Patent ID: 11884632
Assignee: ZHEJIANG HENGYI PETROCHEMICAL RESEARCH INSTITUTE CO., LTD.
Field: Chemical engineering (Chemistry)
Classification: CPC C  B  Y | IPC B  C

Claim 0:
1. A method for preparing caprolactam comprising the following steps:
(1) contacting cyclohexanone oxime with a catalyst to carry out reaction in the presence of ethanol and under the condition of gas phase Beckmann rearrangement reaction of cyclohexanone oxime;
(2) separating the reaction product obtained in step (1) to produce an ethanol solution of crude caprolactam, and then separating the ethanol solution of crude caprolactam to obtain ethanol and crude caprolactam;
(3) removing impurities with boiling points lower than that of caprolactam in the crude caprolactam to obtain a light component removal product;
(4) mixing the light component removal product with a crystallization solvent to carry out crystallization and solid-liquid separation to obtain a crystalline crystal; and
(5) subjecting the crystalline crystal to a hydrogenation reaction;
wherein the crystallization solvent contains 0.1-2 wt % of ethanol.