BSC-LT/ACAData huggingface dataset:
[en] The present Final Grade Project is dedicated to the synthesis and structural characterization of complexes with potential phytosanitary activity. In particular, to the synthesis of hydrazone bidentate [N,N] ligands and tridentate [N,N,S] ligands and to the synthesis of zinc(II) complexes derived from those ligands. By means of a condensation reaction with 2-acetylpyridine and 3-chlorophenyllhydrazine hydrochloride, in ethanol and with acid catalysis, the hydrazone bidentate a has been obtained. The derivative complexes 1a and 2a were obtained by reaction with dihydrated zinc(II) acetate and zinc(II) chloride, respectively, in ethanol. Both complexes present a chelated ring with the metal atom. To obtain the second bidentate hydrazone [N,N] b have been used 2-benzoylpyridine and 3-chlorophenylhydrazine hydrochloride in ethanol with acid catalysis. The reaction of hydrazone [N,N] b with dihydrated zinc(II) acetate in ethanol has led to complex 1b. Finally, tridentate thiosemicarbazone [N,N,S] c has been obtained by the reaction of 2-acetylpiridine and thiosemicarbazone in ethanol with acid catalysis. The reaction of the ligand c with dyhidrated zinc(II) acetate in ethanol has led to obtain complex 1c.

[gl] O presente Traballo de Fin de Grao está dedicado á síntese e caracterización estrutural de complexos con potencial actividade fitosanitaria. En concreto, á síntese de ligandos hidrazona bidentados [N,N] e tridentados [N,N,S] e á síntese de complexos de zinc(II) derivados de ditos ligandos. Mediante unha reacción de condensación con 2-acetilpirinda e clorhidrato de 3-clorofenilhidrazina, en etanol e con catálisis ácida, obtívose a hidrazona bidentada a. A continuación, sintetizáronse os derivados complexos 1a con acetato de zinc(II) dihidratado e por outro lado o complexo 2a con cloruro de zinc(II), en etanol. Ambos complexos forman un anel quelato bidentado co átomo metálico. Para a obtención da segunda hidrazona bidentada [N,N] b utilizouse 2-benzoilpiridina e clorhidrato de 3-clorofenilhidrazina en etanol con catálisis ácida. A reacción a refluxo da hidrazona [N,N] b con acetato de zinc(II) dihidratado en etanol conduxo ao complexo 1b. Para rematar, obtívose a tiosemicarbazona tridentada [N,N,S] c mediante a reacción de 2-acetilpiridina e tiosemicarbazona en etanol con catálisis ácida. A reacción do ligando c con acetato de zinc(II) dihidratado en etanol levou a obter o complexo 1c.
[en] In this paper, we analyse the differences that are manifested in the dimensions of organizational commitment (emotional, normative and ongoing commitment) of the teaching staff at public and private higher education institutions in the Laja-Bajío Metropolitan Area in the state of Guanajuato, Mexico. In a sample of 209 teachers, a general analysis was performed and then analysed by equating one of the conditions (remuneration form and weekly hours), finding insufficient evidence to say there are differences in organizational commitment based on the gender of teachers.

[gl] Neste traballo estúdanse as diferenzas de xénero entre os docentes de institucións de educación superior públicas e privadas da zona metropolitana de Laja-Bajío, no estado de Guanajuato, México, no tocante ás dimensións do compromiso organizacional (compromiso afectivo, compromiso normativo e compromiso continuo), incluídos aspectos como as formas de remuneración e a xornada laboral. Cunha mostra de 209 docentes, realizouse unha análise descritiva e correlacional. Os resultados suxiren que existen factores que inflúen en que actualmente homes e mulleres amosen diferentes niveis de compromiso afectivo e normativo, mais non se atopou evidencia de que o xénero en por si explique o compromiso organizacional dos docentes de institucións públicas e privadas
[en] Along the following work, it is shown the desing process, construction and the economic evaluation about a seabed explotation ship, in this case, the transport and the installation of wind turbines in offshore wind farms. The ship will dispose "legs" that will be moved by hidraulic bombs (With a double ring) to elevate the ship from the water and the vessel will be able to operate with the crane in the installation maneuver.

[gl] Ao longo do presente traballo móstrase o proceso de deseño, construcción e evaluación económica dun buque dedicado á explotación do medio mariño, neste caso é o de transporte e intalación de aeroxeradores en parques eólicos mariños offshore. O buque disporá dunhas "patas" que estarán movidas hidráulicamente (cun dobre anelo) para elevar o buque do auga e así poder operar coa grúa na manobra de instalación de aeroxeradores.
[en] The work of Holland is centered in the study ofthe types (tipology). He understands that most of the persons are seemed, to some extent, to one of the six basic types of personality (Realistic, Investigative, Artistic, Social, Enterprising and Conventional) and that it is probable that express conduct and features associated with that type. In the same way that there are six types of personality, there are six types of environments in those which the persons are developed and that they can be described according to given attributes and characteristic. The environments are characterized by the people that occupies them. The conduct will be determined by the interaction among types and ambient.

[gl] o traballo de Holland céntrase sobre o estudio dos tipos (tipoloxía). El entende que a maioría das persoas parécense, maiormente, a un dos seis tipos básicos de personalidade (Realista, Investigador, Artístico, Social, Emprendedor e Convencional) e que é probable que manifesten conductas e rasgos asociados a estes tipo. Do mesmo xeito que hai seis tipos de personalidade tamén hai seis tipos de ambientes nos que as persoas se desenvolven e que poden ser descritos de acordo con determinados atributos e características. Os ambientes están caracterizados pola xente que os ocupa. A conducta estará determinada pola interacción entre tipos e ambientes
[en] This study focuses on the synthesis and characterization of three ligands, two thiosemicarbazones and one imine, and their corresponding compounds derived from ruthenium. [Fig. Tiosemicaarbazona a; Tiosemicarbazona b; Imina c] The treatment of ligand a with tetrachlorobis(p-cymeno)diruthenium(II) and silver triflate, leads to the preparation of coordination compound 1a. In contrast, with the ligands b and c, the respective coordination compounds were not obtained. [Fig. 1a] On the other hand, the treatment of the ligand c with tetrachlorobis(pcymeno) diruthenium(II), in the presence of a base, led to the obtaining cyclometalated compound 2c. In contrast, ligand a does not produce such cyclometallation. [Fig 2c]

[gl] O presente traballo céntrase no estudo da síntese e caracterización de tres ligandos, duas tiosemicarbazonas e unha imina, e os seus correspondentes compostos derivados de rutenio. [Fig. Tiosemicarbazona a; Tiosemicarbazona b; Imina c] O tratamento do ligando a con tetraclorobis(p-cimeno)dirutenio(II) e triflato de plata, conduce á obtención do composto de coordinación 1a. En cambio, cos ligandos b e c, non se obtuveron os respectivos compostos de coordinación. [Fig. 1a] Por outro lado, o tratamento do ligando c con tetraclorobis(p-cimeno)dirutenio(II), en presencia dunha base, conduciu á obtención do composto ciclometalado 2c. En cambio, co ligando a non se produciu dita ciclometalación. [Fig. 2c]
[en] Due to the great increase in the use of the sandwich panel in the industry, it is necessary to know its structural behavior, in order to optimize the full potential of this type of structure. It is necessary to characterize the mechanical properties of the materials that make up the sandwich panel. In the present work, a 3-point bending test is carried out to obtain the apparent elastic modulus and the flexural strength according to the UNE-ISO 1209-2: 2007 standard. A sandwich panel test piece is also tested to collect data on its behavior and compare them with the results obtained from the simulation by MEF. At the same time, a fluence fluency test is carried out to determine if this type of structures have fluency. Entrusting this type of tests to external laboratories is very expensive due to the long duration involved. For this reason, a low-cost test is carried out to determine approximately whether creep is important in this type of product.

[gl] Debido ao gran incremento no uso do panel sándwich na industria, é necesario coñecer o seu comportamento estrutural, para obter todo o potencial deste tipo de estruturas. É necesario caracterizar as propiedades mecánicas dos materiais que compoñen o panel sándwich. No presente traballo realízase unha proba de flexión de 3 puntos para obter o módulo elástico aparente e a resistencia á flexión de acordo coa norma UNE-ISO 1209-2: 2007. Tamén se proba unha probeta de panel sándwich para recoller datos sobre o seu comportamento e comparalos cos resultados obtidos da simulación por MEF. Ao mesmo tempo, realízase unha proba de fluencia de fluidez para determinar se este tipo de estruturas teñen fluidez. Confiar este tipo de probas a laboratorios externos é moi caro debido ao longo tempo que implica. Por este motivo, lévase a cabo unha proba de baixo custo para determinar se a fluencia é importante neste tipo de productos.
[en] Introduction: Psoriasis is an inflammatory and chronic skin disease, with a global prevalence between 1% and 3%. The cutaneous presentation of this pathology is characterized by the presence of well-defined erythematodescamative plaques present in the trunk, elbows, knees and scalp and can also affect the skin of the joints and nails. 80% - 90% of patients with psoriasis have involvement in the nails. There are numerous treatments for nail psoriasis among which topical, systemic and non-pharmacological treatments stand out. Objective: this bibliographic review aims to know the effectiveness of topical treatment and phototherapy in the treatment of nail psoriasis. Methodology: A search is carried out in the databases Pubmed, Web Of Science, Scopus, Cochrane Library between the months of May-June of the year 2019. Results: A total of 38 articles were obtained, of which 11 articles were selected that met the inclusion criteria in order to answer the study question. Conclusion: Topical corticosteroid treatment is a safe and effective option for the treatment of nail psoriasis. Although it is necessary to carry out new studies that present good scientific evidence, the results obtained with phototherapy so far have been favorable, and can be considered in the future as an alternative treatment for nail psoriasis.

[gl] Introducción: A psoríase é unha enfermidade inflamatoria e crónica da pel, cunha prevalencia mundial entre o 1% e o 3%. A presentación cutánea desta patoloxía caracterízase pola presenza de placas eritematodescamativas ben definidas presentes no tronco, cóbados, xeonllos e coiro cabeludo e ademáis de afectar a pel, pode afectar as articulacións e as uñas. 80% - 90% dos pacientes con psoríase teñen afectación nas uñas. Hai numerosos tratamentos para a psoríase das uñas entre os que destacan os tratamentos tópicos, sistémicos y non farmacolóxicos. Obxectivo: esta revisión bibliográfica pretende coñecer a eficacia do tratamento tópico e a fototerapia no tratamento da psoríase das uñas. Metodoloxía: realízase unha busca nas bases de datos Pubmed, Web Of Science, Scopus, Biblioteca Cochrane entre os meses de maio a xuño do ano 2019. Resultados: obtivéronse un total de 38 artigos, dos que 11 artigos seleccionáronse xa que cumpriron os criterios de inclusión para responder á pregunta do estudo. Conclusión: O tratamento tópico con corticoides é unha opción segura e eficaz para o tratamento da psoríase das uñas. Aínda que é necesario realizar novos estudos que presenten boas evidencias científicas, os resultados obtidos coa fototerapia ata o de agora foron favorables, e pode considerarse no futuro como un tratamento alternativo para a psoríase das uñas.
[en] Introduction. The possibilities of physical therapy treatment of subacromial impingement syndrome are very wide. Within the field of manual therapy there are numerous techniques used in the approach of myofascial pain syndrome, common in subjects with SIS. Dry needling and pressure release are two widely used techniques. Objective. To verify and compare the efficacy of dry needling and pressure release in the hyperactivity of the upper trapezius through surface electromyography, in patients with subacromial impingement syndrome. Methods. A simple blind randomized clinical trial is proposed. Two groups of 7 subjects obtained from the Quirón Hospital are formed. All subjects will be measured by the electrical activity of the upper (bilateral) trapezius with surface electromyography (sEMG), during the abduction movement in the scapular plane. The sEMG data will be exposed as a percentage of the maximum activation of the trapezius in a test of maximum isometric force at 90° of the scapular abduction. Then they will receive two sessions of one of the two techniques within 8 days. On day 1 the measurements and first session will be carried out, on the 4th day the session and measurements will be repeated and on the 8th day it will be measured for the last time. Also the painful process will be evaluated using an analog visual scale and functionality with a Quick Dash scale.

[gl] Introdución. As posibilidades de tratamento de fisioterapia do síndrome de pinzamento subacromial son moi amplias. Dentro do campo da terapia manual hai moitas técnicas empregadas na abordaxe do síndrome de dor miofascial, común en suxeitos con SIS. A punción seca e a inhibición por presión son dúas técnicas moi empregadas. Obxectivo. Comprobar e comparar a eficacia das técnicas de punción seca e inhibición por presión na hiperactividade do trapecio superior a través de electromiografía de superficie, en pacientes con Síndrome de pinzamento subacromial. Material e método. Plantéxase un ensaio clínico aleatorio simple cego. Formaranse dous grupos de 7 suxeitos obtidos do hospital Quirón. A todos os suxeitos se lles medirá a actividade eléctrica do trapecio superior (bilateral) con electromiografía de superficie, durante o movemento de abducción no plano escapular. Os datos da SEMG estarán expostos coma unha porcentaxe da activación máxima do trapecio nunha proba de forza isométrica máxima a 90° da abducción escapular. Despois recibirán dúas sesións dunha das técnicas nun prazo de 8 días. O día 1 realizaranse as medicións e a primeira sesión, o 4° día repetirase a sesión e as medicións e o 8° día medirase por última vez. A maiores avaliarase o proceso doloroso empregando unha escala visual analóxica e a funcionalidade cunha escala Quick Dash.
[en] Introduction: Spinal cord injury affects all aspects of a person daily life. In ddition, most of the population with spinal cord injury are young-adult, age at which sexual activity is a predominant activity. Objectives: The objectives of the study are to determine the importance f sexual function in people with spinal cord injury; to determine the factors associated with the perceived importance of sexual function, to identify the most important areas of functionality for people with spinal cord injury; and o determine the degree of satisfaction with sexual activity of people with spinal cord injury. Methodology: A quantitative methodology is used, with an analytical, escriptive and cross-sectional design. Data will be collected using three questionnaires for the male population, and four questionnaires for the emale population.

[gl] Introdución: A lesión medular afecta a todos os aspectos da vida diaria dunha persoa. Ademais, a maior parte da poboación con lesión medular atópase en idade nova-adulta, momento no que as relacións sexuais son un tema de carácter principal. Obxectivos: Os obxectivos de estudo son determinar a importancia da función sexual en persoas con lesión medular, determinar os factores asociados á importancia percibida da función sexual, determinar as áreas de funcionalidade ás que as persoas con lesión medular dan máis prioridade e determinar o grao de satisfacción respecto da actividade sexual das persoas con lesión medular. Metodoloxía: Utilizarase unha metodoloxía cuantitativa, con un diseño transversal, descriptivo e analítico, a través da recollida e análise de datos mediante o uso de tres cuestionarios dirixidos á poboación masculina, e catro á poboación femenina.
[en] Isolation and social distancing measures taken to reduce the spread of COVID-19 can cause an increase in feelings of loneliness and problems related to this feeling (anxiety, depression and somatic complaints with no known medical cause), especially in groups of vulnerable population such as institutionalized elderly (1). Objetive: Analyze the relationship between feelings of loneliness and problems related to social distancing and confinement (anxiety, depression and somatic complaints with no known medical cause), to understand the impact on people over 65 years of age residing in social-health centers in the health area of Ferrol. Methodology: A quantitative approach will be used. Several validated scales will be used to analyze risk perception, trust in health and government organizations/sources of information/ identification of contagion prevention measures, know the levels of perception of loneliness and identify the levels of internalizing problems; these will be covered by residents of the social-health centers of the Ferrol health area who meet the inclusion and exclusion criteria.

[gl] As medidas de illamento e distanciamento social adoptadas para reducir a propagación do COVID-19 poden provocar un aumento dos sentimentos de soidade e problemas relacionados con este sentimento (ansiedade, depresión e queixas somáticas sen causa médica coñecida), especialmente en grupos de poboación vulnerables como os anciáns institucionalizados (1). Obxectivo: Analizar a relación entre sentimentos de soidade e problemas relacionados co distanciamento e confinamento social (ansiedade, depresión e queixas somáticas sen causa médica coñecida), para comprender o impacto nas persoas maiores de 65 anos que residen en centros sociosanitarios da área sanitaria de Ferrol. Metodoloxía: Empregarase un enfoque cuantitativo. Usaranse varias escalas validadas para analizar a percepción do risco, a confianza nas organizacións sanitarias/gobernamentais/fontes de información e identificación das medidas de prevención do contaxio, coñecer os niveis de percepción da soidade e identificar os niveis de problemas internalizantes; estas serán cubertas por residentes dos centros sociosanitarios da área sanitaria de Ferrol que cumpran os criterios de inclusión e exclusión.
[en] Lack of competitiveness faced by Spanish economy, as a result of the economic crises, which began in 2008, show specific features caused mainly by the belonging of Spain to an economic monetary area, that is the Euro-Zone. In the context of loss of competitiveness, countries involved in that issue usually to conduct a depreciation policy for the domestic currency, then, it produces an internal lower prices, and as a consequence, a best competitive position at the international scheme. But when the country is within a currency area, as is the Spanish case, it is not possible to carry out depreciation because the country has no such monetary policy tool, and, therefore, other options should be explored. All possible choices are related to internal devaluation. In this paper, a brief theoretical analysis of this situation is undertaken, besides the analysis of those factors influencing international competitiveness. In addition, the measures undertaken by Spain to face an unsustainable falling in national competitiveness have been studied. This study has been complemented by an empirical analysis of the situation prior to the crisis and the evolution of the main macroeconomic variables related to competitiveness, which reflect the situation produced following the adoption of such economic policies, particularly the labour reform and fiscal consolidation. The results show an increase in inequality and impoverishment of the working classes, but on the other hand, the recovery of the competitiveness of the Spanish economy on the international stage was achieved.

[gl] Os problemas de competitividade con que se atopou a economía española como consecuencia da crise comezada en 2008 –tamén coñecida como Gran Recesión– tiveron características específicas, debido, entre outras razóns, á pertenza de España a unha área monetaria como é a unión Económica e Monetaria (uEM) da uE ou Zona Euro. En situacións de perda de competitividade é frecuente que os países recorran a unha depreciación da moeda para se posicionaren fronte ao exterior; porén, se o país se atopa inmerso nunha área monetaria, tal depreciación non é posible por carecer deste instrumento de política monetaria, e debe buscar outras opcións, as cales pasan por unha depreciación interna. Neste traballo acométese unha breve análise teórica desta situación e dos factores que inflúen na competitividade internacional, así como das medidas adoptadas por España para facer fronte a unha situación insustentable de diminución da competitividade nacional. Compleméntase cunha análise empírica da situación antes da crise e da evolución das principais magnitudes macroeconómicas relacionadas coa competitividade, as cales reflicten a situación a que se chegou despois de se adoptaren medidas de política económica, principalmente a reforma laboral e a consolidación fiscal. os resultados amosan un aumento das desigualdades e un empobrecemento das clases traballadoras, malia que España conseguiu recuperar a competitividade no ámbito internacional.
[en] The pseudo-Hildegardian prophecy which begins with the words Insurgent gentes is a well known pamphlet allegedly written in the context of the thirteenth-century antimendicant polemic led by William of Saint-Amour in the Paris University. It has been edited many times, but always in its short version. There is another longer version which has remained unedited until now. Among other differences, this last contains passages which are closely related (in form and meaning) to William of Saint-Amour's works, specially to the Tractatus breuis de periculis nouissimorum temporum and the Collectiones catholice et canonice scripture. This article presents the first edition of the longer version of Insurgent gentes with its translation. The analysis of this version of the prophecy allows us to attribute its authorship to William of Saint-Amour himself and to consider it as the original version.

[gl] A profecía pseudohildegardiana que comeza coas palabras Insurgent gentes é un panfleto ben coñecido supostamente escrito no contexto da polémica antimendicante liderada por Guillermo de Saint-Amour na Universidade de París a mediados do século XIII. Foi editada varias veces, pero sempre nunha versión breve. Existe outra versión, máis longa, que ficou inédita ata agora. Entre outras diferencias, esta última contén pasaxes moi estreitamente relacionados (en forma e contido) coas obras de Guillermo de Saint-Amour, especialmente co Tractatus breuis de periculis nouissimorum temporum e coas Collectiones catholice et canonice scripture. O artigo presenta a primera edición da versión longa da profecía Insurgent gentes acompañada dunha traducción. A análise desta versión da profecía permite atribuír a súa autoría ao propio Guillermo de Saint-Amour, así como considerala a versión orixinal.