the new athena alpha particle x ray spectrometer for the mars exploration rovers 1 the new alpha particle x ray spectrometer apxs is part of the athena payload of the two mars exploration rovers mer the apxs sensor head is attached to the turret of the instrument deployment device idd of the rover the apxs is a very light weight instrument for determining the major and minor elemental composition of martian soils rocks and other geological materials at the mer landing sites the sensor head has simply to be docked by the idd on the surface of the selected sample x ray radiation excited by alpha particles and x rays of the radioactive sources is recorded by a high resolution x ray detector the x ray spectra show elements starting from sodium up to yttrium depending on their concentrations the backscattered alpha spectra measured by a ring of detectors provide additional data on carbon and oxygen by means of a proper calibration the elemental concentrations are derived together with data from the two other athena instruments mounted on the idd the samples under investigation can be fully characterized key apxs objectives are the determination of the chemistry of crustal rocks and soils and the examination of water related deposits sediments or evaporates using the rock abrasion tool attached to the idd issues of weathering can be addressed by measuring natural and abraded surfaces of rocks

a global view of martian surface compositions from mgs tes thermal emission spectrometer tes data from the mars global surveyor mgs are used to determine compositions and distributions of martian low albedo regions two surface spectral signatures are identified from low albedo regions comparisons with spectra of terrestrial rock samples and deconvolution results indicate that the two compositions are a basaltic composition dominated by plagioclase feldspar and clinopyroxene and an andesitic composition dominated by plagioclase feldspar and volcanic glass the distribution of the two compositions is split roughly along the planetary dichotomy the basaltic composition is confined to older surfaces and the more silicic composition is concentrated in the younger northern plains

low abundance materials at the mars pathfinder landing site an investigation using spectral mixture analysis and related techniques abstract recalibrated and geometrically registered multispectral images from the imager for mars pathfinder imp were analyzed using spectral mixture analysis sma and related techniques sma models a multispectral image scene as a linear combination of endmember spectra and anomalous materials which do not fit the model are detected as model residuals while most of the imp data studied here are modeled generally well using bright dust gray rock and shade image endmembers additional anomalous materials were detected through careful analysis of root mean square rms error images resulting from sma for example analysis of sma fraction and rms images indicates spectral differences within a previously monolithologic dark soil class a type of dark soil that has high fractional abundances in rock fraction images gray rock soil was identified other anomalous materials identified included a previously noted black rock lithology a class of possibly indurated compacted or partially cemented soils intermediate soil and a unit referred to as anomalous patches on at least one rock the black rock lithology has a strong 900 1000 nm absorption and modeling of the derived image endmembers using a laboratory reference endmember modeling rem approach produced best fit model spectra that are most consistent with the presence of high ca pyroxenes and or olivine crystalline ferric oxide minerals or mixtures of these materials as important components of the black rock endmember more unique mineralogic identifications could not be obtained using our initial rem analyses both intermediate soil and anomalous patches units exhibit a relatively narrow 860 950 nm absorption that is consistent with the presence of either low ca pyroxenes or a cementing crystalline ferric oxide mineral

petrology and chemistry of mil 03346 and its significance in understanding the petrogenesis of nakhlites on mars antarctic meteorite miller range mil 03346 is a nakhlite composed of 79 clinopyroxene 1 olivine and 20 vitrophyric intercumulus material we have performed a petrological and geochemical study of mil 03346 demonstrating a petrogenetic history similar to previously discovered nakhlites quantitative textural study of mil 03346 indicates long 1 x 101 yr residence times for the cumulus augite whereas the skeletal fe ti oxide fayalite and sulfide in the vitrophyric intercumulus matrix suggest rapid cooling probably as a lava flow from the relatively high forsterite contents of olivine up to fo43 compared with other nakhlites and compositions of augite cores wo38 42en35 40fs22 28 and their hedenbergite rims we suggest that mil 03346 is part of the same or a similar martian cumulate rich lava flow as other nakhlites however mil 03346 has experienced less equilibration and faster cooling than other nakhlites discovered to date calculated trace element concentrations based upon modal abundances of mil 03346 and its constituent minerals are identical to whole rock trace element abundances parental melts for augite have ree patterns that are approximately parallel with whole rock and intercumulus melt using experimentally defined partition coefficients this parallelism reflects closed system crystallization for mil 03346 where the only significant petrogenetic process between formation of augite and eruption and emplacement of the nakhlite flow has been fractional crystallization a model for the petrogenesis of mil 03346 and the nakhlites nakhla governador valadares lafayette yamato 000593 northwest africa nwa 817 nwa 998 would include 1 partial melting and ascent of melt generated from a long term lree depleted mantle source 2 crystallization of cumulus augite olivine magnetite in a shallow level martian magma chamber 3 eruption of the crystal laden nakhlite magma onto the surface of mars 4 cooling crystal settling overgrowth and partial equilibration to different extents within the flow 5 secondary alteration through hydrothermal processes possibly immediately succeeding or during emplacement of the flow this model might apply to single or multiple flow models for the nakhlites ultimately mil 03346 and the other nakhlites preserve a record of magmatic processes in volcanic rocks on mars with analogous petrogenetic histories to pyroxene rich terrestrial lava flows and to komatiites

overview of the microscopic imager investigation during spirit s first 450 sols in gusev crater the microscopic imager mi on the mars exploration rover spirit has returned images of mars with higher resolution than any previous camera system allowing detailed petrographic and sedimentological studies of the rocks and soils at the gusev landing site designed to simulate a geologist s hand lens the mi is mounted on spirit s instrument arm and can resolve objects 0 1 mm in size or larger this paper provides an overview of mi operations data calibration processing and analysis of mi data returned during the first 450 sols mars days of the spirit landed mission the primary goal of this paper is to facilitate further analyses of mi data by summarizing the methods used to acquire and process the data the radiometric and geometric accuracy of mi data products and the availability of archival products in addition scientific results of the mi investigation are summarized mi observations show that poorly sorted soils are common in gusev crater although aeolian bedforms have well sorted coarse sand grains on their surfaces abraded surfaces of plains rocks show igneous textures light toned veins or fracture filling minerals and discrete coatings the rocks in the columbia hills have a wide variety of granular textures consistent with volcaniclastic or impact origins case hardening and submillimeter veins observed in the rocks as well as soil crusts and cemented clods imply episodic subsurface aqueous fluid movement which has altered multiple geologic units in the columbia hills the mi also monitored spirit s solar panels and the magnets on the rover s deck

mossbauer mineralogy of rock soil and dust at gusev crater mars spirit s journey through weakly altered olivine basalt on the plains and pervasively altered basalt in the columbia hills 1 the mossbauer spectrometer on spirit measured the oxidation state of fe identified fe bearing phases and measured relative abundances of fe among those phases for surface materials on the plains and in the columbia hills of gusev crater eight fe bearing phases were identified olivine pyroxene ilmenite magnetite nanophase ferric oxide npox hematite goethite and a fe3 sulfate adirondack basaltic rocks on the plains are nearly unaltered fe3 fet px and minor npox and magnetite columbia hills basaltic rocks are nearly unaltered peace and backstay moderately altered woolypatch wishstone and keystone and pervasively altered e g clovis uchben watchtower keel and paros with fe3 fet 0 6 0 9 fe from pyroxene is greater than fe from olivine ol sometimes absent and fe2 from ol px is 40 49 and 9 24 for moderately and pervasively altered materials respectively ilmenite fe from ilm 3 6 is present in backstay wishstone keystone and related rocks along with magnetite fe from mt 10 15 remaining fe is present as npox hematite and goethite in variable proportions clovis has the highest goethite content fe from gt 40 goethite feooh is mineralogical evidence for aqueous processes because it has structural hydroxide and is formed under aqueous conditions relatively unaltered basaltic soils fe3 fet 0 3 occur throughout gusev crater 60 80 fe from ol px 10 30 from npox and 10 from mt pasorobles soil in the columbia hills has a unique occurrence of high concentrations of fe3 sulfate 65 of fe magnetite is identified as a strongly magnetic phase in martian soil and dust

duration of the ma adim vallis gusev crater hydrogeologic system mars abstract ma adim vallis and gusev crater aeolis subquadrangle of mars formed a complex hydrogeologic system through time crater statistics over five geologic units coupled with morphologic and geologic observations show that this system was active over a period ranging from 0 7 to about 2 billion years these results make the floor of gusev crater one of the most prominent martian depositional features the last aqueous sedimentary deposition could have occurred during early amazonian

mineralogy and39ar 40ar age of an old pristine basalt thermal history of the hed parent body previous investigations of mineral chemistry and rbsr and smnd ages indicated that clast 84 from eucrite yamato 75011 had preserved the pristine nature of its initial crystallization during an early stage of the hed parent body microscale mineralogy and39ar 40ar ages of this clast however revealed local disturbance of micrtextures and partially reset ages this evidence suggests that in addition to initial crystallization and rapid cooling the y75011 84 clast experienced shock deformation reheating of short duration at higher temperature and brecciation these characteristics suggest two or more impact events fe rich olivine filling fractures in pyroxene may have been introduced during the accompanying shock fracturing the inferred39ar 40ar degassing ages for y75011 matrix and clast 84 are3 94 0 04 ga and3 98 0 03 ga respectively the suggested degassing age for a clast from y790020 believed to be paired with y75011 is 4 03 ga but could be younger we consider it likely that all three samples experienced a common degassing event3 95 0 05 ga ago but we cannot rule out two or more events spaced over a 0 1 ga interval higher temperature extractions of the two clast samples show significantly older apparent ages up to 4 5 ga and suggest that the time temperature regime of this event was not sufficient to degas ar totally most likely the k ar ages were reset by thermal metamorphism associated with one or more impact events associated with shock fracturing formation of fe rich olivine veins and or meteorite brecciation the pyroxene annealing that commonly occurs in many eucrites is likely to be a much earlier process than the impact produced textural changes and reset k ar ages observed in these meteorites the existence of mineralogical and chronological evidence for metamorphism in an otherwise pristine eucrite suggests that the hed parent body experienced an extensive degree of early cratering

athena microscopic imager investigation 1 the athena science payload on the mars exploration rovers mer includes the microscopic imager mi the mi is a fixed focus camera mounted on the end of an extendable instrument arm the instrument deployment device idd the mi was designed to acquire images at a spatial resolution of 30 microns pixel over a broad spectral range 400 700 nm the mi uses the same electronics design as the other mer cameras but has optics that yield a field of view of 31 31 mm across a 1024 1024 pixel ccd image the mi acquires images using only solar or skylight illumination of the target surface a contact sensor is used to place the mi slightly closer to the target surface than its best focus distance about 66 mm allowing concave surfaces to be imaged in good focus coarse focusing 2 mm precision is achieved by moving the idd away from a rock target after the contact sensor has been activated the mi optics are protected from the martian environment by a retractable dust cover the dust cover includes a kapton window that is tinted orange to restrict the spectral bandpass to 500 700 nm allowing color information to be obtained by taking images with the dust cover open and closed mi data will be used to place other mer instrument data in context and to aid in petrologic and geologic interpretations of rocks and soils on mars

alpha particle x ray spectrometer apxs results from gusev crater and calibration report 1 the chemical composition of rocks and soils on mars analyzed during the mars exploration rover spirit mission was determined by x ray analyses with the alpha particle x ray spectrometer apxs details of the data analysis method and the instrument calibration are presented measurements performed on mars to address geometry effects and background contributions are shown cross calibration measurements among several instrument sensors and sources are discussed an unintentional swap of the two flight instruments is evaluated new concentration data acquired during the first 470 sols of rover spirit in gusev crater are presented there are two geological regions the gusev plains and the columbia hills the plains contain soils that are very similar to previous landing sites on mars a meteoritic component in the soil is identified rocks in the plains revealed thin weathering rinds the underlying abraded rock was classified as primitive basalt one of these rocks contained significant br that is probably associated with vein filling material of different composition one of the trenches showed large subsurface enrichments of mg s and br disturbed soils and rocks in the columbia hills revealed different elemental compositions these rocks are significantly weathered and enriched in mobile elements such as p s cl or br even abraded rock surfaces have high br concentrations thus in contrast to the rocks and soils in the gusev plains the columbia hills material shows more significant evidence of ancient aqueous alteration

overview of the spirit mars exploration rover mission to gusev crater landing site to backstay rock in the columbia hills spirit landed on the floor of gusev crater and conducted initial operations on soil covered rock strewn cratered plains underlain by olivine bearing basalts plains surface rocks are covered by wind blown dust and show evidence for surface enrichment of soluble species as vein and void filling materials and coatings the surface enrichment is the result of a minor amount of transport and deposition by aqueous processes layered granular deposits were discovered in the columbia hills with outcrops that tend to dip conformably with the topography the granular rocks are interpreted to be volcanic ash and or impact ejecta deposits that have been modified by aqueous fluids during and or after emplacement soils consist of basaltic deposits that are weakly cohesive relatively poorly sorted and covered by a veneer of wind blown dust the soils have been homogenized by wind transport over at least the several kilometer length scale traversed by the rover mobilization of soluble species has occurred within at least two soil deposits examined the presence of monolayers of coarse sand on wind blown bedforms together with even spacing of granule sized surface clasts suggests that some of the soil surfaces encountered by spirit have not been modified by wind for some time on the other hand dust deposits on the surface and rover deck have changed during the course of the mission detection of dust devils monitoring of the dust opacity and lower boundary layer and coordinated experiments with orbiters provided new insights into atmosphere surface dynamics

the rocks of mars from far and near award of the meteoritical society 2001 h y mcsween jr the leonard medal address the rocks of mars from far and near

seeing through the dust martian crustal heterogeneity and links to the snc meteorites through the application of new analytical techniques to high spatial resolution imaging spectrometer data the ferrous mineralogy of major volcanic terrains on mars is shown to consist of significant fractions of both low and high calcium pyroxene changes in the relative abundances of these pyroxenes are observed for units of different age and morphology even in regions with higher degrees of alteration and contamination from dust volcanic rocks with these characteristics are uncommon on earth but are typical of the basaltic snc meteorites shergottites nakhlites and chassignites thought to be from mars thus it is possible to infer even through the veil of dust that the snc meteorites have mineralogic affinities to major volcanic provinces on mars and are therefore truly representative of the heterogeneity observed on the surface of the red planet

alkaline volcanic rocks from the columbia hills gusev crater mars 1 irvine backstay and wishstone are the type specimens for three classes of fine grained or fragmental relatively unaltered rocks with distinctive thermal emission spectra found as float on the flanks of the columbia hills chemical analyses indicate that these rocks are mildly alkaline basalt trachybasalt and tephrite respectively their mineralogy consists of na and k rich feldspar s low and high ca pyroxenes ferroan olivine fe ti and possibly cr oxides phosphate and possibly glass the texture of wishstone is consistent with a pyroclastic origin whereas irvine and backstay are lavas or possibly dike rocks chemical compositions of these rocks plot on or near liquid lines of descent for most elements calculated for adirondack class rocks olivine rich basalts from the gusev plains at various pressures from 0 1 to 1 0 gpa we infer that wishstone backstay and irvine class magmas may have formed by fractionation of primitive oxidized basaltic magma similar to adirondack class rocks the compositions of all these rocks reveal that the gusev magmatic province is alkaline distinct from the subalkaline volcanic rocks thought to dominate most of the planet s surface the fact that differentiated volcanic rocks were not encountered on the plains prior to ascending husband hill may suggest a local magma source for volcanism beneath gusev crater

in flight calibration and performance of the mars exploration rover panoramic camera pancam instruments 1 the mars exploration rover panoramic camera mer pancam instruments have acquired more than 60 000 high resolution multispectral stereoscopic images of soil rocks and sky at the gusev crater and meridiani planum landing sites since january 2004 these images combined with other mer data sets have enabled new discoveries about the composition mineralogy and geologic geochemical evolution of both sites one key to the success of pancam in contributing to the overall success of mer has been the development of a calibration pipeline that can quickly remove instrumental artifacts and generate both absolute radiance and relative reflectance images with high accuracy and precision in order to influence tactical rover driving and in situ sampling decisions this paper describes in detail the methods assumptions and models algorithms in the calibration pipeline developed for pancam images based on new measurements and refinements performed primarily from flight data acquired on mars major calibration steps include modeling and removal of detector bias signal active and readout region dark current electronic shutter smear and pixel to pixel responsivity flatfield variations pancam images are calibrated to radiance w m2 nm sr using refined preflight derived calibration coefficients or radiance factor i f using near in time measurements of the pancam calibration target and a model of aeolian dust deposition on the target as a function of time we are able to verify that the absolute radiance calibration of most pancam images is accurate to within about 10 or less and that the filter to filter and pixel to pixel precision of the calibrated relative reflectance data both based on measurements of the pancam calibration target are typically about 3 and 1 or less respectively examples are also presented of scientific applications made possible by the high fidelity of the calibrated pancam data these include 11 color visible to near ir spectral analysis calculation of true color and chromaticity values and generation of super resolution image data products this work represents a follow on and enhancement to the pancam preflight calibration process described by bell et al 2003

geochemical and mineralogical indicators for aqueous processes in the columbia hills of gusev crater mars 1 water played a major role in the formation and alteration of rocks and soils in the columbia hills the extent of alteration ranges from moderate to extensive five distinct rock compositional classes were identified the order for degree of alteration is watchtower clovis wishstone peace backstay the rover s wheels uncovered one unusual soil paso robles that is the most s rich material encountered clovis class rocks have compositions similar to gusev plains soil but with higher mg cl and br and lower ca and zn watchtower and wishstone classes have high al ti and p and low cr and ni peace has high mg and s and low al na and k backstay basalts have high na and k compared to plains adirondack basalts and paso robles soil has high s and p some rocks are corundum normative indicating that their primary compositions were changed by loss and or gain of rock forming elements clovis materials consist of magnetite nanophase ferric oxides npox hematite goethite ca phosphates ca and mg sulfates pyroxene and secondary aluminosilicates wishstone and watchtower rocks consist of fe oxides oxyhydroxides ilmenite ca phosphate pyroxene feldspar mg sulfates and secondary aluminosilicates peace consists of magnetite npox mg and ca sulfates pyroxene olivine feldspar apatite halides and secondary aluminosilicates paso robles consists of fe3 mg ca and other sulfates ca phosphates hematite halite allophane and amorphous silica columbia hills outcrops and rocks may have formed by the aqueous alteration of basaltic rocks volcaniclastic materials and or impact ejecta by solutions that were rich in acid volatile elements

an integrated method for the quantitative evaluation of mineral resources of cobalt rich crusts on seamounts abstract cobalt rich crusts on seamounts potentially have the economic value of multiple metals in the field of exploration it is important to perform quantitative evaluations of mineral resources and delineate promising areas in survey regions for future mining accordingly this study based on prior knowledge develops an integrated method to quantitatively evaluate mineral resources of cobalt rich crusts on seamounts and gives an application example to demonstrate this method the method includes four steps first defining units with certain areas and shapes on the target seamount a 20 km2 square block in the application example and estimating characteristic values of the cobalt rich crust for each unit with known geological survey data using a space interpolation method such as kriging second presenting several model algorithms i e regional coverage of crusts suitable slope percentage for mining and fitting area on slopes to extract the corresponding regional metallogenic factors for each unit by inputting regional surveying data such as bathymetry data into these models third considering both the features and regional metallogenic factors of cobalt rich crusts in each unit to estimate their distribution of mineral resources on the entire seamount and last according to the distribution of the mineral resources and international social and economic requirements such as the regulations of the international seabed authority delineating a promising area for future mining

a volcanic interpretation of gusev crater surface materials from thermophysical spectral and morphological evidence 1 gusev crater the mars exploration rover spirit landing site 160 km diameter 14 5 s 184 5 w has been identified in previous studies as a prime site of geological and exobiological interest on the basis of its potential for having hosted a fluviolacustrine environment such environment may have been favorable for the development of biological activity the origin and nature of the materials present at the surface of gusev crater are still being debated in previous studies based on geomorphological and thermophysical data surface materials in the crater have been interpreted as originating from fluviolacustrine volcanic or aeolian processes or combinations thereof we present results from the analysis of newly compiled thermophysical thermal emission spectrometer tes and thermal emission imaging system themis spectroscopic tes and visible themis and mars observer camera data for the gusev region these data were analyzed using a new mosaicking technique developed to match the values of contiguous scenes and to produce seamless mosaics apt for geological interpretation thermophysical spectroscopic and morphological evidence point to the presence of local outcrops of lava flows of basaltic composition materials consistent with a regolith developed from basaltic materials fine grained deposits of basaltic composition strongly modified by wind erosion and wind deposits according to these findings we conclude that most of the materials occupying the present surface of gusev have characteristics consistent with those of volcanic and aeolian deposits fluviolacustrine deposits proposed by other authors may exist under the volcanic materials and may be exposed in impact craters

the rocks of gusev crater as viewed by the mini tes instrument 1 the miniature thermal emission spectrometer mini tes on board the mars exploration rover spirit is part of a payload designed to investigate whether a lake once existed in gusev crater mini tes has observed hundreds of rocks along the rover s traverse into the columbia hills yielding information on their distribution bulk mineralogy and the potential role of water at the site although dust in various forms produces contributions to the spectra we have established techniques for dealing with it all of the rocks encountered on the plains traverse from the lander to the base of the columbia hills share common spectral features consistent with an olivine rich basaltic rock known as adirondack class beginning at the base of the west spur of the columbia hills and across its length the rocks are spectrally distinct from the plains but can be grouped into a common type called clovis class these rocks some of which appear as in place outcrop are dominated by a component whose spectral character is consistent with unaltered basaltic glass despite evidence from other rover instruments for significant alteration the northwest flank of husband hill is covered in float rocks known as wishstone class with spectral features that can be attributed uniquely to plagioclase feldspar a phase that represents more than half of the bulk mineralogy rare exceptions are three classes of basaltic exotics found scattered across husband hill that may represent impact ejecta and or float derived from local intrusions within the hills the rare outcrops observed on husband hill display distinctive spectral characteristics the outcrop called peace shows a feature attributable to molecular bound water and the outcrop that hosts the rock called watchtower displays a dominant basaltic glass component despite evidence from the rover s payload for significant alteration of some of the rocks no unambiguous detection of crystalline phyllosilicates or other secondary silicates has been observed by mini tes the mineralogical results supplied by mini tes provide no clear evidence that a lake once existed in gusev crater

analysis of terrestrial and martian volcanic compositions using thermal emission spectroscopy 2 application to martian surface spectra from the mars global surveyor thermal emission spectrometer atmospherically corrected thermal infrared spectra of large regions of the martian surface from the mars global surveyor thermal emission spectrometer mgs tes previously have been interpreted to represent two general spectral classes one class represents a basalt to basaltic andesite composition and the other class represents a basaltic andesite to andesite composition we have performed new linear deconvolutions of the two martian surface type spectra with an end member set tailored to represent volcanic rock types our preparatory study of laboratory spectra of terrestrial volcanic rocks acquired at 2 cm 21 sampling convolved to tes spectral sampling 10 cm 21 shows little degradation in deconvolution results when compared to results acquired using the higher spectral resolution data indicating that the deconvolution technique is valid for analyzing data at tes resolution our spectral fits to the martian data agree well with previous models and do not exhibit any notable deviations from the martian spectra that would indicate the absence of any significant end members in our model modal mineralogies obtained with these new spectral fits also compare favorably within the previously stated uncertainties to prior results the newly derived modal mineralogies are used with new and traditional classification schemes for volcanic igneous rocks introduced in a companion paper wyatt et al this issue to classify the martian compositions our results substantiate the previously proposed hypothesis that these two spectral classes on the martian surface represent volcanic compositions with distinguishable differences in silica content ranging from basalt to andesite

spectral variability among rocks in visible and near infrared multispectral pancam data collected at gusev crater examinations using spectral mixture analysis and related techniques 1 visible and near infrared vnir multispectral observations of rocks made by the mars exploration rover spirit s panoramic camera pancam have been analyzed using a spectral mixture analysis sma methodology scenes have been examined from the gusev crater plains into the columbia hills most scenes on the plains and in the columbia hills could be modeled as three end member mixtures of a bright material rock and shade scenes of rocks disturbed by the rover s rock abrasion tool rat required additional end members in the columbia hills there were a number of scenes in which additional rock end members were required the sma methodology identified relatively dust free areas on undisturbed rock surfaces as well as spectrally unique areas on rat abraded rocks spectral parameters from these areas were examined and six spectral classes were identified these classes are named after a type rock or area and are adirondack lower west spur clovis wishstone peace and watchtower these classes are discriminable based primarily on near infrared nir spectral parameters clovis and watchtower class rocks appear more oxidized than wishstone class rocks and adirondack basalts based on their having higher 535 nm band depths comparison of the spectral parameters of these gusev crater rocks to parameters of glass dominated basaltic tuffs indicates correspondence between measurements of clovis and watchtower classes but divergence for the wishstone class rocks which appear to have a higher fraction of crystalline ferrous iron bearing phases despite a high sulfur content the rock peace has nir properties resembling plains basalts

final chemical results from the mars pathfinder alpha proton x ray spectrometer 1 the calibrated pathfinder alpha proton x ray spectrometer apxs instrument is capable of measuring concentrations of all major and minor rock forming elements ranging from carbon through zirconium in atomic number therefore it is capable of constraining the petrology of the measured samples in particular the pathfinder data are the first in situ measurements of martian rocks and may be compared with previous remote sensing measurements as well as with the compositions of snc meteorites pathfinder soil and rock sample abundances from the alpha proton and x ray modes have been quantified the abundances suggest that 1 the rocks are covered with various amounts of soil 2 the soil free rocks on a volatile free basis have some element ratios similar to mars meteorites yet have different bulk chemistry indicative of more evolved rocks with higher silica abundances 3 the carbon and nitrogen contents are below detection limits and 4 the alpha mode oxygen reveals excess amounts of oxygen in some samples which is indicative of sample bound water contained within minerals or glasses in samples

the surface of syrtis major composition of the volcanic substrate and mixing with altered dust and soil syrtis major is an old low relief volcanic plateau near the equatorial regions of mars it is a persistent low albedo feature on the planet and is thought to contain a high abundance of exposed bedrock and or locally derived surface material and debris spatially resolved variations in surface spectral properties and therefore composition are investigated with data from the imaging spectrometer for mars ism instrument ism obtained 128 wavelength channel spectra from 0 76 to 3 16 m for contiguous pixels approximately 22 22 km in size across much of the plateau the value and spatial distribution of four primary spectral variables albedo continuum slope wavelength of the ferric ferrous band minimum area of the ferric ferrous absorption are mapped and coregistered to viking digital photomosaics analysis of these maps shows that although there is a high degree of overall spectral variability on the plateau the key indicators of mafic mineralogy are relatively homogeneous detailed examination of reflectance spectra from representative areas across the plateau indicate the volcanic surface is dominated by augite bearing basalts and the pyroxene composition in the basalts is estimated to be 0 275 0 075 ca ca fe mg and 0 3 0 1 fe fe ca mg additional mineral components may include olivine feldspar and glass most of the spectral variability on the plateau is interpreted to result from mixing of volcanic bedrock and or locally derived surface material and debris with highly altered dust and soil in western syrtis major the altered material is a transient component on the surface or occurs in large spatially coherent patches e g crater rims in eastern syrtis major it is apparent that the dust components are firmly fixed to the basaltic substrate as a stable oxide rind or coating

athena mimos ii mossbauer spectrometer investigation 1 mossbauer spectroscopy is a powerful tool for quantitative mineralogical analysis of fe bearing materials the miniature mossbauer spectrometer mimos ii is a component of the athena science payload launched to mars in 2003 on both mars exploration rover missions the instrument has two major components 1 a rover based electronics board that contains power supplies a dedicated central processing unit memory and associated support electronics and 2 a sensor head that is mounted at the end of the instrument deployment device idd for placement of the instrument in physical contact with soil and rock the velocity transducer operates at a nominal frequency of 25 hz and is equipped with two 57co rh mossbauer sources the reference source 5 mci landed intensity reference target fe2o3 plus fe0 and pin diode detector are configured in transmission geometry and are internal to the instrument and used for its calibration the analysis mossbauer source 150 mci landed intensity irradiates martian surface materials with a beam diameter of 1 4 cm the backscatter radiation is measured by four pin diode detectors physical contact with surface materials is sensed with a switch activated contact plate the contact plate and reference target are instrumented with temperature sensors assuming 18 fe for martian surface materials experiment time is 6 12 hours during the night for quality spectra i e good counting statistics 1 2 hours is sufficient to identify and quantify the most abundant fe bearing phases data stored internal to the instrument for selectable return to earth include mossbauer and pulse height analysis spectra 512 and 256 channels respectively for each of the five detectors in up to 13 temperature intervals 65 mossbauer spectra engineering data for the velocity transducer and temperature measurements the total data volume is 150 kb the mass and power consumption are 500 g 400 g for the sensor head and 2 w respectively the scientific measurement objectives of the mossbauer investigation are to obtain for rock soil and dust 1 the mineralogical identification of iron bearing phases e g oxides silicates sulfides sulfates and carbonates 2 the quantitative measurement of the distribution of iron among these iron bearing phases e g the relative proportions of iron in olivine pyroxenes ilmenite and magnetite in a basalt 3 the quantitative measurement of the distribution of iron among its oxidation states e g fe2 fe3 and fe6 and 4 the characterization of the size distribution of magnetic particles special geologic targets of the mossbauer investigation are dust collected by the athena magnets and interior rock and soil surfaces exposed by the athena rock abrasion tool and by trenching with rover wheels