Patent ID: 9677092
Date: 2017-06-13
CPC Classifications: C12P,Y02E,Y02P

Claim:
1. A continuous process for the anaerobic bioconversion of a gas substrate comprising carbon monoxide, hydrogen and carbon dioxide in an aqueous menstruum containing microorganisms suitable for converting said substrate to an alcohol, that comprises: a. steam reforming hydrocarbonaceous feedstock to provide a syngas having an electron to carbon ratio greater than about 7:1, said steam reforming being performed in a steam reformer having at least one gas reforming section and at least one hotbox section; b. continuously introducing into a bioreactor assembly, said syngas and biogas, said biogas comprising at least about 20 or 25 mole percent carbon dioxide and at least about 40 mole percent methane, said biogas having an electron to carbon ratio not greater than about 0.1:1 to provide an overall gas substrate having an electron to carbon ratio in the range of about 5.2:1 to 6.8:1; c. continuously contacting said syngas and said biogas with said aqueous menstruum to bioconvert substrate gas to alcohol and providing an alcohol-containing menstruum and a substrate depleted gas phase, said contacting being in a bioreactor assembly containing said menstruum; d. continuously withdrawing substrate depleted gas phase from said aqueous menstruum, said depleted gas phase having a lower mole ratio of carbon dioxide to methane than that of the overall gas substrate; e. passing at least a portion of the depleted gas phase to the steam reformer of step (a); and f. continuously or intermittently withdrawing a portion of said menstruum for recovery of said alcohol, said withdrawal being sufficient to maintain the alcohol in said menstruum below a concentration that unduly adversely affects the microorganisms.