Patent ID: 11932586
Assignee: CHINA UNIVERSITY OF MINING AND TECHNOLOGY
Field: Basic materials chemistry (Chemistry)
Classification: CPC C | IPC C

Claim 0:
1. A liquid explosive for in-situ explosive fracturing in low-permeability oilfields, comprising raw materials in parts by mass: 83.6-140 parts of a main explosive with positive oxygen balance, 3.5-7 parts of a guest regulator, and 31-50 parts of isolation microcapsules;
according to parts by mass, raw materials of the main explosive with the positive oxygen balance comprise: 1-5 parts of monomethylamine nitrate, 50-64 parts of ammonium nitrate, 1-9 parts of sodium nitrate, 10-20 parts of water, 0.5-1.5 parts of guar gum, 0.1-0.5 part of sodium nitrite, 1-5 parts of a high-temperature resistant regulator with a low detonation velocity and 20-35 parts of a surfactant;
according to parts by mass, raw materials of the guest regulator comprise: 2-5 parts of a reducing agent and 1.5-2 parts of a density regulator;
according to parts by mass, raw materials of the isolation microcapsules comprise: 15-25 parts of porous hollow microbeads, 8-15 parts of a pore plugging agent and 8-10 parts of wall materials of pressure-resistant microcapsules;
the guest regulator exists in the porous hollow microbeads of the isolation microcapsules;
the high-temperature resistant regulator with the low detonation velocity is one or more of sodium sulfate, sodium bisulfate, sodium phosphate, sodium hydrogen phosphate, sodium dihydrogen phosphate, sodium bicarbonate, sodium carbonate, calcium oxalate, sodium oxalate, calcium carbonate and sodium chloride;
the surfactant is a polyoxyethylene, alkanolamide or amine oxide surfactant;
the reducing agent is flammable alcohol; and the density regulator is an acidic solution;
the flammable alcohol is glycerol or ethanol; the acidic solution is citric acid or acetic acid; and
the porous hollow microbeads are obtained by perforating floating beads; and the pore plugging agent is a colloidal solution made of gelatin powder, agar or sodium alginate.