Reference number : GC-2017-Q1-03291, amendment number : , agreement type : G, recipient legal name : Sargent, Edward (University of Toronto), recipient country : CA, recipient province : nan, recipient city : Ontario, recipient postal code : nan, program name english : Discovery Grants Program - Individual, program name french : Programme de subventions à la découverte - individuelles, program purpose english : This research program seeks to advance the electricity-driven conversion of CO 2 into carbon-based fuels and feedstocks. We will develop systems that renewably synthesize chemicals, such as ethylene - processes that today rely on fossil fuel sources. We will develop physical models that enhance our understanding of these processes, contributing thereby to enabling rational design of new materials for the synthesis of complex target products. The technology developed by this program will help to enable the transformation of CO 2 into a renewable source of valuable chemicals. 
 
Overall, the global goal of reduction net CO 2 emissions requires a combination approach: improved conservation, energy efficiency, and new technologies that not only curtail the current rate of carbon dioxide emissions, but that have the potential for net-negative emission processes. Our work seeks to contribute to the conversion of CO2 to valuable products using renewable electricity. This can offer a carbon-negative method of synthesizing products that today are conventionally derived from fossil fuels. 
 
A CO 2 conversion system includes an anode, a cathode, and an electrolyte solution containing CO 2 . The anodic reaction forms O 2 from water and provides electrons and protons for the cathodic reaction; this is known as the oxygen evolution reaction (OER). At the cathode, CO 2 is converted to the target product in the CO 2 reduction reaction (CO 2 RR). Our program will focus on the design, synthesis, and understanding of new materials and systems for both OER and CO 2 RR. We take a multidisciplinary approach combining computational modeling with experimental synthesis and characterization to develop detailed models of both OER and CO 2 RR materials for energy storage. 
 
By enabling the synthesis of carbon based fuels using renewable electricity, our work addresses the problem of seasonal energy storage faced by intermittent electricity sources such as solar and wind. Generation of renewable, carbon-based feedstocks for manufacturing will help accelerate our transition to a sustainable economy., program purpose french : This research program seeks to advance the electricity-driven conversion of CO 2 into carbon-based fuels and feedstocks. We will develop systems that renewably synthesize chemicals, such as ethylene - processes that today rely on fossil fuel sources. We will develop physical models that enhance our understanding of these processes, contributing thereby to enabling rational design of new materials for the synthesis of complex target products. The technology developed by this program will help to enable the transformation of CO 2 into a renewable source of valuable chemicals. 
 
Overall, the global goal of reduction net CO 2 emissions requires a combination approach: improved conservation, energy efficiency, and new technologies that not only curtail the current rate of carbon dioxide emissions, but that have the potential for net-negative emission processes. Our work seeks to contribute to the conversion of CO2 to valuable products using renewable electricity. This can offer a carbon-negative method of synthesizing products that today are conventionally derived from fossil fuels. 
 
A CO 2 conversion system includes an anode, a cathode, and an electrolyte solution containing CO 2 . The anodic reaction forms O 2 from water and provides electrons and protons for the cathodic reaction; this is known as the oxygen evolution reaction (OER). At the cathode, CO 2 is converted to the target product in the CO 2 reduction reaction (CO 2 RR). Our program will focus on the design, synthesis, and understanding of new materials and systems for both OER and CO 2 RR. We take a multidisciplinary approach combining computational modeling with experimental synthesis and characterization to develop detailed models of both OER and CO 2 RR materials for energy storage. 
 
By enabling the synthesis of carbon based fuels using renewable electricity, our work addresses the problem of seasonal energy storage faced by intermittent electricity sources such as solar and wind. Generation of renewable, carbon-based feedstocks for manufacturing will help accelerate our transition to a sustainable economy., agreement title english : Renewable carbon-based fuels and feedstocks from solar electricity + CO2, agreement title french : Renewable carbon-based fuels and feedstocks from solar electricity + CO2, agreement number : RGPIN, agreement value : 350000.0, agreement start date : 2017-05-10, agreement end date : nan, description english : nan, description french : nan, expected results english : nan, expected results french : nan, additional information english : Grant or Award spanning more than one fiscal year. (2017-2018 to 2022-2023), additional information french : Subvention ou bourse octroyée s'appliquant à plus d'un exercice financier. (2017-2018 à 2022-2023), owner organization : nserc-crsng, owner organization title : Natural Sciences and Engineering Research Council of Canada | Conseil de recherches en sciences naturelles et en génie du Canada