variations in mode of formation and temperature of oceanic deep waters over the past 125 000 years marked changes in the deep water temperature of the different oceanic basins during the past 125 kyr are revealed by a detailed comparison of the oxygen isotopic composition ofbenthicforaminiferafrom sediment cores taken from the norwegian sea and the pacific atlantic and southern oceans the last interglacial deep water temperatures were similar to the modern ones at the 5e 5d transition around 115 kyr bp the deep water temperatures dropped below approximately 0 c in the pacific and southern indian oceans in the atlantic ocean the deep water temperature dropped in 2 successive steps at 115 and 75ky bp the global ocean deep water temperatures were in the 0 to 1 c range for the whole of the last ice age isotope stages 4 2

the role of caco3 compensation in the glacial to interglacial atmospheric co2 change the only viable explanations put forth to date for the glacial to interglacial change in atmospheric co2 content suggested from measurements of the co2 content of gas extracted from ice cores involve changes in the ocean s nutrient cycles any nutrient change capable of creating the 80 atm changes in atmosphere co2 pressure suggested by the ice core results also creates significant change in the deep ocean s co3 content evidence from deep sea sediments suggests that these co3 changes are compensated on the time scale of a few thousand years by reductions or increases in amount of caco3 accumulating in deep sea sediments this compensation process has two important consequences first it significantly increases the magnitude of the co2 change per unit of nutrient forcing second it causes a delay in the response of the atmospheric co2 change while the first of these consequences is a boon to those seeking to explain the co2 change the second may prove to be a curse the ice core co2 record shows no evidence of a significant lag between the co2 response and the polar warming in any case it is important that we improve our knowledge of the magnitude and timing of the caco3 preservation events which mark the close of episodes of glaciation and of the dissolution events which mark the onset of these episodes

millennial scale northwest african droughts related to heinrich events and dansgaard oeschger cycles evidence in marine sediments from offshore senegal 1 we present a suite of new high resolution records 0 135 ka representing pulses of aeolian fluvial and biogenic sedimentation along the senegalese continental margin a multiproxy approach based on rock magnetic element and color data was applied on three cores enclosing the present day northern limit of the itcz a strong episodic aeolian contribution driven by stronger winds and dry conditions and characterized by high hematite and goethite input was revealed north of 13 n these millennial scale dust fluxes are synchronous with north atlantic heinrich stadials fluvial clay input driven by the west african monsoon predominates at 12 n and varies at dansgaard oeschger time scales while marine productivity is strongly enhanced during the african humid periods and marine isotope stage 5 from latitudinal signal variations we deduce that the last glacial itcz summer position was located between core positions at 12 26 and 13 40 n furthermore this work also shows that submillennial periods of aridity over northwest africa occurred more frequently and farther south than previously thought

younger dryas style cooling events at glacial terminations i vi at odp site 658 associated benthic δ13c anomalies constrain meltwater hypothesis high resolution planktonic and epibenthic stable isotope records from ocean drilling program site 658 off northwest africa provide a basis for a detailed study of glacial terminations i vi during the last 650 000 years the duration of the terminations was about one half to one quarter of an orbital precession cycle 5800 10 700 years when its amplitude was high at low amplitudes the terminations lasted longer than half an obliquity cycle 29 000 years marked climatic rebounds similar to the younger dryas each with a duration of 1000 2500 years subdivided all six terminations into distinct steps a b and c important parts of the deglacial steps were as brief as 700 1000 years the speed of climatic change suggests that special associations existed between orbital forcing and inherent instability of the ice sheets in harmony with published models the more rapid pulses of glacial meltwater incursions to the northern north atlantic led to one or more brief short term shut downs of north atlantic deep water formation this process is reflected by pronounced benthic 13c minima that precisely coincide in most cases with the end of the 18o deglaciation steps and immediately terminate with succeeding younger dryas style cooling events thus we conclude that the rebounds resulted from a short term antecedent estuarine circulation regime in the north atlantic except for the younger dryas itself which succeeded the allerod with its well ventilated atlantic deepwater circulation and hence continues to be an enigma

ocean chemistry during glacial time abstract measurements of co2 to air ratios in the gas trapped in bubbles in ice of glacial age suggest that the co2 content of the atmosphere was considerably lower during peak glacial time than during holocene time the purpose of this paper is to show that such a change must in all likelihood be the result of alterations in the nutrient element chemistry of sea water two possible scenarios are presented one involves alternate storage and erosion of phosphorous leaving residues from shelf sediments the other involves changes in the c p ratio in the organic debris falling to the deep sea means of verifying the nutrient cycle hypothesis are also given it is shown that the 13c record as we know it in planktonic and benthic foraminifera the oxygen record as inferred from benthic foraminifera species distributions and the early post glacial caco3 preservation event as recorded by aragonitic pteropods are consistent with both of the hypotheses presented only if an early post glacial spike in the 13c record for planktonic shells could be found would it be possible to eliminate one of these hypotheses i e that involving shelf storage the implications of these nutrient hypotheses to climate theory are as follows if shelf storage is responsible for the glacial to interglacial co2 increase then the co2 change must be considered an amplifier of some primary cause the reason is that sea level changes are needed to drive deposition on and erosion from the shelves on the other hand if changes in the c p ratio for falling debris are responsible then the co2 change could either be an amplifier or a primary cause for the major glacial to interglacial climatic cycle the latter is possible as self sustained oscillations in ocean chemistry might be driven by interactions between ocean ecology and ocean nutrient chemistry

an oceanographic explanation for the apparent carbon isotope cadmium discordancy in the glacial antarctic the seeming discordance between the glacial to interglacial changes in the carbon isotope ratio and cadmium content of benthic foraminifera from the deep antarctic has cast a shadow on the reliability of these proxies as valid of paleocirculation indicators the problem is that while cadmium content shows little glacial to interglacial change lea and boyle 1990 boyle 1992 the carbon isotope change is larger than at any other place in the ocean curry et al 1988 innu et al 1990 charles and fairbanks 199o even after correction for the 0 35 glacial to interglacial change in the isotope ratio for mean ocean atmosphere carbon a difference of 0 5 to 0 6 remains on the basis of redfield ratios for today s ocean this is equivalent to a 25 increase in cadmium content which is not seen this puzzle has been with us for several years

rare earth elements in manganese nodules from the south atlantic ocean as indicators of oceanic bottom water flow abstract the mineralogy and geochemistry of a suite of nine manganese nodules from the south atlantic have been determined the ce la ratios of the nodules were investigated to see if they could be used as redox indicators to trace the oxygen content of the ambient water mass and the flow path of the antarctic bottom water as has previously been successfully carried out in the pacific ocean the ce la ratios of the nodules decrease in the sequence lazarev sea weddell sea 10 4 and 9 7 east georgia basin 6 5 and 7 1 argentine basin 5 0 but then increase in the brazil basin 6 2 and angola basin 9 8 and 15 1 a further decrease was observed in the cape basin 7 6 an extremely high ce la ratio of 24 4 had already been determined for nodules sampled north of the nares abyssal plain in the western north atlantic these data reflect the more complicated pattern of bottom water flow in the south atlantic than in the south pacific the penetration of more oxygenated north atlantic deep water into the south atlantic accounts for the higher ce la ratios in the nodules from the angola and brazil basins based on this study the flow path of the antarctic bottom water could only be traced as far north as the argentine basin the unique geochemistry of nodules from the central angola basin high mn fe and ce la ratios high contents of ni cu zn and mo appears to be a function of the nature of the overlying water mass and of the multiple diagenetic sources of metals to the nodules

deepwater source variations during the last climatic cycle and their impact on the global deepwater circulation the degree of similarity of the 13c records of the planktonic foraminiferal species n pachyderma and of the benthic foraminiferal genus cibicides in the high latitude basins of the world ocean is used as an indicator of the presence of deepwater sources during the last climatic cycle whereas continuous formation of deep water is recognized in the southern ocean the norwegian sea stopped acting as a sink for surface water during isotope stage 4 and the remainder of the last glaciation however deep water formed in the north atlantic south of the norwegian sea during the last climatic cycle as early as isotope substage 5d and this area was also the only active northern source during stages 4 2 a detailed reconstruction of the geographic distribution of 13c in benthic foraminifera in the atlantic ocean during the last glacial maximum shows that the most important deepwater mass originated from the southern ocean whereas the glacial north atlantic deep water cannot be traced south of 40 n at shallower depth an oxygenated 13c rich intermediate water mass extended from 45 n to 15 s in the pacific ocean a ventilation higher than the modern one was also found in open ocean in the depth range 700 2600 m and is best explained by stronger formation of intermediate water in high northern latitudes

cadmium chemical tracer of deepwater paleoceanography the oceanic distribution of cadmium resembles that of phosphorus because the cadmium content of foraminiferal shells is governed by the cadmium content of seawater planktonic and benthic fossil shells can be used to infer nutrient distributions within ancient oceans empirical studies demonstrate that cadmium in benthic foraminiferal shells is related to the bottom water composition through a proportionality constant d 2 9 this constant is the same for each of the species studied cibicidoides wuellerstorfi cibicidoides kullenbergi nuttallides umbonifera and uvigerina spp downcore cadmium data from high quality pacific and atlantic sediment cores suggest that the cadmium inventory of the ocean did not change significantly between the most recent glacial maximum and the present hence changes in the cadmium content of fossils at a site directly reflect changes in nutrient distributions due to altered oceanic circulation patterns studies of cadmium in pleistocene sediments show that deep ocean circulation patterns were significantly different during the most recent glacial maximum in the western north atlantic ocean the nutrient content of waters from 2500 to 3500 m was twice as high during glacials as during interglacial periods signifying an increase in the proportion of waters of antarctic origin in this depth interval and a decrease but not a cessation in the flux of north atlantic deep waters through this depth range below 3500 m the nutrient increase was greater indicating a higher proportion of antarctic bottom water above 2500 m the nutrient content was lower during glacial periods than it has been during interglacial times the cd content of high latitude north atlantic and southern ocean surface waters does not show a significant glacial interglacial change which argues against theories for changes atmospheric carbon dioxide that require changes in high latitude nutrient concentrations

deep thermohaline circulation in the low latitude atlantic during the last glacial present day low latitude eastern and western atlantic basins are geochemically distinct below the sill depth of the mid atlantic ridge while antarctic bottom water aabw circulates freely in the western atlantic flow into the eastern atlantic is restricted below 4 km which results in filling the abyssal depths of this basin with water of geochemical similarity to nutrient depleted north atlantic deep water using carbon isotopes and cd ca ratios in benthic foraminifera we reconstruct the geochemistry of these basins during the last glacial maximum results indicate that deep eastern and western atlantic basins became geochemically identical during the last glacial this was achieved by shoaling of the upper surface of aabw above the sill depth of the mid atlantic ridge which allowed bottom waters in both basins to be filled with the same water mass although aabw became the dominant water mass in the deep eastern atlantic basin during the glacial holocene glacial 13c po4 shifts in this basin are in redfield proportions unlike the disproportionate holocene glacial 13c po4 shifts observed in the southern ocean by examining the composition of deep and intermediate waters throughout the atlantic we show that this effect was induced by a change in gradient of the 13c po4 deepwater mixing line during glacial times evidence from high latitude planktonic data suggests that the change in gradient of the deepwater mixing line was brought about through a significant reduction in the thermodynamic effect on southern ocean surface waters by using coupled 13c po4 data to constrain the composition of end member water masses in the glacial atlantic we conclude that deep waters in the low latitude glacial atlantic were composed of a mixture of northern and southern source waters in a ratio of 1 3

late quaternary paleochemistry of high latitude surface waters recent studies have stressed the role of high latitude nutrient levels and productivity in controlling the carbon isotopic composition of the deep sea and the co2 content of the atmosphere we undertook a study of the chemical composition of the polar planktonic foraminifer neogloboquadrina pachyderma s sinistral coiling from 30 late holocene samples and 49 down core records from the high latitude north and south atlantic oceans to evaluate the history of sea surface chemical change from glacial to interglacial time stable isotopic analysis of coretop samples from the atlantic pacific and southern oceans shows no significant correlation between the 13c of n pachyderma and either 13c or po4 in seawater conversely cd ca ratios in planktonic foraminifera are consistent with the po4 content of surface waters the level of maximum glaciation 18 000 yr b p identified by climap and 18o was chosen for mapping isopleths of 18o on n pachyderma s in the north atlantic reveal a pattern largely influenced by sea surface temperature s s t and generally support the s s t reconstruction of climap differences between the two suggest significantly lower salinity in north atlantic surface waters at high latitudes than in lower latitudes down core 13c records of n pachyderma confirm that low 13c values occurred in the northeast atlantic during the latest glacial maximum labeyrie and duplessy 1985 however a map of 13c for the 18 000 yr b p level for a much larger region in the north atlantic shows that minimum n pachyderma 13c occurred in temperate waters n pachyderma 13c decreased toward the southwest reaching a minimum of 1 at 37 n despite the variability seen in 13c records of n pachyderma none of our cores show significant temporal variability in cd ca from the combined cd ca and 13c data we can see no evidence for an upwelling gyre in the eastern north atlantic during the latest glacial maximum nor evidence that the southern and northern oceans had significantly different levels of preformed nutrients than today

comparison of atlantic and pacific paleochemical records for the last 215 000 years changes in deep ocean circulation and chemical inventories abstract detailed cd ca and 13 c data have been obtained for benthic foraminifera from western north atlantic and equatorial pacific sediment cores in the modern ocean both tracers are closely linked to nutrient distributions the sedimentary records for both tracers indicate that bottom waters overlying the atlantic site have been nutrient depleted relative to those at the pacific site over the last 215 000 years from this evidence it is reasonable to infer that there has been a continuous net flux of nutrient depleted water from the western north atlantic into the pacific this exchange has undergone significant fluctuations with the export of nutrient depleted atlantic water diminishing by about a factor of two relative to the inflow from southern ocean sources over the last 215 000 years carbon isotope fluctuations in both regions are dominated by variable storage of isotopically light carbon on continents with a lesser contribution from these deep ocean circulation changes the cadmium signal in the north atlantic is dominated by changes in deep ocean circulation patterns cadmium shows less variability in the pacific which may reflect changes in the global average cadmium content or minor changes in deep pacific circulation patterns using these records to estimate global averages it appears that glacial ocean water had 22 more cd and 0 46 less 13 c than the modern ocean these numbers are estimates which may be revised as more data become available although they are not likely to be as much as 20 in error for cd or 0 2 for 13 c relative north atlantic deep water nadw formation rates are modulated with a significant 41 kyr periodicity linked to obliquity induced variations in high latitude insolation nadw lags 8 2 kyr behind insolation however

on the late pleistocene ocean geochemistry and circulation a box model of the atmosphere and ocean was developed to investigate how geochemical distributions extant during the late pleistocene may have come about the model simulates the regional distribution of calcium carbonate dissolution as well as the chemical oceanography and atmospheric co2 13c and radiocarbon if the downward biological flux of particulate carbon increases by a factor of 2 to 3 in the antarctic and if this increase is combined with a relative increase of the atlantic sector antarctic bottom water aabw versus north atlantic deep water nadw source ratio from 1 3 to about 2 1 then the model predicts several changes that seem to be recorded in the sedimentary record as follows 1 a global redistribution of nutrients and 12c from the intermediate to deep water takes place with the atlantic intermediate water phosphate decreasing 0 6 mole kg 1 and the 13c increasing 0 3 to 0 5 2 the dissolved oxygen level of the deep sea is reduced from an average of about 180 to 70 mole kg 1 but the intermediate water oxygen declines only a small amount 3 the decrease in intermediate water nutrient concentration results in lower average organic carbon and calcium carbonate production in the warm surface ocean 4 the atmospheric co2 decreases by 90 to 110 ppm 5 initially a global increase in calcium carbonate dissolution occurs which is followed by a relaxation toward better preservation than exists for the present ocean in the model in this paper the reduction of nadw by itself does not produce these effects rather the nutrient decrease that does occur is found mostly in north pacific intermediate water and the model atmospheric co2 decrease is only 10 to 30 ppm it is observed that 92 of the atmospheric co2 change takes place according to a 200 year time constant in the model this corresponds to the response time of the upper ocean and atmosphere to a change in the stationary state atmospheric pco2 thus according to this model the time lag between the nutrient based cause and the atmospheric co2 response is not expected to be particularly large

hydrocarbon accumulation model for neogene traps in the chengdao area bohai bay basin china abstract chengdao is an offshore area in the bohai bay basin that contains approximately 25 7 10 8 bbl of oil and gas reserves within the sandstone reservoirs in neogene strata however previous predictions of hydrocarbon accumulation in neogene traps are inaccurate resulting in a current failure rate of 50 when drilling for hydrocarbons in this area to build an improved exploration model for neogene traps we select 92 traps from neogene strata in the chengdao area to quantify the filling degree which is an indicator of hydrocarbon accumulation efficiency the quantified filling degree is based on actual geological and exploration data and differs significantly among various trap types the filling degree of traps also varies significantly with their structural locations and decreases generally from the northwest to the southeast along the chengbei fault zone vertically the filling degree is highly heterogeneous initially increasing from the bottom to the middle of neogene strata and then decreasing towards the top of the strata these neogene hydrocarbon reservoirs are sourced from the paleogene and as they lay vertically away from the source rocks their hydrocarbon enrichment is constrained largely by hydrocarbon migration distance and vertical migration pathways the sealing capacity of faults and cap rocks sandbody orientation and reservoir sedimentary facies determine the maximum column height which in turn affects the amount of hydrocarbon accumulation within these traps a scatter plot analysis of individual controls and volumetric filling for each trap type is compiled using multivariate linear regression analysis to quantify controls and the dominant control of hydrocarbon accumulation is determined

13c record of benthic foraminifera in the last interglacial ocean implications for the carbon cycle and the global deep water circulation the 13c 12c ratios of upper holocene benthic foraminiferal tests genera cibicides and uvigerina of deep sea cores from the various world ocean basins have been compared with those of the modern total carbon dioxide tco2 measured during the geosecs program the 13c difference between benthic foraminifera and tco2 is 0 07 0 04 for cibicides and 0 83 0 07 for uvigerina at the 95 confidence level 13c analyses of the benthic foraminifera that lived during the last interglaciation isotopic substage 5e about 120 000 yr ago show that the bulk of the tco2 in the world ocean had a 13c value 0 15 0 12 lower than the modern one at the 95 confidence level reflecting a depletion compared to the present value of the global organic carbon reservoir regional differences in 13c between the various oceanic basins are explained by a pattern of deep water circulation different from the modern one the antarctic bottom water production was higher than today during the last interglaciation but the eastward transport in the circumpolar deep water was lower

testing the utility of paleonutrient proxies cd ca and zn ca in benthic foraminifera from thermocline waters 1 reconstruction of oceanic nutrient concentrations in the past provides information about nutrient cycling and physical circulation and the role these processes have played in past climate changes the cd ca and zn ca of benthic foraminifera have been used successfully to reconstruct past deep ocean nutrient concentrations in this study we test the ability of benthic foraminiferal cd ca and zn ca to detect changes in thermocline nutrient concentrations using a set of 31 multicores collected in the florida straits multicore sites span depths of 173 751 m estimated seawater cd concentrations of 0 02 0 42 nmol kg 1 and estimated seawater zn concentrations of 0 3 3 1 nmol kg 1 cd ca in several taxa of benthic foraminifera captures the regional differences and general shape of the nutricline on either side of the florida straits indicating that it is capable of resolving small changes in upper ocean nutrient concentrations in the past we estimate that the upper ocean partition coefficient for calcitic cd ca may be slightly higher than the established value low seawater zn concentrations combined with low partition coefficients and slight laboratory contamination severely complicated the evaluation of benthic foraminiferal zn ca however at least one species c pachyderma incorporates zn with a relatively high partition coefficient 22 minimizing these complications c pachyderma zn ca reflects the regional differences and general shape of the nutricline on either side of the florida straits and demonstrates potential for thermocline paleoceanography

late glacial and holocene palaeocurrents around rockall bank ne atlantic ocean core samples and hydrographic data from 50 to 60 n and 15 to 25 w in the northeast atlantic ocean are used to study changes in current activity from the last glacial to present we establish a new method to distinguish between the effects of changing bottom current speed and varying size input by drawing upon sediment flux data and detailed grain size analysis changes in current speed are recorded by the mean size of the sortable coarse noncarbonate silt component which increases with current vigor by winnowing away of fines our method involves the definition of an ideal sortable silt input function recorded at a site accumulating unmodified pelagic flux only the ideal profile is then compared with records from other sites to determine the history of current speed at a range of water depths the upper surface of southern source water ssw probably shoaled during the glacial as indicated by the covariation of sortable silt records from sites presently covered by ssw and lower north atlantic deep water lnadw the data suggest that production of lnadw was suppressed during the glacial increased following the last glacial maximum and declined at the start of termination 1a a second pulse of production occurred immediately before the younger dryas event intermediate waters were generally faster flowing during the glacial and may have expanded their depth domain such that a single glacial intermediate water mass covered depths from 1100 to more than 2000 m

lack of a significant temperature influence on the incorporation of cd into benthic foraminiferal tests 1 benthic foraminiferal cd ca is an important proxy for seawater paleonutrient concentrations and therefore deep ocean paleocirculation although previous work suggests that the incorporation of cd into benthic foraminiferal calcite is insensitive to temperature at least one species of planktonic foraminifer appears to be strongly influenced the present study provides a closer look at the relationship between benthic cd partition coefficients and temperature using new and previously published data from the bahama banks neither calcitic taxa nor the aragonitic hoeglundina elegans exhibits any consistent changes in partition coefficients over the range 4 to 18 c

temporal changes in north atlantic circulation constrained by planktonic foraminiferal shell weights records of planktonic foraminiferal shell weights for globigerina bulloides covering termination i from four proximal sites at waters depths from 1150 to 4045 m in the northeast atlantic demonstrate the influence of dissolution superimposed upon initial shell weight variability records of shell weight unaffected by dissolution may be used as a reference for interpreting deeper records in terms of preservation history combining records of planktonic shell weight and benthic 13c from shallow and deep sites suggests that maximum oceanic stratification and incursion of southern sourced deep waters in the north atlantic occurred at about 18 20 ka defining the glacial mode of atlantic circulation reduced stratification and enhanced preservation in deeper waters reflect conditions during heinrich event 1 a state similar to the modern mode of atlantic circulation was attained by about 10 ka

reconstructing past particle fluxes in the tropical atlantic ocean using a research strategy analogous to modern sediment trap studies sediment accumulation patterns on submarine rises can be interpreted in terms of past ocean chemistry and circulation we have followed this research strategy to reconstruct the history of surface water productivity and deep water chemistry and circulation in the eastern equatorial atlantic sierra leone rise and western equatorial atlantic ceara rise during the last glacial maximum 18 000 b p on shallow sections of these rises at depths with little carbonate particle degradation we assume that the accumulation of skeletal carbonate approximates the carbonate production rate in surface water during the last glacial maximum the rate of carbonate productivity was lower in the eastern atlantic than it is today while the western atlantic exhibited no glacial interglacial difference in carbonate productivity based on the difference in carbonate accumulation rates between shallow and deep cores on the rises we observed greater dissolution in both basins during the last glaciation the eastern atlantic always had a lower rate of dissolution than the western atlantic despite having deep water with a lower 13c during the last glacial maximum organic carbon accumulation in the eastern atlantic increased with depth in the water column during the last glaciation suggesting that there was a bathymetric decrease in dissolved oxygen concentration at that time these observations are consistent with a glacial decrease in the production rate of northern source deep water during the last glaciation at that time the mixing zone between northern source and southern source deep water migrated to the north in the atlantic resulting in a greater proportion of corrosive southern source deep water in the western atlantic and entering the eastern atlantic through low latitude fracture zones today the ratio of northern and southern components entering the eastern atlantic is about 4 1 based on 13c and carbonate accumulation our best estimate of this ratio during the last glaciation is 1 1

carbon and oxygen isotopic disequilibria of recent deep sea benthic foraminifera abstract the carbon and oxygen isotopic compositions of 149 samples of benthic foraminifera from deep sea core tops indicate that none of the nine species studied secrete calcium carbonate in isotopic equilibrium with ambient bottom water uvigerina pyrgo murrhina and oridorsalis tener are the closest to 18o equilibrium with average deviations about 0 4 while planulina wuellerstorfi and p murrhina are the closest to 13c equilibrium with average deviations about 1 p wuellerstorfi shows the most systematic relationship between 13c and bottom water apparent oxygen utilization the intraspecific variabilities in 18o and 13c suggest that estimates of bottom water paleotemperatures can be made to a precision of 0 7 c while estimates of past apparent oxygen utilization aou can be made to 35 mol kg based on intraspecific comparisons of the recent samples with fossils no temporal changes in the degree of either 18o or 13c disequilibrium have been detected for planulina wuellerstorfi uvigerina oridorsalis tener and globocassidulina subglobosa

northeastern atlantic benthic foraminifera during the last 45 000 years changes in productivity seen from the bottom up we studied benthic foraminifera from the last 45 kyr in the 63 mu m size fraction in biogeochemical ocean flux studies bofs cores 5k 50 degrees 41 3 n 21 degrees 51 9 w depth 3547 m and 14k 58 degrees 37 2 n 19 degrees 26 2 w depth 1756 m at a time resolution of several hundreds to a thousand years the deepest site showed the largest fluctuations in faunal composition species richness and benthic foraminiferal accumulation rates the fluctuations resulted from changes in abundance of epistominella exigua and alabaminella weddellensis in the present oceans these species bloom opportunistically when a spring plankton bloom results in seasonal deposition of phytodetritus on the seafloor the phytodetritus species had very low relative abundances and accumulation rates during the last glacial maximum a strong increase in absolute and relative abundance of e exigua and a weddellensis during deglaciation paralleled the decrease in abundance of the polar planktonic foraminifer neogloboquadrina pachyderma s and the increase in abundance of warmer water planktonic species such as globigerina bulloides this strong increase in relative abundance of the phytodetritus species and the coeval increase in benthic foraminiferal accumulation rate were thus probably caused by an increase in the deposition of phytodetritus to the seafloor and thus probably of surface productivity when the polar front retreated to higher latitudes the abundance of phytodetritus species decreased during the younger dryas but not to the low levels of fully glacial conditions during heinrich events periods of excessive melt water formation and ice rafting benthic accumulation rates were very low as were the absolute and relative abundances of the phytodetritus species supporting suggestions that surface productivity was very low during these events in both cores pullenia and cassidulina species were common during isotope stages 2 3 and 4 as were bolivinid buliminid and uvigerinid species high relative abundances of these species have been interpreted as indicative either of sluggish deep water circulation or of high organic carbon fluxes to the seafloor in our cores relative abundances of these species are negatively correlated with benthic foraminiferal accumulation rates and we can thus not interpret them as indicative of increased productivity during glacials the percentage of these low oxygen species calculated on a phytodetritus species free basis decreased slightly at deglaciation at 5k but not at 14k this suggests that decreased production of north atlantic deep water during the last glacial might have slightly affected benthic foraminiferal faunas in the eastern north atlantic at 3547 m depth but not at 1756 m in conclusion major changes in deep sea benthic foraminiferal faunas over the last 45 000 years in our cores from the northeastern atlantic were the result of changes in surface water productivity not of changes in deep water circulation productivity was lower during the glacial probably because of extensive ice cover

the role of vertical chemical fractionation in controlling late quaternary atmospheric carbon dioxide the 30 decrease in atmospheric carbon dioxide during glacial maxima must be driven by some change in the chemical circulation of the ocean here a new model for late quaternary co2 variability is presented which resolves some problems occurring in previous models including the timing of carbon dioxide response and changes in the oxygen content of the deep ocean the primary driving factor in this model is a rearrangement of chemical distributions in the ocean whereby labile nutrients and metabolic co2 are concentrated in deep waters rather than in intermediate waters as observed in the modern ocean this new bottom heavy chemical structure does not affect atmospheric carbon dioxide directly instead co2 induced acidity lowers the deep ocean carbonate ion concentration and temporarily increases carbonate dissolution rates oceanic alkalinity then rises until the deep ocean carbonate ion is restored to its steady state value the resulting increase in oceanic alkalinity draws co2 out of the atmosphere into the ocean alkalinity and atmospheric co2 lag several thousand years behind the change in oceanic chemical structure this delayed response is determined by the limited rate of continental weathering and deep ocean carbonate dissolution relative to the oceanic alkalinity inventory it is proposed that characteristic deglacial and preglacial states of the ocean are leading factors driving glacial interglacial climate changes this concept reinterprets the carbon isotope contrast between surface water and deep waters 13c p b as due to a shift of light metabolic carbon from intermediate waters into deep waters the process is illustrated here by a simple equilibrium five box ocean model the observed intermediate depth nutrient depletion is not sufficient in itself to determine which of several possible mechanisms are operating and some mechanisms are not as effective in changing atmospheric co2 as others the largest response is seen from deepening the regeneration cycle of organic carbon the least response is seen from converting north atlantic deep water into intermediate water

the deglaciation of the northern hemisphere a global perspective orbitally induced increase in northern summer insolation after growth of a large ice sheet triggered deglaciation and associated global warming ice albedo sealevel and greenhouse gas feedbacks together with tropical warming from weakening winds in response to polar amplification of warming caused regionalto global near synchronization of deglaciation effects were larger at orbital rather than millennial frequencies because ice sheets and carbon dioxide vary slowly ice sheet linked changes in freshwater delivery to the north atlantic and possibly free oscillations in the climate system forced millennial climate oscillations associated with changes in north atlantic deep water nadw flow the north atlantic typically operates in one of three modes modern glacial and heinrich deglaciation occurred from a glacial mode ocean that in comparison to modern had shallower depth of penetration of nadw formed further south causing strong northern cooling and the widespread cold dry and windy conditions associated with the glacial maximum and the cold phases of the millennial dansgaard oeschger oscillations the glacial mode was punctuated by meltwater forced heinrich conditions that caused only small additional cooling at high northern latitudes but greatly reduced the formation of nadw and triggered an oceanic seesaw that warmed some high latitude southern regions centered in the south atlantic

species composition and glacial interglacial variations in the ostracode fauna of the northeast atlantic during the past 200 000 years sediment core m23414 from the rockall plateau north atlantic covering the last two climatic cycles marine isotope stages mis 7 to 1 was investigated for glacial interglacial variations in the deep sea benthic ostracode fauna a highly diversified ostracode fauna including 98 species was found two climate related assemblages were identified associated with interglacial and peak glacial periods respectively the interglacial group occurs during the end of mis 7 5 and 1 and is composed of the genera henryhowella pelecocythere echinocythereis cytherella bradleya aversovalva and eucytherura the glacial group consists of the genera acetabulastoma which is known as sea ice indicator in the modern arctic ocean polycope bythoceratina rhombobythere and some species possibly belonging to the genus pseudocythere and is found during mis 6 4 and 2 these longer term variations within the ostracode fauna seem related to the particular glacial and interglacial climate conditions that affected both deep water production as well as primary production in the surface waters however a detailed comparison of ostracode abundances with the occurrence of events marked by increased ice rafted debris reveals also much shorter term climate related changes in the ostracode fauna thus the temporal fluctuations within ostracode assemblages reflect long and short term alterations of the deep sea environment that are clearly linked to climate changes

molecular stratigraphy of cores off northwest africa sea surface temperature history over the last 80 ka the molecular stratigraphy of biogeochemical oceanic flux study core 31k 19 n 20 10 w and ocean drilling program hole 658c 20 45 n 18 35 w has been studied for c37 alkenone abundances over the past 80 ka at high resolution circa 200 500 years the derived uk37 sea surface temperature record for both cores shows a range of temperatures from about 18 c during the last glacial to 21 5 c during the early holocene both records also reveal changes in sea surface temperature as much as 2 4 c over a few hundred years which correlate well with similar abrupt climatic changes observed in cores from elsewhere in the ne atlantic associated with heinrich events our results indicate that meltwater produced by these ice rafting events was transmitted southward by the canary current where it had considerable impact on sea surface temperatures in the subtropical eastern atlantic

calibration of the c 14 timescale over the past 30 000 years using mass spectrometric u th ages from barbados corals uranium thorium ages obtained by mass spectrometry from corals raised off the island of barbados confirm the high precision of this technique over at least the past 30 000 years comparison of the u th ages with 14c ages obtained on the holocene samples shows that the u th ages are accurate because they accord with the dendrochronological calibration before 9 000 yr bp the 14c ages are systematically younger than the u th ages with a maximum difference of 3 500 yr at 20 000 yrbp the u th technique thus provides a way of calibrating the radiocarbon timescale beyond the range of dendrochronological calibration

carbon isotopes in recent planktonic foraminifera a record of anthropogenic co2 invasion of the surface ocean abstract the release of isotopically light anthropogenic co 2 into the ocean atmosphere carbon reservoir has resulted in a decrease in the carbon isotopic composition of the surface ocean in this paper we examine differences between the carbon isotope composition of planktonic foraminifera from sediment traps with older late holocene material to estimate the change in 13 c 13 c in eastern atlantic surface waters as a result of the invasion of anthropogenic co 2 using stable oxygen isotopes we demonstrate that average trap values for a variety of species are more or less identical to core top values suggesting that foraminifera recovered in sediment traps are representitive of foraminifera deposited in the sediments however carbon isotopes recorded in planktonic foraminifera from recent trap material reveal a decrease in the 13 c composition of all species relative to the core top samples although the magnitude of the decrease varies significantly between species surface dwelling foraminifera g ruber g bulloides show 13 c values of 0 53 to 0 62 which is similar to other estimates from shallow water coral and sponge records for the decrease in the 13 c composition of dissolved organic carbon in surface waters which has taken place since the start of the anthropogenic emissions the magnitude of decrease in the 13 c of surface waters suggested by these records is also close to that predicted by global carbon cycle models deeper thermocline dwelling foraminifera such as g inflata however show 13 c values 0 2 which are substantially lower than their surface dwelling counterparts this reduction in 13 c with increasing depth habitat within the mixed layer may be related to limited vertical penetration of anthropogenic co 2 as a result of the strong upwelling which is observed in the eastern atlantic along the northwest african margin

changes in the oceanic 13c 12c ratio during the last 140 000 years high latitude surface water records detailed records of the carbon and oxygen isotopic ratios of neogloboquadrina pachyderma are compared between nine high latitude sediment cores from the northern and southern hemispheres covering the last 140 000 yrs the strong analogies between the 13c records permit to define a 13c stratigraphic scale with three clear cut transitions simultaneous with the oxygen isotopic transitions 65 125 kyrs 54 65 kyrs and 21 13 kyrs the 13c records of n pachyderma in the high latitude cores which follow the changes in 13c of the surface water tco2 near areas of deep water formation present trends similar to the benthic foraminifera 13c records in cores v19 30 and m12 392 although amplitudes of the isotopic shifts are different this implies that a large part of the observed variations represents global changes in the carbon distribution between biosphere and ocean the 13c12c ratios of n pachyderma in the north atlantic cores display larger regional variations at 18 kyrs b p than at present to explain these differences we have plotted the 18 kyrs b p 13c values of n pachyderma from 17 cores distributed n of 40 n comparison with published surface water temperature distribution at 18 kyrs b p indicates that a strong divergent cyclonic cell centered approximatively 55 n and 15 w was active during most of the last ice age maximum this hydrology analogous to the present weddell sea explains the published evidences of bottom water formation if located on the northern flank of the gyre and the strong polar front on the southern flank probable location of intermediate water formation

ocean circulation at the last glacial maximum a combined modeling and magnetic proxy based study 1 formation of north atlantic deep water nadw is an important component of the ocean thermohaline circulation but debate exists over the ocean circulation state during glacial stages some geological and modeling studies suggest decreased nadw and increased formation of southern ocean deep water during the last glacial maximum lgm others indicate similar or higher rates of nadw advection here we test three different potential lgm ocean states by comparing the modeled iceberg trajectories each produces with magnetically mapped patterns and sources of lgm ice rafted debris ird the three lgm states are characterized by vigorous nadw formation deepwater production in the southern ocean and a third intermediate state with southern ocean deepwater formation but also some north atlantic intermediate water formation cluster analysis of sediment magnetic properties was used to characterize north atlantic ird patterns and sources which match most closely iceberg trajectories arising from some combination of the southern sinking and intermediate ocean circulation states the magnetic data indicate two major ird sources fennoscandia and greenland iceland and one minor source the st lawrence region the model and magnetic data suggest that the lgm north atlantic circulation was dominated by a cyclonic central north atlantic gyre separated from the north atlantic current which was displaced south of 42 n

the influence of air and sea exchange on the carbon isotope distribution in the sea we explore here the influence of the temperature dependence of isotope fractionation between atmospheric co2and ocean co2 on the distribution of carbon isotopes in the ocean this is accomplished by an analysis of departures from the expected redfield tie between po4 and 13c we find that for the surface ocean the temperature influence largely compensates for the biologic influence in the deep ocean the temperature influence imprinted at the sites of deepwater formation reduces somewhat the biologically induced difference between the carbon isotope ratios for deep waters produced in the northern atlantic and in the antarctic these same features are reproduced in the hamburg ocean model in order to assess the impact of changes in the ratio of ocean mixing rate to wind speed we have made a model run in which co2 exchange rates between air and sea were everywhere doubled as expected the influence of the thermodynamic effect on the oceanic carbon isotope distribution is magnified

recirculating components to the deep boundary current of the northern north atlantic abstract the meridional overturning system of the north atlantic is conventionally thought of as transporting warm water 4 c to high latitudes and covd water to low latitudes the northern cold water sources for this system are dense overflow from the nordic seas and less dense water from the labrador sea lsw the overflow components are carried westward by a deep northern boundary current dnbc that is shown here actually to begin southeast of the overflow regions the dnbc lies along the southern side of a system of islands and submarine ridges that divides the nordic seas from the subpolar basins the overflows act to increase the transport of the dnbc and this transport is further increased through the entrainment of warm waters once inside the labrador sea the dnbc is joined by lsw before continuing south to low latitudes as a cold deep western boundary current dwbc however published transport estimates are larger than can be explained by warm water entrainment alone thus indicating entrainment also of recirculating cold components the subject of this paper their sources are shown to be the lsw and cold abyssal waters originating from the southern hemisphere the lsw is entrained downward into the denser part of the dnbc and laterally into the upper part of the dwbc whereas the cold abyssal waters are supplied by an eastern intensified northward flow in the eastern atlantic that serves as the initial source of the dnbc and by a similar northward flow in the western atlantic the meridional overturning system described includes recirculations and poleward transport of cold water in addition tothe components described by the conventional system the cold abyssal waters in both the eastern and western basins have relatively low levels of oxygen and high concentrations of silicate reflecting their southern origin but their influence in the northwestern atlantic is somewhat obscurred by strong recirculating cyclonic gyres in the newfoundland and labrador basins this influence is detected by a deep silicate maximum extending poleward from the mid latitude western atlantic through the two gyres with eastern concentration and recirculating back diluted toward the south in the dwbc within the respective basins such a maximum also extends northward through the irminger basin into the dnbc but there is an ambiguity as to whether this is a direct extension of the signal from the south in the western basin or if it comes from the mid latitude eastern basin by way of westward flow through the charlie gibbs fracture zone it is perhaps consequence of both estimates of the volume transports of the various recirculating cold components indicate that they supply about as much water to the deep boundary currents as do the combined cold water sources in the north

glacial deep water geometry south atlantic benthic foraminiferal cd ca and δ13c evidence a depth transect of cores from 1268 to 3909 m water depth in the western south atlantic are ideally situated to monitor the interocean exchange of deep water and variations in the relative strength of northern and southern sources of deep water production benthic foraminiferal cd ca and 13c data suggest that glacial north atlantic intermediate water gnaiw extended at least as far south as 28 s in the western south atlantic the core of nutrient depleted water was situated at 1500 m above and below water masses with higher nutrient concentrations when examined in conjunction with published paired cd ca and 13c from intermediate depth cores from other basins it appears that the extent of gnaiw influence on the intermediate waters of the world s oceans was less than suggested previously differentiating among possible pathways for the glacial deep ocean 3 km requires a better understanding of the controls on cd ca and 13c values of benthic foraminifera

north atlantic thermohaline circulation during the past 20 000 years linked to high latitude surface temperature during a surface cooling event 10 000 to 12 000 years ago higher cd ca and lower 13c 12c ratios are observed in benthic foraminifera shells from rapidly accumulating western north atlantic sediments data from sediment cores show that marked nutrient depletion of intermediate waters occurs in association with reduced glacial north atlantic deep water flux it is proposed that cold high latitude sea surface temperatures enhance intermediate water formation at the expense of deep water formation

variability in the deep and intermediate water circulation of the atlantic ocean during the past 25 000 years northern hemisphere modulation of the southern ocean the relative flux of north atlantic deep water nadw out of the atlantic can be monitored in the southern ocean where high 13c nadw mixes rapidly with low 13c recirculated pacific water before forming antarctic bottom water aabw by using 13c measured in benthic foraminifera as a water mass tracer it is shown that the southern ocean was dominated by pacific water with little nadw contribution during the last glaciation these tracer results document the direct physical connection between insolation controlled northern hemisphere oscillations and changes in the chemical and physical properties of southern ocean water the 13c records from the deep tropical atlantic document the transition from an atlantic dominated by southern ocean water during the last glaciation to an atlantic dominated by nadw during the holocene with more southern ocean water in the deep atlantic during the last glaciation the boundary between nadw and southern ocean water was north of its modern position allowing more southern ocean water to enter the eastern atlantic through the romanche fracture zone carbon isotope records from the caribbean and mediterranean seas suggest that the influence of mediterranean overflow water mow extended to the caribbean during the last glaciation and therefore was a volumetrically much more important water mass in the intermediate depth atlantic than it is today

foraminiferal reconstruction of barium distributions in water masses of the glacial oceans foraminiferal ba can be used to reconstruct the distribution of deeply regenerated chemical components in past oceans the ba contents of benthic foraminifera recovered from cores in the atlantic ocean indicate that waters deeper than 2900 m had 30 60 higher ba during the last glacial maximum lgm these changes are consistent with previously observed glacial nutrient enrichments based on foraminiferal cd and 13c increases in deepwater nutrient contents in the atlantic can be explained by reductions in north atlantic deep water formation during the lgm ba ca of benthic foraminifera from the glacial sections of intermediate depth atlantic cores are equal to or lower than holocene values this ba evidence argues against the mediterranean as a greatly increased source to atlantic intermediate waters during the lgm since the mediterranean is enriched in ba today and apparently remained enriched during the lgm benthic foraminiferal ba from the glacial sections of cores from the eastern equatorial pacific suggest that deep waters of the glacial pacific were about 25 lower in ba at 3000 m taken together the foraminiferal evidence indicates that the ba content of deep waters of the atlantic antarctic and pacific were similar at the lgm since foraminiferal cd distributions indicate that cd remained significantly lower in the deep atlantic relative to the pacific at the last glacial maximum a seven box ocean model is used to explore several scenarios for reconciling lgm ba and cd distributions while the changed distribution of both tracers suggests diminishment in the flux of nutrient depleted waters to the deep atlantic during the lgm increased atlantic upwelling rates and consequently enhanced ba particle fluxes can account for the the lack of ba fractionation between the deep atlantic and pacific the model suggests that ba can be transferred efficiently to the deep atlantic by enhanced upwelling because the vast majority of the ba is regenerated in the deep atlantic box

changes in the distribution of δ13c of deep water σco2 between the last glaciation and the holocene carbon isotopic measurements on the benthic foraminiferal genus cibicidoides document that mean deep ocean 13c values were 0 46 lower during the last glacial maximum than during the late holocene the geographic distribution of 13c was altered by changes in the production rate of nutrient depleted deep water in the north atlantic during the late holocene north atlantic deep water with high 13c values and low nutrient values can be found throughout the atlantic ocean and its effects can be traced into the southern ocean where it mixes with recirculated pacific deep water during the glaciation decreased production of north atlantic deep water allowed southern ocean deep water to penetrate farther into the north atlantic and across low latitude fracture zones into the eastern atlantic mean southern ocean 13c values during the glaciation are lower than both north atlantic and pacific 13c values suggesting that production of nutrient depleted water occurred in both oceans during the glaciation enriched 13c values in shallow cores within the atlantic ocean indicate the existence of a nutrient depleted water mass above 2000 m in this ocean

cadmium and delta13c paleochemical ocean distributions during the stage 2 glacial maximum changes in heat and salt transport by ocean currents have been implicated in ice age climate cycles weyl 1 968 newell 1 974 broecker et al 1 990b in addition to the direct physical effects of the ocean on climate the ocean carbon system controls atmospheric co2 and the co2 fluctuations documented in ice core bubbles barnola et a1 1 987 neftel et a1 1 988 are thought to be a significant factor in climate oscillations hansen et al 1 984 dramatic changes in oceanic circulation patterns and carbon system chemistry have occurred during the late quaternary glacial interglacial global climate cycles boyle keigwin 1 982 curry lohmann 1 983 shackleton pisias 1 984 boyle keigwin 1 987 duplessy et al 1 988 curry et al 1 988 broecker et al i 990a these changes in the ocean system may be significant driving forces in the progression of ice age co2 cycles toggweiler sarmiento 1 985 ennever mcelroy 1 985 wenk siegenthaler 1 985 boyle 1 988a b broecker peng 1 990 the oceanic distributions of c513c cd and other carbon system linked properties are controlled by the interaction between biological uptake and decomposition with the general circulation of the ocean because records of past oceanic cd and c5 1 3c are preserved in shells of planktonic and benthic foraminifera

reduced advection into atlantic ocean deep eastern basins during last glaciation maximum causes of change in deep water 13c can be either global or local in extent global causes include 1 climatically induced changes in the amount of terrestrial biomass which alter the average carbon isotopic composition of the oceanic reservoir1 and 2 erosion and deposition of organic rich continental shelf sediments during sea level fluctuations which change the mean oceanic carbon phosphorus ratio2 regional gradients of 13c are created by remineralization of organic detritus within the deep ocean itself thus reflecting the distribution of water masses and modern thermohaline flow changes in a single geological record of benthic foraminiferal 13c can result from any combination of these global and abyssal circulation effects by sampling a large number of cores collected over a wide bathymetric range yet confined to a small geographical region we have minimized the ambiguity we can assume that each 13c record was equally affected by global causes of 13c variation the differences seen between the 13c records must therefore reflect changes in the distribution of 13c in the deep ocean we interpret these differences in distribution in terms of changes in the ocean s abyssal circulation benthic foraminiferal carbon isotopic evidence from a suite of sierra leone rise cores indicates that the deeper parts of the eastern atlantic basins underwent a reduction in o2 during the maximum of the last glaciation reduced advection of o2 rich deep water through low latitude fracture zones associated with increased delivery of organic matter to the deep ocean lowered the 13c of deep water co2 at all depths below the sill separating the eastern and western atlantic basins 3 this decreased advection into the eastern atlantic ocean coincides with the overall decrease in deep water production in the north atlantic during the last glacial maximum4 7

tephra in deglacial ocean sediments south of iceland stratigraphy geochemistry and oceanic reservoir ages icelandic tephra layers within deglacial ocean sediment cores from south of iceland have been detected and their timing with respect to the climate shifts of the last deglaciation constrained geochemical analysis of the tephra allowed the likely source volcanic systems to be identified the previously known saksunarvatn ash and vedde ash are recognised and described several other major tephra layers are examined basaltic eruption s of katla at 8 4 ka a basaltic eruption of katla at 12 6 ka a rhyolitic eruption of katla at 13 6 ka producing tephra similar in appearance and composition to the vedde ash a basaltic eruption of katla at 14 0 ka and two basaltic eruptions of grimsvotn at 14 6 ka and 15 0 ka abundant rhyolitic ash with a similar appearance and chemistry to the vedde ash is found throughout the deglacial interval predating the vedde ash by up to 3000 years supporting previous suggestions that there were pre vedde ash eruptions of rhyolite that may have contributed to north atlantic ash zone 1 this study expands the tephro stratigraphic framework of the north atlantic and provides a marine archive in which the timing of tephra layers useful as isochrons can be directly compared to major ocean and climate events of the last deglaciation furthermore by correlating tephra layers and abundance changes in the polar foraminifera neogloboquadrina pachyderma sinistral to equivalent tephra events and inferred abrupt cooling warming in greenland ice cores contemporaneous 14c dated planktonic foraminifera have been used to estimate changes in the surface radiocarbon reservoir age south of iceland consistent with previous studies larger surface reservoir ages are calculated during late heinrich stadial 1 and the younger dryas 2000 years and 800 1900 years respectively

core top evaluation of benthic foraminiferal isotopic ratios for paleo oceanographic interpretations abstract the benthic foraminifera cibicides wuellerstrofi oridforsalis tener and pyrgo rotalaria from twelve core tops in the norwegian greenland sea and c wuellerstorfi o tener and o umbonatus from four core tops on the rio grande rise were analysed for oxygen and carbon isotopes the norwegian greenland sea data yield statistically discrete means for both 18o and 13c for each species the interregional comparison of our data to published data from the east pacific rise shows that c wuellerstorfi 18o and 13c variations reflect oceanographic differences between sites whereas the data on oridorsalis and pyrgo do not we conclude that c wuellerstorfi is a reliable sensor of bottom water conditions whereas other taxa are of unproven utility supportive biological studies and the lack of positive covariance of 18o to 13c among deep sea benthic taxa lead us to reject models calling for incorporation of metabolic co2 to explain the isotopic variation among deep sea benthic foraminifera we propose a within sediment microhabitat hypothesis to explain the 13c variations among taxa

the δ13c in benthic foraminiferal tests of fontbotia wuellerstorfi schwager relative to the δ13c of dissolved inorganic carbon in southern ocean deep water implications for glacial ocean circulation models on a transect between 20 and 70 s in the eastern atlantic ocean and weddell sea water samples from 19 hydrographic stations and bottom water from 55 surface sediment samples taken with a multiple corer were investigated for the stable carbon isotopic composition of the total dissolved inorganic carbon 13c co2 these measurements were compared to 13c values determined on live specimens of the benthic foraminifer fontbotia wuellerstorfi and closely related genera from the same stations in addition at 16 stations the stable carbon isotope composition of sedimentary organic carbon was measured general deepwater and bottom water mass circulation patterns as inferred from the 13c co2 are in close agreement with those known from other nonconservative tracers very low 13c values of upper circumpolar deep water 0 3 pee dee belemnite pdb in the polar front region and the eastern limb of the weddell gyre coincide with nutrient maxima however a significant decoupling of the dissolved phosphate signal from the 13c co2 signal is indicated in the abyssal weddell sea we attribute this to temperature dependent fractionation processes during gas exchange of surface waters with the atmosphere at sites of bottom water formation multiple corer water from the sediment water interface is slightly 13c depleted relative to deepwater and bottom water 13 co2 the surface sediment organic carbon 13c is 3 to 4 lower south of the polar front than north of it and the 13corg in freshly accumulated phytodetritus is 3 to 4 lower than surface sediment organic carbon 13c comparison of live f wuellerstorfi 13c and related genera with bottom water 13c co2 exhibits at most stations between the subtropical front 41 s and the southern boundary of the antarctic circumpolar current 55 s a significant lowering of foraminiferal 13c values compilation of a mean last glacial interglacial 13c amplitude 13c from six published southern ocean cores results in a shift of 0 99 0 13 pdb this shift is greater than that in all other regions however all of these cores are from positions close to recent oceanic fronts thus for these peripheral areas of the southern ocean we suggest about half of the glacial interglacial shift can be explained by varying frontal zone positions and widths accompanied by a change in mode and height of export production

testing the impact of seasonal phytodetritus deposition on δ13c of epibenthic foraminifer cibicidoides wuellerstorfi a 31 000 year high resolution record from the northwest african continental slope 1 studies of temporal changes of ocean circulation and deepwater ventilation often rely on 13c records of epibenthic foraminifer cibicidoides wuellerstorfi however primary productivity related overprints may distort the signal and simulate a chemical age of ambient water mass that is too old and simulates poorly ventilated ambient bottom waters to further constrain the use of c wuellerstorfi 13c records from high productivity areas we analyzed a 14cams dated gravity core from the upwelling regime off northwest africa at 12 n we compare this new record with 37 radiocarbon dated 13c records from the eastern atlantic ocean between 45 n and 25 s that are bathed by the same water mass only during heinrich events 1 and 2 when the investigated core site off northwest africa experienced year round sustained deposition of organic matter the 13c values at this site faithfully record deepwater ventilation states during times of predominantly seasonal deposition of fresh phytodetritus however 13c values were significantly lower than at the reference sites this underscores that reconstruction of paleocirculation and deep ocean ventilation using c wuellerstorfi 13c from regions that experienced seasonal phytodetritus deposition needs to be validated by additional proxies that are not affected by local productivity

seismic evidence of the lithosphere asthenosphere boundary beneath the tonga area southwestern pacific abstract we study the lithosphere asthenosphere boundary lab in the tonga subduction zone using four deep focal events recorded by the capital seismic network csn of china and the northeast china extended seismic array necessarray the existence and depths of the lab beneath the lau ridge are clearly revealed by the linear slant stacking of observed sp precursors sdp as illustrated by the reflected points of robust sdp phases from lab the depth of lab in the northern lau ridge is about 63 km with a range of 63 64 km in the northwest is about 77 km with a range of 76 78 km and in the south is about 72 km the uncertainty of determined depths is no more than 4 km given the effects of the picking errors of arrival times and velocity heterogeneities our results suggest that the oceanic lithosphere of the lau ridge is thinner in the northern part than in the northwestern and the southern parts according to the previous geodynamic and petrological studies the oceanic lithospheric thinning in the northern lau ridge should be related to the strong erosion of the active mantle convection in the back arc mantle wedge with the enrichment of the volatiles and melts

comparison of water mass changes in the deep tropical atlantic derived from cd ca and carbon isotope records implications for changing ba composition of deep atlantic water masses eastern tropical atlantic benthic foraminiferal ba ca and cd ca data from core v30 49 3093 m reveal large inferred changes in nutrient concentrations of deep atlantic waters during the last 250 kyr relative changes in north atlantic deep water contribution to this site are estimated by scaling the v30 49 cd ca record to values of modern end member water masses these estimates agree well with the relative structure and timing of circulation changes in the eastern tropical atlantic reconstructed from a 13c record based mixing model raymo et al 1997 temporal differences between v30 49 cd ca and ba ca records suggest that the ba ca record reflects changes in circulation with an additional increase in the ba composition of deep atlantic water masses during glacial episodes possibly resulting from increased productivity similarity between the 13c and ba ca records suggests that carbon isotopes in the deep glacial atlantic also reflect productivity increases

evidence from southern ocean sediments for the effect of north atlantic deep water flux on climate evidence from southern ocean sediments for the effect of north atlantic deep water flux on climate