geochemistry of meteorite rich marine limestone strata and fossil meteorites from the lower ordovician at kinnekulle sweden abstract thirteen fossil meteorites 1 5 9 cm have been found in lower ordovician orthoceratite limestone at kinnekulle sweden the meteorites were recovered from a 3 5 m thick quarried interval in the middle of a 30 m thick section of orthoceratite limestone the section formed in an epicontinental sea at very slow sedimentation rates 0 2 cm ka the limestones of the lower two thirds of the section are reddish brown except in the quarried interval where a conspicuous 1 m thick grey limestone bed occurs ten of the meteorites were found in a thin bed below the grey limestone one was found in the grey limestone and two in the red limestone above the meteorites are almost completely pseudomorphosed primarily by calcite and barite they were identified by their content of chromite grains and chondrule pseudomorphs the central part of one of the meteorites shows iridium 800 ppb gold 550 ppb and chromium 4400 ppm concentrations in typical chondritic abundances centimeter resolution profiles for iridium and eight other elements have been established through the quarried interval at a site at 4 km distant from the meteorite producing quarry in the reddish brown parts ir concentrations carbonate free basis lie typically in the range 300 400 ppt compared with 50 ppt ir in average shale in the grey limestone the ir concentrations are lower around 100 150 ppt iridium correlates with iron and appears to be related to sedimentation rate and or iron redox state rather than to any variations in the composition of the siliciclastic fraction with estimated sedimentation rates as above the excess ir flux to the sediment was 30 ng cm 2 ma which is a factor 2 3 higher than the present total ir flux and one order of magnitude higher than the extraterrestrial ir flux to the pacific sea floor our data cannot discriminate to what extent the ordovician ir enrichments are related to extraterrestrial matter or to precipitation of ir from seawater in recent deep sea sediments seawater derived ir enrichments are associated with mn oxides but no similar association occurs in the orthoceratite limestone the ten meteorites in the bed below the grey limestone reflect minimum meteorite accumulation rates of one meteorite per 150 m 2 and 175 ka probably the ten meteorites are related to a local strewn field rather than to background influx minimum accumulation rates calculated on three meteorite finds 20 g in the entire quarried interval give one meteorite per 570 m 2 and 1 17 ma which is one order of magnitude higher than present day large area averaged meteorite influx rates the probability is low that the small area 2 of the sea floor studied would happen to be one where an unusually high number of meteorites struck our results may reflect that meteorite and possibly also extraterrestrial ir influx rates were substantially higher than at the present during a period in the early ordovician enhanced influx rates could be related to an asteroid collision in space

extraterrestrial chromite in latest maastrichtian and paleocene pelagic limestone at gubbio italy the flux of unmelted ordinary chondrites the distribution of sediment dispersed extraterrestrial ordinary chondritic chromite ec grains 63 m has been studied across the latest maastrichtian and paleocene in the bottaccione gorge section at gubbio italy this section is ideal for determining the accumulation rate of ec because of its condensed nature and well constrained sedimentation rates in a total of 210 kg of limestone representing eight samples of 14 28 kg distributed across 24 m of the bottaccione section only 6 ec grains were found an average of 0 03 ec grains kg 1 in addition one probable pallasitic chromite grain was found no ec grains could be found in two samples at the cretaceous tertiary k t boundary which is consistent with the k t boundary impactor being a carbonaceous chondrite or comet low in chromite the average influx of ec to earth is calculated to 0 26 grain m 2 kyr 1 this corresponds to a total flux of 200 tons of extraterrestrial matter per year compared to 30 000 tons per year as estimated from os isotopes in deep sea sediments the difference is explained by the ec grains representing only unmelted ordinary chondritic matter predominantly in the size range from 0 1 mm to a few centimeters in diameter sedimentary ec grains can thus give important information on the extent to which micrometeorites and small meteorites survive the passage through the atmosphere the average of 0 03 ec grain kg 1 in the gubbio limestone contrasts with the up to 3 ec grains kg 1 in mid ordovician limestone that formed after the disruption of the l chondrite parent body in the asteroid belt at 470 ma the two types of limestone were deposited at about the same rate and the difference in ec abundance gives support for an increase by two orders of magnitude in the flux of chondritic matter directly after the asteroid breakup

origin of ureilites inferred from a sims oxygen isotopic and trace element study of clasts in the dar al gani 319 polymict ureilite secondary ion mass spectrometer sims oxygen isotope analyses were performed on 24 clasts representing 9 clast types in the dar al gani dag 319 polymict ureilite with precisions better than 1 olivine rich clasts with typical ureilitic textures and mineral compositions have oxygen isotopic compositions that are identical to those of the monomict ureilites and plot along the ccam carbonaceous chondrite anhydrous mineral line other igneous clasts including plagioclase bearing clasts also plot along the ccam line indicating that they were derived from the ureilite parent body upb thus we suggest that some of the plagioclase bearing clasts in the polymict ureilites represent the missing basaltic component produced by partial melting on the upb trace element concentrations mg k sc ti v cr mn fe co ni cu rb sr and ba in ureilitic plagioclase and glass from 13 clasts were obtained by using the sims high mass resolution method the trace element contents of the plagioclase generally show monotonic variations with anorthite content mol that are consistent with partial melting and fractional crystallization incompatible trace element concentrations k ti and ba are low and variable for plagioclase with an 40 indicating that the parental magmas for some clasts were derived from a depleted source we performed partial melt modeling for ci and cm precursor compositions and compared the results to the observed trace element k ba and sr abundances in the plagioclase our results indicate that 1 the upb evolved from a alkali rich carbonaceous chondritic precursor 2 parent melts of porphyritic clasts could have formed by 5 20 equilibrium partial melting and subsequent fractional crystallization and 3 parent melts of the incompatible trace element depleted clasts could be derived from fractional melting where low degree 10 partial melts were repeatedly extracted from their solid sources thus both the oxygen isotopic and trace element compositions of the plagioclase bearing clasts in dag 319 suggest that the upb underwent localized low degree partial melting events the partial melts could have been repeatedly extracted from the precursor resulting in the formation of the olivine pigeonite monomict ureilites as the final residue

middle ordovician chondrite in fossiliferous limestone from brunflo central sweden the few discoveries of fossil meteorites have been attributed1 to the ignorance about the appearance of meteorites among palaeontologists and other geologists who examine limestone quarries coal mines and other excavations in sedimentary rocks we now report the first find of a fossil stony meteorite in ordovician limestone the meteorite is a chondrite possibly an h chondrite and its terrestrial age is 463 myr the fine structural details of the chondrules are often extremely well preserved but the chemical composition and the mineralogy have changed dramatically chromite being the only primary mineral preserved the present major minerals are calcite barite a cr v phengite and a cobaltite group mineral

asteroid breakup linked to the great ordovician biodiversification event the great ordovician biodiversification event coincides 470 million years ago with the break up of a large asteroid and the resultant frequent bombardment of earth with asteroid fragments

a single asteroidal source for extraterrestrial ordovician chromite grains from sweden and china high precision oxygen three isotope sims analysis we examined oxygen three isotope ratios of 48 extraterrestrial chromite ec grains extracted from mid ordovician sediments from two different locations in sweden and one location in south central china the ages of the sediments similar to 470 ma coincide with the breakup event of the l chondrite parent asteroid elemental compositions of the chromite grains are generally consistent with their origin from l or ll chondrite parent bodies the average delta o 17 parts per thousand deviation from the terrestrial mass fractionation line measured in situ from 15 mu m spots by secondary ion mass spectrometry sims of ec grains extracted from fossil meteorites from thorsberg and brunflo are 1 17 0 09 parts per thousand 2 sigma and 1 25 0 16 parts per thousand respectively and those of fossil micrometeorites from thorsberg and puxi river are 1 10 0 09 parts per thousand and 1 11 0 12 parts per thousand respectively within uncertainty these values are all the same and consistent with the l chondrite group average delta o 17 1 07 0 18 parts per thousand but also with the ll chondrite group average delta o 17 1 26 0 24 parts per thousand clayton et al 1991 we conclude that the studied ec grains from correlated sediments from sweden and china are related and most likely originated in the same event the l chondrite parent body breakup we also analyzed chromites of modern h l and ll chondrites and show that their delta o 17 values coincide with averages of delta o 17 of bulk analyses of h l and ll chondrites this study demonstrates that in situ oxygen isotope data measured by sims are accurate and precise if carefully standardized and can be used to classify individual extraterrestrial chromite grains found in sediments c 2009 elsevier ltd all rights reserved less

l chondrite asteroid breakup tied to ordovician meteorite shower by multiple isochron 40ar 39ar dating radiochronometry of l chondritic meteorites yields a rough age estimate for a major collision in the asteroid belt about 500 myr ago fossil meteorites from sweden indicate a highly increased influx of extraterrestrial matter in the middle ordovician 480 myr ago an association with the l chondrite parent body event was suggested but a definite link is precluded by the lack of more precise radiometric ages suggested ages range between 450 30 myr and 520 60 myr and can neither convincingly prove a single breakup event nor constrain the delivery times of meteorites from the asteroid belt to earth here we report the discovery of multiple 40ar 39ar isochrons in shocked l chondrites particularly the regolith breccia ghubara that allow the separation of radiogenic argon from multiple excess argon components this approach applied to several l chondrites yields an improved age value that indicates a single asteroid breakup event at 470 6 myr fully consistent with a refined age estimate of the middle ordovician meteorite shower at 467 3 1 6 myr according to a geologic time scale 2004 our results link these fossil meteorites directly to the l chondrite asteroid destruction rapidly transferred from the asteroid belt the increased terrestrial meteorite influx most likely involved larger projectiles that contributed to an increase in the terrestrial cratering rate which implies severe environmental stress

asteroidal source of l chondrite meteorites abstract establishing connections between meteorites and their parent asteroids is an important goal of planetary science several links have been proposed in the past including a spectroscopic match between basaltic meteorites and 4 vesta that are helping scientists understand the formation and evolution of the solar system bodies here we show that the shocked l chondrite meteorites which represent about two thirds of all l chondrite falls may be fragments of a disrupted asteroid with orbital semimajor axis a 2 8 au this breakup left behind thousands of identified 1 15 km asteroid fragments known as the gefion family fossil l chondrite meteorites and iridium enrichment found in an 467 ma old marine limestone quarry in southern sweden and perhaps also 5 large terrestrial craters with corresponding radiometric ages may be tracing the immediate aftermath of the family forming collision when numerous gefion fragments evolved into the earth crossing orbits by the 5 2 resonance with jupiter this work has major implications for our understanding of the source regions of ordinary chondrite meteorites because it implies that they can sample more distant asteroid material than was previously thought possible

the origin of the brunflo fossil meteorite and extraterrestrial chromite in mid ordovician limestone from the garde quarry jamtland central sweden the brunflo fossil meteorite was found in the 1950s in mid ordovician marine limestone in the garde quarry in jamtland it originates from strata that are about 5 million years younger than similar limestone that more recently has yielded 50 fossil meteorites in the thorsberg quarry at kinnekulle 600 km to the south based primarily on the low tio2 content about 1 8 wt of its relict chromite the brunflo meteorite had been tentatively classified as an h chondrite the meteorite hence appears to be an anomaly in relation to the kinnekulle meteorites in which chromite composition chondrule mean diameter and oxygen isotopic composition all indicate an l chondritic origin reflecting an enhanced flux of meteorites to earth following the disruption of the l chondrite parent body 470 ma new chondrule size measurements for the brunflo meteorite indicate that it too is an l chondrite related to the same parent body breakup chromite maximum diameters and well defined chondrule structures further show that brunflo belongs to the l4 or l5 type chromites in recently fallen l4 chondrites commonly have low tio2 contents similar to the brunflo chromites adding support for brunflo being an l4 chondrite the limestone in the circle quarry is relatively rich about 0 45 grain kg 1 in sediment dispersed extraterrestrial chromite grains 63 mu m with chemical composition similar to those in l chondrites and the limestone 1 3 grains kg 1 at kinnekulle suggesting that the enhanced flux of l chondrites prevailed although somewhat diminished at the time when the brunflo meteorite fell less

sediment dispersed extraterrestrial chromite traces a major asteroid disruption event abundant extraterrestrial chromite grains from decomposed meteorites occur in middle ordovician 480 million years ago marine limestone over an area of 250 000 square kilometers in southern sweden the chromite anomaly gives support for an increase of two orders of magnitude in the influx of meteorites to earth during the mid ordovician as previously indicated by fossil meteorites extraterrestrial chromite grains in mid ordovician limestone can be used to constrain in detail the temporal variations in flux of extraterrestrial matter after one of the largest asteroid disruption events in the asteroid belt in late solar system history

petrographic classification of middle ordovician fossil meteorites from sweden the maximum diameter of chromite fecr2o4 grains within l chondrites reflects the petrographic type of the sample on the basis of our measurements of nine recent l chondrites l3 chromite d mac 34 50 mu m l4 87 150 mu m l5 76 158 mu m and l6 253 638 mu m this variation reflects the crystallization of the chromite grains during parent body thermal metamorphism we use this calibration to classify six fossil meteorites from the middle ordovician in sweden as type 3 or 4 to 6 the high flux of l chondrites at 470 ma contained a range of petrographic types and may have had a higher proportion of lower petrographic type meteorites than are found in recent l chondrite falls the fossil meteorites have in places preserved recognizable chondrule textures including porphyritic olivine barred olivine and radiating pyroxene a large relict clast and fusion crust have also been tentatively identified in one fossil meteorite apart from chromite all of the original meteorite minerals have been replaced by carbonate and sheet silicate and sulfate during diagenesis within the limestone host the preservation of chondrule definition has allowed us to measure the mean diameters of relict chondrules the range 0 4 0 6 mm is consistent with measurements made in the same way on recent l chondrites less

a rain of ordinary chondritic meteorites in the early ordovician forty fossil meteorites with a total original mass of v7 7 kg have been recovered in the first systematic search for fossil meteorites pursued in an active quarry in lower ordovician 480 ma marine limestone in southern sweden the meteorites represent at least 12 different falls over a seafloor area of v6000 m 2 during 91 75 myr making the quarry one of the most meteorite dense areas known in the world geochemical analyses of relict chromite grains indicate that all or most of the meteorites are ordinary chondrites and probably l chondrites mechanisms for meteorite delivery from the asteroid belt to earth were the same 480 ma as today however the flux was one to two orders of magnitude higher most likely reflecting the disruption of the l chondrite parent body at about that time this is a major event in late solar system history which may also have led to an enhanced flux of asteroids to earth during v30 myr fl 2001 elsevier science b v all rights reserved

the rapid heating defocused beam technique a co2 laser based method for highly precise and accurate determination of δ18o values of quartz abstract we describe a laser fluorination technique specifically for quartz that allows both high accuracy and high precision determination of oxygen isotope ratios regardless of grain size the rapid heating defocused beam technique rhd utilizes a defocused 32 w co 2 laser at full power which delivers 17 w 20 w mm 2 to the sample to quickly react quartz in contrast other recent laser fluorination studies use a tightly focused laser beam and slow heating i e sharp and kirschner 1995 fouillac and girard 1996 kirschner and sharp 1997 and find laser analysis of fine grained quartz to be inaccurate three quartz standards nbs 28 qz bra and qz cwru were analyzed using the rhd technique at the university of wisconsin to test for grain size effects rhd analyses show no correlation between grain size and 18 o values and are in excellent agreement with 18 o values obtained using conventional fluorination techniques additional analyses of the same quartz standards performed at university of wisconsin using slow heating and a focused beam yield 18 o values that are both less precise and significantly up to 0 8 lower than the accepted values attempts to use the rhd technique with a 20 w co 2 laser which delivers 8 w 10 w mm 2 to the sample at brgm were unsuccessful probably due to insufficient power density of the defocused beam we conclude that the rhd technique yields excellent accuracy and precision but that power densities of 15 20 w mm 2 may be necessary across a large part of the sample surface we recommend the use of lasers with at least 30 w of power

relict silicate inclusions in extraterrestrial chromite and their use in the classification of fossil chondritic material abstract chromite is the only common meteoritic mineral surviving long term exposure on earth however the present study of relict chromite from numerous ordovician 470 ma fossil meteorites and micrometeorites from sweden reveals that when encapsulated in chromite other minerals can survive for hundreds of millions of years maintaining their primary composition the most common minerals identified in the form of small analyses of recent meteorites holding both inclusions in chromite and corresponding matrix minerals show that for olivine and pyroxene inclusions sub solidus re equilibration between inclusion and host chromite during entrapment has led to an increase in chromium in the former in the case of olivine the re equilibration has also affected the fayalite fa content lowering it with an average of 14 in inclusions for ca poor pyroxene the ferrosilite fs content is more or less identical in inclusions and matrix by these studies an analogue to the commonly applied classification system for ordinary chondritic matrix based on fa in olivine and fs in ca poor pyroxene can be established also for inclusions in chromite all olivine and ca poor pyroxene inclusions 1 5 m in chromite from the ordovician fossil chondritic material plot within the l chondrite field which is in accordance with previous classifications the concordance in classification together with the fact that inclusions are relatively common makes them an accurate and useful tool in the classification of extraterrestrial material that lacks matrix silicates such as fossil meteorites and sediment dispersed chromite grains originating primarily from decomposed micrometeorites but also from larger impacts

experiments on thermal release of implanted noble gases from minerals and their implications for noble gases in lunar soil grains abstract experiments on ion implantation were performed in order to study the release mechanisms of solar particles from lunar soil grains helium neon and argon ions were implanted into olivine and ilmenite the release temperatures of noble gases were investigated by heating samples stepwise the results show that they depend on irradiation energy and dose we conclude that the release temperature is related to the size of bubbles in which noble gases are trapped noble gases in small and large bubbles are released at 400 600 c and 800 1200 c respectively in ne and ar implantation experiments into olivine a component was released during recrystallization of amorphized surfaces based on these experimental results we suggest that components released from lunar ilmenite grains at different temperatures would correspond to solar particles of different energies we also suggest that he and ne of solar wind energy about 1 kev amu should be retained in lunar ilmenite grains while they should be lost from olivine grains

stable isotope thermometry at high temperatures determination of accurate temperatures for geological events has been the grail of stable isotope geochemistry since the seminal 1947 paper by urey in theory this should be simple calibrated mineral pairs are common analysis is rapid and there is no significant pressure correction however in spite of widespread application the promise of reliable thermometry has been elusive stable isotope temperatures in metamorphic and igneous rocks are often controversial is the fractionation between two phases a thermometer speedometer rate dependant hygrometer p h2o dependant or chimera a number of factors have contributed to this uncertainty including incomplete and sometimes conflicting calibration of isotope fractionation factors limited understanding of the kinetics of mineral exchange and the lack of microanalytical techniques this situation has improved dramatically over the past decade permitting reliable and detailed thermal histories to be inferred in a landmark paper bottinga and javoy 1975 empirically calibrated the oxygen isotope fractionation factors among ten rock forming minerals at t 500 c their compilation shows that 84 of analyzed samples contain at least three minerals meeting a concordance test for equilibrium they concluded the great majority of igneous and metamorphic rocks has conserved a state of oxygen isotope exchange equilibrium if correct this bodes well for thermometry however this conclusion was contested by deines 1977 who critically examined the existing data and concluded that less than half of the rocks analyzed to date would yield concordant 18o derived temperatures while seeming irreconcilable both conclusions are based on fact all rocks contain some degree of disequilibrium but many also preserve a thermometric record it is the purpose of this review to discuss the new strategies for reliable isotope thermometry and to explore disequilibrium processes so they may be recognized and properly interpreted the organization of this paper will be to discuss the assumptions

depositional character and preservation potential of coarse grained sediments deposited by flood events in hyper arid braided channels in the rift valley arava israel abstract four coarse grained braided channels undergoing rapid deposition in the hyper arid arava rift valley have been studied to determine the dynamics of strata deposition by monitored flood events and to ascertain the sedimentologic character of these event deposits the systems span granule sand to sandy gravel bed material having longitudinal bars with simultaneously increasing grains size slope and bed relief scour and fill were monitored along cross sections using scour chains and repeat surveys while event strata fill were described with reference to sediment calibre type of support grading thickness and location unlike many previous investigations of gravel sedimentology the source of information for this study involves not only stratigraphic description but also observation of the concomitant dynamics of the channel bed as expressed by the extent of event deposition the texture of the deposited sediment generally coarsens in sympathy with the surface bed texture of the studied channels the thickness of event deposited sediments increases as the magnitude of flow events increases the stratigraphic record is characterized by 1 sub parallel stratification 2 no grading 3 clast supported gravel infilled with sand granule matrices and 4 rapid sedimentation rates this character is hypothesized to mirror the elevated bedload fluxes in this hyper arid fluvial setting lacking densely vegetated banks the proximal braidplain of this arid environment often contains no extensive fine textured floodplain successions the depth of fill as well as the extent of strata obliteration increase with flood magnitude explaining the increased preservation potential of event strata with increase in flood magnitude it also explains why most event strata including large ones are only partially preserved

extraterrestrial chromite in middle ordovician marine limestone at kinnekulle southern sweden traces of a major asteroid breakup event the distribution of sediment dispersed extraterrestrial chromite grains and other cr rich spinels 63 mu m has been studied in middle ordovician orthoceratite limestone from two quarries at kinnekulle southern sweden in the thorsberg quarry all similar to 3 2 m thick sequence of beds previously shown to be rich in fossil meteorites is also rich in sediment dispersed extraterrestrial chromite grains typically 1 3 grains are found per kilogram of limestone in the nearby hallekis quarry the same beds show similarly high concentrations of extraterrestrial chromite grains but in samples representing the 9 m downward continuation of the section exposed at this site only 5 such grains were found in a total of 379 kg of limestone the extraterrestrial equilibrated ordinary chondritic chromite grains call be readily distinguished by a homogeneous and characteristic major element chemistry including 2 0 3 5 wt tio2 and stable v2o3 concentrations close to 0 7 wt terrestrial cr rich spinels have a wide compositional range and co exist with extraterrestrial chromite in some beds these grains may be derived for example from mafic dykes exposed and weathered at the sea floor considering lithologic and stratigraphic aspects variations in sedimentation rate cannot explain the dramatic increase in extraterrestrial chromite seen in the upper part of the composite section studied instead the difference may be primarily related to all increase in the ancient flux or extraterrestrial matter to earth in connection with the disruption of the l chondrite parent body in the asteroid belt at about this time the coexistence in some beds of high concentrations of chondritic chromite and terrestrial cr rich spinels however indicates that redistribution of heavy minerals on the sea floor related to changes in sea level and sea floor erosion and currents must also be considered less

chromium and nickel in shale of the taconic foreland a case study for the provenance of fine grained sediments with an ultramafic source abstract to test the suitability of using shale geochemistry as a provenance indicator of a source with an ultramafic component we used i c p mass spectrometry to analyze 130 samples from seven localities from newfoundland to new york these samples represent mud from the foreland basin produced during the collision of the taconic are with north america in the ordovician the sandstones in the flysch contain detrital chromite and other detritus that indicate that the source contained ultramafic rocks presumably from ophiolites emplaced during collision this setting is an ideal test case for examining the spatial and temporal variation in cr and ni geochemistry of shale derived from ophiolite bearing highlands shale samples with high concentrations of cr and ni have a cr ni ratio of 1 4 which is approximately the cr ni ratio for ultramafic rocks 1 6 suggesting only minor geochemical partitioning but sandstones have a cr ni ratio of 3 0 suggesting significant sedimentary fractionation analyses of samples taken upsection in a single stratigraphic section suggest that proximity to the source influences cr and ni concentrations a decrease in cr and ni concentrations through time suggests that uplift and erosion of the thrust complex non ophiolitic diluted the ultramafic signal we attribute significant along strike variation in cr and ni concentrations to the relative proportion of ultramafic rocks in the source region this case study shows that cr and ni geoch mistry of shale from basin strata can be used to determine the lateral and temporal variability of ultramafic rocks in an active orogenic setting