Exploring for the Future – Baseline whole rock geochemistry of Northern Australia Data Release — Geochemistry of drill core samples from the McArthur Basin, Lawn Hill platform and Tomkinson Province, Northern Territory and Queensland

The Exploring for the Future program is an initiative by the Australian Government dedicated to boosting investment in resource exploration in Northern Australia. The Paleo- to Mesoproterozoic sedimentary and volcanic sequences of the Mount Isa–McArthur Basin region of Northern Territory and Queensland are host to a range of world class mineral deposits (Hutton et al., 2012) and include the basin-hosted base metal deposits of the North Australian Zinc Belt, the world’s richest belt of zinc deposits (Huston et al., 2006; Large et al., 2005). The region demonstrably has potential for additional world class mineral systems (Hutton et al. 2012), as well as potential to host shale gas plays (Gorton &amp; Troup, 2018). An improved understanding of the chemistry of the host sedimentary units, including associated volcanic and intrusive rocks (potential metal source rocks) within these regions is therefore an important requisite to further understand the resource potential of the region. To assist in this we have undertaken a multi-year campaign (2016-2019) of regional geochemical sampling of geological units in the southeastern McArthur Basin, it’s continuation into the Tomkinson Province, and the Lawn Hill Platform regions of Northern Territory and northwest Queensland. Chief aims of the project were to characterise, as much as possible, the inorganic geochemistry of units of the Paleoproterozoic Tawallah, McArthur, Fickling and McNamara Groups and the Mesoproterozoic Roper and South Nicholson groups, with most emphasis on the Tawallah, McNamara and Fickling Groups. Minimal attention was paid to units of the McArthur Group which have been extensively previously sampled. The project also involved exploratory geochemical characterisation of sedimentary and igneous rocks from Paleoproterozoic and Mesoproterozoic rocks of the Tomkinson Province (Tomkinson, Namerinni and Renner groups) in Northern Territory.  Minimal regional geochemical data exists for these rocks which are considered time equivalents of the Tawallah, McArthur, Nathan and Roper groups.
The approach followed was based on targeting as many units as possible from drill core held within the core repository facilities of the Northern Territory and Queensland Geological surveys. Sampling strategy for individual units was based on targeting all lithological variability with particular emphasis on units not previously extensively sampled. Units were sampled at moderate to high resolution, with sampling density ranging from one sample per ~10 m intervals in organic rich intervals or lithological variable units, up to one sample per 20 to 50 m intervals in lithologically-monotonous units or in units recently sampled recently by GA or others. 
This data release contains the results of elemental analyses (XRF, ICP-MS), ferrous iron oxide content (FeO) and Loss-on-ignition (LOI) on 805 samples selected from 42 drill cores housed in the Geological Survey of Northern Territory’s Darwin and Alice Springs core repositories and in the Geological Survey of Queensland’s Brisbane and Mount Isa core repositories. Drillholes sampled include the Amoco holes DDH 83-1, DDH 83-2, DDH 83-3, DDH 83-4, and DDH 83-5, as well as 14MCDDH001, 14MCDDH002, 87CIIDH1, 87CIIDH2, Bradley 1, Broughton 1, DD81CY1, DD91RC18, DD91DC1, DD91HC1, DD95GC001, GCD-1, GCD-2A, GSQ Lawn Hill 3, GSQ Lawn Hill 4, GSQ Westmoreland 2, MWSD05, ND1, ND2, 12BC001, and Willieray (1DD, 3DD, 8DD), Hunter (1DD, 2DD, 3DD) and HSD001, HSD002 holes from the Tomkinson Province. The data also include a small number of non-basin samples (from drill holes AAI POTALLAH CREEK 1, ADRIA DOWNS 1, Bradley 1, GSQ Normanton 1, GSQ Rutland Plains 1, MULDDH001 and MURD013), collected at the same time, largely for isotopic studies. The resultant geochemical data was largely generated at the Inorganic Geochemistry Laboratory at Geoscience Australia (509 of the 805 analyses), with two batches (296 samples) analysed by Bureau Veritas in Perth. Eighteen samples analysed at GA were also reanalysed at Bureau Veritas for QA/QC purposes. All data was collected as part of the Exploring for the Future program. 
The report also includes a statistical treatment of the geochemical data looking at laboratory performance, based on certified reference material (CRMs) and sample duplicates, and interlaboratory agreement, based on samples analysed at both laboratories. Results show accuracies were within acceptable tolerances (±2 SD) for the majority of major and trace elements analysed at both laboratories. Notable exceptions included significant negative bias for Fe2O3 and positive bias for Na2O at Geoscience Australia. The results also showed that Mo (and As and Be) measurements were a consistent problem at GA, and Zn a consistent problem at BV.  Precision (reproducibility) for major elements at both laboratories was very good, generally between 1 to 5%. Precisions for trace elements, varied from generally 5% or better at Geoscience Australia, and mostly between 5 and 10% for Bureau Veritas. Importantly, agreement between laboratories was good, with the majority of elements falling within ±5% agreement, and a few within 5-10% (Th, Tb, Sr, Zn, Ta, and Cr). Major exceptions to this included Na2O, K2O, Rb, Ba and Cs, as well as P2O5 and SO3, as well as those trace elements commonly present in low concentrations (e.g., Cu, As, Be, Mo, Sb, Ge, Bi). The mismatch between the alkalis is notable and of concern, with differences (based on median values) of 17% and 22% for K2O and Ba (higher at Bureau Veritas) and 32% and 300% for Ba and Na2O (higher at Geoscience Australia). 
The geochemical data presented here have formed the basis for ongoing studies into aspects of basin-hosted mineral systems in the McArthur–Mount Isa region, including insights into sources of metals for such deposits and delineating alteration haloes around those deposits (Champion et al., 2020a, b).

Tags: ANALYTICAL CHEMISTRY, EARTH SCIENCES, EFTF, Exploring for the Future, GEOCHEMISTRY, Published_External, Quality Assurance, Chemometrics, Traceability and Metrological Chemistry
Organization: Geoscience Australia Data