Hengzongshu/ArticleAgent huggingface dataset:
Structure-magnetism relationship represents a long-lasting trend in the coordination chemistry.It is manifested by a number of magnetostructural J-correlations where the exchange coupling constant (J) is correlated with some structural parameters (bond angles in bridged complexes).Recently, a magnetostructural D-correlation has been proposed for Ni(II) complexes [1].Within this contribution, a series of mononuclear Co(II) complexes has been synthesized and structurally characterized with the aim to correlate the zero-field splitting parameter (D) with the structural tetragonality of cobalt complexes.
We report a measurement of the branching fraction ratios R(D(*)) of Bbar -> D(*) tau- nubar_tau relative to Bbar -> D()* l- nubar_l (where l = e or mu) using the full Belle data sample of 772 x 10^6 BBbar pairs collected at the Y(4S) resonance with the Belle detector at the KEKB asymmetric-energy e+e- collider. The measured values are R(D)= 0.375 +- 0.064(stat.) +- 0.026(syst.) and R(D*) = 0.293 +- 0.038(stat.) +- 0.015(syst.). The analysis uses hadronic reconstruction of the tag-side B meson and purely leptonic tau decays. The results are consistent with earlier measurements and do not show a significant deviation from the standard model prediction.
The selectivity of Fe-MFI catalysts to partial peroxide oxidation of methane to methanol and formic acid was studied depending on their topology (Nanocrystals, Microcrystals, and bulk Commercial) and activation with oxalic acid.

The catalysts were characterized by XRD, ICP-OES, SEM, UV-vis DR, NH3-TPD, N2 adsorption. TOF of methane oxidation increased in the series: Nanocrystals < Microcrystals << Commercial. The selectivity to methanol depended mainly on the crystallite size and increased in the same series.

The increase in TOF and selectivity to formic acid, as well as a sharp decrease in the selectivity to CO2 over all the activated catalysts were accounted for by an increase in the total acidity of the catalysts and the number of oligomeric Fe oxo-clusters. Different pathways to the formation of methanol/CO2 (via free radical mechanism) and formic acid (via heterogeneous route) over Fe-MFI catalysts were suggested.
The paper is devoted to the study of free objects in the variety of Steiner loops and of the combinatorial structures behind them, focusing on their automorphism groups. We prove that all automorphisms are tame and the automorphism group is not finitely generated if the loop is more than $3$-generated. For the free Steiner loop with $3$ generators we describe the generator elements of the automorphism group and some relations between them.
Microinclusions of high-density fluids (HDFs) were studied in coated diamonds from the Udachnaya kimberlite pipe (Siberian craton, Russia). The presence of C-centers in the coats testifies to their formation shortly before kimberlite eruption, whereas the cores have much longer mantle residence in chemically different mantle substrates, i.e., peridotite-type (P-type) and eclogite-type (E-type). The carbon isotope composition indicates an isotopically homogeneous carbon source for coats and a heterogeneous source for cores.

Microinclusions in the coats belong to two groups: high-Mg carbonatitic and low-Mg carbonatitic to silicic. A relationship was found between high-Mg carbonatitic HDFs and peridotitic host rocks and between low-Mg carbonatitic to silicic and eclogites.

The composition of high-Mg carbonatitic HDFs with a 'planed' trace-element pattern can evolve to low-Mg carbonatitic to silicic during percolation through different mantle rocks. The compositional variations of microinclusions in the coats reflect this evolution.
Electronic correlation is believed to play an important role in exotic phenomena such as insulator-metal transition, colossal magneto resistance and high temperature superconductivity in correlated electron systems. Recently, it has been shown that electronic correlation may also be responsible for the formation of unconventional plasmons.

Herewith, using a combination of angle-dependent spectroscopic ellipsometry, angle resolved photoemission spectroscopy and Hall measurements all as a function of temperature supported by first-principles calculations, the existence of low-loss high-energy correlated plasmons accompanied by spectral weight transfer, a fingerprint of electronic correlation, in topological insulator (Bi$_{0.8}$Sb$_{0.2}$)$_2$Se$_3$ is revealed.

Upon cooling, the density of free charge carriers in the surface states decreases whereas those in the bulk states increase, and that the newly-discovered correlated plasmons are key to explaining this phenomenon. Our result shows the importance of electronic correlation in determining new correlated plasmons and opens a new path in engineering plasmonic-based topologically-insulating devices.
We report synthesis of 15N-3-19F-pyridine via Zincke salt formation with overall 35% yield and 84% 15N isotopic purity. Hyperpolarization studies of signal amplification by reversible exchange (SABRE) and SABRE in SHield Enables Alignment Transfer to Heteronuclei (SABRE-SHEATH) were performed to investigate the mechanism of polarization transfer from parahydrogen-derived hydride protons to 19F nucleus in millitesla and microtesla magnetic-field regimes in 15N-3-19F-pyridine and 14N-3-19F-pyridine. We found the mismatch between 15N and 19F magnetic-field hyperpolarization profiles in the microtesla regime indicating that the spontaneous hyperpolarization process likely happens directly from parahydrogen-derived hydride protons to 19F nucleus without spin-relaying via 15N site. In the case of SABRE magnetic-field regime (millitesla magnetic-field range), we found that magnetic-field profiles for 1H and 19F hyperpolarization are very similar and 19F polarization levels are significantly lower than 1H SABRE polarization levels and lower than 19F SABRE-SHEATH (i.e., obtained at microtesla magnetic field) polarization levels. Our findings support the hypothesis that in millitesla magnetic-field regime, the process of 19F nuclei hyperpolarization is relayed via protons of the substrate and therefore is very inefficient. These findings are important in the context of improvement of the hyperpolarization hardware and rational design of the hyperpolarized molecular probes.
The natural variation of starch phosphate content in potatoes has been previously reported. It is known that, in contrast to raw starch, commercially phosphorylated starch is more stable at high temperatures and shear rates and has higher water capacity. The genetic improvement of phosphate content in potato starch by selection or engineering would allow the production of phosphorylated starch in a natural, environmentally friendly way without chemicals.

The aim of the current research is to identify genomic SNPs associated with starch phosphorylation by carrying out a genome-wide association study in potatoes. A total of 90 S. tuberosum L. varieties were used for phenotyping and genotyping. The phosphorus content of starch in 90 potato cultivars was measured and then statistically analysed. Principal component analysis (PCA) revealed that the third and eighth principal components appeared to be sensitive to variation in phosphorus content (p = 0.0005 and p = 0.002, respectively). PC3 showed the correlation of starch phosphorus content with allelic variations responsible for higher phosphorylation levels, found in four varieties. Similarly, PC8 indicated that hybrid 785/8–5 carried an allele associated with high phosphorus content, while the Impala and Red Scarlet varieties carried alleles for low phosphorus content. Genotyping was carried out using an Illumina 22 K SNP potato array. A total of 15,214 scorable SNPs (71.7% success rate) was revealed. GWAS mapping plots were obtained using TASSEL based on several statistical models, including general linear models (GLMs), with and without accounting for population structure, as well as MLM.

A total of 17 significant SNPs was identified for phosphorus content in potato starch, 14 of which are assigned to 8 genomic regions on chromosomes 1, 4, 5, 7, 8, 10, and 11. Most of the SNPs identified belong to protein coding regions; however, their allelic variation was not associated with changes in protein structure or function. A total of 8 novel genomic regions possibly associated with starch phosphorylation on potato chromosomes 1, 4, 5, 7, 8, 10, and 11 was revealed. Further validation of the SNPs identified and the analysis of the surrounding genomic regions for candidate genes will allow better understanding of starch phosphorylation biochemistry. The most indicative SNPs may be useful for developing diagnostic markers to accelerate the breeding of potatoes with predetermined levels of starch phosphorylation.
The Holliday junction (HJ), a cross-shaped structure that physically links the two DNA helices, is a key intermediate in homologous recombination, DNA repair, and replication. Several helicase-like proteins are known to bind HJs and promote their branch migration (BM) by translocating along DNA at the expense of ATP hydrolysis. Surprisingly, the bacterial recombinase protein RecA and its eukaryotic homologue Rad51 also promote BM of HJs despite the fact they do not bind HJs preferentially and do not translocate along DNA. RecA/Rad51 plays a key role in DNA double-stranded break repair and homologous recombination. RecA/Rad51 binds to ssDNA and forms contiguous filaments that promote the search for homologous DNA sequences and DNA strand exchange. The mechanism of BM promoted by RecA/RAD51 is unknown. Here, we demonstrate that cycles of RecA/Rad51 polymerization and dissociation coupled with ATP hydrolysis drives the BM of HJs.
The modeling of the Couette flow in a circular gap between coaxial cylinders is considered, including rarefied gas conditions at large Knudsen numbers. When developing the experimental facility for this purpose, the geometric sizes were determined taking into account minimum deviation of the velocity profile in the gap from the linear one in the case of laminar flow regime, and also to prevent the formation of Taylor-Görtler vortices with the chosen flow parameters. A series of tests was performed using the hot-wire at atmospheric pressure. It was cofirmed the operability of the facility itself and satisfactory matching of the hot-wire calibration data using the proposed method in the Couette flow and standard data obtained in the DISA calibration wind tunnel. Preliminary data for influence the Knudsen number on the heat transfer between the hot-wire probe and flow.
Based on seismic data from existing seismic networks in Kyrgyzstan, we have constructed new crustal models of seismic velocity and attenuation for P and S wave s beneath the Kyrgyz Tien Shan. With data from more than 6,000 events recorded by the international KNET network, the most detailed structures were detected in the central‐northern part of the study region, where the Kazakh Shield collides with the northern Tien Shan. The independently computed 3‐D distributions of P and S wave attenuation show features that are consistent with the main structural elements. The high‐attenuation areas correspond to folded areas of the northern Tien Shan, whereas the partitions of the stable Kazakh Shield and the Issyk Kul block match with the low‐attenuation areas. The velocity model reveals some structures that help to determine the details of the collision processes in the northern Tien Shan. In the upper crust, we observe the alternation of several higher‐ and lower‐velocity anomalies that likely represent the interaction of brittle and ductile crustal layers of the collided Kazakh and Tien Shan plates. In deeper sections, both P and S wave velocity models show a prominent low‐velocity anomaly just beneath the northern boundary of Tien Shan. We propose that this anomaly represents an anomalous crustal thickening at the point of underthrusting of the Kazakh Plate beneath Tien Shan.
The initial stages of etching the monoclinic (I) and the orthorhombic (II) polymorphs of paracetamol crystals by a series of agents (10%-solutions of acetic anhydride, pyridine, 1,4dioxane, morpholine, N-methylmorpholine in carbon tetrachloride) were studied

and the corresponding etching patterns were compared

For the first time, it was possible to observe different etching patterns when dissolving not only the faces of the crystals parallel to molecular layers, but also the faces normal to the molecular layers.
light deflection by a Coulomb field, due to non-linear quantum electrodynamics effects

pedagogical discussion of the electrodynamical analog of the Aichelburg-Sexl ultraboost
Tan spot caused by the fungus Pyrenophora tritici-repentis is an important leaf spot disease in wheat growing areas throughout the world.

The study aims to identify wheat germplasm resistant to tan spot based on phytopathological screening and molecular marker analysis. A collection of 64 common wheat germplasms, including cultivars and breeding lines from Kazakhstan and CIMMYT, was assessed for tan spot resistance in greenhouse conditions and characterized using the Xfcp623 molecular marker, diagnostic for the Tsn1 gene.

All wheat cultivars/lines varied in their reaction to tan spot isolate race 1, ranging from susceptible to resistant. Most accessions studied (53 %) were susceptible to Ptr race 1. Spring wheat cultivars were more susceptible to race 1 than winter wheat cultivars. As a result of genotyping, an insensitive reaction to Ptr ToxA was predicted in 41 wheat cultivars (64 %). The tsn1 gene carriers identified included 27 Kazakhstani and 14 CIMMYT cultivars/lines, demonstrating insensitivity to Ptr ToxA. The majority of the Tsn1 genotype were sensitive to race 1 and showed susceptibility to the pathogen in the field. Disease scores from seedling stage positively correlated with field disease ratings. Of particular interest are 27 wheat accessions that demonstrated resistance to spore inoculation by Ptr race 1, were characterized by insensitivity to ToxA and showed field resistance to the pathogen. The results of this study will contribute to wheat breeding programs for tan spot resistance with Marker Assisted Selection using the closely flanking markers.
Levitating droplets of liquid condensate are known to organize themselves into ordered arrays over hot liquid-gas interfaces.

We report experimental observation of similar behaviour over a dry heated substrate in the vicinity of the triple-phase contact line with high local evaporation rate.

It was found that there is an area near the contact line, where no levitating droplets are observed. The width of this area increases with the substrate temperature. Also, it was found that the distance between adjacent levitating droplets increases with the temperature.
The methods of optical visualization of droplet dynamics are described. One of them for top view uses microscope system with CCD-camera and the second is a high-resolution shadow technique. Droplet evaporation dynamics are recorded and processed using special programs. Evolution of droplet base diameters and volumes are presented.
The three Drosophila EcR isoforms differ only at their N termini; thus, they share the conserved ligand-binding domain transcriptional activation function (AF2) and only differ in the unconserved A/B region, which contains a second, isoform-specific, activation function (AF1). We have developed a dominant-negative mutant EcR (EcR-DN), expressed it in flies with the GAL4/UAS system, and used it to block ecdysone signaling in eight tissues or groups of tissues. Localized EcR-DN arrests ecdysone-dependent development in the target cells and often--because of a molting checkpoint--arrests development globally. Simultaneously expressing individual wild-type EcR isoforms in the same target tissues suppresses the EcR-DN phenotype and identifies the rescuing isoform as sufficient to support the development of the target. Every isoform, and even an N-terminal truncated EcR that lacks any AF1, supports development in the fat body, eye discs, salivary glands, EH-secreting neurosecretory cells and in the dpp expression domain, implying that AF1 is dispensable in these tissues. By contrast, only EcR-A is able to support development in the margins of the wing discs, and only EcR-B2 can do so in the larval epidermis and the border cells of the developing egg chamber. In light of our results, the simplest explanations for the widespread spatial and temporal variations in EcR isoform titers appear untenable.
Cold and frost are two serious factors limiting the yield of many crops worldwide, including the tea plant (Camellia sinensis (L.) Kuntze). The acclimatization of tea plant from tropical to temperate climate regions resulted in unique germplasm in the North-Western Caucasus with extremely frost-tolerant genotypes.The aim of the current research was to evaluate the physiological, biochemical and genetic responses of tolerant and sensitive tea cultivars exposed to cold (0 to +2 °C for 7 days) and frost (-6 to -8 °C for 5 days). Relative water content, cell membranes integrity, pH of the cell sap, water soluble protein, cations, sugars, amino acids were measured under cold and frost. Comparative expression of the following genes ICE1, CBF1, WRKY2, DHN1, DHN2, DHN3, NAC17, NAC26, NAC30, SnRK1.1, SnRK1.2, SnRK1.3, bHLH7, bHLH43, P5CS, LOX1, LOX6, LOX7 were analyzed.We found elevated protein (by 3-4 times) and cations (potassium, calcium and magnesium) contents in the leaves of both cultivars under cold and frost treatments. Meanwhile, Leu, Met, Val, Thr, Ser were increased under cold and frost, however tolerant cv. Gruzinskii7 showed earlier accumulation of these amino acids. Out of 18 studied genes, 11 were expressed at greater level in the frost- tolerant cultivar comparing with frost-sensitive one: ICE1, CBF1, WRKY2, DHN2, NAC17, NAC26, SnRK1.1, SnRK1.3, bHLH43, P5CS and LOX6. Positive correlations between certain amino acids namely, Met, Thr, Leu and Ser and studied genes were found. Taken together, the revealed cold responses in Caucasian tea cultivars help better understanding of tea tolerance to low temperature stress and role of revealed metabolites need to be further evaluated in different tea genotypes.
The production of \chib1P mesons in $pp$ collisions at a centre-of-mass energy of $7\tev$ is studied using $32\invpb$ of data collected with the \lhcb detector.

The $\chib1P$ mesons are reconstructed in the decay mode $\chib1P \to \Y1S\g \to \mumu\g$. The fraction of \Y1S originating from \chib1P decays in the \Y1S transverse momentum range $6 < \pt^{\Y1S} < 15\gevc$ and rapidity range $2.0 < y^{\Y1S} < 4.5$ is measured

to be $(20.7\pm 5.7\pm 2.1^{+2.7}_{-5.4})%$, where the first uncertainty is statistical, the second is systematic and the last gives the range of the result due to the unknown \Y1S and \chib1P polarizations.
This paper aims at experimental study of gas-liquid flow in a horizontal rectangular hydrophilic microchannel with a cross-section of 200×400 μm.

The ethanol and nitrogen are used as working liquids and gas accordingly in the microchannel with crossflow T-mixer at the channel inlet. Experimental data are obtained using high-speed visualization, laser flow scanning, and LIF method.

The elongated bubble flow and transition flow are observed in the hydrophilic rectangular microchannel depending on gas and liquid flow rates. Using the LIF method, the non-uniform liquid film distribution is observed in the channel cross-section. The liquid film thickness is measured for elongated bubble flow and transition flow and compared with the Taylor law.
A new beam multilayer finite element for solving the bending problems of laminated composites is proposed. The finite element model is based on the asymptotic splitting method, which allows one to obtain a solution to the linear spatial problem of the theory of elasticity without using simplifying hypotheses. The advantage of this approach is that all components of the stress tensor are taken into account and that the stress states of composite beams of a complex cross-section are examined in detail without using the plane strain or plane stress states.
We construct in an explicit algebraic form a family of complete noncompact Ricci-flat metrics which generalize Calabi metrics in real dimension $4(n+1)$ and with holonomy $SU(2(n+1))$.
The aim of this study was to investigate miRNA profiles of clarified urine supernatant and combined urine vesicle fractions of healthy donors and patients with benign prostatic hyperplasia and prostate cancer (PCa).

The comparative analysis of miRNA expression was conducted with a custom miRCURY LNA miRNA qPCR panel. Significant combinations of miRNA pairs were selected by the RandomForest-based feature selection algorithm Boruta; the difference of the medians between the groups and a 95% confidence interval was built using the bootstrap approach. The Asymptotic Wilcoxon-Mann-Whitney Test was performed for miRNA combinations to compare different groups of donors. Benjamini-Hochberg correction was used to adjust the statistical significance for multiple comparisons.

The most diagnostically significant miRNAs pairs were miR-107-miR-26b.5p and miR-375.3p-miR-26b.5p in the urine supernatant fraction that discriminated the group of healthy patients and PCa patients, as well as miR-31.5p-miR-16.5p, miR-31.5p-miR-200b, miR-31.5p-miR-30e.3p and miR-31.5p-miR-660.5p in the fraction extracellular vesicles that were different between healthy men and benign prostate hyperplasia patients. Such statistical criteria as the occurrence of individual significant miRNA pairs in the total number of comparisons, median ΔCt difference, and confidence interval can be useful tools for determining reliable markers of PCa.
A sequence of [Formula: see text]-polynomials [Formula: see text] of virtual knots [Formula: see text] was defined by Kaur et al. in 2018. These polynomials have been expressed in terms of index value of crossing and [Formula: see text]-writhe of [Formula: see text]. By the construction, [Formula: see text]-polynomials are generalizations of Kauffman's Affine Index Polynomial, and are invariants of virtual knot [Formula: see text].

We present values of [Formula: see text]-polynomials of oriented virtual knots having at most four classical crossings in a diagram.