factors controlling the burial of organic carbon in laminated and bioturbated sediments off nw mexico implications for hydrocarbon preservation factors controlling the burial of organic carbon oc in late quaternary sediments on the nw mexican continental margin are assessed using a suite of box and piston cores strategically located on the shelf slope rise with respect to the intense oxygen minimum in this region an oc concentration maximum occurs on the mid slope below the core of an intense water column o2 minimum due to current winnowing on the outer shelf the preferential accumulation of organic matter in fine grained deposits and the offshore decrease in the settling flux of organic detritus the organic matter at all water depths is overwhelmingly marine hydrogen indices hi are higher on the slope 300 mg hc g toc than on the shelf 300 mg hc g toc where current winnowing has promoted organic matter degradation but there is no difference in hi in slope sediments accumulating under well oxygenated and o2 deficient conditions the degree of winnowing appears to be the primary factor affecting the preservational quality of organic matter deposited on this margin rates of accumulation of oc and opal are all higher in the interglacial intervals when compared with the glacial deposits over the last 140 000 yr however matrix corrected hi values in the mid and lower slope cores are invariant and are similar to values in the laminated intervals from the oxygen minimum site thus cyclic changes in organic carbon accumulation on this margin have been controlled by production variations rather than differential preservation hi values in late quaternary sediments from several continental margins including nw mexico and euxinic basins correspond to type ii kerogen irrespective of bottom water o2 concentrations therefore the preservation of oil prone kerogen in productive margin settings does not appear to be restricted to sediments deposited under conditions of low bottom water o2 concentrations as envisioned in models of petroleum source rock deposition

sea surface temperature changes in the southern california borderlands during the last glacial interglacial cycle a variety of evidence suggests that average sea surface temperatures ssts during the last glacial maximum in the california borderlands region were significantly colder than during the holocene planktonic foraminiferal 18o evidence and average sst estimates derived by the modern analog technique indicate that temperatures were 6 10 c cooler during the last glacial relative to the present the glacial plankton assemblage is dominated by the planktonic foraminifer neogloboquadrina pachyderma sinistral coiling and the coccolith coccolithus pelagicus both of which are currently restricted to subpolar regions of the north pacific the glacial interglacial average sst change determined in this study is considerably larger than the 2 c change estimated by climate long range investigation mapping and prediction climap 1981 we propose that a strengthened california current flow was associated with the advance of subpolar surface waters into the borderlands region during the last glacial

sediment cd and mo accumulation in the oxygen minimum zone off western baja california linked to global climate over the past 52 kyr 1 concentrations of organic carbon orgc cadmium cd and molybdenum mo were measured in two sediment cores raised from depths of 430 and 700 m within the oxygen minimum zone omz off southern baja california at a temporal resolution of 0 5 kyr over the past 52 kyr these records are supplemented with diffuse spectral reflectance dsr measurements obtained on board ship soon after collection at a resolution of 0 05 kyr in the core from 700 m depth a component extracted from the dsr data and the three geochemical proxies generally vary in concert with each other and over a wide range 4 22 orgc 1 40 mg kg cd 5 120 mg kg mo intervals of increased orgc cd and mo accumulation generally correspond to warm periods recorded in the oxygen isotopic composition of greenland ice with the exception of the bolling allerod which is only weakly expressed off baja california concentrations of the biogenic proxies are higher in the core from 430 m depth but erratic sediment accumulation before 15 ka precludes dating of the older intervals that are laminated and contain elevated orgc cd and mo concentrations the new data provide further evidence of an intimate teleconnection between global climate and the intensity of the omz and or productivity along the western margin of north america on the basis of a comparison with cd and mo records collected elsewhere in the region we conclude that productivity may actually have varied off southern baja california by no more than a factor of 2 over the past 52 kyr

quaternary sedimentation and origin of the orinoco sediment wave field on the demerara continental rise ne margin of south america abstract new core data from a sediment wave field on the demerara outer ridge show that the waves are mainly built from turbidity currents that flow northwards down the demerara margin the contour currents circulating parallel and obliquely to the margin are apparently not as important to wave formation as previously proposed detailed analysis of the sedimentary facies of cores taken on the crest and flank of a sediment wave indicates that fine grained turbiditic deposits are dominant hemipelagic pelagic deposits are interbedded with the turbidites sediment redistribution by contour currents was only evidenced by the presence of peculiar clay mineral assemblages and microfaunal associations as well as some sedimentary structures such as truncations and cross bedding the turbiditic processes were active during the last glacial in contrast the holocene is characterised by pelagic sedimentation a combination of seismic and core data suggests that the sediment waves result from predominantly turbiditic depositional processes interacting with minor contour currents and synsedimentary deformation processes

the inorganic geochemistry of cretaceous black shales dsdp leg 41 in comparison to modern upwelling sediments from the gulf of california

millennial scale deep water oscillations reflections of the north atlantic in the deep pacific from 10 to 60 ka northeast pacific benthic foraminiferal 18o and 13 reveal repeated millennial scale events of strong deep sea ventilation associated with nutrient depletion and or high gas exchange during stadial cool high ice volume episodes from 10 to 60 ka opposite the pattern in the deep north atlantic two climate mechanisms may explain this pattern north pacific surface waters chilled by atmospheric transmission from a cold north atlantic and made saltier by reduced freshwater vapor transports could have ventilated the deep pacific from above alternatively faster turnover of pacific bottom and mid depth waters driven by southern ocean winds may have compensated for suppressed north atlantic deep water production during stadial intervals during the younger dryas event 11 6 13 0 cal ka ventilation of the deep ne pacific 2700 m lagged that in the santa barbara basin 450 m by 500 years suggesting that the ne pacific was first ventilated at intermediate depth from above and then at greater depth from below this apparent lag may reflect the adjustment time of global thermohaline circulation

latest quaternary north pacific surface water responses imply atmosphere driven climate instability a full sequence of brief interstadials dansgaard oeschger d o cycles are recorded from 60 to 25 ka in santa barbara basin california ocean drilling program hole 893a by planktonic foraminiferal isotopic and assemblage changes at unparalleled high resolution for the oceans synchronous climatic response between north pacific surface waters and the greenland ice sheet during d o cycling is strongly indicated by remarkable similarities in speed magnitude and character of rapid oceanic and atmospheric reorganizations inferred sea surface temperature warmings of as much as 5 c within a few decades and brief warming overshoots of as much as 3 c suggest involvement of an atmospheric amplification top down in situ atmospheric warming of the ocean is implied by differential responses partial decoupling in the changes recorded in surface and thermoclinal waters

late glacial to holocene changes in winds upwelling and seasonal production of the northern california current system abstract a core 120 km off the coast of southern oregon was examined for changes in lithology diatoms and pollen over the past 30 000 yr primary production during the late pleistocene was about half that of the holocene evidence from diatoms and pollen indicates that summer upwelling was much weaker implying an absence of strong northerly winds early pliocene diatoms found throughout the late pleistocene section were probably derived from diatomites east of the cascades and provide evidence for strong easterly winds over a dry continental interior the findings verify predictions of a climate model based on glacial maximum conditions there is no compelling evidence for a climatic reversal corresponding to the european younger dryas chron during the early holocene 9000 7000 yr b p there may have been years when winds were insufficiently strong to support upwelling so that warm stratified waters lay closer to the coast

biomarker temperature estimates for modern and last glacial surface waters of the california current system between 33 and 42 n sea surface temperature sst estimates were made using data for c37 39 alkenones analyzed in modern and glacial age intervals of sediment cores collected along an east west 42 n from 125 to 132 w and a north south 41 33 n transect of the california current system ccs the prymnesiophyte biomarker results suggest that surface waters warmed significantly throughout this region since the last glacial maximum lgm but the magnitude of warming varied spatially stratigraphic profiles from four sediment cores along the north south transect indicate the warming period was confined to the glacial interglacial transition 15 10 ka with sst reaching a maximum value at 10 ka and maintaining a uniformly high value throughout the holocene comparison of estimates derived from analysis of modern and lgm sediment intervals indicates the magnitude of the sst change was minimal for locations south of about 36 n 1 2 c and increased significantly 3 5 c north of this latitude using a simple heat balance model we calculate from the latitudinal gradient in sst that southward flow in the california current system during the lgm was about 60 of that measured today at 36 n our findings support the conclusion of others based on pollen data that coastal upwelling in the region of the northeast pacific off northern california was significantly reduced or even completely shutdown during the lgm

high resolution climatic evolution of coastal northern california during the past 16 000 years holocene and latest pleistocene oceanographic conditions and the coastal climate of northern california have varied greatly based upon high resolution studies ca every 100 years of diatoms alkenones pollen caco 3 and total organic carbon at ocean drilling program odp site 1019 41 682 n 124 930 w 980 m water depth marine climate proxies alkenone sea surface temperatures ssts and caco 3 behaved remarkably like the greenland ice sheet project gisp 2 oxygen isotope record during the balling allerod younger dryas yd and early part of the holocene during the yd alkenone ssts decreased by 3 c below mean bolling allerod and holocene ssts the early holocene ca 11 6 to 8 2 ka was a time of generally warm conditions and moderate caco 3 content generally 4 the middle part of the holocene ca 8 2 to 3 2 ka was marked by alkenone ssts that were consistently 1 2 c cooler than either the earlier or later parts of the holocene by greatly reduced numbers of the gyre diatom pseudoeunotia doliolus 10 and by a permanent drop in caco 3 to 3 starting at ca 5 2 ka coastal redwood and alder began a steady rise arguing for increasing effective moisture and the development of the north coast temperate rain forest at ca 3 2 ka a permanent ca 1 c increase in alkenone sst and a threefold increase in p doliolus signaled a warming of fall and winter ssts intensified higher amplitude and more frequent cycles of pine pollen alternating with increased alder and redwood pollen are evidence that rapid changes in effective moisture and seasonal temperature enhanced el nino southern oscillation enso cycles have characterized the site 1019 record since about 3 5 ka

sensitivity of northern hemisphere air temperatures and snow expansion to north pacific sea surface temperatures in the goddard institute for space studies general circulation model circum pacific marine and terrestrial records indicate a series of temperature inferred oscillations during the late glacial while many previous studies have probed the role of the north atlantic in these oscillations we test the sensitivity of the northern hemisphere air temperatures to north pacific sea surface temperature sst oscillation in the goddard institute for space studies general circulation model the effect of a colder north pacific is to cool air temperatures over north america as well as parts of europe and asia the colder ssts result in a large hemispheric response due to the loss of water vapor as a greenhouse gas the large sensitivity of the northern hemisphere to a north pacific sst change has implications for the ice age climate as well as the late glacial interval the results of this experiment provide a rapid mechanism for widespread cooling which has not been previously addressed

the northeast pacific ocean response to the 1982 1983 el nino the ocean s response to atmospheric forcing and to forcing along the coast by kelvin waves is examined in light of nearshore seasonal variability and the major 1982 1983 el nino in addition to driving the northeast pacific gyre and local currents the wind modifies the depth to the main thermocline changing the apparent westward phase speed of rossby waves excited by passing kelvin waves the amplitude of the passing kelvin wave determines whether the rossby wave depresses or raises the thermocline while propagating westward along the northeast pacific coast from oregon to washington model results suggest that the wind raises the main thermocline during the 1982 1983 el nino generally the coastal response off oregon and washington appears to be strongly driven by the large scale atmosphere while along the california coast and south to the equator the dominant el nino signal has an oceanic origin that signal with periods between 2 and 5 years originates in the western equatorial pacific ocean and is tracked eastward through the equatorial waveguide and then poleward along the coast to 50 n using data from two reduced gravity primitive equation models coupled at 18 n at shorter seasonal time scales the acceleration of the wind appears to be an important mechanism in driving coastal currents

sediment geochemical records of productivity and oxygen depletion along the margin of western north america during the past 60 000 years teleconnections with greenland ice and the cariaco basin abstract many sediment records from the margins of the californias alta and baja collected in water depths between 60 and 1200 m contain anoxic intervals laminated sediments that can be correlated with interstadial intervals as defined by the oxygen isotope composition of greenland ice dansgaard oeschger d o cycles these intervals include all or parts of oxygen isotope stage 3 ois3 60 24 cal ka the bolling allerod warm interval b a 15 13 cal ka and the holocene this study uses organic carbon corg and trace element proxies for anoxia and productivity namely elevated concentrations and accumulation rates of molybdenum and cadmium in these laminated sediments to suggest that productivity may be more important than ventilation in producing changes in bottom water oxygen bwo conditions on open highly productive continental margins the main conclusion from these proxies is that during the last glacial interval lgi 24 15 cal ka and the younger dryas cold interval yd 13 11 6 cal ka productivity was lower and bwo levels were higher than during ois3 the b a and the holocene on all margins of the californias the corg and trace element profiles in the lgi b a holocene transition in the cariaco basin on the margin of northern venezuela are remarkably similar to those in the transition on the northern california margin correlation between d o cycles in greenland ice with gray scale measurements in varved sediments in the cariaco basin also is well established synchronous climate driven changes as recorded in the sediments on the margins of the californias sediments from the cariaco basin and in the gisp 2 greenland ice core support the hypothesis that changes in atmospheric dynamics played a major role in abrupt climate change during the last 60 ka millennial scale cycles in productivity and oxygen depletion on the margins of the californias demonstrate that the california current system was poised at a threshold whereby perturbations of atmospheric circulation produced rapid changes in circulation in the eastern north pacific ocean it is likely that the pacific and atlantic oceans were linked through the atmosphere warmer air temperatures during interstadials would have strengthened hadley and walker circulations which in turn would have strengthened the subtropical high pressure systems in both the north pacific and the north atlantic producing increased rainfall over the cariaco basin and increased upwelling along the margins of the californias

organic matter production and preservation and evolution of anoxia in the holocene black sea dating of sediments collected in gravity cores during leg 1 of the 1988 r v knorr expedition to the black sea suggests that the onset of water column anoxia at 7 5 ka was virtually synchronous across the basin over a depth range of 200 2250 m a finely laminated organic carbon oc rich sapropel unit ii was produced as a result of this anoxia the trigger for increased oc production and development of anoxia was the spillover of saline waters through the bosporus that probably began at 9 0 ka and peaked between 7 0 and 5 5 ka this spillover enhanced vertical mixing and nutrient cycling and caused a short term 2 3 kyr burst in surface water productivity during the early part of unit ii deposition continued incursion of saline waters enhanced vertical stability and inhibited mixing of nutrients into surface waters thus limiting primary production and decreasing the oc flux to sediments beginning 5 5 ka concentration accumulation rate and degree of preservation of organic matter all decreased in the upper part of unit ii as a result of decreasing productivity but anoxia persisted throughout most of the water column the end of unit ii sapropel deposition was synchronous across the black sea as the result of the first blooms of the coccolith emiliania huxleyi which presumably marked an increase in surface water salinity above 11 and the beginning of unit i deposition the high coccolith carbonate fluxes that occurred during deposition of unit i diluted the oc concentration in the sediments but oc accumulation rates are about the same as those in upper part of unit ii

deglacial changes in ocean circulation from an extended radiocarbon calibration temporal variations in the atmospheric concentration of radiocarbon sometimes result in radiocarbon based age estimates of biogenic material that do not agree with true calendar age this problem is particularly severe beyond the limit of the high resolution radiocarbon calibration based on tree ring data which stretches back only to1 2 about 11 8 kyr before present bp near the termination of the younger dryas cold period if a wide range of palaeoclimate records are to be exploited for better understanding the rates and patterns of environmental change during the last deglaciation extending the well calibrated radiocarbon timescale back further in time is crucial several studies attempting such an extension using uranium thorium dated corals3 4 5 and laminae counts in varved sediments6 7 8 9 show conflicting results here we use radiocarbon data from varved sediments in the cariaco basin in the southern caribbean sea to construct an accurate and continuous radiocarbon calibration for the period 9 to 14 5 kyr bp nearly 3 000 years beyond the tree ring based calibration a simple model compared to the calculated atmospheric radiocarbon concentration and palaeoclimate data from the same sediment core suggests that north atlantic deep water formation shut down during the younger dryas period but was gradually replaced by an alternative mode of convection possibly via the formation of north atlantic intermediate water

brief interstadial events in the santa barbara basin ne pacific during the past 60 kyr the instability of the northern hemisphere glacial climate over the past 100 kyr has been revealed by at least 20 brief warm interstadial episodes called dansgaard oeschger events recorded in greenland ice cores1 3 and in north atlantic sedimentary records4 5 a few of these events have been recognized elsewhere6 8 here we describe a record of ocean oxygenation and circulation from the santa barbara basin in the northeast pacific ocean which correlates well with the greenland ice core records we see 19 of the 20 dansgaard oeschger events in the form of laminated sediments deposited under anoxic conditions and we can correlate at least 16 of these with the 17 ice core interstadials of the past 60 kyr thus these short term events were not restricted to the north atlantic region the events had substantial ecological and oceanographic effects in the santa barbara basin including changes in benthic faunal populations and in the age and composition of bottom waters similar ventilation changes have been seen in the gulf of california9 10 suggesting that these changes may have been widespread and synchronous along the northeast pacific margin these results suggest sensitivity of broad areas of the ocean atmosphere cryosphere system to short term climate change

glacial age hydrography of the far northwest pacific ocean stable isotope data on benthic foraminifera from more than 30 cores on the northern emperor seamounts and in the okhotsk sea are synthesized in paleohydrographic profiles spanning the depth range 1000 4000 m holocene core top benthic foraminiferal 18o and 13c data are calibrated to modern hydrographic properties through measurements of 13c of co2 and 18o of seawater cibicidoides stable isotope ratios are close to the 13c and equilibrium 18o of seawater whereas uvigerina 18o and 13c are variably offset from cibicidoides glacial maximum 13c of cibicidoides displays a different vertical profile than that of the holocene when results are adjusted by 0 32 to account for the secular change in 13c during the last glacial maximum the data coincide with the modern seawater and foraminiferal curves deeper than 2 km however at shallower depths 13c gradually increases by as much as 1 above the modern value furthermore above 2 km the benthic 18o decreases by 0 5 these results are consistent with a benthic front at 2 km in the north pacific see herguera et al 1992 but they differ from interpretations based on trace metal data which indicate a source of nutrient depleted deep water during glaciation the isotopic data suggest that during glaciation there was a better ventilated watermass at intermediate depths in the far northwestern pacific it was relatively fresher than deep waters there and deep waters were as nutrient rich as today

evidence for a stronger oxygen minimum zone off central california during late pleistocene to early holocene of 31 deep sea cores collected along the central california continental slope 18 have distinctly laminated sediment at depth but none have laminations in the top few centimetres the cores with laminated facies are restricted to water depths between 508 and 1508 m but not all cores taken from this depth interval have laminated facies 14 c dates yield an extrapolated age of 4700 b p for the top of the uppermost laminated unit comparisons of the diatom flora in the laminated couplets with diatom floras in a 13 month sediment trap record suggest that the laminations are varvelike couplets of seasonal sedimentation the laminated facies represent a period from the last global deglaciation to early holocene when the oxygen minimum zone along the northeastern pacific ocean was stronger than at present a stronger oxygen minimum zone during this time is inferred to be the result of intensified upwelling

on the preservation of laminated sediments along the western margin of north america 1 piston gravity and multicores as well as hydrographic data were collected along the pacific margin of baja california to reconstruct past variations in the intensity of the oxygen minimum zone omz gravity cores collected from within the omz north of 24 n did not contain laminated surface sediments even though bottom water oxygen bwo concentrations were close to 5 mol kg however many of the cores collected south of 24 n did contain millimeter to centimeter scale brown to black laminations in holocene and older sediments but not in sediments deposited during the last glacial maximum in addition to the dark laminations holocene sediments in soledad basin silled at 290 m also contain white coccolith laminae that probably represent individual blooms two open margin cores from 430 and 700 m depth that were selected for detailed radiocarbon dating show distinct transitions from bioturbated glacial sediment to laminated holocene sediment occurring at 12 9 and 11 5 ka respectively the transition is delayed and more gradual 11 3 10 0 ka in another dated core from soledad basin the observations indicate that bottom water oxygen concentrations dropped below a threshold for the preservation of laminations at different times or that a synchronous hydrographic change left an asynchronous sedimentary imprint due to local factors with the caveat that laminated sections should therefore not be correlated without independent age control the pattern of older sequences of laminations along the north american western margin reported by this and previous studies suggests that multiple patterns of regional productivity and ventilation prevailed over the past 60 kyr

assessment of sea surface temperature at 42 n in the california current over the last 30 000 years assessment of changes in surface ocean conditions in particular sea surface temperature sst is essential to understand long term changes in climate especially in regions where continental climate is strongly influenced by oceanographic processes to evaluate changes in sst in the northeast pacific we have analyzed long chain alkenones of prymnesiophyte origin at 38 depths in a piston and associated trigger core collected beneath the contemporary core of the california current system at 42 n 270 km off the coast of oregon california the samples span 30 000 years of deposition at this location unsaturation patterns u37k in the alkenone series display a statistically significant difference p 0 001 between interglacial 0 44 0 02 n 11 and glacial 0 29 0 04 n 20 intervals of the cores detailed examination of other compositional features of the c37 c38 c39 alkenone series and a related c36 alkenoate series measured downcore suggests the published u37k temperature calibration u37k 0 034 t 0 039 defined for cultures of a strain of emiliania huxleyi isolated from the subarctic pacific provides best estimates of winter sst at our study site this inference is purely statistical and does not imply however that the phytoplankton source of these biomarkers is most productive in winter or at the ocean surface the temperature record for u37k implies 1 an 4 c shift occurred in winter sst from 7 5 1 1 c at the last glacial maximum to 11 7 0 7 c in the present interglacial period and 2 this warming trend was confined to the time frame 14 10 ka within the glacial to interglacial transition period these conclusions are corroborated entirely by results from an independent sst transformation of radiolarian species assemblage data obtained from the same core materials

inorganic geochemical indicators of glacial interglacial changes in productivity and anoxia on the california continental margin abstract evidence from sediments in cores collected from within the present oxygen minimum zone omz 600 1200 m on the central and northern california margins record several episodes during the last interstadial ois 3 ca 60 24 ka of deposition of laminated sediments containing elevated concentrations of several trace elements indicative of anoxic conditions e g mo ni zn and cu the presence of abundant well preserved organic matter as well as lack of bioturbation and the presence of elevated concentrations of mo and other trace elements all support the theory that the omz in the northeastern pacific ocean was more intense possibly anoxic at several times during the late pleistocene sediments of all ages in cores from the southern california margin contain elevated concentrations of mo suggesting that this area has always had higher rates of sulfate reduction than either the central or northern california areas most of the ba in sediments in all cores collected on the upper continental slope 200 2700 m off california and southern oregon is derived from detrital clastic material and this source did not change much in time however the amount of biogenic ba did vary with time and these variations closely follow the temporal variations in organic c corg mass accumulation rate using ba and corg mass accumulation rates as proxy variables for productivity all cores show that organic productivity under the california current upwelling system was highest during ois 3 and the holocene and lowest during the last glacial interval lgi ca 24 10 ka all paleoproductivity proxy variables indicate that the southern california area has always experienced higher productivity than other areas under the california current at least over the last 50 ky

variability in the mean latitude of the atlantic intertropical convergence zone as recorded by riverine input of sediments to the cariaco basin venezuela abstract changes in the strength and position of the intertropical convergence zone itcz are an important component of climate variability in the tropical atlantic the cariaco basin located on the northern margin of venezuela is sensitive to tropical atlantic climate change and its sediments provide a record of past itcz behavior today the cariaco basin experiences two distinct seasons that reflect the annual migration of the atlantic itcz between january and march when the itcz lies south of the equator northeasterly trade winds sit directly over cariaco basin and strong coastal upwelling and dry conditions dominate beginning in june july as the itcz moves north local rainfall reaches a maximum and the upwelling diminishes or disappears here we summarize new and previously published data on the river derived terrigenous fraction of cariaco basin sediments as well as comparisons to other paleoclimate records which together suggest a coherent climatologic response in the tropical atlantic triggered by a pattern of itcz migration that mimics the seasonal cycle during periods of cooler north atlantic ssts on time scales ranging from the little ice age to the younger dryas to the cold stadials of the last glacial decreased detrital delivery to cariaco basin from local rivers suggests a southward shift in the mean latitudinal position of the itcz during warm interstadials and periods of holocene and deglacial warmth northward shifts in itcz position and its belt of convective rainfall are inferred from increased detrital delivery to the basin whether the rapid shifts in itcz position and precipitation recorded by cariaco basin sediments and other regional records reflect a response to forcing originating in the high latitude atlantic or to forcing potentially sourced in the tropics is a key question yet to be fully answered

expression of seasonal and enso forcing in climatic variability at lower than enso frequencies evidence from pleistocene marine varves off california abstract upper pleistocene marine sediments along the upper continental slope off northern and central california contain alternations of varved and bioturbated sediments and associated changes in biota and sediment composition these alternations can be related to conditions that accompany el nino and anti el nino enso circulation anti el nino conditions are characterized by increased upwelling and productivity and by low concentrations of dissolved oxygen in the oxygen minimum zone that resulted in varve preservation el nino conditions are characterized by little or no upwelling low productivity and higher concentrations of dissolved oxygen that resulted in zones of bioturbation alternations of varves and zones of bioturbation that range from decades to millennia occur through the upper pleistocene section the inferred long term alternations in el nino and anti el nino conditions appear to be a re expression of enso s primary 3 7 year cycle decadal to millennial cycles of productivity associated with el nino and anti el nino conditions may have served as a carbon pump and transferred atmospheric co 2 to the marine reservoir changes in sediment composition and organisms associated with el nino or anti el nino conditions can be related to both seasonal and enso phenomena expression of these changes at lower than enso frequencies may be partly explained by adding the effects of seasonal variability to effects produced by a self oscillating enso system however deterministic mechanisms including solar modulation of enso may also contribute to long term alternations of el nino and anti el nino conditions

pleistocene to holocene contrasts in organic matter production and preservation on the california continental margin organic matter in sediments from cores collected from the upper continental slope 200 2700 m off california and southern oregon shows marked differences in concentration and marine character between the last glacial interval ca 24 10 ka and either holocene time or last interstadial oxygen isotope stage 3 ca 60 24 ka in general sediments deposited during holocene time and stage 3 contain higher amounts of marine organic matter than those deposited during the last glacial interval and this contrast is greatest in cores collected off southern california the most profound differences in stage 3 sediments are between predominantly bioturbated sediments and occasional interbeds of laminated sediments the sediments are from cores collected within the present oxygen minimum zone on the upper continental slope from as far north as the oregon california border to as far south as point conception these upper pleistocene laminated sediments contain more abundant hydrogen rich type ii marine algal organic matter than even surface sediments that have large amounts of nonrefractory organic matter the stable carbon isotopic composition of the organic matter does not change with time between bioturbated and laminated sediments indicating that the greater abundance of type ii organic matter in the laminated sediments is not due to a change in source but rather represents a greater degree of production and preservation of marine organic matter the presence of abundant well preserved organic matter supports the theory that the oxygen minimum zone in the northeastern pacific ocean was more intense and possibly anoxic during late pleistocene time as a result of increased coastal upwelling that enhanced algal productivity

seasonal cycles of currents temperatures winds and sea level over the northeast pacific continental shelf 35 n to 48 n seasonal cycles of coastal wind stress adjusted sea level asl shelf currents and water temperatures off the west coast of north america 35 n to 48 n are estimated by fitting annual and semiannual harmonics to data from 1981 1983 longer records 9 34 years of monthly asl indicate that these two harmonics adequately represent the long term monthly average seasonal cycle and that the current measurement period is long enough to estimate the seasonal cycles we characterize the differences between fall winter and spring summer as follows for fall winter monthly mean winds north of 35 n are northward for 3 6 months longer in the north than in the south south of 35 n the mean winds are near zero or weakly southward monthly mean alongshore currents are northward over midshelf and shelf break at all locations sampled at depths of 35 m and deeper and are associated with high coastal sea levels and relatively warm water temperatures for spring summer monthly mean wind stresses are southward at all latitudes for 3 6 months longer in the south than in the north sea levels are low and water temperatures are relatively cool monthly mean currents at 35 m depth over the shelf are southward for 1 6 months longer at the shelf break than over midshelf and longer in the north than in the south while the deeper currents are less southward or northward the magnitudes of the seasonal cycles of all variables are maximum between approximately 38 n and 43 n generally decreasing slightly to the north and greatly to the south at each location the seasonal cycle of the alongshore current from 35 m depth at midshelf leads the sea level slightly and both lead the wind stress and temperatures by 1 2 months the seasonal cycles of all variables show a south to north progression south leads north by 1 2 months at 48 n annual mean currents at 50 m depth over the shelf break oppose the annual mean wind northward wind and southward current similarly at 35 n annual mean currents at 35 m depth over both midshelf and shelf break are opposed to the annual mean wind southward wind and northward current from 35 n to 43 n both summer and winter regimes are dominated by strongly fluctuating currents

glacial interglacial variations in production and nitrogen fixation in the cariaco basin during the last 580 kyr the effect of sea level change on nutrient supply to the anoxic cariaco demonstrates the fundamental importance of nitrogen n2 fixation and phosphate to oceanic production as n2 fixation produces biomass of low 15n and has been reported to be an important component of the nitrogen cycle in the modern cariaco basin we propose that it contributes to the light interglacial 15n 2 3 values observed in the ocean drilling program odp site 1002 sediment record during the glacials the sediments are bioturbated oxic conditions with low total organic carbon toc contents and sedimentary 15n values of 5 suggesting that nitrogen n2 fixation contributed little to the n nutrition of cariaco surface waters the most plausible explanation for the inferred glacial interglacial changes in n2 fixation in the cariaco is that they have occurred in response to variations in the n p ratio of the nutrient supply driven by changes in denitrification

sensitivity of the atlantic intertropical convergence zone to last glacial maximum boundary conditions 1 recent paleoproxy records suggest that the mean latitude of the atlantic intertropical convergence zone itcz varied synchronously with north atlantic climate over a range of timescales throughout the holocene and last glacial maximum we show that the present day meridional mode of atmosphere ocean variability in the tropical atlantic is a potentially useful model for understanding these paleoclimate changes the tropical atlantic in a coupled atmospheric general circulation and slab ocean model responds to last glacial maximum conditions with a southward displacement of the itcz this response arises primarily through the land ice sheet that forces increased north atlantic trades analogous to the forcing on the present day meridional mode changes to sea ice coverage and to ocean heat transport associated with a weakened atlantic thermohaline circulation also cause a meridional mode response though through different mechanisms our results highlight the potential for tropical atlantic paleoclimate to be driven from the high latitude influences in particular land ice on glacial interglacial timescales

suboxic trace metal geochemistry in the eastern tropical north pacific abstract we analyzed al ti fe mn cu ba cd u mo v and re in water column settling particulate and sediment 0 to 22 cm samples from the intense oxygen minimum zone omz of the eastern tropical north pacific near mazatlan mexico the goal was to determine how the geochemistry of these elements was influenced by suboxic water column conditions and whether the sediments have a unique suboxic geochemical signature the water column was characterized by a mn maximum reaching 8 nmol kg 1 at 400 m concentrations of cu ba cd mo re u and v were unaffected by the low o2 conditions and were comparable to those of the open ocean sinking particles were composed of lithogenic particles of detrital origin and nonlithogenic particles of biogenic origin al ti and fe were mostly at least 79 lithogenic about 75 of the mn was nonlithogenic significant amounts at least 58 of cu ba cd and mo were nonlithogenic sediment geochemistry varied across the continental shelf and slope cadmium u and re have prominent maxima centered at 310 m with 12 3 ppm 10 9 ppm and 68 3 ppb respectively at the core top high values of mo averaging 6 8 ppm and v averaging 90 ppm are seen in omz surface sediment additional down core enrichment occurs for all redox sensitive elements in the top 10 cm for u mo v and re surface sediments are a poor indicator of metal enrichment comparison of the nonlithogenic composition of sediments with sinking particles suggests that direct input of plankton material enriched in metals makes a significant contribution to the total composition especially for cd u and mo we evaluated re mo and cd u ratios as tracers for redox environments rhenium and mo concentrations and re mo ratios do not lead to consistent conclusions concurrent enrichments of re and mo are an indicator of an anoxic depositional environment in contrast high re mo ratios are an indicator of suboxic conditions cadmium is enriched in surface sediments while u has considerable down core enrichment the concentrations of cd and u and the cd u ratio do not follow patterns predicted from thermodynamics though the water column is suboxic these four redox sensitive elements indicate that the sediments are anoxic the implication for paleostudies is that a trace metal sediment signature that indicates anoxic conditions is not necessarily attributable to an anoxic water column

sea surface temperature changes in the northeastern pacific ocean during the past 20 000 years and their relationship to climate change in northwestern north america abstract modern ocean atmosphere interactions in the northeastern pacific ocean have a significant effect on the climate of the west coast of north america we present radiolarian microfossil based temperature reconstructions for the eastern north pacific spanning the past 20 000 yr to examine possible correlations and linkages between continental climate change and changes in sea surface temperature sst in the northeastern pacific ocean on millennial time scales the reconstructions indicate that the regional pattern of ocean circulation off the west coast of north america was further south 15 000 cal yr b p than it is today and reached its present location 13 000 cal yr b p the north pacific drift and transition zone were further south as a result of a more southerly north pacific high pressure cell prior to 13 000 cal yr b p while two continental paleoclimate records from northwestern north america show regional differences they also can be correlated to the sst changes a coastal site at 48 n shows similar patterns in summer temperatures as observed in offshore marine records of ssts however an inland continental record seems to reflect more regional scale changes in sea surface conditions showing a thermal maximum centered at 10 000 cal yr b p which is observed in the marine transect south of 42 n we conclude based on the pattern of oceanographic change as reflected in radiolarian assemblages that changes in the past latitudinal position of the north pacific drift played a significant role in controlling continental climate immediately to its east as it does in the present environment we also conclude that during the past 20 000 yr much of the evolution of oceanographic change is related to the migration of the atmospheric pressure cells the north pacific high and aleutian low of the northeastern pacific

glacial interglacial variability in the eastern tropical north pacific oxygen minimum zone recorded by redox sensitive trace metals 1 changes in the intensity of the oxygen minimum zone omz in the eastern tropical north pacific over the past 140 kyr are recorded as enrichments and depletions of redox sensitive metals in sediments of two piston cores one within and one below the modern omz from the continental margin off mazatlan mexico 22 41 n 106 28 w concentrations of al 7 7 0 6 ti 0 37 0 03 fe 3 1 0 25 mn 320 31 ppm and ba 560 82 ppm in core nh15p within the omz at 420 m water depth were relatively constant over the last 110 kyr in contrast concentrations of cd 4 8 2 ppm cu 29 8 9 1 ppm u 9 1 3 7 ppm mo 12 1 5 0 ppm v 138 2 51 9 ppm and re 45 8 25 5 ppb were all at least 30 higher in interglacial stages compared to glacial stages concentrations of al 7 4 0 3 ti 0 35 0 03 fe 3 5 0 4 and mn 385 77 ppm in core nh22p below the omz at 2025 m water depth were comparable to those in core nh15p while concentrations of ba 1662 292 ppm were about a factor of three higher in contrast concentrations of cd 0 9 0 3 ppm u 6 6 0 9 ppm mo 3 2 1 2 ppm v 81 8 10 1 ppm and re 25 4 12 ppb were lower in sediments of comparable age than the concentrations of these same metals in the omz core and the differences in their concentrations over glacial interglacial cycles were less pronounced than those in shallower core comparison of the nonlithogenic fraction of metals in the sediments with their estimated contribution from plankton suggests that organic matter is probably the major source of cu ba and perhaps cd to the sediment whereas the indirect effects of organic carbon and low bottom water oxygen concentrations on sediment redox state appear to be more important controls on the distributions u re mo and v changes in the depth at which re and mo precipitated in the sediments and in the re mo ratio suggest that the redox state of the surface sediment and overlying water at both core depths varied over time re and mo removal depths were shallower and re mo ratios were lower at the omz site than in deeper water suggesting that a more reducing environment prevailed over time at the shallower site although the redox state of the waters and sediment at both sites varied over glacial interglacial cycles the omz likely was never anoxic in the last 140 kyr this variability in redox state could be attributed to changes in regional export productivity changes in ocean circulation or a combination of both processes a paleoproductivity reconstruction from biogenic ba data suggests that glacial productivity was considerable lower than it was during interglacial stages model results suggest that the oxygen penetration depth an indicator of sediment redox state changed less than 1 cm as a result of the change in productivity changes in oxygen penetration depth estimated from re and u removal depths are significantly larger suggesting that changes in ventilation are a more important control on sediment redox state overall trace metal results confirm the tight coupling between ocean circulation marine productivity and global change

authigenic molybdenum formation in marine sediments a link to pore water sulfide in the santa barbara basin pore water and sediment mo concentrations were measured in a suite of multicores collected at four sites along the northeastern flank of the santa barbara basin to examine the connection between authigenic mo formation and pore water sulfide concentration only at the deepest site 580 m where pore water sulfide concentrations rise to 0 1 mm right below the sediment water interface was there active authigenic mo formation at shallower sites 550 430 and 340 m where pore water sulfide concentrations were consistently 0 05 mm mo precipitation was not occurring at the time of sampling a sulfide concentration of 0 1 mm appears to be a threshold for the onset of mo fe s co precipitation a second threshold sulfide concentration of 100 mm is required for mo precipitation without fe possibly as mo s or as particle bound mo mass budgets for mo were constructed by combining pore water and sediment results for mo with analyses of sediment trap material from santa barbara basin as well as sediment accumulation rates derived from 210 pb the calculations show that most of the authigenic mo in the sediment at the deepest site is supplied by diffusion from overlying bottom waters there is however a non lithogenic particulate mo associated with sinking particles that contributes 15 to the total authigenic mo accumulation analysis of sediment trap samples and supernant brine solutions indicates the presence of non lithogenic particulate mo a large fraction of which is easily remobilized and perhaps associated with mn oxides our observations show that even with the very high flux of organic carbon reaching the sediment of santa barbara basin active formation of sedimentary authigenic mo requires a bottom water oxygen concentration below 3 mm however small but measurable rates of authigenic mo accumulation were observed at sites where bottom water oxygen ranged between 5 and 23 mm indicating that the formation of authigenic mo occurred in the recent past but not at the time of sampling copyright 2000 elsevier science ltd

climatically related millennial scale fluctuations in strength of california margin oxygen minimum zone during the past 60 k y a strong oxygen minimum zone omz currently exists along the california margin because of a combination of high surface water productivity and poor intermediate water ventilation however the strength of this omz may have been sensitive to late quaternary ocean circulation and productivity changes along the margin although sediment lamination strength has been used to trace ocean oxygenation changes in the past oxygen levels on the open margin are not sufficiently low for laminations to form in these regions benthic foraminifera are highly sensitive monitors of omz strength and their fossil assemblages can be used to reconstruct past fluctuations benthic foraminiferal assemblages from ocean drilling program site 1017 off point conception exhibit major and rapid faunal oscillations in response to late quaternary millennial scale climate change dansgaard oeschger cycles on the open central california margin these faunal oscillations can be correlated to and are apparently synchronous with those reported from santa barbara basin together they represent major fluctuations in the strength of the omz which were intimately associated with global climate change weakening perhaps disappearing during cool periods and strengthening during warm periods these rapid major omz strength fluctuations were apparently widespread on the northeast pacific margin and must have influenced the evolution of margin biota and altered biogeochemicalmore cycles with potential feedbacks to global climate change less

nitrogen isotope and productivity variations along the northeast pacific margin over the last 120 kyr surface and subsurface paleoceanography 1 glacial interglacial changes in sedimentary 15n over the last 120 kyr display a remarkably similar pattern in timing and amplitude in core records extending from the denitrification zone in the eastern tropical north pacific etnp where subsurface denitrification is active to the oregon margin where no denitrification occurs today low 15n values 4 6 generally characterize glacial stages 2 and 4 and higher 15n values 7 10 are representative of the holocene millennial scale periods within stage 3 and stage 5 the inferred synchroneity of 15n variations along the entire margin implies that the nitrate isotopic signal produced in the oxygen poor subsurface waters in the etnp is rapidly advected northward and recorded at sites far beyond the boundaries of the modern denitrification zone similar to 15n primary production indicators percent corg ba al and percent opal show glacial interglacial as well as millennial scale variations along the ne pacific margin with higher primary production during warm periods however the relative phasing between 15n and paleoproduction tracers within individual records changes latitudinally whereas 15n and primary production vary approximately synchronously in the midlatitudes production lags 15n in the etnp by several kiloyears this lag calls for a new understanding of the processes driving denitrification in the etnp we suggest that oxygen input by the equatorial undercurrent as well as local organic matter flux controls denitrification rates in the etnp moreover the differences in relative timing point to a time transgressive development of upwelling favorable winds along the ne pacific margin after the last glaciation with those in the north developing several kiloyears earlier

the geochemistry of redox sensitive trace metals in sediments abstract we analyzed the redox sensitive elements v mo u re and cd in surface sediments from the northwest african margin the u s northwest margin and the arabian sea to determine their response under a range of redox conditions where oxygen penetrates 1 cm or less into the sediments mo and v diffuse to the overlying water as mn is reduced and remobilized authigenic enrichments of u re and cd are evident under these redox conditions with the onset of sulfate reduction all of the metals accumulate authigenically with re being by far the most enriched general trends in authigenic metal accumulation are described by calculating authigenic fluxes for the 3 main redox regimes oxic reducing where oxygen penetrates 1 cm and anoxic conditions using a simple diagenesis model and global estimates of organic carbon rain rate and bottom water oxygen concentrations we calculate the area of sediments below 1000 m water depth in which oxygen penetration is 1 cm to be 4 of the ocean floor we conclude that sediments where oxygen penetrates 1 cm release mn v and mo to seawater at rates of 140 260 60 150 and 5 10 of their respective riverine fluxes using the authigenic metal concentrations and accumulation rates from this work and other literature these sediments are sinks for re cd and u with burial fluxes of 70 140 30 80 and 20 40 respectively of their dissolved riverine inputs we modeled the sensitivity of the response of seawater re cd and v concentrations to changes in the area of reducing sediments where oxygen penetrates 1 cm our analysis suggests a negligible change in seawater re concentration whereas seawater concentrations of cd and v could have decreased and increased respectively by 5 10 over 20 kyr if the area of reducing sediments increased by a factor of 2 and by 10 20 if the area increased by a factor of 3 the concentration variations for a factor of 2 increase in the area of reducing sediments are at about the level of uncertainty of cd ca and v ca ratios observed in foraminifera shells over the last 40 kyr this implies that the area of reducing sediments in the ocean deeper than 1000 m 4 has not been greater than twice the present value in the recent past

el nino like pattern in ice age tropical pacific sea surface temperature sea surface temperatures ssts in the cold tongue of the eastern equatorial pacific exert powerful controls on global atmospheric circulation patterns we examined climate variability in this region from the last glacial maximum lgm to the present using a sst record reconstructed from magnesium calcium ratios in foraminifera from sea floor sediments near the galapagos islands cold tongue sst varied coherently with precession induced changes in seasonality during the past 30 000 years observed lgm cooling of just 1 2 c implies a relaxation of tropical temperature gradients weakened hadley and walker circulation southward shift of the intertropical convergence zone and a persistent el nino like pattern in the tropical pacific this is contrasted with mid holocene cooling suggestive of a la nina like pattern with enhanced sst gradients and strengthened trade winds our results support a potent role for altered tropical pacific sst gradients in global climate variations

origin of xenocrystic garnet and kyanite in clinopyroxene hornblende bearing adakitic meta tonalites from cape hinode prince olav coast east antarctica

is pore water oxygen content decoupled from productivity on the california margin trace element results from ocean drilling program hole 1017e san lucia slope california 1 trace element evidence from the california margin ocean drilling program hole 1017e shows significant changes in sediment redox chemistry at intermediate water depths over the last 60 kyr the influence of export production on intermediate water oxygen content can be distinguished from lateral ventilation through comparisons among proxies representing export production flux percent corg and sediment surface i br and pore water mo ag cd re and u oxygenation proxies sulfate reduction within the uppermost sediment column occurred during late quaternary interstadials and the holocene indicating reduced intermediate water ventilation however sulfate reduction was most intense during major interstadials when productivity was enhanced decoupling between export production and pore water oxygen content is demonstrated during deglaciation when the sediment pore water oxygen content increases without a corresponding reduction in export productivity thus both export production and intermediate water ventilation play a role in oxygen minimum zone processes on the california margin

paleoproductivity and carbon burial across the california current the multitracers transect 42 n the multitracers experiment studied a transect of water column sediment trap and sediment data taken across the california current to develop quantitative methods for hindcasting paleoproductivity the experiment used three sediment trap moorings located 120 km 270 km and 630 km from shore at the oregon california border in north america we report here about the sedimentation and burial of particulate organic carbon corg and caco3 in order to observe how the integrated caco3 and corg burial across the transect has changed since the last glacial maximum we have correlated core from the three sites using time scales constrained by both radiocarbon and oxygen isotopes by comparing surface sediments to a two and a half year sediment trap record we have also defined the modern preservation rates for many of the labile sedimentary materials our analysis of the corg data indicates that significant amounts 20 40 of the total corg being buried today in surface sediments is terrestrial at the last glacial maximum the terrestrial corg fraction within 300 km of the coast was about twice as large such large fluxes of terrestrial corg obscure the marine corg record which can be interpreted as productivity when we corrected for the terrestrial organic matter we found that the mass accumulation rate of marine corg roughly doubled from the glacial maximum to the present because preservation rates of organic carbon are high in the high sedimentation rate cores corrections for degradation are straightforward and we can be confident that organic carbon rain rate new productivity also doubled as confirmation the highest burial fluxes of other biogenic components opal and ba also occur in the holocene productivity off oregon has thus increased dramatically since the last glacial maximum caco3 fluxes also changed radically through the deglaciation however they are linked not to caco3 production but rather to changes in deepwater carbonate chemistry between 18 ka and now

determining the influences of late quaternary ventilation and productivity variations on santa barbara basin sedimentary oxygenation a multi proxy approach abstract a correlation between warm interstadials implied by 18oice in the gisp greenland ice core and anoxic events recorded by the sediments drilled at odp site 893 in santa barbara basin sbb has been used previously to relate variations in bottom water oxygenation to high frequency changes in the ventilation of the sbb nature 379 1996 243 however an additional control on the oxygen content at depth is the local settling flux of metabolizable organic matter to assess the impact of oxygen consumption related to this source mo cd re and u concentration data are used here in conjunction with corg and 15n to deduce past redox conditions variations in the sedimentary redox boundary depth and the impact of local organic flux on the oxygenation of sbb deep waters comparisons between odp sites 893 1017 and 1019 allow the differentiation of regional signals dominated by ventilation changes from local signals dominated by vertical organic flux it is concluded that prior to the holocene local productivity changes in the santa barbara basin are not solely the cause of sedimentary anoxia episodic injections of low oxygen intermediate water identified on the regional scale strongly influenced the oxygen content of the sbb during this time however over the last 10 000 years the influence of local productivity has increased and the regional similarity among the three sites is complicated by local signals

synchronous radiocarbon and climate shifts during the last deglaciation radiocarbon data from the cariaco basin provide calibration of the carbon 14 time scale across the period of deglaciation 15 000 to 10 000 years ago with resolution available previously only from holocene tree rings reconstructed changes in atmospheric carbon 14 are larger than previously thought with the largest change occurring simultaneously with the sudden climatic cooling of the younger dryas event carbon 14 and published beryllium 10 data together suggest that concurrent climate and carbon 14 changes were predominantly the result of abrupt shifts in deep ocean ventilation

mesoscale surveys over the shelf and slope in the upwelling region near point arena california repeated mesoscale surveys of a 40 km wide 100 km long coastal region near point arena california were conducted during the upwelling season april august in 1981 and 1982 each survey included conventional conductivity temperature depth casts at standard locations over the continental shelf and slope between 38 n and 39 10 n and continuous operation of a doppler acoustic log to obtain velocity profiles in the 20 to 150 m depth range synoptic surveys covered the entire grid in 2 3 days winds were strongly favorable for upwelling during the three 1981 surveys and were weak or variable during the three 1982 surveys surface temperature and salinity fields reflect the influence of both the seasonal winds and day to day variations in the wind persistently low surface salinities offshore reflect the general southward advection of subarctic waters and sporadic low salinities over the inner shelf reflect north ward advection of local runoff through an intermittent narrow countercurrent along the coast circulation patterns during all but one of the surveys were very complex and included meandering equatorward flow cyclonic and anticyclonic eddies and inshore countercurrents the simple two dimensional equatorward baroclinic coastal jet usually associated with coastal upwelling was observed during only one of our surveys overall average fields are relatively simple they show broad equatorward surface flow a very weak inshore countercurrent and a definite poleward undercurrent at the shelf break average temperature salinity and density fields are generally congruent with the average flow pattern average isotherms and isohalines are not strictly parallel to the coastline south of the coastline bend at point arena they diverge gradually from the coast comparison of average sections calculated from 10 matched pairs of central and arena lines separated by 50 km shows there are systematic differences between them warmer fresher waters lie nearer shore and in shallower water off point arena than on the central line this suggests that the surface waters flowing past point arena have sufficient southward momentum to cross isobaths comparison of average velocity sections on these two lines shows some differences in structure since the variability is large these may not be significant comparison of the measured and geostrophic average shears suggests there is a significant ageostrophic component in the upper layers above 40 m it may be the signature of an average wind driven ekman spiral

synchroneity of tropical and high latitude atlantic temperatures over the last glacial termination a high resolution western tropical atlantic sea surface temperature sst record from the cariaco basin on the northern venezuelan shelf based on mg ca values in surface dwelling planktonic foraminifera reveals that changes in sst over the last glacial termination are synchronous within 30 to 90 years with the greenland ice sheet project 2 air temperature proxy record and atmospheric methane record the most prominent deglacial event in the cariaco record occurred during the younger dryas time interval when ssts dropped by 3 to 4 c a rapid southward shift in the atmospheric intertropical convergence zone could account for the synchroneity of tropical temperature atmospheric methane and high latitude changes during the younger dryas