climate and the organisms that biomineralised these large and novel magnetite morphologies rather than being a well worn subject that has been studied for over 60 years the magnetic properties of pelagic carbonates hold many secrets that await discovery

introduction studies of ocean wave spectra from the shuttle imaging radar b experiment imagery of ocean surface waves obtained from synthetic aperture radar sar provides a unique two dimensional fine resolution view of the ocean wave field which has been long thought to be of considerable value for studying air sea inter action wave generation and propagation and wave current refraction wave spectra from sar have also been thought to be extremely useful for updating and verifying global wave forecast models such promise prompted a sar to be placed on seasat an oceanographic satellite which operated in a rather glorious mode for only a little over 3 months in 1978 this imagery has been well studied and indeed has demonstrated the feasibility of acquiring useful directional wave spectra from space e g vesecky and stewart 1982

dissolution and pyritization of magnetite in anoxie marine sediments concentrations of magnetite were determined with depth in sediments of varying h2s content taken from long island sound foam nwc and sachem sites and from a site in the rapidly depositing subaqueous portion of the mississippi delta for the three long island sound sites dissolution of magnetite during burial is clearly demonstrated and for all four sites the rate of magnetite dissolution is proportional to the concentration of dissolved pore water sulfide by combining magnetite depth distributions with sedimentation rate data and measurements of dissolved sulfide we find that magnetite dissolution is well described by the following rate law dcmagdt 1 1 10 5c0 5bcmagamag where cmag is the concentration of magnetite grams per gram of sediment cs is the concentration of dissolved sulfide mm and amag is the specific surface area of magnetite in the sediment cm2 per gram of magnetite this equation means that for a typical range of magnetite surface areas and dissolved sulfide concentrations the half life of magnetite in anoxic marine sediments ranges from about 50 to 1000 years sem observations of magnetite grains from the different sediment sites reveal that magnetite dissolution may be accompanied by extensive replacement by pyrite this only occurs if magnetite is in contact with high concentrations of h2s 1 mm for relatively long periods of time several hundred years with low concentrations of h2s 1 mm magnetite dissolution occurs without identifiable pyrite replacement we suggest that this feature of magnetite diagenesis may prove to be a useful paleosulfide indicator

a paleomagnetic and geochemical record of the upper cochiti reversal and two subsequent precessional cycles from southern sicily italy abstract a detailed paleomagnetic and geochemical study of the upper cochiti n r reversal recorded in marine marls on southern sicily shows two consecutive and very rapid transitions r n and n r that coincide with distinct lithological boundaries a fe migration model is presented in which magnetite is formed under different diagenetic conditions during sulphate reduction originally formed primary magnetite is preserved this primary magnetite has recorded the pre transitional normal polarity after burial migration of ferrous iron occurs and subsequent oxidation produces secondary magnetite which records the post transitional reversed polarity and produces the two apparent transitions in addition low temperature lt and high temperature ht components record the reversal in a slightly different way the ht component being acquired with a delay it is probable that both components reside in magnetite but have a different origin and grain size distribution giving different blocking temperature spectra the actual upper cochiti reversal occurs at a level with an estimated astronomically calibrated age of 4 165 ma

magnetic mineral inventory of equatorial atlantic ocean marine sediments off senegal glacial and interglacial contrast summary in complex sedimentary environments with different sources of the magnetic particles it is vital that all factors contributing to and affecting the magnetic signals be well understood for a better constrained interpretation of palaeomagnetic and climatic data palaeoclimatically driven signals may be convolved with volcanic and cosmogenic sources and diagenesis may alter the primary magnetic mineral assemblage rock magnetic methods and electron microscopy provide suitable means to characterize magnetic assemblages in this study of core retrieved sediments from the last 150 kyr off the coast of senegal nw africa the occurrence of magnetic spherules of volcanic origin and cosmogenic particles appeared to be insignificant in glacial stages ferrimagnetic iron and iron titanium oxides magnetically dominate with few signs of a diagenetic overprint low and room temperature magnetic results reveal evidence for haematite and goethite while haemoilmenite and titanomagnetite were identified from low temperature ac susceptibility measurements and sem observations in contrast the interglacial samples appeared to have been severely affected by diagenesis with pyrite making up over 50 per cent of the iron bearing phases the verwey transition observed at 110 k confirms the presence of magnetite the glacial and interglacial contrast reveals the close link between northwest african climate and the magnetic mineralogy of the sediments

magnetic mineral diagenesis in suboxic sediments at bettis site w n ne pacific ocean the effects of iron diagenesis on paleomagnetism and rock magnetism were examined in suboxic sediments from bettis site w n in the ne pacific ocean as part of the oxidative decomposition of organic matter ultrafine grained authigenic magnetites are produced immediately above the iron reduction zone this zone is commonly observed in deep sea sediments as a prominent color change from brown to greenish grey the magnetite authigenesis is evidenced by systematic increases in natural magnetic intensities and stabilities and by comparable shifts in other rock magnetic properties the magnetites are composed of relatively pure fe3o4 and fall within a restricted size range of 0 06 0 12 m which is nominally single domain some of these finest grained magnetites are rapidly destroyed during burial upon entering the zone of iron reduction leaving a relatively coarser population magnetite dissolution appears to continue with depth according to a first order surface area reaction process when at steady state iron reduction is independent of sulfide formation in these sediments because solid sulfur profiles show no increase at depth and most of the sulfur occurs as barite despite a well constrained carbonate stratigraphy comparisons of paleomagnetic directions between nearby cores show little agreement suggesting that the directions are composed of a complex mixture of remanences acquired at different depths subsurface magnetic peaks may represent paleoredox markers preserved by non steady state redox conditions caused by climatically induced variations in organic matter flux and sedimentation rates

diagenetic modification of magnetic properties observed in a piston core md01 2407 from the oki ridge japan sea abstract we investigated the magnetic properties of u channel samples from a giant piston core images md01 2407 in order to obtain high resolution records of past geomagnetic field and paleoenvironmental changes in the japan sea measurements of natural remanent magnetization nrm show occurrence of anomalous magnetic directions at several horizons which may represent geomagnetic polarity excursions in the brunhes chron however most of them occur close to the lithological boundary including tephra layers suggesting that these features might have been caused by deformation of core sediments intensity of nrm normalized by artificially induced remanence shows no significant correlation with a standard paleointensity record this is probably caused by a variation of lithology including volcanic ash layers and effect of the diagenetic changes of magnetic minerals down core variations of magnetic properties in the topmost part depict in detail the process of dissolution and alteration of magnetic minerals during reductive diagenesis which is to be expected for hemipelagic sediments characterized by a high sedimentation rate and a high organic matter content magnetic concentration parameters including low field susceptibility anhysteretic remanent magnetization and isothermal remanent magnetization irm indicate that a loss of fine grained magnetite occurs from 0 6 to 1 2 mbsf while remanence intensities below the level of the early diagenesis are one or two orders of magnitude lower than those in the topmost part most of the thinly laminated tl dark layers showed rather enhanced magnetic intensities typically tl2 shows a marked peak at the top with a gradual decrease towards the bottom variation of s ratio which gives the proportion of a low coercivity component in saturation irm suggests that low coercivity and fine grained ferromagnetic minerals are dominant these data suggest new magnetic minerals formed during deposition of the tl layers which may be analogous to the diagenetic magnetic enhancement known in sapropels of the mediterranean sea

a numerical study of wave refraction in shallow tidal waters wave observations taken at two shallow water sites off the coast of south west wales u k are examined the buoys are located in a region of strong semi diurnal tides and the observations show significant variation at semi diurnal frequencies in period amplitude and direction the interaction between tides and waves is studied using linear theory of wave refraction by slowly varying currents and depths it is shown that quasi steady analytical models fail to reproduce the tidally induced variations in wave parameters a linear ray tracing model including the effects of both spatial and temporal variations in the tidal currents and elevations improves the simulation of the observed modification of the waves short period waves respond to variations in current refraction over a tidal cycle long period waves are more influenced by variations in water depth over a tidal cycle

sedimentation on the inner shelf of the east china sea magnetic properties diagenesis and paleoclimate implications abstract high resolution magnetic analysis was performed on the 19 22 m core md06 3040 27 43 3663 n 121 46 8822 e 46 m water depth from the east china sea ecs inner continental shelf which was recovered during the images xiv md155 marco polo 2 cruise of the r v marion dufresne ipev magnetic grains are mainly transported to the inner shelf from erosion on mainland china delivered by the yangtze river nine 14 c ams dates indicate that the core spans about the last 10 4 ka with an average sedimentation rate of nearly 2 mm yr the primary magnetic mineral assemblage of the uppermost sediments contains magnetite with some contributions from hematite and greigite two main stepwise changes are observed in the magnetic mineral content due to post depositional reductive diagenesis the first occurs from the top of the core to 3 5 m and is characterized by reduction of both the magnetite and hematite contents the second occurs at 8 45 9 m and is characterized by a loss of fine grained ferrimagnetic material variations in the magnetic mineral content of this core are related to geochemical and redox environment changes in the ecs through the oxic suboxic sulfidic methanic zones from top to bottom despite significant reduction of a large amount of the ferrimagnetic mineral content due to diagenesis intervals characterized by lower magnetic mineral concentrations and higher coercivities are still identified at 0 45 0 6 1 5 1 7 2 9 3 1 4 4 4 7 5 3 5 7 5 9 6 1 and 8 2 8 4 ka these intervals are in phase within dating errors these intervals are in phase with weak summer monsoon events which indicate that a relationship between magnetic results and paleoclimatic events is partially preserved

hemipelagic sedimentation in a region of crustal doming between the mendocino and pioneer fracture zones abstract pacific study area w n lies 300 km west of california south of the gorda ridge between the mendocino and pioneer fracture zones hemipelagic mud covers the seafloor over a broad low rise and grades eastward into distal turbidite deposits of the delgada fan 3 5 khz profiles show three kinds of acoustic character for the seafloor strongly reflecting turbidite deposits depositionally draped hemipelagic sediment and an unusual morphology characterized by low relief closely spaced hills these small hills occur in the same area as the low rise implying a common origin calculations of the plate motions for this small corner of the pacific plate suggest that it is overriding the upper mantle thermal trace of the gorda ridge magma chamber this heat source apparently causes doming offsets in the layered hemipelagic sediment and formation of the closely spaced small hills