Clue: Starters from Tijuana a connois­seur of chilli's taken with it­ (4,4)
Answer: TACO CHIP
Explanation: Definition: Starters from Tijuana a connois­seur of chilli's taken with it­
A charade of TACOC ('starters from **T**ijuana **A** **C**onnoisseur **O**f **C**hilli') plus HIP ('with it'), with a slightly tortuous &lit definition.