quantifying climatic change through the last glacial interglacial transition based on lake isotope palaeohydrology from central turkey questions remain as to the nature of climatic change through the last glacial interglacial transition in the eastern mediterranean region particularly the relative contribution of evaporation and precipitation to regional water balance here changes in oxygen isotope values through this time period from eski acigol a crater lake in central turkey are investigated using hydrological and isotope mass balance models these allow changes in evaporation and precipitation to be quantified and their relative importance evaluated we show that it is the volumetric flux rate of water passing through the lake system and not the precipitation to evaporation ratio per se which controlled the stable isotope record in eski acigol early holocene precipitation is shown to be much greater than that during both the latter part of the last glaciation and the present day we test these calculated values against other records in the same region firstly with other lake records in anatolia the konya basin and lake van and secondly with isotope inferred palaeo precipitation data from soreq cave in israel this reveals a contrast between pre and post lgm precipitation values in turkey wetter and drier respectively and also suggests that during the last glacial interglacial transition there was a more marked precipitation gradient than at present between northern interior and southern coastal parts of the eastern mediterranean region

stable isotope records of late quaternary climate and hydrology from mediterranean lakes the isomed synthesis lake isotope records can be used to assess the spatial coherency of late quaternary climate change across the circum mediterranean region we place modern and palaeo data within a simple conceptual lake response model to show that the isotope hydrology of most mediterranean lakes has been influenced strongly by water balance even in those systems that are chemically dilute i e freshwater 18o data on biogenic and endogenic carbonates from 24 lake basins are used to reconstruct multi millennial scale trends since the lgm while it is difficult to make direct comparisons between lake records in terms of single climatic parameters coherent regional isotopic trends can be identified during glacial times mediterranean lakes deposited carbonates isotopically heavier in 18o compared to the holocene partly due to source area effects isotopic enrichment was most marked during intervals corresponding to the h1 and younger dryas events confirming that late pleistocene cold stages in the north atlantic region were marked by aridity around much of the mediterranean almost all mediterranean lake records shifted to more depleted isotopic values during the last glacial interglacial transition lgit this shift is the reverse of the trend which characterised the same transition in lakes from northern and central europe and suggests that temperature changes were not an important direct driver of mediterranean lake isotopic records over glacial interglacial timescales in the early holocene many lakes in the eastern part of the region were more depleted isotopically than in recent millennia this corresponds with marine sapropel formation both chronologically and geographically and implies that increases in local rainfall contributed significantly to the creation of a freshwater lid and anoxia in the east mediterranean sea in contrast no such pattern is currently apparent from lake isotope records from the west mediterranean suggesting a possible nw se contrast in climate history during the holocene

the j m platinum palladium reef of the stillwater complex montana ii origin by double diffusive convective magma mixing and implications for the bushveld complex sequences of cumulates form concurrently by downdip accretion from a column of liquid layers that are primarily separated by diffusive interfaces the low cumulates grow in advance of the upper cumulates in accord with their higher crystallization temperatures an important observation is that mixing of the two parent liquids lowers their crystallization temperatures and consequently should produce unsaturated hybrids that could dissolve earlier cumulates the repetition of cyclic units above the j m reef is explained by having periodic additional injections of dense magma beneath the subsiding column of crystallizing liquid layers neither the j m reef nor the bushveld ore zones should ever have been continuous across the floor of their respective magma chambers and for bushveld the circumstances resulted in zones that are actually minable modified journal abstract

metamorphism of the witwatersrand gold fields conditions during peak metamorphism pelitic assemblages from all major witwatersrand gold fields record metamorphic conditions of the greenschist facies with minimal regional grade changes over at least 200 km strike length diagnostic metamorphic assemblages are less common in the volumetrically dominant quartzites the actively exploited auriferous conglomerates and some of the regionally persistent metapelitic horizons bulk rock composition has been a major control on assemblage development key metapelitic assemblages include pyrophyllite chloritoid chlorite and muscovite in each gold field with less common metamorphic biotite accessory minerals are pyrite tourmaline rutile and zircon the abundance of chloritoid and pyrophyllite in thin shaly units together with their minor but widespread distribution in quartzites and conglomerates indicate that metamorphic temperatures reached 350 c 50 c in all the gold fields pressures are less well constrained 1 2 kbar being inferred outside the gold fields higher grades are indicated by andalusite and kyanite near granitoid domes and later intrusions the temperatures during peak metamorphism and the abundance of pyrite provide ideal conditions to re mobilize gold and may explain its secondary textural features

sea ice and north atlantic climate response to co2 induced warming and cooling conditions using a global climate model coupled with an ocean and a sea ice model we compare the effects of doubling co 2 and halving co 2 on sea ice cover and connections with the atmosphere and ocean an overall warming in the 2 x co 2 experiment causes reduction of sea ice extent by 15 with maximum decrease in summer and autumn consistent with observed seasonal sea ice changes the intensification of the northern hemisphere circulation is reflected in the positive phase of the arctic oscillation ao associated with higher than normal surface pressure south of about 50 n and lower than normal surface pressure over the high northern latitudes strengthening the polar cell causes enhancement of westerlies around the arctic perimeter during winter cooling in the 0 5 co 2 experiment leads to thicker and more extensive sea ice in the southern hemisphere the increase in ice covered area 28 dominates the ice thickness increase 5 due to open ocean to the north in the northern hemisphere sea ice cover increases by only 8 due to the enclosed land sea configuration but sea ice becomes much thicker 108 substantial weakening of the polar cell due to increase in sea level pressure over polar latitudes leads to a negative trend of the winter ao index the model reproduces large year to year variability under both cooling and warming conditions

relationships between the vredefort structure and the witwatersrand basin within the tectonic framework of the kaapvaal craton as interpreted from regional gravity and aeromagnetic data abstract processed gravity and aeromagnetic data covering the witwatersrand basin and adjacent areas have been used to delineate the boundary of the basin and to investigate other features such as the vredefort structure the bethlehem gravity high and the colesberg magnetic anomaly trend a model is proposed in which the regional aeromagnetic and gravity signatures of these features can be related to the disposition of a semi continuous mid crustal magnetite rich layer which is exposed or has a shallow suboutcrop in three regions in the centre of the vredefort structure along the kaapvaal craton boundary and centrally through the craton northwards from colesberg the bethlehem high is thought to be due to elevation of lower levels of the crust along a nw trending geanticlinal arch the apex of this broad arch is termed the vredefort axis and plunges northwestwards beneath the witwatersrand basin the vredefort structure lies at the intersection of this axis and a major nne trending axis of crustal downwarp which also constitutes the long axis of the witwatersrand basin two contrasting scenarios for the development of these major axes are discussed with either scenario genesis of the vredefort structure should be integrated with the genesis and evolution of the vredefort axis and with the tectonic evolution of the kaapvaal craton

nickel copper and platinum mineralization in the lower zone of the bushveld complex south of potgietersrus the lower zone of the potgietersrus limb of the bushveld complex consists of a succession of ultramafic rocks at least 1 600 m thick that can be subdivided into 37 cyclic units ni cu and pt mineralization is developed at two levels in the sequence namely a zone of mineralization within the volspruit pyroxenite subzone and mineralization associated with the chromitite layers of the drummondlea harzburgite chromitite subzone of the two the mineralization in the volspruit subzone is more significant in that values over the basal 6 m of the mineralized zone are on the order of 0 27 percent ni 0 19 percent cu 3 09 ppm pt and 2 56 ppm pd the composition of the coexisting silicates suggests that separation of an immiscible sulfide liquid was brought about by a drop in temperature of the magma possibly caused by the emplacement of less primitive cooler magma that mixed with the residual crystallizing lower zone magma in the drummondlea subzone sulfide mineralization is developed within the upper parts of the chromitite layers and the overlying olivine rich rocks in this case separation of sulfide liquid evidently took place in response to the crystallization of large quantities of chromite as a result of which the feo content of the magma was lowered as well as its sulfur carrying capacity

oxygen isotopic composition of the mediterranean sea since the last glacial maximum constraints from pore water analyses abstract interstitial waters recovered from ocean drilling program leg 161 site 976 in the western mediterranean sea are used in conjunction with a numerical model to constrain the 18o of seawater in the basin since the last glacial maximum including sapropel event 1 to resolve the oxygen isotopic composition of the deep mediterranean we use a model that couples fluid diffusion with advective transport thus producing a profile of seawater 18o variability that is unaffected by glacial interglacial variations in marine temperature comparing our reconstructed seawater 18o to recent determinations of 1 0 for the mean ocean change in glacial interglacial 18o due to the expansion of global ice volume we calculate an additional 0 2 increase in mediterranean 18o caused by local evaporative enrichment this estimate of 18o change due to salinity variability is smaller than previous studies have proposed and demonstrates that mediterranean records of foraminiferal calcite 18o from the last glacial period include a strong temperature component paleotemperatures determined in combination with a stacked record of foraminiferal calcite depict almost 9 c of regional cooling for the last glacial maximum model results suggest a decrease of 1 1 in seawater 18o relative to the modern value caused by increased freshwater input and reduced salinity accompanying the formation of the most recent sapropel the results additionally indicate the existence of isotopically light water circulating down to bottom water depths at least in the western mediterranean supporting the existence of an anti estuarine thermohaline circulation pattern during sapropel event 1

the geology and gravity field in the central core of the vredefort structure the centre of the vredefort structure in south africa comprises an uplifted granitic basement with an associated 300 g u gravity high ringed by upturned sedimentary strata detailed geological mapping of the basement core has delineated a three fold concentric zoning of outer granite gneisses ogg steynskraal formation sf and inlandsee leucogranofels ilg an increase in metamorphic grade occurs toward the centre of the structure from greenschist relics on the basement perimeter to upper amphibolite and granulite facies in the sf and granulite facies in the ilg a marked lithological change occurs within the sf in which perimeter greenschists and inner amphibolites give way to paragneisses in the ilg paragneiss and mafic granulite relics predominate these divisions are consistent with the standing on edge model for the basement 1 three regional metamorphic episodes and two thermal events have been recognised m1 and m3 both attained granulite facies at low medium load pressures in the ilg m1 granulite facies assemblages extended into the ogg but the m3 facies was restricted to the ilg m2 was a k metasomatism event limited to the ogg an extensive thermal episode m4a is provisionally correlated with the collar metamorphism pyroxene hornfels facies t 800 c was attained in the centre as opposed to conditions of p 4 5 kbar and t 650 c for alkali granite stocks in the sedimentary collar 2 this event was thus pre or syn uplift but not post uplift a high level high temperature p 3 kbar and t 800 900 c event m4b occurred at a late stage in the overall sequence a suite of amphibole orthopyroxene rocks of basaltic komatiite type cao al2o3 1 are chemically related to younger high mg tholeiites these tholeiites are correlated with similar rocks in the sedimentary collar and were intruded syn to post m4a in several episodes of decreasing basicity shock metamorphic features granitic breccias and pseudotachylite are linked to the late stage history of the structure and a case is presented for a dynamic metamorphic front advancing outward and upward from the centre in response to unroofing of the basement the central gravity high3 is delineated by 1239 new gravity stations at 1 km and 0 5 km intervals a low frequency oval shaped anomaly with a long axis trending nw se has eccentrically positioned on it a plateau extending southwards as a spur a dyke is responsible for the spur but the source for the plateau is from a recent borehole thought to be largely due to sheared altered harzburgite modelling of the low frequency gravity field component was based on the mapped divisions of the ogg sf and ilg and a density contrast of 200 kg m3 was determined between the ogg and the sf and ilg lithologies a purely crustal solution for the excess mass distribution in the basement is conclusively demonstrated

orbital imprint on holocene palaeohydrological variations in west central europe as reflected by lake level changes at cerin jura mountains eastern france this paper presents a lake level record for the holocene at lake cerin jura mountains eastern france it is based on a range of sedimentological techniques validated in previous studies with a combination of systematic lithostratigraphic investigations of the infillings accumulated in the lacustrine basin and sediment analyses of two selected cores the chronology is based on 10 radiocarbon dates and pollen stratigraphy on a millennial scale the cerin lake level record shows three distinct successive phases characterised by higher lake level conditions until ca 9000 cal a bp followed by a maximal lowering at ca 9000 8500 cal a bp and a progressive rise until the present this rise was punctuated by centennial scale fluctuations with major events around 4000 2800 and after 1500 cal a bp considered on a multimillennial scale the general pattern of palaeohydrological changes reconstructed at cerin reflects the impact of orbitally driven summer insolation this is in agreement with other regional and extra regional palaeoclimatic records although every record shows peculiarities in timing and shape depending on the proxy used for reconstruction in this general context centennial to multicentennial oscillations appear to have been second order events in comparison with the major influence of the orbital factor copyright 2011 john wiley sons ltd

metamorphism of the witwatersrand gold fields a review abstract there is widespread evidence for greenschist facies metamorphism in different rock types within all the witwatersrand gold mines the silicate mineral assemblages suggest near uniform peak metamorphic conditions equivalent to the chlorite zone in all the major witwatersrand gold fields assemblages of coexisting pyrophyllite chloritoid have been recorded in most of the gold mines and the critical assemblage of pyrophyllite chloritoid muscovite chlorite quartz tourmaline rutile pyrite is found in most gold fields kaolinite paragonite biotite pyrrhotite and arsenopyrite have more local distribution pelites shales quartzites meta conglomerates metabasalts and some dykes record these metamorphic assemblages albeit in different mineral proportions and pyrophyllite and chloritoid are recorded from many gold producing reefs andalusite kyanite garnet and or cordierite bearing assemblages indicate higher metamorphic grades in three discrete areas along the nw margin of the witwatersrand basin to the ne of the evander gold field and around the collar of the vredefort dome concentric metamorphic facies around the vredefort dome culminate in granulite facies assemblages near the centre it is important to note that there are no definitive published data constraining the temporal relationships between the granulites and amphibolites of the vredefort dome greenschist facies assemblages in the vredefort collar rocks thermal metamorphism related to intrusion of the bushveld complex and the regional greenschist facies metamorphism documented in the gold fields metamorphic conditions of 350 50 c and up to 3 kbars are inferred for the gold fields with temperatures increasing to around 700 c in granulites of the vredefort dome other geothermometric methods including illite crystallinity fluid inclusions carbon elemental ratios and vitrinite reflectance are compatible with the above estimates but are each associated with considerable temperature uncertainties fluids in equilibrium with pyrophyllite muscovite quartz pyrite paragonite are inferred during metamorphism suggesting slightly acid conditions and elevated sulphur activities regional greenschist facies metamorphism documented in the witwatersrand gold mines was accompanied by widespread deformation large fluxes of aqueous fluid and considerable element mobility the low intermediate pressure of this metamorphic terrain and the lack of large scale tectonic thickening favours underplating by mafic magmas as the likely cause of the metamorphic pattern no model for gold genesis in the witwatersrand basin is complete without accommodating post burial processes including metamorphism deformation and alteration any placer gold would be overprinted by these processes and any epigenetic gold could potentially be introduced during these periods of thermal and fluid activity it is also important to note at least two quite unusual features of the witwatersrand metamorphic assemblages the virtual absence of feldspar from the 3 km thick central rand group over 300 km and the narrow range of metamorphic grade inferred for the gold mines over this same distance

holocene and late pleistocene climate in the sub mediterranean continental environment a speleothem record from poleva cave southern carpathians romania the pp10 stalagmite from poleva cave provides a late pleistocene and holocene isotopic record characteristic for the sw of romania a sub mediterranean climatic region the speleothem was dated by eight tims and one alpha u series dates which showed that it was precipitated between 75 ka and 2 ka with at least two hiatuses the basal sector of the stalagmite showed a slow growing regime of 0 26 cm ka while the upper one grew relatively fast with about 5 cm ka the temporal resolution for the isotopic sampling is thus 2 ka sample for the lower sector and 150 years sample for the upper one the relationship between 18 o and temperature was found positive the isotopic record of the lower sector shows two marked cold intervals during 67 and 58 ka and 40 35 ka respectively which correlate well with the villars and soreq records the upper sector record is so far the most detailed holocene isotopic record in romania and the only one available for the regions located at the exterior of the carpathians range the signal shows a gradual warming after the gs1 event punctuated by several cold events at 8 7 2 and 4 2 ka and also by warm oscillations centered at about 5 2 and 3 3 ka the results seem to indicate that if the north atlantic firstorder signals may extend well to the south eastern europe their amplitude and general trend may be diminished by the interferences with the mediterranean circulation

field relations and strontium isotope systematics of the marginal rocks of the eastern bushveld complex the well exposed basal contact of the eastern bushveld complex was mapped at scales of 1 10 000 and 1 20 000 along 130 km of strike and through a 9 km vertical section field relations petrography and geochemistry of the marginal rocks and associated sills have aided their subdivision into two main groups a broadly pyroxenitic group rims the complex from its base to the top of the pyroxenitic subzone of the critical zone a gabbroic group occurs above this level each group consists of a number of closely related rock types most of which have sill analogs rocks of the first group b1 include pyroxenites norites and peridotites all of which may have quench textures all contain orthopyroxene en 78 plagioclase an 65 and chromite with subordinate clinopyroxene and biotite rare earth element patterns are mostly strongly fractionated ce n yb n approximately 10 and have 40x chondritic abundances at ce their initial strontium isotope ratios at 2 05 b y fall in the range 0 7032 to 0 7057 and rb sr ratios approximate 0 2 the gabbroic group consists of microcrystalline two pyroxene gabbros b2n and b3n and their coarser grained equivalents b2 and b3 that border the upper critical and main zones respectively mineral assemblages are dominated by plagioclase approximately an 55 clinopyroxene and orthopyroxene approximately en 63 with abundant magnetite and traces of ilmenite and biotite their rare earth element patterns are less fractionated than b1 rocks the b2n and b2 family have ce n yb n approximately 6 and 30x chondritic abundances at ce the b3n and b3 rocks have ce n yb n approximately 3 6x chondritic abundances at ce and pronounced positive eu anomalies strontium isotope initial ratios at 2 05 b y fall in the range 0 706 to 0 708 and the rb sr ratios are approximately 0 02 whole rock and sr isotope compositions of the peridotitc sills can be successfully simulated by a model involving olivine fractionation from a liquid with an initial sr isotope ratio r 0 similar to that of the transition zone 0 7056 a fraction of such liquid enriched in cumulus olivine crystals when mixed with up to 30 percent of a pyroxenitic liquid with low r 0 0 7034 yields a product having the isotopic and compositional characteristics of the peridotite sills a continuum exists in the initial sr ratios through the pyroxenitic and gabbroic marginal rocks suggesting that these represent mixtures of at least two sources with distinct initial sr isotope ratio characteristics it is argued that neither magma aging nor crustal contamination adequately accounts for the sr isotope characteristics of the marginal rocks or their derived cumulates the unusual chemistry of the pyroxenitic early liquids sio 2 approximately 55 mgo approximately 13 coupled with high concentrations of incompatible elements should be considered primary

eastern mediterranean hydroclimate over the late glacial and holocene reconstructed from the sediments of nar lake central turkey using stable isotopes and carbonate mineralogy there is a lack of high resolution records of hydroclimate variability in the eastern mediterranean from the late glacial and early holocene more knowledge of the speed of climate shifts and the degree to which they were synchronous with changes in the north atlantic or elsewhere is required to understand better the controls on eastern mediterranean climate using endogenic carbonate from a sediment sequence from nar golu a maar lake in central turkey dated by varve counting and uranium thorium methods we present high resolution 25 years oxygen 18o and carbon isotope records supported by carbonate mineralogy data spanning the late glacial and holocene 18ocarbonate at nar golu has been shown previously to be a strong proxy for regional water balance after a dry period i e evaporation far exceeding precipitation in the younger dryas the data show a transition into the relatively wetter early holocene in the early holocene there are two drier periods that appear to peak at 9 3 ka and 8 2 ka coincident with cooling events seen in north atlantic records after this and as seen in other records from the eastern mediterranean there is a millennial scale drying trend through the mid holocene transition the relatively dry late holocene is punctuated by centennial scale drought intervals at the times of 4 2 ka event and late bronze age societal collapse overall we show that central turkey is drier when the north atlantic is cooler throughout this record and at multiple timescales thought to be due to a weakening of the westerly storm track resulting from reduced cyclogenesis in the north atlantic however some features such as the mid holocene transition and the fact the early holocene dry episodes at nar golu are of a longer duration than the more discrete events seen in north atlantic records imply there are additional controls on eastern mediterranean hydroclimate

systematics of modal phenocryst assemblages in submarine basalts petrologic implications phenocryst assemblages in ocean ridge basalts generally show an increasing proportion of plagioclase as the total amount of phenocrysts increases the variations in phase assemblages as well as most crystal liquid kd s are similar to variations equimodal trends predicted by low pressure laboratory experiments suggesting that many of these basalts have experienced varying degrees of low pressure cyrstallization prior to quenching with little sorting of crystals and liquid important exceptions include moderately to highly phyric basalts enriched either in plagioclase or olivine which lie well off the experimental trends in these basalts megacrysts and xenocrysts usually cited as evidence for magma mixing commonly represent a small proportion of the total crystalline phase assemblage however phase proportions for many of these basalts lie well outside the range that could be produced by simple mixing selective gravitative sorting either prior or subsequent to mixing appears to be the likely explanation for these phyric basalts a relation between spreading rate and phase proportions is neither supported nor refuted by the data which as yet do not adequately represent fast spreading ridges

microscopic planar deformation features in quartz of the vredefort structure anomalous but still suggestive of an impact origin abstract the orientation and distribution of diagnostic shock produced planar features in quartz has been examined in over 80 samples from both the core and collar rocks of the vredefort structure in south africa these features are widespread occurring in all but four samples the majority of the planar features have a basal 0001 orientation with a few higher pressure so called features and three features occurring near the center of the structure their relative distribution and preservation are however anomalous compared to those at other large terrestrial impact structures and recorded shock pressures calculated on the basis of planar feature orientation do not show a regular decrease radially outward as observed at other known impact structures the apparently anomalous development of planar features is interpreted as a result of post shock recrystallization if the effect of recrystallization of quartz which generally increases inward toward the core of the structure is considered and only the highest pressure type planar feature present in any one sample is taken as a measure of shock pressure then higher pressures are recorded in the core compared to the collar rocks no evidence of a previously reported additional post recrystallization shock event is found in this study although previous researchers report that pseudotachylite which may or may not be associated with the shock event cuts recrystallized quartzites in is concluded that although anomalous the evidence from planar features in quartz is still consistent with the vredefort structure being an erosional remnant of a large complex impact structure

ecological thresholds and patterns of millennial scale climate variability the response of vegetation in greece during the last glacial period the regional expression of millennial scale climate variability during the last glacial is examined with particular reference to the vegetation response in greece inspection of three pollen records from contrasting bioclimatic areas suggests that differences in the magnitude of cold events as recognized in the north atlantic and western mediterranean are expressed in terms of tree population changes only in areas with a range of favorable habitats by contrast records from sites where populations approach their tolerance threshold do not appear to resolve differences in the amplitude of the climate oscillations understanding the importance of local factors in modulating the biological response to climate change is critical when attempting to establish the spatial pattern of millennial variability

late postglacial paleoenvironmental change in the northeastern mediterranean region combined palynological and molecular biomarker evidence three gravity cores collected from the ne mediterranean nemr across a transect from the northern aegean sea north skyros basin to the south cretan margin scm were investigated for pollen and terrestrial biomarkers derived from epicuticular waxes of vascular plants during the last 20 ky pollen data show diversified mixed temperate forest in the northern borderlands and enhanced mediterranean vegetation in the southern areas documenting an n s climatic trend terrestrial plant biomarkers and their diagnostic geochemical indices exhibit latitudinal patterns which are interpreted in terms of the different delivery pathways fluvial runoff vs atmospheric transport resulting from the climate conditions during different periods during the late glacial and early deglaciation periods 20 14 ka bp relatively increased humidity h index is recorded in the north aegean sea while in the south drier climate was the limiting factor for vegetation development during this interval terrestrial n alkanes showed increased accumulation rates suggesting massive transport of terrestrial organic matter through runoffs and rivers followed by weaker input after 14 ka bp after 11 ka bp a major expansion of forest cover is evidenced in the nemr accompanied by a higher h index because of the climatic amelioration the forest vegetation exhibited regionally different characteristics with cool temperate taxa being more abundant in the aegean cores while the scm record is being featured by mediterranean elements at the onset of the holocene and throughout the holocene climatic optimum the delivery of terrestrial biomarkers increased and became more significant in the aegean sites compared to the scm site within the holocene the average chain length acl of long chain n alkanes exhibits lower values in the northern aegean than in the southeastern aegean and scm indicating the predominance of warmer species southwards finally the h index records a conspicuous humidity increase between 5 4 and 4 3 ka bp in the south aegean that coincides with an increase in the terrestrial biomarker supply and the deposition of a distinct sapropel like layer smh sapropel mid holocene similar trends in t temperature and h indices are slightly delayed and attenuated in the northern aegean and are accompanied by an increase in the acl index a noticeable increase in the accumulation rates ars of terrestrial biomarkers and the hpa index values during this period are clearly recorded in all three cores indicative of enhanced terrigenous inputs of organic matter along with higher in situ preservation

climate dynamics in the borderlands of the aegean sea during formation of sapropel s1 deduced from a marine pollen record abstract to unravel the climatic and environmental dynamics in the borderlands of the aegean sea during the early and middle holocene and notably for the interval of sapropel s1 s1 formation we have analysed terrestrial palynomorphs from a marine core in the northern aegean sea the qualitative results were complemented by quantitative pollen based climate reconstructions a land sea correlation was established based on pollen data and sediment lightness measurements from the same core and previously published benthic foraminifer data from a nearby core the borderlands of the aegean sea underwent a transition from an open vegetation to oak dominated woodlands between 10 4 and 9 5 ka cal bp a coeval increase in winter precipitation suggests that moisture availability was the main factor controlling holocene reforestation the 50 higher winter precipitation during s1 formation relative to pre sapropelic conditions suggests a strong contribution from the borderlands of the aegean sea to the freshwater surplus during s1 formation the humid and mild winter conditions during s1 formation were repeatedly punctuated by short term climatic events that caused a partial deforestation and a reorganisation within the broad leaved arboreal vegetation in the marine realm these events are documented by improved benthic oxygenation the strongest event represents the regional expression of the 8 2 ka cold event and led to an interruption in s1 formation except for the interval of s1 formation the pollen derived winter temperatures correlate with the smoothed gisp2 k series they support the previously published marine based concept that the intensity of the siberian high strongly controlled the winter climate in the aegean region during s1 formation in the aegean sea however climate conditions in the borderlands were more strongly affected by the monsoonally influenced climate system of the lower latitudes

radioelement concentrations in the deep profile through precambrian basement of the vredefort structure the vredefort basement granite in south africa forms the core of an undomed and overturned sequence of precambrian strata slawson 1976 proposed that the granite core has also been overturned exposing to view a thick section through the archean crust incrasing in depth toward the center of the dome profiles across the vredefort basement provide an opportunity for studying the distribution of u th and k with depth in the upper and middle crust detailed radioelement concentration profiles across the granitic basement showed that 1 the central part of the basement core is depleted in th and u relative to the perimeter and the concentration of th and u falls off regularly from the basement margin inward 2 the distribution of the radioelements and the distribution of heat production with depth over the outer 8 km are consistent with an exponential depth function 3 the felsic rocks of the central basement are characterized by high k u and th u ratios and the ratios k u k th and th u increase from the margin inward and 4 mafic granulites which occur in the central regions of the dome have normal k u k th and th u ratios high grade metamorphic environment resulted in the depletion of bothmore u and th relative to k in the greater proportion of the felsic rocks from the central regions of the vredefort basement depletion of u was far greater than that of th the normal th u k u and k th ratios in mafic rocks in close proximity to the felsic rocks suggest that mineral assemblages have a strong control on the behavior of the radioelements during regional metamorphism in the vredefort basement less

pollen inferred late glacial and holocene climate in southern balkans lake maliq abstract high temporal resolution analysis of pollen records from lake maliq albania provides quantitative estimates of monthly temperature and precipitation changes since the last deglaciation the climate parameters were estimated using the best modern analogue technique with an updated modern pollen climate database composed of 2748 surface samples the record shows two main cooling phases in the maliq area the oldest and younger dryas and a cooling event around 8200 years which suggests that the forcing factors driving climate variations in the north atlantic area since the last glacial period also extended their influence into the mediterranean area the oldest and younger dryas are also characterized by an arid climate and a change in the seasonality of precipitation the summer precipitation tends to be greater during the cooling phases than during the temperate periods the holocene climate is relatively stable and the values of each parameter reach their modern levels except for an arid event between 8300 and 8100 cal bp

quantitative reconstruction of early holocene and last glacial climate on the balkan peninsula using coupled hydrological and isotope mass balance modelling abstract we investigate the modern hydrology of lake ohrid macedonia albania using a combined hydrological and isotope based modelling approach and present a new evaluation of contemporary water balance and palaeoclimate estimates the combined model is able to estimate hydrological components that cannot be directly measured and indicates that sublacustrine spring inflow is in the order of 50 higher than previous estimates and groundwater outflow comprises approximately a third of overall water outflow in combination with sediment core oxygen isotope data we used the combined model to quantitatively reconstruct past climate in particular precipitation during the early holocene and last glacial period calculated precipitation in the early holocene was higher than the value for present day and was approximately 44 lower than present during the last glacial assuming the majority of precipitation fell as snow the estimated amount of precipitation in the last glacial would have been high enough to provide refugial conditions at lake ohrid and to support the continuous existence of arboreal vegetation in the catchment the improved understanding of the modern isotope hydrology of lake ohrid is fundamental for explaining the systematics of past isotope variation and providing context for extended sediment records from the lake which will provide longer term palaeoclimate reconstructions covering multiple glacial interglacial cycles

sulphur saturation in the lower and critical zones of the eastern bushveld complex abstract a suite of ultramafic and mafic rocks from the lower critical and lower portion of the main zones of the bushveld complex has been analysed for th cs zr ni cr and au by inaa and xrf spectrometry the incompatible elements th cs and zr correlate positively and show a gradual upward increase in abundance assuming constant average proportion of intercumulus material this upward increase implies that the zones of the complex studied represent crystallization of a single magma type some 3600 m thick pyroxenites dominate the lower portion of the section studied and their ni content shows an initial rapid decrease from 850 ppm in the lowermost rocks to around 500 ppm with considerable scatter this distribution is most likely to have resulted from bottom crystallization with superimposed convective overturn near the transient floor of the chamber gold abundances are generally higher in chromitites and correlate positively with ni indicating the presence of significant amounts of cumulus immiscible sulphide in the silicate rocks au does not correlate with any of the analysed elements and it is concluded that au was trapped in small quantities of immiscible sulphide which precipitated continuously during crystallization there is an upward increase in the amount of cumulus immiscible sulphide indicating a progressive increase in sulphur solubility in the magma

tracer methods used to verify the hypothesis of cvijic about the underground connection between prespa and ohrid lake prespa lake and ohrid lake constitute a hydraulic system shared between albania fyr of macedonia and greece karst rocks separate both lakes the elevation of prespa lake is about 150 m higher than that of ohrid lake considering these facts cvijic formulated in 1906 the hypothesis that prespa lake recharges the st naum and tushemisht springs at ohrid lakeside environmental isotopes demonstrated that prespa lake recharges about 37 42 and 52 54 of water emerging in st naum and tushemisht springs respectively an artificial tracer experiment carried out in 2002 physically demonstrated the underground connection between both lakes this experiment confirmed the supposed underground connection and brought important information about the groundwater velocity transit time and karst water conduits development

geochemistry across an exposed section of archaean crust at vredefort south africa with implications for mid crustal discontinuities abstract the central region of the vredefort structure consists of a semi circular multi layered sequence of crystalline rocks which are nearly vertical in attitude and which increase in metamorphic grade towards the core of the structure together with the overlying precambrian strata this sequence provides a cross section through almost the entire crustal section of the kaapvaal craton 36 km the upper part of the vredefort crystalline crust consists of a 3 0 ga sequence of differentiated felsic rocks in amphibolite facies the lower crust consists of a complex and heterogeneous both chemically and isotopically high grade metamorphic terrain of charnockites granulites mafic and felsic and supracrustal rocks the upper crust is separated from the lower crust by the vredefort discontinuity a brittle ductile shear zone characterised by a high concentration of pseudotachylite and brecciated rock petrographic chemical and isotopic evidence suggest that the upper and lower crust have undergone very different styles of evolution this is indicative of different geological environments prior to their present juxtaposition we speculate that the upper and the lower parts of the vredefort crystalline crust were juxtaposed during intracratonic thrusting 2 8 ga ago and that the entire 36 km section of crust including the vredefort discontinuity were rotated and uplifted into their present vertical position during the 2 0 ga vredefort catastrophe

ultramafic rocks in the centre of the vredefort structure south africa geochemical affinity to bushveld rocks abstract the geochemistry and mineral chemistry of ultramafic rocks in the centre of the vredefort structure have been reinterpreted a detailed examination of previously published major element trace and ree analyses as well as mineral analyses strongly suggests a magmatic origin in contrast to previously postulated tectonic emplacement of mantle material a strong geochemical affinity to ultramafic rocks from the bushveld complex is evident the magmatic nature of the ultramafic rocks in the centre of the vredefort structure has implications for the discussion of the metamorphic history of the vredefprt structure which shows evidence of unusually high and as yet not satisfactorily explained geothermal gradients during peak metamorphism

a chronostratigraphic framework for the north central kaapvaal craton the bushveld complex and the vredefort structure abstract sufficient geochronological data are available pertaining to the north central part of the kaapvaal craton to construct a chronostratigraphic framework for the rock units involved in the vredefort event from the basement rocks at 3170 ma to the waterberg soutpansberg groups deposited between 2025 and 1425 ma the resulting framework forms a convenient chronological guide to the geological evolution of this area and the timing of events such as that at vredefort the basement on which the supracrustal rocks were deposited stabilised from 3170 to 3060 ma but metamorphism and metasomatism of these rocks occurred up to 2800 m y ago in different parts of the craton the first unit of the wits triad the volcaniclastic dominion group was deposited at 3060 ma on the stabilising basement this was followed by the dominantly clastic witwatersrand supergroup and the overlying ventersdorp supergroup the dominantly volcanic ventersdorp rocks are 2700 m y old and form the last unit of the wits triad a considerable time gap of 200 300 ma separates the triad from the lowermost units of the overlying transvaal sequence the age of these volcanic and clastic protobasinal rocks is poorly constrained between 2500 and 2300 ma they may in fact represent eroded remnants of a more extensive depositional cycle the mainly clastic sedimentary part of the transvaal sequence pretoria group has been dated at 2224 ma the upper part of the transvaal sequence rooiberg group is only constrained by the age of the intrusive bushveld complex the bushveld basic layered rocks are well dated at 2060 ma as are the subsequent granites at 2050 ma the vredefort event which post dates the bushveld complex is reasonably well constrained by the age of the bronzite granophyre at 2000 ma deposition of the waterberg and soutpansberg groups which post date the bushveld complex is poorly constrained between the age of the bushveld granites and younger alkaline intrusives at 1425 ma but these sediments and volcanics were probably formed between 2025 and 1752 ma the waterberg group may therefore contain debris from the vredefort structure

magnetic anomaly near the center of the vredefort structure implications for impact related magnetic signatures a strong magnetic anomaly near the center of the ancient and deeply eroded vredefort structure is attributed to remanent magnetization caused by a large meteorite impact at 2 0 ga the rocks underlying the anomaly are archean gneisses thought to represent mid crustal depths that were uplifted to the surface during the postulated impact event measurements of the remanent magnetization of the basement rocks yielded consistent vectors of declination 25 inclination 56 k 18 16 that correspond to the paleomagnetic pole position at time of impact petrologic studies indicate that during impact large volumes of rock were heated enough to cause thermal remagnetization in the ambient field thermal effects of all large impacts on cratons may induce a remanent magnetization of sufficient intensity to cause anomalies in the geomagnetic field that are detectable even by satellites

processed and enhanced gravity and magnetic images over the vredefort structure and their interpretation abstract cryptoexplosion structures are polygonal features which have experienced violent disruption during their formation the vredefort structure is one of the largest known cryptoexplosion structures and the geology is well exposed over its northern half the origin of the violent disruption experienced by the vredefort structure is controversial and many aspects of its history are under intensive study since most of the southern half of the vredefort structure is blanketed by a cover of karoo permian strata geophysical data are essential in any attempt to map the pre karoo geology data sets of the regional gravity and magnetic fields over the vredefort structure have been processed and enhanced with the aid of an image processor the results are presented as a series of images each one enhancing particular attributes of the data sets an interpretation of the geophysical images is presented focusing on the regional geometry and setting of the structure striking features of the geophysical images include a simple concentric geometry and polygonal shape which reflect the distribution of dense and magnetic lithologies within and surrounding the structure the kinematics of the development of a polygonal uplift are discussed inward movement of about seven collar sectors separated by radial faults and uplift of the central sections of each of the sectors may account for the gross polygonal shape pull apart voids formed at kinks in the radial faults might account for the positions of several alkali stocks within the stratified collar of the vredefort structure the enhanced image of the gravity field highlights a se trending gravity low which extends beyond the southeastern quadrant of the vredefort structure this feature forms part of a fundamental nw se trending intracratonic lineament the vredefort axis

ultramafic rocks in the centre of the vredefort structure south africa possible exposure of the upper mantle abstract the rocks in the central region of the vredefort structure are interpreted as lower crust that has undergone uplift of 36 km during the vredefort cryptoexplosion event 2 0 ga ago the outcrops in this central region are mainly high grade leucogranulites interbanded with mafic granulites and supracrustals rocks from a borehole located near the centre of the structure indicate that the core region is underlain by ultramafic rocks which probably represent the upper mantle beneath this region of the kaapvaal craton the main lithologies sampled by the borehole are serpentinized hornblende bearing harzburgite with minor bands of pyroxenite and glimmerite the major and trace element chemistry of these ultramafic rocks is similar to that of fertile oceanic lithosphere mineral chemistry and petrographic data suggest that the vredefort ultramafics are metamorphic rocks which have undergone a complex tectonic and metamorphic history sm nd and rb sr isotopic data together with the field relationships provide some evidence that these rocks are archaean but also that they have been chemically and isotopically altered similar hydrated and chemically altered ultramafic rocks occur in the jamestown ophiolite complex in the barberton greenstone belt accordingly we speculate that the crust mantle transition zone in the kaapvaal craton consists of a zone of hydrated archaean oceanic lithosphere