Hengzongshu/ArticleAgent huggingface dataset:
Model bimetallic Pd-Au/HOPG catalysts have been investigated in the CO oxidation reaction using a combination of NAP XPS and MS techniques. The samples have shown catalytic activity at temperatures above 150 °C. The redistribution of Au and Pd on the surface depending on the reaction conditions has been demonstrated using NAP XPS. The Pd enrichment of the bimetallic particles' surface under reaction gas mixture has been shown. Apparently, CO adsorption induces Pd segregation on the surface. Heating the sample under reaction conditions above 150 °C decomposes the Pd-CO state due to CO desorption and reaction and simultaneous Pd-Au alloy formation on the surface takes place. Cooling back down to RT results in reversible Pd segregation due to Pd-CO formation and the sample becomes inactive. It has been shown that in situ studies are necessary for investigation of the active sites in Pd-Au bimetallic systems.
The flow around a solid plate and a plate with a sound-absorbing coating at a non-zero angle of attack in a hypersonic flow (M∞=8.44) of a mixture of vibrationally excited carbon dioxide and nitrogen is considered. Numerical simulations are performed by solving two-dimensional unsteady Navier–Stokes equations with a two-temperature model of relaxing flows. The vibrational energy as a function of time is defined by the Landau–Teller equation. A skeleton model, which is a set of square elements arranged in a staggered order, is used for simulating the porous coating made of foamed nickel with a porosity coefficient of 95%. The distance between the elements is equal to the pore diameter of the real sound-absorbing material. Data on the evolution of disturbances on the solid plate and on the plate with the sound-absorbing coating are presented for various angles of attack and CO2 concentrations in the mixture. The experimental and calculated data on pressure fluctuations on the plate surfaces are found to be in good agreement. The effects of various parameters of the sound-absorbing coating (depth, length, and location at the flat plate) are considered. It is shown that the sound-absorbing coating significantly reduces the intensity of pressure fluctuations on the plate surface as compared to the solid surface (up to 50% depending on the length and location of the sound-absorbing coating).
The notion of a derivation with invertible values as a derivation of ring with unity that only takes multiplicatively invertible or zero values appeared in a paper of Bergen, Herstein and Lanski, in which they determined the structure of associative rings that admit derivations with invertible values. Later, the results of this paper were generalized in many cases, for example, for generalized derivations, associative superalgebras, alternative algebras and many others. The present work is dedicated to the description of all Jordan algebras admitting derivations with invertible values.
There is experimental evidence that chronic social defeat stress is accompanied by the development of an anxiety, development of a depression-like state, and downregulation of serotonergic genes in midbrain raphe nuclei of male mice.

Our study was aimed at investigating the effects of chronic lithium chloride (LiCl) administration on anxiety behavior and the expression of serotonergic genes in midbrain raphe nuclei of the affected mice. A pronounced anxiety-like state in male mice was induced by chronic social defeat stress in daily agonistic interactions. After 6 days of this stress, defeated mice were chronically treated with saline or LiCl (100 mg/kg, i.p., 2 weeks) during the continuing agonistic interactions. Anxiety was assessed by behavioral tests. RT-PCR was used to determine Tph2, Htr1a, Htr5b, and Slc6a4 mRNA expression.

The results revealed anxiolytic-like effects of LiCl on social communication in the partition test and anxiogenic-like effects in both elevated plus-maze and social interaction tests. Chronic LiCl treatment upregulated serotonergic genes in midbrain raphe nuclei. Thus, LiCl effects depend on the treatment mode, psycho-emotional state of the animal, and experimental context (tests). It is assumed that increased expression of serotonergic genes is accompanied by serotonergic system activation and, as a side effect, by higher anxiety.
Alterations in white matter (WM) microstructure have been implicated in the pathophysiology of major depressive disorder (MDD). However, previous findings have been inconsistent, partially due to low statistical power and the heterogeneity of depression. In the largest multi-site study to date, we examined WM anisotropy and diffusivity in 1305 MDD patients and 1602 healthy controls (age range 12–88 years) from 20 samples worldwide, which included both adults and adolescents, within the MDD Working Group of the Enhancing Neuroimaging Genetics through Meta-Analysis (ENIGMA) consortium. Processing of diffusion tensor imaging (DTI) data and statistical analyses were harmonized across sites and effects were meta-analyzed across studies. We observed subtle, but widespread, lower fractional anisotropy (FA) in adult MDD patients compared with controls in 16 out of 25 WM tracts of interest (Cohen's d between 0.12 and 0.26). The largest differences were observed in the corpus callosum and corona radiata. Widespread higher radial diffusivity (RD) was also observed (all Cohen's d between 0.12 and 0.18). Findings appeared to be driven by patients with recurrent MDD and an adult age of onset of depression. White matter microstructural differences in a smaller sample of adolescent MDD patients and controls did not survive correction for multiple testing. In this coordinated and harmonized multisite DTI study, we showed subtle, but widespread differences in WM microstructure in adult MDD, which may suggest structural disconnectivity in MDD.
An analytical solution in a closed form is obtained for the three-dimensional elastic strain distribution in an unlimited medium containing an inclusion with a coordinate-dependent lattice mismatch (an eigenstrain). Quantum dots consisting of a solid solution with a spatially varying composition are examples of such inclusions.

It is assumed that both the inclusion and the surrounding medium (the matrix) are elastically isotropic and have the same Young modulus and Poisson ratio. The inclusion shape is supposed to be an arbitrary polyhedron, and the coordinate dependence of the lattice misfit, with respect to the matrix, is assumed to be a polynomial of any degree. The method of constructing the relevant polynomial functions is suggested.

It is shown that, both inside and outside the inclusion, the strain tensor is expressed as a sum of contributions of all faces, edges and vertices of the inclusion. Each of these contributions, as a function of the observation point's coordinates, is a product of some polynomial and a simple analytical function, which is the solid angle subtended by the face from the observation point (for a contribution of a face), or the potential of the uniformly charged edge (for a contribution of an edge), or the distance from the vertex to the observation point (for a contribution of a vertex). We also found out that similar expressions describe an electrostatic or gravitational potential, as well as its first and second derivatives, of a polyhedral body with a charge/mass density that depends on coordinates polynomially.
This paper is concerned with the numerical solution of the unified first order hyperbolic formulation of continuum mechanics recently proposed by Peshkov and Romenski [110], further denoted as HPR model. In that framework, the viscous stresses are computed from the so-called distortion tensor A, which is one of the primary state variables in the proposed first order system. A very important key feature of the HPR model is its ability to describe at the same time the behavior of inviscid and viscous compressible Newtonian and non-Newtonian fluids with heat conduction, as well as the behavior of elastic and visco-plastic solids. Actually, the model treats viscous and inviscid fluids as generalized visco-plastic solids. This is achieved via a stiff source term that accounts for strain relaxation in the evolution equations of A. Also heat conduction is included via a first order hyperbolic system for the thermal impulse, from which the heat flux is computed. The governing PDE system is hyperbolic and fully consistent with the first and the second principle of thermodynamics. It is also fundamentally different from first order Maxwell–Cattaneo-type relaxation models based on extended irreversible thermodynamics. The HPR model represents therefore a novel and unified description of continuum mechanics, which applies at the same time to fluid mechanics and solid mechanics.

In this paper, the direct connection between the HPR model and the classical hyperbolic–parabolic Navier–Stokes–Fourier theory is established for the first time via a formal asymptotic analysis in the stiff relaxation limit. From a numerical point of view, the governing partial differential equations are very challenging, since they form a large nonlinear hyperbolic PDE system that includes stiff source terms and non-conservative products. We apply the successful family of one-step ADER–WENO finite volume (FV) and ADER discontinuous Galerkin (DG) finite element schemes to the HPR model in the stiff relaxation limit, and compare the numerical results with exact or numerical reference solutions obtained for the Euler and Navier–Stokes equations. Numerical convergence results are also provided.

To show the universality of the HPR model, the paper is rounded-off with an application to wave propagation in elastic solids, for which one only needs to switch off the strain relaxation source term in the governing PDE system. We provide various examples showing that for the purpose of flow visualization, the distortion tensor A seems to be particularly useful.
The Cover Feature shows that nature and crystal structure of the two-dimensional PbII iodoacetate complex {Pb(ICH3COO)2}n featuring non-covalent I···I and Pb···I contacts can be mysterious and bewitching like the corals of the Great Barrier Reef.

It was shown that, although there are I···I contacts in its structure, those non-covalent interactions cannot be regarded as "true halogen bonding". Moreover, although it could be expected that the lone pair of PbII interacts with the σ-hole of iodine, an alternative situation is observed (Pb2+ acts as electrophilic center).

More information can be found in the Communication by S. A. Adonin et al.
The catalysts provided complete conversion of DME to hydrogen-rich gas with low (≤ 0,8 vol.%) CH4 content and Н2 productivity ~3,1 l/(gcat · h) at 350 °C under ambient pressure using a reaction mixture (molar ratio): DME : O2 : N2 = 1 : 1 : 4 (DME : air = 1 : 5) at a flow rate 7 l/(gcat · h).

The promise of СuO-CeO2/γ-Al2O3 catalysts for partial oxidation of dimethyl ether (DME) to hydrogen-rich gas for fuel cell feeding was demonstrated.
In the paper, numerical simulation of shock wave propagation in the vicinity of a standalone prism and a prism with a cavity in front of it was carried out. The modeling was based on the solution of 3D Euler equations and Fluent software was used as a main computational tool. The algorithm for local dynamic mesh adaptation to high gradients of pressure was applied. The initial stage of the explosion of condensed explosive was described with the help of "Compressed balloon method". The research allowed describing the characteristic stages of the blast in a semi-closed space, the structure of secondary shock waves and their interaction with obstacles. The numerical approach in Fluent based on combining inviscid gas dynamics methods and "Compressed balloon method" was compared with the method which had been used by the authors earlier with the help of AUTODYN and which is based on the use of the hydrodynamic model of a material to describe state of detonation products. For the problem of shock wave propagation in the vicinity of standalone prism the comparison of the simulation results obtained using both the methods with the experimental data was performed on the dependence of static pressure and effective momentum on time for the characteristic points located on prism walls.
We improve Algorithm 5.1 of [Math. Comp. {\bf 86} (2017), 2519-2534] for computing all non-isomorphic skew left braces, and enumerate left braces and skew left braces of orders up to 868 with some exceptions. Using the enumerated data, we state some conjectures for further research.
We report on the study of terahertz radiation-induced MIRO-like oscillations of magnetoresistivity in GaAs heterostructures.

Our experiments provide an answer on two most intriguing questions---effect of radiation helicity and the role of the edges---yielding crucial information for an understanding of the MIRO (microwave-induced resistance oscillations) origin.

Moreover, we demonstrate that the range of materials exhibiting radiation-induced magneto-oscillations can be largely extended by using high-frequency radiation.
Derivatives of natural diterpenoid lambertianic acid containing alkyne and dialkyne substituent in the furan ring were obtained.1,2,3-Triazole-incarporated furan bridged macrocycles have been prepared by 1,3-dipolar cycloaddition of methyl 15,16-bis[(prop-2-yn-1-yloxy)methyl]lambertianate with various diazides in the presence of Cu(II)/sodium ascorbate in methylene chloride/water reaction medium.
Glass tube reactors with Pd, Pt, Rh or Ir nanoparticles dispersed on a thin layer of TiO2, CeO2, SiO2 or Al2O3

provided mechanistic insight into the hydrogenation of 1,3-butadiene using parahydrogen
In the crust, they show a prominent linear anomaly in central Hokkaido along the Kamuikotan and Hidaka Belts, which represents the area of eastward underthrusting of the Japan Block underneath the Kuril fore arc. We interpret the high‐velocity anomaly beneath the Hidaka zone as being delaminated mafic crust and entrained mantle lithosphere, which developed due to crustal shortening in the collision zone.

We present a new 3‐D anisotropic seismic model for the crust and upper mantle beneath Hokkaido (Japan) based on tomographic inversion of P and S arrival times from a regional seismic database. The P model is parameterized with three parameters at each point that describe the azimuthal anisotropy; the S model is represented isotropically. The isotropic P and S velocity anomalies match nearly perfectly.

One of our vertical sections shows a very unusual configuration for a subduction zone: a low‐velocity slab is overlain by a high‐velocity body in the mantle wedge. We propose that the high‐velocity delaminated material sinking along the slab surface prevents the escape of fluids and melts from the upper part of the slab, where they are generated due to phase transitions. As a result, a large portion of the fluids is entrained downward and lowers the seismic velocities in the slab. The azimuthal anisotropy in the crust clearly corresponds to the major tectonic units and delineates the major suture zones. In the mantle, the anisotropy has a fan‐shaped configuration and most likely represents the deviating of flows starting in southern Hokkaido and splitting into three directions. The western and eastern flows proceed toward the two volcanic groups on Hokkaido, and they may carry with them additional material to trigger the characteristic caldera‐forming eruptions in these groups.
We study the process $e^+e^- \to \pi^+\pi^-\eta \gamma$, where the photon is radiated from the initial state. About 8000 fully reconstructed events of this process are selected from the BaBar data sample with an integrated luminosity of 469~fb$^{-1}$. Using the $\pi^+\pi^-\eta$ invariant mass spectrum we measure the $e^+e^- \to \pi^+\pi^-\eta$ cross section in the $e^+e^-$ center-of-mass energy range from 1.15 to 3.5 GeV. The cross section is well described by the Vector-Meson Dominance model with four $\rho$-like states. We observe $49\pm9$ events of the $J/\psi$ decay to $\pi^+\pi^-\eta$, and measure the product $\Gamma_{J/\Psi \to e^+e^-} \text{B}_{J/\Psi \to \pi^+\pi^-\eta} = 2.34 \pm 0.43_{\text{stat}} \pm 0.16_{\text{syst}}$~eV.
We have previously shown that immunization of C57BL/6 mice, prone to spontaneous development of experimental autoimmune encephalomyelitis (EAE), with three antigens (MOG 35‐55 , DNA‐histone complex or DNA‐methylated BSA complex), alters the differentiation profiles of bone marrow haematopoietic stem cells (HSCs). These are associated with the production of autoantibodies (auto‐Abs) against these antigens and the formation of abzymes hydrolysing DNA, MOG, myelin basic protein (MBP) and histones. Immunization of mice with antigens accelerates the development of EAE. This work is the first to analyse the ratio of auto‐Abs without and with catalytic activities at different stages of EAE development (onset, acute and remission phases) after immunization of mice with the three specific antigens. Prior to immunization and during spontaneous in‐time development of EAE, the concentration of auto‐Abs against MBP, MOG, histones and DNA and activities of IgG antibodies in the hydrolysis of substrates increased in parallel; correlation coefficients = +0.69‐0.94. After immunization with MOG, DNA‐histone complex or DNA‐met‐BSA complex, both positive (from +0.13 to +0.98) and negative correlations (from −0.09 to −0.69) were found between these values. Our study is the first showing that depending on the antigen, the relative amount of harmful auto‐Abs without and abzymes with low or high catalytic activities may be produced only at onset and in acute or remission phases of EAE. The antigen governs the EAE development rate, whereby the ratio of auto‐Abs without catalytic activity and with enzymatic activities of harmful abzymes hydrolysing MBP, MOG, histones and DNA varies strongly between different disease phases.
In China, rock art is spread mainly in the border regions – carvings and engravings in the north of the country and paintings in the south. Before the beginning of the 21st century, research books and albums of petroglyphs were published in four administrative units at provincial level in the north-west of the county: Inner Mongolia, Ningxia, Xinjiang and Qinghai. Petroglyphs of Inner Mongolia were studied and published by Gai Shanlin, Liang Zhenhua and N. Dalengurib. The earliest and the latest books by Gai Shanlin available to us (published in 1985 and 2002 respectively) were entirely devoted to the interpretation of rock carvings and searches for their analogies. All four monographs on Ningxia rock art – by Zhou Xinghua, Li Xiangshi and Zhu Cunshi, Xu Cheng and Wei Zhong were published almost simultaneously, at the beginning of the 1990s. Ancient rock art of Xinjiang was published in albums by Zhao Yangfeng, Wang Linshan and Wang Bo and in books by Wang Binghua and Su Beihai. The monograph by Tang Huisheng and Zhang Wenhua was devoted to the description of Qinghai petroglyphs and the problems of their interpretation.

The album of photos 'The Rock Arts of China' is a kind of a guide to the main rock art sites known by 1993 in all the Chinese provinces.

Generally, it can be stated that modern Chinese scientific rock art research was born in the first half of the 1980s, when the first articles on rock carvings started to appear in Chinese archaeological periodicals and flourished in the second half of the 1980s and the 1990s, when quite a number of monographs were published.
Below is data on the microbial diversity in bottom sediments and microbial mats in water bodies within the Kurai Mercury Province (Ulagan District, Aktash village, Gorny Altai). A database on the geochemical features of water bodies in the study area is presented. Data was obtained using 16 s rRNA amplicon directed metagenomic sequencing on Illumina MiSeq. The raw sequence data used for analysis is available in NCBI under the Sequence Read Archive (SRA) with BioProject No. PRJNA670076 and SRA accession numbers SRX9316205, SRX9316207, SRX9316208, SRX9316209.
We consider the optical fiber channel modeled by the nonlinear Schrödinger equation with zero dispersion and additive Gaussian noise. Using the Feynman path-integral approach for the model, we find corrections to conditional probability density function, output signal distribution, conditional and output signal entropies, and the channel capacity at large signal-to-noise ratio. We demonstrate that the correction to the channel capacity is positive for large signal power. Therefore, this correction increases the earlier calculated capacity for a nondispersive nonlinear optical fiber channel in the intermediate power region.
We continue the study of the compound reneal processes (c.r.p.), where the moment Cramer's condition holds (see [1]-[10], where the study of c.r.p. was started).In the paper arithmetic c.r.p.Z(n) are studied.In such processes random vector ξ = (τ, ζ) has the arithmetic distribution, where τ > 0 defines the distance between jumps, ζ defines the values of jumps.For this processes the fine asymptotics in the local limit theorem for probabilities P(Z(n) = x) has been obtained in Cramer's deviation region of x ∈ Z In [6]-[10] the similar problem has benn solved for non-lattice c.r.p., when the vector ξ = (τ, ζ) has the non-lattice distribution.
Exfoliation of metal-organic frameworks is one of the technological strategy for fabrication of complex metal-organic structures for catalysis and energy storage.

Here we report on exfoliation of 2D metal-organic frameworks in ultrasonic bath for creating monolayers for further investigation of morphology and mechanics of the layers by atomic force microscopy.
To study indicators of bone mineral densit (BMD) and trabecular bone score (TBS) and to reveal the 10-year fracture risk (FRAX®) taking into account the data obtained in persons with type 2 diabetes (DM2).

A clinical study of the type of case - control. The study included 122 people with and without DM2. All persons were: questionnaires, anthropometry, densitometry, determination of TBS and fracture risk on the FRAX®.

Persons with DM2 and fractures have higher BMD values, lower than the FRAX fracture risk values adjusted for the T-score, do not differ significantly in TBS, which determines the difficulties in diagnosis, the need to find additional methods for early diagnosis of increased fracture risk in patients with DM2.
The Bertaut approach associated with charge spreading so as to enhance the rate of convergence of Coulomb series in crystals is extended to the case of an arbitrary multiple spreading with a given initial spreading function.

It is shown that the effect of spreading may in general be treated as a uniform transformation of space, providing that zero mean potential as a universal spatial property is sustained. As a result, electrostatic potentials driven by different orders of multiple spreading can be obtained from the same energy functional in a consistent manner.

It is found that the effect of multiple spreading gives rise to more advanced forms described, for example, by simple exponential decrease, but the functional description based on a Gaussian spreading turns out to be invariant. In addition, the effects of a multiple charge spreading based on simple exponential and Gaussian spreading functions are compared as typical of molecular calculations.