sims zircon u pb geochronology and sr nd isotopes of ni cu bearing mafic ultramafic intrusions in eastern tianshan and beishan in correlation with flood basalts in tarim basin nw china constraints on a ca 280 ma mantle plume zircon sims u pb dating of the poshi hongshishan bijiashan and huangshan ni cu bearing and xiangshan ni cu ti fe bearing mafic ultramafic intrusions in the eastern tianshan and beishan rift yields a relatively restricted range of 278 6 ma to 284 0 ma the histogram of compiled age data of basalts in the tarim basin and mafic ultramafic intrusions in the eastern tianshan and beishan rift has a peak of 280 ma which probably represents the time of mantle plume activity the basalts have lower end t values in the range of 9 2 1 7 and mg of 2 wt indicating that they were generated directly from a peripheral zone of the mantle plume by low degree of melting the mafic ultramafic intrusions have higher end t of 1 3 11 2 and mg of 33 90 and lower tio2

self destructive sulfide segregation systems and the formation of high grade magmatic ore deposits the metal concentrations of sulfide liquids depend upon the mass of silicate magma that they are able to process for metals some high grade magmatic ni cu pge deposits and many magmatic platinum group element pge ni cu deposits demand very high magma sulfide ratios that seem improbable in the light of physical and kinetic constraints recent models for some high grade deposits invoke multistage upgrading processes in which an early formed sulfide liquid reacts with multiple later batches of silicate magma quantitative models of this open system process demonstrate that it is indeed more efficient than a closed system however it is likely that most later magmas in such a system will be sulfur undersaturated and will thus partly redissolve preexisting sulfide liquids further increasing metal concentrations in the remaining sulfide liquids this combined process is termed multistage dissolution upgrading and quantitative models show that it could reduce the mass of silicate magma that must be processed by as much as two orders of magnitude furthermore if sulfide liquids are extensively dissolved during enrichment their base metal concentrations will generally stabilize at a limiting value whereas their pge concentrations will generally increase without limit this divergence could account for unusually high pge concentrations and high pge base metal ratios in many pge dominated deposits the multistage dissolution upgrading model is tested using reasonable degrees of dissolution in the context of natural deposits in the noril sk area and the bushveld intrusion the models reproduce the observed sulfide compositions significantly better than previous models and are also consistent with other aspects of the geology of these deposits thus dynamic sulfide forming magmatic systems may be intrinsically self destructive but this apparently undesirable attribute could play an important role in forming high grade deposits however dissolution could lead to the complete destruction of sulfide liquids and the return of all metals to later magma batches in this case no sulfide deposit would remain but metal depletion signatures indicating sulfide liquid segregation would be preserved in rocks that crystallized from early magmas caution is therefore advised in the use of magmatic depletion signatures to infer overall mineral potential or to estimate the possible sizes of undiscovered magmatic sulfide deposits

cooling history of granulite samples from the ocean continent transition of the galicia margin implications for rifting abstract zircon and apatite fission track ages were obtained on twogranulite samples that were recovered from the sea floor in theocean continent transition area of the galicia margin northatlantic using the french submersible nautile zircon agesindicate that the rocks cooled through about 2508cincarboniferous to early permian time 307 42 ma and287 35 ma hence the granulites do not represent the preriftlower crust but were in an upper crustal position long beforeriftingstarted apatitesyieldedearlycretaceousages 126 6 7myr and 129 13 4 myr indicating cooling through 90 308ccoeval with the main rifting phase that preceded continentalbreakup we assume that the granulite samples originate from atectonic breccia cropping out near one of the sample locations this breccia formed along a synrift detachment accommodatingcontinentalbreakupandfinalexhumationofthegaliciamargin speridotite ridge terra nova 10 96 100 1998 ahedbhedcheddhedref markerfig markertable markerref end ref start correspondence tel fax 41 61 2673610 3613 e mail fuegenschuh ubaclu unibas ch

u pb ages and hf o isotopes of zircons from late paleozoic mafic ultramafic units in the southern central asian orogenic belt tectonic implications and evidence for an early permian mantle plume abstract u pb age and hf o isotope data of zircons from the mafic ultramafic complexes and their related rhyolites and granites in the eastern tianshan and beishan regions were obtained by sims and la icpms the hf o isotopic composition and hf model age of the zircons are closely related to their tectonic setting and formation age the zircons from the mafic ultramafic complexes in the bogeda haerlike and jueluotage belts have higher ehf t 8 17 and lower 18o 4 6 whereas most of the zircons in the gabbros granites and rhyolite from the middle tianshan massif and beishan rift display lower ehf t 0 8 and higher 18o 5 8 the positive ehf t and relatively lower 18o values suggest that these mafic ultramafic complexes were derived from depleted mantle which was subjected to subduction related modification processes the hf isotopic composition of zircons in the granites has revealed that the growth of juvenile crust was also very significant in the southern margin of the central asian orogenic belt during the paleozoic the hf model ages of the analyzed zircons together with the regional geology suggest that the beishan area had a northward subduction possibly from ca 900 ma to ca 400 ma whereas the eastern tianshan had a south directed subduction most likely from ca 600 ma to ca 310 ma additionally zircons with ca 280 ma u pb ages display wider and more scattered ehf t and 18o variations than the relatively older and younger ones which further support the early permian mantle plume model

a review of the cu ni sulphide deposits in the chinese tianshan and altay orogens xinjiang autonomous region nw china principal characteristics and ore forming processes abstract several cu ni sulphide deposits and occurrences have recently been discovered along parallel deep faults in the chinese tianshan and altay orogenic belts xinjiang province nw china the kalatongke and several other cu ni mineralized intrusions are located along the irtysh fault which separates the altay orogenic belt from the junggar basin the huangshan huangshandong xiangshan tudun erhongwa tula ergen and hongling deposits occur along the kanggurtag suture which separates the jueluotage orogenic belt from the turpan hami tuha basin the baishiquan tianyu and tianxiang deposits are located along the arqikekuduke fault which separates the jueluotage orogenic belt from the central tianshan precambrian terrane the poyi poshi and luodong deposits are located along the baidiwa fault which separates the central tianshan precambrian terrane from the beishan paleozoic rift re os dating of cu ni sulphide ores reveals that these cu ni ore belts formed in a narrow age range of 298 282 ma this age range is about the same as those of associated intrusions and dykes dated by the shrimp zircon u pb method tectonic and geochronological constraints suggest that the amalgamation of continental blocks mainly occurred during the late carboniferous in the central asian orogenic belt large scale hydrothermal and magmatic metallogenesis in the region occurred during post collisional stages of latest carboniferous to early permian age the cu ni sulphide deposits are part of this metallogenic event the cu ni orthomagmatic sulphide deposits in northern xinjiang are represented by 1 net textured type deposits by segregation of a cu ni metal sulphide melt and 2 magma conduit type some mafic ultramafic suites exhibit lithological zoning caused by strong differentiation stratiform orebodies are hosted by ultramafic rocks at the base of the magma chamber good examples are the kalatongke huangshandong and poshi deposits others such as the xiangshan baishiquan tianyu and tula ergen deposits are hosted by magma conduits consisting of peridotite troctolite and pyroxenite these ultramafic rocks either occur within faults or are surrounded by gabbroic and dioritic intrusions these two types of orthomagmatic cu ni sulphide deposits are also distributed along the same ore belts for instance the differentiated sill related huangshandong deposit co exists with the magma conduit type tula ergen deposit in the jueluotage orogenic belt orthomagmatic cu ni sulphide deposits in northern xinjiang formed during post collisional extension and are possibly related to a late carboniferous early permian mantle plume event the mafic ultramafic suites and associated cu ni deposits are commonly accompanied by dyke swarms and are characterized by elongated outcrops occurring along parallel e w trending regional faults these mafic ultramafic suites and accompanying dyke swarms are generally fractionated implying that they were feeders of presently eroded flood basalts

in situ u pb hf and re os isotopic analyses of the xiangshan ni cu co deposit in eastern tianshan xinjiang central asia orogenic belt constraints on the timing and genesis of the mineralization abstract the timing and genesis of the major ni cu co sulfide deposit in the xiangshan intrusion have been studied based on newly obtained in situ u pb hf and re os isotopic analyses the sims u pb zircon ages of the gabbro hosting the ni cu co sulfide deposit indicate that the xiangshan intrusion was emplaced at 279 6 1 1 ma 95 confidence level mswd 1 30 n 15 on the basis of combined geological and geochronological evidence we suggest that the xiangshan and other adjacent ni cu deposits were formed in the same period sulphides have low common os concentrations and high re os ratios similar to sulphide ores from the duluth sally malay and voisey bay complexes the re os isotopic data from the disseminated and massive ores from the xiangshan intrusion do not form a single isochron as they have different initial os ratios the hf and os isotopic data suggest that the xiangshan intrusion and associated ni cu co mineralization were derived from crustally contaminated mantle melts the geochemical data show a tholeiitic affinity and a strong suprasubduction zone signature with negative nb sr and ti anomalies similar to n morb and e morb we suggest that the mafic ultramafic rocks and associated ni cu mineralization of the eastern tianshan orogen formed in an alaska type subduction zone arc setting some diagnostic features of ridge trench interaction are present in the chinese east tianshan orogen e g granites adakites high mg andesites near trench magmatism alaskan type mafic ultramafic complexes high temperature metamorphic belts that prograde rapidly from low grade belts and orogenic gold deposits the above distinctive rock groups are probably related to the same thermal event ridge subduction as in the cenozoic orogen of alaska we suggest that ridge subduction is the most plausible mechanism to provide the necessary heat ridge subduction provides an important promising model for understanding many aspects of the evolution of the chinese eastern tianshan orogen and by inference throughout much of central asia

genesis of the wuxing pt pd rich cu ni sulfide deposit in the eastern central asian orogenic belt evidences from geochronology elemental geochemistry and sr nd hf isotopic data the wuxing pt pd rich cu ni sulfide deposit in heilongjiang province northeast china is located to the northeast of the dunhua mishan fracture of the eastern central asian orogenic belt the mafi

constraints on the timing of uplift of the yanshan fold and thrust belt north china this paper reports in situ u pb ages and hf isotopic data on detrital zircons from paleozoic to late mesozoic strata in the xishan area near beijing that provide important constraints on the evolution and paleogeography of the northern part of the north china craton ncc zircons from carboniferous to late mesozoic sandstones are characterized by three major groups of u pb ages 2 5 2 3 ga 1 9 1 7 ga and late phanerozoic ages the neoarchean and paleoproterozoic zircons and some phanerozoic zircons have negative ehf t values similar to igneous zircons from intrusive rocks known from the ncc indicating that the source of the sandstones was locally derived however late triassic to late jurassic 205 158 ma sandstones contain a group of phanerozoic zircons with positive ehf t values distinct from known igneous zircons in the ncc suggesting an exotic source the nearest potential source is the xing meng orogenic belt xmob to the north of the ncc where considerable amounts of juvenile crustal materials exist it is concluded that there are two sudden shifts in source provenances of the xishan sediments from the ncc before the late triassic to a mixed source from the ncc and xmob during the late triassic to late jurassic and then from the ncc again during the late jurassic 158 ma the first shift in source resulted from the exhumation and denudation of rocks due to uplift of the xmob which coincided with post collisional extension in the late triassic and intraplate extension of the ncc in the middle to late jurassic the second source shift resulted from the uplift of the yanshan fold and thrust belt thus constraining the timing of this to the late jurassic

subduction induced mantle heterogeneity beneath eastern tianshan and beishan insights from nd sr hf o isotopic mapping of late paleozoic mafic ultramafic complexes abstract extensive late paleozoic mafic ultramafic complexes in the eastern tianshan and beishan regions in the southern central asian orogenic belt caob represent an ideal opportunity to assess the characteristics of the mantle in this area whole rock nd sr and zircon hf o isotopic data from the mafic ultramafic complexes of the jueluotage belt middle tianshan massif and beishan rift were compiled for isotopic mapping end t and 87sr 86sr i values range from 5 5 to 9 5 and 0 702 to 0 706 respectively in the jueluotage belt and from 2 to 11 and 0 703 to 0 710 respectively in the middle tianshan and beishan zircon ehf t and 18o values are in the range of 6 0 17 0 and 4 14 8 00 respectively in the jueluotage belt 1 8 and 5 17 6 30 respectively in the middle tianshan and show large variations of 1 17 and 4 12 respectively in the beishan spatially the 87sr 86sr i ratios of mafic ultramafic complexes increase from the jueluotage belt and beishan to the middle tianshan while the end t values show an opposite trend and reflect a mixing character between depleted mantle and em ii reservoirs zircon ehf t and 18o values exhibit an apparent southward decreasing and increasing trends respectively from the jueluotage belt through middle tianshan to beishan rift their corresponding hf model ages increase continuously from north to south these observations demonstrate that the mantle sources beneath the eastern tianshan and beishan are compositionally heterogeneous which presumably result from significant and variable degrees of subduction related modification we therefore suggest that the late paleozoic subcontinental lithospheric mantle beneath the jueluotage belt was modified by slab derived melts and fluids during the subduction of the junggar ocean whereas the mantle beneath the beishan rift was influenced mainly by slab derived fluids during the subduction of the south tianshan ocean the unique similarities of the middle tianshan mafic ultramafic complexes reflect a two stage modification of their mantle source namely the sequential subduction of the early south tianshan ocean followed by subduction of the junggar ocean thus the subduction induced mantle heterogeneity beneath the caob is probably regional in scope

diagenesis and metallogenetic mechanisms of the tuanjiegou gold deposit from the lesser xing an range ne china zircon u pb geochronology and lu hf isotopic constraints abstract the tuanjiegou gold deposit is a large sized breccia hosted epithermal gold deposit in heilongjiang province eastern china and was discovered in the late 1950s the scale and unusual metallogenic setting of this gold deposit have made it the focus of many previous studies we systematically analyzed ore samples and volcanic and granitic rocks that are associated with the formation of the deposit by single zircon u pb dating obtaining three distinct concordant groups of u pb ages from dacitic pyroclastic rocks and lavas 119 3 3 3 n 2 113 2 1 1 n 13 and 109 1 1 4 ma n 8 four groups of concordant u pb ages from an ore bearing granite porphyry 112 5 2 2 n 2 107 0 1 2 n 4 103 0 0 70 n 10 and 99 9 1 1 ma n 4 two groups of concordant u pb ages from a pyrite rich quartz vein cemented brecciated and silicified granite porphyry 104 23 0 51 n 16 and 101 3 1 3 ma n 2 and five groups of concordant u pb ages from pyrite rich quartz vein cemented brecciated or chunky ore samples 139 4 to 144 3 n 2 127 4 n 1 113 8 2 1 n 8 101 3 3 4 n 3 and 91 3 ma n 1 combining the whole rock and lu hf isotope geochemistry with the geology of the mining area and these new u pb dates we have redefined the ore deposit related temporal history of the area with formation age of the magma associated with the ningyuancun stage volcanics being 119 1 4 ma and eruption of the volcanics at 113 1 1 ma the granodiorite porphyry and granite porphyry were emplaced at 107 0 1 2 ma and 103 102 ma respectively with ore deposit formation at 102 100 ma the magmato hydrothermal interaction that formed the deposit was closely related to late mesozoic crust mantle interaction with the early stage calc alkaline and high k calc alkaline magmatism in this area potentially being derived from interaction between asthenospheric mantle material and the underplated lower crust however the magmas associated with late stage intrusive calc alkaline and high k calc alkaline magmatism may have been generated during interaction between adakite like magmas derived from the subduction of an oceanic plate and lower crustal material here we suggest that the fluids that formed this deposit formed by interaction with both early and late stage mantle derived magmas and the lower crust with subsequent aggregation after significant igneous differentiation during ore formation the area was in a back arc initial passive rift and continental margin island arc tectonic environment associated with late mesozoic subduction of the pacific plate with metallogenesis occurring during a change in the tectonic environment between the latest early cretaceous and the late cretaceous

petrogenesis of the linxi granitoids northern inner mongolia of china constraints on basaltic underplating five representative granitoid plutons in the linxi area northern inner mongolia of china divided into two suites are mainly granodiorite and syenogranite and correspond to i and a type granites respectively zircon u pb dating yields an age of 230 ma but most ages range from 149 ma to 111 ma for intrusion of the five plutons suite 1 granitoids show lower sio2 66 1 72 51 and k2o higher al2o3 cao mgo feo and tio2 higher sr ba and eu and lower sm gd nb y and yb than suite 2 granitoids 71 73 78 14 sio2 modeling of major and trace elements shows that fractional crystallization of hornblende and lesser amounts of feldspars for suite 1 and plagioclase and alkali feldspar for suite 2 with overprint of magmatic hydrothermal fluids can explain the geochemical variations the linxi granitoids have initial end t values varying between 5 60 and 2 89 and initial 87 sr 86 sr t ratios ranging from 0 701764 to 0 707654 geochronology of inherited zircons coupled with the nd sr isotopic comparison between granitoids late jurassic basalts and proterozoic gneisses indicates that the linxi granitoids derive from a mixed source of dominantly underplated material or mafic magma with various amounts of the proterozoic gneiss basaltic underplating provides both material and heat to produce the late jurassic to early cretaceous granitoids variation of end t and 87 sr 86 sr t with age suggests involvement in the melting of increasingly greater amounts of the old lower crustal rock our refined equation yields less scattered nd isotope depleted mantle model ages the least fractionated granitoids from each suite have low ca sr rb sr rb ba and k ba ratios and hence represent parental magmas suite 1 parent magma is produced by dehydration melting or derives principally from the fluid metasomatized mantle melting of the underplated tholeiites and their differentiated products generates suite 2 parent magma d 2005 elsevier b v all rights reserved

a modified genetic model for the huangshandong magmatic sulfide deposit in the central asian orogenic belt xinjiang western china the huangshandong ni cu deposit is the largest magmatic sulfide deposit discovered to date in the central asian orogenic belt in northern xinjiang western china the host intrusion is a 274 ma composite mafic ultramafic intrusion consisting of four separate intrusive units a large layered gabbroic sequence phase i a sheet like ultramafic body phase ii a dyke like gabbronorite body phase iii and an irregular ultramafic unit phase iv important sulfide mineralization is present in the last three intrusive units predominantly as disseminated and net textured sulfides pyrrhotite pentlandite and chalcopyrite the huangshandong mafic ultramafic intrusive rocks are characterized by arc like geochemical signatures such as low ca content in olivine and negative nb ta anomalies in whole rocks this together with a post subduction setting for the east tianshan in the permian suggests that the source mantle was modified previously by slab derived fluids in the carboniferous the mantle derived magma was ponded in a staging chamber in the lower part of the newly formed arc crust the first batch of magma to arrive at huangshandong was most fractionated and depleted in ni crystallizing fe rich and ni depleted olivine fo67 300 ppm ni the second batch of magma was more primitive crystallizing more primitive olivine fo81 84 the third batch of magma was also highly fractionated and depleted in ni crystallizing fe rich and ni depleted olivine fo72 600 ppm ni the final batch of magma became more primitive again crystallizing the most primitive olivine fo81 86 the occurrence of rounded sulfide inclusions in olivine primocrysts in the huangshandong ultramafic rocks indicates that immiscible sulfide liquid droplets were present during olivine crystallization the ni tenors of disseminated sulfide ores in the gabbronorite dyke vary mainly between 5 and 8 wt which are too high to have been produced by the parental magma of the dyke the ni cu and platinum group elements pge tenors of disseminated sulfide ores in the dyke phase iii and the ultramafic sheet phase ii are remarkably similar these observations together with the sequence of magma emplacement suggest that the sulfide liquids entrapped in the magma of the dyke formed at depth by a previous pulse of more primitive magma the estimated parental magma for the most primitive lherzolites in the huangshandong intrusion contains 10 wt mgo modeling shows that sulfide saturation in the parental magma of the huangshandong lherzolites could have resulted from fractional crystallization significant pge depletions relative to ni and cu in the disseminated sulfide ores of the huangshandong deposit may be due to sulfide retention in the source mantle

formation of the jinchuan ultramafic intrusion and the world s third largest ni cu sulfide deposit associated with the 825 ma south china mantle plume we report here shrimp u pb geochronological geochemical and nd isotopic data for the jinchuan ultramafic intrusion gansu province china which hosts the world s third largest magmatic ni cu sulfide deposits u pb baddeleyite analyses yield an age of 812 26 ma for the ultramafic intrusion this age is indistinguishable within analytical uncertainties from the u pb zircon ages of 827 8 ma and 828 3 ma for the sulfide bearing ultramafic rocks and the dolerite dykes that cut the ultramafic intrusion respectively these u pb dating results show beyond doubt that the jinchuan ultramafic intrusion and associated ni cu sulfide deposit were formed at 825 ma rather than 1500 ma as has been widely believed the ultramafic rocks exhibit large negative nd t values 8 9 to 12 0 that decrease with increasing la sm suggesting that their parental magmas were derived from a long term enriched lithospheric mantle and experienced crustal contamination mineralogical petrological and geochemical data all indicate that the jinchuan intrusion was generated by melting of the enriched lithospheric mantle heated by an anomalously hot plume the u pb ages of 825 ma for igneous baddeleyites and zircons and 900 880 ma for inherited zircons in the jinchuan mafic ultramafic rocks are comparable with those in the qaidam block and qilian belt the western extension of the qinling belt that was likely derived from northern yangtze craton the jinchuan ni cu sulfide bearing intrusion along with coeval regional plume related mafic dykes and tholeiites and mafic ultramafic complexes with associated v ti and ni cu pge mineralization is interpreted to be genetically related to the 825 ma south china mantle plume

wood s metal dynamic wettability on quartz granite and limestone wood s metal wettability was experimentally studied as a function of both liquid and solid parameters the influence of solid liquid relative velocity wood s metal temperature and surface roughness on the unit work of wetting cos was analysed through tests on various specimens made of quartz synthetic single crystal la peyratte granite fine grained and coarse grained and soultz micrite sub micronic limestone a few tests with mercury were performed for comparison a slight temperature dependency is found on both quartz and rocks the largest effect being observed on quartz the most significant dependency observed on quartz la peyratte granite and soultz micrite is controlled by roughness rough specimens always show larger values of unit work of wetting cos when compared to polished ones a range of cos values is determined for each mineral and rocks which implies the determination of break through radii using laplace s equation within ranges of 7 10

detrital zircon constraint on the timing of amalgamation between alxa and ordos with exploration implications for jinchuan type ni cu ore deposit in china abstract the jinchuan ni cu deposit which is the largest single magmatic sulfide ore deposit in the world is hosted by a mafic ultramafic intrusion in the alxa block northwestern china the timing of amalgamation between the alxa block and the adjacent ordos block which is important for precambrian reconstruction of north china craton and the search for another jinchuan type ore deposit is contentious the age distribution patterns of detrital zircon crystals with precambrian ages from the devonian and older sedimentary rocks of the alxa and ordos blocks are similar this supports the traditional view that the alxa and ordos blocks were amalgamated in the paleoproterozoic along the 1 95 ga khondalite belt long before the emplacement of the 830 ma jinchuan intrusion the u pb lu hf isotope data of comagmatic zircon crystals from the jinchuan intrusion together with its whole rock sm nd isotopes and trace element compositions given previously by other researchers indicate that the jinchuan ore bearing intrusion is the product of continental rift related basaltic magmatism which took place during the early stage of rodinia breakup based on these observations we conclude that in addition to the alxa block the adjacent regions in the north china craton such as the ordos basin the khondalite belt and the yinshan terrane are most promising for new discoveries of jinchuan type ni cu ore deposits

collision belt between the khanka block and the north china block in the yanbian region northeast china the pre jurassic geotectonics in northeast china and its adjacent regions are characterized by collision of microcontinental blocks the yanbian region lies between the north china block ncb and the khanka block kb along the dashanzui antu kaishantun collision belt the yanbian pre jurassic fold belt can be divided into two parts one part represents the western margin of the kb which consists of late proterozoic metamorphic basement and a permian active continental margin the other one is located at the eastern margin of the ncb and is composed of proterozoic passive margin deposits where the seluohe and qinglongcun groups are developed and rocks of the permian passive margin collision of these two parts took place along the dashanzui antu kaishantun collision zone during the late permian to early triassic as evidenced by the emplacement of syncollision granites and a type granites in northeast china and adjacent regions a series of microcontinental blocks collided with one other from the end of early paleozoic to the early triassic the collision event that took place in the yanbian region may represent the latest collision event in the paleo asian oceanic domain c 2003 elsevier ltd all rights reserved

permian bimodal dyke of tarim basin nw china geochemical characteristics and tectonic implications abstract this study reports for the first time the occurrence of bimodal dyke in the shuigongtuan area of bachu county tarim basin nw china here quartz syenite porphyry and diabase dykes occur in direct contact showing bimodal feature the quartz syenitic porphyry is metaluminous enriched in k2o na2o 10 11 wt and total rare earth elements ree with low mg mg fe ratios high lree hree and negative eu anomalies the chemical characteristics and tectonic discriminative diagrams show that the rocks have geochemical affinity with a type granites the diabase dyke shows 45 52 wt sio2 and mg mg fe ratio in the range of with high total ree high lree hree ratios and lack of eu anomalies broadly corresponding to tholeiitic composition based on low y nb as low as 0 4 and less than 1 2 enrichment in lile and hfse and uniform nb enrichment patterns in spider diagram for the quartz syenitic porphyry together with the geochemical patterns of the diabases this biomodal association is interpreted to be derived from a mantle source and formed under typical within plate environment the quartz syenitic porphyry and diabase have daly gap of 46 wt 67 wt in sio2 which is explained through formation under bimodal rifting the quartz syenitic dyke probably formed during early permian 277 ma and has geochemical affinity with the xiaohaizi syenitic body we propose that magmas sourced from the mantle intruded into middle upper crust and were emplaced as dykes which indicate large scale extension during the permian in tarim basin the bimodal dyke has genetic affinity with the huge volume of permian basalts and igneous rocks 248 292 ma that occur in the tarim basin the magmatism manifests the culmination of the major thermal event in the tarim basin

lu hf and sm nd isotopic systematics in chondrites and their constraints on the lu hf properties of the earth sm nd and lu hf isotopic data are presented for 19 chondritic meteorites six carbonaceous chondrites five l chondrites seven h chondrites and a single enstatite chondrite the primary goal of the study is to better define the bulk silicate earth bse reference values for hf isotopes except for one sample with lower sm nd the sm nd data define a cluster around the accepted reference values for chondrites and terrestrial planets giving a mean 147sm 144nd of 0 1960 0 0005 and a mean 143nd 144nd of 0 512631 0 000010 uncertainties are two standard errors it seems appropriate to retain the presently accepted sm nd reference parameters 147sm 144nd 0 1966 and 143nd 144nd 0 512638 when fractionation corrected to 146nd 144nd 0 7219 lu hf isotopic data are not clustered but spread along an approximate 4 5 ga isochron trend with a range of 176lu 177hf from 0 0301 to 0 0354 the data are similar to many of the samples of chondrites presented by bizzarro et al nature 421 2003 931 but lack the range to lower lu hf shown by those authors our chondrite data define a regression line of 4 44 0 34 ga when 1 867 10 11 year 1 is used for the decay constant of 176lu science 293 2001 683 earth planet sci lett 219 2004 311 324 combining our data with the main population of analyses from bizzarro et al nature 421 2003 931 yields 4 51 0 24 ga unless samples of eucrite meteorites and deviating replicates of chondrites with 176lu 177hf less than 0 030 are employed no combination of the main population of chondrite lu hf data yields a regression with sufficiently low error to constrain the decay constant of 176lu sample heterogeneity seems to hinder the acquisition of reproducible lu hf analyses from small manually ground pieces of chondrites and we suggest that analysis of powders prepared from large volumes of meteorite will be needed to adequately characterize the lu hf isotope systematics of chondritic reservoirs and of bse our results for carbonaceous chondrites show higher average 176lu 177hf and 176hf 177hf than ordinary chondrites and the mean of carbonaceous chondrites also coincides with replicate analyses of a powder representing a large volume of meteorite the allende powder from the smithsonian institution use of the carbonaceous chondrite mean for bse lu hf characteristics results in a bse hf nd point that lies well within the array of terrestrial compositions and leads to plausible initial ehf values for precambrian rocks an improved objective resolution of meteorite data and of meteoritic models for the earth needs to occur before bse can be established for lu hf

a new genetic model for the giant ni cu pge sulfide deposits associated with the siberian flood basalts the kharaelakh intrusion is one of several sill like multiphase gabbroic intrusions that host world class ni cu pge deposits in the noril sk talnakh region the sulfide ores of the kharaelakh intrusion are characterized by elevated 34s values 10 12 and high pge concentrations e g up to10 ppm pt the 34s values require addition of crustal s with elevated isotope ratios such as evaporite bearing country rocks 34s 20 and r factors magma sulfide mass ratios of 2 000 if pt content in the magma is similar to the values in the coeval most undepleted lavas 10 ppb such a discrepancy can be explained by sulfide resorption by a new flux of mantle derived magma into a deep staging chamber to form pge enriched magma interaction of the pge enriched magma with evaporite bearing country rocks in the plumbing system at higher crustal levels could have produced sulfide liquids with high pge contents as well as elevated 34s values mass balance calculations indicate that 0 9 wt percent anhydrite assimilation from evaporite bearing country rocks is required to explain the elevated 34s values of the sulfide ores this model although developed purely based on data from the kharaelakh deposit can also be applied to other coeval ni cu pge deposits for the coeval noril sk i and talnakh deposits different depths of anhydrite assimilation in the respective plumbing systems are required this model differs from the previously proposed models in detail but reenforces the idea that chalcophile element depletion in continental flood basalts is a useful exploration tool for ni cu pge deposits associated with coeval subvolcanic intrusions

a type granites in northeastern china age and geochemical constraints on their petrogenesis abstract a type granites are widely distributed in northeastern china ne china they were emplaced during three major episodes the permian late triassic to early jurassic and early cretaceous and evolved in different tectonic regimes according to their mineralogical and geochemical characteristics two subgroups of a type granites aluminous and peralkaline can be recognized the peralkaline subgroup contains alkali mafic minerals such as riebeckite arfvedsonite and sodic pyroxene while the aluminous subgroup contains annite and fe rich calcic or sodic calcic amphibole with respect to the aluminous subgroup the peralkaline granites contain higher rb ga and total rare earth elements ree but lower mgo cao al 2 o 3 ba and sr based on the discrimination criteria of eby geology 20 1992 641 the permian and late triassic to early jurassic a type granites belong to the a 2 post orogenic type whereas the early cretaceous granites are of the a 1 anorogenic type nd isotopic compositions of these a type granites indicate their derivation from a dominantly juvenile crustal source their origin is thought to have involved partial melting of an underplated lower crustal source because the generation of a type granites requires high melting temperature we propose models involving slab break off lithospheric delamination and extension the permian a type granites have the same age range as those in eastern junggar southern mongolia and central inner mongolia they occur along a major suture and form a narrow belt between the north china and siberian cratons we suggest that their formation was associated with post collisional slab break off the late triassic to early jurassic a type granites are likely to be the product of lithospheric delamination after the final collision of the major crustal blocks in the late paleozoic to early triassic the early cretaceous a type granites have an anorogenic affinity and were possibly associated with rifting in eastern china at this time associated with the onset of paleo pacific subduction consequently we conclude that the a type granites in ne china were generated at three different times involving multiple processes operative in different tectonic environments

the composition of mineralization at the voisey s bay ni cu sulfide deposit with special reference to platinum group elements the ni cu platinum group element pge and au contents of massive sulfide mineralization leopard textured mineralization sulfides in basal breccia sequence and sulfides in varied troctolite from four mineralized environments the reid brook zone the discovery hill zone the ovoid and mini ovoid and the eastern deeps at voisey s bay have been determined modeling of the compositional data indicates that the large zone of massive sulfide comprising the ovoid has crystallized from the base upward with a fractionated residual liquid becoming concentrated toward the top massive mineralization from the mini ovoid reid brook zone and eastern deeps has undergone postcrystalliztion modification possibly due to the influence of heat from new influxes of magma through the plumbing system this has resulted in a considerable redistribution of cu and to a lesser extent of ni and au leopard textured mineralization from the reid brook and discovery hill zones corresponds closely with the postulated sulfide liquid compositions responsible for the ovoid and mini ovoid but mineralization composition from the feeder to the eastern deeps is exceptional in having many of the characteristics of a monosulfide solid solution cumulate the composition of disseminated and blotchy sulfides in the varied troctolite of the eastern deeps requires a variable but generally higher r factor than that affecting most of the sulfides to have operated here the compositional variability of the voisey s bay mineralization is best explained in terms of a model calling for repeated influxes of magma through the plumbing system to the deposit