Miscibility - wikipedia Miscibility This article needs additional citations for verification. Please help improve this article by adding citations to reliable sources. Unsourced material may be challenged and removed. ( May 2013 ) Diesel fuel is immiscible in water. The bright rainbow pattern is the result of thin film interference. Miscibility / mɪsɪˈbɪlɪti / is the property of substances to mix in all proportions ( that is, to fully dissolve in each other at any concentration ), forming a homogeneous solution. The term is most often applied to liquids, but applies also to solids and gases. Water and ethanol, for example, are miscible because they mix in all proportions. By contrast, substances are said to be immiscible if a significant proportion does not form a solution. Otherwise, the substances are considered miscible. For example, butanone is significantly soluble in water, but these two solvents are not miscible because they are not soluble in all proportions. Contents 1 Organic compounds 2 Metals 3 Effect of entropy 4 Determination 5 See also 6 References Organic compounds In organic compounds, the weight percent of hydrocarbon chain often determines the compound 's miscibility with water. For example, among the alcohols, ethanol has two carbon atoms and is miscible with water, whereas 1 - octanol with eight carbons is not. Octanol 's immiscibility leads it to be used as a standard for partition equilibria. This is also the case with lipids ; the very long carbon chains of lipids cause them almost always to be immiscible with water. Analogous situations occur for other functional groups. Acetic acid ( CH COOH ) is miscible with water, whereas valeric acid ( C H COOH ) is not. Simple aldehydes and ketones tend to be miscible with water, because a hydrogen bond can form between the hydrogen atom of a water molecule and the unbonded ( lone ) pair of electrons on the carbonyl oxygen atom. Metals Immiscible metals are unable to form alloys with each other. Typically, a mixture will be possible in the molten state, but upon freezing the metals separate into layers. This property allows solid precipitates to be formed by rapidly freezing a molten mixture of immiscible metals. One example of immiscibility in metals is copper and cobalt, where rapid freezing to form solid precipitates has been used to create granular GMR materials. There also exist metals that are immiscible in the liquid state. One with industrial importance is that liquid zinc and liquid silver are immiscible in liquid lead, while silver is miscible in zinc. This leads to the Parkes process, an example of liquid - liquid extraction, whereby lead containing any amount of silver is melted with zinc. The silver migrates to the zinc, which is skimmed off the top of the two - phase liquid, and the zinc is boiled away, leaving nearly pure silver. Effect of entropy Substances with extremely low configurational entropy, especially polymers, are likely to be immiscible in one another even in the liquid state. Determination Miscibility of two materials is often determined optically. When the two miscible liquids are combined, the resulting liquid is clear. If the mixture is cloudy the two materials are immiscible. Care must be taken with this determination. If the indices of refraction of the two materials are similar, an immiscible mixture may be clear and give an incorrect determination that the two liquids are miscible. See also Miscibility gap Emulsion Heteroazeotrope ITIES Multiphasic liquid References Wikimedia Commons has media related to Immiscible liquids. Jump up ^ Wade, Leroy G. Organic Chemistry. Pearson Education. p. 412. ISBN 0 - 13 - 033832 - X. GND : 4351500 - 9 Retrieved from `` https://en.wikipedia.org/w/index.php?title=Miscibility&oldid=789418955 '' Categories : Chemical properties Hidden categories : Articles needing additional references from May 2013 All articles needing additional references Wikipedia articles with GND identifiers Talk Contents About Wikipedia Català Deutsch Ελληνικά Español فارسی Français 한국어 Ido Kreyòl ayisyen Nederlands Polski Português Română ไทย Українська Tiếng Việt 中文 Edit links This page was last edited on 7 July 2017, at 06 : 14. Text is available under the Creative Commons Attribution - ShareAlike License ; additional terms may apply. By using this site, you agree to the Terms of Use and Privacy Policy. Wikipedia ® is a registered trademark of the Wikimedia Foundation, Inc., a non-profit organization. About Wikipedia

Question: when do we say that liquids are miscible
Answer: fully dissolve in each other at any concentration