Dragon09/odtu_chatbot huggingface dataset:
hybrid coordination aggregates mofs for carbon dioxide adsorption

existing co2 capture technologies such as aminebased absorption and cryogenic distillation face challenges and problems including high energy requirements large infrastructure needs and high costs these technologies often require significant retrofitting or integration into existing industrial processes limiting their scalability and commercial viability in contrast the utilization of mofs metalorganic frameworks for co2 capture has garnered significant interest due to the numerous advantages they offer compared to other materials such as high adsorption capacity selectivity tunability regenerability and potential for direct utilization making mofs a promising solution for efficient and effective co2 capture however it is challenging to design mof materials with extremely high co2 capture capacity gas selectivity and water stability along with moderate regeneration energy as water dissociation causes hydroxylpoisoning that impairs co2 sorption by both high temperature and moisture exposure additionally the high energy consumption during blowdown and evacuation steps for the process cycle of mofs need to be improved to ensure longterm performance the novelty of this work lies in its ability to strengthen the interaction between co2 molecules and the mof structure through an innovative dual activation method utilizing both n and s atoms this approach surpasses conventional singleatom activation in mofs resulting in enhanced binding furthermore the incorporation of lewis base sites lbss has become increasingly popular for reducing the energy needed for mof regeneration consequently improving co2 binding affinity selectivity and reversibility advanced thermal modeling will be employed to analyze the dynamic processes of co2 adsorptiondesorption sweep gas and dryout sequences this modeling considers both the mechanical and chemical properties of the synthesized mof
the micrornam6a epitranscriptome integrative analysis of its role in normal brain behaviour and the development of epilepsy

evidence is emerging that persistent changes in gene expression regulation and posttranscriptional regulation underlies the epileptogenic process the current proposal builds on preliminary data which suggests that micrornas mirna which have recently emerged as critical regulators of epileptogenesis may be subjected to adenosine methylation m6a and that this process may also be disrupted in epilepsy representing an unexplored layer of gene expression regulation likely to influence neuronal activity and seizures the current proposal will evaluate the effect of m6a on mirna function to understand how this influences normal brain behaviour and epileptogenesis to achieve this a combined strategy will be used including interdisciplinary approaches international and national secondments university of aarhus and rsci and intersectoral collaborations which encompasses clinicians beaumont hospital and industry storm therapeutics first hippocampal m6atagged mirnas both during epileptogenesis and in chronic epilepsy will be profiled using an adapted m6aseq approach using an epilepsy mouse model and resected human epilepsy brain tissue then the effect of m6a on mirna function and neuronal integrity will be evaluated by targeting mirna methylation in both mouse and human cell lines next clinical outcomes of pharmacological targeting of mirna methylation on epilepsy development will be evaluated using an epilepsy mouse model together this proposal represents the first mirna methylation study in the brain which is hoped will illuminate novel therapeutic strategies for the treatment of epilepsy this project is ideal to further my interest in translational neuroscience while also developing a network of collaborators across europe and develop my scientific skills this fellowship represents the best option to achieve my career goal of establishing myself as an independent researcher and consolidating my career in the european research environment
growing online how to protect our children in the digital world

digital technologies have become an important part of childrens daily lives regardless of cultural and geographical context this is often due to the actions of parents who notoriously share information about their children on the internet social media can today be considered a modern baby album where by sharing photos of their children parents present themselves as good parents giving birth to adorable babies with a sense of humor and evidence of milestones achieved all indicators family health and happiness very often children are not aware that thanks to their parents they have become celebrities on social media this parental behavior known as sharenting is becoming more and more common around the world putting children at risk loss of privacy children do not have a say in what information is shared about them online this digital footprint can be difficult to control later in life identity theft personal information can be used for identity theft impacting childrens security exploitation images and information can be used for commercial purposes cyberbullying and harassmentthe main goal of guardian is to investigate the extent and dimensions of sharenting in europe and east africa from intercultural perspectives in order to provide guidance and recommendations on the measures required to respect and protect childrens rights in the digital world the project will promote the rights of the child and raise awareness of the society about risks and challenges experienced by children in the digital environment and help them to navigate the online world responsiblythe project will be implemented by academic institutions from 4 countries poland czechia united kingdom and kenya the transfer of knowledge and common reaserch will contribute not only to the achievement of the project goal but also to the realisation of the potential of participants allowing them to acquire new skills and professional qualifications
a critical relational perspective on peace security in cee

this project establishes tallinn university tlu as a leading institutional and knowledge hub on security in the cee region in close collaboration with the tampere university tau and the university of copenhagen ucph russias war against ukraine has demonstrated incontrovertibly that regional expertise in security and the politics of it is essential to tackle the present as well as future security related issues it has also demonstrated that security needs to be approached with a deeply holistic intersectional and relational lens to truly provide perspectives and connections between different security contexts and matters that can lead to more peaceful just and sustainable futures the cee security hub will bring together diverse knowledge on security academia policymaking and civil society and create different forums to advance expertise on security from research seminars workshops conferences to various knowledge exchange schemes that enhance intellectual and institutional capacities of the hub and in parallel establish tlu as a valued and in demand security hub for diverse local and international audiences
ottoman sea borders fortresses and geopolitical considerations in the eastern mediterranean 16991832

seabord will explore the frontier fortresses of eastern mediterranean in a comparative perspective in order to assign their role in defence socioeconomic development and geopolitical considerations during the ottoman rule this research will focus on fortresstowns of peloponnese cyprus and crete considering their similar historical trajectory in establishing ottoman sea borders in the eastern mediterranean this project will be based on a research conducted and collected qualitative data in various archives in istanbul athens london vienna and nantes and on other primary sources and onsite fieldwork facilitated by advanced digital tools and methods combining use of unpublished archival material with development of new digital reproductions 3d images gis based maps this research offers an innovative approach to share and engage with cultural heritage in europe main outcomes of this project will be a monograph conference papers will be published in edited collective volumes or as journal articles and a digital museum which will contribute to disseminate the project results in a wider audience during two years period of the msca european fellowship ep the researcher will base her research and training activities at science and technology in archaeology and culture research center starc at the cyprus institute cyl as part of her fellowship she intends to complete a 3month secondment at the department of history and archaeology at the university of crete to enhance her training and expand her research overall this project aims address a significant societal challenge primarily resulting from derision of systematic research on such monuments during the ottoman rule in greece and elsewhere in europe in general thus dissemination communication and outreach activities are designed fulfilling this aim promoting research on fortresses and castles and other examples of built military heritage of the ottoman past in europe
resilient and environmentally sustainable engineered crops to address climate change

current global warming caused by anthropogenic emissions of greenhouse gases in particular co2 is expected to rise from 25c to 4c by the end of the century consequently agriculture is faced with the urging needs of increasing co2 sequestration coping with adverse weather and disastrous events ie droughts heat waves fire and flooding and feeding an evergrowing world population projected at 97 billion in 2050 future crops must serve as more efficient carbon sinks to mitigate climate change plus have higher resilience and productivity to feed the global population crop4clima will develop firstofakind canola and rapeseed lines able to assimilate 60 more co2 through photorespiration requiring 20 less amount of water improving biomassha and still maintaining high oil content values as required for canola derived products no commercial crops of that kind exist to reach such product we will improve and bring to commercial use a disruptive synthetic metabolic pathway the taco pathway which turns photorespiration into a co2fixing instead of a co2releasing process leading to increased net carbonuptake under agronomical standard and drought field conditions canola and rapeseed are major crops in eu and worldwide notably our technology has commercial prospects to be introduced in other c3 crops such as soybean cotton rice and more based on photosynthetic and genomic similarity the success of the technology implementation in rapeseed will allow us to establish a startup seed company aiming to produce and sell high oil seeds with low carbon footprint in addition and in frame of the program we will develop an innovative business plan taking into considerations how the food value chain is evolving to cope with food supply and climate change signing a precommercial agreement with our industrial partners for the development of our engineered crops up to trl9 and build trust on the solution proposed
therapeutic artificial cells based on molecular cages for glioblastoma treatment

cancer is still a major societal challenge as reflected by the horizons europe mission on cancer and the europes beating cancer plan in particular despite great advances in cancer treatment in recent decades glioblastoma multiform gbm the most common malignant brain tumor stills remains without an effective cure and patients die in a few months around 220000 people die annually worldwide from gbm and its incidence is expected to increase in europe due to its aging population the standard treatment relies on the systemic administration of chemotherapeutics which has limited efficacy and causes side effects to overcome current limitations theraccage will develop artificial cells based on drugloaded molecular cages as advanced nanosystems to tackle gbm such artificial cells will be equipped with processing machinery resulting in advanced biocompatible nanosystems with the ability to recognize biomarkers of the gbm microenvironment and induce responsive drug delivery in situ the project combines unique expertise of the main host lab molecular cages cagelike molecular architectures with an internal cavity the candidate nanotechnology and artificial cells and a secondary lab evaluation of novel anticancer therapies to ensure fulfillment of objectives in a first stage the fellow will be trained in advanced organic chemistry for the synthesis of degradable drugloaded molecular cages in a second stage the assembly of artificial cells with molecular cages and their in vitro evaluation will be carried out finally the fellow will carry out a secondment in a biological lab for the preclinical evaluation of the developed nanosystems importantly the project will also allow the fellow to gain experience in patenting and tech transfer altogether theaccage will develop a new therapeutic technology and provide the fellow with complementary scientific and transferable skills with a significant impact toward an independent research career
development of a new generation detailed hydrogen combustion mechanism

the most promising carbonless fuels are hydrogen and h2nh3 mixtures burners reciprocating engines and gas turbines using these fuels can be designed by computational fluid dynamics cfd tools provided that an accurate chemical submodel detailed reaction mechanism is available a comprehensive collection of hydrogen combustion experimental data was created 10 years ago by the hosting laboratory and published on the respecthhu website the initial aim of the project is to extend this data collection with all newly published experimental data also further types of laboratory measurement results like extinction limits will be added to the database then a new base chemical kinetics mechanism for hydrogen combustion is set up that uses the latest directly measured and theoretically calculated rate coefficients of the ho system and also takes into account the newly proposed mechanistic approaches like new thirdbody efficiency parameters and a nonlinear mixing model for these parameters new diffusion parameters and reactive termolecular reactions the base model will be optimized using the updated data collection the base model the optimized model and all recently published hydrogen combustion mechanisms will be tested together using the whole data collection it is expected that the obtained new generation detailed hydrogen combustion mechanism will provide more accurate simulation results compared to the currently available ones especially under problematic conditions like high pressure lean combustion and high water vapour concentration in the initial mixture this mechanism will be an important ingredient of the cfd design of devices using hydrogen and h2nh3 and h2natural gas fuel mixtures
breakthroughs in thermal batteries through zeroemission hightemperature static thermaltoelectric converters

blazetec aims to pioneer ultrahightemperature thermal batteries operating from 1200 to 1600 c offering groundbreaking and efficient solutions for longduration energy storage and conversion it focuses the efforts on two pivotal pilot demonstrations an electric thermal battery capable of converting surplus electricity into heat and then back into electricity alongside a solar thermal battery designed to store concentrated sunlight and provide electric power ondemand both of these systems integrate cuttingedge solidstate energy converters including thermionics tig thermoelectrics teg and thermophotovoltaics tpv standard thermal engines cannot support such high operating temperatures therefore solidstate converters are now essential for effectively integrating efficient thermal batteries in renewable energy sources blazetec advances standalone tig teg and tpv technologies by introducing innovations with higher conversion efficiency with respect to the stateoftheart like vacuum microgap tig multimodule teg and multijunction tpv systems through hybridization of these solutions the project introduces titeg tigteg hybrid and tipv tigtpv hybrid with a targeted efficiency of over 30 and a power density higher than 5 wcm all backed by more than 500 hours of reliability the integration of these technologies is facilitated by innovative vacuum encapsulation and the dispatchable power wall concept which enables ondemand power generation by efficiently routing heat through the converters the projects outcomes result in the development of five advanced energy conversion devices an inventive system for dispatchable electricity generation and the successful pilot testing of two kinds of thermal batteries exploiting latent heat and sensible heat ultimately achieving trl 5
transforming interface studies for sustainable desalination the development of interfacespecific heterodynedetected 4 spectroscopy for the study of molybdenum disulfide nanochannels

the world faces an escalating water crisis with over two billion people lacking access to clean drinking water which is further exacerbated by increased droughts due to global warming traditional desalination methods are notorious for their inefficiency and excessive energy consumption which creates an urgent demand for sustainable alternatives interfacial solar vapor generation svg serves as a promising solution to this problem molybdenum disulfide mos2 nanochannels are able to efficiently harness solar energy and have been identified as a transformative material for desalination in the svg process despite this the molecularlevel mechanisms enhancing their svg particularly their interaction with water remain unclear necessitating the need for precise spectroscopic techniques to investigate their interfacial mechanisms secondorder nonlinear susceptibility 2 sum frequency generation sfg spectroscopy emerges as an exceptional tool for unraveling the intricate details of molecular interactions at interfaces while 2 sfg has proven invaluable in deciphering interfacial molecular interactions it has limitations when probing interfaces hidden beneath thick infrared absorbers like water to overcome this obstacle we turn to interfacespecific heterodyne detected hd fourthorder nonlinear susceptibility 4 spectroscopy which employs nearinfrared nir light instead of ir this makes it suitable for interfaces buried within thick ir absorbers that are transparent in the nir region herein i present a cuttingedge proposal for the development of a new and innovative hd4 spectroscopic technique to study mos2 nanochannels used for svg hd4 spectroscopy can not only aid in desalination optimization but also expand into challenging areas like the battery and electrochemical industries this ambitious project aims to enhance our interfacial understanding facilitating sustainable solutions amid water scarcity
bridging models at different scales to design new generation fuel cells for electrified mobility

to achieve the goals of the european green deal on climate neutrality a 90 reduction in transport emissions is needed by 2050 the automotive industry urgently needs to accelerate the introduction of alternative powertrains for electrified vehicles hydrogenpowered proton exchange membrane fuel cells pemfcs are carbonfree power devices that meet these goals in both mobile and stationary applications blessed aims at revolutionising the design process of next generation pemfcs to improve efficiency durability and affordability for widespread use with direct implications in clean energy and sustainable industrymobility blessed will train 15 doctoral candidates dcs to solve multiscale ms engineering challenges from the electrons up to the device level through a unique combination of multidisciplinary computational methods with machine learning ml to bridge each length scales highly accurate model to adjacent scales then a topdown length scale approach will be followed to optimise pemfc and its components to this end the 15 dcs will synergistically develop a unique ms computational framework for the allscale pemfc analysisdesign assisted by ml tools this will allow the simultaneous consideration of complex physicochemical phenomena occurring at all length scales such as catalyticallyassisted chemical reactions contact of rough surfaces mechanicalchemical degradation of membranes fluid flows in porous media etc at affordable computational cost the proposed idnetwork brings together worldclass academic expertise on numerical modelling and simulation in electrochemistry reacting flows fluid mechanics materials optimisation methods and ml with industrial developers with a strong focus on industrial applications blessed will develop methodologies and tools to exceed stateoftheart in pemfcs by minimising the platinum group metal content and corrosion while maximising mass transport and electrical conductivity
digital ecocriticism moving beyond anthropocentrism in the contemporary french novel

the digeco project will construct enrich and analyze a corpus of 700 francophone novels from 2000 to the present day using tools and methods developed in the digital humanities this innovative approach will provide new insights into the influence of ecological discourse on contemporary fiction although recent studies argue that the environmental question is changing the novel beyond the thematic focus on ecology to date no formal investigations have been conducted on such large corporadigeco will thus propose new critical perspectives on the capacity of literature to bring anthropocentrism into question in order to achieve this objective the project will be organized around three research axes biodiversity places and nonhuman agency these three elements are all bound to a shift in the traditional mimetic paradigm of the contemporary novel diverting attention from a previouslydominant focus on human actionsfor each of these research axes i will enrich the digitized corpus using namedentity recognition technologies and semantic ontologies in order to encode a lexicon in biodiversity and identify toponymies and names of animals and plants then using various computational approaches i will leverage semantic lexicometric and stylometric approaches to answer research questions elaborated through an ecocritical methodology using sentiment analysis i will also study the emotions that characters express about concepts places animals and plantsthis project bridges two emerging fields in literary research environmental humanities and digital humanities and will constitute the first major study on the possibilities of dialogue between them it will provide the largest set of data on biodiversity toponyms and nonhuman agency in fiction in any language an unprecedented opportunity to question literatures relationship to anthropocentrism and to look at the contemporary novel through the prism of new tools and interrogations