The fight centers on Shaub’s request in April that all agencies hand over information on how many ethics waivers have been granted to onetime lobbyists who now have administration positions. Although a Trump executive order bars such former lobbyists from working on issues on which they’ve lobbied within the last two years, his administration has nonetheless hired dozens of lobbyists to work on matters that impact their recent lobbying clients. And unlike prior presidents, Trump has refused to publicly disclose or justify the lobbyist waivers.


In a letter obtained by The New York Times, OMB Director Mick Mulvaney ordered Shaub to drop the matter. In response, outraged congressional Democrats pledged to request the waiver information themselves, a watchdog group filed suit, and Shaub fired back with a ten-page letter asserting his legal authority to make sure ethics rules are being followed.


It’s not the first time Shaub has tangled with Trump and his team. In fact, some Facebook fans think Shaub deserves a medal for publicly decrying Trump’s failure to divest from his business interests as “wholly inadequate,” and for flatly rejecting White House lawyers’ claim that government ethics rules don’t apply to employees in the Executive Office of the President.


But Shaub and his agency can only do so much. The OGE plays an essentially advisory role, and lacks the power to launch investigations and impose sanctions. Shaub does note in his ten-page retort to Mulvaney that the federal Inspectors General and the Office of Special Counsel have the power to investigate “allegations of retaliation” against federal officials who fail to hand over the information that OGE has requested.


But there’s no rule that protects Shaub, for example, from being fired without cause—a provision that ethics reform advocates urged Congress to adopt as far back as 1983, and that now seems suddenly timely. It’s one of a long list of OGE changes that reformers have dusted off and are now circulating on Capitol Hill. These include the recommendation that Congress authorize the OGE to investigate ethics violations by high-ranking executive branch employees, and clarify that the agency’s director has the authority to subpoena witnesses, compel evidence, and issue civil penalties for ethics violations.


“When tradition no longer is enough, that means that you’ve got to go back and look at the law,” says Meredith McGehee, chief of policy, programs and strategy at Issue One, a bipartisan campaign reform group, which outlined its OGE recommendations in a memo this week. McGehee says the OGE actually has more statutory authority to police ethics matters than it has exerted until recently, but that tougher rules are still needed.


Two Democrats—Senator Sheldon Whitehouse of Rhode Island and Representative Ted Deutch of Florida—have already introduced legislation that would direct the OGE to require high-level cabinet nominees and appointees to report the undisclosed money they spend on politics. Whitehouse points to big-spending “dark money” groups—politically active nonprofits that operate outside the disclosure rules—with ties to officials such as EPA Administrator Scott Pruitt and Education Secretary Betsy DeVos.


It’s a “huge political enterprise, this whole dark-money apparatus,” says Whitehouse. “And to have no visibility about how cabinet officials have played in that space is just a flagrant loophole packed with conflicts of interest.”


McGehee says a surprising number of Republicans have been willing to discuss OGE changes with Issue One and its allies. While congressional Republicans have so far failed to show much appetite for Trump administration oversight, the president’s ethics controversies continue to mount, all against the background of a special counsel probe into Russia’s alleged tampering in the 2016 campaign.


Foreign holdings by Trump’s daughter, Ivanka, and his son-in-law, Jared Kushner, have drawn ongoing scrutiny and prompted the watchdog group Democracy 21 to call on the OGE to take steps to prevent a conflict of interest. There are also renewed calls for Trump to make good on his pledge to donate to the Treasury all profits from foreign patrons to his hotels and other businesses. Recent reports quote an internal Trump Organization document stating that asking guests about their foreign government connections would be “impractical,” violate their privacy, and “diminish the guest experience of our brand.”


“I’m not yet seeing any significant willingness, readiness, to push on the administration to be more accountable,” says House Democrat John Sarbanes, of Maryland, of his GOP colleagues. “But I think there’s a kind of cumulative effect of things here. And there will come a tipping point where Republican members of Congress will no longer be able to defend the lack of accountability that this White House seems to operate with.”


It was, after all, a Republican—Senator Charles Grassley, of Iowa—who insisted that all administration waivers to executive branch lobbying restrictions be disclosed under President Obama. In his memo to Mulvaney this week, Shaub couldn’t resist quoting Grassley stating that “the work of the Government is the work of the people and it should be public and available for all to see.”<|endoftext|>New York City, NY | https://www.bms.com/about-us/responsibility/bristol-myers-squibb-foundation.html


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1255467  is a renewed and stronger assault on seed ... based on legal systems that permit exclusive rights over seeds on the spurious contention that plant varieties were 'discovered' and improved on. But these 'discovered' varieties are the product of the whole history of collective human improvements and maintenance carried out by peasants. To assert exclusive rights over the whole on the basis of small adjustments is nothing short of outright theft." - SouthSouth Dialogue, Durban, South Africa, November 2015


"The G8 New Alliance for Food Security and Nutrition was launched in 2012 by the eight most industrialised countries to mobilise private capital for investment in African agriculture. To be accepted into the programme, African governments are required to make important changes to their land and seed policies. ... [for example] Despite the fact that more than 80% of all seed in Africa is still produced and disseminated through 'informal' seed systems (on-farm seed saving and unregulated distribution between farmers), there is no recognition in the New Alliance programme of the importance of farmer-based systems of saving, sharing, exchanging and selling seeds." - Alliance for Food Sovereignty in Africa and GRAIN, January 2015


As African leaders and corporate CEOs gather to meet with President Obama and U.S. government officials, a wide variety of civil society activists will also be meeting in Washington, some in officially recognized side events, others in alternative venues. Many more will be issuing statements and communicating their views, some appropriating the twitter hashtag #AfricaSummit used by U.S. government officials, thus inserting their views as well into that hashtag stream.


"The right to food is the right of every individual, alone or in community with others, to have physical and economic access at all times to sufficient, adequate and culturally acceptable food that is produced and consumed sustainably, preserving access to food for future generations. ... Because of the various channels though which access to food can be achieved, the creation of decent jobs in the industry and services sectors plays an essential role in securing the right to food, as does the provision of social protection."- Special Rapporteur on the Right to Food, Final Report


According to a new report from the African Centre for Biosafety, in South Africa, "Monsanto's Bt maize, MON810, has failed hopelessly in South Africa as a result of massive insect resistance, after only 15 years of its introduction into commercial agriculture." Yet the same variety is being promoted in other African countries by projects supported by Monsanto. And South Africa's supply of maize, a staple food, is dominated by a few large companies and consists almost entirely of GM crop varieties.


"These interventions from AGRA [Alliance for a Green Revolution in Africa] and the G8 are, first and foremost, about opening markets and creating space for multinational corporations such as Yara, Monsanto and Cargill, to secure profits. ... As world leaders speak in philanthropic terms about 'ending hunger', behind the scenes Africa's seed and trade laws are being 'harmonised' to the whim of agri-business giants. The efforts of Africa's farmers over millennia stand to be privatised and expropriated, while traditional and vital practices such as seed saving and sharing stand to be criminalised." -- Francis Ngang, Secretary General of Inades-Formation (http://www.inadesfo.net/)


"We, the rural populations, families from the communities of the Nacala Corridor, religious organisations and Mozambican civil society, recognising the importance and urgency of combating poverty and promoting sustainable and sovereign development, believe it is timely and crucial to voice our concerns and proposals in relation to the ProSavana Programme. ... After several discussions at community level in the districts covered by this programme, with Mozambican Government authorities [and with representatives of Brazil and Japan], we find that there are many discrepancies and contradictions [confirming] defects in the programme design; irregularities in the alleged process of public consultation and participation; serious and imminent threat of usurpation of rural populations' lands and forced removal of communities from areas that they currently occupy." - Open letter to leaders of Mozambique, Brazil, and Japan, May 28, 2013


"Under the fast track land reform, 169,000 farmers have received land since 2000. Most are small farmers under model A1, but the fast track also includes model A2 with land for wealthy people prepared to invest in largerscale commercial farming--maintaining the dual agriculture policy that had continued since the colonial era. The 146,000 A1 farmers moved quickly onto their land and are using more of the land than their white predecessors. A2 farm allocation was more competitive and politicized ... [nevertheless] The bulk of settlers are 'ordinary' people ... Undoubtedly some are political elites or what are sometimes called 'cronies,' which we guess to be 5% of farmers and 10% of land." - Hanlon, Mantengwa, and Smart, in Zimbabwe Takes Back the Land


Whether to take credit for it or to cast blame, both ZANU-PF and most of its critics attribute responsibility for the land reform in Zimbabwe since 2000 to the party of Robert Mugabe. Although much of the debate in the media about the book "Zimbabwe Takes Back Its Land," has repeated this familiar point and counterpoint, the authors in fact deny this premise, arguing that the principal force behind the land reform and how it was implemented was not ZANU-PF but Zimbabwean farmers.


Guest Visitor has been a member of AfricanAmericanCareers.com since Dec 31st, 2008. Guest represents class of and is located in the , area. You can connect with Guest Visitor and other interesting members of AfricanAmericanCareers.com by signing up or logging in.


AfricanAmericanCareers.com is the leading career website for African American professionals, and the companies that seek to employ them, in the United States. Our mission is to help our customers source and hire the most qualified black professionals and to provide those professionals with the best job opportunities in their respective fields.<|endoftext|>Chamisal made history in 1973 as the first winery in Edna Valley to plant grapevines. Just 10 minutes from downtown San Luis Obispo, our tasting room offers sustainably produced wines painted with gorgeous natural scenery.


As farmers and stewards of the land, we're constantly striving to find its highest and best use. Our unique soil types and proximity to the ocean have convinced us that it's Chardonnay. At Chamisal, we're commited to growing truly world-class Chardonnay and showcasing each vineyard's unique characteristics.


While some winemakers find their domain is limited mostly to the cellar, Fin is committed to spending just as much time in the Chamisal vineyards. Estate Director Andrea de Palo is dedicated to making sure that guests have a memorable experience at Chamisal.


Because of its east-west orientation so close to the Pacific Coast, the Edna Valley is one of the coolest appellations in California. its long, temperate growing season gives the grapes plenty of time to ripen on the vine — typically several weeks longer than warmer growing regions. This extended hangtime allows cool-climate grapes like Chardonnay to delevop deep, rich flavors and superior fruit intensity.<|endoftext|>This is a whimsical ice cream table that is sure to strike any audience. You can combine it with our ice cream chairs or let it stand out alone. It is a great product for your business, home or themed event.<|endoftext|>July 10, 2018 - The acting Environmental Protection Agency chief, Andrew Wheeler, is bringing to the job a "change in tone," the agency said, that could shed greater light on the decisions and actions of EPA leadership.


The EPA's former administrator, Scott Pruitt, broke with his predecessors' common practices of publishing a calendar online and announcing travel and speeches in advance.


"As with any change in leadership you can expect a change in approach, and in this case a change in tone as well," Konkus said. "A lot of the specifics in regard to how we will change the approach to calendars, schedules, briefings, etc., will be worked out over the coming days and weeks."


A CNN investigation released shortly before Pruitt's departure last week revealed his aides kept "secret" calendars to conceal controversial entries, such as meetings with industries regulated by EPA, according to a former EPA official.


The investigation found more than two dozen meetings described in emails sent or received by agency officials that were not included on Pruitt's official schedule.


Pruitt's EPA published a watered-down version of his schedule after the fact and did not give the public or reporters advance notice of his public appearances. In several instances, reporters who learned where Pruitt would be speaking were removed from the event or denied access. His calendar entries were released only after the Sierra Club and American Oversight filed public record lawsuits.


Wheeler was confirmed by the Senate in April to be the EPA's deputy administrator, but he was criticized by Democrats for his past ties to energy lobbyists.


His firm's clients included Murray Energy, which calls itself "the largest coal mining company in America."


Prior to his time lobbying, Wheeler served on Capitol Hill as a Republican staff member for the Senate Environment and Public Works Committee and as a top aide to Sen. Jim Inhofe, an Oklahoma Republican who's an outspoken climate change skeptic.


Wheeler is originally from Hamilton, Ohio, his biography on the EPA website said. He has a law degree from Washington University in St. Louis and an MBA from George Mason University.


Chuck Hemenway discusses collecting and aligning stakeholders for efficient APC management. Find his slides here.


Liz Bal delivers her presentation on results free review: A new model of peer review to address publication bias. Find her slides here.


Roman Gurinovich delivers his presentation on Open Access for the machines, the sci.AI platform. Find his slides here.


Chuck Hemenway is Director


1255468  for and displayed. The objective began to look achievable in 1808 when the Society was offered suitable accommodation by the Government of India in the Chowringhee-Park Street area. In February 2, 1814, Dr Nathaniel Wallich, a Danish botanist, who had been captured in the siege of Serampore but later released, wrote a letter supporting the formation of a museum in Calcutta which he said should have two sections - an archaeological, ethnological and technical section and a geological and zoological one. The Museum was created, with Wallich named the Honorary Curator and then Superintendent of the Oriental Museum of the Asiatic Society. Wallich also donated a number of botanical specimens to the museum from his personal collection. After the resignation of Dr Wallich, curators were paid salaries ranging from Rs 50 to Rs 200 a month. Until 1836 this salary was paid by the Asiatic Society but in that year its bankers, Palmer and Company became insolvent and the Government began to pay from its public funds. A temporary grant of Rs 200 per month was sanctioned for maintenance of the museum and library, and Dr J. T. Pearson of the Bengal Medical Service was appointed curator followed shortly by Dr John McClelland and after his resignation by Edward Blyth. In 1840, the Government took a keen interest in the geology and mineral resources and this led to an additional grant of Rs 250 per month for the geological section alone. A new building became a need and this was designed by Walter R Granville and completed in 1875 for the cost of Rs 1,40,000.[9] In 1879 it received a portion of the collection from the India Museum (South Kensington) when that collection was dispersed. It currently (2009) occupies a resplendent mansion, and exhibits among others: an Egyptian mummy, The organs are taken out of the mummy's body through nostrils, except heart. The heart is placed in special chambers. The body was then massaged with salt and oil. The covering was done by thin cotton cloth the Buddhist stupa from Bharhut, the Buddha's ashes, the Ashoka pillar, whose four-lion symbol became the official emblem of the Republic of India, fossil skeletons of prehistoric animals, an art collection, rare antiques, and a collection of meteorites. The Indian Museum is also regarded as "the beginning of a significant epoch initiating the socio-cultural and scientific achievements of the country. It is otherwise considered as the beginning of the modernity and the end of mediaeval era" by UZER Places.<|endoftext|>I have installed Filemaker Server V14.0.2.226 software in Database and web server. However, I am facing some issues in the web version link.


I am planning to reinstall the software in both the servers. Kindly suggest the steps/order to be followed during the re-installation.


The uninstall process can be used to completely remove a FileMaker Server deployment. If you are uninstalling FileMaker Server to install it on a new machine, be sure to write down any settings that you want to save as the uninstall process deletes your settings.


If you had some more doubt, try this link & follow the instructions > FileMaker Complete Documentation


Could you confirm whether we need to uninstall all the components as well. Example:(ARR,URL Rewrite, Web farm framework etc.,)


I am also trying to uninstall FMS but on a Mac but I can't see any application called FileMaker Server of FMS. There was an uninstall application for FMS13 in the Extras folder but it won't work for 14. Any clues?


main office with 5 desktop users. Internet test was 20 / .8 Mbps. The solution will have containers for photos and docs.


I am thinking along the lines of the office fm pro clients being separation model with a cloud based fm server remote data source. I am considering local container tables, but not sure here. The container media needs to get to server at some point so may as well be at the point of insert? As the download speed is ok, download of container thumbnails shouldnt be too bad if accessed as a remote source on the office pro clients.


I could have the server in the office and that would be great for local speed, but no good for remote access and webdirect users due to the slow upload internet speed on site.


As for 50 concurrent WD users + iOS users, you'll never have a great experience with < 1mbps upload. I'd consider a hosting company at that point.


Mirrorsync is a good product for syncing multiple instances of filemaker server. That might be your gateway to WD later on.


For the time being, the .8mbps upload is a bit of a bottleneck, and it is a two way bottleneck for what you've proposed. So the decision should lie with what group is considered the primary users. If it's the FMP desktop users, put the server in the office. If it's the iOS users, put it in the cloud.


This is not in “Ideas” as far as I could look. I just want to put it here so that you have an idea of how requested is this feature. I received access to the App but I am not UK-Resident and I have an Android phone<|endoftext|>This Sitting Buffalo Plush Toy is perfect for a child that loves animals. Not only can they cuddle the soft stuffed animal, but they can use it for creative play too!


The lower temperatures may mean a decrease in attendance for some commercial pool facilities. However, wintertime doesn’t have to mean that your site has to be completely quiet. In fact, it’s one of the best times to call in pool construction services to install some great new interactive features at your location, such as a spray pad.


Though there are many houses that boast their own swimming pools, most don’t have the means to install a spray pad. As a property manager, you can take advantage of your facility’s space and have one of these great interactive features installed. Alternatively, if your location has a wading pool, it can be converted into a spray pad by pool construction services.


A spray pad would provide a highly interactive site for children of all ages to gather. Recreation Management magazine suggested having at least three different areas that specifically cater to certain age groups. Young children will be attracted to fun shapes and bright colors. Additionally, this area should have gentle water flow. The second zone should have more interactive features that promote family play and social interaction. The last spray pad should be more complex and require teamwork.


Although pools can be great gathering places for families, it’s important to remember that not all family members may be able to swim. This could bar individuals from entering the pool, thereby limiting social interaction and taking away from quality family time. In contrast, a spray pad offers engaging fun for people of all abilities and ages. Toddlers and grandparents can enjoy the soft mist zone while older children and parents can frolic in the more interactive areas.


Though it would be wise to have one or two staff members keep an eye on the spray pad area, it requires less supervision than a pool. Therefore, it could be be a expansion project that doesn’t require a drastic increase in the employee roster.


Take advantage of this winter season and reach out to professional pool construction services. You’ll have plenty of time to discuss your options and map out a plan. Additionally, you won’t have to worry about the project running over schedule. Acting now will allow your facility to unveil a great new feature for the next swimming season.


Pools are often associated with family fun or competitive activities such as swimming or water polo. They’re even known for being a stage for synchronized swimming, but what about physical therapy?


As a pool manager, you know the physical benefits that working out in the pool can offer. The buoyancy and resistance of water provides a unique environment that can’t be found outside of pools.


Chances are, you’ve experimented with different programs throughout the years. Pools can host a variety of activities, from leisure to recreation to competition. You may even have a multi-use pool that allows swimmers to enjoy different activities at the same time.


Regardless, you can explore the potential benefits of hosting physical therapy sessions. If you have a multi-use pool, you can use the leisure end for these courses. For single-use pools, assess which hours have the lowest attendance and consider closing off the pool for an hour or so to give physical therapy classes a try. There are a number of ways that you can do this. If you’re unsure of where to begin, here are some ideas.


1. Work with the local hospital: Of course, you want certified professionals handling such classes, and there’s no quicker way to find them than at the local hospital or physical rehabilitation center. This can be especially rewarding if the institutions don’t have pools of their own. Collaborate with health care professionals and offer your pool expertise to implement a physical therapy program at your site.


2. Rent it out: If you don’t have the time to coordinate programming with other groups, you can still take advantage of physical therapy sessions by renting out your pool to health care professionals. This shows that you’re committed to the overall well-being of the community and can establish your facility’s presence as both healthy and fun.


3. Have current staff become instructors: If there are staff members who are interested in a health-oriented role but want to remain in the aquatics industry, this can be the perfect opportunity for them to train in physical therapy. This way, you have an in-house specialist who you’ve worked with and know you can rely on.


As peak season returns, planning


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Next week we are at Embedded World Exhibition – see all our boards up and running (including OpenRex :) - iMX6 Rex Projects


Next week we are at Embedded World Exhibition – see all our boards up and running (including OpenRex :)


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1255471  concern in the community at large, regardless of colour.


The Ferguson syndrome includes a malicious and perpetual undercurrent of distrust of authority unjustified or not, racial disparity, racial discrimination, home-taught hate and exacerbated ignorance. Economic disparities, intolerance, a mind-boggling us-vs.-them mentality perpetuates itself through the wanton and willful lack of reason, and yes, a lack of reasonable and decent human values.


What is the answer to the Ferguson syndrome? Let us 'feel good' and reflect. Quietly. Practice humanity. Educate. Practice genuine justice and society without bias. Eliminate systemic discrimination and poverty. Stop hating. Start thinking. Blah, blah. It's endless.


Nice try, but the fact remains, if we think of others as "them" we are part of the problem. Hollow words—without the recognition that although we may be 'colored' one way or the other both physically or in our minds, each differently, —blood is always red, and tears are colourless. Think about it. Common ground. Let's work on that.


Posted in Civilization, Humanity, Major Issues, Politics, Reflections, Uncategorized	| Tagged Arson, common ground, Ferguson, Ferguson Syndrome, hate, justice, Mike Brown, Prejudice, racial discrimination, riots	| 11 Comments<|endoftext|>Grand Total Price:47.7USDPlease be aware that you can opt to be charged in a currency other than JPY (Japanese yen) only if you choose PayPal as your payment option. If you wish to pay with your credit card directly, you will be charged in JPY (Japanese yen) and the exchange rate to your local currency will be determined by your credit card issuing bank.(?click)


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Startup bonus Many of our online business entrepreneur colleagues have already answered you regarding the top high ticket affiliate marketing program that we and they promote that earns you high ticket commissions of more than $1000 per sale and converts well so we won't labor further on that point The Army is seeking to continue upgrading the Abrams tank, as well as pay for training devices, system technical support, and safety and operational field modifications, including upgraded Blue Force Tracking kits. Truck Auctions Great post, very in-depth and informative. I helped my pal who is nearly mind-dead with computer systems get a Join the Highwire Affiliate Program here to earn recurring commissions. 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April 2, 2018 at 5:31 PM “Yesterday is not ours to recover, but Case Study 5: Immense traffic coming to this site. Affiliate Marketing Programs Overview While promoting this program,you can join their dream car contest and win.They provide you everything you need to promote their products such as banner,swipe file and more.Affiliate get high commission starting from $100 -$500 depending on the offer you promote. April 4, 2018 at 10:31 AM It as hard to find knowledgeable people about this topic, but you Click her to learn more about Liquid Propane Frymaster high ticket item. Thanks for mentioning my ebook on your post. Those two sentences managed to get me some sales. I’m impressed! I came across them a few years ago and was impressed with the products and free affiliate training they offered. Commission structure Thanks for the post.Much thanks again. Fantastic. Find Profitable Keywords! I know I have a lot of work to do with figuring out the higher priced affiliate items but I am willing to do all the necessary sacrifices to get to where I want to be. Although I am putting everything I have into it, someday it will be worth it. When I am able to quit my job and work from home I will be so glad I worked as hard as I did. PERSONAL USE • Restaurants If you’re looking for a lucrative home business that can create a substantial income, TiDom may be just what you’re looking for. TiDom is a high ticket sales program and is the leader in the top tier niche. This blog is to demonstrate how you get paid with TiDom…and in case you’re wondering, TiDom stands … Continue reading » Find the best affiliate marketing programs that pay and you are about a quarter of the way there. 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Popular Recommended Discussed April 2, 2018 at 1:34 AM Latest posts by Ken (see all) You will learn how to determine whether an affiliate program should be promoted by building a small web site or blog. And then you'll learn how to do it. It helps build a relationship with the audience. 3) There are 3 categories with high ticket items: You’ll find plenty. There is a link to some on this page. Sincerely – Bill ==> Zero Cost MMO eClass! << BEST I have already signed up with one of the communities you list for beginners. Thank you so much. Jun 26-28, 2018	Hillhead 2018 - RE1 - Buxton,UK April 5, 2018 at 6:05 AM My Wealthy Affiliate Review (Updated May 2018) Each month, in “The Big Ticket Selling Report”, he’ll reveal to you the strategies and techniques that produce remarkable big ticket sales results like this… Support team have pretty terrible response times (I tested this out myself). SiteRubix Website Platform Review (Updated May 2018) Create an Account Auto Donations Passport Vertical Platform Lift Confirm Password * Internet Marketing Events Step 4 – Stand Out From The Crowd! April 2, 2018 at 10:08 AM


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vireporter.net/v/video-k0zQHfqeOzE.html So Skip predicts Lonzo leads Lakers to the playoffs but now that Lebron joins he says 8th seed. No credibility!


SKIP Bayless is butthurt that his Spurs got zero chance of making the WCF while LABRON is a LAKER now .. Lakers have a Swarm of 3 point shooters NOW!!! WTF is Skip smoking or eating or drinking before these shows??? SMDH


Shannon was absolutely right. Lebron will get a ring with the Lakers in 3 years. Facts. But I think that deal would have been much more difficult without Magic Johnson. I do agree with Skip he was destined to be a Laker.


at this point this isnt even a sports analysis show, its just pure comedy when it comes to lebron and the cowboys and i love it..smh at anyone who takes this seriously


I'm seeing Joy less and less... What's goin on guys? She ain't some interchangeable piece, Fox. You shouldn't just bring her back; you should change the format of the show to give her her own chance to voice her thoughts on every topic. This show needs a little "Maybe I'm Crazy" touch to eclipse all these other shows.


Lakers won 35 games last season if you dont think Lebron can get them to win 10-15 more games you trippin


Stephen A. sides with Reggie Miller: Magic Johnson should speak up on LaVar Ball | First Take | ESPN


Michael Rapaport says LeBron's Lakers are finals favorites, CP3's contract and more | NBA | THE HERD


Jason Terry reacts to the Bucks' blowout against the Warriors: Bucks' stock is up | NBA | UNDISPUTED


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In a time of tight public budgets and program cuts, the most important task a publicly-funded program can do is show results. Bring people downtown, attract private investment, increase sales and fill vacancies; i.e. increase the tax base. These are the hard, quantifiable outcomes that a Main Street program should be working toward and that help to make the case for continued funding.


There are other, softer outcomes, such as creating an attractive place that is welcoming and pleasant, increasing civic involvement, pride, cultural exchanges and generational engagement, but all of these really lead to the aforementioned “countable” achievements. The key is to focus on the accomplishments. Instead of thinking, “We can’t do that because we don’t have any money,” an effective Main Street initiative will realize, “We don’t have any money because we don’t do enough.”


The Daily News Record of Harrisonburg, VA recently held their annual “Best of the Valley” competition. Along with the standard categories like “Ice Cream” (Kline’s Dairy Bar), “Outdoor Dining” (Dave’s Downtown Taverna) and “Live Music Venue” (Clementine), the paper has one called “Best Use of Taxpayer Money.” See the complete listing here.


For the second year in a row, Harrisonburg Downtown Renaissance (HDR), the local Main Street organization, won the “Best Use of Taxpayer Money” hands down. To win this two years in a row shows that it is no fluke or lucky timing. It is a mark of the success HDR has had and continues to have using a comprehensive and incremental approach to engaging the community in the downtown revitalization efforts.<|endoftext|>London lights up like magic during December, it seems the city brings out it’s best for Christmas. One of my favorite attractions in London during this time is Winter Wonderland in Hyde Park – a Christmas fair which is open during the months of November to January. Winter Wonderland is a spectacular themed destination which opens up for the public every year in London. The best part is that entry to the wonderland is absolutely free, you only have to pay for the attractions or rides you choose to indulge in. Apart from all the rides, they also have a bunch of themed cafes, restaurants, Christmas markets, street…


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Far Cry 5 launches in just under a month, and so it's time for new screenshots New Topic Reply to Topic<|endoftext|>Judge slapped lawyer with $1,000 fine for menopause “joke” – Women in the World Judge slapped lawyer with $1,000 fine for menopause “joke” – Women in the World


“You’re still hot? You’re not getting menopause, I hope.” That’s the “joke” that got lawyer Camilo Salas in trouble during a deposition back in April, in front 14 other attorneys, as his opposing counsel, Dora Monserrate-Peñagarícano, had complained that the room was too hot. While Salas insisted that he was only worried about Monserrate-Peñagarícano’s “medical condition,” District Judge Francisco Besosa ruled that his comment was meant to embarrass Monserrate-Peñagarícano and ordered Salas to pay $1,000 in attorney fees and take a legal education course on professionalism. In his ruling, Judge Besosa noted the ongoing problem of sexism in the courtroom, writing that “discriminatory comments like this undoubtedly occur on a daily basis in the legal profession and are routinely swept under the rug.” Bloomberg Business linked the story to a study released earlier this year that found female lawyers have to deal with inappropriate, stereotypical or patronizing comments from colleagues and judges all the time, which might be one of the reasons why few female lawyers are arguing cases in lead roles, if at all. Salas has yet to pay the fine and has been allowed to stay on the case, which is taking place in Puerto Rico.


Abortion clinics closing down all around the U.S., even in liberal states – Women in the World Abortion clinics closing down all around the U.S., even in liberal states – Women in the World


Activists chant as they rally in support of Planned Parenthood on the steps of City Hall in Los Angeles, California September 29, 2015. REUTERS/Mario Anzuoni


According to a new report in The Guardian, the war on abortion is not only being waged in Texas, but all over the U.S. Abortion clinics are being shut down and they’re closing in liberal states that have historically been viewed as abortion-friendly as well as conservative states, like Texas. “The trend is disturbing,” Nikki Madsen, executive director of the Abortion Care Network, a group representing independent abortion providers around the country, said in an interview with The Guardian. “It’s taking root in states we traditionally think of as ‘friendly’ to abortion rights, without many people noticing.” The Guardian compiled a list of 50 abortion clinics that shut down permanently in 2014, and more than half were located in liberal states. Exact figures are difficult to pin down, and the phenomenon isn’t limited just to closures. At one abortion clinic in Philadelphia, a staunchly liberal city, obtaining an abortion is becoming significantly more difficult for women. Anyone who does get an abortion there must make it through a gauntlet aimed at changing their mind — like reading a state-mandated pamphlet that tries to do just that.<|endoftext|>Welcome to my personal travel blog! I have been traveling the world and enjoyed all sorts of luxuries and pleasures, no matter if it was riding a yacht, renting an exotic car or indulging in crazy sports activities…find out more about me while reading my posts on this site – and if you want to leave me a message, please use the form below, thanks!<|endoftext|>As a holistic traditional practitioner I am alarmed by how many people with Lyme disease are in fact relentlessly doing very powerful kill therapies, meaning natural and/or conventional treatments to annihilate Spirochete bacteria while mostly ignoring terrain. It seems like a recipe for failure and more suffering. It ignores the fact that there are many people walking around who have been exposed to the Borrelia Burgdorferi infection and all the other bugs that cause Lyme disease who are perfectly healthy, have the antibodies in their blood to prove they were exposed, and are essentially in great health. They are living examples of Bechamp’s theory – they were unaffected by the bug that makes a few individuals sick. There are far more of these people walking around than the relative minority of people who succumb to chronic Lyme disease after exposure.


As stated, by some estimates, more than half the population of the U.S. has already been exposed to this bug and yet remain healthy. They are the majority. That minority who gets sick from Lyme disease were having problems long before exposure to any microbe. In other words, their garbage collectors went on strike sometime prior to the vermin-like, microbial population explosion.<|endoftext|>Crablike Ramesh breathes his cleaves dryer. dating chch nz Wyndham, who does not cooperate, becomes enmity, relates very affectionately. Does the most embarrassing of Jerrold involved in his med


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“Jesus Christ, mister. You’re scaring me.” He searched my face for some kind hint of jocularity, for some sign I was pulling his leg. He found none. He took a last look down the tracks toward the approaching lights and rose to his feet.


The wind howled down the tracks, licking over the cool steel ties and sucking the moisture from my eyes. My mouth pulled back into a cool smile. It was time. I stood up and walked to the platform, and as the train pulled up to greet me


In the rustic decor today, innovation has long passed and the latest styles and designs are adapted slightly but leave its mark. There remain elements of classic country houses: wood, stone, antiques, exposed beams, fireplaces and furniture resistant. However, materials and innovative designs, colors, shabby romanticism, debugging minimalist industrial functionality or make an appearance and lightening the traditional rustic style filling.


The combination of rustic spaces with antique floors and sofas, armchairs or chairs or Nordic industrial design, modern kitchens and appliances and LED lighting last model balanced and updated space without making it lose its essence.


Modern solutions in allocating space, place the decorative, use colors or play with the materials, are a new feature that makes rustic settings to suit even semi urban or urban.


Stone, natural materials like cane, rattan, wicker or esparto, or traditional ceramics can be forged to achieve definitive rustic we want. That, of course, not forgetting the importance acquired in the rustic decor textiles. Curtains, quilts, bedspreads and even towel will be critical to achieving the desired decoration.


Play with colors, uses no natural light or thoroughly studied the location of artificial lighting so that there is no detail to chance. A well-placed little focus can cause an irregular wall decorative object seems genuine. It’s all about taking good care of the details, because a country house is no longer what it was.<|endoftext|>Home; SVDVD-315 The tide that it is huge to rape you if I attack the camp sunburn Schoolgirl in machine Vibrator in secret in shade! The.


Release Date2012-10-06Length127min(SVDVD-315)The tide that it is huge to rape you if I attack the camp sunburn Schoolgirl in machine Vibrator in<|endoftext|>Wed, 01 Feb 2017 Mature abusing redtube blog gay small school twinks boy and gay tie white boy down and fuck him


Get Mature abusing redtube blog gay small school twinks boy and gay tie white boy down and fuck him tube video<|endoftext|>"The 4th hall is fine for having a meal while watching a movie, or if you hate beer in plastic. Or for a date - very comfortable. Ticket's twice as expensive as normal one"<|endoftext|>E Agents Travel Agents Definition is free HD wallpaper. This wallpaper was upload at November 20, 2018 upload by admin in .You can download it in your computer by clicking resolution image in Download by size:. Don't forget to rate and comment if you interest with this wallpaper.<|endoftext|>Ngành nghề đối tượng: Thiết bị điện dân dụng Linh kiện điện tử/Linh kiện điện Thiết bị thông tin/Thiết bị truyền thông<|endoftext|>Last week we worked on the letter B and we focused on the story 'Bear Snores On" By Karma Wilson. I made a couple printables to go with the story as well. (You can find them under resources/ printables). My Dear Grandmaother passed away at the end of the week so we didn't do our usual Friday activities. Wed and Thurs we participate in other preschool co-ops so here is what we did at home on Monday and Tuesday. Watch our slide show to see what we did.


As a computer technician, I have seen some pretty interesting computer problems. The majority of problems I encounter in the home market are adware, spyware or connectivity problems and the occasional hardware problem.


The hardware problems are usually caused by simple manufacturer fault (as in, it was going to fail at one point anyway) or a power surge. However, occasionally I find a computer that was killed by pet hair, dust or cigarette smoke. These three eventually find their way into the computers fans or heatsinks causing the computer to overheat and die.


Over the years I have come across a few bad cases of this and I would love to share some of the photos with you.


Warning: Some of these photos are pretty gross. I purposely kept them at a high resolution so you can see them in all their glory. Click on any of the thumbnails to view the high resolution version.


A client brought in a laptop that kept restarting during bootup. At first, I thought this would be your typical “Windows blue screen of death with the automatic restart option switched on” but the computer didn’t even get to the Windows stage, it would crash out in the CMOS. Suspecting a overheating problem, I entered the BIOS, looked at the temperatures and noticed that they extremely high and climbing. Seconds later, the computer shut itself off again. I knew this was definitely going to be a temperature problem. On the outside, the computer seemed in relatively good shape as seen in the photo below:


I opened up the laptop and looked at the internal parts. The insides were relatively dust free with the exception of a little surface dust in the CPU fan, but nothing that would totally clog it up. So I continued on and took out the heatsink, heatpipe and fan section that is highlighted in red:


I separated the heat sink and the fan and found the problem; a bad case of pet hair. The fan would pull in pet hair through the air vents shown in the first picture and try and push them out the exhaust air vents. However, due to the fine fins on the heatsink it was getting caught and was building up:


I pulled out the hair using tweezers, gave the computer a blast with some compressed air, put it back together and it worked perfectly. Temperature was normal and it ran for a good 5 hours without problems before the client picked it up again. Here is the photo of the ‘hair monster’ I removed:


This computer came in because it wouldn’t boot at all; as if there was no power. This could be caused by a dead power supply, dead CPU or dead motherboard. I opened it up to find out and was greeted with this:


This computer came in because it wouldn’t boot at all. From the smell of it, I was pretty sure the death of this computer was caused by cigarette smoke. You see, when cigarette smoke and dust collide in a computer, it produces this weird dusty-tar combination that has a pasty texture. Its brown, it smells bad and is hard to remove. It turns out that the CPU had overheated and died on this computer because airflow generated by the fan was unable to get air into the heatsink fins; here’s why:


I removed it as a whole by getting my tweezers in between the heatsink fins and pushing the the layer of dust/tar up:<|endoftext|>What can I say about this book that has not already been said? It is a classic, plain and simple. Tolkien is the father of the modern fantasy tale.


Here are my boys all dressed for Halloween. They had so much fun that they are already talking about what they want to dress up as next year. The photos were framed and edited in PSE6, then I used SU paper (Pumpkin Pie and Black) for the base, SU rub-ons (Bats) and Su Stamps (Batty for You stamp set), Eeek is just written in white gel pen and I streaked the edges of the photos with black Staz-on ink. Thanks for looking!


This invitation by Jasmine and Woo features a white background with a light aqua scalloped band at the top. An orange stripe across the top of the card anchors a light yellow oval to print a message greeting. The bottom of the invitations features a light yellow and orange damask pattern. This invitation is perfect for a baby shower invitation, bridal shower invitation or as a birthday party invitation.


This baby girl photo birth announcement by Jasmine and Woo features a beautiful yellow and orange damask pattern background with a light aqua scalloped band along the bottom. Your picture is printed in the center and framed in white.


This flat thank you note by Jasmine and Woo features a light blue scalloped border along the top where your personalization is printed. A light yellow border with white dots accents the bottom of the card.


This stick-on mailing label by Jasmine and Woo features a light aqua along the top and bottom. A yellow circle in the center is printed with your message. Add a touch of fun to your packages with these matching mailing labels!


This stick-on return address label by Jasmine and Woo features a light aqua background with a bright orange damask pattern design on the left side. Your return address is printed on the right in brown. Add a touch of fun


1255475 , you must to know some data about them. As rule, you should find a dog at website or read stories about them.


Bulldog and Golden Doodle dogs are very famous this year. As rule, most recent dogs are German Shepherd Dog and Rottweiler. If you desire to search new mate for your family – you can find dogs at link. At website are working dog masters who understand a lot of information about pawls and know how to care about pawls.


First of all, you must to understand, that there are a lot of breeds of dogs. If you wish to buy small breed, it can be Shih Tzu. If you are ready to purchase big dog, it could be German Shepherd Dog or French Bulldog. At website you could find also a lot of sapid facts about dogs. It can be information about how to feed right dogs and how to care for them, when they are sick.


Dogs for sale are very famous. You can make a choice and purchase different breed of puppy. Dog breeds may be with different bloom. It could be gray with brown or black with dark-brown. When you shall purchase puppy finder, it should be very nice. You must look after and care for it. Puppies for sale may be also adult. But if you would buy puppy with small age, he or she will quickly get used for family.


Site 2puppies.com is famous in Europe. There are a lot of citizenships from different lands bought puppies there. Dogs for sale may be with big or small noses. The weight of puppy can be 10 – 100kg. Price for a puppy also is the main fact. Cost for puppy depends of breed and age of the pawl. As rule, you must to know that when you would buy a dog, you must care about hygiene. The basic age of a dog is 14 years. The pawl need have a certificate of origin, as well as an fresh agreement and a purchase contact.


Before the process of buying you must also think about sex of the dog. If you want to purchase a dog, you need choose the sex of the puppy and be ready keep an eye on this issue. You must to remember, that the size of the dog can be different. That is why before to buy a dog you must to search data about adult dogs of particular breed.


Your child can spend almost 50 hours a week in the child care facility that you choose, so you want to maximize their overall potential by finding the right balance between learning, nurturing and fun. At TLC Schools, your child’s success is our primary focus. We strive to provide an atmosphere in which your child can experience success on a daily basis, build a positive self-image, and acquire a lifelong love of learning. We achieve this goal through state-of-the-art facilities, an outstanding curriculum, an atmosphere that encourages exploration and development, and a caring team of teachers. It’s why we were voted best in Plano child care by Living Magazine.


Our philosophy at TLC is to offer our families and their children the highest quality educational programs and child-care, combined with an appealing, safe, secure and exciting environment for a child to grow and develop. It is our goal to provide an atmosphere where each child can experience success on a daily basis, build a positive self-image, and acquire a love of learning. We offer an excellent curriculum, in a state-of-the-art, developmentally appropriate warm and nurturing environment.


“We pride ourselves in the warm, nurturing environment that we offer along with our outstanding educational programs.”


The passion among our teachers and administration at TLC Schools is beyond compare. Each instructor is dedicated to educating young minds through exploratory learning. Teacher to student ratio is low so children receive individualized attention, customized to their needs. Caring, certified, and degreed teachers in every classroom love their jobs and their students. Teacher longevity creates stability and security for parents and children as the majority of the staff have been with our center for many years -- most over a decade and some even longer. Our nurturing and passionate teachers are unrivaled.


At TLC, our top priority is your child's safety and security. Our open-door policy at TLC allows parents to stop by any time and we use state-of-the-art technology to control access to our facilities. Parents are required to pass a security check at the front door using a personal identification number. In addition, your child must be signed in and out by a parent or person previously designated by you. Each classroom at TLC Schools is equipped with an in-house video camera system that allows you to observe your child in the classroom environment at any time. With a proper access code, parents can log into the WatchMeGrow system from any computer, tablet, or smartphone to see how your child is doing throughout the day and watch classroom activities in real time.


• Our teachers and staff are aware of every students' dietary restrictions, including the need to avoid gluten, dairy, or meat.


• Each child receives a nutritious, made-in-house breakfast, lunch, and 2 snacks throughout the day, prepared by our dedicated chef who accommodates to even the strictest of diets.


• Viruses such as RSV, flu, and Hand-Foot-Mouth are significantly reduced in our facility without compromising air quality with harsh chemical cleaners.


• Students are encouraged to use their imaginations in every subject, from phonics to math and beyond.


• A smart board is available for fun learning games and preschoolers begin the ABC Mouse computer learning curriculum.


• Field trips add to the excitement with outings to Hawaiian Falls, The Dallas Zoo, The Arboretum, The Perot Museum, Dallas World Aquarium, and much more. If the field trips are cancelled due to weather, TLC offers virtual field trips with films about the ocean, the rainforest, and other exploratory films.


• Famous children's performer, David Show from PBS, comes twice a month to educate and entertain the children with music, puppets, and storytelling.


• Themed school days give kids an opportunity to dress up in sports apparel, tye-dye, and other fun costumes.


• Families can celebrate holidays such as Thanksgiving, Halloween, Spring Fling, and Fourth of July in the classroom with their children.<|endoftext|>9 breakfasts, 1 lunch and 7 dinners including Clontarf Castle Hotel welcome dinner, Nancy’s Bar in Ardara, and Abbey Tavern traditional Irish dinner and show.


Visit Florence Court House, home of the Irish Yew. The original tree, discovered in 1760, can still be viewed on the grounds. Tour the magnificent 18th century mansion, renowned for its elaborate rococo plasterwork. Next, a CIE Tours exclusive, visit Blakes of the Hollow Pub, a Victorian bar that retains many features original to its founding in 1887. Famed author John McGahern, a regular visitor, described it as "one to the happiest and most beautiful bars in the whole of Ireland". Take a photo by its official “Game of Thrones” door highlighting the series’ sixth season. Continue your travels north to Donegal, with its windswept hills where only sheep can thrive. Donegal is renowned for woolen production and tweeds.


Head to Teelin to reach the best viewing point of the Slieve League sea cliffs, the highest in Europe. Afterwards, sample home-baked scones with coffee or tea. Travel along the coast then head inland through the majestic Glengesh Pass for views of mountains and valleys to Donegal, renowned for its tweed and knitting industries. Head to Ardara, where you will watch demonstrations of spinning and weaving at a local woolen shop. Enjoy an early dinner in a popular pub.


Explore scenic Connemara to admire how constantly-changing cloud formations give granite hills, sparkling lakes and peat bogs an added dimension. Stop at the Connemara Celtic Crystal Factory where craftsmen demonstrate fine glass cutting. Travel through the picturesque scenery of hills and lakes to visit Dan O’Hara’s Homestead. Experience traditional methods of farming, see Connemara ponies, and have a light lunch. Return to Galway and enjoy free time for the rest of the day.


Drive through Clare to view the Cliffs of Moher, which soar 700 feet above the Atlantic Ocean. Walk to O'Brien's Tower for views of the Aran Islands and Galway Bay. Drive through the pleasant countryside of County Clare which is dotted with ruined castles. Discover St. Brigid's Well, a mystical site whose waters are said to have healing powers. Embark on a short ferry ride across the River Shannon Estuary. Arrive in Killarney and partake of the Whiskey Experience with dinner that includes a chocolate tasting.


nox.rs is a website that ranks 23,623,829 in Alexa. nox.rs is ranked 710,887 on statisy and has 1 backlinks according to Alexa. The hostname or fully qualified domain name (FQDN) nox.rs is identical to the domain name nox.rs. The domain is registered under the domain suffix rs and is named nox. The nox.rs Server is hosted by YUnet International d.o.o. and is located in Serbia (). nox.rs is not listed in the dmoz open directory project.<|endoftext|>They began with a perspective known as the which proposes that people become addicted to cybersex because they both anticipate and then receive sexual satisfaction.


You detect secret flirtatious conversations with distant women who he will most likely never meet in person. It's written from a female perspective, that's true, but what about the poor boyfriend over there in the Philippines sound asleep while honey ko is sneaking out to the internet cafe, or the Russian guy


1255476 NRET) present a particular interest. In the NRET process, exciton energy is transferred from NQD donor to TMDC acceptor via near-field, dipole-dipole energy coupling. This process plays an important role in photosynthetic plants and has been recently considered for energy harvesting in NQD/semiconductor architectures. Its efficiency depends on the distance, spectral overlap and dielectric screening properties of the acceptor material and its dimensionality. With the emergence of 2D materials, there is strong motivation, both for fundamental reasons and for the new applications, to study NRET in these novel systems. We have studied NRET coupling between several types of NQDs and MoS2 monolayers using photoluminescence (PL) and femtosecond transient absorption (TA) spectroscopies. Both methods indicate very efficient NRET into the MoS2 acceptor, with donor PL intensity quenching concurrent with energy influx into acceptor as observed by TA. These effects are facilitated by reduced dielectric screening inherent to strongly polarizable TMDC materials as described by classical electromagnetic model. We envision energy coupling in 0D-2D hybrids enabling applications in photosensing, photovoltaics and light emission.


Proc. SPIE 10521, Black phosphorus: a novel 2D material and its photonics applications (Conference Presentation), 1052106 (14 March 2018); doi: 10.1117/12.2286329


Two-dimensional (2D) materials such as graphene, transition metal dichalcogenides (TMDs), and hexagonal boron nitride (hBN) have attracted a large amount of interests due to their extraordinary electrical, optical, and mechanical properties comparing with their bulk counterparts. Recently, black phosphorus (BP) has emerged as a new 2D material with demonstrated high hole mobility, showing great potential in electronic applications such as field-effect transistors (FETs). In this talk we will first review our recent works on the electric, photo-electrical, mechanical, and thermal behaviors of few-layer black phosphorus [1-4]. We will then discuss the photonics applications of black phosphorus. 2D black phosphorus is an excellent candidate for use in photodetection devices due to its direct and thickness-dependent bandgap [1]. However, light absorptions in these 2D materials are often very low due to its ultra- thin nature. For example, the visible light absorption in single layer graphene is only 2.3%. Making plasmonic structures, such as nano disks and rods, on top of the 2D material can be a possible way to enhance the absorption. In our work, a new bowtie-like plasmonic structure was proposed, and numerical simulations were used to design and optimize the plasmonic structures that are used to enhance both absorption and polarization selectivity in black phosphorus photodetection devices. The optimized structure devices were then fabricated on black phosphorus on transparent substrate. Photocurrent measurements showed strong light polarization dependence/selectivity in the fabricated device as well as much stronger photo responsivity compared with devices without plasmonic enhancement. Our study demonstrated the potentials of black phosphorus for photodetection and other light harvesting applications. [1]	Liu, H., Neal, A., Zhu, Z., Luo, Z., Xu, X., Tomanek, D., Ye, P.D., 2014, “Phosphorene: An Unexplored 2D Semiconductor with a High Hole Mobility,” ACS Nano, 8(4), pp. 4033–4041. [2]	Deng, Y., Luo, Z., Conrad, N. J., Liu, H., Gon,g Y., Najmaei, S., Ajayan, P. M., Lou, J., Xu, X., and Ye, P. D., 2014, “Black Phosphorus-Monolayer MoS2 van der Waals Heterojunction P-N Diode.,” ACS Nano, 8(8), pp. 8292–8299. [3]	Luo, Z., Maassen, J., Deng, Y., Du, Y., Garrelts, R. P., Lundstrom, M. S., Ye, P. D., and Xu, X., 2015, "Anisotropic in-plane thermal conductivity observed in few-layer black phosphorus", Nat. Commun. 6:8572, pp. 9572-1-8. [4]	Du, Y., Maassen, J., Wu, W., Luo, Z., Xu, X., and Ye, P., 2016, "Auxetic Black Phosphorus: A 2D Material with Negative Poisson’s Ratio", Nano Lett., DOI: 10.1021/acs.nanolett.6b03607.


Ultrafast near-field imaging of excitonic waves formation and propagation in WSe2 waveguides (Conference Presentation)


Over the recent years, van der Waals (vdW) materials, a class of materials composed of weakly bound two-dimensional (2D), atomically thin, crystalline layers, have attracted great interest due to their ability to deeply confine light and therefore significantly enhance its interaction with matter. This interaction is embodied in coupled states between light and the polarization of the media, polaritons. The most studied type of polaritons, plasmon polariton, stems from the collective oscillations of conduction electrons. These, however, suffer great losses and therefore offer limited applications. Recently, among the several other types of polaritons supported by vdW materials, the exciton polariton (EP) has stimulated intense research efforts because it can sustain both strong light– matter interactions and long-distance propagation that is necessary for applications associated with energy harvesting or information manipulation and transfer. In this context, WSe2 is of particular interest for integrated applications since it supports EP modes in the Visible- Near Infrared (VIS-NIR) spectral region at room temperature due to its tightly bond excitonic state. In the quest to unravel the underlying physics, scanning near field optical microscope (SNOM) has provided valuable insights on the nature of the steady state EP modes sustained in vdW and in WSe2 in particular. However the dynamics of the EP formation, happening in the first few hundreds of femtoseconds subsequent to light absorption, remains largely unexplored. Here we employ a unique broadband ultrafast near-field pump-probe imaging method and observe for the first time, at femtosecond and nanometric spatiotemporal scale, the dynamics of the EP waves generation and propagation in WSe2 waveguides. Our observations suggest an important interplay between the waveguide EP mode and the tip-supported plasmon. Morever, we observe an intriguing ultrafast change in the EP waveguiding properties of the WSe2 waveguides happening in the first few hundreds of femtoseconds of the EP wave formation. Our method paves the way to in-situ ultrafast coherent control of EPs modes in vdW materials.


Electrochemical nanoimpacts monitoring, developed within the last decade, is based on the time-resolved detection of stochastic collisions of individual NanoParticles (NPs) in micro/nano-confined electrochemical cells[1]. Although electrochemical techniques are now able to measure electron transfer processes associated to single NP impacts, they are not spatially resolved and fail to characterize complex multiple chemical events. Superlocalization optical microscopies have recently allowed a complementary visualization of the transformation of NPs during electrochemical reactions. We proposed the coupling of holographic microscopy to electrochemistry[2] to record scattering by individual NPs. Real-time holograms are reconstructed in order to superlocalize and track several individual NPs in 3D with 3x3x10 nm3 accuracy. During Ag electrodissolution experiments, it allowed the 3D monitoring of Brownian or phoretic motion and individual dissolution. In situations where chemical transformations occur, spectroscopy associated to finite element or FDTD modelling can provide additional information on individual NPs during electrochemical processes. We will illustrate the possibilities of this coupled characterization in several systems, where 3D particle tracking can provide a NP size estimate during the Brownian approach of the particle. During chemical reactions on the metal interface, we will show that holography, spectroscopy, associated to an optical model of the scattering, gives access to relevant information on the size, position, and composition of the NPs. [1]Y.Zhou et al, Angew. Chem. 2011, X.Xiao et al. J. Am. Chem. Soc. 2007 [2] V.Brasiliense et al., Acc. Chem. Res., 2016 V.Brasiliense et al. J. Am. Chem. Soc., 2016 A.N Patel et al. Nano Lett., 2015