Projet D-Carbonize (Horizon Europe, appel à projets 2021)
Action : Doctoral Networks - Joint Doctorates
Panel : Chemistry
Statut du projet : SIGNED

D-Carbonize´s approach targets biocarbon recycling into valuable starting materials for the chemical/polymer industries and will primarily provide innovative low-carb catalysis solutions. The use of biocarbon is advantageous in many respects as it is renewable, generally abundant and non-toxic, and it represents easy-to-handle carbon reagents even on larger scale. Despite the lack of universal (catalytic) strategies available for biocarbon valorization into monomers and polymers, recent advances in catalysis science have demonstrated the engineering and use of new promising metal- and organo-catalysts with high potential to overcome these limitations, thereby creating the necessary feasibility to transform biocarbon into (1) fine chemicals such as carbonates, carbamates, carboxylic acids, and esters, (2) pharmaceutical synthons, and (3) biomass/CO2-based polymers. Thus, catalysis has already been shown to be a useful technology for biocarbon valorization but has been rarely used in the wider context of new and functional biocarbon based monomer/polymer development. The use of the latter helps to shape the future of functionalized poly-esters/carbonates/amides and their subsequent utilization in novel tailor-made and commercially relevant materials. Furthermore, this project will also explore depolymerization pathways to recycle the synthesized polymers obtaining new monomers and/or other added-value molecules that could re-enter the loop and be used in new polymers and materials. The network will recruit 12 doctoral candidates, who will be awarded double doctoral degrees by two universities in two different countries at the end of the training program. D-Carbonize brings together leading high-education institutions, research centers and companies to form an innovation community able to offer excellent research and training both in R&D and entrepreneurship.

Mots clés : homogeneous catalysis, heterogeneous catalysis, organocatalysis, co2 based monomers, bio based monomers, polymers, coatings, adhesives, packaging materials, sustainability

Participants :
- Université de Rennes (France) — Partner, associated partner, Enseignement supérieur ou secondaire, subvention : 0.0 €
- Celabor (Belgique) — Partner, associated partner, Organismes privés (hors enseignement), subvention : 0.0 €
- Université de Heidelberg (Allemagne) — Partner, beneficiary, Enseignement supérieur ou secondaire, subvention : 521078.4 €
- Université du Pays basque (Espagne) — Partner, associated partner, Enseignement supérieur ou secondaire, subvention : 0.0 €
- Total (Belgium) (Belgique) — Partner, associated partner, Organismes privés (hors enseignement), subvention : 0.0 €
- Centre national de la recherche scientifique (France) — Partner, beneficiary, Recherche, subvention : 565387.2 €
- BASF (Germany) (Allemagne) — Partner, associated partner, Organismes privés (hors enseignement), subvention : 0.0 €
- Université de Liège (Belgique) — Partner, beneficiary, Enseignement supérieur ou secondaire, subvention : 525240.0 €
- Université Rovira i Virgili (Espagne) — Partner, associated partner, Enseignement supérieur ou secondaire, subvention : 0.0 €
- Corning sas (France) — Partner, associated partner, Organismes privés (hors enseignement), subvention : 0.0 €
- Co2 value europe aisbl (Belgique) — Partner, associated partner, Autres, subvention : 0.0 €
- Institute of Chemical Research of Catalonia (Espagne) — Coordinator, beneficiary, Recherche, subvention : 723017.36 €
- Université de Groningue (Pays-Bas) — Partner, beneficiary, Enseignement supérieur ou secondaire, subvention : 679859.14 €
- Polykey polymers sl (Espagne) — Partner, beneficiary, Organismes privés (hors enseignement), subvention : 104988.0 €