experimental melting of biotite plagioclase quartz muscovite assemblages and implications for crustal melting abstract in order to understand the role of mica rich rocks as a source of granite magmas a series of melting experiments was performed on two different starting materials the first composition is a model biotite gneiss consisting of 30 wt biotite 30 wt plagioclase and 40 wt quartz the second composition is a model two mica pelites consisting of 15 wt biotite 15 wt muscovite 30 wt plagioclase and 40 wt quartz experiments were performed under vapor absent conditions at 1 0 gpa and between 750 o and 950oc with only biotite in the starting material the volume of melt is always less than 15 vol below 900oc and reaches 25 vol at 950oc in experiments that involve both biotite and muscovite in the starting material the melt proportion increases up to 28 vol at 825oc and reaches 60 vol at 950oc for the biotite plagioclase quartz bpq assemblage the solidus is located at 800oc at 1 0 gpa the melting reaction produces a metaluminous granitic liquid and leaves a residuum consisting of garnet biotite orthopyroxene plagioclase quartz in addition the experiments show that at 1 0 gpa biotite can be stable above 950oc with both micas in the starting material bpqm the solidus at 1 0 gpa is located at 750oc the melting reactions produce a peraluminous granitic liquid and leave a residuum of garnet sillimanite biotite quartz plagioclase kfeldspar in experiments below 900oc at 950oc the residuum consists of garnet orthopyroxene biotite plagioclase the melt fraction is determined by the proportions of the hydrous phases and of the amount of feldspar relative to quartz mineral modes of the source rocks particularly the amount of quartz are at least as important as the amount of available h20 in controlling the melt fraction generated during crustal anatexis

fluid inclusions in the harney peak granite black hills south dakota usa implications for solubility and evolution of magmatic volatiles and crystallization of leucogranite magmas abstract experimental and theoretical studies have shown that magmatic fluids have strong influence on phase equilibria of granitic systems a microthermometric study of fluid inclusions in the proterozoic harney peak granite black hills south dakota usa was undertaken to obtain direct evidence for the composition and evolution of magmatic fluids in a leucogranitic system and to evaluate their effect on liquid lines of descent of leucogranite magmas a previous stable isotopic study has demonstrated that the granite has not interacted with nonmagmatic fluids since its crystallization therefore fluids found in the inclusions are of magmatic origin and present an opportunity to directly sample magmatic fluids trapped during crystallization of a granitic magma and during subsolidus conditions the harney peak granite was emplaced as multiple sills dikes and small intrusions many of which differentiated into coupled aplite pegmatite layers three types of fluid inclusions are found in the granite type 1 consist of variable saline h 2 o c0 2 mixtures with minor ch 4 or other gases inclusions of this type are found in tourmaline and quartz in aplite layers are generally isolated and have negative crystal shapes they are interpreted to be primary there is a general increase in salinity and decrease in isochore temperature with decreasing co 2 h 2 o ratio of the inclusions the trend is ascribed to progressive change in fluid composition with crystallization due to the differential solubility of co 2 and h 2 o in the high silica magma isochores coupled with independently determined crystallization temperatures suggest entrapment pressure 3 5 kbar consistent with geobarometry in the wallrocks type 2 inclusions are carbonic fluids dominated by co 2 whereas type 3 inclusions are saline aqueous fluids without a detected carbonic component both types are mostly found along healed fractures in quartz they are interpreted to be secondary inclusions that formed as a result of unmixing of type 1 inclusions at subsolidus conditions during uplift and cooling of the harney peak granite dome freezing point depressions birefringent daughter crystals phase equilibria considerations and track mapping of b and li distribution in thin sections all indicate that both type 1 and type 3 inclusions contain solutes such as k li and b in addition to nacl using published solubility models for h 2 o and co 2 in granitic melts and the composition of the most co 2 rich type 1 inclusions x co 2 0 55 the initial h 2 o and co 2 concentrations in the harney peak granite magma are deduced to have been 3 5 wt and 1500 ppm respectively the relatively low water concentration is consistent with temperatures of dehydration melting reactions that produced the magma it is suggested that the aplite pegmatite segregations found in parts of the harney peak granite are the result of initial rapid near liquidus crystallization of minerals with high na k ratios including plagioclase and tourmaline along a wide range of increasing h 2 o aplite crystallization was followed by crystallization of relatively potassic residual liquid enriched in fluxing elements under conditions of high h 2 o

fracturing and diking in incompletely crystallized granitic plutons abstract dikes in granitic plutons commonly have mineralogic and textural characteristics indicating a genetic relation to their host the contact between the dike and the host is marked signifcantly by interlocking unfractured crystals rather than by truncations and overgrowths although megascopically the contacts between dike and host pluton may be exceedingly sharp and planar an explanation of these relationships by fracturing an incompletely crystallized host rather than by entirely post magmatic fracturing with subsequent diking is postulated to be consistent with experimental date and certain petrologic observations published experimental research indicates that fracturing of crystal melt systems may occur if there is at least 70 crystals in the system at which point the system is capable of transmitting compressive and shear stresses via a crystalline framework dilatancy pumping of melt into fracture zones and subsequent hydraulic fracturing is thought to be one possible way late stage fluids of granitic systems evolve into dikes in granitic plutons such as leucogranites aplites and pegmatites interlocking textures between dike and host may also develop if magma from some distant source is interjected along the plane of fracturing in crystal melt systems

in situ x ray diffraction study on pressure induced structural changes in hydrous forsterite and enstatite melts abstract we investigated the pressure induced structural changes in hydrous forsterite and enstatite melts using in situ synchrotron x ray diffraction diffraction data was collected up to 6 9 gpa at superliquidus temperatures at pressures below 3 gpa the first sharp diffraction peak fsdp which reflects the silicate network ordering in the silicate melts that consist of si o si linkages is shifted notably toward higher q scattering vector a 1 in both melt compositions this observation indicates that water has a depolymerizing effect on the silicate network below 3 gpa which means that si o si linkages are partially disrupted by hydroxyl species si oh units in contrast the peaks move to lower q at pressures above 3 gpa in spite of the compression which indicates lengthening of the silicate network ordering i e polymerization of silicate network this observation indicates that water changes to have a polymerizing effect on the silicate network above 3 gpa by a new free hydroxyl group such as mg oh which was previously proposed in the study on hydrous silicate glasses structure in fact the structural changes in the present study are more pronounced in the hydrous mg2sio4 melt suggesting that the mgo component has an important influence on the polymerization of hydrous melt structure at 3 5 gpa the present structural change re polymerization at high pressure in hydrous silicate melt can influence the viscosity such a relatively high viscosity hydrous magma may be able to stay or be decreased in the rising velocity at a depth of 100 180 km which can enhance the decrease in a seismological wave velocity in the earth s asthenosphere as proposed in previous seismological observations

lightning in the anvils of supercell thunderstorms abstractthis study uses data from the oklahoma lightning mapping array ok lma the national lightning detection network and the norman oklahoma koun prototype weather surveillance radar 1988 doppler wsr 88d radar to examine the evolution and structure of lightning in the anvils of supercell storms as they relate to storm dynamics and microphysics several supercell storms within the domain of the ok lma were examined to determine whether they had lightning in the anvil region and if so the time and location of the initiation of the anvil flashes were determined every warm season supercell storm had some flashes that were initiated in or near the stronger reflectivities of the parent storm and propagated 40 70 km downstream to penetrate well into the anvil some supercell storms also had flashes that were initiated within the anvil itself 40 100 km beyond the closest 30 dbz contour of the storm these flashes were typically initiated in one of three locations 1 coincident with a local reflec

experimental deformation of partially molten westerly granite under fluid absent conditions with implications for the extraction of granitic magmas the mechanical behavior of partially molten westerly granite was investigated in the temperature range 800 1100 c 250 mpa confining pressure by means of constant strain rate creep and stress relaxation tests the only water in the samples came from the breakdown of hydrous phases biotite minor chlorite and muscovite and alteration products of feldspars thus the amount of melt was controlled by the test temperature and ranged from 3 at 800 c to 50 at 1100 c over that temperature range strength decreased from 500 mpa to less than 1 mpa and a preliminary constitutive flow law for the partially molten rock was obtained to allow extrapolation to low strain rates the comparative viscosity of the melt alone was estimated at 950 and 1000 c from the distance it could be made to penetrate into a porous sand under a known pressure gradient under all conditions deformation of the matrix of solid grains was by brittle fracture only samples containing up to 10 vol melt failed with the formation of a shear fault zone at higher melt fractions melt filled pores collapsed by shear enhanced compaction squeezing the melt into axial cracks above 40 vol melt unfractured solid grains were carried about passively in the flowing liquid there was no evidence of a rheologically critical melt percentage in this system by analogy with the uniaxial compaction of water saturated soils a simple model is erected to describe a two stage process for the extraction of granitic melts from their protoliths with the aid of nonhydrostatic stress shear enhanced compaction is inferred to drive melt into a network of melt filled veins whereupon porous flow through the high permeability vein network allows rapid drainage of melt to higher crustal levels

badrinath gangotri plutons garhwal india petrological and geochemical evidence for fractionation processes in a high himalayan leucogranite the gangotri leucogranite is the western end of the badrinath granite one of the largest bodies of the high himalayan leucogranite belt hhl it is a typical fine grained tourmaline muscovite biotite leucogranite the petrography shows a lack of restitic phases the inferred crystallization sequence is characterized by the early appearance of plagioclase quartz and biotite and by the late crystallization of the k feldspar this suggests that in spite of being of near minimum melt composition the granite probably had long crystallization or melting interval in agreement with previous experimental studies tourmaline and muscovite have a mainly magmatic origin even though the major element composition is homogeneous there are several geochemical trends when cao decreases there is an increase in na2o rb sn u b f and a decrease in k2o fe2o3 tio2 sr ba zr ree th which are best explained by a fractionation process with early crystallizing phases experimental solubility models for zircon and monazite in felsic melt support a magmatic origin for these two accessory phases as well rb sr isotope data show this granite to have like other hhl heterogeneous isotopic values for sr initial 87sr 86sr ratios calculated at 20 ma range between 0 765 and 0 785 therefore no mixing i e no convection occurred between the different batches of magma in contrast 18o data show little variation 13 04 0 25 implying a source with homogeneous 18o values differences in timing between fluid infiltration and the onset of melting related to differences in temperature of the source could explain why source homogenization occurred for the gangotri and not for the manaslu granite the use of experimental results for solubility and the position of the accessory minerals during melting predict a low viscosity for the melt during its extraction this in turn explains the lack of restitic phases major and accessory in the granite as well as some field features lensoid shape pronounced magmatic layering based on the petrographic and isotopic studies it is suggested that the mechanism of ascent was not diapiric but rather that the melt ascended along several fractures and the level of emplacement was partialy controlled by the density contrast between the melt and host rocks

boron in granitic magmas stability of tourmaline in equilibrium with biotite and cordierite experiments at 750 c 200 mpa h2o a h2o 1 and fo2 ni nio established that the equilibrium among tourmaline biotite cordierite and melt spinel aluminosilicate or corundum occurs with 2 wt b2o3 in strongly peraluminous melt with an aluminosity measured by the parameter asi of 1 2 the experiments demonstrate the relationship of tourmaline stability to the activity product of the tourmaline components boron and aluminum which are inversely related to one another tourmaline is unstable in metaluminous to mildly peraluminous melts asi 2 wt b2o3 in their bulk magmas

maximum and minimum water contents of granitic melts implications for chemical and physical properties of ascending magmas new results obtained by the investigation of liquidus and solidus phase relations in the system qz ab or and by the determination of h2o solubility in haplogranitic melts are used to discuss the evolution of granitic quartzo feldspathic magmas during their ascent in the crust particular attention is given to the role of h2o and its effect on physical properties of ascending magmas the evolution of melt fraction h2o content of the melt and viscosity of melt and magma during ascent are discussed for several examples adiabatic ascent ascent with cooling ascent with crystal fractionation it is shown that decompression melting processes may be very important significant increase of the melt proportion especially at low pressure in magmas ascending along adiabats or with slow cooling rates the comparison of the discussed examples shows that melts formed at low t are significantly less viscous than at high t although the degree of melting may remain very low in the case of dehydration melting at low temperature the low viscosity of the generated melts may enhance the extraction of these melts from the source area to produce leucogranites

granitic magma transport by fracture propagation granitic magmas commonly ascend tens of kilometres from their source terranes to upper crustal emplacement levels or to the earth s surface apart from its obvious bearing on the interpretation of the geology and geochemistry of felsic igneous rocks the magma ascent mechanism critically affects any modelling of the metamorphic evolution of the upper lithosphere as well as its rheology we propose that in general granitic magmas ascend via propagating fractures as dykes in extremely short time periods long distance diapiric transport of granitoid magmas through crustal sections is not viable on thermal or mechanical grounds and there is an apparent total absence of field evidence for diapiric rise of such magmas even in supposed type localities neither the shapes nor internal or external characteristics of granitic plutons necessarily reveal anything about the transport of their precursor magmas these are purely arrival phenomena dictated by local structure kinematics and stress states based on existing numerical treatments of the problem we show that granitic magmas are apparently sufficiently inviscid to travel through fractures to high crustal levels without suffering thermal death by freezing for example a 2000 km3 granitic batholith can be inflated by a 1 km 3m 20 km deep dyke system in less than 900 years the model proposed has numerous far reaching petrological and rheological consequences some of which are outlined

calamity peak layered granite pegmatite complex black hills south dakota part i structure and emplacement the calamity peak pluton is a satellitic granite pegmatite intrusion located 2 km southwest of the main harney peak granite dome in the black hills south dakota many aspects of the structural development of the calamity peak pluton 1 km 2 mimic those of the larger harney peak dome 100 km 2 thus the model described here for the calamity peak pluton provides a general basis for evaluating the evolution of proterozoic granite pegmatite intrusives of the harney peak granite system the overall structure of the intrusive rocks at calamity peak is that of a dome as shown by the general geometry of the pluton contacts and by a domical pattern of internal textural layering textural layering is defined by alternating bands of pegmatite and fine grained granite 0 1 2 0 m thick fine grained layers are in turn banded on a scale of 2 20 mm owing to modal variations of tourmaline quartz and feldspars textural differentiation of at least some of these layers resulted from segregation of initially homogeneous magmas into pegmatitic upper and aplitic lower components during crystallization relationships between the pluton and regionally dipping schistose country rocks however do not support a simple domal structure schistosity conforms to the contact only along the southern margin of the pluton the side facing with the regional dip country rock schistosity is at a high angle to the contact at the apparent floor of the pluton which is exposed in the core of the dome and along the northern margin the side that opposes the regional dip in order to explain the structural observations it is inferred that the initial intrusive body at calamity peak consisted of a flat lying discordant sheet intruded into steeply dipping quartz mica schist country rock however an arcuate sheet concave downward cannot be ruled out new magma pulses possibly several thousands were successively emplaced along the hanging wall contact of earlier pulses as indicated by the upward truncation of early layers creating a composite layered pluton intrusions of individual magma pulses were localized in three major composite sheets which form structurally and chemically discrete portions of the pluton growth of the pluton proceeded by forcible distension and plastic deformation of overlying country rocks schistosity was molded into a conformable attitude in portions of the hanging wall and pre intrusive country rock lineations were deflected around the pluton the layered granite pegmatite series is crosscut by four successive stages of fracture filling bodies the orientations and compositions of these bodies record the late stages in the structural and fluid evolution of the plutonic system

water contents of silicic to intermediate magmas silicic to intermediate magmas have water contents that range from 1 wt to around 7 wt depending on the character and depth of the magma source type of melting reaction and the degree of differentiation the condition of water saturation is rare implying that crustal magma genesis generally takes place under fluid absent conditions or that any fluid present must contain volatile species other than h2o the source and quantity of water present during partial melting profoundly affect the types of melting reactions residues and magmas as well as subsequent magma evolution for s type granitic magmas melting reactions involving muscovite breakdown in pelites yield low temperature wet melts that form veins pockets and small plutons in regional metamorphic terranes biotite breakdown in pelites near the amphibolite granulite facies transition yields hotter magmas with variable water contents these are emplaced at medium to high levels under granulite facies conditions biotite breakdown in quartzofeld spathic rocks yields high temperature dry magmas emplaced as subvolcanic batholiths and volcanics

reversed experiments on biotite quartz feldspar melting in the system kmash implications for crustal anatexis melting temperatures of biotite quartz and biotite quartz feldspar assemblages in the system k 2 o mgo al 2 o 3 sio 2 h 2 o have been determined in the pressure range 0 5 18 kbar the subsolidus dehydration of biotite quartz also has been investigated from 300 to 500 bars the melting equilibria studied are phlogopite quartz sanidine vapor liquid o phlogopite quartz vapor enstatite liquid k phlogopite quartz enstatite liquid k v and phlogopite quartz sanidine enstatite liquid v at 10 kbar the o reaction occurs at 700 720 c the k reaction at 780 790 c the k v reaction at 815 850 c and the v reaction at 800 850 c vapor saturated reactions were reversed isobarically in two stage experiments in which the starting assemblage was held at a temperature 10 above the temperature of previously observed melting for a duration equivalent to an initial melting experiment followed by lowering of the temperature below the temperature of initial mel

experimental and theoretical constraints on melt distribution in crustal sources the effect of crystalline anisotropy on melt interconnectivity in partially molten systems the equilibrium distribution of melt at the grain scale is governed by the principle of interfacial energy minimization in ideal sources i e partially molten rocks that are monomineralic have single valued solid liquid and solid solid interfacial energies and are subject to hydrostatic stress the wetting angle is known to be a unique characteristic which specifies the melt configuration for a given melt fraction crustal rocks cannot be modelled as ideal sources because of their polymineralic nature the moderate to high anisotropy of interfacial energies which characterizes common refractory minerals and the possible presence of a crystallographic preferred orientation that partially molten crustal rocks depart from ideal sources is documented by a series of high p high t experiments illustrating the textural relationships of biotite and amphibole with silicic melts the melt distributions observed in these experiments differ significantly from those expected in ideal sources 1 crystal melt interfaces are commonly planar rational faces rather than smoothly curved irrational surfaces and 2 the concept of a unique wetting angle does not hold as shown in the biotite silicic melt system these textural features demonstrate that anisotropy of crystal melt interfacial energy is a factor of primary importance in modelling the grain scale distribution of partial melts the petrological implications of our study are the following 1 1 at high degrees of anisotropy and low melt fractions melt is predicted to form isolated plane faced pockets at grain corners the overall shape of these pockets and therefore the value of the connectivity threshold c are expected to be very sensitive to the ratio of solid solid to solid liquid interfacial energies ss sl c is the melt fraction at which melt interconnectivity is established melt pockets with low volume to surface ratio and low but non constant wetting angles should prevail at high ss sl resulting in very low values of c 1 to a few vol higher values of c a high volume to surface ratio of melt pockets and high wetting angles are expected at low ss sl 2 2 the wetting angle at hornblende hornblende melt junctions at 1200 mpa 975 c is 25 a review of existing data indicates that quartz melt and feldspar melt wetting angles are also low to moderate 12 60 a very low value of c should therefore be the general rule during crustal anatexis in particular a connectivity threshold lower than 3 4 vol is predicted for partially molten amphibolite 3 3 in biotite rich rock types such as melanosomes in migmatites the combination of a pronounced crystalline anisotropy and a marked preferred orientation of mica flakes leads to a very low permeability normal to layering biotite rich melanosomes should therefore impede chemical interactions between neighbouring leucosomes and mesosomes

iron and titanium solution properties in peraluminous and peralkaline rhyolitic liquids the saturation surface of pseudobrookite fe2tio5 was determined for melts in the system sio2 al2o3 k2o feo fe2o3 tio2 at 1400 c and 1 atm the variation in concentrations of fe2o3 tio2 and fe2tio5 in liquids can be used to infer relative changes in activity coefficients of these components with changing k2o k2o al2o3 of the melts saturation concentrations of these components are low and relatively constant in the peraluminous melts and increase with increasing k2o k2o al2o3 in peralkaline liquids the activity coefficients of fe2o3 and tio2 and fe2tio5 therefore are higher in peraluminous liquids than in peralkaline liquids in this system in addition the iron redox ratio was measured as a function of k2o k2o al2o3 for liquids just below the saturation surface f text o text 2 was fixed so all variations in redox ratio are entirely due to changes in melt composition the redox ratio from unsaturated liquids was applied to saturated liquids where redox analysis of the glass is impossible the homogeneous equilibrium experiments indicate that the activity coefficient of fe2o3 relative to that of feo is significantly greater in peraluminous melts than peralkaline melts both the heterogeneous and homogeneous equilibria suggest that in peralkaline liquids k in excess of that required to charge balance tetrahedral al 3 is used to stabilize both fe 3 and ti 4 calculations show that ferric iron and titanium compete equally effectively for charge balancing potassium but neither can outcompete aluminum the observed changes in solution properties of fe2o3 and tio2 in the synthetic melts are used to explain variations in fe ti oxide stabilities in natural peraluminous and peralkaline rhyolites and granites since the activity coefficients of both ferric iron and titanium are significantly higher in peraluminous liquids than in peralkaline liquids fe ti oxides should occur earlier in the crystallization sequence in peraluminous rhyolites than in peralkaline rhyolites in addition iron will be reduced in peraluminous granites and rhyolites relative to peralkaline ones under comparable p t and f text o text 2 finally observed crystallization patterns for minerals containing highly charged cations other than ferric iron and titanium are evaluated in the context of this and other experimental studies

a geochemical and experimental study of the role of k feldspar during water undersaturated melting of metapelites abstract the production of s type granites has been related to the extraction of melts during water undersaturated melting of metasediments in the lower continental crust if this mechanism is of widespread applicability a chemically distinctive granulitic restite must be left behind with a positive eu anomaly and depleted incompatible element concentrations however little geochemical evidence has been found in support of this hypothesis the rare earth element geochemistry of lower crustal granulites and associated melts will depend on the behaviour of the phases in which ree and trace elements are concentrated i e zircon monazite and k rich feldspar new experimental data on synthetic metapelites show that k feldspar can be a product or a reactant during water undersaturated melting of biotite depending on the h2o k2o of the melt relative to biotite past confusion over the role of k feldspar during melting is due to the reaction being close to degeneracy and changing its stoichiometry in response to only small changes in bulk composition coherent interpretation of the role of k feldspar in different experimental studies requires a better knowledge of phase water contents than has commonly been available the leucosomes formed in some antarctic granulite facies migmatites are likely to have had low h2o k2o ratios which suggests that k feldspar would have been a reactant during melting this could cause the positive eu anomalies observed in the leucosomes through the disequilibrium melting of k feldspar during water undersaturated melting the undersaturation of trace elements and ree in the leucosomes strongly suggests that disequilibrium melting took place caused by the incomplete dissolution of accessory phases monazite and zircon these phenomena give the melts a distinctive geochemical character which has also been seen in the other granulite facies leucosomes analysed to date this geochemical character contrasts with that of s type granites and therefore the production of granulites in the lower crust may not necessarily be associated with this type of magmatism if lower crustal granulite facies migmatites are the source region for peraluminous s type granites then the melts generated must undergo considerable modification during ascent

reaction induced microcracking an experimental investigation of a mechanism for enhancing anatectic melt extraction melting reactions can create melt overpressure that may induce microcracking to determine whether such microcracking can enhance rock permeability and melt extraction we have studied the partial melting of a muscovite bearing metaquartzite at 800 mpa and 950 1126 k melting begins at muscovite quartz grain boundaries and results in progressive replacement of muscovite by melt pools containing mullite and biotite the volume change for the reaction 0 021 m 3 per m 3 of original rock generates randomly oriented microcracks that emanate from melting sites the mean crack length in two dimensional sections is 151 5 m and reflects the spacing between melting sites experiments in which quartz sand was loaded with the metaquartzite to act as a drain verified that the microcracks together with the melt pools form a connected network the estimated network permeability is 10 14 1 m 2 at least four orders of magnitude greater than permeabilities characteristic of regional metamorphic environments for reaction induced microcracking to occur the reaction must take place on a time scale such that creep cannot accommodate the associated volume change our analysis suggests that that requirement can be met on regional metamorphic time scales and that reaction induced microcracking is a feasible mechanism of permeability enhancement during partial melting and devolatilization

constraints on melting and magma production in the crust major intrusions of granitic rocks are found in several tectonic settings and in all cases crustal melts may contribute to the volumes of granitic magma high grade metamorphism and partial melting of the crust take place predominantly under fluid absent conditions we present a model for calculating the amounts of melt that may be formed by fluid absent breakdown of micas and amphiboles in common crustal rock types pelitic quartzofeldspathic intermediate and mafic melt proportions depend mainly on the kind of source rock the pressure at which melting takes place the temperature and the hydrous mineral h2o content of the source as a consequence of the pressure dependence of water solubility in silicate melts any given source rock will produce more melt by a given fluid absent reaction at lower pressure at a given pressure higher temperature reactions can produce more melt from a given source rock based on a survey of the compositions of common rock types we show that the amounts of melt can vary from 50vol thus crustal rocks vary widely in their fertility as magma sources depending on the types and amounts of hydrous phases they contain in general muscovite breakdown in pelites will yield only small quantities of melt and lead to migmatite formation biotite breakdown in pelites occurs at higher temperature and because most high grade pelites below granulite grade are biotite rich can yield up to about 50 vol of granitoid melt rocks of intermediate composition and hornblende rich mafic rocks are potentially highly fertile magma sources also provided that the high temperatures necessary for biotite and hornblende breakdown are realized pyroxene rich mafic rocks and quartzofeldspathic rocks are much less potentially fertile data suggest that mechanisms exist for the efficient segregation of melt and restite in systems with 30and probably 20vol melt the pressure temperature history of a region can greatly influence crustal source fertility through its control over the occurrence of subsolidus dehydration and melting equilibria

titanium substitution in biotite an empirical model with applications to thermometry o2 and h2o barometries and consequences for biotite stability abstract an empirical model for solution of ti in biotite is developed and calibrated on the basis of various equilibria among biotite and ti saturating assemblages sources of data used for the calibration include both experimental products and published analyses of natural assemblages ti solution in biotite can be satisfactorily modelled by means of the exchange component tife 2 whose non ideal behavior can be approximated empirically by means of a linear function of the relative concentrations of ti and octahedral al in biotite within assemblages which fix the chemical potential of the exchange component tife 2 the concentration of this component in biotite is very sensitive to temperature and oxygen fugacity making it possible to use biotite oxide assemblages to obtain reliable t and f o 2 estimates in igneous and metamorphic rocks in assemblages which also contain alkali feldspar it is possible to use breakdown equilibria of ti additive components in biotite to estimate h 2 o fugacity such uses are likely to find important applications in rocks in which other assemblages sensitive to temperature f o 2 and or f h 2 o are absent in general rocks containing a single oxide phase plus biotite as the only mafic silicate phase alkali feldspar the empirical model for solution of ti in biotite also allows to calculate the loci of various terminal reactions for the assemblage titanian biotite quartz which by comparison with equivalent equilibria in ti free systems provide insight into the effect of ti on the stability of biotite solubility of ti in biotite increases with temperature in a strongly non linear fashion as a consequence calculations predict that the effect of ti on the stability of biotite is very small up to conditions typical of the beginning of the granulite facies of metamorphism but beyond those conditions ti concentration increases markedly and biotite is rendered very refractory at mid to deep crustal pressures 10 kbar the vapor absent solidus of biotite quartz in rocks containing ti saturating phases is likely to exceed 900 c even in bulk compositions with subequal concentrations of fe and mg

the generation and crystallization conditions of the proterozoic harney peak leucogranite black hills south dakota usa petrologic and geochemical constraints the mineralogy petrology and geochemistry of the proterozoic harney peak granite black hills south dakota were examined in view of experimentally determined phase equilibria applicable to granitic systems in order to place constraints on the progenesis of peraluminous leucogranites and commonly associated rare element pegmatites the granite was emplaced at 3 4 kbar as multiple sills and dikes into quartz mica schists at the culmination of a regional high temperature low pressure metamorphic event principally along the periphery of the main pluton and in satellite intrusions the sills segregated into granite pegmatite couplets the major minerals include quartz k feldspar sodic plagioclase and muscovite biotite mg no molar mgo mgo feo 0 32 0 38 is the predominant ferromagnesian mineral in the granite s core whereas at the periphery of the main pluton and in the satellite intrusions tourmaline mg no 0 18 0 48 is the dominant ferromagnesian phase almandine spessartine garnet is also found in the outer intrusions there is virtually a complete overlap in the wide concentration ranges of sio2 cao mgo feo sr zr w of the biotite and tourmaline bearing granite suites with no discernable differentiation trends on harker diagrams precluding the derivation of one suite from the other by differentiation following emplacement this is consistent with the oxygen isotope compositions which are 11 5 0 6 for the biotite granites and 13 2 0 8 for the tourmaline granites suggesting derivation from different sources the concentrations of tio2 and possibly ba are higher and of mno and b are lower in the biotite granites the normative orthoclase albite ratio is extremely variable ranging from 0 26 to 1 65 in the biotite granites to 0 01 1 75 in the tourmaline granites very few sample compositions fall near the high pressure watersaturated haplogranite minima eutectic trend indicating that the granites for the most part are not minimum melts generated under conditions with a text h text 2 text o 1 instead most biotite granites are more potassic than the water saturated minima and eutectics and in analogy with experimentally produced granitic melts they are best explained by melting at 6 kbar a text h text 2 text o 1 and temperatures 800 c such high temperatures are also indicated by oxygen isotope equilibration among the constituent minerals nabelek et al 1992 several of the tourmaline granite samples contain virtually no k feldspar and have oxygen isotope equilibration temperatures 716 775 c therefore they must represent high temperature accumulations of liquidus minerals crystallized under equilibrium conditions from melts more sodic than the water saturated haplogranite minima or during fractionation of intruded melts into granite pegmatite couplets accompanied by volatile aided differentiation of the alkali elements the indicated high temperatures a text h text 2 text o 1 the relatively high tio2 and ba concentrations and the relatively low partial 18 text o values of the biotite granites suggest that they were generated by high extent biotite dehydration melting of an immature archean metasedimentary source the ascent of the hot melts may have triggered low extent muscovite dehydration melting of schists higher in the crust producing the high b low ti melts comprising the periphery of the main pluton and the satellite intrusions alternatively the different granite types may be the result of melting of a vertical section of the crust in response to the ascent of a thermal pulse with the low partial 18 text o biotite granites generated at a deeper hotter region and the high partial 18 text o tourmaline granites at a higher cooler region of the crust the low ti and high b concentrations in the high partial 18 text o melts resulted in the crystallization of tourmaline rather than biotite which promoted the observed differentiation of the melts into the granitic and pegmatitic layers found along the periphery of the main pluton and the satellite intrusions

the low viscosities of f h2o bearing granitic melts and implications for melt extraction and transport melt viscosity affects virtually all aspects of igneous petrogenesis although addition of h2o is known to lower melt viscosities addition of fluorine is controversial and may raise them because these two volatiles most commonly reach their highest concentrations in granitic rocks the viscosities of peralkaline strongly peraluminous and weakly peraluminous granitic melts with approximately 1 5 wt f and 6 wt h2o were measured to investigate the combined effects of h2o and f on granitic melt viscosities when those volatiles are present at natural concentration levels viscosities were measured between 800 and 1000 c at 1 0 gpa with the falling sphere technique in a piston cylinder apparatus viscosities of all melts studied behave in an arrhenius manner and can be described by the following equations peralkaline 2 70 0 21 10 6exp 181 9 1 0 rt metalminous 4 54 0 44 10 7exp 213 8 1 0 rt peraluminous 2 60 0 25 10 8exp 242 8 1 0 rt where viscosity is in units of pa s and the activation energy is in kj mol r is the gas constant in j mol 1 k 1 andt is temperature in kelvin uncertainties are 1 standard errors based upon estimated uncertainties 5 relative in the viscosity measurements viscosities of these melts with high volatile contents can be well estimated with existing viscosity models viscosities of the peraluminous melts studied are similar to those of hydrous granitic melts containing water concentrations equal to the total of h2o f in the melts studied all volatile bearing per and metaluminous granitic melts display a rapid 6 to 7 orders of magnitude drop in viscosity with the first 3 wt volatiles added followed by only an additional factor of two decrease in viscosity as the volatile concentration is increased from 3 to 12 wt the peralkaline melt displays viscosities significantly below those of all other volatile bearing per and metaluminous melts previously studied the lower viscosities of peralkaline granitic melts allow them to separate more rapidly from their source regions be transported through conduits at a velocity approximately an order of magnitude faster and experience more efficient crystallization fractionation than per and metaluminous granitic melts

geochemistry of granitic melts produced during the incongruent melting of muscovite implications for the extraction of himalayan leucogranite magmas granites formed from the incongruent melting of muscovite preserve evidence of chemical disequilibrium both between restite and melt and within individual phases during crystallization miocene leucogranites from the himalayas exemplify melt formation from a pelitic source through muscovite breakdown trace elements rb sr and ba reside almost entirely in micas and feldspars in the protolith and therefore are appropriate for quantitative modeling equilibrium between melt and restite was established for sr under fluid phase absent conditions but some disequilibrium is suggested by rb abundances consistent with known diffusion rates for these elements abundances of zr and ce in the granites which provide essential structural constituents of the accessory phases zircon and monazite indicate that the himalayan granite melts were saturated in these elements if formed at temperatures of 670 700 c but slightly undersaturated if formed at somewhat higher temperatures ion microprobe traverses of y and heavy rare earth element abundances across single garnets from himalayan leucogranites provide evidence for disequilibrium between melt and phenocryst during garnet growth thus constraining the evolution of magmatic compositions during melt formation and crystallization in some cases progressive melting of the protolith and crystallization of garnet from the melt appear to have been concomitant indicating that minimum solidus temperatures were maintained throughout the melting event this suggests that thermal buffering rather than melt extraction provided the rate determining step in magma evolution

wetting behavior of partial melts during crustal anatexis the distribution of hydrous silicic melts in polycrystalline aggregates of quartz the equilibrium distribution of hydrous silicic melts in polycrystalline aggregates of quartz was characterized in a series of partial melting and melt distribution experiments in the systems quartz albite orthoclase h2o and quartz anorthite h2o at 650 to 1000 mpa and 800 to 900 c near equilibrium textures in these experiments are characterized by very low quartz quartz melt wetting angles and by a substantial number of thin melt films along grain boundaries wetting angles in the h2o saturated experiments are as follows 18 at 800 c 1000 mpa and 12 at 900 c 1000 mpa in the granitic system 18 at 850 c 650 mpa 15 at 900 c 650 mpa and 15 at 900 c 1000 mpa in the quartzanorthite system in the granitic system at 900 c 1000 mpa a decrease of h2o content in melt from 17 wt at saturation to 6 wt results in a slight increase of wetting angle from 12 to 16 these low wetting angles and the observation that many grain boundaries are wetted by melt films indicate that the ratio of quartz quartz to quartz melt interfacial energies ss s1 is high 2 secondary electron imaging of fracture surfaces of melt poor samples provided a three dimensional insight into the geometry of melt at low melt fraction melt forms an interconnected network of channels along grain edges as predicted for isotropic systems with wetting angles below 60 this high permeability geometry suggests that the segregation of granitic melts is not as sluggish as previously anticipated simple compaction calculations for a permeability range of 10 12 to 10 9 m2 indicate that segregation may operate at low to moderate melt fractions below 30 vol within relatively short time scales i e 105 to 106 years quartzmelt textures show significant deviations from the equilibrium geometries predicted for isotropic partially molten systems the most consistent deviation is the pervasive development of crystallographically controlled planar faces of quartz these faces provide definitive evidence for non isotropic quartz melt surface energy for most silicates other than quartz the grain scale distribution of partial melts deviates even more significantly from equilibrium distributions in isotropic systems accordingly in order to describe adequately melt distributions in most natural source regions the equilibrium model should be modified to account for anisotropy of solid liquid interfacial energy

distribution of boron in the tip top pegmatite black hills south dakota experimental evidence has shown the importance of boron on the crystallization behavior of granitic systems however the intercrystalline and intracrystalline distribution of boron in mineral phases crystallizing from granitic systems is not well documented the distribution of boron between coexisting phases in the tip top pegmatite south dakota is as follows beryl ca quartz ca triphylite ca montebrasite ca potassium feldspar biotite albite muscovite spodumene tourmaline the bulk boron content of the tip top pegmatite decreases significantly with the termination of tourmaline crystallization the significant decrease in boron in the inner zones of the pegmatite is consistent with the depletion of boron in the granite melt by either the crystallization of tourmaline from the granitic melt or the partitioning of boron into an exsolved aqueous solutions 35 references

fluid absent melting behavior of a two mica metapelite experimental constraints on the origin of black hills granite we have studied experimentally the vapor absent melting behavior introduction of a proterozoic metapelite hp 60 1 from the black hills south peraluminous leucogranites such as the miocene granites dakota to assess whether the high do tourmaline bearing granites of the himalaya and tourmaline granites of the harney of the harney peak suite resulted from muscovite dominated depeak suite in south dakota are widely considered to be hydration melting at 10 kbar samples were sealed with no added the product of muscovite dehydration melting yet few h2o in gold capsules then run in a 0 5 inch 1 27 cm pistonexperimental studies of muscovite dehydration melting cylinder apparatus over the temperature interval 812 975 c reactions have been performed because the low temexperiments were conducted at 10 kbar to allow comparison with peratures of the reactions hinder the approach to equiother metapelite melting studies mass balance calculations imply librium in addition melt fractions generated are typically the melting reaction muscovite biotite plagioclase quartz low resulting in small melt pockets which are very difficult melt alkali feldspar aluminosilicate garnet until to analyze with the electron microprobe in this study muscovite is exhausted 812 c then the reaction biotite we assess the possible genetic relationship between the plagioclase quartz alkali feldspar aluminosilicate tourmaline bearing granites of the harney peak suite melt garnet the inferred muscovite reaction is completed below and the aluminous metasediments these granites intrude 812 c and produces 1 2 wt melt melt production of the although the attempt to investigate the muscovite decontinuous biotite reaction increases steadily with rising temperature hydration melting reaction was hindered by the surto 32 wt in our highest temperature run the low melt prisingly low melt productivity we were able to infer a productivity of the muscovite reaction at 10 kbar suggests that balanced reaction illuminating the dominantly peritectic melting at lower pressures may be necessary to generate mobile melt nature of fluid absent muscovite breakdown under the fractions by muscovite dominated reactions in our starting material conditions investigated in addition melts of hp 60 1 are considerably more mafic than isotopic and trace element studies indicate a genetic the tourmaline bearing granites with average combined tio2 relationship between s type granites and aluminous metamgo feo contents of 1 85 wt and 0 84 wt respectively sediments in the black hills of south dakota where the in particular melts of hp 60 1 are enriched in ti and would harney peak granite hpg intruded proterozoic and probably stabilize biotite rather than tourmaline upon cooling archean schists and metagreywackes undergoing regional arguing against hp 60 1 as a potential source rock for the metamorphism the timing and mode of emplacement of tourmaline granites the hpg and the deformation and regional metamorphic

lead isotopic evidence for mixed sources of proterozoic granites and pegmatites black hills south dakota usa abstract the lead isotopic compositions of k feldspars separated from the ca 1700 ma harney peak granite complex and spatially associated granitic pegmatites indicate that these rocks were derived from at least two sources it has been reported previously that the core of the harney peak granite complex is dominated by relatively lower gd18o avg 11 5 granites whereas higher gd18o avg 13 2 granites occur around the periphery of the complex the higher 18 o granites and one simple pegmatite have low values of 207 pb 204 pb for their 206 pb 204 pb thus they likely were derived from a source with a short crustal residence time this source may have been the pelitic schists into which the harney peak granite complex and pegmatites were intruded feldspars from granites with lower gd18o values have significantly higher 207 pb 204 pb for their 206 pb 204 pb the data define a linear array with a slope equivalent to an age of ca 2 6 ga with t2 defined to be 1 7 ga such a slope could represent a mixing array or a secondary isochron for the source these low 18o granites could have been derived from a source with a high u pb and with a crustal residence beginning before the proterozoic the source s of these granites may have been a sediment derived from late archean continental crust the highly evolved tin mountain pegmatite has lead isotopic systematics intermediate between those of the two granite groups suggesting either a mixed source or contamination two late archean granites the little elk granite and the bear mountain granite had precursors with high u pb and low th u histories the th u history of the bear mountain granite is too low for this rock to have been an important component of the source of the proterozoic granites however crustal rocks with lead isotopic compositions similar to those of the little elk granite were an important source of lead for some of the proterozoic granitic rocks

the compaction of igneous and sedimentary rocks in many problems of interest to geology and soil mechanics a fluid moves through a solid matrix which is also being deformed in most cases of interest the effective viscosity of the matrix is many orders of magnitude greater than that of the percolating fluid and both form interconnected networks in three dimensions the partial differential equations governing such behaviour can now be obtained and a variety of simple model problems have been investigated some of the more surprising solutions contain solitary waves and compaction fronts some of the less exotic solutions are presently of more geological interest the mobility of volatile rich melts at melt fractions as small as 0 1 has important consequences for trace element geochemistry the geometry of layered intrusives appears to result from differential compaction of the crystal mush and the rates required can be used to estimate a viscosity of 3 x 10 18 pa s for an olivine matrix this value agrees excellently with laboratory experiments when proper account is taken of the grain size dependence compaction in sedimentary rocks results in overpressure when the porosity becomes sufficiently small and can also lead to the development of secondary porosity