isolation of diagenetic overgrowths on quartz sand grains for oxygen isotopic analysis abstract diagenetic overgrowths on detrital quartz sand grains in sandstones can be isolated for direct measurement of their oxygen isotope ratios interfacial materials between detrital cores and diagenetic overgrowths are dissolved by etching with dilute hf the weakened interface breaks when grains are agitated ultrasonically subsequent particle size separation is an effective means of concentrating the diagenetic component

diagenesis and hydrocarbon accumulation brent sandstone jurassic bergen high area north sea diagenesis of brent group sandstones in the bergen high area was studied and related to the history of hydrocarbon maturation and pore fluid environment calcite and kaolinite are low temperature diagenetic precipitates that formed as meteoric pore water entered the brent at the end of brent deposition and later during late cimmerian erosion a major period of feldspar dissolution associated with quartz and illite cementation occurred at huldra field precipitation of diagenetic illite in brent sandstones was closely linked with hydrocarbon maturation in the adjacent viking graben and accumulation of generated fluids in traps at structural highs at huldra field illite k ar ages suggest onset of illite diagenesis in the latest cretaceous initial reservoiring of hydroca bons during the latest paleocene to early eocene 58 ma and filling of the reservoir by early oligocene 38 ma pore water character during illite diagenesis interpreted from oxygen isotope and quartz overgrowth fluid inclusion data was warmer than predicted by burial history analysis and one and a half to two times seawater salinity the incursion of saline isotopically evolved fluids at huldra suggests replacement of paleometeoric water by basin compaction fluid illite k ar ages from veslefrikk field indicate a minimum age of hydrocarbon accumulation at about 30 ma modern pore water chemistry in the brent at veslefrikk is unlike the suggested water chemistry at huldra and indicates that migrating compaction water did not completely displace older fresh connate water this sugge ts that hydrocarbons migrated into veslefrikk as a discrete phase without great volumes of associated compaction water

making diagenesis obey thermodynamics and kinetics the case of quartz cementation in sandstones from offshore mid norway calculation of the quantity and distribution of quartz cement as a function of time and temperature depth in quartzose sandstones is performed using a coupled dissolution diffusional transport precipitation model this model is based on the assumptions that the source of the silica cement is quartz surfaces adjoining mica and or clay grains at stylolite interfaces within the sandstones and the quantity of silica transport into and out of the sandstone by advecting fluids is negligible integration of the coupled mass transfer transport equations over geologically relevant time frames is performed using the quasi stationary state approximation results of calculations performed using quartz dissolution rate constants and aqueous diffusion coefficients generated from laboratory data are in close agreement with both the overall porosity and the distribution of quartz cement in the middle jurassic garn formation only after optimizing the product of the effective surface area and quartz precipitation rate constants with the field data when quartz precipitation rate constants are fixed to equal corresponding dissolution rate constants the effective surface area required to match field data depends on the choice of laboratory generated quartz rate constant algorithm and ranges from 0 008 cm 1 to 0 34 cm 1 in either case these reactive surface areas are 2 to 4 orders of magnitude lower than that computed using geometric models

quartz cementation in late cretaceous mudstones northern north sea changes in rock properties due to dissolution of smectite and precipitation of micro quartz crystals abstract late cretaceous mudstones from two wells located in the northern north sea and the norwegian sea have been examined with respect to quartz cement two different types of quartz cement type 1 and type 2 have been identified using sem eds cl analysis of drill bit cuttings at depths 2370 2670 m 80 85 c type 1 appears as relatively large aggregates 30 100 m of depth temperature related crypto or microcrystalline to macrocrystalline irregular quartz cement formed by local re crystallization of biogenic silica the cl responses of type 1 quartz cement give a clear indication of an authigenic origin type 2 quartz cement represents relatively high amounts of extremely fine grained micro sized 1 3 m crystals embedded as discrete short chains or small clusters nests within the illitized clay matrix the cl responses of micro quartz crystals indicate an authigenic origin the micro quartz is most probably sourced from silica released during the smectite to illite dissolution precipitation reaction the petrographic evidence indicates that most of the silica released by the smectite to illite reaction has not been exported out of the mudstones the silica released produce a subtle inter connected micro quartz network interlocked with aggregates of micro quartz and authigenic clay crystals this micro quartz cementation process causes a significant and sharp change in the mudstone stiffness at the onset of the chemical compaction regime this is indicated by an abrupt increase in well log velocity vp and change in seismic facies close to 2500 m 80 85 c

diagenesis and formation water chemistry of triassic reservoir sandstones from southern tunisia the fluvial triassic reservoir subarkoses and arkoses 2409 5 2519 45 m of the el borma oilfield southern tunisia were subjected to cementation by haematite anatase infiltrated clays kaolinite and k feldspar at shallow burial depths from meteoric waters subsequently basinal brines controlled the diagenetic evolution of the sandstones and resulted initially in the precipitation of quartz overgrowths magnesian siderite minor ferroan magnesite and anhydrite the enrichment of siderite in 12c isotope 13cpdb 14 5 to 9 results from derivation of carbon from the thermal decarboxylation of organic matter during further burial the precipitation of dickite and pervasive transformation of kaolinite into dickite occurred followed by the formation of microcrystalline k feldspar and quartz chlorite and illite prior to the emplacement of oil present day formation waters are na ca cl brines evolved by the evaporation of seawater and water mineral interaction and are in equilibrium with the deep burial 3 1 km minerals these waters are suggested to be derived from the underlying silurian and devonian dolomitic mudstones

intratest oxygen isotope variability in the planktonic foraminifer n pachyderma real vs apparent vital effects by ion microprobe abstract intratest oxygen isotope variations in the planktonic foraminifer neogloboquadrina pachyderma sinistral left coiling from north atlantic core top and multi net samples were assessed by ion microprobe analysis from 2 to 6 m spots with precision and accuracy better than 0 7 in 18 o 2 sd within a single foraminiferal test from a core top sample comprising both ontogenetic calcite and outer crust 18 o values vary from 0 5 to 3 7 pdb exceeding the range of equilibrium 18 o in the specimens habitat by a factor of three the isotopic difference between the ontogenetic calcite and the crust averages 1 8 neither of the two types of foraminiferal calcite precipitates in equilibrium with ambient seawater the ontogenetic calcite exhibits a negative vital effect 18 o m e 18 o measured 18 o equilibrium ranging from 0 5 to 1 the largest negative fractionation is associated to the inner walls of juvenile chambers in contrast a positive vital effect of about 0 8 was observed in the crust with respect to the highest equilibrium 18 o values at water depths below 200 m hence two vital effects that are opposite in sign are effective within a single foraminiferal test indicating that whole test values of this species are highly sensitive to the degree of encrustation and amplify or attenuate environmental signals the negative vital effect of the ontogenetic calcite was verified by ion microprobe analysis of four nonencrusted net sampled specimens reflecting three different depth intervals intra ontogenetic oxygen isotope ratios in these juvenile tests range from 0 6 to 3 0 and exhibit a negative vital effect even larger than that observed in core top samples based on these data the large range of apparent vital effects reported for this foraminiferal species can be assessed by a mass balance calculation assuming that the degree of encrustation is variable

an integrated thermal and isotopic study of the diagenesis of the brent group alwyn south u k north sea abstract the petrography fluid inclusion thermometry and isotope geochemistry of diagenetic cements are used to reconstruct the pore fluid history of the middle jurassic brent group reservoir sandstones in the alwyn south area of the u k north sea the study focuses on a relatively limited area of three adjacent reservoir compartments at successively higher structural levels the cement assemblage of kaolinite quartz and illite has resulted in severe deterioration of otherwise good reservoir quality early precipitation of vermiform and late blocky kaolinite was succeeded by a period of relatively intense illite precipitation temperature estimates for kaolinite precipitation of 80 c and 18o of 15 3 suggest co existing fluids of 18o 3 quartz cementation overlapped both kaolinite and illite formation fluid inclusion data indicate that quartz cementation took place at temperatures of 109 7 c pore fluid salinities were 4 wt nacl with a h2o o isotopic composition of 1 o 0 5 smow the fluids which precipitated coexisting illite were compositionally homogeneous with equilibrium 18o water compositions of 0 5 smow illite sd values range from 33 to 50 smow these fluid inclusion and isotopic data suggest that both quartz and illite were precipitated from pore waters with a uniform marine signature this is consistent with the predominantly marine to paralic depositional context of the brent group in alywn south illite precipitation was followed by hydrocarbon emplacement between the middle eocene and lower oligocene

optically continuous silcrete quartz cements of the st peter sandstone high precision oxygen isotope analysis by ion microprobe a detailed oxygen isotope study of detrital quartz and authigenic quartz overgrowths from shallowly buried 1 km quartz arenites of the st peter sandstone in sw wisconsin constrains temperature and fluid sources during diagenesis quartz overgrowths are syntaxial optically continuous and show complex luminescent zonation by cathodoluminescence detrital quartz grains were separated from 53 rocks and analyzed for oxygen isotope ratio by laser fluorination resulting

evolution of quartz cementation during burial of the cambrian mount simon sandstone illinois basin in situ microanalysis of δ18o the thermal mechanical and chemical evolution of a sedimentary basin exerts important controls on porosity and permeability of reservoir rocks oxygen isotope ratios of individual diagenetic cements record evidence of this history but cannot be analyzed accurately by conventional techniques recent improvements for in situ analysis by ion microprobe provide high precision and accuracy at a scale of 5 10 m in combination with cathodoluminescence imaging in situ analysis of 18 o quartz from the cambrian mount simon sandstone in the illinois basin usa reveals gradients within single overgrowths of as much as 7 7 50 m while the inner portions of overgrowths remain approximately constant in 18 o across the basin the 18 o of the rim becomes lower with depth these data suggest that overgrowths formed during burial and heating possibly with minimal changes in 18 o of pore fluids if 18 o h 2 o 3 the highest temperature calculated for the rim of an overgrowth is 107 c at a paleodepth of 3 5 km the variability both in average 18 o of overgrowths and patterns from individual overgrowths corresponds with a geotherm of 30 c km and there is no evidence of quartz precipitation from higher temperature hydrothermal fluids

sandstone reservoir quality prediction the state of the art joanna ajdukiewicz joined exxon production research company in 1980 she was reservoir quality assessment and prediction team lead there from 1991 to 1995 and at imperial oil research centre in calgary from 1995 to 1997 subsequently she has worked a variety of exploration company assignments in the north sea gulf of mexico and middle east her current interests are in predicting the distribution of early diagenetic controls on deep reservoir quality rob lander develops diagenetic models for geocosm llc he obtained his ph d in geology from the university of illinois in 1991 was a research geologist at exxon production research from 1991 to 1993 and worked for rogaland research and geologica as from 1993 to 2000 he is also a research fellow at the bureau of economic geology to guess is cheap to guess wrongly is expensive chinese proverb reservoir quality predictive models will be a useful element of risk analysis until remote sensing tools are invented that accurately measure effective porosity and permeability ahead of the bit this issue of the aapg bulletin highlights recent advances in a new generation of reservoir quality models that have successfully predicted porosity and permeability in diverse siliclastic reservoirs under many different burial conditions most previous attempts at predrill reservoir quality prediction have relied on empirical correlations or on first principle geochemical simulations that incorporate laboratory derived input parameters wood and byrnes 1994 the new reservoir quality models differ from previous approaches in that although incorporating theory inspired algorithms they include terms with values that are explicitly designed to be calibrated by and tested against data sets of high quality petrographic analyses that are linked to thermal and effective stress histories petrographic observations therefore provide essential constraints in these models on the types timing and rates of key geologic processes affecting sandstone pore systems this approach avoids the pitfalls inherent

origin of quartz cements in some sandstones from the jurassic of the inner moray firth uk the extent of quartz cementation in shallow marine sandstones of the brora arenaceous formation oxfordian is closely related to the occurrence and abundance of rhaxella perforata sponge spicules three cement morphologies are identified chalcedonic quartz microquartz and mesoquartz chalcedonic quartz forms matrix supported cements which preserve moulds of rhaxella spicules chalcedonic quartz crystals have inequant development of crystal faces on average 0 1 m in diameter and are the first formed cement and reveal homogeneous dark grey tones on the sem cl bei microquartz forms 5 10 m diameter crystals which commonly grow on chalcedonic quartz substrates and show various grey tones under sem cl bei mesoquartz crystals grow in optical continuity with their host grains have 20 m a axial diameter crystals and exhibit distinctly zoned luminescence although no opaline silica is preserved the quartz cement is interpreted to have formed from an opaline precursor detrital quartz has an average 18o composition of 12 2 and mesoquartz syntaxial overgrowth has an average 18o composition of 20 0 estimates of the 18o compositions of microquartz and chalcedonic quartz are complicated by the problem of isolating the two textural types mixtures of the two give consistently higher 18o compositions than mesoquartz the higher estimate being 39 2 from oxygen isotope data the formation of quartz microquartz and chalcedonic quartz is interpreted to have taken place between 35 and 71 c in marine derived pore waters organic and inorganic maturation data constrain the upper temperature limit to less than 60 c

quantification of quartz cements using combined sem cl and image analysis quartz cement content is often difficult to quantify using conventional petrography developments in equipment and technique reported here show how excellent high contrast images of quartz cements can be produced using combined scanning electron microscopy and cathodoluminescence sem cl in most cases quartz cement can be differentiated readily from detrital quartz image analysis allows the percentage of authigenic quartz to be quantified advantages of this method are 1 it can be readily automated 2 backscatter electron bse and cl images can be compared directly and 3 images can be improved through acquiring and integrating multiple images comparison of results from conventional optical petrography with those from sem cl suggests that the percentages of quartz cement determined by conventional methods are overestimated where quartz cement is present in high proportions and are underestimated where quartz cement is less abundant by adopting a statistically rigorous approach to image collection the abundance of quartz cement can be determined by sem cl with a known accuracy

clay mineral diagenesis and quartz cementation in mudstones the effects of smectite to illite reaction on rock properties abstract the late cretaceous to early tertiary sequence of the voring and more basins from the norwegian sea has been examined with respect to mineralogy based on 319 cutting samples from five wells a clear relationship between mineralogy and well log data is demonstrated a significant change with respect to velocity porosity and density occurs within the depth interval corresponding to 80 90 c at shallow depths temperatures

pore water evolution in oilfield sandstones constraints from oxygen isotope microanalyses of quartz cement abstract oxygen isotope microanalyses of authigenic quartz in combination with temperatures of quartz precipitation constrained by fluid inclusion microthermometry and burial history modelling are employed to trace the origin and evolution of pore waters in three distinct reservoirs of the brae formation in the miller and kingfisher fields north sea oxygen isotope ratios of quartz cements were measured in situ in nine sandstone thin sections with a cameca ims 4f ion microprobe in conjunction with quartz cement paragenesis in the reservoirs constrained from textural and cathodoluminescence cl microscopy studies pore water evolution was reconstructed from the time of deposition of the sandstones in the upper jurassic until the present cl photomicrographs of quartz overgrowths in the brae formation sandstones show three cement zones a b and c which can be related to different oxygen isotope compositions 1 the earliest and thinnest zone a homogeneous cl pattern with probable 18 o values between 23 and 26 direct measurements were not possible precipitated in the sandstones at temperatures 18 o values between 15 and 18 precipitated in the sandstones most likely between 70 and 90 c 3 the third zone c homogeneous cl pattern and directly measured 18 o values between 16 and 22 precipitated in the sandstones most likely at temperatures 90 c calculated oxygen isotope compositions of pore waters show that zone a quartz cements and enclosing concretionary calcite precipitated from a meteoric type fluid 7 during shallow burial 18 o 7 to a more 18 o enriched fluid 18 o 4 as burial continued to 3 0 km data from zone c quartz cements are consistent with further fluid evolution from 18 o 4 to basinal type fluids with 18 o similar to the present day formation water oxygen isotope composition 0 6 at 4 0 km burial a similar pore water evolution can be derived for all three reservoirs studied indicating that hydrogeologic evolution was similar across sandstones of the whole brae formation the quartz cement zones observed in the brae formation sandstones and the pore water history derived for the area studied is analogous to published petrographic and pore water evolution data from the nearby brent group reservoirs and from reservoirs located in the haltenbanken area on the atlantic margin offshore norway considering quartz cement is a major porosity occluding phase in many reservoir sandstones and because pore waters both dissolve quartz and carry the dissolved silica to cementation sites the data presented are valuable for improving the understanding and prediction of reservoir quality development in sandstones globally

evidence for resetting of fluid inclusion temperatures from quartz cements in oilfields abstract quartz is a major pore occluding cement in north sea oilfield reservoir sandstones fluid inclusions yield homogenization temperatures t h which have been thought to represent growth temperatures for the host quartz however early diagenetic inclusions from the detrital grain overgrowth boundary yield excessively high palaeotemperatures which do not match the growth temperatures calculated from the depth of cementation the temperatures of these inclusions increase with present day depth of burial and approach present day reservoir temperatures this suggests that the inclusions have begun to reset towards present day pressure temperature conditions the t h of the inclusions hence represent burial temperatures rather than growth temperatures for the quartz experimental studies indicate that the amount of resetting undergone by an inclusion varies depending on its size shape and fluid composition a relationship between inclusion t h and these variables has been observed in inclusions from deeply buried quartz cements in the north sea

burial diagenesis of illite smectite in shales and the origins of authigenic quartz and secondary porosity in sandstones several gram size samples of 0 1 mu m nearly monomineralic mixed layer illite smectite i s were isolated from nineteen whole cores of shale of the frio formation from the texas gulf coast between approximately 7 000 ft 2133 m and approximately 15 000 ft 4572 m burial depth i s changes from random interstratification r 0 with low 1 to ordered interstratification r 3 with high i the accompanying chemical changes are loss of si mg and fe sup 3 gain of k al and fe sup 2 and a shift in the ree content of the mineral there is no chemical or mineralogical evidence for a cessation of i s reaction at approximately 80 i as is commonly accepted both chemical and mineralogical changes occur throughout burial continuous change in the oxygen isotopic composition of i s implies that the conversion of smectite layers to illite layers is a dissolution and reprecipitation process mass balance calculations indicate that burial diagenesis of frio formation shales is an open system process that requires addition of k sub 2 o and al sub 2 o sub 3 and results in loss of sio sub 2 the amount of sio sub 2 made available by shale diagenesis is sufficient to be the source of the quartz overgrowth cements in the associated frio sandstones iron reduction in i s is amore significant source of the acid required for the diagenesis of both frio shales and sandstones 68 refs 12 figs 4 tabs less

environmental reconstruction and dating of shizitan 29 shanxi province an early microblade site in north china global cooling during the last glacial maximum lgm posed significant challenges to peoples living in northern eurasia using micromorphology pollen and non pollen palynomorphs npp and faunal analyses this study reconstructs the local paleoenvironmental contexts of repeated ephemeral occupations at shizitan 29 in shanxi province north china across the lgm from ca 28 to 18 ka cal bp followed by a gap until a final occupation ca 13 5 ka cal bp among the significant finds at shizitan 29 are remains of 285 hearths and a rich lithic assemblage that contains the earliest radiocarbon dated evidence for microblades in china appearing first in layer 7 the environmental data show that the low mountains and tributary river valleys of the yellow river in the loess plateau provided abundant sources of water and food in spite of environmental fluctuations microblade producing groups repeatedly visiting this locality survived severe climate change by making use of fire selective herbivore hunting processing plant foods with grinding stones and symbolic ornamentation such as ostrich shell beads npp data also indicate the potential presence of flax and other fiber processing the shizitan 29 data demonstrate how humans adapted to challenging local conditions throughout the lgm allowing them to stay within this northerly region without migrating to warmer southern latitudes

conditions and timing of quartz cementation in brent reservoirs hild field north sea constraints from fluid inclusions and sims oxygen isotope microanalysis abstract the conditions and timing of quartz cementation in the brent sandstones in the hild field norwegian north sea were constrained on the basis of oxygen isotope microanalysis and fluid inclusion microthermometry combined with optical and cathodoluminescence cl microscopy studies samples of the tarbert and the ness formations were investigated in three different wells presently lying at 3 8 4 3 km subsea and at 140 155 c quartz cement is present in all wells abundance varies from 3 to 26 and tends to increase with depth of burial two distinct separate episodes of quartz cementation referred to as q1 and q2 are readily distinguished by cl microscopy the two episodes are also recognized in the bimodal distribution of fluid inclusion temperatures and oxygen isotope microanalyses the data indicate that q1 quartz formed in the early tertiary 65 35 ma at 95 110 c and 2 3 3 0 km burial depth and that q2 mainly precipitated in the oligocene miocene 40 10 ma at 125 135 c and 3 1 3 7 km q1 quartz precipitation follows the onset of overpressuring in the reservoir while precipitation of q2 seems to slightly precede and accompany the main phase of oil filling 35 10 ma secondary ion mass spectrometry sims oxygen isotope microanalyses yield 18o values ranging from 17 to 25 averaging 23 2 for q1 and 19 5 1 5 for q2 calculated 18o values of quartz forming waters are similar for q1 and q2 ranging from 1 to 3 and are similar to the 18o value 2 of present day formation water in the reservoir quartz cementation in the brent reservoir of the hild field occurred during deep burial at high temperature from evolved 18o rich basinal water most likely derived from the viking graben two episodes of enhanced quartz precipitation are recorded around 100 c and 130 c no evidence was found for any significant contribution of 18o depleted jurassic meteoric water and or low temperature precipitation of quartz cement

oxygen isotopic indications of the mechanisms of silica transport and quartz cementation in deeply buried sandstones the oxygen isotopic compositions and inferred precipitation temperatures of quartz cements in a suite of deeply buried sandstones from the north sea gulf coast and western canada basins indicate that in almost every case the quartz precipitated from 18 o rich basinal waters 18 o rich waters are found in strictly limited volumes in sedimentary basins silica transport and quartz cementation could not therefore have occurred as a result of large scale advection of basinal or meteoric waters because this would require very large fluid fluxes quartz cementation was driven by processes operating on a local scale the isotopic data do not uniquely indicate the mechanisms of silica transport but are consistent with both diffusion and local recycling of fluid

new evidence for the origin of quartz cements in hydrocarbon reservoirs revealed by oxygen isotope microanalyses quartz cements degrade hydrocarbon reservoir quality by choking off fluid flow paths therefore it is important to understand the sources and timing of quartz cementation we present in situ microanalyses of oxygen isotope ratios in quartz cements from a jurassic hydrocarbon reservoir located offshore norway showing systematic variations that reveal the isotopic history of the pore fluids that precipitated the quartz earliest quartz cements have 18o values of 20 26 subsequent cements drop in 18o value as low as 13 but then increase back to 23 with increasing cement thickness this isotopic trend was observed in multiple overgrowths with temperatures constrained by fluid inclusions and the burial history of the reservoir the isotopic composition of porewaters can be estimated from the measured isotopic ratios in quartz cement results indicate that 97 of the quartz cement precipitated from negative 18o waters originally meteoric that were gradually modified by burial diagenetic reactions as temperatures increased precipitation began in the middle to late cretaceous however the rate of quartz precipitation increased dramatically in the last 3 5 ma as the reservoir was rapidly buried the data show that quartz precipitation is a continuous process during burial and that silica is derived locally from silicate reactions occurring within the sandstone reservoir the isotopic data do not record evidence of episodic cementation from convection driven hot basinal fluids

open system chemical behavior in deep wilcox group mudstones texas gulf coast usa abstract wilcox group mudstones have been mechanically and geochemically transformed over a temperature range of 20 200 c our research controlled for provenance and age by sampling from five wells parallel to the paleodepositional axis all within the houston delta system across the sampled depths mudstone porosity has been reduced from 25 to

oxygen isotopic analysis of diagenetic quartz overgrowths from the brent sands a comparison of two preparation methods abstract two preparation methods used for determining the 18o of quartz overgrowths are compared from the sandstones of the middle jurassic brent group northern north sea method one uses dilute hf to preferentially attack interfacial materials present between the overgrowth and the detrital core with subsequent ultrasonic agitation used to break the overgrowths off at the weakened contacts size fractionation by sieving should concentrate overgrowths into the smaller grain size separates in the brent sands studied however little interfacial material is present between overgrowth and core and the overgrowths are thinly developed average width 20 50 microns concentration of the diagenetic overgrowths is therefore difficult this difficulty is compounded by large amounts of detrital quartz in the size fractions as a result of internal fracturing of the grains the 18o smow values for the finest size fraction supposedly overgrowth rich ranging from 9 to 13 3 are unusually low for diagenetic quartz overgrowths and result from the high detrital component the second method derives the 18o values for the overgrowths by the difference in 18o for the quartz grains plus overgrowths and quartz grains from which the overgrowths have been removed by hf dissolution the mass balance used requires the overgrowth abundance to be known from point counting the calculated 18o values obtained are typical for authigenic quartz overgrowths and range from 17 1 to 20 9 direct isolation of quartz overgrowths for 18o measurement is suitable where interfacial material exists between the detrital grain and the overgrowth and where overgrowths are well developed otherwise preferential hf dissolution of the overgrowths and a 18o mass balance calculation is the preferred method

development of early diagenetic silica and quartz morphologies examples from the siri canyon danish north sea abstract the siri canyon has proved to be a perfect area for investigating various morphologies of diagenetic silica in sandstones the development in silica morphologies can be observed from very shallow 1700 m to increased burial depth 3000 m and increased proximity to the central graben distance from 0 to 65 km hydrocarbons and pore fluids now found in the siri fairway have at least partly originated from the central graben the siri canyon is a submarine canyon system eroded into the uppermost chalk deposits and filled with palaeogene hemipelagic and turbiditic marls and mudstones interbedded with sandstone units deposited from sandy mass flows and sandy turbidites which originated on the stavanger platform several hydrocarbon exploration and production wells have been drilled in the siri canyon seven of which are included in this study nini 3 nini 1 na 2p sofie 1 siri 4 celilie 1a and augusta 1 the reservoir sandstones in these wells all contain authigenic silica of various morphologies identified with a combination of traditional optical microscopy and scanning electron microscopy the silica morphologies in some places are classic and well documented in the literature whereas others at least to our knowledge have never previously been described some of the silica morphologies presented here show gradual transition from one to another and others are stand alone forms without clear relationships to other forms the silica morphologies can be expressed in the following way 1 opal rims characteristic of the initial phase of the silica diagenesis in most sandstone units in the siri canyon thick opal rims characterise the sandstone parts adjacent to the mudstone units in the stine segment of the siri field 2 microquartz quartz crystals with a size of 1 5 m seen as coatings on the opal rims both ordered and random 3 cavity overgrowth found as quartz outgrowths in circular and angular cavities formed by dissolution of early authigenic phases angular cavities in the microquartz coatings origin from dissolution of clinoptilolite possibly with a source in volcanic ash whereas dissolution of lepispheres probably resulted in circular cavities 4 quartz ridges syntaxial quartz overgrowths a few micro millimetre in width in parallel lines defined in this paper 5 quartz mountains syntaxial irregular 5 10 m large quartz crystals defined in this paper developed in the water filled sandstone intervals where fluids from the central graben were introduced possibly together with the hydrocarbon and where the continued growth was not retarded by the presence of hydrocarbons in the pore fluids 6 macroquartz syntaxial quartz overgrowths 20 m seen as continued growths from quartz mountains this takes place in the deeper reservoir sandstones promoted by fluids originating from the central graben and increased burial depth 7 quartz with sutured grain contacts occurring only in the deepest well 3000 m

quartz cementation history of sandstones revealed by high resolution sims oxygen isotope analysis abstract evaluating the timing and origin of quartz cement is central to understanding how porosity is lost in sandstones during burial kinetic models of quartz cementation have been calibrated using large scale datasets but have never been tested at the microscopic level at which cement forms here we use high precision in situ oxygen isotope analyses on sandstone from the jurassic ness formation from the north sea to reveal the growth history of single quartz overgrowths to a resolution of 2 m measured 18o cement range from 28 to 20 v smow in early to late cement and are consistent with quartz cementation models that propose the bulk of quartz precipitates as a continuous process beginning at 60 70 c quantitative x ray diffraction analyses and clay mineralogical analysis of interbedded shales are inconsistent with a silica source from shale implying that silica for the cement is sourced internally to the sand these isotope data are broadly consistent with predictive conceptual quartz cementation models and provide a critical link from micron scale measurements to basin scale predictions and observations

dating diagenesis in a petroleum basin a new fluid inclusion method the final porosity and permeability of sandstone petroleum reservoirs is greatly affected by the diagenetic growth of minerals after deposition for example a sand may be deposited with a porosity of 25 and a permeability of 5 000 mdarcy md 1 diagenetic growth of quartz around detrital sand grains may leave a rock with only 10 porosity and later growth of clays may partly fill these remaining pores and block inter pore connections reducing permeability to 100 md ref 2 if the depth and timing of such diagenetic alteration can be measured and the extent of diagenesis estimated then prediction of the diagenetic state of undrilled sandstones may become possible and diagenesis related more closely to the timing of hydrocarbon migration and the formation of hydrocarbon traps we present an example of a new method for estimating the date of quartz diagenesis using a combination of techniques from thin section petrography fluid inclusion thermometry organic geochemical thermometry and sedimentary basin stratigraphic analysis these results suggest that quartz in the beatrice oilfield was precipitated from moving and cooling pore fluids at a temperature between 68 c and 94 c in the late jurassic

ion microprobe analysis of 18o 16o in authigenic and detrital quartz in the st peter sandstone michigan basin and wisconsin arch usa contrasting diagenetic histories abstract the oxygen isotopic compositions of authigenic quartz cements in sandstones provide a monitor of the temperatures compositions and origins of pore occluding fluids during diagenesis but quartz overgrowths are too fine grained to be amenable to conventional isotopic analysis we have used a cameca ims 4f ion microprobe to determine oxygen isotopic variations in authigenic and detrital quartz in four samples of the ordovician st peter sandstone from the michigan basin and wisconsin arch midwestern usa ion microprobe isotopic analyses have been successfully accomplished with an internal precision of 1 1 and a spatial resolution of 20 30 m at low mass resolution using a high voltage offset technique repeated analyses of the quartz standard demonstrate a reproducibility of close to 1 1 sd in good agreement with that expected from counting statistics the four ion probe samples were chosen as representative of thirteen samples that were mechanically and chemically disaggregated sieved and analysed as a function of sieve size by conventional bulk mineral techniques conventional and ion microprobe analyses are mutually consistent supporting the accuracy of the ion microprobe analyses within sample isotopic variations of up to 13 and micro scale isotopic variations of at least 4 over a distance of 100 m have been measured within quartz overgrowths in a sandstone from the wisconsin arch overgrowths are uniformly higher in 18o than detrital grains and gradients of up to 25 exist across a few microns 18o enriched quartz overgrowths in sandstones from the wisconsin arch show complex cl zonation and reflect one of two possible processes 1 low temperature quartz precipitation during mixing of meteoric waters with upwelling basinal fluids 2 higher temperature quartz precipitation during episodic gravity driven upwelling of warm basinal fluids of comparable isotopic composition to michigan basin fluids from the illinois basin related to evolution of mississippi valley type pb zn ore forming fluids quartz overgrowths in michigan basin sandstones which derived their silica locally by pressure solution are thought to have precipitated continuously over a range of temperatures from hot basinal fluids of restricted isotopic composition and circulation detrital quartz shows significant intea grain and intergrain isotopic variation 5 13 but no significant inter sample variation consistent with a uniform source of granitoid and metamorphic quartz in space and time

variation in metamorphic style along the northern margin of the damara orogen namibia the northern margin of the inland branch of the pan african damara orogen in namibia shows dramatic along strike variation in metamorphic character during convergence between the congo and kalahari cratons m3 metamorphic cycle low p contact metamorphism with anticlockwise p t paths dominates in the western domains ugab zone and western northern zone and high p barrovian metamorphism with a clockwise p t path is documented from the easternmost domain eastern northern zone the sequence of m3 mineral growth in contact aureoles shows early growth of cordierite porphyroblasts that were pseudomorphed to biotite chlorite muscovite at the same time as an andalusite biotite muscovite transposed foliation was developed in the matrix the peak t metamorphic assemblages and fabrics were overprinted by crenulations and retrograde chlorite muscovite the kfmash p t pseudosection for metapelites in the ugab zone and western northern zone contact aureoles indicates tight anticlockwise p t loops through peak metamorphic conditions of 540 570 c and 2 5 3 2 kbar these semi quantitative p t loops are consistent with average p t calculations using thermocalc which give a pooled mean of 556 26 c and 3 2 0 6 kbar indicating a high average thermal gradient of 50 c km in contrast the eastern northern zone experienced deep burial high p moderate t barrovian m3 metamorphism with an average thermal gradient of 21 c km and peak metamorphic conditions of c 635 c and 8 7 kbar the calculated p t pseudosection and garnet compositional isopleths in kfmash appropriate for the metapelite sample from this region document a clockwisep t path early plagioclase kyanite biotite parageneses evolved by plagioclase consumption and the growth of garnet to increasing xfe xmg and xca and decreasing xmn compositions indicating steep burial with heating the developed kyanite garnet biotite peak metamorphic parageneses were followed by the resorption of garnet and formation of plagioclase moats indicating decompression which was followed by retrogressive cooling and chlorite muscovite growth the clockwise p t loop is consistent with the foreland vergent fold thrust belt geometry in this part of the northern margin earlier formed 580 570ma pervasive matrix foliations m2 were overprinted by contact metamorphic parageneses m3 in the aureoles of 530 3ma granites in the ugab zone and 553 514ma granites in the western northern zone available geochronological data suggest that convergence between the congo and kalahari cratons was essentially coeval in all parts of the northern margin with similar ages of 535 530ma for the main phase of deformation in the eastern northern zone and northern platform and 538 505ma highgrade metamorphism of the central zone immediately to the south consequently nne ssw directed convergent deformation and associated m3 metamorphism of contrasting styles are interpreted to be broadly contemporaneous along the length of the northern margin of the inland branch in the west heat transfer was dominated by conduction and externally driven by granites whereas in the east heat transfer was dominated by advection and internally driven radiogenic heat production the ultimate cause was along orogen variation in crustal architecture including thickness of the passive margin lithosphere and thickness of the overlying sedimentary succession

origin and evolution of formation waters from oil fields on the norwegian shelf abstract stable isotopes of h and o and chemical analyses of formation waters from upper triassic jurassic clastic reservoirs and cretaceous carbonate reservoirs offshore norway are employed to interpret the origin and evolution of these waters in both types of reservoir the formation waters become progressively enriched in total dissolved solids and the heavy isotope of o with increasing depth whereas deuterium varies erratically between 20 and 40 smow bromine analyses and stable isotope data indicate that the formation waters are mixtures of a brine end member formed by evaporation of sea water beyond the point of halite saturation and meteoric water the chemical and isotopic composition of the formation waters and general geological considerations suggest that the brines originated as connate waters in permian evaporites and were later expelled into overlying strata there is a disequilibrium stable isotope distribution between the bulk chalk formations and the formation waters and only minor diagenetic modification of the formation waters appears to have taken place in these reservoirs the formation waters from the clastic reservoirs on the other hand are modified by diagenetic reactions