late mesozoic bimodal volcanic rocks in the jinniu basin middle lower yangtze river belt yrb east china age petrogenesis and tectonic implications abstract late mesozoic intrusive and volcanic rocks are widespread in the southeast hubei province middle lower yangtze river belt yrb east china detailed in situ zircon u pb and hf isotope elemental and sr nd pb isotopic data are presented in this paper for late mesozoic volcanic rocks from the jinniu basin yrb aiming to constrain their age petrogenesis and tectonic implications the jinniu volcanic rocks show a bimodal distribution in composition with dominant rhyolite and dacite and subordinate basalt and basaltic andesite new shrimp and la icpms zircon u pb ages indicate that the volcanic rocks of three formations in the jinniu basin were erupted at quite a short age range of about 5 ma during the early cretaceous 130 125 ma the mafic rocks are moderately enriched in large ion lithophile elements lile e g ba th u and pb and light rare earth elements lree and are characterized by negative nb ta and ti anomalies and relatively high tio2 0 72 2 06 and nb 9 20 26 5 ppm contents these analyses indicate that the geochemical characteristics of the mafic rocks in the jinniu basin are similar to worldwide phanerozoic nb enriched basalt and andesites neba new in situ zircon u pb ages and field geological relationships demonstrate that neba in the southeast hubei province are not spatially or temporally associated with high silica adakitic rocks but were most likely derived from an enriched lithospheric mantle with assimilation of minor crustal materials and then fractional crystallization during the evolution of the magma overall the felsic rocks in the jinniu basin have geochemical characteristics and sr nd pb signatures and in situ zircon hf isotopic compositions similar to those of the mafic rocks compared with the mafic rocks the felsic rocks are characterized by enriched and variable concentrations of lile and ree e g ba 33 3 1372 ppm y 11 4 33 6 ppm ybc 5 07 18 7 and negative eu anomalies eu 0 22 0 98 as well as a wide range of radiogenic nd pb isotopic values with end t 10 2 to 2 4 206pb 204pb i 17 659 18 705 207pb 204pb i 15 478 15 663 and 208pb 204pb i 37 654 38 935 and in situ zircon hf compositions of ehf t 12 7 to 1 8 these features indicate that the genesis of felsic magma in the jinniu basin is consistent with extensive fractional crystallization and large amounts of crustal contamination from an evolved mafic magma sio2 55 the bimodal volcanic rocks in this study provide convincing evidence that early cretaceous volcanic rocks in the yrb developed in a back arc extensional tectonic regime

volcanic history and magmatic evolution of seguam island aleutian island arc alaska new 40 ar 39 ar dating coupled with detailed field mapping stratigraphy and chemical analyses have established an eruptive chronology that reveals and constrains the compositional and volumetric evolution of seguam island in the aleutian island arc alaska sixty new 40 ar 39 ar ages from lavas domes and pyroclastic deposits were obtained using furnace incremental heating techniques on replicate samples of whole rock and ground mass separates and they constrain the duration of pleistocene to holocene subaerial volcanism to 318 k y the 40 ar 39 ar plateau ages indicate that over 85 of the complex 68 km 3 of material was erupted almost continuously between 318 ka and 9 ka at ca 9 ka a stratocone on the eastern half of the island partially collapsed producing a 4 km wide crater rhyolitic dome forming eruptions followed from vents in the newly created crater and were likely contemporaneous with 8 0 km 3 of basaltic and basaltic andesitic effusions from pyre peak and a 1 4 km 3 basaltic eruption from a monogenetic cone on the far eastern end of the island geochemical changes over the last 318 k y are subtle most notably the earliest eruptions from 318 to 142 ka produced no andesite and basalt from this period has larger ranges in zr rb and la yb than younger basalts small volumes of dacitic to rhyolitic magma were produced from basalt by a monotonic crystal liquid fractionation process that varied only slightly in successive eruptive phases over 318 k y we identified minor geochemical changes in magma composition during each of the three main stages of volcanism but overall the monotonic variations in major and trace element compositions of basaltic andesitic to rhyolitic lavas are consistent with an origin via closed system fractional crystallization of basalt using the 40 ar 39 ar geochronology and estimates of individual flow volumes we calculated a time averaged eruptive rate at seguam that is similar to growth rates of other well dated arc volcanoes in the cascades and chilean southern volcanic zone but less than that of mount katmai and mount mageik which are located on the alaska peninsula the eruptive flux at seguam has been highly variable fluctuating more than an order of magnitude from 0 07 km 3 k y during the early history of bimodal volcanism to 1 18 km 3 k y over the past 9 k y

petrology of mariana trough and lau basin basalts the crust of actively opening back arc basins has close chemical and mineralogic similarities to normal mid ocean ridge basalts n morb but some subtle but distinctive differences exist these are largely due to differences in volatiles fe oxidation ratio abundances of large ion lithophile elements lil and some high field strength hfs elements isotope data for sr pb nd he and o are variable but broadly are morb like we present data contrasting mariana trough mtb and lau basin basalts lbb showing how they differ in certain trace element and isotopic signatures and compare both to n morb relative to n morb and lbb the mtb are enriched in alkalis alkaline earths light rare earth elements ree h2o and fe fe even for primitive samples while having morb type he 3 4 7 8 to 8 4 ra sr 87 86 mean 0 70293 and nd e 10 2 the lau basin is zoned with a central area having n morb characteristics for h2o lil ree nd e 8 1 to 9 0 and o but a depletion in hfs elements sr is more radiogenic mean 87 86 0 70347 and 3he 4he 3 4 7 2 to 11 0 ra is high relative to n morb the lau basin has a zone bordering the adjacent island arcs which is like mtb in both back arc basins relatively primitive unfractionated basalts with mg 100 mg fe 62 are found which resemble postulated primitive n morb calculated parental magmas obtained by adding xenocrystic olivine plot near or on 3 and 4 phase boundaries at 1 1 5 gpa for the ol di si system low p fractional crystallization and magma mixing explain most of the observed rock types possible explanations for differences between mtb and lbb include differences in the extent of previous melting episodes of their mantle sources and effects of source metasomatism through dehydration and partial melting of subducted lithosphere the long and complex history of mariana trough mantle sources led to a metasomatized mantle which gives rise to the distinctive mtb in contrast the lau basin is dominated by basalts derived from a source depleted in volatiles lil and hfs elements a previous melting history is implied mixing with a mantle component enriched in 87sr and 3he may be due to mantle counterflow driven by the subduction process

structural evidence for the permo triassic tectonic evolution of the yidun arc eastern tibetan plateau abstract deformation across the yidun arc occurred as a two phase process i early triassic deformation of paleozoic sequences resulting from closure of the jinsha jiang suture and ii late triassic deformation of middle to late triassic rocks as a result of final basin closure deformation in the western yidun arc is dominantly west vergent a north south striking west directed thrust the jinsha thrust forms the boundary between the western yidun arc and the eastern qiangtang block the jinsha thrust incorporates within it ophiolitic material of the jinsha jiang suture and the structural geometry across the jinsha thrust suggests that early triassic subduction was east dipping along the jinsha jiang suture deformation within middle to late triassic sequences of the eastern yidun arc eastern qiangtang block and western songpan garze fold belt is thin skinned being restricted largely to a single generation of upright folds and associated thrusts late triassic westwards subduction underneath the combined western yidun arc qiangtang block resulted in arc volcanism in the eastern yidun arc coeval arc volcanics in the northern margin of the qiangtang block suggest that the suture along the northern margin of the qiangtang block may be correlated with the garze litang suture rather than the jinsha jiang suture

geochemistry and tectonic environment of basaltic rocks from the misis ophiolitic melange south turkey abstract the miocene misis tectonosedimentary melange was formed during the closing stages of the neotethys in what is now the adana basin of southern turkey a major part is characterized by large disorientated limestone blocks set in a predominantly volcanogenic matrix of bedded and chaotic units comprising basaltic pillow lavas associated hyaloclastites serpentinites and various acidic tuffs all the basaltic rocks are mildly metamorphosed zeolite facies variably vesicular and differentially altered to smectite chlorite fe oxides zeolites and carbonate petrographic and chemical data on the least altered pillow lavas indicate they were originally sparsely olivine plagioclase clinopyroxene phyric tholeiites and minor amphibole phyric basaltic andesites the basaltic clasts in the melange matrix are genetically related to the pillow lava sequences with the observed variation throughout the suite being governed by low pressure fractional crystallization as a group the basalts are characterized by low zr y 2 4 relatively high th yb 0 5 0 7 and la nb 1 5 2 5 ratios and moderate chondrite normalized light ree enrichment la yb n 3 patterns the basalts have a mildly enriched subduction related chemistry and were possibly formed initially in a back arc basin setting the supra subduction zone characteristics of the misis basaltic units are similar to other tethyan basalts in eastern mediterranean ophiolites

possible correlation between a mantle plume and the evolution of paleo tethys jinshajiang ocean evidence from a volcanic rifted margin in the xiaru tuoding area yunnan sw china abstract several paleozoic sutures in southwestern china provide a record of the history of the paleo tethys ocean whose birth and final closure are associated with the breakup and assembly of gondwanaland recent studies indicate that there are widespread oib type mafic volcanic rocks within these suture zones and intervening terranes this paper examines the geology and geochemistry of volcanic rocks in the xiaruo tuoding area a remnant passive margin succession of the jinshajiang paleo tethyan ocean the sedimentary and volcanic stratigraphy of this area is interpreted as a seaward dipping margin with a few continentward dipping normal faults the available geochemistry of these volcanic rocks suggest that they are oib like basalts characterised by sio 2 42 78 50 46 wt high tio 2 contents tio 2 2 2 3 55 wt moderate mgo 4 15 6 49 wt mg 0 37 0 50 high ti y ratios mostly 450 large ion lithosphere elements enrichment high strength field elements and rare earth elements with la nb 1 04 1 39 ce yb 18 38 30 sm yb 2 16 3 52 87 sr 86 sr i 0 705350 0 707867 and nd t 1 43 1 90 these geochemical and isotopic signatures are generally similar to those of the emeishan flood basalts which together with stratigraphic constraints demonstrate that these volcanics were formed in a volcanic rifted margin probably associated with a mantle plume a new model is proposed to interpret the evolution of the jinshajiang paleo tethyan ocean and its possible relationship to the emeishan mantle plume in this model we argue that the opening of the jinshajiang paleo tethyan ocean in the carboniferous was caused by a mantle plume the mantle plume was active to the east along the western margin of the yangtze craton between 300 and 260 ma from which the voluminous emeishan flood basalts were erupted at 260 ma the closure of the jinshajiang ocean occurred since the middle permian continuous westward subduction generated the jiangda weixi magmatic arc to the west of the jinshajiang suture this subduction also partly destroyed and or tectonically sliced the volcanic rifted margin some seaward dipping volcanic sedimentary sequences on the east flank of the jinshajiang ocean were preserved but are strongly deformed

a mantle derived bimodal suite in the hercynian belt nd isotope and trace element evidence for a subduction related rift origin of the late devonian brevenne metavolcanics massif central france in the brevenne series ne massif central a low grade bimodal association of metabasalts and metarhyolites is exposed together with intrusive trondhjemite bodies zircon u pb dating constrains their magmatic emplacement at 366 5 ma and 358 1 ma respectively the metabasalts are characterized by a distinct enrichment in incompatible elements e g th and lree and positive ndi from 5 to 8 combined isotope and trace element systematics rule out crustal contamination of mafic melts as a suitable cause of the lile large ion lithophile element enrichment rather a mixing process between a component similar to mid ocean ridge basalts and an enriched end member with ndi 5 is suggested an enriched mantle source of ocean island basalt affinity is precluded by the relative depletion of high field strength elements especially nb which shows negative anomalies in chondrite normalized patterns on the contrary a subduction related origin for the lile enrichment would be more consistent it may be inferred that arc like melts enriched in th and lree light rare earth elements and depleted in nb with ndi 5 were produced through partial melting of a depleted mantle source to which a small amount of crustally derived component had been added the metarhyolites are enriched in lile and have a close genetic relationship with the metabasalts as evidenced by their high ndi from 4 7 to 6 8 although the chemical evidence remains ambiguous it is suggested that fractional crystallization accompanied by subordinate assimilation is the petrogenetic process most consistent with the data the trondhjemites are isotopically distinct from the metarhyolites their ndi values from 1 0 to 2 2 reflect an important contribution of continental crust to their genesis and disprove their inferred cogenetism with the felsic volcanics a review of modern environments in which such bimodal suites are exposed shows that settings involving incipient rifting of a volcanic arc fringing a continental margin or built upon young thin continental crust might provide suitable analogues geodynamic reconstructions are complicated by subsequent tectonic events which disrupted the initial patterns and by mesozoic cenozoic sedimentary cover however this subduction related magmatism enlarges the growing body of evidence for southward subduction processes until the late devonian during the evolution of the northern flank of the european variscides as a general implication it is suggested that the combined use of the sm nd system with incompatible elements relatively resistant during alteration and low grade metamorphism ree th zr nb may provide diagnostic criteria for recognizing the tectonic setting of bimodal metaigneous suites in ancient orogenic belts

shrimp u pb and 40ar 39ar age constraints for relating plutonism and mineralization in the boulder batholith region montana the composite boulder batholith montana hosts a variety of mineral deposit types including important silver rich polymetallic quartz vein districts in the northern part of the batholith and the giant butte porphyry copper molybdenum pre main stage system and crosscutting copper rich main stage vein system in the southern part of the batholith previous dating studies have identified ambiguous relationships among igneous and mineralizing events mineralizing hydrothermal fluids for these types of deposits and magma for quartz porphyry dikes at butte have all been considered to be late stage differentiates of the boulder batholith however previous dating studies indicated that the boulder batholith plutons cooled from about 78 to 72 ma whereas copper rich main stage veins at butte were dated at about 61 ma recent efforts to date the porphyry copper molybdenum pre main stage deposits at butte resulted in conflicting estimates of both 64 and 76 ma for the mineralizing events silver rich polymetallic quartz vein deposits elsewhere in the batholith have not been dated previously to resolve this controversy we used the u s geological survey stanford shrimp rg ion microprobe to date single age domains within zircons from plutonic rock samples and 40 ar 39 ar geochronology to date white mica biotite and k feldspar from mineral deposits u pb zircon ages are rader creek granodiorite 80 4 1 2 ma unionville granodiorite 78 2 0 8 ma pulpit rock granite 76 5 0 8 ma butte granite 74 5 0 9 ma altered steward type quartz porphyry dike i 15 roadcut 66 5 1 0 ma altered steward type quartz porphyry dike continental pit 65 7 0 9 ma and quartz monzodiorite of boulder baldy big belt mountains 66 2 0 9 ma zircons from rader creek granodiorite and quartz porphyry dike samples contain archean inheritance the 40 ar 39 ar ages are muscovite silver rich polymetallic quartz vein basin district 74 4 0 3 ma muscovite silver rich polymetallic quartz vein boulder district 74 4 1 2 ma muscovite early dark micaceous vein continental pit 63 6 0 2 ma biotite early dark micaceous vein continental pit 63 6 0 2 ma potassium feldspar early dark micaceous vein continental pit 63 to 59 ma and biotite biotite breccia dike continental pit 63 6 0 2 ma outlying silver rich polymetallic quartz veins of the basin and boulder mining districts probably are directly related to the 74 5 ma butte granite whereas steward type east west quartz porphyry dikes and butte pre main stage deposits are parts of a 66 to 64 ma magmatic mineralization system unrelated to emplacement of the boulder batholith the age of the crosscutting main stage veins may be about 61 ma as originally reported but can only be bracketed as younger than the 64 ma pre main stage mineralization and older than the about 50 ma eocene lowland creek intrusions the 66 ma age for the quartz monzodiorite of boulder baldy and consideration of previous dating studies in the region indicate that small ca 66 ma plutonic systems may be common in the boulder batholith region and especially to the east the approximately 64 ma porphyry copper systems at butte and gold mineralization at miller mountain are indicative of regionally important mineralizing systems of this age in the boulder batholith region resolution of the age and probable magmatic source of the butte pre main stage porphyry copper molybdenum system and of the silver rich polymetallic quartz vein systems in the northern part of the boulder batholith documents that these deposits formed from two discrete periods of hydrothermal mineralization related to two discrete magmatic events

geology and petrology of ejecta from the 1999 eruption of shishaldin volcano alaska shishaldin volcano erupted repeatedly during april and may 1999 with major eruptive events on 19 april and 23 april tephra deposits 20 cm thick were distributed across the southern flanks and hyperconcentrated debris flows ran down the northern slope all analyzed clasts were basaltic in composition with abundant 29 vol phenocrysts of plagioclase olivine and magnetite glass inclusion analyses indicate low volatile contents 900 to 58 ppm respectively comparisons of sulfur contents in glass inclusions and groundmass glasses suggest significant degassing occurred even prior to eruption trace element studies suggest that the magma reservoir below shishaldin may not be a closed long lived chamber and u th ra isotopic analyses indicate short crustal residence times on the order of at most a few thousand years for the 1999 products comparison of the deposits from this eruption with other similarly sized eruptions suggests the 19 april explosive event should be classified as a sub plinian basaltic eruption such eruptions are rare the 19 april explosive event was the largest at shishaldin during the last 175 years however the petrology chemistry and deposit thickness and distribution resemble those of at least 11 scoria deposits in the last 9 000 years suggesting that this type of eruption is common for shishaldin

zircon u pb ages hf o isotopes and whole rock sr nd pb isotopic geochemistry of granitoids in the jinshajiang suture zone sw china constraints on petrogenesis and tectonic evolution of the paleo tethys ocean the jinshajiang suture zone located in the eastern part of the tethyan tectonic domain is noticeable for a large scale distribution of late jurassic to triassic granitoids these granitoids were genetically related to the evolution of the paleo tethys ocean beiwu linong and lunong granitoids occur in the middle zone of the jinshajiang suture zone and possess similar geochemical features indicating that they share a common magma source sims zircon u pb dating reveals that the beiwu linong and lunong granitic intrusions were emplaced at 233 9 1 4 ma 2 233 1 1 4 ma 2 and 231 0 1 6 ma 2 respectively all of these granitoids are enriched in abundances of si sio2t 65 2 73 5 wt and large ion lithophile elements liles but depleted in high field strength elements contents hfses e g nb ta and ti in addition they have low p2o5 contents 0 06 0 11 wt a cnk values molecular al2o3 cao na2o k2o mostly 1 1 and 10 000 ga al ratios 1 7 2 2 consistent with the characteristics of i type granites in terms of isotopic compositions these granitoids have high initial 87sr 86sr ratios 0 7078 0 7148 pb isotopic compositions 206pb 204pb t 18 213 18 598 207pb 204pb t 15 637 15 730 and 208pb 204pb t 38 323 38 791 zircon 18o values 7 3 9 3 and negative end t values 5 1 to 6 7 suggesting they were predominantly derived from the continental crust their nb ta ratios average value 8 6 are consistent with those of the lower continental crust lcc however variable ehf t values 8 6 to 2 8 and the occurrences of mafic microgranular enclaves mmes suggest that mantle derived melts and lower crustal magmas were involved in the generation of these granitoids moreover the high pb isotopic ratios and elevated zircon 18o values of these rocks indicate a significant contribution of the upper crustal composition we propose a model in which the beiwu linong and lunong granitoids were generated under a late collisional or post collisional setting it is possible that this collision was completed before late triassic decompression induced mantle derived magmas to be underplated and provided the heat for the anatexis of the crust hybrid melts including mantle derived and the lower crustal magmas were then generated the hybrid melts thereafter ascended to a shallow depth and resulted in some degree of sedimentary rock assimilation such three component mixing magma source and subsequent fractional crystallization could be responsible for the formation of the beiwu linong and lunong granitoids

combined sr nd pb and li isotope geochemistry of alkaline lavas from northern james ross island antarctic peninsula and implications for back arc magma formation abstract we present a comprehensive geochemical data set for a suite of back arc alkaline volcanic rocks from james ross island volcanic group jrivg antarctic peninsula the elemental and isotopic sr nd pb and li composition of these cenozoic basalts emplaced east of the antarctic peninsula is different from the compositions of the fore arc alkaline volcanic rocks in southern shetlands and nearby bransfield strait the variability in elemental and isotopic composition is not consistent with the jrivg derivation from a single mantle source but rather it suggests that the magma was mainly derived from a depleted mantle with subordinate oib like enriched mantle component em ii the isotopic data are consistent with mantle melting during extension and possible roll back of the subducted lithosphere of the antarctic plate magma contamination by triassic early tertiary clastic sediments deposited in the back arc basin was only localized and affected li isotopic composition in two of the samples while most of the basalts show very little variation in 7 li values as anticipated for mantle driven li isotopic composition these variations are difficult to resolve with radiogenic isotope systematics but li isotopes may prove sensitive in tracking complex geochemical processes acting through the oceanic crust pile including hydrothermal leaching and seawater equilibration

geochemical constraints on the origin of bimodal magmatism at the okinawa trough an incipient back arc basin abstract the magmatism at the axial zone of the middle okinawa trough a young continental back arc basin comprises a bimodal basaltic rhyolitic suite accompanied by minor intermediate rocks we report major and trace element and sr nd isotopie data for the intermediate to silicic suites to provide constraints on their petrogenesis the rhyolites recovered as lava and pumice fall into three geochemical groups type 1 2 and 3 rhyolites type 1 rhyolites have 87sr 86sr 0 7040 0 7042 and 143nd 144nd 0 5128 0 5129 identical to those of associated basalts and are characterized by highly fractionated ree patterns petrogenesis of type 1 rhyolites is explicable in terms of fractional crystallization of the associated basalt in contrast type 2 rhyolites and andesite have slightly higher 87sr 86sr 0 7044 0 7047 but similar 143nd 144nd 0 5128 compared to those of the basalts the compositions of type 2 rhyolite and andesite can be explained by assimilation and fractional crystallization afc processes of the basalt magma quantitative analysis suggests assimilation fractional crystallization ma mc ratios of 0 05 hybrid andesite generated by mixing of evolved basalt and type 1 rhyolite is also present we emphasize that mechanical extension in this part of the okinawa trough involves gabbro ic lower crust that resulted from fractionation of mantle derived basaltic magmas type 3 rhyolite occurs only as pumice which makes its derivation questionable this rhyolite has major and trace element compositions and sr nd isotopie ratios which suggests that it may be derived from volcanic activity on the southern ryukyu volcanic front and arrived in the okinawa trough by drifting on the kuroshio current

triassic continental subduction in central tibet and mediterranean style closure of the paleo tethys ocean the qiangtang metamorphic belt qmb in central tibet is one of the largest and most recently documented high pressure hp to near ultrahigh pressure near uhp belts on earth lu hf ages of eclogite and blueschist facies rocks within the qmb are 244 223 ma indistinguishable from the age of uhp metamorphism in the qinling dabie orogen results of a u pb detrital zircon study suggest that protoliths of the qmb include upper paleozoic qiangtang continental margin strata and sandstones that were derived from a paleozoic arc terrane that developed within the paleo tethys ocean to the north we attribute qmb hp metamorphism to continental collision between the qiangtang terrane and a paleo tethys arc terrane this collision and the coeval south china north china collision may have slowed convergence between laurasia and gondwana derived terranes and initiated mediterranean style rollback and backarc basin development within much of the remnant paleo tethys ocean realm

petrogenesis and tectonic implications of the triassic volcanic rocks in the northern yidun terrane eastern tibet abstract triassic paleo tethyan subduction related volcanic rocks are extensively distributed in the xiangcheng and changtai regions northern yidun terrane eastern tibet the 228 ma volcanic rocks in the xiangcheng region have intermediate felsic composition 60 1 to 64 7 wt sio 2 with relatively low y 14 18 ppm and high sr 630 1830 ppm yielding high sr y ratios 43 94 they have lree enriched and hree depleted ree patterns la yb 19 26 typical of adakites sr nd isotopic compositions of these volcanic rocks are similar to those of the contemporaneous high silica adakitic rocks in the southern yidun terrane the 231 230 ma volcanic rocks in the changtai region are composed of basalts andesites dacites and rhyolites with sio 2 ranging from 47 7 to 81 0 wt basalts in the changtai region have initial 87 sr 86 sr ratios from 0 7052 to 0 7058 and e nd t from 1 1 to 1 5 they display oib like geochemical signatures and were likely derived from low degrees of partial melting of an oib like mantle source with subordinate input of subduction components indicated by increasing th content andesites and dacites show elemental and isotopic compositions that evolved from the basalts indicative of derivation via crustal contamination and fractional crystallization afc of basaltic magmas rhyolites have lower initial 87 sr 86 sr ratios and higher e nd t values than andesites dacites inconsistent with an afc process and are suggested to have been derived from anatexis of crustal materials emplacement of volcanic rocks in the changtai and xiangcheng regions could be attributed to the subduction of the ganzi litang ocean a branch of the paleo tethys ocean volcanic rocks in the changtai and xiangchang regions have zircon u pb ages about 4 6 myr older than that of arc granites in the eastern yidun terrane the spatio temporal distribution of the volcanic rocks indicates that the subduction was initiated under the southern yidun terrane in the middle triassic and extended to the northern yidun terrane at the beginning of the late triassic

petrogenetic evolution of felsic volcanic sequences associated with phanerozoic volcanic hosted massive sulphide systems the role of extensional geodynamics abstract felsic volcanic hosted massive sulphide deposits form in many different geotectonic environments usually associated with episodes of extension however empirical geochemical links between felsic volcanism geotectonic environment and extensional geodynamics have not been adequately documented so as to distill the fundamental relationships between these features and formation of volcanic hosted massive sulphide vhms mineralization which is important considering most vhms deposits are hosted in felsic volcanic bearing sequences using felsic geochemical data from six different vhms mineralized phanerozoic geotectonic settings it seems that the felsic geochemical data are consistent with the overall geotectonic interpretations for these areas which in turn helps in stratigraphic and geotectonic interpretations for detailed vhms exploration in extensional geodynamic settings bimodal volcanism is common compared to the continuum of compositions observed under compressional to neutral high stress regimes in calc alkaline arc building environments the empirical geochemical metallogenic vhms relationships evident in the archean felsic volcanic rocks in particular the low zr y n yb n 2 o conditions in different source areas and geotectonic environments they seem to be the predominant controls on the compositional evolution of felsic magmas in extensional settings because of the limited degree of assimilation and fractional crystallization afc affecting their compositions with rapid intrusion into the uppermost crust to positions were they achieve neutral buoyancy in the volcanic to subvolcanic environment within plate felsic or a type anorogenic type and anomalous ocean ridge or type felsic magmas that have tholeiitic affinities relatively low alkali elements are common within parts of the volcanic sequences hosting massive sulphide deposits reflecting in part a relationship to extension the high contents of high field strength elements zr ga lree hree y nb etc and other lines of evidence indicate they are relatively high temperature relatively reduced magmas probably derived from previously dehydrated granulitic or melted oceanic simatic or continental sialic crust low p granulites or amphibolites but also in some cases possibly mantle rocks such that they are significantly water undersaturated during melting i e a h 2 o 1 reduced viscosities typical of high temperature melts enable rapid intrusion to higher levels diking vs diapirism higher rates of heat advection from mantle mafic magmas into the thickened oceanic and or continental crust during lithospheric extension are needed to facilitate melting of these rock to form a type and or or type partial melts tholeiitic felsic this usually results in bimodal magmatism as magma mixing is not favored in extensional settings especially at high magma production intrusion and extrusion rates i e high heat flow this would inhibit ferromagnesian phase in particular hornblende and magnetite fractionation especially at low f o 2 in the felsic magmas that would deplete the melt in y hree as well as ore related elements particularly zn which is 2 to 3 times higher in a type and or type rocks compared to other magma types therefore the empirical felsic igneous geochemical metallogenic relationships observed by others low zr y n yb n

the jinshajiang ailaoshan suture zone china tectonostratigraphy age and evolution abstract the jinshajiang suture zone is important for enhancing our understanding of the evolution of the paleo tethys and its age tectonic setting and relationship to the ailaoshan suture zone have long been controversial based on integrated tectonic biostratigraphic chemostratigraphic and isotope geochronological studies four tectono stratigraphic units can be recognized in the jinshajiang suture zone the eaqing complex the jinshajiang ophiolitic melange the gajinxueshan group and the zhongxinrong group isotope geochronology indicates that the redefined eaqing complex composed of high grade metamorphic rocks might represent the metamorphic basement of the jinshajiang area or a remnant micro continental fragment eaqing complex protolith rocks are pre devonian and probably of early middle proterozoic age and are correlated with those of the ailaoshan complex two zircon u pb ages of 340 3 and 294 3 ma separately dated from the shusong and xuitui plagiogranites within the ophiolitic assemblage indicate that the jinshajiang oceanic lithosphere formed in latest devonian to earliest carboniferous times the oceanic lithosphere was formed in association with the opening and spreading of the jinshajiang oceanic basin and was contiguous and equivalent to the ailaoshan oceanic lithosphere preserved in the shuanggou ophiolitic melange in the ailaoshan suture zone the latter yielded a u pb age of 362 41 ma from plagiogranite the re defined gajinxueshan and zhongxinrong groups are dated as carboniferous to permian and latest permian to middle triassic respectively on the basis of fossils and u pb dating of basic volcanic interbeds the gajinxueshan group formed in bathyal slope to neritic shelf environments and the zhongxinrong group as bathyal to abyssal turbidites in the jinshajiang ailaoshan back arc basin latest permian earliest middle triassic synorogenic granitoids with ages of 238 18 and 227 5 255 8 ma respectively and an upper triassic overlap molasse sequence indicate a middle triassic age for the jinshajiang ailaoshan suture formed by collision of the changdu simao block with south china

crustal origin of early proterozoic syenites in the congo craton ntem complex south cameroon two petrographically different syenite suites can be distinguished in the mostly archean ntem complex of cameroon a suite of two pyroxene syenites and a suite of clinopyroxene syenites the syenites occur as discrete intrusions surrounded by archean gneisses based on structural relationships the syenites are of late to post orogenic origin the pb pb zircon evaporation ages indicate that the syenites intruded at ca 2 3 ga and thus postdate significantly the archean episode of crust formation and differentiation that generated the surrounding gneiss terrane the isotope signatures and the trace elements provide unambiguous evidence that the two syenite suites are of crustal origin the syenite suites do not show simple chemical trends have highly variable trace element contents and display only a small variation in their major element contents particularly in their sio2 contents the isotope characteristics including 143nd 144nd 87sr 86sr and common pb point to a heterogeneous source or multiple sources for the syenites the sr isotope compositions calculated for the time of intrusion vary over a wide range from an unrealistically low 87sr 86sr ratio of 0 690 to high values of 0 713 in contrast the initial 143nd 144nd ratios are more homogenous with end 2320 from 5 8 to 7 5 the pb isotopes from leached k feldspars indicate that the sources of the syenites had a history of u depletion and th u enrichment the syenites show the same isotope characteristics as the surrounding gneiss terrane thus the deep continental crust of the ntem complex itself is the most likely source for the syenite melts this conclusion is also supported by the heterogeneity of the trace elements in the syenites that exclude a homogenous source in addition inherited zircons from the syenites yield pb pb evaporation ages that are consistent with ages obtained for zircons extracted from the surrounding gneisses in contrast to many other syenites worldwide the syenites in the ntem complex do not contain juvenile mantle material but are the sole products of crustal reworking thus the syenites did not contribute to the crustal growth in the ntem complex however this conclusion may not preclude the possibility that the syenites were generated in the deep crust during a time of addition of mantle material to the continental crust the cause for the generation of these large syenite bodies in the ntem complex is most likely an episode of deep seated thermal activity that was so far not known from this part of the congo craton

permian peralkaline peraluminous and metaluminous a type granites in the panxi district sw china their relationship to the emeishan mantle plume abstract numerous permian granitic intrusions plutons in the panxi region sw china are spatially and temporally associated with the emeishan large igneous province elip granites from the 260 ma panzhihua and taihe plutons are peralkaline asi 0 76 1 12 na k al 0 78 1 2 and have high fe values 0 92 0 99 with negative eu anomalies eu eu 0 22 0 98 contrasted with the peralkaline plutons syenites from the 260 ma woshui pluton are metaluminous asi 0 84 1 0 na k al 0 91 1 01 and have moderately high fe 0 79 0 81 and positive eu anomalies eu eu 0 82 1 91 both the peralkaline and metaluminous rocks have mantle isotopic signatures end t 1 3 3 2 and were derived from the elip mantle plume source the peralkaline rocks were likely derived by fractional crystallization of the temporally spatially and chemically associated layered mafic intrusions which host giant magmatic fe ti v oxide deposits the metaluminous granitic rocks although spatially related to the peralkaline granites and layered gabbros were likely generated by partial melting of underplated mafic rocks granites from the 251 ma ailanghe pluton are peraluminous asi 0 97 1 29 and have high fe 0 82 0 91 values and negative eu anomalies eu eu 0 10 0 37 their crustal isotopic signature end t 5 7 to 6 7 indicates possible derivation from melting of yangtze block basement rocks the ailanghe pluton is contemporaneous with other a type granites in the region supporting the view that elip magmatism was sporadic for at least 9 million years the coexistence of three chemically exclusive a type granites in the elip suggests that a variety of a type granites can be generated in the same tectonic setting

contrasting rift and subduction related plagiogranites in the jinshajiang ophiolitic melange southwest china and implications for the paleo tethys 1 the jinshajiang ophiolitic melange zone in southwest china represents a remnant of the eastern paleo tethys ocean field geochronological and geochemical studies have identified two distinct suites of plagiogranites within the melange the dongzhulin trondhjemite and jiyidu tonalite which represent rift and subduction settings respectively related to opening and closing of the ocean shrimp u pb analysis on zircons extracted from the dongzhulin trondhjemite yields a mean 206pb 238u age of 347 7 ma ree and isotopic characteristics suggest an origin from low pressure partial melting of an amphibolitic protolith highly variable hf isotopic compositions for zircons from this body may indicate a heterogenous source involving both depleted mantle and enriched continental components this together with geologic relations suggests formation near an embryonic spreading center in a continent ocean transition setting the jiyidu tonalite has a u pb zircon age of 283 3 ma and geochemical data indicates high sr y la yb n nb ta and low y and marked heavy ree depletion these signatures suggest derivation from low degree partial melting of subducted slab at pressure high enough to stabilize garnet and rutile a slab melt origin is also supported by in situ hf and o data for zircon that show isotopic compositions comparable with typical altered oceanic crust thus the crystallization age of the jiyidu high sr y tonalite provides a constraint for the subduction of the jinshajiang ocean floor the rift related dongzhulin trondhjemite and subduction related jiyidu high sr y tonalite constrain the timing and setting of opening and closing of this segment of the paleo tethys ocean

back arc basin basalt systematics the mariana east scotia lau and manus back arc basins babs have spreading rates that vary from slow 100 mm yr and extension axes located from 10 to 400 km behind their island arcs axial lava compositions from these babs indicate melting of mid ocean ridge basalt morb like sources in proportion to the amount added of previously depleted water rich arc like components the arc like end members are characterized by low na ti and fe and by high h2o and ba la the morb like end members have the opposite traits comparisons between basins show that the least hydrous compositions follow global morb systematics and an inverse correlation between na8 and fe8 this is interpreted as a positive correlation between the average degree and pressure of mantle melting that reflects regional variations in mantle potential temperatures lau manus hotter than mariana scotia this interpretation accords with numerical model predictions that faster subduction induced advection will maintain a hotter mantle wedge the primary compositional trends within each bab a positive correlation between fe8 na8 and ti8 and their inverse correlation with h2o 8 and ba la are controlled by variations in water content melt extraction and enrichments imposed by slab and mantle wedge processes systematic axial depth as a proxy for crustal production variations with distance from the island arc indicate that compositional controls on melting dominate over spreading rate hydrous fluxing enhances decompression melting allowing depleted mantle sources just behind the island arc to melt extensively producing shallow spreading axes flow of enriched mantle components around the ends of slabs may augment this process in transform bounded back arcs such as the east scotia basin the re circulation by mantle wedge corner flow to the spreading axes of mantle previously depleted by both arc and spreading melt extraction can explain the greater depths and thinner crust of the east lau spreading center manus southern rifts and mariana trough and the very depleted lavas of east scotia segments e8 e9 the crust becomes mid ocean ridge mor like where the spreading axes further away from the island arc and subducted slab entrain dominantly fertile mantle

mesozoic plutons of the yidun arc sw china u pb geochronology and hf isotopic signature abstract the yidun arc is a triassic volcanic arc located between the songpan garze fold belt and the qiangtang block southwest china to constrain the age of a number of the major granitic plutons from the yidun arc laser ablation icp ms u pb analysis of zircon was conducted hafnium isotope data was also acquired through laser ablation multicollector icpms analysis of zircon with the aim of gaining insight into the age and nature of the source region of the plutons three age groups have been identified from seven granite samples early middle triassic 245 to 229 ma late triassic 219 to 216 ma and cretaceous 105 to 95 ma hafnium analysis shows the triassic granites to have negative and variable e hf values and mesoproterozoic 1 6 ga depleted mantle model ages which is interpreted to reflect derivation from an isotopically heterogeneous largely crustal source the cretaceous granite shows higher and less variable e hf values and slightly younger model ages 1 3 ga and is interpreted to be derived from melting of a more homogeneous crustal source a depleted mantle model age of 1 5 ga is calculated from the pooled triassic and cretaceous samples the source region for these magmas may be tentatively correlated with mesoproterozoic material of the yangtze craton which has been suggested to underlie the yidun arc however further work is necessary to demonstrate this suggestion