surface wave dispersion analysis in mexico city abstract in this article we present an observational investigation of ground motion at mexico city focused on surface waves our purpose is 2 fold first to understand incident ground motion during the great michoacan earthquake of 19 september 1985 and second to characterize surface waves propagating in the lake bed zone to this end we analyze the strong motion records obtained at mexico city for the large m s 8 1 earthquake of 19 september 1985 it is shown that in the low frequency range we observe the rayleigh fundamental mode in both the vertical and the radial components and the love fundamental mode in the transverse component at all the strong motion stations the vertical component also shows the first higher mode of rayleigh waves we use a very broadband record obtained at station cu for the smaller m s 6 7 earthquake of 14 may 1993 to verify that the dispersion computed from the model of campillo et al 1989 represents well the average surface wave propagation between the coast and mexico city in the 7 to 10 sec period range we use this result to assign absolute times to the strong motion records of the michoacan event this allowed us to identify additional wave trains that propagate laterally in directions other than great circle in the 3 to 5 sec period range these wave trains are identified as love waves in a second analysis we study a set of refraction data obtained during a small scale 250 m experiment on the virgin clay of the lake bed zone phase velocity dispersion curves for several modes of rayleigh waves are identified in the refraction data and inverted to obtain an s wave velocity profile this profile is used as the uppermost layering in a 2d model of mexico city valley the results of numerical simulation show that surface waves generated by lateral finiteness of the clay layer suffer large dispersion and attenuation we conclude that surface waves generated by the lateral heterogeneity of the upper most stratigraphy very significantly affect ground motion near the edge of the valley but their importance is negligible for distances larger than 1 5 km from the edge thus locally generated surface waves propagating through the clay layer cannot explain late arrivals observed for the 1985 event we suggest that the long duration of strong motion is due to the interaction between lateral propagation of waves guided by deep layers 1 to 4 km and the surficial clay layer this interaction is possible by the coincidence of the dominant frequency of the uppermost layers and the frequency of the deeply guided waves

geochemistry and provenance of the middle ordovician austin glen member normanskill formation and the taconian orogeny in new england the austin glen member of the upper middle ordovician normanskill formation is a sandstone shale ysch succession deposited in the foreland of the taconian orogen petrographic major and trace element and nd pb isotopic data provide substantial constraints on its provenance lack of k feldspar and paucity of plagioclase in addition to the dominance of sedimentary rock fragments indicate that the source was dominated by recycled sedimentary components major and trace element data support this conclusion and indicate that the provenance of both shales and sandstones was the same no evidence of an ophiolitic or volcanic component was observed interpretation of nd isotopic characteristics are complicated by a partial resetting of the nd isotope system at about the time of sedimentation but indicate that the provenance of the austin glen member had a long term history of light rare earth element lree enrichment average tdm 1a8 ga furthermore nd isotopic compositions are extremely homogeneous end 8a1 0a6 1 s d n 23 at 450 ma the approximate depositional age indicating either a single source or very well mixed sources 207pb 204pb ratios are variable but within the range of pb isotopic compositions typically described as grenvillian the range of 207pb 204pb is greater than expected for the range of 206pb 204pb and suggests an additional component of pb possibly introduced during diagenesis the immediate source of the austin glen member may have been the accretionary prism that developed as older sediments of the laurentian margin were scraped off the basin oor incorporated within the accretionary prism and shed into the basin no evidence indicating the arrival of an undifferentiated island arc or continental fragment during the taconian orogeny has been found the data acquired during this study can be explained almost exclusively by grenville province source components but with possible additional contributions from older laurentian terranes and late proterozoic rift volcanics that are not readily quanti ed but likely to have been minor accordingly we conclude that the taconian orogeny in new england involved either 1 a continental arc that involved exclusively laurentia 2 collision of a continental block with identical geochemical characteristics as laurentia or 3 essentially no detritus from any exotic colliding block island arc or continental fragment reached the foreland basin at the time of austin glen deposition

a synthetic study to assess the applicability of full waveform inversion to infer snow stratigraphy from upward looking ground penetrating radar data snow stratigraphy and liquid water content are key contributing factors to avalanche formation upward looking groundpenetrating radar upgpr systems allow nondestructive monitoring of the snowpack but deriving density and liquid water content profiles is not yet possible based on the direct analysis of the reflection response we have investigated the feasibility of deducing these quantities using full waveform inversion fwi techniques applied to upgpr data for that purpose we have developed a frequency domain fwi algorithm in which we additionally took advantage of time domain features such as the arrival times of reflected waves our results indicated that fwi applied to upgpr data is generally feasible more specifically we could show that in the case of a dry snowpack it is possible to derive snow densities and layer thicknesses if sufficient a priori information is available in case of a wet snowpack in which it also needs to be inverted for the liquid water content the algorithm might fail even if sufficient a priori information is available particularly in the presence of realistic noise finally we have investigated the capability of fwi to resolve thin layers that play a key role in snow stability evaluation our simulations indicate that layers with thicknesses well below the gpr wavelengths can be identified but in the presence of significant liquid water the thin layer properties may be prone to inaccuracies these results are encouraging and motivate applications to field data but significant issues remain to be resolved such as the determination of the generally unknown upgpr source function and identifying the optimal number of layers in the inversion models furthermore a relatively high level of prior knowledge is required to let the algorithm converge however we feel these are not insurmountable and the new technology has significant potential to improve field data analysis

mobility and fractionation of rare earth elements in argillaceous sediments implications for dating diagenesis and low grade metamorphism abstract we report sm nd and rb sr data for the fine fractions of lower paleozoic argillaceous rocks from wales uk and new york usa spanning the range of low grade metamorphic conditions from the diagenetic zone zeolite facies to the epizone greenschist facies in all cases leaching of the fine fractions results in a high 147 sm 144 nd 0 09 0 29 acid soluble component and a complementary low 147 sm 144 nd 0 05 0 14 residual component the observed fractionation is an ancient feature related to diagenesis burial and metamorphism the magnitude of sm nd fractionation between leachates and residues as well as the resulting sm nd ages vary as a function of grain size and metamorphic grade uncleaved welsh mudrocks of the diagenetic zone yield sm nd leachate residue ages of 453 484 ma in agreement with their llanviian to caradocian biostratigraphic ages whereas higher grade rocks of the anchizone and epizone yield sm nd ages as young as 413 ma these ages are transitional between the time of deposition and the time of regional deformation related to the acadian orogeny at 390 ma distinct convex upward rare earth element ree patterns of the leachates suggest that the precipitation of early diagenetic apatite controls the trace element budget of the rock forcing a depletion of middle rees on the subsequently formed diagenetic phyllosilicates the amount of organic matter present and the extent of later prograde reactions are probable modifiers of this fractionation process ordovician and devonian clastic rocks associated with the trenton and onondaga limestones of new york yield single sample and multi sample sm nd isochron ages that agree well with their biostratigraphic ages of 454 ma and 390 ma respectively the ree fractionation observed in shale leachates of the ordovician utica formation is related to ca mg of the bulk rock and hence to the composition of the diagenetic carbonate cement in all cases the sm nd system remained closed subsequent to the peak of diagenesis or metamorphism including the north american rocks that show no evidence of being isotopically reset during widespread remagnetization of the subjacent limestone units in the late paleozoic

the influence of the layered character of snow cover on the triggering of slab avalanches one of the principal aims of avalanche warning is to prevent slab avalanches triggered by skiers other than explosives the best practical tool for stability evaluation is the rutschblock test whether the slab may be triggered by a skier depends on various slab characteristics important factors seem to be depth of the weak layer slab hardness and sublayering of the slab the stress distribution induced by a skier is calculated by the finite element method for typical snow cover configurations the additional shear stress is of the same order of magnitude as the shear strength of weak layers besides the critical weak layer prerequisite for a slab avalanche hard layers seem to be important the analysis suggests that a shear failure is most probable at the transition from a hard to a soft layer this corresponds well to observations of slab avalanche profiles the results may help to improve and quantify the analysis of snow profiles

scaling and parametrization of clear sky solar radiation over complex topography 1 solar radiation at the land surface is influenced by slope aspect shadows and obstruction of the sky all of which vary over a wide range of length scales in regions of complex topography with important consequences for the surface energy balance atmospheric models however generally assume the surface to be flat on subgrid scales for four areas in north america ranging in latitude from 39 n to 69 n and in topography from rolling to mountainous we simulate spatial patterns of clear sky incoming solar radiation it is found that distributions of slope components and variations in shaded area with solar elevation can be approximated by simple functions that scale to each of the areas studied from these results parametrizations are developed for averages standard deviations and distributions of direct beam and diffuse solar radiation results from these parametrizations and from a modified form of a simpler parametrization presented previously compare well with statistics from the spatial simulations the only topographic input required by the parametrizations is the standard deviation of slope components this parameter is again found to have simple scaling relationships with the resolution and extent of the underlying elevation grid and with the standard deviation of elevation

sm nd isotopic dating of proterozoic clay material an example from the francevillian sedimentary series gabon clay fractions of 0 4 m and 0 2 m and acid leachates of these clay fractions were separated from two different kerogen rich black shale samples from the francevillian sedimentary series in gabon they yielded identical sm nd isochron ages of2099 115 ma and2036 79 ma with initial nd values of 6 5 2 0 and 9 3 1 5 respectively these ages define multi episode illitization during early diagenesis as suggested by the differentsm nd ratios of the clay fractions the sm nd isotope data of the kerogen source rock up to 13 organic carbon plot between the two isochrons but close to the clay fractions suggesting that this organic matter reached nd isotopic equilibrium with respect to the clay minerals and the diagenetic fluids analyses of fracture filling bitumen showed that it had very elevated143nd 144nd and147sm 144nd ratios these values are higher than the most elevated values of the leachates but plot on the extension of the two isochrons this indicates that the bitumen reached nd isotopic equilibrium with the kerogen source rock from which it was expelled and the authigenic clay minerals secondary migration and chemical evolution of the bitumen appear to have caused the fractionation between sm and nd with an attendant increase in thesm nd ratio the results suggest that the sm nd isotope method has potential for both dating diagenetically related illitization using leachate residue pairs of small size clay fractions and reconstructing geochemical processes during diagenesis in oil producing sedimentary basins

rare earth element redistribution and its effects on the neodymium isotope system in the austin glen member of the normanskill formation new york usa abstract three groups of ree patterns are observed for the sandstones and shales of the middle ordovician austin glen member of the normanskill formation one sandstone sample is enriched in middle and light rare earth elements the majority of samples are light rare earth element lree enriched with negative eu anomalies and flat heavy rare earth elements hrees whereas a third group appears to have lost lrees and middle rare earth element mrees homogeneous neodymium isotopic compositions for all samples at about the time of deposition nd 470 ma 8 2 1 1 2sd indicate that the source of the austin glen member was well mixed and that the neodymium had a long term enriched history the differences in the shape and abundances of the ree patterns combined with the neodymium isotope characteristics of the samples lead us to the conclusion that samarium and neodymium were fractionated and that the neodymium isotopic system might have been disturbed at about the time of deposition 470 ma most samples appear to have been affected by this process the two most altered shales lost about half of their neodymium and their sm nd ratios are higher than the sm nd ratios of average shales these two shales give clearly erroneous mantle extraction ages but the average tdm of the provenance can still be deduced 1700 1800 ma from the least disturbed sandstones with normal upper crustal sm nd ratios accordingly this study demonstrates that the rees may be transported and neodymium isotopes may be reequilibrated under certain sedimentary conditions e g diagenesis however in spite of evidence for ree redistribution provenance information tdm original ree patterns may still be inferred

impact of a climate change on avalanche hazard the safran crocus mepra software is used to assess the climatology of the avalanche hazard and its sensitivity to climate change a natural avalanche hazard index based on mepra analysis is defined and validated against natural avalanche observations triggered avalanches are not taken into account a 15 year climatology then allows a comparison of avalanche hazard in the different french massifs finally a simple climate scenario with a general increase of precipitation and temperature shows that avalanche hazard may decrease slightly in winter mainly february and more significantly in may june the relative proportion of wet snow avalanches increases

strong motion in central mexico a model based on data analysis and simple modeling predictions of ground motion for mexico city during future large earthquakes are currently based on statistical analysis of the large quantity of data recorded by the mexico city accelerograph network mcan in spite of the robustness of these predictions large uncertanties come from our lack of a physical model that is able to account for the observations in this article we present such a model based on analysis of strong motion records obtained during the 25 april 1989 guerrero earthquake and on numerical modeling data analysis suggests that the large amplitudes and very long duration of ground motion observed in the lake bed zone in mexico city result from the interaction of diffracted wave trains of rayleigh waves and the very soft clay layer that covers the ancient lake of mexico city numerical modeling supports this hypothesis and indicates that this interaction is possible in spite of the largely different scales kilometers for the incident surface waves and tens of meters for the clay layer lateral heterogeneities split incoming wave trains into different modes each is strongly amplified and its duration is increased by the soft clay layer at its resonant frequency resulting in the very long monochromatic ground motion that has been the subject of a large number of articles since the 1985 michoacan earthquake manuscript received 23 august 2001

diagenesis of low mobility elements ti rees th and solid bitumen envelopes in permian kennedy group sandstone western australia the permian kennedy group carnarvon basin western australia is a shallow marine shelf deposit of sandstone and interlaminated siltstone the original sand was apparently arkosic but was altered by dissolution of feldspar and by other diagenetic processes into a kaolinitic sideritic silicified quartz arenite after lithification hydrocarbons moved through the sandstone leaving microscopic solid bitumen envelopes that had formed around radioactive detrital minerals when irradiation polymerized crosslinked and locally solidified the oil most radioactive cores are monazite a few are zircon and xenotime some monazite grains contain minute elongate randomly oriented perforations that almost certainly represent fission tracks and are filled with bitumen the diagenetic sequence can be divided into three phases phase 1 the earliest is an episode of complex diagenesis phase 2 covers the time when pores were filled with hydrocarbons and the solid bitumen envelopes formed but other diagenetic reactions were inhibited phase 3 begins with the entry of formation waters phase 1 authigenic minerals comprise anatase anhydrite brookite florencite thorite halite muscovite pyrite quartz possible rutile siderite cryptocrystalline silica sphalerite and xenotime rare thorite thsio 4 locally replaces monazite siderite crystals contain nine zones the main variations being in fe and mg and contain solution cavities that may have formed in phase 1 two minerals not commonly reported as authigenic are florencite ce la al phosphate mainly as minute pseudocubic euhedra replacing feldspar and mica and xenotime ypo 4 as outgrowths on detrital zircon grains phase 2 diagenesis includes formation of the solid bitumen envelopes and phase 3 includes authigenesis of quartz kaolinite and zoned calcite and perhaps solution of some florencite the solid bitumen envelopes surrounding the radioactive accessory minerals enclose rare minute authigenic halite and anhydrite crystals whose absence elsewhere suggests that the envelopes preserved them from solution during phase 3 titanium dioxide probably from ilmenite or titano magnetite or both partly replaces feldspar and mica some aspects of the diagenesis are particularly significant 1 solid bitumen envelopes not only indicate the former presence of hydrocarbons but also enable the complex diagenetic sequence to be divided into three well defined phases 2 the envelopes can trap and preserve minerals apparently unable to resist solution outside the envelopes i e minerals that would otherwise have disappeared 3 the zoned siderite calcite and florencite indicate changes in pore water composition in the first and third diagenetic phases 4 ti and some ree were mobile at least on the scale of a thin section during early diagenesis

mexico 1985 the case for gravity waves summary the argument for the existence of gravity waves in sedimentary layers during strong earthquakes such as the 1985 mexico earthquake is based on a theory which predicts a discontinuity in surface wave propagation at a finite strain value b effects of stress strain non linearity in sediments and c observations suggesting the presence of ultra short wavelengths in soils during the 1985 mexico earthquake

interaction of seismic waves with a viscous liquid layer abstract the interaction of seismic waves with a layer filled with a viscous fluid is studied this study is intended to provide the basis for designing active seismic experiments to detect the existence of hydraulically induced fractures in a hot dry rock geothermal energy system we compute transmission and reflection coefficients for p sv and sh waves incident at arbitrary angles onto a fluid layer embedded between two homogeneous half spaces we find that coefficients for sh waves at normal incidence can be written in terms of two dimensionless parameters one of these parameters i is the ratio of acoustic impedance of the fluid to the acoustic impedance of the solid the other dimensionless parameter d is a measure of the amount of energy the sh wave loses during one pass through the fluid layer we find that the amplitude of the sh wave transmitted through the fluid layer is equal to the amplitude of the incident sh wave if i is nearly 1 and d is small as d increases energy is lost due to viscous dissipation in the fluid and transmitted wave amplitude diminishes if i is not nearly 1 some energy is reflected by the fluid layer three dimensionless parameters are required for solution for the case of p waves normally incident on the fluid layer one parameter r is the ratio of the bulk modulus to effective shear modulus of the fluid the second parameter is the ratio of elastic impedance of the solid to the shear impedance of the fluid and the third is d we find that the value of r is a good measure of the importance of fluid viscosity on the propagation of p waves through the fluid detailed studies of the effects of fluid and solid physical properties on the amplitudes of transmitted and reflected waves when waves are normally incident provide valuable insight into the importance of physical properties in the calculations for non normal incidence finally reflection and transmission coefficients are computed for p and sv waves incident at arbitrary angle on a viscous fluid layer physical properties of fluid and rock are chosen to be those thought appropriate for the los alamos national laboratory hot dry rock geothermal test site located at fenton hill new mexico

evaluation of slope stability with respect to snowpack spatial variability the evaluation of avalanche release conditions constitutes a great challenge for risk assessment in mountainous areas the spatial variability of snowpack properties has an important impact on snow slope stability and thus on avalanche formation since it strongly influences failure initiation and crack propagation in weak snow layers hence the determination of the link between these spatial variations and slope stability is very important in particular for avalanche public forecasting in this study a statistical mechanical model of the slab weak layer wl system relying on stochastic finite element simulations is used to investigate snowpack stability and avalanche release probability for spontaneously releasing avalanches this model accounts in particular for the spatial variations of wl shear strength and stress redistribution by elasticity of the slab we show how avalanche release probability can be computed from release depth distributions which allows us to study the influence of wl spatial variations and slab properties on slope stability the importance of smoothing effects by slab elasticity is verified and the crucial impact of spatial variation characteristics on the so called knock down effect on slope stability is revisited using this model finally critical length values are computed from the simulations as a function of the various model parameters and are compared to field data obtained with propagation saw tests

geochemistry of the arvonia formation chopawamsic terrane virginia implications for source area weathering and provenance the metasedimentary arvonia formation in the piedmont province of central virginia ranges primarily from slates to garnet schists which unconformably overly middle ordovician metavolcanic rocks of the chopawamsic arc terrane the formation has typically been interpreted as late ordovician based on poorly preserved fossils perhaps having formed as a successor basin following accretion of the chopawamsic arc to laurentia however alternative interpretations have been proposed including deposition outboard of laurentia on chopawamsic arc crust that is prior to accretion furthermore the origin of the chopawamsic arc as peri laurentian or peri gondwanan is an unresolved issue we report whole rock major and trace element compositions as well as nd isotopic compositions of the arvonia formation and use these results to evaluate further its origin samples collected along the length of the outcrop belt show similar major element compositions which are typical of shales chemical index of alteration values 68 89 corrected for k metasomatism indicate intermediate to extreme levels of source weathering a majority of the samples show uniform rare earth element ree patterns that are light ree enriched with negative eu anomalies a few samples display anomalous ree patterns indicative of some disturbance of the light ree at approximately the time of deposition a variety of trace element values or ratios indicate that arvonia sediments are similar to shale composites thus upper continental crust nd isotopic compositions for eight samples are similar with end 5 6 to 8 9 400 ma collectively these results are consistent with derivation of arvonia sediments from a single source or well mixed sources of typical upper crustal composition the isotopic data are compatible with a laurentian provenance however they are equally compatible with a strictly chopawamsic crustal source based on available nd isotopic data

late pleistocene catchment wide denudation patterns across the european alps abstract we compile detrital 10be concentrations of alpine rivers representing the denudation rates pattern for 375 catchments across the entire european alps using a homogeneized framework we employ state of the art techniques for inverting in situ 10be concentrations into denudation rates from our compilation we find that i while lithologic properties and precipitation runoff do influence erosion mechanisms and rates at the scale of individual catchments and in some specific alpine regions such controls do not directly stand for the entire alps ii as also previously suggested catchment wide denudation rates across the entire european alps closely follow first order alpine topographic metrics at the scale of individual catchments or selected alpine sub regions however in addition to previous local scale studies conducted in the european alps our large scale compilation highlights a functional relationship between catchment wide denudation and mean catchment slope angle catchment wide denudation positively correlates with mean catchment slope up to a threshold angle 25 30 above this threshold any correlation between catchment wide denudation and slope as well as other catchment metrics breaks apart we can reconcile these systematic patterns by proposing a regional erosion model based on diffusive transport laws for catchments located below the slope threshold angle in oversteepened catchments situated above threshold slopes erosion is stochastic in nature as glacial carving likely caused a partial decoupling between hillslope and fluvial domains with complex topographic relationships and sediment connectivity patterns finally we identify a first order positive relationship between modern geodetic rock uplift and catchment wide denudation for the european alps the observed spatial pattern is highly variable and possibly reflects the surface response to deep geodynamic mechanisms prevailing in the different alpine regions we conclude that today s topography and geomorphic features of the entire alps are the result of a millenial scale geomorphic response to past glacial processes and active rock uplift highlighting a link between external and internal drivers for mountain erosion

stratigraphic relationships and detrital composition of the medial ordovician flysch of western new england implications for the tectonic evolution of the taconic orogeny a reply to rodgers we present new stratigraphic and petrographic data on the easterly derived medial ordovician flysch sequence of western new england and eastern new york state a conformable relationship exists between the flysch and underlying early paleozoic continental rise sediments within the western taconic allochthon farther east in the allochthon we observe a possibly disconformable relationship contrary to previous interpretations these facts suggest that at any place within this paleogeographic realm the sediments were undeformed and untransported at the initiation of flysch deposition at least three sources contributed detritus to the flysch 1 taconic sequence sediments 2 deformed and metamorphosed pelitic psammitic and volcanic lithologies and 3 igneous rocks of dominantly mafic ultramafic affinities these three sources are respectively interpretable as continental rise accretionary prism and ophiolitic volcanic arc assemblages which are recognized in the regional geology of western new eng

a computer based system simulating snowpack structures as a tool for regional avalanche forecasting this paper describes the current state of a complete automatic system of three numerical models that simulate snow cover stratigraphy and avalanche risks for operational avalanche forecasting the first model safran estimates relevant meteorological parameters affecting snowpack evolution the second crocus is a snow numerical model which simulates the physical processes inside the snowpack and its stratigraphy the last model mepra is an expert system based on an assessment of snowpack stability it deduces natural and accidental avalanche risks to describe the great variability of the snowpack and the associated avalanche risks this automatic system simulates snow cover evolution and its stability for many typical slopes elevations and aspects representative of the different french massifs to achieve this result different kinds of validations have been carried out since winter 1981 they are mainly based on comparisons with different sets of measurements and on the opinion of users although the routinely obtained results do not yet take into account all small scale effects such as wind transport they have been considered as valuable information by avalanche forecasters since 1992 93 and used operationally since then

monitoring of snow avalanches using a seismic array location speed estimation and relationships to meteorological variables 1 monitoring snow avalanches is necessary in order to better understand their triggering mechanisms and ultimately improve forecast performance seismic monitoring has been developed by several groups over the last 20 years and holds great potential to detect locate and characterize snow avalanches during the 2009 2010 winter a seismic antenna was installed in the french alps close to the village of saint christophe en oisans 1700 m above sea level the array of seven sensors operated during 50 days in october and november 2009 under snow free conditions and during 40 days in january and february 2010 in presence of snow it recorded different types of seismic events including snow avalanches rockfalls shots and regional and local microearthquakes eighty avalanche signals were visually identified using a beam forming method we were able to locate snow avalanches on slopes of various orientations in a radius of about 3 km and track their propagation the location technique allowed for the estimation of avalanches front speed which ranged between 12 and 32 m s 1 the method can also distinguish dry and wet snow avalanches durations of avalanches can be as long as 380 s because of the length of the slopes in the area seismic monitoring provides a catalog of avalanches with precise times which can be used to analyze the impact of meteorological forcings on the avalanche triggering snowfall is found to be the dominant forcing of avalanche activity during this period as revealed by the strongest correlation for the period of study our results suggest that the impact of precipitation on the snowpack instability lasts for about 6 days

a petrographic approach for evaluating trace element mobility in a black shale abstract at the time of deposition black shales record geochemical information related to the provenance and conditions of deposition for that rock these initial geochemical conditions are susceptible to alteration and overprinting by the aggressive processes of black shale diagenesis in this study we evaluate a sequence of ordovician black shales from the southern welsh basin for the presence of such a diagenetic overprint through use of cathodoluminescence backscattered electron imaging reflected light microscopy fission tracks and microprobe elemental mapping we can discern textural relationships with in the welsh black shales the relationships observed constrain a paragenetic sequence and overall diagenetic history including the early diagenetic formation of pyrite apatite rare earth element ree rich and carbonate and later formation of diagenetic monazite ree u rich and late stage carbonate the chemical reactions necessary to produce this mineral sequence require postdepositional redistribution of ree including changing cerium anomalies ce ce and uranium as a result ree u and their associated isotopic systems sm nd and u pb can reflect a diagenetic overprint rather than the source area and depositional conditions the paragenetic sequence described in this study records several postdepositional changes in the whole rock mineralogy among these changes are the formation of ree rich apatite and ree and u rich monazite the formation of these phases requires that ree and u are being redistributed on at least a mineral scale and that the initial depositional and provenance information recorded by the whole rock has been disturbed therefore the approach used in this study to carefully characterize the paragenetic sequence from the llandeilo caradoc black shales should be considered necessary in order to fully evaluate the usefulness of trace element proxies susceptible to diagenetic redistribution

a systematic method for analyzing borehole recordings to estimate the wavefield in the lakebed zone of mexico city during the 1985 michoacan earthquake m s 8 1 large amplitude seismograms with extremely long duration hundreds of seconds were recorded in the lakebed zone of mexico city in spite of numerous studies the lakebed seismograms are not well understood in the present study we develop a systematic method for analyzing borehole recordings and apply it to recordings at depths of 0 and 102 m at the roma station to interpret the wavefield in the lakebed zone the target frequency period range is between 0 2 and 3 3 hz 0 3 and 5 0 sec we cross correlate the surface and borehole strong motion seismograms and identify body and surface wave portions in the main motions then we interpret the surface waves as fundamental mode love waves by calculating theoretical amplitude ratios for different scale structures using a statistical time series model with an information criterion we separate s and love wave portions from the surface recordings love waves are dominant and are recognized even in the early time section finally we attempt to explain s wave transfer functions between the surface and borehole recordings by considering subsidence of soft surficial deposits for several years on the basis of a three dimensional finite element technique this simulation demonstrates effects of the subsidence on amplification of s waves

the effects of weathering on rare earth element y and ba abundances in tertiary basalts from southeastern australia tholeiitic basalts showing anomalously high ba y and rare earth element ree concentrations occur within the tertiary newer volcanic province of victoria and these geochemical characteristics are related to incipient alteration accompanying weathering ree and y released during weathering of basalts are retained either in secondary phosphate or clay minerals and in rocks showing very high ba concentrations the ba is present as baso4 leaching experiments suggest that glassy or fine grained rocks are more likely to release ree y and ba while more extensively altered rocks are likely to hold these elements probably because they substitute in or are adsorbed on clay minerals or because secondary baso4 and ree phosphates are resistant to acid leaching samples taken sequentially across a weathering profile in a tholeiitic basalt flow from fresh to intensively altered rock illustrate that in the very earliest stages of alteration extreme variations in the abundances of ba y and ree can occur this is reflected in the broad patterns of trace element behaviour manifested by an extensive analysed sample suite from the victorian newer volcanic province where there is no correlation between anomalous enrichments in ba y or ree and the level of incipient alteration ba anomalies are not necessarily accompanied by abnormal y and ree behaviour and this is probably because the mobility of each trace element is a function of a the ionic radius and charge of the ionic species it forms in solution b local groundwater parameters such as eh ph groundwater flux and concentrations in the groundwater of species such as so42 and c the secondary mineral assemblages developed in a particular situation sr isotopic compositions are not strongly affected by incipient weathering and do not show significant changes until alteration has progressed to the point where plagioclase begins to break down the study illustrates that relatively slight alteration at the earliest stages of weathering can produce drastic changes in the concentrations of ree y and ba and petrographic assessment of the freshness of samples is not precise enough to eliminate prior to analysis cases where these effects may be manifested where weathering has caused changes in abundance patterns these may be recognised by careful comparisons of appropriate elemental ratios e g ba rb throughout a particular analysed sample suite

cerium anomalies in lateritic profiles the ree geochemistry and mineralogy have been studied in four lateritic profiles one derived from a syenite akongo sw cameroon the others being developed on a gneissic basement and located along a soil toposequence goyoum e cameroon there is a fractionation between lree and hree in the lateritic samples during weathering the weathered residual products being enriched in lree from la to eu and depleted in hree from gd to lu sampled waters are enriched in hree in relation to the syenite host rock a positive ce anomaly has been found systematically at the top of the saprolite beneath a zone of iron oxide accumulation in the laterite up to 2000 ppm ce may be present in the akongo profile cerianite ceo2 is present as very fine coatings in non ferruginous clayey domains primary ree bearing accessory minerals are weathered at the bottom of the profile specifically allanite and apatite are transformed into florencite and rhabdophane but these phases have no ce anomaly all the data are interpreted as the result of the following processes 1 1 ree leaching in a reducing environment 2 2 oxidation of ce3 to ce4 in an oxidizing environment 3 3 deposition of cerium as cerianite whereas the other ree remain in solution

gravity waves in mexico city ii coupling between an anelastic solid and a fluid layer abstract this paper completes a previous study of the role of gravity during the 19 september 1985 michoacan earthquake at mexico city it is assumed as suggested by lomnitz 1989 1990 that nonlinear mechanisms could bring the rheology of the mexico city soft clay layer nearer to a fluid than to a solid in order to test whether gravity waves in a viscous fluid could provide an explanation of exceedingly long duration observed at mexico city we have studied the motion on the surface of an irregular viscous fluid layer overlaying an elastic half space our formulation takes into account vertical displacement at the free surface of the fluid layer but requires a linearization of the corresponding boundary condition a decomposition of diffracted fields in terms of plane waves allows the use of aki larner9s method excitation is given by vertically incident sv waves we present results both for nonviscous and viscous fluids and show that an adequate free boundary condition is essential for this problem lacking data we have performed several simulations for values of viscosity going from 300 to 30 000 pa s in the case of a nonviscous fluid gravity surface waves are generated efficiently by diffraction of elastic waves on the irregular interface but attenuate rapidly when including viscosity and are not significant for viscosities above 3000 pa s the results presented in our companion paper and here allow us to conclude that gravity is not a likely explanation to the long duration of ground motion observed at mexico city in a more general context our model may be useful to study the interaction of seismic waves with water reservoirs such as dams

on the nature of regional seismic phases iii the influence of crustal heterogeneity on the wavefield for subduction earthquakes the 1985 michoacan and 1995 copala guerrero mexico earthquakes summary the most prominent feature of the regional seismic wavefield from about 150 to over 1000 km is usually the lg phase this arrival represents trapped s wave propagation within the crust as a superposition of multiple reflections and its amplitude is quite sensitive to the lateral variation in the crust along a propagation path in an environment where the events occur in a subduction zone such as the western coast of mexico quite complex influences on the character of the regional wavefield arise from the presence of the subduction zone the great 1985 michoacan earthquake mw 8 1 which occurred in the mexican subduction zone was one of the most destructive earthquakes in modern history and its notable character was that at mexico city located over 350 km from the epicentre there was strong ground shaking almost comparable to that in the epicentral region that lasted for several minutes considerable effort has been expended to explain the origin of the unusual observed waves that caused the severe damage in the capital city during the destructive earthquake the nature of the propagation process in this region can be understood in part by using the detailed strong motion records from the 1995 copala guerrero mw 7 4 earthquake near the coast to the south of mexico city which also had an enhanced amplitude in the valley of mexico numerical modelling of both p and s seismic waves in 2 d and 3 d heterogeneous crustal models for western mexico using the pseudospectral method provides direct insight into the nature of the propagation processes through the use of sequences of snapshots of the wavefield and synthetic seismograms at the surface a comparison of different models allows the influences of different aspects of the structure to be isolated 2 d and 3 d modelling of the 1985 michoacan and 1995 copala earthquakes clearly demonstrates that the origin of the long duration of strong ground shaking comes from the sn and lg wave trains these s wave arrivals are produced efficiently from shallow subduction earthquakes and are strongly enhanced during their propagation within the laterally heterogeneous waveguide produced by the subduction of the cocos plate beneath the mexican mainland the amplitude and duration of the lg coda is also strongly reinforced by transmission through the mexican volcanic belt from the amplification of s waves in the low velocity surficial layer associated withs to p conversions in the volcanic zone the further amplification of the large and long lg wave train impinging on the shallow structure in the basin of mexico city with very soft soil underlain by nearly rigid bedrock with a strong impedance contrast gives rise to the destructive strong ground shaking from the mexican subduction earthquakes

long lived lree mobility in the cratonic rift and foredeep to foreland sedimentary cover at the western margin of the karelia province abstract the western margin of the karelia province of the fennoscandian shield consists of archean crust covered by remnants of paleoproterozoic c 2 5 1 9 ga metasedimentary rocks the study area in the eastern part of the margin shows 2 3 2 1 ga cratonic sedimentation followed by 2 1 2 05 ga rift sedimentation and c 1 91 1 92 ga foredeep to foreland sedimentation related to continent arc continent collision extreme lree mobility loss up 95 of la is recorded by many samples from these units monazite bastnasite and in some cases allanite have been the prealteration lree host phases in the lree depleted samples monazite was altered to th silicates with variable loss of the lree the remaining part of which was incorporated in th poor monazite the depositional age of the sedimentary units was studied by dating la mc icpms detrital zircon grains and the age of lree mobility by dating monazite and xenotime and by whole rock sm nd modeling the maximum deposition age of the foredeep to foreland basin is 1 91 1 92 ga based on detrital zircon data and the minimum age of the main foliation in the study area is 1 87 1 86 ga based on the younger age limit of late to post tectonic xenotime and the ages of few probable metamorphic zircons coeval bastnasite with xenotime in a lree enriched sample suggests that this was also one important stage of lree mobility monazite crystallizations have occurred 1 76 1 78 ga ago while the rb sr whole rock data suggest that the closure of this isotope system took place 1732 21 ma ago the sm nd modeling gives ages at 0 4 1 0 ga for lree depletion the sm nd age of 412 27 ma can be considered as the age of the latest major lree depletion event we propose that alkali bearing oxidizing fluids started to form in the cratonic sequences due to diagenetic reactions maybe as early as 2 3 2 1 ga alkalinity of fluids was later increased by interaction with alkaline 2 05 ga source materials before and during the c 1 91 1 92 ga foredeep to foreland basin stage basin inversion and metamorphic crystallization occurred at 1 91 1 87 ga episodes of fluid migration at 1 78 1 73 ga and afterwards were focused along fracture zones and in microfracture networks the 0 4 ga stage is the most prominent of the

redistribution of rare earth elements during diagenesis of turbidite hemipelagite mudrock sequences of llandovery age from central wales

prograde rayleigh wave particle motion summary fundamental mode rayleigh waves generally show retrograde particle motion at the surface of the earth if there exists a thick sedimentary layer however reversal of the sign of vertical eigenfunction occurs near the surface resulting in prograde rayleigh wave particle motion at the surface we show that for structures similar to those found in the los angeles basin with thickness up to 8 km surface prograde motion may occur within the frequency band 0 05 0 3 hz although it has been suggested that the effect of gravity on waves in unconsolidated surface layer may be important partitioning of energy between the elatic and gravitational energy shows that the gravitational energy is less than 1 per cent and thus is not important the phenomenon is caused by elastic effects mainly caused by extremely slow shallow seismic velocities observation of prograde elliptical particle motion may be difficult however because particle motion is largely horizontal and high microseismic noise exists in the same frequency band

two dimensional numerical modelling of surface wind velocity and associated snowdrift effects over complex mountainous topography a new experimental software for blowing snow sytron2 is pre sented it takes advantage of the previous limited realization sytron1andof the entire real time operational environment of the automatic chain safran crocus mepra scm it runs presently on a rectangular grid with a mesh size of about 45m covering an area of 3 0 3 0km 2 around the observation test site col du lac blanc french alps 2700m a s l near the alpe d huez ski resort sytron2 is initialized with a realistic snowpack representation derived fromthe scmoutputs andcoupledto awind fieldcom puted by the new samver model the final aim is to build a fully embedded tool sui table for representing snowdrift effects with a better resolution at different specific locations the different tools and operators used are described as well as the field valida tion processes which are based on remote identification of the eroded and accumulated areas using digital pictures

linking the effective thermal conductivity of snow to its shear strength and density 1 the effective thermal conductivity of snow keff is a crucial climatic and environmental variable here we test the intuition that keff is linked to microstructural and mechanical properties by attempting to relate keff to density snow and to shear strength measured with a handheld shear vane we performed 106 combined measurements of keff snow and in the alps svalbard arctic alaska and near the north pole covering essentially all snow types we find a good correlation between keff and snow which is not significantly different from that of sturm et al 1997 the correlation between keff and a combination of and snow is stronger than with density alone we propose an equation linking keff w m 1 k 1 snow kg m 3 and pa keff 7 114 10 5 snow 0 333 2 367 10 2 this equation places constraints on the calculation of keff snow and in avalanche warning models where is a key variable for our samples we calculate from measured values of keff and snow using our equation and compare the value to that predicted by the french mepra avalanche warning model which uses density and grain type as input data mepra and the prediction of based on keff and snow agree within 8 mepra agrees with observations within 11 calculating from density only yields values 55 lower than measured showing the interest of using additional data to predict

interoceanic variation in the rare earth major and trace element depositional chemistry of chert perspectives gained from the dsdp and odp record rare earth element ree major and trace element abundances and relative fractionations in forty nodular cherts sampled by the deep sea drilling project dsdp and ocean drilling program odp indicate that the ree composition of chert records the interplay between terrigenous sources and scavenging from the local seawater major and non ree trace element ratios indicate that the aluminosilicate fraction within the chert is similar to nasc north american shale composite with average pacific chert including 7 nasc like particles indian chert 11 nasc atlantic chert 17 nasc and southern high latitude shl chert 53 nasc using la as a proxy for ree approximations of laex the amount of la in excess of that supplied by the detrital aluminosilicate fraction indicate that pacific chert contains the greatest laex 85 of latotal and shl chert the least 38 of latotal as shown by interelement associations this laex is most likely an adsorbed component onto aluminosilicate and phosphatic phases accordingly chert from the large pacific ocean where deposition occurs relatively removed from significant terrigenous input records a depositional ree signal dominated by adsorption of dissolved rees from seawater pacific chert cece 1 and lanybn 0 8 1 resulting from adsorption of local ce depleted seawater and preferential adsorption of lrees from seawater e g lanybn 0 4 which increases the lanybn ratio recorded in chert chert from the atlantic basin a moderately sized ocean basin lined by passive margins and with more terrigenous input than the pacific records a mix of adsorptive and terrigenous ree signals with moderately negative ce anomalies and lanybn ratios intermediate to those of the pacific and those of terrigenous input chert from the shl region is dominated by the large terrigenous input on the antarctic passive margin with inherited cece 1 and inherited lanybn values of 1 2 1 4 cece does not vary with age either throughout the entire data base or within a particular basin overall cece does not correlate with p2o5 concentrations even though phosphatic phases may be an important ree carrier this and previous studies of the large scale controlling parameters of sedimentary rees across ocean basins collectively indicate that ree indices of depositional regime e g cece lanybn laex are reproducible in a variety of sediment and rock lithologies ages and ocean basins and present a coherent tool for paleoceanographic and tectonic basin reconstructions

seismic coupling of interface modes in sedimentary basins a recipe for disaster abstract coupling between an evanescent p wave and a rayleigh wave can occur when the two modes share the same phase velocity at an interface the result is a new distinctive monochromatic mode of large amplitude and finite duration that may reverberate in a bounded layer generating stationary patterns due to constructive and destructive interference such modes may be responsible for earthquake damage in the valley of mexico and perhaps in other sedimentary basins vulnerable to seismic disasters on soft ground

ree fractionation and ce anomalies in weathered karoo dolerite abstract analyses of samples from a weathering profile on karoo dolerite allow elements to be divided into three groups depending on their behaviour si k na mg ca sr ba and v are mobilized and removed from weathered products fe al ti zr hf zn cu sc co and ni are immobile ree y and to a lesser extent cr are mobile and redistributed within the profile without a net loss of these elements from the profile large positive ce anomalies are developed in oxidized weathered products by preferential leaching of the other ree s negative ce anomalies and ree enrichment is a feature of less altered dolerite

continuous snowpack monitoring using upward looking ground penetrating radar technology snow stratigraphy and water percolation are key contributing factors to avalanche formation so far only destructive methods can provide this kind of information radar technology allows continuous non destructive scanning of the snowpack so that the temporal evolution of internal properties can be followed we installed an upward looking ground penetrating radar system upgpr at the weissfluhjoch study site davos switzerland during two winter seasons 2010 11 and 2011 12 we recorded data with the aim of quantitatively determining snowpack properties and their temporal evolution we automatically derived the snow height with an accuracy of about 5 cm tracked the settlement of internal layers 7 cm and measured the amount of new snow 10 cm using external snow height measurements we determined the bulk density with a mean error of 4 3 compared to manual measurements radar derived snow water equivalent deviated from manual measurements by 5 furthermore we tracked the location of the dry to wet transition in the snowpack until water percolated to the ground based on the transition and an independent snow height measurement it was possible to estimate the volumetric liquid water content and its temporal evolution even though we need additional information to derive some of the snow properties our results show that it is possible to quantitatively derive snow properties with upgpr

3d analysis of s wave propagation in soft deposits during the 1985 michoacan earthquake surface wave magnitude 8 1 large amplitude seismograms of extremely long duration were recorded in the lake bed zone of mexico city large amplification in soft surficial deposits has not been well understood ground subsidence of the soft clay deposits might heavily influence s wave propagation in the present study we attempt to explain both s wave amplification and propagation time between surface and borehole recordings under the action of gravity on the basis of a 3d nonlinear finite element fe technique where a bilinear model with a mohr coulomb criterion is used we identify body wave s wave time sections in the recordings with a cross correlation analysis the fe simulation successfully predicts the s wave amplification and propagation time which cannot be explained by a purely 1d linear model although subsidence changes s wave linear amplification s wave propagation time decreases little

elemental distributions and neodymium isotopic compositions of silurian metasediments western maine usa redistribution of the rare earth elements abstract pelitic schists from the lower garnet to lower staurolite zones from the rangeley perry mountain and smalls falls formations of western maine were analyzed for major elements trace elements and neodymium isotopes these formations were derived from highlands created during the taconian orogeny deposited into a trough and metamorphosed during subsequent orogenic events most major and trace element abundances relative to al 2 o 3 were statistically identical between zones of the same formation as well as between formations although the average major element composition of these formations are the same there are systematic variations in some elements notably plots of sio 2 vs al 2 o 3 and k 2 o vs al 2 o 3 suggest that most of the variation could be produced by mixing of a fairly constant ratio of clay minerals and feldspar with varied amounts of quartz due to sorting in the sedimentary system different amounts of these minerals should not influence the shape of the ree patterns of the metapelites but higher amounts of quartz and feldspar may dilute the rees and most elemental abundances of the clay minerals and lead to lower elemental abundances the major difference between the samples within the perry mountain formation are different lree and mree abundances relative to al 2 o 3 which are not correlated to differences in major element or other trace element abundances relative to al 2 o 3 the samples in the perry mountain with higher lree and mree abundances have for example 42 3 8 3 ppm and those with low abundances have 5 6 3 6 ppm the samples with the high ree abundances of the perry mountain formation are similar in abundances and ree patterns to those of the rangeley and smalls falls formations typical of mudstones derived from granitoids another difference between the low and high ree abundance samples are the calculated t dm model ages the high ree abundance samples of the perry mountain formation show t dm similar to the samples of the rangeley formation with ages of about 1 7 1 8 ga the perry mountain samples with low ree abundances however give unrealistically old t dm s between 2 5 and 5 3 ga these unrealistically old t dm s are due to the relatively high sm nd ratios compared to crustal values which are characteristic of samples of the perry mountain formation with lower ree abundances we therefore suggest that these samples may be indicators for open system behavior of the neodymium isotopic system the timing of this disturbance of the neodymium isotope system is difficult to determine and cannot be tied to weathering or a definite postdepositional event the complexities of the data suggest more than one resetting event the most likely event that could have produced much of the movement of the lrees and mrees could have been due to small scale migration between anoxic hemipelagites and turbidite mudstones during diagenesis but some migration may have continued during metamorphism in order to reconcile the neodymium isotopic data

coexistence of gravity waves and elastic waves in unconsolidated sediments based on a linear viscoelastic model we study the coexistence and transition of gravity waves and surface elastic waves in a half space of unconsolidated sediment the dispersion relation and surface response are calculated as a function of the period and rigidity of the system the dispersion relation shows two branches one branch corresponds to a rayleigh wave for short wave periods and it becomes a leaky surface wave as the period increases the second branch shows a linear dependence of the phase velocity with period as expected for gravity waves as the period increases this branch evolves into a leaky surface wave joining the first branch the surface response function which is related to the vertical displacement is also calculated two distinct peaks are present in the surface response function one corresponds to a classical rayleigh wave while the second is a gravity driven mode whose amplitude is strongly dependent on the wave period and soil rigidity

mixing relationships and the effects of secondary alteration in the wishstone and watchtower classes of husband hill gusev crater mars 1 the wishstone and watchtower class rocks on husband hill preserve evidence for a geochemical relationship consistent with two component mixing between a high al 2 o 3 tio 2 cao na 2 o p 2 o 5 end member and a second end member enriched in the elements mgo zn s br and cl the first end member appears to be reasonably well represented by rocks of the wishstone class while the second end member is consistent with a chemical component not represented by any lithology encountered by spirit the watchtower class appears to be an intermediate in the mixture the concentration of the redox sensitive elements fe and mn display no systematic variation between rock classes and the fe redox state of the watchtower class is elevated relative to the wishstone class combined with evidence for two component mixing these observations suggest that the mixture was generated by interaction between an initially wishstone like deposit and a fluid phase enriched in the elements mgo zn s br and cl the fluid phase may have been weakly acidic ph 4 to basic ph 9 resulting in oxidation and immobilization offe and mn a number of secondary rock surface alteration processes which obscure the mixing relationship are also identified these include 1 removal of cao and p 2 o 5 from rock surfaces by dissolution of ca phosphate minerals under acidic low water to rock ratio conditions 2 addition of so 3 to rock surfaces via aeolian deposition of high so 3 soil and or precipitation of sulfate salts from solution and 3 homogenization of rock surface chemistry by soil contamination

effect of diagenesis on trace element partitioning in shales abstract in order to investigate the partitioning of trace elements in mineral phases of black shales and diagenetic remobilization of trace elements within these phases we isolated major black shale components sulfide carbonate silicate and organic and analyzed the isolated fractions as well as corresponding whole rock for their trace element composition by drc icp ms this study focused on black shales of different grades of thermal maturity from the ordovician utica shale magnafacies of quebec usm immature tmax 20 50 c ro 140 c ro 1 analysis of the isolated rock fractions revealed that the carbonate fraction preserves a sea water like rare earth elements ree abundance pattern with enrichment of the heavy rare earth elements hree dy lu relative to light rare earth lree la sm the sulfide and organic fractions show a slight enrichment in the lree mass balance calculations showed that the organic fraction contains up to about 20 of total trace element content of the whole rock with the sulfide and carbonate fractions each containing less than 10 the partitioning and fractionation of trace elements between different phases may have important implications for paleoenvironmental reconstructions and provenance studies our data suggest that the whole rock signature may be less representative of source area or depositional environment but rather reflects the diagenetic history this is especially the case in organic rich sediments such as black shales where the organic fraction hosts up to 20 of the trace element content of the whole rock

snow avalanche formation 1 snow avalanches are a major natural hazard endangering human life and infrastructure in mountainous areas throughout the world in many countries with seasonally snow covered mountains avalanche forecasting services reliably warn the public by issuing occurrence probabilities for a certain region however at present a single avalanche event cannot be predicted in time and space much about the release process remains unknown mainly because of the highly variable layered character of the snowpack a highly porous material that exists close to its melting point the complex interaction between terrain snowpack and meteorological conditions leading to avalanche release is commonly described as avalanche formation it is relevant to hazard mapping and essential to short term forecasting which involves weighting many contributory factors alternatively the release process can be studied and modeled this approach relies heavily on snow mechanics and snow properties including texture while the effect of meteorological conditions or changes on the deformational behavior of snow is known in qualitative or semiquantitative manner the knowledge of the quantitative relation between snow texture and mechanical properties is limited but promising developments are under way fracture mechanical models have been applied to explain the fracture propagation and micromechanical models including the two competing processes damage and sintering have been applied to explain snow failure there are knowledge gaps between the sequence of processes that lead to the release of the snow slab snow deformation and failure damage accumulation fracture initiation and fracture propagation simultaneously the spatial variability that affects damage fracture initiation and fracture propagation has to be considered this review focuses on dry snow slab avalanches and shows that dealing with a highly porous media close to its melting point and processes covering several orders of scale from the size of a bond between snow grains to the size of a mountain slope will continue to be very challenging

analysis and forecast of extreme new snow avalanches a numerical study of the avalanche cycles of february 1999 in france snow and weather conditions typical of exceptional cycles of fresh snow avalanches in the northern alps are investigated using the numerical avalanche hazard forecasting procedure of meteo france sensitivity tests are performed on the events of february 1999 in the chamonix france region and resulting snowpack instability modeled at the massif scale is compared using adapted new indices and maps our results complete conclusions of earlier observation based studies by providing new insights into the snow and weather conditions of february 1999 the large avalanches mainly resulted from large and very unstable fresh snow accumulations moreover the snowpack instability was increased locally by wind transport of light and fresh snow in february the mechanical weaknesses resulting from the weather conditions prior to february were a key factor in explaining the unusual volumes of these avalanches this study suggests that the operational numerical safran crocus mepra scm chain provides reliable forecasts of extreme new snow avalanche situations at the massif scale but that local scale simulations are still needed to improve the efficiency of risk mitigation and civil protection policies

a numerical model to simulate snow cover stratigraphy for operational avalanche forecasting laws of snow metamorphism have been introduced in a numerical model which simulates the evolution of temperature density and liquid water profiles of snow cover as a function of weather conditions to establish these laws the authors have summarized previous studies on temperature gradient and on wet snow metamorphism and they have also conducted metamorphism experiments on dry or wet fresh snow samples an original formalism was developed to allow a description of snow with parameters evolving continuously throughout time the introduction of laws of metamorphism has improved significantly the derivation of the settlement of internal layers and of snow covered albedo which depend on the simulated stratigraphy i e the type and size of snow grains of different layers of the snow cover the model was tested during a whole winter season without any re initialization comparison between the simulated characteristics of the snow cover and the observations made in the field are described in detail the model proved itself to be very efficient in simulating accurately the evolution of the snow cover stratigraphy throughout the whole winter season

elemental mobility in phosphatic shales during concretion growth and implications for provenance analysis shale normalized rare earth element ree patterns record variable redox conditions in coprolitic phosphorite concretions and their host shales from the pennsylvanian age cyclothems in the u s midwestern states of oklahoma kansas nebraska iowa and ohio as well as the mississippian age fayetteville shale of arkansas shale normalized enrichments in middle ree mree developed as the phosphatic concretions lithified under reducing conditions in pore waters of organic rich muds depletions in mree sm ho in host shales correspond to the mree enrichments in some nearby concretions rare and weak negative cerium depletions in both reworked and unreworked phosphorite concretions suggest exposure to oxygenated waters positive europium anomalies in thick phosphorite coatings on coprolitic phosphorite concretion cores suggest extreme reduction during lithification of the phosphorite coating flat ree patterns in both host shales and phosphorite concretions probably reflect detrital influence phosphate diagenesis can affect the trace element chemistry of black shale enough to alter provenance signals overall enrichment in ree in phosphorite relative to host shale suggests movement of ree as does the mree enriched phosphorite near the mree depleted host shale diagenetically mobile ree can affect la th sc relationships used in provenance analysis the extent of the diagenetic modification of la th sc distribution is related to the amount of p2o5 present typical la th sc distribution in host shale results when p2o5 values are below 0 5 high la abundance substantially skews la th sc distribution when p2o5 is above 5 0 but when p2o5 is between 0 5 and 5 0 the extent of the effect is unclear oxides of aluminum and other major elements may be useful in recording detrital influence and proximity to the shoreline in phosphorite concretions most of the concretions nearest to shoreline sources of detrital input have both flat ree patterns and elevated values of al2o3 al2o3 fe2o3

statistical forecasting of regional avalanche danger using simulated snow cover data in the past numerical prediction of regional avalanche danger using statistical methods with meteorological input variables has shown insufficiently accurate results possibly due to the lack of snow stratigraphy data detailed snow cover data were rarely used because they were not readily available manual observations with the development and increasing use of snow cover models this deficiency can now be rectified and model output can be used as input for forecasting models we used the output of the physically based snow cover model snowpack combined with meteorological variables to investigate and establish a link to regional avalanche danger snow stratigraphy was simulated for the location of an automatic weather station near davos switzerland over nine winters only dry snow situations were considered a variety of selection algorithms was used to identify the most important simulated snow variables data mining and statistical methods including classification trees artificial neural networks support vector machines hidden markov models and nearest neighbour methods were trained on the forecasted regional avalanche danger european avalanche danger scale the best results were achieved with a nearest neighbour method which used the avalanche danger level of the previous day as additional input a cross validated accuracy hit rate of 73 was obtained this study suggests that modelled snow stratigraphy variables as provided by snowpack are able to improve numerical avalanche forecasting

mineralogic controls on ree mobility during black shale diagenesis abstract the llandeilo caradoc black shales of southwest wales u k record a paragenetic sequence that requires redistribution of rare earth elements ree on a mineralogic scale during diagenesis the main evidence for this redistribution is formation and replacement of ree rich apatite and monazite and variations in whole rock ree patterns the processes that produce these mineralogic changes create a diagenetic overprint on the llandeilo caradoc black shales that obscures geochemical information related to both provenance and paleoenvironmental conditions of deposition periods of open system conditions existed during the diagenetic alteration of the llandeilo caradoc black shales which allow an evaluation of the extent and timing of the ree redistribution inferred from petrography the observed variations in la sm ratios in the whole rock ree patterns are strong evidence that ree were redistributed on a scale greater than an individual hand sample this change in the whole rock ree pattern altered the cerium anomaly by as much as 20 and produced a range in the sm nd ratio from 0 14 to 0 20 this change in the whole rock sm nd ratio indicates a disturbance in the sm nd isotopic system at about 460 ma that can be directly linked to the formation and dissolution of diagenetic apatite and monazite during diagenesis one effect of this disturbance is to alter the range in nd model age for the llandeilo caradoc black shales from 1 6 to 1 8 ga to about 1 4 to 2 25 ga thus complicating any interpretation of provenance the ability to link petrographic observations from a black shale to measurable whole rock geochemical changes provides us with one tool to evaluate the presence of a diagenetic overprint on trace elements commonly used in paleoenvironmental reconstruction

tectonic synthesis of the taconian orogeny in western new england a tectonic synthesis based on stratigraphic and structural analysis of western new england is proposed for the ordovician taconian orogeny it emphasizes arc continental collision in which ocean floor continental margin and ensialic rift rocks were imbricated westward in a repeatedly deformed accretionary wedge continued compression displaced segments of the north american sialic crust to the west and deformed the earlier emplaced slices of the taconic allochthons which were derived from the continental margin critical arguments for this synthesis are 1 the west to east stratigraphic relations among the basal rift clastic rocks of the dalton pinnacle and hoosac formations of late precambrian to early cambrian age 2 the stratigraphic and sedimentological similarities between the rocks of the lower taconic sequence and rocks in the pinney hollow and underhill slices to the east and north of the green mountain massif 3 the environmental similarities between the cambrian and lower ordovician section of the giddings brook slice and the age equivalent section in the st albans synclinorium 4 the presence of carbonate platform rocks as slivers between each of the successively higher and younger premetamorphic slices groups 1 and 2 of the taconic allochthons 5 the presence of synmetamorphic fault related structures in the youngest and highest slices group 3 of the taconic allochthons 6 the recognition of extensive thrust zones in the pre silurian eugeoclinal sequence east of the middle proterozoic basement of the housatonic berkshire green mountain and lincoln massifs 7 the location of the taconic root zone within the pre silurian eugeoclinal sequence 8 the recognition of numerous faults in the serpentinite belt 9 the similarity between the rocks of the moretown formation and modern fore arc basin sequences 10 the recognition that the volcanic arc continental complexes of the ascot weedon and bronson hill have been displaced westward over the moretown and or hawley formations along such faults as the bristol and coburn hill thrusts 11 the allochthonous and internally imbricated nature of the north american basement in the berkshire massif 12 the proposition that the housatonic green mountain and lincoln massifs as well as the middle proterozoic cored domes of southeastern vermont are also thick sialic slices of north american basement 13 the recognition of medium high to high pressure metamorphic mineral assemblages in the pre silurian eugeoclinal rocks of vermont and 14 the recent synthesis of isotopic age data by sutter and others 1985 on the basis of an analysis of the foregoing arguments and relationships a chronological sequence of seven structural sections between albany new york and the bronson hill anticlinorium in central massachusetts is used to depict the evolution of the taconian orogeny retrodeformed distances are based on structural overlap and restoration of the taconic slices to their depositional setting along the ancient north american continental margin these easterly younging diverticulated slices formed as a result of horizontal compression rather than gravity sliding this palinspastic analysis implies the following 1 approximately 1 000 km of shortening has occurred during the emplacement of the taconic allochthons and the subsequent imbrication of north american basement as thick sialic slices approximately 330 km of this shortening is attributed to multiple cleavage generations 2 repeated movement along such major surfaces as the cameron9s line whitcomb summit belvidere mountain thrust zone has buried the taconic root zone we suggest that the northern extension of this root zone is exposed to the east of the lincoln massif in vermont where the underhill pinney hollow and hazens notch formations are exposed these formations here considered thrust slices disappear along the belvidere mountain whitcomb summit thrust zone as it is traced southward into western massachusetts and western connecticut 3 taconian metamorphic rocks particularly the older medium high pressure rocks in northern vermont have been transported westward on such reactivated surfaces as the belvidere mountain thrust 4 the anticlinorial form of the middle proterozoic basement in the green mountain and lincoln massifs may have resulted from fault bend folding on deep mantle involved thrusts that developed late in the taconian orogeny

spatio temporal reconstruction of snow avalanche activity using tree rings pierres jean jeanne avalanche talus massif de l oisans france snow avalanches are a major threat in many parts of the alps where they periodically damage infrastructure disrupt transportation corridors or even cause loss of life nonetheless the spatial behavior of past avalanche activity and the analysis of areas affected during particular events remain often imprecise it was therefore the purpose of this study to reconstruct spatio temporal patterns of past avalanche activity on a forested avalanche talus in the french alps pierres jean jeanne talus massif de l oisans france a total of 232 european larches larix decidua mill with clear signs of snow wasting events was analyzed and growth disturbances gd related to avalanche activity was assessed such as tangential rows of traumatic resin ducts the onset of compression wood or abrupt growth suppression and release in total 901 gd were identified in the tree ring samples indicating that 20 high magnitude avalanches occurred between ad 1919 and 1994 the mean return period of snow avalanches was 4 years with a 26 probability that an avalanche occurs in any particular year interpolated maps allowed for explicit spatial estimates of return periods throughout the talus showing a rapid increase of return frequency from 2 5 to 50 years with increasing distance from the talus apex the distribution of avalanche years seems to be quite homogeneous in time with a gap between 1951 and 1959 snowfall from a nearby meteorological station saint christophe en oisans 10 km from the study site indicated that the five most recent high magnitude events on record occurred due to above average snowfall anomalies in december and january associated with abnormally low air temperatures findings suggest that a strong snow metamorphism under high temperature gradients in january could explain the occurrence of high magnitude snow avalanches 2010 elsevier b v all rights reserved

sm nd isochron age and provenance of the argillites of the gunflint iron formation in ontario canada abstract sm nd rb sr and k ar isotope analyses were made on argillaceous sediments from the gunflint iron formation in the lake superior region in order to provide new information on their sedimentation age and evolutionary history the investigations indicate that it might be possible to date the time of sedimentation by the sm nd method by studying specific material such as argillaceous whole rocks enriched in organic matter and clay fractions the spread in the sm nd ratios seems here to have been favoured by the incorporation of organic material in the argillites the sm nd isotope data yield an isochron age of 2 08 0 25 ga which seems to be a fair estimation of deposition age model calculations indicate that the main source supplying the animikie seawater with ree was located at the northern border of the basin the argillites and their clay minerals did not behave as closed systems with regard to the rb sr and k ar systems during further diagenetic evolution

scale and timing of rare earth element redistribution in the taconian foreland of new england clastic sedimentary rocks deposited on eastern north america in response to the taconian orogeny commonly have sm nd isotope relationships indicating substantial isotope disturbance near or subsequent to the time of sedimentation that may be associated with severe depletion in light rare earth elements lree affected units normanskill formation austin glen and pawlet members frankfort formation and perry mountain formation are widely separated both geographically western new york to western maine and stratigraphically middle ordovician to silurian a model is proposed for the most likely explanation of the observed ree and sm nd isotope relationships involving a two stage process in the first stage ree are redistributed on a mineralogical scale dissolution precipitation on a sample scale often with the involvement of ree enriched trace phases such as apatite and monazite this stage typically takes place during diagenesis but may also take place later during metamorphism and or recent weathering and results in isotope re equilibration on a sample scale the second stage occurs when one or more of these phases is redissolved and ree are transported on large advective scales where lree enriched phases are involved this gives rise to lree depletion in whole rocks the timing of this second stage cannot be constrained from sm nd isotope data and may take place at any time subsequent to the isotope re equilibration such complex histories of ree redistribution may result in serious errors in estimating nd model ages but not in estimating the nd isotope composition at the age of sedimentation thus sm nd ratios even of unmetamorphosed sedimentary rocks have to be carefully evaluated before the calculation of depleted mantle model ages for the provenance

sr and nd isotopic evidence for punctuated clay diagenesis texas gulf coast we report rb sr sm nd and mineralogical data for leached whole rock 1200 m independent of the duration of burial the exchangeable sr in the clay has remained an open system and has undergone isotopic exchange since that time minimum fluid rock ratios of 0 2 to 2 are modeled from sr isotopic data consistent with rock dominated open system diagenesis leachates and residues of the 0 1 zm fraction below the smectite illite transition appear to have achieved nd isotopic equilibrium during clay diagenesis and show no signs of subsequent exchange the clay residues have low 147sm 144nd 0 085 indicating that authigenic illite has a lower sm nd ratio than its bulk rock protolith conversely the coexisting exchangeable ree inventory has elevated sm nd as reflected by leachate 14vsm 144nd as high as 0 188 this sm nd fractionation in conjunction with the preserved isotopic equilibrium may be useful for dating diagenesis and associated fluid rock interaction in older rocks

an energy and mass model of snow cover suitable for operational avalanche forecasting a numerical model has been developed to simulate energy and mass evolution of snow cover at a given location as a function of meteorological conditions precipitation air temperature humidity wind velocity and incoming short wave and long wave radiation this model named crocus was first tested on a well instrumented field during a whole winter showing its ability to simulate the important phenomena affecting the evolution of the snow layers high temperature gradients wetting compaction and melting freezing cycles a second test was conducted at two locations in the french network used for operational avalanche forecasting though the weather observations are made there only twice daily the snow profiles calculated by the model were very close to those obtained once a week by a pit observation crocus proved itself sufficient to be considered now as a useful objective tool for operational avalanche forecasting

llanvirnian ord iron ooids in baltoscandia element mobility ree distribution patterns and origin of the ree abstract the chemical and mineralogical compositions of llanvimian ordovician iron and associated phosphate ooids from sweden estonia and russia have been examined the oolites are generally thin and lean mud supported and dominated by fe oxyhydroxide goethite limonite ooids one swedish oolite contains a mixture of chamosite goethite and hematite ooids and it is suggested that the two latter types were derived from chamosite ooids by early diagenetic alteration the ree distribution patterns were unaffected by these reactions all ooids in the area show a typical negative eu anomaly inherited from the source material major and minor element contents in limonite and chamosite ooids are similar whereas their ree patterns are different limonite ooids have a lree hree ratio from 1 to 2 4 and chamosite ooids from 3 to 5 the amounts of ree in the ooids are strongly dependent on the amount of phosphate

rare earth elements in saanich inlet british columbia a seasonally anoxic basin rare earth element and manganese distributions have been investigated in saanich inlet british columbia a seasonally anoxic basin redox cycling of ce and mn takes place across an oxic suboxic boundary approximately 20 m shallower than the o2h2s interface the remaining strictly trivalent ree undergo scavenging above this oxic suboxic boundary and regeneration from dissolving host phases below it these processes result in pronounced removal of ce from solution above the oxic suboxic boundary due to oxidative precipitation along with preferential uptake of the lighter trivalent ree during scavenging below the oxic suboxic boundary regeneration of particulate ree into solution leads to a less pronounced ce depletion and a less pronounced hree enrichment in the anoxic bottom waters dissolved ree concentrations in the sediment pore waters exhibit an approximately ten fold increase across the seawater sediment interface but then decrease with increasing depth indicating removal from solution during later diagenesis calculated diffusive fluxes of the ree and mn from the sediments into the overlying anoxic water column are insufficient to account for the accumulated trace metal enrichments observed in the water column we propose an annual redox cycle for saanich inlet in which flushing causes extensive oxidative precipitation and scavenging of trace elements from the water column each autumn the same material is rapidly regenerated from the underlying near surface sediments when the basin next turns anoxic

sm nd and u pb zircon isotopic constraints on the provenance of sediments from the amadeus basin central australia evidence for ree fractionation abstract the amadeus basin of central australia is a late proterozoic to late palaeozoic ensialic depositional basin located between two proterozoic basement blocks of different nd crustal formation ages the older arunta block t dm nd 2 0 to 2 2 ga u pb zircon ages 1 5 1 9 ga to the north and the younger musgrave block t dm nd 1 7 to 1 9 ga u pb zircon ages 1 0 1 7 ga to the south initial nd isotopic compositions of the amadeus basin sediments generally fall into the region defined by the evolutionary trajectories of these two basement blocks indicating that the sediments are dominated by essentially two source components the older arunta block 147 sm 144 nd 0 114 and nd 0 20 4 and younger musgrave block 147 sm 144 nd 0 118 and nd 0 14 7 and or their equivalents stratigraphically higher sediments plot more closely to the evolutionary trajectory of the musgrave block this result together with the average provenance ages indicates the proportion of material from the musgrave block increases as the sediments become younger the sm nd isotopic data preclude a substantial involvement of archaean sources u pb zircon ion probe analyses of the late proterozoic heavitree quartzite and the late cambrian goyder formation are consistent with the sm nd isotopic constraints most of the zircons from the basal heavitree quartzite give concordant u pb zircon ages of 1500 to 1900 ma consistent with derivation from an arunta type source whilst zircons from the younger goyder sandstone give six discrete u pb zircon age groups of 511 20 615 15 960 109 1190 54 1633 24 and 1878 48 ma indicative of a dominantly musgrave type source with a minor contribution from the arunta block or reworked preexisting amadeus basin sediments the two youngest u pb zircon ages probably indicate some contribution from late proterozoic cambrian volcanics in central australia or a previously unrecognised younger local source in the basement blocks the 511 20 ma constrains the maximum depositional age of the sediment the amadeus basin sediments have a surprisingly wide range of 147sm 144nd ratios 0 077 0 136 irrespective of grain size and rock types in addition the calculated t dm nd values for samples from the same stratigraphic unit are well correlated with 147sm 144nd ratios with samples of different stratigraphic units forming sub parallel arrays these phenomena are interpreted in terms of ree fractionation and preferential sorting of preexisting ree rich phases during sedimentary recycling and deposition this process can lead to either an increase or a decrease in 147sm 144nd ratio of a sediment relative to its source and therefore an erroneous estimate of its t dm nd provenance age a theoretical model is developed which accounts for the observed correlation between t dm nd and 147sm 144nd ratios for suites of stratigraphically related sediments and allows a reliable estimate to be made of the provenance age of individual stratigraphic units assuming the average 147sm 144nd ratio of the source is known or can be estimated the provenance age for each stratigraphic unit of the amadeus basin has been calculated using this method the sm nd isotopic systematics in the amadeus basin sediments suggest that 1 1 ree fractionation during sedimentary recycling can in some cases be an important factor and needs to be considered 2 2 the provenance of the amadeus basin sediments was controlled by local source regions and cannot be used to infer large scale continental averages hence some caution must be evoked in using sm nd isotopic constraints from restricted sampling for more generalised models of crustal evolution

samarium neodymium elemental and isotopic systematics in sedimentary rocks abstract trace element sm nd th sc and nd isotopic data for sedimentary rocks are examined in order to evaluate 1 1 possible secular trends in the composition of the sedimentary mass and upper continental crust 2 2 the role of tectonic setting in controlling the chemical and nd isotopic composition of the sedimentary mass when plotted against either sedimentation age or average provenance age determined mainly from nd model ages sm nd in sedimentary rocks decreases abruptly from about 0 21 to 0 19 at the archean proterozoic transition consistent with a change towards a more felsic upper crustal composition the change is only somewhat less pronounced for turbidite sediments than for those of continental affinity a trend toward increasing sm nd approaching or exceeding archean values is observed for phanerozoic turbidites this latter change is interpreted as indicating undifferentiated young crust as a component in the sediment which has been lost from the older post archean record due to sedimentary and igneous intracrustal recycling processes when plotted against sedimentation age th sc ratios exhibit a trend directly comparable to that of sm nd in this case th sc increases abruptly at the archean proterozoic boundary from about 0 5 to 1 0 and then decreases to about 0 7 during the phanerozoic nd isotopic composition of modern sediments is affected by tectonic association with those deposited at active margin settings tending to have higher nd reflecting younger provenance and higher and more scattered sm nd reflecting less homogenized and differentiated provenance it is likely that these distinctions can be traced back for about 1 2 ga but with the current data base are not readily resolved in older sedimentary rocks the degree to which the preserved sedimentary mass is open to new additions from the mantle either through replacement during sedimentary recycling or sediment mass growth is highly variable but averages about 15 25 during the phanerozoic

rare earth major and trace elements in chert from the franciscan complex and monterey group california assessing ree sources to fine grained marine sediments abstract rare earth element ree major and trace element analyses of 77 samples from the mesozoic franciscan complex and miocene monterey group of california usa indicate that magnitudes of the ce anomaly ce ce and total ree abundances sree in these rocks are controlled dominantly by a the amount of included metalliferous material b the amount of direct terrigenous input and c the overall burial rate the relative importance of these individual processes varies across an ocean basin in such a way that ree relative fractionations and sree correspond with its depositional environment our conclusions are supported by an extensive review of published ree data from various river coastal open ocean and ridge influenced waters as well as terrigenous pelagic and metalliferous sediment the chert sequences record deposition in spreading ridge open ocean basin and continental margin environments the relative importance of metalliferous and terrigenous influences and the role of scavenging from seawater may be estimated from a sample s inferred depositional distance km from the spreading ridge the major element chemistry and the stratigraphie context the ce ce values are low 0 29 in the vicinity of spreading ridges and trend to successively higher 1 values with decreasing metalliferous and increasing terrigenous influences other ree indicators ree lu n la n eu eu also respond to metalliferous and terrigenous influences near the spreading ridge chert ree appears determined by burial rate while shale ree responds to metalliferous abundance in open ocean and continental margin environments ree is controlled by sediment exposure time and therefore is related inversely to burial rate ree data are consistent with the major elements fe2o3 mno and al2o3 in reflecting the respective metalliferous and terrigenous sources p2o5 and cao do not vary with ce ce in any environment but cao shows a weak negative correlation with ree trace element trends e g v cr cu ge si rb sr y th u in general can similarly be accounted for in the context of depositional position relative to metalliferous and terrigenous inputs rees in chert appear less affected by post depositional processes than either major or trace elements indicating that rees are better tools for paleoceanographic or tectonic reconstructions that are based on chert chemistry this work complements recent efforts to elucidate the factors determining large scale ree distributions in marine sediments and has direct bearing on previous attempts to use the ce anomaly in older rocks and sediments as a recorder of secular variations and anoxic events in the overlying water column

rare earth element geochemistry of oceanic ferromanganese nodules and associated sediments abstract analyses have been made of ree contents of a well characterized suite of deep sea 4000 m principally todorokite bearing ferromanganese nodules and associated sediments from the pacific ocean ree in nodules and their sediments are closely related nodules with the largest positive ce anomalies are found on sediments with the smallest negative ce anomalies in contrast nodules with the highest contents of other rare earths 3 ree are found on sediments with the lowest 3 ree contents and vice versa 143 nd 144 nd ratios in the nodules 0 51244 point to an original seawater source but an identical ratio for sediments in combination with the ree patterns suggests that diagenetic reactions may transfer elements into the nodules analysis of biogenic phases shows that the direct contribution of plankton and carbonate and siliceous skeletal materials to ree contents of nodules and sediments is negligible inter element relationships and leaching tests suggest that ree contents are controlled by a p rich phase with a ree pattern similar to that for biogenous apatite and an fe rich phase with a pattern the mirror image of that for sea water it is proposed that 3 ree concentrations are controlled by the surface chemistry of these phases during diagenetic reactions which vary with sediment accumulation rate processes which favour the enrichment of transition metals in equatorial pacific nodules favour the depletion of 3 ree in nodules and enrichment of 3 ree in associated sediments in contrast ce appears to be added both to nodules and sediments directly from seawater and is not involved in diagenetic reactions

the development of middle rare earth element enrichments in freshwaters weathering of phosphate minerals abstract many phosphatic minerals of biogenic authigenic and diagenetic origin are distinguished by rare earth element ree compositions which have a well developed middle rare earth element mree enrichment defined by a gradual increase in the shale normalized ratios of ree toward the middle of the ree series la to lu also the ree composition of dissolved matter in the waters of the amazon fly and sepik rivers as well as other river lake and ground waters have well developed mree enrichments the development of mree enrichments was studied through a series of leaching experiments using river bank sediments from the amazon fly sepik and mississippi rivers a well characterized phosphate mineral rich shale with a pronounced mree enrichment in its bulk composition was also leached in order to better assess the relationship between the weathering of phosphate minerals and the formation of mree enriched solutions the two leaching solutions per sediment consisted of filtered lake water at ph 5 and the same water adjusted to ph 2 leaching experiments with the four river sediments result in extensive fractionation whereby the ree compositions of the solutions develop mree enrichments from starting sediments that show no mree enrichments the ph 2 leachates have much higher concentrations of the ree and more fully developed mree enrichments than do the ph 5 leachates the mree enrichments at ph 2 usually form within an hour of starting the experiments the phosphatic shale results show that there is preferential release of large amounts of mree at ph 5 as well as at ph 2 demonstrating the weather ability of the phosphatic minerals at phs of natural freshwaters the sepik river ph 5 experiment also shows significant mree enrichment under near neutral conditions the development and retention of the mree enrichments in the leaching solutions is accompanied by an increase in dissolved phosphate concentrations although the magnitudes of the mree enrichment do not directly correlate with the percent of phosphate released the experimental data suggest that the preferential dissolution of phosphatic minerals during weathering can result in extensive ree fractionation between bulk river sediment and water leading to freshwaters with mree enrichments

low temperature aqueous mobility of the rare earth elements during sandstone diagenesis abstract diagenetic francolite carbonate fluor apatite occurs as overgrowths on detrital apatite grains in sandstones from the lower jurassic statfjord formation of the north sea the francolite overgrowths are considerably more enriched in the rare earth elements up to 1 wt ce 2 o 3 sr and f than the detrital cores these elements were carried in aqueous solution probably in the form of complex ligands involving organically sourced carbon and halogens it is possible that reported aberrant neodymium isotope model ages within the statfjord formation are the result of mobilization and relative fractionation of sm and nd during diagenesis rather than a result of changes in provenance

a new hierarchical bayesian approach to analyse environmental and climatic influences on debris flow occurrence abstract how can debris flow occurrences be modelled at regional scale and take both environmental and climatic conditions into account and of the two which has the most influence on debris flow activity in this paper we try to answer these questions with an innovative bayesian hierarchical probabilistic model that simultaneously accounts for how debris flows respond to environmental and climatic variables in it full decomposition of space and time effects in occurrence probabilities is assumed revealing an environmental and a climatic trend shared by all years catchments respectively clearly distinguished from residual random effects the resulting regional and annual occurrence probabilities evaluated as functions of the covariates make it possible to weight the respective contribution of the different terms and more generally to check the model performances at different spatio temporal scales after suitable validation the model can be used to make predictions at undocumented sites and could be used in further studies for predictions under future climate conditions also the bayesian paradigm easily copes with missing data thus making it possible to account for events that may have been missed during surveys as a case study we extract 124 debris flow event triggered between 1970 and 2005 in 27 catchments located in the french alps from the french national natural hazard survey and model their variability of occurrence considering environmental and climatic predictors at the same time we document the environmental characteristics of each debris flow catchment morphometry lithology land cover and the presence of permafrost we also compute 15 climate variables including mean temperature and precipitation between may and october and the number of rainy days with daily cumulative rainfall greater than 10 15 20 25 30 40 mm day 1 application of our model shows that the combination of environmental and climatic predictors explained 77 of the overall variability of debris flow occurrences in this data set occurrence probabilities depend mainly on climatic variables which explain 44 of the overall variability through the number of rainy days and maximum daily temperature this important time component in the variability of overall debris flow occurrence is shown to be responsible for a significant increase in debris flow activity between 1970 and 2005 at regional scale environmental variables which account for 33 of the overall variability includes mostly the morphometric variables of the debris flow catchments

some aspects of source characteristics of the 19 september 1985 michoacan earthquake and ground motion amplification in and near mexico city from strong motion data abstract the fourier amplitude ratio of the 19 september m s 8 1 to the 21 september 1985 m s 7 6 michoacan earthquakes obtained from data in and near mexico city increases from about 3 5 at 0 5 hz to about 10 at 0 2 hz this increase is neither seen in the coastal data nor in the teleseismic broadband gdsn p wave spectra it is also not predicted by 2 or gusev9s scaling laws we tentatively attribute the increase at frequencies of less than 0 5 hz to a special path and or a depth of energy release effect for the 19 september earthquake the damage to mexico city is mostly related to 0 5 hz energy since at f 0 5 hz the fourier amplitude ratios in and near mexico city along the coast and at teleseismic distances are nearly equal we attribute this energy to the source characteristics of the 19 september earthquake the evidence suggests that the 19 september was about twice more energetic at f 0 5 hz than expected from scaling laws and from spectral regression of coastal earthquakes recorded in mexico city the analysis of strong motion data recorded in mexico city shows that the ground motions in the lake bed zone are amplified by 8 to 50 times with respect to a hill zone site in ciudad universitaria the frequency at which the maximum relative amplification occurs varies from site to site and lies between 0 2 and 0 7 hz the data suggest that f o 4 h where f o frequency at which maximum relative amplitude occurs and and h are the shear wave velocity and the thickness of the clay layer respectively relatively small if any nonlinear behavior of the clay is found at strains of about 0 2 per cent during the great 19 september earthquake for a given lake bed site maximum relative amplitude and f o are roughly constant independent of magnitude depth and azimuth of sources located more than about 200 km ground motion at lake bed sites in mexico city with f o 0 5 hz appear to be amplified 75 times with respect to hard rock coastal sites at equal distances from the source this is also confirmed by m l calculation of the 19 and 21 september earthquakes for the 19 and 21 september earthquakes the average values of m l at hard rock coastal sites 100 distance 250 km are 7 4 and 6 7 whereas they are 8 7 and 8 4 in the lake bed zone distance 300 km respectively

regional path effects on seismic wave propagation in central mexico we present results of the analysis of a set of seismograms recorded in a temporary array of seven broadband seismic stations located in central mexico our purpose was to investigate path effects on ground motion in central mexico for earthquakes occurring in the subduction zone along the pacific coast all our stations were located on rock nineteen earthquakes 3 6 m c 4 9 recorded by all seven stations were analyzed the results show that path effects result in significant amplification and an increase of the duration of the seismic motion at two stations located in the central part of the transmexican volcanic belt tvb analysis of the records for periods larger than 5 sec shows that the 3d crustal structure acts as an efficient wave guide for surface waves coming from distances greater than 200 km only for paths oriented north south or east west in the band of 2 6 sec we observe large amplification and an increase in the duration of ground motion associated to the regional propagation of higher modes of surface waves after correlating our results with recent geological and gravimetric studies we suggest that this amplification could be due to the impedance contrast of low velocity volcanic rocks of the tvb overlying higher velocity limestones if we are right the increase of ground motion duration would result from mode conversion at the southern boundary of the tvb these path effects in the 2 to 6 sec period band are very important for ground motion in mexico city because the very soft surficial deposits in that basin amplify greatly ground motion in this same period band

upb pbpb and smnd dating of authigenic monazite implications for the diagenetic evolution of the welsh basin abstract authigenic monazite nodules from silurian turbiditic rocks in the central welsh basin are zoned with respect to nd isotope composition the cores are relatively radiogenic and the rim to core trend projects toward the composition of associated very early authigenic apatite concretions these authigenic phases therefore equilibrated with changing fluid composition as they formed the apatites and the monazite nodule cores may have included significant nd from organic matter or seawater whereas the rees in the outer parts of the monazite nodules were derived from clastic detritus the apparent sm nd age obtained from these phosphates is a mixing line which gives an ordovician age for these silurian rocks the u pb isotope system does not show similar trends and shows promise as an alternative method for dating such phosphates a date of 417 11 ma 2 mswd 107 agrees well with recent estimates of the time of the diagenetic smectite illite transition in the rocks of this study a pb pb isochron gave an age of 422 24 ma 2 mswd 0 9 this shows that the pb is in isotopic equilibrium and is undisturbed and that the elevated mswd of the u pb regression is caused by slight subsequent mobility in the u pb system the event dated by the monazite is probably compactional dewatering during accelerated mid silurian sediment loading in the central welsh basin

resetting of neodymium isotopes and redistribution of rees during sedimentary processes the early proterozoic chelmsford formation sudbury basin ontario canada abstract the rees abundances and neodymium isotope compositions of sandstones and siltstones from the early proterozoic chelmsford formation reveal that the rees in some samples were redistributed during the early proterozoic by surficial processes and that prior to redistribution the nd isotope system was partially reset the chelmsford formation is a coarse grained turbidite sequence the youngest of three clastic units that fill the sudbury basin in ontario it is constrained to have been derived from nearby late archean superior province rocks by petrography major and trace element chemistry and pb isotopic compositions of whole rocks and feldspar although ree patterns and nd model ages for samples from around the base of the formation reflect their derivation from undisturbed superior province rocks tdm 2800 ma five samples from higher in the stratigraphic section show evidence that up to 60 of their la has been removed and sm nd has increased by up to 60 these samples also have anomalously high nd model ages tdm 3400 to 4400 ma the presence of pronounced positive ce anomalies in the samples with anomalous tdm indicates the influence of surficial processes on the ree composition the data scatter about a vertical array on a plot of f sm nd vs ndt 1800 nd calculated at 1800 ma approximately the depositional age with values of f sm nd between 0 45 and 0 14 mixing of nd from other sources is difficult to reconcile with the petrography major and trace element geochemistry and nd and pb isotopes removal of an lree enriched phase from the sedimentary system provides a viable mechanism to produce the ree and nd isotopic characteristics of the chelmsford formation samples neodymium isotopes require that this phase was partially isotopically equilibrated with the matrix sediment near the time of sedimentation this study shows the dangers of indiscriminate use of nd model ages in provenance studies and demonstrates that the simultaneous examination of sm nd and nd isotopes on f sm nd vs nd or isochron plots is required for the recognition of sedimentary redistribution of the ree

temporal changes in nd isotopic composition of sedimentary rocks in the sevier and taconic foreland basins increasing influence of juvenile sources initial 143 nd 144 nd ratios of clastic sedimentary rocks in the ordovician taconic and sevier foreland basins increase with decreasing stratigraphic age this shift in isotopic composition reflects an increased influx of juvenile sediment to both basins for the taconic basin geologic and isotopic data are consistent with the juvenile sediment being derivedfromupliftedgrenvillecrust upthrustaspartofthetaconicallochthons sediment derivedfromthebronsonhillarc oracombinationofboth forthesevierforelandbasin there are few geologic constraints on source regions but the similar shift in isotopic ratios with time suggests a similar increase in the influence of juvenile sources such as exotic terranes sevier basin sedimentary rocks have higher nd values than those within the taconic basin thus juvenile source areas were of greater importance to sevier basin sediments