Melting point - wikipedia Melting point For the physical processes that take place at the melting point, see Melting, Freezing, and Crystallization. `` Freezing point '' redirects here. For other uses, see Freezing point ( disambiguation ). The melting point ( or, rarely, liquefaction point ) of a substance is the temperature at which it changes state from solid to liquid at atmospheric pressure. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point. Because of the ability of some substances to supercool, the freezing point is not considered as a characteristic property of a substance. When the `` characteristic freezing point '' of a substance is determined, in fact the actual methodology is almost always `` the principle of observing the disappearance rather than the formation of ice '', that is, the melting point. Contents 1 Examples 2 Melting point measurements 2.1 Techniques for refractory materials 3 Thermodynamics 4 Freezing - point depression 5 Carnelley 's rule 6 Predicting the melting point of substances ( Lindemann 's criterion ) 7 Melting point prediction 8 See also 9 References 10 Bibliography 11 External links Examples Further information : List of elements by melting point Melting points ( in blue ) and boiling points ( in pink ) of the first eight carboxylic acids ( ° C ) For most substances, melting and freezing points are approximately equal. For example, the melting point and freezing point of mercury is 234.32 kelvins ( − 38.83 ° C or − 37.89 ° F ). However, certain substances possess differing solid - liquid transition temperatures. For example, agar melts at 85 ° C ( 185 ° F ) and solidifies from 31 ° C ( 88 ° F ; 304 K ) ; such direction dependence is known as hysteresis. The melting point of ice at 1 atmosphere of pressure is very close to 0 ° C ( 32 ° F ; 273 K ) ; this is also known as the ice point. In the presence of nucleating substances, the freezing point of water is not always the same as the melting point. In the absence of nucleators water can exist as a supercool ed liquid down to − 48.3 ° C ( − 55 ° F, 224.8 K ) before freezing. The chemical element with the highest melting point is tungsten, at 3,414 ° C ( 6,177 ° F ; 3,687 K ) ; this property makes tungsten excellent for use as filaments in light bulbs. The often - cited carbon does not melt at ambient pressure but sublimes at about 3,726.85 ° C ( 6,740.33 ° F ; 4,000.00 K ) ; a liquid phase only exists above pressures of 10 MPa ( 99 atm ) and estimated 4,030 -- 4,430 ° C ( 7,290 -- 8,010 ° F ; 4,300 -- 4,700 K ) ( see carbon phase diagram ). Tantalum hafnium carbide ( Ta HfC ) is a refractory compound with a very high melting point of 4215 K ( 3942 ° C, 7128 ° F ). At the other end of the scale, helium does not freeze at all at normal pressure even at temperatures close to absolute zero ; pressure greater than twenty times of atmosphere of normal one is necessary. hide List of common chemicals Chemical Density ( g / cm ) Melt ( K ) Boil ( K ) Water @ STP 273 373 Solder ( Pb60Sn40 ) 456 Cocoa butter 307.2 - Paraffin wax 0.9 310 643 Hydrogen 0.00008988 14.01 20.28 Helium 0.0001785 -- 4.22 Beryllium 1.85 1560 2742 Carbon 2.267 3800 4300 Nitrogen 0.0012506 63.15 77.36 Oxygen 0.001429 54.36 90.20 Sodium 0.971 370.87 1156 Magnesium 1.738 923 1363 Aluminium 2.698 933.47 2792 Sulfur 2.067 388.36 717.87 Chlorine 0.003214 171.6 239.11 Potassium 0.862 336.53 1032 Titanium 4.54 1941 3560 Iron 7.874 1811 3134 Nickel 8.912 1728 3186 Copper 8.96 1357.77 2835 Zinc 7.134 692.88 1180 Gallium 5.907 302.9146 2673 Silver 10.501 1234.93 2435 Cadmium 8.69 594.22 1040 Indium 7.31 429.75 2345 Iodine 4.93 386.85 457.4 Tantalum 16.654 3290 5731 Tungsten 19.25 3695 5828 Platinum 21.46 2041.4 4098 Gold 19.282 1337.33 3129 Mercury 13.5336 234.43 629.88 Lead 11.342 600.61 2022 Bismuth 9.807 544.7 1837 Notes Jump up ^ Z is the standard symbol for atomic number ; C is the standard symbol for heat capacity ; and χ is the standard symbol for electronegativity on the Pauling scale. Jump up ^ Helium does not solidify at a pressure of one atmosphere. Helium can only solidify at pressures above 25 atmospheres, which corresponds to a melting point of absolute zero. Melting point measurements Main article : Melting point apparatus Kofler bench with samples for calibration Many laboratory techniques exist for the determination of melting points. A Kofler bench is a metal strip with a temperature gradient ( range from room temperature to 300 ° C ). Any substance can be placed on a section of the strip, revealing its thermal behaviour at the temperature at that point. Differential scanning calorimetry gives information on melting point together with its enthalpy of fusion. Automatic digital melting point meter A basic melting point apparatus for the analysis of crystalline solids consists of an oil bath with a transparent window ( most basic design : a Thiele tube ) and a simple magnifier. The several grains of a solid are placed in a thin glass tube and partially immersed in the oil bath. The oil bath is heated ( and stirred ) and with the aid of the magnifier ( and external light source ) melting of the individual crystals at a certain temperature can be observed. In large / small devices, the sample is placed in a heating block, and optical detection is automated. The measurement can also be made continuously with an operating process. For instance, oil refineries measure the freeze point of diesel fuel online, meaning that the sample is taken from the process and measured automatically. This allows for more frequent measurements as the sample does not have to be manually collected and taken to a remote laboratory. Techniques for refractory materials For refractory materials ( e.g. platinum, tungsten, tantalum, some carbides and nitrides, etc. ) the extremely high melting point ( typically considered to be above, say, 1800 ° C ) may be determined by heating the material in a black body furnace and measuring the black - body temperature with an optical pyrometer. For the highest melting materials, this may require extrapolation by several hundred degrees. The spectral radiance from an incandescent body is known to be a function of its temperature. An optical pyrometer matches the radiance of a body under study to the radiance of a source that has been previously calibrated as a function of temperature. In this way, the measurement of the absolute magnitude of the intensity of radiation is unnecessary. However, known temperatures must be used to determine the calibration of the pyrometer. For temperatures above the calibration range of the source, an extrapolation technique must be employed. This extrapolation is accomplished by using Planck 's law of radiation. The constants in this equation are not known with sufficient accuracy, causing errors in the extrapolation to become larger at higher temperatures. However, standard techniques have been developed to perform this extrapolation. Consider the case of using gold as the source ( mp = 1063 ° C ). In this technique, the current through the filament of the pyrometer is adjusted until the light intensity of the filament matches that of a black - body at the melting point of gold. This establishes the primary calibration temperature and can be expressed in terms of current through the pyrometer lamp. With the same current setting, the pyrometer is sighted on another black - body at a higher temperature. An absorbing medium of known transmission is inserted between the pyrometer and this black - body. The temperature of the black - body is then adjusted until a match exists between its intensity and that of the pyrometer filament. The true higher temperature of the black - body is then determined from Planck 's Law. The absorbing medium is then removed and the current through the filament is adjusted to match the filament intensity to that of the black - body. This establishes a second calibration point for the pyrometer. This step is repeated to carry the calibration to higher temperatures. Now, temperatures and their corresponding pyrometer filament currents are known and a curve of temperature versus current can be drawn. This curve can then be extrapolated to very high temperatures. In determining melting points of a refractory substance by this method, it is necessary to either have black body conditions or to know the emissivity of the material being measured. The containment of the high melting material in the liquid state may introduce experimental difficulties. Melting temperatures of some refractory metals have thus been measured by observing the radiation from a black body cavity in solid metal specimens that were much longer than they were wide. To form such a cavity, a hole is drilled perpendicular to the long axis at the center of a rod of the material. These rods are then heated by passing a very large current through them, and the radiation emitted from the hole is observed with an optical pyrometer. The point of melting is indicated by the darkening of the hole when the liquid phase appears, destroying the black body conditions. Today, containerless laser heating techniques, combined with fast pyrometers and spectro - pyrometers, are employed to allow for precise control of the time for which the sample is kept at extreme temperatures. Such experiments of sub-second duration address several of the challenges associated with more traditional melting point measurements made at very high temperatures, such as sample vaporization and reaction with the container. Thermodynamics Pressure dependence of water melting point. For a solid to melt, heat is required to raise its temperature to the melting point. However, further heat needs to be supplied for the melting to take place : this is called the heat of fusion, and is an example of latent heat. From a thermodynamics point of view, at the melting point the change in Gibbs free energy ( ΔG ) of the material is zero, but the enthalpy ( H ) and the entropy ( S ) of the material are increasing ( ΔH, ΔS > 0 ). Melting phenomenon happens when the Gibbs free energy of the liquid becomes lower than the solid for that material. At various pressures this happens at a specific temperature. It can also be shown that : Δ S = Δ H T ( displaystyle Delta S = ( \frac ( Delta H ) ( T ) ) ) Here T, ΔS and ΔH are respectively the temperature at the melting point, change of entropy of melting and the change of enthalpy of melting. The melting point is sensitive to extremely large changes in pressure, but generally this sensitivity is orders of magnitude less than that for the boiling point, because the solid - liquid transition represents only a small change in volume. If, as observed in most cases, a substance is more dense in the solid than in the liquid state, the melting point will increase with increases in pressure. Otherwise the reverse behavior occurs. Notably, this is the case of water, as illustrated graphically to the right, but also of Si, Ge, Ga, Bi. With extremely large changes in pressure, substantial changes to the melting point are observed. For example, the melting point of silicon at ambient pressure ( 0.1 MPa ) is 1415 ° C, but at pressures in excess of 10 GPa it decreases to 1000 ° C. Melting points are often used to characterize organic and inorganic compounds and to ascertain their purity. The melting point of a pure substance is always higher and has a smaller range than the melting point of an impure substance or, more generally, of mixtures. The higher the quantity of other components, the lower the melting point and the broader will be the melting point range, often referred to as the `` pasty range ''. The temperature at which melting begins for a mixture is known as the `` solidus '' while the temperature where melting is complete is called the `` liquidus ''. Eutectics are special types of mixtures that behave like single phases. They melt sharply at a constant temperature to form a liquid of the same composition. Alternatively, on cooling a liquid with the eutectic composition will solidify as uniformly dispersed, small ( fine - grained ) mixed crystals with the same composition. In contrast to crystalline solids, glasses do not possess a melting point ; on heating they undergo a smooth glass transition into a viscous liquid. Upon further heating, they gradually soften, which can be characterized by certain softening points. Freezing - point depression Main articles : Freezing - point depression and Supercooling The freezing point of a solvent is depressed when another compound is added, meaning that a solution has a lower freezing point than a pure solvent. This phenomenon is used in technical applications to avoid freezing, for instance by adding salt or ethylene glycol to water. Carnelley 's rule In organic chemistry, Carnelley 's rule, established in 1882 by Thomas Carnelley, states that high molecular symmetry is associated with high melting point. Carnelley based his rule on examination of 15,000 chemical compounds. For example, for three structural isomers with molecular formula C H the melting point increases in the series isopentane − 160 ° C ( 113 K ) n - pentane − 129.8 ° C ( 143 K ) and neopentane − 16.4 ° C ( 256.8 K ). Likewise in xylenes and also dichlorobenzenes the melting point increases in the order meta, ortho and then para. Pyridine has a lower symmetry than benzene hence its lower melting point but the melting point again increases with diazine and triazines. Many cage - like compounds like adamantane and cubane with high symmetry have relatively high melting points. A high melting point results from a high heat of fusion, a low entropy of fusion, or a combination of both. In highly symmetrical molecules the crystal phase is densely packed with many efficient intermolecular interactions resulting in a higher enthalpy change on melting. Predicting the melting point of substances ( Lindemann 's criterion ) An attempt to predict the bulk melting point of crystalline materials was first made in 1910 by Frederick Lindemann. The idea behind the theory was the observation that the average amplitude of thermal vibrations increases with increasing temperature. Melting initiates when the amplitude of vibration becomes large enough for adjacent atoms to partly occupy the same space. The Lindemann criterion states that melting is expected when the vibration root mean square amplitude exceeds a threshold value. Assuming that all atoms in a crystal vibrate with the same frequency ν, the average thermal energy can be estimated using the equipartition theorem as E = 4 π 2 m ν 2 u 2 = k B T ( displaystyle E = 4 pi ^ ( 2 ) m \nu ^ ( 2 ) ~ u ^ ( 2 ) = k_ ( B ) T ) where m is the atomic mass, ν is the frequency, u is the average vibration amplitude, k is the Boltzmann constant, and T is the absolute temperature. If the threshold value of u is c a where c is the Lindemann constant and a is the atomic spacing, then the melting point is estimated as T m = 4 π 2 m ν 2 c 2 a 2 k B. ( displaystyle T_ ( m ) = ( cfrac ( 4 pi ^ ( 2 ) m \nu ^ ( 2 ) c ^ ( 2 ) a ^ ( 2 ) ) ( k_ ( B ) ) ). ) Several other expressions for the estimated melting temperature can be obtained depending on the estimate of the average thermal energy. Another commonly used expression for the Lindemann criterion is T m = 4 π 2 m ν 2 c 2 a 2 2 k B. ( displaystyle T_ ( m ) = ( cfrac ( 4 pi ^ ( 2 ) m \nu ^ ( 2 ) c ^ ( 2 ) a ^ ( 2 ) ) ( 2k_ ( B ) ) ). ) From the expression for the Debye frequency for ν, we have T m = 2 π m c 2 a 2 θ D 2 k B h 2 ( displaystyle T_ ( m ) = ( cfrac ( 2 pi mc ^ ( 2 ) a ^ ( 2 ) \theta _ ( D ) ^ ( 2 ) k_ ( B ) ) ( h ^ ( 2 ) ) ) ) where θ is the Debye temperature and h is the Planck constant. Values of c range from 0.15 -- 0.3 for most materials. Melting point prediction In February 2011, Alfa Aesar released over 10,000 melting points of compounds from their catalog as open data. This dataset has been used to create a random forest model for melting point prediction which is now freely available. Open melting point data are also available from Nature Precedings. High quality data mined from patents and also models developed with these data were published by Tetko et al. See also Liquidus List of elements by melting point Melting points of the elements ( data page ) Phases of matter Triple point Simon -- Glatzel equation Slip melting point Solidus temperature Melting Heat Pressure Zone melting Phase diagram References Jump up ^ Ramsay, J.A. ( 1949 ). `` A new method of freezing - point determination for small quantities '' ( PDF ). J. Exp. Biol. 26 ( 1 ) : 57 -- 64. PMID 15406812. Jump up ^ Haynes, p. 4.122. Jump up ^ The melting point of purified water has been measured as 0.002519 ± 0.000002 ° C, see Feistel, R. & Wagner, W. ( 2006 ). `` A New Equation of State for H O Ice Ih ''. J. Phys. Chem. Ref. Data. 35 ( 2 ) : 1021 -- 1047. Bibcode : 2006JPCRD... 35.1021 F. doi : 10.1063 / 1.2183324. Jump up ^ Haynes, p. 4.123. Jump up ^ Agte, C. & Alterthum, H. ( 1930 ). `` Researches on Systems with Carbides at High Melting Point and Contributions to the Problem of Carbon Fusion ''. Z. Tech. Phys. 11 : 182 -- 191. Jump up ^ Holman, S.W. ; Lawrence, R.R. ; Barr, L. ( 1 January 1895 ). `` Melting Points of Aluminum, Silver, Gold, Copper, and Platinum ''. Proceedings of the American Academy of Arts and Sciences. 31 : 218 -- 233. doi : 10.2307 / 20020628. JSTOR 20020628. Jump up ^ The exact relationship is expressed in the Clausius -- Clapeyron relation. Jump up ^ `` J10 Heat : Change of aggregate state of substances through change of heat content : Change of aggregate state of substances and the equation of Clapeyron - Clausius ''. Retrieved 19 February 2008. Jump up ^ Tonkov, E. Yu. and Ponyatovsky, E.G. ( 2005 ) Phase Transformations of Elements Under High Pressure, CRC Press, Boca Raton, p. 98 ISBN 0 - 8493 - 3367 - 9 Jump up ^ Brown, R.J.C. & R.F.C. ( 2000 ). `` Melting Point and Molecular Symmetry ''. Journal of Chemical Education. 77 ( 6 ) : 724. Bibcode : 2000JChEd... 77... 724B. doi : 10.1021 / ed077p724. Jump up ^ Haynes, pp. 6.153 -- 155. Jump up ^ Lindemann FA ( 1910 ). `` The calculation of molecular vibration frequencies ''. Physik. Z. 11 : 609 -- 612. Jump up ^ Sorkin, S., ( 2003 ), Point defects, lattice structure, and melting, Thesis, Technion, Israel. Jump up ^ Philip Hofmann ( 2008 ). Solid state physics : an introduction. Wiley - VCH. p. 67. ISBN 978 - 3 - 527 - 40861 - 0. Retrieved 13 March 2011. Jump up ^ Nelson, D.R., ( 2002 ), Defects and geometry in condensed matter physics, Cambridge University Press, ISBN 0 - 521 - 00400 - 4 Jump up ^ Bradley, J-C. and Lang A.S.I.D. ( 2011 ) Random Forest model for melting point prediction. onschallenge.wikispaces.com Jump up ^ Predict melting point from SMILES. Qsardb.org. Retrieved on 13 September 2013. Jump up ^ ONS Open Melting Point Collection. Precedings.nature.com. Retrieved on 13 September 2013. Jump up ^ OCHEM melting point models. ochem.eu. Retrieved on 18 June 2016. Jump up ^ Tetko, Igor V ; m. Lowe, Daniel ; Williams, Antony J ( 2016 ). `` The development of models to predict melting and pyrolysis point data associated with several hundred thousand compounds mined from PATENTS ''. Journal of Cheminformatics. 8. doi : 10.1186 / s13321 - 016 - 0113 - y. Bibliography Haynes, William M., ed. ( 2011 ). CRC Handbook of Chemistry and Physics ( 92nd ed. ). CRC Press. ISBN 1439855110. External links Melting and boiling point tables vol. 1 by Thomas Carnelley ( Harrison, London, 1885 -- 1887 ) Melting and boiling point tables vol. 2 by Thomas Carnelley ( Harrison, London, 1885 -- 1887 ) Patent mined data Over 250,000 freely downloadable melting point data. Also downloadable at figshare States of matter ( list ) State Baryonic matter Solid Liquid Gas / Vapor Plasma Low energy Bose -- Einstein condensate Fermionic condensate Degenerate matter Quantum Hall Rydberg matter Rydberg polaron Strange matter Superfluid Supersolid Photonic matter High energy QCD matter Lattice QCD Quark -- gluon plasma Color - glass condensate Supercritical fluid Other states Colloid Glass Crystal Liquid crystal Time crystal Quantum spin liquid Exotic matter Programmable matter Dark matter Antimatter Magnetically ordered Antiferromagnet Ferrimagnet Ferromagnet String - net liquid Superglass Transitions Boiling Boiling point Condensation Critical line Critical point Crystallization Deposition Evaporation Flash evaporation Freezing Chemical ionization Ionization Lambda point Melting Melting point Recombination Regelation Saturated fluid Sublimation Supercooling Triple point Vaporization Vitrification Quantities Enthalpy of fusion Enthalpy of sublimation Enthalpy of vaporization Latent heat Latent internal energy Trouton 's ratio Volatility Concepts Binodal Compressed fluid Cooling curve Equation of state Leidenfrost effect Macroscopic quantum phenomena Mpemba effect Order and disorder ( physics ) Spinodal Superconductivity Superheated vapor Superheating Thermo - dielectric effect Retrieved from `` https://en.wikipedia.org/w/index.php?title=Melting_point&oldid=854459931 '' Categories : Atmospheric thermodynamics Concepts in physics Phase transitions Threshold temperatures Hidden categories : CS1 : Julian -- Gregorian uncertainty Use dmy dates from October 2015 Talk Contents About Wikipedia Afrikaans Aragonés Asturianu Azərbaycanca বাংলা Bân - lâm - gú Беларуская Беларуская ( тарашкевіца ) ‎ Български Bosanski Català Čeština Cymraeg Dansk Deutsch Eesti Ελληνικά Español Esperanto Euskara فارسی Français Frysk Gaeilge Gaelg Galego 한국어 हिन्दी Hrvatski Bahasa Indonesia Interlingua Íslenska Italiano עברית Basa Jawa ಕನ್ನಡ ქართული Қазақша Kreyòl ayisyen Kurdî Latina Latviešu Lietuvių La. lojban. Lumbaart Magyar Македонски മലയാളം मराठी Bahasa Melayu Монгол မြန်မာဘာသာ Nederlands नेपाल भाषा 日本 語 Norsk Norsk nynorsk Oʻzbekcha / ўзбекча ਪੰਜਾਬੀ پنجابی ភាសា ខ្មែរ Plattdüütsch Polski Português Română Runa Simi Русский Scots සිංහල Simple English Slovenčina Slovenščina Српски / srpski Srpskohrvatski / српскохрватски Suomi Svenska Tagalog தமிழ் తెలుగు ไทย Türkçe Українська اردو Tiếng Việt Winaray 粵語 中文 79 more Edit links This page was last edited on 11 August 2018, at 14 : 36 ( UTC ). Text is available under the Creative Commons Attribution - ShareAlike License ; additional terms may apply. By using this site, you agree to the Terms of Use and Privacy Policy. Wikipedia ® is a registered trademark of the Wikimedia Foundation, Inc., a non-profit organization. About Wikipedia

Question: which type of substance has the highest melting point
Answer: tungsten