palaeo moisture evolution in monsoonal central asia during the last 50 000 years abstract the late quaternary climate history of monsoonal central asia was inferred from 75 palaeoclimatic records which provide information about moisture conditions in the last 50 ka or part of this period wet conditions occurred during middle and late marine isotope stage 3 while the last glacial maximum lgm was characterized by dry climate conditions in the region a stepwise climate amelioration is suggested by the climate records following the lgm several climate signals of this period which were reported from high latitude ice core records are preserved in archives from monsoonal central asia as well during the early holocene high effective moisture was inferred from most records from the area dominated by the indian monsoon e g the tibetan plateau suggesting that holocene optimal climate conditions occurred there during this period in contrast areas which are dominated by the south east asian monsoon se monsoon and the westerlies in north western and north central china mongolia do not uniformly show an early holocene climate optimum for this area optimal conditions prevailed during the mid holocene these apparent contradictions can possibly be explained by the regional uplift and descent of air masses in the holocene during the early holocene strengthened insolation possibly caused an enhanced low level convergence over the tibetan plateau which led to the intensification of the summer monsoon the strong air uplift caused intensified precipitation and air divergence in the upper troposphere over the tibetan plateau the areas adjacent to the north therefore experienced an intensified descent of air masses and consequently increased aridity the majority of the palaeoclimatic records suggest reduced effective moisture since the late holocene in the region

marked decline in atmospheric carbon dioxide concentrations during the paleogene the relation between the partial pressure of atmospheric carbon dioxide pco2 and paleogene climate is poorly resolved we used stable carbon isotopic values of di unsaturated alkenones extracted from deep sea cores to reconstruct pco2 from the middle eocene to the late oligocene approximately 45 to 25 million years ago our results demonstrate that pco2 ranged between 1000 to 1500 parts per million by volume in the middle to late eocene then decreased in several steps during the oligocene and reached modern levels by the latest oligocene the fall in pco2 likely allowed for a critical expansion of ice sheets on antarctica and promoted conditions that forced the onset of terrestrial c4 photosynthesis

fractal dimension and its translation into a model of gold spatial proxy abstract unraveling the spatial distribution of mineral deposits is an essential part of exploration and important for developing a better understanding of ore forming processes in this study gold assay results in g t of twelve boreholes completed from mysore block and eleven boreholes completed from nabhapur north block central lode system gadag gold field ggf india were analyzed using fractal analysis both the fractal correlation integral and rescaled range analysis were used to measure the fractal dimension from the gold concentration values the fractal dimension values obtained from the fractal correlation integral were used to better constrain the possible auriferous fluid flow pathways whilst results obtained from the rescaled range analysis were used to describe the behavior of auriferous veins across the boreholes the fractal dimension values were found to vary from 0 014 to 3 0 with the higher values taken to indicate the presence of well developed interconnected fault fracture networks representing steep permeable fluid flow pathways the lower fractal dimension values were taken to indicate unfavorable fluid flow pathways in other words higher grade gold ores were deposited along the structures represented by steep fractal gradients hurst exponent h values obtained from the rescaled range analysis were found to vary from 0 50 to 0 96 satisfying the condition 0 5

carbon isotopic compositions of long chain n alkanes in the japan sea sediments implications for paleoenvironmental changes over the past 85 kyr abstract carbon isotopic compositions of long chain n alkanes in cores kh 79 3 c 3 and l 3 taken from the oki ridge 37 04 n 134 42 e water depth 935 m in the japan sea were measured by gas chromatography isotope ratio mass spectrometry fluctuations in the carbon isotopic composition of terrestrially derived material as determined from 13 c n alkane weighted average of 13 c values for higher plant derived n c29 and n c31 alkanes range from 29 1 to 32 1 for the past 85 kyr in core kh 79 3 c 3 13 c n alkane values in colder climates 18 o stages 2 and 4 are depleted in 13 c by approximately 1 relative to those in warmer climates stages 1 3 and 5 1 this suggests that the temporal variations of the 13 c values for higher plant derived n alkanes exhibit a close relationship with glacial interglacial cycles the results over the past 30 kyr 14 c age reveal that the 13 c n alkane values shifted abruptly from 31 1 0 5 to 29 9 0 4 at around 10 kyr b p with the isotopic values remaining relatively constant thereafter this positive 1 2 shift in 13 c n alkane values can be attributed to one or both of the following factors i enhancement of primary productivity on land and ii change in vegetational types e g c4 c3 plants ratios and or changes in the species of c3 plants

multiple expansions of c4 plant biomass in east asia since 7 ma coupled with strengthened monsoon circulation the expansion of plants using the c4 photosynthetic pathway is one of the most prominent changes in the global ecosystem during the cenozoic era a significant late miocene expansion is well documented however the existence and cause of subsequent expansions are still not clear owing in part to the lack of long continuous climate vegetation records here we present two high resolution carbon isotope time series covering the past 7 m y derived from eolian deposits on the chinese loess plateau the data indicate three intervals of significant c4 plant expansions within the semiarid monsoonal region of east asia ca 2 9 2 7 ma 1 3 0 9 ma and 0 6 ma present these expansions covary with strengthened east asian summer monsoon circulation we conclude that in east asia large scale late miocene c4 c3 vegetation changes in semiarid areas have been primarily driven by warm seasonal precipitation and temperature variations associated with changes in monsoon circulation

a 16 ma record of paleodiet using carbon and oxygen isotopes in fossil teeth from pakistan abstract the siwalik sequence of northern pakistan contains a 16 ma record of paleosol carbonate and fossil teeth from which a record of paleovegetation can potentially be reconstructed and compared the carbon isotopic composition of paleosol carbonate and organic matter from siwalik strata reflects a major paleoecological change on the floodplains of major rivers beginning7 3 ma ago by 6 ma c 3 dominated plant communities probably composed of mostly trees and shrubs were displaced by nearly continuous c 4 grassland we find that the carbon isotopic ratios in herbivore tooth enamel reflect this dramatic ecologic shift carbonate in enamel older than 7 ma averages 11 in 13 c pdb consistent with a largely c 3 diet enamel from the plio pieistocene averages 1 9 in 13 c similar to the value displayed by modern c 4 grazers analysis of post burial carbonate cements and the concordance with isotopic evidence from paleosols argues strongly against major isotopic alteration of the enamel while coexisting bone may have been altered early in burial this study confirms that enamel apatite is useful for paleodietary reconstruction much further back in the geologic record than was previously thought

the strontium isotopic budget of himalayan rivers in nepal and bangladesh abstract himalayan rivers have very unusual sr characteristics and their budget cannot be achieved by simple mixing between silicate and carbonate even if carbonates are radiogenic we present sr o and c isotopic data from river and rain water bedload and bedrock samples for the western and central nepal himalaya and bangladesh including the monsoon season central himalayan rivers receive sr from several sources carbonate and clastic tethyan sediments high himalayan crystalline hhc gneisses and granitoids with minor marbles carbonates and metasediments of the lesser himalaya lh and miocene recent foreland basin sediment from the siwaliks group and the modern flood plain in the tethyan himalaya rivers have dissolved sr 6 mol l and 87sr 86sr 0 717 with a large contribution from moderately radiogenic carbonate rivers draining hhc gneisses are very dilute with sr 0 2 mol l and 87sr 86sr 0 74 lesser himalayan streams also have low sr 0 4 mol l and are highly radiogenic 87sr 86sr 0 78 highly radiogenic carbonates of the lh do not contribute significantly to the sr budget because they are sparse and have very low sr in large rivers exiting the himalaya sr systematics can be modeled as a mixture between tethyan rivers where slightly radiogenic carbonates mean 87sr 86sr 0 715 are the main source of sr and lesser himalaya waters where extremely radiogenic silicates 0 8 are the main source of sr hhc waters are less important because of their low sr rivers draining the siwaliks foreland basin sediments have sr 4 mol l and 87sr 86sr 0 725 weathering of silicates in the siwaliks and the flood plain results in a probably significant radiogenic 0 72 0 74 input to the ganges and brahmaputra g b but quantification of this flux is limited by uncertainties in the hydrologic budget the g b in bangladesh show strong seasonal variability with low sr and high 87sr 86sr during the monsoon sr in the brahmaputra ranges from 0 9 mol l and 0 722 in march to 0 3 mol l and 0 741 in august we estimate the seasonally weighted flux from the g b to be 6 5 108 mol yr with 87sr 86sr 0 7295

tracing the distribution of erosion in the brahmaputra watershed from isotopic compositions of stream sediments bank sediments and suspended loads of the brahmaputra river and its important tributaries were collected from the himalayan front to bangladesh along with most of the important tributaries chemical and isotopic compositions of the sediments are used to trace sediment provenance and to understand erosion patterns in the basin overall isotopic compositions range from 0 7053 to 0 8250 for sr and nd from 20 5 to 6 9 this large range derives from the variable proportions of sediments from himalayan formations with high sr isotopic ratios and low nd and transhimalayan plutonic belt with lower sr isotopic ratios and higher nd the latter are exposed to erosion in the tsangpo and in the eastern tributary drainages overall erosion of the himalayan rocks is dominant representing ca 70 of the detrital influx compositions of the brahmaputra main channel are rather stable between 0 7177 and 0 7284 for sr and between 14 4 and 12 5 for nd throughout its course in the plain from the siang tsangpo at the foot of the himalayan range down to the delta this stability despite the input of large himalayan rivers suggests that the siang tsangpo river represents the major source of sediment to the whole brahmaputra geochemical budget implies that erosion of the namche barwa zone represents about 45 of the total flux at its outflow before confluence with the ganga from only 20 of the mountain area higher erosion rates in the eastern syntaxis compared to the other himalayan ranges is related to the rapid exhumation rates of this region possibly triggered by higher precipitation over the far eastern himalaya and the high incision potential of the tsangpo river due to its very high water discharge

molecular and isotopic records of c4 grassland expansion in the late miocene abstract siwalik paleosol and bengal fan sediment samples were analyzed for the abundance and isotopic composition ofn alkanes in order to test for molecular evidence of the expansion of c4 grasslands on the indian subcontinent the carbon isotopic compositions of high molecular weight alkanes in both the ancient soils and sediments record a shift from low 13c values ca 30 to higher values ca 22 prior to 6 ma this shift is similar in magnitude to that recorded by paleosol carbonate and fossil teeth and is consistent with a relatively rapid transition from dominantly c3 vegetation to an ecosystem dominated by c4 plants typical of semi arid grasslands the n alkane values from our paleosol samples indicate that the isotopic change began as early as 9 ma reflecting either a growing contribution of c4 plants to a dominantly c3 biomass or a decrease in water availability to c3 plants molecular and isotopic analyses of other compounds including n alcohols and low molecular weightn alkanes indicate paleosol organic matter contains contributions from a mixture of sources including vascular plants algae and or cyanobacteria and microorganisms a range of inputs is likewise reflected in the isotopic composition of the total organic carbon from these samples in addition then alkanes from two samples show little evidence for pedegenic inputs and we suggest the compounds were derived instead from the paleosol s parent materials we suggest the record of vegetation in ancient terrestrial ecosystems is better reconstructed using isotopic signatures of molecular markers rather than bulk organic carbon this approach provides a means of expanding the spatial and temporal records of c4 plant biomass which will help to resolve possible tectonic climatic or biological controls on the rise of this important component of the terrestrial biosphere

compositional polarity of triassic granitoids in the qinling orogen china implication for termination of the northernmost paleo tethys abstract the qinling orogen was formed from the closure of the northernmost paleo tethys sea and the tectonic suturing of the yangtze and north china cratons the timing of this collision and the tectonic framework are debated the widely developed triassic granitoids in the western qinling orogen offer a key to understand the tectonic evolution of this region here we compile the geological geochemical and geochronological data of the triassic granitoids from the qingling orogen and conclude that the granitoids north of the mian lue suture were emplaced in an active continental margin related to the northward subduction of the mian lue oceanic plate during 248 200 ma the granitoids can be classified into i and s types with the former constituting the major variety northward from the mian lue fault an s type granite belt appears followed by and locally overlapping with an i type granite belt the i type granite belt can be subdivided into four sub belts from south to north with increasing contents of k2o k2o na2o sio2 th and u and the ratios of k2o na2o rb sr and 87sr 86sr i but decreasing contents of na2o al2o3 mg and ehf t except for the northernmost belt which occurs in the huaxiong block of the north china craton this geochemical polarity of i type granitoids and the zoned distribution of s and i types granitoids cannot be explained through continental collision orogeny including syn to post collision but can be well interpreted by considering the progressive subduction of the northernmost branch of the paleo tethys as represented by the mian lue ocean thus the termination of the northernmost paleo tethys and the onset of the continental collision between the yangtze and the north china plates are considered to have occurred at about 200 ma during the transition from triassic to jurassic our model is also supported by the available data from other studies and provides a revised framework for the timing and tectonics of assembly of the yangtze and the north china cratons

loading and fate of particulate organic carbon from the himalaya to the ganga brahmaputra delta abstract we use the evolution of river sediment characteristics and sedimentary corg from the himalayan range to the delta to study the transport of corg in the ganga brahmaputra system and especially its fate during floodplain transit a detailed characterisation of both mineral and organic particles for a sampling set of river sediments allows taking into account the sediment heterogeneity characteristic of such large rivers we study the relationships between sediment characteristics mineralogy grain size specific area and corg content in order to evaluate the controls on corg loading contributions of c3 and c4 plants are estimated from corg stable isotopic composition 13corg we use the evolution of 13corg values from the himalayan range to the delta in order to study the fate of corg during floodplain transit ganga and brahmaputra sediments define two distinct linear relations with specific area in spite of 4 5 times higher specific area ganga sediments have similar corg content grain size and mineralogy as brahmaputra sediments indicating that specific area does not exert a primary control on corg loading the general correlation between the total corg content and al si ratio indicates that corg loading is mainly related to 1 segregation of organic particles under hydrodynamic forces in the river and 2 the ability of mineral particles to form organo mineral aggregates bed and suspended sediments have distinct 13corg values in bed sediments 13corg values are compatible with a dominant proportion of fossil corg derived from himalayan rocks erosion suspended sediments from himalayan tributaries at the outflow of the range have low 13corg values 24 8 average indicating a dominant proportion of c3 plant inputs in the brahmaputra basin 13corg values of suspended sediments are constant along the river course in the plain on the contrary suspended sediments of the ganga in bangladesh have higher 13corg values 22 4 to 20 0 consistent with a significant contribution of c4 plant derived from the floodplain our data indicate that during the plain transit more than 50 of the recent biogenic corg coming from the himalaya is oxidised and replaced by floodplain corg this renewal process likely occurs during successive deposition erosion cycles and river course avulsions in the plain

c4 plants decline in the himalayan basin since the last glacial maximum abstract the bengal fan turbiditic system supplied by the ganga brahmaputra river system provides an integrated record of himalayan system erosion thanks to minor inputs of marine organic matter and almost complete preservation of riverine organic carbon organic matter buried in bengal fan sediments is a proxy of himalayan basin paleo vegetation the active channel levee system of the middle fan documents the last 19 ka and allows the reconstruction of vegetation change in the himalayan basin since the last glacial maximum lgm we measured 13 c of organic carbon c org in order to track changes in the proportions of c3 and c4 plants in the himalayan basin from lgm to mid holocene 13 c of bulk c org shifts of 3 4 towards more negative values relative abundance of individual n alkanes reveals that terrestrial higher plant inputs represent a dominant fraction of c org buried in bengal fan sediments 13 c of higher plants biomarkers mimic that of bulk c org showing that the later can be used as continental paleo vegetation proxy 13 c negative shift from lgm to mid holocene mostly indicates the transition from a dominant input of c4 plants to a dominant input of c3 plants and therefore reveals that c4 plants were more abundant in the basin under glacial conditions vegetation repartition in the basin simulated using the caraib dynamic vegetation model is consistent with c org data the model indicates a dominance of c4 plants in the gangetic plain during the lgm while eastern part of the basin remains dominated by c3 plants the comparison between our data and proxies of regional paleo climate suggests that the large decline of c4 plants after the lgm was due to combined increase of atmospheric co 2 and humidity levels integrated record of himalayan basin paleo vegetation suggests more arid conditions during the lgm than during the mid holocene and agrees with reconstructions of the monsoon indicating stronger sw monsoon during interglacial and stronger ne monsoon during glacial periods

neogene himalayan weathering history and river87sr86sr impact on the marine sr record abstract clastic sediments in the bengal fan contain a neogene history of erosion and weathering of the himalaya we present data on clay mineralogy major element stable and radiogenic isotope abundances from lower miocene pleistocene sediments from odp leg 116 nd and sr isotope data show that the himalayan provenance for the eroded material has varied little since 17 ma however from 7 to 1 ma smectite replaces illite as the dominant clay while sediment accumulation decreased implying an interval of high chemical weathering intensity but lower physical erosion rates in the ganges brahmaputra gb basin o and h isotopes in clays are correlated with mineralogy and chemistry and indicate that weathering took place in the paleo gangetic flood plain the87sr86sr ratios of pedogenic clays vermiculite smectite record the isotopic composition of sr in the weathering environment and can be used as a proxy for87sr86sr in the paleo gb basin the sr data from pedogenic clays shows that river87sr86sr values were near 0 72 prior to 7 ma rose rapidly to 0 74 in the pliocene and returned to 0 72 in the middle pleistocene these are the first direct constraints available on the temporal variability of87sr86sr in a major river system the high87sr86sr values resulted from intensified chemical weathering of radiogenic silicates and a shift in the carbonate silicate weathering ratio modeling of the seawater sr isotopic budget shows that the high river87sr86sr values require a ca 50 decrease in the sr flux from the gb system in the pliocene the relationship between weathering intensity 87sr86sr and sr flux is similar to that observed in modern rivers and implies that fluxes of other elements such as ca na and si were also reduced increased weathering intensity but reduced sr flux appears to require a late miocene pliocene decrease in himalayan erosion rates followed by a return to physically dominated and rapid erosion in the pleistocene in contrast to the view that increasing seawater87sr86sr results from increased erosion mio pliocene to mid pleistocene changes in the seawater sr budget were the result of reduced erosion rates and sr fluxes from the himalaya

expansion of c4 grasses in the late miocene of northern pakistan evidence from stable isotopes in paleosols stable isotopic clay mineralogic and bulk chemical analyses were conducted on paleosols of the neogene siwalik sections in northern pakistan in order to reconstruct floodplain environments over the past 17 ma the stable carbon isotopic composition of soil carbonate mean 13c pdb 10 2 and associated organic matter mean 13c pdb 24 1 in paleosols representing 17 7 3 ma reveal that floodplain vegetation was dominated by c3 plants at 7 3 ma a shift toward more positive carbon isotopic values began signaling the gradual expansion of c4 grasses onto the floodplain from 6 ma to present carbon isotopic values for paleosol carbonate mean 13c pdb 0 6 and organic matter mean 13c pdb 14 4 are uniformly enriched in 13c indicating the presence of nearly pure c4 grassland the scarcity of kaolinite and abundance of smectite and pedogenic carbonate in most paleosols suggest that rainfall in the region remained 1 0 1 25 m yr or less for the entire 17 ma of record paleosols in the lower portion of the section lack organic a horizons but have reddish b horizons often containing secondary iron oxide nodules leaching depths of soil carbonate in these older paleosols are typically greater than those in the plio pleistocene part of the section where organic a horizons are common and b horizons are markedly more yellow the combined evidence suggests that the mature paleosols in the pre 7 3 ma part of the record are dominantly calcareous alfisols or mollisols that once underlay nearly pure c3 vegetation perhaps trees and shrubs while calcareous mollisols underlying c4 grassland dominate the upper part of the record the carbon and oxygen isotopic trends in the paleosol record in pakistan are also evident in the diet of fossil mammals and in paleosols from nepal thus demonstrating that these paleoenvironmental changes in floodplain vegetation may be continent wide local effects such as the development or intensification of the asian monsoon driven by uplift of the tibetan plateau may have led to the expansion of c4 grasses if however the expansion of c4 grasses proves globally synchronous then a larger scale cause such as a marked decrease in co2 may be the driving mechanism

oxygen isotope salinity relationship in the northern indian ocean we analyze the surface 18o salinity relationships of the bay of bengal and the arabian sea in the northern indian ocean known for their contrasting hydrological conditions new measurements of these tracers show a very low 18o salinity slope associated with the strong dilution in the bay of bengal but a slope more typical of this latitude in the arabian sea although this region is marked by a complex monsoonal regime numerical modeling using a box model and a general circulation model is able to capture the 18o salinity slope and its geographical variation both models clearly show that the low 18o salinity slope is due to the evaporation minus precipitation balance with an important contribution of the continental runoff in the bay of bengal although the low value of these slopes 0 25 makes past salinity reconstructions uncertain insight into the last glacial maximum conditions shows a probable stability of these slopes and limited error on paleosalinity

was donggou porphyry mo deposit derived from taishanmiao batholith the donggou porphyry mo deposit located in ruyang county of henan province is a giant ore deposit discovered in recent years the donggou molybdenum bearing porphyry is considered to be an apophysis or a fractionated product from the adjacent tai shanmiao batholith accordingly the ore forming process of this deposit seems to be relevant to the differentiation of taishanmiao batholitic magma based on an analysis of geology petrology geochemistry and temperature field the authors hold that the donggou granite porphyry is a product of another magmatic activity independent of taishanmiao batholitic magma as shown by the following evidence according to the age data available the taishanmiao batholith was generated earlier than the donggou porphyry by 3 ma suggesting that the two intrusions were not contemporaneous the thickness of the taishanmiao batholith is about 3 5 km and the exposed elevation is higher than donggou porphyry by 600 m and there are no larger faults within the distance of about 7 km between the intrusions such a spatial relationship is not consistent with the differentiation model of a deep magma chamber the donggou porphyry containing high temperature quartz phenocrysts is a product consolidated from the high temperature magma on the contrary the taishanmiao batholith is a pluton with relatively low initial temperature there are pb zn ore deposits or spots composing a relatively complete ring with the donggou porphyry as the center showing that there existed a temperature field around the donggou porphyry and that the temperature field was not destroyed by the heat from the taishanmiao intrusion during mineralization therefore the donggou porphyry should not be considered as an apophysis or a product fractionated from the adjacent taishanmiao batholith in addition based on the average mo concentration of granotoid and the latest experimental data of molybdenum solubility in the ore bearing fluid the mass balance calculation shows that the donggou porphyry was unable to provide adequate ore forming matter to form a giant deposit therefore the formation of the donggou porphyry mo deposit is attributed to the contribution from additional sources of ore forming matter accordingly the donggou porphyry mo deposit can be thought to be genetically related to the trans magmatic fluid that is to say the magmatic system and the ore forming system can be regarded as two independent geo logical systems a comprehensive analysis indicates that donggou porphyry magma was derived from the lower crust deeper than 30 km and the ore forming matters and fluids had different sources

late miocene vegetation reconstruction with the caraib model abstract climatic outputs from the atmospheric general circulation model echam4 coupled to a mixed layer ocean model are used as inputs to the caraib global vegetation model to reconstruct the distribution of vegetation and the biosphere carbon stocks over the continents during the late miocene tortonian the results show significant changes in the geographical distribution of vegetation during the late miocene compared to the present with a reduction of desert areas and an expansion of tropical seasonal forests which reached temperate latitudes these changes in vegetation distribution are accompanied by a moderate increase of the total biosphere carbon stock by 159 gt sensitivity tests to atmospheric co 2 have also been performed with the vegetation model only i e while keeping constant all climatic variables to their reference tortonian state these tests point out the potential importance of co 2 fertilization both regarding vegetation distribution and biosphere carbon storage the impact of an atmospheric co 2 decrease from 280 to 200 ppmv or increase from 280 to 560 ppmv on the vegetation distribution appears to be at least as large as that of the climate change between the tortonian and the present while in terms of carbon storage the impact of atmospheric co 2 is far much larger than the climatic one although the actual response of vegetation to co 2 fertilization may be much smaller than its theoretical response in the model these results emphasize the need to consider atmospheric co 2 as an important parameter for palaeovegetation reconstructions

late miocene atmospheric co2 concentrations and the expansion of c4 grasses the global expansion of c4 grasslands in the late miocene has been attributed to a large scale decrease in atmospheric carbon dioxide co2 concentrations this triggering mechanism is controversial in part because of a lack of direct evidence for change in the partial pressure of co2 pco2 and because other factors are also important determinants in controlling plant type distributions alkenone based pco2 estimates for the late miocene indicate that pco2 increased from 14 to 9 million years ago and stabilized at preindustrial values by 9 million years ago the estimates presented here provide no evidence for major changes in pco2 during the late miocene thus c4 plant expansion was likely driven by additional factors possibly a tectonically related episode of enhanced low latitude aridity or changes in seasonal precipitation patterns on a global scale or both

development of asian monsoon revealed by marked ecological shift during the latest miocene in northern pakistan carbon isotopes from soil carbonate1 4 and soil organic matter5 6 yield palaeoecological information because the carbon in the soil carbonate forms in isotopic equilibrium with local soil co2 refs 1 7 the isotopic composition of which is in turn determined by local plant cover siwalik group sediments in northern pakistan contain a well exposed palaeosol record spanning the past 18 myr here we report on stable carbon isotope results from associated pedogenic carbonate which indicate a dramatic ecological shift from to dominated floodplain biomass beginning 7 4 7 0 myr ago the earlier c3 floodplain biomasses were probably mainly composed of trees and shrubs whereas c4 grasslands dominated in the plio pleistocene oxygen isotopes also exhibit a shift in the latest miocene probably corresponding to a major climate change which may have induced the forest to grassland transition this dramatic ecological shift in the latest miocene may mark the inception or a marked strengthening of the asian monsoon system

comparison of late pleistocene and modern glacier extents in central nepal based on digital elevation data and satellite imagery abstract late pleistocene and modern ice extents in central nepal are compared to estimate equilibrium line altitude ela depressions new techniques are used for determining the former extent of glaciers based on quantitative objective geomorphic analyses of a 90 m resolution digital elevation model dem for every link of the drainage network valley form is classified as glacial or fluvial based on cross valley shape and slope statistics down valley transitions from glacial to fluvial form indicate the former limits of glaciation in each valley landsat multispectral scanner imagery for the same region is used to map current glacier extents for both full glacial and modern cases elas are computed from the glacier limits using the dem and a toe to headwall altitude ratio of 0 5 computed ela depressions range from 100 900 m with a modal value of 650 m and a mean of 500 m values consistent with previously published estimates for the central himalaya but markedly smaller than estimates for many other regions we suggest that this reflects reduced precipitation rather than a small temperature depression consistent with other evidence for a weaker monsoon under full glacial conditions

δ13c of organic carbon in the bengal fan source evolution and transport of c3 and c4 plant carbon to marine sediments carbon isotopic measurements on organic carbon oc in sediment cores from the bengal fan odp leg 116 show a dramatic 10 increase beginning ca 7 ma ago and a rapid decrease after 0 9 ma these shifts reflect changes in the mixing ratio of terrigenous carbon derived from c3 and c4 plants the rapid increase in 13c of bengal fan oc at 7 ma shows that late miocene expansion of c4 plants already documented in the siwaliks was widespread over all the himalayan foreland after 7 ma relations of 13c with sedimentological parameters show that c4 plants dominate in the foreland whereas c3 plants remain abundant in the mountain range variations in the source of the sediments and of the oc appear to be sensitive to climate hydrologic conditions in the basin major changes in the isotopic composition of the carbon flux in one of the worlds largest river systems modify the isotopic budgets of both marine dissolved carbon and the sedimentary carbon mass

terrestrial vegetation change inferred from n alkane σ13c analysis in the marine environment abstract we report gas chromatography isotope ratio monitoring mass spectrometry gc irm ms measurements of the 13c values of individual biomarker compounds n alkanes extracted from a 3 m marine sediment core taken near the mouth of the johnstone river north queensland australia the technique allows a purely terrestrial isotope signal to be discerned despite mixing of terrestrial and marine derived carbon the results indicate that there has been a 2 increase in the 13c values of terrestrially derived n alkanes c29 c33 since clearing of the forested johnstone river drainage basin for sugarcane and pasture began in the late 19th century a much slower 1 increase in 13c values after 6 000 years bp and prior to european settlement may be related to a decrease in rainfall in the basin or to an increase in the abundance of c4 plants as a result of increased aboriginal burning the results from the sediment core are consistent with data obtained for modern river sediments from forested and cleared subcatchments within the basin and demonstrate that the 13c values of terrestrially derived n alkanes in the marine environment can be used to assess basin wide vegetation changes in adjacent river catchments on geological timescales

mesozoic molybdenum deposits in the east qinling dabie orogenic belt characteristics and tectonic settings abstract the east qinling dabie orogenic belt accommodates the largest mo ore district in the world it contains 8 43 mt of proven mo metal reserves which accounts for 66 of the total proven chinese mo reserves the mo ore district includes 24 deposits and 12 occurrences with four major types of mo mineral systems i e porphyry porphyry skarn skarn and hydrothermal veins the latter can be further subdivided into quartz vein and carbonatite vein types although mo mineralization in the belt began in the paleoproterozoic 1680 24 to 2044 14 ma all economically significant deposits were formed during the mesozoic re os dating of molybdenite has shown that there are three episodes of mo mineralization i e late triassic 233 221 ma late jurassic to early cretaceous 148 138 ma and early to middle cretaceous 131 112 ma late triassic mo deposits developed as molybdenite quartz veins and carbonatite vein types stable isotope systematics c o s and high contents of re and sr indicate that the carbonatite mo veins are mantle derived porphyry and porphyry skarn mo mineral deposits were formed in the late jurassic to early cretaceous and early to middle cretaceous the late jurassic to early cretaceous granite porphyries that are associated with the mo deposits usually occupy less than 1 5 km2 at the surface and are situated in the east qinling area far west of china s continental margin on the other hand the early to middle cretaceous batholiths and granite porphyries with associated mo deposits are located in the dabieshan area and eastern part of the east qinling area the late jurassic to early creataceous granitoids and related mo deposits possibly formed in a back arc extensional setting of the eurasian continental margin which was probably triggered by the oblique subduction of the izanagi plate the early to middle cretaceous batholiths and granite porphyries are linked to the tectonic regime of lithospheric thinning asthenospheric upwelling and partial melting of the crust induced by a change in izanagi plate motion parallel to the continent margin in the east qinling dabie belt there are vein type pb zn ag deposits surrounding porphyry and or porphyry skarn mo w deposits forming well defined ore clusters the same spatial arrangement i e porphyry mo stockworks and outlying pb zn ag ore veins is also observed at the deposit scale thus mo porphyry stockworks and distal polymetallic veins belong to the same ore system and may reflect an outward temperature decrease from the highly fractionated granite plutons both porphyry stockworks and polymetallic veins can be used as vectors for further prospecting

magmatic hydrothermal evolution of the donggou porphyry mo deposit at the southern margin of the north china craton evidence from chemistry of biotite abstract late mesozoic granitoids are widespread in the southern margin of the north china craton ncc occurring commonly as both small porphyritic stocks and large batholiths most of the mo deposits are closely associated with small porphyritic bodies in order to determine the relationship between mo mineralization and the granitoids a systematic geochemical study of biotite from the taishanmiao batholith and the mo mineralization associated donggou porphyry was conducted trace element features of biotites indicate a differentiation trend from rocks of the taishanmiao batholith to those of the donggou porphyry as revealed by systematically decreasing k rb ratios co ba v and ti and increasing cs li ta and tl the contents of mo also increase with the degree of magmatic differentiation the compositions of biotite follow a trend towards more magnesium rich compositions and mostly plot above the nno buffer the fe3 fe2 values of biotite gradually increase from the taishanmiao batholith to the donggou porphyry indicating the progressive increasing fo2 during magmatic differentiation the halogen fugacities of magmatic fluids calculated from biotite compositions show a trend of magmatic differentiation the earlier fluids associated with the taishanmiao batholith are relatively f poor with log fhf fhcl 0 the high degree of melt fractionation and progressive increasing of oxygen fugacity is beneficial to concentrate mo in the residual melt in addition later relatively f rich fluid may be beneficial to extract mo from the melt and thus favorable for mo mineralization