Patent ID: 11952395
Assignee: THE FLORIDA INTERNATIONAL UNIVERSITY BOARD OF TRUSTEES
Field: Organic fine chemistry (Chemistry)
Classification: CPC C | IPC C

Claim 0:
1. A complex having a general structure of formula (I):, wherein
E is NR″, or S;
X is selected from halogens, alkoxides, thioalkoxides, and sulfonates;
R and R′ are each independently selected from hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, heterocycles, substituted heterocycles, —ORa, —Si(Rb)3 and RcRd, wherein Ra, Rb, Rc and Rd are independently selected from hydrogen, alkyl, substituted alkyl, aryl, and substituted aryl;
R″ is selected from hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, heterocycles, and substituted heterocycles; and
L1 and/or L2 are:
(1) NHCs selected from, wherein R4 and R5 are independently selected from hydrogen, alkyl, substituted alkyl, cycloalkyl, substituted cycloalkyl, aryl and substituted aryl;
(2) pyridines having a structure of, wherein R6, R7, R8, R9, R10 are each independently selected from hydrogen, halogens, alkyl, substituted alkyl, hydorxyl, acyl, and —NH2; or
(3) nitriles selected from, wherein R6, R7, R8, R9, R10 are each independently selected from hydrogen, halogens, alkyl, substituted alkyl, hydorxyl, acyl, and —NH2.