Both were major public commissions: the "Rucellai Madonna" (Galleria degli Uffizi), commissioned in April 1285 by the Compagnia del Laudesi di Maria Vergine for a chapel in the church of Santa Maria Novella in Florence, and the Maestà commissioned for the high altar of Siena Cathedral in 1308 and completed by June 1311.
Čeprav je bil Duccio aktiven od leta 1268 do okoli 1311, je le približno 13 njegovih del ohranjeno do danes.