rayleigh waves normally incident at a continental boundary summary some results of a study of the propagation of monochromatic rayleigh waves normally incident on the western ocean continent boundary of the iberian peninsula are described this seismological problem is modelled in two dimensions using the finite element method for periods in the range of 1 5 to 60 0s the following results for ocean continent direction of propagation are presented i the estimate of the reflected and transmitted wavefields ii the phase velocity curves for the fundamental mode in the transition zone iii the transmission and reflection coefficients and iv the seismic energy distribution for transmitted and reflected modes experimental data from porto pto a continental station and ponta delgada pda an oceanic station were compared to ascertain the effect on rayleigh wave propagation across the continental margin comparison of the experimental amplitude ratios and transmission factor suggests a thickness of about 4 km for the sediment layer in the western oceanic zone of the iberian peninsula

geochemistry of fluids associated with the 1995 1996 eruption of mt ruapehu new zealand signatures and processes in the magmatic hydrothermal system abstract the 1995 1996 eruption of mt ruapehu has provided a number of insights into the geochemical processes operating within the magmatic hydrothermal system of this volcano both pre eruption degassing of the rising magma and its eventual intrusion into the convective zone of the hydrothermal system beneath the lake were clearly reflected in lake water compositions the eruptions of september october 1995 expelled the lake and provided the first ever opportunity to characterise gas discharges from this volcano the fumarolic discharges revealed compositions typical of andesite volcanoes and strong interaction with the enclosing meteoric and hydrothermal system fluids some 1 1 mt of so 2 gas was released from the volcano between september 1995 and december 1996 whereas ca twice this amount 2 2 mt equivalent so 2 was erupted as soluble i e leachable oxyanions of sulphur significantly more sulphur was released from the volcano over this period than can be accounted for from the magma volume actually erupted the evidence suggests that a sizable component of the evolved sulphur was remobilised from the long lived hydrothermal system within the volcano during the 1995 1996 activity

fluid geochemistry of nisyros island dodecanese greece abstract two distinct hydrothermal aquifers are present beneath the lakki plain a a deep aquifer characterized by temperatures higher than 290 c and chloride rich fluids and b a shallow aquifer with a chloride content close to that of sea water and temperatures in the range 170 255 c the vapor phase boiled from the shallow aquifer feeds the fumarolic vents in the southern half of the lakki plain and its liquid phase flows northeast and southwest contributing to the thermal springs located along the northern and southern coasts of the island this conceptual hydrogeochemical model of nisyros island can be used to reconstruct past hydrothermal eruptions and to estimate the risk of such events happening again in the future

poas volcano crater lake acts as a condenser for acid metal rich brine models of formation of volcanic hosted metal deposits hypothesize that subsurface brines transport metals to sites of deposition laguna caliente in the active crater of poas volcano central costa rica consists of acid sulphate chloride brine with extreme ph 0 0 lake water sampled between 9 and 12 january 1987 at eight sites within the 40 m deep 210 m wide lake revealed temperatures between 58 and 64 c and densities measured in the laboratory at 60 c of 1 0575 0 0015g cm 3 the water s extreme acidity reflects the dominating input of acid fumaroles the presence of precipitated silica gypsum and sulphur as sediments reflects lake water equilibrium with those phases mass balance considerations require that dense brines percolate downwards from the lake into the volcano these may act as a source of metal rich brine feeding an underground ore forming hydrothermal system

the chemical and hydrologic structure of poa s volcano costa rica comparison of the chemical characteristics of spring and river water draining the flanks of poa s volcano costa rica indicates that acid chloride sulfate springs of the northwestern flank of the volcano are derived by leakage and mixing of acid brines formed in the summit hydrothermal system with dilute flank groundwater acid chloride sulfate waters of the rio agrio drainage basin on the northwestern flank are the only waters on poa s that are affected by leakage of acid brines from the summit hydrothermal system acid sulfate waters found on the northwestern flank are produced by the interaction of surface and shallow groundwater with dry and wet acid deposition of so2 and h2so4 aerosols respectively the acid deposition is caused by a plume of acid gases that is released by a shallow magma body located beneath the active crater of poa s no evidence for a deep reservoir of neutral ph sodium chloride brine is found at poa s the lack of discharge of sodium chloride waters at poa s is attributed to two factors 1 the presence of a relatively volatile rich magma body degassing at shallow depths 1 km into a high level summit groundwater system and 2 the hydrologic structure of the volcano in which high rates of recharge combine with rapid lateral flow of shallow groundwater to prevent deep seated sodium chloride fluids from ascending to the surface the shallow depth of the volatile rich magma results in the degassing of large quantities of so2 and hcl these gases are readily hydrolyzed and quickly mix with meteoric water to form a reservoir of acid chloride sulfate brine in the summit hydrothermal system high recharge rates and steep hydraulic gradients associated with elevated topographic features of the summit region promote lateral flow of acid brines generated in the summit hydrothermal system however the same high recharge rates and steep hydraulic gradients prevent lateral flow of deep seated fluids thereby masking the presence of any sodium chloride brines that may exist in deeper parts of the volcanic edifice structural stratigraphic and topographic features of poa s volcano are critical in restricting flow of acid brines to the northwestern flank of the volcano a permeable lava lahar sequence that outcrops in the rio agrio drainage basin forms a hydraulic conduit between the crater lake and acid chloride sulfate springs spring water residence times are estimated from tritium data and indicate that flow of acid brines from the active crater to the rio agrio source springs is relatively rapid 3 to 17 years hydraulic conductivity values of the lava lahar sequence calculated from residence time estimates range from 10 5 to 10 7 m s these values are consistent with hydraulic conductivity values determined by aquifer tests of fractured and porous lava pyroclastic sequences at the base of the northwestern flank of the volcano fluxes of dissolved rock forming elements in rio agrio indicate that approximately 4300 and 1650 m3 of rock are removed annually from the northwest flank aquifer and the active crater hydrothermal system respectively over the lifetime of the hydrothermal system 100 s to 1000 s of years significant increases in aquifer porosity and permeability should occur in marked contrast to the reduction in permeability that often accompanies hydrothermal alteration in less acidic systems average fluxes of fluoride chloride and sulfur calculated from discharge and compositional data collected in the rio agrio drainage basin over the period 1988 1990 are approximately 2 38 and 30 metric tons day these fluxes should be representative of minimum volatile release rates at poa s in the last 10 to 20 years

sulfur isotopic effects in the disproportionation reaction of sulfur dioxide in hydrothermal fluids implications for the δ 34 s variations of dissolved bisulfate and elemental sulfur from active crater lakes sulfur isotope effects during the so 2 disproportionation reaction to form elemental sulfur 3so 2 3h 2 o 2hso 4 s 2h at 200 330 c and saturated water vapor pressures were experimentally determined initially a large kinetic isotopic fractionation takes place between hso 4 and s followed by a slow approach to equilibrium the equilibrium fractionation factors estimated from the longest run results are expressed by 1000 in hso 4 s 6 21 10 6 t 2 3 62 the rates at which the initial kinetic fractionation factors approach the equilibrium ones were evaluated at the experimental conditions 34 s values of hso 4 and elemental sulfur were examined for active crater lakes including noboribetsu and niseko hokkaido japan khloridnoe bannoe and maly semiachik kamchatka poas costa rica ruapehu new zealand and kawah ijen and keli mutu indonesia hso4 s values are 28 for keli mutu 26 o for kawah ijen 24 c for ruapehu 23 for poas 22 for maly semiachik 21 for yugama 13 for bannoe 9 for niseko 4 o for khloridonoe and 0 for noboribetsu in the decreasing order the so 2 disproportionation reaction in the magmatic hydrothermal system below crater lakes where magmatic gases condense is responsible for high hso4 s values whereas contribution of hso 4 produced through bacterial oxidation of reduced sulfur becomes progressively dominant for lakes with lower hso4 s values currently noboribetsu crater lake contains no hso 4 of magmatic origin a 40 year period observation of 34 s hso4 and 34 s s values at yugama indicated that the isotopic variations reflect changes in the supply rate of so 2 to the magmatic hydrothermal system this implies a possibility of volcano monitoring by continuous observation of 34 s hso4 values the 18 o values of hso 4 and lake water from the studied lakes covary indicating oxygen isotopic equilibration between them the covariance gives strong evidence that lake water circulates through the sublimnic zone at temperatures of 140 30 c

water and gas chemistry of lake nyos and its bearing on the eruptive process abstract the isotopic and chemical composition of water samples collected from lake nyos some two and eight weeks after the eruption of august 21 1986 point to the existence of three distinct mixing regimes involving three water components an essentially homogeneous unmixed body of water at depths 100 m overlain by water increasingly affected by surface evaporation and a 5 10 m layer containing recent but pre eruption rain water the cationic constituents na k mg ca mn fe of the lake water correspond to the dissolution of around 0 1 g of local rock the waters are close to saturation with respect to siderite the composition of the gas dissolved in the deep lake waters 0 65 b w of co2 pco2 4 4b corresponds in mmol mol 1 to 996 co2 2 0 ch4 2 0 n2 0 05 ar 0 004 he 0 0002 h2 0 0001 ne co 2 13 c 3 4 and of he rair 5 5 suggest deep magmatic origins the 13c and 2h content of ch4 organic sedimentary origin the presence of aromatic hydrocarbons indicates very high temperatures of hydrocarbon formation exsolution of gas will first lead to the precipitation of siderite then iron hydroxide the chemistry of the lake waters points to a loss of some 240 000 t of co2 from the upper 100 m of the lake their isotopic composition is consistent with the assumption that the eruption was triggered by the accumulation of cold rain waters at the lake surface prior to the eruption inducing partial convective overturn there is no need to invoke addition of chemical or isotopic constituents from deeper levels during the eruption

analytical laboratory comparison of major and minor constituents in an active crater lake abstract the crater lake water from maly semiachik volcano in kamchatka was used for the international analytical laboratory comparison of major and minor elements and hydrogen sulfur and oxygen isotope data eight institutions participated in this program giving analytical results of 9 major and 20 minor elements mainly by using icp aes for cations and ic for anions among the major elements na mg and si showed coefficients of variation cv of 10 or more whereas b al fe mn had coefficients less than 7 the cv of the minor elements co cu p cr pb was much greater 30 while the v analyses agreed well 2000 ppm and so 4 5000 ppm gave considerable ranges 5 1 and 8 8 cv respectively as did the obtained ph values 22 cv the measured 18 o of the water samples and 34 s of sulfate are in excellent agreement but the d values had cv of 8 technical recommendations are presented to improve the analytical results for these elements with significant deviations from the mean values

d h and 18 o 16 o ratios of water in the crater lake at kusatsu shirane volcano japan abstract the d h and 18o 16o ratios of water in the active crater lake situated on the kusatsu shirane volcano japan are about 20 and 6 respectively higher than local meteoric water the ratios show seasonal variations superimposed on a gradual change over nine years the isotopic ratios started to increase in early 1990 and decrease in the spring of 1995 the seasonal variation which is high in winter and low in summer correlates with the temperature difference between lake water and ambient air the large temperature difference in winter enhances the evaporation of lake water and produces the enriched isotopic ratios relative to the ratios in summer the accumulation of snow and the decrease in the flux of meteoric water into the lake strengthens the winter time isotopic enrichment the enriched isotopic ratios of the lake water over a long time result from the addition of an end member with heavy isotopic ratios contained in a thermal fluid supplied to the lake considering the water balance in the lake the isotopic ratios of the thermal fluid were found to be close to the lake water itself suggesting the circulation of the lake water seeping through lake floor based on the correlation between cl concentration and the isotopic ratios the contribution by the heavy end member was estimated to be 25 36 relative to the enrichment by evaporation the heavy end member could be a liquid phase evolved from a parental fluid which is a mixture of local meteoric water and a magmatic fluid as found in high temperature volcanic gases

evolution of a vent hosted hydrothermal system beneath ruapehu crater lake new zealand a two year chemical monitoring program of ruapehu crater lake shows that it has evolved considerably since the volcano s more active eruptive periods in the early 1970s the present ph 20 c of 0 6 is about one half unit more acid than the baseline values in the 1970s whereas s cl ratios have increased markedly owing in part to declining hcl inputs into the lake but also to absolute increases in so4 levels which now stand at the highest values ever recorded increases in k mg and na mg ratios over the 20 year period are attributed to hydrothermal reaction processes in the vent which are presently causing dissolution of previously formed alteration phases such as natroalunite these observations combined with results of a recent heat budget analysis of the lake have led to the development of hydrothermal convection model for the upper portion of the vent possible vent lake chemical reaction processes between end member reactants have been modelled with the computer code chiller the results are consistent with the view that variations in lake chemistry which are initiated by the introduction of fresh magmatic material into the vent reflect the extent of dissolution reaction progress on the magmatic material and or its alteration products the results also provide insights into the role of such vent processes in the formation of high sulfidation type ore deposits

monitoring of volcanic eruptions at yugama crater lake by aqueous sulfur oxyanions abstract variations of polythionates sulfane disulfonates and sulfate in the yugama crater lake japan have been monitored for more than 25 years just before the 1982 eruption at the crater lake polythionate ions decreased to zero from the normal level of about 2000 ppm and sulfate ions increased from 2500 to 5000 ppm during the 1982 eruption polythionate and sulfate ions varied inversely in concentration and the variations exactly coincided with the frequency of volcanic earthquakes and subsequent explosions these observations are interpreted in terms of aqueous reactions of fumarolic so2 h2s gases resulting in precipitation of alunite the behavior of polythionate and sulfate ions strongly suggests that they are useful indicator for prediction of impending volcanic hazards from active crater lakes

geochemistry of the acid kawah putih lake patuha volcano west java indonesia abstract kawah putih is a summit crater of patuha volcano west java indonesia which contains a shallow 300 m wide lake with strongly mineralized acid sulfate chloride water the lake water has a temperature of 26 34 c ph s tot 2500 4600 ppm and cl 5300 12 600 ppm and floating sulfur globules with sulfide inclusions are common sulfur oxyanion concentrations are unusually high with s 4 o 6 2 s 5 o 6 2 s 6 o 6 2 2400 4200 ppm subaerial fumaroles thermodynamic modeling of the lake fluids indicates that the lake water is saturated with silica phases barite pyrite and various pb sb cu as bi bearing sulfides when sulfur saturation is assumed precipitating phases predicted by the model calculations are consistent with the bulk chemistry of the sulfur rich bottom sediments and their identified mineral phases much of the lake water chemistry can be explained by congruent rock dissolution in combination with preferential enrichments from entering fumarolic gases or brines and element removal by precipitating mineral phases as indicated by a comparison of the fluids volcanic rocks and lake bed sediment flank springs on the mountain at different elevations vary in composition and are consistent with local rock dissolution as a dominant factor and ph dependent element mobility discharges of warm sulfate and chloride rich water at the highest elevation and a near neutral spring at lower level may contain a small contribution of crater lake water the acid fluid induced processes at patuha have led to the accumulation of elements that are commonly associated with volcano hosted epithermal ore deposits the dispersal of heavy metals and other potentially toxic elements from the volcano via the local drainage system is a matter of serious environmental concern

gas buildup in lake nyos cameroon the recharge process and its consequences the gases dissolved in lake nyos cameroon were quantified recently december 1989 and september 1990 by two independent techniques in situ measurements using a newly designed probe and laboratory analyses of samples collected in pre evacuated stainless steel cylinders the highest concentrations of co2 and ch4 were 0 30 mol kg and 1 7 mmol kg respectively measured in cylinders collected 1 m above lake bottom probe measurements of in situ gas pressure at three different stations showed that horizontal variations in total dissolved gas were negligible total dissolved gas pressure near the lake bottom is 1 06 mpa 10 5 atm 50 as high as the hydrostatic pressure of 2 1 mpa 21 atm comparing the co2 profile constructed from the 1990 data to one obtained in may 1987 shows that co2 concentrations have increased at depths to below 150 m based on these profiles the average rate of co2 input to bottom waters was 2 6 108 mol a increased deep water temperatures require an average heat flow of 0 32 mw into the hypolimnion over the same time period the transport rates of co2 heat and major ions into the hypolimnion suggest that a low temperature reservoir of free co2 exists a short distance below lake bottom and that convective cycling of lake water through the sediments is involved in transporting the co2 into the lake from the underlying diatreme increased ch4 concentrations at all depths below the oxycline and a high14c content 41 modern in the ch4 4 m above lake bottom show that much of the ch4 is biologically produced within the lake the ch4 production rate may vary with time but if the co2 recharge rate remains constant co2 saturation of the entire hypolimnion below 50 m depth would require 140a given present day concentrations

the sirung volcanic boiling spring an extreme chloride rich acid brine on pantar lesser sunda islands indonesia abstract the sirung volcano with a history of phreatomagmatic outbreaks has its present active center within a 1000 m wide subsidence crater the sirung crater lake scl has 15 g l 1 cl and 19 g l 1 so4 ph 0 75 temperature 40 c a highly saline brine sirung boiling spring sbs boils to the surface beside the lake it contains 116 g l 1 cl ph 1 4 chemical geothermometers indicate a reservoir temperature of 240 c the maximum depth of this reservoir is estimated to be 400 m the stable isotope composition is d 12 and 18o 5 0 to 6 0 tritium in the sbs is 0 0 tu in the scl 4 6 tu evidence against invading seawater as a source is the negative d value in addition to the six times higher cl concentration of the sbs evaporites are rejected as a source of the cl because of the geologic setting the average cl h 2 o ratio in sirung volcanic glasses as estimated by microprobe is very close to the cl h 2 o ratio of 0 047 for the sbs the zero tritium level in the sbs its high cl concentration and the acid character are other evidences for magmatic water as source for the sbs the acid sbs is poor in sulphur which may have been precipitated at depth as sulphides theories on porphyry cu formation in volcanic arc environments invoke highly saline brines as the transporting agent the acid saline brines from the sirung and white island new zealand craters and cl rich crater lakes associated with andesitic volcanism in subduction zones indicate that such fluids occur more frequently at the surface than has been possibly realized hitherto

volcanic lake systematics ii chemical constraints abstract a database of 373 lake water analyses from the published literature was compiled and used to explore the geochemical systematics of volcanic lakes binary correlations and principal component analysis indicate strong internal coherence among most chemical parameters compositional variations are influenced by the flux of magmatic volatiles and or deep hydrothermal fluids the chemistry of the fluid entering a lake may be dominated by a high temperature volcanic gas component or by a lower temperature fluid that has interacted extensively with volcanic rocks precipitation of minerals like gypsum and silica can strongly affect the concentrations of ca and si in some lakes a much less concentrated geothermal input fluid provides the mineralized components of some more dilute lakes temporal variations in dilution and evaporation rates ultimately control absolute concentrations of dissolved constituents but not conservative element ratios most volcanic lake waters and presumably their deep hydrothermal fluid inputs classify as immature acid fluids that have not equilibrated with common secondary silicates such as clays or zeolites many such fluids may have equilibrated with secondary minerals earlier in their history but were re acidified by mixing with fresh volcanic fluids we use the concept of degree of neutralization as a new parameter to characterize these acid fluids this leads to a classification of gas dominated versus rock dominated lake waters a further classification is based on a cluster analysis and a hydrothermal speedometer concept which uses the degree of silica equilibration of a fluid during cooling and dilution to evaluate the rate of fluid equilibration in volcano hydrothermal systems

geomagnetic poles over the past 10 000 years locations of the geomagnetic pole over the past 10 000 years have been calculated by averaging the vgp positions obtained from paleomagnetic data the distribution of the geomagnetic pole was elongated to the direction parallel to the meridian of 45 and 225 longitude and westward movement of the pole was predominant throughout this period the time sequence of the polar motion can be divided into three intervals the intervals between ca 10 000 b p and ca 7000 b p between ca 7000 b p and ca 3700 b p and between ca 3700 b p and the present during the period between ca 7000 and ca 3700 b p the range of the movement of the geomagnetic pole was limited within 5 degrees around the geographical pole before and after this period the movement was very active fluctuating over 10 degrees the results of the last 2000 years show good consistency with the geomagnetic pole calculated from archaeomagnetic data by merrill and mcelhinny 1983

chemical evolution and volcanic activity of the active crater lake of poas volcano costa rica 1993 1997 abstract concentrations of chloride and sulfate and ph in the hot crater lake laguna caliente at poas volcano and in acid rain varied over the period 1993 1997 these parameters are related to changes in lake volume and temperature and changes in summit seismicity and fumarole activity beneath the active crater during this period lake level increased from near zero to its highest level since 1953 lake temperature declined from a maximum value of 70 c to a minimum value of 25 c and ph of the lake water increased from near zero to 1 8 in may 1993 when the lake was nearly dry chloride and sulfate concentrations in the lake water reached 85 400 and 91 000 mg l 1 respectively minimum concentrations of chloride and sulfate after the lake refilled to its maximum volume were 2630 and 4060 mg l 1 respectively between january 1993 and may 1995 most fumarolic activity was focused through the bottom of the lake after may 1995 fumarolic discharge through the bottom of the lake declined and reappeared outside the lake within the main crater area the appearance of new fumaroles on the composite pyroclastic cone coincided with a dramatic decrease in type b seismicity after january 1996 between may 1995 and december 1997 enhanced periods of type a seismicity and episodes of harmonic tremor were associated with an increase in the number of fumaroles and the intensity of degassing on the composite pyroclastic cone adjacent to the crater lake increases in summit seismic activity type a b and harmonic tremor and in the height of eruption plumes through the lake bottom are associated with a period of enhanced volcanic activity during april september 1994 at this time visual observations and remote fumarole temperature measurements suggest an increase in the flux of heat and gases discharged through the bottom of the crater lake possibly related to renewed magma ascent beneath the active crater a similar period of enhanced seismic activity that occurred between august 1995 and january 1996 apparently caused fracturing of sealed fumarole conduits beneath the composite pyroclastic cone allowing the focus of fumarolic degassing to migrate from beneath the lake back to the 1953 1955 cone changes in the chemistry of summit acid rain are correlated changes in volcanic activity regardless of whether fumaroles are discharging into the lake or are discharging directly into the atmosphere

fluid volcano interaction in an active stratovolcano the crater lake system of poas volcano costa rica rowe g l jr brantley s l fernandez m fernandez j f borgia a and barquero j 1992 fluid volcano interaction in an active stratovolcano the crater lake system of po is volcano costa rica j volcanol geotherm res 49 2351 seismic and geochemical data collected at po is volcano costa rica since 1978 suggest that temperature and chemical variations recorded in subaerial fumaroles and the crater lake are related to episodic release of heat and volatiles associated with hydrofracturing of the upper margin of the shallow magma body power outputs associated with these events approach 600 mw and are superimposed on a baseline energy flux of approximately 200 mw the baseline heat flux suggests a magma solidification rate of 0 012 km3 yr and background volatile release rates of 1000 t d h20 66 t d s 13 t d ci and 0 5 t d f these fluxes are comparable to fluxes of f c1 and s exiting the magmatic hydrothermal system through acidic flank springs and are about a factor of five less than estimated volatile fluxes through summit fumaroles during the high temperature event of 1981 1983 mass balance considerations suggest that heat released at the lake surface is primarily supplied by the ascent of heated brines supplemented by condensation of fumarolic steam calculated average seepage rates out of the lake 450 kg s indicate rapid convection of acidic lake brine through underlying lake sediments and pyroclastic deposits circulation of the extremely corrosive lake brine through the volcanoclastic material beneath the lake may enhance subsurface permeabilities fluxes of rock forming elements observed in the rio agrio basin on the northwest flank of po is suggest that dissolution and removal of volcano elastic material occurs at a rate of approximately 1650 m3 yr however estimated sulfur fluxes from the cooling magma body suggest that porosity created by this dissolution could quickly be filled by the deposition of native sulfur finally analysis of heat and water budgets for the crater lake over the period 1978 1989 indicates that the recent decline and disappearance of the lake was caused by variations in summit rainfall combined with an increase in subsurface heat flow to the lake in 1987 1988 the increase in heat flow is related to continued degassing of high temperature volatiles following a hydrofracturing magma ascent episode that occurred in 1986

the lake nyos gas disaster chemical and isotopic evidence in waters and dissolved gases from three cameroonian crater lakes nyos monoun and wum abstract to better understand the cause of the nyos gas disaster of august 21 1986 we conducted geochemical and limnological surveys in october 1986 of three lakes nyos monoun and wum which are located in the cameroon volcanic zone that is characterized by a prevalence of young alkaline basalts and basanitoids lake wum was studied as a non active control co2 is dissolved in significant concentrations about 1 5 of saturation in gas active lakes nyos and monoun but is virtually absent in lake wum stable isotopic ratios of total dissolved carbon 13c 3 for nyos and 5 5 for monoun and of helium 5 7 ratm for nyos and 3 6 ratm for monoun indicate a mantle origin of these gases however so42 and cl concentrations are found to be very low concentrations of dissolved chemical species like fe2 mg2 ca2 and hco3 are high in the two gas active lakes whereas they are very low in the gas inactive lake high salinities in the gas active lakes are probably due to dissolution of indigenous mafic rocks and transported lateritic soil in acidic co2 rich warm water the gas active lakes are characterized by increasing temperature and salinity with increasing depth indicating an active influx of heat and dissolved materials at the bottom density estimates show that the lake water is stably stratified in spite of the inverse temperature profile of the lakes on account of dissolved chemical species the concentrations of dissolved carbonate species co2 aq and hco3 are positively correlated with those of ionic dissolved species indicating their common occurrence in the bottom water the august 1986 gas bursts from lake nyos were most likely caused by rapid exsolution of dissolved co2 within the lake an explosive process such as a phreatic eruption or a co2 gas jetting from beneath the bottom is unlikely because of low concentrations of cl and so42 no oxygen isotopic shift low turbidity and no reported perturbation of the bottom sediments exsolution of co2 bubbles could occur if co2 saturated bottom water was displaced upwards by an increased influx of high salinity water from the bottom during the rainy season exsolution of co2 at the upper layers was possibly accelerated by upwelling of a two phase fluid co2 bubbles and solution a mechanism known as a pneumatic lift pump resulting in discharge of a large amount of co2 gas the h2s concentration in the gas cloud must have been kept far below the lethal level because of a high fe2 concentration of the lake water

an integrated dynamic model for the volcanic activity at poas volcano costa rica a dynamic model for the activity of poas volcano costa rica is proposed data collected during a three year period show that the volcanic processes occur within a small hydrothermal system heat is supplied by a magma body in the conduit and is transferred to the surface by fluid convection within a given volume of rock pore pressure builds up due to the upward motion of fluids and the increase in vapor pressure when the temperature rises above the boiling point ultimately the system becomes unstable when the pore pressure overcomes the total pressure this leads to the assumption that the kinetic and thermal energies are proportional to the depth at which the mechanical equilibrium is disturbed laboratory experiments were performed by heating samples of the crater lake deposits the preliminary results of these experiments show significant analogies with the low energy activity of the volcano following this model we estimated that a phreatic explosion which reaches 200 m in height comparable to the one observed by francis et al in 1978 originates at a depth of 70 m and a temperature of 180 c these values agree with those reported in the literature in addition magmatic sulfur which partitions into the rising hydrothermal fluids reacts at lower temperature and higher underset raise0 3em hbox smash scriptscriptstyle f o 2 to produce pockets of liquid sulfur in the conduit deposits and the lava dome these pockets are subsequently erupted forming the pyroclastic sulfur

the significance of siderite in the sediments from lake nyos cameroon abstract small amounts 1 3 wt of endogenic siderite feco3 and traces of pyrite fes2 are present in a 1 m long sediment core from lake nyos thermodynamic modeling shows that the deep waters are supersaturated with respect to siderite and pyrite no other carbonates were found to be stable this rare occurrence of siderite is symptomatic of the build up of large concentrations of co2 and fe2 in the lake nyos waters a search for siderite in the deeper sediments could reveal the existence of previous gas burst events that have occurred at lake nyos or in other cameroon lakes

geochemistry mineralogy and chemical modeling of the acid crater lake of kawah ijen volcano indonesia the kawah ijen volcano with a record of phreatic eruptions has its 1000 m wide crater filled with a lake that has existed for at least one century at present the lake waters are hot t 37 c strongly mineralized tds 105 g l and extremely acidic ph 0 4 by its volume the javanese lake is probably the largest accumulation in the world of such acidic waters mineralogy of the suspended solids within the lake waters suggests that concentrations of si ca ti and ba are controlled by precipitation of silica gypsum anatase and barite lake sediment is composed of chemical precipitates with composition similar to the suspended solids thermodynamic calculations predict that the lake waters have reached equilibrium with respect to cristobalite barite gypsum anglesite celestite and amorphous silica in agreement with the analytical observations significant concentrations of ferric iron suggest that the current lake waters are fairly oxidized sulfides are absent in the water column but are always present in the native s spherules that form porous aggregates which float on the lake the presence of native s provides direct evidence of more reduced conditions at the lake floor where h 2 s is probably being injected into the lake with progressive addition of h 2 s to the acid waters native s pyrite and enargite are theoretically predicted to be saturated reactions between upward streaming h 2 s bearing gases discharged by subaqueous fumaroles and metals dissolved in the acidic waters could initiate precipitation of these sulfides a model of direct absorption of hot magmatic gases into cool water accounts for the extreme acidity of the crater lake results show that strongly acidic sulfate rich solutions are formed under oxidizing conditions at high gas water ratios reactions between the acidic fluids and the ijen andesite were modeled to account for elevated cation concentrations in lake water current concentrations of conservative rockforming elements are produced by dissolution of approximately 60 g of andesite per kg of acid solution complete neutralization of the acid lake waters by reaction with the wallrock produces a theoretical alteration assemblage equivalent to that observed in volcano hosted acid sulfate epithermal ore deposits

a telemetering system for monitoring aqueous polythionates in an active crater lake abstract we have developed an in situ monitoring system for aqueous polythionates in the yugama crater lake at kusatsu shirane volcano a commercially available nitrate selective electrode has a nernstian response to the concentration of polythionates in solution in the range of ph 2 5 11 however many active crater lakes contain highly acidic water ph ranges from 0 2 to 2 the monitoring system reduces the acidity of the lake water to ph 4 without changing the concentration of polythionates using a high efficiency cation exchange membrane technique the monitoring system was placed in a submersed station because the yugama surface lake water freezes in mid winter the system is described and preliminary data are reported

using crater lake chemistry to predict volcanic activity at poas volcano costa rica monitoring of crater lake chemistry during the recent decline and disappearance of the crater lake of poas volcano revealed that large variations in so4 cl f cl and mg cl ratios were caused by the enhanced release of hcl vapor from the lake surface due to increasing lake temperature and solution acidity variation in the concentration of polythionic acids h2sxo6 x 4 6 was the most reliable predictor of renewed phreatic eruptive activity at the volcano exhibiting sharp decreases three months prior to the initiation of phreatic eruptions in june 1987 polythionic acids may offer a direct indicator of changing subsurface magmatic activity whereas chloride based element ratios may be influenced by surface volatilization of hcl and subsequent recycling of acidic fluids in crater lake volcanoes

volcanic lake systematics i physical constraints volcanic lakes have a wide range of characteristics and we make an attempt to delineate the limiting physical conditions for several lake classes the ratio between heat input and heat dissipation capacity of a lake constrains the temperature for perfectly mixed steady state volcanic lakes poorly mixed lakes are also conditioned by this ratio but their temperature structure is also strongly influenced by the hydrodynamics resulting from different mechanisms of heat transfer the steady state temperatures of volcanic lakes are largely determined by the magnitude of the volcanic heat influx relative to the surface area of the lake small lakes have only a small capacity for heat dissipation and their temperature rises quickly with only small heat inputs large lakes are buffered against variations in heat input both the heat dissipation and meteoric water input into a lake are functions of lake surface area and therefore each lake water temperature demands a certain precipitation rate for mass conservation independent of lake size the results of energy mass balance modeling shows that under common atmospheric conditions most steady state volcanic lakes are unlikely to maintain a temperature in excess of 45 50 c validation of the volcanic lake model was performed using published data from yugama lake japan and the keli mutu lakes indonesia also the model was applied to 24 natural systems to provide a baseline assessment of energy fluxes under the model assumptions so future work on those systems can identify nuances in individual systems that deviate from the simple model conditions we recommend the model for use in assessing temperature variations and volcanic lake stability in settings with known physical and atmospheric conditions application of the energy mass balance calculations of model lakes provides a genetic classification scheme largely based on physical process parameters