+--------------------------+-------+------+-------+------+-----+------+
| **Name(s) of Risk Team   | **    | *    | **2** | *    | **  | *    |
| Members:** P. Micca, E.  | Point | *1** |       | *3** | 4** | *5** |
| Whittle, M.Miura, R.     | Value |      |       |      |     |      |
| Colichio, A. Emrick      | →**   |      |       |      |     |      |
|                          |       |      |       |      |     |      |
| Conducted: 9/13/06       | *     |      |       |      |     |      |
|                          | *Para |      |       |      |     |      |
|                          | meter |      |       |      |     |      |
|                          | ↓**   |      |       |      |     |      |
+--------------------------+-------+------+-------+------+-----+------+
| **Job Title: Work with   | **F   | *    | **[\< | *    | **[ | **\> |
| laboratory chemicals**   | reque | *[\< | ]{.un | *[\< | \<] | once |
|                          | ncy** | ]{.u | derli | ]{.u | {.u | /shi |
| **Job Number or Job      |       | nder | ne}on | nder | nde | ft** |
| Identifier:**            | **    | line | ce/mo | line | rli |      |
| **DJ-JRA17**             | (B)** | }onc | nth** | }onc | ne} |      |
|                          |       | e/ye |       | e/we | onc |      |
|                          |       | ar** |       | ek** | e/s |      |
|                          |       |      |       |      | hif |      |
|                          |       |      |       |      | t** |      |
+--------------------------+-------+------+-------+------+-----+------+
| **Job Description:**     | **    | **F  | **Me  | **   | **P | **D  |
| Working with hazardous   | Sever | irst | dical | Lost | art | eath |
| chemicals in the         | ity** | Aid  | T     | Ti   | ial | or   |
| following hazard         |       | On   | reatm | me** | Dis | P    |
| classes: Carcinogens,    | **    | ly** | ent** |      | abi | erma |
| Highly Acute Toxin,      | (C)** |      |       |      | lit | nent |
| Reproductive Toxins,     |       |      |       |      | y** | Disa |
| Corrosives, Strong       |       |      |       |      |     | bili |
| Oxidizers, Highly        |       |      |       |      |     | ty** |
| Reactive Materials,      |       |      |       |      |     |      |
| Peroxide forming         |       |      |       |      |     |      |
| chemicals, Pyrophoric    |       |      |       |      |     |      |
| Materials,               |       |      |       |      |     |      |
| Flammables/Combustible   |       |      |       |      |     |      |
| Materials and working    |       |      |       |      |     |      |
| with sharps              |       |      |       |      |     |      |
+--------------------------+-------+------+-------+------+-----+------+
|                          | **Li  | **E  | **    | **Po | **P | **Mu |
|                          | kelih | xtre | Unlik | ssib | rob | ltip |
|                          | ood** | mely | ely** | le** | abl | le** |
|                          |       | Un   |       |      | e** |      |
|                          | **    | like | 1     | \    |     | \>1  |
|                          | (D)** | ly** | x/10- | >1x/ | 1x  | x/yr |
|                          |       |      | 20yrs | 10-2 | /yr |      |
|                          |       | \<\< |       | 0yrs |     |      |
|                          |       | 1x/2 |       |      |     |      |
|                          |       | 0yrs |       |      |     |      |
+--------------------------+-------+------+-------+------+-----+------+
| Training and Procedure   |       |      |       |      |     |      |
| List (Optional):         |       |      |       |      |     |      |
| Laboratory Standard      |       |      |       |      |     |      |
+--------------------------+-------+------+-------+------+-----+------+
| Approved by: R. Colichio |       |      |       |      |     |      |
| Date:9/30/06             |       |      |       |      |     |      |
|                          |       |      |       |      |     |      |
| Rev. #:                  |       |      |       |      |     |      |
+--------------------------+-------+------+-------+------+-----+------+
| **Stressors (if          |       | **Re |       |      | *   |      |
| applicable, please list  |       | ason |       |      | *Co |      |
| all):**                  |       | for  |       |      | mme |      |
|                          |       | Revi |       |      | nts |      |
|                          |       | sion |       |      | :** |      |
|                          |       | (if  |       |      |     |      |
|                          |       | ap   |       |      |     |      |
|                          |       | plic |       |      |     |      |
|                          |       | able |       |      |     |      |
|                          |       | ):** |       |      |     |      |
+--------------------------+-------+------+-------+------+-----+------+

<table style="width:100%;">
<colgroup>
<col style="width: 11%" />
<col style="width: 0%" />
<col style="width: 14%" />
<col style="width: 1%" />
<col style="width: 1%" />
<col style="width: 2%" />
<col style="width: 2%" />
<col style="width: 2%" />
<col style="width: 2%" />
<col style="width: 4%" />
<col style="width: 1%" />
<col style="width: 14%" />
<col style="width: 1%" />
<col style="width: 1%" />
<col style="width: 1%" />
<col style="width: 2%" />
<col style="width: 2%" />
<col style="width: 4%" />
<col style="width: 4%" />
<col style="width: 4%" />
<col style="width: 2%" />
<col style="width: 2%" />
<col style="width: 2%" />
<col style="width: 2%" />
<col style="width: 3%" />
<col style="width: 3%" />
</colgroup>
<thead>
<tr class="header">
<th colspan="3"></th>
<th colspan="7"><strong>Before Controls</strong></th>
<th colspan="2"></th>
<th colspan="6"><p><strong>After Initial</strong></p>
<p><strong>Controls</strong></p></th>
<th colspan="2"></th>
<th colspan="6"><strong>After Additional Controls</strong></th>
</tr>
<tr class="odd">
<th colspan="2"><strong>Job Step / Task</strong></th>
<th><strong>Hazard</strong></th>
<th colspan="2"><blockquote>
<p><strong>Stressors Y/N</strong></p>
</blockquote></th>
<th><blockquote>
<p><strong># of People A</strong></p>
</blockquote></th>
<th><blockquote>
<p><strong>Frequency B</strong></p>
<p><strong>A</strong></p>
</blockquote></th>
<th><blockquote>
<p><strong>Severity C</strong></p>
</blockquote></th>
<th><blockquote>
<p><strong>Likelihood D</strong></p>
</blockquote></th>
<th><blockquote>
<p><strong>Risk* AxBxCxD</strong></p>
</blockquote></th>
<th colspan="2"><h1 id="initial-controls">Initial Controls</h1></th>
<th><blockquote>
<p><strong># of People A</strong></p>
</blockquote></th>
<th colspan="2"><blockquote>
<p><strong>Frequency B</strong></p>
</blockquote></th>
<th><blockquote>
<p><strong>Severity C</strong></p>
</blockquote></th>
<th><blockquote>
<p><strong>Likelihood D</strong></p>
</blockquote></th>
<th><blockquote>
<p><strong>Risk* AxBxCxD</strong></p>
</blockquote></th>
<th colspan="2"><strong>Control(s) Added to Reduce Risk</strong></th>
<th><blockquote>
<p><strong># of People A</strong></p>
</blockquote></th>
<th><blockquote>
<p><strong>Frequency B</strong></p>
</blockquote></th>
<th><blockquote>
<p><strong>Severity C</strong></p>
</blockquote></th>
<th><blockquote>
<p><strong>Likelihood D</strong></p>
</blockquote></th>
<th><blockquote>
<p><strong>Risk* AxBxCxD</strong></p>
</blockquote></th>
<th><blockquote>
<p><strong>% Risk Reduction</strong></p>
</blockquote></th>
</tr>
</thead>
<tbody>
<tr class="odd">
<td colspan="2">Storing containers of hazardous materials</td>
<td><strong>SPILL</strong>: due to container failure may result in
explosion or fire from flammable/combustible materials coming in contact
with an ignition source or chemical reaction</td>
<td colspan="2">N</td>
<td>1</td>
<td>5</td>
<td>5</td>
<td>4</td>
<td>100</td>
<td colspan="2">Segregation of incompatibles, chemical storage cabinets,
PPE, work planning/experimental review, ventilation, secondary
containment, spill response, use of safer substitutes, Tier 1
inspections, container labeling, area posting, shelf-life monitoring,
containers specific for the hazard and operation, training, applicable
subject areas</td>
<td>1</td>
<td colspan="2">5</td>
<td>3</td>
<td>2</td>
<td>30</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="even">
<td colspan="2"></td>
<td><strong>SPILL</strong>: due to container failure may result in
exposure to toxic materials or corrosive splash</td>
<td colspan="2">N</td>
<td>1</td>
<td>5</td>
<td>5</td>
<td>4</td>
<td>100</td>
<td colspan="2">chemical storage cabinets, work planning/experimental
review, ventilation, secondary containment, use of safer substitutes,
Tier 1 inspections, container labeling, area posting, shelf-life
monitoring, containers specific for the hazard and operation, training,
applicable subject areas, PPE</td>
<td>1</td>
<td colspan="2">5</td>
<td>3</td>
<td>2</td>
<td>30</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="odd">
<td colspan="2"></td>
<td><strong>Reaction:</strong> Chemical reaction of hazardous materials
stored in a refrigerator during a power failure</td>
<td colspan="2">N</td>
<td>1</td>
<td>1</td>
<td>4</td>
<td>3</td>
<td>12</td>
<td colspan="2">Emergency power generator, work planning/experimental
review, use of safer substitutes, Tier 1 inspections, container
labeling, area posting, shelf-life monitoring, containers specific for
the hazard and operation, training, applicable subject areas, PPE,
secondary containment</td>
<td>1</td>
<td colspan="2">1</td>
<td>3</td>
<td>2</td>
<td>6</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="even">
<td colspan="2">Moving containers within the department</td>
<td><strong>SPILL</strong>: due to dropping container may result in
explosion or fire from flammable/combustible materials coming in contact
with an ignition source</td>
<td colspan="2">N</td>
<td>1</td>
<td>5</td>
<td>4</td>
<td>3</td>
<td>60</td>
<td colspan="2">work planning/experimental review, spill response, Tier
1 inspections, container labeling, containers specific for the hazard
and operation, training, applicable subject areas, secondary
containment</td>
<td>1</td>
<td colspan="2">5</td>
<td>3</td>
<td>2</td>
<td>30</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="odd">
<td colspan="2"></td>
<td><strong>SPILL</strong>: due to dropping container may result in
exposure to toxic materials or corrosive splash</td>
<td colspan="2">N</td>
<td>1</td>
<td>5</td>
<td>4</td>
<td>3</td>
<td>60</td>
<td colspan="2">work planning/experimental review, PPE, spill response,
Tier 1 inspections, container labeling, containers specific for the
hazard and operation, training, applicable subject areas, secondary
containment</td>
<td>1</td>
<td colspan="2">5</td>
<td>3</td>
<td>2</td>
<td>30</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="even">
<td colspan="2">Measuring chemicals- pipeting, preparing sample cells,
etc.</td>
<td><strong>SPILL</strong>: due to dropping container may result in
explosion or fire from flammable/combustible materials coming in contact
with an ignition source</td>
<td colspan="2">N</td>
<td>1</td>
<td>5</td>
<td>4</td>
<td>3</td>
<td>60</td>
<td colspan="2">spill pads, work planning/experimental review, PPE, use
of small volumes, fume hood, secondary containment, spill response, use
of safer substitutes, Tier 1 inspections, container labeling, area
posting, containers specific for the hazard and operation, applicable
subject areas, safety showers, eyewashes</td>
<td>1</td>
<td colspan="2">5</td>
<td>3</td>
<td>2</td>
<td>30</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="odd">
<td colspan="2"></td>
<td><strong>SPILL</strong>: due to dropping container may result in
exposure to toxic materials or corrosive splash</td>
<td colspan="2">N</td>
<td>1</td>
<td>5</td>
<td>4</td>
<td>3</td>
<td>60</td>
<td colspan="2">spill pads, work planning/experimental review, PPE, use
of small volumes, fume hood, secondary containment, spill response, use
of safer substitutes, Tier 1 inspections, container labeling, area
posting, containers specific for the hazard and operation, applicable
subject areas, safety showers, eyewashes</td>
<td>1</td>
<td colspan="2">5</td>
<td>3</td>
<td>2</td>
<td>30</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="even">
<td colspan="2"></td>
<td><strong>GENERAL USE</strong>: Exposure to toxic materials including
inhalation, absorption, ingestion and injection</td>
<td colspan="2">N</td>
<td>1</td>
<td>4</td>
<td>4</td>
<td>5</td>
<td>80</td>
<td colspan="2">work planning/experimental review, PPE, use of small
volumes, fume hood, use of safer substitutes, container labeling, area
posting, applicable subject areas, area and/or personnel monitoring,
eng. Controls- safety showers, eyewashes</td>
<td>1</td>
<td colspan="2">5</td>
<td>3</td>
<td>2</td>
<td>30</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="odd">
<td colspan="2">Mixing and reacting hazardous materials</td>
<td><strong>SPILL</strong>: due to dropping container may result in
explosion or fire from flammable/combustible materials coming in contact
with an ignition source</td>
<td colspan="2">Y</td>
<td>1</td>
<td>4</td>
<td>3</td>
<td>4</td>
<td>48</td>
<td colspan="2">spill pads, work planning/experimental review, PPE, use
of small volumes, fume hood, secondary containment, training, spill
response, use of safer substitutes, Tier 1 inspections, container
labeling, area posting, containers specific for the hazard and
operation, applicable subject areas, secondary containment, safety
showers, eyewashes</td>
<td>1</td>
<td colspan="2">4</td>
<td>2</td>
<td>3</td>
<td>24</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="even">
<td colspan="2"></td>
<td><strong>SPILL</strong>: due to dropping container may result in
exposure to toxic materials or corrosive splash</td>
<td colspan="2">N</td>
<td>1</td>
<td>4</td>
<td>4</td>
<td>5</td>
<td>80</td>
<td colspan="2">spill pads, work planning/experimental review, PPE, use
of small volumes, fume hood, secondary containment, spill response, use
of safer substitutes, Tier 1 inspections, container labeling, area
posting, containers specific for the hazard and operation, applicable
subject areas, safety showers, eyewashes</td>
<td>1</td>
<td colspan="2">4</td>
<td>3</td>
<td>2</td>
<td>24</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="odd">
<td colspan="2"></td>
<td><strong>General Use</strong>: Exposure to toxic materials including
inhalation, absorption, ingestion and injection</td>
<td colspan="2">Y</td>
<td>1</td>
<td>4</td>
<td>3</td>
<td>4</td>
<td>48</td>
<td colspan="2">work planning/experimental review, training, PPE, use of
small volumes, fume hood, use of safer substitutes, container labeling,
area posting, applicable subject areas, area and/or personnel
monitoring, safety showers, eyewashes</td>
<td>1</td>
<td colspan="2">4</td>
<td>2</td>
<td>3</td>
<td>24</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="even">
<td colspan="2"></td>
<td>Exothermic reaction (pressure/heat—solution bubbles out)</td>
<td colspan="2">Y</td>
<td>1</td>
<td>2</td>
<td>4</td>
<td>5</td>
<td>40</td>
<td colspan="2">work planning/experimental review, PPE, use of small
volumes, use of safer substitutes, container labeling, area posting,
reactions vessels specific for the hazard, applicable subject areas,
safety showers, eyewashes</td>
<td>1</td>
<td colspan="2">2</td>
<td>4</td>
<td>2</td>
<td>16</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="odd">
<td colspan="2">Working with peroxide forming compounds</td>
<td>Rupture of container, exposure to vapors, explosion</td>
<td colspan="2">N</td>
<td>1</td>
<td>3</td>
<td>4</td>
<td>4</td>
<td>48</td>
<td colspan="2">Periodic testing as per SBMS<em><strong>,</strong></em>
CMS, work planning/experimental review, PPE, use of small volumes,
secondary containment, spill response, use of safer substitutes, Tier 1
inspections, container labeling, containers specific for the hazard and
operation, applicable subject areas, safety showers, eyewashes</td>
<td>1</td>
<td colspan="2">3</td>
<td>4</td>
<td>2</td>
<td>24</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="even">
<td colspan="2">Working with pyrophoric compounds</td>
<td>Rupture of container, exposure to vapors, dust, mists, fire
resulting from loss of inerting atmosphere</td>
<td colspan="2">Y</td>
<td>1</td>
<td>1</td>
<td>2</td>
<td>5</td>
<td>10</td>
<td colspan="2">Applicable subject areas, work planning/experimental
review, PPE, use of small volumes, secondary containment, spill
response, use of safer substitutes, Tier 1 inspections, container
labeling, containers specific for the hazard and operation</td>
<td>1</td>
<td colspan="2">1</td>
<td>2</td>
<td>3</td>
<td>6</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="odd">
<td colspan="2">Working with sensitizers, acute toxins, carcinogens
&amp; reproductive toxins</td>
<td>Exposure to vapors, dust, mists, fumes, fire</td>
<td colspan="2">Y</td>
<td>1</td>
<td>4</td>
<td>5</td>
<td>3</td>
<td>60</td>
<td colspan="2">Applicable subject areas, work planning/experimental
review, PPE, area monitoring, personnel monitoring, use of small
volumes, secondary containment, spill response, use of safer
substitutes, Tier 1 inspections, container labeling, area posting,
containers specific for the hazard and operation, fume hood</td>
<td>1</td>
<td colspan="2">4</td>
<td>1</td>
<td>2</td>
<td>8</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="even">
<td colspan="2">Working with flammables and combustible materials</td>
<td>Exposure to vapors, dust, mists, fumes, fire</td>
<td colspan="2">Y</td>
<td>1</td>
<td>5</td>
<td>3</td>
<td>3</td>
<td>45</td>
<td colspan="2">Applicable subject areas, work planning/experimental
review, PPE, area monitoring, personnel monitoring, use of small
volumes, secondary containment, spill response, use of safer
substitutes, Tier 1 inspections, container labeling, area posting,
containers specific for the hazard and operation, fume hood</td>
<td>1</td>
<td colspan="2">5</td>
<td>3</td>
<td>2</td>
<td>30</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="odd">
<td colspan="2">Working with corrosives, strong oxidizers, highly
reactive materials</td>
<td>Exposure to vapors, dust, mists, fumes, fire</td>
<td colspan="2">Y</td>
<td>1</td>
<td>5</td>
<td>3</td>
<td>3</td>
<td>45</td>
<td colspan="2">applicable subject areas, work planning/experimental
review, PPE, area monitoring, personnel monitoring, use of small
volumes, secondary containment, spill response, use of safer
substitutes, Tier 1 inspections, container labeling, area posting,
containers specific for the hazard and operation, fume hood</td>
<td>1</td>
<td colspan="2">5</td>
<td>3</td>
<td>2</td>
<td>30</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="even">
<td colspan="2">Use of sharps</td>
<td>Cuts, puncture wounds, exposure to hazardous materials</td>
<td colspan="2">N</td>
<td>1</td>
<td>5</td>
<td>2</td>
<td>3</td>
<td>30</td>
<td colspan="2">Sharp containers, area posting, tier I, applicable
subject areas, work planning/experimental review</td>
<td>1</td>
<td colspan="2">5</td>
<td>2</td>
<td>2</td>
<td>30</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="odd">
<td colspan="2">Transporting of chemicals</td>
<td>See Transporting Hazardous Materials JRA</td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td colspan="2"></td>
<td></td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td colspan="2"></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
<td></td>
</tr>
<tr class="even">
<td colspan="25"><p><strong>Further Description of Controls Added to
Reduce Risk:</strong></p>
<p>Recommendation to post chemical storage areas with a common
incompatibles list (does not have to be all inclusive)</p></td>
<td></td>
</tr>
<tr class="odd">
<td><strong>*Risk:</strong></td>
<td colspan="3"><p><strong>0 to 20</strong></p>
<p><strong>Negligible</strong></p></td>
<td colspan="7"><p><strong>21 to 40</strong></p>
<p><strong>Acceptable</strong></p></td>
<td colspan="3"><p><strong>41-60</strong></p>
<p><strong>Moderate</strong></p></td>
<td colspan="5"><p><strong>61 to 80</strong></p>
<p><strong>Substantial</strong></p></td>
<td colspan="6"><p><strong>81 or greater</strong></p>
<p><strong>Intolerable</strong></p></td>
<td></td>
</tr>
</tbody>
</table>