Patent ID: 11939336
Assignee: INDIANA UNIVERSITY RESEARCH AND TECHNOLOGY CORPORATION
Field: Chemical engineering (Chemistry)
Classification: CPC C  B | IPC B  C

Claim 37:
38. A composition comprising a metal surface and a coating, wherein the coating comprises an aryl-triazole bicyclic macrocycle selected from the group consisting of Formulas (I), (III), (IV), (V), (VI) and (VII):, wherein for (I), R1, R2, and R3 are independently selected from the group consisting of alkenyl, alkyl, alkoxy, alkyl-NH-alkyl, aryl, cycloalkyl, heteroaryl, heterocycle, haloalkyl, hydrogen, iodo, —OR4, —N(R5R6), —CO2R7, —C(O)—N(R8R9), wherein R4, R5, R6, R7, R8, and R9 are each independently selected from the group consisting of alkenyl, alkyl, aryl, arylalkyl, cycloalkyl, heteroaryl, heterocycle, haloalkyl, and hydrogen,
wherein for (III), X is independently selected from the group consisting of CH, CF and N, and R1, R2, and R3 are independently selected from the group consisting of alkenyl, alkyl, alkoxy, alkyl-NH-alkyl, aryl, cycloalkyl, heteroaryl, heterocycle, haloalkyl, hydrogen, iodo, —OR4, —N(R5R6), —CO2R7, —C(O)—N(R8R9), wherein R4, R5, R6, R7, R8, and R9 are each independently selected from the group consisting of alkenyl, alkyl, aryl, arylalkyl, cycloalkyl, heteroaryl, heterocycle, haloalkyl, and hydrogen,
wherein for (IV), n=1 to 10, and R1 and R2 are independently selected from the group consisting of alkenyl, alkyl, alkoxy, alkyl-NH-alkyl, aryl, cycloalkyl, heteroaryl, heterocycle, haloalkyl, hydrogen, iodo, —OR3, —N(R4R5), —CO2R6, —C(O) N(R7R8), wherein R3, R4, R5, R6, R7, and R8 are each independently selected from the group consisting of alkenyl, alkyl, aryl, arylalkyl, cycloalkyl, heteroaryl, heterocycle, haloalkyl, and hydrogen,
wherein for (V), X and Y are independently selected from the group consisting of CH, CF and N, and R1, R2, R4, R5, R6 and R7 are independently selected from the group consisting of alkenyl, alkyl, alkoxy, alkyl-NH-alkyl, aryl, cycloalkyl, heteroaryl, heterocycle, haloalkyl, hydrogen, iodo, —OR8, —N(R9R10), —CO2R11, —C(O)—N(R12R13), wherein R1, R9, R10, R11, R12 and R13 are each independently selected from the group consisting of alkenyl, alkyl, aryl, arylalkyl, cycloalkyl, heteroaryl, heterocycle, haloalkyl, and hydrogen,
wherein for (VI), R1, R2, and R3 are independently selected from the group consisting of alkenyl, alkyl, alkoxy, alkyl-NH-alkyl, aryl, cycloalkyl, heteroaryl, heterocycle, haloalkyl, hydrogen, iodo, —OR4, —N(R5R6), —CO2R7, —C(O)—N(R8R9), wherein R4, R5, R6, R7, R8, and R9 are each independently selected from the group consisting of alkenyl, alkyl, aryl, arylalkyl, cycloalkyl, heteroaryl, heterocycle, haloalkyl, and hydrogen,
wherein for (VII), n=1 to 4, and R1 and R2 are independently selected from the group consisting of alkenyl, alkyl, alkoxy, alkyl-NH-alkyl, aryl, cycloalkyl, heteroaryl, heterocycle, haloalkyl, hydrogen, iodo, —OR3, —N(R4R5), —CO2R6, —C(O) N(R7R8), wherein R3, R4, R5, R6, R7, and R8 are each independently selected from the group consisting of alkenyl, alkyl, aryl, arylalkyl, cycloalkyl, heteroaryl, heterocycle, haloalkyl, and hydrogen.