did a katian large igneous province trigger the late ordovician glaciation a hypothesis tested with a carbon cycle model abstract the ordovician is known as a period with high temperatures and high sea levels and a cooling event at the end of the period leading to the hirnantian glaciation and the first of the big five mass extinctions of marine life the cause of this cooling event remains unclear several authors correlate it with a drop in atmospheric p co 2 to a threshold permitting the ice accumulation on the gondwana supercontinent however what are the reasons of the atmospheric p co 2 decrease here we follow the hypothesis initiated by barnes 2004 that an ordovician superplume event occurred during the middle to late ordovician such an event would not only have a large impact on the ordovician biodiversification barnes 2004 but it would also be responsible for the climatic upheaval during the late ordovician by the emplacement of a low latitudinal continental basaltic province that had an impact on the atmospheric p co 2 there is no direct evidence of a superplume event or of basaltic traps and the present study is therefore a hypothetical modelling approach where we demonstrate with a numerical box model including carbon alkalinity and phosphorus cycles coupled with a 1d climate model energy balance model ebm francois and walker 1992 that such a scenario allows to explain both the mid ashgill katian global warming event known as the boda event fortey and cocks 2005 and the subsequent late ordovician hirnantian glaciation because silicate weathering is enhanced upon warm and wet climate we try to constrain the size and the latitudinal emplacement of the basaltic province leading to a sufficient consumption of atmospheric p co 2 to the threshold proposed by herrmann et al 2004 a b to initiate a glaciation on gondwana

paired carbon isotopic analysis of ordovician bulk carbonate δ 13 c carb and organic matter δ 13 c org spanning the great ordovician biodiversification event abstract paired measurements of bulk carbonate 13ccarb organic matter 13corg and their difference 13c can be used to estimate changes in isotopic fractionation through time as a function of o2 co2 in the atmosphere however because local scale processes can also affect 13c it is essential to compare sections from widely separated water masses here we present new 13corg data from ordovician carbonate rocks from the great basin oklahoma and appalachian basin and compare with published 13ccarb records from these sections and paired 13c values from other carbonate successions around north america these new data complement previous studies that focused on upper ordovician 13ccarb excursions and now provide a composite ordovician 13corg record new lower ordovician tremadocian stage 13corg data range from ca 26 to 28 decreasing throughout the lower middle ordovician floian dapingian stages to ca 29 to 31 13corg values remain at their lowest throughout the sandbian and are similar to other published upper ordovician sandbian katian 13corg data from north america 13c values from well preserved intervals generally vary between 26 to 28 throughout the lower to middle ordovician tremadocian to early darriwilian but increase to 31 during the mid late darriwilian and mid sandbian similar to published data from younger late ordovician positive 13c excursions known as the guttenberg gice and hirnantian hice events the overall 13c trend shows a 3 increase throughout the early middle ordovician and coincides with a previously interpreted period of ocean cooling and some of the earliest pulses of global biodiversity of marine invertebrates and planktonic organisms modeling studies predict that pco2 decreased during this time suggesting that the effect of pco2 on 13c may have been overwhelmed by other controls such as an in increase in po2 or a higher o2 co2 ratio during this biodiversification event

carbon isotopes and event stratigraphy near the ordovician silurian boundary yichang south china abstract the organic carbon isotope data through the unweathered ordovician silurian boundary strata at the wangjiawan riverside section which is c 180 m southeast of the wangjiawan north section the gssp for the base of the hirnantian stage upper ordovician show that a positive 13 c org excursion begins just below the base of the hirnantian stage and peaks in the lower part of the n extraordinarius biozone this is followed by an interval of slightly reduced 13 c values and a second peak of 2 above pre hirnantian values which occurs in the lower part of the n persculptus biozone upper hirnantian the peaks in 13 c org values can be correlated well with episodes of glacial expansion described from africa and peri gondwanan europe evidence from sedimentological faunal and geochemical data from south china as well as the evidence of glacial sediments in north africa all suggests a short lived glaciation of 1 ma in the ordovician south pole region consisting of at least two major pulses the first phase of gradual glacial expansion began just before the hirnantian epoch and the second phase ended with rapid melting in the late hirnantian early n persculptus biozone

paleostress and statistical analysis using quartz veins from mineralized and non mineralized zones application for exploration targeting abstract quartz vein orientations thickness and spacing data are analyzed from 10 transects each of mineralized and non mineralized zones of gadag region which is a gold bearing terrain within the dharwar craton southern india paleostress analysis reveals that the veins emplaced when fluid pressure pf varied from pf 2 intermediate principle stress to pf 2 to pf

carbon and oxygen isotope stratigraphy of the lower mississippian kinderhookian lower osagean western united states implications for seawater chemistry and glaciation a positive carbon isotope 1 3 c excursion has been recognized in upper kinderhookian and early osagean carbonates in three sections in southeast idaho and nevada the oldest 1 3 c peak 7 is dated to the isostichaconodont zone and a younger peak occurs in the typicus zone the shifts are recorded in a range of carbonate lithofacies representing various water depths along the shelf lithofacies sampled for 1 3 c and 1 8 o at the samaria mountain section in southeast idaho record the shallowest water conditions indicated by cross bedded skeletal and peloidal grainstones the deepest water conditions are present in the pahranagat range section in eastern nevada which consists mainly of bioturbated lime mudstone and skeletal wackestone the 1 3 c values from these widely separated sedimentary basins show a consistent trend that correlates with early mississippian curves generated from brachiopod calcite in western europe and the midcontinent of north america as well as dolomites in utah and wyoming 1 8 o values become more positive up section generally paralleling the positive trend in 1 3 c during the late kinderhookian no subaerial exposure surfaces are recognized in the sections examined in southeast idaho and nevada and at least the 1 3 c trends are interpreted as primary seawater fluctuations sea level changes occurred near the beginning of the late kinderhookian 1 3 c shift early to middle parts of the isosticha zone and within the peak of the 1 3 c excursion kinderhookian osagean boundary although tectonic changes associated with the antler orogeny have likely modified the eustatic signature

the importance of small scale faulting in regional extension a recurring observation in many studies of extensional basins has been that the amount of extension visible on normal faults for example on seismic reflection profiles is significantly less than the amount of extension indicated by crustal thickness and thermal subsidence1 5 one mechanism suggested to account for this discrepancy is small scale faulting with offsets too small to be resolved seismically6 7 but earthquake studies8 10 indicate that small faults are responsible for only a small fraction of the total seismic moment in an active area scholz and cowie11 have recently attempted to extend this approach to the total strain at the end of a finite deformation interval by combining scaling laws describing the distributions of fault lengths and displacements here we present fault displacement data that directly conflict with scholz and cowie s conclusions and imply that up to 40 of the extension may be missed by summing fault offsets on basin profiles the fault population at the end of a long deformation interval may differ substantially from that responsible for the earthquake population at any one time

vein deflections and thickness variations of epithermal quartz veins as indicators of fracture coalescence epithermal quartz veins at the broken hills gold deposit new zealand strike n s and dip steeply westward small changes in the orientations of the three main lodes and associated mesoscopic veins define deflection lines that rake steeply in the vein plane a method of constructing the opening vector from the three dimensional geometry of a vein deflection is presented the resulting vectors plunge steeply and are at low angles to the main veins and the deflection lines indicating a large component of normal dip slip shear during the opening of these veins vein thickness distributions are power law with similar fractal dimensions to previously reported values for non stratabound vein arrays the vein system at broken hills developed by linking of isolated extension dominated shear veins with shear dominated veins generating sub vertical and sub horizontal fluid flow pathways

early silurian wenlockian δ13c profiles from the cape phillips formation arctic canada and their relation to biotic events geochemical data from the cape phillips formation arctic canada are examined in association with three silurian biotic crises in the graptolite community the early wenlockian ireviken mid wenlockian cyrtograptus lundgreni and end wenlockian colonograptus ludensis extinction events positive 13corg excursions are associated with the ireviken and c lundgreni events but not the co ludensis event the ireviken and c lundgreni excursions are recognized worldwide and are herein interpreted to be the result of carbonate weathering in response to eustatic sea level drop the c lundgreni excursion is of greater magnitude in the more proximal basin margin section at abbott river cornwallis island and is explained by the amplification of a more strongly positive 13c signature in shallower parts of an epeiric basin during increased exposure and weathering of the carbonate shelf excursion c5 within the c praedeubeli c deubeli zone is also of regional significance as it occurs in both the abbott r

lithofacies and depositional mechanisms of the ordovician silurian wufeng longmaxi organic rich shales in the upper yangtze area southern china the ordovician silurian organic rich shales in the wufeng and longmaxi formations are widespread in southern china and are the most important shale gas producers in china the shales display varying total organic carbon content ranging from 0 2 to 6 and are composed of black siliceous mudstone shelly limestone siliceous clay rich mudstone gray silty shaly interlaminated mudstone gray argillaceous mudstone and calcareous or dolomitic mudstone detailed stratigraphic correlation of these formations was achieved and a high resolution sequence stratigraphy was constructed based on the integration of well log data mineralogical geochemical and petrophysical analyses the wufeng formation and the guanyinqiao bed were interpreted to be a condensed section with four cycles of sea level fluctuation the longmaxi formation consists of three members the long 1 member was interpreted to be a third order depositional sequence that can be subdivided into a transgressive systems tract an early highstand systems tract and a late highstand systems tract within the constructed isochronal stratigraphic framework the characteristics and genetic mechanism of different shale lithofacies were studied the deposition of black siliceous mudstone of high total organic carbon in the wufeng formation and the long 1 transgressive systems tract was likely influenced by volcanic activity the guanyinqiao shelly limestone or calcareous mudstone was associated with the ordovician silurian transition when glaciation and mass extinction took place the gray silty shaly interlaminated mudstone of moderate total organic carbon in the long 1 early highstand systems tract was the product of bottom flow intrusion the deposition of gray argillaceous mudstone and calcareous or dolomitic mudstone with low total organic carbon in the long 1 late highstand systems tract resulted from enhanced terrigenous input from peripheral uplifts the distribution pattern of different lithofacies varies greatly in the upper yangtze area and this difference is a result of dissimilar sediment provenances and variable hydraulic restriction levels that were controlled by basin geometry a better understanding of the distribution pattern and depositional history of the wufeng and longmaxi formations might provide guidance for future profitable shale gas exploration

populations of faults and fault displacements and their effects on estimates of fault related regional extension abstract measured populations of fault displacements derived from regional seismic oilfield seismic coalmine plans and outcrop data show a power law distribution with exponents s of 0 45 to 0 95 for singleline samples across an array of faults the more negative values indicate relatively larger numbers of smaller faults an expression for a population of active faults derived from the gutenberg richter magnitude frequency relation for earthquakes is log n a b d log d where d maximum displacement of a fault n number of faults of maximum displacement d or greater and b d 1 0 and has the same value as b for the corresponding earthquake population populations of dead faults existing at the end of a tectonic episode have been numerically derived using a fault growth model and satisfy the relation log n a e log d where e has a value between 1 6 and 2 0 numerically derived populations of fault displacements in a dead fault population have slopes of s where s e 1 the contribution of an individual fault to the regional strain varies with the lifetime seismic moment of the fault and is proportional to d 2 estimation of fault related extension by summing heaves on faults of a limited size range is valid only if the measured size range of faults accommodates most of the extension correction can be made if the s value of the fault displacement population is known

quantifying the effects of vein mineralogy thickness and orientation on the strength of intact veined rock abstract the presence of veins in the rock matrix influences the behaviour of a rock this results in a behaviour that is distinct from intact rock without any veins and structure and from jointed rock in this context intact veined rock is a rock containing mineral veins and no joints this paper investigates the influence of vein mineralogy thickness and orientation on the strength of intact veined andesite from the el teniente mine this investigation has focused on a comprehensive vein characterization and analyses of the results of triaxial compression experiments in a comprehensive laboratory investigation it was demonstrated that the peak strength of intact veined rock specimens was strongly influenced by the orientations of individual veins whereby vein mineralogy and thickness had a lesser role a further analysis of the mineral composition of the intact veined rock specimens following a series of triaxial tests revealed a more dominant influence of the mineral composition of the veins it was shown that rock specimens dominated by veins containing 4 attained significantly lower peak strengths than specimens where the average content of hard minerals exceeded 60 of the vein infill analyses of the mobilised shear strength of individual veins demonstrated a strong correlation between the presence of hard minerals and the strength of individual veins in the rock specimens this relationship was stronger when the vein volumetric content of hard minerals was

calibrating the late ordovician glaciation and mass extinction by the eccentricity cycles of earth s orbit a process based sedimentological analysis of upper ordovician glacial marine rocks in africa suggests that full glaciation of the continental shelf started in the late extraordinarius zone of the hirnantian two cycles of ice sheet growth are represented during full glaciation initial terrestrial ice sheet growth in the early extraordinarius zone influenced the first event of the late ordovician mass extinction retreat of the ice sheet from the shelf ended by the persculptus zone when the second event of the late ordovician mass extinction began eccentricity controlled ice sheet growth is assumed periodicity 0 1 m y hence two cycles of full glaciation lasted 0 2 m y the duration of the extraordinarius zone is estimated as 0 5 m y therefore the minimum duration of the first extinction event was 0 3 m y

carbon isotope δ13ccarb stratigraphy of the lower middle ordovician tremadocian darriwilian in the great basin western united states implications for global correlation abstract new stable carbon isotope data 13ccarb from lower middle ordovician tremadocian to darriwilian carbonate mudstone and wackestone rocks of the pogonip group are presented from two sections in the great basin region usa shingle pass east central nevada and the ibex area western utah the pogonip group is a succession of mixed carbonate and siliciclastic rocks that accumulated on a carbonate ramp under normal marine conditions during the late cambrian furongian to middle ordovician darriwilian the shingle pass and ibex area sections have been previously studied for their conodont biostratigraphy and contain a north american midcontinent conodont fauna that range from the cordylodus intermedius zone uppermost cambrian to the phragmodus polonicus zone darriwilian the 13c trend has four distinct characteristics recognized in both great basin sections 1 a drop in 13c from 1 at the base of the ordovician tremadocian to 0 7 2 a 1 to 2 positive 13c shift in the uppermost rossodus manitouensis zone during the late tremadocian 3 a gradual 13c increase from 2 to ca 0 during the end of the early ordovician floian and 4 a steady 13c decrease from 0 to 4 to 5 during middle ordovician dapingian darriwilian in the lower ordovician 13c trends reported here from the great basin are not consistent with a causal mechanism involving sea level change and the migration of isotopically distinct water bodies instead these lower ordovician isotope data most likely reflect primary seawater chemistry and changes in 13c on a global scale this interpretation is supported by the excellent correlation of 13c in the lower ordovician to other 13c trends reported from the sections in the argentine precordillera la silla and san juan formations and in western newfoundland st george and table head groups these correlations using 13c are consistent with published biostratigraphic data and provide an integrated and high resolution chemo biostratigraphic framework for the lower ordovician sedimentary record of the laurentian margin the middle ordovician portion of the 13c curves in the great basin represented by the kanosh and lehman formations shows significant isotopic depletion relative to the section in argentina thus although there is some indication that minima and maxima in the middle ordovician curves can be correlated the great basin sections show clear evidence of overprinting by local variables related to both diagenesis dolomitization and platform restriction

a fractal relationship between vein thickness and gold grade in drill core from la codosera spain analysis of quartz vein thicknesses and gold grades in drill core from western spain indicates that both approximate a power law distribution suggesting an underlying fractal relationship log log plots of cumulative frequency n against vein thickness t show systematic changes in relation to gold grade the exponent d in a power law of the form n c t super d is lower for higher gold grades indicating that a greater proportion of the dilation is taking place on the thicker veins which are interpreted as providing interconnected conduits for gold bearing fluids thus monitoring the vein thickness distribution may provide a means of discriminating mineralized and barren structures in vein hosted mineral deposits

upper ordovician mohawkian carbon isotope δ13c stratigraphy in eastern and central north america regional expression of a perturbation of the global carbon cycle abstract the guttenberg carbon isotope excursion gice documented from eastern north america demonstrates the effects that regional geochemically distinct water masses upwelling and ocean circulation have on the carbon isotope record from carbonate platforms late turinian chatfieldian carbonates from oklahoma kentucky virginia and west virginia record a positive carbon isotope excursion 3 0 the gice excursion the gice excursion has relations to established biostratigraphy beginning in the north american midcontinent phragmodus undatus conodont zone and continuing through the plectodina tenuis zone sequence and event stratigraphy previously established models for positive carbon isotope shifts on carbonate platforms have been tested during the gice excursion where geochemically distinct water masses are defined for the upper ordovician a major eustatic sea level rise before the gice promoted a greater exchange of open ocean waters onto the carbonate platform of laurentia however restricted or sluggish circulation and exchange between water masses within the epeiric seas and the adjacent iapetus ocean were still apparent local variations documented in the gice excursion are directly related to upwelling of nutrient rich isotopically light waters increased primary productivity and the subsequent organic carbon production and burial

the climatic significance of late ordovician early silurian black shales the ordovician silurian transition approximate to 455 430ma is characterized by repeated climatic perturbations concomitant with major changes in the global oceanic redox state best exemplified by the periodic deposition of black shales the relationship between the climatic evolution and the oceanic redox cycles however remains largely debated here using an ocean atmosphere general circulation model accounting for ocean biogeochemistry mitgcm we investigate the mechanisms responsible for the burial of organic carbon immediately before during and right after the latest ordovician hirnantian 445 444ma glacial peak our results are compared with recent sedimentological and geochemical data we show that the late katian time slice approximate to 445ma typified by the deposition of black shales at tropical latitudes represents an unperturbed oceanic state with regional organic carbon burial driven by the surface primary productivity during the hirnantian our experiments predict a global oxygenation event in agreement with the disappearance of the black shales in the sedimentary record this suggests that deep water burial of organic matter may not be a tenable triggering factor for the positive carbon excursion reported at that time our simulations indicate that the perturbation of the ocean circulation induced by the release of freshwater in the context of the post hirnantian deglaciation does not sustain over sufficiently long geological periods to cause the rhuddanian approximate to 444ma oceanic anoxic event input of nutrients to the ocean through increased continental weathering and the leaching of newly exposed glaciogenic sediments may instead constitute the dominant control on the spread of anoxia in the early silurian

outcrops as guides to subsurface natural fractures example from the nikanassin formation tight gas sandstone grande cache alberta foothills canada abstract outcrop studies are essential for understanding subsurface fractures because some key attributes such as length and height distribution cannot be measured using wellbores discrepancies between outcrop and subsurface fracture attributes arise because loading paths due to burial exhumation and thermal paths differ consequently even where rock type and structural setting are close matches differences may exist in mechanical properties and fracture growth here we investigate petrologic criteria and disseminated arrays of quartz filled microfractures as tools for comparing and contrasting fractures in outcrop with those as sampled by core for tight gas sandstones fracture cements are key diagnostic criteria for proving correspondence between outcrop and core we offer guidelines on selecting suitable outcrop analogs that differ markedly from current practice our illustration uses outcrops and core samples of late jurassic to early cretaceous nikanassin formation a tight gas sandstone but aspects of the outcrop vetting procedure can be applied to other rock types in some core and outcrops nikanassin formation fractures contain quartz and ankerite cement assemblages crack seal and rind textures and aperture size distributions that show that the outcrop and subsurface localities we examined share the same fracture stratigraphy and similar diagenesis these outcrops can thus be used to measure attributes including those that are unlikely to be captured in core such as fracture height and length distributions relative and absolute fracture intensity with structural position and degree of fill by synkinematic cement in our example absolute fracture intensity and distribution of postkinematic carbonate cements are site specific and differ between outcrop and core but in ways that can be quantified

scaling of fault displacements from the badajoz cordoba shear zone sw spain faulting occurs over a large range of scale parts of which are sampled by various techniques e g microscopy outcrop measurement mapping seismic reflection and other forms of remote sensing use of a single technique to measure displacement or strain will not sample faults at all scales and hence will give a biased estimate in order to assess this bias a knowledge of the distribution over all scales is needed many samples of fault displacement appear to follow a power law distribution with departures which can be attributed to sampling effects the number of faults with a displacement u is given by n u cu d the power law distribution of displacement is consistent with similar distributions of other fault parameters and earthquake magnitudes when sampling along a line e g a bedding trace on a map or section a self similar fault population would have d 1 whereas self affine geometries yield d 1 displacement and extension are dominated by small faults when d 1 and by large faults when d 1 when sampling over areas or volumes these critical values are 2 and 3 respectively a set of strike slip faults from the badajoz cordoba shear zone spain were sampled at two different scales using 1 50000 maps and outcrop measurements displacement ranges over 6 orders of magnitude these and other fault populations typically have d ranging from 0 6 to 1 5 the power law relationship may be integrated to yield estimates of the displacement or extension for faults which lie beyond the resolution of the sampling system for example a knowledge of d allows the extension measured on a map or seismic section to be corrected for faults whose displacement is below the resolution of the survey based on an overall estimate of d 0 9 for the badajoz cordoba data only some 40 of the extension would be recorded by map scale faults a corrected extension of 41 along the shear zone is estimated which if typical for the entire 300 km zone represents some 87 km of along strike extension thus work suggests that significant displacement occurs on faults which are too small to be interpreted from conventional seismic profiles and geological maps

first record of the hirnantian upper ordovician δ13c excursion in the north american midcontinent and its regional implications the most prominent of the two major global delta c 13 excursions in the ordovician the hirnantian delta c 13 excursion hice which is previously recorded from the uppermost ordovician in a few sections in nevada quebec arctic canada baltoscandia scotland and china is documented for the first time from the north american midcontinent samples through the girardeau limestone and leemon formation in missouri and illinois show elevated delta c 13 values of 4 parts per thousand to 5 parts per thousand although not determined precisely the beginning of the hice is likely to be in the upper part of the orchard creek shale and it ends in the upper leemon formation being extraordinarily useful chronostratigraphically the presence of the hice makes it possible to provide a firm dating of the study interval whose age has long been controversial comparison between the study sections and coeval hice sequences in north america and europe show striking similarities especially in sea level history indicating that major local lowstands reflect eustatic sea level changes a comparison with hirnantian diamictite successions in north and south africa and argentina suggests that these lowstands correspond to two major gondwanan glacial episodes less

sponge dominated offshore benthic ecosystems across south china in the aftermath of the end ordovician mass extinction abstract offshore benthic communities were sparse after the end ordovician mass extinction the recent discovery of diverse abundant sponges in south eastern china anhui and zhejiang provinces that flourished during the hirnantian late ordovician post extinction interval raises questions over the extent and ecological significance of the sponge community at that time this paper dramatically expands the scale of the hirnantian sponge fauna within south china with seven new occurrences across 2000 km these occurrences cross the ordovician silurian boundary interval in the marginal and submerged platform areas of the yangtze sea in jiangsu hubei hunan chongqing and sichuan provinces in condensed sections platform margin facies the occurrences are normally represented by extensive spiculite layers but several sites yield entire exceptionally preserved body fossils at ganggangshan near nanjing jiangsu province such preservation is abundant the new occurrences are combined with palaeogeographic and tectonic reconstructions to produce a model for the distribution and preservation of the sponge fauna we argue that the exceptional preservation was due largely to nepheloid layers that were generated during rapid post glacial transgression that flooded the weathered land surface of the uplifted cathaysia block nepheloid layer collapse led to rapid deposition of suspended sediment within the deeper parts of the intra plate restricted basin and on adjacent platform margins and slopes the suspended sediment influx also introduced abundant nutrients to the water column as indicated by a significant 13c excursion during the sponge bearing mudstone interval at ganggangshan the combined sponge assemblage was dominant over large areas of the hirnantian offshore sea floor across south china we predict that similar occurrences with exceptional preservation will also be found in other continental blocks abundant articulated sponges may be encountered particularly in restricted basin successions containing rapidly deposited graptolitic mudstones near the ordovician silurian boundary

paired isotope records of carbonate and organic matter from the middle ordovician of argentina intrabasinal variation and effects of the marine chemocline abstract we investigate the expression of the middle darriwilian isotope carbon excursion mdice across marine shelf environments in the argentine precordillera previous work identified the mdice in the las chacritas formation in argentina but did not recognize the expression of the mdice in time equivalent strata of the deeper water las aguaditas formation albanesi et al 2013 palaeogeography palaeoclimatology palaeoecology v 398 p 48 66 recent biostratigraphic investigations of these units have for the first time provided the opportunity for high resolution correlation which suggest that the mdice or at least the initiation of the mdice should be observed in both the las chacritas and las aguaditas formations here we present new paired carbon isotope data of carbonate and organic carbon from the las chacritas and las aguaditas formations we identify a 2 positive shift in the isotopic composition of marine carbonate in the las chacritas formation whereas values abruptly fall to

amount of extension on small faults an example from the viking graben extension estimates based on palinspastic restoration of only the largest faults in a deformed terrane may be significantly deficient due to neglect of small faults i e unsampled faults most of which have smaller displacements than do sampled faults small faults individually account for little extension but there may be large numbers of them the cumulative extension on small faults can be calculated from the fractal size distributions of fault displacements independent extension estimates support the inference from fault population statistics that small faults account for significant amounts of extension for example restorations of mesozoic faults interpreted from seismic reflection profiles across the viking graben in the north sea yield extension estimates that are only 40 75 of independent estimates the fractal size distribution of fault displacements in the viking graben is consistent with the hypothesis that the remaining 25 60 of extension resulted from displacements on small faults

sequestration of 12c in the deep ocean during the early wenlock silurian positive carbon isotope excursion abstract marine carbonates from three biostratigraphically well dated silurian sections from the mid continent of north america were analyzed for carbon isotopic 13 c carb study the early wenlock positive carbon isotope excursion ireviken excursion is recorded in three sections from tennessee iowa and ohio with values of 4 5 this global shift in the carbon isotopic ratio of marine waters began during a protracted extinction event ireviken event that spanned the llandovery wenlock boundary although several oceanographic models have been developed to account for the coincident changes in lithology biology and carbon isotope stratigraphy during this interval of the silurian their proposed causal connections among glaciation oceanography primary productivity and the global carbon cycle remain a matter of debate this investigation provides carbon isotopic and lithologic evidence that the ireviken excursion occurred during a time of relatively oligotrophic conditions a third order transgressive regressive cycle and increased carbonate production throughout the mid continent of north america the ireviken excursion is recorded in relatively pure carbonate sequences and is immediately preceded by a significant unconformity in each of the measured sections it is proposed that the ireviken excursion was the product of sequestration and burial of 12 c in deep water as a result of altered deep ocean circulation

hirnantian strata identified in major intracratonic basins of central north america implications for uppermost ordovician stratigraphy carbon isotopes are analyzed for the first time from the ordovician silurian boundary interval in the williston and hudson bay basins of manitoba revealing a prominent positive excursion the nature of this excursion and its co occurrence with the appearance of the ozarkodina hassi conodont zone and a distinctive coral dominated macrofauna indicate that this is the upper portion metabolograptus persculptus graptolite zone of the globally recognized hirnantian isotopic carbon excursion hice as a result the ordovician silurian boundary is placed at a higher position than previously thought at the disconformable stonewall fisher branch formational boundary in the williston basin and probably the port nelson severn river formational boundary in the hudson bay basin disconformities within sections suggest periods of nondeposition due to subaerial exposure as sea level fluctuated during the late ordovician glaciation latest ordovician hirnantian deposition was far more widespread on the laurent

the late ordovician mass extinction abstract near the end of the late ordovician in the first of five mass extinctions in the phanerozoic about 85 of marine species died the cause was a brief glacial interval that produced two pulses of extinction the first pulse was at the beginning of the glaciation when sea level decline drained epicontinental seaways produced a harsh climate in low and mid latitudes and initiated active deep oceanic currents that aerated the deep oceans and brought nutrients and possibly toxic material up from oceanic depths following that initial pulse of extinction surviving faunas adapted to the new ecologic setting the glaciation ended suddenly and as sea level rose the climate moderated and oceanic circulation stagnated another pulse of extinction occurred the second extinction marked the end of a long interval of ecologic stasis an ecologic evolutionary unit recovery from the event took several million years but the resulting fauna had ecologic patterns similar to the fauna that had become e

changes in fault displacement populations correlated to linkage between faults in carboniferous strata exposed at the western margin of the southern appalachian u s a fold thrust belt mesoscopic faults accommodated strains as the cumberland plateau thrust sheet moved 1 km wnw on a sub horizontal detachment these faults are confined to a layer 75 m thick above the detachment in the upper part of this 75 m thick layer a laterally persistent coal seam separates two stratigraphic units subjected to different amounts of sub horizontal elongation distinct sets of mesoscopic faults that cut bedding at high angles and have normal offsets accommodate the strains in each unit below the coal seam a sample line 500 m long intersects 504 faults a plot of log n size rank vs log d dip separation in mm for these faults is linear suggesting that a scaling law n ad c holds for this population least squares regression gives c 0 8 and log10 a 3 1 above the coal seam a sample line 250 m long intersects 745 faults a plot of log n vs log d for these faults has two distinct linear trends faults with separations 1 25 m yield a scaling law n ad c with c 0 5 and log10 a 2 9 seventeen faults with separations d 1 25 m define a second linear segment n a d c with c 1 8 and log10 a 6 9 the break in slope at d 1 25 m corresponds to faults with heights of 30 m roughly equal to the thickness of the faulted strata faults here with d 1 25 m and d 1 25 m which exhibit different scaling characteristics are respectively analogous to faults within and those that extend across the brittle crust in regional studies comparing the two displacement populations described here small offset faults make a proportionally smaller contribution to the total strain in the larger strain setting this pattern which is observed elsewhere suggests that fault systems within individual layers exhibit different scaling characteristics at different stages in their history this contribution argues that fault linkage is the key to such changes in fault scaling behavior it is a mesoscopic to macroscopic structural change that alters the subsequent development of faults fault linkage like fault size or sampling dimension should be considered in examinations of fault scaling laws

macroevolutionary transition in crinoids following the late ordovician extinction event ordovician to early silurian abstract the end katian late ordovician crinoid mass extinction triggered the change from the early to the middle paleozoic crinoid evolutionary faunas cefs this was a change from diplobathrid camerate disparid hybocrinid dominated faunas to faunas dominated by monobathrid camerate cladid and flexible crinoids all clades suffered extinctions at the end katian event but diplobathrid camerates disparids and hybocrinids suffered higher rates of extinction the primary amount of diversification occurred in clades that would become dominant during the silurian however the formation of the characteristic middle paleozoic cef was protracted beyond the late ordovician extinction event monobathrid camerates and flexibles diversified through the llandovery but both dendrocrinid and cyathocrinid cladids did not diversify until later monobathrid camerate genera and families diversified the flexible diversification was largely at the genus level cyathocrine diversification was largely among families and dendrocrinids did not diversify significantly until after the llandovery overall disparity decreased during the end katian extinction by reducing the disparity within each clade disparity remained fairly constant during the hirnantian but increased significantly during the llandovery by both increasing disparity within clades and expanding the morphospace of the disparids due to the radiation of families with new morphologies north america was the biogeographic center of origination for the families that survived to become dominant silurian clades

the end ordovician glaciation and the hirnantian stage a global review and questions about late ordovician event stratigraphy abstract this paper proposes a global review of hirnantian event stratigraphy the hirnantian gssp in south china is tentatively correlated with latest ordovician strata from the peri gondwanan glacial regions problems of biostratigraphical correlation are highlighted at a worldwide scale the major biostratigraphically useful fossil groups graptolites chitinozoans brachiopods conodonts acritarchs are analysed and their limits for global correlation of the uppermost ordovician are discussed palaeobiogeographical disparities are invoked as the primary cause of the difficulty in establishing an effective late ordovician global biostratigraphical scheme as an alternative correlative tool the hice hirnantian isotopic curve excursion event is often put forward in the literature however carbon isotope chemostratigraphy shows like biostratigraphy some limits to the present state of knowledge no good independent biostratigraphical control of the hice exists in both shallow carbonate deposits and deeper shaly ones recent studies have also demonstrated inconsistencies between carbon isotopic signals obtained from organic 13corg and inorganic 13ccarb carbon species further complicating the use of the hice as an isochronous benchmark all of these difficulties for hirnantian event stratigraphy are discussed in detail in order to enable them to be overcome in the future precise late ordovician and early silurian event stratigraphies are essential for the understanding of the mechanisms linked to the first of the big five extinctions

high resolution carbon isotopic records from the ordovician of south china links to climatic cooling and the great ordovician biodiversification event gobe abstract the great ordovician biodiversification event gobe represented the largest increase in diversity in the marine biosphere during the phanerozoic eon yet its causes and consequences remain poorly understood patterns of isotopic variation in high resolution 13ccarb and 13corg records from a well exposed section at honghuayuan in south china may provide important insights regarding the gobe the honghuayuan isotopic profiles which can be correlated with c isotopic records from contemporaneous sections globally reveal large perturbations to the global carbon cycle during the ordovician a 8 increase in 13corg values in the floian implies a large albeit transient increase in the burial rate of organic matter during the mid early ordovician that may have contributed to climatic cooling and played an important role in triggering the gobe a 4 increase in 13ccarb and high frequency variation in 13corg in the darriwilian to sandbian suggest a second episode of elevated organic carbon burial rates accompanied by substantial instability in the global carbon cycle during the late middle and early late ordovician this pattern may mark the onset of climate changes culminating in the end ordovician hirnantian glaciation and mass extinction event that terminated the gobe

trace fossils in the aftermath of mass extinction events abstract ichnology has great potential to advance our understanding of mass extinction events and yet is currently an underutilized resource in such studies here we review published ichnological studies for the ordovician silurian permian triassic and cretaceous tertiary extinction recovery intervals in addition new information regarding the triassic jurassic ichnological record from england austria and the western usa is presented trace fossils provide important information on the ecological response of the benthic community at such times in the immediate post extinction aftermath the ichnodiversity burrow size depth of bioturbation and ichnofabric index of the sediments are all much reduced there is an increase in all these parameters through the post extinction recovery period in some cases the stepwise reappearance of certain distinctive ichnotaxa e g diplocraterion rhizocorallium and thalassinoides may be of some stratigraphic use evidence from permian triassic studies indicates that recovery took longer at low tropical palaeolatitudes than mid high palaeolatitudes trace fossils also provide important information on palaeoenvironmental change through the extinction recovery interval the application of ichnology to mass extinction studies is in its infancy but should prove a valuable tool in future research

high resolution stable isotope stratigraphy of the upper cambrian and ordovician in the argentine precordillera carbon isotope excursions and correlations abstract we report the occurrence of important carbon isotope excursions in early paleozoic formations of the eastern and central argentine precordillera the steptoean positive isotope carbon excursion spice is known from north america kazakhstan south china australia and south america and the negative isotope carbon excursion snice has been described for the first time in south america we report here the record of the spice and snice in a single section in the eastern precordillera in the central precordillera a minor middle darriwilian positive carbon isotope excursion mdice and a late sandbian positive isotope carbon excursion the gice 3 c bicornis biozone are reported from two sections one pre gice positive carbon isotope excursion sandbian sa1 n gracilis biozone in the central precordillera with a 13c peak of 2 is perhaps equivalent to the positive spechts ferry 13c excursion of north america a positive 13c excursion 6 n persculptus biozone recorded at the base of the late hirnantian la chilca formation probably corresponds to hice these carbon isotope excursions resulted from more than one factor where paleoceanographic events probably played a major role a sea level fall and vigorous fluctuations in the steptoean spice b sea level rise in the sunwaptan snice c important transgression in the sandbian pre gice and gice and d sea level fall in the late hirnantian hice in the darriwilian and sandbian stages organic burial has led to a large 12c sequestration in the deep anoxic ocean with saline bottom water recorded by the graptoliferous black shales of the gualcamayo and los azules formations in central precordillera helped the building of the mdice and gice anomalies 18o values for the upper cambrian carbonates are likely near primary isotope signals that point to progressive cooling from the spice to the snice whereas for sandbian carbonates they suggest strong temperature fluctuations the 13c peak of the gice coincides with a cooler period with temperatures warming up towards the late hirnantian to rhuddanian the upper cambrian to the middle ordovician of the precordillera recorded a decrease of seawater 87sr 86sr ratios in accordance to the global picture this decrease probably reflects the influence of widespread volcanic activity from arc terranes in low latitude settings along eastern margins of laurentia and in the argentine precordillera in the early to middle ordovician five carbonate samples from san juan gualcamayo and los azules formations yielded end values that along seven already published values seem to plot along the nd isotopic evolution trend of the iapetus ocean together the record of global upper cambrian and ordovician carbon isotope excursions in the argentine precordillera is a valuable proxy in refining early paleozoic stratigraphy establishing of regional global high resolution correlations and sea level change history in south america

millennial scale paleoclimate cycles recorded in widespread palaeozoic deeper water rhythmites of north america rhythmically interbedded limestone and shale or limestone and chert rhythmites are a common feature of many deep water phanerozoic carbonate marine deposits seventeen different palaeozoic rhythmite successions from across north america 8 studied in detail 9 studied in reconnaissance are described and summarized individual rhythmite couplets 4 20 cm thick are composed of fine grained laminated to massive detrital limestone alternating with shale or marl or laminated spiculitic chert stratigraphic and primary depositional features within rhythmites and associated facies indicates that the carbonate rich and carbonate poor interbedding is the result of repetitive changes in sediment input primary rather than due to diagenetic redistribution of calcareous material secondary the average duration of individual rhythmite couplets is calculated using spectral analysis to determine couplet thickness combined with biostratigraphically calibrated undecompacted average sediment accumulation rates the duration of rhythmite couplets from the eight well studied successions ranges between 150 and 4900 yrs with the majority lying between 1000 and 3000 yrs i e millennial scale the paucity and low diversity of skeletal and trace fossils preserved suspension laminae lack of sediment reworking and facies associations indicate rhythmite accumulation was favored by 1 deposition below storm wave base which limited reworking by currents 2 dysaerobic bottom waters which restricted bioturbation and intermixing of interbedded lithologies and 3 proximity to nearshore carbonates supplying abundant fine grained detrital carbonate these combined conditions were best met along flooded subtropical continental shelves or epeiric seas during my scale 3rd order sealevel rises the rhythmic alternation between carbonate rich and carbonate poor layers is interpreted to represent millennial scale paleoclimatic changes related to 1 wet dry climate cycles which influenced the amount of continent derived eolian and or fluvial sediment input 2 variations in offshore transport via storm generated or density currents of nearshore derived terrigenous or carbonate sediments and or 3 changes in wind driven upwelling and availability of recycled biogenic silica the various rhythmite successions accumulated under dramatically different paleoenvironment and paleogeographic conditions including active to passive tectonic settings equatorial to subtropical latitudes long term icehouse through greenhouse climatic conditions calcite versus aragonitic seas variable atmospheric co2 concentrations before and after land plant and animal evolution and across widely varying ocean basin configurations if our short term paleoclimatic interpretations for the rhythmites are correct then it is apparent that millennial scale climate changes occurred over a very wide spectrum of paleoceanographic paleogeographic paleoclimatic tectonic and biologic conditions and over time periods from the cambrian to the quaternary given this it is difficult to invoke models of internally driven thermohaline oceanic oscillations or continental ice sheet instabilities to explain their origin instead we suggest that

improved efficiency of the biological pump as a trigger for the late ordovician glaciation the first of the big five phanerozoic mass extinctions occurred in tandem with an episode of glaciation during the hirnantian age of the late ordovician the mechanism or change in the carbon cycle that promoted this glaciation thereby resulting in the extinction is still debated here we report new coupled nitrogen isotope analyses of bulk sediments and chlorophyll degradation products porphyrins from the vinini creek section vinini formation nevada usa to show that eukaryotes increasingly dominated marine export production in the lead up to the hirnantian extinction we then use these findings to evaluate changes in the carbon cycle by incorporating them into a biogeochemical model in which production is increased in response to an elevated phosphorus inventory potentially caused by enhanced continental weathering in response to the activity of land plants and or an episode of volcanism the results suggest that expanded eukaryotic algal production may have increased the community average cell size leading to higher export efficiency during the late katian the coincidence of this community shift with a large scale marine transgression increased organic carbon burial drawing down co2 and triggering the hirnantian glaciation this episode may mark an early palaeozoic strengthening of the biological pump which for a short while may have made eukaryotic algae indirect killers enhanced algal productivity during the late ordovician may have led to carbon drawdown and the inception of the hirnantian glaciation according to sediment geochemistry and carbon cycle modelling

nd isotope records of late ordovician sea level change implications for glaciation frequency and global stratigraphic correlation abstract detailed records of ice sheet advances and retreats are reconstructed for the hirnantian and katian ages of the late ordovician using nd isotopes e nd as a sea level proxy in three study sections from the western margin of laurentia two shallow water platform sections located south and north of the paleo equator and one deep water section located in a continental slope rise setting when sea level was high and paleo shorelines had migrated eastward the e nd value of seawater in the vicinity of each of the study sections shifted toward the e nd value of the eastern panthalassa ocean 4 0 by contrast when sea level was low and paleo shorelines had migrated westward the e nd value of seawater shifted toward the e nd value of the continental weathering flux from laurentia 8 5 0 2 2 mean these stratigraphic patterns of changing e nd values are interpreted to reflect the eustatic sea level fluctuations that previous studies have documented in response to gondwanan ice sheet advances and retreats thus linking the e nd sea level proxy to late ordovician global scale climate changes the e nd profiles for the two platform sections yielded similar proxy sea level curves with five cycles of oscillation recorded during the latest katian and hirnantian three additional cycles of late katian sea level change are recognized in the e nd profile of the deep water continental slope rise section the combination of e nd 13 c and graptolite biostratigraphic data facilitates a precise interregional correlation of the hirnantian age and the paleoclimate changes that took place during this interval the new correlations support previous findings that the hirnantian ice age comprised two major glacial periods separated by a minor interglacial during the early part of the metabolograptus persculptus biozone the younger glacial confined to mid m persculptus biozone time led to more extensive sea surface cooling than did the earlier one and resulted in extensive eustatic sea level drawdown and c cycle changes it records the strata most often recognized as hice the hirnantian carbon isotope excursion in sedimentary successions worldwide such as anticosti island scotland estonia siberia and south china the results of this study support and strengthen the view that glaciation predated the hirnantian age in the late ordovician and that the records of small positive 13 c excursions in katian successions from baltica and eastern north america are themselves proxy indicators of glaciation frequency and eustatic sea level changes

fluid circulation in the upper brittle crust thickness distribution hydraulic transmissivity fluid inclusion and isotopic data of veins hosted in the oligocene sandstones of the macigno formation in southern tuscany italy abstract we present structural analysis fluid inclusion data on calcite and quartz and isotopic composition of calcite forming veins occurring in the upper crustal level and hosted in oligocene sandstone in southern tuscany italy the veins have been analysed in two sites few kilometres apart along well exposed coastal cliffs and in an abandoned quarry these two sites were at a different depths at the time of the vein formation with a h 100 m structural analysis of veins provided estimations of stress ratio 2 3 1 3 driving stress ratio r pf 3 1 3 and fluid overpressure po pf 3 at the time of vein formation the estimated po is in the range of 42 103 mpa 0 24 and r 0 45 indicating that fluid pressure was higher than the intermediate principal stress at the time of veins formation the veins thickness t shows a clear power law distribution d 1 8835 and r2 0 9762 in the lowermost site coast and a negative exponential distribution a 0 6943 and r2 0 9921 in the uppermost site abandoned quarry the vein thickness distributions have been used to compute the average transmissivity of the veins in the two sites the computed transmissivity for the vein formation is 10 4 m2 s 1 with higher values attained by the veins having negative exponential thickness distribution fluid inclusions studies highlighted that in both calcite and quartz water rich inclusions with salinities of 2 2 4 3 wt nacl equiv and methane rich inclusions were coevally trapped during fluid un mixing processes thermogenic origin from thermal maturation of organic matter present in the macigno formation is proposed for methane whereas the similarity between the 18o from 14 9 to 17 4 and 13c from 0 4 to 2 4 data of representative calcite veins and the isotopic composition 18o 16 1 13c 1 0 of host rock carbonate component indicates that the fluid which formed calcite was in isotopic equilibrium with the carbonates present in the oligocene sandstones the calculated pressure temperature conditions during the formation of these inclusions are prevalently within the 40 145 mpa and 160 260 c ranges the highest pressure values approximate the lithostatic pressure 120 mpa computed from geological data and are coherent with a geothermal gradient ranges of 35 45 c km whereas the lower pressure values are comparable with hydrostatic pressure conditions the pressure range indicated by fluid inclusion data is also comparable with the fluid pressure estimated from structural analysis the considerable pressure range can be related to pressure cycling between lithostatic and hydrostatic conditions as a consequence of fault valve actions and rock fracturing with subsequent pressure recover due to self sealing process

high resolution stable isotope stratigraphy of upper ordovician sequences constraints on the timing of bioevents and environmental changes associated with mass extinction and glaciation the two phases of the late ordovician mass extinction are approximately coeval with the periods of rapid climate change associated with the onset and demise of the gondwanan glaciation in this paper we argue that the distinctive late ordovician carbon isotope profile provides a chronostratigraphic ruler against which a sequence of environmental and biotic events may be located the ruler also allows regional and global high resolution correlation of successions representing very different environments cores from the upper ordovician succession of estonia and latvia record a large 1 3 c c a r b o n a t e excursion up to 6 with a similar profile shape the consistent relationship between the chemostratigraphy and biostratigraphy in the baltic region suggests that the isotope profile has a regional chronostratigraphic value the presence of similar profiles in nevada united states suggests that the excursion is a global chronostratigraphic signal this interpretation enables a detailed correlation to be made between upper ordovician shallow marine and basinal sequences that have wholly different faunas successions in the baltic area and in canada that do not display the model profile are interpreted as incomplete reinter pretation of these important successions significantly modifies the global database used to assess the pattern of diversity change during the mass extinction key levels of environmental change have been located against the carbon isotope profile new oxygen isotope data from brachiopod and ostracode calcite set tight limits on the start of the glacial events cooling and sea level fall started at the same stratigraphic level as the start of the carbon isotope excursion the later rise in sea level and fall in oxygen isotope values record the end of the glaciation these restrict the duration of the main glaciation to only 1 5 graptolite zones we propose that models of the carbon cycle should be adapted to be consistent with the temporal relationships between carbon cycling sea level fall and temperature change documented here the chronostratigraphic ruler provided by the carbon isotope profiles is used as a scale to determine the sequence of biotic changes and to allow high resolution correlation of biotic events at different locations this approach identifies regional similarities and differences in the patterns of extinction the main phase of graptolite extinction in the monitor range nevada for example is synchronous with the chitinozoan extinction in the baltic region but chitinozoan taxa survive to higher levels in nevada the benthic faunas in the baltic region demonstrate that the main extinction event corresponded with the beginning of the isotope excursion at the start of the hirnantian the level at which the marine environment started to change rapidly but that there were further extinctions of species within the early hirnantian the cold adapted hirnantia fauna did not appear immediately after the extinction in this area the relationship between the second phase of extinction and the carbon isotope excursion is less clear but the available data suggest that the extinction coincides with a time of rapid environmental change but not at the inception of environmental change as happened in the first phase

graptoloid evolutionary rates track ordovician silurian global climate change graptoloid evolutionary dynamics show a marked contrast from the ordovician to the silurian subdued extinction and origination rates during the ordovician give way during the late katian to rates that were highly volatile and of higher mean value through the silurian reflecting the significantly shorter lifespan of silurian species these patterns are revealed in high resolution rate curves derived from the conop constrained optimization scaled and calibrated global composite sequence of 2094 graptoloid species the end ordovician mass depletion was driven primarily by an elevated extinction rate which lasted for c 1 2 ma with two main spikes during the hirnantian the early silurian recovery although initiated by a peak in origination rate was maintained by a complex interplay of origination and extinction rates with both rates rising and falling sharply the global 13 c curve echoes the graptoloid evolutionary rates pattern the prominent and well known positive isotope excursions during the late ordovician and silurian lie on or close to times of sharp decline in graptoloid species richness commonly associated with extinction rate spikes the graptoloid and isotope data point to a relatively steady marine environment in the ordovician with mainly background extinction rates changing during the katian to a more volatile climatic regime that prevailed through the silurian with several sharp extinction episodes triggered by environmental crises the correlation of graptoloid species diversity with isotopic ratios was positive in the ordovician and negative in the silurian suggesting different causal linkages throughout the history of the graptoloid clade all major depletions in species richness except for one were caused by elevated extinction rate rather than decreased origination rate

global and regional controls on marine redox changes across the ordovician silurian boundary in south china abstract the ordovician silurian o s transition coincided with significant environmental and biological changes in south china the yangtze platform experienced both global and regional events at this time including sea level fluctuations tectonic movements volcanic eruptions mass extinction and widespread anoxia the o s transitional strata of the yangtze platform comprise organic rich black shales that are an important oil source rock to explore the evolution of watermass chemistry and its relationship to organic matter accumulation we conducted an integrated fe s c geochemical study i e fe speciation 13corg 34spy pyrite s and toc of the o s boundary sections at datianba chongqing municipality and shuanghe sichuan province these sections were located in the restricted inner yangtze sea in contrast to the previously studied wangjiawan section which was deposited in a more open setting of the outer yangtze sea in contrast to the well oxygenated conditions at wangjiawan the datianba and shuanghe sections record persistently anoxic and episodically euxinic conditions during the hirnantian which can be explained by the unique paleogeography and restricted hydrography of the inner yangtze sea we propose that the regional kwangsian orogeny which was driven by collision of the yangtze and cathaysia blocks played a key role in basin development watermass chemistry changes and accumulation of wufeng formation black shales within the yangtze sea the more widespread black shales of the lower silurian lungmachi formation were linked to the post hirnantian global marine transgression

stratigraphic variation in marine carbonate carbon isotope ratios stratigraphic variation in the carbon isotopic 13c value of marine carbonate and organic matter preserved within it has become a popular tool for supporting paleoclimatic hypotheses and refining stratigraphic correlation virtually every important biostratigraphic and sequence stratigraphic event of the last 800 million years has had a 13c dataset collected to aid in interpreting the causal environmental factors that contributed to the event the stratigraphic resolution obtainable using 13c has yielded critical temporal constraints on the interplay between carbon cycle variation and environmental events such as mass extinction and eustasy although the non uniqueness of the carbon isotopic response to different environmental stimuli has frustrated the identification of a unified mechanism linking marine 13c variation with distinct environmental forcing functions the interpretation of 13c variation can nonetheless provide important insights into processes that influence major global climatic and surficial systems early studies of marine carbonate minerals suggested that the 13c value of ancient oceans was essentially 0 versus the peedee belemnite standard pdb clayton and degens 1959 schidlowski et al 1975 see also keith and weber 1964 it was later recognized however that departures from the pdb standard represented secular variation in the 13c values of the marine environment rather than analytical noise that the record was potentially rich with stratigraphic and paleoenvironmental information scholle and arthur 1980 veizer et al 1980 wadleigh and veizer 1982 arthur et al 1985 holser et al 1986 zachos and arthur 1986 and that variation was intimately linked to the global carbon oxygen and sulfur cycles kump and garrels 1986 holser et al 1988 it is now well established that carbonate 13c values vary within 3 from the pdb standard for

a major drop in seawater 87sr 86sr during the middle ordovician darriwilian links to volcanism and climate a large drop in seawater 87 sr 86 sr during the middle ordovician was among the most rapid in the entire phanerozoic new 87 sr 86 sr measurements from nevada indicate that the rapid shift began in the pygodus serra conodont zone of the upper darriwilian stage we use a numerical model to explore the hypothesis that volcanic weathering provided the flux of nonradiogenic sr to the oceans a close balance between volcanic outgassing and co 2 consumption from weathering produced steady p co 2 levels and climate through the middle katian consistent with recent ordovician paleotemperature estimates in the late katian outgassing was reduced while volcanic weathering continued and resulted in a cooling episode leading into the well known end ordovician glaciation

large perturbations of the carbon and sulfur cycle associated with the late ordovician mass extinction in south china high resolution 13 c data of organic carbon from a continuous section of the late ordovician early silurian reveal two positive 13 c excursions that are associated with the mass extinction in south china the fi rst stratigraphic 34 s measurements on pyrite tied to well established biostratigraphy indicate a large perturbation of the sulfur cycle consistent with major sea level changes related to the glaciation the elevated 34 s values of pyrites and a large short lived negative 34 s excursion of 20 associated with the decay of the glaciation suggest deep water anoxia during the hirnantian stage in contrast to the conventional view that the global oceans were oxygenated we suggest that deep water anoxia may have contributed to the late ordovician mass extinction in south china and possibly elsewhere

scarcity of the c30 sterane biomarker 24 n propylcholestane in lower paleozoic marine paleoenvironments abstract 24 n propylcholestane 24 npc a c30 sterane compound derived from sterol precursors which are the major sterol constituents of modern pelagophyte microalgae occurs in certain neoproterozoic rocks and oils and throughout the phanerozoic rock record this broad distribution leads 24 npc to be widely considered a reliable indicator of open to partially restricted marine depositional conditions for source rocks and oils here we report two significant hiatuses in the occurrences of 24 npc in the lower paleozoic marine rock record the first in the middle late cambrian and the second in the late ordovician early silurian transition for a range of lithofacies carbonates and siliciclastic rocks organic carbon contents both organic lean and organic rich and paleoceanographic environments shelf and deeper water marine settings and observed offshore of two paleocontinents laurentia and baltica the ordovician silurian gap is at least 9 million years and possibly up to 20 million years in duration robust older occurrences of 24 npc steranes in some neoproterozoic rocks and oils suggest that oceanographic conditions in our intervals of lower paleozoic time were unfavorable for the proliferation of pelagophyte algae as phytoplankton caution should therefore be applied when interpreting a lacustrine versus marine depositional environmental setting for source rocks and oils in these intervals of early paleozoic time using lipid biomarker assemblages

late ordovician mass extinction a new perspective from stratigraphic sections in central nevada integrated sequence stratigraphic biostratigraphic and chemostratigraphic analyses of three stratigraphic sections in central nevada indicate that late ordovician glaciation induced sea level fall produced diachronous stepwise faunal turnover in graptolites conodonts chitinozoans and radiolarians and also triggered a strong but transient positive 13c excursion this pattern is very different from that described for most mass extinction events

environmental controls on marine ecosystem recovery following mass extinctions with an example from the early triassic abstract the recovery of marine ecosystems following a mass extinction event involves an extended interval of increasing biotic diversity and ecosystem complexity the pace of recovery may be controlled by intrinsic ecosystem or extrinsic environmental factors here we present an analysis of changes in marine conditions following the end permian mass extinction with the objective of evaluating the role of environmental factors in the protracted 5 myr long recovery of marine ecosystems during the early triassic specifically our study examines changes in weathering productivity and redox proxies in three sections in south china chaohu daxiakou and zuodeng and one in northern india mud our results reveal 1 recurrent environmental perturbations during the early triassic 2 a general pattern of high terrestrial weathering rates and more intensely reducing marine redox conditions during the early griesbachian late griesbachian mid smithian and more weakly the mid spathian 3 increases in marine productivity during the aforementioned intervals except for the early griesbachian and 4 stronger and more temporally discrete intervals of environmental change in deepwater sections chaohu and daxiakou relative to shallow and intermediate sections zuodeng and mud our analysis reveals a close relationship between episodes of marine environmental deterioration and a slowing or reversal of ecosystem recovery based on metrics of biodiversity within community alpha diversity infaunal burrowing and ecosystem tiering we infer that the pattern and pace of marine ecosystem recovery was strongly modulated by recurrent environmental perturbations during the early triassic these perturbations were associated with elevated weathering and productivity fluxes implying that nutrient and energy flows were key influences on recovery more regular secular variation in deepwater relative to shallow water environmental conditions implies that perturbations originated at depth i e within the oceanic thermocline and influenced the ocean surface layer irregularly finally we compared patterns of environmental disturbance and ecosystem recovery following the other four big five phanerozoic mass extinctions to evaluate whether commonalities exist in general the pace of ecosystem recovery depends on the degree of stability of the post crisis marine environment

did changes in atmospheric co2 coincide with latest ordovician glacial interglacial cycles article i nfo the late ordovician hirnantian stage 444 million years ago was one of three time periods during the past half billion years in which large continental glaciers formed over earth s polar regions the effects of this glaciation were far reaching and coincided with one of the largest marine mass extinction events in earth history the cause of this ice age is uncertain and a paradoxical association with evidence for high atmospheric co2 levels has been debated precise linkages between sea level ice volume and carbon isotope 13 ccarb and 13 corg proxy records of pco2 have been poorly understood due in part to uncertainties in stratigraphic correlation and the interpretation of globally important sections although correlation difficulties remain recent hirnantian biostratigraphic studies now allow for improved correlations here we show that consistent trends in both 13 ccarb and 13 corg from two well dated stratigraphic sequences in estonia and anticosti island canada coincide with changes in late ordovician hirnantian climate as inferred from sea level and the extent of ice sheets the integrated datasets are consistent with increasing pco2 levels in response to ice sheet expansion that reduced silicate weathering ultimately the time period of elevated pco2 levels is followed by geologic evidence of deglaciation

scale invariance and self organized criticality in migmatites of the southern hualapai mountains arizona whether or not melt flow networks are scale invariant may have broad implications for the understanding of the development of magmatic systems leucosome distributions in natural migmatite samples from the hualapai mountains arizona are used to investigate the scaling characteristics of an inferred syndeformational melt flow network one dimensional line and two dimensional box counting analyses yield distributions that are consistent with a scale invariant relationship between the leucosome size and leucosome frequency we infer from these results that the interactions of anatexis and deformation gave rise to a self organized critical system in which melt distribution and melt movement were linked over a range of scales at least millimeter to meter scale we conclude that even in metatexite migmatites volumetrically dominated by solid phases melts can play an active role in determining the architecture of the melt flow network one implication of the envisioned self organized critical system is the potential for rapid large scale melt coalescence and escape without long term maintenance of a fully interconnected melt flow network

upper ordovician sequences of western estonia abstract the upper ordovician uppermost caradoc ashgill section of western estonia consists of a series of seven open shelf carbonate sequences depositional facies grade laterally through a series of shelf to basin facies belts grain supported facies shallow shelf mixed facies middle shelf mud supported facies deep shelf and slope and black shale facies basin locally a stromatactis mud mound occurs in a middle to deep shelf position shallow to deep shelf facies occur widely across the estonian shelf and grade laterally through a transitional slope belt into the basinal deposits of the livonian basin each sequence consists of a shallowing upward prograding facies succession sequences 1 upper nabala stage and 2 vormsi stage record step wise drowning of underlying shelf units lower nabala that culminated in the deposition of the most basinal facies fjacka shale in the livonian basin sequences 3 6 comprise the overlying pirgu stage and record the gradual expansion of shallow and middle shelf facies across the estonian shelf the porkuni stage sequence 7 is bracketed by erosional surfaces and contains the shallowest water facies of the preserved strata the uppermost part of the section normalograptus persculptus biozone is restricted to the livonian basin and includes redeposited carbonate and siliciclastic grains it is the lowstand systems tract of the lowest silurian sequence 8 sequence 7 and the overlying basinal redeposited material i e the lowstand of sequence 8 correspond to the latest ordovician hirnantian glacial interval and the bracketing unconformities are interpreted as the widely recognized early and late hirnantian glacial maximums the sequences appear correlative to upper ordovician sequences in laurentia graptolite biozones indicated that the estonian sequences are equivalent to carbonate ramp sequences in the western united states great basin and mixed carbonate siliciclastic sequences in the eastern united states appalachian basin cincinnati arch region these correlations indicate a strong eustatic control over sequence development despite the contrasting tectonic settings of these basins

spatial distribution of melt bearing structures in anatectic rocks from southern brittany france implications for melt transfer at grain to orogen scale abstract in this study we present quantitative spatial information on the one and two dimensional distribution of inferred melt bearing structures in anatectic supracrustal rocks of the southern brittany migmatite belt south of the transcurrent south armorican shear zone sasz based on these data we infer the mechanism of melt extraction from partially molten crust former melt bearing structures include foliation parallel leucosomes and cross cutting granitic leucosomes that infill inter boudin partitions and extensional shear surfaces as well as discordant dykes of granite petrographic i e mineralogical and microstructural continuity of granite from structure to structure suggests that they once formed a continuous melt bearing network measurements along one dimensional line traverses perpendicular to layering of stromatic migmatite exposed in clean sub horizontal outcrop surfaces provide information about thickness and spacing distributions of foliation parallel leucosomes most leucosome thicknesses fall in the range of 1 10 mm with upper limits around 20 30 mm the number of thicker layers decreases abruptly with increasing thickness which is inconsistent with scale invariance this suggests that leucosome formation was controlled by short range melt movement along grain boundaries to form melt rich layers constrained by pre existing compositional layering spacing distributions also are not scale invariant however the large percentage of leucosomes 40 60 in these line traverses suggests that spacing distributions may be controlled in part by impingement of leucosomes making it difficult to derive genetic information from these data qualitative observation of inferred melt bearing structures in mutually perpendicular two dimensional exposures from the same outcrop reveals anisotropy of the leucosome network related to a well developed sub horizontal quartz feldspar lineation reflecting stretching associated with transcurrent movement along the sasz analysis of these two dimensional distributions using the box counting method corroborates the observed anisotropy but indicates that leucosome morphology and perhaps distribution is not scale invariant the applicability of the box counting method or of fractal analysis to understanding melt movement in migmatites is discussed in light of these results based on the anisotropy of melt bearing structures we infer that melt movement in structures now represented by layer parallel leucosomes was primarily sub horizontal these layers fed steeply dipping structures now represented by cross cutting leucosomes in particular those developed at inter boudin partitions and granite dykes the formation and orientation of these steeply dipping structures was in part controlled by far field stresses related to dextral displacement along the sasz melt extraction is inferred to have occurred along these steeply dipping structures extracted melt accumulated in plutons at higher crustal levels such as the quiberon sarzeau and guerande granites

local and global perspectives on carbon and nitrogen cycling during the hirnantian glaciation abstract the impact of climate and ocean circulation changes on marine carbon and nitrogen cycling was investigated for a period covering the late ordovician hirnantian glaciation three sections were studied two from nevada one proximal and one distal and one from the yukon the opportunity to compare 13 c carb 13 c org and 13 c grap profiles between ocean and epeiric platform settings enabled a more thorough assessment of environmental and diagenetic factors influencing the preservation of seawater 13 c values at each stratigraphic section using the best preserved sedimentary components from the two nevada sections a lowstand sedimentary gradient of 4 was found between platform and ocean settings during the hirnantian glaciation gradients of similar magnitude have been reported from hirnantian platforms in the canadian arctic and baltic basins taking the outboard sections as the most representative of the ocean carbon pool a mean positive 13 c shift of just 2 7 0 4 is calculated which is significantly smaller than the 5 7 positive shifts recorded in epeiric platform settings the discrepancy is attributed to the effects of local carbon cycling in tropical and subtropical epeiric seas it is hypothesized that increased carbonate weathering caused 13 c values of local carbon weathering fluxes to increase which in turn caused seawater 13 c values to increase in basin proximal settings in addition nutrient dust fluxes may have contributed to increased levels of photosynthetic activity in proximal settings driving sedimentary 13 c values even higher much higher than sediment deposited in outboard settings where carbon exchanges with the surface ocean were less restrictive a 15 n profile reconstructed from deposits of the distal vinini creek section records a 1 5 positive shift through the hirnantian glacial interval interpreted as a major late ordovician upwelling zone high organic carbon 1 wt and high hydrogen indices 400 600 make the vinini creek section a suitable candidate for the preservation of original sedimentary 15 n records to explain the results a conceptual model of ocean nitrogen cycling under greenhouse climate conditions is presented that highlights the role of cyanobacteria as both primary producers and nitrogen fixers it is hypothesized that in greenhouse climates the fixed nitrogen inventory of the abyssal ocean was low due to efficient denitrification in the ocean s expansive oxygen minimum zones this caused algal productivity to become strongly dependent on continuous supplies of fixed nitrogen from cyanobacteria in the photic zone yielding sedimentary 15 n values between 0 and 2 by contrast the cooler icehouse climate of the hirnantian led to increased ocean ventilation greater partitioning of atmospheric oxygen into downwelling surface waters and oxygen minimum zone shrinkage as a result fixed nitrogen levels climbed in the ocean s abyssal depths due to the lower denitrification rates this in turn allowed nitrogen with high 15 n values to recycle back into the photic zone driving sedimentary 15 n values higher during the hirnantian glaciation

late ordovician carbon isotope trend in estonia its significance in stratigraphy and environmental analysis abstract carbon isotope changes during most of late ordovician time from the mid caradoc kinnekulle k bentonite until the beginning of the silurian were investigated as the corresponding sequence of rocks is stratigraphically nearly complete in estonia an attempt was made to use it to elaborate the general pattern of carbon isotope changes in the late ordovician complications were caused by several local or regional hiatuses in the middle and late caradoc and hirnantian a total of 385 whole rock samples were studied from eight drill cores in northern and central estonia the following positive carbon isotope events were observed 1 the mid caradoc excursion peak 13c value 2 2 in the uppermost part of the keila stage also known in sweden 2 the first late caradoc excursion 1 9 in the lower part of the rakvere stage 3 the second late caradoc excursion 2 4 in the upper part of the nabala stage 4 the early ashgill excursion 2 5 in the lowermost part of the pirgu stage 5 the widely known large hirnantian excursion in estonia the peak value reaches 6 7 in the porkuni stage the study interval comprises a long 10 ma period characterized by low magnitude carbon isotope changes and a following brief 2 ma interval with large changes no obvious lithological preference for hosting the positive shifts was recorded in principle the 13c values exceeding the background values may occur in all types of rocks present in a sedimentary basin several 13c positive excursions values 1 5 to 3 in the mohawkian of north america are evidence that the minor caradoc and early ashgill 13c positive shifts in baltoscandia may have counterparts in laurentia if correctly correlated these shifts may have global significance the hirnantian excursion is usually linked to a major glacial event even if some carbon cycling mechanisms are not completely understood the environmental causes suggested for the earlier minor shifts range from global climatic and glacial events to very local changes in basin regime and sea level our study supports the primary role of climatic or climatically triggered oceanic processes

central pit craters on ganymede central pit craters are common on mars ganymede and callisto and thus are generally believed to require target volatiles in their formation the purpose of this study is to identify the environmental conditions under which central pit craters form on ganymede we have conducted a study of 471 central pit craters with diameters between 5 and 150 km on ganymede and compared the results to 1604 central pit craters on mars diameter range 5 160 km both floor and summit pits occur on mars whereas floor pits dominate on ganymede central peak craters are found in similar locations and diameter ranges as central pit craters on mars and overlap in location and at diameters 60 km on ganymede central pit craters show no regional variations on either ganymede or mars and are not concentrated on specific geologic units central pit craters show a range of preservation states indicating that conditions favoring central pit formation have existed since crater retaining surfaces have existed on ganymede and mars central pit craters on ganymede are generally about three times larger than those on mars probably due to gravity scaling although target characteristics and resolution also may play a role central pits tend to be larger relative to their parent crater on ganymede than on mars probably because of ganymede s purer ice crust a transition to different characteristics occurs in ganymede s icy crust at depths of 4 7 km based on the larger pit to crater diameter relationship for craters in the 70 130 km diameter range and lack of central peaks in craters larger than 60 km diameter we use our results to constrain the proposed formation models for central pits on these two bodies our results are most consistent with the melt drainage model for central pit formation

the ordovician chitinozoan biodiversification and its leading factors abstract regional and global dataset now available for almost all of the ordovician fossil groups have led to a search for the causes controlling the major biodiversification events that occurred during the ordovician period a review of the physico chemical state of the ordovician world is presented with an emphasis on the regional or global changes contemporaneous with the origination and extinction events that could have influenced the chitinozoan diversity this study focuses on the chitinozoans because these enigmatic organic walled microfossils are an important component of the ordovician palaeoplankton and provide one of the best documented dataset the intrinsic factors that initiated the ordovician biodiversification of this group are not discussed because the chitinozoans are regarded as reproduction stages of cryptic chitinozoan animals whose biological characteristics are speculative at best this study has two main goals i the evaluation of the impact of regional and global physico chemical events on chitinozoan diversity ii the comparison of the biodiversification patterns of the chitinozoans with other selected benthic and pelagic ordovician fossil groups the chitinozoan diversification was progressive and showed similar patterns in laurentia baltica and northern gondwana from the tremadocian to the late darriwilian when the group reached its acme in baltica and northern gondwana from the middle upper ordovician boundary onward the biodiversification pattern documented in laurentia diverged drastically from the two other regions in the late ordovician the contribution of the laurentian chitinozoans to the global curve was high suggesting major faunal inputs from the two other regions which significantly lowered the endemic character prevalent in the early middle ordovician in the late ordovician large anti clockwise oceanic currents developed as the result of a thermohaline circulation this marine circulation was likely to have been driven by a global cooling concomitant with a major palaeogeographic reorganisation of the southern hemisphere these oceanic climatic changes intervened in the breakdown of the existing chitinozoan endemism globally the chitinozoan biodiversity was not much higher in the mid late ordovician than in the late darriwilian diversity peak the most obvious feature is the progressive decrease in diversity during the late ordovician long before the hirnantian glaciation the influences of cosmic and volcanic parameters are excluded as they appear to have had too low impact on the late ordovician decrease of chitinozoan diversity correlation is noticed between some diversification events and sea level changes at least on a regional scale more globally however a climatic control is favoured a durable greenhouse environment gave an efficient support to the diversification conversely the onset of an icehouse environment in the early late ordovician onward culminating with the hirnantian glaciation is interpreted as a limiting factor for the chitinozoan diversification the reasons behind the onset of this icehouse episode are not fully understood but they appear to be linked to changes in the palaeogeography e g progressive closure of the iapetus northward drift of avalonia and its docking with baltica and in the carbon cycle e g high organic carbon burial with a lowering of the p co 2

structural and lithological control on fluid circulation dilation and ore mineralization rio albano mine island of elba italy abstract we present the results of geological and structural investigation documenting the interaction between hydrothermal fluids and host rock leading to a vein type ore mineralization at shallow crustal depths

aperture size scaling variations in a low strain opening mode fracture set cozzette sandstone colorado the aperture size distribution of a set of opening mode fractures in the cozzette sandstone is complex and cannot be described uniquely by a single equation this study of horizontal core includes aperture size data of macrofractures measured using a hand lens and microfractures measured using scanning electron microscope based cathodoluminescence sem cl macrofractures are poorly cemented and total fracture strain is an order of magnitude lower than the smallest strain values of most previously described vein sets macrofractures in this set therefore resemble typical joints as opposed to veins in most respects although intragranular microfractures compose about 98 of the microfracture population orientation fracture fill and fracture trace characteristics suggest that only transgranular microfractures can be shown to be genetically related to macrofractures aperture size data below 0 012 mm and above 1 mm follow a log normal distribution intermediate size data though relatively sparse suggest a power law aperture size distribution these results support the notion that this fracture set is an intermediate case between typical veins and joints the results also suggest that processes leading to size distributions commonly associated with veins i e power laws may be present in joint sets but over a more limited range bound at small size scales by grain scale effects and above by mechanical layering effects

thickness and spatial distribution of veins in a porphyry copper deposit rosia poieni romania abstract a statistical analysis of the vein thickness distributions of veins in the rosia poieni porphyry copper deposit romania indicates that vein thickness data conform to a power law distribution whereas the spatial distribution of veins follows a negative exponential law a high clustering of the veins is indicated by both the spacing distribution and the cv values the similar vein densities observed at the open pit scale are representative of a saturation level of vein nucleation differences in the spacing distribution and in the mean vein thickness are explained by different initial nucleation rates in the deepest and the lowest parts of the porphyry copper the highly clustered organization of the system is explained by vein linkage processes during their growth and modification of the fluid pressure and local stress during the hydrofracturing

the late aeronian graptolite sedgwickii event associated positive carbon isotope excursion and facies changes in the prague synform barrandian area bohemia study of the lower silurian black shale succession of the prague synform has enabled detailed insight into graptolite faunal dynamics and diversity trends from the mid aeronian diversity maximum through to the late aeronian crisis graptolite diversity decreased from 33 taxa in the lituigraptus convolutus biozone to 17 taxa in the upper part of the stimulograptus sedgwickii biozone and newly erected lituigraptus rastrum biozone the graptolite assemblages of the latter biozones exhibit low species richness along with high dominance many graptolite species that became extinct in the early part of the sedgwickii zone were promptly replaced by new forms in the later part of the sedgwickii zone however replacement of extinct species by new forms considerably decelerated the increased rate of graptolite extinction recorded in the convolutus sedgwickii biozone boundary beds coincided with subtle changes in black shale lithologies and a positive shift in 13 c org of 2 2 compared to baseline values sea level drawdown can be inferred from siltstones and or temporary nondeposition in the middle sedgwickii zone this level also sees total organic carbon toc fluctuations and a strong positive 13 c org excursion with a peak shift of at least 7 the sedgwickii event exhibits substantial reorganization of the graptolite fauna its taxonomic impoverishment and concomitant increase in species dominance rather than a sudden collapse of the pre extinction assemblage associated changes in lithology toc and the pronounced 13 c org excursion suggest a relatively extended and probably multi phase period of stressed conditions that affected the pelagic realm inhabited by graptolites in the course of the late aeronian interval

late ordovician to earliest silurian graptolite and brachiopod biozonation from the yangtze region south china with a global correlation late ordovician to earliest silurian is an important geological period marked by large geological and biological events however the strata and fossils of this interval are not complete in many parts of the world based on studies of 43 sites in south china in particular the continuous sections on the yangtze platform we recognize a complete succession including seven graptolite zones and two shelly faunas in ascending order the graptolite zones are the dicellograptus complanatus dicellograptus complexus paraorthograptus pacificus including lower subzone tangyagraptus typicus subzone and diceratograptus mirus subzone normalograptus extraordinarius normalograptus ojsuensis normalograptus persculptus akidograptus ascensus and parakidograptus acuminatus zones the shelly faunas are the foliomena nankinolithus and hirnantia faunas which may be correlated with d complanatus zone and n extraordinarius n ojsuensis to part of n persculptus zones respectively the biozonation through this interval from the yangtze region can be correlated with that of other parts of the world such as dob s linn in scotland spain and portugal thuringia saxonia bavaria bohemia poland kazakhstan kolyma malaya peninsula yukon canadian arctic islands nevada argentina niger and victoria australia the hirnantian substage which has been proposed by us recently includes the n extraordinarius n ojsuensis zone hirnantia fauna and n persculptus zone the base of the hirnantian substage is marked by the first appearance data fads of n extraordinarius and n ojsuensis which have been determined to be synchronous on a global scale

quantitative analysis of populations of small faults abstract tectonic strain includes contributions from small faults with length less than the thickness of the brittle upper crust this study derives algebra to determine the strain associated with small faults that follow a power law i e fractal distribution independent of assumptions concerning how they relate to large faults in the same region and discusses how to apply this algebra for a range of small fault sample types the method is illustrated using as case studies the jurassic extension in the north sea the miocene and younger extension in the gulf of suez and the hercynian strike slip faulting the badajoz cordoba fault zone in southern spain my preferred estimates for the strain accommodated on small normal faults with length

the ireviken event in the lower silurian of gotland sweden relation to similar palaeozoic and proterozoic events abstract for a long time the silurian was thought to represent a time of stable environmental conditions in the greenhouse period that followed the late ordovician glaciation during the past decade knowledge about the silurian has increased markedly and today it is known that the conditions in the silurian were much more variable than previously assumed detailed isotopic investigations have revealed several distinct positive excursions in both carbon and oxygen isotope values in low latitudes these periods of high c and o isotope values are in many cases characterised by the growth of reefs and the formation of extended carbonate platforms the sediments deposited during these excursions contain impoverished fossil assemblages especially with respect to conodonts graptolites and trilobites a conspicuous isotope excursion coincident with facies changes and a marked mass extinction is observed near the llandovery wenlock boundary this event is called the ireviken event after its type locality on the island of gotland sweden jeppsson l 1987 in palaeobiology of conodonts ellis horwood ltd chichester pp 129 145 here isotope data from nine sections at the nw coast of gotland are presented that cover the time interval of the ireviken event the 13c mean values rise from 1 4 to 4 5 and the 18o values increase from 5 6 to 5 0 the relative timing of stable isotope development extinctions and facies development is discussed it is shown that first extinctions precede the isotope excursion this indicates that extinction events and stable isotope development are only indirectly connected but might reflect the same causes other events characterised by similar relationships between positive isotope excursions mass extinctions and facies development are found in younger parts of the silurian late wenlock and ludlow in the late ordovician the late cambrian and with some reservations in the proterozoic the similarities between these events indicate analogous controlling mechanisms for the silurian climatic changes between humid and arid conditions in low latitudes were postulated in an earlier study of the authors a palaeoceanographic climatic model was postulated which is consistent with most of the sedimentological palaeontological and geochemical data here we demonstrate that this model may be applicable also for the older events

graptolite biozone correlation charts charts are presented showing the correlation of graptolite biozonations for the lower ordovician to lower devonian i e for the entire stratigraphical range of the planktonic graptoloid graptolites regions chosen are those for which the most detailed biostratigraphical studies have been undertaken for baltica average graptolite zone chron duration appears to vary from c 300000 years ludlow epoch to 2 4 ma lochkovian epoch