helium and carbon fluxes in lake nyos cameroon constraint on next gas burst on 21 august 1986 a lethal gas burst issued from lake nyos in cameroon western africa killing at least 1700 people although the consensus is that the victims died of asphyxiation by co2 of magmatic origin the frequency of such catastrophic degassing events is still unknown the co2 flux at the bottom of lake nyos is estimated based on the measurement of3he4he and4he20ne ratios and the chemical composition of gases exsolved from the lake water the calculated co2 flux at the bottom of lake nyos is 4 4 2 3 1013cm3stp year combined with the estimated release in the august 1986 event of 8 2 1014 cm3 stp the co2 flux suggests that the gas burst may happen about once in18 10 years although the significant uncertainty should be taken into account for the frequency resulting from assumptions such as steady state fluxes in the lake and small fractionization of the c he ratio during the degassing event several yearly measurements of hypolimnetic fluxes and seasonal measurements of epilimnetic fluxes are needed to constrain better the recurrence interval in addition the results of a regional3he4he survey of carbonated mineral springs in northwestern cameroon are discussed in the context of the regional geotectonics

variations in mode of formation and temperature of oceanic deep waters over the past 125 000 years marked changes in the deep water temperature of the different oceanic basins during the past 125 kyr are revealed by a detailed comparison of the oxygen isotopic composition ofbenthicforaminiferafrom sediment cores taken from the norwegian sea and the pacific atlantic and southern oceans the last interglacial deep water temperatures were similar to the modern ones at the 5e 5d transition around 115 kyr bp the deep water temperatures dropped below approximately 0 c in the pacific and southern indian oceans in the atlantic ocean the deep water temperature dropped in 2 successive steps at 115 and 75ky bp the global ocean deep water temperatures were in the 0 to 1 c range for the whole of the last ice age isotope stages 4 2

could deep subantarctic convection feed the world deep basins during the last glacial maximum simple box model calculations are used to simulate the oceanic circulation during the last glacial maximum lgm these experiments show that the main features of the 13c and 14c distributions and of the lysocline depth may be explained by a circulation pattern very different from the modem one intermediate and upper deep waters were produced in the north atlantic ocean whereas deep waters of subantarctic mode type forming at the northern edge of the subantarctic convergence invaded the main oceanic basins the southern ocean mainly self ventilated had a reduced deep component that flew southward along the east pacific ridge and the australian west cost the thermodynamic fractionation that occurs during air sea exchange has only contributed slightly to the glacial deep 13c distribution through surface water temperature variations

gas hazard assessment at the monticchio crater lakes of mt vulture a volcano in southern italy geochemical investigations have shown that there is a considerable inflow of gas into both crater lakes of monticchio southern italy these lakes are located in two maars that formed 140 000 years ago during mt vulture volcanos last eruptive activity isotopic analyses suggest that co2 and helium are of magmatic origin the latter displays 3 he 4 he isotope ratios similar to those measured in olivines of the maar ejecta in spite of the fact that the amount of dissolved gases in the water is less than that found in lake nyos cameroon both the results obtained and the historical reports studied indicate that these crater lakes could be highly hazardous sites even though they are located in a region currently considered inactive this could be of special significance in very popular tourist areas such as the monticchio lakes which are visited by about 30 000 people throughout the summer for the most part on sundays

mantle helium flux from the bottom of lake mashu japan abstract most of the 52 water samples from lake mashu hokkaido japan show large anomalies in their3he 4he ratios up to 4 6 times the atmospheric ratio and4he 20ne ratios indicating continuous injection of mantle he due to hot spring activity at the lake bottom the3he 4he ratio of the injected mantle he is estimated at3he 4he 9 43 0 17 10 6 which is close to the highest value reported for volcanic gases from the japanese islands accumulation of mantle he in the near bottom water can be reasonably explained by a diffusion process with a constant he flux from the lake bottom off4he 9 2 107 atoms cm2 s andf3he 8 7 102 atoms cm2 s the heat 3he ratio 1 7 10 7j atom falls in the range of values reported for submarine hydrothermal systems 0 4 26 10 7 j atom whereas the c3he ratio 1 8 1011 is about two orders of magnitude higher than the morb average 2 109 the mantle he injected from the lake bottom has a fairly short mean residence time in the lake water and is estimated at about 2 4 years overturn of the lake water which occurs twice a year probably plays an important role in the rapid transportation of the mantle he from the bottom to the surface

spatial productivity variations during formation of sapropels s5 and s6 in the mediterranean sea evidence from ba contents abstract we investigated five time equivalent core sections 180 110 kyr bp from the balearic sea menorca rise the easternmost levantine basin and southwest south and southeast of crete to reconstruct spatial patterns of productivity during deposition of sapropels s5 and s6 in the mediterranean sea our indicators are ba total organic carbon and carbonate contents we found no indications of ba remobilization within the investigated core intervals and used the accumulation rate of biogenic ba to compute paleoproductivity maximum surface water productivity up to 350 g c m2 yr was found during deposition of s5 isotope stage 5e but pronounced spatial variability is evident coeval sediment intervals in the balearic sea show very little productivity change suggesting that chemical and biological environments in the eastern and western mediterranean basins were decoupled in this interval we interpret the spatial variability as the result of two different modes of nutrient delivery to the photic zone river derived nutrient input and shoaling of the pycnocline nutricline to the photic zone the productivity increase during the formation of s6 was moderate compared to s5 and had a less marked spatial variability within the study area of the eastern mediterranean sea given that s6 formed during a glacial interval glacial boundary conditions such as high wind stress and or cooler surface water temperatures apparently favored lateral and vertical mixing and prevented the development of the spatial gradients within the eastern mediterranean sea ems observed for s5 a non sapropel sediment interval with elevated ba content and depleted 18o 16o ratios in planktonic foraminifer calcite was detected between s6 and s5 that corresponds to the weak northern hemisphere insolation maximum at 150 kyr at this time productivity apparently increased up to five times over surrounding intervals but abundant benthic fauna show that the deep water remained oxic following our interpretation the interval denotes a failed sapropel when a weaker monsoon did not force the ems into permanent stratification the comparison of interglacial and glacial sapropels illustrates the relevance of climatic boundary conditions in the northern catchment in determining the facies and spatial variability of sapropels within the ems

mediterranean sea surface radiocarbon reservoir age changes since the last glacial maximum sea surface reservoir ages must be known to establish a common chronological framework for marine continental and cryospheric paleoproxies and are crucial for understanding ocean continent climatic relationships and the paleoventilation of the ocean radiocarbon dates of planktonic foraminifera and tephra contemporaneously deposited over mediterranean marine and terrestrial regions reveal that the reservoir ages were similar to the modern one 400 years during most of the past 18 000 carbon 14 years however reservoir ages increased by a factor of 2 at the beginning of the last deglaciation this is attributed to changes of the north atlantic thermohaline circulation during the massive ice discharge event heinrich 1

the circulation of the levantine intermediate water in the algerian basin markedly different scenarios have been proposed for the circulation of the levantine intermediate water liw in the southern part of the western mediterranean sea discrepancies result from the fact that large temperature and salinity values which characterize liw are encountered both in the vicinity of sardinia and off algeria thus it was assumed that the circulation of liw was divided into two major branches one northward along the sardinian continental slope and the other across the algerian basin being dissatisfied with such a branch image of the circulation we have put forth hypotheses millot 1985 1987 which now appear to be supported by the results of the mediprod 5 experiment conducted in june 1986 we propose a scheme for the circulation of liw in the algerian basin wherein a gravity flow is constrained by the topography around sardinia and is subjected to sporadic spreading toward the open basin due to erosion of this vein by mesoscale eddies therefore it seems admissible that no branch of liw flows off the algerian coast

dansgaard oeschger and heinrich event imprints in alboran sea paleotemperatures past sea surface temperature sst evolution in the alboran sea western mediterranean during the last 50 000 years has been inferred from the study of c37 alkenones in international marine global change studies md952043 core this record has a time resolution of 200 years allowing the study of millennial scale and even shorter climatic changes the observed sst curve displays characteristic sequences of extremely rapid warming and cooling events along the glacial period comparison of this alboran record with 18o from greenland ice greenland ice sheet project 2 core shows a strong parallelism between these sst oscillations and the dansgaard oeschger events five prominent cooling episodes standing out in the sst profile are accompanied by an anomalous high abundance of neogloboquadrina pachyderma sinistral which is confined to the duration of these cold intervals these features and the isotopic record reflect drastic changes in the surface hydrography of the alboran sea in association with heinrich events hl 5

development of inverted metamorphic isograds in the western metamorphic belt juneau alaska an inverted metamorphic gradient is preserved in the western metamorphic belt near juneau alaska the western metamorphic belt is part of the coast plutonic metamorphic complex of western canada and southeastern alaska that developed as a result of tectonic overlap and or compressional thickening of crustal rocks during collision of the alexander and stikine terranes detailed mapping of pelitic single mineral isograds systematic changes in mineral assemblages and silicate geothermometry indicate that thermal peak metamorphic conditions increase structurally upward over a distance of about 8 km peak temperatures of metamorphism increase progressively from about 530 c for the garnet zone to about 705 c for the upper kyanite biotite zone silicate geobarometry suggests that the thermal peak metamorphism occurred under pressures of 9 11 kbar the metamorphic isograds are in general parallel to the tonalite sill that is regionally continuous along the east side of the western metamorphic belt although truncation of the isograds north of juneau indicates that the sill intrusion continued after the isograds were established our preferred interpretation of the cause of the inverted gradient is that it formed during compression of a thickened wedge of relatively wet and cool rocks in response to heat flow associated with the formation and emplacement of the tonalite sill magma garnet rim compositions and widespread growth of chlorite suggest partial re equilibration of the schists under pressures of 5 6 kbar during uplift in response to final emplacement and crystallization of the tonalite sill the combined results of this study with previous studies elsewhere in the western metamorphic belt indicate that high t high p metamorphism associated with the collision of the alexander and stikine terranes was a long lived event extending from about 98 ma to about 67 ma

deglacial warming of the northeastern atlantic ocean correlation with the paleoclimatic evolution of the european continent abstract isotopic micropaleontologic and pollen analyses of deep sea cores from the bay of biscay and the northeastern atlantic ocean show that the deglacial warming of this oceanic area was closely correlated with the paleoclimatic evolution of the adjacent european continent temperatures were at least as warm as those of today in the bay of biscay between 13 300 and 11 000 b p coinciding with the combined bolling allerod warm continental events a major spread of polar water occurred between 11 000 and 10 000 b p during this event which coincides with the younger dryas continental cold event marine temperatures were almost as low as those of the last glacial maximum the final deglacial warming of the norteastern atlatntic ocean occurred during the following 3000 yr

stable isotope anomalies in mediterranean pleistocene records oxygen and carbon isotope records of twelve mediterranean cores raised from west alboran sea to east off israel and of four atlantic cores raised from the western side of gibraltar and located respectively inside below and beyond the modern mediterranean outflow are compared to open ocean records of core 71 139c from the north atlantic and core v19 30 from the east pacific oxygen isotope stratigraphies can be established for deep mediterranean records and the major events of the last 150 ka are easily identifiable for instance the five substages of stage 5 or the 18 ka event stage 2 are identified but the 10 ka event younger dryas is only recorded by globigerina bulloides and benthic foraminifera suggesting that the cooling affected only winter sst 14c dates for the two terminations ia and ib of the last deglaciation which are recorded in sediment cores from areas with high sedimentation rates faro ridge alboran sea sicilian strait are in good agreement with the dates published for the same termination in atlantic cores an intermediate step however has been identified in some cores at 14 ka and divides termination ia into two phases oxygen isotope anomalies are recorded by the shallow water species globigerinoides ruber they correspond to 1 a higher amplitude glacial interglacial change in 18o values which exceeds that of the open ocean by 1 in the western basin and by 1 7 in the eastern basin 2 large isotopic depletions during the deposition of sapropel s1 s3 and s5 they are interpreted as the result of fresh water run off responsible for a strong dilution in the shallower layers of the east mediterranean waters the isotopic effect of this dilution averages 0 75 for sapropel s1 and 1 6 for sapropel s5 during the last glacial maximum the mediterranean still acted as a concentration basin and a gradient of 18o values similar to the modern one 0 75 existed from west to east in the deep waters apparently deep water temperatures were lower during the last glacial but the decrease did not exceed 4 c in the eastern basin major anomalies are also contained in the 13c records of g bulloides and benthic foraminifera the 13c records from surface intermediate and deep waters of the eastern basin and from intermediate and deep waters of the western basin are opposite to that of the open ocean during glacial time 13c values were higher in intermediate and deep waters of the whole mediterranean and also in surface water of the eastern basin at the same time the 13c gradient of surface to deep waters was low this gradient increased during the last deglaciation while 13c values of g bulloides and benthic foraminifera decreased this decrease interrupted at 10 ka may have been related to increased fresh water run off from the bordering contintents due to increased precipitation especially in the tropical belt the 13c depletion is clearly recorded in the levantine and deep water masses and can be traced westward in the mediterranean outflow oxygen and carbon isotope anomalies recorded simultaneously in the east mediterranean by the shallow water species globigerinoides ruber during sapropel deposition indicate that increased precipitation on the bordering continents and strong fresh water run off during the time of the last deglaciation may have caused a density stratification and deep stagnation in the eastern basin uncertainties arise from the fact that in the mixing model deglacial mediterranean waters are mixed with continental fresh waters the isotopic characteristics of which are not entirely understood although increased surface water production of biogenic material can not be excluded as a possible cause of 13c depletion it appears that the river discharge including the nile as well as black sea input are also plausible sources for the fresh water layering

noble gases in hydrothermal plumes of loihi seamount abstract seawater samples from hydrothermal plumes of loihi seamount show very high 3 he 4 he ratios up to 15 8 10 6 and 4 he 20 ne ratios higher than that of air saturated seawater assw the 3 he 4 he ratio in the source from which the helium is released into the seawater is estimated as 23 1 2 3 10 6 from the correlation plot of 3 he 20 ne vs 4 he 20 ne the 3 he heat ratio at loihi is 5 49 times higher than that at the galapagos rift and at 21 n epr the difference may be attributed to the differences in the structure of the mantle beneath hot spots and the mid ocean ridge the former representing the deeper mantle region and the latter the shallower depleted mantle these observations are consistent with the view that helium in hydrothermal plumes of loihi seamount was derived from a deeper mantle region via a hot spot where more primordial helium is still preserved

deepwater source variations during the last climatic cycle and their impact on the global deepwater circulation the degree of similarity of the 13c records of the planktonic foraminiferal species n pachyderma and of the benthic foraminiferal genus cibicides in the high latitude basins of the world ocean is used as an indicator of the presence of deepwater sources during the last climatic cycle whereas continuous formation of deep water is recognized in the southern ocean the norwegian sea stopped acting as a sink for surface water during isotope stage 4 and the remainder of the last glaciation however deep water formed in the north atlantic south of the norwegian sea during the last climatic cycle as early as isotope substage 5d and this area was also the only active northern source during stages 4 2 a detailed reconstruction of the geographic distribution of 13c in benthic foraminifera in the atlantic ocean during the last glacial maximum shows that the most important deepwater mass originated from the southern ocean whereas the glacial north atlantic deep water cannot be traced south of 40 n at shallower depth an oxygenated 13c rich intermediate water mass extended from 45 n to 15 s in the pacific ocean a ventilation higher than the modern one was also found in open ocean in the depth range 700 2600 m and is best explained by stronger formation of intermediate water in high northern latitudes

trans mediterranean comparison of geochemical paleoproductivity proxies in a mid pleistocene interrupted sapropel abstract sapropel layers in the sediment record of the mediterranean sea reflect periods of climate induced elevated marine production associated with precessional minima some of these layers feature interruptions that represent centennial to millennial returns to the predominantly low productivity conditions of this sea we have measured multiple geochemical paleoproductivity proxies in the interrupted sapropel layer that corresponds to insolation cycle 90 955 ka at 1 cm intervals in a four site transect from the balearic basin to the levantine basin to assess similarities and differences in its expression at the four locations the interrupted sapropels are similarly divided by an organic carbon poor interval into an upper layer in which organic carbon concentrations reach 2 7 wt and a lower layer in which they peak between 1 and 3 wt the interruption was essentially synchronous in the balearic basin the tyrrhenian basin and the ionian basin but it was delayed and shorter in the levantine basin lighter nitrogen isotope compositions consistently accompany higher organic carbon accumulation rates in the sapropel layers which implies a shift from coccolith dominated organic matter production towards a mode of primary production in which cyanobacteria were important during times of sapropel deposition organic carbon isotopic compositions become heavier as organic carbon accumulation increases at three of the locations which is consistent with elevated productivity however they become lighter at the levantine basin site which suggests greater delivery of isotopically light fluvial waters to this part of the mediterranean sea the local paleoclimate conditions conducive to sapropel formation evidently were not completely uniform across the mediterranean region but their occurrences were synchronous moreover the co existence of an essentially same age interruption of the sapropels at the four locations shows that climate could change rapidly and concordantly across the region at much less than precessional intervals

helium and carbon geochemistry of hydrothermal fluids from the mid okinawa trough back arc basin southwest of japan abstract hydrothermal systems located in the okinawa trough back arc basin are considered to be related to rifting activities in the continental margin hydrothermal fluids sampled from two sites jade and clam are significantly enriched in gas species compared to those from mid oceanic ridges a high temperature fluid 320 c from the jade site shows a co 2 concentration of 200 mmol kg 1 which is more than one order of magnitude higher than that of sediment starved ridge crest hydrothermal systems both helium r r a 6 1 6 5 and carbon 13 c co2 5 0 to 4 7 pdb isotopic compositions are typical of island arc magmatic gases also the abundance ratio of co 2 3 he 3 10 10 is within the range of values found in island arcs chemical and isotopic composition of the jade fluid are considered to indicate that both co 2 and helium are derived from a magmatic source beneath the hydrothermal system without significant contamination contrary to these species ch 4 is attributed to a thermogenic origin based on its isotopic composition 13 c ch 4 41 to 36 pdb and high concentration 7 1 mmol kg 1 which values are similar to those observed in sediment hosted hydrothermal systems the clam fluids show gas geochemistry much more affected by fluid sediment interaction lower 3 he 4 he ratios r r a 3 7 3 8 and higher co 2 3 he ratios 10 11 may reflect involvement of gas species introduced during secondary fluid circulation within the sedimentary pile magmatic activity is the main contributor of gas species to the hydrothermal fluids in both the jade and clam sites although fluid sediment interaction modifies their composition the relatively high abundance of co 2 in the mid okinawa trough hydrothermal systems reflects the geochemical nature of island arc magma

fluctuations in deep western north atlantic circulation on the blake outer ridge during the last deglaciation variations in the mean grain size of the detrital silt fraction from four piston cores along a depth transect on the blake outer ridge were used to examine paleocirculation patterns and intensity between 2650 and 3818 m for the late pleistocene and holocene prior to 12 kyr circulation was focused on the upper part of the ridge above 2700 m and may have corresponded to enhanced levels of intermediate water production in the north atlantic deepwater circulation during deglaciation underwent a two step decrease to minimum speeds from 15 5 to 13 5 kyr followed by a three step increase to maximum speeds at 10 kyr minima in circulation at 13 5 and 12 kyr can be directly associated with oxygen isotopic evidence for advection of reduced salinity surface water to the north atlantic additional circulation minima at 15 and 10 5 kyr may also be the result of reduced salinity from high latitude meltwater discharge evidence for a drop to moderate circulation intensity during the holocene is supported by isolated geochemical records but could also be explained by decoupling of ocean ventilation rates from bottom circulation or a change in sediment provenance at the end of deglaciation

new insights into upper mow variability over the last 150kyr from iodp 339 site u1386 in the gulf of cadiz the upper mediterranean outflow water mow paleo oceanographic history in the gulf of cadiz is poorly constrained due to the lack of high resolution records that pre date the last glaciation existing proxy records concentrate on mow variability along the middle slope of the gulf of cadiz here we present a continuous high resolution benthic foraminifera 18o record from the upper mow core at iodp expedition 339 site u1386 in the gulf of cadiz of the past 150 000 years based on 18o grain size and zr al variability comparison of our results with existing mediterranean sea md01 2472 md95 2043 open ocean lr04 and gulf of cadiz md99 2339 records we have gathered new insights into the evolution of the upper mow core on glacial interglacial timescales the influence of the upper mow at site u1386 was strongest during mis 5 and mis 1 similar 18o variability can be seen in the levantine intermediate water liw originating from the levantine basin of the eastern mediterranean sea we found clear indication for a vertical shift of the mow from the upper to the middle slope of the gulf of cadiz during sea level lowstands coinciding with mis 4 and mis 2 but also during mis 3 additionally our results indicate an increased upper mow flow correlated with heinrich events 7 to 10 and the younger dryas and also inversely relate to precession forced monsoonal freshwater inputs into the eastern mediterranean in the context of sapropel formation we could not find conclusive evidence of the proposed mow shutdown in our data

magnetostratigraphic biostratigraphic and stable isotope stratigraphy of an upper miocene drill core from the sale briqueterie northwestern morocco a high resolution chronology for the messinian stage we report a high resolution stable isotope carbonate magnetostratigraphic and biostratigraphic record from a 175 m drill core from the sale briqueterie which is part of the bou regreg section in northwestern morocco the sale drill core spans the interval from paleomagnetic chron c4n partim to c3r earliest gilbert which represents the time leading up to and including the isolation and desiccation of the mediterranean i e the messinian salinity crisis during chrons c3an and c3ar 6 935 to 5 894 ma the isotope and carbonate signals display quasi periodic variations with estimated periods of 40 and 100 kyr respectively we interpret the 40 kyr 18o variations as reflecting changes in global ice volume caused by obliquity induced changes 41 kyr in solar insolation in polar regions the 100 kyr carbonate variations probably represent long term modulation of the amplitude of the precessional cycle 21 kyr which is not resolved by our sampling frequency the cyclic nature of the oxygen isotope signal permits us to extend the isotope nomenclature of shackleton et al 1994a from stage tg24 in chron c3r earliest gilbert to stage c3ar 18o 18 at the base of chron c3ar 6 935 ma a major change in paleoceanographic conditions is recorded across the tortonian messinian boundary which we correlate to chron c3bn at 7 04 ma benthic foraminiferal 18o values increased by an average of 0 4 in two steps at 7 17 ma and 6 8 ma and 13c values decreased by 0 7 0 8 between 7 1 and 6 8 ma representing the late miocene carbon shift the first step in 18o values coincides with an inferred reversal in deep water circulation through the rifian corridor and the second correlates with the base of the tripoli formation and onset of crisis conditions in the mediterranean we suggest that the increase in 18o values represents at least in part an increase in global ice volume that lowered sea level and contributed to the establishment of a negative water budget in the mediterranean average 18o values remained high throughout most of chrons c3ar and c3an reaching maximum 18o values during isotope stages tg20 and 22 in chron c3r earliest gilbert the glacio eustatic falls associated with these events may have resulted in the complete isolation of the mediterranean from the world ocean shackleton et al 1994a following stage tg12 in the sale record there exists a trend toward progressively lower 18o values that may represent a series of marine transgressions that eventually reflooded the mediterranean and ended the salinity crisis

oxygen isotopic composition of the mediterranean sea since the last glacial maximum constraints from pore water analyses abstract interstitial waters recovered from ocean drilling program leg 161 site 976 in the western mediterranean sea are used in conjunction with a numerical model to constrain the 18o of seawater in the basin since the last glacial maximum including sapropel event 1 to resolve the oxygen isotopic composition of the deep mediterranean we use a model that couples fluid diffusion with advective transport thus producing a profile of seawater 18o variability that is unaffected by glacial interglacial variations in marine temperature comparing our reconstructed seawater 18o to recent determinations of 1 0 for the mean ocean change in glacial interglacial 18o due to the expansion of global ice volume we calculate an additional 0 2 increase in mediterranean 18o caused by local evaporative enrichment this estimate of 18o change due to salinity variability is smaller than previous studies have proposed and demonstrates that mediterranean records of foraminiferal calcite 18o from the last glacial period include a strong temperature component paleotemperatures determined in combination with a stacked record of foraminiferal calcite depict almost 9 c of regional cooling for the last glacial maximum model results suggest a decrease of 1 1 in seawater 18o relative to the modern value caused by increased freshwater input and reduced salinity accompanying the formation of the most recent sapropel the results additionally indicate the existence of isotopically light water circulating down to bottom water depths at least in the western mediterranean supporting the existence of an anti estuarine thermohaline circulation pattern during sapropel event 1

high fertility in the alboran sea since the last glacial maximum based on the glacial to postglacial 13c differences between endobenthic uvigerina peregrina species from the alboran basin and from other mediterranean basins changes in the fertility of the western part of this basin during the last deglaciation are reconstructed as a result of particulate organic carbon poc rain from the highly productive upwelling cell along the northwestern margin of the alboran basin u peregrina is presently depleted by about 1 6 with respect to the measured 13c values of bottom water co2 and by about 0 9 with respect to specimens from other areas of the western mediterranean or from the gulf of cadiz within the mediterranean outflow water the uvigerina 13c difference between the alboran sea and the gulf of cadiz 13c was close to 0 at the beginning of the last deglaciation and during the late glacial time this suggests that highly fertile systems set in the alboran sea near 16 kyr b p two rapid increases in the 13c offset are recorded near 15 kyr and 11 kyr b p fluctuations around 1 1 to 1 2 occurred during the early holocene and a maximum was reached near 9 kyr b p after 4 kyr the 13c offset decreased to its present day average value of 0 9 changes in the intensity of surficial production cannot account for all the observed fluctuations especially in the early holocene time a strong decrease in the intermediate and deep water ventilation of the alboran basin may have occurred near 8 9 kyr in phase with the last stagnant phase in the eastern mediterranean and the deposition of sapropel s1 as a result the redistribution and remineralization at depth of the produced organic matter was incomplete the poc rain reaching the sediment was locally intensified and caused the lowering of the 13c values of endobenthic foraminifers such as u peregrina the benthic 13c signal suggests that the difference between the alboran sea and the gulf of cadiz was at its maximum at the same time an important modification in the water masses structure may have occurred near 9 8 kyr b p the deepening of the permanent pycnocline probably related to a thicker atlantic jet at a stage of high sea level stand is recorded by the replacement of the right coiling n pachyderma dominance coincident with a shallow pycnocline by the g inflata dominance coincident with a deep pycnocline diatom abundances were strongly reduced indicating an important modification of the productive system the glacial postglacial evolution of productivity within the alboran basin was therefore more complex than in the adjacent atlantic ocean and opposite to the global one which displays a general increase in productivity during glacial time although it is the global budget of paleoproductivity that would drive the partitioning of carbon within the ocean local or regional discrepancies with the global glacial interglacial model must be addressed local winds and regional atmospheric pressure systems which are the forcing factors for circulation and exchange with the atlantic control the fertile systems of the alboran basin

on the late pleistocene ocean geochemistry and circulation a box model of the atmosphere and ocean was developed to investigate how geochemical distributions extant during the late pleistocene may have come about the model simulates the regional distribution of calcium carbonate dissolution as well as the chemical oceanography and atmospheric co2 13c and radiocarbon if the downward biological flux of particulate carbon increases by a factor of 2 to 3 in the antarctic and if this increase is combined with a relative increase of the atlantic sector antarctic bottom water aabw versus north atlantic deep water nadw source ratio from 1 3 to about 2 1 then the model predicts several changes that seem to be recorded in the sedimentary record as follows 1 a global redistribution of nutrients and 12c from the intermediate to deep water takes place with the atlantic intermediate water phosphate decreasing 0 6 mole kg 1 and the 13c increasing 0 3 to 0 5 2 the dissolved oxygen level of the deep sea is reduced from an average of about 180 to 70 mole kg 1 but the intermediate water oxygen declines only a small amount 3 the decrease in intermediate water nutrient concentration results in lower average organic carbon and calcium carbonate production in the warm surface ocean 4 the atmospheric co2 decreases by 90 to 110 ppm 5 initially a global increase in calcium carbonate dissolution occurs which is followed by a relaxation toward better preservation than exists for the present ocean in the model in this paper the reduction of nadw by itself does not produce these effects rather the nutrient decrease that does occur is found mostly in north pacific intermediate water and the model atmospheric co2 decrease is only 10 to 30 ppm it is observed that 92 of the atmospheric co2 change takes place according to a 200 year time constant in the model this corresponds to the response time of the upper ocean and atmosphere to a change in the stationary state atmospheric pco2 thus according to this model the time lag between the nutrient based cause and the atmospheric co2 response is not expected to be particularly large

circulation and nutrients in middepth atlantic waters isopycnal analyses of distributions of salinity oxygen apparent oxygen utilization nitrate and silica in the depth range 800 3000 m in the north and tropical atlantic ocean are carried out using data from the transient tracers in the oceans meteor cruise 56 leg 5 atlantis ii cruise 109 legs 1 and 3 and the geosecs atlantic study the results are summarized in isopycnal distribution maps and property property plots the layer between 800 and 1500 m is oxygen poor and nutrient rich and is poorly ventilated below this is a better aerated layer with the deep western boundary current part of which separates along the equator regeneration of nutrients and consumption of oxygen persist into the deep ocean in regions off the west coast of africa the mediterranean outflow water apparently is causing significant cross isopycnal mixing through salt fingering the resultant cross isopycnal velocity may be large enough to cause significant vorticity stretching

13c record of benthic foraminifera in the last interglacial ocean implications for the carbon cycle and the global deep water circulation the 13c 12c ratios of upper holocene benthic foraminiferal tests genera cibicides and uvigerina of deep sea cores from the various world ocean basins have been compared with those of the modern total carbon dioxide tco2 measured during the geosecs program the 13c difference between benthic foraminifera and tco2 is 0 07 0 04 for cibicides and 0 83 0 07 for uvigerina at the 95 confidence level 13c analyses of the benthic foraminifera that lived during the last interglaciation isotopic substage 5e about 120 000 yr ago show that the bulk of the tco2 in the world ocean had a 13c value 0 15 0 12 lower than the modern one at the 95 confidence level reflecting a depletion compared to the present value of the global organic carbon reservoir regional differences in 13c between the various oceanic basins are explained by a pattern of deep water circulation different from the modern one the antarctic bottom water production was higher than today during the last interglaciation but the eastward transport in the circumpolar deep water was lower

distribution and circulation of labrador sea water abstract labrador sea water is the final product of the cyclonic circulation of subpolar mode water in the open northern north atlantic mccartney and talley 1982 the temperature and salinity of the convectively formed subpolar mode water decrease from 14 7 c 36 08 to 3 4 c 34 88 on account of the cumulative effects of excess precipitation and cooling the coldest mode water is labrador sea water which spreads at mid depths and is found throughout the north atlantic ocean north of 40 n and along its western boundary to 18 n a vertical minimum in potential vorticity is used as the primary tracer for labrador sea water labrador sea water is advected in three main directions out of the labrador sea 1 northeastward into the irminger sea 2 southeastward across the atlantic beneath the north atlantic current and 3 southward past newfoundland with the labrador current and thence westward into the slope water region crossing under the gulf stream off cape hatteras the labrador sea water core is

geochemical insight into differences in the physical structures and dynamics of two adjacent maar lakes at mt vulture volcano southern italy 1 we report on the first geochemical investigation of the monticchio maar lakes mt vulture volcano southern italy covering an annual cycle that aimed at understanding the characteristic features of the physical structures and dynamics of the two lakes we provide the first detailed description of the lakes based on high resolution conductivity temperature depth ctd profiles chemical and isotopic h and o compositions of the water and the amounts of dissolved gases e g he ar ch4 and co2 the combined data set reveals that the two lakes which are separated by less than 200 m exhibit different dynamics one is a meromictic lake where the waters are rich in biogenic and mantle derived gases while the other is a monomictic lake which exhibits complete turnover of the water in winter and the release of dissolved gases our data strongly suggest that the differences in the dynamics of the two lakes are due to different density profiles affected by dissolved solutes mainly fe which is strongly enriched in the deep water of the meromictic lake a conceptual model of water balance was constructed based on the correlation between the chemical composition of the water and the hydrogen isotopic signature gas rich groundwaters that feed both of the lakes and evaporation processes subsequently modify the water chemistry of the lakes our data highlight that no further potential hazardous accumulation of lethal gases is expected at the monticchio lakes nevertheless geochemical monitoring is needed to prevent the possibility of vigorous gas releases that have previously occurred in historical time

ocean circulation in the norwegian sea during the last deglaciation isotopic evidence abstract three cores from different depths in the southeastern norwegian sea have been investigated for benthic and planktonic foraminiferal stable isotope records the cores confirm that the last deglaciation occurred in two distinct steps the first step termination ia may have occurred at about 13 000 yr b p while the second step took place shortly after 10 000 yr b p the benthic oxygen isotopes reveal strong influence of deglacial intermediate waters possibly flowing in from the north atlantic with a maximum influence at about 12 000 yr b p both carbon and oxygen isotopic records show that bottom water formation in the norwegian sea was reinitiated after 12 000 yr b p during the first part of the deglaciation the deep water circulation pattern may have been opposite to that of the present the oxygen content in the norwegian sea deep water was low during the last glacial maximum and remained low during the first part of the deglaciation due to low vertical circulation rates the large variations in deep water circulation in the norwegian sea during the last deglaciation may have had important consequences for the interchange of co 2 between ocean and atmosphere

geographical distribution of 3he 4he ratios in japan implications for arc tectonics and incipient magmatism the 3he 4he and 4he 20ne ratios of 115 natural gas samples including various types of gases from volcanoes hot springs mineral springs water wells petroleum fields and natural gas fields were measured using a mass spectrometer the observed 3he 4he and 4he 20ne ratios range from 7 47 10 8 to 9 65 10 6 and from 0 26 to 1100 respectively the 3he 4he ratios reflect well the geotectonic structure of the japanese islands in northeastern ne japan there is a clear geographical difference in the 3he 4he ratios between the frontal arc forearc and volcanic arc back arc regions lower ratios were found in the trench side region and higher ratios in the back arc side this result suggests that the mantle derived helium in the volcanic arc region is associated with the diapiric uprise of a magma lower 3he 4he ratios in the frontal arc region may be due to radiogenic he produced by radioactive decay of u and th in the crustal and sedimentary rocks in southwestern sw japan there is no clear geographical contrast in the 3he 4he ratios some samples in the frontal arc region show quite high 3he 4he ratios the tendency of the 3he 4he ratios agrees with the distribution of terrestrial heat flow data and reflects geotectonic structures different from ne japan the high 3he 4he ratios observed in the frontal arc region in sw japan may be indicative of renewed or incipient magmatism due to a descending young and warm slab

role of sea level forced sedimentary processes on the distribution of organic carbon rich marine sediments a review of the late quaternary sapropels in the mediterranean sea abstract the 124 ka to present sapropel s5 s1 series in the eastern mediterranean sea correspond to the last glacial interglacial period and permit detailed investigation of 5th order sedimentary frequencies the sapropel layers are clustered in high frequency milankovian cycle that occur within sequence stratigraphic 4th order cycles of late pleistocene holocene sea level oscillations the sea level changes had an amplitude exceeding 120 m and have been correlated to the glacial interglacial cycles modulated by the 100 ka eccentricity using published data we examined occurrences of the complete s5 s1 series in the mediterranean sea and then we focussed on two stratigraphic sequences in the central adriatic shelf and middle adriatic depression where sapropels s5 and s1 were deposited during periods of sea level rise recorded by the transgressive systems tract marine isotopic stage 5 and 1 respectively sapropels s4 and s3 were deposited during the highstand systems tract that developed throughout mis 5 of the late pleistocene sequence sapropel s2 should have been deposited during the warm mis 3 3 and followed the mis 4 sea level drop when sediment supply was enhanced during the late highstand and falling stage of sea level of the late pleistocene sequence the pronounced mis 2 cold stage led to a lowstand and to the regional erosional surface sequence boundary we also compared the adriatic sapropel s5 s2 sequence 4th order to the mid pliocene cluster o sequence 3rd order in both cases sapropels are well formed before the increase of sediment supply due to progradation of the shelf wedge that occurs in the late high stand and initial falling stage in sea level finally we considered the influence of sea level lowering which could cause a weakening of north adriatic deep water formation therefore influencing the mediterranean deep water circulation this condition would favour oxygen depletion but it does not correspond to a well developed sapropel as in the case of s2 based on the assumption that productivity increases related to insolation play a dominant role in their sedimentation sapropel s2 is the result of low amplitude insolation maxima that were unable to generate a productivity increase leading to the burial of conspicuous amount of organic matter therefore in the adriatic sea the absence of the s2 sapropel is correlated to the high sedimentation rate diluting the signal whereas in the eastern mediterranean basin this sapropel is virtually absent because of a weak orbital forcing combined with oxidation that erased its record

rare gas isotopic compositions in natural gases of japan isotopic and elemental compositions of rare gases in various types of gas samples collected in the japanese islands were investigated excess3he was found in most samples many samples showed a regionally uniform high3he 4he ratio of about 7 times the atmospheric ratio the he concentrations varied from 0 6 to 1800 ppm and they were low in co2 rich gases and high in n2 rich gases ne isotopic deviations from the atmospheric ne were detected in most volcanic gases the deviations and the elemental abundance patterns in volcanic gases can be explained by a mixing between two components one is mass fractionated rare gases and the other is isotopically atmospheric and is enriched in heavy rare gas elements ar was a mixture of mass fractionated ar atmospheric ar and radiogenic ar and the contribution of radiogenic40ar was small in all samples except for he elemental abundance patterns were progressively enriched in the heavier rare gases relative to the atmosphere several samples were highly enriched in kr and xe relative to the abundance pattern of dissolution equilibrium of atmospheric rare gases in water the component which is highly enriched in heavy rare gases may be released from sedimentary materials in the crust

mediterranean quaternary sapropels an immediate response of the african monsoon to variation of insolation abstract in the subsurface of the east mediterranean sea eleven discrete basin wide organic rich black sapropels were deposited during the last 465 000 years they are dated by oxygen isotopic chronostratigraphy the most recent sapropel has been shown to be the consequence of heavy nile river summer floods due to increased monsoonal summer precipitation over ethiopia and not of scandinavian ice sheet meltwater influx into the east mediterranean sea as was previously believed while most sapropels were deposited during interglacials two thick sapropels formed during glacial periods as shown by their position in the oxygen isotopic stratigraphy and by their pollen record in core rc9 181 the new evidence presented here is that the sapropel sequence in this core including the two glacial sapropels correlates on a one to one basis with the highest values of an index of insolation on top of the atmosphere the concept of this index derives from an analysis of the african monsoon process the index variation is computed for the last 465 000 years from the caloric northern summer insolation in the tropical latitudes controlled by variations of the earth s orbital parameters it is conjectured that this index might be linked through the climate system to the monsoonal precipitation which in africa produces the nile river summer flood

water masses and circulation in the western alboran sea and in the straits of gibraltar abstract some new elements of alboran sea circulation and water masses in close connection with flows through the straits of gibraltar are presented a general description is given of water masses found in 1981 during mediprod iv cruise from the gulf of cadiz to the gulf of lions followed by a brief review of the conditions found in the straits of gibraltar based on 1981 and 1961 observations the hydrological structure vertical and horizontal and surface and bottom currents typical of the western alboran sea are analysed we present some detailed observations about vertical currents in the deep waters near the straits and finally we analyse the characteristics of the mediterranean overflow through the straits our conclusions in part confirm those of bryden and stommel 1982 and in part shed light on the general pattern of the mediterranean currents entering the alboran sea from the east however considering the suggestion of stommel bryden and mangelsdorf 1973 that the deep currents in the interior of the western mediterranean basin are basically controlled by a bernoulli flow induced by the intense currents in the straits and the weak vertical stratification in the mediterranean we suggest that an interaction of a large scale circulation pattern and the topography of the alboran basin which is much shallower than the western mediterranean basin may play a major role in controlling hydraulically the deep mediterranean waters overflow a detailed water mass analysis of 1981 data and comparison with previous data revealed a time and space variability in the mediterranean waters the scales of this variability are unknown but the s variations make it difficult to make assumptions as to the depth of origin of the deep waters found in the alboran sea which flow into the atlantic ocean over the gibraltar sill

south atlantic intermediate water advances into the north east atlantic with reduced atlantic meridional overturning circulation during the last glacial period the nd isotopic composition end of seawater and cold water coral cwc samples from the gulf of cadiz and the alboran sea at a depth of 280 827 m were investigated in order to constrain middepth water mass dynamics within the gulf of cadiz over the past 40 ka end of glacial and holocene cwc from the alboran sea and the northern gulf of cadiz reveals relatively constant values 8 6 to 9 0 and 9 5 to 10 4 respectively such values are similar to those of the surrounding present day middepth waters from the mediterranean outflow water mow end 9 4 and mediterranean sea water msw end 9 9 in contrast glacial end values for cwc collected at thermocline depth 550 827 m in the southern gulf of cadiz display a higher average value 8 9 0 4 compared to the present day value 11 7 0 3 this implies a higher relative contribution of water masses of mediterranean msw or south atlantic origin east antarctic intermediate water eaaiw our study has produced the first evidence of significant radiogenic end values 8 at 19 23 24 and 27 ka which are coeval with increasing iceberg discharges and a weakening of atlantic meridional overturning circulation amoc since mow end values remained stable during the last glacial period it is suggested that these radiogenic end values most likely reflect an enhanced northward propagation of glacial eaaiw into the eastern atlantic basin

carbon and oxygen isotopic disequilibria of recent deep sea benthic foraminifera abstract the carbon and oxygen isotopic compositions of 149 samples of benthic foraminifera from deep sea core tops indicate that none of the nine species studied secrete calcium carbonate in isotopic equilibrium with ambient bottom water uvigerina pyrgo murrhina and oridorsalis tener are the closest to 18o equilibrium with average deviations about 0 4 while planulina wuellerstorfi and p murrhina are the closest to 13c equilibrium with average deviations about 1 p wuellerstorfi shows the most systematic relationship between 13c and bottom water apparent oxygen utilization the intraspecific variabilities in 18o and 13c suggest that estimates of bottom water paleotemperatures can be made to a precision of 0 7 c while estimates of past apparent oxygen utilization aou can be made to 35 mol kg based on intraspecific comparisons of the recent samples with fossils no temporal changes in the degree of either 18o or 13c disequilibrium have been detected for planulina wuellerstorfi uvigerina oridorsalis tener and globocassidulina subglobosa

double diffusion and the distribution of the density ratio in the mediterranean waterfront southeast of the azores abstract temperture and salinity t s finestructure on vertical scales of 10 db and larger is examined in a 500 by 500 km grid located southeast of the azores in the north atlantic the convergence of several water masses dominated by the mediterranean water mw at mid depth 1000 m leads to variety of t s finestructure which is unstable to double diffusive processes by forming histograms of the density ratio r a fundamental parameter in controlling double diffusive processes it is found that 71 of the volume is unstable to salt fingering while only 5 is unstable to diffusive layering the other double diffusive instability in about 24 of the volume r is less than 2 in the salt fingering sense and at these low values salt fingers grow rapidly this suggests that salt fingering may be an important diapycnal mixing process in much of the region two primary salt fingering regions are found a near surface region from about 100 to 500 db with a modal r of 2 0 and a deeper region from about 1000

a quasi synoptic survey of the thermocline circulation and water mass distribution within the canary basin shipboard hydrographic measurements and moored current meters are used to infer both the large scale and mesoscale water mass distribution and features of the general circulation in the canary basin we found a convoluted current system dominated by the time dependent meandering of the eastward flowing azores current and the formation of mesoscale eddies at middepths several distinctly different water masses are identified subpolar mode and labrador sea water are centered in the northwest subantarctic intermediate water is centered in the southeast and the saltier warmer mediterranean tongue lies between them mesoscale structures of these water masses suggest the presence of middepth meanders and detached eddies which may be caused by fluctuations of the azores current

after the deluge mediterranean stagnation and sapropel formation in an east mediterranean marine core the upper sapropel begins soon after the start of a global event a very heavy precipitation which occurred in the equatorial latitudes during the late glacial early holocene this heavy precipitation in africa channelled by the nile river across 35 of latitude produced a low salinity surface layer in the east mediterranean in this confined basin with high bottom salinity the steep salinity gradient stratified the water column the stagnant bottom waters triggered the sapropel formation cretaceous sapropels in the tropical oceans may result from the same chain of events in warm humid climates with contrasting wet and dry seasonal rhythm

astronomical forcing of northwest african climate and glacial history during the late messinian 6 5 5 5 ma abstract high resolution physical chemical and biological based climate proxies from the ain el beida aeb section in atlantic morocco reveal the imprint of the three main orbital parameters precession 19 23 kyr obliquity 41 kyr and eccentricity 95 125 and 400 kyr between 6 5 and 5 5 million years before present ma the precession related variations are most prominently reflected in the color reflectance and chemical composition of the sediment showing that precession minimum configurations lead to more humid climate conditions in northwest africa probably related to the atlantic system while more arid climate conditions prevailed during precession maxima in addition precession bound changes in planktonic foraminifera and calcareous nannofossil assemblages indicate that sea surface temperature sst increased during the humid phases while productivity conditions increased during the dry periods the clear imprint of the short and long term eccentricity cycles is explained by a non linear climatic response to the precession forcing with overall more humid climate conditions during eccentricity maxima the obliquity controlled variations in sst and aridity conditions concur with glacial interglacial variability that is conspicuously recorded in both planktonic and benthic 18 o records of aeb the observed warm and wet climates during interglacial periods most likely reflect the direct ice driven thermal response to the reduced ice sheets and more active atlantic depressions similar as during the pliocene and pleistocene obliquity controlled variations in the planktonic and benthic carbon isotope 13 c records of aeb are inversely related to the oxygen isotope records with more depleted values during glacial stages although with a small lag the close correspondence between the 13 c records of aeb and other open ocean sites i e sites 982 and 926 may therefore point to large scale glacial controlled variations in the deep sea carbon reservoir superimposed on the orbital variations the imprint of the onset of the messinian salinity crisis can be traced by a marked 1 0 negative excursion in planktonic 13 c at 6 0 ma followed by a prominent peak in ti al at 5 97 ma

reconstructed mediterranean salt lens trajectories the existence of energetic anticyclonic mid depth vortices of mediterranean water meddies questions the validity of a conventional advective diffusive balance in the eastern atlantic subtropical gyre a mesoscale experiment in the azores madeira region reveals a link of these meddies to large scale subsurface meanders for the first time it is shown that meddies may have strong surface vorticity indicative of a generation process involving the azores current a deep reaching near surface jet

the role of vertical chemical fractionation in controlling late quaternary atmospheric carbon dioxide the 30 decrease in atmospheric carbon dioxide during glacial maxima must be driven by some change in the chemical circulation of the ocean here a new model for late quaternary co2 variability is presented which resolves some problems occurring in previous models including the timing of carbon dioxide response and changes in the oxygen content of the deep ocean the primary driving factor in this model is a rearrangement of chemical distributions in the ocean whereby labile nutrients and metabolic co2 are concentrated in deep waters rather than in intermediate waters as observed in the modern ocean this new bottom heavy chemical structure does not affect atmospheric carbon dioxide directly instead co2 induced acidity lowers the deep ocean carbonate ion concentration and temporarily increases carbonate dissolution rates oceanic alkalinity then rises until the deep ocean carbonate ion is restored to its steady state value the resulting increase in oceanic alkalinity draws co2 out of the atmosphere into the ocean alkalinity and atmospheric co2 lag several thousand years behind the change in oceanic chemical structure this delayed response is determined by the limited rate of continental weathering and deep ocean carbonate dissolution relative to the oceanic alkalinity inventory it is proposed that characteristic deglacial and preglacial states of the ocean are leading factors driving glacial interglacial climate changes this concept reinterprets the carbon isotope contrast between surface water and deep waters 13c p b as due to a shift of light metabolic carbon from intermediate waters into deep waters the process is illustrated here by a simple equilibrium five box ocean model the observed intermediate depth nutrient depletion is not sufficient in itself to determine which of several possible mechanisms are operating and some mechanisms are not as effective in changing atmospheric co2 as others the largest response is seen from deepening the regeneration cycle of organic carbon the least response is seen from converting north atlantic deep water into intermediate water

paleoenvironmental changes from stable isotopes in planktonic foraminifera from eastern mediterranean sapropels abstract parallel stable oxygen isotope analyses of six planktonic foraminiferal species from an eastern mediterranean deep sea core present clear evidence for abnormal hydrographic regimes during deposition of sapropels s6 and s7 samples from s7 are characterized by a strong depletion of 18 o in epipelagic species while meso and bathypelagic forms are much less depleted this indicates a shallow pycnocline during deposition of s6 all species show a tendency towards lower values pointing to a far more extended pycnocline density stratification of the watercolumn is suggested by the isotopic differences between the species neogloboquadrina dutertrei globigerina bulloides and globorotalia scitula the latter represents the deepest element and shows the highest 18 o values carbon isotopes show two species groups each containing an epi meso and bathypelagic species under normal marine conditions group i globigerinoides ruber neogloboquadrina dutertrei and globorotalia truncatulinoides has relatively high 13 c values while species of group ii globigerina bulloides globorotalia scitula and globigerina quinqueloba show relatively low 13 c values indicating a stronger vital effect during sapropel deposition 12 c isotopes are enriched which we interpreted as the result of increased biological activity due to low oxygen stress conditions g scitula shows different eco phenotypes during times of sapropel deposition and the same may be true for the other members of group ii failure to adapt to adverse environmental conditions may be the cause for the absence of the two group i members globigerinoides ruber and globorotalia truncatulinoides in sapropel s6

anoxic events in the mediterranean sea in relation to the evolution of late neogene climates stable isotopic and micropaleontological studies were made of selected sapropels organic rich sediments deposited in the mediterranean sea during the last 5 0 m y to determine the processes responsible for their formation distinct isotopic and faunal changes occur across sapropels of late pleistocene early pleistocene and latest pliocene age while smaller isotopic changes and more stable faunal assemblages are associated with the early and mid late pliocene sapropels the large 18o depletions and euryhaline fauna associated with latest pliocene pleistocene sapropels supports a density stratification model with a low salinity surface layer in contrast early pliocene and mid late pliocene sapropels appear to have been formed as the result of sluggish circulation and low oxygen contents in bottom waters of the eastern mediterranean due to the stable warm climatic conditions of that time period

modeling the water masses of the atlantic ocean at the last glacial maximum 1 we produced gridded monthly sea surface boundary conditions for the atlantic ocean at the last glacial maximum lgm based on the sea surface temperature reconstruction of the glamap project we used an ocean general circulation model ogcm subject to these sea surface boundary conditions and a corresponding wind stress field from an atmospheric general circulation model to study the differences in the distribution of the main water masses between the lgm and the present our global ogcm is characterized by high vertical resolution low vertical diffusion and isopycnal mixing and hence allows for a realistic representation of the hydrology and circulation of the modern atlantic ocean according to a series of lgm experiments with an increasing sea surface salinity anomaly in the weddell sea the ventilated thermocline was colder than today by 2 3 c in the north atlantic ocean and in the experiment with the largest anomaly 1 0 beyond the global anomaly by 4 5 c in the south atlantic ocean its depth was reduced by 50 m on average most notably in the tropics in the north atlantic ocean the outcrop locations of the thermocline isopycnal surfaces migrated southward by 5 10 and the ventilation increased in the south atlantic ocean the mixed layer and thermocline water masses were dominated by cold water originating from drake passage and the import of warm water from the indian ocean was reduced to about 4 sv or 40 of its modern value antarctic intermediate water was colder by 3 4 c and could be traced as far as 10 n the meridional overturning rates of north atlantic deep water nadw and antarctic bottom water aabw in the atlantic ocean were similar to those of the present day experiment 9 10 sv and 4 sv respectively however nadw cooled by 2 5 c and aabw by 1 c aabw was near the freezing point of seawater at the surface and the saltiest water mass in the atlantic ocean even saltier than nadw we show that the differences between the lgm and the present day experiments can be traced back to the changes in the subpolar and interhemispheric sea surface density gradients

climate change and coastal hydrographic response along the atlantic iberian margin tagus prodelta and muros ria during the last two millennia the tagus prodelta w portugal and the muros ro a nw spain are areas of high deposition rates registering high resolution palaeoclimatic records for western iberia we compare the climatic conditions of the two areas over the last two millennia based on proxies of temperature sea surface temperatures and oxygen isotopes continental input grain size iron and magnetic susceptibility and productivity inorganic and organic carbon carbon isotopes benthic foraminifera and diatoms biogeochemical changes in the tagus prodelta reflect widely recognized north atlantic climatic periods encompassing the roman period ad 0 350 the dark ages ad 400 700 the mediaeval warm period mwp ad 800 1200 and the little ice age lia ad 1300 1750 the atmospheric north atlantic oscillation nao drives the tagus prodelta multidecadal long term variability in precipitation river input during cold periods negative nao and marine upwelling during warmer periods positive nao a scheme that is reversed in the galician region the muros ro a shows only local hydrodynamics until ad 1150 including a suboxic event in the inner ro a around ad 500 700 since ad 1150 atlantic warm upwelled waters have ventilated the outer ro a but only reach the inner ro a at ad 1750 the twentieth century records are also interpreted as a reflex of the inverse nao mode in both areas resulting in amplification of the lia biogeochemical water conditions centennial scale solar activity appears to be another important forcing mechanism or the only one if solar activity drives the nao and bond cycles behind changes in the hydrography of the tagus prodelta and primary production bottom ventilation and organic carbon degradation in the muros ro a

mid depth oxygen drawdown during heinrich events evidence from benthic foraminiferal community structure trace fossil tiering and benthic δ13c at the portuguese margin abstract the distribution of trace fossils and benthic foraminiferal assemblages in two sediment cores from 2160 m water depth at the northern and 1100 m at the southern portuguese continental margin was used to reconstruct the bottom water oxygenation during the last 40 ka emphasis was given to the heinrich events during which enhanced meltwater flux associated with the iceberg surges reduced or even halted deep water formation in the north atlantic condensed trace fossil tiering structures and high proportions of low oxygen tolerant benthic foraminifera suggest a major drawdown of bottom water oxygenation during heinrich events using the benthic foraminiferal oxygenation index bfoi of kaiho 1991 1994 that links benthic foraminiferal communities to ambient bottom water oxygenation we extracted apparent oxygen concentrations from benthic assemblages bfoi values suggest low oxic conditions during heinrich events 1 and 4 with mean oxygen levels of 2 6 to 2 8 ml l 1 and high oxic conditions with 4 1 ml l 1 during heinrich event 2 at the shallower site high proportions of low oxygen tolerant foraminiferal species and bfoi minima are recorded a few centimetres below the maximum concentrations of ice rafted debris indicating that the original microhabitat depth of dysoxic species is preserved beneath the heinrich layers even though bioturbation continued during the events trace fossil tiering calibrated with the redox boundary in low oxic environments and dysoxic ichnotaxa commonly associated with black shales indicate oxygen levels lower than those implied by the bfoi oxygenation estimates derived from trace fossil tiering denote low oxic conditions during h1 13 3 ka with oxygen concentrations slightly above 1 ml l 1 and dysoxic conditions during h2 20 6 ka h3 27 ka and h4 33 5 ka with oxygen concentrations between 0 1 and 1 ml l 1 during the younger dryas bottom waters likely were low oxic negative excursions of benthic carbon isotope values provide independent control on the oxygen drawdown during heinrich events considering a bottom water oxygenation of 6 1 to 6 5 ml l 1 during the last glacial the benthic 13 c minima reveal an oxygen depletion to values between 3 4 and 5 0 ml l 1 during h1 through h4 at the shallower core site differences between estimates from benthic 13 c bfoi and trace fossil tiering suggest that benthic foraminiferal communities are rather robust to oxygen depletion if the level does not fall below 3 ml l 1 whereas burrowing organisms react sensitively to depth variations of the redox boundary in near surface sediments due to even small changes of bottom water oxygenation

garnet chloritoid equilibria in eclogitic pelitic rocks from the sesia zone western alps their bearing on phase relations in high pressure metapelites abstract a detailed study of garnet chloritoid micaschists fom the sesia zone western alps is used to constrain phase relations in high pressure hp metapelitic rocks in addition to quartz phengite paragonite and rutile the micaschists display two distinct parageneses namely garnet chloritoid chlorite and garnet chloritoid kyanite talc has never been observed garnet and chloritoid are more magnesian when chlorite is present instead of kyanite the distinction of the two equilibria results from different bulk rock chemistries not from p t conditions or redox state estimated p t conditions for the eclogitic metamorphism are 550 600 c 15 18 kbar the presence of primary chlorite in association with garnet and chloritoid leads us to construct two possible afm topologies for the sesia metapelites the paper describes a kfmash multisystem for hp pelitic rocks which extends the grid of harte hudson 1979 towards higher pressures and adds the phase talc observed parageneses in hp metapelites are consistent with predicted phase relations critical associations are gt ctd chl and gt ctd ky at relatively low temperatures and gl chl ky and gt tc ky at relatively high temperatures

heat sources of cretaceous metamorphism in the eastern alps a discussion abstract the alpine orogenic cycle is characterised by a series of early metamorphic events that occurred in the cretaceous the eoalpine events a collection of data on peak metamorphic conditions pt paths and on relationships between structure and metamorphism for these events in the eastern alps shows that 1 eoalpine metamorphism occurred largely simultaneously with pervasive deformation 2 the eoalpine thermal peak was reached near the pressure peak 3 lower grade structurally higher rocks reached their metamorphic peak earlier than higher grade structurally lower rocks and there is a wide spread of metamorphic ages 4 low grade metamorphic conditions are probably more perturbed than high grade conditions and 5 there is a conspicuous regional distribution of metamorphic grade with amphibolite and eclogite facies metamorphism occurring predominantly in two regions located symmetrically west and east of the tauern window possible heating mechanisms are discussed that can satisfy these observations and a review of previous thermal models is provided it is shown that models which rely on conductive heat transfer cannot account for all of these observations in order to assess other heat sources the effects of shear heating are evaluated here with simple model calculations and a straightforward comparison of length and time scales of dissipative heat production the results suggest that shear heat episodically released during the stacking of the austroalpine nappe pile may be a significant contributor to the observed thermal perturbation

quantification of gas fluxes from the subcontinental mantle the example of laacher see a maar lake in germany abstract vertical and horizontal distributions of helium and neon isotopes were measured in the water of laacher see a maar lake in the east eifel volcanic field in germany neon is in approximate atmospheric equilibrium throughout the lake but the concentrations of both helium isotopes increase with depth and reach values of up to 10 4 he and 50 3 he times the atmospheric equilibrium concentration the isotopic ratio of the helium excess r ex 3 he ex 4 he ex is 7 42 0 03 10 6 i e r ex r a 5 36 0 02 where r a 1 384 10 6 is the isotopic ratio in air this indicates the presence of mantle derived helium laacher see is thermally stratified during the summer it acts as an almost perfect trap for injected gases the helium concentration in the hypolimnion deep water approximately doubled from may to september 1991 yielding a mean 4 he flux of 10 2 10 12 atoms m 2 s 1 this value is 30 times smaller than in lake nyos cameroon but 20 times larger than in crater lake usa release of bubbles of nearly pure co 2 99 observable in shallow waters at the eastern shore as well as detected by divers in about 30 m depth was identified as an important source of the helium excess in the lake if carefully sampled by divers to avoid air contamination the bubbles exhibit mantle influenced isotopic signatures not only for helium but also for neon and argon 20 ne 22 ne 9 92 0 03 40 ar 36 ar 391 4 based on the elemental ratios of carbon neon and argon to 3 he the fluxes of volatiles from the mantle into laacher see are determined as 7 4 10 7 atoms m 2 s 1 for 3 he 13 10 7 atoms m 2 s 1 for 20 ne 26 10 7 atoms m 2 s 1 for 361 ar and 6 4 10 17 molecules m 2 s 1 for co 2 non atmospheric neon was also found in the well wallenborn in the west eifel volcanic field with a 20 ne 22 ne ratio as high as 11 21 0 06

the metamorphic evolution of garnet cordierite sillimanite gneisses of the gruf complex eastern pennine alps metapelitic gneisses occuring as lenses and bands within the migmatites of the gruf complex in the eastern pennine alps contain various combinations of the minerals quartz biotite cordierite garnet sillimanite plagioclase k feldspar spinel orthopyroxene anthophyllite and muscovite the most common rock type is represented by a darkschistosebiotiterichcordierite garnet sillimanite gneiss a consistent pressure temperature range of 3 4 kb and 600 650 c has been calculated for the last metamorphic equilibration from six geological thermobarometers

the alpine geodynamic evolution of penninic nappes in the eastern central alps the eastern central alps consist of several pennine nappes with different tectonometamorphic histories the tectonically uppermost units oceanic avers bundnerschiefer continental suretta and tambo nappes oceanic vals bundnerschiefer show cretaceous early tertiary w directed thrusting with associated blueschist facies metamorphism related to subduction of the pennine units beneath the austroalpine continental crust this event caused eclogite facies metamorphism in the underlying continental adula nappe the gross effect was crustal thickening the tectonically lower continental simano nappe is devoid of any imprint from this event in the course of continent continent collision high t metamorphism and n directed movements occurred both affected the whole nappe pile more or less continuously from amphibolite to greenschist facies conditions crustal thinning commenced during the regional temperature peak a final phase is related to differential uplift under retrograde p t conditions further thinning of the crust was accommodated by e to ne directed extensional deformation

temperature and salinity records of the tyrrhenian sea during the last 18 000 years abstract we have used the modern analogue technique to derive sea surface temperature sst records of the last 18 000 years from two well dated deep sea cores recovered in the tyrrhenian sea results show two major cooling events synchronous with the european and north atlantic oldest and younger dryas events a later cooling of lower amplitude is observed between about 8000 and 4500 yr bp tyrrhenian ssts were similar to those of the upper holocene only during the bolling allerod event and at the beginning of the holocene we compared the sst and the planktonic foraminiferal oxygen isotope records to estimate the surface salinity variations our reconstruction shows that salinity decreased in the tyrrhenian sea during the three cold events whereas high ssts correlate with high salinities during most of the last 18 000 years tyrrhenian sea salinity variations were similar to those of the north atlantic ocean near the entrance of the mediterranean sea the salinity gradient between the two basins was thus constant indicating that the western mediterranean circulation pattern and the freshwater budget were not significantly different from the modern one the case was however different during the middle holocene when the strong salinity decrease associated with the sapropel deposit in the eastern mediterranean basin had no equivalent in the north atlantic ocean this peculiar event can only be explained by a local climatic change and an increase of precipitation

the plio pleistocene development of atlantic deep water circulation and its influence on climate trends abstract using benthic stable isotope records from 10 sites in the atlantic ocean including two new records from walvis ridge in the southeast atlantic sites 1264 and 1267 we review changes in atlantic deep water circulation in the context of plio pleistocene climate overall we find non linear responses of atlantic deep water circulation to a cooling climate with differently evolving glacial and interglacial states our main conclusion is that peak north atlantic deep water nadw production was reached between 2 0 and 1 5 ma most prominently seen by a maximum in ventilated high 13 c conditions in the mid depth southeast atlantic site 1264 we infer that a major source of nadw at this time was the export of dense overflow water from the nordic seas into the abyssal east atlantic sea surface temperature records from the north and south atlantic support this notion and indicate that the peak nadw production between 2 0 and 1 5 ma was compensated by a stronger warm surface water return flow i e atlantic meridional overturning circulation amoc was enhanced causing long term 10 5 year heat piracy from the south to the north atlantic in the wider picture of plio pleistocene climate evolution we find that a long term enhancement in the average state of amoc 2 4 1 3 ma coincides with the 41 kyr world hence we speculate that the transitory negative feedback response of enhanced amoc to a cooling climate supplied heat to key areas of ice sheet growth acting to limit their size and maintain the 41 kyr world once a threshold in global cooling was reached the strength of amoc lessened providing a positive feedback for the early middle pleistocene transition and the associated build up of northern hemisphere ice sheets

mediterranean functioning and sapropel formation respective influences of climate and hydrological changes in the atlantic and the mediterranean abstract during ocean drilling program odp legs 160 and 161 sapropels were recovered both in the western and eastern mediterranean this obliges to a reassessment of the previous studies focused on sapropels from only the eastern mediterranean and to consider the changes which occurred in the mediterranean climate but also in the water characteristics both in the atlantic and in the western mediterranean in the north atlantic the position of the polar front which migrated southwards during glacial times and the melting of northern ice caps during interglacial periods together with the convection in the labrador and norwegian seas appear essential to control the salinities of the waters facing the strait of gibraltar the salinities of the surface and intermediate layers constitute the first driving force of the mediterranean dynamics the second driving force being the mediterranean climate the stagnation of deep waters leading to sapropel deposition in the western mediterranean may be explained by a drastic weakening of the density difference between mediterranean outflow and atlantic intermediate waters facing the strait of gibraltar this weakening was induced primarily by the salinity decrease of atlantic surface water and secondly by a rather high salinity in the atlantic intermediate layer rather than by a drastic deterioration of the mediterranean climate this scenario probably concerns most of the sapropel events and it may be used for the knowledge of atlantic and mediterranean functioning over climatic changes

an overview of the post messinian paleoenvironmental history of the western mediterranean a review of the pliocene pleistocene paleoenvironmental history of the western mediterranean is presented based on micropaleontological and geochemical studies of ocean drilling program odp leg 107 material and marine outcrops in southern italy the calcareous plankton biochronology proposed for the mediterranean by rio et al 1990 and 1991a provides the necessary age control for determining the timing of major climatic and oceanographic changes in the region the early pliocene period in the mediterranean was not a time of warm stable climate rather it was marked by relatively high amplitude climatic oscillations in marginal areas these climatic oscillations resulted in the rhythmic deposition of limestone marl couplets which have an average duration of approximately 19 000 years it is proposed that these sedimentary couplets are the result of precessionally induced changes in monsoon intensity which in turn cause variability in coastal divergence and upwelling the 18o and the calcareous plankton foraminifera and coccoliths records for tyrrhenian sea odp site 653 reveal a cooling of surface waters at 3 1 ma coincident with this cooling is an increase in the frequency of diatomite formation in southern italy bianco section the global cooling at 2 4 ma and the associated expansion of northern hemisphere glaciation resulted in a shift to more arid conditions in the mediterranean region this climate change may have altered the mediterranean water balance resulting in the establishment of antiestuarine water exchange with the atlantic at this time the 18o record for site 653 is also marked by a sharp cooling across the pliocene pleistocene boundary in the boundary stratotype section at vrica this cooling is manifested as an increase in the abundance of the planktonic foraminifer neogloboquadrina pachyderma

north atlantic thermohaline circulation during the past 20 000 years linked to high latitude surface temperature during a surface cooling event 10 000 to 12 000 years ago higher cd ca and lower 13c 12c ratios are observed in benthic foraminifera shells from rapidly accumulating western north atlantic sediments data from sediment cores show that marked nutrient depletion of intermediate waters occurs in association with reduced glacial north atlantic deep water flux it is proposed that cold high latitude sea surface temperatures enhance intermediate water formation at the expense of deep water formation

variability in the deep and intermediate water circulation of the atlantic ocean during the past 25 000 years northern hemisphere modulation of the southern ocean the relative flux of north atlantic deep water nadw out of the atlantic can be monitored in the southern ocean where high 13c nadw mixes rapidly with low 13c recirculated pacific water before forming antarctic bottom water aabw by using 13c measured in benthic foraminifera as a water mass tracer it is shown that the southern ocean was dominated by pacific water with little nadw contribution during the last glaciation these tracer results document the direct physical connection between insolation controlled northern hemisphere oscillations and changes in the chemical and physical properties of southern ocean water the 13c records from the deep tropical atlantic document the transition from an atlantic dominated by southern ocean water during the last glaciation to an atlantic dominated by nadw during the holocene with more southern ocean water in the deep atlantic during the last glaciation the boundary between nadw and southern ocean water was north of its modern position allowing more southern ocean water to enter the eastern atlantic through the romanche fracture zone carbon isotope records from the caribbean and mediterranean seas suggest that the influence of mediterranean overflow water mow extended to the caribbean during the last glaciation and therefore was a volumetrically much more important water mass in the intermediate depth atlantic than it is today

foraminiferal reconstruction of barium distributions in water masses of the glacial oceans foraminiferal ba can be used to reconstruct the distribution of deeply regenerated chemical components in past oceans the ba contents of benthic foraminifera recovered from cores in the atlantic ocean indicate that waters deeper than 2900 m had 30 60 higher ba during the last glacial maximum lgm these changes are consistent with previously observed glacial nutrient enrichments based on foraminiferal cd and 13c increases in deepwater nutrient contents in the atlantic can be explained by reductions in north atlantic deep water formation during the lgm ba ca of benthic foraminifera from the glacial sections of intermediate depth atlantic cores are equal to or lower than holocene values this ba evidence argues against the mediterranean as a greatly increased source to atlantic intermediate waters during the lgm since the mediterranean is enriched in ba today and apparently remained enriched during the lgm benthic foraminiferal ba from the glacial sections of cores from the eastern equatorial pacific suggest that deep waters of the glacial pacific were about 25 lower in ba at 3000 m taken together the foraminiferal evidence indicates that the ba content of deep waters of the atlantic antarctic and pacific were similar at the lgm since foraminiferal cd distributions indicate that cd remained significantly lower in the deep atlantic relative to the pacific at the last glacial maximum a seven box ocean model is used to explore several scenarios for reconciling lgm ba and cd distributions while the changed distribution of both tracers suggests diminishment in the flux of nutrient depleted waters to the deep atlantic during the lgm increased atlantic upwelling rates and consequently enhanced ba particle fluxes can account for the the lack of ba fractionation between the deep atlantic and pacific the model suggests that ba can be transferred efficiently to the deep atlantic by enhanced upwelling because the vast majority of the ba is regenerated in the deep atlantic box

distribution of helium and tritium in lake baikal the 3 h 3 he age of a water mass is a measure of the time that has passed since the water mass was last in contact with the atmosphere between 1992 and 1995 a detailed study of 3 h 3 he ages was conducted in lake baikal the deepest and largest lake by volume on earth to investigate deep water renewal in its three major basins maximum 3 h 3 he ages are 14 17 years in the southern basin 16 18 years in the central basin and 10 11 years in the northern basin rates of renewal of deep water with surface water deduced from volume weighted mean 3 h 3 he ages below 250 m depth are about 10 yr 1 in the southern and central basins and 15 yr 1 in the northern basin in the southern basin the mean 3 h 3 he age below 250 m depth increased steadily from 9 6 years in 1992 to 11 years in 1995 indicating a slight diminution in deep water renewal during this time bottom water renewal by large scale advection was estimated from the mass balance of 3 he in the 200 m thick bottom layer of each basin bottom water renewal rates in the northern basin were found to be between 80 and 150 km 3 yr 1 and in the central basin between 10 and 20 km 3 yr 1 whereas in the southern basin they were practically zero correlating oxygen and dissolved helium 4 concentrations with 3 h 3 he age allowed us to determine the mean hypolimnetic oxygen depletion rate in the water column 4 5 mol l 1 yr 1 as well as mean helium fluxes from the lake bottom 2 8 x 10 11 atoms m 2 s 1 in the northern basin and 1 3 x 10 11 atoms m 2 s 1 in the central and southern basins the helium isotope ratio of the terrigenic helium component injected from the lake bottom determined from measurements of water from hydrothermal springs in the vicinity of the lake was found to be 2 2 x 10 7

high resolution stratigraphic correlation of benthic oxygen isotopic records spanning the last 300 000 years abstract in order to compare the response of different oceanographic regions to global climate change very detailed stratigraphic techniques are required the global signal of ice volume changes recorded in the oxygen isotopic composition of foraminifera can provide the tool for developing the necessary high resolution stratigraphy in order to evaluate the resolution of a stratigraphy based on detailed isotopic records two techniques are used to correlate a set of benthic oxygen isotope records from seven piston cores taken in the north and south atlantic the indian and the equatorial and north pacific oceans the first technique was modified from the graphic correlation procedure of shaw 1964 this procedure requires the identification of isotopic events that are correlated from core to core detailed correlations for intervals of the cores between events are provided by a series of straight line segments connecting all common events the second technique developed by martinson et al 1982 uses inverse procedures to define a continuous non linear mapping function that correlates the isotopic records the mapping function maximizes the correlation coefficient between data sets being compared the techniques are independent in that they rely on different criteria for correlating the data series stratigraphic correlations obtained by these procedures are in excellent agreement the mean difference between the correlations is on the order of the sampling intervals of each core and when corrected for sedimentation rates suggests that benthic isotope records from the suite of seven cores can be correlated to a resolution of 2000 to 4000 yrs

accumulation of mantle gases in a permanently stratified volcanic lake lac pavin france abstract lac pavin is a volcanic crater lake in the massif central france characterized by a permanent vertical density stratification resulting from a strong and persistent chemocline between about 60 and 70 m depth the deep water below the chemocline forms the monimolimnion in which most dissolved ions as well as helium carbon dioxide and methane are strongly enriched the 3he 4he isotope ratio of the excess helium is 9 09 0 01 10 6 or 6 57 0 01 ra these findings clearly indicate a flux of mantle derived magmatic gases into the monimolimnion in order to derive the fluxes of magmatic volatiles into lac pavin it is essential to understand the hydrologic characteristics of the lake previously published two box models have assumed groundwater input at the lake bottom a short residence time in the monimolimnion and biogenic origin of the co2 we propose an alternative model with a flux of magmatic gases but not of water into the monimolimnion and a weak diffusive coupling between the monimolimnion and the overlying mixolimnion which leads to a long deep water residence time 70 yr we reassess the carbon budget of the lake and conclude that the major part of the accumulated co2 in the monimolimnion is of magmatic origin from the model derived water exchange rates we calculated a mantle 4he flux of 6 2 1011 atoms m 2 s 1 this value lies near the lower end of the range found in comparable volcanic lakes the flux of magmatic co2 is estimated as 1 2 0 4 10 7 mol m 2 s 1 which is also comparatively low the monimolimnion appears to be in steady state with respect to these fluxes therefore no further potentially hazardous accumulation of co2 takes place

core top evaluation of benthic foraminiferal isotopic ratios for paleo oceanographic interpretations abstract the benthic foraminifera cibicides wuellerstrofi oridforsalis tener and pyrgo rotalaria from twelve core tops in the norwegian greenland sea and c wuellerstorfi o tener and o umbonatus from four core tops on the rio grande rise were analysed for oxygen and carbon isotopes the norwegian greenland sea data yield statistically discrete means for both 18o and 13c for each species the interregional comparison of our data to published data from the east pacific rise shows that c wuellerstorfi 18o and 13c variations reflect oceanographic differences between sites whereas the data on oridorsalis and pyrgo do not we conclude that c wuellerstorfi is a reliable sensor of bottom water conditions whereas other taxa are of unproven utility supportive biological studies and the lack of positive covariance of 18o to 13c among deep sea benthic taxa lead us to reject models calling for incorporation of metabolic co2 to explain the isotopic variation among deep sea benthic foraminifera we propose a within sediment microhabitat hypothesis to explain the 13c variations among taxa

late quaternary deep ocean circulation a review of paleoceanographic studies dealing with late quaternary deep water circulation in the oceans is presented these studies which are based on the analysis of deep sea benthic foraminiferal faunal and geochemical data and sedimentological data are discussed in light of physical oceanographic conditions in the modern ocean we include in this review a re evaluation of benthic foraminiferal data from north atlantic and southern ocean piston cores and suggest that the dominance of uvigerina during glacial intervals reflects increased amounts of organic carbon at the sea floor compared to modern values a number of geochemical studies have suggested that the production or characteristics of north atlantic deep water nadw changed during glacial times although these changes have been thought to result from a cessation of overflow water from the norwegian greenland seas it is suggested here that seasonal sea ice cover was possible over southern portions of the norwegian sea during glacial intervals the presence of seasonally open water would have allowed norwegian sea overflow water to have been produced although perhaps at lower volumes and with different hydrographic properties than at present the record of antarctic bottom water aabw circulation does not show a simple relationship with paleoclimatic oscillations indicating that changes in oceanographic conditions in the southern ocean had little effect on aabw formation the aabw record contrasts with the glacial interglacial cycles of nadw suggesting no direct link between aabw and nadw circulation a variety of data suggests that changes in pacific deep water circulation occurred as a result of glacial production of north pacific deep water or from an increased flux of southern ocean water

surface and deep water conditions in the sicily channel central mediterranean at the time of sapropel s5 deposition abstract new centennial scale data of benthic foraminifera assemblages and of stable isotopes of foraminifera shells from the sicily channel representative of surface and bottom waters over the interval between about 140 and 110 kyr bp are presented during this period anoxia developed on the eastern mediterranean basin and sapropel s5 deposited although anoxic sediments have not been deposited in the sicily channel this area is strategic to study the character of intermediate waters whose chemical physical properties strongly precondition the eastern mediterranean deep water formation so far no data from these water masses have been obtained apart from the isotopic composition of shells of the planktonic foraminifera species neogloboquadrina pachyderma which lives at about 200 m depth thus quite far from the intermediate water core we conclude that although with a reduced rate the flowing of intermediate waters coming from the eastern basin together with the surface water masses with a clear western affinity implies the maintenance of an anti estuarine circulation pattern across the sicily channel and in the mediterranean sea also during one of the most severe episodes of anoxia of the late pleistocene

alpine metamorphism of pelitic schists in the nufenen pass area lepontine alps the effects of tertiary alpine metamorphism on pelitic mesozoic cover rocks have been studied along a cross section in the central lepontine alps in the nufenen pass area switzerland greenschist facies to amphibolite facies conditions are indicated by the formation of the index minerals chloritoid garnet staurolite and kyanite in pelitic rocks regional metamorphism reached maximum conditions during the interkinematic period between a main alpine penetrative d2 and a late alpine d3 crenulation type deformation phase or synchronous with the late alpine deformation based on afm phase relationships four different metamorphic zones can be distinguished 1 chloritoid zone 2 staurolite chlorite zone 3 staurolite biotite zone and 4 kyanite zone the isograds that separate these zones can be modelled by univariant reactions in the kfmash system the conditions of metamorphism calculated from geological ther mobarometers for the maximum post d2 por phyroblast stage are from north to south 500 c at 5 6 kbar and 600 c at 7 8 kbar detailed thermobarometry of garnet por phyroblasts with complex textures suggests that maximum temperature was reached later than maximum pressure early garnet growth occurred along a prograde p t path post d2 rims grew with increasing temperature but decreasing pressure and finally post d3 garnet formed along a retrograde p t path it may be concluded from the calculated pressure and temperature difference over a short distance 3 km across the mapped area that the isogradic surfaces of the post d2 metamorphism are steeply oriented the data also suggest that isobaric and isothermal surfaces are parallel much of the observed metamorphic pattern can be explained as the result of a significant post d2 differential uplift of the hot pennine area relative to the helvetic area along a tectonic contact zone the closely spaced isograds isotherms in the north may then be interpreted as a thermal effect owing to the emplacement of the hot pennine rocks against the got thard massif with its cover whereas in the pennine metasediments post d2 porphyroblast formation can be related to the decompression path which was steep enough for dehydration reactions to proceed it is also remarkable that late kyanite porphyroblasts probably formed with decreasing pressure the interpretation given here for the nufenen pass area may also apply to the luk manier pass area where similar metamorphic patterns have been reported by fox 1975 the formation of the northern steep belt as denned by milnes 1974b and the associated late alpine fold zones may therefore have significantly modified the metamorphic pattern of the helvetic penninic contact zone

late quaternary mediterranean sapropels i on the origin of organic matter in sapropel s7 abstract at least twelve organic rich layers so called sapropels s1 s12 occur in late quaternary sediments from the eastern mediterranean organic matter in sapropel s7 organic carbon up to 11 is characterized in detail by gas chromatography gc and gas chromatography mass spectrometry gcms lipids were thus separated to obtain information about their mode of occurrence this procedure separates the lipids into three classes 1 free lipids extracted by soxhlet extraction 2 residual bound lipids extracted after saponification of the soxhlet extracted residue and 3 residual bound lipids extracted after acid treatment of the saponified residue in addition an extract was obtained after saponification of the free lipids the organic matter investigated is of a mixed marine e g dinoflagellates coccolithophorids terrigenous e g cuticles and bacterial origin with the former predominating the formation of sapropel s7 is probably caused by a combination of stagnation and high productivity both induced by a large input of fresh riverine water carrying nutrients and terrigenous organic material

tectonic controls of metamorphic field gradients abstract we investigate the effects of horizontal variations in tectonic factors heat production and rate amount and duration of erosion on the magnitudes and gradients of pressure p temperature t and cooling ages observed in mountain belts horizontal gradients of p t and cooling ages are largely controlled by two dimensionless parameters 1 the horizontal length scale over which erosion erosion rate or erosion duration varies and 2 the peclet number pe which describes the relative rates of advection and diffusion of heat in contrast the magnitudes of observed p and t depend strongly on the degree of thickening and original burial depth as well as pe and since horizontal heat conduction can usually be ignored do not depend strongly on p and t gradients generally increase with decreasing and pe for calculations in which either but not both erosion rate or erosion duration is horizontally constant p and t gradients are moderate in magnitude and increase in the direction of increasing total erosion in contrast calculations with horizontally constant total erosion but varying erosion rate and erosion duration show small temperature and pressure gradients pressures and temperatures can increase in the same or in opposite directions depending on the magnitude of calculations with horizontally varying crustal heat production show small but non zero temperature gradients and negligible pressure gradients these results indicate that knowledge of temperature pressure and cooling age gradients in individual mountain belts can constrain fundamental quantities such as magnitude and horizontal gradient of the exhumation rate and the average shear strain rate occurring during exhumation on the basis of their metamorphic field gradients most mountain belts can be divided into one of three groups the first and largest group shows strongly positive p and t gradients precambrian orogenic areas comprise the second group and have small t gradients

a new geobarometer for the assemblage biotite muscovite chlorite quartz the equilibrium thermodynamics of the reaction 4kmga1si40 o oh mg5a1 si30 o oh muscovlte chlorite muscovite biotite ka13si 0 oh 3kmg3aisi 0 0 oh 7si0 4h o quartz fluid can be formulated as a geobarometer thermo dynamic data for the mg a1 celadonite end member of muscovite is derived from the reversed mineral equilibria experiments of velde i 965 using the calculation method of powell 1978 giving afh 1298 5823 5 kj s 1298 0 3060kjk v 1298 13 8kjkbar

sedimentation on the feni drift and late glacial bottom water production in the northern rockall trough abstract between the last glacial maximum 18 ka and the present day a variety of contrasting oceanographic conditions including changes in surface and bottom water circulation patterns have existed in the north atlantic evidence for the presence of bottom currents in winnowed silt horizons in the feni drift suggests that deep water may have been produced in this region during glacial deglacial intervals current activity and thus perhaps deep water production was apparently intermittent and may have been controlled by a process analogous to the formation of labrador sea water this involves cooling and deep ocean convection during winter months physical factors controlling this production would be temperature and salinity of upper waters which would govern the density and wind stress necessary for vertical overturn coupled with absence of ice cover evidence of bottom current activity suggests that deep water production occurred in the rockall trough throughout termination 1a which closely corresponds to fairbanks 1989 meltwater pulse 1a mwp 1a production of deep water in this region apparently ceased shortly after the decline in influence of the meltwater influx

benthic isotope evidence for changes of the mediterranean outflow during the late quaternary a suit of sediment cores close to and south of the strait of gibraltar 12 36 n 500 2800 m water depth were analyzed for stable isotopes in epibenthic foraminifers cibicidoides wuellerstorfi and planulina ariminensis during peak glacial times the data exhibit higher 13c values of up to 1 6 at intermediate depths near the strait of gibraltar 36 n the values decrease to the south as evidenced by our data but also to the north as revealed by data of intermediate depth cores north of 38 n in duplessy et al 1987 thus the distribution pattern of 13c provides crucial evidence for an increased influence of nutrient depleted mediterranean outflow water mow on the glacial northeast atlantic hydrography during oxygen isotope terminations i and ii the meridional carbon isotope gradient indicates a significantly decreased but still active mow as deduced from the 18o fluctuations the temperatures of the mow in the atlantic were lower during glacial times by as much as 5 c during glacial times and during termination i the maximum 13c values of the mow correlate with minimum values of the north atlantic deep water nadw and vice versa this inverse response to climatic change of the carbon isotope signals of both water masses indicates that the supply of saline mow to the north atlantic may be less important for the formation of nadw than previously assumed

injection of mantle type helium into lake van turkey the clue for quantifying deep water renewal helium neon and tritium concentrations have been measured to study long term vertical mixing and deep water renewal in lake van eastern turkey the largest soda lake on earth helium excesses were found in the water column of lake van although neon concentrations were close to air saturation the excesses of both isotopes are strictly correlated and increase with depth in the bottom water 4he supersaturation is about 20 and the corresponding 3he concentration is 2 5 times the air saturation value the mean excess 3he 4he ratio of 1 1 2 10 5 is slightly higher than the morb ratio found in lake nemrut a neighbouring volcanic crater lake in which a large input of mantle helium was detected mantle helium accounts for the majority of the helium excesses in lake van although part of the 3he excess is attributed to the presence of tritium a one dimensional lake model was used which describes tritium input vertical mixing and gas exchange to reconstruct the evolution of the helium isotopes and the tritium as a conclusion the model based on the measured 3he and 4he profiles shows that 1 the vertical exchange of deep water occurs within 1 2 yr 2 the flux of mantle helium into the lake averaged over the total cross section of lake van is 0 23 0 35 cm3 stp m 2 yr 1 2 3 1011 atoms m 2 s 1 the present estimate of the global mantle helium flux averaged over the total surface area of the earth is 3 9 109 atoms m 2 s 1 the flux into lake van would account for at least 0 04 0 06 of this

spatial distribution and flux of terrigenic he dissolved in the sediment pore water of lake van turkey abstract in this study the largest ever carried out to measure noble gases in the pore water of unconsolidated sediments in lakes the emission of terrigenic he through the sediment column of lake van was successfully mapped on the local scale the main input of he to the water body occurs at the borders of a deep basin within the lake which is probably the remains of a collapsed caldera the 3 he 4 he ratio identifies the he injected into the sedimentary column of lake van as a mixture of he released from a mantle source and radiogenic he of crustal origin 3 he 4 he 2 6 4 1 10 6 during passage through the pore space terrigenic he seems to be further enriched in radiogenic he that is most likely produced in the sediment column in fact two distinct trends in isotopic composition can be distinguished in the he injected from the lake basement into the sediments one of these characterizes samples from the shallow water the other characterizes samples from the deep basin however both of these trends are related to the same source of terrigenic he the he fluxes determined seem to be characteristic of each sampling location and might be considered as a proxy for the fluid permeability of the deep sediment column these new findings provide insight into the process of fluid transport within the sediments and into the process of formation of the lake basin moreover the isotopic signature of the he that emanates into the water column of lake van is strongly affected by the mixing conditions prevailing in the overlying water body this fact misled previous studies to interpret the terrigenic he in lake van as being solely of mantle origin 3 he 4 he 10 5

benthic foraminiferal δ13c and accumulation rates of organic carbon uvigerina peregrina group and cibicidoides wuellerstorfi the glacial to interglacial 13c records of the benthic foraminifera cibicidoides wuellerstorfi and the uvigerina peregrina group from deep sea cores cannot be adjusted by a generally valid constant the 13c values of the u peregrina group largely correlate with the accumulation rates of organic carbon suggesting a local habitat effect those of c wuellerstorfi vary independently with respect to the carbon flux and record fluctuations in the 13c of the ambient bottom water isotopic composition