Deoxidization - wikipedia Deoxidization Deoxidization is a method used in metallurgy to remove the oxygen content during steel manufacturing. In contrast, antioxidants are used for stabilization, such as in the storage of food. Deoxidation is important in the steelmaking process as oxygen is often detrimental to the quality of steel produced. Deoxidization is mainly achieved by adding a separate chemical species to neutralize the effects of oxygen or by directly removing the oxygen. Contents 1 Oxidation 2 Types of deoxidizers 2.1 Metallic deoxidizers 2.2 Vacuum deoxidation 2.3 Diffusion deoxidation 3 References 4 See also Oxidation Oxidation is the process of an element losing electrons. For example, iron will transfer two of its electrons to oxygen, forming an oxide. This occurs all throughout as an unintended part of the steelmaking process. Oxygen blowing is a method of steelmaking where oxygen is blown through pig iron to lower the carbon content. Oxygen forms oxides with the unwanted elements, such as carbon, silicon, phosphorus, and manganese, which appear from various states of the manufacturing process. These oxides will float to the top of the steel pool and remove themselves from the pig iron. However, some of the oxygen will also react with the iron itself. Due to the high temperatures involved in smelting itself, oxygen in the air may dissolve into the molten iron while it is being poured. Slag, a byproduct left over after the smelting process, is used to further absorb impurities such as sulfur or oxides and protect steel from further oxidation. However, it can still be responsible for some oxidation. Some processes, while still able to lead to oxidation, are not relevant to the oxygen content of steel during its manufacture. For example, rust is a red iron oxide that forms when the iron in steel reacts with the oxygen or water in the air. This usually only occurs once the steel has been in use for varying degrees of time. Some physical components of the steelmaking process itself, such as the electric arc furnace, may also wear down and oxidize. This issue is typically dealt with by the use of refractory metals, which are resistant to change. If steel is not properly deoxidized, it will have reduced various properties such as tensile strength, ductility, toughness, weldability, polishability, and machinability. This is due to forming non-metallic inclusions and gas pores, bubbles of gas that get trapped during the solidification process of steel. Types of deoxidizers Metallic deoxidizers This method of deoxidization involves adding specific metals into the steel. These metals will react with the unwanted oxygen, forming a strong oxide that, compared to pure oxygen, will reduce the steel 's strength and qualities by a lesser amount. The chemical equation for deoxidization is represented by : n D + m O ⟶ D n O m ( displaystyle nD + mO longrightarrow D_ ( n ) O_ ( m ) ) where n and m are coefficients, D is the deoxidizing agent, and O is oxygen. Thus, the chemical equilibrium equation involved is : K e q = a o x / ( a D n ∗ a O m ) ( displaystyle K_ ( eq ) = a_ ( ox ) / ( a_ ( D ) ^ ( n ) * a_ ( O ) ^ ( m ) ) ) where a is the activity, or concentration, of the oxide in the steel, a is the activity of the deoxidizing agent, and a is the activity of the oxygen. An increase in the equilibrium constant K will cause an increase in a, and thus more of the oxide product. K can be manipulated by the steel temperature via the following equation : l o g K e q = A D / T − B D ( displaystyle logK_ ( eq ) = A_ ( D ) / T - B_ ( D ) ) where A and B are parameters specific to different deoxidizers and T is the temperature in K °. Below are the values for certain deoxidizers at a temperature of 1873 K °. Deoxidizer Manganese 12,440 5.33 1.318 Silicon 30,000 11.5 4.518 Aluminum 62,780 20.5 13.018 Below is a list of commonly used metallic deoxidizers : Ferrosilicon, ferromanganese, calcium silicide - used in steelmaking in production of carbon steels, stainless steels, and other ferrous alloys Manganese - used in steelmaking Silicon carbide, calcium carbide - used as ladle deoxidizer in steel production Aluminum dross - used to deoxidize slag in secondary steelmaking Calcium - used as a deoxidizer, desulfurizer, or decarbonizer for ferrous and nonferrous alloys Titanium - used as a deoxidizer for steels Phosphorus, copper ( I ) phosphide - used in production of oxygen - free copper Calcium hexaboride - used in production of oxygen - free copper, yields higher conductivity copper than phosphorus - deoxidized Yttrium - used to deoxidize vanadium and other non-ferrous metals Zirconium Magnesium Carbon Tungsten Vacuum deoxidation Vacuum deoxidation is a method which involves using a vacuum to remove impurities. A portion of the carbon and oxygen in steel will react, forming carbon monoxide. CO gas will float up to the top of the liquid steel and be removed by a vacuum system. As the chemical reaction involved in vacuum deoxidation is : C + O ⟶ C O ( displaystyle C + O longrightarrow CO ) the reaction between carbon and oxygen is represented by the following chemical equilibrium equation : K C O = P C O / ( a C ∗ a O ) ( displaystyle K_ ( CO ) = P_ ( CO ) / ( a_ ( C ) * a_ ( O ) ) ) where P is the partial pressure of the carbon monoxide formed. Decreasing the oxygen activity ( a ) will result in a higher equilibrium constant, thus more product, CO. To achieve this, subjecting the pool of steel to vacuum treatment decreases the value of P, allowing for more CO gas to be produced. Diffusion deoxidation This method relies on the idea that deoxidation of slag will lead to the deoxidation of steel. The chemical equilibrium equation used for this process is : K F e O = a ( O ) / a ( O ) ( displaystyle K_ ( FeO ) = a_ ( ( O ) ) / a_ ( ( O ) ) ) where a is the activity of the oxygen in the slag, and a is the activity of oxygen in the steel. Reducing the activity in the slag ( a ) will lower the oxygen levels in the slag. Afterwards, oxygen will diffuse from the steel into the lesser concentrated slag. This method is done by using deoxidizing agents on the slag, such as coke or silicon. As these agents do not come into direct contact with the steel, non-metallic inclusions will not form in the steel itself. References ^ Jump up to : Kopeliovich, Dmitri. `` Deoxidation of steel ''. Subtech. Retrieved 23 October 2014. Jump up ^ Kopeliovich, Dmitri. `` Non-metallic inclusions ''. Subtech. Retrieved 24 October 2014. Jump up ^ `` Steel Deoxidation : Part One ''. Total Materia. Jump up ^ `` Inclusion Formation and Removal ''. neom.mems.cmu.edu. Carnegie Mellon University. Retrieved 26 October 2014. See also Desulfurization is the process of decreasing the sulfur content of steel. Decarburization is the process of decreasing the carbon content in metallurgy. Deoxidized steels are steels categorized by level of deoxidization treatment. Retrieved from `` https://en.wikipedia.org/w/index.php?title=Deoxidization&oldid=823461247 '' Categories : Industrial processes Metallurgy Steelmaking Hidden categories : Articles created via the Article Wizard Talk Contents About Wikipedia Čeština Gaeilge Русский Українська Edit links This page was last edited on 1 February 2018, at 11 : 40 ( UTC ). About Wikipedia

Question: how entrapped bubbles of gases are removed from steel
Answer: Deoxidization