N-heterocyclic silylene
Electronics

N-heterocyclic silylene

Section Title: Electronics
Table Section Text: None

Saturated NHSi (C2)	Unsaturated NHSi (C2V)	NHSilane (C2V)

LUMO	LUMO	LUMO

-	-	-

HOMO (B)	HOMO (B2)	HOMO (B2)

7.54 eV (calc. -8.76)	6.94, -7.13, -7.28 eV (calc. -7.62)	6.56 eV (calc. -7.10)

-	-	-

HOMO - 1 (A)	HOMO - 1 (A1)

8.11 eV (calc. -9.40)	8.21 eV (calc. -9.07)

-	-	No Corresponding Orbital No Empty Si 3pπ

HOMO - 2 (A2)	HOMO -1(A2)

9.08 eV (calc. -11.32)	8.92 eV (calc. -11.32)

No Corresponding Orbital There are no p orbitals on saturated carbons to mix with nitrogen lone pairs	-	-

Sentence(s)

N-heterocyclic silylene has the unsaturated Si at -7.13eV & -7.28eV.

final_sentence: N-heterocyclic silylene has the unsaturated Si at -7.13eV & -7.28eV.