Air stable ligandless heterogeneous catalyst systems based on Pd and Au supported in SiO2 and MCM-41 for Suzuki–Miyaura cross-coupling in aqueous medium
Journal: Applied Catalysis A General
Year: 2013

Palladium and palladium-gold containing siliceous-MCM-41 and sol–gel palladium and palladium-gold silica composites have been prepared. The catalytic performance of incorporated Pd/MCM-41, Au-Pd/MCM-41 and Pd and Au-Pd/SiO2 sol–gel catalysts for the Suzuki–Miyaura cross-coupling reaction was determined and the influence of the matrix and the catalyst composition on the catalytic activity were also studied. The catalysts were characterized by N2 physisorption (BET/BJH methods), X-ray diffraction,