BSC-LT/ACAData huggingface dataset:
[en] Late-stage C–H functionalization has arisen as a powerful instrument for the rapid preparation of libraries of analogues derived from bioactive compounds and for the improvement of biological activity and metabolic stability. Despite the wealth of reports in the field, the site-selective remote modification of both phenylalanine (Phe) and tyrosine (Tyr) compounds upon metal catalysis remains comparatively overlooked. Thus, the main goal of this work relies on the development of a protocol for the meta C(sp2)−H functionalization of Tyr and Phe in a late-stage fashion. In particular, a strategy for the Pd-catalyzed meta C(sp2)−H functionalization was studied for Tyr and Phe units. This strategy involves the design of a removable directing group (DG) connected to the amino acid unit that enables the meta C(sp2)−H activation. A pyridine and benzonitrile-containing template were established as DGs on the N-terminal position of the Tyr and Phe unit. Nevertheless, no optimal protocol has been developed fort the remote C(sp2)−H functionalization

[eu] Azken etapako C–H funtzionalizazioa tresna indartsu gisa sortu da konposatu bioaktiboetatik eratorritako analogoak azkar biltzeko. Modu honetan, jarduera biologikoa eta egonkortasun metabolikoa hobea daukaten analogoak lortu daitezke. Nahiz eta txostenak ugari izan, fenilalaninaren (Phe) eta tirosinaren (Tyr) katalisi metalikoaren bitartez urruneko eraldaketa selektiboa ez da momentuz aztertu. Horrela, lan honen helburu nagusia Tyr eta Phe-ren meta C(sp2 )−H funtzionalizaziorako protokolo bat garatzea da. Zehazki, Pd-katalizatutako meta C(sp2)−H estrategia bat ikertu da Tyr eta Phe-ren funtzionalizaziorako. Estrategia honen bidez, aminoazidoei konektatutako talde zuzentzaile desmuntagarri bat diseinatu nahi da, meta C(sp2)−H-ren aktibazioa aukera emango duena. Piridinina eta benzonitrilo taldeak ezarri ziren talde zuzentzaile gisa Tyr and Phe unitatearen N-posizio terminalean. Hala ere, ez dugu protokolo optimorik garatu urruneko C(sp2)−H funtzionalizaziorako.
[en] The problem of maltreatment is studied from the perspective of the Penal Code and the Procedural Law. Likewise, the regulations about crimes against sexual liberty are analysed centring the attention on sexual aggressions to children, and explaining also the attitude in the matter of the European Council. Finally, the assistance and compensation's possibilities to the victims of violent crimes and crimes against sexual liberty are stated, with a special interest in minors.

[eu] Kode penala eta Auzipitze Zibileko legeen perspektibatik tratu txarren problematika aztertzen da. Era berean, askatasun sexualaren kontrako delituak erregulatzen dituen arautegiaz hitzegiten da, haurren aurkako eraso sexualetan sakonduz eta Europar Erkidegoko Kontseiluak duen iritzia azalduz. Azkenik, indarkeriazko delituen kaltetuen aldeko asistentzia eta ordainen posibilitateak aztertzen dira, bereziki kaltetu adingabetuenak.
[en] The aim of this final grade project is to estimate the amount of fuel necessary to supply a possible future nuclear fusion power plant in Euskadi and to study the process of obtaining this fuel. The plant will have a 2GW power deuterium-tritium Tokamak reactor that will satisfy the electrical energy demand in Euskadi. Firstly, the plasma has been sized by comparing it to the ITER project. Secondly it has been decided to install a breeding-blanket of beryllium and lithium that will produce tritium from the neutrons produced in the fusion reaction. Finally, different procedures have been analyzed in order to obtain the fuel and an indicative fuelling budget has been carried out.

[eu] Gradu amaierako lan honen helburua etorkizunean Euskadin kokatutako energia elektrikoa ekoitziko lukeen fusio planta posible bat hornitzeko beharrezko erregaiaren kalkulua egitea eta erregai hori lortzeko bideak aztertzea izan da. Plantak 2GW-ko potentziadun deuterio-tritio Tokamak erreaktorea izango du, Euskadiko eskari energetikoa asetzeko gai izango dena. Lehenik eta behin plasma dimentsionatu egin da ITER proiektuarekin konparaketa bat eginez. Ondoren berilio eta litiozko breeding blanket bat instalatzea erabaki da, fusioan sortutako neutroiei esker tritioa ekoitziko duena. Azkenik erregaiak lortzeko bide ezberdinak aztertu egin dira eta haien lorpenerako aurrekontu hurbila garatu egin da.
[en] This End of Degree Project is part of the EHUkhi project, a working group made up of administration and services staff, teachers and students that has been formed thanks to the Campus Bizia Lab (CBL) programme, which aims to respond to sustainability challenges within the University itself. This End of Degree Project aims to analyse the production of the photovoltaic potential in the University of Engineers of Bilbao. Through this work, the methodological bases for the calculation of the photovoltaic potential of any building have been established. For this purpose, building maps have been combined with maps containing the orography of the surroundings, as well as maps containing the necessary information to calculate the photovoltaic potential (for example, radiation, slope, orientation...) in order to obtain the production of each building, both per year, per month and per hour per day. In addition, a basic energy analysis has been carried out (through the calculation of the supply rate of each building and the energy pay back of the panels).

[eu] Gradu Amaierako Lan hau EHUkhi proiektuaren parte da, administrazio eta zerbitzuen langileen, irakasleen eta ikasleen lankidetza talde bat Campus Bizia Lab (CBL) programaren ondorioz sortu egin dena Unibertsitateko jasangarritasun erronkei erantzuteko. Lan honen helburua, Bilboko Ingeniaritza Eskolaren potentzial fotovoltaikoaren produkzioa aztertzea da. Lan honekin edozein eraikinen potentzial fotovoltaikoaren kalkuluaren oinarri metodologikoak finkatzea bilatu da. Horretarako, eraikinen mapak eta inguruneko orografia biltzen duten mapak, hala nola, potentzial fotovoltaikoa kalkulatzeko funtsezkoak diren beste elementuak (adb. Irradiazioa, maldak, orientazioa…) konbinatuz, eraikin bakoitzaren urteko, hileko eta eguneko ekoizpena kalkulatuz. Horretaz gain, oinarrizko analisi energetikoa burutu da (eraikin bakoitzaren hornikuntza tasa eta panelen pay back energetikoa kalkulatuz).
[en] The main purpose of this final degree project is to analyse the feasibility of an urban wind power system and to evaluate different alternatives of small-wind technology for the generation of electricity in the city, taking into account the current moment of this type of energy and the most recent developments in this field.On the one hand, this project was born of the desire of a "greener" and more sustainable city of Bilbao, in addition to the attraction of researching an emerging technology like this one. On the other hand, the importance of betting on renewable energies as the unique source of energy in the early future, while the city gains a modern image and a relevant social awareness.

[eu] Gradu Amaierako Lan honen helburua hiri batean energia eolikoa aprobetxatzearen bideragarritasuna ikertzea da. Gainera, energia sortzeko hainbat teknologia minieolikoa ebaluatzea helburutzat hartu da, energia mota horren momentua eta eremu horren azken garapenak kontuan hartzen. Alde batetik, proiektu honek hiri "berdeago" eta iraunkor baten nahiaz sortu zen, sortzen ari den teknologia honen ikerketak eta ezaguerak daukan interesaz beste. Beste aldetik, energia berriztagarriengan etorkizunarenenergia iturri bezala apustu egitearen garrantziaz, Bilbo hiriak gizartearen kontzientziazio eta sentsibilizazioan irudi modernoago eta garrantzitsuagoa hartzen duen eran.
[en] Nowadays, the early schooling rate is higher than ever before, and considering the importance and transcendence of the first years of life, we must reflect on the educator´s work. The educator performs direct interventions when taking care of children, one of the most important care moments is the meal, because children build safe and strong relationships with the food (which will be their energy source) and with their caregiver (which will be their security source). Thus, the aim of this work is to observe and to analyze the educator´s performance at mealtime, in particular the aspects related to actions, gesture and language. The outcomes of this systematic observation show that different aspects must be taken into consideration in order to become the meal into a moment of quality care. This way, we would help children to become aware of themselves and promote their participation in meals. (English)

[eu] Gaur egun eskolaratzea inoiz baino goiztiarragoa da, eta lehen haurtzaroak bizitza osoan zehar duen garrantzia kontutan hartuta, hezitzailearen jardunaren inguruko hausnarketa beharrezkoa da. Hezitzaileak zaintza uneetan esku hartze zuzena egiten du, eta zaintza une garrantzitsuenetako bat jateko ordua da, bai energia iturri duen janariarekin bai hezitzailearekin harreman sendoa eraikitzen duelako. Gradu Amaierako Lan honen helburua egoera erreal batean, bazkalorduak behatzea da, hain zuzen ere, hezitzaile batek bazkalorduetan ekintzari, keinuei eta hizkuntzari dagokionez dituen portaerak eta joerak behatzea eta aztertzea. Behaketa sistematikoaren ondorioz lortutako emaitzek erakutsi dute hainbat alderdi izan behar direla kontutan zaintza kalitatezkoa izan dadin, umeari bere buruaren kontzientzia hartzen laguntzeko eta jatorduetan bere parte hartzea bultzatzeko. (Euskara)
[en] The present doctoral thesis centers on studying pyrolysis as a chemical recycling technique for rejected packaging waste fractions coming from separation and sorting plants. The pyrolysis experiments have been carried out in a lab-scale installation equipped with a 3.5 L semi-batch reactor and a condensation and collection system for the liquids and gases generated. In the present thesis, an experimental study on the conventional pyrolysis process applied to the aforementioned waste fractions has been conducted, as well as the study of non-conventional or advanced pyrolysis processes such as catalytic and stepwise pyrolysis. The study of the operating parameters has been carried out using a mixed plastics simulated sample, the composition of which is similar to that found in real fractions, and subsequently the optimized process has been applied to real packaging waste. An exhaustive characterization of the solids, liquids and gases obtained in the process has been made after each experiment and their potential uses have been established. Finally, an empirical model that will predict the pyrolysis yields (% organic liquid, % aqueous liquid, % gases, % char, % inorganic solid) as a function of the composition of the initial sample has been developed. As a result of the experimental work done, the requirements have been established for an industrial packaging waste pyrolysis plant that aims to be sufficiently versatile as to generate useful products regardless of the nature of the raw material.

[eu] Pirolisia hiriko ontzi-hondakinen erreusen birziklapenerako aukera gisa aztertu da tesi lan honetan. Pirolisi saiakuntzak 3,5 litro bolumeneko semi-batch erreaktoreaz eta likido eta gas produktuen kondentsazio eta bilketen sistemaz osatutako laborategiko instalazio batean egin dira. Lan honetan, pirolisi konbentzionalaz gain, pirolisi prozesu aurreratuak ere aztertu dira, besteak beste, pirolisi katalitikoa edota etapaz etapa egindako pirolisia. Lan parametroak simulatutako lagin bat erabiliz aztertu eta optimizatu dira eta, ondoren, lortutako parametroak lagin errealen saiakuntzetan erabili dira. Saiakuntza guztietan, lortu diren produktu gaseoso, likido eta solidoak sakonki karakterizatu dira eta ondoren izan litzaketen erabilerak aztertu dira. Azkenik, pirolisi errendimenduak (likido organikoak %, likido urtsuak %, gasak %, char %, solido inorganikoak %) erabilitako laginaren konposizioaren arabera zenbatesteko tresna bat garatu da (modelo enpirikoa). Egindako lan esperimentalean oinarrituta, ontzi-hondakinen erreusa tratatzeko instalazio industrial batek bete beharreko baldintzak ezarri dira, instalazioa, lehengaiak edonolako ezaugarriak dituztelarik, produktu baliagarri bihurtzeko gai izan dadin.
[en] The fundamental objective of this Final Degree Project is to carry out an analysis on the constitutional scope of the Minimum Vital Income, an economic benefit aimed at reducing the poverty rate in Spain and which has been aggravated by COVID-19. To do this, in the first place, the regulation of the benefit will be analyzed, to later make a comparison with the Universal Basic Income and the Minimum Insertion Income, including resolutions of European law. Subsequently, it will be examined whether the benefit complies with some of the constitutional provisions: the right to equality and non- discrimination, and the mandate addressed to the public powers regarding the sufficiency of Social Security benefits together with the principle of human dignity.

[eu] Gradu Amaierako Lan honen helburu nagusia Bizitzeko Gutxieneko Diru sarreraren esparru konstituzionalari buruzko azterketa egitea da. Prestazio ekonomiko hori Espainiako pobrezia-tasa murriztera bideratuta dago, COVID-19k areagotu duen tasa. Horretarako, lehenik eta behin, prestazioaren erregulazioa aztertuko da, eta ondoren, Oinarrizko Errenta Unibertsalarekin eta Diru-sarrerak Bermatzeko Errentarekin alderatuko da, Europako zuzenbideko ebazpenak barne. Ondoren, prestazioak konstituzio-xedapenetako batzuk betetzen dituen aztertuko da: berdintasunerako eta diskriminaziorik ezerako eskubidea, eta Gizarte Segurantzaren prestazioen nahikotasunari buruzko botere publikoei zuzendutako agindua, giza duintasunaren printzipioarekin batera.
[en] it is explained the meaning of the Criminology and the legislative penal policy and it is brought out the difficulty and the importance of the criminological research and its role in the criminal policy praxis.

[eu] Kriminologiaren eta penal-legegintza politikaren garrantziaz adieratzen da eta azaltzen da ere, kriminolojiko ikerketak daukan zailtasuna era ardura; eta bere garrantzitasuna kriminal politika egiterakoan.
[en] In Industry 4.0, the use of wireless technologies is to be encouraged. However, due to the nature of wireless propagation, it is still difficult to meet the reliability, latency and determinism requirements offered by wired communications. To evaluate the performance of wireless communications, field testing is required, which increases the overall cost. Another option is to make use of a channel emulator, saving the cost. This Master's Thesis focuses on the design and implementation of new functionalities in an RF channel emulator on a development card with asymmetric multiprocessing and programmable logic. A Zynq Ultrascale+ family board with a Cortex A53 processor is used with a Linux for general tasks and a Cortex R5 for time-sensitive tasks, making use of the openAMP framework and implementing the channel emulator on the board's FPGA. An analysis of the technologies related to the emulator is carried out, as well as the study of the emulator itself. The development of the new functionalities is detailed from the design to the evaluation by means of different tests.

[eu] 4.0 industrian, haririk gabeko teknologien erabilera sustatu nahi da. Hala ere, haririk gabeko hedapenaren izaera dela eta, oraindik zaila da komunikazio kableatuek eskaintzen dituzten fidagarritasun, latentzia eta determinismo baldintzak betetzea. Haririk gabeko komunikazioen funtzionamendua ebaluatzeko, kanpo-probak egin behar dira, eta horrek kostu osoa handitzea dakar. Beste aukera bat kanal-emuladore bat erabiltzea da, kostua aurreztuz. Master Amaierako Lan hau multiprozesamendu asimetriko eta logiko programagarria duen garapen-txartel baten gainean RF kanaleko emuladore batean funtzionalitate berriak diseinatzean eta inplementatzean oinarritzen da. Zynq Ultrascale+ familiako txartel bat erabiltzen da, Cortex A53 prozesadore batekin, Linux batekin, zeregin orokorretarako, eta Cortex R5 txartel batekin, denbora-eskakizunak dituzten zereginetarako, openAMP framework-a erabiliz eta txartelaren FPGAn kanal-emuladorea inplementatuz. Emuladorearekin lotutako teknologien azterketa egiten da, baita emuladorearen beraren analisia ere. Funtzionalitate berrien garapena zehazten da, diseinutik hasi eta proba desberdinen bidezko ebaluaziora arte.
[en] This Final Degree Project has attempted to detect the lack of implementation of Sex Education in the Primary Education stage despite the fact that it appears in both the current law, LOMLOE (2020), and the Curriculum. By means of a questionnaire carried out with Primary Education teachers in schools in Bizkaia, this study has tried to identify the needs of these teachers with regard to the implementation of Sex Education in their classrooms. Bearing this in mind, this study has attempted to respond to these needs by means of a didactic proposal for the implementation of Sex Education in the first cycle of Primary Education, specifically, to work on the topics of consent and sexual diversity.

[eu] Gradu Amaierako Lan honetan, sexu-hezkuntza Lehen Hezkuntzan ez dela ezarri antzematen saiatu da, indarrean dagoen legean, LOMLOE (2020), eta curriculumean agertu arren. Bizkaiko ikastetxeetako Lehen Hezkuntzako irakasleei egindako galdetegi baten bidez, irakasle horiek beren ikasgeletan sexu-hezkuntza ezartzeari dagokionez dituzten beharrak identifikatzen saiatu da. Hori kontuan hartuta, lan honen bidez, premia horiei erantzuten saiatu da, Lehen Hezkuntzako lehen zikloan sexu-hezkuntza ezartzeko proposamen didaktiko baten bidez, zehazki, sexu-onarpena eta sexu-aniztasunaren gaiak lantzeko.
[en] While the education community is in constant development, we can see little change in everyday classrooms. In order to make a contribution to science education, we will develop a didactical proposal to teach forces and dynamics in high school. To do that, we will use the most widely accepted methodology in science education and Physics Education Research (PER): Research-Based Design (DBR). This method is based on the principles of constructivism and is made up by some iterative phases. That non-stop iteration makes possible to evaluate and rebuild the Design whenever is needed. Then, first of all we will observe what has been researched in science education. After that, we will learn about what physics tells us about forces and dynamics and last but not least, we will combine the analysis we have talked about with an appropriate methodology to build a problem sequence that it will be applicable in class.

[eu] Hezkuntza komunitatea etengabeko garapenean dabilen bitartean aldaketa gutxi ikus ditzakegu egungo ikasgeletan. Garapen horri ekarpen txiki bat egin asmoz garatu da Gradu Amaierako Lan honetan Batxilergoko lehenengo mailan indarrak eta dinamika lantzeko proposamen didaktikoa. Horretarako, zientzien irakaskuntza komunitatean onespen zabalena duen metodologia erabili da, hain zuzen ere Ikerkuntzan Oinarritutako Diseinua (Design-Based Research, DBR). Konstruktibismoaren printzipioak bere egiten dituen metodologia hau hainbat fase ezberdinez osatzen da eta etengabeko iterazioetan duenez bere funtsa, oztopoen aurrean moldatzen da eta edozein ekarpenen aurrean, eraberritzen. Beraz, lehenik zientziaren irakaskuntzari buruz ikertu dena aztertuko dugu. Ondoren, indarrei eta dinamikari buruz fisikak diona begiratuko dugu, azkenik egindako analisia metodo egokiarekin uztartu eta ikasgeletan aplikagarria izango den jardueren sekuentzia bat eraikitzeraino.
[en] In the first part of this paper we describe the evolution of Translation Studies as a discipline: we recall the main different points of view and translation theories and we explain in which context the cultural and sociological turn have occurred in order to overcome some aspects of the systemic theories. In the second part of the paper, we focus on the sociological turn in Translation Studies: we recall the main research-trends, projects and different aspects considered in the area. Finally, we try to show why and how is the sociology of translation useful to study Basque translation history, based on Ibarluzea 2017 doctoral research. Few works have been done in the area of Basque translation studies folowing the sociology of translation and we try to make visible some posible research topics.

[eu] Lan honen lehenbiziko atalean itzulpen-ikasketak diziplinaren bilakabidearen berri ematen da: itzulpena aztertzeko ereduen eta itzulpen-teorien errepasoa egiten da; halaber, polisistemen teoriatik harago jota ikuspegi berriek ekarri dituzten "kultur bira" eta "bira soziologikoa" zein testuingurutan gertatu diren azaltzen da. Artikuluaren bigarren atalean bira soziologikoak ekarritako ikerketa-ildoak azaltzen dira: alorrari buruzko gogoetak biltzeaz gain, ikuspegi soziologikoz egindako ikerketa nagusien berri ematen da. Azkenik, itzulpenaren soziologiak euskal itzulpengintza aztertzeko daukan balioabistaratzen da, bakan-bakanak baitira ildo horretan egindako lanak. Ibarluzea 2017lana oinarri hartuta, euskal itzulpengintzaren historiaren ikerketarako egokitasuna agerrarazten da, eta etorkizunean azter daitezkeen alorretako batzuk proposatzen
[en] A brief analysis of the international instruments regarding criminal justice is followed by a proposal to use substitute measures to prison, not only as a simple penal reform, but as a deep and radical change reflecting a new ethical attitude towards the delinquent.

[eu] Justizi penalari buruzko nazioarteko tresnak aztertu ondoren, presondegi zigorraren ordezko neurrietako aplikazioa proposatzen da, ez bakarrik berrikuntza penala bezala baizik eta aldaketa sakon eta funtsezkoa, zeinek gaizkilearen aurrean jarrera etiko berri bat islada dezan.
[en] Only recently has International Law – i.e., the States – shown interest in victims, and that interest has taken the concrete form of a body of international norms with regard to the different categories of victims. Even so, although terrorism constitutes a grave violation of human rights and is an international crime, today, barring the Council of Europe, there is no international norm specifically conceived with the victims of terrorism in mind. This is a void that must be filled, and urgently so, within the UN, as well as the European Union. It is not a difficult task. We simply have to follow the steps laid down by the Council of Europe in its general guidelines on the protection of victims of terrorist acts, adopted by the Committee of Ministers of the Council of Europe on March 2, 2005.

[eu] Soilik duela gutxi erakutsi du Nazioarteko Zuzenbideak –hots, estatuek– biktimekiko interesa; interes hori biktimen kategoriei buruzko nazioarteko arau multzo batean zehaztuta dago. Hala ere, terrorismoa giza eskubideen urradura larria eta nazioarteko krimena izanagatik, gaur egun ez dago terrorismoaren biktimei buruzko nazioarteko araurik, Europako Kontseilua salbu. Beharrezkoa da hutsune hori lehenbailehen betetzea NBEren nahiz Europar Batasunaren arloan. Ez da la erraza. Nahikoa da Europako Kontseiluak ezarritako urratsei jarraitzea, hain zuzen ere, Europako Kontseiluko Ministro Batzordeak 2005eko martxoaren 2an onartutako ekintza terroristen biktimak babesteari buruzko arauei.