characterization of magma from inclusions in zircon apatite and biotite work well feldspar less so detrital zircon grains are employed to decipher sediment provenances and crustal evolution and they provide unique evidence of hadean crust mantle differentiation processes we demonstrate that mineral inclusions in zircon provide valuable information on the conditions under which zircon crystallized zircon grains from selected plutonic rocks from dronning maud land antarctica contain inclusions of apatite biotite amphibole and pyroxenes that accurately reflect the chemical compositions of the equivalent phases in the host rock matrix and the compositions of the whole rocks high concentrations of y and low concentrations of sr in apatite inclusions in zircon are diagnostic of evolved felsic granitoid host rocks in contrast the relative abundances and compositions of plagioclase and alkali feldspar inclusions in zircon are decoupled from the composition of the whole rock and they are generally indicative of granitic melts regardless of the bulk rock this is best explained by the late crystallization of zircon relative to the bulk of the feldspars we conclude that inclusions of apatite and mafic phases in zircon constrain the potential source rocks of detrital zircon whereas feldspar inclusions do not

mauna loa volcano is not a methane source implications for mars 1 thirteen years of continuous atmospheric carbon dioxide and methane measurements at the mauna loa observatory in hawaii are used to determine the methane emission rate from the summit of mauna loa volcano we find no measurable methane emissions coming from the summit area with a 95 confidence upper limit of 9 t ch4 yr 1 recent studies have detected 10 ppb ch4 in the martian atmosphere requiring emissions of about 300 t ch4 yr 1 volcanic activity has been suggested as a source of abiogenic ch4 on mars either by magmatic degassing or reactions in hydrothermal fluids heated by a magma intrusion the most recent lava flows on mars 2 my ago are on the tharsis shield volcanoes which may still be active if mauna loa is a valid terrestrial analog our findings suggest that volcanic activity is not a significant source of methane to the martian atmosphere

rapid mass wasting following nearshore submarine volcanism on kilauea volcano hawaii abstract the rapid mass wasting of shallow submarine basalts was documented during scuba dives along the flanks of kilauea volcano hawaii during the kii lava entry of the current eruption 19 20 5 n 154 59 8 w lava entered the ocean at this site from mid february to late march 1990 with several pauses dives on 19 20 march 1990 confirmed the widespread formation of lava pillows at this site over a water depth range of 20 40 m and visual observations suggested that the resulting volcanic deposits were generally stable despite the steep 40 incline of the seafloor the pre eruptive nearshore seafloor slope was 14 however dives on 2 april 1990 revealed that nearly all submarine volcanic features had been subject to mass wasting as the offshore area had been transformed into a debris field composed of material ranging in size from fine sand to boulder fragments this generally featureless seascape extended uniformly to beyond the visual range of divers 60 m water depth high resolution multibeam bathymetry and sidescan imaging indicate that steeply sloped coarse sediment extends down the flanks of kilauea in this area to abyssal depths implying a linkage between nearshore submarine volcanism and deep water deposits

apatite composition tracing petrogenetic processes in transhimalayan granitoids apatites crystallized from different types of igneous rocks show significant variations in the abundances of some minor and trace elements in this study electron probe microanalysis and laser ablation inductively coupled plasma mass spectrometry were used to determine the concentrations of 25 minor and trace elements in apatite separated from three principal rock types of thetranshimalayan igneous plutonic suite s type granites the i type gangdese batholith and postcollisional adakites f mn sr and rare earth elements ree in apatite vary systematically with the composition of the host magma and thus have high potential as petrogenetic tracers more specifically the f and mn contents of apatite can be used as an indicator of magma aluminosity or differentiation index combined with sr and ree data which show significant variations in apatite from different rock types these elements are useful for constructing discrimination diagrams this study also reveals that apatite has the capacity to retain geochemical information about the host magma through the course of magmatic evolution systematic variations of sr and ree in apatite with bulk rock aluminosity are the results of partition competition with pre existing and coexisting major and accessory minerals in silicate melts and thus are useful for more detailed investigations of petrogenetic processes such as fractional crystallization and magma mixing which is signaled by inconsistent eu anomalies sr abundances and ree patterns relative to bulkrock compositions

trace element degassing and enrichment in the eruptive plume of the 2000 eruption of hekla volcano iceland during its last eruption in february 2000 hekla volcano iceland emitted a sub plinian plume that was condensed and scavenged down to the ground by heavy snowstorms offering the unique opportunity to study the chemistry of the gaseous plume released during highly explosive eruptions in this paper we present results on trace element and minor volatile species sulfates chlorides and fluorides concentrations in snow samples collected shortly after the beginning of the eruption the goal of this study is to better constrain the degassing and mobility of trace elements in gaseous emissions trace element volatility at hekla is quantified by means of enrichment factors ef relative to be well known volatile trace elements e g transition metals heavy metals and metalloids are considerably enriched in the volcanic plume of hekla their abundances are governed by the primary magmatic degassing of sulfate and or halide compounds which are gaseous at magmatic temperature their volatility is however slightly lower than in basaltic systems most likely because of the lower magma temperature and higher magma viscosity at hekla more surprisingly refractory elements e g ree th ba and y are also significantly enriched in the eruptive plume of hekla where their apparent volatility is two orders of magnitude higher than in mafic systems in addition ree patterns normalized to the hekla 2000 lava composition show a significant enrichment of hree over lree suggesting the presence of ree fluorides in the volcanic plume such enrichments in the most refractory elements and ree fractionation are difficult to reconcile with primary degassing processes since ree fluorides are not gaseous at magma temperature ree enrichments at hekla could be attributed to incongruent dissolution of tephra grains at low temperature by f rich volcanic gases and aerosols within the eruptive plume this view is supported by both leaching experiments performed on hekla tephra and thermodynamic considerations on ree mobility in hydrothermal fluids and modeling of glass dissolution in f rich aqueous solutions tephra dissolution may also explain the observed enrichments in other refractory elements e g th y and ba and could contribute to the degassing mass balance of some volatile trace elements provided they are mobile in f rich fluids it thus appears that both primary magmatic degassing and secondary tephra dissolution processes govern the chemistry of eruptive plumes released during explosive eruptions

determining accurate temperature time paths from u pb thermochronology an example from the kaapvaal craton southern africa thermochronology has revolutionized our understanding of the establishment and evolution of lithospheric thermal structure however many potential benefits provided by the application of diffusion theory to thermochronology have yet to be fully exploited this study uses apatite tc 450 550 c and titanite tc 550 650 c u pb id tims thermochronology at the single to sub grain scale to separate the variable effects of volume diffusion of pb from metamorphic over growth above and below the tc of a mineral data are presented from two ca 3227 ma tonalite samples from north and south of the barberton greenstone belt bgb southern africa two distinct populations of apatite from a sample north of the bgb record fast cooling followed by metamorphic growth 10 myr later both apatite and titanite dates from south of the bgb show a strong correlation with the grain size and record 100 myr of post emplacement cooling complex core rim zoning observed in cathodoluminescence images of apatite is interpreted to reflect metamorphic overgrowth above the tc the age and topology of grain size versus date curves from titanite and apatite are used in combination with a finite difference numerical model to show that slow non linear cooling and not thermal resetting is responsible for the observed distribution the thermal histories from either side of the bgb are very different and provide unique insight into the bgb s tectonic evolution a 70 myr period of apparent stability after ca 3 2 ga terrane assembly was followed by fast exhumation south of the bgb that led to lower crustal melting and intrusion of granitic batholiths ca 3 14 3 10 ga

apatite chemical composition determined by electron microprobe and laser ablation inductively coupled plasma mass spectrometry as a probe into granite petrogenesis abstract major minor and trace element abundances in apatites from various i and s type igneous and sedimentary granites of the lachlan fold belt have been determined using electron microprobe and laser ablation inductively coupled plasma mass spectrometer the results show that apatite can accommodate many minor and trace elements whose concentrations and ratios are relatively sensitive to factors controlling many of the fundamental differences between i and s type granites apatites from s type granites generally have higher f but lower cl contents than those from i type granites which is ascribed mainly to the loss of cl during the weathering processes forming the source rocks of s type granites although fractional crystallisation can cause significant enrichment in f as well high mn and fe contents in apatites from s type granites and high s and as abundances in apatites from mafic i type granites result from different oxygen fugacities and degrees of al saturation or aluminosity between metaluminous mafic i type magmas and peraluminous s type and felsic i type magmas there are systematic and distinctive differences in absolute rare earth element ree abundances ree distribution patterns and element ratios e g la y sm nd etc between apatites from different types of granite the strong eu depletion that characterises apatites from s and felsic i type granites is interpreted here to be a result of the uniqueness of crystal chemistry of apatite and high eu2 eu3 ratios in s type and felsic i type magmas which are more reduced and peraluminous than mafic i type magmas strong ree la to eu and th enrichment in apatites from mafic i type granites and marked nd depletion in apatites from most s type and felsic i type granites are caused by the precipitation and fractionation of monazite in the parental magmas of the latter rocks substitution mechanisms are responsible for high na in apatites from s type and felsic i type granites and for high si in apatites from mafic i type granites and may also have important effects on ree partitioning between apatite and melt thus apatite chemistry can be used as an excellent indicator of granite petrogenesis the results have important implications for identifying different types of granite and are potentially significant for determining the provenance of sedimentary rocks

comment on paper morphology and compositions of spinel in pu u ō ō lava 1996 1998 kilauea volcano hawaii enigmatic discrepancies between lava and gas based fo2 determinations of pu u ō ō lava

metamorphic formation of sr apatite and sr bearing monazite in a high pressure rock from the bohemian massif accessory 10 300 m grains of sr apatites with sro contents up to 33 wt were found in a high pressure 26 3 kbar 830 30 c garnet rich rock from the bohemian massif czech republic furthermore this rock contains unusual sr bearing accessory monazite sro up to 2 wt it is argued that the sr apatite and the sr bearing monazite formed as a result of plagioclase breakdown during hp metamorphism during a subsequent phase of near isothermal decompression and partial retrogression of the hp paragenesis at 8 2 kbar and 800 900 c many apatites have lost their sr through diffusion to newly formed plagioclase some of which accommodated sro contents of ca 7 wt at apatite plagioclase contacts a distribution coefficient c p l s r c a p s r of ca 4 was measured implying that in plagioclase bearing rocks i e most crustal rocks sr apatites have little chance to form in the investigated rock only apatites enclosed and shielded in unretrogressed garnet were able to preserve high sr despite strong compositional differences from grain to grain individual apatites are homogenous with respect to contents of sr as well as ree and y showing that at ca 800 c rapid diffusion must have taken place in contrast to the apatites monazite grains inside and outside of garnet were both equally sr bearing lacking any signs of a secondary diffusion related sr depletion even in the most marginal zones this observation in conjunction with an occasionally preserved growth zoning illustrates the status of monazite as a slow diffusion mineral therefore sr bearing monazite potentially may be an important long term indicator of a hp history of rock units or terranes

an apatite for progress inclusions in zircon and titanite constrain petrogenesis and provenance apatite has recently gained considerable attention as a mineral with many uses within the earth and planetary sciences apatite chemistry has recently given new insight into a wide range of geological processes and tools for example magmatism metasomatism planetary geochemistry and geochronology we expand the utility of apatite here by presenting a novel way to fingerprint magma chemistry and petrogenesis using apatite inclusions within robust titanite and zircon we present trace element data from apatite mineral inclusions shielded within magmatic zircon and titanite importantly apatite inclusion and host titanite chemistries detailed in this study allow estimation of the whole rock sr and sio2 we show how these data can be used to assess the degree of fractionation of the host magma and to calculate key trace element abundances and ratios we demonstrate that the inclusions can be linked to discrete periods in the crystallization history of the host phases thus providing insight into petrogenesis the results highlight that apatite compositions might discriminate modern granitoids younger than 2 5 ga from archean proterozoic transitional granitoid compositions sanukitoid signatures development of such a petrological tool has important potential for interpretation of provenance and a better understanding of the secular evolution of the continental crust including that of early earth

ferric ferrous ratios h 2 o contents and d h ratios of phlogopite and biotite from lavas of different tectonic regimes complete chemical analyses including ferric and ferrous iron h2o contents and dd values for 16 phlogopite and biotite and 2 hornblende separates are presented samples were obtained from volcanic rocks from four localities 1 phlogopite phenocrysts from minette lavas from the western mexico continental arc 2 biotite and hornblende phenocrysts from andesite lavas from mono basin california 3 phlogopite and biotite from clinopyroxenite nodules entrained in potas sic lavas from the east african rift uganda and 4 phlogopite phenocrysts from a wyomingite lava in the leucite hills wyoming the fe 2 o 3 contents in the mi cas range from 0 8 to 10 5 wt corresponding to 0 09 to 1 15 fe 31 per formula unit pfu water contents vary from 1 6 to 3 0 wt corresponding to 1 58 to 3 04 oh pfu significantly less than would be expected for a site fully occupied by hydroxyl cation and anion based normalization procedures provide accurate mineral for mulae with respect to most cations and anions but are unable to generate accurate estimates of fe 31 yfe t a nd overestimate oh at the expense of o on the hydroxyl site these inaccuracies are present despite acceptable adjust ed totals and stoichiometric calculated site occupancies the phlogopite and biotite phenocrysts in arc related lavas from western mexico and eastern california have the highest fe 31 yfe t ratios 56 87 reflecting high magmatic oxygen fugacities dnno 51 2t o 15 in contrast to those from uganda 25 40 and the leucite hills 23 there is no correlation between the oh content and the fe 31 yfe t ratio in the micas values of k mgyfe 21 d 2s errors were calculated for three phlogo pite olivine pairs 0 12 0 12 0 26 0 14 0 09 0 12 two biotite hornblende pairs 0 73 0 08 and 1 22 0 10 and a single phlogopite augite pair 1 15 0 12 values of k fyoh d for two biotite and hornblende pairs could not be determined without significant error because of the extremely low f contents 0 2 wt of the four phases the dd values obtained in this study encompass a large range 2137 to 243 the phlogo pite and biotite separates from uganda have dd values of 270 to 249 which overlap those believed to represent primary mantle there is a larger range in dd values 2137 to 243 for phlogopite phenocrysts from west ern mexico minette lavas although their range in d 18 o values 5 2 6 2 is consistent with normal mantle it is unlikely therefore that the variable dd values reflect heterogeneity in the mantle source region of the minette magmas nor can the extremely low dd values reflect degassing of h2 or h2o since almost 100 loss of dis solved water in the magma is required an unrealistic scenario given the stability of the hydrous phenocrysts the very low dd values of the mascota minette phlogo pites require that the hydrogen be introduced from an external source e g meteoric water whatever the pro cess responsible for the observed hydrogen isotope com position it had no effect on the d 18 o value fo2 ah2o or bulk composition of the host magmas

the pleistocene cinder cones surrounding volcan colima mexico re visited eruption ages and volumes oxidation states and sulfur content located at the volcanic front in the western mexican arc in the colima rift is the active volcan colima which lies on the southern end of the massive 450 km3 colima nevado volcanic complex along the margins of this andesitic volcanic complex is a group of 11 scoria cones and associated lavas which have been dated by the 40ar 39ar method nine scoria cones erupted 1 3 km3 of alkaline magma basanite leucite basanite minette between 450 and 60 ka with 99 between 240 and 60 ka two additional cones both the oldest and calc alkaline erupted 0 003 km3 of basalt 0 5 ma and 0 003 km3 of basaltic andesite 1 2 ma respectively cone and lava volumes were estimated with the aid of digital elevation models dems the eruption rate for these scoria cones and their associated lavas over the last 1 2 myr is 1 2 km3 myr which is more than 400 times smaller than that from the andesitic colima nevado edifice in addition to these alkaline colima cones two other potassic basalts erupted at the volcanic front but 200 km to the ese near the historically active volcan jorullo and were dated at 1 06 and 0 10 ma these potassic suites reflect the tendency in the west central mexican arc for magmas close to the volcanic front to be enriched in k2o relative to those farther from the trench

apatite triple dating and white mica 40ar 39ar thermochronology of syntectonic detritus in the central andes a multiphase tectonothermal history we applied apatite u pb fission track and u th he triple dating and white mica 40 ar 39 ar thermochronology to syntectonic sedimentary rocks from the central andean puna plateau in order to determine the source area geochronology and source sedimentary basin thermal histories and ultimately the timing of multiple tectonothermal events in the central andes apatite triple dating of samples from the eocene geste formation in the salar de pastos grandes basin shows late precambrian devonian apatite u pb crystallization ages eocene apatite fission track aft and eocene miocene u th he ca 8 47 ma cooling ages double dating of cobbles from equivalent strata in the arizaro basin documents early eocene 46 2 3 9 ma and cretaceous 107 6 7 6 109 5 7 7 ma aft and eocene oligocene ca 55 30 ma u th he ages thermal modeling suggests relatively rapid cooling between ca 80 and 50 ma and reheating and subsequent diachronous basin exhumation between ca 30 ma and 5 ma the 40 ar 39 ar white mica ages from the same samples in the salar de pastos grandes area are mainly 400 350 ma younger than apatite u pb ages suggesting source terrane cooling and exhumation during the devonian early carboniferous together these data reveal multiple phases of mountain building in the paleozoic and cenozoic basin burial temperatures within the plateau were limited to

geochemical evidence of the renewal of volcanic activity inferred from co2 soil and so2 plume fluxes the 2007 stromboli eruption italy on 27 february 2007 a new eruption occurred on stromboli which lasted until 2 april it was characterized by effusive activity on the sciara del fuoco and by a paroxysmal event 15 march this crisis represented an opportunity for us to refine the model that had been developed previously 2002 2003 eruption and to improve our understanding of the relationship between the magmatic dynamics of the volcano and the geochemical variations in the fluids in particular the evaluation of the dynamic equilibrium between the volatiles co2 and so2 released from the magma and the corresponding fluids discharged from the summit area allowed us to evaluate the level of criticality of the volcanic activity one of the major accomplishments of this study is a 4 year database of summit soil co2 flux on the basis of which we define the thresholds low medium high for this parameter that are empirically based on the natural volcanological evolution of stromboli the so2 fluxes of the degassing plume and the co2 fluxes emitted from the soil at pizzo sopra la fossa are also presented it is noteworthy that geochemical signals of volcanic unrest have been clearly identified before during and after the effusive activity these signals were found almost simultaneously in the degassing plume so2 flux and in soil degassing co2 flux at the summit although the two degassing processes are shown to be clearly different the interpretation of the results will be useful for future volcanic surveillance at stromboli

reply to comment on paper morphology and composition of spinel in pu u o o lava 1996 1998 kilauea volcano hawaii enigmatic discrepancies between lava and gas based fo2 determinations of pu u o o lava

review of the evolution of geochemical monitoring networks and methodologies applied to the volcanoes of the aeolian arc italy abstract fluids discharged from volcanic systems are the direct surface manifestation of magma degassing at depth and provide primary insights for evaluating the state of volcanic activity we review the geochemical best practice in volcanic surveillance based to a huge amount of monitoring data collected at different active volcanoes using both continuous and discontinuous approaches the targeted volcanoes belong to the aeolian arc located in the tyrrhenian sea italy and they have exhibited different activity states during the monitoring activities reported here la fossa cone on vulcano island has been in an uninterrupted quiescent stage characterized by variable solfataric activity in contrast stromboli island has shown a persistent mild explosive activity episodically interrupted by effusive eruptions in 1985 2002 2007 and 2014 panarea island which is the summit of a seamount rising from the seafloor of the southern tyrrhenian sea showed only undersea fluid release the only observable clues of active volcanism at panarea island have been impulsive changes in the undersea fluid release with the last submarine gas burst event being observed in november 2002 the geochemical monitoring and observations at each of these volcanoes has directly involved the volcanic plume and or the fumarole vents thermal waters and diffuse soil degassing depending on the type of manifestations and the level of activity encountered through direct access to the magmatic samples when possible and the collection of as much observable data related to the fluid release as possible the aim has been i to verify the thermodynamic equilibrium condition ii to discern among the possible hydrothermal magmatic marine and meteoric sources in the fluid mixtures iii to develop models of the fluid circulation supported by data iv to follow the evolution of these natural systems by long term monitoring and v to support surveillance actions related to defining the volcanic risk and the evaluation and possible mitigation of related hazards the examples provided in this review article show the close relationships among data analysis interpretation and modeling we particularly focus on describing the fieldwork procedures since any theoretical approach must always be verified and supported by field data rather than just by experiments controlled in laboratory indeed the natural systems involve many variables producing effects that cannot be neglected the monitored volcanic systems have been regarded as natural laboratories and all of the activities have focused on both volcanological research and surveillance purposes in order to ensure that these two goals have overlapped an appendix is also included that explains the scientific approach to the systematic activities regarding geochemical monitoring of volcanic activity

detrital apatite u pb and trace element analysis as a provenance tool insights from the yenisey ridge siberia abstract the use of zircon u pb geochronology to study the provenance of sediment is well established yet there are fundamental biases that are hard to avoid these biases are due in part to the limited range of magmatic compositions from which zircon will crystallise this can manifest as the over under representation of particular age populations i e sediment sources in the data the analysis of apatite a mineral found in a wide variety of igneous rocks can help to address this bias in detrital geochronology in this study we combine geochemical and u pb la icp ms analysis of individual apatite grains to characterise the potential source rocks this information is integrated with zircon u pb data from the same samples in order to demonstrate the complementary provenance information that can be derived from apatite and zircon archives the analysis of detrital apatite from sedimentary rocks in the yenisey ridge siberia found two main u pb age populations an apatite u pb population at 880 720 ma corresponds to neoproterozoic magmatism in the yenisey ridge and a second at 1800 ma to magmatism related to the assembly of the siberian craton abundant neoproterozoic apatites many of which have chemistries indicative of crystallising from a mafic magma are considerably more common than the relatively rare zircons of the same age the ability of apatite analysis to detect mafic magmatic sources is one of the strengths of this approach that makes it particularly useful when used in combination with zircon u pb geochronology this study shows that multi method analysis of detrital apatite has the potential to be an important tool in conjunction with detrital zircon analysis in future efforts to understand the provenance of sedimentary rocks

u pb dating on single detrital zircon grains from the triassic songpan ganze flysch central china provenance and tectonic correlations the songpan ganze flysch belt central china covers a huge triangular area of more than 200 000 km and is bounded by the continental blocks of south china north china and the tibetan plateau detrital zircons extracted from three flysch samples collected in the central part of the belt were analyzed grain by grain using the u pb method two samples of middle triassic sandstones collected at different locations in the belt provide identical results which suggests similar source regions the detrital zircons yield a wide range of ages and indicate their principal derivation from mid proterozoic 1 8 2 0 ga source rocks with minor contribution from late archean ca 2 5 2 6 ga material the discordance and pb loss patterns from low u zircons indicate disturbances during a subsequent event which may be of caledonian age as suggested by concordant zircon grains at ca 420 and 450 ma one sample collected within the palang shan pass zone provides concordant zircon grains at around 230 ma 231 1 ma and 233 1 ma these triassic ages are synchronous to flysch deposition and suggest intense geological activity calc alkaline volcanism at that time in the area close to the basin the data support an origin of the clastic material mainly from a northeastern landmass corresponding to the southern margin of the sino korean craton to a lesser degree inputs from the yangtze craton and possibly from the northern margin of the basin kunlun arc are also detected the age spectrum from the upper triassic sandstone is significantly different and shows predominance of sinian ca 760 ma grains probably derived from the yangtze craton this change in the source region is interpreted as reflecting the tectonic evolution of this area and in particular as being linked to the late triassic collision between south china and north china in the middle triassic while subduction of the songpan sea northward beneath the north china plate was still taking place continental subduction of south china in the dabie region was responsible for uplift of the overriding plate i e the sino korean craton which supplied large volumes of sediments during the late triassic clockwise rotation of the south china block uplifted the indo sinian part of the qinling belt and closed the basin as the accretionary wedge was thickening along the southern margin of north china detritus derived from this source region were unable to reach the flysch basin the age spectrum presented by detrital zircons indicates

time scales of magma transport and mixing at kīlauea volcano hawai i modeling of volcanic processes is limited by a lack of knowledge of the time scales of storage mixing and final ascent of magmas into the shallowest portions of volcanic plumbing systems immediately prior to eruption it is impossible to measure these time scales directly however micro analytical techniques provide indirect estimates based on the extent of diffusion of species through melts and crystals we use diffusion in olivine phenocrysts from the a d 1959 k lauea iki hawai i usa eruption to constrain the timing of mixing events in the crustal plumbing system on time scales of months to years before eruption the time scales derived from zonation of fe mg in olivines combined with contemporaneous geophysical data suggest that mixing occurred on three time scales 1 as much as 2 yr prior to eruption in the deep storage system 2 in a shallow reservoir between incoming hot melts and resident melt for several weeks to months prior to eruption and 3 in the conduit and summit reservoir between the resident magma and cooled surface lava draining back into the vent on time scales of hours to several days during pauses between episodes synchronous inflation of the shallow reservoir with deep earthquake swarms and mixing suggests an intermittently open transcrustal magmatic system

detrital zircon record of meso and neoproterozoic sedimentary basins in northern part of the siberian craton characterizing buried crust of the basement abstract we present new la icp ms detrital zircon data from meso and neoproterozoic sedimentary basins located in the northern and western parts of the siberian craton along the western cratonic margin turukhansk uplift northern yenisei ridge the basins accumulated predominantly 2 6 2 5 ga and 1 9 1 85 ga erosional products while the main sources for the fill of intracratonic basin to the northeast near the anabar shield east anabar basin were 2 9 2 7 ga and 2 1 1 95 ga old igneous rocks the studied meso to early neoproterozoic sandstones were deposited in rift related or passive margin settings and underwent major craton wide recycling to produce late ediacaran silicilastic successions meso to early neoproterozoic sandstones are immature to submature pointing to erosion of proximal archean and paleoproterozoic crustal units the unique detrital age spectra for the northeast and western basins indicate provinciality and provide a basis for unravelling the age of buried domains of the siberian craton basement

magma supply and storage at kilauea volcano hawaii 1956 1983 abstract shallow crustal magma reservoirs beneath the summit of kilauea volcano and within its rift zones are linked in such a way that the magma supply to each can be estimated from the rate of ground deformation at the volcano s summit our model builds on the well documented pattern of summit inflation as magma accumulates in a shallow summit reservoir followed by deflation as magma is discharged to the surface or into the rift zones magma supply to the summit reservoir is thus proportional to summit uplift and supply to the rift zones is proportional to summit subsidence the average proportionality constant is 0 33 10 6 m 3 rad this model yields minimum supply estimates because it does not account for magma which escapes detection by moving passively through the summit reservoir or directly into the rift zones calculations suggest that magma was supplied to kilauea during july 1956 april 1983 at a minimum average rate of 7 2 10 6 m3 month roughly 35 of the net supply was extruded the rest remains stored within the volcano s east rift zone 55 and southwest rift zone 10 periods of relatively rapid supply were associated with the large kapoho eruption in 1960 and the sustained mauna ulu eruptions in 1969 1971 and 1972 1974 bursts of harmonic tremor from the mantle beneath kilauea were also unusually energetic during 1968 1975 suggesting a close link between kilauea s deep magma supply region and shallow storage reservoirs it remains unclear whether pulses in magma supply from depth give rise to corresponding increases in shallow supply or if instead unloading of a delicately balanced magma transport system during large eruptions or intrusions triggers more rapid ascent from a relatively constant mantle source

meso cenozoic multiple exhumation in the shandong peninsula eastern north china craton implications for lithospheric destruction abstract the shandong peninsula in the eastern north china craton ncc forms part of the region that witnessed extensive tectonic reactivation with concomitant craton destruction and lithospheric thinning during the meso cenozoic previous studies concentrated mainly on the timing mechanism and tectonic setting of the meso cenozoic magmatism with inadequate evidence from low temperature thermochronology to constrain the thermo tectonic exhumation history of this region in this study we present new apatite u pb aupb and fission track aft data with corresponding thermal history models for igneous rocks from the two flanks of the tan lu fault zone tlfz that bisects the shandong peninsula with a view to gain insights into the meso cenozoic exhumation history of this region and to evaluate its implications on the lithospheric destruction of the ncc the newly obtained aupb ages of 2 5 1 5 ga for the precambrian intrusive rocks and of 162 112 ma for the mesozoic igneous suite are mainly used to constrain their thermal history models in addition the mesozoic aupb ages of 162 112 ma highly overlap with their corresponding zircon u pb ages 161 115 ma suggesting shallow granitoid emplacement and associated rapid post magmatic cooling in response to the westward subduction of the paleo pacific plate the aft dating results yield two groups of aft central ages at 122 113 ma and 98 59 ma and corresponding thermal history models also reveal two rapid cooling stages during the early cretaceous 130 105 ma and late cretaceous to paleogene 85 55 ma by integrating previous low temperature thermochronological studies with this study we interpret that the early cretaceous rapid exhumation corresponds to the peak timing of craton destruction resulting from the paleo pacific slab rollback within a back arc extensional setting the late cretaceous rapid exhumation is interpreted as a response to continuing craton destruction derived by the nnw directed pacific plate subduction the paleogene cooling might represent the termination of craton destruction of shandong peninsula associated with a dextral motion along the tlfz triggered by the change in direction of the pacific plate from nnw to wnw and or far field effect of the india eurasia collision

re and os concentrations in arc basalts the roles of volatility and source region fo2 variations olivine and spinel compositions major elements including ferric and ferrous iron s re and os contents have been measured for a suite of primitive most 6 wt mgo basalts from the trans mexican volcanic belt tmvb including the western mexican volcanic belt the michoacan guanajuato volcanic field sierra chichinautzin pico de orizaba region palma sola san martin tuxtlas and the eastern alkaline province eap sulfur contents at sulfide saturation were calculated to determine whether the measured s contents are representative of sulfide saturated liquids most of the samples have s contents much lower than expected for sulfide saturation a few have higher contents than calculated perhaps due to the presence of sulfate in the measured total sulfur i e more oxidized samples comparison of the tmvb samples along with previously analyzed morb oib babb and arc samples reveals a continuum of re and os contents that is best explained by variation in oxygen fugacity and thus sulfide stability in the source region high re and os magmatic suites are best explained by derivation by melting of oxidized mantle where sulfide is no longer stable and re and os behave incompatibly whereas low re and os magmatic suites are derived from melting of relatively reduced mantle where sulfide is stable and re and os behave compatibly intermediate examples abound and arc magmas span a wide range of re and os concentrations due to variation of fo2 in the source during genesis of arc magmas low re magmatic suites are furthermore potentially affected by volatility which can lower re by a factor of 3 5

thermochronological insights into the structural contact between the tian shan and pamirs tajikistan gilby jepson stijn glorie dmitry konopelko jack gillespie martin danisik noreen j evans yunus mamadjanov alan s collins

apatite geochronology and chemistry of luanchuan granitoids in the east qinling orogen china implications for petrogenesis metallogenesis and exploration abstract the luanchuan granitoids in the east qinling orogen central china host multiple genetic types of mo w pb zn ag polymetallic deposits here we present results from systematic geochronological and geochemical investigations on apatite with a view to gain insights into the petrogenesis metallogenesis and potential for mineral exploration we analyzed 388 apatite grains from eight late mesozoic granitic plutons in the luanchuan ore district apatite u pb geochronology yields 206pb 238u mean ages in the range of 151 5 102 3 ma representing the crystallization ages through integrating our results with those from previous studies on the multi stage magmatism 160 130 ma 111 108 ma and metallogeny 150 139 ma 138 135 ma 114 ma the newly obtained apatite ages can be correlated with coeval magmatic and metallogenetic events of this ore district in comparison except for the nannihu pluton which is ca 19 ma younger than the corresponding zircon u pb ages the other studied plutons show almost consistent apatite and zircon u pb ages within error ranges suggesting rapid post magmatic cooling below 450 c in response to shallow emplacement apatite chemistry displays ree concentrations in the range of 2379 15 925 ppm characterized by rather high lree concentrations depleted to flat hree profiles and distinctive negative eu anomalies suggesting crust mantle mixing in the magma source prior to apatite crystallization which incorporated different degrees of sediment melting and slab melting components triggered by the subducted paleo pacific slab derived fluids in conjunction with element concentrations and ratios e g sr mn cl y la y eu eu sm nd n la sm n eu eu n ce ce n la yb n in apatite the luanchuan granitoids are classified as moderately oxidized and mineralized i type granites we suggest that the huangbeiling pluton and other igneous rocks in its vicinity likely have relatively higher potential for future w mo mo w exploration and that different degrees of magmatic differentiation might have generated the porphyry skarn mo w deposit in the yuku ore field moreover our study also demonstrates that the apatite ree concentrations and ratios can be used as potential indicators for mineral exploration

modeling the three dimensional structure of macroscopic magma transport systems application to kilauea volcano hawaii we report the results of modeling the three dimensional internal structure of kilauea s magmatic passageways the approach uses a clear plexiglass model containing equally spaced levels upon which well located seismic hypocenters are plotted application of constraining geologic and geophysical criteria to this distributed volume of earthquakes permits the interpretation of seismic structures produced by fracturing in response to locally high fluid pressures four magma transport and storage structures have been identified within and beneath kilauea 1 primary conduit the conduit transporting magma into kilauea s summit storage reservoir rises from the model base 14 6 km to the 6 5 km depth level it is a zone of intense fracturing and inferred intrusion whose horizontal sections are elliptical in planform over its height the average major axis of the component horizontal sections is 3 3 km with an average minor axis of 1 7 km this yields an aspect ratio of 0 52 at the 14 6 km level the strike of the major axis is n67 e during passage from the upper mantle through the oceanic crust this axis rotates in a right handed sense until the strike is n41 w at the 6 5 km level 2 magma chamber complex floor the interval from 6 5 to 5 7 km immediately over the primary conduit is aseismic this suggests differentially high fluid to rock ratios and relatively weak pathways for further vertical transport into higher levels of the storage complex as well as lateral leakage eastward into the mauna ulu staging area for later vertical ascent beneath the upper east rift zone seismicity within the immediately subjacent rocks that form the top of the primary conduit at 6 5 km suggests that this inferred magma rich horizon forms the effective floor of the summit storage complex 3 magma chamber crown intense seismicity over the 1 1 1 9 km depth interval defines an elliptical region in plan view the top of this region has a broad apex with an average major axis of 1 5 km and an average minor axis of 1 1 km producing an aspect ratio of 0 73 this region coincides with the epicentral position of summit vertical displacement maxima during inflationary deformation and is interpreted as a region of intense diking crowning the summit storage complex 4 upper east rift zone pipe from a depth of 5 7 km a cylindrical region of seismicity rises beneath the upper east rift zone to the 1 9 km level where it merges with the subhorizontal upper east rift zone duct this pipe like zone has a mean diameter of 1 4 km and a vertical axis that pierces the surface of the volcano at the intersection of the koae fracture system and the upper east rift zone we suggest this pipe forms a principal connection between the base of the summit storage reservoir and near surface storage compartments and ducts in the upper east rift zone in this role the pipe is suggested to have contributed heavily to mauna ulu s magma supply during 1969 1974 the model of magma transport and storage thus constructed provides a context in which other types of data e g ground deformation and electrical conductivity may be interpreted as well as a means of refining petrological inferences based on lava chemistry

high temperature 350 c thermochronology and mechanisms of pb loss in apatite abstract natural processes driven by heat flow can be understood using quantitative reconstruction of the thermal history of accessory and common minerals that were formed or modified in these processes thermochronology assumes that isotopes are lost from minerals by thermally activated volume diffusion and forms the basis of many studies of the thermal evolution of the crust however some studies challenge this assumption and suggest that the mechanisms controlling isotope transport in minerals over geological time scales are dominated by aqueous fluid flow within mineral pathways here we test these contrasting hypotheses by inverse modelling apatite uranium lead u pb dates to produce theoretical t t solutions assuming pb was lost by volume diffusion these solutions are compared with independent geological constraints and intra grain apatite u pb dates which demonstrate that volume diffusion governed the displacement of pb this confirmation combined with an inverse modeling procedure that permits reheating and cooling paths to be distinguished between 375 and 570 c provides geologists with a unique tool for investigating the high temperature thermal evolution of accessory minerals using the u pb method

interannual variability in the spatial distribution of winter accumulation at a high arctic glacier finsterwalderbreen svalbard and its relationship with topography glacier mass balance and hydrology are strongly influenced by the distribution of snow accumulation at the start of the melt season two successive end of winter snow cover surveys at finsterwalderbreen svalbard are here used to investigate the interannual variability in the spatial distribution of accumulation and its relationship with topography 40 62 of the variance in snow depth was not determined by elevation assessed by linear regression of snow depth on surface elevation which could not therefore necessarily be used as a sole predictor of the spatial distribution of accumulation here principal components pc analysis of the topographic variables elevation slope north south and east west aspects shows that only two of six pcs determined for 2 years sampling locations had maximum loadings on altitude aspect was more important with maximum loadings on four pcs hierarchical cluster analysis was then applied to these pcs significant correlations with accumulation in each of two terrain clusters were given by 1 elevation and slope 2 east west aspect only 1999 1 elevation only 2 no significant correlations 2000 there is strong interannual variability not only in the magnitude of winter accumulation 0 41 m w e in 1999 0 58 m w e in 2000 but also in its spatial distribution and its relationship with topography

the aurora volcanic field california nevada oxygen fugacity constraints on the development of andesitic magma the aurora volcanic field located along the northeastern margin of mono lake in the western great basin has erupted a diverse suite of high k and shoshonitic lava types with 48 to 76 wt sio2 o ver the last 3 6 million years there is no correlation between the age and composition of the lavas three quarters of the volcanic field consists of evolved 4 wt mgo basaltic andesite and andesite lava cones and flows the majority of which contain sparse euhedral phenocrysts that are normally zoned there is no evidence of mixed hybrid magmas the average eruption rate over this time period was 200 m 3 ykm 2 yyear which is typical of con tinental arcs and an order of magnitude lower than that for the slow spreading mid atlantic ridge all of the au rora lavas display a trace element signature common to subduction related magmas as exemplified by baynb ratios between 52 and 151 pre eruptive water contents ranged from 1 5 wt in plagioclase rich two pyroxene andesites to 6 wt in a single hornblende lamprophyre and several biotite hornblende andesites calculated oxygen fugacities fall within 0 4 and 12 4 log units of the ni nio buffer the aurora potassic suite follows a classic calc alkaline trend in a plot of feo t ymgo vs sio 2 and displays linear decreasing trends in feo t and tio2 with sio2 content suggesting a prominent role for fe ti oxides during differentiation however develop ment of the calc alkaline trend through fractional crys tallization of titanomagnetite would have caused the residual liquid to become so depleted in ferric iron that its oxygen fugacity would have fallen several log units below that of the ni nio buffer nor can fractionation of hornblende be invoked since it has the same effect as titanomagnetite in depleting the residual liquid in ferric iron together with a thermal stability limit that is lower than the eruption temperatures of several andesites 1040 10808c derived from two pyroxene ther mometry unless some progressive oxidation process occurs fractionation of titanomagnetite or hornblende cannot explain a calc alkaline trend in which all erupted lavas have oxygen fugacites the ni nio buffer in con trast to fractional crystallization closed system equi librium crystallization will produce residual liquids with an oxygen fugacity that is similar to that of the initial melt however the eruption of nearly aphryic lavas ar gues against tapping from a magma chamber during equilibrium crystallization a process that requires crys tals to remain in contact with the liquid a preferred model involves the accumulation of basaltic magmas at the mantle crust interface which solidify and are later remelted during repeated intrusion of basalt as an end member case closed system equilibrium crystallization of a basalt followed by equilibrium partial melting of the gabbro will produce a calc alkaline evolved liquid namely high sio 2 and low feo t ymgo with a relative fo2 corrected for the effect of changing temperature that is similar to that of the initial basalt differentiation of the aurora magmas by repeated partial melting of previous underplates in the lower crust rather than by crystal fractionation in large stable magma chambers is consistent with the low eruption rate at the aurora vol canic field

gas composition of the january 1983 eruption of kilauea volcano hawaii abstract gas collections were made from a 900 c vent both by conventional evacuated bottle wet chemical techniques and by manual pumping of flowthrough bottles the complete analyses suggest an equilibrium assemblage quenched at 1 010 c about midway between fountain and vent temperatures i suggest that the very low c s ratio is due to degassing of co2 during storage of the magma in a shallow reservoir before eruption the two sampling techniques yielded analytical data in mutual agreement

h2s fluxes from mt etna stromboli and vulcano italy and implications for the sulfur budget at volcanoes abstract we present here new measurements of sulfur dioxide and hydrogen sulfide emissions from vulcano etna and stromboli italy made by direct sampling at vents and by filter pack and ultraviolet spectroscopy in downwind plumes measurements at the f0 and fa fumaroles on vulcano yielded so 2 h 2 s molar ratios of 0 38 and 1 4 respectively from which we estimate an h 2 s flux of 6 to 9 t d 1 for the summit crater for mt etna and stromboli we found so 2 h 2 s molar ratios of 20 and 15 respectively which combined with so 2 flux measurements suggest h 2 s emission rates of 50 to 113 t d 1 and 4 to 8 t d 1 respectively we observe that source and plume so 2 h 2 s ratios at vulcano are similar suggesting that hydrogen sulfide is essentially inert on timescales of seconds to minutes this finding has important implications for estimates of volcanic total sulfur budget at volcanoes since most existing measurements do not account for h 2 s emission

routine low damage apatite u pb dating using laser ablation multicollector icpms 1 apatite is a common u bearing accessory mineral with a u pb closure temperature of 500 c making u pb dating of apatite a potentially valuable thermochronometer however its low u concentration and tendency to incorporate common lead has limited widespread application to destructive isotope dilution methods we overcome previous limitations by using a nu plasma multicollector icpms with an attached short pulse excimer laser and by identifying two new matrix matched reference apatites to correct for elemental fractionation gem quality 485 myr old apatite from madagascar which we independently characterized by id tims analysis and 523 5 ma apatite from the mcclure mountain syenite source of the40ar 39ar reference mmhb common pb is corrected using measured 204pb isobarically corrected for hg interference and a five step iterative process using stacey and kramers common pb model we accurately reproduce ages of numerous independently characterized apatites regularly achieving precision of 2 2 by pooling as few as five 30 m spot analyses data quality in apatite with low u concentrations low 206pb 204pb values 30 and young ages 75 ma is compromised by the goal of avoiding significant grain damage such limitations can be overcome by using spot sizes 65 m or greater but at the expense of substantial grain damage for single detrital apatite grains with ages of 500 ma precision of 4 2 was achieved by pooling 2 to 3 spots per grain the accuracy of our detrital results is supported by a good age match with similar closure temperature 40ar 39ar detrital hornblende ages from the same sediment

oxygen buffering of kilauea volcanic gases and the oxygen fugacity of kilauea basalt volcanic gases collected during episode 1 of the puu oo eruption along the east rift zone of kilauea volcano hawaii have uniform c o h s cl f compositions that are sharply depleted in co2 the co2 poor gases are typical of type ii volcanic gases gerlach and graeber 1985 and were emitted from evolved magma stored for a prolonged period of time in the east rift zone after releasing co2 rich gases during an earlier period of temporary residence in the summit magma chamber the samples are remarkably free of contamination by atmospheric gases and meteoric water thermodynamic evaluation of the analytical data shows that the episode 1 gases have equilibrium compositions appropriate for temperatures between 935 and 1032 c open and closed system equilibrium models of species distributions for the episode 1 gases show unequivocally that coexisting lavas buffered the gas oxygen fugacities during cooling these models indicate that the fo2 buffering process occurs by transfer of oxygen from the major species in the gas phase h2o co2 so2 to the lava during cooling and that the transfer of oxygen also controls the fugacities of several minor and trace species h2 co h2s s2 cl2 f2 in addition to o2 during cooling gas lava exchanges of other components are apparently insignificant and exert little influence compared to oxygen exchange during cooling oxygen transfer during cooling is variable presumably reflecting short term fluctuations in gas flow rates higher flow rates restrict the time available for gas lava oxygen transfer and result in gases with higher equilibrium temperatures lower flow rates favor fo2 constrained equilibration by oxygen transfer down to lower temperatures thus the chemical equilibrium preserved in these gases is a heterogeneous equilibrium constrained by oxygen fugacity and the equilibrium temperatures implied by the compositions of the gases reflect the temperatures at which gas lava oxygen exchange ceased this conclusion challenges the common assumption that volcanic gases are released from lava in a state of chemical equilibrium and then continue equilibrating homogeneously with falling temperature until reaction rates are unable to keep pace with cooling no evidence is found moreover that certain gas species are kinetically more responsive and able to equilibrate down to lower temperatures than those of the last gas lava oxygen exchange homogeneous reaction rates in the gas phase are apparently slow compared to the time it took for the gases to move from the last site of gas lava equilibration to the site of collection an earlier set of data for higher temperature co2 rich type i volcanic gases which come from sustained summit lava lake eruptions supplied by magma that experienced substantially shorter periods of crustal storage shows fo2 buffering by oxygen transfer up to 1185 c oxygen fugacity measurements in drill holes into ponded lava flows suggest that buffering by oxygen transfer may control the fo2 of residual gases down to several hundred degrees below the solidus in the early stages of cooling although the details of the fo2 buffering mechanisms for oxygen transfer are unknown the fact that fo2 buffering is effective from molten to subsolidus conditions suggests that the reaction mechanisms must change with cooling as the reactants change from predominantly melt to melt plus crystals to glass plus crystals mass balance calculations suggest that redox reactions between the gas and ferrous ferric iron in the lava are plausible mechanisms for the oxygen transfer and that the fo2 of the gases is buffered by sliding ferrous ferric equilibria in the erupting lavas contrary to expectations based on models predicting the oxidation of basalt by h2 and co escape during crustal storage co2 rich type i gases and co2 poor type ii gases have identical oxygen fugacities despite greatly different crustal storage and degassing histories volcanic gas data give a tightly constrained log fo2 of nno 0 5 0 05 for subaerially erupted kilauea basalt from liquidus to solidus temperatures consistent with recent fo2 determinations for the mantle source regions of ocean island basalts because the oxygen fugacities of volcanic gases emitted by subaerial lavas imply that the fo2 of kilauea basalt is unchanged during crustal storage kilauea basalt either arrives in the crust with an oxygen fugacity between nno and fmq or it develops an oxygen fugacity in this range immediately upon arrival in the summit chamber

alunite and the role of magmatic fluids in the tambo high sulfidation deposit el indio pascua belt chile the tambo high sulfidation deposit located within the el indio pascua belt in chile produced almost 25 t 0 8 m oz of gold from altered tertiary rhyodacitic volcanic rocks episodic magmatic hydrothermal activity in the district occurred over at least 4 my and is characterized by several stages of acid sulfate alteration including magmatic hydrothermal magmatic steam steam heated and apparent supergene assemblages two stages of aufag mineralization are recognized and are hosted in barite and alunite within hydrothermal breccias and veins isotopic compositions of fluid in alunite show a dominant magmatic signature with only a variable 18 o enriched meteoric water component throughout the entire hydrothermal process alunite 40 ar 39 ar ages constrain the timing of alteration and the duration of the hydrothermal system pre ore alteration occurred at about 10 to 11 ma and was contemporaneous with the volcanism of the tambo formation alunite from this stage of alteration occurs in the matrix of barren breccias and as fine intergrowths of alunite quartzfclays that selectively replaced feldspars and pumice fragments the textural relationships combined with stable isotope systematics suggest a magmatic hydrothermal origin for the alunite with a local magmatic steam overprint early ore stage alunite 8 7f0 2 ma occurs with barite and goldfwalthierite within open spaces of the breccia matrix and has d 34 s values 24 27x typical of magmatic hydrothermal alunite reflecting equilibrium between aqueous h2s and so4 fluid inclusion ratios of h2s so2 approximately 6 are consistent with ratios determined from stable isotope data and indicate reduced fluid conditions during ore deposition vaporphase transport of au and deposition from condensed magmatic vapor rising from the brittle ductile transition is inferred late gold coprecipitated with a third stage of alunite 8 2f0 2 ma that is characterized by nearly uniform chemical compositions and d 34 s values 1x similar to those for associated enargite reflecting disequilibrium between h2s and so4 this third stage of alunite is isotopically and chemically similar to that of post ore coarse banded alunitefhematite quartz veins that crosscut the breccias in the tambo area analyses of fluid inclusion gas from alunite in these veins indicate high so2 and disequilibrium co2 co ch4 h2 species consistent with a magmatic steam origin the gases are also depleted in he and the late goldbearing alunite was probably precipitated from rapidly ascending so2 rich vapors that were flashed from condensed magmatic

the impact of degassing on the oxidation state of basaltic magmas a case study of kīlauea volcano volcanic emissions link the oxidation state of the earth s mantle to the composition of the atmosphere whether the oxidation state of an ascending magma follows a redox buffer hence preserving mantle conditions or deviates as a consequence of degassing remains under debate thus further progress is required before erupted basalts can be used to infer the redox state of the upper mantle or the composition of their co emitted gases to the atmosphere here we present the results of x ray absorption near edge structure xanes spectroscopy at the iron k edge carried out for a series of melt inclusions and matrix glasses from ejecta associated with three eruptions of k lauea volcano hawai i we show that the oxidation state of these melts is strongly correlated with their volatile content particularly in respect of water and sulfur contents we argue that sulfur degassing has played a major role in the observed reduction of iron in the melt while the degassing of h2o and co2 appears to have had a negligible effect on the melt oxidation state under the conditions investigated using gas melt equilibrium degassing models we relate the oxidation state of the melt to the composition of the gases emitted at k lauea our measurements and modelling yield a lower constraint on the oxygen fugacity of the mantle source beneath k lauea volcano which we infer to be near the nickel nickel oxide nno buffer our findings should be widely applicable to other basaltic systems and we predict that the oxidation state of the mantle underneath most hotspot volcanoes is more oxidised than that of the associated lavas we also suggest that whether the oxidation states of a basalt in particular morb reflects that of its source is primarily determined by the extent of sulfur degassing

u pb shrimp ii lu hf isotope and trace element geochemistry of zircons from high grade metamorphic rocks of the irkut terrane sharyzhalgay uplift implications for the neoarchaean evolution of the siberian craton abstract this paper presents new data on the bulk rock composition petrogenesis and u pb zircon ages of high grade metamorphic rocks and granitoids of the irkut terrane which is part of the sharyzhalgay basement uplift located at the southwestern margin of the siberian craton our results allowed us to reliably constrain the neoarchaean evolution of the southwestern siberian craton the high grade rocks under study are two pyroxene amphibole mafic granulites and orthopyroxene bearing intermediate felsic granulites both types of granulite are enriched in ba th and lree and both show clear nb depletion characteristics that are typical of subduction related volcanic rocks the mafic and felsic granulites contain magmatic zircons of 2698 9 ma and 2662 16 ma respectively indicating that most of the protoliths of the high grade rocks formed in the neoarchaean the variable values of end 4 8 to 1 2 whole rock and ehf 1 6 to 2 4 zircons suggest contribution of older crust in the genesis of intermediate felsic granulites the relicts of ca 3 4 ga older rocks have recently been recognized within the irkut high grade metamorphic complex the petrological geochemical and isotopic features of high grade rocks are indicative of their protolith formation in a subduction related setting at the margin of an older continental block the metamorphic zircons in the high grade rocks with ages of 2567 6 and 2540 10 ma and the zircons in the gneissic granitoids with an age of 2540 11 ma probably record neoarchaean collisional events in the irkut terrane the coeval metamorphism ca 2 6 ga and granitoid magmatism ca 2 54 ga in the irkut and kitoy high grade terranes of the sharyzhalgay uplift suggest their neoarchean collision which resulted in the assembly of the sharyzhalgay superterrane similarly amalgamation of the ancient core of the siberian craton which consisted of the west aldan daldyn terranes and the two high grade terranes of the sharyzhalgay uplift probably began in the neoarchaean and was completed by 2 0 to 1 85 ga

long term geochemical surveillance of fumaroles at showa shinzan dome usu volcano japan this study investigates 31 years of fumarole gas and condensate trace elements data from showa shinzan a dacitic dome cryptodome complex that formed during the 1943 1945 eruption of usu volcano forty two gas samples were collected from the highest temperature fumarole named a 1 from 1954 800 c to 1985 336 c and from lower temperature vents condensates were collected contemporaneously with the gas samples and we reanalyzed ten of these samples mostly from the a 1 vent for 32 cations and three anions modeling using the thermochemical equilibrium program solvgas shows that the gas samples are mild disequilibrium mixtures because they a contain unequilibrated sedimentary ch4 and nh3 b have unequilibrated meteoric water or c lost co either by air oxidation or by absorption by the sodium hydroxide sampling solution solvgas also enabled us to restore the samples by removing these disequilibrium effects and to estimate their equilibrium oxygen fugacities and amounts of s2 and ch4 the restored compositions contain 98 h2o with minor to trace amounts of co2 h2 hcl so2 hf h2s co s2 and ch4 we used the restored gas and condensate data to test the hypotheses that these time series compositional data from the dome s fumaroles provide 1 sufficient major gas data to analyze long term degassing trends of the dome s magma hydrothermal system without the influence of sampling or contamination effects 2 independent oxygen fugacity versus temperature estimates of the showa shinzan dacite 3 the order of release of trace elements especially metals from magma and 4 useful information for assessing volcanic hazards the 1954 1985 restored a 1 gas compositions confirm the first hypothesis because they are sufficient to reveal three long term degassing trends 1 they became increasingly h2o rich with time due to the progressive influx of meteoric water into the dome 2 their csandscl ratios decreased dramatically while their clf ratios stayed roughly constant indicating the progressive outgassing of less soluble components f cl s c from the magma reservoir and 3 their h2oh2 co2coandh2sso2 ratios increased significantly in concert with equilibrium changes expected for the 500 c temperature drop when plotted against reciprocal temperature the restored gas log oxygen fugacities follow a tight linear trend from 800 c to nno 2 5 at 400 c this trend largely disproves the second hypothesis because the oxygen fugacities for the 800 c restored gases can only be explained by mixing of hot magmatic gases with 350 c steam from superheated meteoric water but above 800 c this trend intersects the opposing linear trend for other usu eruptive products implying a log oxygen fugacity of 11 45 at 902 c for the showa shinzan magma the time series trace element data also disprove the third hypothesis because rock and incrustation particle contaminants in the condensates account for most of the trace element variation nonetheless highly volatile elements like b and as are relatively unaffected by this particle contamination and they show similar time series trends as cl and f finally except for infrequent sampling around the 1977 usu eruption the results generally confirm the fourth hypothesis since the time series trends for the major gases and selected trace elements indicate that with time the system cooled degassed and was infiltrated by meteoric water all of which are positive signs that volcanic activity declined over the 31 year history this study also suggests that second boiling of shallow magma within and possibly beneath the cryptodome sustained magmatic degassing for at least 20 years after emplacement

equilibrium temperature and redox state of volcanic gas at unzen volcano japan abstract high temperature volcanic gases were collected from a growing dacitic dome of unzen volcano japan apparent equilibrium temperatures aet were calculated for the following two reactions so2 3h2 h2s 2h2o and co2 h2 co h2o both the aet s are higher than the outlet temperature to two hypotheses are examined as a cause of this disagreement one is a partial advancement in the reaction so2 3h2 h2s 2h2o the other is an addition of external water after a final equilibrium attainment based on these hypotheses the equilibrium compositions temperatures and redox potentials were estimated resulting in similar values the estimated temperatures range from 850 to 911 c which is consistent with a petrological estimation made with the lava however the estimated redox potential is one unit less in logfo2 scale than the petrological estimation

a precise 40ar 39ar reference age for the durango apatite u th he and fission track dating standard the distinctive durango apatite is widely distributed as a reference material for mineralogy geochemistry and thermochronology the apatite occurs within the cerro de mercado open pit iron mine located in the northern portion of durango city mexico it is largely confined to vugs and open fractures within the lower portion of the ore deposit apatite and iron ore formed in situ and concurrently along with emplacement of small felsic intrusions along the southern margin of the chupaderos caldera complex this activity occurred between eruptions of two major ignimbrites from the caldera complex four single crystal sanidine anorthoclase 40 ar 39 ar ages from these ignimbrites and from a conformable older unit have been used to compute a reference age of 31 44 0 18 ma 2 for the apatite itself four additional multi crystal measurements are in general agreement with this age also in agreement are a set of 24 u th sm he ages recently determined directly on the apatite which have a mean of 31 02 1 01 ma 1 with a standard error s e of 0 22 ma

degassing of halogens from basaltic volcanism insights from volcanic gas observations abstract the currently available data set of s cl f abundances in volcanic gas plumes and high temperature fumarolic gas samples from basaltic volcanism is reviewed here in the attempt to derive constraints on the modes of halogen degassing from mafic silicate melts apart from large volcano to volcano variations reflecting remarkable differences in volatile abundances in the source magmas each of the explored volcanoes displays large changes of so2 hcl and so2 hf ratios with the style of volcanic activity with hcl hf staying fairly constant halogen abundances are low and so2 hcl and so2 hf are high when fresh volatile rich magmas sustain degassing as during explosive eruptions at the onset of eruptive cycles or shortly before paroxysmal events low so2 hcl and so2 hf ratios are instead characteristic of late stages of volcanic degassing typically being observed in the concluding stages of basaltic eruptions or during periods of reduced magma supply at persistently degassing volcanoes these observations are taken as evidence of halogens being less keen to enter the gas phase relative to s during degassing of basaltic magmas and quantitatively interpreted in light of a rayleigh type open system degassing model the model though simple quantitatively reproduces the range of volcanic gas compositions observed at basaltic volcanoes worldwide and allows prediction of vapour melt partitioning contrasts of factors 9 and 36 for the volatile couples s cl and s f respectively these predictions require validation from appropriately designed experiments of halogen partitioning between magmatic vapours and silicate melts over a range of p t x conditions

halogens and trace metal emissions from the ongoing 2008 summit eruption of kīlauea volcano hawai i volcanic plume samples taken in 2008 and 2009 from the halema uma u eruption at k lauea provide new insights into k lauea s degassing behaviour the cl f and s gas systematics are consistent with syn eruptive east rift zone measurements suggesting that the new halema uma u activity is fed by a convecting magma reservoir shallower than the main summit storage area comparison with degassing models suggests that plume halogen and s composition is controlled by very shallow 77 as gaseous elemental mercury at the point of emission sulphate is an important aerosol component modal particle diameter 0 44 m aerosol halide ion concentrations are low compared to other systems consistent with the lower proportion of gaseous hydrogen halides plume concentrations of many metallic elements rb cs be b cr ni cu mo cd w re ge as in sn sb te tl pb mg sr sc ti v mn fe co y zr hf ta al p ga th u la ce pr nd sm eu gd tb dy er tm are elevated above background air there is considerable variability in metal to so2 ratios but our ratios generally at the lower end of the range previously measured at k lauea support assertions that k lauea s emissions are metal poor compared to other volcanic settings our aerosol re and cd measurements are complementary to degassing trends observed in hawaiian rock suites although measured aerosol metal s ratios are about an order of magnitude lower than those calculated from degassing trends determined from glass chemistry plume enrichment factors with respect to hawaiian lavas are in broad agreement with those from previous studies allowing similar element classification schemes to be followed i e lithophile elements having lower volatility and chalcophile elements having higher volatility the proportion of metal associated with the largest particle size mode collected 2 5 m and that bound to silicate is significantly higher for lithophiles than chalcophiles many metals show higher solubility in ph 7 buffer solution than deionised water suggesting that acidity is not the sole driver in terms of solubility nonetheless many metals are largely water soluble when compared with the other sequential leachates suggesting that they are delivered to the environment in a bioavailable form preliminary analyses of environmental samples show that concentrations of metals are elevated in rainwater affected by the volcanic plume and even more so in fog however metal levels in grass samples showed no clear enrichment downwind of the active vents

degassing of metals and metalloids from erupting seamount and mid ocean ridge volcanoes observations and predictions recently it has been reported that the element polonium degasses from mid ocean ridge and seamount volcanoes during eruptions published and new observations on other volatile metal and metalloid elements can also be interpreted as indicating significant degassing of magmatic vapors during submarine eruptions this process potentially plays an important role in the net transfer of chemical elements from erupting volcanoes to seawater in addition to that arising from sea floor hydrothermal systems in this paper a framework is constructed for predicting and assessing semiquantitatively the potential magnitude and chemical fingerprints in the water column of metal and metalloid degassing using 1 predictions from a summary of element volatilities during mafic subaerial volcanism worldwide and 2 limited data from submarine volcanic effusives the latter include analyses of polonium and trace metals in near volcano water masses sampled following a submarine eruption at loihi seamount hawaii 1000 m bsl in 1996 the element volatility predictions and observations show good agreement considering the limited dataset some of the highest volatility main group and transition element enrichments in seawater over loihi are predicted by the degassing mass transfer model i present when expanded to cover all submarine volcanic activity it is predicted that exit fluxes of these elements are up to 102 103 greater by degassing than by normal mor hydrothermalism in contrast mor exit fluxes of low volatility alkali and alkaline earth elements are likely 102 106 greater from hydrothermal inputs degassing inputs to the ocean are probably highly episodic occurring almost entirely during eruptions these are times of enhanced and abnormal hydrothermalism as well although major hydrothermal and degassing events may not be chemically recognizable in real water masses as wholly distinct entities it is nevertheless possible to predict to what extent each process flavors the effluents of the other degassing at mid ocean ridges may explain a variety of observations previously ascribed to complexities occurring during hydrothermal venting and or fluid ascent in the buoyant hydrothermal plumes above ridges

the precambrian of transangaria yenisei ridge siberia neoproterozoic microcontinent grenville age orogen or reworked margin of the siberian craton abstract the yenisei ridge was traditionally perceived as an uplifted segment of the western siberian craton affected by neoproterozoic collision events however the suggestions for archaean or palaeoproterozoic siberian basement in transangaria have not been confirmed by reliable geochronological data a new view regards most of the ridge namely its transangarian segment to be an exotic neoproterozoic terrane that collided with siberia in the late neoproterozoic this paper presents new u pb shrimp zircon ages demonstrating that archaean rocks 2611 12 ma actually exist in this territory we also provide a review of published u pb zircon ages for igneous and metamorphic rocks of transangaria together with our new age data this geochronological dataset clarifies the geology of the yenisei ridge and leads to new conclusions as follows 1 it is likely that transangaria was originally underlain by an archaean palaeoproterozoic basement similar to that of the siberian craton 2 geochronological data do not confirm the idea of widespread greenvillian age granitoides in transangaria 3 the neoproterozoic evolution of the yenisei ridge segment of the siberian craton margin includes the following events i collision of an unidentified terrane with the western margin in recent coordinates of the siberian craton during 900 855 ma the colliding terrane is no longer present in the current structure ii dextral shearing during 830 800 ma may have been caused by counter clockwise rotation of the siberian craton iii extensional conditions prevailed during 800 700 ma the isakovka oceanic basin formed at this time interval iv thrusting of the isakovka island arc and accretionary prism onto the siberian margin occurred during the late neoproterozoic 650 630 ma and caused high pressure metamorphism

u pb systematics of the mcclure mountain syenite thermochronological constraints on the age of the 40 ar 39 ar standard mmhb recent advances in u pb geochronology allow unprecedented levels of precision in the determination of geological ages however increased precision has also illuminated the importance of understanding subtle sources of open system behavior such as pb loss inheritance intermediate daughter product disequilibria and the accuracy of the model assumptions for initial pb deconvolution of these effects allows a much richer understanding of the power and limitations of u pb geochronology and thermochronology in this study we report high precision id tims u pb data from zircon baddelleyite titanite and apatite from the mcclure mountain syenite from which the 40 ar 39 ar hornblende standard mmhb is derived we find that excess 206 pb in zircon due to inclusions of high th minerals and ele vated th u in titanite and apatite jeopardize the utility of the 238 u 206 pb system in this rock strongly air abraded zircons give dates that are younger than chemical abraded zircons which yield a statistically robust 207 pb 235 u date of 523 98 0 12 ma that is interpreted as the crystallization age we explore the best method of pbc correction in titanite and apatite by analyzing the u pb isotopes of k feldspar and using 2 d and 3 d regression methods the latter of which yields the best results in each case however the calcu lated compositions of pbc for titanite apatite and k feldspar are different implying that using a single pbc correction for multiple u pb thermochronometers may be inaccurate the u pb thermochronological results are used to predict a closure time for ar in hornblende of 522 98 1 00 ma widely cited k ar and 40 ar 39 ar dates overlap with the u pb date and relatively large errors make it impossible to verify whether u pb dates are systematically 1 older than k ar and 40 ar 39 ar dates

apatite monazite and xenotime in metamorphic rocks this chapter focuses on phosphates that are significant in metamorphic rocks a quick survey of phosphate mineral descriptions at a commercial mineral web site revealed over 500 phosphate mineral names remarkably only three are common in metamorphic rocks apatite monazite and xenotime and this chapter is restricted to discussion of these minerals apatite monazite and to a lesser extent xenotime have enjoyed intensive study during the previous half century following world war ii considerable study was made of minerals that contain fissionable materials and the sometimes large concentrations of u and th in monazite culminated in a number of seminal papers on the occurrence of that mineral e g overstreet 1967 during the 1970s and early 1980s the study of apatite and monazite turned towards their role as a sink for rees and other trace elements in rocks e g watson 1980 watson and capobianco 1981 throughout this period monazite and to some extent xenotime enjoyed attention as a geochronometer e g parrish 1990 and through today this attention has continued to grow accessory minerals such as monazite xenotime and apatite have come to the forefront of research in metamorphic petrology in recent years for two reasons first it has recently been recognized that trace elements in metamorphic rocks and especially trace element zoning in garnet and other major phases contain considerable detailed information about the reaction history a rock has experienced coupled with the fact that diffusion of many trace elements in metamorphic minerals is in general considerably slower than diffusion of major elements in those same minerals the possibility has recently emerged of recovering details of metamorphic petrogenesis that were previously unattainable inasmuch as accessory minerals play a dominant role in the mass budget of many trace elements attention has naturally turned to their paragenesis it has also recently been discovered that

apatite in igneous systems apatite is a minor but ubiquitous mineral in most igneous rocks although the modal proportion of apatite in common rocks is generally low it can reach high concentrations in enclaves cumulates and other rocks of low abundance i e rocks that constitute a small volume of the crust and mantle e g nelsonites the presence of apatite in most rocks is due not only to its low solubility in naturally occurring melts and aqueous solutions but also to the limited ability of common rock forming minerals to accept the amount of phosphorus that occurs in most rocks into their structure in this paper we will discuss some aspects of the occurrence texture composition physical chemistry and petrogenetic significance of apatite in felsic rocks i e andesite to rhyolite and their plutonic analogs in mafic i e basalts and related rocks and plutonic analogs and ultramafic rocks of the earth s crust and mantle fluorapatite is by far the most common member of apatite family found in igneous rocks however most natural fluorapatite contains some chlorine and hydroxyl as well and these constituents can attain high concentrations in some cases the other halogens bromine and iodine also occur in apatite but their concentrations are much lower than chlorine and fluorine many cations commonly substitute for calcium and phosphorus in apatite however they rarely reach concentrations that warrant the definition of a separate mineral species apatite can be described by the general formula a5 xo4 3z following sommerauer and katz lehnert 1985 the a site accommodates large cations e g ca2 sr2 pb2 ba2 mg2 mn2 fe2 ree3 eu2 cd2 na pan and fleet ch 2 in this volume and comprises two sites that exhibit vii fold

4d gravity changes associated with the 2005 eruption of sierra negra volcano galapagos sierra negra volcano the most voluminous shield volcano in the galapagos archipelago and one of the largest basaltic calderas in the world erupted on october 22 2005 after more than 25 years of quiescence gps and satellite radar interferometryinsar monitoring of the deformation of the caldera floor in the months prior to the eruption documented extraordinary inflation rates 1c m day the total amount of uplift recorded since monitoring began in 1992 approached 5 m at the center of the caldera over the eight days of the eruption the caldera floor deflated a maximum of 5 m and subsquently renewed its inflation but at a decelerating rate to gain insight into the nature of the subsurface mass density changes associated with the deformation gravity measurements performed in 2005 2006 and 2007 are compared to previous measurements from 2001 2002 when the volcano underwent a period of minor deflation and magma withdrawal the residual gravity decrease between 2001 2002 and 2005 is among the largest ever recorded atan active volcano950 gal and suggests that inflation was accompanied by a relative density decrease in the magmatic system forward modeling of the residual gravity data in 4d from 2002 to 2005 gives an estimate of the amount of vesiculation in the shallow sill required to explain the observed gravity variations geochemical constraints from melt inclusion and satellite remote sensing data allow us to estimate the pre eruptive gas content of the magma and place constraints on the thickness of the gas rich sill necessary to produce the gravity anomalies observed results suggest that reasonable sill thicknesses 700 800 m and bubble contents 10 50 volume can explain the large decrease in residual gravity prior to eruption following the eruption 2006 and 2007 the deformation and gravity patterns suggest re equilibration of the pressure regime in the shallow magma system via a renewed influx of relatively gas poor magma into the shallow parts of the system