# Presentation: 186979

- Chemical Management at
- Sandia National Laboratories/CA
- Mark Brynildson, SNL/CA ES&H
- 5/4/2005

- 5/4/2005

## Chemical Management at 
Sandia National Laboratories/CA

- Mark Brynildson, Ph.D.
- SNL/CA ES&H - Hazardous Materials Management Program

- Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company,for the United States Department of Energy’s National Nuclear Security Administration under contract DE-AC04-94AL85000.

- Chemical Management at
- Sandia National Laboratories/CA

- 5/4/2005

## General nature of SNL/CA lab work
Small scale research and development
Small, laboratory quantities of chemicals
Facilities Designation & Significant Buildings
Protective Action Sectors Map 
CRF (906), 910, 916, MANTL (941, 942, 943), CRADL (968), ESA (981, 982)
CIS – Chemical Information System
Modern application design Web-interface/Oracle database
Corporate application - SNL/NM, SNL/CA & SNL/NV
Corporate MSDS Library ~ 90,000 MSDSs
SNL/CA Chemical Inventory ~ 35,000 barcoded containers
SNL/NM Chemical Inventory ~ 115,000 barcoded containers
Well suited for use with Hazard Survey Requirements

- Small scale research and development
- Small, laboratory quantities of chemicals
- Facilities Designation & Significant Buildings
- Protective Action Sectors Map
- CRF (906), 910, 916, MANTL (941, 942, 943), CRADL (968), ESA (981, 982)
- CIS – Chemical Information System
- Modern application design Web-interface/Oracle database
- Corporate application - SNL/NM, SNL/CA & SNL/NV
- Corporate MSDS Library ~ 90,000 MSDSs
- SNL/CA Chemical Inventory ~ 35,000 barcoded containers
- SNL/NM Chemical Inventory ~ 115,000 barcoded containers
- Well suited for use with Hazard Survey Requirements

- _SNL/CA Hazards Survey Basics_

- 5/4/2005

## Slide 4

- 5/4/2005

## Current six step process:
1. Screen inventory using DOE O 151.1B quantities vs. Site
a. 29 CFR 1910.119 (OSHA PSM) No Site Exceedance
b. 40 CRF 68.130 (CAA RMP) No Site Exceedance
c. 40 CFR 355 (EPCRA EHS) One Site Exceedance
	Sulfuric Acid ~ 1721 lbs. (1000 lbs. EPCRA threshold)
d. 10 CFR 30.72, Schedule C No Site Exceedances
e. 40 CFR 302.4 (CERCLA) 16 Site Exceedances

2. Screen inventory using DOE O 151.1B quantities vs. “Facility” (Sector)
a. 40 CFR 355 (EPCRA EHS) No Sector Exceedance
Sulfuric Acid - maximum single location ~ 527 lbs. 
(well below the 1000 lbs. sector threshold)

- 1. Screen inventory using DOE O 151.1B quantities vs. Site
- a. 29 CFR 1910.119 (OSHA PSM) No Site Exceedance
- b. 40 CRF 68.130 (CAA RMP) No Site Exceedance
- c. 40 CFR 355 (EPCRA EHS) One Site Exceedance
- 	Sulfuric Acid ~ 1721 lbs. (1000 lbs. EPCRA threshold)
- d. 10 CFR 30.72, Schedule C No Site Exceedances
- e. 40 CFR 302.4 (CERCLA) 16 Site Exceedances
- 2. Screen inventory using DOE O 151.1B quantities vs. “Facility” (Sector)
- a. 40 CFR 355 (EPCRA EHS) No Sector Exceedance
- Sulfuric Acid - maximum single location ~ 527 lbs.
- (well below the 1000 lbs. sector threshold)

- _Hazards Screening_

- 5/4/2005

## 3. Use DOE G 151.1-1 criteria for further screening
a. Commonly used by general public
b. Monolithic solids > 100 microns
c. Not a inhalation, ingestion, or dermal hazard
d. Low vapor pressure & >1ppm ERPG-2
e. Laboratory scale, end user quantities
4. Evaluate inventory for hazards mitigation opportunities
5. Evaluate inventory using the Los Alamos EPRG-2 @ 30 meters tables
6. Conduct an Emergency Planning Hazards Assessment

- a. Commonly used by general public
- b. Monolithic solids > 100 microns
- c. Not a inhalation, ingestion, or dermal hazard
- d. Low vapor pressure & >1ppm ERPG-2
- e. Laboratory scale, end user quantities
- 4. Evaluate inventory for hazards mitigation opportunities
- 5. Evaluate inventory using the Los Alamos EPRG-2 @ 30 meters tables
- 6. Conduct an Emergency Planning Hazards Assessment

- _Six Step Process (continued)_

- 5/4/2005

## Screening Step 4 actions;
Regulation Review
CIS Reports Review
Inventory Data Verification
Field Inventory Verification
Material Need Verification
Field Inventory Reduction
Additional Ongoing Surveillance

- Regulation Review
- CIS Reports Review
- Inventory Data Verification
- Field Inventory Verification
- Material Need Verification
- Field Inventory Reduction
- Additional Ongoing Surveillance

- _Potential Exceedance Mitigation_

- 5/4/2005

## Jim Stromberg (Team Leader)
Christy Gilbert
Tammie Muniz
Kyle Hayden
David Hendrickson
Randy Castillo
Sylvia Saltzstein
Mark Brynildson
Susie Orth

- Christy Gilbert
- Tammie Muniz
- Kyle Hayden
- David Hendrickson
- Randy Castillo
- Sylvia Saltzstein
- Mark Brynildson
- Susie Orth

- CIS Redevelopment Core Team

- 5/4/2005

## Chemical Information System Demonstration

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