Patent ID: 11970662
Assignee: RICOH COMPANY, LTD.
Field: Organic fine chemistry (Chemistry)
Classification: CPC C  G | IPC C  G

Claim 11:
12. An electrochromic element comprising:
a first electrode;
a second electrode disposed to face the first electrode with a gap between the first electrode and the second electrode;
a first electrochromic layer disposed on or above the first electrode, where the first electrochromic layer includes conductor or semiconductor nano-structures and an electrochromic compound;
a second electrochromic layer disposed on or above the second electrode, where the second electrochromic layer includes triarylamine, or tetraarylbendizine, or a mixture of triarylamine and tetraarylbenzidine; and
an electrolyte layer including an electrolyte, disposed between the first electrochromic layer and the second electrode,
wherein the electrochromic compound is a compound represented by General Formula 1, and an anion of the electrolyte is a monovalent anion having an oxidation potential higher than a reduction potential of a dication of General Formula 1 by 3.1 V or greater,, , where, in General Formula 1, R1 and R2 are each a hydrogen atom, an aryl group having 14 or less carbon atoms, a heteroaryl group having 14 or less carbon atoms, a branched alkyl group having 10 or less carbon atoms, an alkenyl group having 10 or less carbon atoms, a cycloalkyl group having 10 or less carbon atoms, a phosphonic acid group, a phosphoric acid group, a carboxylic acid group, a sulfonyl group, a silyl group, or a silanol group; R3 and R4 are each an alkylene group having from 1 through 10 carbon atoms or an arylene group that may have a substituent and has 12 or less carbon atoms; Z is alkylene, cycloalkylene, or a divalent group represented by —R7—Y—R8, where R7 and R8 are each independently a single bond, alkylene, or cycloalkylene, and Y is arylene, cycloalkylene, heteroarylene, arylene-arylene, or arylene—CR′R″—arylene, where R′ and R″ form a carbon ring group together with a carbon atom to which R′ and R″ are bonded, where the alkylene, the cycloalkylene, the arylene, the heteroarylene, and the carbon ring group may be substituted with one or more substituents selected from the group consisting of halogen, alkyl, alkoxy, alkyl thio, hydroxyalkyl, acyloxy, cycloalkyl, aryl, substituted aryl, aryloxy, heteroaryl, and substituted heteroaryl; k is 0 or 1; X−is a monovalent anion having an oxidation potential higher than a reduction potential of the dication of General Formula 1 by 3.1 V or greater; and W2+is the dication represented by General Formula 2,, , where, in General Formula 2, o, p, and q are each independently 0 or 1; and A, B, and C are each independently an arylene group that may have a substituent and has from 2 through 20 carbon atoms, or a heterocycle group,
wherein the anion of the electrolyte of the electrolyte layer is one or more selected from the group consisting of (FSO2)2N−, (CF3SO2)2N−, (CN)4B−, BF4−, PF6−, and ClO4−.