LC temps de rétention (min) m/z observé Composition élémentaire Δppm Annotation Extrait apolaire 2.42 311.1455 [M+H] + C11H23N2O8 0.3 Glucopine, Mannopine ou isomère 309.1294 [M-H] - C11H21N2O8 -1.3 2.54 312.1295 [M+H] + C11H22NO9 0.0 Acide Mannopinique ou isomère 2.55 195.0500 [M-H] - C6H11O7 -2.6 Acide Gluconique ou isomére 3.09 341.1085 [M-H] - C12H21O11 0.3 Saccharose 4.61 294.1194 [M+H] + C11H20NO8 1.0 Non assigné 292.1029 [M-H] - C11H18NO8 -1.0 4.73 243.0618 [M-H] - C9H11N2O6 0.4 Uridine 4.74 268.1045 [M+H] + C10H14N5O4 -0.1 Adenosine 4.82 282.0836 [M-H] - C10H12N5O5 -0.7 Guanosine 4.96 180.1389 [M+H] + C11H18NO 0.6 Non assigné 5.25 253.1188 [M+H] + C12H17N2O4 0.0 Dipeptide Phe-Ser ou isomère 5.28 144.0485 [M+H] + ? - Non assigné 5.36 270.2542 [M+H] + ? - Non assigné 5.61 380.2914 [M+H] + C21H38N3O3 0.3 Non assigné 5.74 267.1345 [M+H] + C13H19N2O4 0.0 Dipeptide Thr-Phe ou isomère 265.1189 [M-H] - C13H17N2O4 0.4 5.98 299.0770 [M-H] - C13H15O8 1.0 Hydroxybenzoyl glucose 5.98 382.3071 [M+H] + C21H40N3O3 0.3 Cannabisativine 6.20 188.0713 [M+H] + C11H10NO2 0.5 Non assigné 6.41 284.2338 [M+H] + C15H30N3O2 0.0 Non assigné 6.54 233.1504 [M+H] + C10H21N2O4 1.3 Dipeptide Thr-Leu ou isomère 231.1345 [M-H] - C10H19N2O4 0.0 6.66 217.1554 [M+H] + C10H21N2O3 0.3 Dipeptide Val-Val ou isomére 215.1400 [M-H] - C10H19N2O3 1.9 6.79 215.1397 [M-H] - C10H19N2O3 0.5 Dipeptide Val-Val ou isomère 6.98 266.2232 [M+H] + ? - Non assigné 7.05 249.1244 [M-H] - C13H17N2O3 2.0 Non assigné 7.22 467.1552 [M-H] - C22H27O11 -0.2 Non assigné 7.50 236.0556 [M-H] - C11H10NO5 -1.3 Non assigné 7.50 268.2386 [M+H] + C15H30N3O -1.1 Non assigné 7.59 326.2445 [M+H] + C17H32N3O3 0.3 Non assigné 7.87 444.1658 [M-H] - C23H26NO8 0.0 N-Coumaroyltyramine glucoside 282.1129 [M-H-Glu] - C17H16NO3 -0.4 N-Coumaroyltyramine fragment 7.98 476.1922 [M+H] + C24H30NO9 0.2 N-Feruloyltyramine glucoside 474.1771 [M-H] - C24H28NO9 1.5 N-Feruloyltyramine glucoside 312.1239 [M-H-Glu] - C18H18NO4 1.0 N-Feruloyltyramine fragment 8.10 474.1762 [M-H] - C24H28NO9 -0.4 N-Feruloyltyramine glucoside isomer2 8.20 328.2602 [M+H] + C17H34N3O3 0.6 Non assigné 8.53 488.1920 [M-H] - C25H30NO9 -0.2 Non assigné 8.78 121.0290 [M-H] - C7H5O2 0.0 Acide benzoique 9.59 298.1076 [M-H] - C17H16NO4 -1.0 N-Caffeoyltyramine 9.80 453.2337 [M-H] - C20H37O11 0.2 Non assigné 10.00 187.0966 [M-H] - C9H15O4 -2.1 Acide azelaique 10.57 423.2235 [M-H] - C19H35O10 1.2 Non assigné 10.82 325.2277 [M+H] + C21H29N2O -0.9 Non assigné 10.94 284.1288 [M+H] + 282.1132 [M-H] - C17H18NO3 C17H16NO3 0.4 0.7 N-Coumaroyltyramine 11.26 314.1393 [M+H] + 312.1241 [M-H] - C18H20NO4 C18H18NO4 0.3 1.0 N-Feruloyltyramine 12.06 625.2550 [M+H] + 623.2396 [M-H] - C36H37N2O8 C36H35N2O8 0.0 0.5 Cannabisine D ou G ou F ou isomère 12.19 328.1548 [M+H] + C19H22NO4 -0.3 Non assigné 12.27 625.2550 [M+H] + 623.2401 [M-H] - C36H37N2O8 C36H35N2O8 0.0 1.3 Cannabisine D ou G ou F ou isomère 13.21 327.2178 [M-H] - C18H31O5 2.1 Dérivé d’acide gras C18 14.18 329.2334 [M-H] - C18H33O5 1.8 Dérivé d’acide gras C18 14.55 565.2342 [M+H] + C34H33N2O6 0.5 Non assigné 14.70 625.2556 [M+H] + 623.2394 [M-H] - C36H37N2O8 C36H35N2O8 1.0 0.3 Cannabisine D ou G ou F ou isomère 15.41 639.2704 [M+H] + 637.2552 [M-H] - C37H39N2O8 C37H37N2O8 -0.3 0.3 Non assigné 16.11 316.2852 [M+H] + C18H38NO3 0.0 Dérivé Sphingosine 16.49 934.3574 [M-H] - ? - Non assigné 17.03 318.3006 [M+H] + C18H40NO3 -0.6 Dérivé Sphingosine 18.82 476.2780 [M-H] - ? - Non assigné 19.99 603.3898 [M+H] + 601.3741 [M-H] - C35H55O8 C35H53O8 0.2 0.2 Non assigné 24.21 471.3109 [M-H] - C29H43O5 -0.2 Non assigné 24.34 481.2936 [M+H] + C30H41O5 -3.7 Non assigné 24.63 271.2271 [M-H] - C16H31O3 -0.7 Acide Palmitique 25.59 355.3218 [M-H] - C22H43O3 1.7 Acide Hydroxydocosanoique 26.26 455.3532 [M-H] - C30H47O3 1.5 Triterpène (oleanolique ou ursolique ou isomère) 26.90 299.2593 [M-H] - C18H35O3 2.3 Dérivé d’acide gras C18 28.22 605.4058 [M-H] - C36H53N4O4 -1.5 Non assigné Extrait polaire 2.42 311.1455 [M+H] + 309.1294 [M-H] - C11H23N2O8 C11H21N2O8 0.3 -1.3 Glucopine or Mannopine ou isomére 2.54 312.1295 [M+H] + C11H22NO9 0.0 Acide Mannopinique ou isomère 2.55 195.0500 [M-H] - C6H11O7 -2.6 Acide Gluconique ou isomère 2.77 404.1041 [M-H] - C12H22NO14 0.2 Non assigné 3.09 341.1085 [M-H] - C12H21O11 0.3 Saccharose 3.18 253.0926 [M-H] - C9H17O8 1.2 Hexoside de Glycerol 3.91 606.0735 [M-H] - C25H20NO17 0.7 Non assigné 4.61 294.1194 [M+H] + 292.1029 [M-H] - C11H20NO8 C11H18NO8 1.0 -1.0 Non assigné 4.82 282.0836 [M-H] - C10H12N5O5 -0.7 Guanosine 5.74 267.1345 [M+H]+ 265.1189 [M-H]- C13H19N2O4 C13H17N2O4 0.0 0.4 Dipeptide Thr-Phe ou isomère 6.54 233.1504 [M+H]+ 231.1345 [M-H]- C10H21N2O4 C10H19N2O4 1.3 0.0 Dipeptide Thr-Leu ou isomère 6.66 217.1554 [M+H]+ 215.1400 [M-H]- C10H21N2O3 C10H19N2O3 0.3 1.9 Dipeptide Val-Val ou isomère 6.98 266.2232 [M+H]+ ? - Non assigné 7.50 236.0556 [M-H]- C11H10NO5 -1.3 Non assigné 7.50 268.2386 [M+H]+ C15H30N3O -1.1 Non assigné 8.20 328.2602 [M+H]+ C17H34N3O3 0.6 Non assigné